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Home My WebLink AboutNC0003425_Submittal of Analytical Results AOW's identified during Spring Evaluation_20170815�, eta*, DUKE ENERGY® Julie Grzyb, Supervisor Complex NPDES Permitting Unit NC Division of Water Resources 1617 Mail Service Center Raleigh, NC 27699-1617 August 15, 2017 RECEIVED/NCDEQ�DWR AUG 17 2017 Water Quality Permitting Section Subject: Submittal of analytical results AOW's identified during Spring evaluation Duke Energy Facilities Duke Energy has completed the Spring 2017 semi-annual Area of Wetness (AOW) inspections at it NC facilities. As required in the Plan for Identification of New Discharges (DIPs) for the various facilities, the spring inspections were completed during the months of April and May. In completing those inspections, new areas of wetness were identified at five of the inspected facilities. Follow-up AOW sampling occurred, where applicable, in accordance with the Standard Operating Procedure for Seep Sampling, prepared by Duke Energy (March 24, 2016). Specific details for the five sites with newly identified AOW's are provided below along with attached analytical results for any AOW's with enough flow to be sampled. Rogers Energy Complex (Cliffside), NC0005088 - Reported to NCDEQ on April 19, 2017. Two AOWs, with coordinates, reported as Areas C and D. Area C was sampled (analytical results attached). Area D could not be sampled at the time of the inspection due to insufficient flow. Cape Fear (NC0003433)- Reported to NCDEQ on April 25, 2017. Four AOWs, with coordinates, reported as Areas A, B, C and D. Due to insufficient flow, none of the four AOWs could be sampled during the inspection. Belews Creek Steam Station (NC0024406)- Reported to NCDEQ on May 17, 2017. One new AOW, with coordinates, was initially reported as Area AA. Area AA was changed to a S-16 designation and was sampled (analytical results attached). Riverbend (NC0004961)- Reported to NCDEQ on May 18, 2017. One new AOW, with coordinates, was reported as S-23. S-23 could not be sampled at the time of the inspection due to insufficient flow. Roxboro Steam Plant (NC003425)- Reported to NCDEQ on May 23, 2017. Four AOWs, with coordinates, reported as AOWs S-20, S-21, S-22 and S-23. AOW S-21 was sampled (analytical results attached). The remaining three AOWs could not be sampled at the time of the inspection due to insufficient flow. Further information, relative to the new AOWs at Roxboro, was submitted to the Division of Water Resources on July 13, 2017 in support of its NPDES renewal application. Where applicable, requests for permit coverage have been made under appropriate signatory submittal. Should further discussions/submittals be required to address any permitting issues associated with the new AOWs and their respective NPDES permits please let us know. If there are any questions about this matter please feel free to contact me at (919) 546-2439 or shannon.langley a,duke-energy. Sincerely, r E. Shannon Langley Lead Environmental Specialist Attachments Cc: Sergei Chernikov —DWR w/attachments via email Jeff Poupart — DWR w/attachments via email Chris Hallman — Duke Energy w/attachments via email Ross Hartfield — Duke Energy w/attachments via email Robert Wylie — Duke Energy w/attachments via email Joyce Dishmon — Duke Energy w/attachments via email Steve Cahoon — Duke Energy w/attachments via email Brad Loveland — Duke Energy w/attachments via email Lori Tollie — Duke Energy w/attachments via email Eurika Rogers/Filenet - Duke Energy w/attachments via email Attachment Analytical results from identified AOW's Spring 2017 evaluation Analytical lab f DUKE Analytical Laboratory Page 1of54 ENERGY, Order Number: Project Name Customer Name(s) Customer Address Lab Contact Report Authorized By, (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone 980-875-5245 Fax 980-875-4349 Order Summary Report J17040410 CLIFFSIDE - NPDES - AOW Ross Hartfield, Tim Hunsucker, Kathy Webb, Brandon Russo 573 Duke Power Rd Mail Code Clliffside Steam Station Mooresboro, NC 28024 Mary Ann Ogle Phone 980-875-5274 Mary Ann Ogle Date: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report Data Flags & Calculations: 4/28/2017 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading All results are reported on a dry weight basis unless otherwise noted Subcontracted data included on the Duke Certificate of Analysis is to be used as information only Certified vendor results can be found in the subcontracted lab final report Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative An estimation of the uncertainty of measurement for the results in the report is available upon request This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory Please contact the Analytical laboratory with any questions The order of individual sections within this report is as follows Job Summary Report Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Cham of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005 Contact the Analytical Laboratory for definitive information about the certification status of specific methods Sample ID's & Descriptions: Analytical lab Page 2 of 54 Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2017012819 CLIFFSIDE 13 -Apr -17 930 AM Synterra S-18 2017012820 CLIFFSIDE 13 -Apr -17 11 30 AM Synterra Area C 2017012821 CLIFFSIDE 13 -Apr -17 1 20 PM Synterra S-31 2017012822 CLIFFSIDE 13 -Apr -17 3 20 PM Synterra S-19 2017012823 CLIFFSIDE 13 -Apr -17 3 45 PM Synterra S -19A 2017012824 CLIFFSIDE 13 -Apr -17 9 00 AM Synterra S-2 6 Total Samples Analytical lab Page 3 of 54 Technical Validation Review Checklist: COC and pdf report are In agreement with sample totals 0 Yes ❑ No and analyses (compliance programs and procedures) All Results are less than the laboratory reporting limits ❑ Yes 0 No All laboratory QA/QC requirements are acceptable Report Sections Included: ❑� Job Summary Report ❑� Sample Identification Technical Validation of Data Package ❑� Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report 0 Yes ❑ No 0 Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries W Chain of Custody 0 Electronic Data Deliverable (EDD) Sent Separatel Reviewed By Mary Ann Ogle Date 4/28/2017 Certificate of Laboratory Analysis This report shall not be reproduced, except /n full Order # A7040410 Site S-18 Sample #: 2017012819 Collection Date 13 -Apr -17 9 30 AM Matrix NPDES Analyte Result Units Qualifiers RDL OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L 5 ALKALINITY - (Analysis Performed by Shealy Labs) 04/24/2017 10 45 Vendor Parameter Complete Vendor Method NITRITE + NITRATE (COLORIMETRIC) 20 EPA 353 2 Nitrite + Nitrate (Colonmetnc) < 0 2 mg -NIL 02 INORGANIC IONS BY IC BGN9034 5 EPA 300 0 Chloride 43 mg/L 05 Fluoride < 0 5 mg/L 05 Sulfate 330 mg/L 5 MERCURY IN WATER - (Analysis Performed by Shealy Labs) 1 Vendor Parameter Complete SLS2560 1 TOTAL RECOVERABLE METALS BY ICP 04/21/2017 13 55 SLS2560 Aluminum (AI) 0.069 mg/L 0 005 Barium (Ba) 0.020 mg/L 0 005 Boron (B) 0 815 mg/L 005 Calcium (Ca) 96.2 mg/L M4 001 Iron (Fe) 1 20 mg/L 001 Magnesium (Mg) 33.1 mg/L M4 0 005 Manganese (Mn) 256 mg/L 0 005 Potassium (K) 5.02 mg/L 01 Sodium (Na) 5.47 mg/L 005 Total Hardness (Ca and Mg) 376 mg/L 019 1 EPA 200 8 (CaCO3) CWSPEN3 Zinc (Zn) < 0 005 mg/L 0 005 TOTAL RECOVERABLE METALS BY ICP -MS EPA 200 8 04/20/2017 17 52 Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 14.9 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0 2 Analytical lab Page 4 of 54 DF Method Analysis Date/Time Analyst 1 EPA 16648 04/24/2017 10 45 CJELLIO Vendor Method V_SHEALY 20 EPA 353 2 04/20/2017 15 05 TLINN 5 EPA 300 0 04/21/2017 16 13 BGN9034 5 EPA 300 0 04/21/2017 16 13 BGN9034 50 EPA 300 0 04/21/2017 16 13 BGN9034 Vendor Method V_SHEALY 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SL32560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 Analytical lab Certificate of Laboratory Analysis Page 5 of 54 This report shall not be reproduced, except in full Order # A 7040410 Site S-18 Collection Date 13 -Apr -17 9 30 AM Sample #: Matrix 2017012819 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 650 SI Units 1 Field Work Temperature 17.0 °C 1 Field Work Specific Conductance 740 us/cm 1 Field Work Turbidity 09 NTU 1 Field Work Flow 0.0320 cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 580 mg/L 25 1 SM2540C 04/20/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 04/20/2017 10 00 MGIGANT Certificate of Laboratory Analysis This report shall not be reproduced, except in full Order # J17040410 Site Area C Sample #: 2017012820 Collection Date 13 -Apr -17 11 30 AM Matrix NPDES Analyte Result Units Qualifiers RDL OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION EPA 1664B Oil and Grease < 5 mg/L 5 ALKALINITY - (Analysis Performed by Shealy Labs) V_SHEALY Vendor Parameter Complete 04/19/2017 13 11 TLINN NITRITE + NITRATE (COLORIMETRIC) EPA 300 0 04/21/2017 16 30 Nitrite + Nitrate (Colonmetnc) 079 mg-N/L 001 INORGANIC IONS BY IC 1 EPA 300 0 04/21/2017 16 30 Chloride 26 mg/L 01 Fluoride < 0 1 mg/L 01 Sulfate 080 mg/L 01 MERCURY IN WATER - (Analysis Performed by Shealy Labs) EPA 200 7 Vendor Parameter Complete 1 EPA 200 7 TOTAL RECOVERABLE METALS BY ICP SLS2560 1 Aluminum (AI) 0 018 mg/L 0 005 Barium (Ba) 0 021 mg/L 0 005 Boron (B) < 0 05 mg/L 005 Calcium (Ca) 1 38 mg/L 001 Iron (Fe) 0.017 mg/L 001 Magnesium (Mg) 0.774 mg/L 0 005 Manganese (Mn) < 0 005 mg/L 0 005 Potassium (K) 1 57 mg/L 01 Sodium (Na) 302 mg/L 005 Total Hardness (Ca and Mg) 6.64 mg/L 019 EPA 200 8 04/20/2017 18 46 (CaCO3) 1 Zinc (Zn) < 0 005 mg/L 0 005 TOTAL RECOVERABLE METALS BY ICP -MS 04/20/2017 18 46 CWSPEN3 Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Copper (Cu) <1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) <1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0 2 ug/L B3 0 2 Analytical lab Page 6 of 54 DF Method Analysis Daterrime Analyst 1 EPA 1664B 04/24/2017 10 45 CJELLIO Vendor Method V_SHEALY 1 EPA 353 2 04/19/2017 13 11 TLINN 1 EPA 300 0 04/21/2017 16 30 BGN9034 1 EPA 300 0 04/21/2017 16 30 BGN9034 1 EPA 300 0 04/21/2017 16 30 BGN9034 Vendor Method V_SHEALY 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 Analytical lab Certificate of Laboratory Analysis Page 7 of 54 This report shall not be reproduced, except /n full Order # J17040410 Site Area C Collection Date 13 -Apr -17 11 30 AM Sample #: Matrix 2017012820 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 520 SI Units 1 Field Work Temperature 150 °C 1 Field Work Specific Conductance 370 us/cm 1 Field Work Turbidity 0.4 NTU 1 Field Work Flow 00060 cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 37 mg/L 25 1 SM2540C 04/20/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 04/20/2017 10 00 MGIGANT Analytical lab Certificate of Laboratory Analysis Page 8 of 54 This report shall not be reproduced, except in full Order # J17040410 Site S-31 Collection Date 13 -Apr -17 120 PM Sample #: 2017012821 Matrix NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Daterrime Analyst OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L 5 1 EPA 1664B 04/24/2017 10 45 CJELLIO ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colonmetnc) 007 mg-N/L 001 1 EPA 353 2 04/19/2017 13 12 TLINN INORGANIC IONS BY IC Chloride 61 mg/L 1 10 EPA 300 0 04/21/2017 16 47 BGN9034 Fluoride < 0 1 mg/L 01 1 EPA 300 0 04/21/2017 16 47 BGN9034 Sulfate 70 mg/L 1 10 EPA 300 0 04/21/2017 16 47 BGN9034 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V SHEALY TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) 0 054 mg/L 0 005 1 EPA 200 7 04/21/2017 13 42 SLS2560 Barium (Ba) 0 036 mg/L 0 005 1 EPA 200 7 04/21/2017 13 42 SLS2560 Boron (B) 1 21 mg/L 005 1 EPA 200 7 04/21/2017 13 42 SLS2560 Calcium (Ca) 403 mg/L 001 1 EPA 200 7 04/21/2017 13 42 SLS2560 Iron (Fe) 0 027 mg/L 001 1 EPA 200 7 04/21/2017 13 42 SLS2560 Magnesium (Mg) 7.65 mg/L 0 005 1 EPA 200 7 04/21/2017 13 42 SLS2560 Manganese (Mn) 1 67 mg/L 0 005 1 EPA 200 7 04/21/2017 13 42 SLS2560 Potassium (K) 339 mg/L 01 1 EPA 200 7 04/21/2017 13 42 SLS2560 Sodium (Na) 12.0 mg/L 005 1 EPA 200 7 04/21/2017 13 42 SLS2560 Total Hardness (Ca and Mg) 132 mg/L 019 1 EPA 200 7 04/21/2017 13 42 SLS2560 (CaCO3) Zinc (Zn) < 0 005 mg/L 0 005 1 EPA 200 7 04/21/2017 13 42 SLS2560 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 Arsenic (As) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 Cadmium (Cd) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 Chromium (Cr) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 Copper (Cu) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 Lead (Pb) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 Molybdenum (Mo) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 Nickel (Ni) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 Selenium (Se) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 Thallium (TI) Low Level < 0.2 ug/L 02 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 Analytical lab Certificate of Laboratory Analysis Page 9 of 54 This report shall not be reproduced, except in full Order # J17040410 Site S-31 Collection Date 13 -Apr -17 1 20 PM Sample #: Matrix 2017012821 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 650 SI Units 1 Field Work Temperature 223 °C 1 Field Work Specific Conductance 380 us/cm 1 Field Work Turbidity 07 NTU 1 Field Work Flow 00010 cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 290 mg/L 25 1 SM2540C 04/20/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 04/20/2017 10 00 MGIGANT Certificate of Laboratory Analysis This report shall not be reproduced, except in full Order # A7040410 Site S-19 Collection Date 13 -Apr -17 3 20 PM Analyte Result Units Qualifiers RDL OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION EPA 16648 Oil and Grease < 5 mg/L 5 ALKALINITY - (Analysis Performed by Shealy Labs) 1 Vendor Parameter Complete TLINN 5 NITRITE + NITRATE (COLORIMETRIC) 04/21/2017 17 04 BGN9034 Nitrite + Nitrate (Colorimetric) < 0 01 mg-N/L 001 INORGANIC IONS BY IC EPA 300 0 04/21/2017 17 04 BGN9034 Chloride 5.1 mg/L 05 Fluoride < 0.1 mg/L 01 Sulfate 38 mg/L 05 MERCURY IN WATER - (Analysis Performed by Shealy Labs) 04/21/2017 13 46 Vendor Parameter Complete EPA 200 7 04/21/2017 13 46 TOTAL RECOVERABLE METALS BY ICP 1 EPA 200 7 Aluminum (AI) 0.021 mg/L 0 005 Barium (Ba) 0.052 mg/L 0 005 Boron (B) 0.078 mg/L 005 Calcium (Ca) 397 mg/L 001 Iron (Fe) 0.086 mg/L 001 Magnesium (Mg) 17.0 mg/L 0 005 Manganese (Mn) 0.265 mg/L 0 005 Potassium (K) 279 mg/L 01 Sodium (Na) 3.97 mg/L 005 Total Hardness (Ca and Mg) 169 mg/L 019 04/20/2017 18 31 CWSPEN3 (CaCO3) EPA 200 8 Zinc (Zn) < 0 005 mg/L 0 005 TOTAL RECOVERABLE METALS BY ICP -MS CWSPEN3 1 Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.26 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0 2 ug/L B3 0 2 Sample #: 2017012822 Matrix NPDES Analytical lab Page 10 of 54 DF Method Analysis Date/Time Analyst 1 EPA 16648 04/24/2017 10 45 CJELLIO Vendor Method V SHEALY 1 EPA 353 2 04/19/2017 13 13 TLINN 5 EPA 300 0 04/21/2017 17 04 BGN9034 1 EPA 300 0 04/21/2017 17 04 BGN9034 5 EPA 300 0 04/21/2017 17 04 BGN9034 Vendor Method V_SHEALY 1 EPA 200 7 04/21/2017 13 46 SLS2560 1 EPA 200 7 04/21/2017 13 46 SLS2560 1 EPA 200 7 04/21/2017 13 46 SLS2560 1 EPA 200 7 04/21/2017 13 46 SLS2560 1 EPA 200 7 04/21/2017 13 46 SLS2560 1 EPA 200 7 04/21/2017 13 46 SLS2560 1 EPA 200 7 04/21/2017 13 46 SLS2560 1 EPA 200 7 04/21/2017 13 46 SLS2560 1 EPA 200 7 04/21/2017 13 46 SLS2560 1 EPA 200 7 04/21/2017 13 46 SLS2560 1 EPA 200 7 04/21/2017 13 46 SLS2560 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 lab Certificate of Laboratory Analysis Page 111 of 54 This report shall not be reproduced, except in full Order # J17040410 Site S-19 Collection Date 13 -Apr -17 3 20 PM Sample #: Matrix 2017012822 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 5.80 SI Units 1 Field Work Temperature 18.3 °C 1 Field Work Specific Conductance 286 us/cm 1 Field Work Turbidity 0.5 NTU 1 Field Work Flow 00020 cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 210 mg/L 25 1 SM2540C 04/20/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 04/20/2017 10 00 MGIGANT lab tical Certificate of Laboratory Analysis Pagey12 of 54 This report shall not be reproduced, except in full Order # J17040410 Site S-1 9A Collection Date 13 -Apr -17 3 45 PM Sample #: Matrix 2017012823 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Daterrime Analyst OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L 5 1 EPA 1664B 04/24/2017 10 45 CJELLIO ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0 05 mg-N/L 005 5 EPA 353 2 04/20/2017 15 00 TLINN INORGANIC IONS BY IC Chloride 51 mg/L 02 2 EPA 300 0 04/21/2017 17 21 BGN9034 Fluoride < 0 2 mg/L 02 2 EPA 300 0 04/21/2017 17 21 BGN9034 Sulfate 83 mg/L 2 20 EPA 300 0 04/21/2017 17 21 BGN9034 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0 028 mg/L 0 005 1 EPA 200 7 04/21/2017 13 51 SLS2560 Barium (Ba) 0.040 mg/L 0 005 1 EPA 200 7 04/21/2017 13 51 SLS2560 Boron (B) 0.121 mg/L 005 1 EPA 200 7 04/21/2017 13 51 SLS2560 Calcium (Ca) 64.9 mg/L 001 1 EPA 200 7 04/21/2017 13 51 SLS2560 Iron (Fe) 0 287 mg/L 001 1 EPA 200 7 04/21/2017 13 51 SLS2560 Magnesium (Mg) 238 mg/L 0 005 1 EPA 200 7 04/21/2017 13 51 SLS2560 Manganese (Mn) 1.55 mg/L 0 005 1 EPA 200 7 04/21/2017 13 51 SLS2560 Potassium (K) 2.01 mg/L 01 1 EPA 200 7 04/21/2017 13 51 SLS2560 Sodium (Na) 357 mg/L 005 1 EPA 200 7 04/21/2017 13 51 SLS2560 Total Hardness (Ca and Mg) 260 mg/L 019 1 EPA 200 7 04/21/2017 13 51 SLS2560 (CaCO3) Zinc (Zn) < 0 005 mg/L 0 005 1 EPA 200 7 04/21/2017 13 51 SLS2560 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 Arsenic (As) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 Cadmium (Cd) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 Chromium (Cr) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 Copper (Cu) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 Lead (Pb) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 Molybdenum (Mo) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 Nickel (Ni) 290 ug/L 1 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 Selenium (Se) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 Thallium (TI) Low Level < 0.2 ug/L B3 02 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 Analytical lab Certificate of Laboratory Analysis Page 13 of 54 This report shall not be reproduced, except in full Order # A7040410 Site S-1 9A Collection Date 13 -Apr -17 3 45 PM Sample #: Matrix 2017012823 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 640 SI Units 1 Field Work Temperature 172 °C 1 Field Work Specific Conductance 483 us/cm 1 Field Work Turbidity 1 37 NTU 1 Field Work Flow 00070 cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 300 mg/L 25 1 SM2540C 04/20/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 04/20/2017 10 00 MGIGANT Analytical lab Certificate of Laboratory Analysis Page 14 of 54 This report shall not be reproduced, except in full Order # A 7040410 Site S-2 Sample #: 2017012824 Collection Date 13 -Apr -17 9 00 AM Matrix NPDES Analyte Result Units Qualifiers RDL OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION EPA 1664B Oil and Grease < 5 mg/L 5 ALKALINITY - (Analysis Performed by Shealy Labs) V SHEALY Vendor Parameter Complete 04/19/2017 13 33 TLINN NITRITE + NITRATE (COLORIMETRIC) EPA 300 0 04/21/2017 17 38 Nitrite + Nitrate (Colorimetric) < 0.1 mg-N/L 01 INORGANIC IONS BY IC 25 EPA 300 0 04/21/2017 17 38 Chloride 4.4 mg/L 05 Fluoride < 0.5 mg/L 05 Sulfate 180 mg/L 25 MERCURY IN WATER - (Analysis Performed by Shealy Labs) EPA 200 7 Vendor Parameter Complete 1 EPA 200 7 TOTAL RECOVERABLE METALS BY ICP SLS2560 1 Aluminum (AI) 0 170 mg/L 0 005 Barium (Ba) 0.031 mg/L 0 005 Boron (B) 0 445 mg/L 005 Calcium (Ca) 659 mg/L 001 Iron (Fe) 1.35 mg/L 001 Magnesium (Mg) 23.0 mg/L 0 005 Manganese (Mn) 1.69 mg/L 0 005 Potassium (K) 408 mg/L 01 Sodium (Na) 473 mg/L 005 Total Hardness (Ca and Mg) 259 mg/L 019 EPA 200 8 04/20/2017 19 17 (CaCO3) 1 Zinc (Zn) 0.005 mg/L 0 005 TOTAL RECOVERABLE METALS BY ICP -MS 04/20/2017 19 17 CWSPEN3 Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 8.15 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L B3 02 DF Method Analysis Daterrime Analyst 1 EPA 1664B 04/24/2017 10 45 CJELLIO Vendor Method V SHEALY 10 EPA 353 2 04/19/2017 13 33 TLINN 5 EPA 300 0 04/21/2017 17 38 BGN9034 5 EPA 300 0 04/21/2017 17 38 BGN9034 25 EPA 300 0 04/21/2017 17 38 BGN9034 Vendor Method V_SHEALY 1 EPA 200 7 04/21/2017 14 07 SLS2560 1 EPA 200 7 04/21/2017 14 07 SLS2560 1 EPA 200 7 04/21/2017 14 07 SLS2560 1 EPA 200 7 04/21/2017 14 07 SLS2560 1 EPA 200 7 04/21/2017 14 07 SLS2560 1 EPA 200 7 04/21/2017 14 07 SLS2560 1 EPA 200 7 04/21/2017 14 07 SLS2560 1 EPA 200 7 04/21/2017 14 07 SLS2560 1 EPA 200 7 04/21/2017 14 07 SLS2560 1 EPA 200 7 04/21/2017 14 07 SL32560 1 EPA 200 7 04/21/2017 14 07 SLS2560 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 Analytical lab Certificate of Laboratory Analysis Page 15 of 54 This report shall not be reproduced, except in full Order # J17040410 Site S-2 Collection Date 13 -Apr -17 9 00 AM Sample #: Matrix 2017012824 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 670 SI Units 1 Field Work Temperature 145 °C 1 Field Work Specific Conductance 395 us/cm 1 Field Work Turbidity 294 NTU 1 Field Work Flow 00720 cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 380 mg/L 25 1 SM2540C 04/20/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS 5 mg/L 5 1 SM2540D 04/20/2017 10 00 MGIGANT Qualifiers: B3 Target analyte was detected in Continuing Calibration Blank (CCB) at a concentration greater than Y2 the reporting limit, but less than the reporting limit M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to the spike level The associated Laboratory Control Spike recovery was acceptable Certificate of Laboratory Analysis Analytical lab y Page 16 of 54 This report shall not be reproduced, except in full Order # A7040410 Level II QC Summary Q17040560 1664—SPE OIL AND GREASE IN WATER- SOLID PHASE EXTRACTION Blank # 1 Parameter Measured Final Oil and Grease 0 LCS #1 Parameter Measured Final Oil and Grease 337 MS #1 Parameter Measured Final Oil and Grease 31 9 Units Dd RDL Relative Concentration Qualifier mg/L 1 5 < 1/2 RDL - Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 361673 933 78 114 - Parent Sample J17030191 -- 2017007594 Units Dd Spike % Recovery LCL UCL Qualifier mg/L 1 351426 88 78 114 - Analytical lab Certificate of Laboratory Analysis Page 17 of 54 This report shall not be reproduced, except in full Order # A 7040410 Level II QC Summary Q17040534 C NO2NO3 NITRITE + NITRATE (COLORIMETRIC) Blank # 1 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 00007 00007 mg-N/L 1 001 < 1/2 RDL 301 (Colorimetric) 90 110 (Colorimetric) Blank # 2 LCS # 3 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate -00011 -00011 mg-N/L 1 001 < 1/2 RDL - (Colorimetric) Qualifier Nitrite + Nitrate 03 3 mg-N/L 10 301 Blank # 3 90 110 (Colorimetric) Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate -00001 -00001 mg-N/L 1 001 < 1/2 RDL - (Colorimetric) Measured Final Units Dil Spike % Recovery LCL Blank # 4 Qualifier Nitrite + Nitrate 0 296 296 mg-N/L 10 301 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate -00002 -00002 mg-N/L 1 001 < 1/2 RDL (Colorimetric) Blank # 5 Measured Final Units Dil Spike % Recovery LCL Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 00048 00048 mg-N/L 1 001 < 1/2 RDL (Colorimetric) LCS #1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitnte + Nitrate 0 303 303 mg-N/L 10 301 101 90 110 - (Colorimetric) LCS # 2 Parameter Measured Final Units Dil Spike % RecoveN LCL UCL Qualifier Nitnte + Nitrate 0 301 301 mg-N/L 10 301 999 90 110 (Colorimetric) LCS # 3 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 03 3 mg-N/L 10 301 996 90 110 (Colorimetric) LCS # 4 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 296 296 mg-N/L 10 301 982 90 110 (Colorimetric) LCS # 5 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitnte + Nitrate 0 306 306 mg-N/L 10 301 102 90 110 (Colorimetric) Analytical lab Certificate of Laboratory Analysis Page 18 of 54 Thls report shall not be reproduced, except /n full Order # A 7040410 Level II QC Summary Q17040534 C NO2NO3 NITRITE + NITRATE (COLORIMETRIC) MS # 1 Parent Sample J17040409 -- 2017012812 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 225 225 mg-N/L 10 25 954 90 110 (Colonmetric) MSD #1 Parent Sample J17040409 -- 2017012812 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 227 227 mg-N/L 10 25 961 90 110 084 (Colorimetric) MS #2 Parent Sample J17040410 -- 2017012824 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 236 236 mg-N/L 10 25 972 90 110 (Colorimetric) MSD #2 Parent Sample J17040410 -- 2017012824 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 235 235 mg-N/L 10 25 967 90 110 051 - (Colorimetric) MS #3 Parent Sample J17040387 -- 2017012687 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 346 0 346 mg-N/L 1 025 964 90 110 - (Colorimetric) MSD #3 Parent Sample J17040387 -- 2017012687 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 347 0 347 mg-N/L 1 025 965 90 110 00866 - (Colorimetric) MS #4 Parent Sample J17040409 -- 2017012813 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 231 6 92 mg-N/L 30 7 5 966 90 110 - (Colorimetric) MSD #4 Parent Sample J17040409 -- 2017012813 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 231 692 mg-N/L 30 7 5 965 90 110 00867 - (Colonmetnc) MS #5 Parent Sample J17040409 -- 2017012814 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 228 228 mg-N/L 10 25 944 90 110 (Colorimetric) MSD #5 Parent Sample J17040409 -- 2017012814 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 229 229 mg -NIL 10 2 5 949 90 110 0 569 (Colorimetric) Analy lab Certificate of Laboratory Analysis Page 19 olf 54 This report shall not be reproduced, except in full Order # J17040410 Level II QC Summary Q17040534 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC) MS #6 Parameter Measured Final Nitrite + Nitrate 0 234 468 (Colorimetric) MSD #6 Parameter Measured Final Nitrite + Nitrate 0 233 467 (Colorimetric) MS #7 Parameter Measured Final Nitrite + Nitrate 0 233 466 (Colorimetric) MSD #7 Parameter Measured Final Nitrite + Nitrate 0 233 465 (Colorimetric) MS #8 Parameter Measured Final Nitrite + Nitrate 0 235 1 18 (Colorimetric) MSD #8 Parameter Measured Final Nitrite + Nitrate 0 235 1 17 (Colorimetric) Parent Sample J17040409 -- 2017012815 Units Dil Spike % Recovery LCL UCL Qualifier mg-N/L 20 5 955 90 110 Parent Sample J17040409 -- 2017012815 Units Dil Spike % Recovery LCL UCL RPD Qualifier mg-N/L 20 5 953 90 110 0 171 - Parent Sample J17040410 -- 2017012819 Units Dil Spike % Recovery LCL UCL Qualifier mg-N/L 20 5 962 90 110 Parent Sample J17040410 -- 2017012819 Units Dil Spike % Recovery LCL UCL RPD Qualifier mg-N/L 20 5 961 90 110 0129 - Parent Sample J17040410 -- 2017012823 Units Dil Spike % Recovery LCL UCL Qualifier mg-N/L 5 1 25 954 90 110 - Parent Sample J17040410 -- 2017012823 Units Dil Spike % Recovery LCL UCL RPD Qualifier mg-N/L 5 1 25 952 90 110 0 213 - Analytical lab Certificate of Laboratory Analysis Page 20 of 54 This report shall not be reproduced, except ►n full Order # J17040410 Level II QC Summary Q17040509 Dionex INORGANIC IONS BY IC Blank # 1 Measured Final Units Dil Spike % Recovery LCL UCL Parameter Measured Final Units Dil RDL Relative Concentration 125 Chloride 00466 00466 mg/L 1 01 < 1/2 RDL 126 mg/L Fluoride 00485 00485 mg/L 1 01 < 1/2 RDL Sulfate 863 Sulfate 00136 00136 mg/L 1 01 < 1/2 RDL 039 - IS # 1 Measured Final Units Dil Spike % Recovery LCL UCL Parameter Measured Final Units Dil Spike % Recovery LCL UCL Chloride 577 144 mg/L 25 125 100 80 120 Fluoride 5 125 mg/L 25 125 99 80 120 Sulfate 861 215 mg/L 25 125 100 80 120 ISD # 1 IS #2 ISD # 2 LCS #1 Qualifier Qualifier Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Chloride 579 145 mg/L 25 125 101 80 120 0 271 Fluoride 503 126 mg/L 25 125 995 80 120 0 531 Sulfate 863 216 mg/L 25 125 101 80 120 039 - Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Chloride 778 15600 mg/L 2000 10000 102 80 120 Fluoride 502 10000 mg/L 2000 10000 993 80 120 Sulfate 568 11400 mg/L 2000 10000 100 80 120 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Chloride 778 15600 mg/L 2000 10000 102 80 120 00571 Fluoride 602 10000 mg/L 2000 10000 994 80 120 00845 - Sulfate 568 11400 mg/L 2000 10000 100 80 120 017 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Chloride 507 507 mg/L 1 5 101 90 110 - Fluoride 497 4 97 mg/L 1 5 994 90 110 Sulfate 504 504 mg/L 1 5 101 90 110 - lab Certificate of Laboratory Analysis Page 2'1 of 54 This report shall not be reproduced, except in full Order # A 7040410 Level II QC Summary Q17040440 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Blank # 1 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Aluminum (AI) -00011 mg/L 1 0 005 < 1/2 RDL - Barium (Ba) -00009 mg/L 1 0 005 < 1/2 RDL - Boron (B) -00002 mg/L 1 005 < 1/2 RDL - Calcium (Ca) -00026 mg/L 1 001 < 1/2 RDL - Iron (Fe) -00015 mg/L 1 001 < 1/2 RDL - Magnesium (Mg) -0001 mg/L 1 0 005 < 1/2 RDL - Manganese (Mn) -00008 mg/L 1 0 005 < 1/2 RDL - Potassium (K) -00132 mg/L 1 01 < 1/2 RDL - Sodium (Na) -00068 mg/L 1 005 < 1/2 RDL - Zinc (Zn) -00004 mg/L 1 0 005 < 1/2 RDL - LCS #1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Aluminum (AI) 477 mg/L 1 5 954 85 115 - Barium (Ba) 483 mg/L 1 5 966 85 115 - Boron (B) 496 mg/L 1 5 992 85 115 - Calcium (Ca) 497 mg/L 1 5 994 85 115 - Iron (Fe) 492 mg/L 1 5 985 85 115 - Magnesium (Mg) 495 mg/L 1 5 991 85 115 - Manganese (Mn) 482 mg/L 1 5 964 85 115 - Potassium (K) 4 74 mg/L 1 5 948 85 115 - Sodium (Na) 491 mg/L 1 5 983 85 115 - Zinc (Zn) 475 mg/L 1 5 95 85 115 - MS # 1 Parent Sample J17040409 -- 2017012812 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Aluminum (AI) 528 528 mg/L 1 5 100 70 130 - Barium (Ba) 511 511 mg/L 1 5 102 70 130 - Boron (B) 531 5 31 mg/L 1 5 103 70 130 - Calcium (Ca) 166 166 mg/L 1 5 110 70 130 - Iron (Fe) 729 729 mg/L 1 5 104 70 130 - Magnesium (Mg) 763 763 mg/L 1 5 101 70 130 - Manganese (Mn) 514 514 mg/L 1 5 101 70 130 - Potassium (K) 722 722 mg/L 1 5 101 70 130 - Sodium (Na) 131 131 mg/L 1 5 106 70 130 - Zinc (Zn) 4 89 489 mg/L 1 5 976 70 130 - MSD 91 Parent Sample J17040409 -- 2017012812 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Aluminum (AI) 489 489 mg/L 1 5 923 70 130 803 Certificate of Laboratory Analysis This report shall not be reproduced, except in full Order # A7040410 Level II QC Summary Q17040440 ICP_TRM TOTAL RECOVERABLE METALS BY ICP ru[.y31 Parameter Measured Final Units Dd Spike Barium (Ba) 465 465 mg/L 1 5 Boron (B) 491 491 mg/L 1 5 Calcium (Ca) 156 156 mg/L 1 5 Iron (Fe) 673 673 mg/L 1 5 Magnesium (Mg) 713 713 mg/L 1 5 Manganese (Mn) 469 469 mg/L 1 5 Potassium (K) 673 673 mg/L 1 5 Sodium (Na) 123 123 mg/L 1 5 Zinc (Zn) 451 451 mg/L 1 5 MS #2 Parameter Measured Final Units Dil Spike Aluminum (AI) 495 495 mg/L 1 5 Barium (Ba) 492 492 mg/L 1 5 Boron (B) 59 59 mg/L 1 5 Calcium (Ca) 102 102 mg/L 1 5 Iron (Fe) 613 613 mg/L 1 5 Magnesium (Mg) 383 383 mg/L 1 5 Manganese (Mn) 741 741 mg/L 1 5 Potassium (K) 101 101 mg/L 1 5 Sodium (Na) 107 107 mg/L 1 5 Zinc (Zn) 462 462 mg/L 1 5 MSD #2 Parameter Measured Final Units Dd Spike Aluminum (AI) 444 444 mg/L 1 5 Barium (Ba) 439 439 mg/L 1 5 Boron (B) 526 526 mg/L 1 5 Calcium (Ca) 973 973 mg/L 1 5 Iron (Fe) 556 556 mg/L 1 5 Magnesium (Mg) 368 368 mg/L 1 5 Manganese (Mn) 681 681 mg/L 1 5 Potassium (K) 937 937 mg/L 1 5 Sodium (Na) 997 997 mg/L 1 5 Zinc (Zn) 414 414 mg/L 1 5 Analytical lab Page 22 of 54 Parent Sample J17040409 -- 2017012812 % Recovery LCL UCL RPD Qualifier 924 70 130 945 - 94 8 70 130 796 - 89 9 70 130 203 - 92 5 70 130 115 - 91 70 130 104 - 92 1 70 130 941 - 90 8 70 130 102 - 89 7 70 130 168 - 90 1 70 130 799 - Parent Sample J17040410 -- 2017012819 % Recovery LCL UCL Qualifier 976 70 130 - 97 9 70 130 - 102 70 130 - 114 70 130 - 98 5 70 130 - 105 70 130 - 97 70 130 - 101 70 130 - 105 70 130 - 92 4 70 130 - Parent Sample J17040410 -- 2017012819 % Recovery LCL UCL RPD Qualifier 874 70 130 11 - 87 3 70 130 114 - 88 9 70 130 134 - 23 2 70 130 132 - 87 1 70 130 123 - 74 5 70 130 338 - 84 9 70 130 133 - 86 9 70 130 149 - 90 1 70 130 149 - 82 7 70 130 11 1 - Analytical lab Certificate of Laboratory Analysis Page 23 of 54 This report shall not be reproduced, except in full Order # J17040410 Level II QC Summary Q17040449 IMS TRM TOTAL RECOVERABLE METALS BY ICP -MS Blank # 1 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Antimony (Sb) 0 009 0 009 ug/L 1 1 < 1/2 RDL Arsenic (As) 0 017 0 017 ug/L 1 1 < 1/2 RDL Cadmium (Cd) 0 002 0 002 ug/L 1 1 < 1/2 RDL - Chromium (Cr) -0008 -0008 ug/L 1 1 < 1/2 RDL - Copper (Cu) -0015 -0015 ug/L 1 1 < 1/2 RDL - Lead (Pb) 0 0 ug/L 1 1 < 1/2 RDL - Molybdenum (Mo) 0 012 0 012 ug/L 1 1 < 1/2 RDL - Nickel (Ni) -0017 -0017 ug/L 1 1 < 1/2 RDL - Selenium (Se) -0039 -0039 ug/L 1 1 < 1/2 RDL - Thallwm (TI) Low Level -0029 -0029 ug/L 1 02 < 1/2 RDL - LCS # 1 Parameter Measured Final Units Dil S ike % Recovery LCL UCL Qualifier Antimony (Sb) 497 497 ug/L 1 50 993 85 115 - Arsenic (As) 493 493 ug/L 1 50 986 85 115 - Cadmium (Cd) 502 502 ug/L 1 50 100 85 115 - Chromium (Cr) 491 491 ug/L 1 50 982 85 115 - Copper (Cu) 497 497 ug/L 1 50 993 85 115 - Lead (Pb) 499 499 ug/L 1 50 997 85 115 - Molybdenum (Mo) 51 51 ug/L 1 50 102 85 115 - Nickel (Ni) 501 501 ug/L 1 50 100 85 115 - Selenium (Se) 493 493 ug/L 1 50 986 85 115 - Thallium (TI) Low Level 482 482 ug/L 1 50 964 85 115 - MS #1 Parent Sample J17040409 -- 2017012815 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Antimony (Sb) 493 493 ug/L 1 50 982 70 130 Arsenic (As) 51 1 51 1 ug/L 1 50 978 70 130 Cadmium (Cd) 485 485 ug/L 1 50 969 70 130 - Chromium (Cr) 486 486 ug/L 1 50 96 70 130 - Copper (Cu) 48 48 ug/L 1 50 947 70 130 - Lead (Pb) 502 502 ug/L 1 50 995 70 130 - Molybdenum (Mo) 573 573 ug/L 1 50 996 70 130 - Nickel (Ni) 51 3 51 3 ug/L 1 50 963 70 130 - Selenium (Se) 481 481 ug/L 1 50 954 70 130 - Thallium (TI) Low Level 466 466 ug/L 1 50 93 70 130 - MSD #1 Parent Sample J17040409 -- 2017012815 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Antimony (Sb) 478 478 ug/L 1 50 951 70 130 321 - Certificate of Laboratory Analysis This report shall not be reproduced, except in full Order # A 7040410 Level II QC Summary Q17040449 IMS TRM TOTAL RECOVERABLE METALS BY ICP -MS MSD #1 Parameter Measured Final Units Dil Spike Arsenic (As) 497 497 ug/L. 1 50 Cadmium (Cd) 474 474 ug/L 1 50 Chromium (Cr) 474 474 ug/L 1 50 Copper (Cu) 472 472 ug/L 1 50 Lead (Pb) 493 493 ug/L 1 50 Molybdenum (Mo) 56 56 ug/L. 1 50 Nickel (Ni) 504 504 ug/L 1 50 Selenium (Se) 464 464 ug/L. 1 50 Thallium (TI) Low Level 461 461 ug/L. 1 50 MS #2 Parameter Measured Final Units Dil Spike Antimony (Sb) 497 497 ug/L 1 50 Arsenic (As) 486 486 ug/L 1 50 Cadmium (Cd) 499 499 ug/L. 1 50 Chromium (Cr) 492 492 ug/L. 1 50 Copper (Cu) 494 494 ug/L. 1 50 Lead (Pb) 505 505 ug/L 1 50 Molybdenum (Mo) 509 50 9 ug/L 1 50 Nickel (Ni) 50 50 ug/L 1 50 Selenium (Se) 477 477 ug/L 1 50 Thallium (TI) Low Level 478 478 ug/L. 1 50 MSD #2 Parameter Measured Final Units Dil Spike Antimony (Sb) 467 467 ug/L 1 50 Arsenic (As) 459 459 ug/L 1 50 Cadmium (Cd) 471 471 ug/L 1 50 Chromium (Cr) 47 47 ug/L 1 50 Copper (Cu) 46 5 465 ug/L. 1 50 Lead (Pb) 482 482 ug/L 1 50 Molybdenum (Mo) 478 478 ug/L 1 50 Nickel (Ni) 476 476 ug/L 1 50 Selenium (Se) 456 456 ug/L 1 50 Thallium (TI) Low Level 463 463 ug/L 1 50 Analytical lab Page 24 of 54 Parent Sample J17040409 -- 2017012815 % Recovery LCL UCL RPD Qualifier 95 70 130 295 - 94 7 70 130 234 - 93 6 70 130 247 - 92 9 70 130 1 83 - 97 5 70 130 1 97 - 96 9 70 130 277 - 94 5 70 130 1 95 - 91 9 70 130 369 - 92 1 70 130 1 04 - Parent Sample J17040410 -- 2017012820 % Recovery LCL UCL Qualifier 993 70 130 - 97 2 70 130 - 99 8 70 130 - 98 2 70 130 - 98 6 70 130 - 101 70 130 - 102 70 130 - 99 7 70 130 - 95 7 70 130 - 95 5 70 130 - Parent Sample J17040410 -- 2017012820 % Recovery LCL UCL RPD Qualifier 933 70 130 63 91 8 70 130 564 - 94 2 70 130 574 - 93 8 70 130 455 - 92 8 70 130 606 - 96 4 70 130 452 - 95 5 70 130 637 - 94 8 70 130 501 - 91 5 70 130 45 - 92 7 70 130 305 - Certificate of Laboratory Analysis Th/s report shall not be reproduced, except /n full Order # 717040410 Level II QC Summary Q17040477 TDS TOTAL DISSOLVED SOLIDS Blank # 1 Parameter Measured Final TDS 0 0 Blank # 2 Parameter Measured Final TDS 0 0 Duplicate # 1 Parameter Measured Final TDS 91 91 Duplicate # 2 Parameter Measured Final TDS 276 276 Duplicate # 3 Parameter Measured Final TDS 387 387 Duplicate # 4 Parameter Measured Final TDS 147 147 LCS #1 Parameter Measured Final TDS 99 99 Analytical lab Page 25 of 54 Units Dil RDL Relative Concentration Qualifier mg/L 1 25 < 1/2 RDL - Units Dil RDL Relative Concentration Qualifier mg/L 1 25 < 1/2 RDL Parent Sample J17040409 -- 2017012812 Units Dil RPD Qualifier mg/L 1 222 Parent Sample J17040409 - 2017012813 Units Dil RPD Qualifier mg/L 1 0 722 - Parent Sample J17040409 -- 2017012814 Units Dil RPD Qualifier mg/L 1 0 258 - Parent Sample J17040409 -- 2017012815 Units Dil RPD Qualifier mg/L 1 206 Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 100 99 90 110 Analytical lab Certificate of Laboratory Analysis Page 26 of 54 This report shall not be reproduced, except ►n full Order # J17040410 Level II QC Summary Q17040472 TSS TOTAL SUSPENDED SOLIDS Blank # 1 Parameter Measured Final TSS 0 0 Blank # 2 Parameter Measured Final TSS 0 0 Duplicate # 1 Parameter Measured Final TSS 32 32 Duplicate # 2 Parameter Measured Final TSS 28 28 Duplicate # 3 Parameter Measured Final TSS 04 04 LCS #1 Parameter Measured Final TSS 492 492 Units Dil RDL Relative Concentration Qualifier mg/L 1 5 < 1/2 RDL - Units Dil RDL Relative Concentration Qualifier mg/L 1 5 < 1/2 RDL - Parent Sample J17030105 -- 2017007196 Units Dil RPD Qualifier mg/L 1 0 - Parent Sample J17030142 -- 2017007366 Units Dil RPD Qualifier mg/L 1 7 41 - Parent Sample J17030186 -- 2017007580 Units Dil RPD Qualifier mg/L 1 667 - Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 50 984 90 110 - SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle Project Name Cliffside NPDES AOW Project Number A 7040410 Lot Number SD14062 Date Completed 04/26/2017 Date Revised 04/26/2017 Grant Wilton Project Manager LABORATORY BUREAU wiv BUREAU This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc The following non -paginated documents are considered part of this report Chain of Custody Record and Sample Receipt Checklist Shealy Environmental Services, Inc Page: 1 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax(803)791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No 32010 NELAC No E87653 NC DENR No 329 NC Field Parameters No 5639 Case Narrative Duke Energy Lot Number: SD14062 Project Name: Cliffside NPDES AOW Project Number: J17040410 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative The sample receiving date is documented in the header information associated with each sample All results listed in this report relate only to the samples that are contained within this report Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page REVISION 1 Shealy Environmental Services, Inc Page- 2 Of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: SD14062 Project Name: Cliffside NPDES AOW Project Number: J17040410 Sample Number Sample ID Matrix Date Sampled Date Received 001 2017012819 Aqueous 04/13/2017 0930 04/14/2017 002 2017012820 Aqueous 04/13/20171130 04/14/2017 003 2017012821 Aqueous 04/13/20171320 04/14/2017 004 2017012822 Aqueous 04/13/20171520 04/14/2017 005 2017012823 Aqueous 04/13/2017 1545 04/14/2017 006 2017012824 Aqueous 04/13/2017 0900 04/14/2017 (6 samples) Shealy Environmental Services, Inc Page: 3 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com (14 detections) Shealy Environmental Services, Inc Page: 4 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: SD14062 Project Name: Cliffside NPDES AOW Project Number: J17040410 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2017012819 Aqueous Alkalinity SM 2320B- 63 mg/L 5 001 2017012819 Aqueous Bicarbonate Alkalinity SM 2320B- 63 mg/L 5 001 2017012819 Aqueous Mercury (CVAFS) 1631E 0 595 ng/L 6 002 2017012820 Aqueous Mercury (CVAFS) 1631E 0 513 ng/L 8 003 2017012821 Aqueous Mercury (CVAFS) 1631E 347 ng/L 10 004 2017012822 Aqueous Alkalinity SM 2320B- 130 mg/L 11 004 2017012822 Aqueous Bicarbonate Alkalinity SM 2320B- 130 mg/L 11 004 2017012822 Aqueous Mercury (CVAFS) 1631E 0 545 ng/L 12 005 2017012823 Aqueous Alkalinity SM 2320B- 180 mg/L 13 005 2017012823 Aqueous Bicarbonate Alkalinity SM 2320B- 180 mg/L 13 005 2017012823 Aqueous Mercury (CVAFS) 1631E 0 673 ng/L 14 006 2017012824 Aqueous Alkalinity SM 2320B- 81 mg/L 15 006 2017012824 Aqueous Bicarbonate Alkalinity SM 2320B- 81 mg/L 15 006 2017012824 Aqueous Mercury (CVAFS) 1631E 0 557 ng/L 16 (14 detections) Shealy Environmental Services, Inc Page: 4 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals Client Duke Energy Laboratory ID SD14062-001 Description 2017012819 Matrix Aqueous Date Sampled 04/13/2017 0930 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/17/2017 1619 BWS 39707 1 (Bicarbonate ) SM 23208-2011 1 04/17/2017 1619 BWS 1 (Carbonate AI) SM 2320B-2011 1 04/17/2017 1619 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a' W' S = MS/MSD failure Shealy Environmental Services, Inc Page: 5 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 63 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 63 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a' W' S = MS/MSD failure Shealy Environmental Services, Inc Page: 5 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Mercury (CVAFS) Client Duke Energy Laboratory ID SD14062-001 Description 2017012819 Matrix Aqueous Date Sampled 04/13/2017 0930 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 04/20/2017 1946 COH 04/18/2017 1331 39701 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 0 595 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < POL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of cntena L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page: 6 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Inorganic non-metals Client Duke Energy Laboratory ID SD14062-002 Description 2017012820 Matrix Aqueous Date Sampled 04/13/2017 1130 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/17/2017 1642 BWS 39707 1 (Bicarbonate ) SM 2320B-2011 1 04/17/2017 1642 BWS 1 (Carbonate Al) SM 2320B-2011 1 04/17/2017 1642 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page: 7 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page: 7 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Mercury (CVAFS) Client Duke Energy Laboratory ID SD14062-002 Description 2017012820 Matrix Aqueous Date Sampled 04/13/2017 1130 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 04/20/2017 2002 COH 04/18/2017 1331 39701 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 0 513 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MSlMSD failure Shealy Environmental Services, Inc Page 8 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Inorganic non-metals Client Duke Energy Laboratory ID SD14062-003 Description 2017012821 Matrix Aqueous Date Sampled 04/13/2017 1320 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 23208-2011 1 04/17/2017 1648 BWS 39707 1 (Bicarbonate ) SM 2320B-2011 1 04/17/2017 1648 BWS 1 (Carbonate Al) SM 2320B-2011 1 04/17/2017 1648 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page- 9 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 23208-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page- 9 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SD14062-003 Description 2017012821 Matrix Aqueous Date Sampled 04/13/2017 1320 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysts Date Analyst Prep Date Batch 1 1631 E 1 04/20/2017 2008 COH 04/18/2017 1331 39701 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 3.47 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page 10 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals Client Duke Energy Laboratory ID SD14062-004 Description 2017012822 Matrix Aqueous Date Sampled 04/1312017 1 520 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/17/2017 1654 BWS 39707 1 (Bicarbonate ) SM 2320B-2011 1 04/17/2017 1654 BWS 1 (Carbonate Al) SM 2320B-2011 1 04/17/2017 1654 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of cntena L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page: 11 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 130 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 130 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of cntena L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page: 11 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SD14062-004 Description 2017012822 Matrix Aqueous Date Sampled 04/13/2017 1520 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 04/20/2017 2013 COH 04/18/2017 1331 39701 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 0.545 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page: 12 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Inorganic non-metals Client Duke Energy Laboratory ID SD14062-005 Description 2017012823 Matrix Aqueous Date Sampled 04/13/2017 1545 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/17/2017 1701 BWS 39707 1 (Bicarbonate ) SM 2320B-2011 1 04/17/2017 1701 BWS 1 (Carbonate Al) SM 23208-2011 1 04/17/2017 1701 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of cntena L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page. 13 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 180 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 180 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of cntena L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page. 13 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Mercury (CVAFS) Client Duke Energy Laboratory ID SD14062-005 Description 2017012823 Matrix Aqueous Date Sampled 04/13/2017 1545 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 04/20/2017 2018 COH 04/18/2017 1331 39701 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 0 673 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page 14 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals Client Duke Energy Laboratory ID SD14062-006 Description 2017012824 Matrix Aqueous Date Sampled 04/13/2017 0900 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/17/2017 1707 BWS 39707 1 (Bicarbonate ) SM 23208-2011 1 04/17/2017 1707 BWS 1 (Carbonate AI) SM 23208-2011 1 04/17/2017 1707 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page- 15 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 81 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 81 10 mg/L 1 Carbonate Alkalinity SM 23208-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page- 15 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SD14062-006 Description 2017012824 Matrix Aqueous Date Sampled 04/13/2017 0900 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 04/20/2017 2024 COH 04/18/2017 1331 39701 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 0.557 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page- 16 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn QC Summary Shealy Environmental Services, Inc QC Data for Lot Number. SD14062 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals - MB Sample ID SQ39707-001 Matrix, Aqueous Batch.39707 Analytical Method SM 232013-2011 Parameter Result Q Dil PQL Units Analysis Date Alkalinity ND 1 10 mg/L 04/17/20171533 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of cnteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of cnteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' Note Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number: SD14062 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Inorganic non-metals - LCS Sample ID. SQ39707-002 Matrix: Aqueous Batch.39707 Analytical Method SM 23208-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q DO % Rec Limit Analysts Date Alkalinity 100 97 1 97 90-110 04/17/20171527 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL += RPD is out of entente Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number: SD14062 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals - Duplicate SamplelD SD14062-001DU Matrix Aqueous Batch 39707 Analytical Method. SM 23208-2011 Sample Amount Result % RPD Parameter (mg/L) (mg/L) Q Dil % RPD Limit Analysis Date Alkalinity 63 64 1 058 20 04/17/2017 1624 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' Note. Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number. SD14062 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) - MB Sample ID SQ39701-001 Matrix Aqueous Batch 39701 Prep Method 1631E Analytical Method 1631E Prep Date 04/18/2017 1331 Parameter Result Q Dill PQL Units Analysis Date Mercury (CVAFS) ND 1 0 500 ng/L 04/20/2017 1831 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' Note Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number. SD14062 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Mercury (CVAFS) - LCS Sample ID' SQ39701-002 Matrix: Aqueous Batch -39701 Prep Method, 1631E Analytical Method: 1631E Prep Date: 04/18/2017 1331 Spike Amount Result % Rec Parameter (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date Mercury (CVAFS) 500 471 1 94 75-125 04/20/2017 1836 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number. SD14062 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Mercury (CVAFS) - MS Sample ID SD14062-001MS Matrix Aqueous Batch 39701 Prep Method 1631 E Analytical Method 1631E Prep Date 04/18/2017 1331 Sample Spike Amount Amount Result % Rec Parameter (ng/L) (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date Mercury (CVAFS) 0 595 500 491 1 86 71-125 04/20/2017 1951 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of cnteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number. SD14062 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Mercury (CVAFS) - MSD Sample ID SD14062-001MD Matrix: Aqueous Batch'39701 Prep Method 1631E Analytical Method- 1631E Prep Date 04/18/2017 1331 Sample Spike Amount Amount Result % Rec % RPD Parameter (ng/L) (ng/L) (ng/L) Q Dill % Rec % RPD Limit Limit Analysis Date Mercury (CVAFS) 0 595 500 47 1 82 44 71-125 24 04/20/2017 1957 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of cntena Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' Note- Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number. SD14062 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Chain of Custody and Miscellaneous Documents Shealy Environmental Services, Inc 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com u) S N d N — ' m _ _,.— ---- - - - — CHAIN OF CUSTODY RECORD AND ANALYSIS _REQUEST P6RNI rCD o < P DNko Energy [Liles Energy An�ryacel Lafaoamry -� r- -- - -- --- ^'•••••"• __ — -- twl `Uhauia Uaa CD i Anal Gual Laborratary — NaiC.LYMlAT(auNnrTCC91 joldwm , Amir ME6 -�_ uNf a.7�Y �af,J�73, z t,.,y so I fi 2 3 i ChUinoiClnsOrty a H.,.... 4 cCzmra : -- SD1 {? r2 mrsmn.. ^--. Samp(LLCo�------I---- mare, - ;�9U�®hInou sr.., tl�rJYfi�S D3 +aapLE paoortl+M ; �RIGIr:Ac to us o L r•a fTf fox { I.a.ny itihx _ t1PDE9 s I lw.n NPDES-ACyM noeo.,m-_N ID Cnrl,vllt'aee U5Tencs^ :a' IAcanwsnJnt� Unrllarea Unit; ram ,�Yq Gc.le•Ta �.,.,,.� Pft!Se9Yat,ra ++.Yaw Iq I:d IEd to O_ O F..q 101 — �-- 'Nu,[d, Contalnar Valums (ML) 12,50 209 2w 20O 250 FIELD MEIISURLMENTS $b SOO � wnnwar - sl.va t-IF� r m Cont711ti1r Type How M Per µPCT HCPE t7 HDPE Olass � _ w Sam Pie Description orlD mplalanirgiugonste to ami v ea x o Cuat�mcr ro cu t% en ,` a �-' I a !V!i N C f+i G 1, d Z Z ,-�h ` I v rde lD v 1 oration ld OPSLOCallu CeLsflnnlnlaemlWn i' ` a r H Y I o $ a _C; 7 kZ4 �_ o■ta �rm.� 3, ears µ n r E' zum� 1^0 �zz I - - _ � � o,e,ea . S" �`L2.3 J) ba J 3•� �� 1 �. Lz� 1 ' - E I5Ir x ' � - - lqq -71 s iE g d'3 —•» i Q g Field Blank - --- g Trip blank 3 9 a i — TWAL 2 a 1 0 Cus hrro n e uw rima e - .p ( �p;� DaealTmae f • ' +, ��f3� � � � /(ffr` ,15 9'w a Requemted Turnaraurrl rout a nG[nshstl sy /Q`� Da4nnTiM nA `'' Y m"tib f '114 Mys ihnq�7ietl Elr OatefTtln �Attaptad BY Oa i. G� ,a - •'" - f — �{ rYlr D rE+r� ? ! 11 11 �,'Jr^,,- ,1. raj Dar. aauloekarpr DawnraA j sseladl � jam':' �,�cirOr+�uad9y UntnrCuno •v <� �rrr"� .51'Y l:�CI•y'iCl�fff!?li,��- � � ��J�' %%r`{�/J�•�idc} �� •aSHr_� � � EiE6leHts b tC? u jr f • 9 ° y MS lIDgeatad•TRhq. As, Ctl, Cr, Cu, Mu, Ni, PV, Sb, 6e I RC Methadj Tl {iy� Kwell 7Dtal Herdrnca tae `Ctner f @1EM2NtS by ICP;Dlpested YriM}: N, Ca, W, g. Fr, % Mrd J4„ Na, 2n Flease copy Tun Ilnrrsucker on *Keel EDD results •and Cruz Vdl! i.pph } 1 ed a /Y SHEALY ENVIRONMENTAL SERVICES, INC. Sheah) Cnvnronmsnol Sereic,,nuc Decimeat Namber. Mao YOC-68 Y.LIofI £fieenve Da -x, 3j'0 -?,20I 7 hrpi:�r 17n[r O�+Q"..':022 t� I Sample Receipt Checklist (SRC Cl ierit:_ _ t1 Cooler In_pecten byidato: L,ot 4 Meansnfrewipt: o 5ESl o Client a UPS ❑ FcdEx _i; - r =wtiL Yes o Ao"eT' 1, Were custody seals presernl on the coolst7 Ycs ❑ No ❑ T•A ❑ 2. If custody seals �maie prm-.1bl, were the• intact and unbroken? pH strip ID: Cl strip ID. Cooler 1DICriginal temperature upon receipt0ei Ived (corrected) temperature upon receipt: ii -`)/11 °C 119,L'WtV-("C t 11 7C 1 i °C Method: ❑ Temperature Blaiik P Aga[nst Bottles lR Gun ID; iR Gtalt Correction Factor: CJ' °C: Method of cool ant: ,oVVct Ice: n il;ltte 1co o Dry Ice +-Kone G -L. 1 , `f No o NA3' If temperature of any cooler�et;edr i 6,00C. was Project ManagerNotified ? PM, +vas Notified bs,: hone v l all ?? face-to-face (circle one), Ycs ❑ No _i NA 4. Is the comnr-rcial courier', pmking slip attached to this form? YcsJ3-' No n 5. Were proper custody procedures (relin uished+'received) followed? Yespr No 1_ 6. Were sannplc :Cis listed on the COC? Yes ra/ No ❑ 7, 'Nure sample lDs listed on all sample containers? Yrs P-" No ❑ 3, Was coIlecthm date K. time listed on the COC? Yes No Ct 9. Was collection date 9- time listed on all sample ennit:incrs? Yes No ❑ 10 Did sill container label intormation (ID, date, time) agree with the CDC? Yes No 0 11. Were tests to be performed listed on the COC? Yc*, er__�' Nn n 12. Did all samples an ive in the proper containers for each test andlor in good condition funbroken. Ilds on. otc.)? Y V0 0 13. We>a ode eluate satele volume available? Yrs No ti 14. Were all samples received within V, the holdingtime or 48 houns, v h;chever comes first? Yes ❑ No a--~- 15. any sample,% cnntaimrs missingfexce ss (circle one) samples Not listed on COCn Yes t7 No 0 NA -6 16, %1cre bubbles present > "pea -size" ('1"or Smml in diameter) in any VOA vials? Y°cs ❑ No ❑ � NMI- 17 Were all ll1ZU+nteta]S;nutrieril Samp] rs received at a pH of < 2? Yea Cl No 0 NA 19 Were all cyanide samples received ata pH- 12 and sulfide samples received al a pH `- 9? Yet; Cn No � NA � 14, Were all appi,enble NH3+'1 KNicy anideiphcnolBNA (� 0.5ingIL) samples tree of ruidual chlorine? Yes o No ❑ NA pl,' 20. Were collection temperatures documented on i le COC for NC sampleb? Yes ❑ Na ❑ NA 21. Fero client temarlslrequesn ti_c, rcqucsted dilutions, iVIS.'h'ISD des;<-ni;s�ons, ctc..) correctly transcribed fnom the COG into the comment section in LIMS? Yes o Nn O 22, Was the quote number u-, rd taken from the container label'? tiatnple Preservation (Must be cutn lcted for any snmple(s) incorrect]r preserved ar Mth headspacr,) Sample(,) sample mceioin with wort received incorrectly prescncd and wtrr ddjtlsted accordingly in (H�SOa, HNQ1, FiC t, NaOH) using S[i it Sam [e(s) werc reczivcd with NI11es >6 ntnt in dia,neter. 53111ptes(s) tivcrc received with TRC > 0.5 merf- (ir+r21 is No) and m ere adjusted accordingly in satat le receivin with sodium dtiosu[fate (NatSz4� with Shealy lid: SC Drinking Nater Project Sample(s) pH ver[fied to be < 2 by pjttc; Sam le(s vrorn Not received a: a pl l of < 2 and were adjusted :ec4artlingly t slop SRS - Sample label_ apphed b : Verified by; Date. Onnrlents. Shealy Environmental Services, Inc 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com -84 1 DaNWTkrw a., Requested Turnaround R -W;4 I d By CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM Analytical lab Duke E auks enevoy Amallywail za� --- --------- --------------- -- Analytical LabOrAltory Um IF Page 54 of 54 Analytical Laboratory jw,"hw ! i 123M Kagm I" Old i Order N 01 1 cif It; NPOES NC !Page _1_ 01 _3_ DISTRIBUTION Chain of Custody A SoMpk Log ....... -- - "M-6w"ow Ill C. all t"AjvIN6#48 . —�P Pat& & tw" "a"" oy'7-(;,c 04feq SAIMPLE PROCINAM ONWA W~ Npt*s )I_ OWGINAI to LAB COPY to CLIE'41 SHEALY -------- P P NPOES. AGW firm" me: -- I Client iaw—AML louGWAU ullft PINION& lVander on"Wil UST qc" voutil, — COC REV DATE 512012016 ..... " .. ------ PO 5021013 Filtration (0.45 um) Unfliftered Preservatwe wcn Il Ice Ice MrYlY NA container Volwne ffnL) 1250 2DOO 250 300 250 FIELD MEASUREMENTS 40 ContainarType, Holm PEI PEI PEt title[ Glass NnPE Field Blank Trip Blank T I TOTAL 2 4 : --i— ---, 0 nr DatelTirna 4 Y/f rw%�'M 1 DaNWTkrw a., Requested Turnaround R -W;4 I d By 1"Wed Arv. — v .......... u E 14 Days ReNiquished By Accepted 13,W Sample Description or ID Cush~ to cel all apf"uprato 0 W :t s LL 0 ILL D In 22 :2 C -0 — 2-1 tn ci d 1-: fA 'Other ELEMENTS by ICP MS 10igested-TRI111111, At, Cd, Cr. Cu, MQ,'NI, Pb, Sb, So (6RC Method) TI (k,,* kil Total Hardness LOA U06 owv Location 10 GPS Location 10 (n t;- :u E LL i ") u CLI -Z 0 1 J .1 0;..� Lob 10 Date Time Slunah" 43 0 0 1,- -it u I- z Q I.- LL on T > -C (j a z ;=':or -140 2 1 4 3 1'), ZRq Field Blank Trip Blank T I TOTAL 2 4 : --i— ---, 0 nr DatelTirna 4 Y/f rw%�'M 1 DaNWTkrw a., Requested Turnaround R -W;4 I d By 1"Wed Arv. — v .......... ------- "a .2 ;; IL I E 14 Days ReNiquished By Accepted 13,W 7 Days S"IJLiri:kcd By Dotoffkft Sl ar*<"id By lllkDateFTinw �b '48 Hr 'Other ELEMENTS by ICP MS 10igested-TRI111111, At, Cd, Cr. Cu, MQ,'NI, Pb, Sb, So (6RC Method) TI (k,,* kil Total Hardness ELEMENTS by ICP [Digested TRM)-. At, Co. Ba, B, Fla. Mg, Mn, K, No, Zn Please copy Tim Hunsucker en excel EDD nimults Acid Cost V Apply DUKE E Analytical Laboratory Page I of 36 Order Number: Project Name Customer Name(s) Customer Address Lab Contact Report Authorized By. (Signature) Program Comments: 13339 Hagers Ferry Road Huntersvllle, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone 980-875-5245 Fax 980-875-4349 Order Summary Report J17060014 BELEWS - NPDES - AOW Ross Hartfield, Tim Hunsucker,Chns Suttel, Chris Hallman, Kathy Webb, Brando 3195 Pine Hall Rd Mailcode Belews Steam Station Belews Creek, NC 28012 Mary Ann Ogle Phone 980-875-5274 Mary Ann Ogle Date: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report Data Flags & Calculations: 6/18/2017 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading All results are reported on a dry weight basis unless otherwise noted Subcontracted data included on the Duke Certificate of Analysis is to be used as information only Certified vendor results can be found in the subcontracted lab final report Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative An estimation of the uncertainty of measurement for the results in the report is available upon request This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory Please contact the Analytical laboratory with any questions The order of individual sections within this report is as follows Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005 Contact the Analytical Laboratory for definitive information about the certification status of specific methods Sample ID's & Descriptions: Page 2 of 36 Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2017018245 BELEWS 31 -May -17 12 45 PM Daniel Youngblood S-16 2017018246 BELEWS 31 -May -17 1 50 PM Daniel Youngblood FIELD BLANK 2017018247 BELEWS 31 -May -17 1 50 PM Daniel Youngblood Trip Blank 3 Total Samples Technical Validation Review Checklist: COC and pdf report are In agreement with sample totals Yes ❑ No and analyses (compliance programs and procedures) All Results are less than the laboratory reporting limits ❑ Yes No All laboratory QA/QC requirements are acceptable 0 Yes ❑ No Report Sections Included: ❑ Job Summary Report Sample Identification d❑ Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Page 3 of 36 ❑�/ Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries V] Chain of Custody 0 Electronic Data Deliverable (EDD) Sent Separatel Reviewed By Peggy Kendall Date 6/18/2017 Certificate of Laboratory Analysis Page 4of36 This report shall not be reproduced, except in full Order # J17060014 Site S-16 Sample #: 2017018245 Collection Date 31 -May -17 12 45 PM Matrix NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L 5 1 EPA 1664B 06/07/2017 09 45 CJELLIO ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colonmetric) < 0.01 mg-N/L 001 1 EPA 353 2 06/07/2017 13 39 JASTOWE INORGANIC IONS BY IC Chloride 20 mg/L 01 1 EPA 300 0 06/02/2017 12 02 BGN9034 Fluoride < 0.1 mg/L 01 1 EPA 300 0 06/02/2017 12 02 BGN9034 Sulfate 1.1 mg/L 01 1 EPA 300 0 06/02/2017 12 02 BGN9034 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 240 mg/L 0 025 1 EPA 200 7 06/12/2017 11 01 MHH7131 Barium (Ba) 0.025 mg/L 0 005 1 EPA 200 7 06/12/2017 11 01 MHH7131 Boron (B) < 0.05 mg/L 005 1 EPA 200 7 06/12/2017 11 01 MHH7131 Calcium (Ca) 1.85 mg/L 001 1 EPA 200 7 06/12/2017 11 01 MHH7131 Iron (Fe) 1.44 mg/L 001 1 EPA 200 7 06/12/2017 11 01 MHH7131 Magnesium (Mg) 1.48 mg/L 0 005 1 EPA 200 7 06/12/2017 11 01 MHH7131 Manganese (Mn) 0.033 mg/L 0 005 1 EPA 200 7 06/12/2017 11 01 MHH7131 Potassium (K) 172 mg/L 01 1 EPA 200 7 06/12/2017 11 01 MHH7131 Sodium (Na) 431 mg/L b2,b4, 005 1 EPA 200 7 06/12/2017 11 01 MHH7131 Total Hardness (Ca and Mg) 10.7 mg/L 1 EPA 200 7 06/12/2017 11 01 MHH7131 (CaCO3) Zinc (Zn) 0.005 mg/L 0 005 1 EPA 200 7 06/12/2017 11 01 MHH7131 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 Arsenic (As) < 1 ug/L 1 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 Cadmium (Cd) < 1 ug/L 1 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 Chromium (Cr) < 1 ug/L 1 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 Copper (Cu) < 1 ug/L 1 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 Lead (Pb) <1 ug/L 1 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 Molybdenum (Mo) <1 ug/L 1 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 Nickel (Ni) <1 ug/L 1 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 Selenium (Se) <1 ug/L 1 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 Thallium (TI) Low Level < 0.2 ug/L 0 2 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 Certificate of Laboratory Analysis Page 5 of 36 This report shall not be reproduced, except In full Order # J17060014 Site S-16 Collection Date 31 -May -17 12 45 PM Sample #: Matrix 2017018245 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 730 SI Units 1 Field Work Temperature 200 °C 1 Field Work Specific Conductance 669 us/cm 1 Field Work Turbidity 35.4 NTU 1 Field Work Flow NM cfS 1 Field Work TOTAL DISSOLVED SOLIDS TDS 59 mg/L 25 1 SM2540C 06/05/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS 34 mg/L 5 1 SM2540D 06/02/2017 10 00 MGIGANT Certificate of Laboratory Analysis Page 6 of 36 This report shall not be reproduced, except in full Order # J17060014 Site FIELD BLANK Sample #: 2017018246 Collection Date 31 -May -17 1 50 PM Matrix NPDES Analyte Result Units Qualifiers RDL DF MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Method Analysis Date/Time Analyst Vendor Method V_SHEALY Certificate of Laboratory Analysis Page 7 of 36 This report shall not be reproduced, except in full. Order # J17060014 Site Trip Blank Sample #: 2017018247 Collection Date 31 -May -17 1 50 PM Matrix NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY Qualifiers: B2 Target analyte was detected in Method Blank(s) at a concentration greater than 1/2 the reporting limit but less than the reporting limit Analyte concentration in sample is valid and may be used for compliance purposes 134 Continuing Calibration Blank (CCB) is greater than Reporting Limit (RL) Certificate of Laboratory Analysis Page 8 of 36 This report shall not be reproduced, except In full Order # J17060014 Level II QC Summary Q17060122 1664—SPE OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Blank # 1 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Oil and Grease 00923 mg/L 1 5 < 1/2 RDL LCS # 1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Oil and Grease 335 mg/L 1 357207 937 78 114 MS #1 Parent Sample 717040194 -- 2017011694 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Oil and Grease 31 2 mg/L 1 330333 93 78 114 Certificate of Laboratory Analysis Page 9 of 36 Th/s report shall not be reproduced, except in full Order # J17060014 Level II QC Summary Q17060147 C_NO2NO3 NITRITE + NITRATE (COLORLMETRIC) Blank #I Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 00021 00021 mg-N/L 1 001 < 1/2 RDL (Colorimetric) Blank # 2 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 00026 00026 mg-N/L 1 001 < 1/2 RDL (Colorimetric) Blank # 3 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 00036 00036 mg-N/L 1 001 < 1/2 RDL (Colorimetric) Blank # 4 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 00018 00018 mg-N/L 1 001 < 1/2 RDL (Colorimetric) LCS #1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 299 299 mg-N/L 10 301 992 90 110 (Colorimetric) LCS #2 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 299 299 mg-N/L 10 301 993 90 110 (Colorimetric) LCS # 3 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 297 297 mg-N/L 10 301 988 90 110 (Colorimetric) LCS #4 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 299 299 mg-N/L 10 301 994 90 110 (Colorimetric) MS #1 Parent Sample J17050155 -- 2017015216 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 311 0 311 mg-N/L 1 025 98 90 110 (Colorimetric) MSD #1 Parent Sample J17050155 -- 2017015216 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 312 0 312 mg-N/L 1 025 983 90 110 0 193 (Colorimetric) Certificate of Laboratory Analysis Page 10 of 36 This report shall not be reproduced, except in full Order # J17060014 Level II QC Summary Q17060147 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC) MS #2 Parameter Measured Final Nitrite + Nitrate 0 336 0 336 (Colorimetric) MSD #2 Parameter Measured Final Nitrite + Nitrate 0 324 0 324 (Colorimetric) MS #3 Parameter Measured Final Nitrite + Nitrate 0 245 0 245 (Colorimetric) MSD #3 Parameter Measured Final Nitrite + Nitrate 0 245 0 245 (Colorimetric) MS #4 Parameter Measured Final Nitrite + Nitrate 0 259 0 259 (Colorimetric) MSD #4 Parameter Measured Final Nitrite + Nitrate 0 259 0 259 (Colorimetric) Parent Sample J17050777 -- 2017018040 Units Dil Spike % Recovery LCL UCL Qualifier mg-N/L 1 025 103 90 110 Parent Sample J17050777 -- 2017018040 Units Dil Spike % Recovery LCL UCL RPD Qualifier mg-N/L 1 025 978 90 110 358 Parent Sample J17060014 -- 2017018245 Units Dil Spike % Recovery LCL UCL Qualifier mg-N/L 1 025 96 90 110 Parent Sample J17060014 -- 2017018245 Units Dil Spike % Recovery LCL UCL RPD Qualifier mg-N/L 1 025 96 90 110 00408 - Parent Sample J17050190 -- 2017015339 Units Dil Spike % Recovery LCL UCL Qualifier mg-N/L 1 025 989 90 110 Parent Sample J17050190 -- 2017015339 Units Dil Spike % Recovery LCL UCL RPD Qualifier mg-N/L 1 025 99 90 110 0 116 Certificate of Laboratory Analysis Page 11 of 36 This report shall not be reproduced, except in full Order # J17060014 Level II QC Summary Q17060036 Dionex INORGANIC IONS BY IC Blank # 1 Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Chloride 59 295 Parameter Measured Final Units Dil RDL Relative Concentration Fluoride 522 Qualifier mg/L Chloride 00329 00329 mg/L 1 01 < 1/2 RDL 69 345 mg/L 5 25 Fluoride 00348 00348 mg/L 1 01 < 1/2 RDL Sulfate 00045 00045 mg/L 1 0 1 < 1/2 RDL Spike % Recovery LCL UCL IS #1 Chloride 499 499 mg/L 1 5 997 90 110 Fluoride 503 Parameter Measured Final Units Dil Spike % Recovery LCL UCL 497 Qualifier mg/L Chloride 704 704 mg/L 1 5 100 80 120 Fluoride 509 509 mg/L 1 5 100 80 120 Sulfate 621 621 mg/L 1 5 102 80 120 ISD #1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Chloride 704 704 mg/L 1 5 100 80 120 0 167 Fluoride 51 51 mg/L 1 5 101 80 120 0 329 Sulfate 622 622 mg/L 1 5 102 80 120 0 211 IS #2 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Chloride 587 293 mg/L 5 25 103 80 120 Fluoride 518 259 mg/L 5 25 103 80 120 Sulfate 685 343 mg/L 5 25 102 80 120 ISD # 2 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Chloride 59 295 mg/L 5 25 104 80 120 0 583 Fluoride 522 261 mg/L 5 25 103 80 120 0 719 Sulfate 69 345 mg/L 5 25 103 80 120 0 952 LCS #1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Chloride 499 499 mg/L 1 5 997 90 110 Fluoride 503 503 mg/L 1 5 101 90 110 Sulfate 497 497 mg/L 1 5 994 90 110 Certificate of Laboratory Analysis Page 12 of 36 This report shall not be reproduced, except In full Order # J17060014 Level II QC Summary Q17060212 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Blank # 1 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Aluminum (AI) 00002 mg/L 1 0 005 < 1/2 RDL Barium (Ba) 0000242 0000242 mg/L 1 0 005 < 1/2 RDL Boron (B) -000943 -000943 mg/L 1 005 < 1/2 RDL Calcium (Ca) 000329 000329 mg/L 1 001 < 1/2 RDL Iron (Fe) 000192 000192 mg/L 1 001 < 1/2 RDL Magnesium (Mg) 00012 00012 mg/L 1 0 005 < 1/2 RDL Manganese (Mn) 000046 000046 mg/L 1 0 005 < 1/2 RDL Potassium (K) -00104 -00104 mg/L 1 01 < 1/2 RDL Sodium (Na) 00274 00274 mg/L 1 005 > 1/2 RDL b2,b4 Zinc (Zn) 000096 000096 mg/L 1 0 005 < 1/2 RDL LCS #1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Aluminum (Al) 479 mg/L 1 5 958 85 115 Barium (Ba) 49 49 mg/L 1 5 979 85 115 Boron (B) 489 489 mg/L 1 5 978 85 115 Calcium (Ca) 489 489 mg/L 1 5 978 85 115 Iron (Fe) 49 49 mg/L 1 5 979 85 115 Magnesium (Mg) 487 487 mg/L 1 5 973 85 115 Manganese (Mn) 49 49 mg/L 1 5 98 85 115 Potassium (K) 482 482 mg/L 1 5 964 85 115 Sodium (Na) 483 483 mg/L 1 5 965 85 115 Zinc (Zn) 49 49 mg/L 1 5 98 85 115 MS #I Parent Sample J17060014 -- 2017018245 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Aluminum (AI) 564 282 mg/L 1 25 103 70 130 Barium (Ba) 503 503 mg/L 1 5 100 70 130 Boron (B) 501 501 mg/L 1 5 100 70 130 Calcium (Ca) 683 683 mg/L 1 5 998 70 130 Iron (Fe) 649 649 mg/L 1 5 101 70 130 Magnesium (Mg) 642 642 mg/L 1 5 988 70 130 Manganese (Mn) 504 504 mg/L 1 5 100 70 130 Potassium (K) 67 67 mg/L 1 5 995 70 130 Sodium (Na) 916 916 mg/L 1 5 971 70 130 Zinc (Zn) 5 5 mg/L 1 5 999 70 130 MSD #1 Parent Sample J17060014 -- 2017018245 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Aluminum (AI) 532 266 mg/L 1 25 968 70 130 64 Certificate of Laboratory Analysis This report shall not be reproduced, except in full Order # J17060014 Level II QC Summary Q17060212 ICP_TRM TOTAL RECOVERABLE METALS BY ICP MSD #1 Parameter Measured Final Units Dil Spike Barium (Ba) 475 475 mg/L 1 5 Boron (B) 464 464 mg/L 1 5 Calcium (Ca) 651 651 mg/L 1 5 Iron (Fe) 62 62 mg/L 1 5 Magnesium (Mg) 616 616 mg/L 1 5 Manganese (Mn) 476 476 mg/L 1 5 Potassium (K) 64 64 mg/L 1 5 Sodium (Na) 882 882 mg/L 1 5 Zinc (Zn) 472 472 mg/L 1 5 Qualifiers: Page 13 of 36 Parent Sample J17060014 -- 2017018245 % Recovery LCL UCL RPD Qualifier 945 70 130 584 929 70 130 766 934 70 130 663 953 70 130 595 937 70 130 532 945 70 130 575 936 70 130 615 903 70 130 73 943 70 130 575 B2 Target analyte was detected in Method Blank(s) at a concentration greater than 1/z the reporting limit but less than the reporting limit Analyte concentration in sample is valid and maybe used for compliance purposes 134 Continuing Calibration Blank (CCB) is greater than Reporting Limit (RL) Certificate of Laboratory Analysis Page 14 of 36 This report shall not be reproduced, except in full. Order # J17060014 Level II QC Summary Q17060220 IMS_TRM TOTAL RECOVERABLE METALS BY ICP -MS Blank # 1 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Antimony (Sb) -0033 -0033 ug/L 1 1 < 1/2 RDL Arsenic (As) 0 016 0 016 ug/L 1 1 < 1/2 RDL Cadmium (Cd) 0 013 0 013 ug/L 1 1 < 1/2 RDL Chromium (Cr) 0 031 0 031 ug/L 1 1 < 1/2 RDL Copper (Cu) -0028 -0028 ug/L 1 1 < 1/2 RDL Lead (Pb) 0 012 0 012 ug/L 1 1 < 1/2 RDL Molybdenum (Mo) 0 006 0 006 ug/L 1 1 < 1/2 RDL Nickel (Ni) -0029 -0029 ug/L 1 1 < 1/2 RDL Selenium (Se) 0 014 0 014 ug/L 1 1 < 1/2 RDL Thallium (TI) Low Level -0007 -0007 ug/L 1 02 < 1/2 RDL LCS #1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Antimony (Sb) 489 489 ug/L 1 50 979 85 115 Arsenic (As) 494 494 ug/L 1 50 988 85 115 Cadmium (Cd) 502 502 ug/L 1 50 100 85 115 Chromium (Cr) 509 509 ug/L 1 50 102 85 115 Copper (Cu) 501 501 ug/L 1 50 100 85 115 Lead (Pb) 49 4 49 4 ug/L 1 50 988 85 115 Molybdenum (Mo) 504 504 ug/L 1 50 101 85 115 Nickel (Ni) 497 497 ug/L 1 50 994 85 115 Selenium (Se) 488 488 ug/L 1 50 977 85 115 Thallium (TI) Low Level 48 9 489 ug/L 1 50 979 85 115 MS #1 Parent Sample J17050090 -- 2017014781 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Antimony (Sb) 505 506 ug/L 1 500 101 70 130 Arsenic (As) 51 4 514 ug/L 1 500 102 70 130 Cadmium (Cd) 485 485 ug/L 1 500 97 70 130 Chromium (Cr) 489 489 ug/L 1 500 975 70 130 Copper (Cu) 491 491 ug/L 1 500 978 70 130 Lead (Pb) 50 500 ug/L 1 500 999 70 130 Molybdenum (Mo) 253 2530 ug/L 1 2500 933 70 130 Nickel (Ni) 499 499 ug/L 1 500 98 9 70 130 Selenium (Se) 154 1540 ug/L 1 500 120 70 130 Thallium (TI) Low Level 461 461 ug/L 1 500 922 70 130 MSD #1 Parent Sample J17050090 -- 2017014781 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Antimony (Sb) 48 480 ug/L 1 500 959 70 130 526 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # A 7060014 Level II QC Summary Q17060220 IMS_TRM TOTAL RECOVERABLE METALS BY ICP -MS MSD #1 Parameter Measured Final Units Dil Spike Arsenic (As) 489 489 ug/L 1 500 Cadmium (Cd) 461 461 ug/L 1 500 Chromium (Cr) 464 464 ug/L 1 500 Copper (Cu) 464 464 ug/L 1 500 Lead (Pb) 473 473 ug/L 1 500 Molybdenum (Mo) 244 2440 ug/L 1 2500 Nickel (Ni) 473 473 ug/L 1 500 Selenium (Se) 146 1460 ug/L 1 500 Thallium (TI) Low Level 445 445 ug/L 1 500 Page 15 of 36 Parent Sample J17050090 -- 2017014781 % Recovery LCL UCL RPD Qualifier 975 70 130 496 921 70 130 518 925 70 130 527 925 70 130 557 946 70 130 544 897 70 130 391 937 70 130 539 104 70 130 141 89 70 130 352 Certificate of Laboratory Analysis Page 16 of 36 This report shall not be reproduced, except in full Order # J17060014 Level II QC Summary Q17060061 TDS TOTAL DISSOLVED SOLIDS Blank #I Dil RDL Parameter Measured Final TDS 0 0 Blank # 2 Units Dil Parameter Measured Final TDS 0 0 Duplicate # 1 Parameter Measured Final TDS 140 140 Duplicate # 2 RPD Qualifier Parameter Measured Final TDS 53 53 Duplicate # 3 Parent Sample Parameter Measured Final TDS 140 140 LCS #1 1 Parameter Measured Final TDS 103 103 Units Dil RDL Relative Concentration Qualifier mg/L 1 25 < 1/2 RDL Units Dil RDL Relative Concentration Qualifier mg/L 1 25 < 1/2 RDL Parent Sample J17050329 -- 2017015953 Units Dil RPD Qualifier mg/L 1 0 717 Parent Sample J17050329 -- 2017015954 Units Dil RPD Qualifier mg/L 1 784 Parent Sample J17050329 -- 2017015955 Units Dil RPD Qualifier mg/L 1 1 42 Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 100 103 90 110 Certificate of Laboratory Analysis Page 17 of 36 This report shall not be reproduced, except in full Order # J17060014 Level II QC Summary Q17060035 TSS TOTAL SUSPENDED SOLIDS Blank # 1 Parameter Measured Final TSS 0 0 Blank # 2 Dil RDL Parameter Measured Final TSS 0 0 Duplicate # 1 Units Dil Parameter Measured Final TSS 46 46 Duplicate # 2 Parameter Measured Final TSS 28 28 Duplicate # 3 RPD Qualifier Parameter Measured Final TSS 28 28 LCS #I Parameter Measured Final TSS 472 472 Units Dil RDL Relative Concentration Qualifier mg/L 1 5 < 1/2 RDL Units Dil RDL Relative Concentration Qualifier mg/L 1 5 < 1/2 RDL Parent Sample J17040222 -- 2017011810 Units Dil RPD Qualifier mg/L 1 833 Parent Sample J17050779 -- 2017018053 Units Dil RPD Qualifier mg/L 1 0 Parent Sample J17050779 - 2017018054 Units DO RPD Qualifier mg/L 1 194 Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 50 944 90 110 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersvllle, NC 28078 Attention: Mary Ann Ogle Project Name Belews Creek NPDES AOW Project Number -J17060014 Lot Number•SF02014 Date Completed 06/11/2017 Grant Wilton Project Manager m LABORATORY Fm ACCREDITATION F, BUREAU .a . ,e Lam` .AC'CREDITEt° Zr UVt!IA This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc The following non -paginated documents are considered part of this report Chain of Custody Record and Sample Receipt Checklist Shealy Environmental Services, Inc Page 1 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No 32010 NELAC No E87653 NC DENR No 329 NC Field Parameters No 5639 Case Narrative Duke Energy Lot Number SF02014 Project Name. Belews Creek NPDES AOW Project Number J17060014 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative The sample receiving date is documented in the header information associated with each sample All results listed in this report relate only to the samples that are contained within this report Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies Any exceptions to the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or discussed below If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page Low Level Mercury Analysis - Method 1631 E Sample -001 The sample, MS and MSD were run straight and twice at an 8x dilution The maxtrix spike was recovered below the control limit in each of the three runs A blank was analyzed between the sample, the MS and MSD for the second 8X dilution run Shealy Environmental Services, Inc Page 2 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number SF02014 Project Name Belews Creek NPDES AOW Project Number J17060014 Sample Number Sample ID Matrix Date Sampled Date Received 001 2017018245 Aqueous 05/31/2017 1245 06/02/2017 002 2017018246 Aqueous 05/31/20171350 06/02/2017 003 2017018247 Aqueous 05/31/20171350 06/02/2017 (3 samples) Shealy Environmental Services, Inc Page 3 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number SF02014 Project Name Belews Creek NPDES AOW Project Number J17060014 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2017018245 Aqueous Alkalinity SM 23206- 17 mg/L 5 001 2017018245 Aqueous Bicarbonate Alkalinity SM 23206- 17 mg/L 5 001 2017018245 Aqueous Mercury (CVAFS) 1631E 645 S ng/L 6 (3 detections) Shealy Environmental Services, Inc Page 4 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals Client Duke Energy Laboratory ID SF02014-001 Description 2017018245 Matrix Aqueous Date Sampled 05/31/2017 1245 Project Name Belews Creek NPDES AOW Date Received 06/02/2017 Project Number J17060014 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/06/2017 1041 BWS 43560 1 (Bicarbonate ) SM 2320B-2011 1 06/06/2017 1041 BWS 1 (Carbonate AI) SM 23208-2011 1 06/06/2017 1041 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and : MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W° S = MS/MSD failure Shealy Environmental Services, Inc Page 5 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 17 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 17 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and : MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W° S = MS/MSD failure Shealy Environmental Services, Inc Page 5 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SF02014-001 Description 2017018245 Matrix Aqueous Date Sampled 05/31/2017 1245 Project Name Belews Creek NPDES AOW Date Received 06/02/2017 Project Number J17060014 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 1631 E 8 06/08/2017 1950 SLS 06/02/2017 2324 43419 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 645 S 400 ng/L 2 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCSILCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 6 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SF02014-002 Description 2017018246 Matrix Aqueous Date Sampled 05/31/2017 1350 Project Name Belews Creek NPDES AOW Date Received 06/02/2017 Project Number J17060014 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 06/06/2017 2207 SLS 06/02/2017 2324 43419 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E ND 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCSILCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 7 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SF02014-003 Description 2017018247 Matrix Aqueous Date Sampled 05/31/2017 1350 Project Name Belews Creek NPDES AOW Date Received 06/02/2017 Project Number J17060014 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 06/06/2017 2211 SLS 06/02/2017 2324 43419 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E ND 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a 'W" S = MS/MSD failure Shealy Environmental Services, Inc Page 8 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com QC Summary Shealy Environmental Services, Inc QC Data for Lot Number SF02014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals - MB Sample ID SQ43560-001 Matrix Aqueous Batch 43560 Analvtical Method SM 2320B-2011 Parameter Result Q DO PQL Units Analysis Date Alkalinity ND 1 10 mg/L 06/06/2017 0917 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a °W" Note Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number SF02014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Sample ID SQ43560-002 Batch 43560 Analytical Method SM 2320B-2011 Inorganic non-metals - LCS Matrix Aqueous Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q DO % Rec Limit Analysis Date Alkalinity 100 98 1 98 90-110 06/06/2017 0924 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and a MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a 'W Note Calculations are performed before rounding to avoid round -off errors In calculated results Shealy Environmental Services, Inc QC Data for Lot Number SF02014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) - MB Sample ID SQ43419-001 Matrix Aqueous Batch 43419 Prep Method 1631E Analytical Method 1631E Prep Date 06/02/2017 2324 Parameter Result Q Dil PQL Units Analysis Date Mercury (CVAFS) ND 1 0 500 ng/L 06/06/2017 2055 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note Calculations are performed before rounding to avoid round -off errors In calculated results Shealy Environmental Services, Inc QC Data for Lot Number SF02014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv shealylab com Mercury (CVAFS) - LCS Sample ID SQ43419-002 Matrix Aqueous Batch 43419 Prep Method 1631 E Analvtical Method 1631E Prep Date 06/02/2017 2324 Spike Amount Result % Rec Parameter (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date Mercury (CVAFS) 500 493 1 99 75-125 06/06/2017 2104 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of cntena ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of cnteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a 'W° Note Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number SF02014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) - MS Sample ID SF02014-001MS Matrix Aqueous Batch 43419 Prep Method 1631E Analvtical Method 1631 E Prep Date 06/02/2017 2324 Sample Spike Amount Amount Result % Rec Parameter (ng/L) (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date Mercury (CVAFS) 645 400 338 N 8 68 71-125 06/08/2017 1955 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and> MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a "W" Note Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number SF02014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) - MSD Sample ID SF02014-001MD Matrix Aqueous Batch 43419 Prep Method 1631E Analytical Method 1631E Prep Date 06/02/2017 2324 Sample Spike Amount Amount Result % Rec % RPD Parameter (ng/L) (ng/L) (ng/L) Q DO % Rec % RPD Limit Limit Analysis Date Mercury (CVAFS) 645 400 378 8 78 11 71-125 24 06/08/2017 1959 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a "W" Note Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number SF02014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Chain of Custody and Miscellaneous Documents Shealy Environmental Services, Inc 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. rl a.J,apia3tlasa( a a e o l v v a Y o o r v a a o A 4 w N � fall Ira11.1 •aw •��H'n®�®� � 1 LU p a 846 A „� � ci a o. M 3G1j (LE9L)am O I i J BUJ to AN" ffi ' O _ punauaanq pwtaop ! 6S Wei 1i� Y " ` �9P 7¢WadcuE'm¢ioicq� LL e ; ; woreiasa�n� z ' S 13 �i I �'� � p OM1•$•-� £O6l2�N I r- S d •COs )� as"10 PULP 110 IX — ^ 1i N uI w 0 v f g cn ' <, tin G1 u _ m L it py, a u I�r��€ d Y Y I i I AIN= iY6J \vJryo:., ,dd: q«awas ns —5.0 i k5 �& J_ F W4 JV�.P puwW L Shealy Environmental Services, Inc 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. Slrulf Ices, Inc, Cn� I art Ek�cumc�rltdurnLar hfErK116f-7> 6C'ectiveDam- Mi7 517 Sample Receipt Checklist (SRC) NKpm1 Uulc 03107512011 Client; �4f % Cooler Impct ted byidzte: 'Qi al,10 . Lot;: 5FC3��l Masm5 of receipt: ❑ SESI o Clicnt .1 11"P'S D FedEx ,ET oilier cCU ri°dl/ Yes Q No _ 1. Wel e custody teals preselit an the COulcr?J - Yes ❑ No c� NA,fr1 2, If custody, seal, were prtscut v�cre tlley intact and unbrolteo? pH scrip IT): 0 strip ID: Coolur IU'Oiiginal _ temperriture upon receipl/D.rivcd (corrected) rerltperature upon receipt: ac vc Method: ❑ Temperature Blank 71 Against Battles IR Gun lD;�iR CTun Correction Factor, °C Method of coolant -0 "Wet lee hNb Bluu Ice o Div lee None [.Cr 5 o NA 3. iftemperature ofany coolerexceeded 6_G°t.,writs Project hianagur Notified? P,vf was N061nctl by: hone i email! face-to-face (cirrje one). Nuc N 4. Is the commercial courier's acking slit} attached to this form? I No Q 3. Were proper custody procedures Cretin uished!received) follotiN�ed?No o 6, Were sample IDs listed on the (70C? No tt 7, Wele sample IDs lisl.d on allsample containers? No u S. WAS collection date & lime listed on the C:OC? Nu ❑ 9. Wis collection date & time listed on all sample containers: Yes,d NO 13 10. Did all container label information (ID. date, time) agrcc with the COC? Ycs,el No ❑ 11, Were tests to br performed tilted on the COC? Yc-s o N., El" 12, Did all satttptes 7rrivo in the proper conlhiners for each test and+oi in good condition lirly on, ctc,)? Yes No 0 13 Was Adequate sample volume tradable:' Yes ;t No ❑ 14. Wet a all santpl,.� received within 'A- the holding tints or $hours, Wl11ChCVer bit3e5 tint? tti_ 11'err.: anv samples cnnlainers mis3in_z4_-Naess (circle one) samples Not listed on COC? Yrs ❑ No,- m Yma ® No ❑ NA.LA 16. Wert; babbles present "Pea -size ('/,''or 6mm in diameter) in arty VOA vials? Yes 0 No 0 17 Were all DRO.rmetalsinutrient samples receirvecl Ila pli of< 2u Yes ❑ No ❑ NA 1$, Were all cyanide %amples received It a pH ? 12 and sulfite samples receival at s pi7 > 9? Yes C3 Nu 0 19. Were. -d] applicabic NH_'V1`KN1g2iriiddphenoUBNA (- 0.5m&+L) saniyles free ofiesidual NA� chlorine? Yrs ❑ No ❑ NAA 20, Wti -rc collection reniperatures documeilted un the COC for NC samples9 Yes E No ❑ NA 21 'Were client rcmarksireguests (i.e. requested dilulions, MVNISD dcsipation;, etc,,,) cormctly transcr]bed from the COC inro the comment section in LIMB? Yes ❑ Nur 22. Was the quote number used taken fruni the container labc17 Sample N-escrvation (Matt he completed for any sarrnp]e(s) incorrectly preserved or with limds ace.) sample(s) were received inoorrcctly preserved and were adjimted occotdingly in saris PIC rcc:ei'!ngwith (Ti_SO', HU;, HCI. MOM using SR # Santple(s) ___ _ were reccived with babbles >6 min in diameter. _ 5i mples(s) were received wi lh TFCC > 0.5 ing!L (if V21 is Na) and were adjusted acwrdtn l ' in le sain receivinS with Sudium thip 1fate (Na:SzO.j) Wltli SullcaN ID: SC Drinking Water Project Samples) pH verified to be --a by Date; Sam le[s) _ 1Aere Not received at a rI I of i 2 and Frere dc]_j usted acctrrdin l} usit:- 5l2# Sam ie labels appliLd bl : S,Pt--_. Verircd by• Tale r..17. -2 Comments: Shealy Environmental Services, Inc 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM Duke Lnsm mo"y tsLJsborMory f -'----'-•-•------__ __._.- .... use Duke Energy mwcosema mjv.0dkyTenq 1iorder4 /._' ■trntNPt]es •s«e..atte.rens. We-- Page mw 36 of 36 Analytical Laboratory 17S1eitsewsr«ryas I i/' Gid ee, DISTRIBUTION ORIGINAL Chain or Cussedly a !sear 0"I, of M C. " „ 0.ne0aA By ■Time 7 sAIIKE i►AoOR/IM s■mpN Loo J to LAB. COPY 10 CUEN I I oa a»war i _ �_ l 1 on ap Vkhm NP06RS West, utr rtPDES-AOIM —' SHEALY c'�t""PLCI __ . RCRA �..—.. C S Client I,--. �. -- _ . _ PO 5021013 +ion toga wrq. b U"flaared _ a Business Unit: Preserv■tive eeo. k. Iw to enoa NA P.MK,1O A PAM wa CorHalner Volume ItnLypl 1230 ttMa 250 300 2S0 FIELD MEASUREMENTS {0 goo rr - ComtalnerTe slaw PET PET PEt love Glass � Sample Description or ID Pt Crarlwaw mewnv,ror. rrae�ty Nt. n v y f two a mj! u V_ �1 w W1U■[aMIY L ocalfon Collection nametionD GPS Location 11 tp ? _ i0 �D■tmx Lb 10 O Z + h 4 it w Z `t"i —_� _. _� 2 1 b.G s t e I e 0 0 0 _ 0 � o - S FMid 64nk g / j 2 ! 2 �Trip Blank —_ 117 1 2 ! § TOTAL a 3 t t 0 f t t! Re —..y lin Accepted By. osio T111M '7. G �% : �, u6 @� y -i S 31 1 6O : Requested Turn■roum� TOW1137 -. R- 7m ' hqulm" MY D■seRirlte `AC 1 -til 14 Days Ralinpdeiteo3 _ __ ;Accepted 8y: i. -y+ a Oa1/s SaslAoeked _ D ISealedit_eck Op■IMA all 48 Hr : A CrCu. NII Pb Sb. Se CRC Method TI loo Weft ToW Hardness ? Oltxer As. Cd C ! ELT:ME#iTs by 1Cf_MS i�eseed•TRnry . I I t 11111.0110M111111111.0110MMby ICP jt?y "ted TRU11- AL Co. Be. B. Fe, Mres,e, Mn, K. ka, Zn Plans& copy Tim Hunsux*vf on excel EDD ults – Add Cost WIN Apply s,fi Anal lab cal DUKE Analytical Laboratory Page 11 of 52 *. ' ENERGY Order Number: Project Name Customer Name(s) Customer Address Lab Contact Report Authorized By - (Signature) Program Comments: 13339 Hagers Ferry Road Huntersvllle, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone 980-875-5245 Fax 980-875-4349 Order Summary Report J17050567 ROXBORO- NPDES -AOW Ross Hartfield, Craig Eady, Tim Hunsucker, Kathy Webb, Brandon Russo, Chris Roxboro Steam Station 1700 Dunnaway Road Semora,NC 27343 Mary Ann Ogle Phone 980-875-5274 Mary Ann Ogle Date: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report Data Flags & Calculations - 6/5/2017 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading All results are reported on a dry weight basis unless otherwise noted Subcontracted data Included on the Duke Certificate of Analysis is to be used as information only Certified vendor results can be found in the subcontracted lab final report Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted Data Package: This data package Includes analytical results that are applicable only to the samples described in this narrative An estimation of the uncertainty of measurement for the results In the report is available upon request This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory Please contact the Analytical laboratory with any questions The order of individual sections within this report is as follows Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005 Contact the Analytical Laboratory for definitive information about the certification status of specific methods Analytical lab Sample ID's & Descriptions: Page 2 of 52 Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2017017103 Roxboro 18 -May -17 11 22 AM Kaitlyn Fox S-21 2017017104 Roxboro 18 -May -17 10 15 AM Kaitlyn Fox S-14 2017017105 Roxboro 18 -May -17 12 22 PM Kaitlyn Fox S-09 2017017106 Roxboro 18 -May -17 9 45 AM Kaitlyn Fox S-13 2017017107 Roxboro 18 -May -17 9 45 AM Kaitlyn Fox S-14 Duplicate 2017017108 Roxboro 18 -May -17 2 20 PM Kaitlyn Fox FIELD BLANK 2017017109 Roxboro 18 -May -17 2 20 PM Kaitlyn Fox TRIP BLANK 7 Total Samples Technical Validation Review Checklist: COC and pdf report are In agreement with sample totals 0 Yes ❑ No and analyses (compliance programs and procedures) All Results are less than the laboratory reporting limits ❑ Yes 0 No All laboratory QA/QC requirements are acceptable 0 Yes ❑ No Report Sections Included: Job Summary Report Sample Identification Technical validation of Data Package ❑� Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Analytical lab Page 3 of 52 S6 Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries ❑d Chain of Custody ❑d Electronic Data Deliverable (EDD) Sent Separatel Reviewed By Mary Ann Ogle Date 6/5/2017 Analytical lab Certificate of Laboratory Analysis Page 4 of 52 This report shall not be reproduced, except in full Order # A 7050567 Site S-21 Collection Date 18 -May -17 11 22 AM Sample #: Matrix 2017017103 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L 5 1 EPA 1664B 05/25/2017 08 30 CJELLIO ALKALINITY - (Analysis Performed bV Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 009 mg-N/L 001 1 EPA 353 2 06/03/2017 12 28 JASTOWE INORGANIC IONS BY IC Chloride 30 mg/L 05 5 EPA 300 0 05/22/2017 14 24 BGN9034 Fluoride < 0 5 mg/L 05 5 EPA 300 0 05/22/2017 14 24 BGN9034 Sulfate 150 mg/L 25 25 EPA 300 0 05/22/2017 14 24 BGN9034 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.093 mg/L B2 0 005 1 EPA 200 7 06/02/2017 11 07 MHH7131 Barium (Ba) 0 072 mg/L 0 005 1 EPA 200 7 06/02/2017 11 07 MHH7131 Boron (B) 117 mg/L 005 1 EPA 200 7 06/02/2017 11 07 MHH7131 Calcium (Ca) 63.1 mg/L B2 001 1 EPA 200 7 06/02/2017 11 07 MHH7131 Iron (Fe) 1.84 mg/L 001 1 EPA 200 7 06/02/2017 11 07 MHH7131 Magnesium (Mg) 297 mg/L 0 005 1 EPA 200 7 06/02/2017 11 07 MHH7131 Manganese (Mn) 436 mg/L 0 005 1 EPA 200 7 06/02/2017 11 07 MHH7131 Potassium (K) 1.64 mg/L 01 1 EPA 200 7 06/02/2017 11 07 MHH7131 Sodium (Na) 35.6 mg/L 005 1 EPA 200 7 06/02/2017 11 07 MHH7131 Total Hardness (Ca and Mg) 280 mg/L 019 1 EPA 200 7 06/02/2017 11 07 MHH7131 (CaCO3) Zinc (Zn) < 0.005 mg/L 0 005 1 EPA 200 7 06/02/2017 11 07 MHH7131 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 Arsenic (As) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 Cadmium (Cd) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 Chromium (Cr) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 Copper (Cu) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 Lead (Pb) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 Molybdenum (Mo) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 Nickel (Ni) 145 ug/L 1 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 Selenium (Se) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 Thallium (TI) Low Level < 0.2 ug/L 02 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 Analytical lab Certificate of Laboratory Analysis Page 5 of 52 This report shall not be reproduced, except In full Order # J17060567 Site S-21 Collection Date 18 -May -17 11 22 AM Sample #: Matrix 2017017103 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 646 SI Units 1 Field Work Temperature 15.9 °C 1 Field Work Specific Conductance 675 US/cm 1 Field Work Turbidity 649 NTU 1 Field Work Flow NM cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 450 mg/L 25 1 SM2540C 05/22/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS 7 mg/L 5 1 SM2540D 05/19/2017 10 00 MGIGANT Certificate of Laboratory Analysis Analytical lab y Page 6 of 52 This report shall not be reproduced, except in full Order # J17050667 Site S-14 Collection Date 18 -May -17 10 15 AM Sample #: Matrix 2017017104 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L 5 1 EPA 16646 05/25/2017 08 30 CJELLIO ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colonmetnc) < 0 01 mg-N/L 001 1 EPA 353 2 06/03/2017 12 42 JASTOWE INORGANIC IONS BY IC Chloride 52 mg/L 1 10 EPA 300 0 05/22/2017 13 22 BGN9034 Fluoride < 1 mg/L 1 10 EPA 300 0 05/22/2017 13 22 BGN9034 Sulfate 370 mg/L 10 100 EPA 300 0 05/22/2017 13 22 BGN9034 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.089 mg/L B2 0 005 1 EPA 200 7 06/02/2017 11 20 MHH7131 Barium (Ba) 0.057 mg/L 0 005 1 EPA 200 7 06/02/2017 11 20 MHH7131 Boron (B) 0 500 mg/L 005 1 EPA 200 7 06/02/2017 11 20 MHH7131 Calcium (Ca) 148 mg/L B2 01 10 EPA 200 7 06/02/2017 11 20 MHH7131 Iron (Fe) 1 26 mg/L 001 1 EPA 200 7 06/02/2017 11 20 MHH7131 Magnesium (Mg) 226 mg/L 0 005 1 EPA 200 7 06/02/2017 11 20 MHH7131 Manganese (Mn) 2.42 mg/L 0 005 1 EPA 200 7 06/02/2017 11 20 MHH7131 Potassium (K) 375 mg/L 01 1 EPA 200 7 06/02/2017 11 20 MHH7131 Sodium (Na) 130 mg/L 005 1 EPA 200 7 06/02/2017 11 20 MHH7131 Total Hardness (Ca and Mg) 463 mg/L 019 1 EPA 200 7 06/02/2017 11 20 MHH7131 (CaCO3) Zinc (Zn) < 0 005 mg/L 0 005 1 EPA 200 7 06/02/2017 11 20 MHH7131 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 Arsenic (As) 3.29 ug/L 1 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 Cadmium (Cd) < 1 ug/L 1 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 Chromium (Cr) < 1 ug/L 1 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 Copper (Cu) < 1 ug/L 1 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 Lead (Pb) < 1 ug/L 1 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 Molybdenum (Mo) 11.3 ug/L 1 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 Nickel (Ni) 1.10 ug/L 1 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 Selenium (Se) < 5 ug/L 5 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 Thallium (TI) Low Level < 0 2 ug/L 02 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 Certificate of Laboratory Analysis Analytical lab y Page 7 of 52 This report shall not be reproduced, except /n full Order # A 7050667 Site S-14 Collection Date 18 -May -17 10 15 AM Sample #: Matrix 2017017104 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 6.80 SI Units 1 Field Work Temperature 178 °C 1 Field Work Specific Conductance 860 us/cm 1 Field Work Turbidity 267 NTU 1 Field Work Flow 00400 cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 660 mg/L 25 1 SM2540C 05/22/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/19/2017 10 00 MGIGANT Certificate of Laboratory Analysis This report shall not be reproduced, except in full Order # A7050667 Site S-09 Collection Date 18 -May -17 12 22 PM Analyte Result Units Qualifiers RDL OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION EPA 1664B Oil and Grease < 5 mg/L 5 ALKALINITY - (Analysis Performed by Shealy Labs) 1 Vendor Parameter Complete JASTOWE 1 NITRITE + NITRATE (COLORIMETRIC) 05/22/2017 14 57 BGN9034 Nitrite + Nitrate (Colorimetric) 0.01 mg -NIL 001 INORGANIC IONS BY IC EPA 300 0 05/22/2017 14 57 BGN9034 Chloride 3.3 mg/L 01 Fluoride 0.13 mg/L 01 Sulfate 48 mg/L 2 MERCURY IN WATER - (Analysis Performed by Shealy Labs) 06/02/2017 11 25 Vendor Parameter Complete EPA 200 7 06/02/2017 11 25 TOTAL RECOVERABLE METALS BY ICP 1 EPA 200 7 Aluminum (AI) 0.526 mg/L B2 0 005 Barium (Ba) 0.037 mg/L 0 005 Boron (B) 126 mg/L 005 Calcium (Ca) 18.8 mg/L B2 001 Iron (Fe) 1.26 mg/L. 001 Magnesium (Mg) 735 mg/L. 0 005 Manganese (Mn) 0.998 mg/L 0 005 Potassium (K) 2.55 mg/L 01 Sodium (Na) 9.44 mg/L 005 Total Hardness (Ca and Mg) 77.3 mg/L 019 05/31/2017 13 14 CWSPEN3 (CaCO3) EPA 200 8 Zinc (Zn) < 0.005 mg/L 0 005 TOTAL RECOVERABLE METALS BY ICP -MS CWSPEN3 1 Antimony (Sb) < 1 ug/L 1 Arsenic (As) 102 ug/L 1 Cadmium (Cd) e 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Copper (Cu) 1 36 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 458 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 02 Sample #: 2017017105 Matrix NPDES Analytical lab Page 8 of 52 DF Method Analysis Date/Time Analyst 1 EPA 1664B 05/25/2017 08 30 CJELLIO Vendor Method V_SHEALY 1 EPA 353 2 06/03/2017 12 44 JASTOWE 1 EPA 300 0 05/22/2017 14 57 BGN9034 1 EPA 300 0 05/22/2017 14 57 BGN9034 20 EPA 300 0 05/22/2017 14 57 BGN9034 Vendor Method V_SHEALY 1 EPA 200 7 06/02/2017 11 25 MHH7131 1 EPA 200 7 06/02/2017 11 25 MHH7131 1 EPA 200 7 06/02/2017 11 25 MHH7131 1 EPA 200 7 06/02/2017 11 25 MHH7131 1 EPA 200 7 06/02/2017 1125 MHH7131 1 EPA 200 7 06/02/2017 11 25 MHH7131 1 EPA 200 7 06/02/2017 11 25 MHH7131 1 EPA 200 7 06/02/2017 11 25 MHH7131 1 EPA 200 7 06/02/2017 11 25 MHH7131 1 EPA 200 7 06/02/2017 11 25 MHH7131 1 EPA 200 7 06/02/2017 11 25 MHH7131 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 Certificate of Laboratory Analysis Analytical lab y Page 9 of 52 This report shall not be reproduced, except in full Order # J17050567 Site S-09 Collection Date 18 -May -17 12 22 PM Sample #: Matrix 2017017105 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 710 SI Units 1 Field Work Temperature 29.0 °C 1 Field Work Specific Conductance 282 us/cm 1 Field Work Turbidity 140 NTU 1 Field Work Flow NM cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 140 mg/L 25 1 SM2540C 05/22/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS 8 mg/L 5 1 SM2540D 05/19/2017 10 00 MGIGANT Analytical lab Certificate of Laboratory Analysis Page 10 of 52 This report shall not be reproduced, except in full Order # J17050567 Site S-13 Sample #: 2017017106 Collection Date 18 -May -17 9 45 AM Matrix NPDES Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete EPA 353 2 06/03/2017 12 45 NITRITE + NITRATE (COLORIMETRIC) 5 EPA 300 0 Nitrite + Nitrate (Colorimetnc) 002 mg-N/L 001 INORGANIC IONS BY IC BGN9034 25 EPA 300 0 Chloride 69 mg/L 05 Fluoride < 0 5 mg/L 05 Sulfate 75 mg/L 25 MERCURY IN WATER - (Analysis Performed by Shealy Labs) 1 Vendor Parameter Complete MHH7131 1 TOTAL RECOVERABLE METALS BY ICP 06/02/2017 11 29 MHH7131 Aluminum (AI) 0.112 mg/L B2 0 005 Barium (Ba) 0.039 mg/L 0 005 Boron (B) 0 662 mg/L 005 Calcium (Ca) 298 mg/L B2 001 Iron (Fe) 0 801 mg/L 001 Magnesium (Mg) 122 mg/L 0 005 Manganese (Mn) 0 423 mg/L 0 005 Potassium (K) 316 mg/L 01 Sodium (Na) 109 mg/L 005 Total Hardness (Ca and Mg) 125 mg/L 019 1 EPA 200 8 (CaCO3) CWSPEN3 Zinc (Zn) 0 007 mg/L 0 005 TOTAL RECOVERABLE METALS BY ICP -MS EPA 200 8 05/31/2017 13 22 Antimony (Sb) < 1 ug/L 1 Arsenic (As) 1.90 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Copper (Cu) 270 ug/L 1 Lead (Pb) <1 ug/L 1 Molybdenum (Mo) 601 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0 2 ug/L 02 DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353 2 06/03/2017 12 45 JASTOWE 5 EPA 300 0 05/22/2017 13 53 BGN9034 5 EPA 300 0 05/22/2017 13 53 BGN9034 25 EPA 300 0 05/22/2017 13 53 BGN9034 Vendor Method V_SHEALY 1 EPA 200 7 06/02/2017 11 29 MHH7131 1 EPA 200 7 06/02/2017 11 29 MHH7131 1 EPA 200 7 06/02/2017 11 29 MHH7131 1 EPA 200 7 06/02/2017 11 29 MHH7131 1 EPA 200 7 06/02/2017 11 29 MHH7131 1 EPA 200 7 06/02/2017 11 29 MHH7131 1 EPA 200 7 06/02/2017 11 29 MHH7131 1 EPA 200 7 06/02/2017 11 29 MHH7131 1 EPA 200 7 06/02/2017 11 29 MHH7131 1 EPA 200 7 06/02/2017 11 29 MHH7131 1 EPA 200 7 06/02/2017 11 29 MHH7131 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full Order # J17050667 Site S-13 Collection Date 18 -May -17 9 45 AM Analyte Result Units Qualifiers RDL Field Parameters (certification not covered under DPAL certification) pH 7.39 SI Units Temperature 21.2 °C Specific Conductance 302 us/cm Turbidity 512 NTU Flow NM cis TOTAL DISSOLVED SOLIDS TDS 200 mg/L 25 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Sample #: 2017017106 Matrix NPDES Analytical lab Page 11 of 52 DF Method Analysis Date/Time Analyst 1 Field Work 1 Field Work 1 Field Work 1 Field Work 1 Field Work 1 SM2540C 05/22/2017 15 00 MGIGANT 1 SM2540D 05/19/2017 10 00 MGIGANT Analytical lab Certificate of Laboratory Analysis Page 12 of 52 This report shall not be reproduced, except in full Order # J17060667 Site S-14 Duplicate Collection Date 18 -May -17 9 45 AM Sample #: Matrix 2017017107 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Daterrime Analyst OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L 5 1 EPA 1664B 05/25/2017 08 30 CJELLIO ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colonmetnc) < 0.01 mg-N/L 001 1 EPA 353 2 06/03/2017 12 46 JASTOWE INORGANIC IONS BY IC Chloride 53 mg/L 1 10 EPA 300 0 05/22/2017 14 08 BGN9034 Fluoride < 1 mg/L 1 10 EPA 300 0 05/22/2017 14 08 BGN9034 Sulfate 380 mg/L 10 100 EPA 300 0 05/22/2017 14 08 BGN9034 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0 085 mg/L B2 0 005 1 EPA 200 7 06/02/2017 11 33 MHH7131 Barium (Ba) 0 057 mg/L 0 005 1 EPA 200 7 06/02/2017 11 33 MHH7131 Boron (B) 0.500 mg/L 005 1 EPA 200 7 06/02/2017 11 33 MHH7131 Calcium (Ca) 148 mg/L B2 01 10 EPA 200 7 06/02/2017 11 33 MHH7131 Iron (Fe) 1 26 mg/L 001 1 EPA 200 7 06/02/2017 11 33 MHH7131 Magnesium (Mg) 228 mg/L 0 005 1 EPA 200 7 06/02/2017 11 33 MHH7131 Manganese (Mn) 243 mg/L 0 005 1 EPA 200 7 06/02/2017 11 33 MHH7131 Potassium (K) 380 mg/L 01 1 EPA 200 7 06/02/2017 11 33 MHH7131 Sodium (Na) 13.0 mg/L 005 1 EPA 200 7 06/02/2017 11 33 MHH7131 Total Hardness (Ca and Mg) 463 mg/L 019 1 EPA 200 7 06/02/2017 11 33 MHH7131 (CaCO3) Zinc (Zn) < 0.005 mg/L 0 005 1 EPA 200 7 06/02/2017 11 33 MHH7131 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Arsenic (As) 314 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Cadmium (Cd) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Chromium (Cr) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Copper (Cu) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Lead (Pb) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Molybdenum (Mo) 11.3 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Nickel (Ni) 1.07 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Selenium (Se) 1.41 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Thallium (TI) Low Level < 0.2 ug/L 02 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Analytical lab Certificate of Laboratory Analysis Page 13 of 52 This report shall not be reproduced, except in full Order # J17050567 Site S-14 Duplicate Sample #: 2017017107 Collection Date 18 -May -17 9 45 AM Matrix NPDES Analyte Result Units Qualifiers RDL Field Parameters (certification not covered under DPAL certification) pH 6.80 SI Units Temperature 17.8 °C Specific Conductance 860 us/cm Turbidity 267 NTU Flow 0.0400 cis TOTAL DISSOLVED SOLIDS 05/22/2017 15 00 MGIGANT 1 TDS 660 mg/L 25 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 DF Method Analysis Date/Time Analyst 1 Field Work 1 Field Work 1 Field Work 1 Field Work 1 Field Work 1 SM2540C 05/22/2017 15 00 MGIGANT 1 SM2540D 05/19/2017 10 00 MGIGANT Analytical lab Certificate of Laboratory Analysis Page 14 of 52 This report shall not be reproduced, except In full Order # J17060667 Site FIELD BLANK Sample #: 2017017108 Collection Date 18 -May -17 2 20 PM Matrix NPDES Analyte Result Units Qualifiers RDL DF MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Method Analysis Date/Time Analyst Vendor Method V_SHEALY Site TRIP BLANK Collection Date 18 -May -17 2 20 PM Analytical lab Certificate of Laboratory Analysis Page 15 of 52 This report shall not be reproduced, except in full Order # J17050667 Sample #: 2017017109 Matrix NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY Qualifiers: B2 Target analyte was detected in Method Blank(s) at a concentration greater than'/ the reporting limit but less than the reporting limit Analyte concentration in sample is valid and may be used for compliance purposes Analytical lab Certificate of Laboratory Analysis Page 16 of 52 Thls report shall not be reproduced, except in full Order # J17060567 Level II QC Summary Q17050612 1664—SPE OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Blank # 1 Parameter Measured Final Oil and Grease 0 LCS #1 Parameter Measured Final Oil and Grease 344 MS # 1 Parameter Measured Final Oil and Grease 304 Units Dil RDL Relative Concentration Qualifier mg/L 1 5 < 1/2 RDL - Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 369208 933 78 114 - Parent Sample J17040260 -- 2017011969 Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 337866 90 78 114 - Analytical lab Certificate of Laboratory Analysis Page 17 of 52 This report shall not be reproduced, except In full Order # J17050567 Level II QC Summary Q17060054 C NO2NO3 NITRITE + NITRATE (COLORIMETRIC) Blank # 1 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 00048 00048 mg -NIL 1 001 < 1/2 RDL (Colorimetric) Blank # 2 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 00043 00043 mg-N/L 1 001 < 1/2 RDL - (Colorimetric) Blank # 3 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 00046 00046 mg-N/L 1 001 < 1/2 RDL (Colorimetric) Blank # 4 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 0 0 mg-N/L 1 001 < 1/2 RDL (Colorimetric) Blank # 5 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate -00002 -00002 mg-N/L 1 001 < 1/2 RDL (Colorimetric) LCS # 1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 295 295 mg-N/L 10 301 981 90 110 (Colorimetric) LCS # 2 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 292 292 mg-N/L 10 301 971 90 110 - (Colorimetric) LCS # 3 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 029 2 9 mg-N/L 10 301 965 90 110 - (Colorimetric) LCS # 4 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 291 2 91 mg-N/L 10 301 967 90 110 - (Colorimetric) LCS #5 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 289 2 9 mg-N/L 10 301 962 90 110 - (Colorimetric) Certificate of Laboratory Analysis Analytical lab y Page 18 of 52 Thls report shall not be reproduced, except In full Order # J17050667 Level II QC Summary Q17060054 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC) MS #I Parent Sample J17040263 -- 2017011984 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 261 0 261 mg-N/L 1 025 964 90 110 - (Colorimetric) MSD #1 Parent Sample J17040263 -- 2017011984 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 261 0 261 mg-N/L 1 025 964 90 110 00767 - (Colorimetric) MS #2 Parent Sample J17050035 -- 2017014449 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 417 0 417 mg-N/L 1 025 98 90 110 - (Colorimetric) MSD #2 Parent Sample J17050035 -- 2017014449 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 412 0 412 mg-N/L 1 025 963 90 110 1 04 (Colorimetric) MS #3 Parent Sample J17050232 -- 2017015526 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 407 0 407 mg-N/L 1 025 962 90 110 - (Colorimetric) MSD #3 Parent Sample J17050232 -- 2017015526 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 414 0 414 mg-N/L 1 025 99 90 110 1 73 - (Colorimetric) MS #4 Parent Sample J17050576 -- 2017017130 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 254 0 254 mg-N/L 1 025 943 90 110 - (Colorimetric) MSD #4 Parent Sample J17050576 -- 2017017130 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 255 0 255 mg-N/L 1 025 946 90 110 0 314 - (Colorimetric) MS #5 Parent Sample J17050694 -- 2017017659 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 249 0 249 mg-N/L 1 025 966 90, 110 (Colorimetric) MSD #5 Parent Sample J17050694 -- 2017017659 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 247 0 247 mg-N/L 1 025 959 90 110 0 725 - (Colorimetric) Analytical lab Certificate of Laboratory Analysis Page 19 of 52 This report shall not be reproduced, except in full Order # J17050567 Level II QC Summary Q17050522 Dionex INORGANIC IONS BY IC Blank # 1 Parameter Measured Final Units Dil Spike Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Chloride 0 039 0 039 mg/L 1 01 < 1/2 RDL - Fluoride 00431 00431 mg/L 1 01 < 1/2 RDL - Sulfate 00061 00061 mg/L 1 01 < 1/2 RDL Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Chloride 548 274 mg/L 50 250 964 80 120 Fluoride 482 241 mg/L 50 250 954 80 120 Sulfate 913 457 mg/L 50 250 948 80 120 ISD # 1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Chloride 552 276 mg/L 50 250 972 80 120 0 864 - Fluoride 484 242 mg/L 50 250 959 80 120 0 523 - Sulfate 918 459 mg/L 50 250 957 80 120 0 943 LCS #1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Chloride 468 468 mg/L 1 5 93 5 90 110 Fluoride 469 469 mg/L 1 5 937 90 110 - Sulfate 469 469 mg/L 1 5 939 90 110 - MS #I Parent Sample J17040141 -- 2017011488 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Chloride 548 274 mg/L 50 250 958 80 120 Fluoride 482 241 mg/L 50 250 80 120 Sulfate 913 457 mg/L 50 250 94 8 80 120 MSD #1 Parent Sample J17040141 -- 2017011488 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Chloride 552 276 mg/L 50 250 966 80 120 0 869 Fluoride 484 242 mg/L 50 250 80 120 - Sulfate 918 459 mg/L 50 250 957 80 120 0 943 - Analytical lab Certificate of Laboratory Analysis Page 20 of 52 This report shall not be reproduced, except /n full Order # A 7060567 Level II QC Summary Q17050687 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Blank # 1 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Aluminum (AI) 000715 000715 mg/L 1 0 005 > RDL - Barium (Ba) -0000053 -0000053 mg/L 1 0 005 < 1/2 RDL - Boron (B) -000187 -000187 mg/L 1 005 < 1/2 RDL - Calcium (Ca) 00114 00114 mg/L 1 001 > RDL - Iron (Fe) 000107 000107 mg/L 1 001 < 1/2 RDL - Magnesium (Mg) 0 001 0 001 mg/L 1 0 005 < 1/2 RDL - Manganese (Mn) 0000078 0000078 mg/L 1 0 005 < 1/2 RDL - Potassium (K) -000222 -000222 mg/L 1 01 < 1/2 RDL - Sodium (Na) 00138 00138 mg/L 1 005 < 1/2 RDL - Zinc (Zn) -0000373 -0000373 mg/L 1 0 005 < 1/2 RDL - LCS #1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Aluminum (AI) 485 485 mg/L 1 5 97 85 115 Barium (Ba) 494 494 mg/L 1 5 988 85 115 Boron (B) 494 494 mg/L 1 5 988 85 115 - Calcium (Ca) 497 497 mg/L 1 5 994 85 115 - Iron (Fe) 497 497 mg/L 1 5 993 85 115 - Magnesium (Mg) 495 495 mg/L 1 5 989 85 115 - Manganese (Mn) 496 496 mg/L 1 5 992 85 115 - Potassium (K) 489 489 mg/L 1 5 977 85 115 - Sodium (Na) 488 488 mg/L 1 5 976 85 115 - Zinc (Zn) 5 5 mg/L 1 5 100 85 115 - MS #I Parent Sample J17050567 -- 2017017103 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Aluminum (AI) 501 501 mg/L 1 5 983 70 130 Barium (Ba) 509 509 mg/L 1 5 100 70 130 - Boron (B) 625 625 mg/L 1 5 102 70 130 - Calcium (Ca) 676 676 mg/L 1 5 90 70 130 - Iron (Fe) 671 671 mg/L 1 5 975 70 130 - Magnesium (Mg) 346 346 mg/L 1 5 98 70 130 - Manganese (Mn) 934 934 mg/L 1 5 995 70 130 - Potassium (K) 665 665 mg/L 1 5 100 70 130 - Sodium (Na) 406 406 mg/L 1 5 100 70 130 - Zinc (Zn) 491 491 mg/L 1 5 982 70 130 - MSD #1 Parent Sample J17050567 -- 2017017103 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Aluminum (Al) 471 471 mg/L 1 5 923 70 130 636 - Certificate of Laboratory Analysis This report shall not be reproduced, except in full Order # A 7050567 Level II QC Summary Q17050687 ICP_TRM TOTAL RECOVERABLE METALS BY ICP MSD #1 Parameter Measured Final Units Dil Spike Barium (Ba) 475 475 mg/L 1 5 Boron (B) 595 595 mg/L 1 5 Calcium (Ca) 674 674 mg/L 1 5 Iron (Fe) 64 64 mg/L 1 5 Magnesium (Mg) 344 344 mg/L 1 5 Manganese (Mn) 902 902 mg/L 1 5 Potassium (K) 633 633 mg/L 1 5 Sodium (Na) 404 404 mg/L 1 5 Zinc (Zn) 46 46 mg/L 1 5 Analytical lab Page 21 of 52 Parent Sample J17050567 -- 2017017103 % Recovery LCL UCL RPD Qualifier 937 70 130 689 956 70 130 602 867 70 130 374 91 2 70 130 67 938 70 130 444 93 70 130 675 939 70 130 651 951 70 130 5 92 70 130 648 Analytical lab Certificate of Laboratory Analysis Page 22 of 52 This report shall not be reproduced, except in full Order # J17050667 Level II QC Summary Q17050692 IMS TRM TOTAL RECOVERABLE METALS BY ICP -MS Blank # 1 Parameter Measured Final Units Dd RDL Relative Concentration Qualifier Antimony (Sb) -0007 -0007 ug/L 1 1 < 1/2 RDL Arsenic (As) 0 037 0 037 ug/L 1 1 < 1/2 RDL Cadmium (Cd) 0 014 0 014 ug/L 1 1 < 1/2 RDL - Chromium (Cr) 0 163 0 163 ug/L 1 1 < 1/2 RDL - Copper (Cu) 0 001 0 001 ug/L 1 1 < 1/2 RDL - Lead (Pb) 0 017 0 017 ug/L 1 1 < 1/2 RDL - Molybdenum (Mo) 0 017 0 017 ug/L 1 1 < 1/2 RDL - Nickel (Ni) 025 025 ug/L 1 1 < 1/2 RDL - Selenium (Se) 0 032 0 032 ug/L 1 1 < 1/2 RDL - Thallwm (TI) Low Level 0 016 0 016 ug/L 1 02 < 1/2 RDL - LCS # 1 Parameter Measured Final Units Dd Spike % Recovery LCL UCL Qualifier Antimony (Sb) 474 474 ug/L 1 50 948 85 115 - Arsenic (As) 491 491 ug/L 1 50 982 85 115 - Cadmium (Cd) 492 492 ug/L 1 50 985 85 115 - Chromium (Cr) 481 481 ug/L 1 50 963 85 115 - Copper (Cu) 488 488 ug/L 1 50 977 85 115 - Lead (Pb) 485 485 ug/L 1 50 971 85 115 - Molybdenum (Mo) 488 488 ug/L 1 50 976 85 115 - Nickel (Ni) 492 492 ug/L 1 50 985 85 115 - Selenium (Se) 49 49 ug/L 1 50 993 85 115 - Thallium (TI) Low Level 471 471 ug/L 1 50 942 85 115 - MS #1 Parent Sample J17050567 -- 2017017104 Parameter Measured Final Units Dd Spike % Recovery LCL UCL Qualifier Antimony (Sb) 485 485 ug/L 1 50 967 70 130 - Arsenic (As) 51 9 51 9 ug/L 1 50 972 70 130 - Cadmium (Cd) 476 476 ug/L 1 50 952 70 130 - Chromium (Cr) 479 479 ug/L 1 50 95 70 130 - Copper (Cu) 48 48 ug/L 1 50 946 70 130 - Lead (Pb) 48 48 ug/L 1 50 959 70 130 - Molybdenum (Mo) 60 60 ug/L 1 50 975 70 130 - Nickel (Ni) 496 496 ug/L 1 50 97 70 130 - Selenium (Se) 46 9 469 ug/L 1 50 903 70 130 - Thallium (TI) Low Level 476 476 ug/L 1 50 951 70 130 - MSD #1 Parent Sample J17050567 -- 2017017104 Parameter Measured Final Units Dd Soike % Recovery LCL UCL RPD Qualifier Antimony (Sb) 471 471 ug/L 1 50 938 70 130 3 07 - Certificate of Laboratory Analysis Thls report shall not be reproduced, except /n full Order # A 7050567 Level II QC Summary Q17050692 IMS TRM TOTAL RECOVERABLE METALS BY ICP -MS MSD #1 Parameter Measured Final Units Dd Spike Arsenic (As) 505 505 ug/L 1 50 Cadmium (Cd) 463 463 ug/L 1 50 Chromium (Cr) 467 467 ug/L 1 50 Copper (Cu) 461 461 ug/L 1 50 Lead (Pb) 461 461 ug/L 1 50 Molybdenum (Mo) 58 8 588 ug/L 1 50 Nickel (Ni) 476 476 ug/L 1 50 Selenium (Se) 448 448 ug/L 1 50 Thallium (TI) Low Level 457 45 7 ug/L 1 50 Analytical lab Page 23 of 52 Parent Sample J17050567 -- 2017017104 % Recovery LCL UCL RPD Qualifier 944 70 130 296 926 70 130 275 925 70 130 263 907 70 130 421 921 70 130 401 951 70 130 25 93 70 130 429 862 70 130 468 91 3 70 130 407 - Certificate of Laboratory Analysis Analytical lab y Page 24 of 52 Thls report shall not be reproduced, except In full Order # J17050567 Level II QC Summary Q17050525 TDS TOTAL DISSOLVED SOLIDS Blank # 1 Parameter Measured Final TDS 0 0 Blank # 2 Dil RDL Parameter Measured Final TDS 0 0 Duplicate # 1 Units Dil Parameter Measured Final TDS 17700 17700 Duplicate # 2 Parameter Measured Final TDS 303 303 Duplicate # 3 RPD Qualifier Parameter Measured Final TDS 44 44 LCS # 1 Parameter Measured Final TDS 103 103 Units Dil RDL Relative Concentration Qualifier mg/L 1 25 < 1/2 RDL Units Dil RDL Relative Concentration Qualifier mg/L 1 25 < 1/2 RDL Parent Sample J17040141 -- 2017011490 Units Dil RPD Qualifier mg/L 1 0 113 Parent Sample J17040141 -- 2017011491 Units Dil RPD Qualifier mg/L 1 0 - Parent Sample J17050012 -- 2017014343 Units Dil RPD Qualifier mg/L 1 465 Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 100 103 90 110 Certificate of Laboratory Analysis Analytical lab y Page 25 of 52 This report shall not be reproduced, except ►n full Order # A 7050567 Level II QC Summary Q17050493 TSS TOTAL SUSPENDED SOLIDS Blank # 1 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier TSS 0 0 mg/L 1 5 < 1/2 RDL - LCS #1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier TSS 50 50 mg/L 1 50 100 90 110 - LCSD # 1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier TSS 496 496 mg/L 1 50 992 90 110 0 803 - LCS # 2 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier TSS 504 504 mg/L 1 50 101 90 110 LCSD #2 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier TSS 48 48 mg/L 1 50 96 90 110 488 - LCS # 3 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier TSS 496 496 mg/L 1 50 992 90 110 - LCSD #3 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier TSS 496 496 mg/L 1 50 992 90 110 0 - LCS # 4 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier TSS 484 484 mg/L 1 50 968 90 110 - LCSD # 4 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier TSS 488 488 mg/L 1 50 976 90 110 0 823 - SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersvllle, NC 28078 Attention- Mary Ann Ogle Project Name Roxboro NPDES AOW Project Number.J17050567 Lot Number SE19042 Date Completed 05/23/2017 Grant Wilton Project Manager a LABORATORY z'' o ACCREDITATION BUREAU This report shall not be reproduced, except In Its entirety, without the written approval of Shealy Environmental Services, Inc The following non -paginated documents are considered part of this report Chain of Custody Record and Sample Receipt Checklist Shealy Environmental Services, Inc Page 1 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No 32010 NELAC No E87653 NC DENR No 329 NC Field Parameters No 5639 Case Narrative Duke Energy Lot Number SE19042 Project Name Roxboro NPDES AOW Project Number A 7050567 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative The sample receiving date Is documented in the header information associated with each sample All results listed in this report relate only to the samples that are contained within this report Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies Any exceptions to the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or discussed below If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page Shealy Environmental Services, Inc Page 2 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number SE19042 Project Name Roxboro NPDES AOW Project Number J17050567 Sample Number Sample ID Matrix Date Sampled Date Received 001 2017017103 Aqueous 05/18/2017 1122 05/19/2017 002 2017017104 Aqueous 05/18/2017 1015 05/19/2017 003 2017017105 Aqueous 05/18/20171222 05/19/2017 004 2017017106 Aqueous 05/18/2017 0945 05/19/2017 005 2017017107 Aqueous 05/18/2017 0945 05/19/2017 006 2017017108 Aqueous 05/18/2017 1420 05/19/2017 007 2017017109 Aqueous 05/18/20171420 05/19/2017 (7 samples) Shealy Environmental Services, Inc Page 3 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com (15 detections) Shealy Environmental Services, Inc Page 4 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number SE19042 Project Name Roxboro NPDES AOW Project Number- J17050567 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2017017103 Aqueous Alkalinity SM 23206- 160 mg/L 5 001 2017017103 Aqueous Bicarbonate Alkalinity SM 23206- 160 mg/L 5 001 2017017103 Aqueous Mercury (CVAFS) 1631E 576 ng/L 6 002 2017017104 Aqueous Alkalinity SM 23206- 82 mg/L 7 002 2017017104 Aqueous Bicarbonate Alkalinity SM 232013- 82 mg/L 7 002 2017017104 Aqueous Mercury (CVAFS) 1631E 11.6 ng/L 8 003 2017017105 Aqueous Alkalinity SM 23206- 40 mg/L 9 003 2017017105 Aqueous Bicarbonate Alkalinity SM 23206- 40 mg/L 9 003 2017017105 Aqueous Mercury (CVAFS) 1631E 595 ng/L 10 004 2017017106 Aqueous Alkalinity SM 232013- 62 mg/L 11 004 2017017106 Aqueous Bicarbonate Alkalinity SM 23206- 62 mg/L 11 004 2017017106 Aqueous Mercury (CVAFS) 1631E 1 55 ng/L 12 005 2017017107 Aqueous Alkalinity SM 23206- 81 mg/L 13 005 2017017107 Aqueous Bicarbonate Alkalinity SM 23206- 81 mg/L 13 005 2017017107 Aqueous Mercury (CVAFS) 1631E 11 6 ng/L 14 (15 detections) Shealy Environmental Services, Inc Page 4 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Inorganic non-metals Client Duke Energy Laboratory ID SE19042-001 Description 2017017103 Matrix Aqueous Date Sampled 05/18/2017 1122 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/22/2017 1841 BWS 42563 1 (Bicarbonate) SM 2320B-2011 1 05/22/2017 1841 BWS 1 (Carbonate AI) SM 2320B-2011 1 05/22/2017 1841 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure NO = Not detected at or above the PQL J = Estimated result < PQL and 2t MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable all soil sample analysis are reported on a dry weight basis unless Flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 5 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 160 10 mg/L 1 Bicarbonate Alkalinity SM 23208-20 160 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure NO = Not detected at or above the PQL J = Estimated result < PQL and 2t MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable all soil sample analysis are reported on a dry weight basis unless Flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 5 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SE19042-001 Description 2017017103 Matrix Aqueous Date Sampled 05/18/2017 1122 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 05/20/2017 1706 SLS 05/20/2017 0024 42512 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 576 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCSILCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a W S = MSIMSD failure Shealy Environmental Services, Inc Page 6 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab conn Inorganic non-metals Client Duke Energy Laboratory ID SE19042-002 Description 2017017104 Matrix Aqueous Date Sampled 05/18/2017 1015 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 23208-2011 1 05/22/2017 1846 BWS 42563 1 (Bicarbonate) SM 2320B-2011 1 05/22/2017 1846 BWS 1 (Carbonate AI) SM 2320B-2011 1 05/22/2017 1846 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page 7 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 23208-20 82 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 82 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page 7 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SE19042-002 Description 2017017104 Matrix Aqueous Date Sampled 05/18/2017 1015 Project Name Roxboro NPDES ACW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/20/2017 1719 SLS 05/20/2017 0024 42512 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 11 6 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a W S = MS/MSD failure Shealy Environmental Services, Inc Page 8 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 wvvvv shealylab com Inorganic non-metals Client Duke Energy Laboratory ID SE19042-003 Description 2017017105 Matrix Aqueous Date Sampled 05/18/2017 1222 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/22/2017 1852 BWS 42563 1 (Bicarbonate ) SM 23208-2011 1 05/22/2017 1852 BWS 1 (Carbonate Al) SM 23208-2011 1 05/22/2017 1852 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and 2 MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCSILCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 9 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 40 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 40 10 mg/L 1 Carbonate Alkalinity SM 23208-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and 2 MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCSILCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 9 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Mercury (CVAFS) Client Duke Energy Laboratory ID SE19042-003 Description 2017017105 Matrix Aqueous Date Sampled 05/18/2017 1222 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/20/2017 1723 SLS 05/20/2017 0024 42512 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 595 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and 2 MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a °W' S = MS/MSD failure Shealy Environmental Services, Inc Page 10 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals Client Duke Energy Laboratory ID SE19042-004 Description 2017017106 Matrix Aqueous Date Sampled 05/18/2017 0945 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/22/2017 1857 BWS 42563 1 (Bicarbonate ) SM 2320B-2011 1 05/22/2017 1857 BWS 1 (Carbonate AI) SM 23208-2011 1 05/22/2017 1857 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and 2 MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 11 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 62 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 62 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and 2 MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 11 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SE19042-004 Description 201 701 71 06 Matrix Aqueous Date Sampled 05/18/2017 0945 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 05/20/2017 1728 SLS 05/20/2017 0024 42512 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 1 55 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of critena L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 12 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv shealylab corn Inorganic non-metals Client Duke Energy Laboratory ID SE19042-005 Description 2017017107 Matrix Aqueous Date Sampled 05/18/2017 0945 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/22/2017 1902 BWS 42563 1 (Bicarbonate) SM 2320B-2011 1 05/22/2017 1902 BWS 1 (Carbonate AI) SM 2320B-2011 1 05/22/2017 1902 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a °W' S = MS/MSD failure Shealy Environmental Services, Inc Page 13 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 81 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 81 10 mg/L 1 Carbonate Alkalinity SM 23208-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a °W' S = MS/MSD failure Shealy Environmental Services, Inc Page 13 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Mercury (CVAFS) Client Duke Energy Laboratory ID SE19042-005 Description 2017017107 Matrix Aqueous Date Sampled 05/18/2017 0945 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/20/2017 1741 SLS 05/20/2017 0024 42512 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 11 6 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and a MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a "W" S = MSIMSD failure Shealy Environmental Services, Inc Page 14 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SE19042-006 Description 2017017108 Matrix Aqueous Date Sampled 05/18/2017 1420 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 05/20/2017 1746 SLS 05/20/2017 0024 42512 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E ND 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCSILCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a "W" S = MSIMSD failure Shealy Environmental Services, Inc Page 15 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SE19042-007 Description 2017017109 Matrix Aqueous Date Sampled 05/18/2017 1420 Project Name Roxboro NPDES ACW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 05/20/2017 1750 SLS 05/20/2017 0024 42512 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E ND 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 16 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com QC Summary Shealy Environmental Services, Inc QC Data for Lot Number SE19042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals - MB Sample ID SQ42563-001 Matrix Aqueous Batch 42563 Analytical Method SM 23208-2011 Parameter Result Q DO PQL Units Analysis Date Alkalinity ND 1 10 mg/L 05/22/20171803 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a 'W' Note Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number SE19042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals - LCS Sample ID SQ42563-002 Matrix Aqueous Batch 42563 Analytical Method SM 2320B-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 100 1 100 90-110 05/22/20171809 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and 2 MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a "W" Note Calculations are performed before rounding to avoid round -off errors In calculated results Shealy Environmental Services, Inc QC Data for Lot Number SE19042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv shealylab com Mercury (CVAFS) - MB Sample ID SQ42512-001 Matrix Aqueous Batch 42512 Prep Method 1631 E Analytical Method 1631E Prep Date 05/20/2017 24 Parameter Result Q DII PQL Units Analysis Date Mercury (CVAFS) ND 1 0 500 ng/L 05/20/2017 1657 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a 'W' Note Calculations are performed before rounding to avoid round -off errors In calculated results Shealy Environmental Services, Inc QC Data for Lot Number SE19042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) - LCS Sample ID SQ42512-002 Matrix Aqueous Batch 42512 Prep Method 1631E Analytical Method 1631E Prep Date 05/20/2017 24 Spike Amount Result % Rec Parameter (ng/L) (ng/L) Q DII % Rec Limit Analysis Date Mercury (CVAFS) 500 483 1 97 75-125 05/20/2017 1701 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and> MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number SE19042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) - MS Sample ID SE19042-001MS Matrix Aqueous Batch 42512 Prep Method 1631E Analytical Method 1631E Prep Date 05/20/2017 24 Sample Spike Amount Amount Result % Rec Parameter (ng/L) (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date Mercury (CVAFS) 5.76 500 105 1 95 71-125 05/20/2017 1710 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and MDL + = RPD is out of cntena Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' Note Calculations are performed before rounding to avoid round -off errors In calculated results Shealy Environmental Services, Inc QC Data for Lot Number SE19042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) - MSD Sample ID SE19042-001MD Matrix Aqueous Batch 42512 Prep Method 1631E Analytical Method 1631E Prep Date 05/20/2017 24 Sample Spike Amount Amount Result % Rec % RPD Parameter (ng/L) (ng/L) (ng/L) Q Dil % Rec % RPD Limit Limit Analysis Date Mercury (CVAFS) 576 500 103 1 91 20 71-125 24 05/20/2017 1715 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and> MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note Calculations are performed before rounding to avoid round -off errors In calculated results Shealy Environmental Services, Inc QC Data for Lot Number SE19042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Chain of Custody and Miscellaneous Documents Shealy Environmental Services, Inc 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com o � rn CD m m = CD 0 m o� d CD m (D n o� m cn n co N 00 O 0 X C CD 0 3 mg F18111961111% TOP Honk '-�:1-1i-., L__F.i I -1-f-0 N� 'am { rm 2 at vS 8 :J� jfw CHAIN OF CUSTODY RECORD AND ANALYSIS REOLEST FORM 'a i Duke Ener" akr m+ r AmflSsai u { 1— _ ar t..e+, w.On '.•�•••��_��_- -- - ---� Mum S4w�lil�ii� An®1yflral Lsboroloty s>tiCvdNr407A;{d.raigTa9t ,t3Ss r.,gtei �OPdIr#NSYtaNP0E9 I . 560-1 a""� r� N6 , Pxge_7_ofr3_ � A ZrwnaiCuwatly 1 =+roPl� rlpmw vr,■.a 7m IAr u"a$ I. r i `i er ac_ :019TPt! VJnDN SAMPL9 PROW" = Cs MINA 40IAB. COPY to CLIENT Cu R4M1 no" 1 � � 4 ammilNwr NPT enw NPDF$ ji . kft w u�eenr '�tktpYntir sx� —�untiltrnd � tpo-� p0302101:3 rmmn("Sum) -al I�I��fi�ll�l�i��IF�Ig ON ■ommm i3umieseunk .;� -- pleftrati a r.m, Im Ica am e,w tta _ — .— ncl"Mt0. Korot $E1904'2 C6t7t7�nafVOiY1110 �} 1250 I=M ift �''1 O �'IC/�.741�iEi��1M Contamor" Eh,r per ret p" K; Sample Castout:rmcamp.MnrMropropnttm a+ LL $�j -cgs Dass{,prion or ID natrsnrWCatrar, v b Lry LO 7 aH �01c �t I uyeV'f5pr;r t I.asMtlnnit] CIPS tocsHon CdlrtflontrtEormreca, F18111961111% TOP Honk '-�:1-1i-., L__F.i I -1-f-0 N� 'am { rm 2 at vS 8 :J� jfw !u}rnphdEY7 o.cdi>tna �. { � • f 1 ;>f 'a team% Fbitrx'IuIoMQBV-DOerFP+rr. AenphdByr _ DmMmr/� I - ' Accrpd� Ir: C4,SH[Ime ap to Mum S4w�lil�ii� b�eteder �Q � A 14691 'Other ELM tP/ =F -Mg Ftgest atl TFWi A1, Cd, Cr, OU. Mo, NL Pb.9b, 96 JMC T1 pow lefto row Ram"" €C.PMOMbyICP IDVOV dT MC Al, CO, dl, 0, Fe, Mgr, Mo, Mft7n PISMOcopyTIM WnauAeronOVA COD MOM NOW MOWN NJ �l�. ON ■ommm _ F18111961111% TOP Honk '-�:1-1i-., L__F.i I -1-f-0 N� 'am { rm 2 at vS 8 :J� jfw !u}rnphdEY7 o.cdi>tna �. { � • f 1 ;>f Re4ugoo$W Tu7Mroumd team% Fbitrx'IuIoMQBV-DOerFP+rr. AenphdByr _ DmMmr/� I - ' Accrpd� Ir: C4,SH[Ime ap to 5-51 Q b�eteder �Q � A 14691 'Other ELM tP/ =F -Mg Ftgest atl TFWi A1, Cd, Cr, OU. Mo, NL Pb.9b, 96 JMC T1 pow lefto row Ram"" €C.PMOMbyICP IDVOV dT MC Al, CO, dl, 0, Fe, Mgr, Mo, Mft7n PISMOcopyTIM WnauAeronOVA COD MOM �AUdCostY41tAPPh oc ^cel 1} raw 7a SHEALY ENVIRONMENTAL SERVICES, INC. s�enty Fn.irnrrnenL�l Servfen' [nC atocutaccniFumbcr ME0018C-03 Sainple Receipt Cheeldist (SRC) y / J ' Client: 01jNe /-n6-z10 cooler Inspected byMate: -ams-11 q 'LrSt h: Peke t of I EfratrveDaie 03MT2017 Ex.Fvyt}.:W U3'r17i:U22 Mcans(if receipt: ❑ SES[ Client D UPS o FedEx ❑ Other Yes ❑ 1 No I. Were custody seals present on the cooler? Yes ❑ _ No ❑ NA 2, ]f cttstody seals were present, ►vera they intact and unbroken? pH strip ID. (A strip ifs: Cooler Odto (ttpell tlire ea Deri, ed (corrected) temperature upon rmeipt: C ia C I I � t cis. A+IcthQd: r1 Temperature Flank Against Bottles IR Gun IT]: Ifi Gun Correction Factor: °G Method of cool.3nt; w,t Ica ❑ Blue lce ❑ Dry ice XNone Yes ❑ Na to NA 3. Iftereperalture of any coo erexceeded 6.0'C, was i'rolcct MainagerNotified? PM was, Notified by: phonE I email 1 face -to -fact: (6rele 011e), Yes o No ❑ N 4. Is the ronimereial courier's gacking slip attached to this farm? YcsX No ❑ 5. Were proper custudy procedures (relinquisheMeceived) followed? Yes 9f, No ❑ 6. Wcrc sample IDs listed on the COC? Yes No r37. Were sample IDs listed on all sample containers? ycs'o No ❑ R. Was collection data & time listed art the GOC? Yes No ❑ 9. Wats collection elate R tittle listed on all sawn le containers? Yes No ❑ 10. Did all container label information (ID, date. time) agree with the COC2 YesNo ❑ 11. -Were tests to be performed listed on the COC? Yes/ No ❑ 12. Dist all samples arrive in the proper containers for each test and/or in rood condition (unbroken, lids on, etc.)? Yes No [3 13. Was adequate sem le volume available? ' Yes,4 Na ❑ 14. Were all sam ]es received within 1/7 the holding time or 48 hours, wlkichever comes first? Ycs ❑ t; Yes ❑ No ❑ 1.5. Were any samples containers missing+excess (circle onel samples Not listed on COC? NAe lb. Were bubbles prescnl-"prar-tiizz" ('A"or 6aum in diamater) ut any VOA vials? Yes ❑ No a NAjd 17. Were all DRQlmetaWnutrient samples received at a pH of = 2? Yes ❑ No O TTA 18. Were all cyanide sam les rccci%1cd at a pH > 12 m A sulfide samples received at a pH > 9? Yes [:I Nou 19.1A -ere all applicable NH3+7KNIcyatnide+phenol?RNA (< IT-SmgjL) samples free of residual IA/151 Chlorin''? Yes ❑ No ❑ vA 20. Were collection tem eraturk, documented on the COC for NC srimplea? Y" u Na ❑ Y" r_1 NO 0 NA 21 • XV ere client remarkslrequect<s (i a. requested dilutions, MS.NISD dc5ignatliorts, etc,..) ]1 A correctly transcribed from the COC into the cuinment section in LINTS? Ycs ❑ No z22, Was the quote number used taken from the container label? Sample lr r ervation (Must be compluled for any sample(s) hicoirrectly preserved or with headsmce.) Surnple(s) were received incorrectly preserved xnd were adjtjsted ttecordinoly in sate lc receiving, with _ _ (H2SO_ {, HNO., HCl, NaOH) using SR # Sam k(s) Kexe received %0th btabbicr, h6 mm in diameter. samples(s) were received wilh TRC > 0.5 rugfL (If 421 is No) and were adjusted accordingly in sample receiving xvtth sodium thiosulfatle Na,-S20a with Sbealy ID. SC Drinking Water Project Sample(s) pH verified to be < 2 br Date: -sample(s) were 'ot r ccL`• l_tri a pA of < 2 and were adjusted accordin usitw SRS Sample labels applied by: Vetitted Ley. _ nate: Comments: Shealy Environmental Services, Inc 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com CHAIN OF CUSTODY RECORD AND ANALYSIS KLQLES I i-QRAnalytical lab Page 52 of 52 -V, x -,w, _r" ... A-rm-d-y-fi—vW Lali;;i�ry i Anst ral La U"(WV N 0.11114-974(n) uw 000 sc-- i DISTRIBUTION 0RIGiNAL Duke Enor I---- C� Chak* of CuSW* N C- MT& �Lvwo# I I SAMPLE PROGRAM 11 to L. CZJVl to CLIEN I Anallylicai Lab( 1 ers , Sample Log -1 114 NPOSS OMWI 0 Wolof UST WOES- Plow 3-4 dOC REV DATE 6101201S SHFALY PO 5021013 stion (0,46 urrij Uplilksued tl !Ft"p f*- It too NA lousiness UNC preservative 10004 low" C.'d RELD MEASUREM114-rS i 40 $00 Contilolner Volume (MIL) '11M 1000 M SOO : , Preservative 14 Mass COmill rTYPO M� PET PET Pr' 14 1pp- I U %L a samplef Doscription or ID to CAMP499 On VP10"If L'I �' 0 v) , P� i 96 in -6 1 x E w Canoction Go z ,he Ost OM GPS Location > is r LotablonlD Two i5 Dom an Ip 39 2 2 t I I k lc 0 ef r7 X 0 P-(4 TOTAL L DoloTMO Id By, Data O. uIl y: Lock C�perw*d ft pb, Sbwe (CRC MetheJ) T1 jWw Wi*Q TOW (Awdnv*s 2 2 ToW is ttoquest*4 Tummmund-- -14 Days 7 Days 48 Hr .Cmief - Add, Cost WN ApptY