NC0026123_Lab Data_20230308

® Laboratories LLc
a member of The GEL Group INC
April 04, 2023
Stephanie Zorio
NCDENR
1641 Mail Service Center
Raleigh, North Carolina 27607
Re: Biosolids Sampling
Work Order: 613703
Dear Stephanie Zorio:
Po Box 30712 Charleston_ SC 29417
2040 Savage Road Chad "on. 8C 29407
P 843.556.8171
F 843.766.1178
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on March 09, 2023. This original data report has been prepared and reviewed in
accordance with GEL's standard operating procedures.
The samples were delivered with proper chain of custody documentation and signatures. All sample containers
arrived without any visible signs of tampering or breakage. There are no additional comments concerning sample
receipt.
Test results for NELAP or ISO 17025 accredited tests are verified to meet the requirements of those standards,
with any exceptions noted. The results reported relate only to the items tested and to the sample as received by
the laboratory. These results may not be reproduced except as full reports without approval by the laboratory.
Copies of GEL's accreditations and certifications can be found on our website at www.gel.com.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 1614.
Sincerely,
sX�
ordan Melton for
Delaney Stone
Project Manager
Purchase Order: NCDAQ
Enclosures
gel. com
Page 1 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
for
NCDQ001 NC Dept Environmental Quality
Client SDG: 613703 GEL Work Order: 613703
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
B The target analyte was detected in the associated blank.
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the'U' qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Delaney Stone.
Reviewed by
Page 2 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
NCO026123-INF-20230308
Sample ID:
613703001
Matrix:
Water
Collect Date:
08-MAR-23 11:19
Receive Date:
09-MAR-23
Collector:
Client
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
11-Chloroeicosafluoro-3-
U
ND
oxaundecane-l-sulfonic acid(F-
53B Minor)
2-(N-ethylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
J
1.36
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U
ND
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 6:2 (6:2
5.56
FTS)
N-ethylperfluoro-l-
U
ND
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
U
ND
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
U
ND
octanesulfonamide (N-McFOSA)
N-methylperfluoro-1-
U
ND
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
5.67
Perfluorodecanesulfonic acid
U
ND
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
Perfluorododecanoic acid (PFDOA)
U
ND
Perfluoroheptanesulfonic acid
U
ND
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
J
1.41
Perfluorohexanesulfonic acid
2.18
(PFHxS)
Perfluorohexanoic acid (PFHxA)
2.21
Perfluorononanesulfonic acid
U
ND
(PFNS)
Perfluorononanoic acid (PFNA)
J
0.692
0.646
1.96
ng/L
0.0196
1 JMB3 03/17/23 1108 2400161 1
1.29
3.91
ng/L
0.0196
1
1.29
3.91
ng/L
0.0196
1
1.29
3.84
ng/L
0.0196
1
1.29
3.72
ng/L
0.0196
1
1.29
3.91
ng/L
0.0196
1
1.29
3.91
ng/L
0.0196
1
1.29
3.91
ng/L
0.0196
1
1.29
3.91
ng/L
0.0196
1
0.646
3.91
ng/L
0.0196
1
0.646
1.74
ng/L
0.0196
1
0.646
1.90
ng/L
0.0196
1
0.763
1.96
ng/L
0.0196
1
0.646
1.96
ng/L
0.0196
1
0.646
1.86
ng/L
0.0196
1
0.646
1.96
ng/L
0.0196
1
0.646
1.78
ng/L
0.0196
1
0.783
1.96
ng/L
0.0196
1
0.685
1.88
ng/L
0.0196
1
0.646
1.96
ng/L
0.0196
1
Page 3 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-INF-20230308
Sample ID: 613703001
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
Perfluorooctanesulfonamide
U
ND
(PFESA)
Perfluorooctanesulfonic acid (PFOS)
2.95
Perfluorooctanoic acid (PFOA)
2.59
Perfluoropentanesulfonic acid
U
ND
(PFPeS)
Perfluoropentanoic acid (PFPeA)
36.9
Perfluoroundecanoic acid (PFUnA)
U
ND
4,8-Dioxa-3H-perfluorononanoic
U
ND
acid (DONA,ADONA)
Perfluorobutanoic acid (PFBA)
U
ND
Perfluorohexadecanoic acid
U
ND
(PFHxDA)
Perfluorooctadecanoic acid
U
ND
(PFODA)
Perfluorotetradecanoic acid (PFTA)
U
ND
Perfluorotridecanoic Acid (PFTriA)
U
ND
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
FTS)
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
XU
ND
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nafion Byproduct 4 (PFESA BP4)
UX
ND
Nafion Byproduct 5 (PFESA BP5)
UX
ND
Nafion Byproduct 6 (PFESA BP6)
UX
ND
Hydro -EVE
UX
ND
Nafion Byproduct 1 (PFESA BPI)
UX
ND
Nafion Byproduct 2 (PFESA BP2)
UX
ND
Nonafluoro-3,6-dioxaheptanoic
U
ND
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
0.646
1.96
ng/L
0.0196
1
0.783
1.96
ng/L
0.0196
1
0.783
1.96
ng/L
0.0196
1
0.646
1.84
ng/L
0.0196
1
0.646
1.96
ng/L
0.0196
1
0.646
1.96
ng/L
0.0196
1
0.646
1.96
ng/L
0.0196
1
3.91
9.79
ng/L
0.0196
5 JMB3 03/17/23 1536 2400161
6.46
19.6
ng/L
0.0196
5
6.46
19.6
ng/L
0.0196
5
3.91
9.79
ng/L
0.0196
5
3.23
9.79
ng/L
0.0196
5
161
460
ng/L
0.0196
125 JMB3 03/17/23 1647 2400161
161
470
ng/L
0.0196
125
0.196
0.489
ng/L
0.0196
1 RR3 03/18/23 0411 2400161
0.196
0.489
ng/L
0.0196
1
0.196
0.489
ng/L
0.0196
1
0.196
0.489
ng/L
0.0196
1
0.196
0.489
ng/L
0.0196
1
0.196
0.489
ng/L
0.0196
1
0.196
0.489
ng/L
0.0196
1
0.196
0.489
ng/L
0.0196
1
0.196
0.489
ng/L
0.0196
1
0.196
0.489
ng/L
0.0196
1
0.196
0.489
ng/L
0.0196
1
►F]
t1J
4
Page 4 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-INF-20230308 Project: NCDQ00123
Sample ID: 613703001 Client ID: NCDQ001
April 4, 2023
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic) UX
ND
0.196
0.489
ng/L
0.0196
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid UX
ND
0.196
0.489
ng/L
0.0196
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid JX
0.460
0.196
0.489
ng/L
0.0196
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid UX
ND
0.196
0.489
ng/L
0.0196
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid U
ND
0.196
0.489
ng/L
0.0196
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid U
ND
0.196
0.489
ng/L
0.0196
1
(PFMOBA)
Perfluoroethoxypropionic acid UX
ND
0.196
0.489
ng/L
0.0196
1
(EVE)
Perfluoropropanoic acid (PFPrA) BX
78.4
1.47
3.91
ng/L
0.0196
1
R-EVE UX
ND
1.29
3.91
ng/L
0.0196
1
Perfluoro(3,5,7,9,11- UX
ND
0.196
0.489
ng/L
0.0196
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2- UX
ND
0.196
0.489
ng/L
0.0196
1
(pentafluoroethoxy)propanoic acid
(PEPA)
Perfluoro-2- UX
ND
0.196
0.391
ng/L
0.0196
1
(perfluoromethoxy)propanoic acid
(PMPA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
SR2
03/18/23
1649 2400727
EPA 537.1 Modified PFCs Extraction in Liquid
SR2
03/17/23
0659 2400160
The following Analytical Methods were performed:
Method Description Analyst Comments
1 EPA 537.1 Modified
2 EPA 537.1 Modified
EPA 537.1 Modified
EPA 537.1 Modified
Page 5 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-INF-20230308
Sample ID: 613703001
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Notes:
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 6 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: April 4, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
NCO026123-EFF-20230308 Project: NCDQ00123
Sample ID:
613703002 Client ID: NCDQ001
Matrix:
Water
Collect Date:
08-MAR-23 11:33
Receive Date:
09-MAR-23
Collector:
Client
Parameter Qualifier
Result
DL
RL
Units
PF
DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
0.177
0.443
ng/L
0.0177
1 RR3 03/20/23 1916 2400729 1
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
J
0.182
0.177
0.443
ng/L
0.0177
1
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
0.177
0.443
ng/L,
0.0177
1
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nation Byproduct 4 (PFESA BP4)
UX
ND
0.177
0.443
ng/L
0.0177
1
Nafion Byproduct 5 (PFESA BP5)
UX
ND
0.177
0.443
ng/L
0.0177
1
Nafion Byproduct 6 (PFESA BP6)
UX
ND
0.177
0.443
ng/L
0.0177
1
Hydro -EVE
UX
ND
0.177
0.443
ng/L
0.0177
1
Nation Byproduct 1 (PFESA BPI)
UX
ND
0.177
0.443
ng/L
0.0177
1
Nafion Byproduct 2 (PFESA BP2)
UX
ND
0.177
0.443
ng/L
0.0177
1
Nonafluoro-3,6-dioxahepanoic
U
ND
0.177
0.443
ng/L
0.0177
1
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
0.177
0.443
ng/L
0.0177
1
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic)
UX
ND
0.177
0.443
ng/L
0.0177
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid
UX
ND
0.177
0.443
ng/L
0.0177
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid
XU
ND
0.177
0.443
ng/L
0.0177
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid
UX
ND
0.177
0.443
ng/L
0.0177
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid
U
ND
0.177
0.443
ng/L
0.0177
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid
U
ND
0.177
0.443
ng/L
0.0177
1
(PFMOBA)
Perfluoroethoxypropionic acid
UX
ND
0.177
0.443
ng/L
0.0177
1
(EVE)
Perfluoropropanoic acid (PFPrA)
BX
13.6
1.33
3.54
ng/L
0.0177
1
R-EVE
UX
ND
1.17
3.54
ng/L
0.0177
1
Perfluoro(3,5,7,9,1 1 -
UX
ND
0.177
0.443
ng/L
0.0177
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2-
UX
ND
0.177
0.443
ng/L
0.0177
1
(pentafluoroethoxy)propanoic acid
Page 7 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: April 4, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-EFF-20230308 Project: NCDQ00123
Sample ID: 613703002 Client ID: NCDQ001
Parameter Qualifier
Result
DL
RL
Units
PF
DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
(PEPA)
Perfluoro-2-
UX
ND
0.177
0.354
ng/L
0.0177
1
(perfluoromethoxy)propanoic acid
(PMPA)
11-Chloroeicosafluoro-3-
U
ND
0.585
1.77
ng/L
0.0177
1 JMB3 03/20/23 1037 2400729 2
oxaundecane-l-sulfonic acid (F-
53B Minor)
2-(N-ethylperfluoro-1-
U
ND
1.17
3.54
ng/L
0.0177
1
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
1.17
3.54
ng/L
0.0177
1
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U
ND
1.17
3.48
ng/L
0.0177
1
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 6:2 (6:2
12.3
1.17
3.37
ng/L
0.0177
1
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
1.17
3.40
ng/L
0.0177
1
FTS)
N-ethylperfluoro-I-
U
ND
1.17
3.54
ng/L
0.0177
1
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
U
ND
1.17
3.54
ng/L
0.0177
1
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
U
ND
1.17
3.54
ng/L
0.0177
1
octanesulfonamide (N-McFOSA)
N-methylperfluoro-1-
U
ND
1.17
3.54
ng/L
0.0177
1
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
0.585
3.54
ng/L
0.0177
1
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
7.54
0.585
1.58
ng/L
0.0177
1
Perfluorobutanoic acid (PFBA)
6.65
0.709
1.77
ng/L
0.0177
1
Perfluorodecanesulfonic acid
U
ND
0.585
1.72
ng/L
0.0177
1
(PFDS)
Perfluorodecanoic acid (PFDA)
J
0.792
0.691
1.77
ng/L
0.0177
1
Perfluorododecanoic acid (PFDOA)
U
ND
0.585
1.77
ng/L
0.0177
1
Perfluoroheptanesulfonic acid
U
ND
0.585
1.68
ng/L
0.0177
1
(PFHpS)
Page 8 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: April 4, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-EFF-20230308 Project: NCDQ00123
Sample ID: 613703002 Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
Perfluoroheptanoic acid (PFHpA) 2.82
0.585
1.77
ng/L
0.0177
1
Perfluorohexadecanoic acid U ND
1.17
3.54
ng/L
0.0177
1
(PFHxDA)
Perfluorohexanesulfonic acid 3.94
0.585
1.61
ng/L
0.0177
1
(PFHxS)
Perfluorohexanoic acid (PFHxA) 16.3
0.709
1.77
ng/L
0.0177
1
Perfluorononanesulfonic acid U ND
0.620
1.70
ng/L
0.0177
1
(PFNS)
Perfluorononanoic acid (PFNA) J 0.797
0.585
1.77
ng/L
0.0177
1
Perfluorooctadecanoic acid U ND
1.17
3.54
ng/L
0.0177
1
(PFODA)
Perfluorooctanesulfonamide U ND
0.585
1.77
ng/L
0.0177
1
(PFOSA)
Perfluorooctanesulfonic acid (PFOS) 7.51
0.709
1.77
ng/L
0.0177
1
Perfluorooctanoic acid (PFOA) 7.18
0.709
1.77
ng/L
0.0177
1
Perfluoropentanesulfonic acid J 0.732
0.585
1.67
ng/L
0.0177
1
(PFPeS)
Perfluoropentanoic acid (PFPeA) 12.8
0.585
1.77
ng/L
0.0177
1
Perfluorotetradecanoic acid (PFTA) U ND
0.709
1.77
ng/L
0.0177
1
Perfluorotridecanoic Acid (PFTriA) U ND
0.585
1.77
ng/L
0.0177
1
Perfluoroundecanoic acid (PFUnA) U ND
0.585
1.77
ng/L
0.0177
1
4,8-Dioxa-3H-perfluorononanoic U ND
0.585
1.77
ng/L
0.0177
1
acid (DONA,ADONA)
Fluorotelomer sulfonic acid 4:2 (4:2 U ND
29.2
83.3
ng/L
0.0177
25 JMB3 03/20/23 1345 2400729 3
FTS)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
SR2
03/18/23
1649 2400727
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 EPA 537.1 Modified
2 EPA 537.1 Modified
3 EPA 537.1 Modified
Notes:
Page 9 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-EFF-20230308
Sample ID: 613703002
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 10 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
NCO026123-BIOS-20230308
Sample ID:
613703003
Matrix:
Solid
Collect Date:
08-MAR-23 11:58
Receive Date:
09-MAR-23
Collector:
Client
Moisture:
81.9%
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
LC-MS/MS EPA 537Mod PFAS,
Solid "Dry
Weight Corrected"
11-Chloroeicosafluoro-3-
U
ND
0.833
oxaundecane-l-sulfonic acid (F-
53B Minor)
2-(N-ethylperfluoro-l-
J
2.41
1.99
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
8.10
1.97
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
9.55
1.67
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
24.9
1.67
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
U
ND
1.67
acid (3:3 FTCA)(FPrPA)
9-Chlorohexadecafluoro-3-
U
ND
0.833
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
2.02
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
1.97
FTS)
N-ethylperfluoro-1-
U
ND
2.07
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
J
4.32
1.39
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
U
ND
2.20
octanesulfonamide (N-McFOSA)
N-methylperfluoro-l-
6.80
1.67
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
0.833
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
U
ND
0.833
Perfluorobutanoic acid (PFBA)
U
ND
1.01
Perfluorodecanesulfonic acid
J
1.18
0.833
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
1.87
Perfluorododecanoic acid (PFDOA)
J
1.73
0.833
2.38
ng/g
4.57
1 MB2 03/18/23 1423 2400381 1
5.05
ng/g
4.57
1
5.05
ng/g
4.57
1
5.05
ng/g
4.57
1
5.05
ng/g
4.57
1
5.05
ng/g
4.57
1
2.35
ng/g
4.57
1
4.74
ng/g
4.57
1
4.80
ng/g
4.57
1
5.05
ng/g
4.57
1
5.05
ng/g
4.57
1
5.05
ng/g
4.57
1
5.05
ng/g
4.57
1
2.44
ng/g
4.57
1
2.25
ng/g
4.57
1
2.52
ng/g
4.57
1
2.45
ng/g
4.57
1
5.05
ng/g
4.57
1
2.52
ng/g
4.57
1
Page 11 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-BIOS-20230308
Sample ID: 613703003
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
LC-MS/MS EPA 537Mod PFAS, Solid "Dry
Weight Corrected"
Perfluoroheptanesulfonic acid
U
ND
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
Perfluorohexanesulfonic acid
U
ND
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
Perfluorononanesulfonic acid
U
ND
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
Perfluorooctanesulfonamide
J
1.03
(PFESA)
Perfluorooctanesulfonic acid (PFOS)
9.72
Perfluorooctanoic acid (PFOA)
U
ND
Perfluoropentanesulfonic acid
U
ND
(PFPeS)
Perfluoropentanoic acid (PFPeA)
U
ND
Perfluorotetradecanoic acid (PFTA)
U
ND
Perfluorotridecanoic Acid (PFTriA)
U
ND
Perfluoroundecanoic acid (PFUnA)
J
0.911
4,8-Dioxa-3H-perfluorononanoic
U
ND
acid (DONA,ADONA)
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nafion Byproduct 4 (PFESA BP4)
UX
ND
Nation Byproduct 5 (PFESA BP5)
UX
ND
Nation Byproduct 6 (PFESA BP6)
UX
ND
Hydro -EVE
UX
ND
Nation Byproduct 1 (PFESA BPI)
UX
ND
Nafion Byproduct 2 (PFESA BP2)
UX
ND
Nonafluoro-3,6-dioxaheptanoic
U
ND
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
0.934
2.40
ng/g
4.57
1
0.833
2.52
ng/g
4.57
1
0.833
2.30
ng/g
4.57
1
1.01
2.52
ng/g
4.57
1
0.833
2.42
ng/g
4.57
1
0.833
2.52
ng/g
4.57
1
0.833
2.52
ng/g
4.57
1
1.01
2.52
ng/g
4.57
1
1.01
2.52
ng/g
4.57
1
0.833
2.37
ng/g
4.57
1
0.833
2.52
ng/g
4.57
1
1.01
2.52
ng/g
4.57
1
0.833
2.52
ng/g
4.57
1
0.833
2.52
ng/g
4.57
1
0.833
2.52
ng/g
4.57
1
1.67
5.05
ng/g
4.57
1 RR3
0.833
2.52
ng/g
4.57
1
1.67
5.05
ng/g
4.57
1
1.67
5.05
ng/g
4.57
1
1.67
5.05
ng/g
4.57
1
1.67
5.05
ng/g
4.57
1
1.67
5.05
ng/g
4.57
1
1.67
5.05
ng/g
4.57
1
1.67
5.05
ng/g
4.57
1
0.833
5.05
ng/g
4.57
1
0.833
2.52
ng/g
4.57
1
03/20/23 1514 2400381 2
Page 12 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: April 4, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-BIOS-20230308 Project: NCDQ00123
Sample ID: 613703003 Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
LC-MS/MS EPA 537Mod PFAS, Solid "Dry Weight Corrected"
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic) UX ND
1.67
5.05
ng/g
4.57
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid UX ND
1.67
5.05
ng/g
4.57
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid UX ND
1.67
5.05
ng/g
4.57
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid UX ND
1.67
5.05
ng/g
4.57
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid U ND
1.67
5.05
ng/g
4.57
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid U ND
1.67
5.05
ng/g
4.57
1
(PFMOBA)
Perfluoroethoxypropionic acid UX ND
1.67
5.05
ng/g
4.57
1
(EVE)
R-EVE UX ND
1.67
5.05
ng/g
4.57
1
Perfluoro(3,5,7,9,1 1 - UX ND
1.67
5.05
ng/g
4.57
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2- UX ND
1.67
5.05
ng/g
4.57
1
(pentafluoroethoxy)propanoic acid
(PEPA)
Perfluoro-2- UX ND
1.67
5.05
ng/g
4.57
1
(perfluoromethoxy)propanoic acid
(PMPA)
Fluorotelomer sulfonic acid 8:2 (8:2 U ND
9.72
24.2
ng/g
4.57
5
M132 03/18/23 1625 2400381 3
FTS)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time
Prep Batch
EPA 537.1 Modified PFCs Extraction in Solid
DK2
03/17/23
1309
2400378
EPA 537.1 Modified PFCs Extraction in Solid
DK2
03/20/23
1339
2401162
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 EPA 537.1 Modified
2 EPA 537.1 Modified
3 EPA 537.1 Modified
Page 13 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-BIOS-20230308
Sample ID: 613703003
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Notes:
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 14 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
NCO026123-GUIS-20230308
Sample ID:
613703004
Matrix:
Solid
Collect Date:
08-MAR-23 13:43
Receive Date:
09-MAR-23
Collector:
Client
Moisture:
18.2%
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
LC-MS/MS EPA 537Mod PFAS,
Solid "Dry
Weight Corrected"
11-Chloroeicosafluoro-3-
U
ND
0.183
oxaundecane-l-sulfonic acid (F-
53B Minor)
2-(N-ethylperfluoro-l-
U
ND
0.439
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
0.433
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
U
ND
0.367
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
U
ND
0.367
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
U
ND
0.367
acid (3:3 FTCA)(FPrPA)
9-Chlorohexadecafluoro-3-
U
ND
0.183
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
0.444
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
0.433
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
0.428
FTS)
N-ethylperfluoro-l-
U
ND
0.455
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
U
ND
0.305
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
U
ND
0.483
octanesulfonamide (N-McFOSA)
N-methylperfluoro-l-
J
0.367
0.367
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
0.183
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
J
0.406
0.183
Perfluorobutanoic acid (PFBA)
J
0.395
0.222
Perfluorodecanesulfonic acid
U
ND
0.183
(PFDS)
0.523
ng/g
4.55
1 MB2 03/21/23 1710 2401164 1
1.11
ng/g
4.55
1
1.11
ng/g
4.55
1
1.11
ng/g
4.55
1
1.11
ng/g
4.55
1
1.11
ng/g
4.55
1
0.518
ng/g
4.55
1
1.04
ng/g
4.55
1
1.06
ng/g
4.55
1
1.07
ng/g
4.55
1
1.11
ng/g
4.55
1
1.11
ng/g
4.55
1
1.11
ng/g
4.55
1
1.11
ng/g
4.55
1
0.538
ng/g
4.55
1
0.494
ng/g
4.55
1
0.555
ng/g
4.55
1
0.539
ng/g
4.55
1
Page 15 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-GUIS-20230308
Sample ID: 613703004
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
LC-MS/MS EPA 537Mod PFAS, Solid "Dry
Weight Corrected"
Perfluorodecanoic acid (PFDA)
10.5
Perfluorododecanoic acid (PFDOA)
3.83
Perfluorohepanesulfonic acid
U
ND
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
J
0.545
Perfluorohexanesulfonic acid
U
ND
(PFHxS)
Perfluorohexanoic acid (PFHxA)
0.680
Perfluorononanesulfonic acid
U
ND
(PFNS)
Perfluorononanoic acid (PFNA)
2.41
Perfluorooctanesulfonamide
U
ND
(PFESA)
Perfluorooctanesulfonic acid (PFOS)
3.81
Perfluorooctanoic acid (PFDA)
4.17
Perfluoropenanesulfonic acid
U
ND
(PFPeS)
Perfluoropentanoic acid (PFPeA)
1.71
Perfluorotetradecanoic acid (PFTA)
1.06
Perfluorotridecanoic Acid (PFTriA)
J
0.477
Perfluoroundecanoic acid (PFUnA)
1.81
4,8-Dioxa-3H-perfluorononanoic
U
ND
acid (DONA,ADONA)
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
XU
ND
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nafion Byproduct 4 (PFESA BP4)
UX
ND
Nafion Byproduct 5 (PFESA BP5)
UX
ND
Nafion Byproduct 6 (PFESA BP6)
UX
ND
Hydro -EVE
UX
ND
Nafion Byproduct 1 (PFESA BPI)
UX
ND
Nafion Byproduct 2 (PFESA BP2)
UX
ND
0.411
1.11
ng/g
4.55
1
0.183
0.555
ng/g
4.55
1
0.206
0.528
ng/g
4.55
1
0.183
0.555
ng/g
4.55
1
0.183
0.505
ng/g
4.55
1
0.222
0.555
ng/g
4.55
1
0.183
0.533
ng/g
4.55
1
0.183
0.555
ng/g
4.55
1
0.183
0.555
ng/g
4.55
1
0.222
0.555
ng/g
4.55
1
0.222
0.555
ng/g
4.55
1
0.183
0.522
ng/g
4.55
1
0.183
0.555
ng/g
4.55
1
0.222
0.555
ng/g
4.55
1
0.183
0.555
ng/g
4.55
1
0.183
0.555
ng/g
4.55
1
0.183
0.555
ng/g
4.55
1
0.367
1.11
ng/g
4.55
1 RR3 03/22/23 2005 2401164 2
0.183
0.555
ng/g
4.55
1
0.367
1.11
ng/g
4.55
1
0.367
1.11
ng/g
4.55
1
0.367
1.11
ng/g
4.55
1
0.367
1.11
ng/g
4.55
1
0.367
1.11
ng/g
4.55
1
0.367
1.11
ng/g
4.55
1
0.367
1.11
ng/g
4.55
1
Page 16 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: April 4, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-GUIS-20230308 Project: NCDQ00123
Sample ID: 613703004 Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
LC-MS/MS EPA 537Mod PFAS, Solid "Dry Weight Corrected"
Nonafluoro-3,6-dioxahepanoic U ND
0.183
1.11
ng/g
4.55
1
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic U ND
0.183
0.555
ng/g
4.55
1
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic) UX ND
0.367
1.11
ng/g
4.55
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid UX ND
0.367
1.11
ng/g
4.55
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid UX ND
0.367
1.11
ng/g
4.55
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid UX ND
0.367
1.11
ng/g
4.55
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid U ND
0.367
1.11
ng/g
4.55
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid U ND
0.367
1.11
ng/g
4.55
1
(PFMOBA)
Perfluoroethoxypropionic acid UX ND
0.367
1.11
ng/g
4.55
1
(EVE)
R-EVE UX ND
0.367
1.11
ng/g
4.55
1
Perfluoro(3,5,7,9,11- UX ND
0.367
1.11
ng/g
4.55
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2- UX ND
0.367
1.11
ng/g
4.55
1
(pentafluoroethoxy)propanoic acid
(PEPA)
Perfluoro-2- UX ND
0.367
1.11
ng/g
4.55
1
(perfluoromethoxy)propanoic acid
(PMPA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Solid
DK2
03/17/23
1309 2400378
EPA 537.1 Modified PFCs Extraction in Solid
DK2
03/20/23
1339 2401162
The following Analytical Methods were performed:
Method Description Analyst Comments
1 EPA 537.1 Modified
2 EPA 537.1 Modified
Page 17 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: NCO026123-GUIS-20230308
Sample ID: 613703004
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Notes:
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 18 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
TB-Asheboro-20230308
Sample ID:
613703005
Matrix:
Water
Collect Date:
08-MAR-23 09:52
Receive Date:
09-MAR-23
Collector:
Client
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS
"As
Received"
11-Chloroeicosafluoro-3-
U
ND
oxaundecane-l-sulfonic acid(F-
53B Minor)
2-(N-ethylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U
ND
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
BJ
1.98
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
FTS)
N-ethylperfluoro-1-
U
ND
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
U
ND
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
U
ND
octanesulfonamide (N-McFOSA)
N-methylperfluoro-l-
U
ND
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
U
ND
Perfluorobutanoic acid (PFBA)
U
ND
Perfluorodecanesulfonic acid
U
ND
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
Perfluorododecanoic acid (PFDOA)
U
ND
Perfluoroheptanesulfonic acid
U
ND
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
Perfluorohexadecanoic acid
U
ND
0.641
1.94
ng/L
0.0194
1 JMB3 03/21/23 1006 2401145 1
1.28
3.89
ng/L
0.0194
1
1.28
3.89
ng/L
0.0194
1
1.28
3.82
ng/L
0.0194
1
1.28
3.65
ng/L
0.0194
1
1.28
3.69
ng/L
0.0194
1
1.28
3.73
ng/L
0.0194
1
1.28
3.89
ng/L
0.0194
1
1.28
3.89
ng/L
0.0194
1
1.28
3.89
ng/L
0.0194
1
1.28
3.89
ng/L
0.0194
1
0.641
3.89
ng/L
0.0194
1
0.641
1.73
ng/L
0.0194
1
0.777
1.94
ng/L
0.0194
1
0.641
1.89
ng/L
0.0194
1
0.758
1.94
ng/L
0.0194
1
0.641
1.94
ng/L
0.0194
1
0.641
1.85
ng/L
0.0194
1
0.641
1.94
ng/L
0.0194
1
1.28
3.89
ng/L
0.0194
1
Page 19 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: TB-Asheboro-20230308
Sample ID: 613703005
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
(PFHxDA)
Perfluorohexanesulfonic acid
U
ND
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
Perfluorononanesulfonic acid
U
ND
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
Perfluorooctadecanoic acid
U
ND
(PFODA)
Perfluorooctanesulfonamide
U
ND
(PFESA)
Perfluorooctanesulfonic acid (PFOS)
U
ND
Perfluorooctanoic acid (PFOA)
U
ND
Perfluoropentanesulfonic acid
U
ND
(PFPeS)
Perfluoropentanoic acid (PFPeA)
U
ND
Perfluorotetradecanoic acid (PFTA)
U
ND
Perfluorotridecanoic Acid (PFTriA)
U
ND
Perfluoroundecanoic acid (PFUnA)
U
ND
4,8-Dioxa-3H-perfluorononanoic
U
ND
acid (DONA,ADONA)
1,1,2,2-Tctrafluoro-2-(1,2,2,2-
UX
ND
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nafion Byproduct 4 (PFESA BP4)
UX
ND
Nation Byproduct 5 (PFESA BP5)
UX
ND
Nation Byproduct 6 (PFESA BP6)
UX
ND
Hydro -EVE
UX
ND
Nation Byproduct 1 (PFESA BPI)
UX
ND
Nafion Byproduct 2 (PFESA BP2)
UX
ND
Nonafluoro-3,6-dioxaheptanoic
U
ND
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
0.641
1.77
ng/L
0.0194
1
0.777
1.94
ng/L
0.0194
1
0.680
1.87
ng/L
0.0194
1
0.641
1.94
ng/L
0.0194
1
1.28
3.89
ng/L
0.0194
1
0.641
1.94
ng/L
0.0194
1
0.777
1.94
ng/L
0.0194
1
0.777
1.94
ng/L
0.0194
1
0.641
1.83
ng/L
0.0194
1
0.641
1.94
ng/L
0.0194
1
0.777
1.94
ng/L
0.0194
1
0.641
1.94
ng/L
0.0194
1
0.641
1.94
ng/L
0.0194
1
0.641
1.94
ng/L
0.0194
1
0.194
0.486
ng/L
0.0194
1 RR3
0.194
0.486
ng/L
0.0194
1
0.194
0.486
ng/L
0.0194
1
0.194
0.486
ng/L
0.0194
1
0.194
0.486
ng/L
0.0194
1
0.194
0.486
ng/L
0.0194
1
0.194
0.486
ng/L
0.0194
1
0.194
0.486
ng/L
0.0194
1
0.194
0.486
ng/L
0.0194
1
0.194
0.486
ng/L
0.0194
1
0.194
0.486
ng/L
0.0194
1
03/21/23 1311 2401145 2
Page 20 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: TB-Asheboro-20230308 Project: NCDQ00123
Sample ID: 613703005 Client ID: NCDQ001
April 4, 2023
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic) UX
ND
0.194
0.486
ng/L
0.0194
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid UX
ND
0.194
0.486
ng/L
0.0194
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid UX
ND
0.194
0.486
ng/L
0.0194
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid UX
ND
0.194
0.486
ng/L
0.0194
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid U
ND
0.194
0.486
ng/L
0.0194
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid U
ND
0.194
0.486
ng/L
0.0194
1
(PFMOBA)
Perfluoroethoxypropionic acid UX
ND
0.194
0.486
ng/L
0.0194
1
(EVE)
Perfluoropropanoic acid (PFPrA) BX
4.84
1.46
3.89
ng/L
0.0194
1
R-EVE UX
ND
1.28
3.89
ng/L
0.0194
1
Perfluoro(3,5,7,9,1 I - UX
ND
0.194
0.486
ng/L
0.0194
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2- UX
ND
0.194
0.486
ng/L
0.0194
1
(pentafluoroethoxy)propanoic acid
(PEPA)
Perfluoro-2- UX
ND
0.194
0.389
ng/L
0.0194
1
(perfluoromethoxy)propanoic acid
(PMPA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
BPI
03/20/23
1412 2401141
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 EPA 537.1 Modified
EPA 537.1 Modified
Notes:
Page 21 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: TB-Asheboro-20230308
Sample ID: 613703005
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 22 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
AsheboroWWTP-FRB-20230308
Sample ID:
613703006
Matrix:
Water
Collect Date:
08-MAR-23 11:14
Receive Date:
09-MAR-23
Collector:
Client
Parameter Qualifier Result
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
11-Chloroeicosafluoro-3-
U
ND
oxaundecane-l-sulfonic acid(F-
53B Minor)
2-(N-ethylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U
ND
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
FTS)
N-ethylperfluoro-1-
U
ND
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
U
ND
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
U
ND
octanesulfonamide (N-McFOSA)
N-methylperfluoro-l-
U
ND
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
U
ND
Perfluorobutanoic acid (PFBA)
U
ND
Perfluorodecanesulfonic acid
U
ND
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
Perfluorododecanoic acid (PFDOA)
U
ND
Perfluoroheptanesulfonic acid
U
ND
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
Perfluorohexadecanoic acid
U
ND
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
DL RL Units PF DF Analyst Date Time Batch Method
0.629
1.91
ng/L
0.0191
1 JMB3 03/20/23 1046 2400729 1
1.26
3.81
ng/L
0.0191
1
1.26
3.81
ng/L
0.0191
1
1.26
3.74
ng/L
0.0191
1
1.26
3.58
ng/L
0.0191
1
1.26
3.62
ng/L
0.0191
1
1.26
3.66
ng/L
0.0191
1
1.26
3.81
ng/L
0.0191
1
1.26
3.81
ng/L
0.0191
1
1.26
3.81
ng/L
0.0191
1
1.26
3.81
ng/L
0.0191
1
0.629
3.81
ng/L
0.0191
1
0.629
1.70
ng/L
0.0191
1
0.762
1.91
ng/L
0.0191
1
0.629
1.85
ng/L
0.0191
1
0.743
1.91
ng/L
0.0191
1
0.629
1.91
ng/L
0.0191
1
0.629
1.81
ng/L
0.0191
1
0.629
1.91
ng/L
0.0191
1
1.26
3.81
ng/L
0.0191
1
Page 23 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: April 4, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: AsheboroWWTP-FRB-20230308 Project: NCDQ00123
Sample ID: 613703006 Client ID: NCDQ001
Parameter Qualifier
Result
DL
RL
Units
PF
DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
(PFHxDA)
Perfluorohexanesulfonic acid
U
ND
0.629
1.73
ng/L
0.0191
1
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
0.762
1.91
ng/L
0.0191
1
Perfluorononanesulfonic acid
U
ND
0.667
1.83
ng/L
0.0191
1
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
0.629
1.91
ng/L
0.0191
1
Perfluorooctadecanoic acid
U
ND
1.26
3.81
ng/L
0.0191
1
(PFODA)
Perfluorooctanesulfonamide
U
ND
0.629
1.91
ng/L
0.0191
1
(PFESA)
Perfluorooctanesulfonic acid (PFOS)
U
ND
0.762
1.91
ng/L
0.0191
1
Perfluorooctanoic acid (PFOA)
U
ND
0.762
1.91
ng/L
0.0191
1
Perfluoropentanesulfonic acid
U
ND
0.629
1.79
ng/L
0.0191
1
(PFPeS)
Perfluoropentanoic acid (PFPeA)
U
ND
0.629
1.91
ng/L
0.0191
1
Perfluorotetradecanoic acid (PFTA)
U
ND
0.762
1.91
ng/L
0.0191
1
Perfluorotridecanoic Acid (PFTriA)
U
ND
0.629
1.91
ng/L
0.0191
1
Perfluoroundecanoic acid (PFUnA)
U
ND
0.629
1.91
ng/L
0.0191
1
4,8-Dioxa-3H-perfluorononanoic
U
ND
0.629
1.91
ng/L
0.0191
1
acid (DONA,ADONA)
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
0.191
0.476
ng/L
0.0191
1 RR3 03/20/23 1931 2400729 2
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
0.191
0.476
ng/L
0.0191
1
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
0.191
0.476
ng/L
0.0191
1
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nafion Byproduct 4 (PFESA BP4)
UX
ND
0.191
0.476
ng/L
0.0191
1
Nation Byproduct 5 (PFESA BP5)
UX
ND
0.191
0.476
ng/L
0.0191
1
Nation Byproduct 6 (PFESA BP6)
UX
ND
0.191
0.476
ng/L
0.0191
1
Hydro -EVE
UX
ND
0.191
0.476
ng/L
0.0191
1
Nation Byproduct 1 (PFESA BPI)
UX
ND
0.191
0.476
ng/L
0.0191
1
Nafion Byproduct 2 (PFESA BP2)
UX
ND
0.191
0.476
ng/L
0.0191
1
Nonafluoro-3,6-dioxaheptanoic
U
ND
0.191
0.476
ng/L
0.0191
1
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
0.191
0.476
ng/L
0.0191
1
Page 24 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: AsheboroWWTP-FRB-20230308 Project: NCDQ00123
Sample ID: 613703006 Client ID: NCDQ001
April 4, 2023
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic) UX ND
0.191
0.476
ng/L
0.0191
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid UX ND
0.191
0.476
ng/L
0.0191
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid UX ND
0.191
0.476
ng/L
0.0191
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid UX ND
0.191
0.476
ng/L
0.0191
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid U ND
0.191
0.476
ng/L
0.0191
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid U ND
0.191
0.476
ng/L
0.0191
1
(PFMOBA)
Perfluoroethoxypropionic acid UX ND
0.191
0.476
ng/L
0.0191
1
(EVE)
Perfluoropropanoic acid (PFPrA) BX 6.16
1.43
3.81
ng/L
0.0191
1
R-EVE UX ND
1.26
3.81
ng/L
0.0191
1
Perfluoro(3,5,7,9,11- UX ND
0.191
0.476
ng/L
0.0191
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2- UX ND
0.191
0.476
ng/L
0.0191
1
(pentafluoroethoxy)propanoic acid
(PEPA)
Perfluoro-2- UX ND
0.191
0.381
ng/L
0.0191
1
(perfluoromethoxy)propanoic acid
(PMPA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
SR2
03/18/23
1649 2400727
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 EPA 537.1 Modified
EPA 537.1 Modified
Notes:
Page 25 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: AsheboroWWTP-FRB-20230308
Sample ID: 613703006
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 26 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: April 4, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
AsheboroField-FRB-20230308 Project: NCDQ00123
Sample ID:
613703007 Client ID: NCDQ001
Matrix:
Water
Collect Date:
08-MAR-23 12:56
Receive Date:
09-MAR-23
Collector:
Client
Parameter Qualifier
Result
DL
RL
Units
PF
DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
0.190
0.476
ng/L
0.0190
1 RR3 03/20/23 1946 2400729 1
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
0.190
0.476
ng/L
0.0190
1
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
0.190
0.476
ng/L
0.0190
1
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nation Byproduct 4 (PFESA BP4)
UX
ND
0.190
0.476
ng/L
0.0190
1
Nafion Byproduct 5 (PFESA BP5)
UX
ND
0.190
0.476
ng/L
0.0190
1
Nafion Byproduct 6 (PFESA BP6)
UX
ND
0.190
0.476
ng/L
0.0190
1
Hydro -EVE
UX
ND
0.190
0.476
ng/L
0.0190
1
Nation Byproduct 1 (PFESA BPI)
UX
ND
0.190
0.476
ng/L
0.0190
1
Nafion Byproduct 2 (PFESA BP2)
UX
ND
0.190
0.476
ng/L
0.0190
1
Nonafluoro-3,6-dioxahepanoic
U
ND
0.190
0.476
ng/L
0.0190
1
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
0.190
0.476
ng/L
0.0190
1
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic)
UX
ND
0.190
0.476
ng/L
0.0190
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid
UX
ND
0.190
0.476
ng/L
0.0190
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid
UX
ND
0.190
0.476
ng/L
0.0190
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid
UX
ND
0.190
0.476
ng/L
0.0190
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid
U
ND
0.190
0.476
ng/L
0.0190
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid
U
ND
0.190
0.476
ng/L
0.0190
1
(PFMOBA)
Perfluoroethoxypropionic acid
UX
ND
0.190
0.476
ng/L
0.0190
1
(EVE)
Perfluoropropanoic acid (PFPrA)
BX
5.87
1.43
3.81
ng/L
0.0190
1
R-EVE
UX
ND
1.26
3.81
ng/L
0.0190
1
Perfluoro(3,5,7,9,1 1 -
UX
ND
0.190
0.476
ng/L
0.0190
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2-
UX
ND
0.190
0.476
ng/L
0.0190
1
(pentafluoroethoxy)propanoic acid
Page 27 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: April 4, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: AsheboroField-FRB-20230308 Project: NCDQ00123
Sample ID: 613703007 Client ID: NCDQ001
Parameter Qualifier
Result
DL
RL
Units
PF
DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
(PEPA)
Perfluoro-2-
UX
ND
0.190
0.381
ng/L
0.0190
1
(perfluoromethoxy)propanoic acid
(PMPA)
11-Chloroeicosafluoro-3-
U
ND
0.628
1.90
ng/L
0.0190
1 JMB3 03/20/23 1055 2400729 2
oxaundecane-l-sulfonic acid (F-
53B Minor)
2-(N-ethylperfluoro-1-
U
ND
1.26
3.81
ng/L
0.0190
1
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
1.26
3.81
ng/L
0.0190
1
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U
ND
1.26
3.74
ng/L
0.0190
1
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
1.26
3.58
ng/L
0.0190
1
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
1.26
3.62
ng/L
0.0190
1
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
1.26
3.65
ng/L
0.0190
1
FTS)
N-ethylperfluoro-1-
U
ND
1.26
3.81
ng/L
0.0190
1
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
U
ND
1.26
3.81
ng/L
0.0190
1
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
U
ND
1.26
3.81
ng/L
0.0190
1
octanesulfonamide (N-McFOSA)
N-methylperfluoro-1-
U
ND
1.26
3.81
ng/L
0.0190
1
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
0.628
3.81
ng/L
0.0190
1
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
U
ND
0.628
1.69
ng/L
0.0190
1
Perfluorobutanoic acid (PFBA)
U
ND
0.761
1.90
ng/L
0.0190
1
Perfluorodecanesulfonic acid
U
ND
0.628
1.85
ng/L
0.0190
1
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
0.742
1.90
ng/L
0.0190
1
Perfluorododecanoic acid (PFDOA)
U
ND
0.628
1.90
ng/L
0.0190
1
Page 28 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: April 4, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: AsheboroField-FRB-20230308 Project: NCDQ00123
Sample ID: 613703007 Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
Perfluoroheptanesulfonic acid U
ND
0.628
1.81
ng/L
0.0190
1
(PFHpS)
Perfluoroheptanoic acid (PFHpA) U
ND
0.628
1.90
ng/L
0.0190
1
Perfluorohexadecanoic acid U
ND
1.26
3.81
ng/L
0.0190
1
(PFHxDA)
Perfluorohexanesulfonic acid U
ND
0.628
1.73
ng/L
0.0190
1
(PFHxS)
Perfluorohexanoic acid (PFHxA) U
ND
0.761
1.90
ng/L
0.0190
1
Perfluorononanesulfonic acid U
ND
0.666
1.83
ng/L
0.0190
1
(PFNS)
Perfluorononanoic acid (PFNA) U
ND
0.628
1.90
ng/L
0.0190
1
Perfluorooctadecanoic acid U
ND
1.26
3.81
ng/L
0.0190
1
(PFODA)
Perfluorooctanesulfonamide U
ND
0.628
1.90
ng/L
0.0190
1
(PFOSA)
Perfluorooctanesulfonic acid (PFOS) U
ND
0.761
1.90
ng/L
0.0190
1
Perfluorooctanoic acid (PFOA) U
ND
0.761
1.90
ng/L
0.0190
1
Perfluoropentanesulfonic acid U
ND
0.628
1.79
ng/L
0.0190
1
(PFPeS)
Perfluoropentanoic acid (PFPeA) U
ND
0.628
1.90
ng/L
0.0190
1
Perfluorotetradecanoic acid (PFTA) U
ND
0.761
1.90
ng/L
0.0190
1
Perfluorotridecanoic Acid (PFTriA) U
ND
0.628
1.90
ng/L
0.0190
1
Perfluoroundecanoic acid (PFUnA) U
ND
0.628
1.90
ng/L
0.0190
1
4,8-Dioxa-3H-perfluorononanoic U
ND
0.628
1.90
ng/L
0.0190
1
acid (DONA,ADONA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
SR2
03/18/23
1649 2400727
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 EPA 537.1 Modified
2 EPA 537.1 Modified
Notes:
Page 29 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: AsheboroField-FRB-20230308
Sample ID: 613703007
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 30 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
EB-CC-ExtendableDipper
Sample ID:
613703008
Matrix:
Water
Collect Date:
08-MAR-23 08:31
Receive Date:
09-MAR-23
Collector:
Client
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
11-Chloroeicosafluoro-3-
U
ND
oxaundecane-l-sulfonic acid(F-
53B Minor)
2-(N-ethylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U
ND
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
FTS)
N-ethylperfluoro-1-
U
ND
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
U
ND
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
U
ND
octanesulfonamide (N-McFOSA)
N-methylperfluoro-l-
U
ND
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
U
ND
Perfluorobutanoic acid (PFBA)
U
ND
Perfluorodecanesulfonic acid
U
ND
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
Perfluorododecanoic acid (PFDOA)
U
ND
Perfluoroheptanesulfonic acid
U
ND
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
Perfluorohexadecanoic acid
U
ND
0.594
1.80
ng/L
0.0180
1 JMB3 03/20/23 1104 2400729 1
1.19
3.60
ng/L
0.0180
1
1.19
3.60
ng/L
0.0180
1
1.19
3.53
ng/L
0.0180
1
1.19
3.38
ng/L
0.0180
1
1.19
3.42
ng/L
0.0180
1
1.19
3.46
ng/L
0.0180
1
1.19
3.60
ng/L
0.0180
1
1.19
3.60
ng/L
0.0180
1
1.19
3.60
ng/L
0.0180
1
1.19
3.60
ng/L
0.0180
1
0.594
3.60
ng/L
0.0180
1
0.594
1.60
ng/L
0.0180
1
0.720
1.80
ng/L
0.0180
1
0.594
1.75
ng/L
0.0180
1
0.702
1.80
ng/L
0.0180
1
0.594
1.80
ng/L
0.0180
1
0.594
1.71
ng/L
0.0180
1
0.594
1.80
ng/L
0.0180
1
1.19
3.60
ng/L
0.0180
1
Page 31 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: EB-CC-ExtendableDipper
Sample ID: 613703008
Parameter Qualifier Result
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
(PFHxDA)
Perfluorohexanesulfonic acid
U
ND
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
Perfluorononanesulfonic acid
U
ND
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
Perfluorooctadecanoic acid
U
ND
(PFODA)
Perfluorooctanesulfonamide
U
ND
(PFESA)
Perfluorooctanesulfonic acid (PFOS)
U
ND
Perfluorooctanoic acid (PFOA)
U
ND
Perfluoropentanesulfonic acid
U
ND
(PFPeS)
Perfluoropentanoic acid (PFPeA)
U
ND
Perfluorotetradecanoic acid (PFTA)
U
ND
Perfluorotridecanoic Acid (PFTriA)
U
ND
Perfluoroundecanoic acid (PFUnA)
U
ND
4,8-Dioxa-3H-perfluorononanoic
U
ND
acid (DONA,ADONA)
1,1,2,2-Tctrafluoro-2-(1,2,2,2-
UX
ND
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nafion Byproduct 4 (PFESA BP4)
UX
ND
Nation Byproduct 5 (PFESA BP5)
UX
ND
Nation Byproduct 6 (PFESA BP6)
UX
ND
Hydro -EVE
UX
ND
Nation Byproduct 1 (PFESA BPI)
UX
ND
Nafion Byproduct 2 (PFESA BP2)
UX
ND
Nonafluoro-3,6-dioxaheptanoic
U
ND
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
DL RL Units PF DF Analyst Date Time Batch Method
0.594
1.64
ng/L
0.0180
1
0.720
1.80
ng/L
0.0180
1
0.630
1.73
ng/L
0.0180
1
0.594
1.80
ng/L
0.0180
1
1.19
3.60
ng/L
0.0180
1
0.594
1.80
ng/L
0.0180
1
0.720
1.80
ng/L
0.0180
1
0.720
1.80
ng/L
0.0180
1
0.594
1.69
ng/L
0.0180
1
0.594
1.80
ng/L
0.0180
1
0.720
1.80
ng/L
0.0180
1
0.594
1.80
ng/L
0.0180
1
0.594
1.80
ng/L
0.0180
1
0.594
1.80
ng/L
0.0180
1
0.180
0.450
ng/L
0.0180
1 RR3
0.180
0.450
ng/L
0.0180
1
0.180
0.450
ng/L
0.0180
1
0.180
0.450
ng/L
0.0180
1
0.180
0.450
ng/L
0.0180
1
0.180
0.450
ng/L
0.0180
1
0.180
0.450
ng/L
0.0180
1
0.180
0.450
ng/L
0.0180
1
0.180
0.450
ng/L
0.0180
1
0.180
0.450
ng/L
0.0180
1
0.180
0.450
ng/L
0.0180
1
03/20/23 2002 2400729 2
Page 32 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: EB-CC-ExtendableDipper Project: NCDQ00123
Sample ID: 613703008 Client ID: NCDQ001
April 4, 2023
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic) UX
ND
0.180
0.450
ng/L
0.0180
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid UX
ND
0.180
0.450
ng/L
0.0180
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid UX
ND
0.180
0.450
ng/L
0.0180
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid UX
ND
0.180
0.450
ng/L
0.0180
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid U
ND
0.180
0.450
ng/L
0.0180
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid U
ND
0.180
0.450
ng/L
0.0180
1
(PFMOBA)
Perfluoroethoxypropionic acid UX
ND
0.180
0.450
ng/L
0.0180
1
(EVE)
Perfluoropropanoic acid (PFPrA) BJX
3.35
1.35
3.60
ng/L
0.0180
1
R-EVE UX
ND
1.19
3.60
ng/L
0.0180
1
Perfluoro(3,5,7,9,11- UX
ND
0.180
0.450
ng/L
0.0180
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2- UX
ND
0.180
0.450
ng/L
0.0180
1
(pentafluoroethoxy)propanoic acid
(PEPA)
Perfluoro-2- UX
ND
0.180
0.360
ng/L
0.0180
1
(perfluoromethoxy)propanoic acid
(PMPA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
SR2
03/18/23
1649 2400727
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 EPA 537.1 Modified
EPA 537.1 Modified
Notes:
Page 33 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: EB-CC-ExtendableDipper
Sample ID: 613703008
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 34 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
EB-CC-Trowel
Sample ID:
613703009
Matrix:
Water
Collect Date:
08-MAR-23 08:26
Receive Date:
09-MAR-23
Collector:
Client
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
11-Chloroeicosafluoro-3-
U
ND
oxaundecane-l-sulfonic acid(F-
53B Minor)
2-(N-ethylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U
ND
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
FTS)
N-ethylperfluoro-1-
U
ND
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
U
ND
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
U
ND
octanesulfonamide (N-McFOSA)
N-methylperfluoro-l-
U
ND
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
U
ND
Perfluorobutanoic acid (PFBA)
U
ND
Perfluorodecanesulfonic acid
U
ND
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
Perfluorododecanoic acid (PFDOA)
U
ND
Perfluoroheptanesulfonic acid
U
ND
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
Perfluorohexadecanoic acid
U
ND
0.602
1.82
ng/L
0.0182
1 JMB3 03/20/23 1113 2400729 1
1.20
3.65
ng/L
0.0182
1
1.20
3.65
ng/L
0.0182
1
1.20
3.58
ng/L
0.0182
1
1.20
3.43
ng/L
0.0182
1
1.20
3.46
ng/L
0.0182
1
1.20
3.50
ng/L
0.0182
1
1.20
3.65
ng/L
0.0182
1
1.20
3.65
ng/L
0.0182
1
1.20
3.65
ng/L
0.0182
1
1.20
3.65
ng/L
0.0182
1
0.602
3.65
ng/L
0.0182
1
0.602
1.62
ng/L
0.0182
1
0.729
1.82
ng/L
0.0182
1
0.602
1.77
ng/L
0.0182
1
0.711
1.82
ng/L
0.0182
1
0.602
1.82
ng/L
0.0182
1
0.602
1.73
ng/L
0.0182
1
0.602
1.82
ng/L
0.0182
1
1.20
3.65
ng/L
0.0182
1
Page 35 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: EB-CC-Trowel
Sample ID: 613703009
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
(PFHxDA)
Perfluorohexanesulfonic acid
U
ND
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
Perfluorononanesulfonic acid
U
ND
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
Perfluorooctadecanoic acid
U
ND
(PFODA)
Perfluorooctanesulfonamide
U
ND
(PFESA)
Perfluorooctanesulfonic acid (PFOS)
U
ND
Perfluorooctanoic acid (PFOA)
U
ND
Perfluoropentanesulfonic acid
U
ND
(PFPeS)
Perfluoropentanoic acid (PFPeA)
U
ND
Perfluorotetradecanoic acid (PFTA)
U
ND
Perfluorotridecanoic Acid (PFTriA)
U
ND
Perfluoroundecanoic acid (PFUnA)
U
ND
4,8-Dioxa-3H-perfluorononanoic
U
ND
acid (DONA,ADONA)
1,1,2,2-Tctrafluoro-2-(1,2,2,2-
UX
ND
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nafion Byproduct 4 (PFESA BP4)
UX
ND
Nation Byproduct 5 (PFESA BP5)
UX
ND
Nation Byproduct 6 (PFESA BP6)
UX
ND
Hydro -EVE
UX
ND
Nation Byproduct 1 (PFESA BPI)
UX
ND
Nafion Byproduct 2 (PFESA BP2)
UX
ND
Nonafluoro-3,6-dioxaheptanoic
U
ND
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
0.602
1.66
ng/L
0.0182
1
0.729
1.82
ng/L
0.0182
1
0.638
1.75
ng/L
0.0182
1
0.602
1.82
ng/L
0.0182
1
1.20
3.65
ng/L
0.0182
1
0.602
1.82
ng/L
0.0182
1
0.729
1.82
ng/L
0.0182
1
0.729
1.82
ng/L
0.0182
1
0.602
1.71
ng/L
0.0182
1
0.602
1.82
ng/L
0.0182
1
0.729
1.82
ng/L
0.0182
1
0.602
1.82
ng/L
0.0182
1
0.602
1.82
ng/L
0.0182
1
0.602
1.82
ng/L
0.0182
1
0.182
0.456
ng/L
0.0182
1 RR3
0.182
0.456
ng/L
0.0182
1
0.182
0.456
ng/L
0.0182
1
0.182
0.456
ng/L
0.0182
1
0.182
0.456
ng/L
0.0182
1
0.182
0.456
ng/L
0.0182
1
0.182
0.456
ng/L
0.0182
1
0.182
0.456
ng/L
0.0182
1
0.182
0.456
ng/L
0.0182
1
0.182
0.456
ng/L
0.0182
1
0.182
0.456
ng/L
0.0182
1
03/20/23 2017 2400729 2
Page 36 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: EB-CC-Trowel Project: NCDQ00123
Sample ID: 613703009 Client ID: NCDQ001
April 4, 2023
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic) UX
ND
0.182
0.456
ng/L
0.0182
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid UX
ND
0.182
0.456
ng/L
0.0182
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid UX
ND
0.182
0.456
ng/L
0.0182
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid UX
ND
0.182
0.456
ng/L
0.0182
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid U
ND
0.182
0.456
ng/L
0.0182
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid U
ND
0.182
0.456
ng/L
0.0182
1
(PFMOBA)
Perfluoroethoxypropionic acid UX
ND
0.182
0.456
ng/L
0.0182
1
(EVE)
Perfluoropropanoic acid (PFPrA) BJX
3.40
1.37
3.65
ng/L
0.0182
1
R-EVE UX
ND
1.20
3.65
ng/L
0.0182
1
Perfluoro(3,5,7,9,11- UX
ND
0.182
0.456
ng/L
0.0182
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2- UX
ND
0.182
0.456
ng/L
0.0182
1
(pentafluoroethoxy)propanoic acid
(PEPA)
Perfluoro-2- UX
ND
0.182
0.365
ng/L
0.0182
1
(perfluoromethoxy)propanoic acid
(PMPA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
SR2
03/18/23
1649 2400727
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 EPA 537.1 Modified
EPA 537.1 Modified
Notes:
Page 37 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: EB-CC-Trowel
Sample ID: 613703009
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 38 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
EB-CC-Soil probe
Sample ID:
613703010
Matrix:
Water
Collect Date:
08-MAR-23 08:20
Receive Date:
09-MAR-23
Collector:
Client
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
11-Chloroeicosafluoro-3-
U
ND
oxaundecane-l-sulfonic acid(F-
53B Minor)
2-(N-ethylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U
ND
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
FTS)
N-ethylperfluoro-1-
U
ND
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
U
ND
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
U
ND
octanesulfonamide (N-McFOSA)
N-methylperfluoro-l-
U
ND
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
U
ND
Perfluorobutanoic acid (PFBA)
U
ND
Perfluorodecanesulfonic acid
U
ND
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
Perfluorododecanoic acid (PFDOA)
U
ND
Perfluoroheptanesulfonic acid
U
ND
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
Perfluorohexadecanoic acid
U
ND
0.571
1.73
ng/L
0.0173
1 JMB3 03/20/23 1131 2400729 1
1.14
3.46
ng/L
0.0173
1
1.14
3.46
ng/L
0.0173
1
1.14
3.40
ng/L
0.0173
1
1.14
3.25
ng/L
0.0173
1
1.14
3.29
ng/L
0.0173
1
1.14
3.32
ng/L
0.0173
1
1.14
3.46
ng/L
0.0173
1
1.14
3.46
ng/L
0.0173
1
1.14
3.46
ng/L
0.0173
1
1.14
3.46
ng/L
0.0173
1
0.571
3.46
ng/L
0.0173
1
0.571
1.54
ng/L
0.0173
1
0.692
1.73
ng/L
0.0173
1
0.571
1.68
ng/L
0.0173
1
0.675
1.73
ng/L
0.0173
1
0.571
1.73
ng/L
0.0173
1
0.571
1.64
ng/L
0.0173
1
0.571
1.73
ng/L
0.0173
1
1.14
3.46
ng/L
0.0173
1
Page 39 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: EB-CC-Soil probe
Sample ID: 613703010
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
(PFHxDA)
Perfluorohexanesulfonic acid
U
ND
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
Perfluorononanesulfonic acid
U
ND
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
Perfluorooctadecanoic acid
U
ND
(PFODA)
Perfluorooctanesulfonamide
U
ND
(PFESA)
Perfluorooctanesulfonic acid (PFOS)
U
ND
Perfluorooctanoic acid (PFOA)
U
ND
Perfluoropentanesulfonic acid
U
ND
(PFPeS)
Perfluoropentanoic acid (PFPeA)
U
ND
Perfluorotetradecanoic acid (PFTA)
U
ND
Perfluorotridecanoic Acid (PFTriA)
U
ND
Perfluoroundecanoic acid (PFUnA)
U
ND
4,8-Dioxa-3H-perfluorononanoic
U
ND
acid (DONA,ADONA)
1,1,2,2-Tctrafluoro-2-(1,2,2,2-
UX
ND
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nafion Byproduct 4 (PFESA BP4)
UX
ND
Nation Byproduct 5 (PFESA BP5)
UX
ND
Nation Byproduct 6 (PFESA BP6)
UX
ND
Hydro -EVE
UX
ND
Nation Byproduct 1 (PFESA BPI)
UX
ND
Nafion Byproduct 2 (PFESA BP2)
UX
ND
Nonafluoro-3,6-dioxaheptanoic
U
ND
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
0.571
1.57
ng/L
0.0173
1
0.692
1.73
ng/L
0.0173
1
0.605
1.66
ng/L
0.0173
1
0.571
1.73
ng/L
0.0173
1
1.14
3.46
ng/L
0.0173
1
0.571
1.73
ng/L
0.0173
1
0.692
1.73
ng/L
0.0173
1
0.692
1.73
ng/L
0.0173
1
0.571
1.63
ng/L
0.0173
1
0.571
1.73
ng/L
0.0173
1
0.692
1.73
ng/L
0.0173
1
0.571
1.73
ng/L
0.0173
1
0.571
1.73
ng/L
0.0173
1
0.571
1.73
ng/L
0.0173
1
0.173
0.432
ng/L
0.0173
1 RR3
0.173
0.432
ng/L
0.0173
1
0.173
0.432
ng/L
0.0173
1
0.173
0.432
ng/L
0.0173
1
0.173
0.432
ng/L
0.0173
1
0.173
0.432
ng/L
0.0173
1
0.173
0.432
ng/L
0.0173
1
0.173
0.432
ng/L
0.0173
1
0.173
0.432
ng/L
0.0173
1
0.173
0.432
ng/L
0.0173
1
0.173
0.432
ng/L
0.0173
1
03/20/23 2032 2400729 2
Page 40 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: EB-CC-Soil probe Project: NCDQ00123
Sample ID: 613703010 Client ID: NCDQ001
April 4, 2023
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic) UX
ND
0.173
0.432
ng/L
0.0173
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid UX
ND
0.173
0.432
ng/L
0.0173
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid UX
ND
0.173
0.432
ng/L
0.0173
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid UX
ND
0.173
0.432
ng/L
0.0173
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid U
ND
0.173
0.432
ng/L
0.0173
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid U
ND
0.173
0.432
ng/L
0.0173
1
(PFMOBA)
Perfluoroethoxypropionic acid UX
ND
0.173
0.432
ng/L
0.0173
1
(EVE)
Perfluoropropanoic acid (PFPrA) BJX
3.01
1.30
3.46
ng/L
0.0173
1
R-EVE UX
ND
1.14
3.46
ng/L
0.0173
1
Perfluoro(3,5,7,9,11- UX
ND
0.173
0.432
ng/L
0.0173
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2- UX
ND
0.173
0.432
ng/L
0.0173
1
(pentafluoroethoxy)propanoic acid
(PEPA)
Perfluoro-2- UX
ND
0.173
0.346
ng/L
0.0173
1
(perfluoromethoxy)propanoic acid
(PMPA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
SR2
03/18/23
1649 2400727
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 EPA 537.1 Modified
EPA 537.1 Modified
Notes:
Page 41 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: EB-CC-Soil probe
Sample ID: 613703010
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 42 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
EB-CC-Dipper2
Sample ID:
613703011
Matrix:
Water
Collect Date:
08-MAR-23 08:46
Receive Date:
09-MAR-23
Collector:
Client
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
11-Chloroeicosafluoro-3-
U
ND
oxaundecane-l-sulfonic acid(F-
53B Minor)
2-(N-ethylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U
ND
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
FTS)
N-ethylperfluoro-1-
U
ND
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
U
ND
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
U
ND
octanesulfonamide (N-McFOSA)
N-methylperfluoro-l-
U
ND
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
U
ND
Perfluorobutanoic acid (PFBA)
U
ND
Perfluorodecanesulfonic acid
U
ND
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
Perfluorododecanoic acid (PFDOA)
U
ND
Perfluoroheptanesulfonic acid
U
ND
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
Perfluorohexadecanoic acid
U
ND
0.598
1.81
ng/L
0.0181
1 JMB3 03/20/23 1140 2400729 1
1.20
3.62
ng/L
0.0181
1
1.20
3.62
ng/L
0.0181
1
1.20
3.56
ng/L
0.0181
1
1.20
3.41
ng/L
0.0181
1
1.20
3.44
ng/L
0.0181
1
1.20
3.48
ng/L
0.0181
1
1.20
3.62
ng/L
0.0181
1
1.20
3.62
ng/L
0.0181
1
1.20
3.62
ng/L
0.0181
1
1.20
3.62
ng/L
0.0181
1
0.598
3.62
ng/L
0.0181
1
0.598
1.61
ng/L
0.0181
1
0.725
1.81
ng/L
0.0181
1
0.598
1.76
ng/L
0.0181
1
0.707
1.81
ng/L
0.0181
1
0.598
1.81
ng/L
0.0181
1
0.598
1.72
ng/L
0.0181
1
0.598
1.81
ng/L
0.0181
1
1.20
3.62
ng/L
0.0181
1
Page 43 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: EB-CC-Dipper2
Sample ID: 613703011
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
(PFHxDA)
Perfluorohexanesulfonic acid
U
ND
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
Perfluorononanesulfonic acid
U
ND
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
Perfluorooctadecanoic acid
U
ND
(PFODA)
Perfluorooctanesulfonamide
U
ND
(PFESA)
Perfluorooctanesulfonic acid (PFOS)
U
ND
Perfluorooctanoic acid (PFOA)
U
ND
Perfluoropentanesulfonic acid
U
ND
(PFPeS)
Perfluoropentanoic acid (PFPeA)
U
ND
Perfluorotetradecanoic acid (PFTA)
U
ND
Perfluorotridecanoic Acid (PFTriA)
U
ND
Perfluoroundecanoic acid (PFUnA)
U
ND
4,8-Dioxa-3H-perfluorononanoic
U
ND
acid (DONA,ADONA)
1,1,2,2-Tctrafluoro-2-(1,2,2,2-
UX
ND
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nafion Byproduct 4 (PFESA BP4)
UX
ND
Nation Byproduct 5 (PFESA BP5)
UX
ND
Nation Byproduct 6 (PFESA BP6)
UX
ND
Hydro -EVE
UX
ND
Nation Byproduct 1 (PFESA BPI)
UX
ND
Nafion Byproduct 2 (PFESA BP2)
UX
ND
Nonafluoro-3,6-dioxaheptanoic
U
ND
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
0.598
1.65
ng/L
0.0181
1
0.725
1.81
ng/L
0.0181
1
0.634
1.74
ng/L
0.0181
1
0.598
1.81
ng/L
0.0181
1
1.20
3.62
ng/L
0.0181
1
0.598
1.81
ng/L
0.0181
1
0.725
1.81
ng/L
0.0181
1
0.725
1.81
ng/L
0.0181
1
0.598
1.70
ng/L
0.0181
1
0.598
1.81
ng/L
0.0181
1
0.725
1.81
ng/L
0.0181
1
0.598
1.81
ng/L
0.0181
1
0.598
1.81
ng/L
0.0181
1
0.598
1.81
ng/L
0.0181
1
0.181
0.453
ng/L
0.0181
1 RR3
0.181
0.453
ng/L
0.0181
1
0.181
0.453
ng/L
0.0181
1
0.181
0.453
ng/L
0.0181
1
0.181
0.453
ng/L
0.0181
1
0.181
0.453
ng/L
0.0181
1
0.181
0.453
ng/L
0.0181
1
0.181
0.453
ng/L
0.0181
1
0.181
0.453
ng/L
0.0181
1
0.181
0.453
ng/L
0.0181
1
0.181
0.453
ng/L
0.0181
1
03/20/23 2102 2400729 2
Page 44 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
April 4, 2023
Client Sample ID: EB-CC-Dipper2 Project: NCDQ00123
Sample ID: 613703011 Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic) UX ND
0.181
0.453
ng/L
0.0181
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid UX ND
0.181
0.453
ng/L
0.0181
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid UX ND
0.181
0.453
ng/L
0.0181
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid UX ND
0.181
0.453
ng/L
0.0181
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid U ND
0.181
0.453
ng/L
0.0181
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid U ND
0.181
0.453
ng/L
0.0181
1
(PFMOBA)
Perfluoroethoxypropionic acid UX ND
0.181
0.453
ng/L
0.0181
1
(EVE)
Perfluoropropanoic acid (PFPrA) BJX 3.01
1.36
3.62
ng/L
0.0181
1
R-EVE UX ND
1.20
3.62
ng/L
0.0181
1
Perfluoro(3,5,7,9,11- UX ND
0.181
0.453
ng/L
0.0181
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2- UX ND
0.181
0.453
ng/L
0.0181
1
(pentafluoroethoxy)propanoic acid
(PEPA)
Perfluoro-2- UX ND
0.181
0.362
ng/L
0.0181
1
(perfluoromethoxy)propanoic acid
(PMPA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
SR2
03/18/23
1649 2400727
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 EPA 537.1 Modified
EPA 537.1 Modified
Notes:
Page 45 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: EB-CC-Dipper2
Sample ID: 613703011
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 46 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
EB-CC-Dipperl
Sample ID:
613703012
Matrix:
Water
Collect Date:
08-MAR-23 08:41
Receive Date:
09-MAR-23
Collector:
Client
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
FTS)
Perfluorodecanoic acid (PFDA)
U
ND
Perfluoroheptanoic acid (PFHpA)
U
ND
11-Chloroeicosafluoro-3-
U
ND
oxaundecane-l-sulfonic acid (F-
53B Minor)
2-(N-ethylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
McFOSE)
9-Chlorohexadecafluoro-3-
U
ND
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
FTS)
N-ethylperfluoro-1-
U
ND
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
U
ND
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
U
ND
octanesulfonamide (N-McFOSA)
N-methylperfluoro-l-
U
ND
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorododecanesulfonic acid
U
ND
(PFDoS)
Perfluorobutanesulfonic acid (PFBS)
U
ND
Perfluorobutanoic acid (PFBA)
U
ND
Perfluorodecanesulfonic acid
U
ND
(PFDS)
Perfluorododecanoic acid (PFDOA)
U
ND
Perfluoroheptanesulfonic acid
U
ND
(PFHpS)
Perfluorohexadecanoic acid
U
ND
6.08
17.3
ng/L
0.0184
5 JMB3 03/20/23 1327 2400729
3.59
9.21
ng/L
0.0184
5
3.04
9.21
ng/L
0.0184
5
0.608
1.84
ng/L
0.0184
1 JMB3 03/20/23 1149 2400729
1.22
3.68
ng/L
0.0184
1
1.22
3.68
ng/L
0.0184
1
1.22
3.62
ng/L
0.0184
1
1.22
3.50
ng/L
0.0184
1
1.22
3.54
ng/L
0.0184
1
1.22
3.68
ng/L
0.0184
1
1.22
3.68
ng/L
0.0184
1
1.22
3.68
ng/L
0.0184
1
1.22
3.68
ng/L
0.0184
1
0.608
3.68
ng/L
0.0184
1
0.608
1.64
ng/L
0.0184
1
0.737
1.84
ng/L
0.0184
1
0.608
1.79
ng/L
0.0184
1
0.608
1.84
ng/L
0.0184
1
0.608
1.75
ng/L
0.0184
1
1.22
3.68
ng/L
0.0184
1
0
4
Page 47 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: EB-CC-Dipperl
Sample ID: 613703012
Parameter Qualifier Result
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
(PFHxDA)
Perfluorohexanesulfonic acid
U
ND
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
Perfluorononanesulfonic acid
U
ND
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
Perfluorooctadecanoic acid
U
ND
(PFODA)
Perfluorooctanesulfonamide
U
ND
(PFESA)
Perfluorooctanesulfonic acid (PFOS)
U
ND
Perfluorooctanoic acid (PFOA)
U
ND
Perfluoropentanesulfonic acid
U
ND
(PFPeS)
Perfluoropentanoic acid (PFPeA)
U
ND
Perfluorotetradecanoic acid (PFTA)
U
ND
Perfluorotridecanoic Acid (PFTriA)
U
ND
Perfluoroundecanoic acid (PFUnA)
U
ND
4,8-Dioxa-3H-perfluorononanoic
U
ND
acid (DONA,ADONA)
1,1,2,2-Tctrafluoro-2-(1,2,2,2-
UX
ND
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Nafion Byproduct 4 (PFESA BP4)
UX
ND
Nation Byproduct 5 (PFESA BP5)
UX
ND
Nation Byproduct 6 (PFESA BP6)
UX
ND
Hydro -EVE
UX
ND
Nation Byproduct 1 (PFESA BPI)
UX
ND
Nafion Byproduct 2 (PFESA BP2)
UX
ND
Nonafluoro-3,6-dioxaheptanoic
U
ND
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
DL RL Units PF DF Analyst Date Time Batch Method
0.608
1.68
ng/L
0.0184
1
0.737
1.84
ng/L
0.0184
1
0.645
1.77
ng/L
0.0184
1
0.608
1.84
ng/L
0.0184
1
1.22
3.68
ng/L
0.0184
1
0.608
1.84
ng/L
0.0184
1
0.737
1.84
ng/L
0.0184
1
0.737
1.84
ng/L
0.0184
1
0.608
1.73
ng/L
0.0184
1
0.608
1.84
ng/L
0.0184
1
0.737
1.84
ng/L
0.0184
1
0.608
1.84
ng/L
0.0184
1
0.608
1.84
ng/L
0.0184
1
0.608
1.84
ng/L
0.0184
1
0.184
0.460
ng/L
0.0184
1 RR3
0.184
0.460
ng/L
0.0184
1
0.184
0.460
ng/L
0.0184
1
0.184
0.460
ng/L
0.0184
1
0.184
0.460
ng/L
0.0184
1
0.184
0.460
ng/L
0.0184
1
0.184
0.460
ng/L
0.0184
1
0.184
0.460
ng/L
0.0184
1
0.184
0.460
ng/L
0.0184
1
0.184
0.460
ng/L
0.0184
1
0.184
0.460
ng/L
0.0184
1
03/20/23 2117 2400729 3
Page 48 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
April 4, 2023
Client Sample ID: EB-CC-Dipperl Project: NCDQ00123
Sample ID: 613703012 Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As Received"
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic) XU
ND
0.184
0.460
ng/L
0.0184
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid UX
ND
0.184
0.460
ng/L
0.0184
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid UX
ND
0.184
0.460
ng/L
0.0184
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid UX
ND
0.184
0.460
ng/L
0.0184
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid U
ND
0.184
0.460
ng/L
0.0184
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid U
ND
0.184
0.460
ng/L
0.0184
1
(PFMOBA)
Perfluoroethoxypropionic acid UX
ND
0.184
0.460
ng/L
0.0184
1
(EVE)
Perfluoropropanoic acid (PFPrA) BJX
2.48
1.38
3.68
ng/L
0.0184
1
R-EVE UX
ND
1.22
3.68
ng/L
0.0184
1
Perfluoro(3,5,7,9,11- UX
ND
0.184
0.460
ng/L
0.0184
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2- UX
ND
0.184
0.460
ng/L
0.0184
1
(pentafluoroethoxy)propanoic acid
(PEPA)
Perfluoro-2- UX
ND
0.184
0.368
ng/L
0.0184
1
(perfluoromethoxy)propanoic acid
(PMPA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
SR2
03/18/23
1649 2400727
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 EPA 537.1 Modified
EPA 537.1 Modified
EPA 537.1 Modified
Notes:
Page 49 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: EB-CC-Dipperl
Sample ID: 613703012
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 50 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID:
EB-CC-MetalBucket
Sample ID:
613703013
Matrix:
Water
Collect Date:
08-MAR-23 08:36
Receive Date:
09-MAR-23
Collector:
Client
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
2-(N-ethylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
octanesulfonamido)-ethanol (N-
McFOSE)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
FTS)
N-ethylperfluoro-l-
U
ND
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
U
ND
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
U
ND
octanesulfonamide (N-McFOSA)
N-methylperfluoro-l-
U
ND
octanesulfonamidoacetic acid (N-
McFOSAA)
Perfluorobutanesulfonic acid (PFBS)
U
ND
Perfluorobutanoic acid (PFBA)
U
ND
Perfluorododecanoic acid (PFDOA)
U
ND
Perfluorohexadecanoic acid
U
ND
(PFHxDA)
Perfluorohexanoic acid (PFHxA)
U
ND
Perfluorooctadecanoic acid
U
ND
(PFODA)
Perfluorooctanesulfonamide
U
ND
(PFOSA)
Perfluoropentanoic acid (PFPeA)
U
ND
Perfluorotetradecanoic acid (PFTA)
U
ND
Perfluorotridecanoic Acid (PFTriA)
U
ND
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
2,3,3,3-Tetrafluoro-2-
U
ND
(1, 1,2,2,3,3,3 -heptafluoropropoxy)-
propanoic acid (Gen-X)
4-
UX
ND
1.11
3.35
ng/L
0.0168 1 JMB3 03/20/23 1158 2400729 1
1.11
3.35
ng/L
0.0168 1
1.11
3.19
ng/L
0.0168 1
1.11
3.22
ng/L
0.0168 1
1.11
3.35
ng/L
0.0168 1
1.11
3.35
ng/L
0.0168 1
1.11
3.35
ng/L
0.0168 1
1.11
3.35
ng/L
0.0168 1
0.553
1.49
ng/L
0.0168
1
0.671
1.68
ng/L
0.0168
1
0.553
1.68
ng/L
0.0168
1
1.11
3.35
ng/L
0.0168
1
0.671
1.68
ng/L
0.0168
1
1.11
3.35
ng/L
0.0168
1
0.553
1.68
ng/L
0.0168
1
0.553
1.68
ng/L
0.0168
1
0.671
1.68
ng/L
0.0168
1
0.553
1.68
ng/L
0.0168
1
0.168
0.419
ng/L
0.0168
1 RR3 03/20/23 2132 2400729
0.168
0.419
ng/L
0.0168
1
0.168
0.419
ng/L
0.0168
1
►F]
Page 51 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: EB-CC-MetalBucket
Sample ID: 613703013
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier
Result
DL
RL
Units
PF
DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
(Heptafluoroisopropoxy)hexafluorob
utanoic acid (PFECA-G)
Naflon Byproduct 4 (PFESA BP4)
UX
ND
0.168
0.419
ng/L
0.0168
1
Nation Byproduct 5 (PFESA BP5)
UX
ND
0.168
0.419
ng/L
0.0168
1
Nafion Byproduct 6 (PFESA BP6)
UX
ND
0.168
0.419
ng/L
0.0168
1
Hydro -EVE
UX
ND
0.168
0.419
ng/L
0.0168
1
Nafion Byproduct 1 (PFESA BPI)
UX
ND
0.168
0.419
ng/L
0.0168
1
Naflon Byproduct 2 (PFESA BP2)
UX
ND
0.168
0.419
ng/L
0.0168
1
Nonafluoro-3,6-dioxahepanoic
U
ND
0.168
0.419
ng/L
0.0168
1
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
0.168
0.419
ng/L
0.0168
1
acid (PFEESA or PES)
Perfluoro(3,5,7,9-tetraoxadecanoic)
UX
ND
0.168
0.419
ng/L
0.0168
1
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) acid
UX
ND
0.168
0.419
ng/L
0.0168
1
(PF030A)
Perfluoro(3,5-dioxahexanoic) acid
UX
ND
0.168
0.419
ng/L
0.0168
1
(PF02HxA)
Perfluoro-2-methoxyacetic acid
UX
ND
0.168
0.419
ng/L
0.0168
1
(PFMOAA)
Perfluoro-3-methoxypropanoic acid
U
ND
0.168
0.419
ng/L
0.0168
1
(PFMOPrA)
Perfluoro(4-methoxybutanoic) acid
U
ND
0.168
0.419
ng/L
0.0168
1
(PFMOBA)
Perfluoroethoxypropionic acid
UX
ND
0.168
0.419
ng/L
0.0168
1
(EVE)
Perfluoropropanoic acid (PFPrA)
BJX
1.95
1.26
3.35
ng/L
0.0168
1
R-EVE
UX
ND
1.11
3.35
ng/L
0.0168
1
Perfluoro(3,5,7,9,1 I -
UX
ND
0.168
0.419
ng/L
0.0168
1
pentaoxadodecanoic) acid (PF05DA
or TAFN4)
2,3,3,3-Tetrafluoro-2-
UX
ND
0.168
0.419
ng/L
0.0168
1
(pentafluoroethoxy)propanoic acid
(PEPA)
Perfluoro-2-
UX
ND
0.168
0.335
ng/L
0.0168
1
(perfluoromethoxy)propanoic acid
(PMPA)
11-Chloroeicosafluoro-3-
U
ND
2.77
8.38
ng/L
0.0168
5 JMB3 03/20/23 1336 2400729 3
oxaundecane-l-sulfonic acid (F-
53B Minor)
Page 52 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: April 4, 2023
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: EB-CC-MetalBucket Project: NCDQ00123
Sample ID: 613703013 Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
LCMSMS PFCs
EPA 537Mod PFCs by LC-MS/MS "As
Received"
9-Chlorohexadecafluoro-3- U
ND
5.53
16.5
ng/L
0.0168
5
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2 U
ND
5.53
15.8
ng/L
0.0168
5
FTS)
Perfluorododecanesulfonic acid U
ND
2.77
16.8
ng/L
0.0168
5
(PFDoS)
Perfluorodecanesulfonic acid U
ND
2.77
8.13
ng/L
0.0168
5
(PFDS)
Perfluorodecanoic acid (PFDA) U
ND
3.27
8.38
ng/L
0.0168
5
Perfluorohepanesulfonic acid U
ND
2.77
7.96
ng/L
0.0168
5
(PFHpS)
Perfluoroheptanoic acid (PFHpA) U
ND
2.77
8.38
ng/L
0.0168
5
Perfluorohexanesulfonic acid U
ND
2.77
7.63
ng/L
0.0168
5
(PFHxS)
Perfluorononanesulfonic acid U
ND
2.93
8.05
ng/L
0.0168
5
(PFNS)
Perfluorononanoic acid (PFNA) U
ND
2.77
8.38
ng/L
0.0168
5
Perfluorooctanesulfonic acid (PFOS) U
ND
3.35
8.38
ng/L
0.0168
5
Perfluorooctanoic acid (PFDA) U
ND
3.35
8.38
ng/L
0.0168
5
Perfluoropentanesulfonic acid U
ND
2.77
7.88
ng/L
0.0168
5
(PFPeS)
Perfluoroundecanoic acid (PFUnA) U
ND
2.77
8.38
ng/L
0.0168
5
4,8-Dioxa-3H-perfluorononanoic U
ND
2.77
8.38
ng/L
0.0168
5
acid (DONA,ADONA)
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
EPA 537.1 Modified PFCs Extraction in Liquid
SR2
03/18/23
1649 2400727
The following Analytical Methods were performed:
Method Description Analyst Comments
1 EPA 537.1 Modified
2 EPA 537.1 Modified
3 EPA 537.1 Modified
Notes:
Page 53 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact: Stephanie Zorio
Project: Biosolids Sampling
Client Sample ID: EB-CC-MetalBucket
Sample ID: 613703013
Report Date: April 4, 2023
Project: NCDQ00123
Client ID: NCDQ001
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Column headers are defined as follows
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 54 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Company
Address :
Contact:
Project:
NCDENR
1641 Mail Service Center
Raleigh, North Carolina 27607
Stephanie Zorio
Biosolids Sampling
Certificate of Analysis
Report Date: April 4, 2023
Client Sample ID:
NCO026123-BIOS-20230308 Project: NCD000123
Sample ID:
613703003 Client ID: NCD0001
Matrix:
Solid
Collect Date:
08-MAR-23
Receive Date:
09-MAR-23
Collector:
Client
Moisture:
81.9%
Parameter Qualifier Result Uncertainty MDC TPU RL Units PF DF Analyst Date Time Batch Mtd.
Gravimetric Solids
'As Received"
The following Analytical Methods were performed
Method Description
ASTM D 2216 (Modified)
Surrogate/Tracer Recovery Test
Notes:
The MDC is a sample specific MDC.
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
Column headers are defined as follows:
DF: Dilution Factor Mtd.: Method
DL: Detection Limit PF: Prep Factor
Lc/LC: Critical Level RL: Reporting Limit
MDA: Minimum Detectable Activity TPU: Total Propagated Uncertainty
MDC: Minimum Detectable Concentration
Batch ID Recovery% Acceptable Limits
Page 55 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company: NCDENR
Address : 1641 Mail Service Center
Raleigh, North Carolina 27607
Contact:
Stephanie Zorio
Project:
Biosolids Sampling
Client Sample ID: NCO026123-GUIS-20230308
Sample ID:
613703004
Matrix:
Solid
Collect Date:
08-MAR-23
Receive Date:
09-MAR-23
Collector:
Client
Moisture:
18.2%
Report Date:
Project: NCD000123
Client ID: NCD0001
April 4, 2023
Parameter Qualifier Result Uncertainty MDC TPU RL Units PF DF Analyst Date Time Batch Mtd.
Gravimetric Solids
'As Received"
The following Analytical Methods were performed
Method Description
1 ASTM D 2216 (Modified)
Surrogate/Tracer Recovery Test Batch ID Recovery% Acceptable Limits
Notes:
The MDC is a sample specific MDC.
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
Column headers are defined as follows:
DF: Dilution Factor Mtd.: Method
DL: Detection Limit PF: Prep Factor
Lc/LC: Critical Level RL: Reporting Limit
MDA: Minimum Detectable Activity TPU: Total Propagated Uncertainty
MDC: Minimum Detectable Concentration
Page 56 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
NCDENR Renort Date: April 4, 2023
1641 Mail Service Center
Raleigh, North Carolina
Contact: Stephanie Zorio
Workorder: 613703
Page 1 of 66
Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400161
QC1205348953 LCS
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
19.7
x 17.4
ng/L
88
(60%-158%)
RR3
03/18/23 03:41
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
18.6
21.3
ng/L
114
(59%-144%)
JMB3
03/17/2310:50
oxaundecane- 1 -sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
19.7
19.3
ng/L
98
(67%-144%)
RR3
03/18/23 03:41
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
19.7
x 20.4
ng/L
103
(58%-144%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
19.7
25.8
ng/L
131 *
(54%-128%)
JM133
03/17/23 10:50
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
19.7
28.2
ng/L
143 *
(52%-141%)
octanesulfonamido)-ethanol (N-
McFOSE)
4,8-Dioxa-3H-perfluorononanoic
19.7
23.9
ng/L
121
(67%-154%)
acid (DONA,ADONA)
4-
19.7
x 20.5
ng/L
104
(73%-141%)
RR3
03/18/23 03:41
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
18.4
20.1
ng/L
109
(68%-135%)
JM133
03/17/2310:50
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
18.5
19.4
ng/L
105
(56%-151%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
18.8
16.2
ng/L
87
(60%-153%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2 19.0 21.3 ng/L 112 (60%-141%
FTS)
Hydro -EVE 19.7 x 22.7 ng/L 115 (61%-148%) RR3 03/18/23 03:41
Page 57 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 613703
Page 2 of 66
Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2400161
N-ethylperfluoro-l-
19.7
26.9
ng/L
136
(23%-155%) JMB3 03/17/2310:50
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
19.7
22.4
ng/L
113
(57%-139%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
19.7
24.3
ng/L
123
(20%-154%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-1-
19.7
28.7
ng/L
146*
(59%-145%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Naflon Byproduct 1 (PFESA BPI)
19.7
X
13.6
ng/L
69
(35%-138%) RR3 03/18/23 03:41
Nation Byproduct 2 (PFESA BP2)
19.7
X
20.1
ng/L
102
(63%-143%)
Nation Byproduct 4 (PFESA BP4)
19.7
X
2.63
ng/L
13
(5%-158%)
Nation Byproduct 5 (PFESA BP5)
19.7
X
3.42
ng/L
17
(5%-149%)
Nafion Byproduct 6 (PFESA BP6)
19.7
X
16.9
ng/L
86
(59%-145%)
Nonafluoro-3,6-dioxahepanoic
19.7
20.9
ng/L
106
(48%-149%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
19.7
18.0
ng/L
91
(52%-148%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 I -
19.7
x
22.0
ng/L
111
(58%-147%)
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
19.7
x
22.9
ng/L
116
(60%-151%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) 19.7 x 20.4 ng/L 103 (62%-148%
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid 19.7 X 19.6 ng/L 99 (60%-144%
(PF02HxA)
Page 58 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 613703
Page 3 of 66
Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400161
Perfluoro(4-methoxybutanoic) acid
19.7
19.4
ng/L
98
(58%-142%)
RR3
03/18/23 03:41
(PFMOBA)
Perfluoro-2-
19.7
x 18.9
ng/L
96
(50%-150%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
19.7
x 19.3
ng/L
98
(52%-144%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
19.7
19.6
ng/L
99
(60%-149%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid
17.5
19.7
ng/L
113
(70%-144%)
JMB3
03/17/23 10:50
(PFBS)
Perfluorobutanoic acid (PFBA)
19.7
21.8
ng/L
110
(73%-151%)
Perfluorohecanesulfonic acid
19.1
20.1
ng/L
106
(58%-134%)
(PFDS)
Perfluorodecanoic acid (PFDA)
19.7
22.5
ng/L
114
(65%-145%)
Perfluorododecanesulfonic acid
19.1
20.1
ng/L
105
(57%-134%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
19.7
23.6
ng/L
120
(65%-137%)
Perfluoroethoxypropionic acid
19.7
x 16.9
ng/L
86
(20%-160%)
RR3
03/18/23 03:41
(EVE)
Perfluoroheptanesulfonic acid
18.8
21.5
ng/L
115
(68%-138%)
JMB3
03/17/23 10:50
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
19.7
23.6
ng/L
119
(71%-133%
Perfluorohexadecanoic acid
19.7
22.2
ng/L
113
(69%-144%
(PFHxDA)
Perfluorohexanesulfonic acid 18.0 20.5 ng/L 114 (67%-145%
(PFHxS)
Page 59 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 613703
Page 4 of 66
Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400161
Perfluorohexanoic acid (PFHxA)
19.7
24.8
ng/L
126
(70%-138%)
JMB3
03/17/23 10:50
Perfluorononanesulfonic acid
19.0
20.0
ng/L
106
(64%-133%)
(PFNS)
Perfluorononanoic acid (PFNA)
19.7
19.7
ng/L
100
(69%-133%)
Perfluorooctadecanoic acid
19.7
14.9
ng/L
75
(35%-165%)
(PFODA)
Perfluorooctanesulfonamide
19.7
22.1
ng/L
112
(64%-134%)
(PFOSA)
Perfluorooctanesulfonic acid
19.7
23.2
ng/L
117
(65%-145%)
(PFOS)
Perfluorooctanoic acid (PFOA)
19.7
23.2
ng/L
118
(66%-139%)
Perfluoropentanesulfonic acid
18.6
20.9
ng/L
113
(67%-136%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
19.7
21.9
ng/L
111
(72%-143%)
Perfluoropropanoic acid (PFPrA)
19.7
BX 23.9
ng/L
121
(49%-153%)
RR3
03/18/23 03:41
Perfluorotetradecanoic acid (PFTA)
19.7
23.3
ng/L
118
(66%-138%)
JMB3
03/17/23 10:50
Perfluorotridecanoic Acid (PFTriA)
19.7
23.0
ng/L
117
(58%-140%)
Perfluoroundecanoic acid (PFUnA)
19.7
23.2
ng/L
117
(63%-135%)
R-EVE
19.7
7X 3.54
ng/L
18
(5%-158%)
RR3
03/18/23 03:41
QC1205348954 LCSD
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
19.4
X 19.3
ng/L 10
99
(0%-30%)
03/18/23 03:56
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
Page 60 of 136 SDG: 613703

GEL LABORATORIES LLC
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QC Summary
Workorder: 613703
Page 5 of 66
Parmname
NOM
Sample Qual QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400161
11-Chloroeicosafluoro-3-
18.3
20.2
ng/L
5
111
(0%-27%)
JMB3
03/17/2310:59
oxaundecane-1-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
19.4
21.8
ng/L
12
112
(0%-30%)
RR3
03/18/23 03:56
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
19.4
x 22.8
ng/L
11
117
(0%-27%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
19.4
27.6
ng/L
7
142*
(0%-28%)
JMB3
03/17/2310:59
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-1-
19.4
28.6
ng/L
2
147*
(0%-30%)
octanesulfonamido)-ethanol (N-
McFOSE)
4,8-Dioxa-3H-perfluorononanoic
19.4
25.4
ng/L
6
131
(0%-26%)
acid (DONA,ADONA)
4-
19.4
x 23.3
ng/L
13
120
(0%-24%)
RR3
03/18/23 03:56
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
18.1
24.2
ng/L
18
134
(0%-26%)
JMB3
03/17/23 10:59
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
18.2
15.3
ng/L
24
84
(0%-32%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
18.4
21.1
ng/L
26
114
(0%-32%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
18.6
22.2
ng/L
4
119
(0%-36%)
FTS)
Hydro -EVE
19.4
x 25.9
ng/L
13
134
(0%-24%)
RR3
03/18/23 03:56
N-ethylperfluoro-l-
19.4
25.3
ng/L
6
130
(0%-27%)
JMB3
03/17/2310:59
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
19.4
21.9
ng/L
2
113
(0%-27%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
19.4
28.8
ng/L
17
148
(0%-36%)
octanesulfonamide (N-McFOSA)
Page 61 of 136 SDG: 613703

GEL LABORATORIES LLC
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QC Summary
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Page 6 of 66
Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2400161
N-methylperfluoro-I-
19.4
25.7
ng/L
11
132
(0%-27%) JMB3
03/17/2310:59
octanesulfonamidoacetic acid (N-
McFOSAA)
Nation Byproduct 1 (PFESA BPI)
19.4
x
17.9
ng/L
27
92
(0%-28%) RR3
03/18/23 03:56
Nafion Byproduct 2 (PFESA BP2)
19.4
x
22.9
ng/L
13
118
(0%-23%)
Nafion Byproduct 4 (PFESA BP4)
19.4
x
2.53
ng/L
4
13
(0%-45%)
Naflon Byproduct 5 (PFESA BP5)
19.4
x
2.91
ng/L
16
15
(0%-40%)
Nafion Byproduct 6 (PFESA BP6)
19.4
x
20.4
ng/L
19
105
(0%-26%)
Nonafluoro-3,6-dioxahepanoic
19.4
23.3
ng/L
11
120
(0%-27%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
19.4
21.5
ng/L
18
111
(0%-35%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 I -
19.4
x
23.8
ng/L
8
123
(0%-40%)
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
19.4
x
23.5
ng/L
2
121
(0%-39%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
19.4
x
24.2
ng/L
17
125
(0%-36%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
19.4
x
21.3
ng/L
8
110
(0%-27%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
19.4
22.0
ng/L
13
114
(0%-29%)
(PFMOBA)
Perfluoro-2-
19.4
x
22.0
ng/L
15
113
(0%-30%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
19.4
x
22.2
ng/L
14
114
(0%-31%)
(PFMOAA)
Page 62 of 136 SDG: 613703

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QC Summary
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Page 7 of 66
Parmname
NOM
Sample Qual QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400161
Perfluoro-3-methoxypropanoic
19.4
22.7
ng/L
15
117
(0%-25%)
RR3
03/18/23 03:56
acid (PFMOPrA)
Perfluorobutanesulfonic acid
17.2
19.6
ng/L
0
114
(0%-35%)
JMB3
03/17/23 10:59
(PFBS)
Perfluorobutanoic acid (PFBA)
19.4
24.4
ng/L
12
126
(0%-20%)
Perfluorodecanesulfonic acid
18.7
21.8
ng/L
8
116
(0%-30%)
(PFDS)
Perfluorodecanoic acid (PFDA)
19.4
24.4
ng/L
8
125
(0%-31%)
Perfluorododecanesulfonic acid
18.8
21.1
ng/L
5
112
(0%-32%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
19.4
23.5
ng/L
0
121
(0%-26%)
Perfluoroethoxypropionic acid
19.4
X 20.8
ng/L
21
107
(0%-30%)
RR3
03/18/23 03:56
(EVE)
Perfluoroheptanesulfonic acid
18.4
23.4
ng/L
9
127
(0%-40%)
JMB3
03/17/23 10:59
(PFHpS)
Perfluorohepanoic acid (PFHpA)
19.4
23.4
ng/L
1
120
(0%-23%)
Perfluorohexadecanoic acid
19.4
23.6
ng/L
6
122
(0%-26%)
(PFHxDA)
Perfluorohexanesulfonic acid
17.7
23.0
ng/L
11
130
(0%-27%)
(PFHxS)
Perfluorohexanoic acid (PFHxA)
19.4
26.0
ng/L
4
134
(0%-27%)
Perfluorononanesulfonic acid
18.6
22.9
ng/L
13
123
(0%-27%)
(PFNS)
Perfluorononanoic acid (PFNA) 19.4 24.1 ng/L 20 124 (0%-25%
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Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400161
Perfluorooctadecanoic acid
19.4
11.5
ng/L
26
59
(0%-39%)
JMB3
03/17/23 10:59
(PFODA)
Perfluorooctanesulfonamide
19.4
22.7
ng/L
3
117
(0%-26%)
(PFOSA)
Perfluorooctanesulfonic acid
19.4
26.7
ng/L
14
138
(0%-25%)
(PFOS)
Perfluorooctanoic acid (PFOA)
19.4
23.2
ng/L
0
119
(0%-27%)
Perfluoropentanesulfonic acid
18.3
21.8
ng/L
4
120
(0%-40%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
19.4
25.4
ng/L
15
131
(0%-25%)
Perfluoropropanoic acid (PFPrA)
19.4
BX
25.4
ng/L
6
131
(0%-26%)
RR3
03/18/23 03:56
Perfluorotetradecanoic acid (PFTA)
19.4
25.5
ng/L
9
131
(0%-26%)
JMB3
03/17/23 10:59
Perfluorotridecanoic Acid (PFTriA)
19.4
24.7
ng/L
7
127
(0%-31%)
Perfluoroundccanoic acid (PFUnA)
19.4
22.2
ng/L
4
114
(0%-30%)
R-EVE
19.4
A
3.03
ng/L
15
16
(0%-26%)
RR3
03/18/23 03:56
QC1205348952 MB
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
ng/L
03/18/23 03:26
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
U
ND
ng/L
JMB3
03/17/2310:42
oxaundecane-l-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
U
ND
ng/L
RR3
03/18/23 03:26
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
UX
ND
ng/L
(pentafluoroethoxy)propanoic acid
(PEPA)
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QC Summary
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Parmname NOM
Sample Qual
QC
Units RPD/D% REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2400161
2-(N-ethylperfluoro-l-
U
ND
ng/L
JMB3
03/17/2310:42
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-I-
U
ND
ng/L
octanesulfonamido)-ethanol (N-
McFOSE)
4,8-Dioxa-3H-perfluorononanoic
U
ND
ng/L
acid (DONA,ADONA)
4-
Ux
ND
ng/L
RR3
03/18/23 03:26
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
U
ND
ng/L
JMB3
03/17/2310:42
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
ng/L
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
ng/L
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
ng/L
FTS)
Hydro -EVE
xU
ND
ng/L
RR3
03/18/23 03:26
N-ethylperfluoro-I-
U
ND
ng/L
JMB3
03/17/2310:42
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
U
ND
ng/L
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-I-
U
ND
ng/L
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
U
ND
ng/L
octanesulfonamidoacetic acid (N-
McFOSAA)
Nation Byproduct 1 (PFESA BPI)
Ux
ND
ng/L
RR3
03/18/23 03:26
Naflon Byproduct 2 (PFESA BP2) Ux ND ng/L
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QC Summary
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC% Range Anlst Date Time
Perfluorinated Compounds
Batch 2400161
Nation Byproduct 4 (PFESA BP4)
Ux
ND
ng/L RR3 03/18/23 03:26
Nation Byproduct 5 (PFESA BP5)
Ux
ND
ng/L
Nation Byproduct 6 (PFESA BP6)
Ux
ND
ng/L
Nonafluoro-316-dioxaheptanoic
U
ND
ng/L
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
ng/L
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 1 -
Ux
ND
ng/L
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
Ux
ND
ng/L
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
Ux
ND
ng/L
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
Ux
ND
ng/L
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
U
ND
ng/L
(PFMOBA)
Perfluoro-2-
Ux
ND
ng/L
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
Ux
ND
ng/L
(PFMOAA)
Perfluoro-3-methoxypropanoic
U
ND
ng/L
acid (PFMOPrA)
Perfluorobutanesulfonic acid U ND ng/L JMB3 03/17/23 10:42
(PFBS)
Perfluorobutanoic acid (PFBA) U ND ng/L
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QC Summary
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2400161
Perfluorodecanesulfonic acid
U
ND
ng/L
JMB3 03/17/23 10:42
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
ng/L
Perfluorododecanesulfonic acid
U
ND
ng/L
(PFDoS)
Perfluorododecanoic acid (PFDOA)
U
ND
ng/L
Perfluoroethoxypropionic acid
UX
ND
ng/L
RR3 03/18/23 03:26
(EVE)
Perfluoroheptanesulfonic acid
U
ND
ng/L
JMB3 03/17/23 10:42
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
ng/L
Perfluorohexadecanoic acid
U
ND
ng/L
(PFHxDA)
Perfluorohexanesulfonic acid
U
ND
ng/L
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
ng/L
Perfluorononanesulfonic acid
U
ND
ng/L
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
ng/L
Perfluorooctadecanoic acid
U
ND
ng/L
(PFODA)
Perfluorooctanesulfonamide
U
ND
ng/L
(PFOSA)
Perfluorooctanesulfonic acid U ND ng/L
(PFOS)
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400161
Perfluorooctanoic acid (PFOA)
U
ND
ng/L
JMB3
03/17/23 10:42
Perfluoropentanesulfonic acid
U
ND
ng/L
(PFPeS)
Perfluoropentanoic acid (PFPeA)
U
ND
ng/L
Perfluoropropanoic acid (PFPrA)
X
5.83
ng/L
RR3
03/18/23 03:26
Perfluorotetradecanoic acid (PFTA)
U
ND
ng/L
JMB3
03/17/23 10:42
Perfluorotridecanoic Acid (PFTriA)
U
ND
ng/L
Perfluoroundecanoic acid (PFUnA)
U
ND
ng/L
R-EVE
UX
ND
ng/L
RR3
03/18/23 03:26
Batch 2400381
QC1205349340 LCS
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
4.72
X
5.60
ng/g
119
(50%-150%)
RR3
03/20/2314:59
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
4.44
5.91
ng/g
133
(69%-143%)
MB2
03/18/2314:14
oxaundecane-l-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
4.72
4.93
ng/g
104
(72%-137%)
RR3
03/20/2314:59
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
4.72
X
5.57
ng/g
118
(59%-145%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
4.72
4.87
ng/g
103
(61%-131%)
MB2
03/18/2314:14
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
4.72
5.02
ng/g
106
(66%-140%)
octanesulfonamido)-ethanol (N-
McFOSE)
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QC Summary
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Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400381
2H,2H,3H,3H-Perfluorodecanoic
4.72
4.92
ng/g
104
(49%-150%)
MB2
03/18/2314:14
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
4.72
5.37
ng/g
114
(54%-145%)
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
4.72
5.06
ng/g
107
(59%-131%)
acid (3:3 FTCA)(FPrPA)
4,8-Dioxa-3H-perfluorononanoic
4.72
5.70
ng/g
121
(70%-135%)
acid (DONA,ADONA)
4-
4.72
x 4.92
ng/g
104
(60%-141%)
RR3
03/20/2314:59
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
4.40
5.78
ng/g
131
(66%-140%)
M132
03/18/23 14:14
oxanonane-l-sulfonic acid (F-5313
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
4.41
4.51
ng/g
102
(63%-144%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
4.48
5.66
ng/g
126
(62%-148%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
4.53
5.64
ng/g
125
(65%-144%)
FTS)
Hydro -EVE
4.72
x 6.23
ng/g
132
(50%-150%)
RR3
03/20/2314:59
N-ethylperfluoro-l-
4.72
5.65
ng/g
120
(73%-140%)
M132
03/18/2314:14
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
4.72
5.00
ng/g
106
(66%-141%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-I-
4.72
6.61
ng/g
140*
(70%-136%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
4.72
6.60
ng/g
140
(68%-141%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Naflon Byproduct 1 (PFESA BPI)
4.72
x 5.34
ng/g
113
(63%-138%)
RR3
03/20/23 14:59
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Page 14 of 66
Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2400381
Nation Byproduct 2 (PFESA BP2)
4.72
X
5.35
ng/g
113
(64%-142%) RR3 03/20/23 14:59
Nation Byproduct 4 (PFESA BP4)
4.72
X
5.26
ng/g
112
(50%-150%)
Nation Byproduct 5 (PFESA BP5)
4.72
X
5.56
ng/g
118
(50%-150%)
Naflon Byproduct 6 (PFESA BP6)
4.72
X
5.47
ng/g
116
(50%-150%)
Nonafluoro-316-dioxaheptanoic
4.72
5.41
ng/g
115
(50%-150%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
4.72
5.52
ng/g
117
(50%-150%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,11-
4.72
X
4.84
ng/g
103
(58%-151%)
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
4.72
X
5.26
ng/g
112
(59%-158%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
4.72
x
4.80
ng/g
102
(58%-156%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
4.72
x
5.27
ng/g
112
(67%-142%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
4.72
5.36
ng/g
114
(64%-142%)
(PFMOBA)
Perfluoro-2-
4.72
X
5.40
ng/g
115
(50%-150%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
4.72
X
5.17
ng/g
110
(64%-146%)
(PFMOAA)
Perfluoro-3-methoxypropanoic 4.72 5.60 ng/g 119 (60%-159%
acid (PFMOPrA)
Perfluorobutanesulfonic acid 4.17 4.81 ng/g 115 (71%-136%) MB2 03/18/23 14:14
(PFBS)
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Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst Date Time
Perfluorinated Compounds
Batch 2400381
Perfluorobutanoic acid (PFBA)
4.72
5.72
ng/g
121
(66%-141%)
MB2 03/18/23 14:14
Perfluorodecanesulfonic acid
4.55
5.95
ng/g
131
(70%-139%)
(PFDS)
Perfluorodecanoic acid (PFDA)
4.72
5.92
ng/g
125
(66%-139%)
Perfluorododecanesulfonic acid
4.57
5.98
ng/g
131
(54%-148%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
4.72
5.73
ng/g
122
(70%-139%)
Perfluoroethoxypropionic acid
4.72
X 5.28
ng/g
112
(50%-150%)
RR3 03/20/23 14:59
(EVE)
Perfluoroheptanesulfonic acid
4.48
5.45
ng/g
122
(72%-138%)
MB2 03/18/23 14:14
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
4.72
4.77
ng/g
101
(72%-132%)
Perfluorohexanesulfonic acid
4.30
5.20
ng/g
121
(68%-139%)
(PFHxS)
Perfluorohexanoic acid (PFHxA)
4.72
4.77
ng/g
101
(70%-135%)
Perfluorononanesulfonic acid
4.53
5.95
ng/g
131
(60%-138%)
(PFNS)
Perfluorononanoic acid (PFNA)
4.72
5.39
ng/g
114
(70%-136%)
Perfluorooctanesulfonamide
4.72
5.50
ng/g
117
(76%-138%)
(PFOSA)
Perfluorooctanesulfonic acid
4.72
5.94
ng/g
126
(73%-135%)
(PFOS)
Perfluorooctanoic acid (PFDA)
4.72
5.32
ng/g
113
(72%-135%)
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400381
Perfluoropentanesulfonic acid
4.43
5.14
ng/g
116
(66%-138%)
MB2
03/18/23 14:14
(PFPeS)
Perfluoropentanoic acid (PFPeA)
4.72
5.19
ng/g
110
(72%-155%)
Perfluorotetradecanoic acid (PFTA)
4.72
5.32
ng/g
113
(72%-139%)
Perfluorotridecanoic Acid (PFTriA)
4.72
5.40
ng/g
115
(60%-149%)
Perfluoroundecanoic acid (PFUnA)
4.72
5.44
ng/g
115
(70%-135%)
R-EVE
4.72
X
5.66
ng/g
120
(50%-150%)
RR3
03/20/2314:59
QC1205349339 MB
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
ng/g
03/20/2314:44
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
U
ND
ng/g
MB2
03/18/2314:05
oxaundecane-l-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
U
ND
ng/g
RR3
03/20/2314:44
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
UX
ND
ng/g
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
U
ND
ng/g
MB2
03/18/2314:05
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
U
ND
ng/g
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
U
ND
ng/g
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
U
ND
ng/g
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
U
ND
ng/g
acid (3:3 FTCA)(FPrPA)
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QC Summary
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Page 17 of 66
Parmname NOM
Sample Qual
QC
Units RPD/D% REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2400381
4,8-Dioxa-3H-perfluorononanoic
U
ND
ng/g
MB2
03/18/2314:05
acid (DONA,ADONA)
4-
Ux
ND
ng/g
RR3
03/20/2314:44
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
U
ND
ng/g
MB2
03/18/23 14:05
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
ng/g
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
ng/g
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
ng/g
FTS)
Hydro -EVE
Ux
ND
ng/g
RR3
03/20/2314:44
N-ethylperfluoro-I-
U
ND
ng/g
MB2
03/18/2314:05
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
U
ND
ng/g
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-I-
U
ND
ng/g
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
U
ND
ng/g
octanesulfonamidoacetic acid (N-
McFOSAA)
Nafion Byproduct 1 (PFESA BPI)
Ux
ND
ng/g
RR3
03/20/23 14:44
Naflon Byproduct 2 (PFESA BP2) Ux ND ng/g
Nation Byproduct 4 (PFESA BP4) Ux ND ng/g
Naflon Byproduct 5 (PFESA BP5) Ux ND ng/g
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC% Range Anlst Date Time
Perfluorinated Compounds
Batch 2400381
Nation Byproduct 6 (PFECA BP6)
Ux
ND
ng/g RR3 03/20/23 14:44
Nonafluoro-316-dioxaheptanoic
U
ND
ng/g
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
ng/g
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 1 -
Ux
ND
ng/g
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
Ux
ND
ng/g
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
Ux
ND
ng/g
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
Ux
ND
ng/g
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
U
ND
ng/g
(PFMOBA)
Perfluoro-2-
Ux
ND
ng/g
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
Ux
ND
ng/g
(PFMOAA)
Perfluoro-3-methoxypropanoic
U
ND
ng/g
acid (PFMOPrA)
Perfluorobutanesulfonic acid
U
ND
ng/g MB2 03/18/23 14:05
(PFBS)
Perfluorobutanoic acid (PFBA) U ND ng/g
Perfluorodecanesulfonic acid U ND ng/g
(PFDS)
Perfluorodecanoic acid (PFDA) U ND ng/g
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2400381
Perfluorododecanesulfonic acid
U
ND
ng/g
MB2 03/18/23 14:05
(PFDoS)
Perfluorododecanoic acid (PFDOA)
U
ND
ng/g
Perfluoroethoxypropionic acid
UX
ND
ng/g
RR3 03/20/23 14:44
(EVE)
Perfluoroheptanesulfonic acid
U
ND
ng/g
MB2 03/18/23 14:05
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
ng/g
Perfluorohexanesulfonic acid
U
ND
ng/g
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
ng/g
Perfluorononanesulfonic acid
U
ND
ng/g
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
ng/g
Perfluorooctanesulfonamide
U
ND
ng/g
(PFOSA)
Perfluorooctanesulfonic acid
U
ND
ng/g
(PFOS)
Perfluorooctanoic acid (PFOA) U ND ng/g
Perfluoropentanesulfonic acid U ND ng/g
(PFPeS)
Perfluoropentanoic acid (PFPeA) U ND ng/g
Perfluorotetradecanoic acid (PFTA) U ND ng/g
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Parmname
NOM
Sample
Qual
QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400381
Perfluorotridecanoic Acid (PFTriA)
U
ND
ng/g
MB2
03/18/23 14:05
Perfluoroundecanoic acid (PFUnA)
U
ND
ng/g
R-EVE
UX
ND
ng/g
RR3
03/20/2314:44
QC1205349341 613703003 MS
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
25.8
UX
ND
X
31.0
ng/g
120
(42%-158%)
03/20/2315:29
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
24.3
U
ND
20.8
ng/g
85
(43%-141%)
MB2
03/18/2314:31
oxaundecane- 1 -sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
25.8
U
ND
34.3
ng/g
133
(61%-150%)
RR3
03/20/2315:29
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
25.8
UX
ND
X
29.9
ng/g
116
(43%-154%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
25.8
7
2.41
18.0
ng/g
60
(49%-153%)
MB2
03/18/2314:31
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
25.8
8.10
36.4
ng/g
110
(54%-154%)
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
25.8
9.55
44.4
ng/g
135
(30%-157%)
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
25.8
24.9
61.4
ng/g
141
(31%-158%)
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
25.8
U
ND
33.4
ng/g
129
(32%-153%)
acid (3:3 FTCA)(FPrPA)
4,8-Dioxa-3H-perfluorononanoic
25.8
U
ND
34.1
ng/g
132
(63%-143%)
acid (DONA,ADONA)
4-
25.8
UX
ND
X
27.3
ng/g
106
(54%-161%)
RR3
03/20/2315:29
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
24.1
U
ND
23.4
ng/g
97
(62%-146%)
MB2
03/18/2314:31
oxanonane-l-sulfonic acid (F-53B
Major)
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Parmname
NOM
Sample
Qual
QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400381
Fluorotelomer sulfonic acid 4:2 (4:2
24.1
U
ND
26.8
ng/g
111
(62%-148%)
MB2
03/18/23 14:31
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
24.5
U
ND
28.3
ng/g
115
(50%-153%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
24.8
U
ND
J
18.4
ng/g
74
(53%-158%)
03/18/23 16:33
FTS)
Hydro -EVE
25.8
UX
ND
X
35.1
ng/g
136
(51 %-148%)
RR3
03/20/23 15:29
N-ethylperfluoro-1-
25.8
U
ND
30.6
ng/g
118
(48%-148%)
MB2
03/18/2314:31
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
25.8
J
4.32
31.9
ng/g
107
(65%-152%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-I-
25.8
U
ND
35.1
ng/g
136
(55%-151%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
25.8
6.80
47.5
ng/g
158 *
(59%-152%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Nafion Byproduct 1 (PFESA BPI)
25.8
UX
ND
X
31.0
ng/g
120
(60%-147%)
RR3
03/20/23 15:29
Nation Byproduct 2 (PFESA BP2)
25.8
UX
ND
X
32.1
ng/g
124
(65%-150%)
Nafion Byproduct 4 (PFESA BP4)
25.8
UX
ND
X
121
ng/g
470 *
(40%-160%)
Nafion Byproduct 5 (PFESA BP5)
25.8
UX
ND
X
86.0
ng/g
333 *
(40%-160%)
Nafion Byproduct 6 (PFESA BP6)
25.8
UX
ND
X
33.1
ng/g
128
(53%-153%)
Nonafluoro-316-dioxaheptanoic
25.8
U
ND
32.3
ng/g
125
(43%-163%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic 25.8 U ND 33.1 ng/g 128 (48%-148%
acid (PFEESA or PES)
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Parmname
NOM
Sample
Qual
QC
Units RPD/D%
REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2400381
Perfluoro(3,5,7,9,11-
25.8
UX
ND
X
33.9
ng/g
131
(42%-167%) RR3 03/20/2315:29
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
25.8
UX
ND
X
30.2
ng/g
117
(49%-162%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
25.8
UX
ND
X
31.6
ng/g
123
(44%-167%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
25.8
UX
ND
X
35.1
ng/g
136
(57%-153%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
25.8
U
ND
34.4
ng/g
133
(47%-166%)
(PFMOBA)
Perfluoro-2-
25.8
UX
ND
X
34.4
ng/g
133
(50%-150%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
25.8
UX
ND
X
30.0
ng/g
116
(49%-169%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
25.8
U
ND
35.5
ng/g
137
(40%-162%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid
22.9
U
ND
29.0
ng/g
127
(67%-146%) MB2 03/18/23 14:31
(PFBS)
Perfluorobutanoic acid (PFBA)
25.8
U
ND
32.2
ng/g
125
(56%-156%)
Perfluorodecanesulfonic acid
24.9
J
1.18
27.8
ng/g
107
(61%-150%)
(PFDS)
Perfluorodecanoic acid (PFDA)
25.8
U
ND
31.9
ng/g
117
(59%-153%
Perfluorododecanesulfonic acid
25.0
U
ND
22.4
ng/g
89
(39%-149%
(PFDoS)
Perfluorododecanoic acid (PFDOA)
25.8
J
1.73
31.6
ng/g
116
(59%-147%)
Perfluoroethoxypropionic acid
25.8
UX
ND X
28.9
ng/g
112
(49%-151%) RR3 03/20/23 15:29
(EVE)
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2400381
Perfluoroheptanesulfonic acid
24.5
U
ND
29.5
ng/g
120
(50%-156%) MB2 03/18/23 14:31
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
25.8
U
ND
30.9
ng/g
120
(61%-149%)
Perfluorohexanesulfonic acid
23.6
U
ND
25.2
ng/g
107
(64%-150%)
(PFHxS)
Perfluorohexanoic acid (PFHxA)
25.8
U
ND
28.0
ng/g
108
(61%-151%)
Perfluorononanesulfonic acid
24.8
U
ND
27.7
ng/g
112
(47%-147%)
(PFNS)
Perfluorononanoic acid (PFNA)
25.8
U
ND
30.0
ng/g
116
(58%-152%)
Perfluorooctanesulfonamide
25.8
7
1.03
33.4
ng/g
126
(68%-153%)
(PFOSA)
Perfluorooctanesulfonic acid
25.8
9.72
37.8
ng/g
109
(53%-157%)
(PFOS)
Perfluorooctanoic acid (PFOA)
25.8
U
ND
31.2
ng/g
121
(53%-155%)
Perfluoropentanesulfonic acid
24.3
U
ND
27.0
ng/g
111
(58%-150%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
25.8
U
ND
28.8
ng/g
111
(66%-150%)
Perfluorotetradecanoic acid (PFTA)
25.8
U
ND
29.9
ng/g
116
(60%-157%)
Perfluorotridecanoic Acid (PFTriA)
25.8
U
ND
38.0
ng/g
147
(35%-157%)
Perfluoroundecanoic acid (PFUnA)
25.8
7
0.911
31.9
ng/g
120
(58%-154%)
R-EVE
25.8
UX
ND X
103
ng/g
400*
(40%-160%) RR3 03/20/2315:29
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Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400381
QC1205349342 613703003 MSD
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
25.4
UX
ND X
31.5
ng/g
2
124
(0%-30%)
RR3
03/20/2315:45
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
23.9
U
ND
20.9
ng/g
1
88
(0%-30%)
MB2
03/18/2314:40
oxaundecane- 1 -sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
25.4
U
ND
33.0
ng/g
4
130
(0%-30%)
RR3
03/20/2315:45
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
25.4
UX
ND X
28.3
ng/g
5
112
(0%-30%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
25.4
J
2.41
26.5
ng/g
38*
95
(0%-30%)
MB2
03/18/2314:40
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
25.4
8.10
39.9
ng/g
9
125
(0%-30%)
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
25.4
9.55
43.2
ng/g
3
133
(0%-30%)
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
25.4
24.9
55.7
ng/g
10
122
(0%-30%)
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
25.4
U
ND
28.2
ng/g
17
ill
(0%-30%)
acid (3:3 FTCA)(FPrPA)
4,8-Dioxa-3H-perfluorononanoic
25.4
U
ND
30.5
ng/g
11
120
(0%-30%)
acid (DONA,ADONA)
4-
25.4
UX
ND X
26.5
ng/g
3
105
(0%-30%)
RR3
03/20/2315:45
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
23.6
U
ND
25.2
ng/g
8
107
(0%-30%)
MB2
03/18/2314:40
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
23.7
U
ND
28.0
ng/g
5
118
(0%-30%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
24.1
U
ND
30.5
ng/g
8
127
(0%-30%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
24.3
U
ND
32.0
ng/g
54 *
132
(0%-30%)
03/18/23 16:42
FTS)
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Parmname
NOM
Sample
Qual
QC
Units
RPD/D%
REC%
Range
Anlst Date Time
Perfluorinated Compounds
Batch 2400381
Hydro -EVE
25.4
UX
ND
X
33.2
ng/g
6
131
(0%-30%)
RR3 03/20/2315:45
N-ethylperfluoro-I-
25.4
U
ND
31.4
ng/g
3
124
(0%-30%)
MB2 03/18/2314:40
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
25.4
7
4.32
29.0
ng/g
10
97
(0%-30%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
25.4
U
ND
29.7
ng/g
17
117
(0%-30%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-1-
25.4
6.80
37.1
ng/g
25
119
(0%-30%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Naflon Byproduct 1 (PFESA BPI)
25.4
UX
ND
X
30.7
ng/g
1
121
(0%-30%)
RR3 03/20/23 15:45
Nafon Byproduct 2 (PFESA BP2)
25.4
UX
ND
X
29.2
ng/g
10
115
(0%-30%)
Nafon Byproduct 4 (PFESA BP4)
25.4
UX
ND
X
145
ng/g
17
570 *
(0%-30%)
Naflon Byproduct 5 (PFESA BP5)
25.4
UX
ND
X
91.0
ng/g
6
359 *
(0%-30%)
Nation Byproduct 6 (PFESA BP6)
25.4
UX
ND
X
33.0
ng/g
0
130
(0%-30%)
Nonafluoro-3,6-dioxaheptanoic
25.4
U
ND
32.8
ng/g
2
129
(0%-30%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
25.4
U
ND
32.3
ng/g
3
127
(0%-30%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 I -
25.4
UX
ND
X
33.5
ng/g
1
132
(0%-30%)
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
25.4
UX
ND
X
30.3
ng/g
0
119
(0%-30%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic) 25.4 UX ND X 30.7 ng/g 3 121 (0%-30%
acid (PF030A)
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Parmname
NOM
Sample
Qual
QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400381
Perfluoro(3,5-dioxahexanoic) acid
25.4
UX
ND
X
33.5
ng/g
5
132
(0%-30%)
RR3
03/20/23 15:45
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
25.4
U
ND
34.2
ng/g
1
135
(0%-30%)
(PFMOBA)
Perfluoro-2-
25.4
UX
ND
X
33.4
ng/g
3
132
(0%-30%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
25.4
UX
ND
X
29.1
ng/g
3
115
(0%-30%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
25.4
U
ND
35.2
ng/g
1
139
(0%-30%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid
22.4
U
ND
26.3
ng/g
10
117
(0%-30%)
MB2
03/18/23 14:40
(PFBS)
Perfluorobutanoic acid (PFBA)
25.4
U
ND
30.9
ng/g
4
122
(0%-30%)
Perfluorodecanesulfonic acid
24.5
J
1.18
29.5
ng/g
6
116
(0%-30%)
(PFDS)
Perfluorodecanoic acid (PFDA)
25.4
U
ND
34.2
ng/g
7
128
(0%-30%)
Perfluorododecanesulfonic acid
24.5
U
ND
22.7
ng/g
2
93
(0%-30%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
25.4
J
1.73
30.9
ng/g
2
115
(0%-30%)
Perfluoroethoxypropionic acid
25.4
UX
ND
x
30.4
ng/g
5
120
(0%-30%)
RR3
03/20/23 15:45
(EVE)
Perfluoroheptanesulfonic acid
24.1
U
ND
31.3
ng/g
6
130
(0%-30%)
MB2
03/18/23 14:40
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
25.4
U
ND
27.6
ng/g
11
109
(0%-30%
Perfluorohexanesulfonic acid
23.1
U
ND
25.5
ng/g
1
110
(0%-30%
(PFHxS)
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QC Summary
Workorder: 613703
Page 27 of 66
Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400381
Perfluorohexanoic acid (PFHxA)
25.4
U
ND
29.0
ng/g
4
114
(0%-30%)
MB2
03/18/23 14:40
Perfluorononanesulfonic acid
24.3
U
ND
30.0
ng/g
8
123
(0%-30%)
(PFNS)
Perfluorononanoic acid (PFNA)
25.4
U
ND
27.5
ng/g
9
108
(0%-30%)
Perfluorooctanesulfonamide
25.4
J
1.03
29.6
ng/g
12
113
(0%-30%)
(PFOSA)
Perfluorooctanesulfonic acid
25.4
9.72
37.4
ng/g
1
109
(0%-30%)
(PFOS)
Perfluorooctanoic acid (PFOA)
25.4
U
ND
29.8
ng/g
4
118
(0%-30%)
Perfluoropentanesulfonic acid
23.8
U
ND
28.7
ng/g
6
121
(0%-30%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
25.4
U
ND
27.6
ng/g
4
109
(0%-30%)
Perfluorotetradecanoic acid (PFTA)
25.4
U
ND
28.7
ng/g
4
113
(0%-30%)
Perfluorotridecanoic Acid (PFTriA)
25.4
U
ND
36.3
ng/g
4
143
(0%-30%)
Perfluoroundecanoic acid (PFUnA)
25.4
J
0.911
33.3
ng/g
4
128
(0%-30%)
R-EVE
25.4
UX
ND X
106
ng/g
3
418 *
(0%-30%)
RR3
03/20/23 15:45
Batch 2400729
QC1205350051 LCS
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
19.4
X
17.9
ng/L
92
(60%-158%)
RR3
03/20/2318:31
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
18.3
18.1
ng/L
99
(59%-144%)
JMB3
03/20/2310:11
oxaundecane-l-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
19.4
19.0
ng/L
98
(67%-144%)
RR3
03/20/2318:31
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
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Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400729
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
19.4
X 19.0
ng/L
98
(58%-144%)
RR3
03/20/2318:31
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
19.4
22.0
ng/L
113
(54%-128%)
JMB3
03/20/2310:11
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-1-
19.4
25.5
ng/L
131
(52%-141%)
octanesulfonamido)-ethanol (N-
McFOSE)
4,8-Dioxa-3H-perfluorononanoic
19.4
19.7
ng/L
101
(67%-154%)
acid (DONA,ADONA)
4-
19.4
X 17.9
ng/L
92
(73%-141%)
RR3
03/20/2318:31
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
18.1
21.3
ng/L
118
(68%-135%)
JMB3
03/20/2310:11
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
18.2
15.1
ng/L
83
(56%-151%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
18.4
20.1
ng/L
109
(60%-153%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
18.6
20.9
ng/L
112
(60%-141%)
FTS)
Hydro -EVE
19.4
X 21.9
ng/L
113
(61%-148%)
RR3
03/20/2318:31
N-ethylperfluoro-l-
19.4
22.8
ng/L
117
(23%-155%)
JMB3
03/20/2310:11
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
19.4
19.3
ng/L
99
(57%-139%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
19.4
26.8
ng/L
138
(20%-154%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-1-
19.4
21.9
ng/L
113
(59%-145%)
octanesulfonamidoacetic acid (N-
McFOSAA)
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2400729
Nation Byproduct 1 (PFESA BPI)
19.4
X
12.1
ng/L
62
(35%-138%) RR3 03/20/23 18:31
Nation Byproduct 2 (PFESA BP2)
19.4
X
20.1
ng/L
103
(63%-143%)
Naflon Byproduct 4 (PFESA BP4)
19.4
X
7.79
ng/L
40
(5%-158%)
Naflon Byproduct 5 (PFESA BP5)
19.4
X
11.3
ng/L
58
(5%-149%)
Naflon Byproduct 6 (PFESA BP6)
19.4
X
18.8
ng/L
97
(59%-145%)
Nonafluoro-316-dioxahepanoic
19.4
20.1
ng/L
104
(48%-149%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
19.4
18.9
ng/L
97
(52%-148%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 I -
19.4
X
18.2
ng/L
94
(58%-147%)
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
19.4
X
16.4
ng/L
85
(60%-151%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
19.4
X
18.7
ng/L
96
(62%-148%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
19.4
x
19.3
ng/L
99
(60%-144%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
19.4
19.4
ng/L
100
(58%-142%)
(PFMOBA)
Perfluoro-2-
19.4
X
19.8
ng/L
102
(50%-150%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
19.4
X
19.0
ng/L
98
(52%-144%)
(PFMOAA)
Perfluoro-3-methoxypropanoic 19.4 20.6 ng/L 106 (60%-149%
acid (PFMOPrA)
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QC Summary
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Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst Date Time
Perfluorinated Compounds
Batch 2400729
Perfluorobutanesulfonic acid
17.2
17.0
ng/L
99
(70%-144%)
JMB3 03/20/23 10:11
(PFBS)
Perfluorobutanoic acid (PFBA)
19.4
20.7
ng/L
107
(73%-151%)
Perfluorodecanesulfonic acid
18.7
18.7
ng/L
100
(58%-134%)
(PFDS)
Perfluorodecanoic acid (PFDA)
19.4
20.0
ng/L
103
(65%-145%)
Perfluorododecanesulfonic acid
18.8
21.6
ng/L
115
(57%-134%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
19.4
22.0
ng/L
113
(65%-137%)
Perfluoroethoxypropionic acid
19.4
X 14.6
ng/L
75
(20%-160%)
RR3 03/20/23 18:31
(EVE)
Perfluoroheptanesulfonic acid
18.4
21.0
ng/L
114
(68%-138%)
JMB3 03/20/23 10:11
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
19.4
21.1
ng/L
109
(71%-133%)
Perfluorohexadecanoic acid
19.4
21.3
ng/L
110
(69%-144%)
(PFHxDA)
Perfluorohexanesulfonic acid
17.7
20.1
ng/L
114
(67%-145%)
(PFHxS)
Perfluorohexanoic acid (PFHxA) 19.4 22.1 ng/L 114 (70%-138%
Perfluorononanesulfonic acid 18.6 20.6 ng/L 110 (64%-133%
(PFNS)
Perfluorononanoic acid (PFNA) 19.4 20.5 ng/L 106 (69%-133%
Perfluorooctadecanoic acid 19.4 15.7 ng/L 81 (35%-165%
(PFODA)
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Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400729
Perfluorooctanesulfonamide
19.4
20.4
ng/L
105
(64%-134%)
JMB3
03/20/2310:11
(PFOSA)
Perfluorooctanesulfonic acid
19.4
21.9
ng/L
113
(65%-145%)
(PFOS)
Perfluorooctanoic acid (PFOA)
19.4
21.1
ng/L
109
(66%-139%)
Perfluoropentanesulfonic acid
18.3
20.7
ng/L
113
(67%-136%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
19.4
21.5
ng/L
111
(72%-143%)
Perfluoropropanoic acid (PFPrA)
19.4
BX
23.2
ng/L
119
(49%-153%)
RR3
03/20/23 18:31
Perfluorotetradecanoic acid (PFTA)
19.4
21.5
ng/L
111
(66%-138%)
JMB3
03/20/23 10:11
Perfluorotridecanoic Acid (PFTriA)
19.4
22.7
ng/L
117
(58%-140%)
Perfluoroundecanoic acid (PFUnA)
19.4
19.4
ng/L
100
(63%-135%)
R-EVE
19.4
X
8.32
ng/L
43
(5%-158%)
RR3
03/20/2318:31
QC1205350052 LCSD
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
19.8
X
20.2
ng/L
12
102
(0%-30%)
03/20/2318:46
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
18.7
16.8
ng/L
8
90
(0%-27%)
JMB3
03/20/2310:20
oxaundecane-l-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
19.8
20.7
ng/L
9
105
(0%-30%)
RR3
03/20/2318:46
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
19.8
X
21.3
ng/L
11
108
(0%-27%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
19.8
24.4
ng/L
10
123
(0%-28%)
JMB3
03/20/2310:20
octanesulfonamido)-ethanol (N-
EtFOSE)
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Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400729
2-(N-methylperfluoro-l-
19.8
24.0
ng/L
6
121
(0%-30%)
JMB3
03/20/2310:20
octanesulfonamido)-ethanol (N-
McFOSE)
4,8-Dioxa-3H-perfluorononanoic
19.8
25.5
ng/L
26
129
(0%-26%)
acid (DONA,ADONA)
4-
19.8
x
21.0
ng/L
16
106
(0%-24%)
RR3
03/20/2318:46
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
18.5
19.9
ng/L
7
108
(0%-26%)
JMB3
03/20/2310:20
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
18.5
17.4
ng/L
14
94
(0%-32%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
18.8
21.6
ng/L
7
115
(0%-32%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
19.0
21.8
ng/L
4
115
(0%-36%)
FTS)
Hydro -EVE
19.8
x
24.6
ng/L
12
124
(0%-24%)
RR3
03/20/2318:46
N-ethylperfluoro-l-
19.8
27.2
ng/L
18
137
(0%-27%)
JMB3
03/20/2310:20
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
19.8
23.4
ng/L
19
118
(0%-27%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-l-
19.8
27.9
ng/L
4
141
(0%-36%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-l-
19.8
22.8
ng/L
4
115
(0%-27%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Nation Byproduct 1 (PFESA BPI)
19.8
x
14.3
ng/L
16
72
(0%-28%)
RR3
03/20/23 18:46
Nation Byproduct 2 (PFESA BP2)
19.8
x
21.8
ng/L
8
110
(0%-23%)
Naflon Byproduct 4 (PFESA BP4)
19.8
x
3.78
ng/L
69 *
19
(0%-45%)
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Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2400729
Nation Byproduct 5 (PFESA BP5)
19.8
X
5.03
ng/L
76*
25
(0%-40%) RR3
03/20/23 18:46
Nation Byproduct 6 (PFESA BP6)
19.8
X
20.3
ng/L
7
102
(0%-26%)
Nonafluoro-316-dioxaheptanoic
19.8
21.6
ng/L
7
109
(0%-27%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
19.8
21.7
ng/L
14
109
(0%-35%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 1 -
19.8
X
22.2
ng/L
20
112
(0%-40%)
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
19.8
X
22.0
ng/L
29
ill
(0%-39%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
19.8
X
21.0
ng/L
12
106
(0%-36%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
19.8
X
21.8
ng/L
12
110
(0%-27%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
19.8
21.6
ng/L
11
109
(0%-29%)
(PFMOBA)
Perfluoro-2-
19.8
X
22.5
ng/L
13
114
(0%-30%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
19.8
x
21.4
ng/L
12
108
(0%-31%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
19.8
22.7
ng/L
10
114
(0%-25%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid
17.5
19.4
ng/L
13
110
(0%-35%) JMB3
03/20/23 10:20
(PFBS)
Perfluorobutanoic acid (PFBA)
19.8
21.7
ng/L
5
110
(0%-20%
Perfluorodecanesulfonic acid
19.1
19.0
ng/L
2
100
(0%-30%
(PFDS)
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Parmname
NOM
Sample Qual QC
Units
RPD/D%
REC%
Range
Anlst Date Time
Perfluorinated Compounds
Batch 2400729
Perfluorodecanoic acid (PFDA)
19.8
22.1
ng/L
10
112
(0%-31%)
JMB3 03/20/23 10:20
Perfluorododecanesulfonic acid
19.2
20.2
ng/L
7
105
(0%-32%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
19.8
22.2
ng/L
1
112
(0%-26%)
Perfluoroethoxypropionic acid
19.8
X 16.1
ng/L
10
81
(0%-30%)
RR3 03/20/23 18:46
(EVE)
Perfluoroheptanesulfonic acid
18.8
21.5
ng/L
2
114
(0%-40%)
JMB3 03/20/23 10:20
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
19.8
25.0
ng/L
17
126
(0%-23%)
Perfluorohexadecanoic acid
19.8
23.8
ng/L
11
120
(0%-26%)
(PFHxDA)
Perfluorohexanesulfonic acid
18.1
22.4
ng/L
11
124
(0%-27%)
(PFHxS)
Perfluorohexanoic acid (PFHxA)
19.8
23.2
ng/L
5
117
(0%-27%)
Perfluorononanesulfonic acid
19.0
20.9
ng/L
2
110
(0%-27%)
(PFNS)
Perfluorononanoic acid (PFNA)
19.8
20.2
ng/L
1
102
(0%-25%)
Perfluorooctadecanoic acid
19.8
13.9
ng/L
12
70
(0%-39%)
(PFODA)
Perfluorooctanesulfonamide
19.8
23.5
ng/L
14
118
(0%-26%)
(PFOSA)
Perfluorooctanesulfonic acid
19.8
22.3
ng/L
2
113
(0%-25%)
(PFOS)
Perfluorooctanoic acid (PFDA) 19.8 23.9 ng/L 12 121 (0%-27%
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Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400729
Perfluoropentanesulfonic acid
18.6
22.6
ng/L
9
121
(0%-40%)
JMB3
03/20/23 10:20
(PFPeS)
Perfluoropentanoic acid (PFPeA)
19.8
22.6
ng/L
5
114
(0%-25%)
Perfluoropropanoic acid (PFPrA)
19.8
BX
25.9
ng/L
11
131
(0%-26%)
RR3
03/20/23 18:46
Perfluorotetradecanoic acid (PFTA)
19.8
23.2
ng/L
8
117
(0%-26%)
JMB3
03/20/23 10:20
Perfluorotridecanoic Acid (PFTriA)
19.8
23.4
ng/L
3
118
(0%-31%)
Perfluoroundecanoic acid (PFUnA)
19.8
22.9
ng/L
16
115
(0%-30%)
R-EVE
19.8
X
5.16
ng/L
47 *
26
(0%-26%)
RR3
03/20/23 18:46
QC1205350050 MB
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
ng/L
03/20/2318:16
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
U
ND
ng/L
JMB3
03/20/2310:02
oxaundecane-l-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
U
ND
ng/L
RR3
03/20/2318:16
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
U%
ND
ng/L
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
U
ND
ng/L
JMB3
03/20/2310:02
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-1-
U
ND
ng/L
octanesulfonamido)-ethanol (N-
McFOSE)
4,8-Dioxa-3H-perfluorononanoic
U
ND
ng/L
acid (DONA,ADONA)
4-
UX
ND
ng/L
RR3
03/20/2318:16
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
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Parmname NOM
Sample Qual
QC
Units RPD/D% REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2400729
9-Chlorohexadecafluoro-3-
U
ND
ng/L
JMB3
03/20/2310:02
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
ng/L
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
ng/L
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
ng/L
FTS)
Hydro -EVE
Ux
ND
ng/L
RR3
03/20/2318:16
N-ethylperfluoro-1-
U
ND
ng/L
JMB3
03/20/2310:02
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-I-
U
ND
ng/L
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-I-
U
ND
ng/L
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
U
ND
ng/L
octanesulfonamidoacetic acid (N-
McFOSAA)
Nafion Byproduct I (PFESA BPI)
Ux
ND
ng/L
RR3
03/20/23 18:16
Nafion Byproduct 2 (PFESA BP2) Ux ND ng/L
Nafion Byproduct 4 (PFESA BP4) Ux ND ng/L
Nafion Byproduct 5 (PFESA BP5) Ux ND ng/L
Nation Byproduct 6 (PFESA BP6) Ux ND ng/L
Nonafluoro-316-dioxaheptanoic U ND ng/L
acid (NFDHA or PFECA B)
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC% Range Anlst Date Time
Perfluorinated Compounds
Batch 2400729
Perfluoro(2-ethoxyethane)sulfonic
U
ND
ng/L RR3 03/20/2318:16
acid (PFEESA or PES)
Perfluoro(3,5,7,9,11-
Ux
ND
ng/L
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
UX
ND
ng/L
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
UX
ND
ng/L
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
UX
ND
ng/L
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
U
ND
ng/L
(PFMOBA)
Perfluoro-2-
UX
ND
ng/L
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
UX
ND
ng/L
(PFMOAA)
Perfluoro-3-methoxypropanoic
U
ND
ng/L
acid (PFMOPrA)
Perfluorobutanesulfonic acid
U
ND
ng/L JMB3 03/20/23 10:02
(PFBS)
Perfluorobutanoic acid (PFBA)
U
ND
ng/L
Perfluorodecanesulfonic acid
U
ND
ng/L
(PFDS)
Perfluorodecanoic acid (PFDA) U ND ng/L
Perfluorododecanesulfonic acid U ND ng/L
(PFDoS)
Perfluorododecanoic acid (PFDOA) U ND ng/L
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QC Summary
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC% Range Anlst Date Time
Perfluorinated Compounds
Batch 2400729
Perfluoroethoxypropionic acid
UX
ND
ng/L RR3 03/20/23 18:16
(EVE)
Perfluoroheptanesulfonic acid
U
ND
ng/L JMB3 03/20/23 10:02
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
ng/L
Perfluorohexadecanoic acid
U
ND
ng/L
(PFHxDA)
Perfluorohexanesulfonic acid
U
ND
ng/L
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
ng/L
Perfluorononanesulfonic acid
U
ND
ng/L
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
ng/L
Perfluorooctadecanoic acid
U
ND
ng/L
(PFODA)
Perfluorooctanesulfonamide
U
ND
ng/L
(PFOSA)
Perfluorooctanesulfonic acid
U
ND
ng/L
(PFOS)
Perfluorooctanoic acid (PFOA) U ND ng/L
Perfluoropentanesulfonic acid U ND ng/L
(PFPeS)
Perfluoropentanoic acid (PFPeA) U ND ng/L
Perfluoropropanoic acid (PFPrA) X 4.14 ng/L RR3 03/20/23 18:16
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QC Summary
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2400729
Perfluorotetradecanoic acid (PFTA)
U
ND
ng/L
JMB3
03/20/23 10:02
Perfluorotridecanoic Acid (PFTriA)
U
ND
ng/L
Perfluoroundecanoic acid (PFUnA)
U
ND
ng/L
R-EVE
UX
ND
ng/L
RR3
03/20/2318:16
Batch 2401145
QC1205350874 LCS
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
19.2
X
19.5
ng/L
102
(60%-158%)
RR3
03/21/2312:41
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
18.1
19.2
ng/L
106
(59%-144%)
JMB3
03/21/23 09:48
oxaundecane-1-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
19.2
19.9
ng/L
104
(67%-144%)
RR3
03/21/2312:41
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
19.2
X
21.4
ng/L
112
(58%-144%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
19.2
24.2
ng/L
126
(54%-128%)
JMB3
03/21/23 09:48
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-1-
19.2
24.4
ng/L
127
(52%-141%)
octanesulfonamido)-ethanol (N-
McFOSE)
4,8-Dioxa-3H-perfluorononanoic
19.2
20.0
ng/L
104
(67%-154%)
acid (DONA,ADONA)
4-
19.2
X
19.0
ng/L
99
(73%-141%)
RR3
03/21/2312:41
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
17.9
20.3
ng/L
114
(68%-135%)
JMB3
03/21/23 09:48
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
18.0
23.6
ng/L
131
(56%-151%)
FTS)
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QC Summary
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range
Anlst Date Time
Perfluorinated Compounds
Batch 2401145
Fluorotelomer sulfonic acid 6:2 (6:2
18.2
B
20.0
ng/L
110
(60%-153%)
JMB3 03/21/23 09:48
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
18.4
20.8
ng/L
113
(60%-141%)
FTS)
Hydro -EVE
19.2
X
24.0
ng/L
125
(61%-148%)
RR3 03/21/2312:41
N-ethylperfluoro-l-
19.2
28.6
ng/L
149
(23%-155%)
JMB3 03/21/23 09:48
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-I-
19.2
23.6
ng/L
123
(57%-139%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
19.2
32.0
ng/L
167*
(20%-154%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
19.2
22.9
ng/L
119
(59%-145%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Nafion Byproduct 1 (PFESA BPI)
19.2
X
13.7
ng/L
71
(35%-138%)
RR3 03/21/23 12:41
Nafion Byproduct 2 (PFESA BP2)
19.2
X
20.6
ng/L
107
(63%-143%)
Nation Byproduct 4 (PFESA BP4)
19.2
X
20.5
ng/L
107
(5%-158%)
Nafion Byproduct 5 (PFESA BP5)
19.2
X
26.4
ng/L
138
(5%-149%)
Nafion Byproduct 6 (PFESA BP6)
19.2
X
23.4
ng/L
122
(59%-145%)
Nonafluoro-316-dioxaheptanoic
19.2
23.5
ng/L
123
(48%-149%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
19.2
22.7
ng/L
118
(52%-148%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 1 - 19.2 X 21.1 ng/L 110 (58%-147%
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2401145
Perfluoro(3,5,7,9-tetraoxadecanoic)
19.2
x
21.5
ng/L
112
(60%-151%) RR3 03/21/2312:41
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
19.2
x
19.7
ng/L
102
(62%-148%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
19.2
X
21.0
ng/L
109
(60%-144%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
19.2
22.0
ng/L
114
(58%-142%)
(PFMOBA)
Perfluoro-2-
19.2
X
21.5
ng/L
112
(50%-150%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
19.2
X
21.2
ng/L
110
(52%-144%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
19.2
21.3
ng/L
111
(60%-149%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid
17.0
18.3
ng/L
108
(70%-144%) JMB3 03/21/23 09:48
(PFBS)
Perfluorobutanoic acid (PFBA)
19.2
21.5
ng/L
112
(73%-151%)
Perfluorodecanesulfonic acid
18.5
20.4
ng/L
110
(58%-134%)
(PFDS)
Perfluorodecanoic acid (PFDA)
19.2
21.7
ng/L
113
(65%-145%)
Perfluorododecanesulfonic acid
18.6
22.8
ng/L
123
(57%-134%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
19.2
22.8
ng/L
119
(65%-137%)
Perfluoroethoxypropionic acid
19.2
x 17.4
ng/L
91
(20%-160%) RR3 03/21/23 12:41
(EVE)
Perfluoroheptanesulfonic acid 18.2 22.5 ng/L 123 (68%-138%) JMB3 03/21/23 09:48
(PFHpS)
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QC Summary
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Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2401145
Perfluoroheptanoic acid (PFHpA)
19.2
23.2
ng/L
121
(71%-133%) JMB3 03/21/23 09:48
Perfluorohexadecanoic acid
19.2
22.1
ng/L
115
(69%-144%)
(PFHxDA)
Perfluorohexanesulfonic acid
17.5
20.4
ng/L
117
(67%-145%)
(PFHxS)
Perfluorohexanoic acid (PFHxA)
19.2
22.0
ng/L
115
(70%-138%)
Perfluorononanesulfonic acid
18.4
21.5
ng/L
117
(64%-133%)
(PFNS)
Perfluorononanoic acid (PFNA)
19.2
20.2
ng/L
105
(69%-133%)
Perfluorooctadecanoic acid
19.2
16.1
ng/L
84
(35%-165%)
(PFODA)
Perfluorooctanesulfonamide
19.2
21.2
ng/L
110
(64%-134%)
(PFOSA)
Perfluorooctanesulfonic acid
19.2
23.0
ng/L
120
(65%-145%)
(PFOS)
Perfluorooctanoic acid (PFOA) 19.2 21.2 ng/L 110 (66%-139%)
Perfluoropentanesulfonic acid 18.1 22.3 ng/L 123 (67%-136%
(PFPeS)
Perfluoropentanoic acid (PFPeA)
19.2
23.1
ng/L
120
(72%-143%)
Perfluoropropanoic acid (PFPrA)
19.2
BX 25.7
ng/L
134
(49%-153%) RR3 03/21/23 12:41
Perfluorotetradecanoic acid (PFTA)
19.2
23.0
ng/L
120
(66%-138%) JMB3 03/21/23 09:48
Perfluorotridecanoic Acid (PFTriA)
19.2
21.8
ng/L
113
(58%-140%)
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QC Summary
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Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2401145
Perfluoroundecanoic acid (PFUnA)
19.2
21.9
ng/L
114
(63%-135%)
JMB3
03/21/23 09:48
R-EVE
19.2
x
20.2
ng/L
105
(5%-158%)
RR3
03/21/2312:41
QC1205350875 LCSD
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
19.4
x
22.2
ng/L
13
115
(0%-30%)
03/21/2312:56
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
18.3
19.7
ng/L
3
108
(0%-27%)
JMB3
03/21/23 09:57
oxaundecane- 1 -sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
19.4
21.2
ng/L
6
109
(0%-30%)
RR3
03/21/2312:56
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
19.4
x
23.3
ng/L
8
120
(0%-27%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
19.4
26.9
ng/L
10
139*
(0%-28%)
JMB3
03/21/23 09:57
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
19.4
27.1
ng/L
10
140
(0%-30%)
octanesulfonamido)-ethanol (N-
McFOSE)
4,8-Dioxa-3H-perfluorononanoic
19.4
21.7
ng/L
8
112
(0%-26%)
acid (DONA,ADONA)
4-
19.4
x
20.0
ng/L
5
103
(0%-24%)
RR3
03/21/2312:56
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
18.1
21.2
ng/L
4
117
(0%-26%)
JMB3
03/21/23 09:57
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
18.1
22.0
ng/L
7
122
(0%-32%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
18.4
B
24.5
ng/L
20
133
(0%-32%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
18.6
22.1
ng/L
6
119
(0%-36%)
FTS)
Hydro -EVE
19.4
x
23.6
ng/L
2
122
(0%-24%)
RR3
03/21/2312:56
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QC Summary
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Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2401145
N-ethylperfluoro-l-
19.4
30.0
ng/L
5
154
(0%-27%) JMB3
03/21/23 09:57
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
19.4
23.2
ng/L
2
119
(0%-27%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
19.4
31.0
ng/L
3
160*
(0%-36%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-1-
19.4
23.9
ng/L
4
123
(0%-27%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Naflon Byproduct 1 (PFESA BPI)
19.4
X
13.4
ng/L
3
69
(0%-28%) RR3
03/21/23 12:56
Nation Byproduct 2 (PFESA BP2)
19.4
X
22.6
ng/L
9
116
(0%-23%)
Nation Byproduct 4 (PFESA BP4)
19.4
X
17.4
ng/L
16
90
(0%-45%)
Nation Byproduct 5 (PFESA BP5)
19.4
X
23.0
ng/L
14
119
(0%-40%)
Nafion Byproduct 6 (PFESA BP6)
19.4
X
20.3
ng/L
14
104
(0%-26%)
Nonafluoro-3,6-dioxahepanoic
19.4
23.6
ng/L
0
122
(0%-27%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
19.4
22.2
ng/L
2
115
(0%-35%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 I -
19.4
x
23.6
ng/L
11
122
(0%-40%)
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
19.4
x
21.7
ng/L
1
112
(0%-39%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
19.4
x
21.2
ng/L
8
109
(0%-36%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid 19.4 X 21.9 ng/L 4 113 (0%-27%
(PF02HxA)
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Parmname
NOM
Sample Qual QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2401145
Perfluoro(4-methoxybutanoic) acid
19.4
23.2
ng/L
5
119
(0%-29%)
RR3
03/21/23 12:56
(PFMOBA)
Perfluoro-2-
19.4
x 22.5
ng/L
4
116
(0%-30%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
19.4
X 23.0
ng/L
8
119
(0%-31%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
19.4
23.6
ng/L
10
121
(0%-25%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid
17.2
21.6
ng/L
16
126
(0%-35%)
JMB3
03/21/23 09:57
(PFBS)
Perfluorobutanoic acid (PFBA)
19.4
23.4
ng/L
8
121
(0%-20%)
Perfluorodecanesulfonic acid
18.7
19.7
ng/L
3
105
(0%-30%)
(PFDS)
Perfluorodecanoic acid (PFDA)
19.4
22.4
ng/L
3
115
(0%-31%)
Perfluorododecanesulfonic acid
18.8
21.4
ng/L
6
114
(0%-32%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
19.4
22.6
ng/L
1
116
(0%-26%)
Perfluoroethoxypropionic acid
19.4
x 17.7
ng/L
1
91
(0%-30%)
RR3
03/21/23 12:56
(EVE)
Perfluoroheptanesulfonic acid
18.4
22.1
ng/L
2
120
(0%-40%)
JMB3
03/21/23 09:57
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
19.4
26.2
ng/L
12
135 *
(0%-23%)
Perfluorohexadecanoic acid
19.4
23.1
ng/L
4
119
(0%-26%)
(PFHxDA)
Perfluorohexanesulfonic acid 17.7 24.7 ng/L 19 139 (0%-27%
(PFHxS)
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Parmname
NOM
Sample Qual QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2401145
Perfluorohexanoic acid (PFHxA)
19.4
24.0
ng/L
8
124
(0%-27%)
JMB3
03/21/23 09:57
Perfluorononanesulfonic acid
18.6
21.3
ng/L
1
115
(0%-27%)
(PFNS)
Perfluorononanoic acid (PFNA)
19.4
23.9
ng/L
17
123
(0%-25%)
Perfluorooctadecanoic acid
19.4
15.6
ng/L
3
80
(0%-39%)
(PFODA)
Perfluorooctanesulfonamide
19.4
24.0
ng/L
12
124
(0%-26%)
(PFOSA)
Perfluorooctanesulfonic acid
19.4
23.4
ng/L
2
121
(0%-25%)
(PFOS)
Perfluorooctanoic acid (PFOA)
19.4
22.5
ng/L
6
116
(0%-27%)
Perfluoropentanesulfonic acid
18.2
25.0
ng/L
11
137 *
(0%-40%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
19.4
23.2
ng/L
0
119
(0%-25%)
Perfluoropropanoic acid (PFPrA)
19.4
BX 27.7
ng/L
7
143
(0%-26%)
RR3
03/21/23 12:56
Perfluorotetradecanoic acid (PFTA)
19.4
23.3
ng/L
1
120
(0%-26%)
JMB3
03/21/23 09:57
Perfluorotridecanoic Acid (PFTriA)
19.4
22.0
ng/L
1
113
(0%-31%)
Perfluoroundecanoic acid (PFUnA)
19.4
23.8
ng/L
8
123
(0%-30%)
R-EVE
19.4
X 22.3
ng/L
10
115
(0%-26%)
RR3
03/21/2312:56
QC1205350873 MB
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX ND
ng/L
03/21/2312:26
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
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Parmname NOM
Sample Qual
QC
Units RPD/D% REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2401145
11-Chloroeicosafluoro-3-
U
ND
ng/L
JMB3
03/21/23 09:39
oxaundecane-1-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
U
ND
ng/L
RR3
03/21/2312:26
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
Ux
ND
ng/L
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
U
ND
ng/L
JMB3
03/21/23 09:39
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-1-
U
ND
ng/L
octanesulfonamido)-ethanol (N-
McFOSE)
4,8-Dioxa-3H-perfluorononanoic
U
ND
ng/L
acid (DONA,ADONA)
4-
Ux
ND
ng/L
RR3
03/21/2312:26
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
U
ND
ng/L
JMB3
03/21/23 09:39
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
ng/L
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
J
1.75
ng/L
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
ng/L
FTS)
Hydro -EVE
Ux
ND
ng/L
RR3
03/21/2312:26
N-ethylperfluoro-l-
U
ND
ng/L
JMB3
03/21/23 09:39
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
U
ND
ng/L
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-1-
U
ND
ng/L
octanesulfonamide (N-McFOSA)
Page 103 of 136 SDG: 613703

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QC Summary
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC% Range Anlst Date Time
Perfluorinated Compounds
Batch 2401145
N-methylperfluoro-I-
U
ND
ng/L JMB3 03/21/23 09:39
octanesulfonamidoacetic acid (N-
McFOSAA)
Nation Byproduct 1 (PFESA BPI)
Ux
ND
ng/L RR3 03/21/23 12:26
Nafion Byproduct 2 (PFESA BP2)
Ux
ND
ng/L
Nafion Byproduct 4 (PFESA BP4)
Ux
ND
ng/L
Naflon Byproduct 5 (PFESA BP5)
Ux
ND
ng/L
Nafion Byproduct 6 (PFESA BP6)
Ux
ND
ng/L
Nonafluoro-3,6-dioxahepanoic
U
ND
ng/L
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
ng/L
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 I -
Ux
ND
ng/L
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
Ux
ND
ng/L
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
Ux
ND
ng/L
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
Ux
ND
ng/L
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
U
ND
ng/L
(PFMOBA)
Perfluoro-2-
Ux
ND
ng/L
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
Ux
ND
ng/L
(PFMOAA)
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QC Summary
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2401145
Perfluoro-3-methoxypropanoic
U
ND
ng/L
RR3
03/21/2312:26
acid (PFMOPrA)
Perfluorobutanesulfonic acid
U
ND
ng/L
JMB3
03/21/23 09:39
(PFBS)
Perfluorobutanoic acid (PFBA)
U
ND
ng/L
Perfluorodecanesulfonic acid
U
ND
ng/L
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
ng/L
Perfluorododecanesulfonic acid
U
ND
ng/L
(PFDoS)
Perfluorododecanoic acid (PFDOA)
U
ND
ng/L
Perfluoroethoxypropionic acid
UX
ND
ng/L
RR3
03/21/23 12:26
(EVE)
Perfluoroheptanesulfonic acid
U
ND
ng/L
JMB3
03/21/23 09:39
(PFHpS)
Perfluorohcptanoic acid (PFHpA)
U
ND
ng/L
Perfluorohexadecanoic acid
U
ND
ng/L
(PFHxDA)
Perfluorohexanesulfonic acid
U
ND
ng/L
(PFHxS)
Perfluorohexanoic acid (PFHxA) U ND ng/L
Perfluorononanesulfonic acid U ND ng/L
(PFNS)
Perfluorononanoic acid (PFNA) U ND ng/L
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QC Summary
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2401145
Perfluorooctadecanoic acid
U
ND
ng/L
JMB3
03/21/23 09:39
(PFODA)
Perfluorooctanesulfonamide
U
ND
ng/L
(PFOSA)
Perfluorooctanesulfonic acid
U
ND
ng/L
(PFOS)
Perfluorooctanoic acid (PFOA)
U
ND
ng/L
Perfluoropentanesulfonic acid
U
ND
ng/L
(PFPeS)
Perfluoropentanoic acid (PFPeA)
U
ND
ng/L
Perfluoropropanoic acid (PFPrA)
X
4.71
ng/L
RR3
03/21/23 12:26
Perfluorotetradecanoic acid (PFTA)
U
ND
ng/L
JMB3
03/21/23 09:39
Perfluorotridecanoic Acid (PFTriA)
U
ND
ng/L
Perfluoroundccanoic acid (PFUnA)
U
ND
ng/L
R-EVE
UX
ND
ng/L
RR3
03/21/2312:26
Batch 2401164
QC1205350936 LCS
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
4.65
X
5.66
ng/g
122
(50%-150%)
RR3
03/22/2319:34
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
4.38
5.14
ng/g
117
(69%-143%)
MB2
03/21/2316:19
oxaundecane-l-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
4.65
5.25
ng/g
113
(72%-137%)
RR3
03/22/2319:34
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
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QC Summary
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Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2401164
2,3,3,3-Tetrafluoro-2-
4.65
x 5.32
ng/g
114
(59%-145%)
RR3
03/22/2319:34
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
4.65
4.82
ng/g
104
(61%-131%)
MB2
03/21/2316:19
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-1-
4.65
5.11
ng/g
110
(66%-140%)
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
4.65
4.96
ng/g
107
(49%-150%)
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
4.65
4.64
ng/g
100
(54%-145%)
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
4.65
4.72
ng/g
101
(59%-131%)
acid (3:3 FTCA)(FPrPA)
4,8-Dioxa-3H-perfluorononanoic
4.65
5.27
ng/g
113
(70%-135%)
acid (DONA,ADONA)
4-
4.65
X 5.33
ng/g
115
(60%-141%)
RR3
03/22/2319:34
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
4.33
5.20
ng/g
120
(66%-140%)
MB2
03/21/23 16:19
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
4.35
4.29
ng/g
99
(63%-144%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
4.42
4.06
ng/g
92
(62%-148%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
4.47
4.12
ng/g
92
(65%-144%)
FTS)
Hydro -EVE
4.65
X 5.57
ng/g
120
(50%-150%)
RR3
03/22/2319:34
N-ethylperfluoro-l-
4.65
4.37
ng/g
94
(73%-140%)
MB2
03/21/2316:19
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
4.65
4.51
ng/g
97
(66%-141%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
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QC Summary
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2401164
N-methylperfluoro-I-
4.65
4.98
ng/g
107
(70%-136%) MB2
03/21/2316:19
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
4.65
5.07
ng/g
109
(68%-141%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Nafion Byproduct 1 (PFESA BPI)
4.65
X
5.18
ng/g
111
(63%-138%) RR3
03/22/23 19:34
Nafion Byproduct 2 (PFESA BP2)
4.65
X
5.40
ng/g
116
(64%-142%)
Nafion Byproduct 4 (PFESA BP4)
4.65
X
5.09
ng/g
109
(50%-150%)
Nafion Byproduct 5 (PFESA BP5)
4.65
X
5.03
ng/g
108
(50%-150%)
Nafion Byproduct 6 (PFESA BP6)
4.65
X
4.81
ng/g
103
(50%-150%)
Nonafluoro-3,6-dioxahepanoic
4.65
5.14
ng/g
110
(50%-150%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
4.65
5.46
ng/g
117
(50%-150%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 I -
4.65
X
5.67
ng/g
122
(58%-151%)
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
4.65
x
5.25
ng/g
113
(59%-158%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
4.65
x
5.28
ng/g
114
(58%-156%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
4.65
x
5.32
ng/g
114
(67%-142%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
4.65
5.43
ng/g
117
(64%-142%)
(PFMOBA)
Perfluoro-2- 4.65 X 5.37 ng/g 115 (50%-150%
(perfluoromethoxy)propanoic acid
(PMPA)
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QC Summary
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Parmname
NOM
Sample Qual QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2401164
Perfluoro-2-methoxyacetic acid
4.65
x 5.40
ng/g
116
(64%-146%)
RR3
03/22/23 19:34
(PFMOAA)
Perfluoro-3-methoxypropanoic
4.65
5.14
ng/g
110
(60%-159%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid
4.12
4.74
ng/g
115
(71%-136%)
MB2
03/21/23 16:19
(PFBS)
Perfluorobutanoic acid (PFBA)
4.65
5.35
ng/g
115
(66%-141%)
Perfluorodecanesulfonic acid
4.49
5.21
ng/g
116
(70%-139%)
(PFDS)
Perfluorodecanoic acid (PFDA)
4.65
4.92
ng/g
106
(66%-139%)
Perfluorododecanesulfonic acid
4.50
5.33
ng/g
118
(54%-148%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
4.65
5.70
ng/g
123
(70%-139%)
Perfluoroethoxypropionic acid
4.65
X 4.99
ng/g
107
(50%-150%)
RR3
03/22/23 19:34
(EVE)
Perfluoroheptanesulfonic acid
4.42
5.13
ng/g
116
(72%-138%)
MB2
03/21/23 16:19
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
4.65
5.44
ng/g
117
(72%-132%)
Perfluorohexanesulfonic acid
4.24
4.16
ng/g
98
(68%-139%)
(PFHxS)
Perfluorohexanoic acid (PFHxA) 4.65 5.09 ng/g 109 (70%-135%
Perfluorononanesulfonic acid 4.47 4.58 ng/g 103 (60%-138%
(PFNS)
Perfluorononanoic acid (PFNA) 4.65 5.03 ng/g 108 (70%-136%
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QC Summary
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Page 54 of 66
Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2401164
Perfluorooctanesulfonamide
4.65
5.33
ng/g
115
(76%-138%)
MB2
03/21/2316:19
(PFOSA)
Perfluorooctanesulfonic acid
4.65
5.35
ng/g
115
(73%-135%)
(PFOS)
Perfluorooctanoic acid (PFOA)
4.65
5.14
ng/g
110
(72%-135%)
Perfluoropentanesulfonic acid
4.37
4.42
ng/g
101
(66%-138%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
4.65
5.21
ng/g
112
(72%-155%)
Perfluorotetradecanoic acid (PFTA)
4.65
5.32
ng/g
114
(72%-139%)
Perfluorotridecanoic Acid (PFTriA)
4.65
4.90
ng/g
105
(60%-149%)
Perfluoroundecanoic acid (PFUnA)
4.65
5.04
ng/g
108
(70%-135%)
R-EVE
4.65
X
5.26
ng/g
113
(50%-150%)
RR3
03/22/2319:34
QC1205350935 MB
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
UX
ND
ng/g
03/22/2319:19
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
U
ND
ng/g
MB2
03/21/2316:10
oxaundecane-l-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
U
ND
ng/g
RR3
03/22/2319:19
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
UX
ND
ng/g
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
U
ND
ng/g
MB2
03/21/2316:10
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-1-
U
ND
ng/g
octanesulfonamido)-ethanol (N-
McFOSE)
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QC Summary
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Parmname NOM
Sample Qual
QC
Units RPD/D% REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2401164
2H,2H,3H,3H-Perfluorodecanoic
U
ND
ng/g
MB2
03/21/2316:10
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
U
ND
ng/g
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
U
ND
ng/g
acid (3:3 FTCA)(FPrPA)
4,8-Dioxa-3H-perfluorononanoic
U
ND
ng/g
acid (DONA,ADONA)
4-
Ux
ND
ng/g
RR3
03/22/2319:19
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
U
ND
ng/g
M132
03/21/23 16:10
oxanonane-l-sulfonic acid (F-5313
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
U
ND
ng/g
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
U
ND
ng/g
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
U
ND
ng/g
FTS)
Hydro -EVE
Ux
ND
ng/g
RR3
03/22/2319:19
N-ethylperfluoro-l-
U
ND
ng/g
M132
03/21/2316:10
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
U
ND
ng/g
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-I-
U
ND
ng/g
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
U
ND
ng/g
octanesulfonamidoacetic acid (N-
McFOSAA)
Naflon Byproduct I (PFESA BPI)
Ux
ND
ng/g
RR3
03/22/23 19:19
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QC Summary
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC% Range Anlst Date Time
Perfluorinated Compounds
Batch 2401164
Nation Byproduct 2 (PFESA BP2)
Ux
ND
ng/g RR3 03/22/23 19:19
Nation Byproduct 4 (PFESA BP4)
Ux
ND
ng/g
Nation Byproduct 5 (PFESA BP5)
Ux
ND
ng/g
Naflon Byproduct 6 (PFESA BP6)
Ux
ND
ng/g
Nonafluoro-316-dioxahepanoic
U
ND
ng/g
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
U
ND
ng/g
acid (PFEESA or PES)
Perfluoro(3,5,7,9,11-
Ux
ND
ng/g
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
Ux
ND
ng/g
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
Ux
ND
ng/g
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
Ux
ND
ng/g
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
U
ND
ng/g
(PFMOBA)
Perfluoro-2-
Ux
ND
ng/g
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
Ux
ND
ng/g
(PFMOAA)
Perfluoro-3-methoxypropanoic U ND ng/g
acid (PFMOPrA)
Perfluorobutanesulfonic acid U ND ng/g MB2 03/21/23 16:10
(PFBS)
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QC Summary
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Parmname
NOM Sample Qual
QC
Units RPD/D% REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2401164
Perfluorobutanoic acid (PFBA)
U
ND
ng/g
MB2 03/21/23 16:10
Perfluorodecanesulfonic acid
U
ND
ng/g
(PFDS)
Perfluorodecanoic acid (PFDA)
U
ND
ng/g
Perfluorododecanesulfonic acid
U
ND
ng/g
(PFDoS)
Perfluorododecanoic acid (PFDOA)
U
ND
ng/g
Perfluoroethoxypropionic acid
XU
ND
ng/g
RR3 03/22/23 19:19
(EVE)
Perfluoroheptanesulfonic acid
U
ND
ng/g
MB2 03/21/23 16:10
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
U
ND
ng/g
Perfluorohexanesulfonic acid
U
ND
ng/g
(PFHxS)
Perfluorohexanoic acid (PFHxA)
U
ND
ng/g
Perfluorononanesulfonic acid
U
ND
ng/g
(PFNS)
Perfluorononanoic acid (PFNA)
U
ND
ng/g
Perfluorooctanesulfonamide
U
ND
ng/g
(PFOSA)
Perfluorooctanesulfonic acid
U
ND
ng/g
(PFOS)
Perfluorooctanoic acid (PFDA)
U
ND
ng/g
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QC Summary
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Parmname
NOM
Sample
Qual
QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2401164
Perfluoropentanesulfonic acid
U
ND
ng/g
MB2
03/21/23 16:10
(PFPeS)
Perfluoropentanoic acid (PFPeA)
U
ND
ng/g
Perfluorotetradecanoic acid (PFTA)
U
ND
ng/g
Perfluorotridecanoic Acid (PFTriA)
U
ND
ng/g
Perfluoroundecanoic acid (PFUnA)
U
ND
ng/g
R-EVE
UX
ND
ng/g
RR3
03/22/2319:19
QC1205350937 613703004 MS
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
5.76
XU
ND
X
6.27
ng/g
109
(42%-158%)
03/22/23 20:20
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
5.43
U
ND
6.42
ng/g
118
(43%-141%)
M132
03/21/2317:19
oxaundecane-l-sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
5.76
U
ND
6.23
ng/g
108
(61%-150%)
RR3
03/22/23 20:20
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
5.76
UX
ND
X
6.39
ng/g
111
(43%-154%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
5.76
U
ND
5.58
ng/g
97
(49%-153%)
MB2
03/21/2317:19
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
5.76
U
ND
6.93
ng/g
120
(54%-154%)
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
5.76
U
ND
6.35
ng/g
110
(30%-157%)
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
5.76
U
ND
6.20
ng/g
108
(31%-158%)
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
5.76
U
ND
6.06
ng/g
105
(32%-153%)
acid (3:3 FTCA)(FPrPA)
Page 114 of 136 SDG: 613703

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QC Summary
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Parmname
NOM
Sample
Qual
QC
Units RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2401164
4,8-Dioxa-3H-perfluorononanoic
5.76
U
ND
7.55
ng/g
131
(63%-143%)
MB2
03/21/2317:19
acid (DONA,ADONA)
4-
5.76
UX
ND
X
6.05
ng/g
105
(54%-161%)
RR3
03/22/23 20:20
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
5.37
U
ND
6.91
ng/g
129
(62%-146%)
MB2
03/21/2317:19
oxanonane-l-sulfonic acid (F-53B
Major)
Fluorotelomer sulfonic acid 4:2 (4:2
5.39
U
ND
6.08
ng/g
113
(62%-148%)
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
5.48
U
ND
6.53
ng/g
114
(50%-153%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
5.53
U
ND
5.74
ng/g
104
(53%-158%)
FTS)
Hydro -EVE
5.76
UX
ND
X
6.91
ng/g
120
(51%-148%)
RR3
03/22/23 20:20
N-ethylperfluoro-I-
5.76
U
ND
6.33
ng/g
110
(48%-148%)
MB2
03/21/2317:19
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-l-
5.76
U
ND
6.49
ng/g
108
(65%-152%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-I-
5.76
U
ND
7.00
ng/g
121
(55%-151%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
5.76
J
0.367
6.97
ng/g
115
(59%-152%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Nafion Byproduct 1 (PFESA BPI)
5.76
UX
ND
X
6.55
ng/g
114
(60%-147%)
RR3
03/22/23 20:20
Nafion Byproduct 2 (PFESA BP2)
5.76
UX
ND
X
6.27
ng/g
109
(65%-150%)
Nafion Byproduct 4 (PFESA BP4)
5.76
UX
ND
X
13.9
ng/g
241 *
(40%-160%)
Nafion Byproduct 5 (PFESA BP5)
5.76
UX
ND
X
12.9
ng/g
224 *
(40%-160%)
Page 115 of 136 SDG: 613703

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QC Summary
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Parmname
NOM
Sample
Qual
QC
Units RPD/D%
REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2401164
Nation Byproduct 6 (PFECA BP6)
5.76
Ux
ND
X
7.34
ng/g
127
(53%-153%) RR3
03/22/23 20:20
Nonafluoro-316-dioxaheptanoic
5.76
U
ND
6.82
ng/g
118
(43%-163%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic
5.76
U
ND
6.80
ng/g
118
(48%-148%)
acid (PFEESA or PES)
Perfluoro(3,5,7,9,1 1 -
5.76
Ux
ND
X
7.00
ng/g
121
(42%-167%)
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
5.76
UX
ND
X
6.61
ng/g
115
(49%-162%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
5.76
UX
ND
X
6.70
ng/g
116
(44%-167%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
5.76
UX
ND
X
6.98
ng/g
121
(57%-153%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
5.76
U
ND
6.49
ng/g
113
(47%-166%)
(PFMOBA)
Perfluoro-2-
5.76
UX
ND
X
6.55
ng/g
114
(50%-150%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
5.76
UX
ND
X
6.34
ng/g
110
(49%-169%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
5.76
U
ND
6.98
ng/g
121
(40%-162%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid
5.10
J
0.406
7.16
ng/g
132
(67%-146%) MB2
03/21/23 17:19
(PFBS)
Perfluorobutanoic acid (PFBA)
5.76
J
0.395
7.43
ng/g
122
(56%-156%)
Perfluorodecanesulfonic acid
5.56
U
ND
6.96
ng/g
122
(61%-150%)
(PFDS)
Perfluorodecanoic acid (PFDA) 5.76 10.5 15.5 ng/g 86 (59%-153%
Page 116 of 136 SDG: 613703

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QC Summary
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Parmname
NOM
Sample Qual
QC
Units RPD/D%
REC%
Range
Anlst Date Time
Perfluorinated Compounds
Batch 2401164
Perfluorododecanesulfonic acid
5.58
U
ND
6.30
ng/g
113
(39%-149%)
MB2 03/21/23 17:19
(PFDoS)
Perfluorododecanoic acid (PFDOA)
5.76
3.83
11.2
ng/g
129
(59%-147%)
Perfluoroethoxypropionic acid
5.76
UX
ND X
5.79
ng/g
100
(49%-151%)
RR3 03/22/23 20:20
(EVE)
Perfluoroheptanesulfonic acid
5.48
U
ND
6.52
ng/g
119
(50%-156%)
MB2 03/21/23 17:19
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
5.76
J
0.545
6.94
ng/g
111
(61%-149%)
Perfluorohexanesulfonic acid
5.26
U
ND
4.99
ng/g
95
(64%-150%)
(PFHxS)
Perfluorohexanoic acid (PFHxA)
5.76
0.680
7.12
ng/g
112
(61%-151%)
Perfluorononanesulfonic acid
5.53
U
ND
6.73
ng/g
122
(47%-147%)
(PFNS)
Perfluorononanoic acid (PFNA)
5.76
2.41
8.68
ng/g
109
(58%-152%)
Perfluorooctanesulfonamide
5.76
U
ND
6.68
ng/g
113
(68%-153%)
(PFOSA)
Perfluorooctanesulfonic acid
5.76
3.81
11.2
ng/g
127
(53%-157%)
(PFOS)
Perfluorooctanoic acid (PFOA)
5.76
4.17
11.8
ng/g
133
(53%-155%)
Perfluoropentanesulfonic acid
5.42
U
ND
5.31
ng/g
98
(58%-150%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
5.76
1.71
8.47
ng/g
117
(66%-150%
Perfluorotetradecanoic acid (PFTA)
5.76
1.06
8.26
ng/g
125
(60%-157%
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Parmname
NOM
Sample
Qual
QC
Units
RPD/D%
REC%
Range
Anlst
Date Time
Perfluorinated Compounds
Batch 2401164
Perfluorotridecanoic Acid (PFTriA)
5.76
7
0.477
6.96
ng/g
112
(35%-157%)
MB2
03/21/23 17:19
Perfluoroundecanoic acid (PFUnA)
5.76
1.81
8.57
ng/g
117
(58%-154%)
R-EVE
5.76
UX
ND
X
11.4
ng/g
198 *
(40%-160%)
RR3
03/22/23 20:20
QC1205350938 613703004 MSD
1,1,2,2-Tetrafluoro-2-(1,2,2,2-
5.82
XU
ND
X
7.02
ng/g
11
121
(0%-30%)
03/22/23 20:35
tetrafluoroethoxy)ethane sulfonic
acid (NVHOS)
11-Chloroeicosafluoro-3-
5.48
U
ND
6.04
ng/g
6
110
(0%-30%)
MB2
03/21/2317:28
oxaundecane- 1 -sulfonic acid (F-
53B Minor)
2,3,3,3-Tetrafluoro-2-
5.82
U
ND
6.76
ng/g
8
116
(0%-30%)
RR3
03/22/23 20:35
(1,1,2,2,3,3,3-
heptafluoropropoxy)-propanoic
acid (Gen-X)
2,3,3,3-Tetrafluoro-2-
5.82
UX
ND
X
7.01
ng/g
9
120
(0%-30%)
(pentafluoroethoxy)propanoic acid
(PEPA)
2-(N-ethylperfluoro-l-
5.82
U
ND
6.22
ng/g
11
107
(0%-30%)
MB2
03/21/2317:28
octanesulfonamido)-ethanol (N-
EtFOSE)
2-(N-methylperfluoro-l-
5.82
U
ND
5.30
ng/g
27
91
(0%-30%)
octanesulfonamido)-ethanol (N-
McFOSE)
2H,2H,3H,3H-Perfluorodecanoic
5.82
U
ND
5.63
ng/g
12
97
(0%-30%)
acid (7:3 FTCA)(FHpPA)
2H,2H,3H,3H-Perfluorooctanoic
5.82
U
ND
5.90
ng/g
5
101
(0%-30%)
acid (5:3 FTCA)(FPePA)
4,4,5,5,6,6-Heptafluorohexanoic
5.82
U
ND
5.95
ng/g
2
102
(0%-30%)
acid (3:3 FTCA)(FPrPA)
4,8-Dioxa-3H-perfluorononanoic
5.82
U
ND
6.32
ng/g
18
109
(0%-30%)
acid (DONA,ADONA)
4-
5.82
UX
ND
X
6.93
ng/g
14
119
(0%-30%)
RR3
03/22/23 20:35
(Heptafluoroisopropoxy)hexafluoro
butanoic acid (PFECA-G)
9-Chlorohexadecafluoro-3-
5.42
U
ND
6.07
ng/g
13
112
(0%-30%)
MB2
03/21/2317:28
oxanonane-l-sulfonic acid (F-53B
Major)
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Parmname
NOM
Sample
Qual
QC
Units
RPD/D%
REC%
Range
Anlst Date Time
Perfluorinated Compounds
Batch 2401164
Fluorotelomer sulfonic acid 4:2 (4:2
5.44
U
ND
5.42
ng/g
11
100
(0%-30%)
MB2 03/21/23 17:28
FTS)
Fluorotelomer sulfonic acid 6:2 (6:2
5.53
U
ND
6.63
ng/g
1
114
(0%-30%)
FTS)
Fluorotelomer sulfonic acid 8:2 (8:2
5.59
U
ND
6.47
ng/g
12
116
(0%-30%)
FTS)
Hydro -EVE
5.82
UX
ND
X
7.42
ng/g
7
127
(0%-30%)
RR3 03/22/23 20:35
N-ethylperfluoro-1-
5.82
U
ND
5.90
ng/g
7
101
(0%-30%)
MB2 03/21/2317:28
octanesulfonamide (N-EtFOSA)
N-ethylperfluoro-1-
5.82
U
ND
6.74
ng/g
4
ill
(0%-30%)
octanesulfonamidoacetic acid (N-
EtFOSAA)
N-methylperfluoro-I-
5.82
U
ND
6.46
ng/g
8
ill
(0%-30%)
octanesulfonamide (N-McFOSA)
N-methylperfluoro-I-
5.82
7
0.367
7.42
ng/g
6
121
(0%-30%)
octanesulfonamidoacetic acid (N-
McFOSAA)
Nafion Byproduct 1 (PFESA BPI)
5.82
UX
ND
X
7.84
ng/g
18
135
(0%-30%)
RR3 03/22/23 20:35
Nation Byproduct 2 (PFESA BP2)
5.82
UX
ND
X
7.03
ng/g
12
121
(0%-30%)
Nafion Byproduct 4 (PFESA BP4)
5.82
UX
ND
X
14.9
ng/g
7
256 *
(0%-30%)
Nafion Byproduct 5 (PFESA BP5)
5.82
UX
ND
X
14.1
ng/g
8
242 *
(0%-30%)
Nafion Byproduct 6 (PFESA BP6)
5.82
UX
ND
X
7.45
ng/g
2
128
(0%-30%)
Nonafluoro-316-dioxaheptanoic
5.82
U
ND
7.14
ng/g
5
123
(0%-30%)
acid (NFDHA or PFECA B)
Perfluoro(2-ethoxyethane)sulfonic 5.82 U ND 7.00 ng/g 3 120 (0%-30%
acid (PFEESA or PES)
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QC Summary
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Parmname
NOM
Sample
Qual
QC
Units
RPD/D%
REC%
Range Anlst
Date Time
Perfluorinated Compounds
Batch 2401164
Perfluoro(3,5,7,9,11-
5.82
UX
ND
X
7.42
ng/g
6
128
(0%-30%) RR3
03/22/23 20:35
pentaoxadodecanoic) acid
(PF05DA or TAFN4)
Perfluoro(3,5,7,9-tetraoxadecanoic)
5.82
UX
ND
X
7.16
ng/g
8
123
(0%-30%)
acid (PF04DA)
Perfluoro(3,5,7-trioxaoctanoic)
5.82
UX
ND
X
7.02
ng/g
5
121
(0%-30%)
acid (PF030A)
Perfluoro(3,5-dioxahexanoic) acid
5.82
UX
ND
X
7.14
ng/g
2
123
(0%-30%)
(PF02HxA)
Perfluoro(4-methoxybutanoic) acid
5.82
U
ND
7.24
ng/g
11
124
(0%-30%)
(PFMOBA)
Perfluoro-2-
5.82
UX
ND
X
6.93
ng/g
6
119
(0%-30%)
(perfluoromethoxy)propanoic acid
(PMPA)
Perfluoro-2-methoxyacetic acid
5.82
UX
ND
X
6.89
ng/g
8
118
(0%-30%)
(PFMOAA)
Perfluoro-3-methoxypropanoic
5.82
U
ND
7.26
ng/g
4
125
(0%-30%)
acid (PFMOPrA)
Perfluorobutanesulfonic acid
5.15
J
0.406
7.03
ng/g
2
129
(0%-30%) MB2
03/21/23 17:28
(PFBS)
Perfluorobutanoic acid (PFBA)
5.82
J
0.395
7.15
ng/g
4
116
(0%-30%)
Perfluorodecanesulfonic acid
5.62
U
ND
6.53
ng/g
6
114
(0%-30%)
(PFDS)
Perfluorodecanoic acid (PFDA)
5.82
10.5
16.9
ng/g
9
110
(0%-30%)
Perfluorododecanesulfonic acid
5.63
U
ND
6.50
ng/g
3
115
(0%-30%)
(PFDoS)
Perfluorododecanoic acid (PFDOA)
5.82
3.83
10.3
ng/g
9
111
(0%-30%)
Perfluoroethoxypropionic acid
5.82 UX
ND X
6.93
ng/g
18
119
(0%-30%) RR3 03/22/23 20:35
(EVE)
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Parmname
NOM
Sample Qual
QC
Units
RPD/D%
REC%
Range Anlst Date Time
Perfluorinated Compounds
Batch 2401164
Perfluoroheptanesulfonic acid
5.53
U
ND
6.61
ng/g
1
120
(0%-30%) MB2 03/21/23 17:28
(PFHpS)
Perfluoroheptanoic acid (PFHpA)
5.82
7
0.545
6.48
ng/g
7
102
(0%-30%)
Perfluorohexanesulfonic acid
5.31
U
ND
6.07
ng/g
19
114
(0%-30%)
(PFHxS)
Perfluorohexanoic acid (PFHxA)
5.82
0.680
7.13
ng/g
0
ill
(0%-30%)
Perfluorononanesulfonic acid
5.59
U
ND
6.37
ng/g
5
114
(0%-30%)
(PFNS)
Perfluorononanoic acid (PFNA)
5.82
2.41
8.96
ng/g
3
113
(0%-30%)
Perfluorooctanesulfonamide
5.82
U
ND
7.11
ng/g
6
120
(0%-30%)
(PFOSA)
Perfluorooctanesulfonic acid
5.82
3.81
10.2
ng/g
9
109
(0%-30%)
(PFOS)
Perfluorooctanoic acid (PFOA)
5.82
4.17
9.66
ng/g
20
94
(0%-30%)
Perfluoropentanesulfonic acid
5.47
U
ND
6.01
ng/g
12
110
(0%-30%)
(PFPeS)
Perfluoropentanoic acid (PFPeA)
5.82
1.71
9.20
ng/g
8
129
(0%-30%)
Perfluorotetradecanoic acid (PFTA)
5.82
1.06
8.04
ng/g
3
120
(0%-30%)
Perfluorotridecanoic Acid (PFTriA)
5.82 7
0.477
7.18
ng/g
3
115
(0%-30%)
Perfluoroundecanoic acid (PFUnA)
5.82
1.81
7.94
ng/g
8
105
(0%-30%)
R-EVE
5.82 UX
ND X
10.1
ng/g
12
174 *
(0%-30%) RR3 03/22/23 20:35
Notes
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QC Summary
Workorder: 613703 Page 66 of 66
Parmname NOM Sample Qual QC Units RPD/D% REC% Range Anlst Date Time
The Qualifiers in this report are defined as follows:
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
J Value is estimated
P Organics --The concentrations between the primary and confirmation columns/detectors is >40% different. For HPLC, the difference is >70%.
C Analyte has been confirmed by GUMS analysis
B The target analyte was detected in the associated blank.
E Concentration of the target analyte exceeds the instrument calibration range
A The TIC is a suspected aldol-condensation product
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
N Organics --Presumptive evidence based on mass spectral library search to make a tentative identification of the analyte (TIC). Quantitation is based
on nearest internal standard response factor
H Analytical holding time was exceeded
** Analyte is a surrogate compound
< Result is less than value reported
> Result is greater than value reported
h Preparation or preservation holding time was exceeded
R Sample results are rejected
^ RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
D Results are reported from a diluted aliquot of the sample
N/A RPD or %Recovery limits do not apply.
ND Analyte concentration is not detected above the detection limit
NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
JNX Non Calibrated Compound
UJ Compound cannot be extracted
Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
N1 See case narrative
Y QC Samples were not spiked with this compound
N Presumptive evidence based on mass spectral library search to make a tentative identification of the analyte (TIC). Quantitation is based on nearest
internal standard response factor
J See case narrative for an explanation
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone. by a factor of 4 or more or %RPD not applicable.
The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
Page 122 of 136 SDG: 613703

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Client: NCDENR QC Summary Report Date: April 4, 2023
1641 Mail Service Center Page 1 of l
Raleigh, North Carolina
Contact: Stephanie Zorio
Workorder: 613703
Parmname NOM Sample Qual QC Units RPD% REC% Range Anlst Date Time
Notes:
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The Qualifiers in this report are defined as follows:
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
J Value is estimated
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
H Analytical holding time was exceeded
< Result is less than value reported
> Result is greater than value reported
UI Gamma Spectroscopy --Uncertain identification
BD Results are either below the MDC or tracer recovery is low
h Preparation or preservation holding time was exceeded
R Sample results are rejected
^ RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
N/A RPD or %Recovery limits do not apply.
ND Analyte concentration is not detected above the detection limit
M M if above MDC and less than LLD
NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
FA Failed analysis.
UJ Gamma Spectroscopy --Uncertain identification
Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
K Analyte present. Reported value may be biased high. Actual value is expected to be lower.
UL Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
L Analyte present. Reported value may be biased low. Actual value is expected to be higher.
N1 See case narrative
Y Other specific qualifiers were required to properly define the results. Consult case narrative.
** Analyte is a Tracer compound
M REMP Result > MDC/CL and < RDL
J See case narrative for an explanation
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone. by a factor of 4 or more or %RPD not applicable.
** Indicates analyte is a surrogate/tracer compound.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC
standard unless qualified on the QC Summary.
Page 123 of 136 SDG: 613703

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Laboratories LiLq-,-
SAMPLE RECEIPT & REVIEW FORM4 3�
Clien
SD('=/AR/COC/Work Order:
Received By: MVH
Date Received
(7in• ppnoahlc:
FedEx Express FedEx Ground UPS Field Services Courier Other
Carrier and Tracking Number
Suspected Hazard lnrormation
z
*If Net Counts> 100epm on samples not marled "radioactive", contact the Radiation Safely Group far further inves(igaliun.
Hazard Class Shipped: UN#:
A)Shipped as a DOT Hazudcros7
If UN2910, Is the Radioactive Shipment Survey Compliant? Yes No—
B) Did the client designate the samples are to be
COC natation or radioactive stickers on containers equal client designation.
received as radioactive?
C) Did the RSO classify the samples as
aximum Net Counts ObservRaded* (Observed Couus - Area Background Counts): CPM /H aRr
I i'ed
COC notation or hazard labels on containers equal client designation.
D) Did the client designate samples are hazardous?
f D or E is yes. select Hazards below.
Flammable Foreign Soil RCRA Asbestos Beryllium Other:
E) Did the RSO identify possible hazards?PCB's
Sample Receipt Criteria
r Z
Z
Comments/Qualiflers (Required fur Non -Conforming Items)
Shipping containers received intact andI
Circle App[icabie: Seals broken Damaged conlamer Leaking conuainer Other (dessrribe)
1
sealed?
Chain of custody documents included
Circle Applicable:m Client cmncied and provided COC COC created upon receipt
Z
with shipment?
Prcservatiun Metlr We Ice ce packs Dry ice NORe Other:
3
Samples requiring cold preservation
*all tempemrune ed in Celsius TENIP-
within (0 < 6 deg. C)?"
Daily check performed and passed on IR
Temperature Device Serial #:IR2-21
4
?
temperature gun.
Secondary Temperature Device Serial It(If Applicable):
Circle Applicable_ Seals hroken Dammed conlaurer Leaking container Other (describe)
5
Sample containers intact and sealed?
Samples requiring chemise[ preservation
Sample D's and Cnnminers Affected:
6
at proper pH?
If preservation added- Lot#:
If Yes, are Encores or Soil Kits present for solids? Yes_ No_ NA ((ryes- take to VOA Freezer)
Do any samples require Volatile
o liquid VOA vials contain acid preservation? Yes_ No_ NA (If unknown, select No)
Are liquid VOA vials free of heaclspace? Yes_ No NA_
7
Analysis?
Sample ID's and conainers affected:
ID's and tests affected:
8
Samples received within holding time?
Sample ID's on COC match ID's on
ID's and containersaffected:
9
bottles?
10
Date & time on COC match date & time
Circle Applicable: No dates on containers No times on containers COC missing info Other (describe)
on bottles?
11
Number of containers received match
Circle Applicable: No container count on COC Od:cr (describe)
number indicated on COC?
12
Are sample containers identifiable as
�F
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1
COC form is properly signed in
tmleApplicable- Not relinquished Other (describe)
13
relinquished/received sections?
Comments (Use Continuation Form if needed):
4
FM;or PM.4) revierv; Initials Date Page � of
GL-CHL-SR-001 Rev 7
Page 126 of 136 SDG: 613703

List of current GEL Certifications as of 04 April 2023
State
Certification
Alabama
42200
Alaska
17-018
Alaska Drinking Water
SC00012
Arkansas
88-0651
CLIA
42DO904046
California
2940
Colorado
SC00012
Connecticut
PH-0169
DoD ELAP/ ISO17025 A2LA
2567.01
Florida NELAP
E87156
Foreign Soils Permit
P330-15-00283, P330-15-00253
Georgia
SC00012
Georgia SDWA
967
Hawaii
SC00012
Idaho
SC00012
Illinois NELAP
200029
Indiana
C-SC-01
Kansas NELAP
E-10332
Kentucky SDWA
90129
Kentucky Wastewater
90129
Louisiana Drinking Water
LA024
Louisiana NELAP
03046 (A133904)
Maine
2019020
Maryland
270
Massachusetts
M-SCO12
Massachusetts PFAS Approv
Letter
Michigan
9976
Mississippi
SC00012
Nebraska
NE-OS-26-13
Nevada
SC000122023-4
New Hampshire NELAP
2054
New Jersey NELAP
SCO02
New Mexico
SC00012
New York NELAP
11501
North Carolina
233
North Carolina SDWA
45709
North Dakota
R-158
Oklahoma
2022-160
Pennsylvania NELAP
68-00485
Puerto Rico
SC00012
S. Carolina Radiochem
10120002
Sanitation Districts of L
9255651
South Carolina Chemistry
10120001
Tennessee
TN 02934
Texas NELAP
T104704235-22-20
Utah NELAP
SC000122022-37
Vermont
VT87156
Virginia NELAP
460202
Washington
C780
Page 127 of 136 SDG: 613703

Technical Case Narrative
NC Dept Environmental Quality
SDG #: 613703
LCMSMS-Misc
Product: The Extraction and Analysis of Per- and Polyfluoroalkyl Substances Using LCMSMS
Analytical Method: EPA 537.1 Modified
Analytical Procedure: GL-OA-E-076 REV# 13
Analytical Batches: 2400161 and 2400160
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID# Client Sample Identification
613703001 NCO026123-INF-20230308
1205348952 Method Blank (MB)
1205348953 Laboratory Control Sample (LCS)
1205348954 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Quality Control (QC) Information
Method Blank (MB) Statement
The blank analyzed with this SDG did not meet the established acceptance criteria for PPF Acid (PFPrA). The
extraction cartridges used in the prep process contains PFF Acid (PFPrA) above GEL's reporting limit or
exhibits an interference/enhancement mimicking PPF Acid (PFPrA). Levels detected in the samples and QC
should be assessed accordingly.
Sample
Analyte
Value
1205348952 (MB)
Perfluoropropanoic acid (PFPrA)
5.83 * 10 > 4.5
Laboratory Control Sample Duplicate (LCSD)
An LCSD was used in place of matrix QC due to limited sample volume.
Laboratory Control Sample (LCS) Recovery
The LCS and/or LCSD (See Below) did not meet the spike recovery acceptance limits with a positive bias. As
target analytes were not detected in the associated samples, the data were not adversely impacted.
Sample
Analyte
Value
1205348953 (LCS)
2-(N-ethylperfluoro-l-octanesulfonamido)-ethanol (N-EtFOSE)
131* (54%-128%)
2-(N-methylperfluoro-l-octanesulfonamido)-ethanol (N-McFOSE)
143* (52%-141%)
N-methylperfluoro-l-octanesulfonamidoacetic acid (N-McFOSAA)
146* (59%-145%)
1205348954 (LCSD)
2-(N-ethylperfluoro-l-octanesulfonamido)-ethanol (N-EtFOSE)
142* (54%-128%)
Page 128 of 136 SDG: 613703

2-(N-methylperfluoro-l-octanesulfonamido)-ethanol (N-McFOSE) 147* (52%-141%)
Internal Standard (ISTD) Acceptance
Sample 613703001 (NC0026123-INF-20230308) did not meet acceptance criteria for one or more internal
standards with a negative bias. The sample was diluted in order to bring internal standards within acceptance
criteria. The sample was then re -extracted and the low internal standard failures were confirmed, therefore the
failures were attributed to matrix interference. The results for this sample were reported from the undiluted and
diluted analyses of the original extraction.
Technical Information
Sample Dilutions
The following sample and/or QC were diluted due to the Internal Standard Recovery not within the limits in the
undiluted analysis. 613703001 (NC0026123-INF-20230308).
Analyte
613703
001
Fluorotelomer sulfonic acid 4:2 (4:2 FTS)
125X
Fluorotelomer sulfonic acid 8:2 (8:2 FTS)
125X
Perfluorobutanoic acid (PFBA)
5X
Perfluorohexadecanoic acid (PFHxDA)
5X
Perfluorooctadecanoic acid (PFODA)
5X
Perfluorotetradecanoic acid (PFTA)
5X
Perfluorotridecanoic Acid (PFTriA)
5X
Miscellaneous Information
Additional Comments
Some analytes are X qualified because the standards used to make the initial calibration curve did not meet the
ISO 17025 criterion. These are the only standards available for these analytes. Samples 613703001
(NC0026123-INF-20230308) did not meet acceptance criteria for one or more internal standards with a positive
bias. The samples were diluted in order to bring internal standards within acceptance criteria. The results for
these samples were reported from the undiluted and diluted analyses.
Product: The Extraction and Analysis of Per- and Polyfluoroalkyl Substances Using LCMSMS
Ana"cal Method: EPA 537.1 Modified
Ana"cal Procedure: GL-OA-E-076 REV# 13
Ana"cal Batches: 2400381 and 2400378
The following samples were analyzed using the above methods and analytical procedure(s)
GEL Sample ID#
Client Sample Identification
613703003
NCO026123-BIOS-20230308
1205349339
Method Blank (MB)
1205349340
Laboratory Control Sample (LCS)
1205349341
613703003(NC0026123-BIOS-20230308) Matrix Spike (MS)
1205349342
613703003(NC0026123-BIOS-20230308) Matrix Spike Duplicate (MSD)
Page 129 of 136 SDG: 613703

The samples in this SDG were analyzed on a "dry weight" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Calibration Information
CCV Requirements
Calibration verification standards (ICV or CCV) requirements have not been met for samples in this batch in this
SDG. One or more target analytes failed acceptance criteria with a positive bias in the standards bracketing the
samples in this SDG. These target analytes were not detected in the associated environmental samples; therefore,
the non-compliance had no adverse effect on the data.
Quality Control (QQ Information
Laboratory Control Sample (LCS) Recovery
The LCS and/or LCSD (See Below) did not meet the spike recovery acceptance limits with a positive bias. As
target analytes were not detected in the associated samples, the data were not adversely impacted.
Sample
Analyte
Value
1205349340 (LCS)
N-methylperfluoro-l-octanesulfonamide (N-McFOSA)
140* (70/ 136%)
Matrix Spike (MS) Recovery Statement
The MS or MSD (See Below) recovered spiked analytes outside of the established acceptance limits. As similar
recoveries were displayed in the MS and MSD, the failures were attributed to sample matrix interference and the
data were reported.
Sample
Analyte
Value
1205349341
N-methylperfluoro-l-octanesulfonamidoacetic acid
158*
(NC0026123-BIOS-20230308MS)
(N-McFOSAA)
(59%-152%)
Nafion Byproduct 4 (PFESA BP4)
470*
(40%-160%)
Nafion Byproduct 5 (PFESA BP5)
333*
(40%-160%)
400*
R-EVE
(40%-160%)
1205349342
Nafion Byproduct 4 (PFESA BP4)
570*
(NC0026123-BIOS-20230308MSD)
(40%-160%)
Nafion Byproduct 5 (PFESA BP5)
359*
(40%-160%)
418*
R-EVE
(40%-160%)
MS/MSD Relative Percent Difference (RPD) Statement
The RPD values between the MS and MSD (See Below) were not within the acceptance limits. Since all other
RPD values met acceptance criteria, the noted exceptions are attributed to vagaries in the extraction process. The
Page 130 of 136 SDG: 613703

data are reported.
Sample
Analyte
Value
120534934IMS and 1205349342MSD
2-(N-ethylperfluoro-l-octanesulfonamido)-ethanol
RPD 38*
(NC0026123-BIOS-20230308)
(N-EtFOSE)
(0%-30%)
Fluorotelomer sulfonic acid 8:2 (8:2 FTS)
RPD 54*
(0%-30%)
Internal Standard (ISTD) Acceptance
Sample and its MS/MSD pair 1205349341 (NC0026123-BIOS-20230308MS), 1205349342
(NC0026123-BIOS-20230308MSD) and 613703003 (NC0026123-BIOS-20230308) did not meet acceptance
criteria for one or more internal standards. The samples were diluted in order to bring internal standards within
acceptance criteria. As the MS/MSD pair failed internal standard criteria in the same manner as the parent
sample, the failures were attributed to matrix interference. The results for these samples were reported from the
undiluted and diluted analyses.
Technical Information
Sample Dilutions
The following samples and/or QC were diluted due to matrix interference. 1205349341
(NC0026123-BIOS-20230308MS), 1205349342 (NC0026123-BIOS-20230308MSD) and 613703003
(NC0026123-BIO 5-202303 08).
Analyte
613703
003
Fluorotelomer sulfonic acid 8:2 (8:2 FTS)
5X
Miscellaneous Information
Additional Comments
Some analytes are X qualified because the standards used to make the initial calibration curve did not meet the
ISO 17025 criterion. These are the only standards available for these analytes.
Product: The Extraction and Analysis of Per- and Polyfluoroalkyl Substances Using LCMSMS
Analytical Method: EPA 537.1 Modified
Analytical Procedure: GL-OA-E-076 REV# 13
Analytical Batches: 2400729 and 2400727
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
613703002
613703006
613703007
613703008
613703009
613703010
613703011
613703012
Client Sample Identification
NCO026123-EFF-20230308
AsheboroW W TP-FRB-20230308
AsheboroField-FRB-2023 0308
EB-CC-ExtendableDipper
EB-CC-Trowel
EB-CC-Soil probe
EB-CC-Dipper2
EB-CC-Dipperl
Page 131 of 136 SDG: 613703

613703013
EB-CC-MetalBucket
1205350050
Method Blank (MB)
1205350051
Laboratory Control Sample (LCS)
1205350052
Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Calibration Information
CCB Requirements
The continuing calibration verifications (CCVs) were outside the acceptable criteria for PFMOBA with a
positive bias. There were no hits for PFMOBA in any of the unknown samples. Thus, this was not a factor in the
analysis. 1205350050 (MB), 1205350051 (LCS), 1205350052 (LCSD), 613703001
(NC0026123-INF-20230308), 613703002 (NC0026123-EFF-20230308), 613703006
(AsheboroWWTP-FRB-20230308), 613703007 (AsheboroField-FRB-20230308), 613703008
(EB-CC-ExtendableDipper), 613703009 (EB-CC-Trowel) and 613703010 (EB-CC-Soil probe).
Quality Control (QQ Information
Method Blank (MB) Statement
The blank analyzed with this SDG did not meet the established acceptance criteria for PPF Acid (PFPrA). The
extraction cartridges used in the prep process contains PFF Acid (PFPrA) above GEL's reporting limit or
exhibits an interference/enhancement mimicking PPF Acid (PFPrA). Levels detected in the samples and QC
should be assessed accordingly.
Sample
Analyte
Value
1205350050 (MB)
Perfluoropropanoic acid (PFPrA)
4.14 * 10 > 1.95
Laboratory Control Sample Duplicate (LCSD)
An LCSD was used in place of matrix QC due to limited sample volume.
LCS/LCSD Relative Percent Difference (RPD) Statement
Not all of the relative percent differences (RPDs) between the LCS and the LCSD were within the acceptance
limits for this SDG. However, the LCS and LCSD recoveries were all acceptable.
Sample
Analyte
Value
1205350051 (LCS) and 1205350052 (LCSD)
Nation Byproduct 4 (PFESA BP4)
RPD 69* (0%-45%)
Nation Byproduct 5 (PFESA BP5)
RPD 76* (0%-40%)
R-EVE
RPD 47* (0%-26%)
Internal Standard (ISTD) Acceptance
Samples 613703002 (NC0026123-EFF-20230308), 613703011 (EB-CC-Dipper2), 613703012 (EB-CC-Dipperl)
and 613703013 (EB-CC-MetalBucket) did not meet acceptance criteria for one or more internal standards with a
positive bias. The samples were diluted in order to bring internal standards within acceptance criteria. The results
for these samples were reported from the undiluted and diluted analyses.
Page 132 of 136 SDG: 613703

Technical Information
Sample Dilutions
The following samples were diluted to bring the over range concentrations within the calibration range.
613703002 (NC0026123-EFF-20230308), 613703012 (EB-CC-Dipperl) and 613703013 (EB-CC-MetalBucket).
Analyte
613703
002
012
013
11-Chloroeicosafluoro-3-oxaundecane-1-sulfonic acid (F-53B Minor)
1X
1X
5X
9-Chlorohexadecafluoro-3-oxanonane-l-sulfonic acid (F-53B Major)
1X
1X
5X
Fluorotelomer sulfonic acid 4:2 (4:2 FTS)
25X
5X
5X
Perfluorododecanesulfonic acid (PFDoS)
1X
1X
5X
Perfluorodecanesulfonic acid (PFDS)
1X
1X
5X
Perfluorodecanoic acid (PFDA)
1X
5X
5X
Perfluoroheptanesulfonic acid (PFHpS)
1X
1X
5X
Perfluoroheptanoic acid (PFHpA)
1X
5X
5X
Perfluorohexanesulfonic acid (PFHxS)
1X
1X
5X
Perfluorononanesulfonic acid (PFNS)
1X
1X
5X
Perfluorononanoic acid (PFNA)
1X
1X
5X
Perfluorooctanesulfonic acid (PFOS)
1X
1X
5X
Perfluorooctanoic acid (PFDA)
1X
1X
5X
Perfluoropentanesulfonic acid (PFPeS)
1X
1X
5X
Perfluoroundecanoic acid (PFUnA)
1X
1X
5X
4,8-Dioxa-3H-perfluorononanoic acid (DONA,ADONA)
1X
1X
SX
Miscellaneous Information
Additional Comments
Some analytes are X qualified because the standards used to make the initial calibration curve did not meet the
ISO 17025 criterion. These are the only standards available for these analytes.
Product: The Extraction and Analysis of Per- and Polyfluoroalkyl Substances Using LCMSMS
Analytical Method: EPA 537.1 Modified
Analytical Procedure: GL-OA-E-076 REV# 13
Analytical Batches: 2401145 and 2401141
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
Client Sample Identification
613703005
TB-Asheboro-20230308
1205350873
Method Blank (MB)
1205350874
Laboratory Control Sample (LCS)
1205350875
Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on an "as received" basis.
Page 133 of 136 SDG: 613703

Data Summary
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Calibration Information
CCB Requirements
A continuing calibration verification (CCV) was outside the acceptable criteria for PFEESA with a positive bias.
There were no hits for PFEESA in any of the unknown samples bracketed by this CCV. Thus, this was not a
factor in the analysis.
Quality Control (QQ Information
Method Blank (MB) Statement
The blank analyzed with this SDG did not meet the established acceptance criteria for PPF Acid (PFPrA). The
extraction cartridges used in the prep process contains PFF Acid (PFPrA) above GEL's reporting limit or
exhibits an interference/enhancement mimicking PPF Acid (PFPrA). Levels detected in the samples and QC
should be assessed accordingly.
Sample
Analyte
Value
1205350873 (MB)
Perfluoropropanoic acid (PFPrA)
4.71 * 10 > 4.84
There were confirmed hits of target analytes in the blank above the MDL but below the PQL. Samples with
similar hits above the MDL but below the PQL were re -extracted with the exception of 613703005 and
614487016. There were no additional sample containers to allow for re -extractions therefore data for these
samples were reported as is. Results for sample 614969006 were also reported from this extraction batch because
the 6:2 FTS was not detected above the MDL in this sample. 613703005 (TB-Asheboro-20230308).
Laboratory Control Sample Duplicate (LCSD)
An LCSD was used in place of matrix QC due to limited sample volume.
Laboratory Control Sample (LCS) Recovery
The LCS and/or LCSD (See Below) did not meet the spike recovery acceptance limits with a positive bias. As
target analytes were not detected in the associated samples, the data were not adversely impacted.
Sample
Analyte
Value
1205350874 (LCS)
N-methylperfluoro-l-octanesulfonamide (N-McFOSA)
167* (20%-154%)
1205350875 (LCSD)
2-(N-ethylperfluoro-l-octanesulfonamido)-ethanol (N-EtFOSE)
139* (54%-128%)
N-methylperfluoro- I -octanesulfonamide (N-McFOSA)
160* (20%-154%)
Perfluoroheptanoic acid (PFHpA)
135* (71%-133%)
Perfluoropentanesulfonic acid (PFPeS)
137* (67%-136%)
Miscellaneous Information
Additional Comments
Some analytes are X qualified because the standards used to make the initial calibration curve did not meet the
ISO 17025 criterion. These are the only standards available for these analytes.
Page 134 of 136 SDG: 613703

Product: The Extraction and Analysis of Per- and Polyfluoroalkyl Substances Using LCMSMS
Analytical Method: EPA 537.1 Modified
Analytical Procedure: GL-OA-E-076 REV# 13
Analytical Batches: 2401164 and 2401162
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
Client Sample Identification
613703004
NCO026123-GUIS-20230308
1205350935
Method Blank (MB)
1205350936
Laboratory Control Sample (LCS)
1205350937
613703004(NC0026123-GUIS-20230308) Matrix Spike (MS)
1205350938
613703004(NC0026123-GUIS-20230308) Matrix Spike Duplicate (MSD)
The samples in this SDG were analyzed on a "dry weight" basis.
Data Summary
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Quality Control (QC1 Information
Matrix Spike (MS) Recovery Statement
The MS or MSD (See Below) recovered spiked analytes outside of the established acceptance limits. As similar
recoveries were displayed in the MS and MSD, the failures were attributed to sample matrix interference and the
data were reported.
Sample
Analyte
Value
1205350937 (NC0026123-GUIS-20230308MS)
Nafion Byproduct 4 (PFESA BP4)
241* (40%-160%)
Nafion Byproduct 5 (PFESA BP5)
224* (40%-160%)
R-EVE
198* (40%-160%)
1205350938 (NC0026123-GUIS-20230308MSD)
Nafion Byproduct 4 (PFESA BP4)
256* (40%-160%)
Nafion Byproduct 5 (PFESA BP5)
242* (40%-160%)
R-EVE
174* (40%-160%)
Miscellaneous Information
Manual Integrations
Some initial calibration standards, continuing calibration standards, and/or samples required manual integrations
due to software limitations. 613703003 (NC0026123-BIOS-20230308).
Additional Comments
Some analytes are X qualified because the standards used to make the initial calibration curve did not meet the
ISO 17025 criterion. These are the only standards available for these analytes. 613703003
(NC0026123-BIOS-20230308) and 613703004 (NC0026123-GUIS-20230308).
Certification Statement
Page 135 of 136 SDG: 613703

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 136 of 136 SDG: 613703