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HomeMy WebLinkAboutNCS000522_HISTORICAL WITH APPLICATION_20071204STORMWATER DIVISION CODING SHEET PERMIT NO. DOC TYPE ❑FINAL PERMIT 0 MONITORING INFO APPLICATION COMPLIANCE ❑ OTHER DOC DATE ❑ _Za'l IZ 0 YYYYMMDD Michael F. Easley, Governor State of North Carolina December 4, 2007 DEC 6 2007 Mr. Robert Rebello, President � US Polymers NC DENR MRO 4330 Chesapeake Drive Charlotte, North Carolina 28216 DWQSuddce Watc+ Subject: Draft NPDES Stormwater Permit Permit No. NC-S000522 US Polymers - Charlotte, NC Mecklenburg County Dear Mr. Rebello: Enclosed with this letter is a copy of the draft stormwater permit for your facility. Please review the draft very carefully to ensure thorough understanding of the conditions and requirements it contains. The draft permit contains the following significant items for this facility's future permit: • All analytical monitoring is semi-annual. This makes stormwater discharge sampling frequency consistent with qualitative monitoring. Please note that analytical monitoring must be performed during a representative storm event. • Monitoring is not required at SDO #3. There are no industrial activities in this drainage area. If this changes in the future, the Division must be notified in writing. • The Division has incorporated benchmark values into the permit. These benchmarks are not permit limits but should be used as guidelines for your facility's Stormwater Pollution Prevention Plan (SPPP). If any measurements exceed benchmark values, your facility should evaluate the effectiveness of its Best Management Practices (BMPs), review and/or update its SPPP, and document any efforts to address stormwater contamination (see Part II, Sections B and D). • The permit requires Total Rainfall amount be recorded for each sampling event. Please note that the Stormwater Pollution Prevention Plan (SPPP) site map must include drainage area for each autfall in acres and the percentage of each drainage area that is impervious (see Part H, Sec. A). Please submit any comments to me no later than thirty (30) days following your receipt of the draft. Comments should be sent to the address listed at the bottom of this page. If no adverse comments are received from the public or from you, this permit will likely be issued in about two months. If you have any questions or comments concerning this draft permit, contact me at (919) 733-5083 x 360 or robert,patterson@ncmail.net. North Carolina Division of Water Quality (919) 733-7015 1617 Mail Service Center FAX (919) 733-0719 Raleigh, North Carolina 27699-1617 On the Internet at http://h2o.enr.state.nc.us/ Mr. Robert Rebello US Polymers Permit No. NCS000522 Page 2 Sincerely, Robert D. Patterson, P.E. Environmental Engineer t ' v Stormwater Permitting Unit cc: David Kirby - Project Integration Inc, PO Box 1414, Greer, SC 29652-1414 (w/ attachment) Mooresville Regional Office, Water Quality Section (w/ attachment) Stormwater Permitting Unit Attachments VJ NCS000522 STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY . PERMIT TO DISCHARGE STORMWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provisions of North Carolinaf'General Statute 143-215.1, other lawful 'I �v standards and regulations promulgated and adopted by�le6 North Carolina Environmental Management Commission, and the Federal Water Pollutions:Control Act, as amended, US°Polymers is hereby sch authorized'Yo dirge stormwater from a facility located at %'I' US Polymers 1 4336 Chesapeake Drive Charlotte, NC Mecklenburg County to receiving waters designated as Stewart Creek, a class C stream in the Catawba River Basin, in accordance with the discharge limitations, monitoring requirements, and other conditions set forth in Parts I, II, III, IV, V and VI hereof. Note: Draft Permit Dates are Approximate This permit shall become effective February 1, 2008. This permit and the authorization to discharge shall expire at midnight on January 31, 2013. Signed this 28`}' day of January, 2008. for Coleen H. Sullins Director Division of Water Quality By the Authority of the Environmental Management Commission r Permit No. NCS000522 PART Section A: Section B: Section C: PART II Section A: Section B: Section C: Section D: TABLE OF CONTENTS INTRODUCTION Individual Permit Coverage Permitted Activities Location h MONITORIN, DISCHARGE Stormwate Analytical Qualitativc, On -Site Vt PERMITTED PART III STANDARD CONDITIONS FOR NPDES STORMWATER INDIVIDUAL PERMITS Section A: Compliance and Liability 1. Compliance Schedule 2. Duty to Comply 3. Duty to Mitigate 4. Civil and Criminal Liability 5. Oil and Hazardous Substance Liability 6. Property Rights 7. Severability 8. Duty to Provide Information 9. Penalties for Tampering 10. Penalties for Falsification of Reports Section B: General Conditions 1. Individual Permit Expiration 2. 'Transfers k i Permit No. NCS000522 3. Signatory Requirements 4. Individual Permit Modification, Revocation and Reissuance, or Termination 5. Permit Actions Section C: Operation and Maintenance of Pollution Controls 1. Proper Operation and Maintenance 2. Need to Halt or Reduce Not a Defense 3. Bypassing of Stormwater Control Facilities Section D: Monitoring and Records 1. Representative Sampling 2. Recording Results 3. Flow Measurements y� 4. Test Procedures 5. Representative utfall, 6. 7. Records''Rete4t on Inspection,ardaEntry Section E:. Reporting Requirements 1. DiscYiargMonitoring Reports 2. Submitting Reports 3. Availability of Reports 4. Non-Stormwater Discharges 5. Planned Changes 6. Anticipated Noncompliance .7. Bypass 8. Twenty-four Hour Reporting 9. Other Noncompliance 10. Other Information PART IV LIMITATIONS REOPENER PART V. ADMINISTERING AND COMPLIANCE MONITORING FEE REQUIREMENTS PART VI DEFINITIONS ii Permit No. NCS000522 PART I INTRODUCTION SECTION A: INDIVIDUAL PERMIT COVERAGE During the period beginning on the effective date of the permit and lasting until expiration, the permittee is authorized to discharge stormwater associated with industrial activity. Such discharges shall be controlled, limited and monitored as specified in this permit. If industrial materials and activities are not exposed to precipitation or runoff as described in 40 CFR § I22.26(g), the facility may qualify for. a No Exposure Exclusion from NPDES stormwater discharge permit. requirements. Any owner or operator wishn,dl: g,:to obtain a No Exposure .c Certification must submit a No Exposure CertificationINi•'Ol- form to the,,Division; must receive. approval by the Division; must maintain no exposure,,conditions unless authorized to discharge under a valid NPDES stormwater permit; and must re pply for the -No Exposure Exclusion once every five (5) years. �. 44 SECTION B: PERMITTED ACTIVITIES Until this permit expires or is modified'or revoked; the permittee is authorized to discharge stormwater to the surface waters'of NorthaCarolina or separate storm sewer system that has been adequately treated and managed n1fdcardance with the terms and conditions of this individual permit. All stormwater discharges shall -be in accordance with the conditions of this permit. Any other point source dischargetovsurface waters of the state is prohibited unless it is an allowable non-stormwater discharge or is covered by another permit, authorization, or approval. The stormwater discharges allowed by this individual permit shall not cause or contribute to violations of Water Quality Standards. This permit does not relieve the permittee from responsibility for compliance with any other applicable federal, state, or local law, rule, standard, ordinance, order, judgment, or decree. Part 1 Page 1 of 2 SECTION C: LOCATION MAP Permit No. NCS000522 * Y � � -, i^r��"�1��ie}0 � � rki '!� x � t �,k� l ��+�`' ��- N� 3�} lri+ti + .`�i . �'y�` � N...• �, r - , r �� !Axx } ZI117 4 x _ � . � i `yr.. �� y ,�: $ r � d ti� "a� T � �r��' i.✓ _ + ' � ��,,.r r . r;IM-^,�r�ti ��z 4�,��' ". �_ -� '�� s° tf�' � � - ^�„ " • I :� � I +� �+' J � �,I ! . . y� rt . �e'`�k� � ; �, • ,. � I' � � n � iti t »i��CGa � '� � '�F ft• � � �> k i,7_�to� Yr. .,�� { a �. 1 �,y' t i ti s /" I� k •u q'1J1� �54y r 5 ��y.Y �.�u' R." � y.� � , �r r .iR ( �! .�y ,] �S.'�•: �1 u�1n 1� � J�4 'r Y.- .��� A � �.'�, 4. '�'� W �. J�. i x!' i7 f`�'1 - 1"���, �"1'f ��_ �.^'�� i'^�f� ♦l� Y.r�F T r •�4 r � .�-* . . • 'S xh ''a ,_ 7Y,� ��' l� ~' , i R },� •1�,d ��a � , 33 �� 11�,`'-�..'`:ti�,,��` 1 � , �, � °t r � 1 $°` �«„,. '-re Y r'- Y!"'• �...' �}� _�,�. r {4P*'� * �a"wb.:r . r +'. .rxC% b s ar-r a. � � � r 4� i. `9., li'"i � " �,� .r`�.✓ 4k�,,� y+ S t «',' :� AI ,,�.�' • �, w, 4 ?�r� � xr w � �} '' r�� � � g ..�,` i � 3 ,1' 11 "�• •� r � . y, r� r z,.�'( �+ Y :. n '=° 'S*'$ I L�,..�,pvaJ 't• ��' � .� it f. ,....., "e tL � , � �� ip U-S i?oiymers P xi + +4w W t Spy°w r ;, 3i - :` AFIR 1 y _ NX ^f'� .�p y '�'",,� ��" � tk' d Ai � �-„ � x �'' a � ✓r` ill '�*� . [ ♦.—'.t`"'^y hyy r. a °fit , • T irN .r� . ti f�,. � � -� L 6 ��, NCSO0O522 N W E S US Polymers, Inc. US Polymers - Charlotte Latitude: 351, 16' 40" N Longitude: 800 52' 20" W Recelving Stream: Stewart Creek Stream Ciass: C Sub -basin: 03-08-34 (Catawba River Basin) Facility Location Part I Page 2 of 2 Permit No. NCS000522 PART II MONITORING, CONTROLS, AND LIMITATIONS FOR PERMITTED DISCHARGES SECTION A: STORMWATER POLLUTION PREVENTION PLAN The permittee shall develop a Stormwater Pollution Prevention Plan, herein after referred to as the Plan. This Plan shall be considered public information in accordance with Part III, Standard Conditions, Section E, Paragraph 3 of this individual permit. The Plan shall include, at a minimum, the following items: Site Plan. The site plan shall provide a description of thephysical facility and the potential pollutant sources that may be expected,to contfibute to contamination of stormwater discharges. The site plan shall contain tlie;following: a. A general location map (USGS quadrangle,map or -appropriately drafted equivalent map), showing the facility' location in relation to transportation routes and surface waters, the name Hof the rece receiving water(s) to which the stormwater outfall(s) discharges, or if the discharge is to a municipal separate storm sewer system, the name. of municipality and the ultimate receiving waters; and accurate latitude and longitude of the point(s) of discharge. The map / ,� ss.+ 4,+� should identify whether ea,"ch,receiving water is impaired (on the state's 303(d) List of impaired atrs) r''is,locatcd in a watershed for which a TMDL has been established�d'what the parameter(s) of concern are. North Caroline s 303(Z`List can be found here: http://h2o.enr.state.nc.us/tmdl/Gencral_3d3d.htm#Downloads North CarolinI'MDL documents can be found here: http://h2o.enr.state.ac.us/tmdV]7MDL—list.htm#Final—TMDLs b. A narrative description of storage practices, loading and unloading activities, outdoor process areas, dust or particulate generating or control processes, and waste disposal practices. A narrative description of the potential pollutants which could be expected to be present in the stormwater discharge from each outfall. C. A site map drawn to scale with the following items: (1) Distance legend and north arrow (2) Site property boundary and topography (3) Location of industrial activities (including storage of materials, disposal areas, process areas, and loading and unloading areas) (4) Drainage features and structures (5) Stormwater discharge points (outfalls) (6) Delineated drainage areas for each outfall (7) Drainage area for each outfall in acres and percentage or each . drainage area that is impervious (8) All on -site and adjacent surface waters and wetlands. (9) Building locations Part 1I Page l of 10 Permit No. NCS000522 (10) Existing BMPs and impervious surfaces d. A list of significant spills or leaks of pollutants that have occurred at the facility during the three (3) previous years and any corrective actions taken to mitigate spill impacts. e. Certification that the stormwater outfalls have been evaluated for the presence of non- stormwater discharges. The certification statement will be signed in accordance with the requirements found in Part III, Standard Conditions, Section B, Paragraph 3. 2. Stormwater Management Plan. The stormwater management plan shall contain a narrative description of the materials management practices employed which control or minimize the exposure of significant materials to stormwa er, including structural and nonstructural measures. The stormwater management,,plan, at a.minimum, shall incorporate the following: a. Feasibility Study. A review of the techni6al7and economic feasibility of changing NJ) WN the methods of operations and/or storage practices to eliminate or reduce exposure of materials and processes to stormwater. 7,Wherever practical, the permittee shall prevent exposure of all storage areas material handling operations, and . parr W manufacturing or fueling operations.,Jn areas where elimination of exposure is not practical, the stbrmwaterfmanagement plan shall document the feasibility of diverting the stormwater runaffaway from areas of potential contamination. b. Secondary ContainmentRequirements and Records. Secondary containment is required for: bulk storage of liquid materials; storage in any amount of Section 313 of Title IIiof the perfund Amendments and Reauthorization Act (SARA) water priority ch'eiricals; and storage in any amount of hazardous substances to prevent leaks and spills from contaminating stormwater runoff. A table or summary of all such tanks and stored materials and their associated secondary containment areas shall be maintained. If the secondary containment devices are connected directly to stormwater conveyance systems, the connection shall be controlled by manually activated valves or other similar devices which shall be secured closed with a locking mechanism, and any stormwater that accumulates in the containment area shall be at a minimum visually observed for color, foam,. outfall staining, visible sheens and dry weather flow, prior to release of the accumulated stormwater. Accumulated stormwater shall be released if found to be uncontaminated by the material stored within the containment area. Records documenting the individual making the observation, the description of the accumulated stormwater and the date and time of -the release shall be kept for a period of five (5) years. BMP Summary. A narrative description shall be provided of Best Management Practices (BMPs) to be considered such as, but not limited to, oil and grease separation, debris -control, vegetative filter strips, infiltration and stormwater detention or retention, where necessary. The need for structural BMPs shall be based on the assessment of the potential of pollutant sources to contribute Part II Page 2 of 10 Permit No. NCS000522 significant quantities of pollutants to stormwater discharges and data collected through monitoring of stormwater discharges. 3. Spill Prevention and Response Plan. The Spill Prevention and Response Plan (SPRP) shall incorporate an assessment of potential pollutant sources based on a materials inventory of the facility. Facility personnel (or team) responsible for implementing the SPRP shall be identified. A responsible person shall be on -site at all times during facility operations that have the potential to contaminate stormwater runoff through spills or exposure of materials associated with the facility operations. The SPRP must be site stormwater specific. Therefore, an oil SPCC plan may be a component of the SPRP, but may not be sufficient to completely address the stormwater aspects of the SPRP. The common elements of the SPCC with the SPRP may be incorporated by reference into the SPRP. A.. 4. Preventative Maintenance and Good Housekeeping%Prdgrain: A preventative maintenance program shall be developed. The program shall document schedules of inspections and maintenance activities of stormwater: control systems, plant equipment and systems. Inspection of material handling areas -and regular cleaning schedules of these areas shall be incorporated into the p gram.: Employee Training. Training schedules sha1l°lie developed and training provided at a minimum on an annual basis on%proper spill response and cleanup procedures and preventative maintenance activities°far;all personnel involved in any of the'facility's operations that have the pote ' ial,to contaminate stormwater runoff. Facility personnel V. (or team) responsible for mplementing the training shall be identified. 6. Responsible Party. Tbj �Stormwater Pollution Prevention Plan shall identify a specific position(s) responsible'�O'the overall coordination, development, implementation, and revision to the Plan. Responsibilities for all components of the Plan shall be documented and position assignments provided. 7. Plan Amendment. The permittee shall amend the Plan whenever there is a change in design, construction, operation, or maintenance that has a significant effect on the potential for the discharge of pollutants to surface waters. The Stormwater Pollution Prevention Plan shall be reviewed and updated on .an annual basis. The annual update shall include an updated list of significant spills or leaks of pollutants for the previous three years, or the notation that no spills have occurred. The annual update shall include re -certification that the stormwater outfalls have been evaluated for the presence of non- stormwater discharges. The Director may notify the permittee when the Plan does not meet one or more of the minimum requirements of the permit. Within 30 days of such notice, the permittee shall submit a time schedule to the Director for modifying the Plan to meet minimum requirements. The permittee shall provide certification in writing (in accordance with Part III, Standard Conditions, Section B, Paragraph 3) to the Director that the changes have been made. Part II Page 3 of 10 0- Permit No. NCS000522 8. Facility Inspection Program. Inspections of the facility and all stormwater systems shall occur at a minimum on a semi-annual schedule, once during the first half of the year (January through June) and once during the second half (July through December), with at least 60-days separating inspection dates (unless performed more frequently). The inspection and any subsequent maintenance activities performed shall be documented, recording date and time of inspection, individual(s) making the inspection and a narrative description of the facility's stormwater control systems, plant equipment and systems. Records of these inspections shall be incorporated into the Stormwater Pollution Prevention Plan. These facility inspections are different from, and in addition to, the stormwater discharge characteristic monitoring required in Part II of this permit. 9. Implementation. The permittee shall implement the Plan. The permittee shall document all monitoring, measurements, inspections and maintenance activities and training provided to employees, including the log of thePsamplin g data amend of actions taken to implement BMPs associated with the industrial activities including vehicle maintenance activities. Such documentation shall be kept otis to for a period of five years and made available to the Director or the Director's authorized,.representative immediately upon request. Part II Page 4 of 10 A . Permit No. NCS000522 SECTION B: ANALYTICAL MONITORING REQUIREMENTS Analytical monitoring of stormwater discharges shall be performed as specified in Table 1. All analytical monitoring shall be performed during a representative storm event. The required monitoring will result in a minimum of ten analytical samplings being conducted over the term of the permit at each stormwater discharge outfall (SDO). A representative storm event is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no precipitation. For example, if it rains for 2 hours without producing any collectable discharge, and then stops, a sample may be collected if a rain producing a discharge begins again within the next 10 hours. ,fh.., Table 1. Analytical Monitoring,Requi Measureme'nt Fre uenc 1 Sam le Sam le Characteristicsr �"-Units ` ' T I;ocation3 eZ ,, Ac lamide m semi-annual ,;... Grab SDO Total Sus ended Solids m L semi-annual Grab SDO „ Oil and Grease m ILA;,," semi-annual Grab SDO H `T' standard_ semi-annual Grab SDO a Total Rainfall � ' I'� tnches�sr�ll�> � semi-annual ain Gauge - Footnotes: i� Measurement Frequency: Twice per year during a representative storm event, for each year until either another permit is issued for this facility or until this permit is revoked or rescinded. If at the end of this permitting cycle the permittee has submitted the appropriate paperwork for a renewal permit before the submittal deadline, the permittee will be considered for a renewal application. The applicant must continue semi-annual monitoring until the renewed permit is issued. See Table 2 for schedule of monitoring periods through the end of this permitting cycle. 2 If the stormwater runoff is controlled by a stormwater detention pond, a grab sample of the discharge from the . pond shall be collected within the first 30 minutes of discharge. 3 Sample Location: Samples shall be collected at each stormwater discharge outfall (SDO) unless representative outfall status has been granted. 4 For each sampled representative storm event the total precipitation must be recorded. An on -site rain gauge or local rain gauge reading must be recorded. Part lI Page 5 of 10 Permit No. NCS000522 The permittee shall complete the minimum ten analytical samplings in accordance with the schedule specified below in Table 2. A minimum of 60 days must separate Period 1 and Period 2 sample dates unless monthly monitoring has been instituted under a Tier Two response. Table 2. Monitoring Schedule Monitoring periodI'Z, '' Sa'mple`Numlier ... ii , start' $ l r r End- -Year 1 — Period 1 1 January 1, 2008 June 30, 2008 Year 1 — Period 2 2 July 1, 2008 December 31, 2008 Year 2 — Period 1 3 January 1, 2009 June 30, 2009 Year 2 — Period 2 4 July 1, 2009 December 31, 2009 Year 3 — Period 1 5 January 1,?2O_ b June 30, 2010 Year 3 — Period 2 6 July 1, 20IT, r December 31, 2010 Year 4 —Period 1 7 January41, 20f1,,jar , June 30, 2011 Year 4 — Period 2 8 July" 2011 December 31, 2011 Year 5 — Period 1 9 January,,rl,` 2012 June 30, 2012 Year 5 — Period 2 10 y�l; 2012 December 31, 2012 Footnotes: I Maintain semi-annual monitoring during monitoring until the renewed permit -is is 2 If no discharge occurs during the samprlu Flow" within 30 days of the end of tl The applicant must continue semi-annual �ermittee must submit a monitoring report indicating "No ing period. Monitoring results shall be compared to the benchmark values in Table 3. The benchmark values in Table 3 are not permit limits but -should be used as guidelines for the permittee's Stormwater Pollution Prevention Plan (SPPP). Exceedences of benchmark values require the permittee to increase monitoring, increase management actions, increase record keeping, and/or install stormwater Best Management Practices (BMPs) in a tiered program. See below the descriptions of Tier One and Tier Two. Table 3_ Benchmark Valuer for Analvtical Monitoring Discharge Characteristics `E' '' Units ;;; ,r' ,r Acrylamide mg/L 28 Total Suspended Solids mg/L 100 Oil and Grease mg/L 30 LPH standard 1 6 - 9 PartIl Page 6 of I0 Permit No. NCS000522 74 ]��Tj: Al.ierOnem 7 If: The sampling results are above a benchmark value, or outside of the benchmark range, for any parameter at any outfall; Then: The permittee shall: 1. Conduct a stormwater management inspection of the facility within two weeks of receiving sampling results. 2. Identify and evaluate possible causes of the benchmark value exceedence. 3. Identify potential, and select the specific: source controls, operational controls, or physical "A 10�1 improvements to reduce concentrations of the parametcr§ of concern, or to bring concen trations to within the benchmark range. 4. Implement the selected actions within two months of the inspection. 4/ 5. Record each instance of a Tier One response in.,the St6rmwater Pollution Prevention Plan. Include the date and value of the benchmark ekceede"&e, the inspection date, the personnel 4f 1� I 11 conducting the inspection, the selectedlactions, Eiih-a the date the selected actions were Nz5V implemented. S4'( (�, ier. W T, T! o If. During the term of this pennit, the sampling results are above the benchmark values, or outside of the benchmark range, for any specific parameter at a specific discharge outfall two times in a row (consecutive); Then: The permittee shall: 1. Repeat all the required actions outlined above in Tier One. 2. Immediately institute monthly monitoring for all parameters at every outfall where a sampling result exceeded the benchmark value for two consecutive samples. Monthly (analytical and qualitative) monitoring shall continue until three consecutive sample results are below the benchmark values, or within the benchmark range, for all parameters at that outfall. 3. If no discharge occurs during the sampling period, the pehnittee is required to submit a monthly monitoring report indicating "No Flow". 4. Maintain a record of the Tier Two response in the Stormwater Pollution Prevention Plan. Part 11 Page 7 of 10 Permit No. NCS000522 During the term of this permit, if the sampling results exceed the benchmark value, or are outside the benchmark range, for any specific parameter at any specific outfall on more than four occasions, DWQ may: • Require that the permittee increase or decrease the monitoring frequency for the remainder of the permit; • require the permittee to install structural stormwater controls; • require the permittee to implement other stormwater control measures; or • require that the permittee implement site modifications to{qualify for the No Exposure Exclusion. X This site discharges to a tributary of an impaired coliform bacteria. A Total Maximum Daily Load Watershed. The permittee may required tome future and submit results to the Division of�Watei monitoring results in determining whether tidditi of concern to the maximum exterit�,ijiacticable. Kp encing problems with fecal ,).was approved for the Irwin Creels ,the pollutant(s) of concern in the . The Division will consider the :Is are needed to control the pollutant(s) If additional BMPs are needed to achieve�the required level of control, the permittee will be required to (1) develop a strat gy for implementing appropriate BMPs, and (2) submit a timetable for incorporation of those BMPs into; the permitted Stormwater Pollution Prevention Plan. Part I Page 8 of 10 Perm it No. NCS000522 SECTION C: QUALITATIVE MONITORING REQUIREMENTS Qualitative monitoring requires a visual inspection of each stormwater outfall regardless of representative outfall status and shall be performed as specified in Table 4, and during the analytical monitoring event. Qualitative monitoring is for the purpose of evaluating the effectiveness of the Stormwater Pollution Prevention Plan (SPPP) and assessing new sources of stormwater pollution. In the event an atypical condition is noted at a stormwater discharge outfall, the permittee shall document the suspected cause of the condition and any actions taken in response to the discovery. This documentation will be maintained with the SPPP,, Table 4 Qualitative Monitoring Re utremen t9� D�sehargc Char1.acteristics , Frequencyt Monrtortng n, ���'t Lo�cation2 Color semi-annual �.SD.O ,� Odor semi-annual ' ,... Sa✓DO Clarity semi-annual f )/ SDO Floating Solids ,,semi„ani ual SDO Suspended Solids 'semi arnu 1, SDO Foam en i-annual SDO Oil Sheen semi'Lual SDO Erosion or deposition at the r "', semi-annual SDO outfall Other obvious indicators semi-annual SDO of stormwater pollution Footnotes: 1 . Measurement Frequency: Twice per year during a representative storm event, for each year until either another permit is issued for this facility or until this permit is revoked or rescinded. If at the end of this permitting cycle the permittee has submitted the appropriate paperwork for a renewal permit before the submittal deadline, the permittee will be considered for a renewal application. The applicant must continue semi-annual monitoring until the renewed permit is issued. See Table 2 for schedule of monitoring periods through the end of this permitting cycle. 2 Monitoring Location: Qualitative monitoring shall be performed at each stormwater discharge outfall (SDO) regardless of representative outfall status. SECTION D: ON -SITE VEHICLE MAINTENANCE MONITORING REQUIREMENTS Facilities which have any vehicle maintenance activity occurring on -site which uses more than 55 gallons of new motor oil per month when averaged over the calendar year shall perform analytical monitoring as specified below in Table 5. This monitoring shall be performed at all stormwater discharge outfalls which discharge stormwater runoff from vehicle maintenance Part I Page 9 of 10 Permit No. NCS000522 areas, and in accordance with the schedule presented in Table 2 (Section B). All analytical monitoring shall be performed during a representative storm event. Table 5. Analytical Monitoring Requirements for On -Site Vehicle Maintenance Discharge Characteristics Units i Measurement + Sam' le'Samp e a r �u �� a -°.f 3 �..1 Fre a 2 9 Location 3' ;r; E 4.> uenc �. :T ,. H standard semi-annual Grab SDO Oil and Grease m /l semi-annual Grab SDO Total Suspended Solids mgzl semi-annual Grab SDO Total Rainfa114 inches semi-annual Rain gaue New Motor Oil Usagegallons/month I semi-annual Estimate Footnotes: l Measurement Frequency: Twice per year during a represent permit is issued for this facility or until this permit is revoke the permittee has submitted the appropriate paperwork for a permittee will be considered for a renewal application. The. the renewed permit is issued. See Table 2 for schedule 0 m' cycle. lfl 'f 2 If the stormwater runoff is controlled by a pond shall be collected within the frst;30 i 3 Sample Location: Samples shall be stormwater runoff from area(s) whe 4 For each sampled repr gauge reading must be of ,n event, far"'each year until either another ndedif t the end of this permitting cycle Permit before the submittal deadline, the must continue semi-annual monitoring until periods through the end of this permitting i pond a grab sample of the discharge from the from the pond. water discharge outfall (SDO) that discharges activities occur. the total precipitation must be recorded. An on -site or local rain Monitoring results shall be compared to the benchmark values in Table 6. The benchmark values in Table 6 are not permit limits but should be used as guidelines for the permittee's Stormwater Pollution Prevention Plan (SPPP). Exceedences of benchmark values require the permittee to increase monitoring, increase management actions, increase record keeping, and/or install stormwater Best Management Practices (BMPs), as provided in Part II Section B. Table 6. Benchmark Values for Vehicle Maintenance Analytical Monitoring Drscha rge Characteristics;' '� Units' !',:. ,, 1 ;'...;.._ ''Benchmark pH standard 6-9 Oil and Grease mg/L 30 Total Suspended Solids mg/L 100 Part II Page 10 of 10 Permit No. NCS000522 PART III STANDARD CONDITIONS FOR NPDES STORMWATER INDIVIDUAL PERMITS SECTION A: COMPLIANCE AND LIABILITY Compliance Schedule The permittee shall comply with Limitations and Controls specified for stormwater discharges in accordance with the following schedule: Existing Facilities already operating but applying for permit coverage for the first time: The Stormwater Pollution Prevention Plan shall be developed and implemented within 12 months of the effective date of the initial permit and updated thereafter on an annual basis. Secondary containment, as specified in Part II, Section A, Paragraph 2(b) of this permit, shall be accomplished within,l2 months of the effective date of the initial permit issuance. ,a New Facilities applying for coverage for the first time and exist gkf tcilities previous) permitted and g o r" N. , previously applying for renewal under this permit: The Stormwater�Pollution Prevention Plan shall be developed and implemented prior to the beginning of discharges from the operation of the industrial activity and be updated thereafter on an annual basis. Secondary containment, as;specified in Part II, Section A, Paragraph 2(b) of this permit shall be accomplished prior to'. e9beginr rung of discharges from the operation of the industrial activity. Duty to Comply ; The permittee must comply witl�all,conditi ns�of this individual permit. Any permit noncompliance constitutes a violation of the Clean `VJdter Act;and is grounds for enforcement action; for permit --,kV termination, revocation and reissuance,K -r. odi ication; or denial of a permit upon renewal application. a. The permittee shall•complyiwith standards or prohibitions established under section 307(a) of the Clean Water Act,fdritoxic pollutants within the time provided in the regulations that establish these standards or prohigitio s even if the permit has not yet been modified to incorporate the requirement. b. The Clean Water Act provides that any person who violates a permit condition is subject to a civil penalty not to exceed $27,500 per day for each violation. Any person who negligently violates any permit condition is subject to criminal penalties of $2,500 to $25,000 per day of violation, or imprisonment for not more than 1 year, or both. Any person who knowingly violates permit conditions is subject to criminal penalties of $5,000 to $50,000 per day of violation, or imprisonment for not more than 3 years, or both. Also, any person who violates a permit condition may be assessed an administrative penalty not to exceed $11,000 per violation with the maximum amount not to exceed $137,500..[Ref: Section 309 of the Federal Act 33 USC 1319 and 40 CFR 122.41(a).] C. Under state law, a daily civil penalty of not more than twenty-five thousand dollars ($25,000) per violation may be assessed against any person who violates or fails to act in accordance with the terms, conditions, or requirements of a permit. [Ref: North Carolina General Statutes 143- 215.6A] d. Any person may be assessed an administrative penalty by the Director for violating section 301, 302, 306, 307, 308, 318, or 405 of the Act, or any permit condition or limitation implementing any of such sections in a permit issued under section 402 of the Act. Administrative penalties for Class I violations are not to exceed $11,000 per violation, with the maximum amount of any Class I penalty assessed not to exceed $27,500. Penalties for Class II violations are not to exceed $11,000 Part III Page I of 8 Permit No. NCS000522 per day for each day during which the violation continues, with the maximum amount of any Class II penalty not to exceed $137,500. 3. Du!,Du!y to Mitigate The permittee shall take all reasonable steps to minimize or prevent any discharge in violation of this individual permit which has a reasonable likelihood of adversely affecting human health or the environment. 4. Civil and Criminal Liability Except as provided in Part I11, Section C of this permit regarding bypassing of stormwater control facilities, nothing in this individual permit shall be construed to relieve the permittee from any responsibilities, liabilities, or penalties for noncompliance pursuant to NCGS 143-215.3, 143-215.6A, 143-215.613, 143- 215.6C or Section 309 of the Federal Act, 33 USC 13 l9. Furthermore, the permittee is responsible for Ile consequential damages, such as fish kills, even though the responsibility for effective compliance may be temporarily suspended. A ,, J7 5. Oil and Hazardous Substance Liability Nothing in this individual permit shall be construed to:preclude'the institution of any legal action or relieve the permittee from any responsibilities, liabilitie�j�or,pgenalties'to which the permittee is or may be subject to under NCGS 143-215.75 et seq. or Section 311 of the FederahAct, 33 USG 1321. 6. Property Rightsi , 1r The issuance of this individual permit doesinot convey any property rights in either real or personal property, or any exclusive priville�ges fibr does t authorize any injury to private property or any invasion of personal rights, nor any infringement afilf9deral, State or local laws or regulations. 7. Severability The provisions of this individual permit are severable, and if any provision of this individual permit, or the application of any provision of this in permit to any circumstances, is held invalid, the application of such provision to other circumstances, and the remainder of this individual permit, shall not be affected thereby. 8. Duty to Provide Information The permittee shall furnish to the Director, within a reasonable time, any information which the Director may request to determine whether cause exists for modifying, revoking and reissuing, or terminating the permit issued pursuant to this individual permit or to determine compliance with this individual permit. The permittee shall also furnish to the Director upon request, copies of records required to be kept by this individual permit. 9. Penalties for Tampering The Clean Water Act provides that any person who falsifies, tampers with, or knowingly renders inaccurate, any monitoring device or method required to be maintained under this individual permit shall, upon conviction, be punished by a fine of not more than $10,000 per violation, or by imprisonment for not more than two years per violation, or by both. If a conviction of a person is for a violation committed after a first conviction of such person under this paragraph, punishment is a fine of not more that $20,000 per day of violation, or by imprisonment of not more than 4 years, or both. Part III Page 2 of 8 Permit No. NCS000522 10. Penalties for Falsification of Reports The Clean Water Act provides that any person who knowingly makes any false statement, representation, or certification in any record or other document submitted or required to be maintained under this individual permit, including monitoring reports or reports of compliance or noncompliance shall, upon conviction, be punished by a fine of not more than $10,000 per violation, or by imprisonment for not more than two years per violation, or by both. SECTION B: GENERAL CONDITIONS Individual Permit Expiration The permittee is not authorized to discharge after the expiration date�In order to receive automatic authorization to discharge beyond the expiration date,'the permittee'shall submit forms and fees as are required by the agency authorized to issue permits no later"than180'days prior to the expiration date. Any permittee that has not requested renewal at least 180 days prior to expiration, or any permittee that does not have a permit after the expiration and has not requested�"renewal at least 180 days prior to expiration, will be subjected to enforcement procedures as provided in NCGS.§.143-2153.E and 33 USC 1251 et. seq. Transfers This permit is not transferable to any Director may require modification or incorporate such other requirements required to notify the Divisionginvril 3. Signatory Requirements All applications, reports, a. All applications fte(notice to and approval by the Director. The eissuance of the permit to change the name and 01 ,ary under the Clean Water Act. The Permittee is the permitted facility is sold or closed. submitted to the Director shall be signed and certified. under this individual permit shall be signed as follows: (1) For a corporation: by a responsible corporate officer. For the purpose of this Section, a . responsible corporate officer means: (a) a president, secretary, treasurer or vice president of the corporation in charge of a principal business function, or any other person who performs similar policy or decision making functions for the corporation, or (b) the manager of one or more manufacturing production or operating facilities employing more than 250 persons or having gross annual sales or expenditures exceeding 25 million (in second quarter 1980 dollars), if authority to sign documents has been assigned or delegated to the manager in accordance with corporate procedures. (2) For a partnership or sole proprietorship: by a general partner or the proprietor, respectively; or (3) For a municipality, State, Federal, or other public agency: by either a principal executive officer or ranking elected official. b. All reports required by the individual permit and other information requested by the Director shall be signed by a person described above or by a duly authorized representative of that person. A person is a duly authorized representative only if (1) The authorization is made in writing by a person described above; Part III Page 3 of 8 Permit No. NCS000522 (2) The authorization specified either an individual or a position having responsibility for the overall operation of the regulated facility or activity, such as the position of plant manager, operator of a well or well field, superintendent, a position -of equivalent responsibility, or an individual or position having overall responsibility for environmental matters for the company. (A duly authorized representative may thus be either a named individual or any individual occupying a named position.); and (3) The written authorization is submitted to the Director. C. Any person signing a document under paragraphs a. or b. of this section shall make the following certification: "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submittedk%Based on my inquiry of the person or persons who manage the system, or those persons' dJrectlyresponsible for gathering the W i"� T-, 4F information, the information submitted is, to the best of my:knowledge and belief, true, accurate, and complete. I am aware that there are significant p nalti slf r submitting false information, %1. `n including the possibility of fines and imprisonment:,for knowing violations." 4. The issuance of this individual permit does naf prohibit the Director from reopening and modifying the individual permit, revoking and reissuing the ndivf.i ualXpermit, or terminating the individual permit as allowed by the laws, rules, and:regulatians�contaiued;in Title 40, Code of Federal Regulations, Parts 122 ` ' a , b ` and 123; Title 15A of the North Ciro]ina."Administrative Code, Subchapter 2H .0100; and North Carolina General Statute 143-215.1 et. al. 5. Permit Actions The permit may be modified;revok d and reissued or terminated for cause. The notification of planned changes or anticipated noncompliance does not stay any individual permit condition. SECTION C: OPERATION AND MAINTENANCE OF POLLUTION CONTROLS Proper Operation and Maintenance The permittee shall at all times properly operate and maintain all facilities and systems of treatment and control (and related appurtenances) which are installed or used by the permittee to achieve compliance with the conditions of this individual permit. Proper operation and maintenance also includes adequate laboratory controls and appropriate quality assurance procedures. This provision requires the operation of back-up or auxiliary facilities or similar systems which are installed by a permittee only when the operation is necessary to achieve compliance with the conditions of this individual permit. 2. Need to Halt or Reduce Not a Defense It shall not be a defense for a permittee in an enforcement action that it would have been necessary to halt or reduce the permitted activity in order to maintain compliance with the condition of this individual permit. 3. Bypassing of Stormwater Control Facilities Bypass is prohibited and the Director may take enforcement action against a permittee for bypass unless: Part III Page 4 of 8 Permit No. NCS000522 a. Bypass was unavoidable to prevent loss of life, personal injury or severe property damage; and b. There were no feasible alternatives to the bypass, such as the use of auxiliary control facilities, retention of stormwater or maintenance during normal periods of equipment downtime or dry weather. This condition is not satisfied if adequate backup controls should have been installed in the exercise of reasonable engineering judgment to prevent a bypass which occurred during normal periods of equipment downtime or preventive maintenance; and C. The permittee submitted notices as required under, Part III, Section E of this permit. If the Director determines that it will meet the three conditions listed above, the Director may approve an anticipated bypass after considering its adverse effects. SECTION D: MONITORING AND RECORDS I. Representative Sampling Samples collected and measurements taken, as required,terein;,shalI be characteristic of the volume and nature of the permitted discharge. Analytical sampling shall,b&performed during a representative storm event. Samples shall be taken on a day and time that�'is characteristic of the discharge. All samples shall be taken before the discharge joins or is diluted by any other waste stream, body of water, or substance. Monitoring points as specified in this permitshall not beichanged without notification to and approval of the Director. /c Recording Results For each measurement, sampler; -inspecti6fi,or maintenance activity performed or collected pursuant to the requirements of this individual permit the permittee shall record the following information: a. The date, exact place,and'fime of sampling, measurements, inspection or maintenance activity; b. The individual(s) who performed the sampling, measurements, inspection or maintenance activity; C. . The date(s) analyses were performed; d. The individual(s) who performed the analyses; e. The analytical techniques or methods used; and The results of such analyses. Flow Measurements Where required, appropriate flow measurement devices and methods consistent with accepted scientific practices shall be selected and used to ensure the accuracy and reliability of measurements of the volume of monitored discharges. 4. Test Procedures Test procedures for the analysis of pollutants shall conform to the EMC regulations published pursuant to NCGS 143-215.63 et. seq, the Water and Air Quality Reporting Acts, and to regulations published pursuant to Section 304(g), 33 USC 1314, of the Federal Water Pollution Control Act, as Amended, and Regulation 40 CFR 136. Part III Page 5 of 8 Permit No. NCS000522 To meet the intent of the monitoring required by this individual permit, all test procedures must produce minimum detection and reporting levels and all data generated must be reported down to the minimum detection or lower reporting level of the procedure. Representative Outfall If a facility has multiple discharge locations with substantially identical stormwater discharges that are required to be sampled, the permittee may petition the Director for representative outfall status. If it is established that the stormwater discharges are substantially identical and the permittee is granted representative outfall status, then sampling requirements may be performed at a reduced number of outfalls. 6. Records Retention Visual monitoring shall be documented and records maintained at Pollution Prevention. Plan. Copies of analytical monitoring result! permittee shall retain records of all monitoring information' incluc records and all original strip chart recordings for continuous mo i reports required by this individual permit for a period of at le st 5 measurement, report or application. This period may be extended Inspection and Ent the facility along with the Stormwater ,hall also be maintained on -site. The ing all calibration and maintenance ilv'.: � . ormg-ms rumentation, and copies of all years from the date of the sample, by request of the Director at any time. The permittee shall allow the Director, or an authorized representative (including an authorized contractor acting as a representative of the Director),.or n the case of a facility which discharges through a municipal separate storm sewer system, an:authorized representative of a municipal operator or the separate storm sewer system receiving the discharge, upon,the,presentation of credentials and other documents as may be required by law, to; a. Enter upon the p�,r�inittee's premises where a regulated facility or activity is located or conducted, or where records;musfbe kept under the conditions of this individual permit; b. Have access to an`d''c'opy, at reasonable times, any records that must be kept under the conditions of this individual permit; C. Inspect at reasonable times any facilities, equipment (including monitoring and control equipment), practices, or operations regulated or required under this individual permit; and d. Sample or monitor at reasonable times, for the purposes of assuring individual permit compliance or as otherwise authorized by the Clean Water Act, any substances or parameters at any location. SECTION E: REPORTING REQUIREMENTS Discharize MOnitOTing Reports Samples analyzed in accordance with the terms of this permit shall be submitted to the Division on Discharge Monitoring Report forms provided by the Director. Submittals shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory. When no discharge has occurred from the facility during the report period, the permittee is required to submit a discharge monitoring report within 30 days of the end of the six-month sampling period, giving all required information and indicating "NO FLOW" as per NCAC T15A 0213.0506. Part III Page 6 of 8 Permit No. NCS000522 2. SubmittingAeports Duplicate signed copies of all reports required herein, shall be submitted to the following address: Division of Water Quality Surface Water Protection Section ATTENTION: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Availability of Reports Except for data determined to be confidential under NCGS 143-215.3(a)(2) or Section 308 of the Federal Act, 33 USC 1318, all reports prepared in accordance with the terms shall be available for public inspection at the offices of the Division of Water Quality. As required by the Act;analytical data shall not be considered confidential. Knowingly making any false statement'obmany such report may result in the imposition of criminal penalties as provided for in NCGS 143 2 i.5 6B or in Section 309 of the Federal Act. 4. Non-Stormwater Discharges If the storm event monitored in accordance with this indi% discharge, the permittee shall separately monitor al -pavan r discharge permit and provide this information, with the stc 5. Planned Changes mit coincides with a non-stormwater required under the non-stormwater discharge monitoring report. The permittee shall give notice°to,�the DirerLaas soon as possible of any planned changes at the permitted facility which could significantlywalter-the�nature or quantity of pollutants discharged. This notification requirement includes pollutants which are not specifically listed in the individual permit or subject to notification requirements under 40 CFR�Part 122.42 (a). l t - 11 6. . Anti The permittee shall give notice to the Director as soon as possible of any planned changes at the permitted facility which may result in noncompliance with the individual permit requirements. 7. Bypass a. Anticipated bypass. If the permittee knows in advance of the need for a bypass, it shall submit prior notice, if possible at least ten days before the date of the bypass; including an evaluation of the anticipated quality and affect of the bypass. b. Unanticipated bypass. The permittee shall submit notice within 24 hours of becoming aware of an unanticipated bypass. 8. Twenty-four Hour Reporting The permittee shall report to the central office or the appropriate regional office any noncompliance which may endanger health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. The written submission shall contain a description of the noncompliance, and its causes; the period of noncompliance, including exact dates and times, and if the noncompliance has not been corrected, the Part III Page 7 of 8 Permit No. NCS000522 9 10. anticipated time compliance is expected to continue; and steps taken or planned to reduce, eliminate, and prevent reoccurrence of the noncompliance. The Director may waive the written report on a case -by -case basis if the oral report has been received within 24 hours. Other Noncompliance The permittee shall report all instances of noncompliance not reported under 24 hour reporting at the time monitoring reports are submitted. Other Information Where the permittee becomes aware that it failed to submit any relevant facts in an application for an individual permit or in any report to the Director, it shall promptlynsubmit such facts or information. Part III Page 8 of 8 NCS000522 PART IV LIMITATIONS REOPENER This individual permit shall be modified or alternatively, revoked and reissued, to comply with any applicable effluent guideline or water quality standard issued or approved under Sections 302(b) (2) (c), and (d), 304(b) (2) and 307(a) of the Clean Water Act, -if the effluent guideline or water quality standard so issued or approved: a. Contains different conditions or is otherwise more stringent than any effluent limitation in the individual permit; or b. . Controls any pollutant not limited in the individual permit. The individual permit as modified or reissued under this Act then applicable. PART V ADMINISTERING AND REQUIRE! The permittee must pay the administering and the Division. Failure to pay the fee in timely i Division to initiate action to revoke the;Indivi P 1. Act See Clean Water Act. 2. Arithmetic Mean filk ance;monitorn in accordance -mit. other requirements in the MONITORING FEE ig fee within 30 (thirty) days after being billed by with 15A NCAC 2H .0105(b)(4) may cause this DEFINITIONS The arithmetic mean of any set of values is the summation of the individual values divided by the number of individual values. 3. Allowable Non-Stormwater Discharges This permit regulates stormwater discharges. Non-stormwater discharges which shall be allowed in the stormwater conveyance system are: (a) All other discharges that are authorized by a non-stormwater NPDES permit. (b) Uncontaminated groundwater, foundation drains, air -conditioner condensate without added chemicals, springs, discharges of uncontaminated potable water, waterline and fire hydrant flushings, water from footing drains, flows from riparian habitats and wetlands. (c) Discharges resulting from fire -fighting or fire -fighting training. 4. Best Management Practices (BMPs) Measures or practices used to reduce the amount of pollution entering surface waters. BMPs may take the form of a process, activity, or physical structure. Parts IV, V and VI Page 1 of 5 Permit No. NCS000522 5, Bypass 6. 7. 8 9. A bypass is the known diversion of stormwater from any portion of a stormwater control facility including the collection system, which is not a designed or established operating mode for the facility. Bulk Storage of Liquid Products Liquid raw materials, manufactured products, waste materials or by-products with a single above ground storage container having a capacity of greater than 660 gallons or with multiple above ground storage containers located in close proximity to each other having a total combined storage capacity of greater than 1,320 gallons. Clean Water Act The Federal Water Pollution Control Act, also known USC 1251, et. seq. Division or DWQ The Division of Water Quality, Department of Enyir Director , Z/ The Director of the Division of{Water�'qiiality, The North Carolina Environmental Mann eme 11. Grab Sample 3' .he Cleaii Water Act (CWA), as amended, 33 11 nt and'Natural Resources. - issuing authority. Commission. An individual sample collected instantaneously. Grab samples that will be directly analyzed or qualitatively monitored must be taken within the first 30 minutes of discharge. 12. Hazardous Substance Any substance designated under 40 CFR Part 116 pursuant to Section 311 of the Clean Water Act. 13. Landfill A disposal facility or part of a disposal facility where waste is placed in or on land and which is not a land treatment facility, a surface impoundment, an injection well, a hazardous waste long-term storage facility or a surface storage facility. 14, Municipal Separate Storm Sewer System A stormwater collection system within an incorporated area of local self-government such as a city or town. 15, No Exposure A condition of no exposure means that all industrial materials and activities are protected by a storm resistant shelter or acceptable storage containers to prevent exposure to rain, snow, snowmelt, or runoff. Industrial materials or activities include, but are not limited to, material handling equipment or activities, Part VI Page 2 of 5. Pages Permit No. NCS000522 16. 17 18 19 20 21 22 23, industrial machinery, raw materials, intermediate products, by-products, final products, or waste products. DWQ may grant a No Exposure Exclusion from NPDES Stormwater Permitting requirements only if a facility complies with the terms and conditions described in 40 CFR §I22.26(g). Overburden Any material of any nature, consolidated or unconsolidated, that overlies a mineral deposit, excluding topsoil or similar naturally -occurring surface materials that are not disturbed by mining operations. Permittee The owner or operator issued a permit pursuant to this individual permit. Point Source Discharge of Stormwater Aq - Any discernible, confined and discrete conveyance including, bait not specifically limited to, any pipe, ditch, channel, tunnel, conduit, well, or discrete fissure from which, tormwater is,or may be discharged to waters of the state.Y:' Representative Storm Event - Viz" A storm event that measures greater than 0.1 inches df idiiif_all'and that is preceded by at least 72 hours in which no storm event measuring greater than 0.1. inches has yoccurred. A single storm event may contain up to 10 consecutive hours of no precipitation. For example,�ifiit r ins for�2;hours without producing any collectable discharge, and then stops, a sample may be collectcdlif a rain producing,a discharge begins again within the next 10 hours. Renresentative Outfall Status.'.` -°'� When it is established that,the discharge of stormwater runoff from a single outfall is representative of the discharges at multiple outfalls, the DWQ may grant representative outfall status. Representative outfall status allows the permittee to perform analytical monitoring at a reduced number of outfalls. Rinse Water Discharge The discharge of rinse water from equipment cleaning areas associated with industrial activity. Rinse waters from vehicle and equipment cleaning areas are process wastewaters and do not include washwaters utilizing any type of detergent or cleaning agent. Secondary Containment Spill containment for the contents of the single largest tank within the containment structure plus sufficient freeboard to allow for the 25-year, 24-hour storm event. Section 313 Water Priority Chemical A chemical or chemical category which: a. is listed in 40 CFR 372.65 pursuant to Section 313 of Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986, also titled the Emergency Planning and Community Right - to -Know Act of 1986; b. Is present at or above threshold levels at a facility subject to SARA Title I1I, Section 313 reporting requirements; and C. That meet at least one of the following criteria: Part VI Page 3 of 5 Pages Permit No. NCS000522 (1) Is listed in Appendix D of 40 CFR part 122 on either Table II (organic priority pollutants), Table III (certain metals, cyanides, and phenols) or Table IV (certain toxic pollutants and hazardous substances); (2) Is listed as a hazardous substance pursuant to section 3.11(b)(2)(A) of the CWA at 40 CFR 116.4; or (3) Is a pollutant for which EPA has published acute or chronic water quality criteria. 24. " Severe Prope , Damage Means substantial physical damage to property, damage to the control facilities which causes them to become inoperable, or substantial and permanent loss of natural resources which can reasonably be expected to occur in the absence of a bypass. Severe property damage does not mean economic loss caused by delays in production. 1." ,, 0 25, Significant Materials Includes, but is not limited to: raw materials; fuels; maferiafs�such°as solvents, detergents, and plastic pellets; finished materials such as metallic products"; raw materials used in food processing or production; hazardous substances designated under sectionl01(14) 6fCERCLA; any chemical the facility is required to report pursuant to section 313 of Title III of SARA; fertilizers; pesticides; and waste products such as ashes, stag and sludge that have the potential to he released with stormwater discharges. 26. Significant Spills - Includes, but is not limited to releasesi, oil or hazardous substances in excess of reportable quantities under section 311 of the Clean Water Act(Ref: 40 CFR 110.10 and CFR 117.21) or section 102 of CERCLA (Ref: 40 CFR 302.4). , 27. Stormwater Runoff The flow of water which results from precipitation and which occurs immediately following rainfall or as a result of snowmelt. 28. Stormwater Associated with Industrial Activity The discharge from any point source which is used for collecting and conveying stormwater and which is directly related to manufacturing, processing or raw material storage areas at an industrial site. Facilities considered to be engaged in "industrial activities" include those activities defined in 40 CFR 122.26(b)(14). The term does not include discharges from facilities or activities excluded from the NPDES program. 29. Stormwater Pollution Prevention Plan A comprehensive site -specific plan which details measures and practices to reduce stormwater pollution and is based on an evaluation of the pollution 'potential of the site. 30. Ten Year Design Storm The maximum 24 hour precipitation event expected to be equaled or exceeded on the average once in ten years. Design storm information can be found in the State of North Carolina Erosion and Sediment Control Planning and Design Manual. Part VI Page 4 of 5 Pages Permit No. NCS000522 31. Total Flow The flow corresponding to the time period over which the entire storm event occurs. Total flow shall be either; (a) measured continuously, (b) calculated based on the amount of area draining to the outfall, the amount of built -upon (impervious) area, and the total amount of rainfall, or (c) estimated by the measurement of flow at 20 minute intervals during the rainfall event. 32. - Total Maximum Daily Load (TMDL) 11 A TMDL is a calculation of the maximum amount of a pollutant that a waterbody can receive and still meet water quality standards, and an allocation of that amount to the pollutant's sources. A TMDL is a detailed water quality assessment that provides the scientific foundation for an implementation plan. The implementation plan outlines the steps necessary to reduce pollutant loads in a certain body of water to restore and maintain water quality standards in all seasons. The}Clean Water Act, section 303; establishes the water quality standards and TMDL programs. 0 33. Toxic Pollutant Any pollutant listed as toxic under Section 307(a)(I),ofthe CleaMater Act. 34. Upset 35, Means an exceptional incident in which there is dnintetitional and temporary noncompliance with ":1, ._ Oe technology based permit effluent}limitatons because of factors beyond the reasonable control of the permittee. An upset does not include noncompliance to the extent caused by operational error, improperly designed treatment or control facilities; inadequate treatment or control facilities, lack of preventive maintenance, or careless or imp p etoperation. Vehicle rehabilitation, mechanical repairs, painting, fueling, lubrication, vehicle cleaning operations, or airport deicing operations. 36. Visible Sedimentation Solid particulate matter, both mineral and organic, that has been or is being transported by water, air, gravity, or ice from its site of origin which can be seen with the -unaided eye. 37. 257,year, 24 hour storm event r The maximum 24-hour precipitation event expected to be equaled or exceeded, on the average, once in 25 years. Part VI Page 5 of 5 Pages �kf Michael F. Easley, Governor State of North Carolina f2 0 November 30, 2007 NOV 2 W Mr. Robert Rebello, President �C DENR MRO US Polymers 4330 Chesapeake Drive Ar Charlotte, North Carolina 28216 ; DIM -Surface dater Protection Subject: Draft NPDES Stormwater Permit Permit No, NCS000522 US Polymers - Charlotte, NC Mecklenburg County Dear Mr. Rebello: Enclosed with this Ietter is a copy of the draft stormwater permit for your facility. Please review the draft very carefully to ensure thorough understanding of the conditions and requirements it contains. The draft permit contains the following significant items for this facility's future permit: • All analytical monitoring is semi-annual. This makes stormwater discharge sampling frequency consistent with qualitative monitoring. Please note that analytical monitoring must be performed during a representative storm event. • The Division has incorporated benchmark values into the permit. These benchmarks are not permit limits but should be used as guidelines for your facility's Stormwater Pollution Prevention Plan (SPPP). If any measurements exceed benchmark values, your facility should evaluate the effectiveness of its Best Management Practices (BMPs), review and/or update its SPPP, and document any efforts to address stormwater contamination (see Part 11, Sections B and D). The permit requires Total Rainfall amount be recorded for each sampling event. Please note that the Stormwater Pollution Prevention Plan (SPPP) site map must include drainage area for each outfall in acres and the percentage of each drainage area that is impervious (see Part II, Sec. A). PIease submit any comments to me no later than thirty (30) days following your receipt of the draft. Comments should be sent to the address listed at the bottom of this page. If no adverse comments are received from the public or from you, this permit will likely be issued in about two months. If you have any questions or comments concerning this draft permit, contact me at (919) 733-5083 x 360 or robert.patterson®ncmail.net. Sincerely, Robert D. Patterson, PE Environmental Engineer Stormwater Permitting Unit North Carolina Division of Water Quality 1617 Mail Service Center Raleigh, North Carolina 27699-1617 (919) 733-7015 FAX (919) 733-0719 On the Internet at http://h2o.enr.Mte.nc.us/ Mr. Robert Rebello US Polymers Permit No. NCS000522� Page 2 IV 11 ` _ , ',tj,j4 cc: David Kirby -7ject Integration Inc, PO Box 1414, Greer, SC 29652-1414 (w/ attachment) Mooresville Regional Office, Water Quality Section (w/ attachment) orrriwater f'errWting Unit � ' Attachments 2 NCS000522 STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY PERMIT TO DISCHARGE STORMWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provisions of North Carolina eneral Statute 143-215.1, other lawful standards and regulations promulgated and adopted by t eNorth Carolina Environmental Management Commission, and the Federal Water pollution%Gontrot Act, as amended, is hereby authorized„�to,LdissZrLrg9 stormwater from a facility located at FIMUS Polymers 33 Chesapeak.e Drive Charlotte, NC Mecklenburg County to receiving waters designated as Stewart Creek, a class C stream in the Catawba River Basin, in accordance with the discharge limitations, monitoring requirements, and other conditions set forth in Parts I, II, III, IV, V and VI hereof. Note: Draft Permit Dates are Approximate This permit shall become effective February 1, 2008. This permit and the authorization to discharge shall expire at midnight on January 31, 2013. Signed this day January 15, 2008. for CoIeen H. Sullins Director Division of Water Quality By the Authority of the Environmental Management Commission Permit No. NCS000522 r PART Section A: Section B: Section C: all Section A: Section B: Section C: Section D: PART III Section A: Section B: TABLE OF CONTENTS INTRODUCTION Individual Permit Coverage Permitted Activities Location r MONITORIN DISCHARGE Stormwat( Analytical Qualitativ, On -Site V PERMITTED STANDARD CONDITIONS FOR NPDES STORMWATER INDIVIDUAL PERMITS Compliance and Liability 1. Compliance Schedule 2. Duty to Comply 3. Duty to Mitigate 4. Civil and Criminal Liability 5. Oil and Hazardous Substance Liability 6. Property Rights 7. Severability 8. Duty to Provide Information 9. Penalties for Tampering 10. Penalties for Falsification of Reports General Conditions 1. Individual Permit Expiration 2. Transfers Permit No. NCS000522 3. Signatory Requirements 4. Individual Permit Modification, Revocation and Reissuance, or Termination 5. Permit Actions Section C: Operation and Maintenance of Pollution Controls 1. Proper Operation and Maintenance 2. Need to Halt or Reduce Not a Defense 3. Bypassing of Stormwater Control Faciliti Section D: Monitoring and Records 1. Representative Sampling 2. Recording Results 3. Flow Measurements 4. Test Procedures 5. Representative 4utfal b. Record to " ion 7. Inspection and Entuy` Section E: Reporting Requirements I. Dis arge,Nlonitoring Reports 2. Submitting Reports 3. Availability of Reports 4. Non-Stormwater Discharges 5. Planned Changes b. Anticipated Noncompliance 7. Bypass 8. Twenty-four Hour Reporting 9. Other Noncompliance 10. Other Information PART IV LIMITATIONS REOPENER PART V ADMINISTERING AND COMPLIANCE MONITORING FEE REQUIREMENTS PART VI DEFINITIONS 11 Permit No. NCS000522 PART I INTRODUCTION SECTION A: INDIVIDUAL PERMIT COVERAGE During the period beginning on the effective date of the permit and lasting until expiration, the permittee is authorized to discharge stormwater associated with industrial activity. Such discharges shall be controlled, limited and monitored as specified in this permit. If industrial materials and activities are not exposed to precipitation or runoff as described in 40 CFR § 122.26(g), the facility may qualify for a No Exposure Exclusion from NPDES stormwater discharge permit requirements. Any owner or operator wis ing�o obtain a No Exposure Certification must submit a No Exposure Certification�`I401, ormto the Division; must receive approval by the Division; must maintain no exposureLcondi i-ons unless authorized to discharge under a valid NPDES stormwater permit; and must reply for the'Na Exposure Exclusion once every five (5) years. 4 SECTION B: PERMITTED ACTIVITIE Until this permit expires or is m6aified"or revoked the permittee is authorized to discharge stormwater to the surface waters of�Nor Carolina or separate storm sewer system that has been adequately treated and managedir?ad6ordande with the terms and conditions of this individual permit. All stormwater discharges shall�hbe in accordance with the conditions of this permit. Any other point source discge-to'" surface waters of the state is prohibited unless it is an allowable non-stormwater discharg or is covered by another permit, authorization, or approval. The stormwater discharges allowed by this individual permit shall not cause or contribute to violations of Water Quality Standards. This permit does not relieve the permittee from responsibility for compliance with any other applicable federal, state, or local law, rule, standard, ordinance, order, judgment, or decree. Part 1 Page I of 2 SECTION C: LOCATION MAP Permit No. NCS000522 NCS000522 N W *- E S ; US Polymers. US Polymers, Inc. US Polymers - Charlotte Latitude: 350 16' 40" N Longitude: 800 52- 20" W Receiving Stream: Stewart Creek Stream Class: C - Sub-basln: 03-08-34 (Catawba Rlv6r Basin) IFacility Location Part I Page 2 of 2 Permit No. NCS000522 PART II MONITORING, CONTROLS, AND LIMITATIONS FOR PERMITTED DISCHARGES SECTION A: STORMWATER POLLUTION PREVENTION PLAN The permittee shall develop a Stormwater Pollution Prevention Plan, herein after referred to as the Plan. This Plan shall be considered public information in accordance with Part III, Standard Conditions, Section E, Paragraph 3 of this individual permit. The Plan shall include, at a minimum, the following items: Site Plan. The site plan shall provide a description of the physical facility and the potential pollutant sources that may be expected,to c ntti ute to contamination of stormwater discharges. The site plan shall coma n tlie�f a. A general location map (USGS quadranglb.map or appropriately drafted equivalent map), showing the facility's to atlon in relation to transportation A NPV routes and surface waters, the name.okhe receiving water(s) to which the stormwater outfall(s) discharges or if she -cri�scharge is to a municipal separate storm sewer system, the nameofjthe municipality and the ultimate receiving waters; and accurate latitude andiongitude of the point(s) of discharge. The map should identify whether each,rece v ng water is impaired (on the state's 303(d) List of impaired waters) or'i'§ located in a watershed for which a TMDL has i been established;; nd what t9e parameter(s) of concern are. North Carolinars 303(`List can be found here: http://h2o.eiiF.state nc.us/tmdl/General_303d.htm#Downloads North Caroliha� !V!6; documents can be found here: http://h2o.enr. is ate.ne.us/tmdllTMDL_list.htm#Final_TMDLs b. A narrative description of storage practices, loading and unloading activities, outdoor process areas, dust or particulate generating or control processes, and waste disposal practices. A narrative description of the potential pollutants which could be expected to be present in the stormwater discharge from each outfall. A site map drawn to scale with the following items: (1) Distance legend and north arrow (2) Site property boundary and topography (3) Location of industrial activities (including storage of materials, disposal areas, process areas, and loading and unloading areas) (4) Drainage features and structures (5) Stormwater discharge points (outfalls) (6) Delineated drainage areas for each outfall (7) Drainage area for each outfall in acres and percentage or each drainage area that is impervious (8) All on -site and adjacent surface waters and wetlands (9) Building locations Part II Page 1 of 10 Permit No. NCS000522 (10) Existing BMPs and impervious surfaces d. A list of significant spills or leaks of pollutants that have occurred at the facility during the three (3) previous years and any corrective actions taken to mitigate spill impacts. e. Certification that the stormwater outfalls have been evaluated for the presence of non- stormwater discharges. The certification statement will be signed in accordance with the requirements found in Part III, Standard Conditions, Section B, Paragraph 3. 2. Stormwater Management Plan. The stormwater management plan shall contain a narrative description of the materials management practices employed which control or minimize the exposure of significant materials to storm�er, including structural and nonstructural measures. The stormwater managementplan, at a,minimum, shall incorporate.the following: a. Feasibility Study. A review of the teclTiicaland economic feasibility of changing the methods of operations and/or storage p a'q,','Uces to eliminate or reduce exposure of materials and processes to stormwaterWherever practical, the permittee shall prevent exposure of all storage areas, at vial handling operations, and manufacturing or fueling operations. IInf areas where elimination of exposure is not practical, theme water,management plan shall document the feasibility of diverting the stormwater r7aff�.away from areas of potential contamination. b. Secondary Containment (Requirements and Records. Secondary containment is required for: bilk storage of liquid materials; storage in any amount of Section 313 of Title I I of the Superfund Amendments and Reauthorization Act (SARA) water priority chemicals; and storage in any amount of hazardous substances to prevent leaks and spills from contaminating stormwater runoff. A table or summary of all such tanks and stored materials and their associated secondary containment areas shall be maintained. If the secondary containment devices are connected directly to stormwater conveyance systems, the connection shall be controlled by manually activated valves or other similar devices which shall be secured closed with a locking mechanism, and any stormwater that accumulates in the containment area shall be at a minimum visually observed for color, foam, outfall staining, visible sheens and dry weather flow, prior to release of the accumulated stormwater. Accumulated stormwater shall be released if found to be uncontaminated by the material stored within the containment area. Records documenting the individual making the observation, the description of the accumulated stormwater and the date and time of the release shall be kept for a period of five (5) years. BMP Summary. A narrative description shall be provided of Best Management Practices (BMPs) to be considered such as, but not limited to, oil and grease separation, debris control, vegetative filter strips, infiltration and stormwater detention or retention, where necessary. The need for structural BMPs shall be based on the assessment of the potential of pollutant sources to contribute Part II Page 2 of 10 Permit No. NCS000522 significant'quantities of pollutants to stormwater discharges and data collected through monitoring of stormwater discharges. 3. Spill Prevention and Response Plan. The Spill Prevention and Response Plan (SPRP) shall incorporate an assessment of potential pollutant sources based on a materials inventory of the facility, Facility personnel (or team) responsible for implementing the SPRP shall be identified. A responsible person shall be on -site at all times during facility operations that have the potential to contaminate stormwater runoff through spills or exposure of materials associated with the facility operations. The SPRP must be site stormwater specific. Therefore, an oil SPCC plan may be a component of the SPRP, but may not be sufficient to completely address the stormwater aspects of the SPRP. The common elements of the SPCC with the SPRP may be incorporated by reference into the SPRP. 4. Preventative Maintenance and Good Housekee" ing%Pr6grarn..yA preventative ., maintenance program shall be developed. The program shall document schedules of inspections and maintenance activities of stom aate`r•control systems, plant equipment and systems. Inspection of material handlin yeas and'regular cleaning schedules of these areas shall be incorporated into the program 5. Employee Training. Training schedules ghvl be developed and training provided at a minimum on an annual basis�on,oper spill response and cleanup procedures and preventative maintenance activities -for all personnel involved in any of the facility's entiR operations that have the pottoontaminate stormwater runoff. Facility personnel (or team) responsible far implementing the training shall be identified. 6. Responsible Party. The,Storrfiwater Pollution Prevention Plan shall identify a specific position(s) responsibl'Z�foi fie overall coordination, development, implementation, and revision to the Plan. Responsibilities for all components of the Plan shall be documented and position assignments provided. 7. Plan Amendment. The permittee shall amend the Plan whenever there is a change in design, construction, operation, or maintenance that has a significant effect on the potential for the discharge of pollutants to surface waters. The Stormwater Pollution Prevention Plan shall be reviewed and updated on an annual basis. The annual update shall include an updated list of significant spills or leaks of pollutants for the previous three years, or the notation that no spills have occurred. The annual update shall include re -certification that the stormwater outfalls have been evaluated for the presence of non- stormwater discharges. The Director may notify the permittee when the Plan does not meet one or more of the minimum requirements of the permit. Within 30 days of such notice, the permittee shall submit a time schedule to the Director for modifying the PIan to meet minimum requirements. The permittee shall provide certification in writing (in accordance with Part III, Standard Conditions, Section B, Paragraph 3) to the Director that the changes have been made. Part 11 Page 3 of 10 Permit No. NCS000522 8. Facility Inspection Program. Inspections of the facility and all stormwater systems shall occur at a minimum on a semi-annual schedule, once during the first half of the year (January through June) and once during the second half (July through December), with at least 60-days separating inspection dates (unless performed more frequently). The inspection and any subsequent maintenance activities performed shall be documented, recording date and time of inspection, individual(s) making the inspection and a narrative description of the facility's stormwater control systems, plant equipment and systems. Records of these inspections shall be incorporated into the Stormwater Pollution Prevention Plan. These facility inspections are different from, and in addition to, the stormwater discharge characteristic monitoring required in Part II of this permit. 9. Implementation. The permittee shall implement the Plan, The permittee shall document all monitoring, measurements, inspections and maintenance activities and training provided to employees, including the log of the samplin data and of actions taken to implement BMPs associated with the industrial activities, i hiding vehicle maintenance activities. Such documentation shall be kept on -site for a period of five years and made available to the -Director or the Director's autho' d epresentative immediately upon request. Part II Page 4 of 10 Permit No. NCS000522 SECTION B: ANALYTICAL MONITORING REQUIREMENTS Analytical monitoring of stormwater discharges shall be performed as specified in Table 1. All analytical monitoring shall be performed during a representative storm event. The required monitoring will result in a minimum' of ten analytical samplings being conducted over the term of the permit at each stormwater discharge outfall (SDO). A representative storm event is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no precipitation, For example, if it rains for 2 hours without producing any collectable discharge, and then stops, a sample may be collected if a rain producingharge begins again within the next 10 hours, Table I. Analytical Discharge, £. Ciaracterisfics Ac lamide Units msenji Measurement Frequencyt ,. Sample's T. "e2`=' Grab Sample °' Locaton3 SDO Total Suspended Solids m g/L , s. semt-annual Grab SDO Oil and Grease : /Lsemi -annual Grab SDO H stMg d_ semi-annual Grab SDO Total Rainfall4 inche semi-annual Rain Gauge - Ad Footnotes: Measurement Frequency: Twice pePyear during a representative storm event, for each year until either another permit is issued for this facility or until this permit is revoked or rescinded. If at the end of this permitting cycle the permittee has submitted the appropriate paperwork for a renewal permit before the submittal deadline, the permittee will be considered for a renewal application. The applicant must continue semi-annual monitoring until the renewed permit is issued. See Table 2 for schedule of monitoring periods through the end of this permitting cycle. 2 If the stormwater runoff is controlled by a stormwater detention pond, a grab sample of the discharge from the pond shall be collected within the first 30 minutes of discharge. 3 Sample Location: Samples shall be collected at each stormwater discharge outfall (SDO) unless representative outfall status has been granted. 4 For each sampled representative storm event the total precipitation must be recorded. An on -site rain gauge or local rain gauge reading must be recorded. Part II Page 5 of 10 Permit No. NCS000522 The permittee shall complete the minimum ten analytical samplings in accordance with the schedule specified below in Table 2. A minimum of 60 days must separate Period 1 and Period 2 sample dates unless monthly monitoring has been instituted under a Tier Two response. Table 2, Monitoring Schedule FMoriitori g p iod ,,, aSam le Number !, , Starts, Year 1 — Period 1 1 January 1, 2008 June 30, 2008 Year 1 — Period 2 2 July 1, 2008 December 31, 2008 Year 2 — Period 1 3 January 1, 2009 June 30, 2009 Year 2 — Period 2 4 July 1, 2009 December 31, 2009' Year 3 — Period 1 5 January 1,,*L20j116 June 30, 2010 Year 3 — Period 2 6 July 1,3qLO w December 31, 2010 Year 4 — Period 1 7 Jan ar. 120� W June 30, 2011 Year 4 — Period 2 8 h ty 1 201 l December 31, 2011 Year 5 — Period 1 9 January 1,72012 June 30, 2012 Year 5 — Period 2 10 juhyAj�2012 —t--December 31, 2012 Footnotes: 1 Maintain semi-annual monitoring during monitoring until the renewed permit is is 2 If no discharge occurs during the samplii Flow" within 30 days of the end of th si The applicant must continue semi-annual permittee must submit a monitoring report indicating "No ding period. Monitoring results shall be compared to the benchmark values in Table 3. The benchmark values in Table 3 are not permit limit%b.Wtsho Id be used as guidelines for the permittee's Stormwater Pollution Prevention Plan (SPPP). Exceedences of benchmark values require the permittee to increase monitoring, increase management actions, increase record keeping, and/or install stormwater'Best Management Practices (BMPs) in a tiered program. See below the descriptions of Tier One and Tier Two: Table 3. Benchmark Values for Analytical Monitoring Discharge Ch ra acteristic0 T,14 4 _ S ,: , gt Bench 'arE,`'* Acrylamide mg/L 28 Total Suspended Solids mg/L 100 Oil and Grease mg/L 30 pl-1 standard 6-9 Part II Page 6 of 10 Permit No. NCS000522 Tier One ''" If: The sampling results are above a benchmark value, or outside of the benchmark range, for any parameter at any outfall; Then: The permittee shall: 1. Conduct a stormwater management inspection of the facility within two weeks of receiving sampling results. 2. Identify and evaluate possible causes of the benchmark value exceedence. 3. Identify potential, and select the specific: source controls, gperational controls, or physical improvements to reduce concentrations of the parameters of concern, or to bring concentrations to within the benchmark range. 4. Implement the selected actions within two m n s of the inspection. 5. Record each instance of a Tier One response in the St water Pollution Prevention Plan. Include the date and value of the benchm exeeede ce, the inspection date, the personnel conducting the inspection, the selecteds tions, and date the selected actions were implemented. Ak Atr" "Tier?Two: j. x. If: During the.term of this permit,he sampling results are above the benchmark values, or outside of the benchmark range, for any specific parameter at a specific discharge outfall two times in a row (consecutive); Then: The permittee shall: I . Repeat all the required actions outlined above in Tier One, 2. Immediately institute monthly monitoring for all parameters at every outfall where a sampling result exceeded the benchmark value for two consecutive samples. Monthly (analytical and qualitative) monitoring shall continue until three consecutive sample results are below the benchmark values, or within the benchmark range, for all parameters at that outfall. 3. If no discharge occurs during the sampling period, the permittee is required to submit a monthly monitoring report indicating "No Flow". 4. Maintain a record of the Tier Two response in the Stormwater Pollution Prevention Plan. Part II Page 7 of 10 Permit No. NCS000522 During the term of this permit, if the sampling results exceed the benchmark value, or are outside the benchmark range, for any specific parameter at any specific outfall on more than four occasions, DWQ may: • Require that the permittee increase or decrease the monitoring frequency for the remainder of the permit; • require the permittee to install structural stormwater controls; • require the permittee to implement other stormwater control measures; or • require that the permittee implement site modifications for the No Exposure Exclusion. This site discharges to a tributary of an impaired coliform bactefia. A Total Maximum Daily Lope Watershed. The permittee may be required tognc future and submit results to the Division oFatei monitoring results in determiningowhether-additc of concern to the maximum extent*practi` cable. kp encing problems with fecal )ywas approved for the Irwin Creek the pollutant(s) of concern in the . The Division will consider the ?s are needed to control the pollutant(s) If additional BMPs are needed torachiee tthe required level of control, the permittee will be required to (1) develop;). strategy for implementing appropriate BMPs, and (2) submit a timetable for incorporation of those BMPs intothe permitted Stormwater Pollution Prevention Plan. Part it Page 8 of l0 Permit No. NCS000522 SECTION C: QUALITATIVE MONITORING REQUIREMENTS Qualitative monitoring requires a visual inspection of each stormwater outfall regardless of representative outfall status and shall be performed as specified in Table 4, and during the analytical monitoring event. Qualitative monitoring is for the purpose of evaluating the effectiveness of the Stormwater Pollution Prevention Plan (SPPP) and assessing new sources of stormwater pollution. In the event an atypical condition is noted at a stormwater discharge outfall, the permittee shall document the suspected cause of the condition and any actions taken in response to the discovery. This documentation will be maintained with the SPPP. Table 4. Qualitative onitoring Re uirement41 Discharge Char acteristics ti Frequency fi Monitoring Lo6ation2. Color semi-annual �. S Odor semi-annual, 1 SDO Clarity semi-annual Z fSDO Floating Solids semi? al b SDO Suspended Solids rni- 1, SDO Foam sew;4hnuxal SDO Oil Sheen 9 semi'. annual SDO Erosion or deposition at the outfall sem Ti-annual SDO Other obvious indicators of stormwater pollution semi-annual SDO Footnotes: I Measurement Frequency: Twice per year during a representative storm event, for each year until either another permit is issued for this facility or until this permit is revoked or rescinded. If at the end of this permitting cycle the permittee has submitted the appropriate paperwork for a renewal permit before the submittal deadline, the permittee will be considered for a renewal application. The applicant must continue semi-annual monitoring until the renewed permit is issued. See Table 2 for schedule of monitoring periods through the end of this permitting cycle. 2 Monitoring Location: Qualitative monitoring shall be performed at each stormwater discharge outfall (SDO) regardless of representative outfall status. SECTION D: ON -SITE VEHICLE MAINTENANCE MONITORING REQUIREMENTS Facilities which have any vehicle maintenance activity occurring on -site which uses more than 55 gallons of new motor oil per month when averaged over the calendar year shall perform analytical monitoring as specified below in Table 5. This monitoring shall be performed at all stormwater discharge outfalls which discharge stormwater runoff from vehicle maintenance Part II Page 4 of 10 Permit No. NCS000522 areas, and in accordance with the schedule presented in Table 2 (Section B). All analytical monitoring shall be performed during a representative storm event. Table S. Analytical Monitoring Requirements for On -Site Vehicle Maintenance tDts'cha g CharacteHs't�cs�' ra <� �' ' r� iJnits _:. Y Measur meri _ t o F Sample T �? _.J, Sample LL` Yion Lo'ca '3,,, H standard semi-annual Grab SDO Oil and Grease mg/1 semi-annual Grab SDO Total Suspended Solids mgA semi-annual Grab SDO Total Rainfa114 inches semi-annual Rain gauge - New Motor Oil Usagegallons/month 1 semi-annual Estimate - Footnotes: I Measurement Frequency: Twice per year during a represent permit is issued for this facility or until this permit is revoke the permittee has submitted the appropriate paperwork for a permittee will be considered for a renewal application. The the renewed permit is issued. See Table 2 for scheduleof rn cycle. J 2 If the stormwater runoff is controlled by a pond shall be collected within the Fr_ stt30 I 3 Sample Location: Samples shall be stormwater runoff from area(s) whe. 4 For each sampled repr gauge reading must be of ve storm ev aj-, for`each year until either another >cinded. if at the end of this permitting cycle MMI permit before the submittal deadline, the plicant must continue semi-annual monitoring until itoring periods through the end of this permitting i pond a grab sample of the discharge from the from the pond, stormwater discharge outfall (SDO) that discharges lance activities occur. the total precipitation must be recorded. An on -site or local rain Monitoring results shall be compared to the benchmark values in Table 6. The benchmark values in Table 6 are not permit limits but should be used as guidelines for the permittee's Stormwater Pollution Prevention Plan (SPPP). Exceedences of benchmark values require the permittee to increase monitoring, increase management actions, increase record keeping, and/or install stormwater Best Management Practices (BMPs), as provided in Part II Section B. . Table 6. Benchmark Values for Vehicle Maintenance Analytical Monitoring Ch ,.ram: •,: Discharge ,aracfer�st�cs iJgits��i k, �14 ; , Benchmarks ,-„.,r, pH standard 6-9 Oil and Grease mg/L 30 Total Suspended Solids mg/L 100 Part II Page 10 of 10 Permit No. NCS000522 PART III STANDARD CONDITIONS FOR NPDES STORMWATER INDIVIDUAL PERMITS SECTION A: COMPLIANCE AND LIABILITY Compliance Schedule The permittee shall comply with Limitations and Controls specified for stormwater discharges in accordance with the following schedule: Existing Facilities already operating but applying for permit coverage for the first time: The Stormwater Pollution Prevention Plan shall be developed and implemented within 12 months of the effective date of the initial permit and updated thereafter on an annual basis. Secondary containment, as specified in Part 11, Section A, Paragraph 2(b) of this permit, shall be accomplished within 12 months of the effective date of the initial permit issuance. �� New Facilities applying for coverage for the first time applying for renewal under this permit: The Stormwat implemented prior to the beginning of discharges fron updated thereafter on an annual basis. Secondary con 2(b) of this permit shall be accomplished prior to,tl edl industrial activity. Duty to Comply fAlitiesypreviously permitted and Preventiion Plan shall be developed and on of the industrial activity and be ;specified in Part 11, Section A, Paragraph ' discharges from the operation of the The permittee must comply witho]Pconditions.of this individual permit. Any permit noncompliance me constitutes a violation of the Clean Water Ar,;and is grounds for enforcement action; for permit 4W1termination, revocation and reiss Rormodification; or denial of a permit upon renewal application. a. The permittee shall comply ith standards or prohibitions established under section 307(a) of the Clean Water Ac for toxic pollutants within the time provided in the regulations that establish these standards or prohibitions, even if the permit has not yet been modified to incorporate the requirement. b. The Clean Water Act provides that any person who violates a permit condition is subject to a civil penalty not to exceed $27,500 per day for each violation. Any person who negligently violates any permit condition is subject to criminal penalties of $2,500 to $25,000 per day of violation, or imprisonment for not more than I year, or both. Any person who knowingly violates permit conditions is subject to criminal penalties of $5,000 to $50,000 per day of violation, or imprisonment for not more than 3 years, or both. Also, any person who violates a permit condition .may be assessed an administrative penalty not to exceed $11,000 per violation with the maximum amount not to exceed $137,500. [Ref: Section 309 of the Federal Act 33 USC 1319 and 40 CFR 122.41(a).] C. Under state law, a daily civil penalty of not more than twenty-five thousand dollars ($25,000) per violation may be assessed against any person who violates or fails to act in accordance with the terms, conditions, or requirements of a permit. [Ref: North Carolina General Statutes I43- 2 l 5.6A] d. Any person may be assessed an administrative penalty by the Director for violating section 301, 302, 306, 307, 308, 318, or 405 of the Act, or any permit condition or limitation implementing any of such sections in a permit issued under section 402 of the Act. Administrative penalties for Class I violations are not to exceed $11,000 per violation, with the maximum amount of any Class I penalty assessed not to exceed $27,500. Penalties for Class II violations are not to exceed $11,000 Part III Page I of 8 Permit No. NCS000522 per day for each day during which the violation continues, with the maximum amount of any Class 11 penalty not to exceed $137,500. Duty to Mitigate The permittee shall take all reasonable steps to minimize or prevent any discharge in violation of this individual permit which has a reasonable likelihood of adversely affecting human health or the environment. 4. Civil and Criminal Liability Except as provided in Part III, Section C of this permit regarding bypassing of stormwater, control facilities, nothing in this individual permit shall be construed to relieve the permittee from any responsibilities, liabilities, or penalties for noncompliance pursuant to NCGS 143-215.3, 143-215.6A, 143-215.613, 143- 215.6C or Section 309 of the Federal Act, 33 USC 1319. Furthermore; the permittee is responsible for r!r consequential damages, such as fish kills, even though the responsibility for effective compliance may be temporarily suspended. L.. i� Oil and Hazardous Substance Liabil Nothing in this individual permit shall be construed o-precludehthe institution of any legal action or relieve the permittee from any responsibilities, liabilities„o altiesto which the permittee is or may be subject to under NCGS 143-215.75 et seq. or Section 311 �`I the " ederalKct, 33 USC 1321. Property Rights The issuance of this individual it does not -convey any property rights in either real or personal property, or any exclusive privileg s�nor does,it' authorize any injury to private property or any invasion of personal rights, nor any infringement f.Federal, State or local laws or regulations. _ Severabi I ity The provisions of this individual permit are severable, and if any provision of this individual permit, or the application of any provision of this individual permit to any circumstances, is held invalid, the application of such provision to other circumstances, and the remainder of this individual permit, shall not be affected thereby. 8. Duty to Provide_ Information The permittee shall furnish to the Director, within a reasonable time, any information which the Director may request to determine whether cause exists for modifying, revoking and reissuing, or terminating the permit issued pursuant to this individual permit or to determine compliance with this individual permit. The permittee shall also furnish to the Director upon request, copies of records required to be kept by this individual permit. Penalties for Tampering The Clean Water Act provides that any person who falsifies, tampers with, or knowingly renders inaccurate, any monitoring device or method required to be maintained under this individual permit shall, upon conviction, be punished by a fine of not more than $10,000 per violation, or by imprisonment for not more than two years per violation, or by both. If a conviction of a person is for a violation committed after a first conviction of such person under this paragraph, punishment is a fine of not more that $20,000 per day of violation, or by imprisonment of not more than 4 years, or both. Part IIl Page 2 of 8 Permit No. NCS000522 10. Penalties for Falsification of Reports The Clean Water Act provides that any person who knowingly makes any false statement, representation, or certification in any record or other document submitted or required to be maintained under this individual permit, including monitoring reports or reports of compliance or noncompliance shall, upon conviction, be punished by a fine of not more than $10,000 per violation, or by imprisonment for not more than two years per violation, or by both. SECTION B: GENERAL CONDITIONS Individual Permit Exl2iration The permittee is not authorized to discharge after the expiration date.,rin order to receive automatic authorization to discharge beyond the expiration date, the permitteersh'all submit forms and fees as are required by the agency authorized to issue permits no later tha'-lZdays prior to the expiration date. Any permittee that has not requested renewal at least 180 days prior to ex.pi tign, or any permittee that does not have a permit after the expiration and has not requestecrenew al at least-180 days prior to expiration, will be subjected to enforcement procedures as provided in NCGSJ t4,3-2153.6 and 33 USC 1251 et. seq. 2. Transfers This permit is not transferable to any F Director may require modification or i incorporate such other requirements a: +. required to notify the Division :m write Signatory Requirements All applications, reports, a. All applications fter'•notice to and approval by the Director. The eissuance of the permit to change the name and ary under the Clean Water Act. The Permittee is the permitted facility is sold or closed. submitted to the Director shall be signed and certified. under this individual permit shall be signed as follows: (1) For a corporation: by a responsible corporate officer. For the purpose of this Section, a responsible corporate officer means: (a) a president, secretary, treasurer or vice president of the corporation in charge of a principal business function, or any other person who performs similar policy or decision making functions for the corporation, or (b) the manager of one or more manufacturing production or operating facilities employing more than 250 persons or having gross annual sales or expenditures exceeding 25 million (in second quarter 1980 dollars), if authority to sign documents has been assigned or delegated to the manager in accordance with corporate procedures. (2) For a partnership or sole proprietorship: by a general partner or the proprietor, respectively; or (3) For a municipality, State, Federal, or other public agency: by either a principal executive officer or ranking elected official. All reports required by the individual permit and other information requested by the Director shall be signed by a person described above or by a duly authorized representative of that person. A person is a duly authorized representative only if: (1) The authorization is made in writing by a person described above; Part III Page 3 of 8 Permit No. NCS000522 (2) The authorization specified either an individual or a position having responsibility for the overall operation of the regulated facility or activity, such as the position of plant manager, operator of a well or well field, superintendent, a position of equivalent responsibility, or an individual or position having overall responsibility for environmental matters for the company. (A duly authorized representative riiay thus be either a named individual or any individual occupying a named position.); and (3) The written authorization is submitted to the Director. C. Any person signing a document under paragraphs a. or b, of this section shall make the following certification: "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directlyresponsible for gathering the information, the information submitted is, to the bestdf my owledge and belief, true, accurate, and complete. I am aware that there are significant penalt s,for submitting false information, including the possibility of fines and imprisonment, 'orknowing violations." 4. Indivi The issuance of this individual permit doesLpt ptoffibit the Director from reopening and modifying the individual permit, revoking and reissuing thZ individualypermit, or terminating the individual permit as allowed by the laws, rules, and'regulations cont med'in Title 40, Code of Federal Regulations, Parts 122 and 123; Title 15A of the North'G olin11 a,A istrative Code, Subchapter 2H .0 ] 00; and North Carolina General Statute 143-215.1 et. al. 5. Permit Actions The permit may be modified; revoked and reissued, or terminated for cause. The notification of planned changes or anticipated noncompliance does not stay any individual permit condition. SECTION C: OPERATION AND MAINTENANCE OF POLLUTION CONTROLS Proper Operation and Maintenance The permittee shall at all times properly operate and maintain all facilities and systems of treatment and control (and related appurtenances) which are installed or used by the permittee to achieve compliance with the conditions of this individual permit. Proper operation and maintenance also includes adequate laboratory controls and appropriate quality assurance procedures. This provision requires the operation of back-up or auxiliary facilities or similar systems which are installed by a permittee only when the operation is necessary to achieve compliance with the conditions of this individual permit. 2. - Need to Halt or Reduce Not a Defense It shall not be a defense for a permittee in an enforcement action that it would have been necessary to halt or reduce the permitted activity in order to maintain compliance with the condition of this individual permit. Bypassing of Stormwater Control Facilities Bypass is prohibited and the Director may take enforcement action against a permittee for bypass unless: Part III Page 4 of 8 Permit No. NCS000522 a. Bypass was unavoidable to prevent loss of life, personal injury or severe property damage; and b. There were no feasible alternatives to the bypass, such as the use of auxiliary control facilities, retention of stormwater or maintenance during normal periods of equipment downtime or dry weather. This condition is not satisfied if adequate backup controls should have been installed in the exercise of reasonable engineering judgment to prevent a bypass which occurred during normal periods of equipment downtime or preventive maintenance; and C. The permittee submitted notices as required under, Part III, Section E of this permit. If the Director determines that it will meet the three conditions listed above, the Director may approve an anticipated bypass after considering its adverse effects. SECTION D: MONITORING AND RECORDS 3. Representative Sampling Samples collected and measurements taken, as regi nature of the permitted discharge. Analytical samp event. Samples shall be taken on a day and time di taken before the discharge joins or is diluted band Monitoring points as specified in this permit�shalfll r the Director. . I1 Recording Results For each measurement, requirements of this ind a. The date, exac' shall be characteristic of the volume and performed during a representative storm ristic of the discharge. All samples shall be stream, body of water, or substance. d without notification to and approval of maintenance activity performed or collected pursuant to the rmittee shall record the following information: impling, measurements, inspection or maintenance activity; b. The individual(s) who performed the sampling, measurements, inspection or maintenance activity; C. The date(s) analyses were performed; d. The individual(s) who performed the analyses; e. The analytical techniques or methods used; and f. The results of such analyses. Flow Measurements Where required, appropriate flow measurement devices and methods consistent with accepted scientific practices shall be selected and used to ensure the accuracy and reliability of measurements of the volume of monitored discharges. Test Procedures Test procedures for the analysis of pollutants shall conform to the EMC regulations published pursuant to NCGS 143-215.63 et. seq, the Water and Air Quality Reporting Acts, and to regulations published pursuant to Section 304(g), 33 USC 1314, of the Federal Water Pollution Control Act, as Amended, and Regulation 40 CFR 136. Part III Page 5 of 8 Permit No. NCS000522 To meet the intent of the monitoring required by this individual permit, all test procedures must produce minimum detection and reporting levels and all data generated must be reported down to the minimum detection or lower reporting level of the procedure. 5. Representative Outfall If a facility has -multiple discharge locations with substantially identical stormwater discharges that are required to be sampled, the permittee may petition the Director for representative outfall status. If it is established that the stormwater discharges are substantially identical and the permittee is granted representative outfall status, then sampling requirements may be performed at a reduced number of outfalls. 6. Records Retention Visual monitoring shall be documented and records maintained at the�facility along with the Stormwater Pollution Prevention Plan. Copies of analytical monitoring results. hall also be maintained on -site. The permittee shall retain records of all monitoring information; mcl�g all calibration and maintenance records and all original strip chart recordings for continuous ous monitioTilt . g4nst umentation, and copies of all reports required by this individual permit for a period of at'least 5 y ars4from the date of the sample, measurement, report or application. This period may beext tided by request of the Director at any time. 7. Inspection and Entry The permittee shall allow the Director, or an authorized representative (including an authorized contractor acting as a representative of the Director, or in the case of a facility which discharges through a municipal separate storm sewer system,,an aatithor fedkreprese ive of a municipal operator or the separate storm sewer system receiving the discharge, upon the, presentation of credentials and other documents as may be required by law, to; a a. Enter upon the permittee's premises where a regulated facility or activity is located or conducted, or where records/must be kept under the conditions of this individual permit; b. Have access to ai',cop dy, at reasonable times, any records that must be kept under the conditions of this individual permit; C. Inspect at reasonable times any facilities, equipment (including monitoring and control equipment), practices, or operations regulated or required under this individual permit; and d. Sample or monitor at reasonable times, for the purposes of assuring individual permit compliance or as otherwise authorized by the Clean Water Act, any substances or parameters at any location. SECTION E: REPORTING REQUIREMENTS Dischar a Monitoring Reports Samples analyzed.in accordance with the terms of this permit shall be submitted to the Division on Discharge Monitoring Report forms provided by the Director. Submittals shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory. When no discharge has occurred from the facility during the report period, the permittee is required to submit a discharge monitoring report within 30 days of the end of the six-month sampling period, giving all required information and indicating "NO FLOW" as per NCAC Tt5A 02B .0506. Part III Page 6 of 8 Permit No. NCS000522 04 Submitting Reports Duplicate signed copies of all reports required herein, shall be submitted to the following address: Division of Water Quality Surface Water Protection Section ATTENTION: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-16 t 7 Availabilily of Reports Except for data determined to be confidential under NCGS 143-215.3(a)(2) or Section 308 of the Federal Act, 33 USC 1318, all reports prepared in accordance with the terms shall be available for public inspection at the offices of the Division of Water Quality. As required by the Ark analytical data shall not be considered confidential. Knowingly making any false statement%n•any such report may result in the imposition of criminal penalties as provided for in NCGS�1'43 �2B or in Section 309 of the Federal Act. 4. Non-Stormwater Discharges If the storm event monitored in accordance with discharge, the permittee shall separately monitor discharge permit and provide this informationy, 5. Planned Chances -mit coincides with a non-stormwater required under the non-stormwater discharge monitoring report. The permittee shall give notice,to-the Director as soon as possible of any planned changes at the permitted .:�- � ,.> facility which could significantly alter the nature or quantity of pollutants discharged. This notification 4P _ °.. . requirement includes pollutants whichlrre not specifically listed in the individual permit or subject to notification requirements under 40 CFR'Part 122.42 (a). 6. Anticipated Noncompliance- .� The permittee shall give notice to the Director as soon as possible of any planned changes at the permitted facility which may result in noncompliance with the individual permit requirements. 7. Bypass a. Anticipated bypass. If the permittee knows in advance of the need for a bypass, it shall submit prior notice, if possible at least ten days before the date of the bypass; including an evaluation of the anticipated quality and affect of the bypass. b. Unanticipated bypass. The permittee shall submit notice within 24 hours of becoming aware of an unanticipated bypass. Twenty-four Hour Reporting The permittee shall report to the central office or the appropriate regional office any noncompliance which may endanger health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. The written submission shall contain a description of the noncompliance, and its causes; the period of noncompliance, including exact dates and times, and if the noncompliance has not been corrected, the Part III Page 7 of 8 Permit No. NCS000522 anticipated time compliance is expected to continue; and steps taken or planned to reduce, eliminate, and prevent reoccurrence of the noncompliance. The Director may waive the written report on a case -by -case basis if the oral report has been received within 24 hours. Other Noncompliance The permittee shall report all instances of noncompliance not reported under 24 hour reporting at the time monitoring reports are submitted. 10. Other Information Where the permittee beci individual permit or in ar in an application for an h facts or information. Part III Page 8 of 8 NCS000522 PART IV LIMITATIONS REOPENER This individual permit shall be modified or alternatively, revoked and reissued, to comply with any applicable effluent guideline or water quality standard issued or approved under Sections 302(b) (2) (c), and (d), 304(b) (2) and 307(a) of the Clean Water Act, if the effluent guideline or water quality standard so issued or approved: a. Contains different conditions or is otherwise more stringent than any effluent limitation in the individual permit; or b. Controls any pollutant not limited in the individual permit. The individual permit as modified or reissued under this paragra �h~�sha l a�ontain any other requirements in the Act then applicable. 7r ?T�S� PART V � ADMINISTERING AND The permittee must pay the administering and the Division. Failure to pay the fee in timely i Division to initiate action to revoke t ddn�divi P I. Act See Clean Water Act. 2. Arithmetic Mean in MONITORING FEE ig fee within 30 (thirty) days after being billed by with I5A NCAC 2H .0105(b)(4) may cause this DEFINITIONS The arithmetic mean of any set of values is the summation of the individual values divided by the number of individual values. 3. Allowable Non-Stormwater Discharges This permit regulates stormwater discharges, Non-stormwater discharges which shall be allowed in the stormwater conveyance system are: (a) ' All other discharges that are authorized by a non-stormwater NPDES permit. (b) Uncontaminated groundwater, foundation drains, air -conditioner condensate without added chemicals, springs, discharges of uncontaminated potable water, waterline and fire hydrant flushings, water from footing drains, flows from riparian habitats and wetlands. (c) Discharges resulting from fire -fighting or fire -fighting training. 4. Best Management Practices (BMPs) Measures or practices used to reduce the amount of pollution entering surface waters. BMPs may take the form of a process, activity, or physical structure. Parts IV, V and VI Page 1 of 5 Permit No, NCS000522 5. Bypass A bypass is the known diversion of stormwater from any portion of a stormwater control facility including the collection system, which is not a designed or established operating mode For the facility. 6. Bulk Storage of Liquid Products Liquid raw materials, manufactured products, waste materials or by-products with a single above ground storage container having a capacity of greater than 660 gallons.or with multiple above ground storage containers located in close proximity to each other having a total combined storage capacity of greater than 1,320 gallons. 7. Clean Water Act The Federal Water Pollution Control Act, also known as the Clean Water Act (CWA), as amended, 33 USC 1251, et. seq. 8. Division or DWQ The Division of Water Quality, Department of En6r� 6riment and'Natural Resources. 9. Director The Director of the Division of^ er`Quality, theipermit issuing authority. 10. EMC The North Carolina Environmental Management Commission. 11. Grab Sample An individual sample collected instantaneously. Grab samples that will be directly analyzed or qualitatively monitored must be taken within the first 30 minutes of discharge. 12. Hazardous Substance Any substance designated under 40 CFR Part 116 pursuant to Section 311 of the Clean Water Act. 13. Landfill A disposal facility or pari of a disposal facility where waste is placed in or on land and which is not a land treatment facility, a surface impoundment, an.injection well, a hazardous waste long-term storage facility or a surface storage facility. 14. Municipal Separate Storm Sewer SysLtem A stormwater collection system within an incorporated area of local self-government such as a city or town. 15. No Exposure A condition of no exposure means that all industrial materials and activities are protected by a storm resistant shelter or acceptable storage containers to prevent exposure to rain, snow, snowmelt, or runoff. Industrial materials or activities include, but are not limited to, material handling equipment or activities, Part VI Page 2 of 5 Pages Permit No. NCS000522 16 17 18. 19 20 04 22 23 industrial machinery, raw materials, intermediate products, by-products, final products, or waste products. DWQ may grant a No Exposure Exclusion from NPDES Stormwater Permitting requirements only if a facility complies with the terms and conditions described in 40 CFR § 122.26(g). Overburden Any material of any nature, consolidated or unconsolidated, that overlies a mineral deposit, excluding topsoil or similar naturally -occurring surface materials that are not disturbed by mining operations. Permittee The owner or operator issued a permit pursuant to this individual permit. Point Source Discharge of Stormwater /> Any discernible, confined and discrete conveyance inc channel, tunnel, conduit, well, or discrete fissure from of the state. Representative Storm Event A storm event that measures greater than 0.1 i storm event measuring greater than 0.1 inches hours of no precipitation. For example, if i stops, a sample may be collect d4f a ri ini "' Representative Outfall Status illy limited to, any pipe, ditch, may be discharged to waters "rainfall'and that is preceded by at least 72 hours in which no irrr A single storm event may contain up to 10 consecutive :thours without producing any collectable discharge, and then discharge begins again within the next 10 hours. When it is established that,t}ie discharge,6f stormwater runoff from a single outfall is representative of the !.e discharges at multiple ouAIls, the DWQ may grant representative outfall status. Representative outfall status allows the permittee ox'pe�rforrm analytical monitoring at a reduced number of outfalls. Rinse Water Discharge The discharge of rinse water from equipment cleaning areas associated with industrial activity. Rinse waters from vehicle and equipment cleaning areas are process wastewaters and do not include washwaters utilizing any type of detergent or cleaning agent. Secondary Containment Spill containment for the contents of the single largest tank within the containment structure plus sufficient freeboard to allow for the 25-year, 24-hour storm event. Section 313 Water Prioritv Chemical A chemical or chemical category which: Is listed in 40 CFR 372.65 pursuant to Section 313 of Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986, also titled the Emergency Planning and Community Right - to -Know Act of 1986; b. Is present at or above threshold levels at a facility subject to SARA Title III, Section 313 reporting requirements; and C. That meet at least one of the following criteria: Part VI Page 3 of 5 Pages Permit No. NCS000522 24. 25 (1) Is listed in Appendix D of 40 CFR.part 122 on either Table II (organic priority pollutants), Table III (certain metals, cyanides, and phenols) or Table IV (certain toxic pollutants and hazardous substances); (2) Is listed as a hazardous substance pursuant to section 311(b)(2)(A) of the CWA at 40 CFR 116.4; or (3) Is a pollutant for which EPA has published acute or chronic water quality criteria. Severe Proj2eM Damage Means substantial physical damage to property, damage to the control facilities which causes them to become inoperable, or substantial and permanent loss of natural resources which can reasonably be expected to occur in the absence of a bypass. Severe property damage does not mean economic loss caused by delays in production. f Significant Materials Includes, but is not limited to: raw materials; fuels; ma[erial's+stuk as solvents, detergents, and plastic pellets; finished materials such as metallic products aw maat!rrials used in food processing or production; Ar hazardous substances designated under section�101�1 }cif CCERCLA; any chemical the facility is required to report pursuant to section 313 of Title I[I oARA'; fertilizers; pesticide-s; and waste products such as ashes, AN slag and sludge that have the potential to.,be releassedmwith stormwater discharges. 26. Significant Spills 27 28. 29. 30. Includes, but is not limited to:%releaseses oQil or hazardous substances in excess of reportable quantities under section 311 of the Clan Water Actr{Ref: 40 CFR 110.10 and CFR 1 I7.21) or section 102 of CERCLA (Ref: 40 CFR 302.4). Stormwater Runoff The flow of water which results from precipitation and which occurs immediately following rainfall or as a result of snowmelt. Stormwater Associated_ with Industrial Activity The discharge from any point source which is used for collecting and conveying stormwater and which is directly related to manufacturing, processing or raw material storage areas at an industrial site. Facilities considered to be engaged in "industrial activities" include those activities defined in 40 CFR 122.26(b)(14). The term does not include discharges from facilities or activities excluded from the NPDES program. Stormwater Pollution Prevention Plan A comprehensive site -specific plan which details measures and practices to reduce stormwater pollution and is based on an evaluation of the pollution potential of the site. Ten Year Design Storm The maximum 24 hour precipitation event expected to be equaled or exceeded on the average once in ten years. Design storm information can be found in the State of North Carolina Erosion and Sediment Control Planning and Design Manual. Part VI Page 4 of 5 Pages Permit No. NCS000522 31. 32. Total Flow The flow corresponding to the time period over which the entire storm event occurs. Total flow shall be either; (a) measured continuously, (b) calculated based on the amount of area draining to the outfall, the amount of built -upon (impervious) area, and the total amount of rainfall, or (c) estimated by the measurement of flow at 20 minute intervals during the rainfall event. Total Maximum Daily Load (TMDL) A TMDL is a calculation of the maximum amount of a pollutant that a waterbody can receive and still meet water quality standards, and an allocation of that amount to the pollutant's sources. A TMDL is a detailed water quality assessment that provides the scientific foundation for an implementation plan. The implementation plan outlines the steps necessary to reduce pollutant loads in a certain body of water to restore and maintain water quality standards in all seasons. Thetlean Water Act, section 303, establishes the water quality standards and TMDL programs. /�, Sit I# 33. Toxic Pollutant 34. 35. 36. 37 Any pollutant listed as toxic under Section 307(a)(1),gfthe Clean ;Water Act. upset Means an exceptional incident in which there is unintentional and temporary noncompliance with technology based permit effluen 1 mita`on becads'e of factors beyond the reasonable control of the permittee. An upset does not include noncompliance to the extent caused by operational error, improperly V. � y designed treatment or control facilities; inadequate treatment or control facilities, lack of preventive i✓ ^, maintenance, or careless or improper operation. Vehicle rehabilitation, mechanical repairs, painting, fueling, lubrication, vehicle cleaning operations, or airport deicing operations. Visible Sedimentation Solid particulate matter, both mineral and organic, that has been or is being transported by water, air, gravity, or ice from its site of origin which can be seen with the unaided eye. 25-year, 24 hour storm event The maximum 24-hour precipitation event expected to be equaled or exceeded, on the average, once in 25 years. Part VI Page 5 of 5 Pages l NCS 000522 Facility Name: NPDES Permit Number: Facility Location: Type of Activity: SIC Code: Receiving Streams: River Basin: . Stream Classification: Proposed Permit Requirements: .Monitoring Data: Facility Location: Response Requested by (Date): Central Office Staff Contact: Michael F. Easley, Governor William G. Ross 5r., Secretary North Carolina Department of Environment and Natural Resources Coleen H. Sullins Director Division of Water Quality STAFF REVIEW AND EVALUATION NPDES Stormwater Permit US Polymers, Inc. — Charlotte, NC NCS000522 Charlotte, NC (Mecklenburg County) Manufacture wastewater treatment chemicals 2899 (chemicals & chemical preparation, not elsewhere classified) Stewart Creek, See Figure 1 Catawba River Basin, Sub -basin 03-08-34 C See attached draft permit. Proposed facility, no monitoring performed See Figure 1 November 30, 2007 Robert Patterson, (919) 733-5083, ext. 360 NOV 2 2007 P}V r�► r+. , �•; �,r i fry{1r Prc r: Description of Onsite Activities: This facility produces wastewater treatment chemicals to be used by various industries. The raw materials (Acrylamide, Surfactants, oils) are stored in outside above ground tanks (AGTs) with secondary containment. The manufacturing takes place inside a building in mixing and reaction tanks. The final products (flocculants) are stored inside in AGTs with secondary containment. The products are shipped via truck. The storm drains that capture the truck areas have manual shut-off valves that are closed during loading/unloading, and then checked for chemicals before being opened. Documents Reviewed: • NPDES Stormwater Permit Application Materials • Catawba River Basinwide Plan • Final 2006 303(d) List • EPA Sector -Specific Permit, 2006 draft • Natural Heritage Program's Federal Threatened and Endangered Species Database • Check 40 CFR Subchapter N, Stormwater Effluent Guidelines • BASF former permits for this site (NCS000356 and.NCGNE0120) History: • Site is owned by BASF. N. C. Division of Water Quality 1617 Mail Service Center Raleigh, North Carolina 27699-1617 (919) 733-7015 Customer Service 1-877-623.6748 i r NCS000522 • 3/9/1996: 30% HCI spill near RR tracks at east property line. • 12/16/1996: NCS000356 issued to BASF (SIC 2869, made textile dyes and pigments) • 12/31/2002: BASF stopped manufacturing dye and pigment chemicals on site. • January -- August 2003: BASF cleaned up and decommissioned manufacturing and chemical handling equipment on site. Wastewater lift stations and pre-treatment system were cleaned and converted to handle stormwater. • June 5, 2003: BASF applied for No Exposure coverage. Site only housed research and labs. • 4/29/2005: NCGNE0120 issued to BASF. • Permittee leased facility from BASF. .. October 23, 2007: Permittee submitted new individual application package. Figure 1: See attached map. -w Central Office Review Summary: 1. Owner's Other Permits: (If applicable) %r)p N/A- for US Polymers, Inc. o BASF has NCGNE0120 currently, that needs to be rescinded since they are leasing to US Polymers. 2. General Observations: Existing facility owned by BASF. SW001 and SWO02 drain to existing storm sewer pipe systems; SWO03 sheet flows over grass area to the property line. Previous spill of 30% HCl back in 1996 (not by r.. current permittee). ASTs and maintenance shops in SW001 DA. UST for fuel oil and truck docks in SWO02 DA. 3. Impairment: The receiving stream, Stewart Creek, is not itself impaired. Though, Stewart Creek is a tributary to Irwin Creek which is impaired for aquatic life and has a Fecal Coliform Bacteria TMDL established (7.7xl012 cfU/100m1). Max loading allowed in the Irwin Creek watershed is 7.0xl012 co1/100ml for point sources and 7.3x1011 col/100ml for nonpoint sources. Impairment is primarily from SSOs and WWTPs. 4. Threatened and Endangered: N/A 5. Location: 4330. Chesapeake Drive, Charlotte, NC (former BASF facility) 6. Industrial Changes Since Previous Permit: former BASF facility that produced textile dyes and pigments (SIC 2869). BASF facility changed to SIC 8731 in 2003; and granted no exposure certification. Proposed facility SIC 2899. Analytical Monitoring Notes: None provided for proposed facility. Previous BASF individual permit monitored for COD, MBAS, and pH (and oil & grease for vehicle maint.). Consulted with Connie Brower on benchmarks for possible pollutants. 8. Qualitative Monitoring Notes: SW001, 002, and 003 were visually observed that no non-stonnwater discharges went to these outfalls. Permit Recommendations: Analytical Monitoring: 1. Possible pollutants: Acrylamide, Span 80, oil & grease, Euroquat 80MC, Exxsol D80 (solvent) Monitor for: Oil & grease, Acrylamide, and pH 2. Benchmarks have been added to this draft permit. 3. All analytical monitoring has been set to semi-annually. 4. The flow reporting requirement is not required per DWQ revised strategy. (The total rainfall and event duration parameters are in this permit, however.) 2 s ' ' r NCS000522 5. The"permittee is required to collect all of the analytical monitoring samples during representative storm events as defined in this permit. Qualitative monitoring does not have to be performed during a representative storm. event. Other Proposed Changes to the Previous Permit: 1. NIA — new permit Discussions with permittee: David Kirby (Project Integration, Inc), 864-497-6802, October 31, 2007 I. Q: Will hazardous waste be stored/produced on the site? a. ANSWER: No 2. Q: What is the facility's contact phone number? a: ANSWER: They don't have land lines setup yet. Will provide once they have them. 3. Q: What chemicals are stored inside/outside? a. ANSWER: Final products stored inside in tanks. Raw chemicals are stored in ASTs outside, with secondary containment that has manual shut-off valves in the storm drains. 4. Q: How are the chemicals shipped? a. ANSWER: Raw and final products are shipped via truck. If they decide to use the rail line in the future, they will notify DWQ and modify the stormwater plan. 5. Q: Current BASF NCGNE? a. ANSWER: David will contact BASF about requesting the NCGNE0120 to be rescinded. 3 NCS000522 Recommendations: Based on the documents reviewed, the application information submitted on October 23, 2007 is sufficient to issue an Individual Stormwater Permit. Prepared by (Signature) Date Stormwater Permitting Unit Supervisor Date /A91 Concurrence by Regional Offic Date WaterQuality Supervisor Date Regional Office Staff Comments 'Le - 1'o6 �46 iele (lea-7. 440t e4y 7. 1-11';g2e f 6. 4. -e-vule'w' 4 WIM, 300522 11 US. PC "!; Pin Mr. Robert Rebello, CEO US Polymers, Inc. 4330 Chesapeake Drive Charlotte, North Carolina Dear Mr. Rebello: Michael F. Easley, Governor William G. Ross Jr., Secretary North Carolina Departmp Cnt nd Natural Resources I'EeDisio of t October 8, 2007 OCT 10 2007 NC DENR MRO 28216 TWA -Surface Water Protection - . Subject: Stormwater application return #1159 US Polymers, Inc. - Charlotte Mecklenburg County On October 4, 2007, the Division of Water Quality, Stormwater Permitting Unit received your application for an individual NPDES stormwater discharge permit. The submittal included a transmittal letter from Project Integration, Inc., a single copy, of EPA Forms 1 and 2F, an 11" x 17" site layout drawing, and a single page of notes. Our initial. screening review indicates that the submittal is deficient, and we are returning it unprocessed. The submittal is deficient in the following particulars. 1. No application fee was included. The fee for an individual.NPDES stormwatee discharge permit is $860.. Our fee schedule is posted on the Stormwater Permitting Unit website at http://h2o.enr.state.nc.us/su/Fee schedule.html. 2'. North Carolina rules at 15A NCAC 2H .0105(a) require that the application package be submitted in triplicate. 3. The submittal did not include a location map as required by EPA Form 1 Section XI. The required contents of that map are identified on the face of the form,, and in the instructions for the form, both posted on our website at htto://h2o.enr.state.nc.us/su/Forms Documents.htm. 4. The included site plan is insufficient in several particulars: the 11" x 17" format is too small to legibly present the stormwater control features; the quality of reproduction is insufficient to allow us to understand the information on the drawing; and, the map does not identify outdoor areas of material storage or loading and unloading as required on the face of EPA Form 2F section III Site Drainage Map, and in the accompanying instructions. North Carolina Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 Phone (919) 733-7058 Internet: www.ncwatMualitv.ore Location; 512 N. Salisbury St. Raleigh, NC 27604 • Fax (919) 733-9612 Nno Caro ina ratura�ly Customer Service 1.877-623-6748 An Equal Opportunity/Affirmative Action Employer— 50% Recycled/10% Post Consumer Paper Mr. Robert Rebello Page 2 of 2 October 8, 2007 5. EPA Form 2F Section, IV B requires a narrative description of the potential for site materiafi to �e exposed to stormwater. The information supplied is insufficient for us to understand the potential for exposure. Please note that we phis information to identify the sampling parameters to be included in your stormwater permit: The notations, "Raw materials: Acrylamide, Surfactants,,oi" and "Products: Wastewater chemicals" are insufficient for that purpose,.?DWQ typically issues individual stormwater permits containing monitoring requirement$ for the significant process materials handled on a site; unless site conditions and/or analytical testing of the stormwater runoff will allow us to conclude that there is no potential for the materials to be present in the stormwater runoff. The on -site process materials were not tested for as part of the submittal, and it is likely that we will include some of them in the final permit. 6. EPA Form 2F Section VII Part C requires that you identify the pollutants shown, in Tables 2F-2, 2F-3, and 2F-4 that you know or have reason to believe will be present within the drainage area of each of your stormwater outfalls. You have provided no response to this requirement. I conclude from the application transmittal letter that a Stormwater Pollution Prevention Plan has already been developed for this site. Please submit that to me for a separate review when you resubmit the application package. Please contact me with any comments or questions. Sincerely," 4�Pk-, Ken Pickle DWQ Stormwater Permitting Unit (919)733-5083x584 ken.pickle@ncmail.net Enclosures: Returned application package cc letter only: D. Kirby, Project Integration, Inc., POB 1414, Greer, SC 29652-1414 DWQ Mooresville Regional Office SPU County Files - Mecklenburg County Bradley Bennett, SPU _SiYe i5c'f ` (z ? Ipip fpro ect gnte tadon, 2nc. October 16, 2007 ✓ Bradley Bennett ✓ North Carolina Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 Subject: US Polymers, Inc. Storm Water Permit Application Revised Dear Mr. Bennett: o 12=1 The US Polymers company has leased the existing BASF facility located on 4330 Chesapeake Drive, Charlotte, North Carolina 28216. The facility is planning to operate a waste water treatment chemicals manufacturing facility at the site. The facility will be using existing aboveground storage tanks (ASTs) to store chemicals and is installing tanks in the facility to complete the mixing and reaction processes. Based on the use of the chemicals as.well as the ASTs and loading and unloading of chemicals at the site the facility is required to obtain a NPDES Storm Water permit. The facility has a Standard Industrial code (SIC) of 2899. There is no general permit for this SIC, therefore US Polymers is submitting a permit application to obtain an individual permit for the facility. Previously, US Polymers submitted an application providing the Forms as well as an existing site map that was used by BASF. The submittal was provided with the understanding that a new drawing would follow. -- After the review of the submittal, North Carolina Division of Water Quality requested that, in addition to the new drawing, US Polymers provide MSDS for the raw materials being used, a $860 application fee, and also provide a draft copy of the facility SWPPP. The draft SWPPP was provided by e-mail to Ken Pickle on October 15th for review and comment. This application includes the application in triplicate (App. A), the back-up MSDS's (App. B), a site location map (Fig. 1, App. C), aerial photo of the plant layout (Fig. 2, App C) and the updated SWPPP site plan (Fig. 3, App. C). Please feel free to call me at (864) 497-6802 or David Soares at (803) 554-2188 with any questions or to set up a site visit to discuss any questions that you may have. We will be happy to quickly respond to any questions to expedite the permitting process. Thank you for your assistance. P_ 2350 Highway 101 South Greer, SC 29651(864) 655-8281, salesQpintegration.com P.O. Box 1414 Greer, SC 29652-1414 NC DWQ October 16, 2007 Page 2 Sincerely, M-4 David Kirby Project Manager • • 2350 Highway 101 South Greer, SC 29651 (864) 655-8281, P.O. Box 1414 Greer, SC 29652-1414 Sal esRp integration.com • 0 • Appendix A USEPA Application Forms land 2F 2350 Highway 101 South Greer, SC 29651 (864) 655-8281, sales@pintegration.com P.O. Box 1414 Greer, SC 29652-1414 Please print or tvpe in the unshaded areas only. � Cqo65 L2 Form Approved, OMB No, 2040-0086. 9 • • FORM U.S. ENVIRONMENTAL PROTECTION AGENCY I. EPA I.D. NUMBER 8 ,IA 1 ..EPA GENERAL INFORMATION F Consolidated Permits Program p GENERAL (Read the "General instructions" before starling) 2 s u Is LABEL ITEMS GENERAL INSTRUCTIONS If a preprinted tabs? has been provided, allot it in the designated space. Review the information careruily; it any of it I. EPA I.D. NUMBER Is incorrect, cross through it and enter the correct data in the - appropriate fill-in area below. Also, if any of the preprinted data is absent (the area to the left of the label space lists the III, FACILITY NAME PLEASE PLACE LABEL IN THIS SPACE information that should appear), please provide it in the proper ' fill-in area(s) below, If the label is complete and correct, you V. FACILITY MAILING need not complete Items I, ill, V, and VI (except VI-8 which ADDRESS must be completed regardless). Complete all items if na label has been provided. Refer to the instructions for detailed Item VI. FACILITY LOCATION descnpGons and for the iegal authorizations under which this data is collected, It. POLLUTANT CHARACTERISTICS INSTRUCTIONS: Complete A through J to determine whether you need to submit any permit application forms to the EPA. If you answer "yes" to any questions, you must submit this form and the supplemental form listed in the parenthesis following the question. Mark "X" In the box In the third column if the supplemental form is attached. If you answer "no" to each question, you need not submit any of these forms. You may answer "no" if your activity is excluded from permit requirements; see Section C of the instructions. See also, Section 0 of the instructions for definitions of bold-faced terms. Mark'X' Mark "x" YES NO FORM ATTACHED YES No FORM ATTACHED SPECIFIC QUESTIONS SPECIFIC QUESTIONS A. Is this facility a publicly owned treatment works which results in a discharge to waters of the U.S.? (FORM 2A) X B. Does or will this facility (either existing or proposed) include a concentrated animal feeding operation or X aquatic animal production facility which results in a IS I7 18 19 t W ], discharge to waters of the U.S.? (FORM 2B) C. Is this a facility which currently results in discharges to waters of the U.S. other than those described in A or B �/ X D, Is this a proposed facility (other than those described in A or B above) which will result in a discharge to waters of X above? (FORM 2C) Z] ]3 21 the U.S.? (FORM 2D) 25 70 27 E. Does or will this facility treat, store, or dispose of F. Do you or will you inject at this facility industrial or hazardous wastes? (FORM 3) X municipal effluent below the lowermost stratum X containing, within one quarter mile of the well bore, 2e 29 W underground sources of drinking water? (FORM 4) a, as es G. Do you or will you Inject at this facility any produced water H. Do you or will you inject at this facility fluids for special or other fluids which are brought to the surface in processes such as mining of sulfur by the Frasch process, connection with conventional oil or natural gas production, X solution mining of minerals, in situ combustion of fossil X inject fluids used for enhanced recovery of oil or natural fuel, or recovery of geothermal energy? (FORM 4) gas, or inject fluids for storage of liquid hydrocarbons? (FORM 4) 31 35 X a7 b I. Is this facility a proposed stationary source which is one J. Is this facility a proposed stationary source which is of the 28 industrial categories listed in the instructions and �/ X NOT one of the 28 industrial categories listed in the which will potentially emit 100 tons per year of any air instructions and which will potentially emit 250 tons per /\ pollutant regulated under the Clean Air Act and may affect year of any air pollutant regulated under the Clean Air Act b •I 42 4a 14 43 or be located in an attainment areal (FORM 5) and may affect or be located in an attainment area? (FORM 5) Ill. NAME OF FACILITY I US Polymers tSKIP ..,, IV. FACILITY CONTACT A. NAME & TITLE (last, frsi, & rifle) B. PHONE (area code & no.) 2 Robert e alto, PresYdent':- 71. ��:. •• •`-,: Is 1e 15 M foe Ie el s]• ffi Lb'•:'� h''.. l'-; V.FACILTY MAILING ADDRESS A. STREET OR P.O. BOX A 3 4 3 hes Capeaa e Drive IS le 16 B. CITY OR TOWN C. STATE D. ZIP CODE 4 0 Charlotte C 2 216 1s le 10 It 13 17 51 VI. FACILITY LOCATION A. STREET, ROUTE NO. OR OTHER SPECIFIC IDENTIFIER } ' { . .. �s •rh>�� 4 3 hesapea e Drive t" 5 Is B. COUNTY NAME ',.• ,;," 'r,r Meck en urg C. CITY OR TOWN D. STATE E. ZIP CODE F. COUNTY CODE (iflarolcrr) c 6 C a l t e C 2 216 15 to M ll �] 17 51 1 51 EPA Form 3510-1 (8-90) CONTINUE ON REVERSE WCztlhlll :1HyctilIT, rla:119[ielarl • 0 • VII. SIC CODES 4-dr' if in order of riori A, FIRST B. SECOND 2(spe7 m 2899 le I. (spec•if} Miscellaneous chemical Products 7 �15 In 19 rif') C, THiRD D, FOURTH c (specifj•) (specifj') 7 Tc7:: IY Vlll. OPERATOR INFORMATION A. NAME B. Is the name listed in Item ° VIII-A also the owner? US Polymers, Inc g . ❑ YES ❑ NO u 16 54 ea C. STATUS OF OPERATOR (Earer the appropriate leller i,rro Tire answer box i( •'Usher, " spcc ffy.) D. PHONE (area code & rro.) F=FEDERAL M= PUBLIC (vlher'rhvnfederalorslure) p (aperfj) c STATEPRIVA0 = OTHER (speed') A P = 5n 15 19 1e jig i+ 122 aB E. STREET OR P.O. BOXip,17 ` 0 14k 'i5 4 3 Chesapeake rive 5 F. CITY OR TOWN I G. STATE I H. ZIP CODE IX. INDIAN LAND Is the facility located on Indian lands? N15 Charlotte1128216 NC ❑ YES m NO 12 +e w n �a a 51 X. EXISTING ENVIRONMENTAL PERMITS A. NPDES D chur'es ro Sur ace !Ye D. PSD Air E,niaaklns root 1'rn rased Sources C T I C t 1 IK'! T B. UIC eUndcaFtard fn'ecrion v Fluids E. OTHER s tact r' C T I C T I 9 U 9 Is le n In 70 1e T ss C. RCRA Nuzwidous Waves) E. OTHER s Teci '' c T 1 (spec•if') 9 R 9 1s In 1 IT lie 30 1 IS 1 18 1 17 Ile 3e Xi. MAP Attach to this application a topographic map of the area extending to at least one mile beyond property boundaries. The map must show the outline cf the facility, the location of each of its existing and proposed intake and discharge structures, each of its hazardous waste treatment, storage, or disposal facilities, and each well where it injects fluids underground, Include all springs, rivers, and other surface water bodies in the map area. See instructions for precise requirements. XII. NATURE OF BUSINESS(provide a brief descri tion The facility Produces wastewater treatment chemicals to be used by various industries. XIII. CERTIFICATION (sea instructions) l certify under penally of law that l have personally examined and am familiar with the information submitted in this application and all attachments and that, based on my inquiry of those persons immediately responsible for obtaining the information contained in the application, l believe that the information is true, accurate, and complete. l am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment. A. NAME & OFFICIAL TiTLE (rlre or print) B. SIGNATURE 01C. DATE SIGNED Robert Rebello, President COMMENTS FOR OFFICIAL USE ONLY JCP ss LVA 1•prm Jb10-1 (8-90) S • 9 EPA ID Number (copy from Item 1 of Form 1) Form Approved. OMB No. 2040-0086 Please print or type in the unshaded areas only, I I Avoroval explres 5-31-92 FARM ZF NPDES U.S. Environmental Protection Agency EPA Washington, DC 20460 Application for Permit to Discharge Storm Water Discharges Associated with Industrial Activity Paperwork Reduction Act Notice Public reporting burden for this application is estimated to average 28.6 hours per application, including time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding the burden estimate, any other aspect of this collection of information, or suggestions for Improving this form, including suggestions which may Increase or reduce this burden to: Chief, Information Policy Branch, PM-223, U.S. Environmental Protection Agency. 1200 Pennsylvania Avenue, NW, Washington, DC 20460, or Director, Office of Information and Regulatory Affairs, Office of Management and Budget, Washington, DC 20503. 1. Outfall Location For each outfali, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A.Outfall Number (list) B. Latitude C. Longitude D. Receiving Water (name) SW 001 35.00 16.00 40.00 80.00 52.00 20.00 Unnamed Tributary to Stewart Creek SW 002 35.00 16.00 41.00 80.00 52.00 30.00 Unnamed Tributary to Stewart Creek SW 003 35.00 16.00 49.00 80.00 52.00 26.00 Unnamed Tributary to Stewart Creek 11. Improvements A. Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or operation of wastewater treatment equipment or practices or any other environmentat programs which may affect the discharges described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, and grant or loan conditions. 1. Identification of Conditions, Agreements, Etc. 2. Affected Ouffalls 3. Brief Description of Project 4, Final Compliance Date number source of discharge a. req. b. pro. N/A B: You may attach additional sheets describing any additional water pollution (or other environmental projects which may affect your discharges) you now have under way or which you plan. Indicate whether each program is now under way or planned, and indicate your actual or planned schedules for construction. III. Site Drainage Map Attach a site map showing topography (or Indicating the outline of drainage areas served by the outfalls(s) covered in the application if a topographic map is unavailable) depicting the facility including: each of its intake and discharge structures; the drainage area of each storm water outfall; paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for outdoor storage of disposal of significant materials, each existing structural control measure to reduce pollutants in storm water runoff, materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied; each of its hazardous waste treatmenl, storage or disposal units (including each area not required to have a RCRA permit which is used for accumulating hazardous waste under 40 CFR 262,34); each well where fluids from the facility are injected underground; springs, and other surface water bodies which received storm water discharges from the facility, • EPA Form 3510.2F (1-92) Page 1 of 3 Continue on Page 2 • �i Continued from the Front IV. Narrative description of Pollutant Sources A. For each oulfall, provide an estimate of the area (Include units) of imperious surfaces (Including paved areas and bullding roofs) drained to the outfall, and an estimate of the total surface area drained by the oulfall. r Outfall Area of impervious Surface Total Area Drained Oulfall Area of Impervious Surface Total Area Drained Number (provida units) (provida units) Number (provide units) (provide units) SW 001 2.50 acres 4.13 acres SW 002 2.73 acres 5.99 acres SW 003 0.95 acres 0.95 acres B. Provide a narrative description of significant materials that are currently or in the past three years have been treated, stored or disposed in a manner to allow exposure to storm water; method of treatment, storage, or disposal; past and present materials management practices employed to minimize contact by these materials with storm water runoff; materials loading and access areas, and the location, manner, and frequency in which pesticides, herbicides, sot conditioners, and fertilizers are applied. Raw Materials: Acrylamide, Surfactants, oils. ' Products: Wastewater chemicals The raw materials (see above) are Stared in ASTa outside in the secondary containment. The product will be scored inside and shipped. The MSDSs are attached in Appendix A C. For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants In storm water runoff; and a description of the treatment the storm water receives, including the schedule and type of maintenance for control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge. Outfall List Codes from Number Treatment Table 2F-1 01 N/A 02 N/A 03 4A V. Nonstormwater Discharges A. I certify under penalty of law hat the ouffell(s) covered by this application have been tested or evaluated for the presence of nonstormwater discharges, and that all nonsiormwater discharged from these Dutfall(s) are identified in either an accompanying Form 2C or From 2E application for the outfall. Name and Official Title (type or print) Signature Date Signed Robert Rebello, President B. Provide a description of the method used, the date of any testing, and the onsite drainage points that were directly observed during a test, Visual Observation of outfalls 1-3 i. Significant Leaks or Spills Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three years, including the approximate date and location of the spill or leak, and the type and amount of material released, one tNA Form 3510-2F (1.92) Page 2 of 3 Continue on Page 3 11 Continued from Page 2 1 EPA ID Number (copy from atom 1 of Form 1) il. Discharge Information A. B, C, & D; See instructions before proceeding. Complete one set of tables for each outfatl. Annotate the outfall number in the space provided. Table VII-A, VII-B, VII-C are included on separate sheets numbers VII-1 and VII-2. E. Potential discharges not covered by analysis - is any toxic pollutant listed in table 2F-2, 2F-3, or 2F-4, a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? © Yes (list al1 such pollutants below) ❑ No (go to Section IX) oil & grease Vill. Biological Toxicity Testing Data Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? ❑ Yes (list all such pollutants below) Q No (go to Section IX) IX. Contract Analysis Information Were any of the analyses reported in Item VII performed by a contract laboratory or consulting firm? ❑ Yes (list the name, address, and telephone number of, and pollutants © No (go to Soction X) analyzed by, each such laboratory or firm below) A. Name B. Address C. Area Code & Phone No. D. Pollutants Analyzed X. Certification l certify under penalty of few that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualif+ed personnel property gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gatherfng the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. ! am aware that there aro significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. A. Name & Official Title (Type Or Print) B. Area Code and Phone No. Robert Rebello, President (980) 329-8109 C. Signaturl D. Data Signed , q /� ✓ 1 EPA Form 3510-2F (1-92) Page 3 of 3 • • EPA ID Number (copy from Item f of Form 1) Form Approved. OMB No. 2040-0086 Approval expires 5-31-92 VI I. Discharge information (Continued from page 3 of Form 2)9 Part A — You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. Pollutant and CAS Number (if available) Maximum Values {include units) Average Values include units) Number of Storm Events Sampled Sources of Pollutants Grab Sample Taken During First 20 Minutes Flow -Weighted Composite Grab Sample Taken During First 20 Minutes Flow -Weighted Composite Oil and Grease N/A -New Facili NIA Biological Oxygen Demand BODS) Chemical Oxygen Demand (COD) Total Suspended Solids (TSS) Total Nitrogen Total Phosphorus PH Minimum Maximum Minimum Maximum Pert B — List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater (if the facility is operating under an existing NPDES permit). Complete one table for each oulfall. See the instructions for additional details and requirements. Pollutant and CAS Number Ofaveilablo) Maximum Values include units) Average Values include units) Number of Storm Events Sampled Sources of Pollutants Grab Sample Taken During First 20 Minutes Flow -Weighted Composite Grab Sample Taken During First 20 Minutes Flow -Weighted Composite EPA Form 3510-2F (1-92) Page VII-1 Continue on Reverse Continued from the Front • • Part C - List each pollutant shown in Table 2F-2, 2F-3, and 2F-4 that you know or have reason to believe is present. See the instructions for additional details and requirements. Complete one table for each outfall. PoWlenl and CAS Number (ifavailable) Maximum Values (include units) Average Values {include units) Number of Storm Events Sampled Sources of Pollutants Grab Sample Taken During First 20 Minutes Flow -Weighted Composite Grab Sample Taken During First 20 Minutes Flow -Weighted Composite If Part D — Provide data for the storm event(s) which resulted in the maximum values for the flow weighted composite sample. 1. Date of Storm Event 2. Duration of Storm Event (in minutes) 3. Total rainfall during storm event (in inches) 4. Number of hours between beginning of storm measured and end of previous measurable rain event 5, Maximum flow rate during rain event (gaiionsiminufo or specify units) S• Total flow from rain event (gallons or specify units) 7. Provide a description of the method of flow measurement or estimate. EPA Form 3510-2F (1-92) Page VII.2 0 Appendix B • 0 2350 Highway 101 South Greer, SC 29651(864) 655-8281, P.O. Box 1414 Greer, SC 29652-1414 sales®pintegration.com MSDS's Kemira MSDS: 0000210 Print Date: 01-Oct-2006 Revision Date: 26-Sep-2006 SAFETY DATA SHEET 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Product name: Acrylamide, 60% Aqueous, Inhibited Product Description: Acrylamide in water Intended/Recommended Use: Process Chemical Kemira Kemi AB, P.O. Box 902, SE-25109, HELSINGBORG, Sweden - Phone No.: +46 42 17 10 00 EMERGENCY PHONE: IN THE NETHERLANDS: 0181-295500; OUTSIDE THE NETHERLANDS: 31-181-295500 2. COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS INGREDIENTS Component/ CAS No. % (WIW) EC -No Symbol 1 Risk Phrases Acrylamide -- 50 201-173-7 T; R45 R46 R20121 R25 79-06-1 R36138 R43 R48/23/24/25 0 R62 See Section 16 for Ingredient Risk Phrase Text 3. HAZARDS IDENTIFICATION HUMAN AND ENVIRONMENTAL. HAZARDS May cause sensitization by skin contact. May cause cancer. May cause heritable genetic damage. Possible risk of impaired fertility. Harmful by inhalation, in contact with skin and if swallowed. Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. 4. FIRST AID MEASURES Ingestion: Obtain medical attention. Do NOT induce vomiting unless directed to do so by a physician. Never give anything by mouth to an unconscious person. Skin contact: Take off immediately all contaminated clothing. Wash immediately with plenty of water and soap. Pay particular attention to skin crevices, nail folds, etc. Do not reuse contaminated clothing without laundering. Do not reuse contaminated leatherware. Get medical attention if signs and symptoms of toxic effects appear. Eye contact: Rinse immediately with plenty of water for at least 15 minutes. Obtain medical advice if there are persistent symptoms. Acrylamide, 50% Aqueous, Inhibited MSDS: 0000210 Print Date: oi-ocr2ow Page 2 of 10 Inhalation: Remove to fresh air. If breathing is difficult, give oxygen. Obtain medical advice if there are persistent symptoms. If not breathing, give artificial respiration. Notes to physician: Ingestion may cause central nervous system (CNS) depression and seizures. Do not induce vomiting if these symptoms are present because of the potential for aspiration. Gastric lavage may be indicated if performed soon after ingestion, or for patients who are comatose or at risk of convulsing. Either acute or chronic exposure may lead to weak or absent reflexes, positive Romberg's sign, loss of vibration and position senses and numbness and tingling of the limbs. An early sign of toxic effects is peeling of the skin of the fingertips. Weekly examinations (by plant medical staff or supervisor) of the skin of hands and fingers for peeling are recommended. Evidence of peeling requires removal from work duties with possible exposure. Once the skin has returned to normal, the employee may be returned to normal duties. If the peeling should occur a second time, permanent removal from work duties with possible exposure is recommended. Other than removal from exposure and decontamination, there is no definite proven treatment for acrylamide intoxication. Pyridoxine (vitamin 136), pyruvate, and N-acetylcysteine have been used to reduce toxicity in experimental studies, but are unproven. 5. FIRE -FIGHTING MEASURES Suitable Extinguishing Media: For small fires, use water spray, carbon dioxide or dry chemical to extinguish fires. For large fires, use water spray or fog or dry chemical. Move containers from fire area if it can be done without risk. Dike fire control water for later disposal; do not scatter the material. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. If a truck, rail car, shipping container or other large quantity of acrylamide is involved in a fire, ISOLATE for 800 meters in all directions and consider initial evacuation for 800 meters in all directions. Protective Equipment: Wear self-contained, positive pressure breathing apparatus and full firefighting protective clothing for fire situations only. This equipment is not effective in spill situations - See MSDS Section 6 (Accidental Release Measures). Special Hazards: Elevated temperatures or contamination may cause material to polymerize causing a pressure buildup that may violently rupture tanks or containers. In the event this material begins to polymerize, isolate the area, use water fog or spray to control vapors. Take defensive actions only. Let the reaction nun its course. Once the reaction is complete, normal precautions for acrylamide should be followed. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Refer to Section 8 (Exposure Controls/Personal Protection) for appropriate personal protective equipment. Wear recommended, full facepieoe, positive pressure, self-contained breathing apparatus, two piece. PVC suit with hoof of r:Vc, coveralls with hood, impervious 916ves (e.g., Butyl or neoprene), and rubber or neoprene boots. 0 Acrylamide, 50% Aqueous, Inhibited MSDS: 0000210 Print Date: oi-oa-zoos Page 3 of 10 Methods for cleaning up: Isolate the spill or leak area immediately. Keep unauthorized personnel away, upwind and out of low areas. Ventilate enclosed areas. For larger spills, the area should be isolated immediately for at least 25 to 50 meters in all directions. Do not touch damaged containers or spilled material unless wearing appropriate protective equipment. Stop leak if possible if it can be done without risk. Prevent entry into waterways, sewers, basements or confined areas. SPILLS OF ACRYLAMiDE MUST BE PROMPTLY REMOVED. Cover liquid spills with an inert absorbent material. Sweep up and place in a waste disposal container. Do not permit liquid spills to dry. Flush spill area with plenty of water to 'chemical sewer (if permitted) or otherwise dispose of in accordance with applicable governmental regulations. If allowed by local regulations, a sewage treatment plant with sludge adapted to acrylamide is the preferred method for disposing spill cleanup water. Check with local authorities before disposing of spill cleanup water in this manner. Areas not thoroughly cleaned will retain a residue of dry acrylamide after the water evaporates. This residue is very water soluble and should be removed by re -flushing the spill area with plenty of water as described above. If the spill partially polymerizes, the resulting acrylamide polymers formed are very slippery when wet. Exercise caution to avoid slipping and falling. The spill area should be re -cleaned if slipperiness remains. In the event of release due to accidental polymerization, isolate the area and use water fog or spray to control vapors. Dike control water for later disposal. Take defensive actions only. Let the reaction run its course. Once the reaction is complete, normal precautions for acrylamide should be followed. 7. HANDLING AND STORAGE Handling Acrylamide solutions must be kept free of any contamination to avoid accidental polymerization. Contact with rust, oxidizing and reducing agents, and vinyl polymerization intiators will cause rapid polymerization. Avoid contact with materials such as persulfates, bisulfites, peroxides and azo compounds. Avoid contact with adds and bases as these materials may result in a solution pH outside the recommended range as discussed herein. The cupric ion inhibitor in acrylamide solution may be rendered ineffective by chelating agents and precipitants for copper, Avoid contact with materials such as EDTA, polyphosphates, sulfides, carbonates, etc. Metallic copper, aluminum, brass, bronze and iron will cause slow polymerization in the area of contact with acrylamide solution. Avoid contact with metals above copper in the Electromotive (EMF) series. Stainless steel (304-316) is the recommended material of construction. Drums that have contained the material should be stored separately and not used for any other purpose. To prevent inadvertent exposure, it is important that surfaces subject to acrylamide contamination be thoroughly cleaned on a routine basis. For additional information, see publication 'ACRYLAMIDE AQUEOUS SOLUTION HANDLING & STORAGE PROCEDURES'. Storage To prevent accidental polymerization, Acrylamide solutions are stabilized by cupric ion (Cu++) and dissolved oxygen (air). Storage tanks must be sparged with air to maintain dissolved oxygen (air) levels. A 4 m3 tank should be sparged at a rate of a least 300 Ilhr, A 40 m3 tank should be sparged at a rate of at least 600 Ar. Maintain a pH range between 5.2 and 6.0 to avoid destabilizing the solution. (High pH will cause the cupric ion inhibitor to precipitate rendering it ineffective, whereas low pH reduce the stability of the solution.) Keep away from heat sources and direct sunlight. Storage temperatures must be maintained below 32 C (90 F) and above the crystallization point - See Section 9, Melting Point. (Acrylamide stability decreases at elevated temperatures. Low temperatures may destabilize the solution if acrylamide crystals separate from the solution). Ambient air storage temperatures may exceed 32 C (90 F) for short tern periods, but should never exceed 45 C (113 F). To prevent the loss of dissolved oxygen -(air), acrylamide solutions shouid not'be kept under or sparged with an inert gas. Heating in an open container may cause loss of oxygen. Shipping containers should not be overfilled - Retain --7% air space to maintain adequate dissolved oxygen levels for normal shipping conditions. Uncontaminated acrylamide solutions that are properly maintained (i.e., aerated and pHttemperature controlled) can be stored safely at temperatures up to 32 C (90 F) for 6 months. Packaged acrylamide solutions should be consumed on a first in, first out basis. r 8. EXPOSURE CONTROLS 1 PERSONAL PROTECTION 3?�5 0 CONTROL PARAMETERS - Limits Acrylamide, 50% Aqueous, Inhibited MSDS: OOM210 Print Date: oi-oa-20m Page 4 of 10 8. EXPOSURE CONTROLS 1 PERSONAL PROTECTION Acrylamide 78-06-1 Germany: MAK (Maximale Arbeitsplatzkonzentration) 0.03 mg,1W (TWA) 0.06 mg/m3 solid (TWA) 0.06 mg1m3 solid (TRK) 0,03 mg/m3 others (TRK) (skin) United Kingdom: MEL (Maximum Exposure Limits) 0.3 mg/m3 (MEL-TWA) (MEL-skin) France: VLEP (Valeur Limites dExposition Professionnelle) 0.1 ppm (VME) 0.3 mg/m3 (VME) Denmark: Graensevaerdier 0.03 mg/m3 (TWA) (skin) Norway: 0.03 mg/m3 (TWA - OEL) (skin) Sweden: Hygieniska Gransvarden 0.03 m91m3 (LLV) 0.1 mg/m3 (STV) (skin) ACGIH (TLV) 0.03 mg/m3 (TWA) (skin) Engineering measures: Utilize a closed system process where feasible. Where a closed system is not used, good enclosure and local exhaust ventilation should be provided to minimize exposure. Eyewash fountains and safety showers should be available where this material is handled. Respiratory protection: Where adequate engineering controls are in effect, and measurements confirm airborne concentrations are below the permissible exposure level, no respiratory protection is required. Full facepiece, positive pressure, supplied air respirators or self-contained breathing apparatus must be used for unknown concentrations. Acrylamide exhibits no warning properties at concentrations at or below the permissible exposure level. Although a cartridge respirator is not specifically government recommended for use with acrylamide, this type of respirator can be effective in controlling exposures of known concentrations in the workplace. Respirator cartridge service life tests show that organic vapor cartridges will provide protection from airborne levels of acrylamide up to 9 mg/m3. No breakthrough at this concentration was detected after eight hours at a relative humidity of 85%. THE CARTRIDGES MUST BE CHANGED AT THE BEGINNING OF EACH SHIFT. Eye protection: For operations where eye and face contact with this material can occur, wear head covering and chemical splash proof goggles or faceshield. A full facepiece respirator will provide the necessary eye protection where handling makes it desirable. Skin Protection: For operations where skin contact with this material can occur, wear impervious gloves (e.g. PVC or nitrile), rubber or neoprene shoes or boots (leather is unsuitable unless covered) and impervious disposable coveralls that provide head, arm and foot protection from contact with this material. WASH GLOVES THOROUGHLY BEFORE REMOVING AND DISCARD GLOVES THAT ARE CONTAMINATED ON THE INSIDE. Additional advice: Food, beverages, and tobacco products should not be carried, stored, or consumed where this material is in use. Before eating, drinking, or smoking, wash face and hands thoroughly with soap and water. Shower after completion ofworkshift. Launder work clothing at end of workshift, prior to use. Store street clothing separately from work clothing and protective equipment. Work clothing and shoes must not be taken home. D �� y qD Acrylamide, 50% Aqueous, Inhibited NISIDS: 0000210 Print Date: oi.oa-zoos Page 5 of 10 0 9. PHYSICAL AND CHEMICAL PROPERTIES Colour: colorless to light -yellow or blue-green ° Appearance: liquid 5� Odour: odourless 53. Bolling Point: 106 °C Melting Paint: Crystallization point varies with % solids. 12-14 C @ 50%; 16-18 C @ 55%. Vapour pressure: 19 mm Hg @ 25 °C Partial pressure of acrylamide above solution is 0.0023 mm Hg@25C. , Specific GravitylDensity: 1.04 @ 25 °C Vapour density: similar to water Percent Volatile (% by wt.): --50 pH: 5.2 - 6.0 Saturation In Air (% By Vol.): 2.5@ 25 C (water) plus 0.0003% @ 25 C (acrylamide) Evaporation rate: similar to water Solubility In Water: All proportions Volatile Organic Content (EU): Not available Flash point: Not applicable Flammable Limits (% By Vol): Not applicable Autoigniiion temperature: Not available Decomposition temperature: --200 °C Partition coefficient (n- Log Pow = -0.67 to -1.65 (value for 100% acrylamide) octanoltwater): • 10. STABILITY AND REACTIVITY Stability: Stable Conditions To Avoid: Stable if handled and stored according to recommendations shown in Section 7 (Handling and Storage). These solutions are highly reactive however, and can polymerize if not maintained as recommended. Polymerization: May occur Conditions To Avoid: Avoid contamination with rust, oxidizing and reducing agents, vinyl polymerization initiators, acids, bases, and materials that chelate or precipitate copper. Avoid temperatures above 32 C (90 F) and below the crystallization point. Avoid loss of dissolved oxygen. Maintain dissolved oxygen levels by sparging with air. Maintain a pH range between 5.2 and 6.0. Keep away from heat sources and direct sunlight. See Section 7 (Handling and Storage). Mater!c:c tc avoid; :' Oxidizing age, is (e.g. persuifates), reducing agents'(e.g. bisulfites), vinyl polymerization initiators (e.g. peroxides, azo compounds), acids, bases, chelating agents (e.g. EDTA), precipitants for copper (e.g. sulfides, carbonates), rust, metallic copper, aluminum, brass, bronze, iron. Hazardous decomposition Carbon monoxide products: carbon dioxide ammonia oxides of nitrogen I I - TOXICOLOGICAL INFORMATION • Potential health effects Acrylarnide, 50% Aqueous, Int ibded WDS: 0000210 Print Date: oi-oct-2= • 11. TOXICOLOGICAL INFORMATION Page 6 of 10 May cause sensitization by skin contact. May cause cancer. May cause heritable genetic damage. Possible risk of impaired fertility. Harmful by inhalation, in contact with skin and if swallowed. Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. PRODUCT TOXICITY INFORMATION ACUTE TOXICITY DATA Oral rat dermal rabbit Inhalation rat LOCAL EFFECTS ON SKIN AND EYE Acute Irritation dermal Acute Irritation eye ALLERGIC SENSITIZATION Sensitization dermal Sensitization Inhalation GENOTOXICITY Assays for Gene Mutations to Ames Salmonella Assay Not mutagenic OTHER INFORMATION May Cause Nervous System Damage Carcinogenic to Laboratory Animals Reproductive Toxin in Laboratory Animals HAZARDOUS INGREDIENT TOXICITY DATA ACUTE TOXICITY DATA Acrylamide oral (gavage) rat Acute LD50 (Actual) 294 mg/kg dermal rabbit Acute LD50 (Actual) 252 mg/kg Inhalation rat Acute LC50 (4 hr) > 1.5 mg/l LOCAL EFFECTS ON SKIN AND EYE Acrylamide Acute Dermal Irritation rabbit Not irritating Acute Eye Irritation rabbit irritating ALLERGIC SENSITIZATION Acrylamide Skin Sensitization guinea pig Sensitizing GENOTOXICITY Assays for Gene Mutations Acrylamide Ames Salmonella Assay Not mutagenic Acute LD50 200 - 800 mg/kg Acute LD50 1747 mg/kg Acute LC50 4 hr >3.0 mg/I Not irritating Not irritating Sensitizing No data Acrylamide, 50% Aqueous, Inhibited MSDS: 0000210 Print Date: 01-0d-ewe Page 7 of 10 OTHER INFORMATION Acrylamide May Cause Nervous System Damage Carcinogenic to Laboratory Animals Reproductive Toxin in Laboratory Animals 12. ECOLOGICAL INFORMATION This material is readily biodegradable. Acrylamide is readily biodegradable. B005 test results range from less than 10% to more than 70% ThbD, depending on the adaptation (acclimation) of the biomass. Wastewater treatment plants with well adapted biomass can achieve 100% removal by biodegradation. ALGAE TEST RESULTS Test: Growth Inhibition (OECD 201) Duration:72 hr Species: Green Algae (Selenastrum capricomutum) 67.7 mg/l EbC50 >100 mgA ErC50 FISH TEST RESULTS Test: Acute toxicity, freshwater (OECD 203) Duration: 96 hr. Procedure: Flow -through. Species: Bluegiil Sunfish (Lepomis macrochirus) 200 mg/I LC50 Test: Acute toxicity, freshwater (OECD 203) Duration: 96 hr Procedure: Flow -through Species: Rainbow Trout (Oncorhyncus mykiss) 220 mg/I LC50 Test: Acute toxicity, freshwater (OECD 203) Duration: 96hr Procedure: Flow -through Species: Fathead Minnow (Pimephales promelas) 240 mg/l LC50 INVERTEBRATE TEST RESULTS Test: Acute Immobilisation (OECD 202) Duration: 48 hr Procedure: Flow -through Species: Water Flea (Daphnia magna) 320 mg/I LC50 Test: Acute Immobilisation (OECD 202) Duration: 96 hr Procedure: Flow -through • Species: Mysid Shrimp (Mysidopsis bahia) Acrylamide, 50% Aqueous, Inhibited NISDS: 00D0210 Print Date: oi-ob-zoos 12. ECOLOGICAL INFORMATION 156 mg/I LC50 OTHER TEST RESULTS Test: Sediment Toxicity (PARCOM) Duration:48 hr Species: Midge Larvae (Paratanytarsus parthenogenetica) 820 mg/I LC50 DEGRADATION Test: Biological Oxygen Demand Duration:28 day Procedure: Other 1.35 g/g 100% of Th0D Test: Biological Oxygen Demand Duration:5 day Procedure: Other <10-70% Page 8 of 10 13. DISPOSAL CONSIDERATIONS KEMIRA encourages the recycle, recovery and reuse of materials, where permitted. If•disposal is necessary, KEMIRA recommends that organic materials, especially when classified as hazardous waste, be disposed of by thermal treatment or incineration at approved facilities. All local and national regulations should be followed. 14. TRANSPORT INFORMATION This section provides basic shipping classification information. Refer to appropriate transportation regulations for specific requirements. ADR/RID Proper Shipping Name: Acrylamide, solution Class: 6.1 UN Number: 3426 Packing Group: III Transport Label Required. toxic IMO Proper shipping name: Acrylamide solution Hazard Class: 6.1 UN Number: 3426 Packing group: III Transport Label Required: toxic ICAO / IATA Proper shipping name: Acrylamide solution Hazard Class: 6.1 Packing group: III UN Number. 3426 Transport Label Required: toxic Packing Instructions/Maximum Net Quantity Per Package: Passenger Aircraft: 611; 60L Cargo aircraft: 618; 220L • Acrylamide, 50% Aqueous, Inhibited MSDS: 0000210 Print Date: oi-oa zoos Page 9 of 10 15: REGULATORY INFORMATION EU MARKING AND LABELING Symbol(s): T - Toxic Risk Phrases: R43 - May cause sensitization by skin contact. R45 -'May cause cancer. R46 - May cause heritable genetic damage. R62 - Possible risk of impaired fertility. R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R48/23/24/25 - Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Safety Phrases: 853 - Avoid exposure - obtain special instructions before use. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). INVENTORY INFORMATION European Union (EU): All components of this product are included on the European Inventory of Existing Chemical Substances (EINECS) or are not required to be listed on EINECS. United States (USA): All components of this product are included on the TSCA Chemical Inventory or are not required to be listed on the TSCA Chemical Inventory. This product contains a chemical substance that is subject to export notification under Section 12 (b) of the Toxic Substances Control Act, 15 U. S. C. 2601 et. seq. (This requirement applies to exports from the United States only.) Canada: All components of this product are included on the Domestic Substances List (DSL) or are not required to be listed on the DSL. Australia: All components of this product are included in the Australian Inventory of Chemical Substances (AICS). China: All components of this product are included on the Chinese inventory or are not required to be listed on the Chinese inventory. Japan: All components of this product are included on the Japanese (ENCS) inventory or are not required to be listed on the Japanese inventory. Korea: All components of this product are included on the Korean (ECL) inventory or are not required to be listed on the Korean inventory. Philippines: All components of this product are included on the Philippine (PICCS) inventory or are not required to be listed on the Philippine inventory. 16.OTHER INFORMATION Reasons for Issue: New Format Component Risk Phrases Acrylamide Acrylamide, 50% Aqueous, Inhibited MSDS: 0000210 Print Date: oi-oc+-ww Page 10 of 10 R45 - May cause cancer. R46 - May cause heritable genetic damage. R25 - Toxic if swallowed. R43 - May cause sensitization by skin contact. R62 - Possible risk of impaired fertility. R20/21 - Harmful by inhalation and in contact with skin. R36/38 - Irritating to eyes and skin. R48/23/24/25 - Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Randy Deskin, MD„ DABT+1-973-357-3100 This information is given without any warranty or representation. we do not assume any legal responsibility for same, nor do we give permission, inducement, or recommendation to practice any patented invention without a license. It is offered solely for your consideration, investigation, and verification. Before using any product, read its label. • 17J Safety Data Sheet►, EUROQUAT 80MC Xn Safety Data Sheet dated 06/01/2007, version 3 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANYIUNDERTAKING Trade name: EUROQUAT 80MC Trade code: M0381 Product type: (dimethhylaminoethyl acrylate) quaternizated by methyl chloride Use: Process chemical Company: EUROPOLIMERI S.p.A. - Via Galvani, 40 - 36066 Sandrigo (Vi) — Italy Phone +39 0444 750039 Fax +39 0444 657185 e-mail: info@3fchimica.com Emergency telephone number of the company and/or of an authorised advisory centre: EUROPOLIMERI S.p.A. - Phone +39 0444 750039 2. COMPOSITIONIINFORMATION ON INGREDIENTS SUBSTANCE CONC.% #CAS SYMBOL R PHRASES (2-(acryloyloxy)ethyl] 80% --- Xn R20/22-R36137/38 trimethylammonium chloride R41-R43 3. HAZARDS IDENTIFICATION The product is harmful if inhaled or ingested. If brought into contact with the eyes, the product causes considerable irritation which can last for . over 24 hours. If brought into contact with the skin, the product may cause sensitisation of the skin. 4. FIRST AID MEASURES Contact with skin: Immediately take off all contaminated clothing. Areas of the body that have - or are only even suspected of having - come into contact with the product must be rinsed immediately with plenty of running water and possibly with soap. Remain under shower for a minimun of 10-20 minutes. Contact with eyes: Wash immediately and thoroughly with running water, keeping eyelids raised, for at least 10 minutes. Following this, protect the eyes with sterile gauze or a clean, dry, handkerchief. OBTAIN A MEDICAL EXAMINATION. Do not use eyewash or ointment of any kind (before obtaining an examination or advice from an eye specialist). Swallowing: Do not under any circumstances induce vomiting. If unconscious do not give anything by mouth. Check for breathing and pulse if present. If conscious rinse out the mouth with water. Give 500 mL of water to drink immediately and repeated drinks of water at a rate of a cupful (200 mL) every 10 minutes. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY. Inhalation: Ventilate the premises. The patient is to be removed immediately from the contaminated premises. If conscious place in a well ventilated area. If unconscious do not give anything by mouth. Check for breathing and pulse. Artificial respiration and/or oxygen may be necessary. OBTAIN MEDICAL ATTENTION. . 5. FIRE -FIGHTING MEASURES Recommended extinguishers: Water, COZ, Foam, Chemical powders, according to the materials involved in the fire. M0381 /2 Page n. 1 of 5 EUROPOLIMERI S.p.A. 36066 SANDRIGO Tel. +39(0)444-750039 P.Iva 02(14497n-401 Safety Data Sheet' EUROQUAT 80MC JV4011fifird 49 Extinguishers not to be used: None in particular. Risks arising from combustion: There is a danger of polymerisation occuring if involved in a fire. Combustion may result in the formation of NOx. Cool containers at risk with water spray jet. Protective equipment: Use protection for the respiratory tract. 6. ACCIDENTAL RELEASE MEASURES Measures for personal safety: Use a mask, gloves and protective clothing. Environmental measures: Limit leakages with earth or sand. 1f the product has escaped into a water course, into the drainage system, or has contaminated the ground or vegetation, notify the competent authorities. Cleaning methods: Rapidly recover the product. To do so, wear a mask and protective clothing. Stop the product from entering the drainage system. Recover the product for re -use if possible, or for elimination. The product might, where appropriate, be absorbed by inert material. After the product has been recovered, rinse the area and materials involved with water. 7. HANDLING AND STORAGE Handling precautions: Avoid contact with the eyes and the skin. Avoid inhalation of the vapours. See, too, . paragraph 8 below. Do not eat or drink while working. Follow the industrial hygiene norms as for the handling of chemicals. Incompatible materials: None in particular. Storage conditions: Keep the product in the original containers. Avoid extremes of temperature. Keep at temperature between 0°C and 25°C. Store away from heat sources and direct sunlight. Keep away from oxidizing agents. The presence of dissolved oxygen is essential to activate the inhibitor; maintain adequate headspace. If correctly stored the product remains stable for 6 months. Instructions as regards storage premises: Cool and adequately ventilated. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Precautionary measures: Give adequate ventilation to the premises where the product is stored and/or handled. If ventilation is insufficient, use air conditioning system when the product is handfed. Respiratory protection: Use adequate protective respiratory equipment, e.g. CENIFFP-2(S) or CEN/FFP-3(S). Protection for hands: Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber. Eye protection: Use close fitting safety goggles and/or visor conforming to BS 2092 GRADE 1). Keep near a eyewash. Protection for skin: •_ Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton. Wash the contaminated clothing and clean the protection equipment before the re -use. Exposure limit(s) (ACGIH): M038112 Page n. 2 of 5 EUROPOL.IMERI S.p.A. 36066 SANDRIGO Tel. +39(01444-750039 P.iva n)(1 4AM'Ani 0� s Safety Data Sheet , EUROQUAT 80MC • None. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance and colour: colourless to light yellow liquid Odour, ester -like pH: approx. 6.0 Melting point: not applicable Boiling point: > 1000C Flash point: not applicable Autoignition temperature: not applicable Explosive properties: not applicable Oxidizing properties: not applicable Vapour pressure: not available Relative density: approx, 1.1 glcm3 Partition c. (n-octanol/HZO): not applicable 10. STABILITY AND REACTIVITY Conditions to avoid: Stable under normal conditions. Avoid direct sunlight. Avoid temperatures below 0°C and above 25°C. Substances to avoid: Strong oxidizing agents. Hazardous decomposition products: Exothermic polymerisation may occur if storage conditions are exceeded or inhibitors become inefficient. • Combustion may result in the formation of NOx. 11. TOXICOLOGICAL INFORMATION EUROQUAT 80MC Acute toxicity: LD50 (oral, rat) > 1600 mg/KG Eyes irritating effects, rabbit: the product may be irritant for the eyes in case of prolonged and repeated exposure. Skin sensitizer effects, guinea pig: the product is extremely sensitising with contact of the skin. Cases of human skin sensitization have been observed. Harmful by inhalation and if swallowed. 12. ECOLOGICAL INFORMATION Adopt good working practices, so that the produci: is not released into the environment. Product is expected to be toxic to the aquatic environment. 13. DISPOSAL CONSIDERATIONS Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and national regulations currently in force. 14. TRANSPORT INFORMATION ADR-UN number: NOT APPLICABLE ADR-Class: NOT APPLICABLE ADR-Upper number: NOT APPLICABLE ADR-Shipping Name: NOT APPLICABLE M0381/2 Page n. 3 of 5 EUROPOLIMIERI S.p.A. 36066 SANDRIGO Tel. +39(0)444-750039 P.Tva n7n440w4n1 • 10 Safety Data Sheet EUROQUAT 80MC • ADR-Label: ADR-Packing Group: Rail (RID): IATA-Un number: IATA-Class: IATA-Technical name: IATA-Passenger Aircraft: IATA-Cargo Aircraft: IATA-Label: IATA-Packing group: Marine pollutant: IMDG-Un number. IMDG-Class: IMDG-Technical name: IMDG-Packing group: IMDG-Page: IMDG-Label: IMDG-EMS: IMDG-MFAG: 0 NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE No NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE 16. REGULATORY INFORMATION Council Directive 67/548/EEC (Classification, packaging and labelling of dangerous substances) and subsequent amendments. Commmission Directive 1999/45/CE (Classification, packaging and labelling of dangerous preparation) and subsequent amendments. Commission Directive 2001/58/CE (Safety data sheets). Commission Directive 9812410E (Protection of the health and safety of workers from the risk related to chemical agent). Commission Directive 2000/39/CE (Occupational exposure limit values). Symbols: Xn Harmful R Phrases: R20/22 Harmful by inhalation and if swallowed. R36 Irritating to eyes. R43 May cause sensitization by skin contact. S Phrases: S9 Keep container in a well -ventilated place. 824 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water'and seek medical advice. S36/37 Wear suitable protective clothing and gloves. Where applicable, refer to the following regulatory provisions: Directive 2003/105/CE ('Activities linked to risks of serious accidents'). 1999/13/EC (VOC directive) 16.OTHER INFORMATION Main bibliographic sources: ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities M0381 /2 Page n. 4 of 5 EUROPOLIMERI S.p.A. 36066 SANDRIGO Tel. +39(0)444-750039 P.Iva 02044670in1 0 • Safety Data Sheets EUROQUAT 80MC SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold ACGIH - Treshold Limit Values- 1997 edition The information contained herein is based on our state of knowledge at the above -specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality. It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended. This MSDS cancels and replaces any preceding release. Paragraphs modified from the previous revision: 15. REGULATORY INFORMATION M0381 /2 Page n. 5 of 5 EUROPOLIMERI S.p.A. 36066 SANDRIGO Tel. +39(0)444-750039 P.Iva 0204467nini E%&^nMobilo Product Name: FXXSOL D80 FLUID Revision Date: 21Dec2006 Page 1 of 10 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND -COMPANY IDENTIFICATION PRODUCT Product Name: EXXSOL D80 FLUID Product Description: Dearomatized Hydrocarbons Product Code: Intended Use: Solvent COMPANY IDENTIFICATION Supplier: EXXONMOBIL CHEMICAL COMPANY P.O. BOX 3272 HOUSTON, TX. 77253-3272 USA 24 Hour Health Emergency (800) 72&2015 Transportation Emergency Phone (800) 424-9300 CHEMTREC Product Technical Information (281) 870-60001Health 8 Medical (281) 870-6884 Supplier General Contact (281) 870-6000 SECTION 2 ;:COMPOSITION ! INFORMATION ON INGREDIENTS . Hazardous Constituent(s) Contained In Names " All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. SECTION 3 1, , : , `l� r HAZARDS IDENTIFICATION : ;: This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 16). POTENTIAL PHYSICAL 1 CHEMICAL EFFECTS Combustible. Material can release vapors that readily form flammable mixtures. Vapor accumulation could flash andlor explode if ignited. Material can accumulate static charges which may cause an incendiary electrical discharge. POTENTIAL HEALTH EFFECTS Repeated exposure may cause skin dryness or cracking. If swallowed, may be aspirated and cause lung damage. May be irritating to the eyes, nose, throat, and lungs. NFPA Hazard ID: Health: 1 Flammability: 2 Reactivity: 0 HMIS Hazard ID: Health: 1 Flammability: 2 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary • from person to person. `:. 1F1RST:AID MEASURES . . E�onMobil .Product Name: EXXSOL D80 FLUID Revision Date: 21 Dec2006 Page 2 of 10 INHALATION Remove from further exposure. For ;hose providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION Seek immediate medical attention. Do not induce vomiting. NOTE TO PHYSICIAN If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately. SECTION 5 : .f1RE.`FIGHTING:MEA5URES :" EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Combustible. Hazardous material. Firefighters should consider protective equipment indicated in Section 8. Hazardous Combustion Products: Oxides of carbon, Incomplete combustion products, Smoke, Fume FLAMMABILITY PROPERTIES Flash Point [Method]: >77C (171 F) [ ASTM D-93] Flammable Limits (Approximate volume % In air): LEL: 0.6 UEL: 5.0 Autoignition Temperature: 251 °C (484°F) [Approximate] SECTIONACCIDENTAGsRELE45E MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. U.S. regulations require reporting releases of this material to the environment which exceed the reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National E*(o n M o b i I •Product Name: EXXSOL D80 FLUID Revision Date: 21 Dec2006 Page 3 of 10 Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required due to toxicity or flammability of the material. See Section 5 for fire fighting information. See Section 3 for Significant Hazards. See Section 4 for first Aid Advice. See Section 8 for Personal Protective Equipment. SPILL MANAGEMENT Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do it without risk. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapor suppressing foam may be used to reduce vapors. Use clean non -sparking tools to collect absorbed material. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills: Water spray may reduce vapor; but may not prevent ignition in closed spaces. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL. PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 :HANDLING AND:STORAGE HANDLING Avoid contact with skin. Use proper bonding and/or grounding procedures. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Loading/Unloading Temperature: [Ambient ] Transport Temperature: [Ambient ] Static Accumulator: This material is a static accumulator. STORAGE Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well -ventilated area. Storage containers should be grounded and bonded. Drums must be grounded and bonded and equipped with self -closing valves, pressure vacuum bungs and flame arresters. Storage Temperature: [Ambient ] Storage Pressure: [Ambient ] • Suitable Containers/Packing: Barges; Drums; Tank Cars; Tank Trucks Suitable Materials and Coatings: Carbon Steel; Stainless Steel; Polyethylene; Polypropylene; Teflon Unsuitable Materials and Coatings: Natural Rubber; Butyl Rubber; Ethylene-proplyene-diene monomer E�on Mob! I Product Name: EXXSOL D80 FLUID Revision Date: 21Dec2006 Page 4 of 10 (EPDM); Polystyrene SECTION B ' EXPOSURE CONTROLS ! PERSONAL PRO TECTION EXPOSURE LIMIT VALUES Exposure limitslstandards (Note: Exposure limits are not additive) Source Form Llmit I Standard Note I Source DISTILLATES (PETROLEUM), HYDROTREATED LIGHT Vapor. RCP - 1200 i TWA I m Im3 1165 ppm Total Hydrocarbons ExxonMobil NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: Adequate ventilation should be provided so that exposure limits are not exceeded. Use explosion - proof ventilation equipment. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: Half -face filter respirator For high airborne concentrations, use an approved supplied -air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacitylrating maybe exceeded. . . Hand Protection: Any speck glove information provided is based on published literature and glove manufacturer data. Work conditions can greatly effect glove durability; inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: If prolonged or repeated contact is likely, chemical resistant gloves are recommended. If contact with forearms is likely, wear gauntlet style gloves. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or . manufacturer data. The types of clothing to be considered for this material include: If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended. E*,onMobil Product Name: EXXSOL D80 FLUID Revision Date: 21Dec2006 Page 5 of 10 Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND.CHEMICALPROPERTIES .., Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data. GENERAL INFORMATION Physical State: Liquid Form: Clear Color: Colorless Odor: Mild Petroleum/Solvent Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15.6 C ): 0.798 Density: 798 kg/m3 (6.66 Ibs/gal, 0.8 kg/dm-1) Flash Point [Method]: >77C (171F) [ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: 0.6 UEL: 5.0 Autoignition Temperature: 251 °C (484°F) [Approximate ] Boiling Point / Range: 200C (392F) - 250C (482F) Vapor Density (Air = 1): 6.2 at 101 kPa Vapor Pressure: 0.023 kPa (0.17 mm Hg) at 20 C Evaporation Rate (n-butyl acetate =1): 0.1 pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): N/D Solubility in Water: Negligible Viscosity: 1.68 cSt (1.68 mm2/sec) at 40 C 1 2.16 cSt (2.16 mm21sec) at 25C Oxidizing Properties: See Sections 3, 15, 16. OTHER INFORMATION Freezing Point: N/D Melting Point: N/D Pour Point: -390C (-39°F) Molecular Weight: 171 [Calculated ] Hygroscopic: No Coefficient of Thermal Expansion: 0.00074 VNDEGC •8ECTION10' $TABIkITYAND'.REACTIVITY.'. STABILITY: Material is stable under normal conditions. 0 CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources. .Product Name: EXXSOL D80 FLUID Revision Date: 21Dec2006 Page 6 of 10 ,7 • MATERIALS TO AVOID: Strong oxidizers bf(onMobil HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION III - TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Ex osure Conclusion / Remarks Inhalation Toxicity: Data available. Minimally Toxic. Based on test data for structurally similar materials. Irritation: Data available. Negligible hazard at ambient/normal handling temperatures. Based on test data for structurally similar materials. Inglestlon Toxicity: LD50 > 15000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Skin Toxicity: LD50 > 3160 mglkg Minimally Toxic. Based on test data for structurally similar materials. Irritation: Data available. Mildly irritating to skin with prolonged exposure. Based on test data for structurally similar materials. Eye Irritation: Data available. May cause mild, short -lasting discomfort to eyes. Based on test data for structurally similar materials. CHRONICIOTHER EFFECTS For the product itself: Vapor/aerosol concentrations above recommended exposure levels are irritating to the eyes and respiratory tract, may cause headaches, dizziness, anesthesia, drowsiness, unconsciousness and other central nervous system effects including death. Prolonged and/or repeated skin contact with low viscosity materials may defat the skin resulting in possible irritation and dermatitis. Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Additional information is available by request. The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 rj .:: ECOLOGICAL INFORMATION E*(onMobil Product Name: F)(XSOL D80 FLUID Revision Date: 21Dec2006 Page 7 of 10 The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. Material -- Not expected to demonstrate chronic toxicity to aquatic organisms. PERSISTENCE AND DEGRADABILITY Biodegradation: Material -- Expected to be readily biodegradable. Hydrolysis: Material — Transformation due to hydrolysis not expected to be significant. Photolysis: Material -- Transformation due to photolysis not expected to be significant. Atmospheric Oxidation: Material — Expected to degrade rapidly in air OTHER ECOLOGICAL INFORMATION VOC (EPA Method 24): 6.659 Ibslgal 'SECTION 13 _......''..: i -`_ DISPOSAL�CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, Is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261 D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Empty Container Warning PRECAUTIONARY LABEL TEXT: Empty containers may retain residue and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO BEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. SECTION 14 '. TRANSPDRTINFORMATION LAND (DOT) Proper Shipping Name: PETROLEUM DISTILLATES, N.O.S. Hazard Class & Division: COMBUSTIBLE LIQUID ID Number: 1268 •Product Name: EXXSOL DBd FLUID Revision Date: 21Dec2006 Page 8 of 90 • E*,onMobil Packing Group: III ERG Number: 128 Label(s): NONE Transport Document Name: PETROLEUM DISTILLATES, N.O.S., COMBUSTIBLE LIQUID, UN1268, PG III Footnote: This material is not regulated under 49 CFR in a container of 119 gallon capacity or less when transported solely by land, as long as the material is not a hazardous waste, a marine pollutant, or specifically listed as a hazardous substance. LAND (TDG) : Not Regulated for Land Transport SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code AIR (IATA) : Not Regulated for Air Transport :SECTION 15'. tREGULATORYINFORMATION OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purpose, this material is classified as hazardous in accordance with OSHA 29CFR 1910.1200. NATIONAL CHEMICAL INVENTORY LISTING: AICS, DSL, EINECS, ENCS, KECI, PICCS, TSCA EPCRA: This material contains no extremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: Fire. SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. The Following Ingredients are Cited on the Lists Below:" None. --REGULATORY LISTS SEARCHED-- - = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH Al 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 1$ = PA RTK 4 = OSHA Z 9 = TSCA 12b' " 14 = LA RTK {9` R! RTK 5 = TSCA 4 10'= CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive EPA recently added new chemical substances to its TSCA Section 4 test rules. Please contact the supplier to confirm whether the ingredients in this product currently appear on a TSCA 4 or TSCA 12b list. N/D = Not determined, NIA = Not applicable 0 E;konMobil Product Name. EXXSOL DSO FLUID Revision Date: 21 Dec2006 Page 9 of 10 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Not Applicable PRECAUTIONARY LABEL TEXT: Contains: DISTILLATES (PETROLEUM), HYDROTREATED LIGHT CAUTION! HEALTH HAZARDS Repeated exposure may cause skin dryness or cracking. If swallowed, may be aspirated and cause lung damage. PHYSICAL HAZARDS Combustible. Material can accumulate static charges which may cause an incendiary electrical discharge. PRECAUTIONS Avoid contact with skin. Use proper bonding and/or grounding procedures. FIRST AID Inhalation: Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Eye: Flush thoroughly with water. if irritation occurs, get medical assistance. Oral: Seek immediate medical attention. Do not induce vomiting. Skin: Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. FIRE FIGHTING MEDIA Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPILULEAK Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do it without risk. Prevent entry into waterways, sewer, basements or confined areas. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Report spills as required to appropriate authorities. Seek the advice of a specialist before using dispersants. Th'e information and recommendations—contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe -handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re- publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. Product Name: EXXSOL D80 FLUID Revision Date: 21 Dec2006 Page 10 of 10 Internal Use Only MHC: 1A, 0, 0, 0, 2, 0 DGN: 4400220HUS (1007664) Copyright 2002 Exxon Mobil Corporation, All rights reserved • 0 E)ko n M o b i I • • SPAN® 80 Material Safety Data Sheet Date(s):: 2006-03-08 15:26:35 Version 12 MSDS#: 001158 Product Name SPAN® 80 Product Use Nonionic surfactant Address/Telephone number Uniqema Uniqema Corporate Center 1000 Uniqema Boulevard New Castle, DE 19720-2790 Uniqema Operator (Mon. -Fri., 8:15 AM - 4.30 PM Eastern): (302) 574-5000 Medical Emergency (24 hr.): (888) 456-6218 Transportation Emergency Involving Chemical Spills, Leaks, Fires, or Accidents (24 hr.): (800) 424- 9300 Uniqema is an international business of Imperial Chemical Industries PLC. Uniqema operates through ICI affiliated companies in the relevant countries such as ICI Americas Inc., Unichema, a division of ICI Uniqema Inc., and Mona Industries Inc. in the USA. 2. COMPOSITIONIINF_ORMA110N ON JMG13�DIENTS Component Name CAS Number % (wlw) OSHA PiEL• ACGIH TLV Sorbitan monooleate 1338-43-8 97-100 No PEL No TLV established established Ingredients not precisely identified are proprietary or nonhazardous. Values are not product specifications. Page 1 of 10 • SPAN® 80 Material Safety Data Sheet Date(s):: 2006-03-08 15:26:35 Version 12 MSDS#: 00115B Emergency Overview Color yellow -amber Form Liquid @ 25 °C Odor No data. NO HAZARDS ARE KNOWN TO BE ASSOCIATED WITH EXPOSURES TO THIS PRODUCT. Limited toxicity data are available on this specific product; this health hazard assessment is based on the results of screening tests. Routes of Exposure Eye contact Skin contact Inhalation Eye contact No irritation is likely to develop following contact with human eyes. Skin contact No irritation is likely to develop following contact with human skin. This product will probably not be absorbed through human skin. Inhalation No irritation Is expected to be associated with inhalation of this material. No toxic effects are known to be associated with Inhalation of this material. Ingestion This material is not likely to cause irritation upon ingestion. No toxic effects are expected following ingestion of this product. Other - Not listed by ACGIH, IARC, NIOSH, NTP OR OSHA. Page 2 of 10 0 • r1 0 SPAN® 80 Material Safety Data Sheet Date (s):: 2006-03-08 15:26:35 Version 12 MSDS#: 001158 Eye contact Skin contact Inhalation Ingestion Flash Point (OF) Flash Point (°C) Autoignition Temperature (OF) Autoignitlon Temperature (°C) Flammable Limits Extinguishing Media Special fire -fighting protective equipment Fire and explosion hazards Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Immediately flush with plenty of water for at least 15 minutes. If redness, itching, or a burning sensation develops, have eyes examined and treated by medical personnel. Wash material off of the skin with plenty of soap and water. If redness, itching, or a burning sensation develops, get medical attention. Remove victim to fresh air. If a cough or other respiratory symptoms develop, consult medical personnel. DO NOT INDUCE VOMITING. Give one or two glasses of water to drink and refer to medical personnel or take direction from either a physician or a poison control center. Never give anything by mouth to an unconscious person. > 300 (open cup) >148.9 (open cup) No data. No data. No data. Water fog, alcohol foam, carbon dioxide, dry chemical. A self contained breathing apparatus and suitable protective clothing must be worn in fire conditions. None known. No data. No data. 6. ACCIDENTAL RELEASE MEASURES Page 3 of 10 1� • SPAN® 80 Material Safety Data Sheet Date(s):: 2006-03-08 15:26:35 Version 12 MSDS#: 001158 Personal precautions Steps to be taken in case material is released or spilled • Storage Refer to section 8 for proper personal protective equipment. Contain spill. Soak up material with absorbent and shovel into a chemical waste container. Wash residue from spill area with water containing detergent and flush to a sewer serviced by a permitted wastewater treatment facility. Store in original containers. • • ► ► • ► • ► � i • • 1. Exposure limits OSHA PEL Component Name Exposure limits No OSHA PEL assigned. Minimize exposure in accordance with good hygiene practice. Notes ACGIH TL:V Component Name Exposure limits Notes No ACGIH TLV assigned. Minimize exposure in accordance with good hygiene practice. Engineering controls Provide adequate ventilation. Page 4 of 10 0 • SPAN® 80 Material Safety Data Sheet Date(s):: 2006-03-08 15:26:35 Version 12 MSDS#: 001158 Eye protection Protective clothing Respiratory protection Other Safety glasses with side shields. Impervious gloves. Respiratory protection is not normally needed if controls are adequate. Eyewash and safety shower easily accessible to the work area. 3 a , 7"TaneEiRm- Color Form Odor PH Boiling Point {°F} Boiling Point (°C) Flash Point (°F) Flash Point (°C) Autoignition Temperature (°F) Autoignition Temperature (°C) Flammable Limits Explosive Properties Oxidizing Properties Vapor Pressure (mmHg) Specific Gravity Solubility (water) Solubility (other) Partition Coefficient Dynamic viscosity (mPa.$) Density (glml) Freezing/malting point (°C) Pour Point (OF) Pour Point (°C) % Volatile by volume 0 yellow -amber Liquid @ 25 °C No data. No data. > 212 > 100 > 300 (open cup) > 148.9 (open cup) No data. No data. No data. No data. No data. < 1,0000 -1 Insoluble soluble in:, ethyl acetate, 2-ethoxyethanol, vegetable oil, mineral oil, cottonseed oil, insoluble im, acetone, ethylene glycol, propylene glycol, slightly soluble in:, lower alcohols, diethylether, 1,4-dioxane, 1,1,1-trichloroethylene No data. �. -1000 (@25 deg.C) No data. No data. ^-3 ­ 16.1 Negligible Page 5 of 10 • 0 SPAN® 80 Material Safety Data Sheet Date(s):: 2006-03-08 15:26:35 Version 12 MSDS#: 001158 1-0. STABILITY . Ihl Stability Stable under normal conditions. Materials to avoid Strong oxidizing agents. Conditions to avoid None known. Hazardous decomposition products None known. Hazardous polymerization Will not occur. 11- TOXICOLOGICAL INFORMATION Eye contact A 100% suspension of Rabbit Draize 7 days Practically this material was tested. nonirritating. Skin contact A 100% suspension Rabbit Draize 72 hours Nonirritating. of this material was tested. Ingestion A 100% suspension of this LD50 rat > 39.8 g/kg material was tested. Chronic Toxicologically synergistic products 14 days Relatively harmless, A chronic ingestion study in animals has shown that repeated doses produce no significant effects. None known. Page 6 of 10 31 /811971 31/8/1971 23111 /1966 • SPAN® 80 Material Safety Data Sheet Date(s):: 2006-03-08 15:26:35 Version 12 MSDS#: 001158 W-W-We]K-eZclWiTs1►11411 �i1_yiC+1►1 Environmental Fate & Distribution Persistance & Degradation Toxicity Effect on Effluent Treatment ig i FUGUYARK91 MMIX1110 The product is essentially insoluble in water. Dissolved Organic Carbon Removal (DOC removal) (OECD 301C) 98.2 % Biological Oxygen Demand (BOD 28 DAY/COD) (OECD 301 C) 62 % Theoretical Oxygen Demand (THOD)2.39 gO2/g This product is substantially biodegradable in water. LC50 (96 hour) (static) rainbow trout > 1000 mg/l This product is substantially removed in biological treatment processes. RCRA (Resource Conservation and Recovery Act) Classification: Specifically Listed Not applicable. Wastes Characteristic Wastes Ignitability Not applicable. Corrosivity Not applicable. Reactivity Not applicable. Toxicity Not applicable. Disposal method Disposal should be in accordance with local, state or national legislation. Page 7 of 10 • • E SPAN0 80 Material Safety Data Sheet Date(s):: 2006-03-08 15:26:35 Version 12 MSDS#: 001158 Container disposal Empty container retains product residue. Observe all hazard precautions. Do not distribute, make available, furnish or reuse empty container except for storage and shipment of original product. Remove all product residue from container and puncture or otherwise destroy empty container before disposal. Department of Transportation: Not regulated. TDG (Transportation of Dangerous Goods): Not regulated. Not classified in RIDIADR - ADNR - IMDG - ICAOIIATA-DGR. Inventory Status EU (EINECSIELINCSINLP) Compliant. USA (TSCA) Compliant. Canada (DSL) Compliant. Australia (AICS) Compliant. Japan (ENCS) Compliant. China (IECSC) Compliant. Page 8 of 10 • SPAN® 80 Material Safety Data Sheet Date(s):: 2006-03-08 15:26:35 Version 12 MSDS#: 001158 Korea (ECt.) Compliant. Philippines (PICCS) Compliant. OSHA Hazard Communication Standard, 29 CFR 1910.1200, Hazard Summary: Health Hazards None Physical Hazards None WHMIS Classification Noncontrolled (Nonhazardous). CERCI_A and SARA Regulations (40 CFR 355, 370, and 372): This material contains the following No 313-listed chemicals subject to the reporting chemicals in this requirements of SARA 313: product SARA 3111312 Hazard Categories: Immediate N Delayed N Fire N Pressure N Reactivity N Page 9 of 10 0 • • r f� SPAN® 80 Material Safety Data Sheet Date(s):: 2006-03-08 15:26:35 Version 12 MSDS#: 001158 We assigned NFPA ratings and HMIS ratings to this product based on the hazards of its ingredient(s). Because the customer is most aware of the application of the product, he must ensure that the proper personal protective equipment (PPE) is provided consistent with information contained in the product MSDS. HMIS Information Health 0 Flammability 1 Physical Hazards 0 The HMIS ratings displayed above are from the HMIS III Third Edition. There have been significant changes made to the system. "Physical hazard" stands for physical hazard as defined in the OSHA Hazard Communication Standard and replaces the former code for reactivity. For a more detailed explanation of the system and the ratings, please contact our Product Safety and Regulatory Affairs group. NFPA Information Health 0 Flammability 1 Instability 0 This information is intended solely for the use of individuals trained in the particular hazard rating system. The following sections contain revisions or new statements: 15 The information herein is given in good faith but no warranty, expressed or implied, is made. (R) is a Registered Trademark of ICI Americas. (TM) is a Trademark of ICI Americas. See also www.unigema.com Page 10 of 10 0 Appendix C E 0 Site Location Plant Layout SWPPP Site Plan 2350 Highway 101 South Greer, SC 29651 (864) 655-8281, P.O. Box 1414 Greer, SC 29652-1414 sales@pintegration.com OUTFALL SWO03 Q C 4 51 GRASS VEGETATED AREA (GRASS) TANKS IN USE 4 _-__...._._ TK TANK SIZE TANK CONTENTS LOCATION OF 30/. HCL SPILL (03-09-96) T-1 10,000 gat EUROQUAT � WASTEIL / c - OUTFACE --- -- - - — -- M O N T ASPHALT ROAD N. I . P. WELL ASPHALT DRIVE, rr T-2 12,000 gal EUROQUAT -- . FENCE -- wool —� FENCE GRASS FENCEa _ c;L_rvr���LINE ----- ._ FENCE a� e' T-3 12,Od0 gal LIALET QR CREEK WA C mayor t Y -'` IC;.5' R PLMP_� CENTERL.INC OF CREEK 7� / Fr" � t �y. _� �" cup CURB ��� .c�' T a i y c �� � /E, `I �, T-4 12,000 gal SPAN-80 ; / �4� �_�-` PAVED D. �' `` _ j f,/ \.m T-5 12,000 gal ACRYLAMIDE �_ % ` J /,� m Ov \ ` e� `` NOTE 11 /� �r T-g 12,000 gal ACRYLAMIDE f /� �o o°� _ �`' wq GRASS '°Rpp 1�/ /� N0 TE 9 ��� ��� �\ cc` o' f sT fw qSp �( qN o Sro ERED TRfq gTFR pgtr Hq�T _ / �� `. T-7 12,000 gal EXXSOL `�\ T �k Ly Q� Rq�F rMEN eMFkT co" o� r o U o �' coHcR\ T /� CR �o i T-8 12,000 gal EXXSOL / b c ° � M ` z iOq ` FT �\` q �FM FTf " ` �. 4/NT �� fyFNT `` `o fir -���e i e, T-9 12,000 gal EXXSOL \ `_3\_ NOTE 7 t'_ SyOpFNq \ �� / . -�� a s NC �, _.� J� NOTE 8 ��, \ `aFF/ �NO� T-10 12,000 al EXXSOL a A ~ T-11 12,000 gal WASTEWATER " W 4Q 4Ca� °``i_,3 �� �- L // �� �"_� T-12 12,000 gal WASTEWATER GRASS L e <>m E� ` g A_ a ems" _4CJ=c, �lA y U J�Q �� �� , Pli ���_,�4-F�F=i E ®� m off' _ NOTES 1 - 11 ARE ITEMS BEING e� ti �� ` i / ��� O 4QE�=v �Q4 Q MANUAL vALVE� PAVED \ {-� �L r COMPLETED ON -SITE BY BASF QQ \ IN SW PIPE \ GRASS ��, °u c°� ��J �wi ti Q �_\\� �c4 0 \ �� / - / PAVED PARKING / NOTE * COMMENT `�4! NOTE 1 Separate roof drainage to stormwater from trenches: Install roof drain collector header, pipe to exterior of bldg (Cod GF q `' m SS °_� �" �� m & discharge at grade or pipe underground to nearest NOTE 6 L' xco U c Qr �� Q _ �` _ storm drain. NOTE 10 NOTE 2 Install new 8" PVC process drain collector outside of bldg; tie in 3 process lines & blank off these lines from pump station A. Route new 8" line to sanitary manhole �\ shown. (Need to verifyinverts are high enough to drain Z) �� S g 9 �.R f ` to sanitary manhole) _ NOTE 3 Install new 8 line from storm/process MH to sanitary MH; blank off the existing 8 outlet pipe from the R 44 \_ �/ \ storm/process MH. NOTE 4 �\ 4 , z� NOTE 4 8 pipe into south wall of pump station A is assumed / < v- from Admin/Lab bid Re-route line to nearby sanitary Xl� tt 9 Y Y A � vt ,`r_ MF �� ��-v• MH and blank off #carrti pump station A. �� At this point, there are no active lines left feeding pump IZ station A except for connection to nearby storm drain. NOTE 2 3- v,;� ; Remove pumps & open storm drain valve to allow pit to drain to storm drain CB. Cover pit or raise floor of m U ti m Q_ pit to allow complete drainage. NOT. 5 , Re-route leather lab area lift station discharge from J !°?` WWTc outfall to nearest sanitaryMH. (route to be t V �f+: ( t ��,`\ \ determined) 1 �'p r `r NOTE 6 Re-route truck unloading sump pump discharge from i WWTc outfall to dumpover the curb as storm �, /cC �u 4 �� drainage. This pump should be manually operated after 4 water quality inspection. � /� UFO , s / �� \ NOTE 7 Add a manual valve at WWTc area storm CB discharge Q // NOTE 3 g / J ` line. This valve should be manually opened after water NOTE 1 quality inspection. c�✓c�,c \� NOTE 8 Verify WWTa curbed area drainage is to Ib or WWTc; Agrr operate valve manually after water quality inspection. F Q L7 oy / NOTE 9 Install new 6 PVC collector line outside maintenance bldg. to collect floor drains, lab drains and toilet drain lines, and tie into existing "CMUD" line shown. (verify inverts allow this re -configuration). Blank off O �Q o� ��� a �� process drain lines beyond new collector line. GRASS NOTE 10 Re -connect 15" storm line outfall from pump station B. �• = L� r,-' /`� Ro thve station B pumps, verify pit can drain fully to s. v \ 1 NOTE 5 ��� � , �, _.% a NOTE 11 lnstall 8" pipe from wastewater pit to southeast storm cQ) `J_ r_J �� \� �/ drain CB. Open valves to allow all pits to drain to outfall. \.` P7AVED PARKING U � v. ff 1 11' ! cR 14S Is, \ /Y GRASS '. 4 11 ~ 15 R ASS R 1 - -�: - GRASS - OUTFALL I Swo02 C r'60, PUPI D R�W1 LEGEND -) SEPERATED STORM \ DRAIN / SANITARY SEWER _ CATCH BASIN (CB) O MAN HOLE (MH) \` STORMWATER FLOW RUN-OFF DIRCETION MANUAL STORM \ DRAIN VALVE u, Z GRgss c� 4� A ISSUED FOR PERMIT REVIEW REV DESGRIPTION� D Build up pit bottoms to prevent standing water. Remove or blank off all inlet sources to the pits, GENERAL All sanitary MH's should have solid (vented) sanitary NOTE type manhole covers - not storm grates. DRAINAGE AREAS TOTAL AREA AREA (ACRES) PERCENT AREA DISCHARGE POINT (ACRES) IMPERVIOUS PERVIOUS IMPERVIOUS IG OUT FALL 4.96 1.64 3.32 67 SW 001 Ib TO OUTFALL SWO01 1.86 0.29 1.57 85 II OUT FALL 5.99 3.26 2.73 46 SW 002 OUT FALL 0.95 0.71 0.24 25 SW 003 INFILTRATION AND SHEET FLOW RUN-OFF 0.95 0.0 0.95 100 US POLYMER - CHARLOTTE, NC WATER CHEMICAL TREATMENT SWPPP / SPCC SITE MAP SCALE: DRAWN BY: CHECKED BY: JOB NUMBER: NONE EAT - C3060707 Pro --C t 1/7 to rd t10/7, 1/7C, DRAW[NG NUMBER: REV: FAT - 10-18-07 2359 Ilighrr y 1015outh S T- O 1 A R4 C HNC D D ATE Greer, 5C 296'51 F 4 5 Gil i 1