NC0026123_Lab Data_20230504

® Laboratories LLc
a member of The GEL Group INC
May 19, 2023
Stephanie Zorio
NCDENR
1641 Mail Service Center
Raleigh, North Carolina 27607
Re: Biosolids Sampling
Work Order: 621012
Dear Stephanie Zorio:
PO Box 30712 Charleston_ SC 29417
2040 Savage Road Chad "on. 8C 29407
P 843.556.8171
F 843.766.1178
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on May 05, 2023. This original data report has been prepared and reviewed in accordance
with GEL's standard operating procedures.
The samples were delivered with proper chain of custody documentation and signatures. All sample containers
arrived without any visible signs of tampering or breakage. There are no additional comments concerning sample
receipt.
Test results for NELAP or ISO 17025 accredited tests are verified to meet the requirements of those standards,
with any exceptions noted. The results reported relate only to the items tested and to the sample as received by
the laboratory. These results may not be reproduced except as full reports without approval by the laboratory.
Copies of GEL's accreditations and certifications can be found on our website at www.gel.com.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 1614.
Sincerely,
Adrian Melendrez for
Delaney Stone
Project Manager
Purchase Order: NCDAQ
Enclosures
gel. com
Page 1 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
for
NCDQ001 NC Dept Environmental Quality
Client SDG: 621012 GEL Work Order: 621012
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
B The target analyte was detected in the associated blank.
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the'U' qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Delaney Stone.
Reviewed by
Page 2 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: May 19, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
NCO024210-TB-20230504 Project: NCDQ00123
Sample ID:
621012001 Client ID: NCDQ001
Matrix:
Water
Collect Date:
04-MAY-23 07:56
Receive Date:
05-MAY-23
Collector:
Client
Parameter Qualifier
Result
DL
RL
Units
PF
DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
0.193
0.481
ng/L
0.0193
1 RR3 05/18/23 0539 2426059 1
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
0.193
0.481
ng/L
0.0193
1
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
0.193
0.481
ng/L
0.0193
1
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nation Byproduct 4 (PFESA BP4)
UX
ND
0.193
0.481
ng/L
0.0193
1
Nafion Byproduct 5 (PFESA BP5)
UX
ND
0.193
0.481
ng/L
0.0193
1
Nafion Byproduct 6 (PFESA BP6)
UX
ND
0.193
0.481
ng/L
0.0193
1
Hydro -EVE
UX
ND
0.193
0.481
ng/L
0.0193
1
Nation Byproduct 1 (PFESA BPI)
UX
ND
0.193
0.481
ng/L
0.0193
1
Nafion Byproduct 2 (PFESA BP2)
UX
ND
0.193
0.481
ng/L
0.0193
1
Nonafluoro-3,6-dioxahepanoic
U
ND
0.193
0.481
ng/L
0.0193
1
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
0.193
0.481
ng/L
0.0193
1
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic)
UX
ND
0.193
0.481
ng/L
0.0193
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid
UX
ND
0.193
0.481
ng/L
0.0193
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid
UX
ND
0.193
0.481
ng/L
0.0193
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid
UX
ND
0.193
0.481
ng/L
0.0193
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid
U
ND
0.193
0.481
ng/L
0.0193
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid
U
ND
0.193
0.481
ng/L
0.0193
1
(PFMOBA)
Perfluoroethoxypropionic acid
UX
ND
0.193
0.481
ng/L
0.0193
1
(EVE)
Perfluoropropanoic acid (PFPrA)
BJX
7.89
7.70
19.3
ng/L
0.0193
1
R-EVE
UX
ND
1.27
3.85
ng/L
0.0193
1
Perfluoro(3,5,7,9,1 1 -
UX
ND
0.193
0.481
ng/L
0.0193
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2-
UX
ND
0.193
0.481
ng/L
0.0193
1
(pentafluoroethoxy)propanoic acid
Page 3 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: May 19, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO024210-TB-20230504 Project: NCDQ00123
Sample ID: 621012001 Client ID: NCDQ001
Parameter Qualifier
Result
DL
RL
Units
PF
DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
(PEPA)
Perfluoro-2-
UX
ND
0.193
0.385
ng/L
0.0193
1
(perfluoromethoxy)propanoic acid
(PMPA)
11-Chloroeicosafluoro-3-
U
ND
0.635
1.93
ng/L
0.0193
1 JMB3 05/10/23 2310 2426059 2
oxaundecane-l-sulfonic acid (F-
53B Minor)
2-(N-ethylperfluoro-1-
U
ND
1.27
3.85
ng/L
0.0193
1
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
1.27
3.85
ng/L
0.0193
1
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U
ND
1.27
3.78
ng/L
0.0193
1
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
1.27
3.62
ng/L
0.0193
1
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
5.18
14.4
ng/L
0.0193
1
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
1.27
3.70
ng/L
0.0193
1
FTS)
N-ethylperfluoro-1-
U
ND
1.27
3.85
ng/L
0.0193
1
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
U
ND
1.27
3.85
ng/L
0.0193
1
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
U
ND
1.27
3.85
ng/L
0.0193
1
octanesulfonamide (N-McFOSA)
N-methylperfluoro-1-
U
ND
1.27
3.85
ng/L
0.0193
1
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
0.635
3.85
ng/L
0.0193
1
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
U
ND
0.635
1.71
ng/L
0.0193
1
Perfluorobutanoic acid (PFBA)
U
ND
0.770
1.93
ng/L
0.0193
1
Perfluorodecanesulfonic acid
U
ND
0.635
1.87
ng/L
0.0193
1
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
0.751
1.93
ng/L
0.0193
1
Perfluorododecanoic acid (PFDOA)
U
ND
0.635
1.93
ng/L
0.0193
1
Page 4 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: May 19, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO024210-TB-20230504 Project: NCDQ00123
Sample ID: 621012001 Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
Perfluoroheptanesulfonic acid U
ND
0.635
1.83
ng/L
0.0193
1
(PFHpS)
Perfluoroheptanoic acid (PFHpA) U
ND
0.635
1.93
ng/L
0.0193
1
Perfluorohexadecanoic acid U
ND
1.27
3.85
ng/L
0.0193
1
(PFHxDA)
Perfluorohexanesulfonic acid U
ND
0.635
1.75
ng/L
0.0193
1
(PFHxS)
Perfluorohexanoic acid (PFHxA) U
ND
0.770
1.93
ng/L
0.0193
1
Perfluorononanesulfonic acid U
ND
0.674
1.85
ng/L
0.0193
1
(PFNS)
Perfluorononanoic acid (PFNA) U
ND
0.635
1.93
ng/L
0.0193
1
Perfluorooctadecanoic acid U
ND
1.27
3.85
ng/L
0.0193
1
(PFODA)
Perfluorooctanesulfonamide U
ND
0.635
1.93
ng/L
0.0193
1
(PFOSA)
Perfluorooctanesulfonic acid (PFOS) U
ND
0.770
1.93
ng/L
0.0193
1
Perfluorooctanoic acid (PFOA) U
ND
0.770
1.93
ng/L
0.0193
1
Perfluoropentanesulfonic acid U
ND
0.635
1.81
ng/L
0.0193
1
(PFPeS)
Perfluoropentanoic acid (PFPeA) U
ND
0.635
1.93
ng/L
0.0193
1
Perfluorotetradecanoic acid (PFTA) U
ND
0.770
1.93
ng/L
0.0193
1
Perfluorotridecanoic Acid (PFTriA) U
ND
0.635
1.93
ng/L
0.0193
1
Perfluoroundecanoic acid (PFUnA) U
ND
0.635
1.93
ng/L
0.0193
1
4,8-Dioxa-3H-perfluorononanoic U
ND
0.635
1.93
ng/L
0.0193
1
acid (DONA,ADONA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
RR4
05/09/23
1346 2426055
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 EPA 537.1 Modified
2 EPA 537.1 Modified
Notes:
Page 5 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO024210-TB-20230504
Sample ID: 621012001
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 6 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: May 19, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
NCO024210-FRB-20230504 Project: NCDQ00123
Sample ID:
621012002 Client ID: NCDQ001
Matrix:
Water
Collect Date:
04-MAY-23 09:26
Receive Date:
05-MAY-23
Collector:
Client
Parameter Qualifier
Result
DL
RL
Units
PF
DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
0.191
0.479
ng/L
0.0191
1 RR3 05/18/23 0554 2426059 1
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
0.191
0.479
ng/L
0.0191
1
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
0.191
0.479
ng/L
0.0191
1
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nation Byproduct 4 (PFESA BP4)
UX
ND
0.191
0.479
ng/L
0.0191
1
Nafion Byproduct 5 (PFESA BP5)
UX
ND
0.191
0.479
ng/L
0.0191
1
Nafion Byproduct 6 (PFESA BP6)
XU
ND
0.191
0.479
ng/L
0.0191
1
Hydro -EVE
UX
ND
0.191
0.479
ng/L
0.0191
1
Nation Byproduct 1 (PFESA BPI)
UX
ND
0.191
0.479
ng/L
0.0191
1
Nafion Byproduct 2 (PFESA BP2)
UX
ND
0.191
0.479
ng/L
0.0191
1
Nonafluoro-3,6-dioxahepanoic
U
ND
0.191
0.479
ng/L
0.0191
1
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
0.191
0.479
ng/L
0.0191
1
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic)
UX
ND
0.191
0.479
ng/L
0.0191
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid
UX
ND
0.191
0.479
ng/L
0.0191
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid
UX
ND
0.191
0.479
ng/L
0.0191
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid
UX
ND
0.191
0.479
ng/L
0.0191
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid
U
ND
0.191
0.479
ng/L
0.0191
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid
U
ND
0.191
0.479
ng/L
0.0191
1
(PFMOBA)
Perfluoroethoxypropionic acid
UX
ND
0.191
0.479
ng/L
0.0191
1
(EVE)
Perfluoropropanoic acid (PFPrA)
BJX
9.49
7.66
19.1
ng/L
0.0191
1
R-EVE
UX
ND
1.26
3.83
ng/L
0.0191
1
Perfluoro(3,5,7,9,1 1 -
UX
ND
0.191
0.479
ng/L
0.0191
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2-
UX
ND
0.191
0.479
ng/L
0.0191
1
(pentafluoroethoxy)propanoic acid
Page 7 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO024210-FRB-20230504
Sample ID: 621012002
Parameter Qualifier Result
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
(PEPA)
Perfluoro-2-
UX ND
(perfluoromethoxy)propanoic acid
(PMPA)
11-Chloroeicosafluoro-3-
U ND
oxaundecane-l-sulfonic acid (F-
53B Minor)
2-(N-ethylperfluoro-1-
U ND
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U ND
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U ND
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U ND
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U ND
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U ND
FTS)
N-ethylperfluoro-1-
U ND
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
U ND
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
U ND
octanesulfonamide (N-McFOSA)
N-methylperfluoro-1-
U ND
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U ND
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
U ND
Perfluorobutanoic acid (PFBA)
U ND
Perfluorodecanesulfonic acid
U ND
(PFDS)
Perfluorodecanoic acid (PFDA)
U ND
Perfluorododecanoic acid (PFDOA)
U ND
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
DL RL Units PF DF Analyst Date Time Batch Method
0.191
0.383
ng/L
0.0191
1
0.632
1.91
ng/L
0.0191
1 JMB3 05/10/23 2319 2426059
1.26
3.83
ng/L
0.0191
1
1.26
3.83
ng/L
0.0191
1
1.26
3.76
ng/L
0.0191
1
1.26
3.60
ng/L
0.0191
1
5.15
14.4
ng/L
0.0191
1
1.26
3.68
ng/L
0.0191
1
1.26
3.83
ng/L
0.0191
1
1.26
3.83
ng/L
0.0191
1
1.26
3.83
ng/L
0.0191
1
1.26
3.83
ng/L
0.0191
1
0.632
3.83
ng/L
0.0191
1
0.632
1.70
ng/L
0.0191
1
0.766
1.91
ng/L
0.0191
1
0.632
1.86
ng/L
0.0191
1
0.747
1.91
ng/L
0.0191
1
0.632
1.91
ng/L
0.0191
1
FA
Page 8 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: May 19, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO024210-FRB-20230504 Project: NCDQ00123
Sample ID: 621012002 Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
Perfluoroheptanesulfonic acid U ND
0.632
1.82
ng/L
0.0191
1
(PFHpS)
Perfluoroheptanoic acid (PFHpA) U ND
0.632
1.91
ng/L
0.0191
1
Perfluorohexadecanoic acid U ND
1.26
3.83
ng/L
0.0191
1
(PFHxDA)
Perfluorohexanesulfonic acid U ND
0.632
1.74
ng/L
0.0191
1
(PFHxS)
Perfluorohexanoic acid (PFHxA) U ND
0.766
1.91
ng/L
0.0191
1
Perfluorononanesulfonic acid U ND
0.670
1.84
ng/L
0.0191
1
(PFNS)
Perfluorononanoic acid (PFNA) U ND
0.632
1.91
ng/L
0.0191
1
Perfluorooctadecanoic acid U ND
1.26
3.83
ng/L
0.0191
1
(PFODA)
Perfluorooctanesulfonamide U ND
0.632
1.91
ng/L
0.0191
1
(PFOSA)
Perfluorooctanesulfonic acid (PFOS) U ND
0.766
1.91
ng/L
0.0191
1
Perfluorooctanoic acid (PFOA) U ND
0.766
1.91
ng/L
0.0191
1
Perfluoropentanesulfonic acid U ND
0.632
1.80
ng/L
0.0191
1
(PFPeS)
Perfluoropentanoic acid (PFPeA) U ND
0.632
1.91
ng/L
0.0191
1
Perfluorotetradecanoic acid (PFTA) U ND
0.766
1.91
ng/L
0.0191
1
Perfluorotridecanoic Acid (PFTriA) U ND
0.632
1.91
ng/L
0.0191
1
Perfluoroundecanoic acid (PFUnA) U ND
0.632
1.91
ng/L
0.0191
1
4,8-Dioxa-3H-perfluorononanoic U ND
0.632
1.91
ng/L
0.0191
1
acid (DONA,ADONA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
RR4
05/09/23
1346 2426055
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 EPA 537.1 Modified
2 EPA 537.1 Modified
Notes:
Page 9 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO024210-FRB-20230504
Sample ID: 621012002
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 10 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
NCO026123-FRB-20230504-SO
Sample ID:
621012003
Matrix:
Water
Collect Date:
04-MAY-23 12:07
Receive Date:
05-MAY-23
Collector:
Client
Parameter Qualifier Result
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
11-Chloroeicosafluoro-3-
U
ND
oxaundecane-l-sulfonic acid(F-
53B Minor)
2-(N-ethylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U
ND
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
FTS)
N-ethylperfluoro-1-
U
ND
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
U
ND
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
U
ND
octanesulfonamide (N-McFOSA)
N-methylperfluoro-l-
U
ND
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
U
ND
Perfluorobutanoic acid (PFBA)
U
ND
Perfluorodecanesulfonic acid
U
ND
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
Perfluorododecanoic acid (PFDOA)
U
ND
Perfluoroheptanesulfonic acid
U
ND
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
Perfluorohexadecanoic acid
U
ND
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
DL RL Units PF DF Analyst Date Time Batch Method
0.628
1.90
ng/L
0.0190
1 JMB3 05/10/23 2328 2426059 1
1.26
3.81
ng/L
0.0190
1
1.26
3.81
ng/L
0.0190
1
1.26
3.74
ng/L
0.0190
1
1.26
3.58
ng/L
0.0190
1
5.12
14.3
ng/L
0.0190
1
1.26
3.66
ng/L
0.0190
1
1.26
3.81
ng/L
0.0190
1
1.26
3.81
ng/L
0.0190
1
1.26
3.81
ng/L
0.0190
1
1.26
3.81
ng/L
0.0190
1
0.628
3.81
ng/L
0.0190
1
0.628
1.69
ng/L
0.0190
1
0.761
1.90
ng/L
0.0190
1
0.628
1.85
ng/L
0.0190
1
0.742
1.90
ng/L
0.0190
1
0.628
1.90
ng/L
0.0190
1
0.628
1.81
ng/L
0.0190
1
0.628
1.90
ng/L
0.0190
1
1.26
3.81
ng/L
0.0190
1
Page 11 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: May 19, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-FRB-20230504-SO Project: NCDQ00123
Sample ID: 621012003 Client ID: NCDQ001
Parameter Qualifier
Result
DL
RL
Units
PF
DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
(PFHxDA)
Perfluorohexanesulfonic acid
U
ND
0.628
1.73
ng/L
0.0190
1
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
0.761
1.90
ng/L
0.0190
1
Perfluorononanesulfonic acid
U
ND
0.666
1.83
ng/L
0.0190
1
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
0.628
1.90
ng/L
0.0190
1
Perfluorooctadecanoic acid
U
ND
1.26
3.81
ng/L
0.0190
1
(PFODA)
Perfluorooctanesulfonamide
U
ND
0.628
1.90
ng/L
0.0190
1
(PFESA)
Perfluorooctanesulfonic acid (PFOS)
U
ND
0.761
1.90
ng/L
0.0190
1
Perfluorooctanoic acid (PFOA)
U
ND
0.761
1.90
ng/L
0.0190
1
Perfluoropentanesulfonic acid
U
ND
0.628
1.79
ng/L
0.0190
1
(PFPeS)
Perfluoropentanoic acid (PFPeA)
U
ND
0.628
1.90
ng/L
0.0190
1
Perfluorotetradecanoic acid (PFTA)
U
ND
0.761
1.90
ng/L
0.0190
1
Perfluorotridecanoic Acid (PFTriA)
U
ND
0.628
1.90
ng/L
0.0190
1
Perfluoroundecanoic acid (PFUnA)
U
ND
0.628
1.90
ng/L
0.0190
1
4,8-Dioxa-3H-perfluorononanoic
U
ND
0.628
1.90
ng/L
0.0190
1
acid (DONA,ADONA)
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
0.190
0.476
ng/L
0.0190
1 RR3 05/18/23 0609 2426059 2
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
0.190
0.476
ng/L
0.0190
1
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
0.190
0.476
ng/L
0.0190
1
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nafion Byproduct 4 (PFESA BP4)
UX
ND
0.190
0.476
ng/L
0.0190
1
Nation Byproduct 5 (PFESA BP5)
UX
ND
0.190
0.476
ng/L
0.0190
1
Nation Byproduct 6 (PFESA BP6)
UX
ND
0.190
0.476
ng/L
0.0190
1
Hydro -EVE
UX
ND
0.190
0.476
ng/L
0.0190
1
Nation Byproduct 1 (PFESA BPI)
UX
ND
0.190
0.476
ng/L
0.0190
1
Nafion Byproduct 2 (PFESA BP2)
UX
ND
0.190
0.476
ng/L
0.0190
1
Nonafluoro-3,6-dioxaheptanoic
U
ND
0.190
0.476
ng/L
0.0190
1
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
0.190
0.476
ng/L
0.0190
1
Page 12 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: May 19, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-FRB-20230504-SO Project: NCDQ00123
Sample ID: 621012003 Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic) UX
ND
0.190
0.476
ng/L
0.0190
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid UX
ND
0.190
0.476
ng/L
0.0190
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid UX
ND
0.190
0.476
ng/L
0.0190
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid UX
ND
0.190
0.476
ng/L
0.0190
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid U
ND
0.190
0.476
ng/L
0.0190
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid U
ND
0.190
0.476
ng/L
0.0190
1
(PFMOBA)
Perfluoroethoxypropionic acid UX
ND
0.190
0.476
ng/L
0.0190
1
(EVE)
Perfluoropropanoic acid (PFPrA) BJX
8.89
7.61
19.0
ng/L
0.0190
1
R-EVE UX
ND
1.26
3.81
ng/L
0.0190
1
Perfluoro(3,5,7,9,11- UX
ND
0.190
0.476
ng/L
0.0190
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2- UX
ND
0.190
0.476
ng/L
0.0190
1
(pentafluoroethoxy)propanoic acid
(PEPA)
Perfluoro-2- UX
ND
0.190
0.381
ng/L
0.0190
1
(perfluoromethoxy)propanoic acid
(PMPA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
RR4
05/09/23
1346 2426055
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 EPA 537.1 Modified
EPA 537.1 Modified
Notes:
Page 13 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-FRB-20230504-SO
Sample ID: 621012003
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 14 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: May 19, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
NCO026123-FRB-20230504 Project: NCDQ00123
Sample ID:
621012004 Client ID: NCDQ001
Matrix:
Water
Collect Date:
04-MAY-23 10:35
Receive Date:
05-MAY-23
Collector:
Client
Parameter Qualifier
Result
DL
RL
Units
PF
DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
0.191
0.479
ng/L
0.0191
1 RR3 05/18/23 0052 2428642 1
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
0.191
0.479
ng/L
0.0191
1
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
0.191
0.479
ng/L
0.0191
1
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nation Byproduct 4 (PFESA BP4)
UX
ND
0.191
0.479
ng/L
0.0191
1
Nafion Byproduct 5 (PFESA BP5)
UX
ND
0.191
0.479
ng/L
0.0191
1
Nafion Byproduct 6 (PFESA BP6)
UX
ND
0.191
0.479
ng/L
0.0191
1
Hydro -EVE
UX
ND
0.191
0.479
ng/L
0.0191
1
Nation Byproduct 1 (PFESA BPI)
UX
ND
0.191
0.479
ng/L
0.0191
1
Nafion Byproduct 2 (PFESA BP2)
UX
ND
0.191
0.479
ng/L
0.0191
1
Nonafluoro-3,6-dioxahepanoic
U
ND
0.191
0.479
ng/L
0.0191
1
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
0.191
0.479
ng/L
0.0191
1
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic)
UX
ND
0.191
0.479
ng/L
0.0191
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid
UX
ND
0.191
0.479
ng/L
0.0191
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid
UX
ND
0.191
0.479
ng/L
0.0191
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid
UX
ND
0.191
0.479
ng/L
0.0191
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid
U
ND
0.191
0.479
ng/L
0.0191
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid
U
ND
0.191
0.479
ng/L
0.0191
1
(PFMOBA)
Perfluoroethoxypropionic acid
UX
ND
0.191
0.479
ng/L
0.0191
1
(EVE)
Perfluoropropanoic acid (PFPrA)
JX
9.23
7.66
19.1
ng/L
0.0191
1
R-EVE
UX
ND
1.26
3.83
ng/L
0.0191
1
Perfluoro(3,5,7,9,1 1 -
UX
ND
0.191
0.479
ng/L
0.0191
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2-
UX
ND
0.191
0.479
ng/L
0.0191
1
(pentafluoroethoxy)propanoic acid
Page 15 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-FRB-20230504
Sample ID: 621012004
Parameter Qualifier Result
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
(PEPA)
Perfluoro-2-
UX ND
(perfluoromethoxy)propanoic acid
(PMPA)
11-Chloroeicosafluoro-3-
U ND
oxaundecane-l-sulfonic acid (F-
53B Minor)
2-(N-ethylperfluoro-1-
U ND
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U ND
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U ND
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U ND
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U ND
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U ND
FTS)
N-ethylperfluoro-1-
U ND
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
U ND
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
U ND
octanesulfonamide (N-McFOSA)
N-methylperfluoro-1-
U ND
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U ND
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
U ND
Perfluorobutanoic acid (PFBA)
U ND
Perfluorodecanesulfonic acid
U ND
(PFDS)
Perfluorodecanoic acid (PFDA)
U ND
Perfluorododecanoic acid (PFDOA)
U ND
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
DL RL Units PF DF Analyst Date Time Batch Method
0.191
0.383
ng/L
0.0191
1
0.632
1.91
ng/L
0.0191
1 JMB3 05/16/23 1036 2428642
1.26
3.83
ng/L
0.0191
1
1.26
3.83
ng/L
0.0191
1
1.26
3.76
ng/L
0.0191
1
1.26
3.60
ng/L
0.0191
1
5.15
14.4
ng/L
0.0191
1
1.26
3.68
ng/L
0.0191
1
1.26
3.83
ng/L
0.0191
1
1.26
3.83
ng/L
0.0191
1
1.26
3.83
ng/L
0.0191
1
1.26
3.83
ng/L
0.0191
1
0.632
3.83
ng/L
0.0191
1
0.632
1.70
ng/L
0.0191
1
0.766
1.91
ng/L
0.0191
1
0.632
1.86
ng/L
0.0191
1
0.747
1.91
ng/L
0.0191
1
0.632
1.91
ng/L
0.0191
1
FA
Page 16 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: May 19, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-FRB-20230504 Project: NCDQ00123
Sample ID: 621012004 Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
Perfluoroheptanesulfonic acid U ND
0.632
1.82
ng/L
0.0191
1
(PFHpS)
Perfluoroheptanoic acid (PFHpA) U ND
0.632
1.91
ng/L
0.0191
1
Perfluorohexadecanoic acid U ND
1.26
3.83
ng/L
0.0191
1
(PFHxDA)
Perfluorohexanesulfonic acid U ND
0.632
1.74
ng/L
0.0191
1
(PFHxS)
Perfluorohexanoic acid (PFHxA) U ND
0.766
1.91
ng/L
0.0191
1
Perfluorononanesulfonic acid U ND
0.670
1.84
ng/L
0.0191
1
(PFNS)
Perfluorononanoic acid (PFNA) U ND
0.632
1.91
ng/L
0.0191
1
Perfluorooctadecanoic acid U ND
1.26
3.83
ng/L
0.0191
1
(PFODA)
Perfluorooctanesulfonamide U ND
0.632
1.91
ng/L
0.0191
1
(PFOSA)
Perfluorooctanesulfonic acid (PFOS) U ND
0.766
1.91
ng/L
0.0191
1
Perfluorooctanoic acid (PFOA) U ND
0.766
1.91
ng/L
0.0191
1
Perfluoropentanesulfonic acid U ND
0.632
1.80
ng/L
0.0191
1
(PFPeS)
Perfluoropentanoic acid (PFPeA) U ND
0.632
1.91
ng/L
0.0191
1
Perfluorotetradecanoic acid (PFTA) U ND
0.766
1.91
ng/L
0.0191
1
Perfluorotridecanoic Acid (PFTriA) U ND
0.632
1.91
ng/L
0.0191
1
Perfluoroundecanoic acid (PFUnA) U ND
0.632
1.91
ng/L
0.0191
1
4,8-Dioxa-3H-perfluorononanoic U ND
0.632
1.91
ng/L
0.0191
1
acid (DONA,ADONA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
BPI
05/15/23
1253 2428641
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 EPA 537.1 Modified
2 EPA 537.1 Modified
Notes:
Page 17 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-FRB-20230504
Sample ID: 621012004
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 18 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: May 19, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
NCO024210-EFF-20230504 Project: NCDQ00123
Sample ID:
621012005 Client ID: NCDQ001
Matrix:
Waste Water
Collect Date:
04-MAY-23 09:30
Receive Date:
05-MAY-23
Collector:
Client
Parameter Qualifier
Result
DL
RL
Units
PF
DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
0.182
0.455
ng/L
0.0182
1 RR3 05/12/23 0436 2424988 1
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
J
0.268
0.182
0.455
ng/L
0.0182
1
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
0.182
0.455
ng/L
0.0182
1
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nation Byproduct 4 (PFESA BP4)
UX
ND
0.182
0.455
ng/L
0.0182
1
Nafion Byproduct 5 (PFESA BP5)
X
0.951
0.182
0.455
ng/L
0.0182
1
Nafion Byproduct 6 (PFESA BP6)
UX
ND
0.182
0.455
ng/L
0.0182
1
Hydro -EVE
UX
ND
0.182
0.455
ng/L
0.0182
1
Nation Byproduct I (PFESA BPI)
UX
ND
0.182
0.455
ng/L
0.0182
1
Nation Byproduct 2 (PFESA BP2)
UX
ND
0.182
0.455
ng/L
0.0182
1
Nonafluoro-3,6-dioxahepanoic
J
0.263
0.182
0.455
ng/L
0.0182
1
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
0.182
0.455
ng/L
0.0182
1
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic)
UX
ND
0.182
0.455
ng/L
0.0182
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid
UX
ND
0.182
0.455
ng/L
0.0182
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid
UX
ND
0.182
0.455
ng/L
0.0182
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid
UX
ND
0.182
0.455
ng/L
0.0182
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid
U
ND
0.182
0.455
ng/L
0.0182
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid
U
ND
0.182
0.455
ng/L
0.0182
1
(PFMOBA)
Perfluoroethoxypropionic acid
UX
ND
0.182
0.455
ng/L
0.0182
1
(EVE)
Perfluoropropanoic acid (PFPrA)
JX
13.0
7.28
18.2
ng/L
0.0182
1
R-EVE
UX
ND
1.20
3.64
ng/L
0.0182
1
Perfluoro(3,5,7,9,1I-
UX
ND
0.182
0.455
ng/L
0.0182
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2-
UX
ND
0.182
0.455
ng/L
0.0182
1
(pentafluoroethoxy)propanoic acid
Page 19 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: May 19, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO024210-EFF-20230504 Project: NCDQ00123
Sample ID: 621012005 Client ID: NCDQ001
Parameter Qualifier
Result
DL
RL
Units
PF
DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS
"As
Received"
(PEPA)
Perfluoro-2-
A
0.186
0.182
0.364
ng/L
0.0182
1
(perfluoromethoxy)propanoic acid
(PMPA)
11-Chloroeicosafluoro-3-
U
ND
0.600
1.82
ng/L
0.0182
1 JMB3 05/08/23 1629 2424988 2
oxaundecane-l-sulfonic acid (F-
53B Minor)
2-(N-ethylperfluoro-1-
U
ND
1.20
3.64
ng/L
0.0182
1
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
1.20
3.64
ng/L
0.0182
1
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U
ND
1.20
3.57
ng/L
0.0182
1
oxanonane-l-sulfonic acid (F-53B
Major)
N-ethylperfluoro-l-
U
ND
1.20
3.64
ng/L
0.0182
1
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
U
ND
1.20
3.64
ng/L
0.0182
1
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
U
ND
1.20
3.64
ng/L
0.0182
1
octanesulfonamide (N-McFOSA)
N-methylperfluoro-l-
J
1.56
1.20
3.64
ng/L
0.0182
1
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
0.600
3.64
ng/L
0.0182
1
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
7.13
0.600
1.62
ng/L
0.0182
1
Perfluorobutanoic acid (PFBA)
23.4
0.728
1.82
ng/L
0.0182
1
Perfluorodecanesulfonic acid
U
ND
0.600
1.77
ng/L
0.0182
1
(PFDS)
Perfluorodecanoic acid (PFDA)
J
1.19
0.710
1.82
ng/L
0.0182
1
Perfluorododecanoic acid (PFDOA)
U
ND
0.600
1.82
ng/L
0.0182
1
Perfluoroheptanesulfonic acid
U
ND
0.600
1.73
ng/L
0.0182
1
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
5.30
0.600
1.82
ng/L
0.0182
1
Perfluorohexadecanoic acid
U
ND
1.20
3.64
ng/L
0.0182
1
(PFHxDA)
Perfluorohexanesulfonic acid
9.75
0.600
1.66
ng/L
0.0182
1
Page 20 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO024210-EFF-20230504
Sample ID: 621012005
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
(PFHxS)
Perfluorohexanoic acid (PFHxA)
19.6
0.728
1.82
ng/L
0.0182
1
Perfluorononanesulfonic acid U
ND
0.637
1.75
ng/L
0.0182
1
(PFNS)
Perfluorononanoic acid (PFNA) J
1.33
0.600
1.82
ng/L
0.0182
1
Perfluorooctadecanoic acid U
ND
1.20
3.64
ng/L
0.0182
1
(PFODA)
Perfluorooctanesulfonamide U
ND
0.600
1.82
ng/L
0.0182
1
(PFOSA)
Perfluorooctanesulfonic acid (PFOS)
19.0
0.728
1.82
ng/L
0.0182
1
Perfluorooctanoic acid (PFOA)
13.2
0.728
1.82
ng/L
0.0182
1
Perfluoropentanesulfonic acid
2.17
0.600
1.71
ng/L
0.0182
1
(PFPeS)
Perfluoropentanoic acid (PFPeA)
19.3
0.600
1.82
ng/L
0.0182
1
Perfluorotetradecanoic acid (PFTA) U
ND
0.728
1.82
ng/L
0.0182
1
Perfluorotridecanoic Acid (PFTrJA) U
ND
0.600
1.82
ng/L
0.0182
1
Perfluoroundecanoic acid (PFUnA) U
ND
0.600
1.82
ng/L
0.0182
1
4,8-Dioxa-3H-perfluorononanoic U
ND
0.600
1.82
ng/L
0.0182
1
acid (DONA,ADONA)
Fluorotelomer sulfonic acid 6:2 (6:2 U
ND
24.5
68.2
ng/L
0.0182
5
JMB3 05/09/23 1357 2424988
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2 U
ND
6.00
17.5
ng/L
0.0182
5
FTS)
Fluorotelomer sulfonic acid 4:2 (4:2 U
ND
30.0
85.5
ng/L
0.0182
25
JMB3 05/09/23 1758 2424988
FTS)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time
Prep Batch
EPA 537.1 Modified PFCs Extraction in
Liquid
SR2
05/08/23
0749
2424987
The following Analytical Methods were performed:
Method Description Analyst Comments
1 EPA 537.1 Modified
2 EPA 537.1 Modified
3 EPA 537.1 Modified
4 EPA 537.1 Modified
Notes:
3
4
Page 21 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO024210-EFF-20230504
Sample ID: 621012005
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 22 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
NCO024210-INF-20230504
Sample ID:
621012006
Matrix:
Waste Water
Collect Date:
04-MAY-23 09:52
Receive Date:
05-MAY-23
Collector:
Client
Parameter Qualifier Result
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
11-Chloroeicosafluoro-3-
U
ND
oxaundecane-l-sulfonic acid(F-
53B Minor)
2-(N-ethylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U
ND
oxanonane-l-sulfonic acid (F-53B
Major)
N-ethylperfluoro-l-
U
ND
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
U
ND
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
U
ND
octanesulfonamide (N-McFOSA)
N-methylperfluoro-l-
U
ND
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
U
ND
Perfluorobutanoic acid (PFBA)
J
11.4
Perfluorodecanesulfonic acid
U
ND
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
Perfluorododecanoic acid (PFDOA)
U
ND
Perfluoroheptanesulfonic acid
U
ND
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
Perfluorohexanesulfonic acid
J
12.2
(PFHxS)
Perfluorohexanoic acid (PFHxA)
J
12.0
Perfluorononanesulfonic acid
U
ND
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
Perfluorooctanesulfonamide
U
ND
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
DL RL Units PF DF Analyst Date Time Batch Method
8.25
25.0
ng/L
0.250
1 JMB3 05/08/23 1637 2424988 1
16.5
50.0
ng/L
0.250
1
16.5
50.0
ng/L
0.250
1
16.5
49.1
ng/L
0.250
1
16.5
50.0
ng/L
0.250
1
16.5
50.0
ng/L
0.250
1
16.5
50.0
ng/L
0.250
1
16.5
50.0
ng/L
0.250
1
8.25
50.0
ng/L
0.250
1
8.25
22.3
ng/L
0.250
1
10.0
25.0
ng/L
0.250
1
8.25
24.3
ng/L
0.250
1
9.75
25.0
ng/L
0.250
1
8.25
25.0
ng/L
0.250
1
8.25
23.8
ng/L
0.250
1
8.25
25.0
ng/L
0.250
1
8.25
22.8
ng/L
0.250
1
10.0
25.0
ng/L
0.250
1
8.75
24.0
ng/L
0.250
1
8.25
25.0
ng/L
0.250
1
8.25
25.0
ng/L
0.250
1
Page 23 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO024210-INF-20230504
Sample ID: 621012006
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
(PFESA)
Perfluorooctanesulfonic acid (PFOS)
J 19.7
Perfluorooctanoic acid (PFOA)
U ND
Perfluoropentanesulfonic acid
U ND
(PFPeS)
Perfluoropentanoic acid (PFPeA)
J 12.0
Perfluorotetradecanoic acid (PFTA)
U ND
Perfluorotridecanoic Acid (PFTriA)
U ND
Perfluoroundecanoic acid (PFUnA)
U ND
4,8-Dioxa-3H-perfluorononanoic
U ND
acid (DONA,ADONA)
Fluorotelomer sulfonic acid 8:2 (8:2
U ND
FTS)
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX ND
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U ND
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX ND
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nafion Byproduct 4 (PFESA BP4)
UX ND
Nafion Byproduct 5 (PFESA BP5)
UX ND
Nafion Byproduct 6 (PFESA BP6)
UX ND
Hydro -EVE
UX ND
Nafion Byproduct 1 (PFESA BPI)
UX ND
Nafion Byproduct 2 (PFESA BP2)
UX ND
Nonafluoro-3,6-dioxaheptanoic
U ND
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U ND
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic)
UX ND
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid
UX ND
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid
UX ND
(PF02HxA)
Perfluoro-2-methoxyacetic acid
UX ND
10.0
25.0
ng/L
0.250
1
10.0
25.0
ng/L
0.250
1
8.25
23.5
ng/L
0.250
1
8.25
25.0
ng/L
0.250
1
10.0
25.0
ng/L
0.250
1
8.25
25.0
ng/L
0.250
1
8.25
25.0
ng/L
0.250
1
8.25
25.0
ng/L
0.250
1
413
1200
ng/L
0.250
25 JMB3 05/09/23 1807 2424988
2.50
6.25
ng/L
0.250
1 RR3 05/12/23 0452 2424988
2.50 6.25
2.50 6.25
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
6.25
6.25
6.25
6.25
6.25
6.25
6.25
6.25
6.25
6.25
6.25
6.25
ng/L 0.250 1
ng/L 0.250 1
ng/L
ng/L
ng/L
ng/L
ng/L
ng/L
ng/L
9-Wo
ng/L
ng/L
ng/L
ng/L
0.250 1
0.250 1
0.250 1
0.250 1
0.250 1
0.250 1
0.250 1
0.250 1
0.250 1
0.250 1
0.250 1
0.250 1
2
3
Page 24 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: May 19, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO024210-INF-20230504 Project: NCDQ00123
Sample ID: 621012006 Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
(PFMOAA)
Perfluoro-3-methoxypropanoic acid U ND
2.50
6.25
ng/L
0.250
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid U ND
2.50
6.25
ng/L
0.250
1
(PFMOBA)
Perfluoroethoxypropionic acid UX ND
2.50
6.25
ng/L
0.250
1
(EVE)
Perfluoropropanoic acid (PFPrA) JX 159
100
250
ng/L
0.250
1
R-EVE UX ND
16.5
50.0
ng/L
0.250
1
Perfluoro(3,5,7,9,11- UX ND
2.50
6.25
ng/L
0.250
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2- UX ND
2.50
6.25
ng/L
0.250
1
(pentafluoroethoxy)propanoic acid
(PEPA)
Perfluoro-2- UX ND
2.50
5.00
ng/L
0.250
1
(perfluoromethoxy)propanoic acid
(PMPA)
Fluorotelomer sulfonic acid 4:2 (4:2 U ND
82.5
235
ng/L
0.250
5 JMB3 05/09/23 1406 2424988 4
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2 U ND
336
938
ng/L
0.250
5
FTS)
Perfluorohexadecanoic acid U ND
82.5
250
ng/L
0.250
5
(PFHxDA)
Perfluorooctadecanoic acid U ND
82.5
250
ng/L
0.250
5
(PFODA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
SR2
05/08/23
0749 2424987
The following Analytical Methods were performed:
Method Description
Analyst
Comments
1 EPA 537.1 Modified
EPA 537.1 Modified
EPA 537.1 Modified
EPA 537.1 Modified
Notes:
Page 25 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO024210-INF-20230504
Sample ID: 621012006
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 26 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
NCO024210-BIOS-20230504
Sample ID:
621012007
Matrix:
Sludge
Collect Date:
04-MAY-23 09:42
Receive Date:
05-MAY-23
Collector:
Client
Moisture:
69.4%
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
LC-MS/MS EPA 537Mod PFAS,
Solid "Dry
Weight Corrected"
11-Chloroeicosafluoro-3-
U
ND
0.505
oxaundecane-l-sulfonic acid (F-
53B Minor)
2H,2H,3H,3H-Perfluorodecanoic
3.41
1.01
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
10.4
1.01
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
U
ND
1.01
acid (3:3 FTCA)(FPrPA)
9-Chlorohexadecafluoro-3-
U
ND
0.505
oxanonane-l-sulfonic acid (F-53B
Major)
N-ethylperfluoro-l-
3.90
0.841
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
4.99
1.01
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
0.505
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
U
ND
0.505
Perfluorobutanoic acid (PFBA)
2.17
0.612
Perfluorodecanesulfonic acid
U
ND
0.505
(PFDS)
Perfluorodecanoic acid (PFDA)
J
1.72
1.13
Perfluorododecanoic acid (PFDOA)
J
0.777
0.505
Perfluoroheptanesulfonic acid
U
ND
0.566
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
0.505
Perfluorohexanesulfonic acid
2.04
0.505
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
0.612
Perfluorononanesulfonic acid
U
ND
0.505
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
0.505
Perfluorooctanesulfonamide
1.75
0.505
(PFOSA)
Perfluorooctanesulfonic acid (PFOS)
18.5
0.612
Perfluorooctanoic acid (PFDA)
J
1.26
0.612
1.44
ng/g
4.67
1 JMB3 05/11/23 0939 2426643 1
3.06
ng/g
4.67
1
3.06
ng/g
4.67
1
3.06
ng/g
4.67
1
1.43
ng/g
4.67
1
3.06
ng/g
4.67
1
3.06
ng/g
4.67
1
1.48
ng/g
4.67
1
1.36
ng/g
4.67
1
1.53
ng/g
4.67
1
1.48
ng/g
4.67
1
3.06
ng/g
4.67
1
1.53
ng/g
4.67
1
1.45
ng/g
4.67
1
1.53
ng/g
4.67
1
1.39
ng/g
4.67
1
1.53
ng/g
4.67
1
1.47
ng/g
4.67
1
1.53
ng/g
4.67
1
1.53
ng/g
4.67
1
1.53
ng/g
4.67
1
1.53
ng/g
4.67
1
Page 27 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO024210-BIOS-20230504
Sample ID: 621012007
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
LC-MS/MS EPA 537Mod PFAS, Solid "Dry
Weight Corrected"
Perfluoropentanesulfonic acid
U
ND
0.505
(PFPeS)
Perfluoropentanoic acid (PFPeA)
U
ND
0.505
Perfluoroundecanoic acid (PFUnA)
J
0.639
0.505
4,8-Dioxa-3H-perfluorononanoic
U
ND
0.505
acid (DONA,ADONA)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
30.6
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
103
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
147
FTS)
2-(N-ethylperfluoro-I-
U
ND
6.04
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
5.96
octanesulfonamido)-ethanol (N-
McFOSE)
N-ethylperfluoro-1-
U
ND
6.27
octanesulfonamide (N-EtFOSA)
N-methylperfluoro-1-
U
ND
6.65
octanesulfonamide (N-McFOSA)
Perfluorotetradecanoic acid (PFTA)
U
ND
3.06
Perfluorotridecanoic Acid (PFTriA)
U
ND
2.52
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
1.01
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
0.505
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
1.01
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nafion Byproduct 4 (PFESA BP4)
UX
ND
1.01
Nafion Byproduct 5 (PFESA BP5)
XU
ND
1.01
Nafion Byproduct 6 (PFESA BP6)
UX
ND
1.01
Hydro -EVE
UX
ND
1.01
Nafion Byproduct 1 (PFESA BPI)
UX
ND
1.01
Nafion Byproduct 2 (PFESA BP2)
UX
ND
1.01
1.44
ng/g
4.67
1
1.53
ng/g
4.67
1
1.53
ng/g
4.67
1
1.53
ng/g
4.67
1
71.9
ng/g
4.67
25
JMB3
05/11/23
1509 2426643 2
287
ng/g
4.67
25
367
ng/g
4.67
125
JMB3
05/11/23
1741 2426643 3
15.3
ng/g
4.67
5
JMB3
05/11/23
0948 2426643 4
15.3
ng/g
4.67
5
15.3
ng/g
4.67
5
15.3
ng/g
4.67
5
7.65
ng/g
4.67
5
7.65
ng/g
4.67
5
3.06
ng/g
4.67
1
RR3
05/16/23
0241 2426643 5
1.53
ng/g
4.67
1
3.06
ng/g
4.67
1
3.06
ng/g
4.67
1
3.06
ng/g
4.67
1
3.06
ng/g
4.67
1
3.06
ng/g
4.67
1
3.06
ng/g
4.67
1
3.06
ng/g
4.67
1
Page 28 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: May 19, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO024210-BIOS-20230504 Project: NCDQ00123
Sample ID: 621012007 Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
LC-MS/MS EPA 537Mod PFAS, Solid "Dry Weight Corrected"
Nonafluoro-3,6-dioxahepanoic U
ND
0.505
3.06
ng/g
4.67
1
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic U
ND
0.505
1.53
ng/g
4.67
1
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic) UX
ND
1.01
3.06
ng/g
4.67
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid UX
ND
1.01
3.06
ng/g
4.67
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid UX
ND
1.01
3.06
ng/g
4.67
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid UX
ND
1.01
3.06
ng/g
4.67
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid U
ND
1.01
3.06
ng/g
4.67
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid U
ND
1.01
3.06
ng/g
4.67
1
(PFMOBA)
Perfluoroethoxypropionic acid UX
ND
1.01
3.06
ng/g
4.67
1
(EVE)
R-EVE UX
ND
1.01
3.06
ng/g
4.67
1
Perfluoro(3,5,7,9,11- UX
ND
1.01
3.06
ng/g
4.67
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2- UX
ND
1.01
3.06
ng/g
4.67
1
(pentafluoroethoxy)propanoic acid
(PEPA)
Perfluoro-2- UX
ND
1.01
3.06
ng/g
4.67
1
(perfluoromethoxy)propanoic acid
(PMPA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Solid
DK2
05/10/23
0934 2426642
Page 29 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO024210-BIOS-20230504
Sample ID: 621012007
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
The following Analytical Methods were performed:
Method Description Analyst Comments
1 EPA 537.1 Modified
2 EPA 537.1 Modified
3 EPA 537.1 Modified
4 EPA 537.1 Modified
5 EPA 537.1 Modified
Notes:
Column headers are defined as follows:
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 30 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
NC0026123-SO-20230504-RA-42
Sample ID:
621012008
Matrix:
Soil
Collect Date:
04-MAY-23 13:00
Receive Date:
05-MAY-23
Collector:
Client
Moisture:
20.8%
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
LC-MS/MS EPA 537Mod PFAS, Solid "Dry
Weight Corrected"
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
0.406
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
0.203
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
0.406
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nation Byproduct 4 (PFESA BP4)
UX
ND
0.406
Nafion Byproduct 5 (PFESA BP5)
UX
ND
0.406
Nafion Byproduct 6 (PFESA BP6)
UX
ND
0.406
Hydro -EVE
UX
ND
0.406
Nation Byproduct 1 (PFESA BPI)
UX
ND
0.406
Nafion Byproduct 2 (PFESA BP2)
UX
ND
0.406
Nonafluoro-3,6-dioxahepanoic
U
ND
0.203
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
0.203
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic)
UX
ND
0.406
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid
UX
ND
0.406
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid
UX
ND
0.406
(PF02HxA)
Perfluoro-2-methoxyacetic acid
UX
ND
0.406
(PFMOAA)
Perfluoro-3-methoxypropanoic acid
U
ND
0.406
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid
U
ND
0.406
(PFMOBA)
Perfluoroethoxypropionic acid
UX
ND
0.406
(EVE)
R-EVE
UX
ND
0.406
Perfluoro(3,5,7,9,1 I -
UX
ND
0.406
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2-
UX
ND
0.406
(pentafluoroethoxy)propanoic acid
(PEPA)
1.23
ng/g
4.88
1 RR3 05/18/23 0856 2429817 1
0.616
ng/g
4.88
1
1.23
ng/g
4.88
1
1.23
ng/g
4.88
1
1.23
ng/g
4.88
1
1.23
ng/g
4.88
1
1.23
ng/g
4.88
1
1.23
ng/g
4.88
1
1.23
ng/g
4.88
1
1.23
ng/g
4.88
1
0.616
ng/g
4.88
1
1.23
ng/g
4.88
1
1.23
ng/g
4.88
1
1.23
ng/g
4.88
1
1.23
ng/g
4.88
1
1.23
ng/g
4.88
1
1.23
ng/g
4.88
1
1.23
ng/g
4.88
1
1.23
ng/g
4.88
1
1.23
ng/g
4.88
1
1.23
ng/g
4.88
1
Page 31 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NC0026123-SO-20230504-RA-42
Sample ID: 621012008
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
LC-MS/MS EPA 537Mod PFAS, Solid "Dry
Weight Corrected"
Perfluoro-2-
UX
ND
0.406
1.23
ng/g
4.88
1
(perfluoromethoxy)propanoic acid
(PMPA)
11-Chloroeicosafluoro-3-
U
ND
0.203
0.580
ng/g
4.88
1 JMB3 05/17/23 1757 2429817
oxaundecane-l-sulfonic acid (F-
53B Minor)
2-(N-ethylperfluoro-l-
U
ND
0.486
1.23
ng/g
4.88
1
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
0.480
1.23
ng/g
4.88
1
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
U
ND
0.406
1.23
ng/g
4.88
1
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
U
ND
0.406
1.23
ng/g
4.88
1
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
U
ND
0.406
1.23
ng/g
4.88
1
acid (3:3 FTCA)(FPrPA)
9-Chlorohexadecafluoro-3-
U
ND
0.203
0.574
ng/g
4.88
1
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
0.492
1.16
ng/g
4.88
1
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
1.66
4.62
ng/g
4.88
1
FTS)
N-ethylperfluoro-1-
U
ND
0.505
1.23
ng/g
4.88
1
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
U
ND
0.339
1.23
ng/g
4.88
1
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
U
ND
0.536
1.23
ng/g
4.88
1
octanesulfonamide (N-McFOSA)
N-methylperfluoro-1-
J
0.751
0.406
1.23
ng/g
4.88
1
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
0.203
0.596
ng/g
4.88
1
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
0.619
0.203
0.548
ng/g
4.88
1
Perfluorobutanoic acid (PFBA)
0.775
0.246
0.616
ng/g
4.88
1
Perfluorodecanesulfonic acid
U
ND
0.203
0.597
ng/g
4.88
1
2
Page 32 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NC0026123-SO-20230504-RA-42
Sample ID: 621012008
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
LC-MS/MS EPA 537Mod PFAS, Solid "Dry Weight Corrected"
(PFDS)
Perfluorodecanoic acid (PFDA) 1.68
0.455
1.23
ng/g
4.88
1
Perfluorododecanoic acid (PFDOA) 1.05
0.203
0.616
ng/g
4.88
1
Perfluoroheptanesulfonic acid U ND
0.228
0.585
ng/g
4.88
1
(PFHpS)
Perfluoroheptanoic acid (PFHpA) J 0.474
0.203
0.616
ng/g
4.88
1
Perfluorohexanesulfonic acid U ND
0.203
0.560
ng/g
4.88
1
(PFHxS)
Perfluorohexanoic acid (PFHxA) 1.16
0.246
0.616
ng/g
4.88
1
Perfluorononanesulfonic acid U ND
0.203
0.591
ng/g
4.88
1
(PFNS)
Perfluorononanoic acid (PFNA) J 0.580
0.203
0.616
ng/g
4.88
1
Perfluorooctanesulfonamide U ND
0.203
0.616
ng/g
4.88
1
(PFOSA)
Perfluorooctanesulfonic acid (PFDS) 4.18
0.246
0.616
ng/g
4.88
1
Perfluorooctanoic acid (PFDA) 1.77
0.246
0.616
ng/g
4.88
1
Perfluoropentanesulfonic acid U ND
0.203
0.579
ng/g
4.88
1
(PFPeS)
Perfluoropentanoic acid (PFPeA) 2.39
0.203
0.616
ng/g
4.88
1
Perfluorotetradecanoic acid (PFTA) J 0.451
0.246
0.616
ng/g
4.88
1
Perfluorotridecanoic Acid (PFTriA) J 0.336
0.203
0.616
ng/g
4.88
1
Perfluoroundecanoic acid (PFUnA) J 0.558
0.203
0.616
ng/g
4.88
1
4,8-Dioxa-3H-perfluorononanoic U ND
0.203
0.616
ng/g
4.88
1
acid (DONA,ADONA)
Fluorotelomer sulfonic acid 8:2 (8:2 U ND
2.37
5.91
ng/g
4.88
5
JM133 05/18/23 0858 2429817
FTS)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time
Prep Batch
EPA 537.1 Modified PFCs Extraction in Solid
RR4
05/16/23
1213
2429816
The following Analytical Methods were performed:
Method Description Analyst Comments
1 EPA 537.1 Modified
2 EPA 537.1 Modified
3 EPA 537.1 Modified
Notes:
3
Page 33 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NC0026123-SO-20230504-RA-42
Sample ID: 621012008
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 34 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
NCO026123-BIOS-20230504
Sample ID:
621012009
Matrix:
Sludge
Collect Date:
04-MAY-23 10:56
Receive Date:
05-MAY-23
Collector:
Client
Moisture:
80.4%
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
LC-MS/MS EPA 537Mod PFAS,
Solid "Dry
Weight Corrected"
11-Chloroeicosafluoro-3-
U
ND
0.816
oxaundecane-l-sulfonic acid (F-
53B Minor)
2-(N-ethylperfluoro-l-
J
2.07
1.95
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
7.09
1.93
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
10.9
1.63
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
31.3
1.63
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
U
ND
1.63
acid (3:3 FTCA)(FPrPA)
9-Chlorohexadecafluoro-3-
U
ND
0.816
oxanonane-l-sulfonic acid (F-53B
Major)
N-ethylperfluoro-1-
U
ND
2.03
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
J
4.37
1.36
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
U
ND
2.15
octanesulfonamide (N-McFOSA)
N-methylperfluoro-l-
5.32
1.63
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
0.816
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
U
ND
0.816
Perfluorobutanoic acid (PFBA)
U
ND
0.989
Perfluorodecanesulfonic acid
4.02
0.816
(PFDS)
Perfluorodecanoic acid (PFDA)
J
2.87
1.83
Perfluorododecanoic acid (PFDOA)
J
1.54
0.816
Perfluoroheptanesulfonic acid
U
ND
0.915
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
0.816
Perfluorohexanesulfonic acid
U
ND
0.816
2.33
ng/g
4.85
1 JMB3 05/17/23 1823 2429817 1
4.95
ng/g
4.85
1
4.95
ng/g
4.85
1
4.95
ng/g
4.85
1
4.95
ng/g
4.85
1
4.95
ng/g
4.85
1
2.31
ng/g
4.85
1
4.95
ng/g
4.85
1
4.95
ng/g
4.85
1
4.95
ng/g
4.85
1
4.95
ng/g
4.85
1
2.39
ng/g
4.85
1
2.20
ng/g
4.85
1
2.47
ng/g
4.85
1
2.40
ng/g
4.85
1
4.95
ng/g
4.85
1
2.47
ng/g
4.85
1
2.35
ng/g
4.85
1
2.47
ng/g
4.85
1
2.25
ng/g
4.85
1
Page 35 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-BIOS-20230504
Sample ID: 621012009
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
LC-MS/MS EPA 537Mod PFAS, Solid "Dry
Weight Corrected"
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
Perfluorononanesulfonic acid
U
ND
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
Perfluorooctanesulfonamide
J
1.54
(PFOSA)
Perfluorooctanesulfonic acid (PFOS)
20.3
Perfluorooctanoic acid (PFOA)
U
ND
Perfluoropentanesulfonic acid
U
ND
(PFPeS)
Perfluoropentanoic acid (PFPeA)
U
ND
Perfluorotetradecanoic acid (PFTA)
U
ND
Perfluorotridecanoic Acid (PFTriA)
U
ND
Perfluoroundecanoic acid (PFUnA)
J
1.05
4,8-Dioxa-3H-perfluorononanoic
U
ND
acid (DONA,ADONA)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
FTS)
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nafion Byproduct 4 (PFESA BP4)
UX
ND
Nation Byproduct 5 (PFESA BP5)
UX
ND
Nafion Byproduct 6 (PFESA BP6)
UX
ND
Hydro -EVE
UX
ND
Nafion Byproduct 1 (PFESA BPI)
UX
ND
Nation Byproduct 2 (PFESA BP2)
UX
ND
Nonafluoro-3,6-dioxaheptanoic
U
ND
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic)
UX
ND
0.989
2.47
ng/g
4.85
1
0.816
2.37
ng/g
4.85
1
0.816
2.47
ng/g
4.85
1
0.816
2.47
ng/g
4.85
1
0.989
2.47
ng/g
4.85
1
0.989
2.47
ng/g
4.85
1
0.816
2.33
ng/g
4.85
1
0.816
2.47
ng/g
4.85
1
0.989
2.47
ng/g
4.85
1
0.816
2.47
ng/g
4.85
1
0.816
2.47
ng/g
4.85
1
0.816
2.47
ng/g
4.85
1
33.3
92.8
ng/g
4.85
5 JMB3 05/18/23 0924 2429817
1.63
4.95
ng/g
4.85
1 JMB3 05/18/23 1917 2429817
0.816
2.47
ng/g
4.85
1
1.63
4.95
ng/g
4.85
1
1.63
4.95
ng/g
4.85
1
1.63
4.95
ng/g
4.85
1
1.63
4.95
ng/g
4.85
1
1.63
4.95
ng/g
4.85
1
1.63
4.95
ng/g
4.85
1
1.63
4.95
ng/g
4.85
1
0.816
4.95
ng/g
4.85
1
0.816
2.47
ng/g
4.85
1
1.63
4.95
ng/g
4.85
1
2
3
Page 36 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-BIOS-20230504
Sample ID: 621012009
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
LC-MS/MS EPA 537Mod PFAS, Solid "Dry
Weight Corrected"
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid UX
ND
1.63
4.95
ng/g
4.85
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid UX
ND
1.63
4.95
ng/g
4.85
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid UX
ND
1.63
4.95
ng/g
4.85
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid U
ND
1.63
4.95
ng/g
4.85
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid U
ND
1.63
4.95
ng/g
4.85
1
(PFMOBA)
Perfluoroethoxypropionic acid UX
ND
1.63
4.95
ng/g
4.85
1
(EVE)
R-EVE UX
ND
1.63
4.95
ng/g
4.85
1
Perfluoro(3,5,7,9,1 1 - UX
ND
1.63
4.95
ng/g
4.85
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2- UX
ND
1.63
4.95
ng/g
4.85
1
(pentafluoroethoxy)propanoic acid
(PEPA)
Perfluoro-2- UX
ND
1.63
4.95
ng/g
4.85
1
(perfluoromethoxy)propanoic acid
(PMPA)
Fluorotelomer sulfonic acid 8:2 (8:2 U
ND
238
594
ng/g
4.85
125
JM133 05/18/23 1717 2429817
FTS)
Fluorotelomer sulfonic acid 4:2 (4:2 U
ND
49.5
116
ng/g
4.85
25
JMB3 05/18/23 1249 2429817
FTS)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time
Prep Batch
EPA 537.1 Modified PFCs Extraction in
Solid
RR4
05/16/23
1213
2429816
The following Analytical Methods were performed:
4
61
Method
Description Analyst Comments
1
EPA 537.1 Modified
2
EPA 537.1 Modified
3
EPA 537.1 Modified
4
EPA 537.1 Modified
5
EPA 537.1 Modified
Page 37 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-BIOS-20230504
Sample ID: 621012009
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Notes:
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 38 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
NCO026123-INF-20230504
Sample ID:
621012010
Matrix:
Waste Water
Collect Date:
04-MAY-23 10:48
Receive Date:
05-MAY-23
Collector:
Client
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
FTS)
Perfluorohexadecanoic acid
U
ND
(PFHxDA)
Perfluorooctadecanoic acid
U
ND
(PFODA)
11-Chloroeicosafluoro-3-
U
ND
oxaundecane-l-sulfonic acid (F-
53B Minor)
2-(N-ethylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U
ND
oxanonane-l-sulfonic acid (F-53B
Major)
N-ethylperfluoro-1-
U
ND
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
U
ND
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
U
ND
octanesulfonamide (N-McFOSA)
N-methylperfluoro-l-
U
ND
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
U
ND
Perfluorobutanoic acid (PFBA)
U
ND
Perfluorodecanesulfonic acid
U
ND
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
Perfluorododecanoic acid (PFDOA)
U
ND
165
470
ng/L
0.500
5 JMB3 05/09/23 1415 2424988
673
1880
ng/L
0.500
5
165
480
ng/L
0.500
5
165
500
ng/L
0.500
5
165
500
ng/L
0.500
5
16.5
50.0
ng/L
0.500
1 JMB3 05/08/23 1646 2424988
33.0
100
ng/L
0.500
1
33.0
100
ng/L
0.500
1
33.0
98.2
ng/L
0.500
1
33.0
100
ng/L
0.500
1
33.0
100
ng/L
0.500
1
33.0
100
ng/L
0.500
1
33.0
100
ng/L
0.500
1
16.5
100
ng/L
0.500
1
16.5
44.5
ng/L
0.500
1
20.0
50.0
ng/L
0.500
1
16.5
48.5
ng/L
0.500
1
19.5
50.0
ng/L
0.500
1
16.5
50.0
ng/L
0.500
1
0
FA
Page 39 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-INF-20230504
Sample ID: 621012010
Parameter Qualifier Result
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
Perfluoroheptanesulfonic acid
U
ND
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
Perfluorohexanesulfonic acid
U
ND
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
Perfluorononanesulfonic acid
U
ND
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
Perfluorooctanesulfonamide
U
ND
(PFESA)
Perfluorooctanesulfonic acid (PFOS)
J
38.4
Perfluorooctanoic acid (PFOA)
U
ND
Perfluoropentanesulfonic acid
U
ND
(PFPeS)
Perfluoropentanoic acid (PFPeA)
U
ND
Perfluorotetradecanoic acid (PFTA)
U
ND
Perfluorotridecanoic Acid (PFTriA)
U
ND
Perfluoroundecanoic acid (PFUnA)
U
ND
4,8-Dioxa-3H-perfluorononanoic
U
ND
acid (DONA,ADONA)
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nafion Byproduct 4 (PFESA BP4)
XU
ND
Nation Byproduct 5 (PFESA BP5)
UX
ND
Nation Byproduct 6 (PFESA BP6)
UX
ND
Hydro -EVE
UX
ND
Nation Byproduct 1 (PFESA BPI)
UX
ND
Nafion Byproduct 2 (PFESA BP2)
UX
ND
Nonafluoro-3,6-dioxaheptanoic
U
ND
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
DL
RL
Units
PF
DF Analyst Date Time Batch Method
16.5
47.5
ng/L
0.500
1
16.5
50.0
ng/L
0.500
1
16.5
45.5
ng/L
0.500
1
20.0
50.0
ng/L
0.500
1
17.5
48.0
ng/L
0.500
1
16.5
50.0
ng/L
0.500
1
16.5
50.0
ng/L
0.500
1
20.0
50.0
ng/L
0.500
1
20.0
50.0
ng/L
0.500
1
16.5
47.0
ng/L
0.500
1
16.5
50.0
ng/L
0.500
1
20.0
50.0
ng/L
0.500
1
16.5
50.0
ng/L
0.500
1
16.5
50.0
ng/L
0.500
1
16.5
50.0
ng/L
0.500
1
5.00
12.5
ng/L
0.500
1 RR3 05/12/23 0507 2424988 3
5.00
12.5
ng/L
0.500
1
5.00
12.5
ng/L
0.500
1
5.00
12.5
ng/L
0.500
1
5.00
12.5
ng/L
0.500
1
5.00
12.5
ng/L
0.500
1
5.00
12.5
ng/L
0.500
1
5.00
12.5
ng/L
0.500
1
5.00
12.5
ng/L
0.500
1
5.00
12.5
ng/L
0.500
1
5.00
12.5
ng/L
0.500
1
Page 40 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: May 19, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-INF-20230504 Project: NCDQ00123
Sample ID: 621012010 Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic) UX
ND
5.00
12.5
ng/L
0.500
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid UX
ND
5.00
12.5
ng/L
0.500
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid UX
ND
5.00
12.5
ng/L
0.500
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid UX
ND
5.00
12.5
ng/L
0.500
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid U
ND
5.00
12.5
ng/L
0.500
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid U
ND
5.00
12.5
ng/L
0.500
1
(PFMOBA)
Perfluoroethoxypropionic acid UX
ND
5.00
12.5
ng/L
0.500
1
(EVE)
Perfluoropropanoic acid (PFPrA) JX
409
200
500
ng/L
0.500
1
R-EVE UX
ND
33.0
100
ng/L
0.500
1
Perfluoro(3,5,7,9,11- UX
ND
5.00
12.5
ng/L
0.500
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2- UX
ND
5.00
12.5
ng/L
0.500
1
(pentafluoroethoxy)propanoic acid
(PEPA)
Perfluoro-2- UX
ND
5.00
10.0
ng/L
0.500
1
(perfluoromethoxy)propanoic acid
(PMPA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
SR2
05/08/23
0749 2424987
The following Analytical Methods were performed:
Method Description
Analyst
Comments
1 EPA 537.1 Modified
EPA 537.1 Modified
EPA 537.1 Modified
Notes:
Page 41 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-INF-20230504
Sample ID: 621012010
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 42 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
NCO026123-EFF-20230504
Sample ID:
621012011
Matrix:
Waste Water
Collect Date:
04-MAY-23 10:38
Receive Date:
05-MAY-23
Collector:
Client
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
FTS)
11-Chloroeicosafluoro-3-
U
ND
oxaundecane-l-sulfonic acid (F-
53B Minor)
2-(N-ethylperfluoro-1-
U
ND
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U
ND
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
FTS)
N-ethylperfluoro-1-
U
ND
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
U
ND
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
U
ND
octanesulfonamide (N-McFOSA)
N-methylperfluoro-1-
U
ND
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
8.38
Perfluorobutanoic acid (PFBA)
4.18
Perfluorodecanesulfonic acid
U
ND
(PFDS)
Perfluorodecanoic acid (PFDA)
J
1.89
Perfluorododecanoic acid (PFDOA)
U
ND
Perfluoroheptanesulfonic acid
U
ND
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
4.32
Perfluorohexadecanoic acid
U
ND
31.4
89.4
ng/L
0.0190
25 JMB3 05/09/23 1816 2424988
0.628
1.90
ng/L
0.0190
1 JMB3 05/08/23 1655 2424988
1.26
3.81
ng/L
0.0190
1
1.26
3.81
ng/L
0.0190
1
1.26
3.74
ng/L
0.0190
1
5.12
14.3
ng/L
0.0190
1
1.26
3.65
ng/L
0.0190
1
1.26
3.81
ng/L
0.0190
1
1.26
3.81
ng/L
0.0190
1
1.26
3.81
ng/L
0.0190
1
1.26
3.81
ng/L
0.0190
1
0.628
3.81
ng/L
0.0190
1
0.628
1.69
ng/L
0.0190
1
0.761
1.90
ng/L
0.0190
1
0.628
1.85
ng/L
0.0190
1
0.742
1.90
ng/L
0.0190
1
0.628
1.90
ng/L
0.0190
1
0.628
1.81
ng/L
0.0190
1
0.628
1.90
ng/L
0.0190
1
1.26
3.81
ng/L
0.0190
1
I
Page 43 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-EFF-20230504
Sample ID: 621012011
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
(PFHxDA)
Perfluorohexanesulfonic acid
3.94
(PFHxS)
Perfluorohexanoic acid (PFHxA)
15.9
Perfluorononanesulfonic acid
U
ND
(PFNS)
Perfluorononanoic acid (PFNA)
J
1.00
Perfluorooctadecanoic acid
U
ND
(PFODA)
Perfluorooctanesulfonamide
U
ND
(PFESA)
Perfluorooctanesulfonic acid (PFOS)
14.3
Perfluorooctanoic acid (PFOA)
14.6
Perfluoropentanesulfonic acid
J
0.800
(PFPeS)
Perfluoropentanoic acid (PFPeA)
17.1
Perfluorotetradecanoic acid (PFTA)
U
ND
Perfluorotridecanoic Acid (PFTriA)
U
ND
Perfluoroundecanoic acid (PFUnA)
U
ND
4,8-Dioxa-3H-perfluorononanoic
U
ND
acid (DONA,ADONA)
1,1,2,2-Tctrafluoro-2-(1,2,2,2-
UX
ND
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nafion Byproduct 4 (PFESA BP4)
UX
ND
Nation Byproduct 5 (PFESA BP5)
UX
ND
Nation Byproduct 6 (PFESA BP6)
UX
ND
Hydro -EVE
UX
ND
Nation Byproduct 1 (PFESA BPI)
UX
ND
Nafion Byproduct 2 (PFESA BP2)
UX
ND
Nonafluoro-3,6-dioxaheptanoic
U
ND
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
0.628
1.73
ng/L
0.0190
1
0.761
1.90
ng/L
0.0190
1
0.666
1.83
ng/L
0.0190
1
0.628
1.90
ng/L
0.0190
1
1.26
3.81
ng/L
0.0190
1
0.628
1.90
ng/L
0.0190
1
0.761
1.90
ng/L
0.0190
1
0.761
1.90
ng/L
0.0190
1
0.628
1.79
ng/L
0.0190
1
0.628
1.90
ng/L
0.0190
1
0.761
1.90
ng/L
0.0190
1
0.628
1.90
ng/L
0.0190
1
0.628
1.90
ng/L
0.0190
1
0.628
1.90
ng/L
0.0190
1
0.190
0.476
ng/L
0.0190
1 RR3
0.190
0.476
ng/L
0.0190
1
0.190
0.476
ng/L
0.0190
1
0.190
0.476
ng/L
0.0190
1
0.190
0.476
ng/L
0.0190
1
0.190
0.476
ng/L
0.0190
1
0.190
0.476
ng/L
0.0190
1
0.190
0.476
ng/L
0.0190
1
0.190
0.476
ng/L
0.0190
1
0.190
0.476
ng/L
0.0190
1
0.190
0.476
ng/L
0.0190
1
05/12/23 0522 2424988 3
Page 44 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: May 19, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-EFF-20230504 Project: NCDQ00123
Sample ID: 621012011 Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic) UX ND
0.190
0.476
ng/L
0.0190
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid UX ND
0.190
0.476
ng/L
0.0190
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid JX 0.232
0.190
0.476
ng/L
0.0190
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid UX ND
0.190
0.476
ng/L
0.0190
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid U ND
0.190
0.476
ng/L
0.0190
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid U ND
0.190
0.476
ng/L
0.0190
1
(PFMOBA)
Perfluoroethoxypropionic acid UX ND
0.190
0.476
ng/L
0.0190
1
(EVE)
Perfluoropropanoic acid (PFPrA) X 24.0
7.61
19.0
ng/L
0.0190
1
R-EVE XU ND
1.26
3.81
ng/L
0.0190
1
Perfluoro(3,5,7,9,11- UX ND
0.190
0.476
ng/L
0.0190
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2- UX ND
0.190
0.476
ng/L
0.0190
1
(pentafluoroethoxy)propanoic acid
(PEPA)
Perfluoro-2- JX 0.205
0.190
0.381
ng/L
0.0190
1
(perfluoromethoxy)propanoic acid
(PMPA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
SR2
05/08/23
0749
2424987
The following Analytical Methods were performed:
Method Description
Analyst
Comments
1 EPA 537.1 Modified
EPA 537.1 Modified
EPA 537.1 Modified
Notes:
Page 45 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-EFF-20230504
Sample ID: 621012011
Report Date: May 19, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 46 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Company
Address :
Contact:
Project:
NCDENR
1641 Mail Service Center
Raleigh, North Carolina 27607
Stephanie Zorio
Biosolids Sampling
Certificate of Analysis
Report Date: May 19, 2023
Client Sample ID:
NCO024210-BIOS-20230504 Project: NCD000123
Sample ID:
621012007 Client ID: NCD0001
Matrix:
Sludge
Collect Date:
04-MAY-23
Receive Date:
05-MAY-23
Collector:
Client
Moisture:
69.4%
Parameter Qualifier Result Uncertainty MDC TPU RL Units PF DF Analyst Date Time Batch Mtd.
Gravimetric Solids
'As Received"
The following Analytical Methods were performed
Method Description
ASTM D 2216 (Modified)
Surrogate/Tracer Recovery Test
Notes:
The MDC is a sample specific MDC.
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
Column headers are defined as follows:
DF: Dilution Factor Mtd.: Method
DL: Detection Limit PF: Prep Factor
Lc/LC: Critical Level RL: Reporting Limit
MDA: Minimum Detectable Activity TPU: Total Propagated Uncertainty
MDC: Minimum Detectable Concentration
Batch ID Recovery% Acceptable Limits
Page 47 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607 Report Date:
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NC0026123-SO-20230504-RA-42 Project: NCD000123
Sample ID: 621012008 Client ID: NCD0001
Matrix: Soil
Collect Date: 04-MAY-23
Receive Date: 05-MAY-23
Collector: Client
Moisture: 20.8%
May 19, 2023
Parameter Qualifier Result Uncertainty MDC TPU RL Units PF DF Analyst Date Time Batch Mtd.
Gravimetric Solids
'As Received"
The following Analytical Methods were performed
Method Description
1 ASTM D 2216 (Modified)
Surrogate/Tracer Recovery Test Batch ID Recovery% Acceptable Limits
Notes:
The MDC is a sample specific MDC.
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
Column headers are defined as follows:
DF: Dilution Factor Mtd.: Method
DL: Detection Limit PF: Prep Factor
Lc/LC: Critical Level RL: Reporting Limit
MDA: Minimum Detectable Activity TPU: Total Propagated Uncertainty
MDC: Minimum Detectable Concentration
Page 48 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact:
Stephanie Zorio
Project:
Biosolids Sampling
Client Sample ID: NCO026123-BIOS-20230504
Sample ID:
621012009
Matrix:
Sludge
Collect Date:
04-MAY-23
Receive Date:
05-MAY-23
Collector:
Client
Moisture:
80.4%
Report Date:
Project: NCD000123
Client ID: NCD0001
May 19, 2023
Parameter Qualifier Result Uncertainty MDC TPU RL Units PF DF Analyst Date Time Batch Mtd.
Gravimetric Solids
'As Received"
The following Analytical Methods were performed
Method Description
1 ASTM D 2216 (Modified)
Surrogate/Tracer Recovery Test Batch ID Recovery% Acceptable Limits
Notes:
The MDC is a sample specific MDC.
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
Column headers are defined as follows:
DF: Dilution Factor Mtd.: Method
DL: Detection Limit PF: Prep Factor
Lc/LC: Critical Level RL: Reporting Limit
MDA: Minimum Detectable Activity TPU: Total Propagated Uncertainty
MDC: Minimum Detectable Concentration
Page 49 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
NCDENR Renort Date: May 19, 2023
1641 Mail Service Center
Raleigh, North Carolina
Contact: Stephanie Zorio
Workorder: 621012
Page 1 of 67
Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2424988
QC1205396672 LCS
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
19.1
x 20.7
ng/L
108
(60%-158%)
RR3
05/12/23 03:51
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
18.0
17.4
ng/L
97
(59%-144%)
JMB3
05/08/2316:02
oxaundecane- 1 -sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
19.1
17.8
ng/L
93
(67%-144%)
RR3
05/12/23 03:51
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
19.1
x 18.3
ng/L
96
(58%-144%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
19.1
19.4
ng/L
102
(54%-128%)
JM133
05/08/2316:02
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
19.1
21.3
ng/L
112
(52%-141%)
octanesulfonamido)-ethanol (N-
McFOSE)
4,8-Dioxa-3H-perfluorononanoic
19.1
18.1
ng/L
95
(67%-154%)
acid (DONA,ADONA)
4-
19.1
x 18.5
ng/L
97
(73%-141%)
RR3
05/12/23 03:51
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
17.8
17.8
ng/L
100
(68%-135%)
JM133
05/08/2316:02
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
17.9
12.6
ng/L
70
(56%-151%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
18.2
16.5
ng/L
91
(60%-153%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2 18.4 14.5 ng/L 79 (60%-141%
FTS)
Hydro -EVE 19.1 x 19.0 ng/L 99 (61%-148%) RR3 05/12/23 03:51
Page 50 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 621012
Page 2 of 67
Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2424988
N-ethylperfluoro-l-
19.1
20.0
ng/L
105
(23%-155%) JMB3 05/08/2316:02
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
19.1
18.7
ng/L
98
(57%-139%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
19.1
19.1
ng/L
100
(20%-154%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-1-
19.1
17.2
ng/L
90
(59%-145%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Naflon Byproduct 1 (PFESA BPI)
19.1
X
11.6
ng/L
61
(35%-138%) RR3 05/12/23 03:51
Nation Byproduct 2 (PFESA BP2)
19.1
X
17.7
ng/L
93
(63%-143%)
Nation Byproduct 4 (PFESA BP4)
19.1
X
12.4
ng/L
65
(5%-158%)
Nation Byproduct 5 (PFESA BP5)
19.1
X
17.9
ng/L
93
(5%-149%)
Nafion Byproduct 6 (PFESA BP6)
19.1
X
15.6
ng/L
82
(59%-145%)
Nonafluoro-3,6-dioxahepanoic
19.1
17.5
ng/L
91
(48%-149%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
19.1
19.3
ng/L
101
(52%-148%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,11-
19.1
x
16.9
ng/L
88
(58%-147%)
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
19.1
x
19.6
ng/L
102
(60%-151%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) 19.1 x 19.1 ng/L 100 (62%-148%
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid 19.1 X 17.9 ng/L 93 (60%-144%
(PF02HxA)
Page 51 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 621012
Page 3 of 67
Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2424988
Perfluoro(4-methoxybutanoic) acid
19.1
18.7
ng/L
98
(58%-142%)
RR3
05/12/23 03:51
(PFMOBA)
Perfluoro-2-
19.1
x 18.6
ng/L
97
(50%-150%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
19.1
x 19.8
ng/L
103
(52%-144%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
19.1
19.7
ng/L
103
(60%-149%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid
16.9
15.1
ng/L
89
(70%-144%)
JMB3
05/08/23 16:02
(PFBS)
Perfluorobutanoic acid (PFBA)
19.1
19.7
ng/L
103
(73%-151%)
Perfluorohecanesulfonic acid
18.5
16.9
ng/L
92
(58%-134%)
(PFDS)
Perfluorodecanoic acid (PFDA)
19.1
17.7
ng/L
93
(65%-145%)
Perfluorododecanesulfonic acid
18.5
15.4
ng/L
83
(57%-134%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
19.1
18.4
ng/L
96
(65%-137%)
Perfluoroethoxypropionic acid
19.1
x 13.2
ng/L
69
(20%-160%)
RR3
05/12/23 03:51
(EVE)
Perfluoroheptanesulfonic acid
18.2
20.5
ng/L
113
(68%-138%)
JMB3
05/08/23 16:02
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
19.1
17.5
ng/L
92
(71%-133%
Perfluorohexadecanoic acid
19.1
21.2
ng/L
111
(69%-144%
(PFHxDA)
Perfluorohexanesulfonic acid 17.4 16.8 ng/L 96 (67%-145%
(PFHxS)
Page 52 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 621012
Page 4 of 67
Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2424988
Perfluorohexanoic acid (PFHxA)
19.1
19.9
ng/L
104
(70%-138%)
JMB3
05/08/23 16:02
Perfluorononanesulfonic acid
18.4
18.7
ng/L
102
(64%-133%)
(PFNS)
Perfluorononanoic acid (PFNA)
19.1
18.7
ng/L
98
(69%-133%)
Perfluorooctadecanoic acid
19.1
10.4
ng/L
54
(35%-165%)
(PFODA)
Perfluorooctanesulfonamide
19.1
20.7
ng/L
108
(64%-134%)
(PFOSA)
Perfluorooctanesulfonic acid
19.1
19.7
ng/L
103
(65%-145%)
(PFOS)
Perfluorooctanoic acid (PFOA)
19.1
17.1
ng/L
89
(66%-139%)
Perfluoropentanesulfonic acid
18.0
15.5
ng/L
86
(67%-136%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
19.1
17.8
ng/L
93
(72%-143%)
Perfluoropropanoic acid (PFPrA)
19.1
x 25.7
ng/L
134
(49%-153%)
RR3
05/12/23 03:51
Perfluorotetradecanoic acid (PFTA)
19.1
18.0
ng/L
94
(66%-138%)
JMB3
05/08/23 16:02
Perfluorotridecanoic Acid (PFTriA)
19.1
17.6
ng/L
92
(58%-140%)
Perfluoroundecanoic acid (PFUnA)
19.1
20.0
ng/L
105
(63%-135%)
R-EVE
19.1
X 13.7
ng/L
72
(5%-158%)
RR3
05/12/23 03:51
QC1205396673 LCSD
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
19.5
X 21.6
ng/L 4
110
(0%-30%)
05/12/23 04:06
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
Page 53 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 621012
Page 5 of 67
Parmname
NOM
Sample Qual QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2424988
11-Chloroeicosafluoro-3-
18.4
15.7
ng/L
10
85
(0%-27%)
JMB3
05/08/2316:11
oxaundecane- 1 -sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
19.5
18.8
ng/L
6
96
(0%-30%)
RR3
05/12/23 04:06
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
19.5
x 18.6
ng/L
2
95
(0%-27%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
19.5
21.6
ng/L
10
110
(0%-28%)
JMB3
05/08/2316:11
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-1-
19.5
21.6
ng/L
1
ill
(0%-30%)
octanesulfonamido)-ethanol (N-
McFOSE)
4,8-Dioxa-3H-perfluorononanoic
19.5
21.8
ng/L
18
112
(0%-26%)
acid (DONA,ADONA)
4-
19.5
x 18.8
ng/L
2
96
(0%-24%)
RR3
05/12/23 04:06
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
18.2
18.1
ng/L
2
99
(0%-26%)
JMB3
05/08/2316:11
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
18.3
17.2
ng/L
31
94
(0%-32%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
18.6
19.6
ng/L
17
105
(0%-32%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
18.8
17.3
ng/L
17
92
(0%-36%)
FTS)
Hydro -EVE
19.5
x 20.4
ng/L
7
104
(0%-24%)
RR3
05/12/23 04:06
N-ethylperfluoro-l-
19.5
16.9
ng/L
17
87
(0%-27%)
JMB3
05/08/2316:11
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
19.5
22.8
ng/L
19
117
(0%-27%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
19.5
22.5
ng/L
16
115
(0%-36%)
octanesulfonamide (N-McFOSA)
Page 54 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 621012
Page 6 of 67
Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2424988
N-methylperfluoro-I-
19.5
17.3
ng/L
1
89
(0%-27%) JMB3
05/08/2316:11
octanesulfonamidoacetic acid (N-
McFOSAA)
Nation Byproduct 1 (PFESA BPI)
19.5
x
11.8
ng/L
1
60
(0%-28%) RR3
05/12/23 04:06
Nafion Byproduct 2 (PFESA BP2)
19.5
x
18.6
ng/L
5
95
(0%-23%)
Nafion Byproduct 4 (PFESA BP4)
19.5
x
9.51
ng/L
27
49
(0%-45%)
Naflon Byproduct 5 (PFESA BP5)
19.5
x
14.3
ng/L
22
73
(0%-40%)
Nafion Byproduct 6 (PFESA BP6)
19.5
x
17.1
ng/L
9
88
(0%-26%)
Nonafluoro-3,6-dioxahepanoic
19.5
18.6
ng/L
6
95
(0%-27%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
19.5
19.4
ng/L
1
99
(0%-35%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 I -
19.5
x
16.7
ng/L
1
85
(0%-40%)
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
19.5
x
21.4
ng/L
9
109
(0%-39%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
19.5
x
20.1
ng/L
5
103
(0%-36%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
19.5
x
19.1
ng/L
7
98
(0%-27%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
19.5
18.9
ng/L
1
97
(0%-29%)
(PFMOBA)
Perfluoro-2-
19.5
x
19.0
ng/L
2
97
(0%-30%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
19.5
x
19.6
ng/L
1
100
(0%-31%)
(PFMOAA)
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Parmname
NOM
Sample Qual QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2424988
Perfluoro-3-methoxypropanoic
19.5
19.5
ng/L
1
100
(0%-25%)
RR3
05/12/23 04:06
acid (PFMOPrA)
Perfluorobutanesulfonic acid
17.3
17.1
ng/L
12
99
(0%-35%)
JMB3
05/08/23 16:11
(PFBS)
Perfluorobutanoic acid (PFBA)
19.5
20.6
ng/L
5
105
(0%-20%)
Perfluorodecanesulfonic acid
18.9
17.2
ng/L
2
91
(0%-30%)
(PFDS)
Perfluorodecanoic acid (PFDA)
19.5
19.3
ng/L
8
99
(0%-31%)
Perfluorododecanesulfonic acid
18.9
15.7
ng/L
2
83
(0%-32%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
19.5
20.5
ng/L
11
105
(0%-26%)
Perfluoroethoxypropionic acid
19.5
X 13.0
ng/L
2
66
(0%-30%)
RR3
05/12/23 04:06
(EVE)
Perfluoroheptanesulfonic acid
18.6
20.8
ng/L
1
112
(0%-40%)
JMB3
05/08/23 16:11
(PFHpS)
Perfluorohcptanoic acid (PFHpA)
19.5
20.4
ng/L
15
105
(0%-23%)
Perfluorohexadecanoic acid
19.5
22.2
ng/L
5
114
(0%-26%)
(PFHxDA)
Perfluorohexanesulfonic acid
17.8
18.1
ng/L
8
102
(0%-27%)
(PFHxS)
Perfluorohexanoic acid (PFHxA)
19.5
17.7
ng/L
12
91
(0%-27%)
Perfluorononanesulfonic acid
18.8
19.4
ng/L
4
103
(0%-27%)
(PFNS)
Perfluorononanoic acid (PFNA) 19.5 19.1 ng/L 2 98 (0%-25%
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Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2424988
Perfluorooctadecanoic acid
19.5
12.8
ng/L
21
65
(0%-39%)
JMB3
05/08/23 16:11
(PFODA)
Perfluorooctanesulfonamide
19.5
19.9
ng/L
4
102
(0%-26%)
(PFOSA)
Perfluorooctanesulfonic acid
19.5
19.8
ng/L
0
101
(0%-25%)
(PFOS)
Perfluorooctanoic acid (PFOA)
19.5
20.2
ng/L
17
103
(0%-27%)
Perfluoropentanesulfonic acid
18.4
18.5
ng/L
17
101
(0%-40%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
19.5
19.2
ng/L
8
98
(0%-25%)
Perfluoropropanoic acid (PFPrA)
19.5
X
25.6
ng/L
0
131
(0%-26%)
RR3
05/12/23 04:06
Perfluorotetradecanoic acid (PFTA)
19.5
19.3
ng/L
7
99
(0%-26%)
JMB3
05/08/23 16:11
Perfluorotridecanoic Acid (PFTriA)
19.5
18.9
ng/L
7
97
(0%-31%)
Perfluoroundccanoic acid (PFUnA)
19.5
20.5
ng/L
2
105
(0%-30%)
R-EVE
19.5
X
11.9
ng/L
14
61
(0%-26%)
RR3
05/12/23 04:06
QC1205396671 MB
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
ng/L
05/12/23 03:36
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
U
ND
ng/L
JMB3
05/08/2315:53
oxaundecane-l-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
U
ND
ng/L
RR3
05/12/23 03:36
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
UX
ND
ng/L
(pentafluoroethoxy)propanoic acid
(PEPA)
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Parmname NOM
Sample Qual
QC
Units RPD/D% REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2424988
2-(N-ethylperfluoro-l-
U
ND
ng/L
JMB3
05/08/2315:53
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-I-
U
ND
ng/L
octanesulfonamido)-ethanol (N-
McFOSE)
4,8-Dioxa-3H-perfluorononanoic
U
ND
ng/L
acid (DONA,ADONA)
4-
Ux
ND
ng/L
RR3
05/12/23 03:36
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
U
ND
ng/L
JMB3
05/08/2315:53
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
ng/L
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
ng/L
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
ng/L
FTS)
Hydro -EVE
Ux
ND
ng/L
RR3
05/12/23 03:36
N-ethylperfluoro-I-
U
ND
ng/L
JMB3
05/08/2315:53
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
U
ND
ng/L
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-I-
U
ND
ng/L
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
U
ND
ng/L
octanesulfonamidoacetic acid (N-
McFOSAA)
Nation Byproduct I (PFESA BPI)
Ux
ND
ng/L
RR3
05/12/23 03:36
Naflon Byproduct 2 (PFESA BP2) Ux ND ng/L
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC% Range Anlst Date Time
Perfluorinated Compounds
Batch 2424988
Nation Byproduct 4 (PFESA BP4)
Ux
ND
ng/L RR3 05/12/23 03:36
Nation Byproduct 5 (PFESA BP5)
Ux
ND
ng/L
Nation Byproduct 6 (PFESA BP6)
xU
ND
ng/L
Nonafluoro-316-dioxaheptanoic
U
ND
ng/L
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
ng/L
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 1 -
Ux
ND
ng/L
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
Ux
ND
ng/L
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
Ux
ND
ng/L
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
Ux
ND
ng/L
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
U
ND
ng/L
(PFMOBA)
Perfluoro-2-
Ux
ND
ng/L
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
Ux
ND
ng/L
(PFMOAA)
Perfluoro-3-methoxypropanoic
U
ND
ng/L
acid (PFMOPrA)
Perfluorobutanesulfonic acid U ND ng/L JMB3 05/08/23 15:53
(PFBS)
Perfluorobutanoic acid (PFBA) U ND ng/L
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2424988
Perfluorodecanesulfonic acid
U
ND
ng/L
JMB3 05/08/23 15:53
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
ng/L
Perfluorododecanesulfonic acid
U
ND
ng/L
(PFDoS)
Perfluorododecanoic acid (PFDOA)
U
ND
ng/L
Perfluoroethoxypropionic acid
UX
ND
ng/L
RR3 05/12/23 03:36
(EVE)
Perfluoroheptanesulfonic acid
U
ND
ng/L
JMB3 05/08/23 15:53
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
ng/L
Perfluorohexadecanoic acid
U
ND
ng/L
(PFHxDA)
Perfluorohexanesulfonic acid
U
ND
ng/L
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
ng/L
Perfluorononanesulfonic acid
U
ND
ng/L
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
ng/L
Perfluorooctadecanoic acid
U
ND
ng/L
(PFODA)
Perfluorooctanesulfonamide
U
ND
ng/L
(PFOSA)
Perfluorooctanesulfonic acid U ND ng/L
(PFOS)
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2424988
Perfluorooctanoic acid (PFOA)
U
ND
ng/L
JMB3
05/08/23 15:53
Perfluoropentanesulfonic acid
U
ND
ng/L
(PFPeS)
Perfluoropentanoic acid (PFPeA)
U
ND
ng/L
Perfluoropropanoic acid (PFPrA)
UX
ND
ng/L
RR3
05/12/23 03:36
Perfluorotetradecanoic acid (PFTA)
U
ND
ng/L
JMB3
05/08/23 15:53
Perfluorotridecanoic Acid (PFTriA)
U
ND
ng/L
Perfluoroundecanoic acid (PFUnA)
U
ND
ng/L
R-EVE
UX
ND
ng/L
RR3
05/12/23 03:36
Batch 2426059
QC1205399358 LCS
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
18.4
X
14.7
ng/L
80
(60%-158%)
RR3
05/18/23 05:09
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
17.3
14.8
ng/L
86
(59%-144%)
JMB3
05/10/23 22:52
oxaundecane-l-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
18.4
16.6
ng/L
90
(67%-144%)
RR3
05/18/23 05:09
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
18.4
X
18.3
ng/L
100
(58%-144%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
18.4
20.3
ng/L
110
(54%-128%)
JMB3
05/10/23 22:52
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
18.4
17.0
ng/L
93
(52%-141%)
octanesulfonamido)-ethanol (N-
McFOSE)
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Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2426059
4,8-Dioxa-3H-perfluorononanoic
18.4
16.8
ng/L
91
(67%-154%)
JMB3
05/10/23 22:52
acid (DONA,ADONA)
4-
18.4
x 17.3
ng/L
94
(73%-141%)
RR3
05/18/23 05:09
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
17.1
15.6
ng/L
91
(68%-135%)
JMB3
05/10/23 22:52
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
17.2
17.3
ng/L
101
(56%-151%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
17.4
17.9
ng/L
103
(60%-153%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
17.6
14.2
ng/L
81
(60%-141%)
FTS)
Hydro -EVE
18.4
x 22.8
ng/L
124
(61%-148%)
RR3
05/18/23 05:09
N-ethylperfluoro-I-
18.4
18.6
ng/L
101
(23%-155%)
JMB3
05/10/23 22:52
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
18.4
15.8
ng/L
86
(57%-139%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-I-
18.4
15.6
ng/L
85
(20%-154%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
18.4
14.2
ng/L
77
(59%-145%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Nafion Byproduct 1 (PFESA BPI)
18.4
x 14.2
ng/L
78
(35%-138%)
RR3
05/18/23 05:09
Nafion Byproduct 2 (PFESA BP2)
18.4
x 17.8
ng/L
97
(63%-143%
Nation Byproduct 4 (PFESA BP4)
18.4
x 13.4
ng/L
73
(5%-158%
Nafion Byproduct 5 (PFESA BP5)
18.4
x 17.4
ng/L
94
(5%-149%
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2426059
Nation Byproduct 6 (PFECA BP6)
18.4
X
17.5
ng/L
95
(59%-145%) RR3 05/18/23 05:09
Nonafluoro-316-dioxaheptanoic
18.4
18.0
ng/L
98
(48%-149%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
18.4
15.9
ng/L
87
(52%-148%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 1 -
18.4
X
16.3
ng/L
89
(58%-147%)
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
18.4
X
18.8
ng/L
102
(60%-151%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
18.4
X
17.0
ng/L
93
(62%-148%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
18.4
X
17.2
ng/L
94
(60%-144%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
18.4
17.9
ng/L
98
(58%-142%)
(PFMOBA)
Perfluoro-2-
18.4
X
17.1
ng/L
93
(50%-150%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
18.4
R
17.5
ng/L
95
(52%-144%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
18.4
18.2
ng/L
99
(60%-149%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid
16.3
14.5
ng/L
89
(70%-144%) JMB3 05/10/23 22:52
(PFBS)
Perfluorobutanoic acid (PFBA)
18.4
19.2
ng/L
104
(73%-151%
Perfluorodecanesulfonic acid
17.7
16.1
ng/L
91
(58%-134%
(PFDS)
Perfluorodecanoic acid (PFDA) 18.4 18.7 ng/L 102 (65%-145%
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Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst Date Time
Perfluorinated Compounds
Batch 2426059
Perfluorododecanesulfonic acid
17.8
14.8
ng/L
83
(57%-134%)
JMB3 05/10/23 22:52
(PFDoS)
Perfluorododecanoic acid (PFDOA)
18.4
18.7
ng/L
102
(65%-137%)
Perfluoroethoxypropionic acid
18.4
X 15.8
ng/L
86
(20%-160%)
RR3 05/18/23 05:09
(EVE)
Perfluoroheptanesulfonic acid
17.4
14.4
ng/L
83
(68%-138%)
JMB3 05/10/23 22:52
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
18.4
20.1
ng/L
109
(71%-133%)
Perfluorohexadecanoic acid
18.4
17.2
ng/L
94
(69%-144%)
(PFHxDA)
Perfluorohexanesulfonic acid
16.7
14.9
ng/L
89
(67%-145%)
(PFHxS)
Perfluorohexanoic acid (PFHxA)
18.4
16.6
ng/L
90
(70%-138%)
Perfluorononanesulfonic acid
17.6
15.3
ng/L
87
(64%-133%)
(PFNS)
Perfluorononanoic acid (PFNA)
18.4
17.2
ng/L
94
(69%-133%)
Perfluorooctadecanoic acid
18.4
13.4
ng/L
73
(35%-165%)
(PFODA)
Perfluorooctanesulfonamide
18.4
15.8
ng/L
86
(64%-134%)
(PFOSA)
Perfluorooctanesulfonic acid 18.4 16.8 ng/L 91 (65%-145%
(PFOS)
Perfluorooctanoic acid (PFOA)
18.4
16.1
ng/L
87
(66%-139%
Perfluoropentanesulfonic acid
17.3
14.1
ng/L
82
(67%-136%
(PFPeS)
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Page 16 of 67
Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2426059
Perfluoropentanoic acid (PFPeA)
18.4
17.1
ng/L
93
(72%-143%)
JMB3
05/10/23 22:52
Perfluoropropanoic acid (PFPrA)
18.4
BX
22.4
ng/L
122
(49%-153%)
RR3
05/18/23 05:09
Perfluorotetradecanoic acid (PFTA)
18.4
15.6
ng/L
85
(66%-138%)
JMB3
05/10/23 22:52
Perfluorotridecanoic Acid (PFTriA)
18.4
14.7
ng/L
80
(58%-140%)
Perfluoroundecanoic acid (PFUnA)
18.4
16.9
ng/L
92
(63%-135%)
R-EVE
18.4
X
14.0
ng/L
76
(5%-158%)
RR3
05/18/23 05:09
QC1205399359 LCSD
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
18.0
X
17.8
ng/L
19
98
(0%-30%)
05/18/23 05:24
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
17.0
16.5
ng/L
11
97
(0%-27%)
JMB3
05/10/23 23:01
oxaundecane- 1 -sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
18.0
19.4
ng/L
15
107
(0%-30%)
RR3
05/18/23 05:24
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
18.0
X
21.5
ng/L
16
119
(0%-27%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
18.0
18.6
ng/L
9
103
(0%-28%)
JMB3
05/10/23 23:01
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
18.0
19.0
ng/L
11
105
(0%-30%)
octanesulfonamido)-ethanol (N-
McFOSE)
4,8-Dioxa-3H-perfluorononanoic
18.0
18.5
ng/L
10
103
(0%-26%)
acid (DONA,ADONA)
4-
18.0
X
18.8
ng/L
8
104
(0%-24%)
RR3
05/18/23 05:24
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
16.8
18.3
ng/L
16
109
(0%-26%)
JMB3
05/10/23 23:01
oxanonane-l-sulfonic acid (F-53B
Major)
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Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2426059
Fluorotelomer sulfonic acid 4:2 (4:2
16.9
15.3
ng/L
12
91
(0%-32%)
JMB3
05/10/23 23:01
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
17.1
1
11.9
ng/L
41 *
69
(0%-32%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
17.3
15.9
ng/L
11
92
(0%-36%)
FTS)
Hydro -EVE
18.0
X
25.3
ng/L
10
140
(0%-24%)
RR3
05/18/23 05:24
N-ethylperfluoro-1-
18.0
17.7
ng/L
5
98
(0%-27%)
JMB3
05/10/23 23:01
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
18.0
16.7
ng/L
5
93
(0%-27%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-I-
18.0
16.7
ng/L
7
93
(0%-36%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
18.0
17.7
ng/L
22
98
(0%-27%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Nafion Byproduct 1 (PFESA BPI)
18.0
X
15.6
ng/L
9
87
(0%-28%)
RR3
05/18/23 05:24
Nation Byproduct 2 (PFESA BP2)
18.0
R
20.0
ng/L
12
111
(0%-23%)
Nafion Byproduct 4 (PFESA BP4)
18.0
X
13.3
ng/L
1
74
(0%-45%)
Nafion Byproduct 5 (PFESA BP5)
18.0
X
16.6
ng/L
4
92
(0%-40%)
Nafion Byproduct 6 (PFESA BP6)
18.0
X
20.7
ng/L
17
115
(0%-26%)
Nonafluoro-316-dioxaheptanoic
18.0
20.8
ng/L
14
115
(0%-27%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic 18.0 20.5 ng/L 25 113 (0%-35%
acid (PFEESA or PES)
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Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2426059
Perfluoro(3,5,7,9,11-
18.0
X
18.6
ng/L
13
103
(0%-40%) RR3
05/18/23 05:24
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
18.0
X
21.7
ng/L
14
120
(0%-39%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
18.0
X
20.2
ng/L
17
112
(0%-36%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
18.0
X
20.0
ng/L
15
ill
(0%-27%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
18.0
19.7
ng/L
9
109
(0%-29%)
(PFMOBA)
Perfluoro-2-
18.0
X
20.4
ng/L
18
113
(0%-30%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
18.0
X
20.7
ng/L
17
115
(0%-31%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
18.0
21.6
ng/L
17
120
(0%-25%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid
16.0
15.0
ng/L
3
94
(0%-35%) JMB3
05/10/23 23:01
(PFBS)
Perfluorobutanoic acid (PFBA)
18.0
18.3
ng/L
4
102
(0%-20%)
Perfluorodecanesulfonic acid
17.4
17.4
ng/L
8
100
(0%-30%)
(PFDS)
Perfluorodecanoic acid (PFDA)
18.0
17.0
ng/L
9
94
(0%-31%)
Perfluorododecanesulfonic acid
17.5
15.6
ng/L
6
90
(0%-32%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
18.0
17.4
ng/L
7
96
(0%-26%)
Perfluoroethoxypropionic acid
18.0
X 16.9
ng/L
7
94
(0%-30%) RR3 05/18/23 05:24
(EVE)
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Parmname
NOM
Sample Qual QC
Units
RPD/D%
REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2426059
Perfluoroheptanesulfonic acid
17.1
17.7
ng/L
20
103
(0%-40%) JMB3 05/10/23 23:01
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
18.0
17.0
ng/L
17
94
(0%-23%)
Perfluorohexadecanoic acid
18.0
19.2
ng/L
11
106
(0%-26%)
(PFHxDA)
Perfluorohexanesulfonic acid
16.4
16.3
ng/L
9
99
(0%-27%)
(PFHxS)
Perfluorohexanoic acid (PFHxA)
18.0
17.0
ng/L
3
94
(0%-27%)
Perfluorononanesulfonic acid
17.3
17.3
ng/L
12
100
(0%-27%)
(PFNS)
Perfluorononanoic acid (PFNA)
18.0
18.3
ng/L
6
102
(0%-25%)
Perfluorooctadecanoic acid
18.0
9.17
ng/L
38
51
(0%-39%)
(PFODA)
Perfluorooctanesulfonamide
18.0
17.5
ng/L
10
97
(0%-26%)
(PFOSA)
Perfluorooctanesulfonic acid
18.0
19.2
ng/L
13
107
(0%-25%)
(PFOS)
Perfluorooctanoic acid (PFOA)
18.0
17.6
ng/L
9
98
(0%-27%)
Perfluoropentanesulfonic acid
16.9
15.9
ng/L
12
94
(0%-40%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
18.0
17.3
ng/L
1
96
(0%-25%)
Perfluoropropanoic acid (PFPrA)
18.0
BX 27.4
ng/L
20
152
(0%-26%) RR3 05/18/23 05:24
Perfluorotetradecanoic acid (PFTA)
18.0
17.7
ng/L
13
98
(0%-26%) JMB3 05/10/23 23:01
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Parmname NOM
Sample Qual
QC
Units RPD/D% REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2426059
Perfluorotridecanoic Acid (PFTriA) 18.0
16.8
ng/L 14 93
(0%-31%)
JMB3
05/10/23 23:01
Perfluoroundecanoic acid (PFUnA) 18.0
17.8
ng/L 5 99
(0%-30%)
R-EVE 18.0
X
15.9
ng/L 12 88
(0%-26%)
RR3
05/18/23 05:24
QC1205399357 MB
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
ng/L
05/18/23 04:54
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
U
ND
ng/L
JMB3
05/10/23 22:34
oxaundecane- 1 -sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
U
ND
ng/L
RR3
05/18/23 04:54
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
UX
ND
ng/L
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
U
ND
ng/L
JMB3
05/10/23 22:34
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
ng/L
octanesulfonamido)-ethanol (N-
McFOSE)
4,8-Dioxa-3H-perfluorononanoic
U
ND
ng/L
acid (DONA,ADONA)
4-
U%
ND
ng/L
RR3
05/18/23 04:54
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
U
ND
ng/L
JMB3
05/10/23 22:34
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
ng/L
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
ng/L
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
ng/L
FTS)
Page 69 of 129 SDG: 621012

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Parmname
NOM Sample Qual
QC
Units RPD/D% REC% Range Anlst Date Time
Perfluorinated Compounds
Batch 2426059
Hydro -EVE
Ux
ND
ng/L RR3 05/18/23 04:54
N-ethylperfluoro-l-
U
ND
ng/L JMB3 05/10/23 22:34
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
U
ND
ng/L
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
U
ND
ng/L
octanesulfonamide (N-McFOSA)
N-methylperfluoro-1-
U
ND
ng/L
octanesulfonamidoacetic acid (N-
McFOSAA)
Naflon Byproduct 1 (PFESA BPI)
Ux
ND
ng/L RR3 05/18/23 04:54
Nafon Byproduct 2 (PFESA BP2)
Ux
ND
ng/L
Nafon Byproduct 4 (PFESA BP4)
Ux
ND
ng/L
Naflon Byproduct 5 (PFESA BP5)
Ux
ND
ng/L
Nation Byproduct 6 (PFESA BP6)
Ux
ND
ng/L
Nonafluoro-3,6-dioxaheptanoic
U
ND
ng/L
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
ng/L
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 I -
Ux
ND
ng/L
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
Ux
ND
ng/L
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) Ux ND ng/L
acid (PF030A)
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2426059
Perfluoro(3,5-dioxahexanoic) acid
Ux
ND
ng/L
RR3 05/18/23 04:54
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
U
ND
ng/L
(PFMOBA)
Perfluoro-2-
UX
ND
ng/L
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
UX
ND
ng/L
(PFMOAA)
Perfluoro-3-methoxypropanoic
U
ND
ng/L
acid (PFMOPrA)
Perfluorobutanesulfonic acid
U
ND
ng/L
JMB3 05/10/23 22:34
(PFBS)
Perfluorobutanoic acid (PFBA)
U
ND
ng/L
Perfluorodecanesulfonic acid
U
ND
ng/L
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
ng/L
Perfluorododecanesulfonic acid
U
ND
ng/L
(PFDoS)
Perfluorododecanoic acid (PFDOA)
U
ND
ng/L
Perfluoroethoxypropionic acid
UX
ND
ng/L
RR3 05/18/23 04:54
(EVE)
Perfluoroheptanesulfonic acid U ND ng/L JMB3 05/10/23 22:34
(PFHpS)
Perfluoroheptanoic acid (PFHpA) U ND ng/L
Perfluorohexadecanoic acid U ND ng/L
(PFHxDA)
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC% Range Anlst Date Time
Perfluorinated Compounds
Batch 2426059
Perfluorohexanesulfonic acid
U
ND
ng/L JMB3 05/10/23 22:34
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
ng/L
Perfluorononanesulfonic acid
U
ND
ng/L
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
ng/L
Perfluorooctadecanoic acid
U
ND
ng/L
(PFODA)
Perfluorooctanesulfonamide
U
ND
ng/L
(PFOSA)
Perfluorooctanesulfonic acid
U
ND
ng/L
(PFOS)
Perfluorooctanoic acid (PFOA)
U
ND
ng/L
Perfluoropentanesulfonic acid
U
ND
ng/L
(PFPeS)
Perfluoropentanoic acid (PFPeA) U ND ng/L
Perfluoropropanoic acid (PFPrA) 7x 7.61 ng/L RR3 05/18/23 04:54
Perfluorotetradecanoic acid (PFTA) U ND ng/L JMB3 05/10/23 22:34
Perfluorotridecanoic Acid (PFTriA) U ND ng/L
Perfluoroundecanoic acid (PFUnA) U ND ng/L
R-EVE UX ND ng/L RR3 05/18/23 04:54
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Page 24 of 67
Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2426643
QC1205400360 LCS
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
4.74
X 4.83
ng/g
102
(50%-150%)
RR3
05/16/23 00:55
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
4.46
4.66
ng/g
104
(69%-143%)
JMB3
05/10/2319:09
oxaundecane- 1 -sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
4.74
4.48
ng/g
95
(72%-137%)
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
4.74
4.70
ng/g
99
(72%-137%)
RR3
05/16/23 00:55
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
4.74
X 4.93
ng/g
104
(59%-145%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
4.74
5.40
ng/g
114
(61%-131%)
JMB3
05/10/2319:09
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-1-
4.74
4.34
ng/g
92
(66%-140%)
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
4.74
5.05
ng/g
107
(49%-150%)
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
4.74
4.38
ng/g
92
(54%-145%)
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
4.74
4.39
ng/g
93
(59%-131%)
acid (3:3 FTCA)(FPrPA)
4,8-Dioxa-3H-perfluorononanoic
4.74
4.78
ng/g
101
(70%-135%)
acid (DONA,ADONA)
4-
4.74
X 4.78
ng/g
101
(60%-141%)
RR3
05/16/23 00:55
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
4.42
4.51
ng/g
102
(66%-140%)
JMB3
05/10/2319:09
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
4.43
4.80
ng/g
108
(63%-144%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
4.50
3.59
ng/g
80
(62%-148%)
FTS)
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Page 25 of 67
Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range
Anlst Date Time
Perfluorinated Compounds
Batch 2426643
Fluorotelomer sulfonic acid 8:2 (8:2
4.55
4.53
ng/g
100
(65%-144%)
JMB3 05/10/23 19:09
FTS)
Hydro -EVE
4.74
x
5.32
ng/g
112
(50%-150%)
RR3 05/16/23 00:55
N-ethylperfluoro-l-
4.74
4.74
ng/g
100
(73%-140%)
JMB3 05/10/2319:09
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
4.74
3.95
ng/g
83
(66%-141%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
4.74
4.08
ng/g
86
(70%-136%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-1-
4.74
4.11
ng/g
87
(68%-141%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Nafion Byproduct 1 (PFESA BPI)
4.74
x
4.64
ng/g
98
(63%-138%)
RR3 05/16/23 00:55
Nafion Byproduct 2 (PFESA BP2)
4.74
x
4.92
ng/g
104
(64%-142%)
Nafion Byproduct 4 (PFESA BP4)
4.74
x
5.32
ng/g
112
(50%-150%)
Nafion Byproduct 5 (PFESA BP5)
4.74
x
5.89
ng/g
124
(50%-150%)
Nafion Byproduct 6 (PFESA BP6)
4.74
x
4.60
ng/g
97
(50%-150%)
Nonafluoro-3,6-dioxaheptanoic
4.74
4.84
ng/g
102
(50%-150%)
acid (NFDHA or PFECA B)
Nonafluoro-316-dioxaheptanoic
4.74
3.44
ng/g
72
(50%-150%)
JMB3 05/10/2319:09
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic 4.74 5.00 ng/g 105 (50%-150%) RR3 05/16/23 00:55
acid (PFEESA or PES)
Perfluoro(2-ethoxyethane)sulfonic 4.74 4.10 ng/g 87 (50%-150%) JMB3 05/10/2319:09
acid (PFEESA or PES)
Page 74 of 129 SDG: 621012

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Page 26 of 67
Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range
Anlst Date Time
Perfluorinated Compounds
Batch 2426643
Perfluoro(3,5,7,9,11-
4.74
X
4.39
ng/g
93
(58%-151%)
RR3 05/16/23 00:55
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
4.74
X
4.87
ng/g
103
(59%-158%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
4.74
X
4.73
ng/g
100
(58%-156%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
4.74
X
4.64
ng/g
98
(67%-142%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
4.74
4.74
ng/g
100
(64%-142%)
JMB3 05/10/23 19:09
(PFMOBA)
Perfluoro(4-methoxybutanoic) acid
4.74
4.71
ng/g
99
(64%-142%)
RR3 05/16/23 00:55
(PFMOBA)
Perfluoro-2-
4.74
X
5.08
ng/g
107
(50%-150%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
4.74
X
4.92
ng/g
104
(64%-146%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
4.74
4.75
ng/g
100
(60%-159%)
acid (PFMOPrA)
Perfluoro-3-methoxypropanoic
4.74
5.10
ng/g
108
(60%-159%)
JMB3 05/10/2319:09
acid (PFMOPrA)
Perfluorobutanesulfonic acid
4.19
3.71
ng/g
89
(71%-136%)
(PFBS)
Perfluorobutanoic acid (PFBA)
4.74
4.94
ng/g
104
(66%-141%)
Perfluorodecanesulfonic acid
4.57
4.77
ng/g
104
(70%-139%)
(PFDS)
Perfluorodecanoic acid (PFDA)
4.74
4.93
ng/g
104
(66%-139%
Perfluorododecanesulfonic acid
4.59
4.61
ng/g
100
(54%-148%
(PFDoS)
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Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst Date Time
Perfluorinated Compounds
Batch 2426643
Perfluorododecanoic acid (PFDOA)
4.74
4.68
ng/g
99
(70%-139%)
JMB3 05/10/23 19:09
Perfluoroethoxypropionic acid
4.74
x 4.30
ng/g
91
(50%-150%)
RR3 05/16/23 00:55
(EVE)
Perfluoroheptanesulfonic acid
4.50
4.38
ng/g
97
(72%-138%)
JMB3 05/10/23 19:09
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
4.74
4.62
ng/g
97
(72%-132%)
Perfluorohexanesulfonic acid
4.32
4.10
ng/g
95
(68%-139%)
(PFHxS)
Perfluorohexanoic acid (PFHxA)
4.74
4.33
ng/g
91
(70%-135%)
Perfluorononanesulfonic acid
4.55
4.57
ng/g
100
(60%-138%)
(PFNS)
Perfluorononanoic acid (PFNA)
4.74
4.41
ng/g
93
(70%-136%)
Perfluorooctanesulfonamide
4.74
4.58
ng/g
97
(76%-138%)
(PFOSA)
Perfluorooctanesulfonic acid
4.74
4.57
ng/g
96
(73%-135%)
(PFOS)
Perfluorooctanoic acid (PFOA)
4.74
4.47
ng/g
94
(72%-135%)
Perfluoropentanesulfonic acid
4.45
3.62
ng/g
81
(66%-138%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
4.74
4.65
ng/g
98
(72%-155%)
Perfluorotetradecanoic acid (PFTA)
4.74
4.43
ng/g
93
(72%-139%
Perfluorotridecanoic Acid (PFTriA)
4.74
4.38
ng/g
92
(60%-149%
Page 76 of 129 SDG: 621012

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Parmname NOM
Sample Qual
QC
Units RPD/D%
REC% Range Anlst
Date Time
Perfluorinated Compounds
Batch 2426643
Perfluoroundecanoic acid (PFUnA) 4.74
4.72
ng/g
100 (70%-135%) JMB3
05/10/23 19:09
R-EVE 4.74
x
5.06
ng/g
107 (50%-150%) RR3
05/16/23 00:55
QC1205400359 MB
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
Ux
ND
ng/g
05/16/23 00:40
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
U
ND
ng/g
JMB3
05/10/2319:00
oxaundecane- 1 -sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
U
ND
ng/g
RR3
05/16/23 00:40
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
U
ND
ng/g
JMB3
05/10/2319:00
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
Ux
ND
ng/g
RR3
05/16/23 00:40
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
U
ND
ng/g
JMB3
05/10/2319:00
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
ng/g
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
U
ND
ng/g
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
U
ND
ng/g
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
U
ND
ng/g
acid (3:3 FTCA)(FPrPA)
4,8-Dioxa-3H-perfluorononanoic
U
ND
ng/g
acid (DONA,ADONA)
4-
Ux
ND
ng/g
RR3
05/16/23 00:40
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
U
ND
ng/g
JMB3
05/10/2319:00
oxanonane-l-sulfonic acid (F-53B
Major)
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Parmname NOM
Sample Qual
QC
Units RPD/D% REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2426643
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
ng/g
JMB3
05/10/23 19:00
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
ng/g
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
ng/g
FTS)
Hydro -EVE
Ux
ND
ng/g
RR3
05/16/23 00:40
N-ethylperfluoro-1-
U
ND
ng/g
JMB3
05/10/2319:00
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
U
ND
ng/g
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-I-
U
ND
ng/g
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
U
ND
ng/g
octanesulfonamidoacetic acid (N-
McFOSAA)
Nafion Byproduct 1 (PFESA BPI)
Ux
ND
ng/g
RR3
05/16/23 00:40
Nation Byproduct 2 (PFESA BP2) Ux ND ng/g
Nafion Byproduct 4 (PFESA BP4) Ux ND ng/g
Nafion Byproduct 5 (PFESA BP5) Ux ND ng/g
Nafion Byproduct 6 (PFESA BP6) Ux ND ng/g
Nonafluoro-316-dioxaheptanoic U ND ng/g JMB3 05/10/2319:00
acid (NFDHA or PFECA B)
Nonafluoro-316-dioxaheptanoic U ND ng/g RR3 05/16/23 00:40
acid (NFDHA or PFECA B)
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2426643
Perfluoro(2-ethoxyethane)sulfonic
U
ND
ng/g
JMB3
05/10/23 19:00
acid (PFEESA or PES)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
ng/g
RR3
05/16/23 00:40
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 1 -
Ux
ND
ng/g
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
Ux
ND
ng/g
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
Ux
ND
ng/g
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
Ux
ND
ng/g
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
U
ND
ng/g
JMB3
05/10/23 19:00
(PFMOBA)
Perfluoro(4-methoxybutanoic) acid
U
ND
ng/g
RR3
05/16/23 00:40
(PFMOBA)
Perfluoro-2-
Ux
ND
ng/g
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
Ux
ND
ng/g
(PFMOAA)
Perfluoro-3-methoxypropanoic
U
ND
ng/g
JMB3
05/10/23 19:00
acid (PFMOPrA)
Perfluoro-3-methoxypropanoic
U
ND
ng/g
RR3
05/16/23 00:40
acid (PFMOPrA)
Perfluorobutanesulfonic acid
U
ND
ng/g
JMB3
05/10/23 19:00
(PFBS)
Perfluorobutanoic acid (PFBA)
U
ND
ng/g
Perfluorodecanesulfonic acid
U
ND
ng/g
(PFDS)
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC% Range Anlst Date Time
Perfluorinated Compounds
Batch 2426643
Perfluorodecanoic acid (PFDA)
U
ND
ng/g JMB3 05/10/23 19:00
Perfluorododecanesulfonic acid
U
ND
ng/g
(PFDoS)
Perfluorododecanoic acid (PFDOA)
U
ND
ng/g
Perfluoroethoxypropionic acid
UX
ND
ng/g RR3 05/16/23 00:40
(EVE)
Perfluoroheptanesulfonic acid
U
ND
ng/g JMB3 05/10/23 19:00
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
ng/g
Perfluorohexanesulfonic acid
U
ND
ng/g
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
ng/g
Perfluorononanesulfonic acid
U
ND
ng/g
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
ng/g
Perfluorooctanesulfonamide
U
ND
ng/g
(PFOSA)
Perfluorooctanesulfonic acid
U
ND
ng/g
(PFOS)
Perfluorooctanoic acid (PFDA)
U
ND
ng/g
Perfluoropentanesulfonic acid
U
ND
ng/g
(PFPeS)
Perfluoropentanoic acid (PFPeA)
U
ND
ng/g
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Parmname
NOM
Sample
Qual
QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2426643
Perfluorotetradecanoic acid (PFTA)
U
ND
ng/g
JMB3
05/10/23 19:00
Perfluorotridecanoic Acid (PFTriA)
U
ND
ng/g
Perfluoroundecanoic acid (PFUnA)
U
ND
ng/g
R-EVE
UX
ND
ng/g
RR3
05/16/23 00:40
QC1205400361 620804001 MS
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
16.4
UX
ND
X
15.6
ng/g
95
(42%-158%)
05/16/23 02:11
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
15.4
U
ND
14.3
ng/g
93
(43%-141%)
JMB3
05/10/23 20:03
oxaundecane-l-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
16.4
U
ND
16.9
ng/g
103
(61%-150%)
RR3
05/16/23 02:11
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
16.4
UX
ND
X
15.7
ng/g
96
(43%-154%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
16.4
U
ND
17.3
ng/g
106
(49%-153%)
JMB3
05/10/23 20:03
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
16.4
U
ND
15.4
ng/g
94
(54%-154%)
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
16.4
U
ND
17.6
ng/g
107
(30%-157%)
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
16.4
U
ND
17.5
ng/g
107
(31%-158%)
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
16.4
U
ND
16.2
ng/g
99
(32%-153%)
acid (3:3 FTCA)(FPrPA)
4,8-Dioxa-3H-perfluorononanoic
16.4
U
ND
15.9
ng/g
97
(63%-143%)
acid (DONA,ADONA)
4-
16.4
UX
ND
X
15.4
ng/g
94
(54%-161%)
RR3
05/16/23 02:11
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2426643
9-Chlorohexadecafluoro-3-
15.2
U
ND
15.0
ng/g
99
(62%-146%)
JMB3
05/10/23 20:03
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
15.3
U
ND
15.0
ng/g
98
(62%-148%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
15.5
U
ND
14.2
ng/g
84
(50%-153%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
15.7
U
ND
13.4
ng/g
85
(53%-158%)
FTS)
Hydro -EVE
16.4
UX
ND X
17.7
ng/g
108
(51%-148%)
RR3
05/16/23 02:11
N-ethylperfluoro-1-
16.4
U
ND
15.7
ng/g
96
(48%-148%)
JMB3
05/10/23 20:03
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-I-
16.4
J
1.01
17.6
ng/g
101
(65%-152%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-I-
16.4
U
ND
16.2
ng/g
99
(55%-151%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
16.4
J
1.38
17.1
ng/g
96
(59%-152%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Nafion Byproduct 1 (PFESA BPI)
16.4
UX
ND X
14.2
ng/g
87
(60%-147%)
RR3
05/16/23 02:11
Nafion Byproduct 2 (PFESA BP2)
16.4
UX
ND X
16.2
ng/g
99
(65%-150%
Nafion Byproduct 4 (PFESA BP4)
16.4
UX
ND X
49.6
ng/g
303 *
(40%-160%
Nafion Byproduct 5 (PFESA BP5)
16.4
UX
ND X
37.0
ng/g
226 *
(40%-160%
Nation Byproduct 6 (PFESA BP6)
16.4
UX
ND X
17.2
ng/g
105
(53%-153%
Nonafluoro-316-dioxaheptanoic
16.4
U
ND
16.7
ng/g
102
(43%-163%
acid (NFDHA or PFECA B)
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Parmname
NOM
Sample
Qual
QC
Units RPD/D%
REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2426643
Perfluoro(2-ethoxyethane)sulfonic
16.4
U
ND
16.9
ng/g
103
(48%-148%) RR3
05/16/23 02:11
acid (PFEESA or PES)
Perfluoro(3,5,7,9,11-
16.4
UX
ND
X
16.2
ng/g
99
(42%-167%)
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
16.4
UX
ND
X
17.4
ng/g
106
(49%-162%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
16.4
UX
ND
X
16.5
ng/g
101
(44%-167%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
16.4
UX
ND
X
18.1
ng/g
111
(57%-153%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
16.4
U
ND
15.8
ng/g
97
(47%-166%)
(PFMOBA)
Perfluoro-2-
16.4
UX
ND
X
16.9
ng/g
103
(50%-150%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
16.4
UX
ND
X
14.4
ng/g
88
(49%-169%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
16.4
U
ND
16.2
ng/g
99
(40%-162%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid
14.5
U
ND
13.8
ng/g
95
(67%-146%) JMB3
05/10/23 20:03
(PFBS)
Perfluorobutanoic acid (PFBA)
16.4
U
ND
22.0
ng/g
135
(56%-156%)
Perfluorodecanesulfonic acid
15.8
U
ND
16.0
ng/g
101
(61%-150%)
(PFDS)
Perfluorodecanoic acid (PFDA)
16.4
J
2.15
16.6
ng/g
89
(59%-153%)
Perfluorododecanesulfonic acid
15.8
U
ND
14.6
ng/g
92
(39%-149%)
(PFDoS)
Perfluorododecanoic acid (PFDOA) 16.4 J 0.833 16.7 ng/g 97 (59%-147%
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2426643
Perfluoroethoxypropionic acid
16.4
UX
ND X
15.8
ng/g
96
(49%-151%) RR3
05/16/23 02:11
(EVE)
Perfluoroheptanesulfonic acid
15.5
U
ND
15.0
ng/g
96
(50%-156%) JMB3
05/10/23 20:03
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
16.4
U
ND
16.8
ng/g
102
(61%-149%)
Perfluorohexanesulfonic acid
14.9
U
ND
15.8
ng/g
106
(64%-150%)
(PFHxS)
Perfluorohexanoic acid (PFHxA)
16.4
J
0.929
17.3
ng/g
100
(61%-151%)
Perfluorononanesulfonic acid
15.7
U
ND
15.2
ng/g
97
(47%-147%)
(PFNS)
Perfluorononanoic acid (PFNA)
16.4
J
0.965
17.9
ng/g
104
(58%-152%)
Perfluorooctanesulfonamide
16.4
U
ND
16.5
ng/g
101
(68%-153%)
(PFOSA)
Perfluorooctanesulfonic acid
16.4
4.19
19.6
ng/g
94
(53%-157%)
(PFOS)
Perfluorooctanoic acid (PFOA)
16.4
J
0.769
17.3
ng/g
101
(53%-155%)
Perfluoropentanesulfonic acid
15.4
U
ND
15.5
ng/g
101
(58%-150%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
16.4 U
ND
15.8
ng/g
96
(66%-150%
PerFluorotetradecanoic acid (PFTA)
16.4 J
0.683
17.4
ng/g
102
(60%-157%
Perfluorotridecanoic Acid (PFTriA)
16.4 J
0.576
17.0
ng/g
101
(35%-157%
Perfluoroundecanoic acid (PFUnA)
16.4 J
0.905
16.8
ng/g
97
(58%-154%
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QC Summary
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Parmname NOM Sample Qual QC Units RPD/D% REC% Range Anlst Date Time
Perfluorinated Compounds
Batch 2426643
R-EVE 16.4 UX ND X 38.7 ng/g 237* (40%-160%) RR3 05/16/23 02:11
QC1205400362 620804001 MSD
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
15.8
UX
ND X
17.0
ng/g
8
107
(0%-30%)
05/16/23 02:26
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
14.9
U
ND
13.5
ng/g
6
90
(0%-30%)
JMB3 05/10/23 20:12
oxaundecane- 1 -sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
15.8
U
ND
16.8
ng/g
1
106
(0%-30%)
RR3 05/16/23 02:26
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
15.8
UX
ND X
14.8
ng/g
6
93
(0%-30%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
15.8
U
ND
15.4
ng/g
12
97
(0%-30%)
JM133 05/10/23 20:12
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
15.8
U
ND
15.1
ng/g
2
95
(0%-30%)
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
15.8
U
ND
17.2
ng/g
2
109
(0%-30%)
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
15.8
U
ND
16.5
ng/g
6
104
(0%-30%)
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
15.8
U
ND
15.8
ng/g
2
100
(0%-30%)
acid (3:3 FTCA)(FPrPA)
4,8-Dioxa-3H-perfluorononanoic
15.8
U
ND
16.6
ng/g
4
105
(0%-30%)
acid (DONA,ADONA)
4-
15.8
UX
ND X
16.2
ng/g
5
102
(0%-30%)
RR3 05/16/23 02:26
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
14.8
U
ND
14.5
ng/g
4
98
(0%-30%)
JMB3 05/10/23 20:12
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
14.8
U
ND
13.5
ng/g
10
91
(0%-30%)
FTS)
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Parmname
NOM
Sample
Qual
QC
Units
RPD/D%
REC%
Range
Anlst Date Time
Perfluorinated Compounds
Batch 2426643
Fluorotelomer sulfonic acid 6:2 (6:2
15.1
U
ND
16.9
ng/g
17
105
(0%-30%)
JMB3 05/10/23 20:12
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
15.2
U
ND
11.4
ng/g
16
75
(0%-30%)
FTS)
Hydro -EVE
15.8
UX
ND
X
19.2
ng/g
8
121
(0%-30%)
RR3 05/16/23 02:26
N-ethylperfluoro-l-
15.8
U
ND
17.1
ng/g
8
108
(0%-30%)
JMB3 05/10/23 20:12
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-I-
15.8
J
1.01
17.7
ng/g
1
105
(0%-30%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
15.8
U
ND
15.7
ng/g
4
99
(0%-30%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
15.8
J
1.38
14.6
ng/g
16
84
(0%-30%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Nafion Byproduct 1 (PFESA BPI)
15.8
UX
ND
X
15.4
ng/g
9
97
(0%-30%)
RR3 05/16/23 02:26
Nafion Byproduct 2 (PFESA BP2)
15.8
Ux
ND
X
15.7
ng/g
3
99
(0%-30%)
Nation Byproduct 4 (PFESA BP4)
15.8
UX
ND
X
39.3
ng/g
23
248 *
(0%-30%)
Nafion Byproduct 5 (PFESA BP5)
15.8
UX
ND
x
37.0
ng/g
0
234 *
(0%-30%)
Nafion Byproduct 6 (PFESA BP6)
15.8
UX
ND
x
18.8
ng/g
9
119
(0%-30%)
Nonafluoro-316-dioxaheptanoic
15.8
U
ND
16.3
ng/g
2
103
(0%-30%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
15.8
U
ND
16.4
ng/g
3
104
(0%-30%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 1 - 15.8 UX ND X 14.4 ng/g 12 91 (0%-30%
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
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Parmname
NOM
Sample
Qual
QC
Units
RPD/D%
REC%
Range
Anlst Date Time
Perfluorinated Compounds
Batch 2426643
Perfluoro(3,5,7,9-tetraoxadecanoic)
15.8
UX
ND
X
16.4
ng/g
6
103
(0%-30%)
RR3 05/16/23 02:26
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
15.8
UX
ND
X
17.5
ng/g
6
110
(0%-30%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
15.8
UX
ND
X
15.9
ng/g
13
101
(0%-30%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
15.8
U
ND
14.6
ng/g
8
92
(0%-30%)
(PFMOBA)
Perfluoro-2-
15.8
UX
ND
X
16.3
ng/g
4
103
(0%-30%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
15.8
UX
ND
X
13.6
ng/g
5
86
(0%-30%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
15.8
U
ND
15.0
ng/g
8
95
(0%-30%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid
14.0
U
ND
13.9
ng/g
1
99
(0%-30%)
JMB3 05/10/23 20:12
(PFBS)
Perfluorobutanoic acid (PFBA)
15.8
U
ND
20.3
ng/g
8
128
(0%-30%)
Perfluorodecanesulfonic acid
15.3
U
ND
15.5
ng/g
3
101
(0%-30%)
(PFDS)
Perfluorodecanoic acid (PFDA)
15.8
J
2.15
15.9
ng/g
4
87
(0%-30%)
Perfluorododecanesulfonic acid
15.3
U
ND
14.3
ng/g
2
93
(0%-30%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
15.8
J
0.833
16.3
ng/g
2
97
(0%-30%)
Perfluoroethoxypropionic acid
15.8
UX
ND
X
16.1
ng/g
2
102
(0%-30%)
RR3 05/16/23 02:26
(EVE)
Perfluoroheptanesulfonic acid 15.1 U ND 14.4 ng/g 4 96 (0%-30%) JMB3 05/10/23 20:12
(PFHpS)
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Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2426643
Perfluoroheptanoic acid (PFHpA)
15.8
U
ND
14.0
ng/g
18
88
(0%-30%) JMB3 05/10/23 20:12
Perfluorohexanesulfonic acid
14.4
U
ND
14.4
ng/g
9
100
(0%-30%)
(PFHxS)
Perfluorohexanoic acid (PFHxA)
15.8
J
0.929
17.9
ng/g
3
107
(0%-30%)
Perfluorononanesulfonic acid
15.2
U
ND
15.4
ng/g
1
101
(0%-30%)
(PFNS)
Perfluorononanoic acid (PFNA)
15.8
J
0.965
16.7
ng/g
7
99
(0%-30%)
Perfluorooctanesulfonamide
15.8
U
ND
16.0
ng/g
3
101
(0%-30%)
(PFOSA)
Perfluorooctanesulfonic acid
15.8
4.19
18.9
ng/g
4
93
(0%-30%)
(PFOS)
Perfluorooctanoic acid (PFOA)
15.8
J
0.769
17.3
ng/g
0
105
(0%-30%)
Perfluoropentanesulfonic acid
14.9
U
ND
13.5
ng/g
14
91
(0%-30%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
15.8
U
ND
15.0
ng/g
5
95
(0%-30%)
Perfluorotetradecanoic acid (PFTA)
15.8
J
0.683
17.2
ng/g
1
104
(0%-30%)
Perfluorotndecanoic Acid (PFTriA)
15.8
J
0.576
15.3
ng/g
11
93
(0%-30%)
Perfluoroundecanoic acid (PFUnA)
15.8
J
0.905
16.7
ng/g
1
99
(0%-30%)
R-EVE
15.8
UX
ND X
36.9
ng/g
5
233 *
(0%-30%) RR3 05/16/23 02:26
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2428642
QC1205403891 LCS
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
19.5
X
17.8
ng/L
91
(60%-158%)
RR3
05/18/23 00:21
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
18.4
16.2
ng/L
88
(59%-144%)
JMB3
05/16/2310:10
oxaundecane- 1 -sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
19.5
18.5
ng/L
95
(67%-144%)
RR3
05/18/23 00:21
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
19.5
X
20.4
ng/L
105
(58%-144%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
19.5
18.5
ng/L
95
(54%-128%)
JMB3
05/16/2310:10
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
19.5
16.3
ng/L
84
(52%-141%)
octanesulfonamido)-ethanol (N-
McFOSE)
4,8-Dioxa-3H-perfluorononanoic
19.5
18.7
ng/L
96
(67%-154%)
acid (DONA,ADONA)
4-
19.5
X
19.0
ng/L
97
(73%-141%)
RR3
05/18/23 00:21
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
18.2
17.4
ng/L
96
(68%-135%)
JMB3
05/16/2310:10
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
18.2
19.6
ng/L
107
(56%-151%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
18.5
17.8
ng/L
96
(60%-153%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
18.7
19.5
ng/L
104
(60%-141%)
FTS)
Hydro -EVE
19.5
X
25.4
ng/L
130
(61%-148%)
RR3
05/18/23 00:21
N-ethylperfluoro-l-
19.5
22.7
ng/L
116
(23%-155%)
JMB3
05/16/2310:10
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
19.5
17.8
ng/L
91
(57%-139%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2428642
N-methylperfluoro-I-
19.5
19.6
ng/L
101
(20%-154%) JMB3
05/16/2310:10
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
19.5
19.1
ng/L
98
(59%-145%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Nafion Byproduct 1 (PFESA BPI)
19.5
x
13.3
ng/L
68
(35%-138%) RR3
05/18/23 00:21
Nafion Byproduct 2 (PFESA BP2)
19.5
x
20.0
ng/L
103
(63%-143%)
Nafion Byproduct 4 (PFESA BP4)
19.5
x
19.5
ng/L
100
(5%-158%)
Nafion Byproduct 5 (PFESA BP5)
19.5
x
25.8
ng/L
132
(5%-149%)
Nafion Byproduct 6 (PFESA BP6)
19.5
x
17.7
ng/L
91
(59%-145%)
Nonafluoro-3,6-dioxahepanoic
19.5
18.9
ng/L
97
(48%-149%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
19.5
18.9
ng/L
97
(52%-148%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 I -
19.5
x
17.6
ng/L
90
(58%-147%)
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
19.5
x
19.0
ng/L
98
(60%-151%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
19.5
x
19.5
ng/L
100
(62%-148%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
19.5
x
18.7
ng/L
96
(60%-144%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
19.5
19.1
ng/L
98
(58%-142%)
(PFMOBA)
Perfluoro-2- 19.5 x 19.7 ng/L 101 (50%-150%
(perfluoromethoxy)propanoic acid
(PMPA)
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Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2428642
Perfluoro-2-methoxyacetic acid
19.5
x 20.3
ng/L
104
(52%-144%)
RR3
05/18/23 00:21
(PFMOAA)
Perfluoro-3-methoxypropanoic
19.5
20.9
ng/L
107
(60%-149%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid
17.3
17.6
ng/L
102
(70%-144%)
JMB3
05/16/23 10:10
(PFBS)
Perfluorobutanoic acid (PFBA)
19.5
18.4
ng/L
94
(73%-151%)
Perfluorodecanesulfonic acid
18.8
17.4
ng/L
93
(58%-134%)
(PFDS)
Perfluorodecanoic acid (PFDA)
19.5
17.6
ng/L
90
(65%-145%)
Perfluorododecanesulfonic acid
18.9
16.6
ng/L
88
(57%-134%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
19.5
19.7
ng/L
101
(65%-137%)
Perfluoroethoxypropionic acid
19.5
X 15.0
ng/L
77
(20%-160%)
RR3
05/18/23 00:21
(EVE)
Perfluoroheptanesulfonic acid
18.5
17.7
ng/L
96
(68%-138%)
JMB3
05/16/23 10:10
(PFHpS)
Perfluorohepanoic acid (PFHpA)
19.5
19.3
ng/L
99
(71%-133%)
Perfluorohexadecanoic acid
19.5
19.7
ng/L
101
(69%-144%)
(PFHxDA)
Perfluorohexanesulfonic acid 17.8 15.3 ng/L 86 (67%-145%
(PFHxS)
Perfluorohexanoic acid (PFHxA)
19.5
19.2
ng/L
98
(70%-138%
Perfluorononanesulfonic acid
18.7
18.8
ng/L
100
(64%-133%
(PFNS)
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Parmname
NOM
Sample Qual QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2428642
Perfluorononanoic acid (PFNA)
19.5
20.6
ng/L
105
(69%-133%)
JMB3
05/16/23 10:10
Perfluorooctadecanoic acid
19.5
17.3
ng/L
89
(35%-165%)
(PFODA)
Perfluorooctanesulfonamide
19.5
19.4
ng/L
99
(64%-134%)
(PFOSA)
Perfluorooctanesulfonic acid
19.5
18.3
ng/L
94
(65%-145%)
(PFOS)
Perfluorooctanoic acid (PFOA)
19.5
18.9
ng/L
97
(66%-139%)
Perfluoropentanesulfonic acid
18.3
15.0
ng/L
82
(67%-136%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
19.5
18.4
ng/L
94
(72%-143%)
Perfluoropropanoic acid (PFPrA)
19.5
X 25.9
ng/L
133
(49%-153%)
RR3
05/18/23 00:21
Perfluorotetradecanoic acid (PFTA)
19.5
18.8
ng/L
97
(66%-138%)
JMB3
05/16/23 10:10
Perfluorotridecanoic Acid (PFTriA)
19.5
19.4
ng/L
99
(58%-140%)
Perfluoroundecanoic acid (PFUnA)
19.5
19.3
ng/L
99
(63%-135%)
R-EVE
19.5
X 21.3
ng/L
109
(5%-158%)
RR3
05/18/23 00:21
QC1205403892 LCSD
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
19.3
X 18.5
ng/L
4
96
(0%-30%)
05/18/23 00:36
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
18.2
18.3
ng/L
12
101
(0%-27%)
JMB3
05/16/2310:27
oxaundecane-l-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
19.3
18.2
ng/L
2
94
(0%-30%)
RR3
05/18/23 00:36
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
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Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2428642
2,3,3,3-Tetrafluoro-2-
19.3
x
19.2
ng/L
6
100
(0%-27%)
RR3
05/18/23 00:36
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
19.3
21.3
ng/L
14
110
(0%-28%)
JMB3
05/16/2310:27
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-1-
19.3
19.0
ng/L
15
99
(0%-30%)
octanesulfonamido)-ethanol (N-
McFOSE)
4,8-Dioxa-3H-perfluorononanoic
19.3
19.9
ng/L
6
103
(0%-26%)
acid (DONA,ADONA)
4-
19.3
X
19.2
ng/L
1
99
(0%-24%)
RR3
05/18/23 00:36
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
18.0
19.1
ng/L
9
106
(0%-26%)
JMB3
05/16/2310:27
oxanonane-l-sulfonic acid (F-5313
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
18.0
18.4
ng/L
6
102
(0%-32%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
18.3
16.4
ng/L
8
90
(0%-32%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
18.5
23.2
ng/L
18
125
(0%-36%)
FTS)
Hydro -EVE
19.3
X
23.5
ng/L
7
122
(0%-24%)
RR3
05/18/23 00:36
N-ethylperfluoro-l-
19.3
21.8
ng/L
4
113
(0%-27%)
JMB3
05/16/2310:27
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
19.3
21.6
ng/L
19
112
(0%-27%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-I-
19.3
20.2
ng/L
3
105
(0%-36%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
19.3
18.3
ng/L
4
95
(0%-27%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Naflon Byproduct 1 (PFESA BPI)
19.3
X
14.3
ng/L
7
74
(0%-28%)
RR3
05/18/23 00:36
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Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2428642
Nation Byproduct 2 (PFESA BP2)
19.3
X
19.2
ng/L
4
100
(0%-23%) RR3 05/18/23 00:36
Nation Byproduct 4 (PFESA BP4)
19.3
X
17.3
ng/L
12
90
(0%-45%)
Nation Byproduct 5 (PFESA BP5)
19.3
X
23.6
ng/L
9
122
(0%-40%)
Naflon Byproduct 6 (PFESA BP6)
19.3
X
18.3
ng/L
3
95
(0%-26%)
Nonafluoro-316-dioxahepanoic
19.3
19.9
ng/L
5
103
(0%-27%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
19.3
18.9
ng/L
0
98
(0%-35%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,11-
19.3
X
18.6
ng/L
5
96
(0%-40%)
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
19.3
X
19.8
ng/L
4
102
(0%-39%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
19.3
X
20.3
ng/L
4
105
(0%-36%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
19.3
X
19.0
ng/L
2
98
(0%-27%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
19.3
18.8
ng/L
2
98
(0%-29%)
(PFMOBA)
Perfluoro-2-
19.3
x
19.6
ng/L
0
102
(0%-30%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
19.3
X
18.5
ng/L
9
96
(0%-31%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
19.3
19.9
ng/L
5
103
(0%-25%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid 17.1 16.8 ng/L 4 99 (0%-35%) JMB3 05/16/23 10:27
(PFBS)
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Parmname
NOM
Sample Qual QC
Units
RPD/D%
REC%
Range
Anlst Date Time
Perfluorinated Compounds
Batch 2428642
Perfluorobutanoic acid (PFBA)
19.3
19.8
ng/L
8
103
(0%-20%)
JMB3 05/16/23 10:27
Perfluorodecanesulfonic acid
18.6
19.3
ng/L
10
104
(0%-30%)
(PFDS)
Perfluorodecanoic acid (PFDA)
19.3
18.2
ng/L
3
95
(0%-31%)
Perfluorododecanesulfonic acid
18.7
18.5
ng/L
11
99
(0%-32%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
19.3
19.8
ng/L
0
103
(0%-26%)
Perfluoroethoxypropionic acid
19.3
X 14.7
ng/L
2
76
(0%-30%)
RR3 05/18/23 00:36
(EVE)
Perfluoroheptanesulfonic acid
18.3
19.2
ng/L
8
105
(0%-40%)
JMB3 05/16/23 10:27
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
19.3
18.8
ng/L
3
98
(0%-23%)
Perfluorohexadecanoic acid
19.3
23.2
ng/L
16
120
(0%-26%)
(PFHxDA)
Perfluorohexanesulfonic acid
17.6
16.6
ng/L
8
94
(0%-27%)
(PFHxS)
Perfluorohexanoic acid (PFHxA)
19.3
20.2
ng/L
5
105
(0%-27%)
Perfluorononanesulfonic acid
18.5
19.7
ng/L
5
106
(0%-27%)
(PFNS)
Perfluorononanoic acid (PFNA)
19.3
18.9
ng/L
9
98
(0%-25%)
Perfluorooctadecanoic acid
19.3
19.1
ng/L
10
99
(0%-39%)
(PFODA)
Perfluorooctanesulfonamide
19.3
19.6
ng/L
1
101
(0%-26%)
(PFOSA)
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Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2428642
Perfluorooctanesulfonic acid
19.3
19.4
ng/L
6
101
(0%-25%)
JMB3
05/16/23 10:27
(PFOS)
Perfluorooctanoic acid (PFOA)
19.3
19.9
ng/L
5
103
(0%-27%)
Perfluoropentanesulfonic acid
18.1
15.7
ng/L
5
87
(0%-40%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
19.3
19.1
ng/L
3
99
(0%-25%)
Perfluoropropanoic acid (PFPrA)
19.3
x
23.6
ng/L
9
123
(0%-26%)
RR3
05/18/23 00:36
Perfluorotetradecanoic acid (PFTA)
19.3
19.9
ng/L
5
103
(0%-26%)
JMB3
05/16/23 10:27
Perfluorotridecanoic Acid (PFTriA)
19.3
21.2
ng/L
9
110
(0%-31%)
Perfluoroundecanoic acid (PFUnA)
19.3
19.8
ng/L
2
103
(0%-30%)
R-EVE
19.3
x
16.9
ng/L
23
88
(0%-26%)
RR3
05/18/23 00:36
QC1205403890 MB
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
Ux
ND
ng/L
05/18/23 00:06
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
U
ND
ng/L
JMB3
05/16/2310:01
oxaundecane-l-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
U
ND
ng/L
RR3
05/18/23 00:06
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
Ux
ND
ng/L
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
U
ND
ng/L
JMB3
05/16/2310:01
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-1-
U
ND
ng/L
octanesulfonamido)-ethanol (N-
McFOSE)
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Parmname NOM
Sample Qual
QC
Units RPD/D% REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2428642
4,8-Dioxa-3H-perfluorononanoic
U
ND
ng/L
JMB3
05/16/2310:01
acid (DONA,ADONA)
4-
Ux
ND
ng/L
RR3
05/18/23 00:06
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
U
ND
ng/L
JMB3
05/16/2310:01
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
ng/L
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
ng/L
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
ng/L
FTS)
Hydro -EVE
Ux
ND
ng/L
RR3
05/18/23 00:06
N-ethylperfluoro-I-
U
ND
ng/L
JMB3
05/16/2310:01
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
U
ND
ng/L
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-I-
U
ND
ng/L
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
U
ND
ng/L
octanesulfonamidoacetic acid (N-
McFOSAA)
Nafion Byproduct 1 (PFESA BPI)
Ux
ND
ng/L
RR3
05/18/23 00:06
Nafion Byproduct 2 (PFESA BP2) Ux ND ng/L
Nation Byproduct 4 (PFESA BP4) Ux ND ng/L
Nafion Byproduct 5 (PFESA BP5) Ux ND ng/L
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC% Range Anlst Date Time
Perfluorinated Compounds
Batch 2428642
Nation Byproduct 6 (PFECA BP6)
Ux
ND
ng/L RR3 05/18/23 00:06
Nonafluoro-316-dioxaheptanoic
U
ND
ng/L
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
ng/L
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 1 -
Ux
ND
ng/L
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
Ux
ND
ng/L
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
Ux
ND
ng/L
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
Ux
ND
ng/L
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
U
ND
ng/L
(PFMOBA)
Perfluoro-2-
Ux
ND
ng/L
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
Ux
ND
ng/L
(PFMOAA)
Perfluoro-3-methoxypropanoic
U
ND
ng/L
acid (PFMOPrA)
Perfluorobutanesulfonic acid
U
ND
ng/L JMB3 05/16/23 10:01
(PFBS)
Perfluorobutanoic acid (PFBA) U ND ng/L
Perfluorodecanesulfonic acid U ND ng/L
(PFDS)
Perfluorodecanoic acid (PFDA) U ND ng/L
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2428642
Perfluorododecanesulfonic acid
U
ND
ng/L
JMB3 05/16/23 10:01
(PFDoS)
Perfluorododecanoic acid (PFDOA)
U
ND
ng/L
Perfluoroethoxypropionic acid
UX
ND
ng/L
RR3 05/18/23 00:06
(EVE)
Perfluoroheptanesulfonic acid
U
ND
ng/L
JMB3 05/16/23 10:01
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
ng/L
Perfluorohexadecanoic acid
U
ND
ng/L
(PFHxDA)
Perfluorohexanesulfonic acid
U
ND
ng/L
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
ng/L
Perfluorononanesulfonic acid
U
ND
ng/L
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
ng/L
Perfluorooctadecanoic acid
U
ND
ng/L
(PFODA)
Perfluorooctanesulfonamide
U
ND
ng/L
(PFOSA)
Perfluorooctanesulfonic acid U ND ng/L
(PFOS)
Perfluorooctanoic acid (PFOA) U ND ng/L
Perfluoropentanesulfonic acid U ND ng/L
(PFPeS)
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QC Summary
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2428642
Perfluoropentanoic acid (PFPeA)
U
ND
ng/L
JMB3
05/16/23 10:01
Perfluoropropanoic acid (PFPrA)
U%
ND
ng/L
RR3
05/18/23 00:06
Perfluorotetradecanoic acid (PFTA)
U
ND
ng/L
JMB3
05/16/23 10:01
Perfluorotridecanoic Acid (PFTriA)
U
ND
ng/L
Perfluoroundecanoic acid (PFUnA)
U
ND
ng/L
R-EVE
UX
ND
ng/L
RR3
05/18/23 00:06
Batch 2429817
QC1205406636 LCS
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
4.95
X
4.79
ng/g
97
(50%-150%)
RR3
05/18/23 08:41
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
4.66
4.53
ng/g
97
(69%-143%)
JMB3
05/17/2317:48
oxaundecane-l-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
4.95
4.91
ng/g
99
(72%-137%)
RR3
05/18/23 08:41
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
4.95
X
5.54
ng/g
112
(59%-145%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
4.95
5.35
ng/g
108
(61%-131%)
JMB3
05/17/2317:48
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
4.95
4.07
ng/g
82
(66%-140%)
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
4.95
4.94
ng/g
100
(49%-150%)
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
4.95
5.15
ng/g
104
(54%-145%)
acid (5:3 FTCA)(FPePA)
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Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2429817
4,4,5,5,6,6-Heptafluorohexanoic
4.95
5.61
ng/g
113
(59%-131%)
JMB3
05/17/2317:48
acid (3:3 FTCA)(FPrPA)
4,8-Dioxa-3H-perfluorononanoic
4.95
5.44
ng/g
110
(70%-135%)
acid (DONA,ADONA)
4-
4.95
X 4.84
ng/g
98
(60%-141%)
RR3
05/18/23 08:41
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
4.61
4.56
ng/g
99
(66%-140%)
JMB3
05/17/2317:48
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
4.63
5.77
ng/g
125
(63%-144%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
4.70
5.94
ng/g
126
(62%-148%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
4.75
4.99
ng/g
105
(65%-144%)
FTS)
Hydro -EVE
4.95
X 6.70
ng/g
135
(50%-150%)
RR3
05/18/23 08:41
N-ethylperfluoro-l-
4.95
5.18
ng/g
105
(73%-140%)
JMB3
05/17/2317:48
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-I-
4.95
4.74
ng/g
96
(66%-141%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-I-
4.95
4.88
ng/g
99
(70%-136%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
4.95
5.54
ng/g
112
(68%-141%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Nation Byproduct 1 (PFESA BPI)
4.95
x 4.95
ng/g
100
(63%-138%)
RR3
05/18/23 08:41
Nation Byproduct 2 (PFESA BP2)
4.95
x
5.09
ng/g
103
(64%-142%
Naflon Byproduct 4 (PFESA BP4)
4.95
X
5.35
ng/g
108
(50%-150%
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2429817
Nation Byproduct 5 (PFESA BP5)
4.95
X
4.59
ng/g
93
(50%-150%) RR3 05/18/23 08:41
Nation Byproduct 6 (PFESA BP6)
4.95
X
5.09
ng/g
103
(50%-150%)
Nonafluoro-316-dioxaheptanoic
4.95
5.34
ng/g
108
(50%-150%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
4.95
5.12
ng/g
103
(50%-150%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 1 -
4.95
X
4.45
ng/g
90
(58%-151%)
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
4.95
X
5.53
ng/g
112
(59%-158%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
4.95
X
4.99
ng/g
101
(58%-156%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
4.95
X
5.02
ng/g
101
(67%-142%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
4.95
5.30
ng/g
107
(64%-142%)
(PFMOBA)
Perfluoro-2-
4.95
X
5.17
ng/g
104
(50%-150%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
4.95
x
5.21
ng/g
105
(64%-146%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
4.95
5.78
ng/g
117
(60%-159%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid 4.38 4.32 ng/g 98 (71%-136%) JMB3 05/17/23 17:48
(PFBS)
Perfluorobutanoic acid (PFBA)
4.95
4.70
ng/g
95
(66%-141%
Perfluorodecanesulfonic acid
4.78
4.80
ng/g
100
(70%-139%
(PFDS)
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Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst Date Time
Perfluorinated Compounds
Batch 2429817
Perfluorodecanoic acid (PFDA)
4.95
4.94
ng/g
100
(66%-139%)
JMB3 05/17/23 17:48
Perfluorododecanesulfonic acid
4.79
4.45
ng/g
93
(54%-148%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
4.95
4.99
ng/g
101
(70%-139%)
Perfluoroethoxypropionic acid
4.95
X 4.39
ng/g
89
(50%-150%)
RR3 05/18/23 08:41
(EVE)
Perfluoroheptanesulfonic acid
4.70
4.42
ng/g
94
(72%-138%)
JMB3 05/17/23 17:48
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
4.95
5.06
ng/g
102
(72%-132%)
Perfluorohexanesulfonic acid
4.51
4.30
ng/g
95
(68%-139%)
(PFHxS)
Perfluorohexanoic acid (PFHxA)
4.95
5.09
ng/g
103
(70%-135%)
Perfluorononanesulfonic acid
4.75
4.60
ng/g
97
(60%-138%)
(PFNS)
Perfluorononanoic acid (PFNA)
4.95
4.28
ng/g
86
(70%-136%)
Perfluorooctanesulfonamide
4.95
4.73
ng/g
96
(76%-138%)
(PFOSA)
Perfluorooctanesulfonic acid
4.95
4.71
ng/g
95
(73%-135%)
(PFOS)
Perfluorooctanoic acid (PFDA)
4.95
4.95
ng/g
100
(72%-135%)
Perfluoropentanesulfonic acid
4.65
4.39
ng/g
94
(66%-138%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
4.95
4.86
ng/g
98
(72%-155%)
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC% Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2429817
Perfluorotetradecanoic acid (PFTA)
4.95
5.03
ng/g
102 (72%-139%)
JMB3
05/17/23 17:48
Perfluorotridecanoic Acid (PFTriA)
4.95
4.82
ng/g
97 (60%-149%)
Perfluoroundecanoic acid (PFUnA)
4.95
4.59
ng/g
93 (70%-135%)
R-EVE
4.95
X
5.45
ng/g
110 (50%-150%)
RR3
05/18/23 08:41
QC1205406635 MB
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
ng/g
05/18/23 08:26
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
U
ND
ng/g
JMB3
05/17/2317:39
oxaundecane-l-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
U
ND
ng/g
RR3
05/18/23 08:26
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
UX
ND
ng/g
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
U
ND
ng/g
JMB3
05/17/2317:39
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
ng/g
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
U
ND
ng/g
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
U
ND
ng/g
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
U
ND
ng/g
acid (3:3 FTCA)(FPrPA)
4,8-Dioxa-3H-perfluorononanoic
U
ND
ng/g
acid (DONA,ADONA)
4-
UX
ND
ng/g
RR3
05/18/23 08:26
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
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Parmname NOM
Sample Qual
QC
Units RPD/D% REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2429817
9-Chlorohexadecafluoro-3-
U
ND
ng/g
JMB3
05/17/2317:39
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
ng/g
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
ng/g
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
ng/g
FTS)
Hydro -EVE
Ux
ND
ng/g
RR3
05/18/23 08:26
N-ethylperfluoro-1-
U
ND
ng/g
JMB3
05/17/2317:39
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-I-
U
ND
ng/g
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-I-
U
ND
ng/g
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
U
ND
ng/g
octanesulfonamidoacetic acid (N-
McFOSAA)
Nafion Byproduct 1 (PFESA BPI)
Ux
ND
ng/g
RR3
05/18/23 08:26
Nafion Byproduct 2 (PFESA BP2) Ux ND ng/g
Nafion Byproduct 4 (PFESA BP4) Ux ND ng/g
Nafion Byproduct 5 (PFESA BP5) Ux ND ng/g
Nation Byproduct 6 (PFESA BP6) Ux ND ng/g
Nonafluoro-316-dioxaheptanoic U ND ng/g
acid (NFDHA or PFECA B)
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC% Range Anlst Date Time
Perfluorinated Compounds
Batch 2429817
Perfluoro(2-ethoxyethane)sulfonic
U
ND
ng/g RR3 05/18/23 08:26
acid (PFEESA or PES)
Perfluoro(3,5,7,9,11-
Ux
ND
ng/g
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
UX
ND
ng/g
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
UX
ND
ng/g
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
UX
ND
ng/g
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
U
ND
ng/g
(PFMOBA)
Perfluoro-2-
UX
ND
ng/g
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
UX
ND
ng/g
(PFMOAA)
Perfluoro-3-methoxypropanoic
U
ND
ng/g
acid (PFMOPrA)
Perfluorobutanesulfonic acid
U
ND
ng/g JMB3 05/17/23 17:39
(PFBS)
Perfluorobutanoic acid (PFBA)
U
ND
ng/g
Perfluorodecanesulfonic acid
U
ND
ng/g
(PFDS)
Perfluorodecanoic acid (PFDA) U ND ng/g
Perfluorododecanesulfonic acid U ND ng/g
(PFDoS)
Perfluorododecanoic acid (PFDOA) U ND ng/g
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC% Range Anlst Date Time
Perfluorinated Compounds
Batch 2429817
Perfluoroethoxypropionic acid
UX
ND
ng/g RR3 05/18/23 08:26
(EVE)
Perfluoroheptanesulfonic acid
U
ND
ng/g JMB3 05/17/23 17:39
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
ng/g
Perfluorohexanesulfonic acid
U
ND
ng/g
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
ng/g
Perfluorononanesulfonic acid
U
ND
ng/g
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
ng/g
Perfluorooctanesulfonamide
U
ND
ng/g
(PFOSA)
Perfluorooctanesulfonic acid
U
ND
ng/g
(PFOS)
Perfluorooctanoic acid (PFOA) U ND ng/g
Perfluoropentanesulfonic acid U ND ng/g
(PFPeS)
Perfluoropentanoic acid (PFPeA) U ND ng/g
Perfluorotetradecanoic acid (PFTA) U ND ng/g
Perfluorotridecanoic Acid (PFTriA) U ND ng/g
Perfluoroundecanoic acid (PFUnA) U ND ng/g
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QC Summary
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Parmname NOM Sample Qual QC Units RPD/D% REC% Range Anlst Date Time
Perfluorinated Compounds
Batch 2429817
R-EVE UX ND ng/g RR3 05/18/23 08:26
QC1205406637 621012008 MS
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
6.16
UX
ND X
6.77
ng/g
110
(42%-158%)
05/18/23 09:11
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
5.80
U
ND
4.81
ng/g
83
(43%-141%)
JMB3 05/17/2318:06
oxaundecane- 1 -sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
6.16
U
ND
6.29
ng/g
102
(61%-150%)
RR3 05/18/23 09:11
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
6.16
UX
ND X
6.85
ng/g
111
(43%-154%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
6.16
U
ND
6.93
ng/g
113
(49%-153%)
JM133 05/17/2318:06
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
6.16
U
ND
6.24
ng/g
101
(54%-154%)
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
6.16
U
ND
5.96
ng/g
97
(30%-157%)
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
6.16
U
ND
6.14
ng/g
100
(31%-158%)
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
6.16
U
ND
6.29
ng/g
102
(32%-153%)
acid (3:3 FTCA)(FPrPA)
4,8-Dioxa-3H-perfluorononanoic
6.16
U
ND
6.73
ng/g
109
(63%-143%)
acid (DONA,ADONA)
4-
6.16
UX
ND X
6.88
ng/g
112
(54%-161%)
RR3 05/18/23 09:11
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
5.74
U
ND
5.75
ng/g
100
(62%-146%)
JM133 05/17/2318:06
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
5.76
U
ND
6.10
ng/g
106
(62%-148%)
FTS)
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Parmname
NOM
Sample
Qual
QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2429817
Fluorotelomer sulfonic acid 6:2 (6:2
5.85
U
ND
5.03
ng/g
86
(50%-153%)
JMB3
05/17/23 18:06
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
5.91
U
ND
6.59
ng/g
111
(53%-158%)
05/18/23 09:06
FTS)
Hydro -EVE
6.16
UX
ND
X
8.27
ng/g
134
(51 %-148%)
RR3
05/18/23 09:11
N-ethylperfluoro-l-
6.16
U
ND
6.07
ng/g
99
(48%-148%)
JMB3
05/17/2318:06
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-I-
6.16
U
ND
6.64
ng/g
103
(65%-152%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
6.16
U
ND
6.11
ng/g
99
(55%-151%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
6.16
J
0.751
6.98
ng/g
101
(59%-152%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Nafion Byproduct 1 (PFESA BPI)
6.16
UX
ND
X
6.28
ng/g
102
(60%-147%)
RR3
05/18/23 09:11
Nafion Byproduct 2 (PFESA BP2)
6.16
UX
ND
X
6.86
ng/g
111
(65%-150%)
Nation Byproduct 4 (PFESA BP4)
6.16
UX
ND
X
15.2
ng/g
247 *
(40%-160%)
Nafion Byproduct 5 (PFESA BP5)
6.16
UX
ND
X
12.2
ng/g
198 *
(40%-160%)
Nafion Byproduct 6 (PFESA BP6)
6.16
UX
ND
X
6.53
ng/g
106
(53%-153%)
Nonafluoro-316-dioxaheptanoic
6.16
U
ND
6.31
ng/g
103
(43%-163%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
6.16
U
ND
6.79
ng/g
110
(48%-148%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 1 - 6.16 UX ND X 6.41 ng/g 104 (42%-167%
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
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Parmname
NOM
Sample
Qual
QC
Units RPD/D%
REC%
Range
Anlst Date Time
Perfluorinated Compounds
Batch 2429817
Perfluoro(3,5,7,9-tetraoxadecanoic)
6.16
UX
ND
X
6.44
ng/g
105
(49%-162%)
RR3 05/18/23 09:11
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
6.16
UX
ND
X
6.45
ng/g
105
(44%-167%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
6.16
UX
ND
X
7.11
ng/g
115
(57%-153%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
6.16
U
ND
10.6
ng/g
172 *
(47%-166%)
(PFMOBA)
Perfluoro-2-
6.16
UX
ND
X
7.52
ng/g
122
(50%-150%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
6.16
UX
ND
X
6.85
ng/g
111
(49%-169%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
6.16
U
ND
7.91
ng/g
129
(40%-162%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid
5.45
0.619
6.14
ng/g
101
(67%-146%)
JMB3 05/17/23 18:06
(PFBS)
Perfluorobutanoic acid (PFBA)
6.16
0.775
7.89
ng/g
116
(56%-156%)
Perfluorodecanesulfonic acid
5.94
U
ND
6.05
ng/g
99
(61%-150%)
(PFDS)
Perfluorodecanoic acid (PFDA)
6.16
1.68
8.13
ng/g
105
(59%-153%)
Perfluorododecanesulfonic acid
5.96
U
ND
5.15
ng/g
86
(39%-149%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
6.16
1.05
6.82
ng/g
94
(59%-147%)
Perfluoroethoxypropionic acid
6.16
UX
ND
X
6.10
ng/g
99
(49%-151%)
RR3 05/18/23 09:11
(EVE)
Perfluoroheptanesulfonic acid 5.85 U ND 5.47 ng/g 94 (50%-156%) JMB3 05/17/23 18:06
(PFHpS)
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2429817
Perfluoroheptanoic acid (PFHpA)
6.16
J
0.474
6.91
ng/g
105
(61%-149%) JMB3
05/17/23 18:06
Perfluorohexanesulfonic acid
5.61
U
ND
6.26
ng/g
112
(64%-150%)
(PFHxS)
Perfluorohexanoic acid (PFHxA)
6.16
1.16
7.34
ng/g
100
(61%-151%)
Perfluorononanesulfonic acid
5.91
U
ND
6.01
ng/g
102
(47%-147%)
(PFNS)
Perfluorononanoic acid (PFNA)
6.16
J
0.580
7.54
ng/g
113
(58%-152%)
Perfluorooctanesulfonamide
6.16
U
ND
6.43
ng/g
104
(68%-153%)
(PFOSA)
Perfluorooctanesulfonic acid
6.16
4.18
10.3
ng/g
99
(53%-157%)
(PFOS)
Perfluorooctanoic acid (PFOA)
6.16
1.77
7.90
ng/g
100
(53%-155%)
Perfluoropentanesulfonic acid
5.79
U
ND
6.43
ng/g
111
(58%-150%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
6.16
2.39
8.20
ng/g
94
(66%-150%)
Perfluorotetradecanoic acid (PFTA)
6.16
J
0.451
6.61
ng/g
100
(60%-157%)
Perfluorotridecanoic Acid (PFTriA)
6.16
J
0.336
6.92
ng/g
107
(35%-157%)
Perfluoroundecanoic acid (PFUnA)
6.16
J
0.558
6.79
ng/g
101
(58%-154%)
R-EVE
6.16
UX
ND X
12.9
ng/g
209*
(40%-160%) RR3
05/18/23 09:11
QC1205406638 621012008 MSD
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
6.25
UX
ND X
6.86
ng/g 1
110
(0%-30%)
05/18/23 09:26
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
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Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2429817
11-Chloroeicosafluoro-3-
5.88
U
ND
5.02
ng/g
4
85
(0%-30%)
JMB3
05/17/2318:14
oxaundecane-1-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
6.25
U
ND
6.42
ng/g
2
103
(0%-30%)
RR3
05/18/23 09:26
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
6.25
UX
ND X
7.32
ng/g
7
117
(0%-30%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
6.25
U
ND
6.61
ng/g
5
106
(0%-30%)
JMB3
05/17/2318:14
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-1-
6.25
U
ND
6.19
ng/g
1
99
(0%-30%)
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
6.25
U
ND
6.93
ng/g
15
111
(0%-30%)
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
6.25
U
ND
7.29
ng/g
17
117
(0%-30%)
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
6.25
U
ND
6.53
ng/g
4
105
(0%-30%)
acid (3:3 FTCA)(FPrPA)
4,8-Dioxa-3H-perfluorononanoic
6.25
U
ND
6.93
ng/g
3
111
(0%-30%)
acid (DONA,ADONA)
4-
6.25
UX
ND X
6.63
ng/g
4
106
(0%-30%)
RR3
05/18/23 09:26
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
5.82
U
ND
5.99
ng/g
4
103
(0%-30%)
JMB3
05/17/2318:14
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
5.84
U
ND
6.10
ng/g
0
105
(0%-30%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
5.93
U
ND
5.24
ng/g
4
88
(0%-30%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
6.00
U
ND
7.25
ng/g
10
121
(0%-30%)
05/18/23 09:15
FTS)
Hydro -EVE
6.25
UX
ND X
8.08
ng/g
2
129
(0%-30%)
RR3
05/18/23 09:26
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Parmname
NOM
Sample
Qual
QC
Units
RPD/D%
REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2429817
N-ethylperfluoro-l-
6.25
U
ND
5.82
ng/g
4
93
(0%-30%) JMB3
05/17/2318:14
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
6.25
U
ND
6.31
ng/g
5
96
(0%-30%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
6.25
U
ND
7.40
ng/g
19
118
(0%-30%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-1-
6.25
J
0.751
7.41
ng/g
6
107
(0%-30%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Naflon Byproduct 1 (PFESA BPI)
6.25
UX
ND
X
6.63
ng/g
5
106
(0%-30%) RR3
05/18/23 09:26
Nation Byproduct 2 (PFESA BP2)
6.25
Ux
ND
X
6.90
ng/g
1
110
(0%-30%)
Nation Byproduct 4 (PFESA BP4)
6.25
Ux
ND
X
13.0
ng/g
16
209 *
(0%-30%)
Nation Byproduct 5 (PFESA BP5)
6.25
Ux
ND
X
13.7
ng/g
12
219 *
(0%-30%)
Nafion Byproduct 6 (PFESA BP6)
6.25
Ux
ND
X
6.98
ng/g
7
112
(0%-30%)
Nonafluoro-3,6-dioxaheptanoic
6.25
U
ND
7.17
ng/g
13
115
(0%-30%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
6.25
U
ND
6.80
ng/g
0
109
(0%-30%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 I -
6.25
UX
ND
X
6.10
ng/g
5
98
(0%-30%)
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
6.25
UX
ND
x
6.94
ng/g
8
111
(0%-30%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
6.25
UX
ND
X
6.69
ng/g
4
107
(0%-30%)
acid (PF030A)
Perfluoro(4-methoxybutanoic) acid 6.25 U ND 7.10 ng/g 39* 114 (0%-30%
(PFMOBA)
Page 113 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 621012
Page 65 of 67
Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2429817
Perfluoro-2-
6.25
UX
ND X
7.20
ng/g
4
115
(0%-30%)
RR3
05/18/23 09:26
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
6.25
UX
ND X
6.62
ng/g
4
106
(0%-30%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
6.25
U
ND
7.86
ng/g
1
126
(0%-30%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid
5.53
0.619
6.31
ng/g
3
103
(0%-30%)
JMB3
05/17/23 18:14
(PFBS)
Perfluorobutanoic acid (PFBA)
6.25
0.775
7.86
ng/g
0
113
(0%-30%)
Perfluorodecanesulfonic acid
6.03
U
ND
6.24
ng/g
3
100
(0%-30%)
(PFDS)
Perfluorodecanoic acid (PFDA)
6.25
1.68
6.93
ng/g
16
84
(0%-30%)
Perfluorododecanesulfonic acid
6.05
U
ND
5.54
ng/g
7
92
(0%-30%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
6.25
1.05
7.82
ng/g
14
108
(0%-30%)
Perfluoroethoxypropionic acid
6.25
UX
ND X
6.17
ng/g
1
99
(0%-30%)
RR3
05/18/23 09:26
(EVE)
Perfluoroheptanesulfonic acid
5.93
U
ND
5.66
ng/g
3
95
(0%-30%)
JMB3
05/17/23 18:14
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
6.25
J
0.474
7.56
ng/g
9
113
(0%-30%)
Perfluorohexanesulfonic acid
5.70
U
ND
5.97
ng/g
5
105
(0%-30%)
(PFHxS)
Perfluorohexanoic acid (PFHxA)
6.25
1.16
7.51
ng/g
2
102
(0%-30%
Perfluorononanesulfonic acid
6.00 U
ND
6.17
ng/g
3
103
(0%-30%
(PFNS)
Page 114 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 621012
Page 66 of 67
Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2429817
Perfluorononanoic acid (PFNA)
6.25 J
0.580
6.47
ng/g
15
94
(0%-30%) JMB3 05/17/23 18:14
Perfluorooctanesulfonamide
6.25 U
ND
6.34
ng/g
1
102
(0%-30%)
(PFOSA)
Perfluorooctanesulfonic acid
6.25
4.18
10.6
ng/g
3
102
(0%-30%)
(PFOS)
Perfluorooctanoic acid (PFOA)
6.25
1.77
8.40
ng/g
6
106
(0%-30%)
Perfluoropentanesulfonic acid
5.87 U
ND
6.14
ng/g
5
104
(0%-30%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
6.25
2.39
8.64
ng/g
5
100
(0%-30%)
Perfluorotetradecanoic acid (PFTA)
6.25 J
0.451
7.22
ng/g
9
108
(0%-30%)
Perfluorotridecanoic Acid (PFTriA)
6.25 J
0.336
7.03
ng/g
2
107
(0%-30%)
Perfluoroundecanoic acid (PFUnA)
6.25 J
0.558
6.54
ng/g
4
96
(0%-30%)
R-EVE
6.25 UX
ND X
11.7
ng/g
10
187 *
(0%-30%) RR3 05/18/23 09:26
Notes:
The Qualifiers in this report are defined as follows:
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
J Value is estimated
P Organics --The concentrations between the primary and confirmation columns/detectors is >40% different. For HPLC, the difference is >70%.
C Analyte has been confirmed by GUMS analysis
B The target analyte was detected in the associated blank.
E Concentration of the target analyte exceeds the instrument calibration range
A The TIC is a suspected aldol-condensation product
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
N Organics --Presumptive evidence based on mass spectral library search to make a tentative identification of the analyte (TIC). Quantitation is based
on nearest internal standard response factor
Page 115 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 621012
Page 67 of 67
Parmname NOM Sample Qual QC Units RPD/D% REC% Range Anlst Date Time
H Analytical holding time was exceeded
** Analyte is a surrogate compound
< Result is less than value reported
> Result is greater than value reported
It Preparation or preservation holding time was exceeded
R Sample results are rejected
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
D Results are reported from a diluted aliquot of the sample
N/A RPD or %Recovery limits do not apply.
ND Analyte concentration is not detected above the detection limit
NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
JNX Non Calibrated Compound
UJ Compound cannot be extracted
Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
N1 See case narrative
Y QC Samples were not spiked with this compound
N Presumptive evidence based on mass spectral library search to make a tentative identification of the analyte (TIC). Quantitation is based on nearest
internal standard response factor
J See case narrative for an explanation
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
Page 116 of 129 SDG: 621012

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Client: NCDENR QC Summary Report Date: May 19, 2023
1641 Mail Service Center Page 1 of 1
Raleigh, North Carolina
Contact: Stephanie Zorio
Workorder: 621012
Parmname NOM Sample Qual QC Units RPD% REC% Range Anlst Date Time
Notes:
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The Qualifiers in this report are defined as follows:
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
J Value is estimated
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
H Analytical holding time was exceeded
< Result is less than value reported
> Result is greater than value reported
UI Gamma Spectroscopy --Uncertain identification
BD Results are either below the MDC or tracer recovery is low
h Preparation or preservation holding time was exceeded
R Sample results are rejected
^ RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
N/A RPD or %Recovery limits do not apply.
ND Analyte concentration is not detected above the detection limit
M M if above MDC and less than LLD
NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
FA Failed analysis.
UJ Gamma Spectroscopy --Uncertain identification
Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
K Analyte present. Reported value may be biased high. Actual value is expected to be lower.
UL Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
L Analyte present. Reported value may be biased low. Actual value is expected to be higher.
N1 See case narrative
Y Other specific qualifiers were required to properly define the results. Consult case narrative.
** Analyte is a Tracer compound
M REMP Result > MDC/CL and < RDL
J See case narrative for an explanation
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone. by a factor of 4 or more or %RPD not applicable.
** Indicates analyte is a surrogate/tracer compound.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC
standard unless qualified on the QC Summary.
Page 117 of 129 SDG: 621012

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If D or R N yes, select Hunixis below.
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Page 120 of 129 SDG: 621012

List of current GEL Certifications as of 19 May 2023
State
Certification
Alabama
42200
Alaska
17-018
Alaska Drinking Water
SC00012
Arkansas
88-0651
CLIA
42DO904046
California
2940
Colorado
SC00012
Connecticut
PH-0169
DoD ELAP/ ISO17025 A2LA
2567.01
Florida NELAP
E87156
Foreign Soils Permit
P330-15-00283, P330-15-00253
Georgia
SC00012
Georgia SDWA
967
Hawaii
SC00012
Idaho
SC00012
Illinois NELAP
200029
Indiana
C-SC-01
Kansas NELAP
E-10332
Kentucky SDWA
90129
Kentucky Wastewater
90129
Louisiana Drinking Water
LA024
Louisiana NELAP
03046 (A133904)
Maine
2019020
Maryland
270
Massachusetts
M-SCO12
Massachusetts PFAS Approv
Letter
Michigan
9976
Mississippi
SC00012
Nebraska
NE-OS-26-13
Nevada
SC000122023-4
New Hampshire NELAP
2054
New Jersey NELAP
SCO02
New Mexico
SC00012
New York NELAP
11501
North Carolina
233
North Carolina SDWA
45709
North Dakota
R-158
Oklahoma
2022-160
Pennsylvania NELAP
68-00485
Puerto Rico
SC00012
S. Carolina Radiochem
10120002
Sanitation Districts of L
9255651
South Carolina Chemistry
10120001
Tennessee
TN 02934
Texas NELAP
T104704235-22-20
Utah NELAP
SC000122022-37
Vermont
VT87156
Virginia NELAP
460202
Washington
C780
Page 121 of 129 SDG: 621012

Technical Case Narrative
NC Dept Environmental Quality
SDG #: 621012
LCMSMS-Misc
Product: The Extraction and Analysis of Per- and Polyfluoroalkyl Substances Using LCMSMS
Analytical Method: EPA 537.1 Modified
Analytical Procedure: GL-OA-E-076 REV# 14
Analytical Batches: 2424988 and 2424987
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
Client Sample Identification
621012005
NCO024210-EFF-20230504
621012006
NCO024210-INF-20230504
621012010
NCO026123-INF-20230504
621012011
NCO026123-EFF-20230504
1205396671 Method Blank (MB)
1205396672 Laboratory Control Sample (LCS)
1205396673 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Quality Control (QC) Information
Laboratory Control Sample Duplicate (LCSD)
An LCSD was used in place of matrix QC due to limited sample volume.
Internal Standard (ISTD) Acceptance
Samples 621012006 (NC0024210-INF-20230504), 621012010 (NC0026123-INF-20230504) and 621012011
(NC0026123-EFF-20230504) did not meet acceptance criteria for one or more internal standards. The samples
were diluted in order to bring internal standards within acceptance criteria. The results for these samples were
reported from the undiluted and diluted analyses.
Technical Information
Sample Dilutions
The following samples and/or QC were diluted due to matrix interference. 621012006
(NC0024210-INF-20230504). The following samples and/or QC were diluted due to the Internal Standard
Recovery not within the limits in the undiluted analysis. 621012006 (NC00242I0-INF-20230504), 621012010
(NC0026123-INF-20230504) and 621012011 (NC0026123-EFF-20230504).
Analyte
621012
005
006
010
011
Fluorotelomer sulfonic acid 4:2 (4:2 FTS)
25X
5X
5X
25X
Fluorotelomer sulfonic acid 6:2 (6:2 FTS)
5X
5X
5X
1X
Page 122 of 129 SDG: 621012

Fluorotelomer sulfonic acid 8:2 (8:2 FTS)
5X
25X
5X
1X
Perfluorohexadecanoic acid (PFHxDA)
1X
5X
5X
1X
Perfluorooctadecanoic acid (PFODA)
1X
5X
5X
1X
Miscellaneous Information
Manual Integrations
Manual integrations were performed on client sample chromatograms 621012006 (NC0024210-INF-20230504),
621012010 (NC0026123-INF-20230504) and 621012011 (NC0026123-EFF-20230504) because the sample
matrices affected the ability of the software to draw appropriate peak baselines.
Additional Comments
Some analytes are X qualified because the standards used to make the initial calibration curve did not meet the
ISO 17025 criterion. These are the only standards available for these analytes.
Product: The Extraction and Analysis of Per- and Polyfluoroalkyl Substances Using LCMSMS
Analytical Method: EPA 537.1 Modified
Analytical Procedure: GL-OA-E-076 REV# 14
Analytical Batches: 2426059 and 2426055
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID# Client Sample Identification
621012001 NCO024210-TB-20230504
621012002 NCO024210-FRB-20230504
621012003
NCO026123-FRB-20230504-SO
1205399357
Method Blank (MB)
1205399358
Laboratory Control Sample (LCS)
1205399359
Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary•
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Calibration Information
CCV Requirements
Calibration verification standards (ICV or CCV) requirements have not been met for samples in this batch in this
SDG. One or more target analytes failed acceptance criteria with a positive bias in the standards bracketing the
samples in this SDG. These target analytes were not detected in the associated environmental samples; therefore,
the non-compliance had no adverse effect on the data.
Quality Control (QC) Information
Laboratory Control Sample Duplicate (LCSD)
An LCSD was used in place of matrix QC due to limited sample volume.
Page 123 of 129 SDG: 621012

LCS/LCSD Relative Percent Difference (RPD) Statement
Not all of the relative percent differences (RPDs) between the LCS and the LCSD were within the acceptance
limits for this SDG. However, the LCS and LCSD recoveries were all acceptable.
Sample
Analyte
Value
1205399358 (LCS) and 1205399359 (LCSD)
Fluorotelomer sulfonic acid 6:2 (6:2 FTS)
RPD 41* (0%-32%)
Miscellaneous Information
Additional Comments
Some analytes are X qualified because the standards used to make the initial calibration curve did not meet the
ISO 17025 criterion. These are the only standards available for these analytes.
Product: The Extraction and Analysis of Per- and Polyfluoroalkyl Substances Using LCMSMS
Analytical Method: EPA 537.1 Modified
Analytical Procedure: GL-OA-E-076 REV# 14
Analytical Batches: 2426643 and 2426642
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID# Client Sample Identification
621012007 NCO024210-BIOS-20230504
1205400359 Method Blank (MB)
1205400360 Laboratory Control Sample (LCS)
1205400361 620804001(NonSDG) Matrix Spike (MS)
1205400362 620804001(NonSDG) Matrix Spike Duplicate (MSD)
The samples in this SDG were analyzed on a "dry weight" basis.
Data Summary•
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Calibration Information
Initial Calibration
Not all of the initial calibration requirements have been met for this SDG. An analyte of interest, NVHOS, was
not within 70-130% of its true value for a single level of the ICAL. Due to the relative standard deviation (RSD)
and coefficient of correlation being within acceptance criteria, the data is reported as is. 621012007
(NC0024210-BIOS-20230504).
CCV Requirements
Calibration verification standard (ICV or CCV) requirements have not been met for sample 621012007
(NC0024210-BIOS-20230504) in this batch in this SDG. One or more target analytes failed acceptance criteria
with a positive bias in the standards bracketing the samples in this SDG. These target analytes were not detected
in the associated environmental samples; therefore, the non-compliance had no adverse effect on the data.
Quality Control (QC) Information
Matrix Spike (MS) Recovery Statement
Page 124 of 129 SDG: 621012

The MS or MSD (See Below) recovered spiked analytes outside of the established acceptance limits. As similar
recoveries were displayed in the MS and MSD, the failures were attributed to sample matrix interference and the
data were reported.
Sample
Analyte
Value
1205400361 (Non SDG 620804001MS)
Nafion Byproduct 4 (PFESA BP4)
303* (40%-160%)
Nafion Byproduct 5 (PFESA BP5)
226* (40%-160%)
R-EVE
237* (40%-160%)
1205400362 (Non SDG 620804001MSD)
Nafion Byproduct 4 (PFESA BP4)
248* (40%-160%)
Nafion Byproduct 5 (PFESA BP5)
234* (40%-160%)
R-EVE
233* (40%-160%)
Internal Standard (ISTD) Acceptance
Samples 621012007 (NC002421O-BIOS-20230504) did not meet acceptance criteria for one or more internal
standards. The samples were diluted in order to bring internal standards within acceptance criteria. The results
for these samples were reported from the undiluted and diluted analyses.
Technical Information
Sample Dilutions
The following sample and/or QC were diluted due to the Internal Standard Recovery not within the limits in the
undiluted analysis. 621012007 (NC00242IO-BIOS-20230504).
Analyte
621012
007
2-(N-ethylperfluoro-l-octanesulfonamido)-ethanol (N-EtFOSE)
5X
2-(N-methylperfluoro-l-octanesulfonamido)-ethanol (N-McFOSE)
5X
Fluorotelomer sulfonic acid 4:2 (4:2 FTS)
25X
Fluorotelomer sulfonic acid 6:2 (6:2 FTS)
25X
Fluorotelomer sulfonic acid 8:2 (8:2 FTS)
125X
N-ethylperfluoro-l-octanesulfonamide (N-EtFOSA)
5X
N-methylperfluoro-l-octanesulfonamide (N-McFOSA)
5X
Perfluorotetradecanoic acid (PFTA)
5X
Perfluorotridecanoic Acid (PFTriA)
5X
Miscellaneous Information
Additional Comments
Some analytes are X qualified because the standards used to make the initial calibration curve did not meet the
ISO 17025 criterion. These are the only standards available for these analytes. 621012007
(NC0024210-BIOS-20230504).
Product: The Extraction and Analysis of Per- and Polyfluoroalkyl Substances Using LCMSMS
Analytical Method: EPA 537.1 Modified
Page 125 of 129 SDG: 621012

Analytical Procedure: GL-OA-E-076 REV# 14
Analytical Batches: 2428642 and 2428641
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID# Client Sample Identification
621012004 NCO026123-FRB-20230504
1205403890 Method Blank (MB)
1205403891 Laboratory Control Sample (LCS)
1205403892 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Calibration Information
CCV Requirements
Calibration verification standards (ICV or CCV) requirements have not been met for samples in this batch in this
SDG. One or more target analytes failed acceptance criteria with a positive bias in the standards bracketing the
samples in this SDG. These target analytes were not detected in the associated environmental samples; therefore,
the non-compliance had no adverse effect on the data.
Oualitv Control (OCl Information
Laboratory Control Sample Duplicate (LCSD)
An LCSD was used in place of matrix QC due to limited sample volume.
Miscellaneous Information
Additional Comments
Some analytes are X qualified because the standards used to make the initial calibration curve did not meet the
ISO 17025 criterion. These are the only standards available for these analytes.
Product: The Extraction and Analysis of Per- and Polyfluoroalkyl Substances Using LCMSMS
Analytical Method: EPA 537.1 Modified
Analytical Procedure: GL-OA-E-076 REV# 14
Analytical Batches: 2429817 and 2429816
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID# Client Sample Identification
621012008 NC0026123-SO-20230504-RA-42
621012009 NCO026123-BIOS-20230504
1205406635 Method Blank (MB)
1205406636 Laboratory Control Sample (LCS)
1205406637 621012008(NC0026123-SO-20230504-RA-42) Matrix Spike (MS)
1205406638 621012008(NC0026123-SO-20230504-RA-42) Matrix Spike Duplicate (MSD)
The samples in this SDG were analyzed on a "dry weight" basis.
Page 126 of 129 SDG: 621012

Data Summary
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Calibration Information
CCV Requirements
Calibration verification standards (ICV or CCV) requirements have not been met for samples in this batch in this
SDG. One or more target analytes failed acceptance criteria with a positive bias in the standards bracketing the
samples in this SDG. These target analytes were not detected in the associated environmental samples; therefore,
the non-compliance had no adverse effect on the data.
Quality Control (QQ Information
Matrix Spike (MS) Recovery Statement
The MS or MSD (See Below) recovered spiked analytes outside of the established acceptance limits. As similar
recoveries were displayed in the MS and MSD, the failures were attributed to sample matrix interference and the
data were reported.
Sample
Analyte
Value
1205406637
Nafion Byproduct 4 (PFESA BP4)
247*
(NC0026123-SO-20230504-RA-42MS)
(40%-160%)
Nafion Byproduct 5 (PFESA BP5)
198*
(40%-160%)
Perfluoro(4-methoxybutanoic) acid
172*
(PFMOBA)
(47%-166%)
209*
R-EVE
(40%-160%)
1205406638
Nafion Byproduct 4 (PFESA BP4)
209*
(NC0026123-SO-20230504-RA-42MSD)
(40%-160%)
Nafion Byproduct 5 (PFESA BP5)
219*
(40%-160%)
187*
R-EVE
(40%-160%)
MS/MSD Relative Percent Difference (RPD) Statement
The RPD values between the MS and MSD (See Below) were not within the acceptance limits. Since all other
RPD values met acceptance criteria, the noted exceptions are attributed to vagaries in the extraction process. The
data are reported.
Sample
Analyte
Value
1205406637MS and 1205406638MSD
(NC0026123-SO-20230504-RA-42)
Perfluoro(4-methoxybutanoic) acid
(PFMOBA)
RPD 39*
(0%-30%)
Internal Standard (ISTD) Acceptance
Samples 1205406637 (NC0026123-SO-20230504-RA-42MS), 1205406638
(NC0026123-SO-20230504-RA-42MSD), 621012008 (NC0026123-SO-20230504-RA-42) and 621012009
Page 127 of 129 SDG: 621012

(NC0026123-BIOS-20230504) did not meet acceptance criteria for one or more internal standards. The samples
were diluted in order to bring internal standards within acceptance criteria. The results for these samples were
reported from the undiluted and diluted analyses.
Technical information
Sample Dilutions
The following samples and/or QC were diluted due to the Internal Standard Recovery not within the limits in the
undiluted analysis. 1205406637(NC0026123-SO-20230504-RA-42MS), 1205406638
(NC0026123-SO-20230504-RA-42MSD), 621012008 (NC0026123-SO-20230504-RA-42) and 621012009
(NC0026123-BIOS-20230504).
Analyte
621012
008
009
Fluorotelomer sulfonic acid 4:2 (4:2 FTS)
1X
25X
Fluorotelomer sulfonic acid 6:2 (6:2 FTS)
1X
5X
Fluorotelomer sulfonic acid 8:2 (8:2 FTS)
I 5X
I 125X
Miscellaneous Information
Additional Comments
Some analytes are X qualified because the standards used to make the initial calibration curve did not meet the
ISO 17025 criterion. These are the only standards available for these analytes.
Radiochemistry
Product: Dry Weight
Preparation Method: ASTM D 2216 (Modified)
Preparation Procedure: GL-OA-E-020 REV# 13
Preparation Batch: 2424989
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID# Client Sample Identification
621012007 NCO024210-BIOS-20230504
621012008 NC0026123-SO-20230504-RA-42
621012009 NCO026123-BIOS-20230504
1205396674 621012007(NC0024210-BIOS-20230504) Sample Duplicate (DUP)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary
There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.
Page 128 of 129 SDG: 621012

Certification Statement
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 129 of 129 SDG: 621012