NCG020854_2016 Analytical Results Wastewater_20160621

accAnalytical0
wwwpacefabsoom
June z,,o1a 41,
a
Glenn Amey
Charrah
330 S Tryon St
Suite 510
Charlotte, NC 28202
RE: Project: 2016 SW 6/16116
Pace Project No.: 92301709
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Dear Glenn Amey:
Enclosed are the analytical results for sample(s) received by the laboratory on June 16, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Chris Derouen
[e-mail]
Project Manager
Enclosures
cc: Collin Mummert, Charah Inc
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
Page 1 of 17

acoAnalyticalo
www.pecelabs.mn
Project: 2016 SW 6/16/16
Pace Project No-: 92301709
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
Eden Certification IDs
205 East Meadow Road Suite A. Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
CERTIFICATIONS
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 633
VirginiaNELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc,
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville. NC 28804
[phone]
Page 2 of 17

.110';alce Analytical"
wwwpacelsbs com
SAMPLE ANALYTE COUNT
Project: 2016 SW 6116/16
Pace Project No : 92301709
Pace Analytical Services, Inc.
2225 Riverside Or
Asheville, NC 28804
[phone]
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92301709001
SED 4
SM 2540D
CRP
1
PASI-E
SM 2540F
CHM
1
PASI-E
EPA 180.1
DMN
i
PASI-A
92301709002
SED 3
SM 2540D
CRP
1
PASI-E
SM 254OF
CHM
1
PASI-E
EPA 180.1
DMN
1
PASI-A
92301709003
SED 1
SM 2540D
CRP
1
PASI-E
SM 254OF
CHM
1
PASI-E
EPA 180.1
DMN
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
Page 3 of 17

aeeAnalytical*
ww ,pacaleb c m
Project:
2016 SW 6116/16
Pace Project No
92301709
Lab Sample ID
Client Sample ID
Method
Parameters
92301709001
SED 4
SM 2540D
Total Suspended Solids
EPA 180.1
Turbidity
92301709002
SED 3
SM 2540D
Total Suspended Solids
EPA 180.1
Turbidity
92301709003
SED 1
SM 2540D
Total Suspended Solids
EPA 180.1
Turbidity
Pace Analytical Services, Inc.
2225 Riverside Or
Asheville, NC 28804
[phone]
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed Qualifiers
61.8
mg/L
7.6
06/20/1615:58
58.2
NTU
1.0
06/17/16 23:14
23.9
mg/L
4.4
06/20/1615:58
%0
NTU
1.0
06/17/16 23:14
8.8
mg/L
2.5
06/20/1615:58
6.9
NTU
1.0
06/17/16 23:14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc,
Page 4 of 17

aceAnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
2225 Riverside Dr
Asheville, NC 28804
[phone]
PROJECT NARRATIVE
Project: 2016 SW 6/16/16
Pace Project No 92301709
Method: SM 2540D
Description: 2540D Total Suspended Solids
Client: Charah
Date: June 21, 2016
General Information:
3 samples were analyzed for SM 2540D. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inca Page 5 of 17

aciel`inaljd real'
www.pacelabs.com
PROJECT NARRATIVE
Project: 2016 SW 6/16/16
Pace Project No.: 92301709
Method: SM 254OF
Description: 2540F Total Settleable Solids
Client: Charah
Date: June 21, 2016
Pace Analytical Services, Inc.
2225 Riverside Or
Asheville, NC 28804
[phone]
General Information:
3 samples were analyzed for SM 2540F. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. Page 6 of 17

a7ceAnalytical '
www.pacelabscom
Pace Analytical Services, Inc.
2225 Riverside Dr
Asheville, NC 28804
[phone]
PROJECT NARRATIVE
Project: 2016 SW 6/16/16
Pace Project No. 92301709
Method: EPA 180.1
Description: 180.1 Turbidity
Client: Charah
Date: June 21, 2016
General Information:
3 samples were analyzed for EPA 180.1 All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. Page 7 of 17

1�;a'ceAnalytical'
WNW,Pacata'as.cam
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: 2016 SW 6/16116
Pace Project No. 92301709
Sample: SED 4
Lab ID: 92301709001 Collected: 06/16/16 09:00
Received: 06/16/16 14:35 Matrix: Water
Parameters
Results Units
Report Limit DF
Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
61.8 mg/L
7.6 1
06/20/16 15:58
254OF Total Settleable Solids
Analytical Method: SM 254OF
Total Settleable Solids
ND mUUhr
0.10 1
06/17/16 09:05
180.1 Turbidity
Analytical Method: EPA 180.1
Turbidity
58.2 NTU
1.0 1
06/17/16 23:14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/21/2016 10:53 AM without the written consent of Pace Analytical Services, Inc_ Page 8 of 17

Pace Analytical Services, Inc.
r� q �y ) �+ j c 2225 Riverside Dr
ac A /alytica Asheville, NC 28804
wwwpac0abs.com [phone]
ANALYTICAL RESULTS
Project: 2016 SW 6116/16
Pace Project No. 92301709
Sample: SED 3
Lab ID: 92301709002 Collected:
06/16/16 09:00
Received: 06/16/16 14:35 Matrix: Water
Parameters
Results Units
Report Limit DF
Prepared Analyzed CAS No, Qua]
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
23.9 mg/L
4.4 1
06/20/16 15:58
254OF Total Settleable Solids
Analytical Method: SM 254OF
Total Settleable Solids
ND mUUhr
010 1
06/17/16 09:05
180.1 Turbidity
Analytical Method: EPA 180.1
Turbidity
19.0 NTU
1.0 1
06/17/16 23:14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/21/2016 10:53 AM without the written consent of Pace Analytical Services, Inc Page 9 of 17

Ll fcie Analyt ca e
t www.pacafabs.com
ANALYTICAL RESULTS
Project: 2016 SW 6/16/16
Pace Project No : 92301709
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: SED 1
Parameters
lab ID: 92301709003 Collected: 06/16/16 09:00
Results Units Report Limit DF
Received: 06/16/16 14:35 Matrix: Water
Prepared Analyzed CAS No. Quaff
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
8.8 mg/L
2.5
1
06/20/16 15:58
2540F Total Settleable Solids
Analytical Method: SM 2540F
Total Settleable Solids
ND mL/L/hr
0.10
1
06/17/16 09:05
180.1 Turbidity
Analytical Method: EPA 180 1
Turbidity
6.9 NTU
1.0
1
06/17/16 23:14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 06/21/2016 10:53 AM without the written consent of Pace Analytical Services, Inc. Page 10 of 17

aceAnalXical s'
www.pacelabs.com
QUALITY CONTROL DATA
Project: 2016 SW 6116/16
Pace Project No, 92301709
QC Batch: EDEN/23188 Analysis Method: SM 2540D
QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids
Associated Lab Samples: 92301709001, 92301709002, 92301709003
METHOD BLANK: 1759839 Matrix: Water
Associated Lab Samples: 92301709001, 92301709002, 92301709003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Suspended Solids mg/L ND 2.5 06/20/16 15:56
Pace Analytical Services, Inc.
2225 Riverside Dr
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 1759840
Spike LCS LCS % Rae
Parameter Units Cone. Result % Rec Limits Qualifiers
Total Suspended Solids mg/L 250 258 103 90-110
SAMPLE DUPLICATE: 1759841
92301706001 Dup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids mg/L 26.7 27.5 3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/21/2016 10:53 AM without the written consent of Pace Analytical Services, Inc
Page 11 of 17

aeAnalytieal
www.pacatabacom
QUALITY CONTROL DATA
Project: 2016 SW 6/16/16
Pace Project No.: 92301709
QC Batch: EDEN/23166 Analysis Method: SM 254OF
QC Batch Method: SM 2540F Analysis Description: 2540F Total Settable Solids
Associated Lab Samples: 92301709001, 92301709002, 92301709003
METHOD BLANK: 1758042 Matrix: Water
Associated Lab Samples: 92301709001, 92301709002, 92301709003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Settleable Solids mUUhr ND 0.10 06/17/16 09:05
SAMPLE DUPLICATE: 1758043
92301709001 Dup
Parameter Units Result Result RPD Qualifiers
Total Settleable Solids mUUhr ND ND
Pace Analytical Services, Inc.
2225 Riverside Dr
Asheville, NC 28804
[phone]
Results presented an this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/21 /2016 10:53 AM without the written consent of Pace Analytical Services, Inc.
Page 12 of 117

/4;'aceAnalytical
bairn
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Dr
Asheville, NC 28804
[phone]
Project: 2016 SW 6/16/16
Pace Project No: 92301709
QC Batch: WET/45610
Analysis Method: EPA 180.1
QC Batch Method: EPA 180.1
Analysis Description: 180.1 Turbidity
Associated Lab Samples: 92301709001, 92301709002, 92301709003
METHOD BLANK: 1758931
Matrix: Water
Associated Lab Samples: 92301709001, 92301709002, 92301709003
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Turbidity � NTU
ND 1.0 06/17/16 23:14
LABORATORY CONTROL SAMPLE: 1768932
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Turbidity NTU 10 10.0 100 90-110
SAMPLE DUPLICATE: 1758933
92301709001 Dup
Parameter Units Result Result RPD Qualifiers
Turbidity NTU 58.2 58.7 1
Results presented on this page are in the units indicated by the"Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 06/21 /2016 10:53 AM without the written consent of Pace Analytical Services, Inc Page 13 of 17

. , 2ce Analytical
z wwwpacelabs.com
r
QUALIFIERS
Project: 2016 SW 6/16/16
Pace Project No 92301709
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL- Practical Quantitation Limit
RL - Reporting Limit.
Pace Analytical Services, Inc.
2225 Riverside Dr
Asheville, NC 28804
[phone]
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270 The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270 The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PAST -A Pace Analytical Services -Asheville
PASI-E Pace Analytical Services - Eden
REPORT OF LABORATORY ANALYSIS
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Date: 06/21/2016 10:53 AM without the written consent of Pace Analytical Services, Inc Page 14 of 17

atJeA alyt al -
wwwpacelabscam
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: 2016 SW 6116/16
Pace Project No.: 92301709
Pace Analytical Services, Inc.
2225 Riverside Dr
Asheville, NC 28804
[phone]
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
92301709001
SED 4
SM 2540D
EDEN/23188
92301709002
SED 3
SM 2540D
EDEN/23188
92301709003
SED 1
SM 2540D
EDEN/23188
92301709001
SED 4
SM 254OF
EDEN/23166
92301709002
SED 3
SM 254OF
EDEN/23166
92301709003
SED 1
SM 2540F
EDEN/23166
92301709001
SED 4
EPA 180.1
WET/45610
92301709002
SED 3
EPA 180.1
WET/45610
92301709003
SED 1
EPA 180.1
WET/45610
Date: 06/21/2016 10:53 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Analytical
Batch
Page 15of17

Document Name:
Document No.:
Document Revised: May 24, 2016
Page 1 of 2
Issuing AuthoritW
Pace RalelRh Qualltv Office
Cilent Name:
i I . Project. 92361709
Courier: []Fed Ex [:)UPS MUSPS
0 commercial OPace [-]Other:
Custody Seat Present? []Yes ZN. Sears Intact? Elyes o
92301709
Datelln!tials Person Examining Contents:
Packing Material: MBubble Wrap E]Dubble Bags P one [Other.
< []Samples on ice, cooling process has b un
Thermometer: T1505 Type of Ice: one
Orgue
Correction Factor: O.IrC Cooler Temp Corrected (*C); one Samples
Frozen? nYes FINO N/A
Temp should be above free to 6.0
USDA Regulated Solt ,0-N/A, water sample)
Did samples 0 ate In a quarantine zone within the United States: CA NY, or SC (check maps)? Did samples originate from a foreign source tInternat
6 01111-,
0ye-S D490 Induding Hawaii and Puerto Rim)? E]Ye5 Oro
-Chain of Custody Present?
Ores'
NaO
oN/A
1.
-Samples Arrived within Hold Time?
0!es
No
[],/A
2.
-Short Hold Time An Ls (C12 hr.)?
0yes
EIA
[JN/A
3.
-Rush Turn Around Time Requested?
OYes
'[)do
ON/A
C
ufficlent Volume?
e6PS
r
No
EINIA
5.
Correct Containers Wed?
_2(es
DO
ON/A
6.
- -Pace Containers Used?
!,tYes
No
ON/A
Containers Intact?
ZYea
[I Na
E]N/A
7,
Samples Field Filtered?
OYes
[]No
E:N/A
B. Note if sediment IsvIsIble in the dissolved container
Sample Labels Match COC?
,Ores
[]No
[3N/A
9.
-includes Date/Time/ID/Analysis Matrix:
All containers needing acid/base preservation have been
10.
checked?
[3Yes
ONO
/A
All containers needing preservation we found to be in
f
HORHQ
compliance with EPA recommendation?
NUAM PWI
(HNOj, H7SOq, 14CI<2; NaOH >9 Sulfide, NaOH>12 Cyanide)
Dyes
[]No
_Ptlu
Exceptions: VOA, Collform, TOC, Oil and Grease,
/N/A
-DRO/8015 {water) Dor� UlHg
13yes
QNo
2f;�/A
Samples checkecl for dechlorinatlon?
QYes
No
W</A
11.
_Headace In VOA Vials (>S-6mm)?
Ejus
NaQ
[241A
12.
Trip Blank Present?
[]Yes
[]Nc-
0djA
13.
Trip Blank Custody Seats Present?
OYes
ONo
CVfA
Pace Trip Blank Lot# (if purchased):
7-
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Dateff"Ime:
Comments/Sample
Discrepancy:
Field Oats Required? Des E3No
Project Manger SCURF Review,
Project Manager 5RF Review: Date, 4
Note: Whenever there Is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the CA
Out of hold, Incorrect preservative, out f tamp, Incorrect containers)
Certification Office [i.e.
Page 16 of 17

w.psaelatl9,cam
d 6701 Conference Drive, Raleigh, NC 27607
ph: (919) &UA984, fax: [phone]
NCWW Cert#67, NCDW CeW7731
Report Results To:
Company:
Address: t7,71
Attn: 4
Phone: sy2 -Y 3sZ. s')
Sampled by (signature):
Chain Custody
t O
Bill To:
Project Reference: OY (-
51 er W eY
i
Project Number:
Purchase Order #:
❑ Standard Report Delivery
❑ Rush Report Delivery (wtsurcharge)
"Rush p pleas are subject to ptlpr approval by
the laboratory
Requested Due Date:
Re1'usquistci by (signature
y (s natu
>'
T
i u od by (signature)
y (signature)
7Rece-lvad
Datd
lime
;einquished by (signature)
by (signature)
Data
Tme
Receipt Conditions (La i
4t2°C ❑ Ternp
Res. Chlorine:
❑ Absent ❑ Present O nla
Add preserv. a2?
❑ Yes O No ❑ rda
Base preserv, a12?
❑ Yes ❑ No ❑ n/a
Page 17 of 17