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HomeMy WebLinkAboutNC0021024_Fact Sheet_20231003Fact Sheet NPDES Permit No. NCO021O24 Permit Writer / e-mail Contact: Gary Perlmutter / gary.perlmutter@deq.nc.gov Date: October 3, 2023 Division / Branch: NC Division of Water Resources / NPDES Municipal Permitting Fact Sheet Template: Version 09Jan2017 Permitting Action: ❑X Renewal ❑ Renewal with Expansion ❑ New Discharge ❑ Modification (Fact Sheet should be tailored to mod request) Note: A complete application should include the following: • For New Dischargers: EPA Form 2A or 2D requirements, Engineering Alternatives Analysis, Fee • For Existing Dischargers (POTW): EPA Form 2A, three (3) effluent pollutant scans, four (4) 2nd species WET tests. • For Existing Dischargers (Non-POTW): EPA Form 2C with correct analytical requirements based on industry category. Complete applicable sections below. If not applicable, enter NA. 1. Basic Facility Information Facility Information Applicant/Facility Name: City of Roxboro - Roxboro WWTP Applicant Address: P.O. Box 128, Roxboro, NC 27573 Facility Address: 902 Cavel-Chub Lake Rd, Roxboro, NC 27574 Permitted Flow: 5.0 MGD Facility Type/Waste: MAJOR Municipal; 96.0% domestic, 4.0% industrial' Facility Class: Grade IV Treatment Units: Septic Tank Unloading, Bar Screens, Grit Removal, Aeration Basins, Secondary Clarifiers, Chlorination disinfection, De -chlorination, Aerobic Digesters, Sludge Dewatering and Drying Pretreatment Program (Y/N) Yes, active County: Person Region Raleigh Footnote. 1. Based on total permitted flow of 0.20 MGD. Briefly describe the proposed permitting action and facility background: The City of Roxboro has applied for NPDES permit renewal and submitted a renewal application, received by the Division on 11/22/2021. Review of the application found it incomplete with the required four 2nd species Whole Effluent Toxicity tests, the Process Narrative, and Chemical Addendum lacking. These items were received by request on NC0021024 5/8/2023. The three required effluent pollutant scans were run in June 2019, September 2020 and March 2021; the four 2nd species tests were conducted in June 2019, March 2020, September 2020 and December 2020. This facility serves a total population of —12,425 residents comprising populations of Roxboro (-8362), and unincorporated areas of Person County (-4063). The facility operates a pretreatment program with two (2) Significant Industrial Users (SIUs): Eaton Corp. (permitted flow = 0.15 MGD), a manufacturer, and Spuntech Industries, LLC (permitted flow = 0.125 MGD), a textile facility. The WWTP was issued Authorization to Construct (AtC) permit no. 021024A03 in August 2016 to make the following system upgrades: • Install a 2.4 MG multiple ring oxidation ditch system with surface rotors, pumps and controls; • Repurpose two existing 3 MG aeration basins to 3 EQ basins of 3 MG, 1.3 MG and 1.3 MG and a 75,000-gal leachate tank plus install associated equipment; • Install new EQ pump station with associated equipment; • Install 2 new 500,000-gal digesters with associated equipment; • Install 3 new blowers • Replace 2 existing RAS/WAS pump stations with 3 new RAS pumps, 1 new scum pump, and 2 new WAS pumps; • Install 2 new 1,150-gal sodium hypochlorite tanks in a repurposed roofed structure and associated pump system and equipment The AtC permitted upgrade construction is currently underway, and once completed will result in no increase in design flow. The system component list on the permit's Supplement to Cover Sheet will reflect the above changes. Sludge management: The cover letter to the permit renewal application states: "Synagro Central land applies the biosolid residuals generated from the operation of the WWTP per our land application permit WQ0021826. " 2. Receiving Waterbody Information Receiving Waterbody Information Outfall(s) / Receiving Stream(s): Outfall 001 / Marlowe Creek Stream Segment: 22-58-12-6a Stream Classification: C Drainage Area (mi2): 4.7 Summer 7Q10 (cfs): 0.0 Winter 7Q10 (cfs): 0.0 30Q2 (cfs): 0.0 Average Flow (cfs): 4.0 IWC (% effluent): 100 2022 303(d) listed / parameter: Benthos Subject to TMDL / parameter: Statewide TMDL / Mercury Basin / HUC: Roanoke / 03010104 USGS Topo Quad: Roxboro, NC Page 2 of 14 NC0021024 The receiving stream, Marlowe Creek, has no downstream water supply waters before crossing the Virginia state line at -10.6 miles downstream of the outfall. 3. Effluent Data Summary Effluent data is summarized below for the period August 2018 through February 2023. Table 1. Effluent Data Summary Parameter Units Average Max Min Permit Limit' Flow MGD 2.0 14.02 0.93 MA = 5.0 BOD, summer mg/L 3.8 31.2 < 2.0 MA = 16.0 WA = 24.0 BOD, winter mg/L 5.7 37.7 < 2.0 MA = 20.0 WA = 30.0 BOD removal % 96.1 99.4 48.8 > 85 Total Suspended Solids mg/L 4.3 42.0 2.3 MA = 30.0 (TSS) WA = 45.0 TSS removal % 95.5 99.8 18.4 > 85 Ammonia (NH3-N), summer mg/L 0.24 2.0 < 0.2 MA = 5.0 WA = 15.0 (through Oct 2021) Ammonia (NH3-N), winter mg/L 0.26 1.5 < 0.2 MA = 13.0 (through Nov 2021) WA = 35.0 Ammonia (NH3-N), summer mg/L 0.25 2.4 < 0.2 MA = 1.0 WA = 3.0 (beginning Apr 2022) Ammonia (NH3-N), winter mg/L 0.36 3.00 < 0.2 MA = 1.8 (beginning Dec 2021) WA = 5.4 Dissolved Oxygen (DO) mg/L 7.2 9.4 5.1 DA > 5.0 pH SU 7.0 7.5 6.6 6.0 - 9.0 Fecal Coliform #/100 mL 7.4 > 2420 < 1 MA = 200 (geomean) WA = 400 Total Residual Chlorine µg/L 16.1 49 15 DM = 17 2 (TRC) Temperature °C 18.5 26.4 8.6 Monitor & Report Total Nitrogen mg/L 7.83 22.30 1.65 Monitor & Report Total Phosphorus mg/L 1.56 6.04 0.25 Monitor & Report Page 3 of 14 NCO021024 Parameter Units Average Max Min Permit Limit' Oil & Grease mg/L 5.1 9 5 MA = 30.0 Total Copper µg/L 8.3 32.0 3.6 MA = 14.8 DM = 21.0 Total Nickel µg/L 2.1 < 10 0.5 Monitor & Report Total Zinc µg/L 41 72 14 Monitor & Report Total Hardness mg/L g 48 76 36 Monitor & (as CaCO3) Report Footnotes. 1. MA = Monthly Average; WA = Weekly Average; DA = Daily Average; DM = Daily Maximum. 2. TRC values < 50 µg/L are considered compliant. The highest annual average effluent flow is 2.06 MGD or 41.2% of the permitted flow in calendar year (CY) 2022. 4. Instream Data Summary Instream monitoring may be required in certain situations, for example: 1) to verify model predictions when model results for instream DO are within 1 mg/L of instream standard at full permitted flow; 2) to verify model predictions for outfall diffuser; 3) to provide data for future TMDL; 4) based on other instream concerns. Instream monitoring may be conducted by the Permittee, and there are also Monitoring Coalitions established in several basins that conduct instream sampling for the Permittee (in which case instream monitoring is waived in the permit as long as coalition membership is maintained). Is this facility a member of a Monitoring Coalition with waived instream monitoring (YIN): NO Name of Monitoring Coalition: NA If applicable, summarize any instream data and what instream monitoring will beproposedfor this permit action: The current permit requires instream monitoring for DO, Temperature and Conductivity under 15A NCAC 02B .0508. The upstream location is at NC 1351 (Cavel Chub Lake Road), —0.2 miles above the outfall. The downstream location is at NC 1322 (Edwin Robertson Road), —3.8 miles below the outfall. Instream data were acquired from submitted DMRs from August 2018 through February 2023 for review. The data were checked against applicable stream standards as well as for effluent impacts, the latter via statistical testing of downstream averages against the upstream average of each parameter using t-test with the level of significance (p-value) set at 0.05. The data are summarized in Table 2 and discussed below. Page 4 of 14 NC0021024 Table 2. Instream Data Summary: averages with ranges in parentheses. *Statistically significantly different from Upstream. Parameter, units Upstream Downstream Standard DO, mg/L Avg = 9.1 Avg = 9.1 5.0 (7.0-13.9) (6.5-14.3) Temperature, °C Avg = 18.1 Avg = 18.4 32.0 (3.4-26.2) (3.5-26.6) Conductivity, µmhos/cm Avg = 220 Avg = 231 (68-768) (59-519) Dissolved Oxygen (DO) — DO is in the permit as a parameter of concern for aquatic life. Summer minima of both stations were all above the stream standard of 5.0 mg/L. No statistically significant differences were found between the upstream and downstream stations. Concurrent effluent average DO is similar with lower summer minima, and thus may be affecting the instream DO. Temperature — Temperature is in the permit as a parameter of concern for aquatic life. Summer maxima at both stations were below the 32°C standard for lower piedmont and coastal plain waters. No statistically significant differences were found between the upstream and downstream stations; no upstream to downstream increases were greater than the 2.8°C standard. Concurrent effluent temperatures appear higher, with substantially higher winter minima. Conductivity — Conductivity is in the permit as an indicator of industrial sources. The Town has an active pretreatment program with two SIUs, a parts manufacturer and a textile industry. The downstream Conductivity was found to be higher than upstream on average (p < 0.05). Effluent Conductivity monitoring has been added to compare with instream values. Fecal Coliform instream monitoring is not in the permit, nor is there any history of this parameter being required for instream monitoring in any past permit since 1997. Division guidance for instream monitoring allows Fecal Coliform to be removed from instream monitoring unless the receiving water is either Class B or is impaired for fecal coliform. The receiving stream is Class C and is not impaired for fecal coliform; therefore, it is not required and was not added to the permit. 5. Compliance Summary Summarize the compliance record with permit effluent limits (past 5 years): From March 2018 through February 2023 (past 5 years) no limit violations were reported. Summarize the compliance record with aquatic toxicity test limits and any second species test results (past 5 years): The facility passed 17 of 17 quarterly chronic toxicity tests, as well as all 4 second species chronic toxicity tests, sampled in June 2019 and March, September and December 2020. Summarize the results from the most recent compliance inspection: The most recent facility inspection, conducted on 02/15/2022, did not report any compliance issues. The most recent pretreatment inspection was on 05/31/2022, also not reporting any compliance issues. Page 5 of 14 NC0021024 6. Water Quality -Based Effluent Limitations (WQBELs) 6.1. Dilution and Mixing Zones In accordance with 15A NCAC 2B.0206, the following streamflows are used for dilution considerations for development of WQBELs: 1 Q 10 streamflow (acute Aquatic Life); 7Q 10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMIX model results): NA. If applicable, describe any mixing zones established in accordance with 15A NCAC 2B.0204(b): NA. 6.2. Oxygen -Consuming Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD= 30 mg/L for Municipals) may be appropriate if deemed more stringent based on dilution and model results. If permit limits are more stringent than TBELs, describe how limits were developed: Monthly/weekly average BOD limits of 16.0/24.0 mg/L summer and 20.0/30.0 mg/L winter are derived from a wasteload allocation (WLA) conducted in 1994. 6.3. Ammonia and Total Residual Chlorine Limitations Limitations for ammonia are based on protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/L (summer) and 1.8 mg/L (winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non -Municipals. Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 µg/L) and capped at 28 µg/L (acute impacts). Due to analytical issues, all TRC values reported below 50 µg/L are considered compliant with their permit limit. Describe any proposed changes to ammonia and/or TRC limits for this permit renewal: The current permit's Ammonia limits were 5.0115.0 mg/L monthly/weekly average in summer and 13.0/35.0 mg/L monthly/weekly average in winter, originally set based on a WLA run in 1994 to protect the DO water quality standard. In the 2013 permit renewal, Ammonia limits were updated to 1.0/3.0 mg/L summer and 1.8/5.4 mg/L winter with a compliance schedule to allow the Permittee time to make updates to the plant. Since the 2013 permit issuance, the Ammonia compliance schedule has been extended multiple times, most recently in 2021 to expire on November 30, 2021. In the permit renewal application, the City has requested another extension, through December 31, 2022. However, since the expiration date has passed without extension, the updated limits became effective December 1, 2021. A Wasteload Allocation (WLA) was calculated for protection against Ammonia toxicity using the WWTPs design flow of 5.0 MGD and the receiving stream's 7Q 10 of 0.0 cfs summer and winter. Resulting allowable concentrations as protective as the current limits. The earlier limits were removed from the permit. After the draft permit was sent to public notice for a 30-day comment period, comments were received from the City, requesting reinstatement and extension of the ammonia compliance schedule, and requesting site - specific limits be applied using the 70th percentile of input data. The facility is consistently meeting the current limits, thus no need to reinstate or extend the expired compliance schedule. Site -specific allowable concentrations were calculated using partially available and default data, with the former using the standard 901h percentiles, with results similar to but not necessarily less stringent than the current limits. Therefore, no changes were made. See the attached Fact Sheet Addendum for details. Page 6 of 14 NC0021024 The current permit TRC limit is 17 µg/L. The WLA used for Ammonia also produced an allowable TRC concentration of 17 µg/L. No changes were made. 6.4. Reasonable Potential Analysis RPA) for Toxicants If applicable, conduct RPA analysis and complete information below. The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of '/2 detection limit for "less than" values; and 4) streamflows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. Because the receiving stream has a 7Q10 of 0.0 cfs, only effluent hardness sampling is required in the current permit. Average effluent hardness = 47.6 mg/L; the effluent data are used in the RPA. A reasonable potential analysis was conducted on effluent toxicant data collected between August 2018 through February 2023. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. Based on this analysis, the following permitting actions are proposed for this permit: • Effluent Limit with Monitoriniz. The following parameters will receive a water quality -based effluent limit (WQBEL) since they demonstrated a reasonable potential to exceed applicable water quality standards/criteria: Copper: MA = 13.67 µg/L; DM = 19.23 µg/L. • Monitoring Only. The following parameters will receive a monitor -only requirement since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria, but the maximum predicted concentration was > 50% of the allowable concentration: None. • No Limit or Monitoring: The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was < 50% of the allowable concentration: All remaining parameters analyzed. • POTW Effluent Pollutant Scan Review: Three effluent pollutant scans were evaluated for additional pollutants of concern. o The following parameter(s) will receive a water quality -based effluent limit (WQBEL) with monitoring, since as part of a limited data set, two samples exceeded the allowable discharge concentration: None. o The following parameter(s) will receive a monitor -only requirement, since as part of a limited data set, one sample exceeded the allowable discharge concentration: None. Only Chloroform and Chlorodibromomethane were detected. No detections were reported among the remaining parameters analyzed. If applicable, attach a spreadsheet of the RPA results as well as a copy of the Dissolved Metals Implementation Fact Sheet for freshwater/saltwater to this Fact Sheet. Include a printout of the RPA Dissolved to Total Metal Calculator sheet if this is a Municipality with a Pretreatment Program. 6.5. Toxicity Testing Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits issued to Major facilities or any facility discharging "complex" wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Page 7 of 14 NC0021024 Describe proposed toxicity test requirement: This is a Major POTW with a chronic WET limit at 90% effluent and monitoring at a quarterly frequency, required under 40 CFR 1220)(5). No changes were made. 6.6. Mercury Statewide TMDL Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA's mercury fish tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 lb/year), and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point sources (-2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging quantifiable levels of mercury (> 1 ng/L) will receive an MMP requirement. Industrials are evaluated on a case -by -case basis, depending if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/L) and/or if any individual value exceeds a TBEL value of 47 ng/L. The current permit requires a Mercury Minimization Plan to be maintained. Data are summarized below. Table 3. Mercury Effluent Data Summary. 2018 2019 2020 2021 2022 # of Samples 1 4 3 4 4 Annual Average Conc. ng/L 8.4 3.6 3.2 2.1 1.7 Maximum Conc., ng/L 8.35 4.65 3.99 3.57 2.48 TBEL, ng/L 47 WQBEL, ng/L 12.0 Describe proposed permit actions based on mercury evaluation: Since no annual average mercury concentration exceeded the WQBEL, and no individual mercury sample exceeded the TBEL, no limits are required. Since the facility is > 2 MGD and reported quantifiable levels of mercury (> 1 ng/L), the mercury minimization plan (MMP) special condition is needed and is reworded toward its maintenance. 6.7. Other TMDL/Nutrient Management Strategy Considerations If applicable, describe any other TMDLs/Nutrient Management Strategies and their implementation within this permit: The receiving stream currently has no TMDLs of Nutrient Management Strategy. The current permit has monthly monitoring requirements for Total Nitrogen (TN) and Total Phosphorus (TP). Monthly reporting of TN components Total Kjeldahl Nitrogen (TKN) and Nitrite -Nitrate (NO2+NO3) were added to the permit to better understand nitrogen content of the effluent. 6.8. Other WQBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: The current permit has Oil & Grease (O&G) requirements of a 30.0 mg/L monthly average limit with monthly monitoring, based on BPJ. The limit was first added to the permit in 2002 with a weekly monitoring requirement, then monitoring was reduced in the 2013 permit after comments by the EPA who questioned O&G limits in permits for POTWs. O&G is a parameter of concern in the pretreatment program, based in part on its regulation in the Industrial User Permits for the SIU Eaton Corporation, which has O&G limits. Based on review of the data and that it is being tracked through the pretreatment program, O&G limits and monitoring were removed from the permit. A request for a Chemical Addendum was sent to the ORC after review of the permit application found it lacking. The ORC responded: "At this time the City of Roxboro has not sampled for and does not have information/analysis results for any additional pollutants (in particular emerging compounds 1,4-Dioxane and PFAS chemicals)." The facility's discharge lies —10.6 miles upstream of the Virginia state line with no water supply waters in between. Neither of the facility's SIUs belong to a category suspected of a source Page 8 of 14 NC0021024 for 1,4-Dioxane, so no monitoring for this parameter will be added to the permit. Because of the general pervasiveness of PFAS, monitoring has been added to the permit with a delayed implementation (see Monitoring Requirements section below). If applicable, describe any special actions (HQW or ORW) this receiving stream and classification shall comply with in order to protect the designated waterbody: NA. If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H.0107(c)(2)(B), 40CFR 122.47, and EPA May 2007 Memo: NA. If applicable, describe any water quality standards variances proposed in accordance with NCGS 143- 215.3(e) and 15A NCAC 2B.0226 for this permit renewal: NA. 7. Technology -Based Effluent Limitations (TBELs) Municipals (if not applicable, delete and skip to Industrials) Are concentration limits in the permit at least as stringent as secondary treatment requirements (30 mg/L BODS/TSS for Monthly Average, and 45 mg/L for BODS/TSS for Weekly Average). YES If NO, provide a justification for alternative limitations (e.g., waste stabilization pond). NA Are 85% removal requirements for BOD51TSS included in the permit? YES. Review of BOD and TSS data found a total of 26 occurrences below 85% BOD removal and 38 occurrences below 85% TSS removal. Occurrences were due to a combination of relatively low influent and/or high effluent values. Overall BOD and TSS removal was greater than 85%. If NO, provide a justification (e.g., waste stabilization pond). NA 8. Antidegradation Review (New/Expanding Discharge) The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation review in accordance with 15A NCAC 213.0201. Each applicant for a new/expanding NPDES permit must document an effort to consider non -discharge alternatives per 15A NCAC 2H.0105(c)(2). In all cases, existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: NA 9. Antibacksliding Review: Sections 402(o)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(1) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or WQBELs may be less stringent based on updated RPA or dilution). Are any effluent limitations less stringent than previous permit (YES/NO): NO. Page 9 of 14 NC0021024 If YES, confirm that antibacksliding provisions are not violated: NA. 10. Monitoring Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 2B.0500; 2) NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10/22/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(o) of the Clean Water Act, and therefore anti -backsliding prohibitions would not be triggered by reductions in monitoring frequencies. The current permit has reduced monitoring requirements at 2/week for BOD, Ammonia and Fecal Coliform from a renewal in 2018. The City requested reduced monitoring frequencies for BOD, TSS, Ammonia and Fecal Coliform based on Division Guidance for reduced monitoring frequencies for exceptionally performing facilities (DWQ 2012) with justification on 5/8/2023. Effluent data from the past three years (February 2020 — January 2023) were evaluated and found all applicable target parameters, including Ammonia using the current limits, to meet the criteria. Monitoring for BOD, TSS, Ammonia and Fecal Coliform is maintained at 2/week. To identify PFAS contamination in waters throughout the state, monitoring requirements are to be implemented in permits. Monitoring of PFAS chemicals has been added to the permit at a quarterly frequency due to the pervasive nature of the chemical group and following guidance by EPA (memo, 12/5/2022). Since an EPA -approved method for sampling and analyzing PFAS in wastewater is not currently available, the PFAS sampling requirement in the Permit includes a delayed implementation of this requirement until the first full calendar quarter beginning 6 months after EPA has a final wastewater method in 40 CFR 136 published in the Federal Register. This date may be extended upon request and if there are no NC -certified labs. For instream monitoring, refer to Section 4. 11. Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was finalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. Effective December 21, 2020, NPDES regulated facilities will be required to submit additional NPDES reports electronically. This permit contains the requirements for electronic reporting, consistent with Federal requirements. Page 10 of 14 NC0021024 12. Summary of Proposed Permitting Actions Table 4. Current Permit Conditions and Proposed Changes 1,2 Parameter Current Permit Proposed Change Basis for Condition/Change Flow 5.0 MGD No change 15A NCAC 213.0505 Summer: MA = 16.0 mg/L WQBEL. QUAL2E model WA = 24.0 mg/L No change in limits or performed in September 2007. BOD5 Winter: MA = 20 mg/L monitoring frequency Effluent data meet criteria for WA = 30 mg/L reduced monitoring frequency. Monitor 2/week TBEL. Secondary treatment MA = 30 mg/L No change in limits or standards/40 CFR 133 / 15A NCAC TSS WA = 45 mg/L monitoring frequency 2B .0406. Monitor 2/week Effluent data meet criteria for reduced monitoring frequency. Interim Limits Summer: MA = 5.0 mg/L WA = 15.0 mg/L Winter: MA = 13.0 mg/L WQBEL. WLA-based for protection WA = 35.0 mg/L Remove Interim Limits against ammonia toxicity. Interim Monitor 2/week limits removed based on expiration NH3-N Final Limits Reduce monitoring to of compliance schedule on Summer 2/week. November 30, 2021. Effluent data MA 1.0 mg/L meet criteria for reduced monitoring WA = 3.0 mg/L frequency. Winter MA = 1.8 mg/L WA = 5.4 mg/L Monitor daily MA = 200 /100 mL WQBEL. State WQ standard, 15A Fecal Coliform WA = 400 A 00 mL No change in limits or NCAC 213.0200. Monitor 2/week monitoring frequency Effluent data meet criteria for reduced monitoring frequency. Total Residual DM — 17 µg/L No change WQBEL. State WQ standard, 15A Chlorine (TRC) NCAC 213.0200. > 5 mg/L WQBEL. State WQ standard, 15A DO No change NCAC 213.0200. Monitor Daily Temperature Monitor daily No change State reporting requirements, 15A NCAC 2B .0508. pH 6 — 9 SU No change WQBEL. State WQ standard, 15A Monitor daily NCAC 213 .0200. Page 11 of 14 NC0021024 Parameter Current Permit Proposed Change Basis for Condition/Change State reporting requirements, 15A Instream monitoring NCAC 2B .0508. Facility has a Conductivity only Add weekly effluent pretreatment program; increased 3/week Jun — Sep monitoring concentrations found downstream. 1/week Oct — May Effluent monitoring frequency to better match instream frequency. TKN No requirement Add monthly monitoring To calculate Total Nitrogen NO2+NO3 No requirement Add monthly monitoring To calculate Total Nitrogen Total Nitrogen Monitor monthly No change State reporting requirements, 15A (TN) NCAC 2B .0508. Total Phosphorus Monitor monthly No change State reporting requirements, 15A (TP) NCAC 2B .0508. BPJ. Effluent data average 5.1 Oil &Grease MA = 30.0 mg/L Remove from permit mg/L, < 50% of previous limit; Monitor monthly parameter is monitored through pretreatment program. Required to assess dissolved metal Total Hardness Monitor quarterly No change limitations (instream monitoring not required as 7Q10 = 0 cfs). MA = 13.7 µg/L DM = 19.2 µg/L No change in MA = 14.8 µg/L monitoring. WQBEL. Reasonable Potential to Total Copper DM = 21.0 µg/L Add note that Permittee exceed stream water quality standard Monitor monthly can request re- (RP) found with updated Hardness evaluation after 24 data. months data collection from monthly to quarterly. No RP found; maximum predicted Total Nickel Monitor quarterly Remove from permit effluent value < 50% of the allowable concentration. No RP found; maximum predicted Total Zinc Monitor quarterly Remove from permit effluent value < 50% of the allowable concentration. Mercury Reword toward MMP Minimization Plan Special condition maintenance Statewide Mercury TMDL (MMP) PFAS No requirement Add quarterly monitoring with delayed EPA recommendations (guidance implementation memo, 12/5/2022). Chronic limits 90% WQBEL. No toxics in toxic Toxicity Test effluent using C effluent usingiodaphnia dubia. No change amounts. 15A NCAC 2B.0200 and Monitor quarterly 15A NCAC 2B.0500. Page 12 of 14 NC0021024 Parameter Current Permit Proposed Change Basis for Condition/Change Effluent Pollutant Three times per Update sampling years: 40 CFR 122 Scan permit cycle 2025, 2026, 2027. Electronic Special Condition Update language In accordance with EPA Electronic Reporting Reporting Rule 2015. Footnote: 1. MGD = Million gallons per day; MA = Monthly Average; WA = Weekly Average; DM = Daily Max. 13. Public Notice Schedule Permit to Public Notice: 05/25/2023, 08/17/2023. Per 15A NCAC 21-1.0109 & .0111, The Division will receive comments for a period of 30 days following the publication date of the public notice. Any request for a public hearing shall be submitted to the Director within the 30-day comment period indicating the interest of the party filing such request and the reasons why a hearing is warranted. 14. NPDES Division Contact If you have any questions regarding any of the above information or on the attached permit, please contact Gary Perlmutter at (919) 707-3611 or via email at gary.perlmutter@deq.nc.gov. 15. Fact Sheet Addendum (if applicable) Were there any changes made since the Draft Permit was public noticed (Yes/No): Yes. With public notice, copies of the draft permit were sent to the City, USEPA, various members of the Division and the Virginia DEQ since the receiving stream crosses state lines. Comments were received only from the City, on 6/21/2023, with several requests. A full list of comments and Division responses are provided in the attached Fact Sheet Addendum. If Yes, list changes and their basis below: • Effluent conductivity monitoring is reduced from daily to weekly to better match instream monitoring. • A footnote was added to the effluent requirements sheet stating that the Permittee may request a re-evaluation of copper limits after 24 months of sampling based on evaluation of effluent data showing no reasonable potential to exceed allowable concentrations from the previous two years. • The annual mercury limit was removed as the limit was based on data older than 4.5 yrs and outside the review period. Based on these changes, primarily the removal of the annual Mercury limit, the draft was sent for a second public comment period. No comments on the second draft were received. Only one change was made to the final permit: • The PFAS condition was revised to reflect the EPA 4"' Daft Method 1633, released in July, 2023. Page 13 of 14 NC0021024 16. Fact Sheet Attachments (if applicable) • NPDES Pretreatment POC form • Monitoring report violations • WET Summary sheet, p. 89 • Compliance inspection report • NH3/TRC WLA calculation form • RPA Spreadsheet Summary • Dissolved Metals Fact Sheet Memo • Mercury TMDL Evaluation • Correspondence with ORC re: requested information • Monitoring reduction request from ORC • Monitoring Reduction spreadsheet • Comments to the first draft permit by the City of Roxboro • Fact Sheet Addendum Page 14 of 14 A 13 C D E F I G I H I J K L M N O 1 P NPDES/PT POC Review Form Version: 2022.06.22 2 1. Facility's General Information 3 Data of (draft) Review 4/6/2023 c. POC review due to: e. Contact Information 4 Data cf (final) Review Municipal NPDES rarawal ❑ Regicnal Office (RO) Raleigh 5 NPDES Permit Writer (pw) Gary Perlmutter HWA-AT/LTMP Review ❑ RO PT Staff Chang Zhang RO NPDES Staff Scott Vincent 6 Permitlee-Facility Name City of Roxboro - Roxboro W WTP New Industries ❑ Facility PT Staff, email Crystal Shotwell <crbowes(Dcitvofroxboro.ci 7 NPDES Permit Number NCO021024 WWTP e>gansion ❑ f. Receiving Stream 8 NPDES Permit Effective Date 7/1/2014 Stream reclasedadjustment ❑ Outfall 9 Chemical Addendum Submittal Data Outfall relmationladjustment ❑ Receiving Stream: Madowe Creek CA, cfs: 4 10 NPDES Permit Public Notice Date 7Q10 update ❑ Stream Class C 7Q10I cts: 0 11 eDMR data evaluated from: to Other POC review trigger, explain: Oufall Lat. 36.26.41 N Ouffall Long. 78.58.47 Wthe 12 3 a. W WTP Capacity Summary Outfall 11 Current Permitted Flow, mgd 5.0 Designed d Fes'' 5.0 Receiving Stream: OA, cfs: 14 Permitted SIU Flow, mgd 0.20 d. IU Summary Stream Class 7Q10. cfs: 771F 15 b. PT Docs. Summary #IUs Oufall Let. Ouffall Long. 16 IWS approval date 11/18/2019 #SIUs 2 Is there a PWS downstream of the Facility's Outfalls? ❑ YES NO 17 3 USTMP approval date: 10/30/2017 # Clue 0 Comments: 18 19 .E d H W A approval data m 0 10/29/2018 If NSCIUs The outiall lies about 10.25 miles upstream or the Virginia state line. If Us w/Local Permits or Other T es 20 Z 2. Industrial Users' Information. 21 # Industrial User (IU) Name IU Activity IU Non Conventional Pdhtans 8 Toxic Pollutant IUP Effective Date 22 1 Eaton Corporation Manufacturing NH3-N, Cu, CN, Ni, Zn, Oil 8 Grease 7 112022 23 2 Spuntech Industries, Inc. Textiles NH3-N, Cu, CN, Sit, Zn 1:4/2022 24 3 25 4 26 s ir 31 comment: 32 3. Status of Pretreatment Program (check all that apply) 33 Status of Pretreatment Pro ram check all that appl 34 ❑ 1) facility has no SIUs, does have Division approved Pretreatment Program that is INACTIVE 35 ❑ 2) facility has no SIUs, does not have Division approved Pretreatment Program 36 ❑ 3) facility has SIUs and DWQ approved Pretreatment Program 37 ❑ 3a) Full Program with LTMP 38 ❑ 31b) Modified Program with STMP 39 ❑ 4) additional conditions regarding Pretreatment attached or listed below 4D 5) facility's sludge is being land applied or composted 41 ❑ 6) facility's sludge is incinerated (add Beryllium and Mercury sampling according to § 503.43) 42 43 ❑ ❑ 7) facility's sludge is taken to a landfill, if yes which landfill: 8) other 44 45 46 Sludge Disposal Plan: tjil" 47 Sludge Permit No: W00003417 Page 1 21024 POC Review Form PW: Find L/STMP document, HWA spreadsheet, DMR, previous and new NPDES permit for next section. a � Comment N� PQLs review U m New Previous % PQL from Required PQL Recomm. Parameter of Concern NPDES NPDES Required by POC due to POC due to POTW Removal L/STMP NPDES L/STMP, ug/I per NPDES PQL, ug/I POC Check List POC POC EPA PT 1 Sludge 2 SIU 3 POC 4 Rate Effluent Freq Effluent Freq permit 0 Flow ❑ ❑ ❑ ❑ ❑ BOD Li ❑ ❑ El2.0 0 TSS El F17 ❑ ❑ O NH3 ❑ ❑ ❑ ❑ n Arsenic n n n n n 2.0 2.0 Footnotes: (1) Always in the LTMP/STMP due to EPA -PT requirement (2) Only in LTMP/STMP R listed in sludge permit (3) Only in LTMP/STMP while SIU still discharges to POTW (4) Only in LTMP/STMP when pollutant is still of concern to POTW (5) In LTMP/STMP, R sewage sludge is incinerated Please use blue fort for the info updated by pw Please use red font for POC that need to be addedlmodi ied In L/STMP sampling plan Blue shaded cell (D60:H82): I Parameters usually included under that POC list Facility Summary/background information/NPDES-PT regulatory action: POC to be added/modified In USTMP: ORC's comments on IU/POC: POC submitted through Chemical Addendum or Supplemental Chemical Datasheet: Additional pollutants added to USTMP due to POTWs concerns: NPDES pw's comments on IU/POC. Page 2 21024 POC Review Form MONITORING REPORT(MR) VIOLATIONS for: Permit: NC21024 MRS Betweel 3 - 2018 and 4 - 2023 Region: % Facility Name: % Param Nam(% County: % Major Minor: % Report Date: 04/10/22 Page 1 of 1 Violation Category:% Program Category: NPDES WW Subbasin: % Violation Action: PERMIT: FACILITY: COUNTY: REGION: MONITORING VIOLATION UNIT OF CALCULATED % REPORT LOCATION PARAMETER DATE FREQUENCY MEASURE LIMIT VALUE Over VIOLATION TYPE VIOLATION ACTION Whole Effluent Toxicity Testing and Self Monitoring Summary Roseboro WWTP NCO026816/001 County: Sampson Ceri7dPF Begin: 11/1/2017 chr lim: 52% NonComp: Single J F M A M 2019 - Pass - - Pass 2020 - Pass - - Pass 2021 - Pass - - Pass 2022 - Pass - - Pass 2023 - Pass - - - Roxboro Steam Electric Power Plant NC0003425/003 County: Person Fthd24PF Begin: 8/1/2021 24hr ac p/f lim: 90%f + NonComp: Single J F M A M 2019 - - Pass - - 2019 - - >100 - - 2020 - - - >100 - 2020 - - Pass - - 2020 2021 - - Pass - - 2021 - - Pass - - 2021 2022 - - Pass - - 2022 2022 - - Pass - - Roxboro WTP NC0003042/001 County: Person Ceri7dPF Begin: 4/1/2018 Chr Monit: 90% NonComp: J F M A M 2019 Pass - - Pass - 2020 Pass - - Pass - 2021 Fail - - Pass - 2022 Pass - - Pass - 2023 Pass - - - - Roxboro WWTP NCO021024/001 County: Person Ceri7dPF Begin: 11/1/2018 chr lim: 90% NonComp: Single J F M A M 2019 - - Pass - - 2020 - - Pass>100(P) - - 2021 - - Pass - - 2022 - - Pass - - 2023 - - Pass - - Region: FRO Basin: CPF19 Feb May Aug Nov 7Q10: 1.0 PF: 0.49 IWC: 52 Freq: Q J J A S O Pass Pass Pass Pass Region: RRO Basin: ROA05 Mar Jun Sep Dec 7Q10: Lake PF: NA IWC: NA Freq: Q J J A S O Pass - - Pass - Pass - - Pass - Pass Pass - - Pass - Pass - - Pass - H Pass - - Pass - H Pass - - Pass Pass - Region: RRO Basin: ROA05 Jan Apr Jul Oct 7Q10: PF: IWC: Freq: Q J J A S O - Pass - - Pass - Pass - - Pass - Fail - - Pass - Pass - - Fail SOC JOC: N Pass Pass Pass Pass SOC JOC: N C D Pass Pass Pass H Pass Pass Pass SOC JOC: N D Region: FRO Basin: ROA05 Mar Jun Sep Dec SOC JOC: 7Q10: 0.0 PF: 5.0 IWC: 100 Freq: Q J J A S O N D Pass >100(P) - - Pass - - Pass Pass - - Pass - - Pass Pass - - Pass - - Pass Pass - - Pass - - Pass Leeend: P= Fathead minnow (Pimohales oromelas). H=No Flow (facilitv is active). s = SDlit test between Certified Labs Page 89 of 112 United States Environmental Protection Agency Form Approved. EPA Washington, D.C. 20460 OMB No. 2040-0057 Water Compliance Inspection Report Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code NPDES yr/mo/day Inspection Type Inspector Fac Type 1 IN 1 2 u 3 I NCO021024 I11 121 22/02/15 I17 18I � I 19 I s I 201 I 211IIIII 111111III II III III1 I I IIIII IIIIIIIII II r6 Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 QA ---------------------- Reserved ------------------- 67 I 72 I n, I 71 I 74 79 I I I I I I I80 701 I 71 I LL -1 I I LJ Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include Entry Time/Date Permit Effective Date POTW name and NPDES permit Number) 10:OOAM 22/02/15 18/11/01 Roxboro WWTP 902 Cavel-Chub Lake Rd Exit Time/Date Permit Expiration Date Roxboro NC 27573 01:OOPM 22/02/15 22/05/31 Name(s) of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) Other Facility Data Derek Lynn Clayton/ORC/336-599-8232/ Name, Address of Responsible Official/Title/Phone and Fax Number Contacted Derek Lynn Clayton,PO Box 128 Roxboro NC 275730128//336-599-8232/ No Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Permit 0 Flow Measurement Operations & Maintenar Records/Reports Self -Monitoring Progran 0 Sludge Handling Dispo: Facility Site Review Effluent/Receiving Wate Laboratory Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/Office/Phone and Fax Numbers Date Stephanie Goss DWR/RRO WQ/919-791-4200/ Molly Nicholson DWR/RRO WQ/919-791-4240/ Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. Page# NPDES yr/mo/day Inspection Type NCO021024 I11 12I 22/02/15 117 18 i c i Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) Page# Permit: NCO021024 Inspection Date: 02/15/2022 Owner -Facility: Roxboro WWTP Inspection Type: Compliance Evaluation Operations & Maintenance Yes No NA NE Is the plant generally clean with acceptable housekeeping? 0 ❑ ❑ ❑ Does the facility analyze process control parameters, for ex: MLSS, MCRT, Settleable ❑ ❑ ❑ Solids, pH, DO, Sludge Judge, and other that are applicable? Comment: Permit Yes No NA NE (If the present permit expires in 6 months or less). Has the permittee submitted a new 0 ❑ ❑ ❑ application? Is the facility as described in the permit? 0 ❑ ❑ ❑ # Are there any special conditions for the permit? ❑ ❑ ■ ❑ Is access to the plant site restricted to the general public? 0 ❑ ❑ ❑ Is the inspector granted access to all areas for inspection? 0 ❑ ❑ ❑ Comment: Record Keeping Yes No NA NE Are records kept and maintained as required by the permit? 0 ❑ ❑ ❑ Is all required information readily available, complete and current? 0 ❑ ❑ ❑ Are all records maintained for 3 years (lab. reg. required 5 years)? ■ ❑ ❑ ❑ Are analytical results consistent with data reported on DMRs? 0 ❑ ❑ ❑ Is the chain -of -custody complete? ❑ ❑ ❑ Dates, times and location of sampling ❑ Name of individual performing the sampling ❑ Results of analysis and calibration ❑ Dates of analysis ❑ Name of person performing analyses ❑ Transported COCs ❑ Are DMRs complete: do they include all permit parameters? ❑ ❑ ❑ Has the facility submitted its annual compliance report to users and DWQ? ❑ ❑ ❑ (If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified ❑ ❑ ❑ operator on each shift? Is the ORC visitation log available and current? ❑ ❑ ❑ Is the ORC certified at grade equal to or higher than the facility classification? ❑ ❑ ❑ Is the backup operator certified at one grade less or greater than the facility ❑ ❑ ❑ classification? Page# 3 Permit: NC0021024 Owner -Facility: Inspection Date: 02/15/2022 Inspection Type: Roxboro WWTP Compliance Evaluation Record Keeping Yes No NA NE Is a copy of the current NPDES permit available on site? 0 ❑ ❑ ❑ Facility has copy of previous year's Annual Report on file for review? 0 ❑ ❑ ❑ Comment: Effluent Pipe Yes No NA NE Is right of way to the outfall properly maintained? 0 ❑ ❑ ❑ Are the receiving water free of foam other than trace amounts and other debris? ■ ❑ ❑ ❑ If effluent (diffuser pipes are required) are they operating properly? M ❑ ❑ ❑ Comment: Flow Measurement - Effluent Yes No NA NE # Is flow meter used for reporting? 0 ❑ ❑ ❑ Is flow meter calibrated annually? 0 ❑ ❑ ❑ Is the flow meter operational? 0 ❑ ❑ ❑ (If units are separated) Does the chart recorder match the flow meter? ❑ ❑ 0 ❑ Comment: Aerobic Digester Yes No NA NE Is the capacity adequate? ■ ❑ ❑ ❑ Is the mixing adequate? ❑ ❑ ❑ ■ Is the site free of excessive foaming in the tank? 0 ❑ ❑ ❑ # Is the odor acceptable? ■ ❑ ❑ ❑ # Is tankage available for properly waste sludge? ■ ❑ ❑ ❑ Comment: Drying Beds Yes No NA NE Is there adequate drying bed space? ❑ ❑ ❑ Is the sludge distribution on drying beds appropriate? ❑ ❑ ❑ ■ Are the drying beds free of vegetation? ❑ ❑ ❑ # Is the site free of dry sludge remaining in beds? ❑ ❑ ❑ Is the site free of stockpiled sludge? ❑ ❑ ❑ Is the filtrate from sludge drying beds returned to the front of the plant? ❑ ❑ ❑ ■ # Is the sludge disposed of through county landfill? ❑ ❑ ❑ Page# 4 Permit: NC0021024 Inspection Date: 02/15/2022 Owner -Facility: Roxboro WWTP Inspection Type: Compliance Evaluation Drying Beds Yes No NA NE # Is the sludge land applied? ❑ ❑ ❑ (Vacuum filters) Is polymer mixing adequate? ❑ ❑ ❑ Comment: Bar Screens Yes No NA NE Type of bar screen a.Manual ❑ b.Mechanical Are the bars adequately screening debris? 0 ❑ ❑ ❑ Is the screen free of excessive debris? 0 ❑ ❑ ❑ Is disposal of screening in compliance? 0 ❑ ❑ ❑ Is the unit in good condition? 0 ❑ ❑ ❑ Comment: Grit Removal Yes No NA NE Type of grit removal a.Manual ❑ b.Mechanical Is the grit free of excessive organic matter? ■ ❑ ❑ ❑ Is the grit free of excessive odor? ■ ❑ ❑ ❑ # Is disposal of grit in compliance? 0 ❑ ❑ ❑ Comment: Equalization Basins Yes No NA NE Is the basin aerated? ❑ ❑ 0 ❑ Is the basin free of bypass lines or structures to the natural environment? ❑ ❑ 0 ❑ Is the basin free of excessive grease? ❑ ❑ ■ ❑ Are all pumps present? ❑ ❑ ■ ❑ Are all pumps operable? ❑ ❑ 0 ❑ Are float controls operable? ❑ ❑ 0 ❑ Are audible and visual alarms operable? ❑ ❑ 0 ❑ # Is basin size/volume adequate? ❑ ❑ ■ ❑ Comment: Page# 5 Permit: NCO021024 Inspection Date: 02/15/2022 Equalization Basins Owner -Facility: Roxboro WWTP Inspection Type: Compliance Evaluation Secondary Clarifier Is the clarifier free of black and odorous wastewater? Is the site free of excessive buildup of solids in center well of circular clarifier? Are weirs level? Is the site free of weir blockage? Is the site free of evidence of short-circuiting? Is scum removal adequate? Is the site free of excessive floating sludge? Is the drive unit operational? Is the return rate acceptable (low turbulence)? Is the overflow clear of excessive solids/pin floc? Is the sludge blanket level acceptable? (Approximately'/4 of the sidewall depth) Comment: Aeration Basins Mode of operation Type of aeration system Is the basin free of dead spots? Are surface aerators and mixers operational? Are the diffusers operational? Is the foam the proper color for the treatment process? Does the foam cover less than 25% of the basin's surface? Is the DO level acceptable? Is the DO level acceptable?(1.0 to 3.0 mg/1) Comment: Standby Power Is automatically activated standby power available? Is the generator tested by interrupting primary power source? Is the generator tested under load? Was generator tested & operational during the inspection? Do the generator(s) have adequate capacity to operate the entire wastewater site? Yes No NA NE Yes No NA NE ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ❑ ❑ ❑ ■ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ Yes No NA NE ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ❑ ❑ ❑ ■ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ Yes No NA NE ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ Page# 6 Permit: NCO021024 Owner -Facility: Roxboro WWTP Inspection Date: 02/15/2022 Inspection Type: Compliance Evaluation Standby Power Yes No NA NE Is there an emergency agreement with a fuel vendor for extended run on back-up 0 ❑ ❑ ❑ power? Is the generator fuel level monitored? 0 ❑ ❑ ❑ Comment: Effluent Sampling Yes No NA NE Is composite sampling flow proportional? 0 ❑ ❑ ❑ Is sample collected below all treatment units? 0 ❑ ❑ ❑ Is proper volume collected? ■ ❑ ❑ ❑ Is the tubing clean? ❑ ❑ 0 ❑ # Is proper temperature set for sample storage (kept at less than or equal to 6.0 ■ ❑ ❑ ❑ degrees Celsius)? Is the facility sampling performed as required by the permit (frequency, sampling type ■ ❑ ❑ ❑ representative)? Comment: Influent Sampling Yes No NA NE # Is composite sampling flow proportional? 0 ❑ ❑ ❑ Is sample collected above side streams? 0 ❑ ❑ ❑ Is proper volume collected? 0 ❑ ❑ ❑ Is the tubing clean? ❑ ❑ 0 ❑ # Is proper temperature set for sample storage (kept at less than or equal to 6.0 ■ ❑ ❑ ❑ degrees Celsius)? Is sampling performed according to the permit? 0 ❑ ❑ ❑ Comment: Disinfection -Liquid Yes No NA NE Is there adequate reserve supply of disinfectant? ❑ ❑ ❑ ■ (Sodium Hypochlorite) Is pump feed system operational? 0 ❑ ❑ ❑ Is bulk storage tank containment area adequate? (free of leaks/open drains) ❑ ❑ ❑ Is the level of chlorine residual acceptable? 0 ❑ ❑ ❑ Is the contact chamber free of growth, or sludge buildup? ■ ❑ ❑ ❑ Is there chlorine residual prior to de -chlorination? ❑ ❑ ❑ Comment: Page# 7 Permit: NCO021024 Owner -Facility: Roxboro WWTP Inspection Date: 02/15/2022 Inspection Type: Compliance Evaluation Laboratory Yes No NA NE Are field parameters performed by certified personnel or laboratory? ■ ❑ ❑ ❑ Are all other parameters(excluding field parameters) performed by a certified lab? ■ ❑ ❑ ❑ # Is the facility using a contract lab? ■ ❑ ❑ ❑ # Is proper temperature set for sample storage (kept at less than or equal to 6.0 ■ ❑ ❑ ❑ degrees Celsius)? Incubator (Fecal Coliform) set to 44.5 degrees Celsius+/- 0.2 degrees? ■ ❑ ❑ ❑ Incubator (BOD) set to 20.0 degrees Celsius +/- 1.0 degrees? ❑ ❑ ■ ❑ Comment: De -chlorination Yes No NA NE Type of system ? Liquid Is the feed ratio proportional to chlorine amount (1 to 1)? ❑ ❑ ❑ ■ Is storage appropriate for cylinders? ❑ ❑ ❑ ■ # Is de -chlorination substance stored away from chlorine containers? ❑ ❑ ❑ ■ Comment: Are the tablets the proper size and type? ❑ ❑ ■ ❑ Are tablet de -chlorinators operational? ❑ ❑ ■ ❑ Number of tubes in use? Comment: Page# 8 NH3/TRC WLA Calculations Roxboro WWTP Permit No. NC0021024 Prepared By: Gary Perlmutter Enter Design Flow (MGD): 5 Enter s7Q10 (cfs): 0 Enter w7Q10 (cfs): 0 Total Residual Chlorine (TRC) Ammonia (Summer) Daily Maximum Limit (ug/1) Monthly Average Limit (mg NH3-N/1) s7Q10 (CFS) 0 s7Q10 (CFS) 0 DESIGN FLOW (MGD) 5 DESIGN FLOW (MGD) 5 DESIGN FLOW (CFS) 7.75 DESIGN FLOW (CFS) 7.75 STREAM STD (UG/L) 17.0 STREAM STD (MG/L) 1.0 Upstream Bkgd (ug/1) 0 Upstream Bkgd (mg/1) 0.22 IWC (%) 100.00 IWC (%) 100.00 Allowable Conc. (ug/1) 17 Allowable Conc. (mg/1) 1.0 Ammonia (Winter) Monthly Average Limit (mg NH3-N/1) Fecal Coliform w7Q10 (CFS) 0 Monthly Average Limit: 200/100ml DESIGN FLOW (MGD) 5 (If DF >331; Monitor) DESIGN FLOW (CFS) 7.75 (If DF<331; Limit) STREAM STD (MG/L) 1.8 Dilution Factor (DF) 1.00 Upstream Bkgd (mg/1) 0.22 IWC (%) 100.00 Allowable Conc. (mg/1) 1.8 Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/I to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/l, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals); capped at 35 mg/I 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis); capped at 35 mg/I Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 1. Proiect Information Facility Name WWTP/WTP Class NPDES Permit Outfall Flow, Qw (MGD) Receiving Stream HUC Number Stream Class ❑ CHECK IF HQW OR ORW WQS Roxboro WWTP Grade IV NCO021024 001 5.000 Marlowe Creek 03010104 C ❑ Apply WS Hardness WQC 7Q10s (cfs) 7Q10w (cfs) 30Q2 (cfs) QA (cfs) 1Q10s (cfs) 0.00 0.00 0.00 4.00 0.00 _Effluent Hardness Upstream Hardness Combined Hardness Chronic Combined Hardness Acute 47.65 mg/L (Avg) NO UPSTREAM HARDNESS DATA I _ _ _ _ _ _ _ 47.65 mg/L I 47.65 mg/L Permittee-submitted DMRs and PPAs. Data Source(s) ❑ CHECK TO APPLY MODEL Par01 Par02 Par03 Par04 Par05 Par06111111 Par07 Par08 Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Parts Par19 Par20 Par21 Par22 Par23 Par24 Table 2. Parameters of Concern Name w4s Type Chronic ModIer Acute PQL Units Arsenic Aquactic Life C 150 FW 340 ug/L Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L Beryllium Aquatic Life NC 6.5 FW 65 ug/L Cadmium Aquatic Life NC 0.9605 FW 5.6880 ug/L Chlorides Aquatic Life NC 230 FW Chlorinated Phenolic Compounds Water Supply NC 1 A ug/L Total Phenolic Compounds Aquatic Life NC 300 A ug/L Chromium III Aquatic Life NC 199.6661 FW 1534.9549 ug/L Chromium VI Aquatic Life NC 11 FW 16 pg/L Chromium, Total Aquatic Life NC N/A FW N/A pg/L Copper Aquatic Life NC 13.6745 FW 19.2285 ug/L Cyanide Aquatic Life NC 5 FW 22 10 ug/L Fluoride Aquatic Life NC 1,800 FW ug/L Lead Aquatic Life NC 6.0532 FW 155.3350 ug/L Mercury Aquatic Life NC 12 FW 0.5 ng/L Molybdenum Human Health NC 2000 HH ug/L Nickel Aquatic Life NC 64.2509 FW 578.4768 pg/L Nickel Water Supply NC 25.0000 WS N/A pg/L Selenium Aquatic Life NC 5 FW 56 ug/L Silver Aquatic Life NC 0.06 FW 0.8988 ug/L Zinc Aquatic Life NC 218.8901 FW 217.1141 ug/L Chlorodibromomethane Human Health C 21 HH pg/L Chloroform Aquatic Life NC 2000 1 FW I pg/L 21024 FW RPA 2023, input 5/24/2023 H1 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 REASONABLE POTENTIAL ANALYSIS H2 Use "PASTE SPECIAL Use "PASTE SPECIAL Effluent Hardness Values" then "COPY• Upstream Hardness Values" then "COPY" . Maximum data . Maximum data points = 58 points = 58 Date Data BDL=1/2DL 8/7/2018 46 46 9/4/2018 44 44 9/11/2018 41.2 41.2 10/2/2018 48 48 11/6/2018 36 36 2/6/2019 52 52 6/4/2019 55.6 55.6 7/2/2019 52 52 8/6/2019 76 76 10/1/2019 72 72 1 /7/2020 44 44 5/5/2020 52 52 7/7/2020 48 48 9/22/2020 45.9 45.9 10/6/2020 48 48 1/5/2021 40 40 3/2/2021 49.1 49.1 4/6/2021 48 48 7/5/2021 40 40 10/5/2021 44 44 1/5/2022 36 36 2/1/2022 64 64 3/8/2022 40 40 4/5/2022 44 44 5/4/2022 44 44 6/7/2022 48 48 7/5/2022 44 44 10/4/2022 36 36 1/10/2023 44 44 Results Std Dev. 9.4681 Mean 47.6483 C.V. 0.1987 n 29 10th Per value 39.20 mg/L Average Value 47.65 mg/L Max. Value 76.00 mg/L Date Data BDL=1/2DL Results 1 Std Dev. NO DATA 2 Mean NO DATA 3 C.V. NO DATA 4 n 0 5 10th Per value NO DATA mg/L 6 Average ValueVESS DATA mg/L 7 Max. Value NO DATA mg/L 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 21024 FW RPA 2023, data -2- 5/24/2023 REASONABLE POTENTIAL ANALYSIS Par01 & Par02 Date Data 1 8/13/2018 < 2 9/11/2018 < 3 11 /30/2018 < 4 2/6/2019 < 5 7/10/2019 < 6 1 /7/2020 < 7 3/3/2020 < 8 5/18/2020 < 9 9/22/2020 < 10 10/6/2020 < 11 3/2/2021 < 12 6/7/2021 < 13 9/14/2021 < 14 12/9/2021 < 15 3/8/2022 < 16 6/7/2022 < 17 9/13/2022 < 18 12/6/2022 < 19 20 21 22 23 24 25 26 27 28 29 3 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Arsenic BDL=1/2DL Results 2 1 Std Dev. 2 1 Mean 2 1 C.V. 2 1 n 2 1 2 1 Mult Factor = 2 1 Max. Value 2 1 Max. Fred Cw 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 Use "PASTE SPECIAL Par03 Values" then "COPY" . Maximum data points = 58 1.0000 0.0000 18 1.00 1.0 ug/L 1.0 ug/L Date Data 1 3/2/2021 < 2 6/7/2022 < 3 6/1/2019 < 4 9/1/2020 < 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Beryllium Values" then "COPY" . Maximum data points = 58 BDL=1/2DL Results 5 2.5 Std Dev. 1.2990 5 2.5 Mean 1.3750 0.5 0.25 C.V. (default) 0.6000 0.5 0.25 n 4 ■ Mult Factor = 2.59 Max. Value 2.50 ug/L Max. Fred Cw 6.48 ug/L -3- 21024 FW RPA 2023, data 5/24/2023 REASONABLE POTENTIAL ANALYSIS Par04 Cadmium Date Data BDL=1/2DL Results 1 8/13/2018 < 0.15 0.075 Std Dev. 2 9/11/2018 < 0.15 0.075 Mean 3 11/30/2018 < 0.15 0.075 C.V. 4 2/6/2019 0.15 0.15 n 5 7/10/2019 < 0.15 0.075 6 10/1/2019 < 0.15 0.075 Mult Factor = 7 1/7/2020 < 0.15 0.075 Max. Value 8 3/3/2020 < 0.15 0.075 Max. Fred Cw 9 5/18/2020 < 0.15 0.075 10 9/22/2020 < 0.15 0.075 11 10/6/2020 < 0.15 0.075 12 6/7/2021 < 0.15 0.075 13 9/14/2021 < 0.15 0.075 14 12/9/2021 < 0.15 0.075 15 3/8/2022 < 0.15 0.075 16 6/7/2022 < 0.15 0.075 17 9/13/2022 < 0.15 0.075 18 12/6/2022 < 0.15 0.075 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Pdr05 Values" then "COPY" . Maximum data points = 58 0.0792 0.2233 18 1.15 0.150 ug/L 0.173 ug/L 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Chlorides Date Data BDL=1/2DL Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Fred Cw Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 NO DATA NO DATA 0 N/A N/A mg/L N/A mg/L -4- 21024 FW RPA 2023, data 5/24/2023 REASONABLE POTENTIAL ANALYSIS Par06 Chlorinated Phenolic Compounds Use "PASTE SPECIAL valves" imthenum •copydata . Max Par07 Total Phenolic Compounds points = 58 Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 Std Dev. NO DATA 1 6/7/2022 12 12 Std Dev. 2 Mean NO DATA 2 Mean 3 C.V. NO DATA 3 C.V. (default) 4 n 0 4 n 5 5 6 Mult Factor = N/A 6 Mult Factor = 7 Max. Value N/A ug/L 7 Max. Value 8 Max. Fred Cw N/A ug/L 8 Max. Fred Cw 9 9 10 10 11 11 12 12 13 13 14 14 15 15 16 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 12.0000 0.6000 1 6.20 12.0 ug/L 74.4 ug/L 21024 FW RPA 2023, data -5- 5/24/2023 REASONABLE POTENTIAL ANALYSIS Par08 Chromium III Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Fred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Pdr09 Use "PASTE SPECIAL Values" then "COPY" Chromium VI . Maximum data points = 58 Date Data BDL=1/2DL Results NO DATA 1 Std Dev. NO DATA 2 Mean NO DATA 3 C.V. 0 4 n 5 N/A 6 Mult Factor = N/A Ng/L 7 Max. Value N/A Ng/L 8 Max. Fred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY' . Maximum data points = 58 NO DATA NO DATA NO DATA 0 N/A N/A Ng/L N/A Ng/L 21024 FW RPA 2023, data -6- 5/24/2023 REASONABLE POTENTIAL ANALYSIS Par10 Chromium, Total Date Data BDL=1/2DL Results 1 8/13/2018 3 3 Std Dev. 2 9/11/2018 3 3 Mean 3 11/30/2018 < 2 1 C.V. 4 2/6/2019 < 2 1 n 5 7/10/2019 < 2 1 6 10/1/2019 < 2 1 Mult Factor = 7 1/7/2020 < 2 1 Max. Value 8 3/3/2020 < 2 1 Max. Fred Cw 9 5/18/2020 < 2 1 10 9/22/2020 < 2 1 11 10/6/2020 < 2 1 12 3/2/2021 < 2 1 13 6/7/2021 < 2 1 14 9/14/2021 < 2 1 15 12/9/2021 < 2 1 16 3/8/2022 < 2 1 17 6/7/2022 < 2 1 18 9/13/2022 < 2 1 19 12/6/2022 < 2 1 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Pa11 Values" then "COPY" . Maximum data points = 58 1.2105 0.5209 19 1.34 3.0 Ng/L 4.0 Ng/L Date Data 1 1 /7/2020 2 2/4/2020 3 3/3/2020 4 4/7/2020 5 5/5/2020 6 5/18/2020 7 6/3/2020 8 7/7/2020 9 8/4/2020 10 9/22/2020 11 10/6/2020 12 11/3/2020 13 12/1/2020 14 12/8/2020 15 12/10/2020 16 12/11 /2020 17 12/22/2020 18 12/29/2020 19 1/5/2021 20 2/3/2021 21 3/2/2021 22 4/6/2021 23 5/5/2021 24 6/7/2021 25 7/5/2021 26 8/3/2021 27 9/14/2021 28 10/5/2021 F11 /2/2021 12/9/2021 1/5/2022 32 2/1/2022 33 3/8/2022 34 4/5/2022 35 5/4/2022 36 6/7/2022 37 7/5/2022 38 8/2/2022 39 9/13/2022 40 10/4/2022 41 11/8/2022 42 12/6/2022 43 1/10/2023 44 2/7/2023 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Copper BDL=1/2DL Results 6 6 Std Dev. 9 9 Mean 8 8 C.V. 11 11 n 8 8 10 10 Mult Factor = 7 7 Max. Value 8 8 Max. Fred Cw 11 11 7 7 8 8 10 10 32 32 13 13 12 12 12 12 18 18 8 8 8 8 6 6 8 8 8 8 10 10 6 6 8 8 6 6 9 9 8 8 6 6 5.6 5.6 3.6 3.6 7 7 5 5 6 6 7 7 5 5 7 7 6 6 7 7 6 6 9 9 7 7 6 6 5 5 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 8.4818 0.5245 44 1.07 32.00 ug/L 34.24 ug/L -7- 21024 FW RPA 2023, data 5/24/2023 REASONABLE POTENTIAL ANALYSIS Par12 Cyanide Date Data BDL=1/2DL Results 1 8/13/2018 < 5 5 Std Dev. 2 9/11/2018 < 5 5 Mean 3 11/30/2018 < 5 5 C.V. 4 2/6/2019 5 5 n 5 7/10/2019 < 5 5 6 3/3/2020 < 5 5 Mult Factor = 7 5/18/2020 < 5 5 Max. Value 8 9/22/2020 < 5 5 Max. Fred Cw 9 10/6/2020 < 5 5 10 3/2/2021 < 5 5 11 6/7/2021 < 5 5 12 9/14/2021 < 5 5 13 12/9/2021 < 5 5 14 3/8/2022 < 5 5 15 6/7/2022 < 5 5 16 9/13/2022 < 5 5 17 12/6/2022 < 5 5 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Par13 Values" then "COPY" . Maximum data points = 58 5.00 0.0000 17 1.00 5.0 ug/L 5.0 ug/L 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Fluoride values" then "COPY" . Maximum data points = 58 Date Data BDL=1/2DL Results Std Dev. NO DATA Mean NO DATA C.V. NO DATA n 0 Mult Factor = N/A Max. Value N/A ug/L Max. Fred Cw N/A ug/L -8- 21024 FW RPA 2023, data 5/24/2023 REASONABLE POTENTIAL ANALYSIS Par14 Lead Date BDL=1/2DL Results 1 8/13/2018 < 0.5 0.25 Std Dev. 2 9/11/2018 < 0.5 0.25 Mean 3 11/30/2018 < 0.5 0.25 C.V. 4 2/6/2019 < 0.5 0.25 n 5 7/10/2019 < 0.5 0.25 6 10/1/2019 < 0.5 0.25 Mult Factor = 7 1/7/2020 < 0.5 0.25 Max. Value 8 3/3/2020 < 0.5 0.25 Max. Fred Cw 9 5/18/2020 < 0.5 0.25 10 9/22/2020 < 0.5 0.25 11 10/6/2020 < 0.5 0.25 12 3/2/2021 0.6 0.6 13 6/7/2021 < 0.5 0.25 14 9/14/2021 < 0.5 0.25 15 12/9/2021 < 0.5 0.25 16 3/8/2022 < 0.5 0.25 17 6/7/2022 < 0.5 0.25 18 9/13/2022 < 0.5 0.25 19 12/6/2022 0.9 0.9 20 21 22 23 24 25 26 27 28 29 3 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Par15 Values" then "COPY" . Maximum data points = 58 0.3026 0.5465 19 1.35 0.900 ug/L 1.215 ug/L 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Mercury Values" then "COPY" . Maximum data points = 58 Date Data BDL=1/2DL Results Std Dev. NO DATA Mean NO DATA C.V. NO DATA n 0 Mult Factor = N/A Max. Value N/A ng/L Max. Fred Cw N/A ng/L -9- 21024 FW RPA 2023, data 5/24/2023 REASONABLE POTENTIAL ANALYSIS Par16 Date Data 1 8/13/2018 2 9/11/2018 3 11 /30/2018 < 4 2/6/2019 < 5 7/10/2019 6 10/1/2019 7 1 /7/2020 < 8 3/3/2020 < 9 5/18/2020 < 10 9/22/2020 < 11 3/2/2021 < 12 6/7/2021 < 13 9/14/2021 < 14 12/9/2021 < 15 3/8/2022 < 16 6/7/2022 < 17 9/13/2022 < 18 12/6/2022 < 19 20 21 22 23 24 25 26 27 28 29 3 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Molybdenum BDL=1/2DL Results 5 5 Std Dev. 12 12 Mean 2 1 C.V. 2 1 n 3 3 2 2 Mult Factor = 2 1 Max. Value 2 1 Max. Fred Cw 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 Use "PASTE SPECIAL Par17 & Pdr18 Values" then "COPY" Nickel . Maximum data points = 58 2.0000 1.3504 18 1.89 12.0 ug/L 22.7 ug/L Use "PASTE SPECIAL Values " then "COPY" . Maximum data points = 58 Date Data BDL=1/2DL Results 1 8/13/2018 2.8 2.8 Std Dev. 0.9137 2 9/11/2018 3.3 3.3 Mean 1.9230 3 11/6/2018 1.7 1.7 C.V. 0.4751 4 11 /30/2018 2.2 2.2 n 37 5 2/6/2019 1.8 1.8 6 6/4/2019 2 2 Mult Factor = 1.11 7 7/2/2019 < 10 5 Max. Value 5.0 Ng/L 8 7/10/2019 2.2 2.2 Max. Fred Cw 5.6 Ng/L 9 10/1/2019 3.3 3.3 10 1 /7/2020 1.1 1.1 11 3/3/2020 1.4 1.4 12 3/3/2020 1.4 1.4 13 5/5/2020 1.8 1.8 14 5/18/2020 2.2 2.2 15 7/7/2020 1.9 1.9 16 9/22/2020 1.3 1.3 17 9/22/2020 1.3 1.3 18 10/6/2020 1.7 1.7 19 1 /5/2021 4 4 20 3/2/2021 1.2 1.2 21 4/6/2021 1.1 1.1 22 6/7/2021 2 2 23 7/5/2021 2.1 2.1 24 9/14/2021 2.1 2.1 25 10/5/2021 2.8 2.8 26 12/9/2021 1.6 1.6 27 1/5/2022 0.8 0.8 28 2/1/2022 1.3 1.3 1.9 1.9 F3/8/2022 4/5/2022 1.6 1.6 5/4/2022 2.3 2.3 32 6/7/2022 2.5 2.5 33 7/5/2022 1.8 1.8 34 9/13/2022 1.4 1.4 35 10/4/2022 1.3 1.3 36 12/6/2022 < 0.5 0.25 37 1/10/2023 0.7 0.7 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 21024 FW RPA 2023, data -10- 5/24/2023 REASONABLE POTENTIAL ANALYSIS Par19 Date Data 1 8/13/2018 < 2 9/11/2018 < 3 11 /30/2018 < 4 2/6/2019 < 5 7/10/2019 < 6 10/1/2019 < 7 1 /7/2020 < 8 3/3/2020 < 9 5/18/2020 < 10 9/22/2020 < 11 10/6/2020 < 12 3/2/2021 < 13 6/7/2021 < 14 9/14/2021 < 15 12/9/2021 < 16 3/8/2022 < 17 6/7/2022 < 18 9/13/2022 < 19 12/6/2022 < 20 21 22 23 24 25 26 27 28 29 3 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Selenium BDL=1/2DL Results 2 1 Std Dev. 2 1 Mean 2 1 C.V. 2 1 n 1 0.5 1 0.5 Mult Factor = 1 0.5 Max. Value 1 0.5 Max. Fred Cw 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 Use "PASTE SPECIAL Par20 Values" then "COPY" . Maximum data points = 58 0.6053 0.3460 19 1.22 1.0 ug/L 1.2 ug/L Use "PASTE SPECIAL Silver Values" then "COPY" . Maximum data points = 58 Date Data BDL=1/2DL Results 1 8/13/2018 < 0.5 0.25 Std Dev. 1.2733 2 9/11/2018 < 0.5 0.25 Mean 0.5421 3 11/30/2018 < 0.5 0.25 C.V. 2.3487 4 2/6/2019 < 0.5 0.25 n 19 5 7/10/2019 < 0.5 0.25 6 10/1/2019 < 0.5 0.25 Mult Factor = 2.24 7 1/7/2020 < 0.5 0.25 Max. Value 5.800 ug/L 8 3/3/2020 < 0.5 0.25 Max. Fred Cw 12.992 ug/L 9 5/18/2020 < 0.5 0.25 10 9/22/2020 < 0.5 0.25 11 10/6/2020 < 0.5 0.25 12 3/2/2021 < 0.5 0.25 13 6/7/2021 5.8 5.8 14 9/14/2021 < 0.5 0.25 15 12/9/2021 < 0.5 0.25 16 3/8/2022 < 0.5 0.25 17 6/7/2022 < 0.5 0.25 18 9/13/2022 < 0.5 0.25 19 12/6/2022 < 0.5 0.25 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 21024 FW RPA 2023, data 5/24/2023 REASONABLE POTENTIAL ANALYSIS Par21 Zinc Use"PASTE SPECIAL Values" the "COPY" Par22 . Maximum data points = 58 Date Data BDL=1/2DL Results 1 8/13/2018 35 35 Std Dev. 11.5564 1 2 9/11/2018 52 52 Mean 40.4474 2 3 9/13/2018 46 46 C.V. 0.2857 3 4 11/6/2018 47 47 n 38 4 5 11 /30/2018 47 47 5 6 2/6/2019 56 56 Mult Factor = 1.06 6 7 6/4/2019 34 34 Max. Value 72.0 ug/L 7 8 7/2/2019 38 38 Max. Fred Cw 76.3 ug/L 8 9 7/10/2019 31 31 9 10 10/1/2019 37 37 10 11 1/7/2020 36 36 11 12 3/3/2020 40 40 12 13 3/3/2020 40 40 13 14 5/5/2020 32 32 14 15 5/18/2020 72 72 15 16 7/7/2020 33 33 16 17 9/22/2020 25 25 17 18 9/22/2020 25 25 18 19 10/6/2020 32 32 19 20 1/5/2021 69 69 20 21 3/2/2021 39 39 21 22 4/6/2021 31 31 22 23 6/7/2021 52 52 23 24 7/5/2021 38 38 24 25 9/14/2021 40 40 25 26 10/5/2021 44 44 26 27 12/9/2021 50 50 27 28 1 /5/2022 14 14 28 29 2/1/2022 49 49 29 30 3/8/2022 49 49 30I 31 4/5/2022 50 50 31 32 5/4/2022 46 46 32 33 6/7/2022 41 41 33 34 7/5/2022 24 24 34 35 9/13/2022 39 39 35 36 10/4/2022 27 27 36 37 12/6/2022 39 39 37 38 1/10/2023 38 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 Use "PASTE SPECIAL Chlorodibromomethane Values" then "COPY" . Maximum data points = 58 Date Data BDL=1/2DL Results 6/1/2019 1.21 1.21 Std Dev. 0.4099 9/1/2020 < 1 0.5 Mean 0.7367 3/1/2021 < 1 0.5 C.V. (default) 0.6000 n 3 Mult Factor = 3.00 Max. Value 1.210000 Ng/L Max. Fred Cw 3.630000 Ng/L 21024 FW RPA 2023, data -12- 5/24/2023 REASONABLE POTENTIAL ANALYSIS Par23 Use "PASTE SPECIAL Par24 Chloroform Values then COPY . Maximum data points = 58 Date Data BDL=1/2DL Results 1 6/1/2019 6.74 6.74 Std Dev. 1.7746 1 2 9/1/2020 6.08 6.08 Mean 5.4033 2 3 3/1/2021 3.39 3.39 C.V. (default) 0.6000 3 4 In 3 4 5 5 6 Mult Factor = 3.00 6 7 Max. Value 6.740000 Ng/L 7 8 Max. Pred Cw 20.220000 Ng/L 8 9 9 10 10 11 11 12 12 13 13 14 14 15 15 16 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 Use "PASTE SPECIAL 0 Values" then "COPY" . Maximum data points = 58 Date Data BDL=1/2DL Results Std Dev. NO DATA Mean NO DATA C.V. NO DATA n 0 Mult Factor = N/A Max. Value N/A Max. Pred Cw N/A 21024 FW RPA 2023, data -13- 5/24/2023 Roxboro WWTP - Outfall 001 NCO021024 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 5 MGD MAXIMUM Qw (MGD) = 5.0000 1Q10S (cfs) = 0.00 7Q10S (cfs) = 0.00 7Q10W (cfs) = 0.00 30Q2 (cfs) = 0.00 Avg. Stream Flow, QA (cfs) = 4.00 Receiving Stream: Marlowe Creek HUC 03010104 DATA POINTS = 58 WWTP/WTP Class: Grade IV IWC% @ 1Q10S = 100 IWC% @ 7Q10S = 100 IWC% @ 7Q10W = 100 IWC% @ 30Q2 = 100 IW%C @ QA = 65.95744681 Stream Class: C COMBINED HARDNESS (mg/L) Acute = 47.65 mg/L Chronic = 47.65 mg/L PARAMETER NC STANDARDS OR EPA CRITERIA Y) REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION TYPE J a z Applied Chronic Acute n # Det. Max Pred Cw Allowable Cw Standard Acute (FW): 340.0 Arsenic C 150 FW 340 ug L 18 0 1.0 Chronic (FW): --- 150.0 Max MDL Arsenic C 10 HH/WS ug/L NO DETECTS Chronic (HH): 15.2 No detects - no monitoring or limits required Max MDL = 2 Acute: 65.00 Beryllium NC 6.5 FW 65 ug/L 4 0 6.48 Note: n 5 9 C.V. (default) Chronic: 6.50 No detects - no monitoring or limits required Limited data set NO DETECTS Max MDL = 5 Acute: 5.688 Cadmium NC 0.9605 FW 5.6880 ug/L 18 1 0.173 Chronic: 0.961 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: NO WQS Chlorides NC 230 FW mg/L 0 0 N/A Chronic:----- 230.0 Acute: NO WQS Chlorinated Phenolic Compounds NC 1 A ug/L 0 0 N/A ------------------------------ Chronic:----- 1.0 Acute: NO WQS Total Phenolic Compounds NC 300 A ttgL 1 1 74.4 __ _ _______ _____ _ _ _ _ _ _ _ _ _ _ _____ Note: n 5 9 C.V. (default) Chronic: 300.0 No RP for limited dataset (n<8 samples). No Limited data set No value > Allowable Cw monitoring or limits required Acute: 1,535.0 Chromium III NC 199.6661 FW 1534.9549 µg L 0 0 N/A Chronic:----- 199.7 Acute: 16.0 Chromium VI NC 11 FW 16 µg L 0 0 N/A Chronic:----- 11.0 ------------------------------ Tot Cr value(s) < 5 and < Cr VI Allowable Cw Chromium, Total NC µg/L 19 2 4.0 Max reported value = 3 a: No monitoring required if all Total Chromium samples are < 5 pg/L or Pred. max for Total Cr is < allowable Cw for Cr VI. 21024 FW RPA 2023, rpa Page 14 of 15 5/24/2023 Roxboro WWTP - Outfall 001 NCO021024 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 5 MGD Acute: 19.23 Copper NC 13.6745 FW 19.2285 ug/L 44 44 34.24 Chronic: 13.67 RP shown - apply Monthly Monitoring with Limit 2 values > Allowable Cw Acute: 22.0 Cyanide NC 5 FW 22 10 ug/L 17 1 5.0 Chronic: 5.0 All values < 10 considered compliant; no monitoring No value > Allowable Cw or limits required Acute: NO WQS Fluoride NC 1800 FW ug/L 0 0 N/A Chronic: -----1,800.0-- ------------------------- Acute: 155.335 Lead NC 6.0532 FW 155.3350 ug/L 19 2 1.215 Chronic: 6.053 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: NO WQS Mercury NC 12 FW 0.5 ng/L 0 0 N/A Chronic:----- 12.0 --- ------------------------- Acute: NO WQS Molybdenum NC 2000 HH ug/L 18 4 22.7 Chronic: 2,000.0 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute (FW): 578.5 Nickel NC 64.2509 FW 578.4768 µg/L 37 35 5.6 Chronic (FW): 64.3 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw ------------------------------ Monitoring required Nickel NC 25.0000 WS µg/L Chronic (WS): 25.0 No value > Allowable Cw Acute: 56.0 Selenium NC 5 FW 56 ug/L 19 0 1.2 _ _ _ _ _ _ _ _ Chronic: 5.0 _ _ _ _ _ _ _ _ _ _ _ _ No detects - no monitoring or limits required NO DETECTS Max MDL = 2 Acute: 0.899 Silver NC 0.06 FW 0.8988 ug/L 19 1 12.992 Chronic: 0.060 All data < 0.5 ug/L except for one value of 5.8 ug/L on 19 values > Allowable Cw 6/7/2021 Acute: 217.1 Zinc NC 218.8901 FW 217.1141 ug/L 38 38 76.3 Chronic: 218.9 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: NO WQS Chlorodibromomethane C 21 HH µg/L 3 1 3.63000 Note: n < 9 C.V. (default) Chronic: 31.83871 No RP for limited dataset (n<8 samples). No Limited data set No value > Allowable Cw monitoring or limits required Acute: NO WQS Chloroform NC 2000 FW µg/L 3 3 20.22000 Note: n < 9 C.V. (default) Chronic: 2000.00000 No RP for limited dataset (n<8 samples). No Limited data set INo value > Allowable Cw monitoring or limits required 21024 FW RPA 2023, rpa Page 15 of 15 5/24/2023 Permit No. NC0021024 NPDES Implementation of Instream Dissolved Metals Standards - Freshwater Standards The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Therefore, metal limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 1. NC Dissolved Metals Water Q ality Standards/A uatic Life Protection Parameter Acute FW, µg/1 (Dissolved) Chronic FW, µg/1 (Dissolved) Acute SW, µg/1 (Dissolved) Chronic SW, µg/1 (Dissolved) Arsenic 340 150 69 36 Beryllium 65 6.5 --- --- Cadmium Calculation Calculation 40 8.8 Chromium III Calculation Calculation --- --- Chromium VI 16 11 1100 50 Copper Calculation Calculation 4.8 3.1 Lead Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 8.2 Silver Calculation 0.06 1.9 0.1 Zinc Calculation Calculation 90 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness dependent standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 213.0200 (e.g., arsenic at 10 µg/1 for human health protection; cyanide at 5 µg/L and fluoride at 1.8 mg/L for aquatic life protection). Table 2. Dissolved Freshwater Standards for Hardness -Dependent Metals The Water Effects Ratio (WER) is equal to one unless determined otherwise under 15A NCAC 02B .0211 Subparagraph (11)(d) Metal NC Dissolved Standard, µg/I Cadmium, Acute WER*{1.136672-[1n hardness] (0. 04183 8)) • e^{0.9151 [In hardness]-3.1485) Cadmium, Acute Trout waters WER*{1.136672-[ln hardness](0.041838)} • e^{0.9151[ln hardness] -3.623 6) Cadmium, Chronic WER*{1.101672-[ln hardness](0.041838)} • e^{0.7998[ln hardness]-4A45l) Chromium III, Acute WER*0.316 e^{0.8190[ln hardness]+3.7256} Chromium III, Chronic WER*0.860 e^{0.8190[ln hardness]+0.6848} Copper, Acute WER*0.960 e^{0.9422[ln hardness]-1.700) Copper, Chronic WER*0.960 e^{0.8545[ln hardness]-1.702) Lead, Acute WER*{1.46203-[ln hardness](0.145712)) • e^{1.273[ln hardness]-1.460) Lead, Chronic WER*{1.46203-[ln hardness](0.145712)) • e^{1.273[ln hardness]-4.705) Nickel, Acute WER*0.998 e^{0.8460[ln hardness]+2.255) Nickel, Chronic WER*0.997 e^{0.8460[ln hardness]+0.0584) Page 1 of 4 Permit No. NCO021024 Silver, Acute WER*0.85 • eA0.72[ln hardness]-6.59} Silver, Chronic Not applicable Zinc, Acute WER*0.978 e^{0.8473[ln hardness]+0.884} Zinc, Chronic WER*0.986 e^{0.8473[ln hardness]+0.884} General Information on the Reasonable Potential Analysis (RPA) The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved and hardness -dependent standards requires additional consideration in order to establish the numeric standard for each metal of concern of each individual discharge. The hardness -based standards require some knowledge of the effluent and instream (upstream) hardness and so must be calculated case -by -case for each discharge. Metals limits must be expressed as `total recoverable' metals in accordance with 40 CFR 122.45(c). The discharge -specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on default translator values developed for each metal (more on that below), but it is also possible to consider case -specific translators developed in accordance with established methodology. RPA Permitting Guidance/WOBELs for Hardness -Dependent Metals - Freshwater The RPA is designed to predict the maximum likely effluent concentrations for each metal of concern, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the critical low -flow values for the receiving stream. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. To perform a RPA on the Freshwater hardness -dependent metals the Permit Writer compiles the following information: • Critical low flow of the receiving stream, 7Q10 (the spreadsheet automatically calculates the 1 Q 10 using the formula 1 Q 10 = 0.843 (s7Q 10, cfs) 0.993 • Effluent hardness and upstream hardness, site -specific data is preferred • Permitted flow • Receiving stream classification 2. In order to establish the numeric standard for each hardness -dependent metal of concern and for each individual discharge, the Permit Writer must first determine what effluent and instream (upstream) hardness values to use in the equations. The permit writer reviews DMR's, Effluent Pollutant Scans, and Toxicity Test results for any hardness data and contacts the Permittee to see if any additional data is available for instream hardness values, upstream of the discharge. If no hardness data is available, the permit writer may choose to do an initial evaluation using a default hardness of 25 mg/L (CaCO3 or (Ca + Mg)). Minimum and maximum limits on the hardness value used for water quality calculations are 25 mg/L and 400 mg/L, respectively. If the use of a default hardness value results in a hardness -dependent metal showing reasonable potential, the permit writer contacts the Permittee and requests 5 site -specific effluent and upstream hardness samples over a period of one week. The RPA is rerun using the new data. Page 2 of 4 Permit No. NCO021024 The overall hardness value used in the water quality calculations is calculated as follows: Combined Hardness (chronic) _ (Permitted Flow, cfs *Avfz. Effluent Hardness, mg/L)+s7Q10, cfs *Avg. Upstream Hardness, mg/L) (Permitted Flow, cfs + s7Q 10, cfs) The Combined Hardness for acute is the same but the calculation uses the 1 Q 10 flow. 3. The permit writer converts the numeric standard for each metal of concern to a total recoverable metal, using the EPA Default Partition Coefficients (DPCs) or site -specific translators, if any have been developed using federally approved methodology. EPA default partition coefficients or the "Fraction Dissolved" converts the value for dissolved metal at laboratory conditions to total recoverable metal at in -stream ambient conditions. This factor is calculated using the linear partition coefficients found in The Metals Translator: Guidance for Calculating a Total Recoverable Permit Limit from a Dissolved Criterion (EPA 823-B-96-007, June 1996) and the equation: Cdiss = 1 Ctotal 1 + { [Kpo] [ss('+a)] [10-6] } Where: ss = in -stream suspended solids concentration [mg/1], minimum of 10 mg/L used, and Kpo and a = constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A list of constants used for each hardness -dependent metal can also be found in the RPA program under a sheet labeled DPCs. 4. The numeric standard for each metal of concern is divided by the default partition coefficient (or site -specific translator) to obtain a Total Recoverable Metal at ambient conditions. In some cases, where an EPA default partition coefficient translator does not exist (ie. silver), the dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. For more information on conversion factors see the June, 1996 EPA Translator Guidance Document. 5. The RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7Q 10 + Qw) (Cwgs)(s7Q 10) (Cb) Qw Where: Ca = allowable effluent concentration (µg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (µg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (µg/L or mg/L) Qw = permitted effluent flow (cfs, match s7Q 10) s7Q 10 = summer low flow used to protect aquatic life from chronic toxicity and human health through the consumption of water, fish, and shellfish from noncarcinogens (cfs) * Discussions are on -going with EPA on how best to address background concentrations Flows other than s7Q 10 may be incorporated as applicable: 1 Q 10 = used in the equation to protect aquatic life from acute toxicity Page 3 of 4 Permit No. NC0021024 QA = used in the equation to protect human health through the consumption of water, fish, and shellfish from carcinogens 30Q2 = used in the equation to protect aesthetic quality 6. The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality -Based Toxics Control published in 1991. 7. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. The Total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium Water Quality Standards. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium III or VI. In these cases, the projected maximum concentration (95th %) for total chromium will be compared against water quality standards for chromium III and chromium VI. 9. Effluent hardness sampling and instream hardness sampling, upstream of the discharge, are inserted into all permits with facilities monitoring for hardness -dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. 10. Hardness and flow values used in the Reasonable Potential Analysis for this permit included: Parameter Value Comments (Data Source) Average Effluent Hardness, mg/L 47.65 Permittee submitted DMRs (Total as CaCO3) Average Upstream Hardness, mg/L NA 7Q10 = 0.0 cfs (Total as CaCO3) 7Q 10 summer (cfs) 0.0 Reported in previous permit Fact Sheet 1 Q 10 (cfs) 0.0 Calculated in RPA spreadsheet Permitted Flow (MGD) 5.0 Design flow Date: April 24, 2023 Permit Writer: Gary Perlmutter Page 4 of 4 5/24/23 WQS = 12 ng/L Facility Name Roxboro WWTP / NC0021024 /Permit No.: Total Mercury 1631E PQL = 0.5 ng/L Date Modifier Data Entry Value MERCURY WQBEL/TBEL EVALUATION V:2013-6 Annual Limit 12 ng/L with Quarterly Monitoring MMP Required 7Q10s = 0.000 cfs WQBEL = 12.00 ng/L Permitted Flow = 5.000 47 ng/L 8/13/18 51.9 51.9 > TBEL 9/11/18 16.1 16.1 11/30/18 8.35 8.35 WQBEL< 25.5 ng/L - Annual Average for 2018 2/6/19 4.65 4.65 6/4/19 3.92 3.92 7/10/19 4.43 4.43 10/1/19 1.52 1.52 3.6 ng/L - Annual Average for 2019 3/3/20 2.59 2.59 5/18/20 2.9 2.9 10/6/20 3.99 3.99 3.2 ng/L - Annual Average for 2020 3/2/21 3.57 3.57 6/7/21 3.14 3.14 9/14/21 < 1 0.5 12/9/21 1.1 1.1 2.1 ng/L - Annual Average for 2021 3/8/22 1.3 1.3 6/7/22 1.91 1.91 9/13/22 2.48 2.48 12/6/22 1.19 1.19 1.7 ng/L - Annual Average for 2022 From: Perlmutter, Gary Sent: Wednesday, April 26, 2023 1:43 PM To: Derek Clayton Subject: EXTERNAL: Reduced monitoring; system component list Hi Derek, I see that in your current permit there is reduced monitoring of 2/week for BOD, TSS and Fecal Coliform. If you wish to maintain the reduced monitoring for these parameters, please submit a request (an e-mail to me is ok) supporting your request that your facility meets criteria for reduced monitoring (see guidance, attached). Also, please check the system component list for any updates: • a septic tank unloading facility two bar screens two grit removal devices two aeration basins (3 MG each) three secondary clarifiers a disinfection system (sodium hypochlorite) with two contact chambers a calcium thiosulfate dechlorination system two aerobic digesters sludge dewatering facility three sludge drying beds. Thanks again, Gary Gary Perlmutter, MSc. Environmental Specialist II NCDEQ/Division of Water Resources NPDES Municipal Permitting Unit City of Roxboro Mr. Gary Perlmutter NC DENR/ DWQ Attn: NPDES Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Dear Mr. Perlmutter The City of Roxboro formerly request a "Reduction of Monitoring Frequencies" for parameters associated with its NPDES permit k NC0021024. We are making this request in conjunction with our NPDES permit renewal application and have included support information/data to justify the reduction in monitoring frequencies. If you have questions or need additional information please contact me at 336-322-6010 or our WWTP Supt. Derek Clayton at 336-322-6000. T Allen Brooks Lockhart City Manager/Permittee City of Roxboro 105 S. LAMAR STREET • PO BOX 128 • ROXBORO, NORTH CAROLINA 27573 • (336) 599-3116 • FAX (336) 599-3774 www. cityofroxboro. com Roxboro WWTP Permit # NCO021024 NPDES Monitoring Frequencies Reduction Data January 2018 - September 2021 Month/ Monthly Monthly Month/ Monthly Monthly Fecal avg. =s Parameter Year Avg. mg/I Max. mg/I Parameter Year Avg. Max. G c #/100 ml #/100 ml mean NH3 Jan-18 0 O'Fecal Jan-18 7.54 7Z Feb-18 0.035 0.3'Coliform Feb-18 8.89 32 Mar-18 0 0 Mar-18 6.35 72 Apr-18 0.12 1.7 Apr-18 11.94 1046 May-18' 0.17 2.1 May-18 --- -7.13 159 Jun-18 0.08 1 Jun-18 8.95 131 Jul-18 0 0 Jul-18 4.41 51 Aug-18 0.39 0.5 Aug-18 13.33 144 Sep-18 0.05 0.9 Sep-18 25.48 2420 Oct-18 0 05 1.2 - Oct-18 8.52 326 Nov-18 0.21' 1 Nov-18 16.49 24N Dec-18 0.02 0.3 Dec-18 4.24 16 Jan-19 0.02 0.4 Jan-19 6.83 1120 Feb-19 0.08 1.1, Feb-19 8.93 24201 Mar-19 0.03 0.4, Mar-19 3.28 2420 - -- Apr-19 0 0 A r-19 2.85 12'' May-19 0 0 May-19 4.61 23 Jun-19' 0.04 0.4 Jun-19 7.98 32 Jul-19 0.09 1.3 Jul-19 6.63 91 Aug-19 0.01 0.2 Aug-19 8.33 - 107 Sep-19 0 0 Sep-19 4.03 48 Oct-19 0.12 1.6 Oct-19 16.72 2420 Nov-19 0.05 0.8 Nov-19 13.35 56 Dec-19 0.04 0.7 Dec-19 10.41 48 Jan-20 0 0 Jan-20 8.48 9.4 Feb-20 0.15 1.3 Feb-20' 11.26 2420 Mar-20 0.02 0.5 Mar-20 3.91 72' Apr-20 0 0 Apr-20 5.26 108' Ma -20, 0.31 2 May-20 12.06 2420 Jun-20 0.1 1 Jun-20 8.94 261 Jul-20 0.03 0.3 - Jul-20 - 2.27' -- - - S Aug-20 0 0 Aug-20' 4.47 86 Sep-20 0.08 1.2 Sep-20 7.49 126 Oct-20 0.12 1.25 Oct-20 4.95 138 Nov-20 0.1 1 Nov-20 17.33 2420 Dec-20 0.32 1.5 Dec-20, 14.14 66 Jan-21 0.07 0.6 - Jan-21 6.12 69: Feb-21 0.27 1.5 Feb-21 11.51 727' Mar-21 0.03 0.4 Mar-21 5.83 19 Apr-21 0.02 0.4 Apr-21 4.13 9 May-21 0 0 May-21 3.8' 22 Jun-21 0.05 0.5 Jun-21 5.37' 387 Jul-21 0.06 1 Jul-21 3.95 57 Aug-21 0 0 Aug-21 5.7 93 Sep-2 1 0.11 1.5 Sep-21 4.77 64 Avg. 0.076556 0.707778 7.11848 133.687 Roxboro WWTP Perrrlit# NCO021024 NPDES Monitoring Frequencies Reduction Data January 2018 - September 2021 Month/ Monthly Monthly Month/ Monthly Monthly Parameter, Year Avg. mg/I parameter Max. mg/I Year Avg. mg/I Max. mg/I BOD Jan-18 6.79 11.9 TSS Jan-18 6.47 17.3 Feb-18, 7.1 11.7 Feb-18 9.2 23.5' Mar-18I 6.19 9.2 Mar-18 7.35 13.9 Apr-18 4.59 8.7 Apr-18 2.92 16.2 May-18 --Jun-18 4.15 10.6 May-18 1.13 14.1 4.71 9.5 Jun-18 0.56 6.1 Jul-18 3.54 6 Jul-18 0 0, Aug48 4.01 7.2 Aug-18 0.04 4.2 Sep-1-8- 4.62 8.7 Sep-18 2.421 36.5' Oct-18 2.85 8.8 Oct-18 1.28 i 21.4 Nov-18 4.59 10.2 Nov-18 6.59 24.2 Dec-18 4.63 7.8 Dec-18 3.57 6.6 Jan-19 4.13 7.4 Jan-19 2.93 9.7 Feb-19 5.29 11.9 Feb-19 _ 5.77 1T - Mar-19 4.52 11.7 Mar-19 5.49 14.41 Apr-19 4.05 7.2 Apr-19' 3.32 7 May-19 2.28, 3.2 May-19' 0.19 3 Jun-19 2.78 5.1 Jun-19 - 1.31 --- 5.9 Jul-19 2.64 5 Jul-19 0.59 7 Aug-19 3.34 8.5 Aug-19 0.191 3.2 Sep-19 3.51 8.2 Sep-19 0', - 0 Oct-19 3.85 5.5' Oct-19 3.67 22.8 Nov-19 - - - 5.15' 7.7 Nov-19 3.85 5.4 Dec-19, ---- 5.09 6.6 Dec-19 4.01 - 11 Jan-20' 4.36 7.2 Jan-20 5.38 7.9 Feb-20 5.22 14.1 Feb-201 4.19 9.5 Mar-20 5.73 10.7 Mar-20' 3.25 9.6 Apr-20 6.19' 9.4 Apr-20 5.14 13 May-20' 6.86 20.5 May-20 7.7, 25.9. Jun-20. 4.24 6.3 Jun-20 3.12 9.9 Jul-20 3.16 4.7 Jul-20 0.48 3.6 Aug-20 3.41 5.2 Aug-20 1.01 4 Sep-20 4.94 12.6 Sep-20 1.91 18.7, Oct-20' _ 5.48 11.7 Oct-20 3.98 10.61 Nov-20 ---- 5.58 _ 11.9 Nov-20 5.34 19.6' Dec-20 6.6 - - 14.5 - Dec-20 8.53 - -- 28.4 Jan-21 6.39' 11.3 Jan-21 5.93 16.3 Feb-21 $.41 19.4 1`eb-21 7.21 28.8, Mar-21 5.49 10 Mar-21 4.87' 7.4 Apr-21 3.69 4.4 Apr-21 2.13 4.2 May-21 3.26 - 4.2 May-21 3.46 5.4 Jun-21 3.04 6.6 Jun-21 1.42 6.9 Jul-21 3.09 6.8 Jul-21 0.62 8.7' Aug-21' 2.47 3.9 Aug-21 0 0 Sep-21 3.14 8.4 -- Sep-21' 1.19 11.5 avg. 4.558889 8.935556 3.212632 12.00667 Roxboro WWTP NCO021024 NPDES Monitoring Frequencies Reduction Data 2018 - 2021 (BOD, Nh3 winter / summer limits) Parameter Month/ Monthly Monthly Parametet Month/ Monthly Monthly Year Avl[_mgn Max. Mgn Year Avg. mgA Max. BOD 6.79 11.9 NH3 Jan-18 0 0 --Jan-1-8 - -- -_ Feb-18 7.1 11.7 Feb-18 Mar-18 0.035 0.3 _ Mar-18 6.19 9.2 _ 0 _ 0 Nov-18 4.59 10.2 NOV-18 0.21 1 Dec-18 4.63 7.8 Dec-18 0.02 0.3 Jan-19 4.13 _ 7.4 Jan-19 0.02 0.4 Feb-19 - 5.29 11.9 11.9 Feb-19 _ _0.08 0.03 1.1 Mar-19 _ 4.52 5.15 11.7 Mar-19 _ 0.4 Nov-19 7.7 Nov-19 _ _0.05 0.04 0.8 0.7 Der,19 5.09 6.6 Dec-19 _ Jan-20 4.36 7.2 Jan-20 0 0 _ Feb-20 5.22 14.1 Feb-20 0.15 1.3 Mar-20 5.73 10.7 Mar-2-0 0.02 - -0.1 0.5 - - Nov-20 5.58 11 .9 Nov-20 1 Deo-20 6.6 14.5 Dec-20 0.32 1.5 Jan-21 6.3911 11.3 Jan-21 _ 0.07 - 0.27 0.6 _ Feb-211 8.411 19.4 1 Feb-21 1.5 Mar-21 5491 10 Mar-21 0.03 0.4 WINTER AVG 1 5.6255551 10.84444 AVG 0.080278 0.655556 Current Limits Effective 10/1/2019 - NOTE: Due to W WTP Upgrade NH3 limits were extended. WRITER UMITS... BOO ... MONTHLY AVG. 20.OMG/L WEEKLY AVG 30.0 MG(L INH3 ... MONTHLY AVG. 1.8 MG/L WEEKLY AVG. 5.4 MG/L SUMMER UNUTB._BOD... MONTHLY AVG. 16.0 MGA. WEEKLY AVG. Z4.0 MGA. NH3... MONTHLY AVG. 1.0 MGIL WEEKLY AVG. 3.0 MGIL SUMMER _ SOD -18 4.59 -- 4.15 8.7 NH3 Apr-18 Ma 18 0.12 1.7 -- M -18 10.6 0.17 2.1 - Jun-18 4.71 9.5 Jun-18 0.08 0 1 0 Jul-18 3.54 6 Jut18 Aug-18 4.01 - -4.62 7.2 18 0.39 0.5 Sep-18 8.7 Sep-18 0.05 _ 0.9 1.2 Od-18 - 8.8 Oct-1_8 0.05 r-19 _ _2.85 4.05 7.2 Apr-19 0 0 Ma -19 2.281 3.2 _ Ma -19 0 0.04 0 --0.4 Jun-19 2.78 5.1 Jun-19 Jul-19 2-64 5 Jut19 0.09 1.3 _ Aug-19 3.34 8.5 19 0.01 0.2 Sep-19 3.51 8.2 19 0 0.12 _ 0 1.6 Oct-19 3.85 5.5 Oct 19 Apr-20 6.19 9.4 r-20 01 0 Ma 20 6.86 20.5 Ma 20 0.31 2 Jun-20 4.24 6.3 Jun-20 0.1 1 Jul-20 3.16 4.7 Jut20 0.03 _ 0.3 20 3.41 5.2 20 0 0 1.2 Sep-2-0 __- 4.94 12.6 _ .. Sep-20 0.08 Oct-20 5.46 11.7 Oct- 0.12 1.25 Apr-21 3.69 4.4 Apr-21 0.02 0.4 May-21 Jun-21 3.26 4.2 M 21 0 _ 0- 0.5 3.04 6.6 Jun-21 0.05 Jul-21 3.09 6.8 3.9 Jul-21 0.06 1 Aug-21 2.47 Aug-21 0 0. Sep-21 3.14 8.4 21 0.11 1.5 SUMMER Ave 3.819231 7.623077 AVo 0.072308 0.706769 Roxboro WWTP System Component List As of 4/28/2023 • Two Bar Screens • Two Grit Removal Devices • Two Aeration Basins (3 MG Each, only one in operation because permit compliance is achieved without the electrical cost of running both) • Three secondary clarifiers (only two in operation, east clarifier was taken offline to accommodate the WWTP upgrade, will be brought back online when the treatment /solids are transferred to the Oxidation Ditch) • A disinfection system (sodium hypochlorite) with two contact chambers • A calcium thiosulfate dichlorination system • Four aerobic digesters (two were added and online as part of the current WWTP upgrade) • Sludge dewatering facility • 1.5 sludge drying beds ... (the sludge dewatering facility utilized one of these beds and the two new aerobic digesters used %= of another) It is anticipated that the repair to the Oxidation Ditch floor that put the Roxboro WWTP upgrade on hold will be completed in August of 2023. The new 2.4 MG, 5.0 mgd ditch rated multiple ring oxidation ditch system is expected to come online at some point after the repair is made . As per A to C NCDEQ RRO will be notified in advance. Attachment: Scheduled Improvements 2.5 Completion of the $23,000,000 upgrade to the City of Roxboro W WTP which began on July 23rd 2018 has and continues to be delayed due to construction related issues with the Oxidation Ditch. At this time there is no set date for completion and transfer of treatment into the Oxidation Ditch. Currently, all biological treatment still occurs in the existing activated sludge basins. The W WTP upgrade became necessary when the City's NPDES permit limit for NH3 was reduced from 5mg/l to 1 mg/l in the 2013 permit. UPDATE 4/28/2023 Repair work has begun on the construction related issues with the new Oxidation Ditch, current estimates have this work being completed in August of 2023. Reduction in Frequency Evalaution Facility: Roxboro WWTP Permit No. NC0021024 Review period (use 03/2020 - 02/2023 3 yrs) Approval Criteria: Y/N? 1. Not currently under SOC Y 2. Not on EPA Quarterly noncompliance report Y 3. Facility or employees convicted of CWA violations N # of non - Monthly 3-yr mean # daily # daily Reduce Weekly average 50% 200% 200% monthly # civil penalty Data Review Units average (geo mean < 50%? samples <15? samples < 20? > 2? > 1? Frequency? limit limit MA for FC) MA >200% WA >200% limit asessment (Yes/No) violations BOD (Weighted) mg/L 26.50 17.67 8.8 4.27 Y 35.33 0 Y 0 N 0 N Y TSS mg/L 45.00 30.00 15 1.93 Y 60.00 0 Y 0 N 0 N Y Ammonia (weighted) mg/L 4.00 1.33 0.7 0.17 Y 2.67 0 Y 0 N 0 N Y Fecal Coliform #/100 400.00 200.00 1001 6.796032 Y 800 8 Y 0 N 0 N Y City of Roxboro Mr. Gary Perlmutter, MSc. Environmental Specialist II NCDEQ/ Division of Water Resources NPDES Municipal Permitting Unit Subject: Draft NPDES Permit NCO021024 Roxboro WWTP Person County Grade IV Biological WPCS SIC Code 4952 Dear Mr. Perlmutter: The City of Roxboro NC would like to offer the following comments concerning the DRAFT NPDES permit NCO021024 for its WWTP. Mr. Andrew M. Oakley is no longer the City of Roxboro's Public Services Director. Mr. Kenneth Griffin is the new City of Roxboro Public Services Director and the process of naming Mr. Griffin "permittee" will begin as soon as possible. Page 2 of 11 of the Draft permit list both current and future components at the Roxboro WWTP. An updated list was emailed to you on 4/28/23, it included this notable change; 1. 1.5 sludge drying beds...( the sludge dewatering facility utilized one of these beds and the two new aerobic digesters used A of another) We request that notification be given when EPA publishes 40 CFR part 136 Final PFAS Method for wastewater in the Federal Register in -order to meet the 15` full calendar quarter following six (6) months after publication monitoring requirement included in the draft permit. Conductivity. Downstream conductivity is just 5% higher than upstream therefore we don't see why monitoring our effluent for it is necessary. At a minimum we request that the monitoring be reduced to once per week which is 250 plus samples/data points over the five year permit term. 105 S. LAMAR STREET • PO BOX 128 • ROXBORO, NORTH CAROLINA 27573 • (336) 599-3116 • FAX (336) 599-3774 wivw.cityof oxboro.com Ammonia. The City of Roxboro request that the modified compliance Special Condition A. (1) Effluent Limitations and Monitoring Requirements, Footnotes 3 and 4 that expired on November 30, 2021 be reinstated through March of 2024. Completion of the Roxboro WWTP upgrade which began on July 23'd of 2018 continues to be delayed due to construction related issues with the Oxidation Ditch. A repair resolution was approved and the repair work to the structure was started on April 3`d 2023, the Oxidation Ditch repair is scheduled to be completed in late 2023. Once this occurs the biological treatment process will be transferred from the existing activated sludge basins to the Oxidation Ditch. The requested March 2024 compliance schedule would also allow time to get the new system up and running efficiently after the projected solids transfer. Additionally, the City of Roxboro had an outside consultant (AquaLaw) compare our data (Nh3, ph, temp.) against EPA's 2013 Freshwater NH3-N criteria. Their findings and recommendations are as follows: Roxboro objects to the ammonia ("NH3-N") limits, as proposed, and requests different numeric limits for the following reasons. The proposed limits (summer 1.0 mg/I monthly average/3.0 weekly; winter 1.8 mg/I/5.4) are unnecessarily stringent for protection of aquatic life, arbitrary and unsupported legally. We note that we have had no ammonia toxicity as verified through our passing all of our WET tests during the prior permit cycle. EPA's 2013 Freshwater NH3-N criteria ("EPA 2013") are the nationally recommended criteria for NH3-N toxicity. Those criteria are so stringent that many states have not adopted them (also pointing to the fact that WET testing results demonstrate no need for more stringent NH3-N criteria). EPA's recommended criteria are highly pH and temperature dependent. We propose the application of EPA's 2013 creiteria with the pH and temperature inputs set at the upper 75th percentile values. The upper 75th percentile represents a reasonable, largely worst -case, application of EPA 2013. We compiled the daily pH and temperature records for our facility for 2020, 2021 and 2022, and then ranked the data separately for the DEQ-defined summer and winter tiers. The data are included in the tables following, including values for a more stringent 90th percentile approach (although we believe that the 75th percentile is adequately conservative, particularly as used with both variables for EPA 2013 criteria): Summer 2020-2022 Effluent Data Max 75th 90th pH 7.4 7.2 7.3 T 26.4 24.2 25.1 Winter 2020-2022 Effluent Data Max 75th 90th pH 7.4 7.1 7.1 T 20.8 15.3 16.7 The approximate EPA 2013 criteria values are the following; EPA 2013 NH3-N WQC (mg/1) Summer Acute/Chronic Winter Acute/Chronic 75`h 9.7/1.3 22/2.4 90`h 7.9/1.2 20/2.2 For permit limits Roxboro requests that DEQ use an approach recommended by U.S. EPA in its Technical Support Document for Water Quality -Based Toxics Control ("TSD"). The first TSD option is to use the criteria values themselves as limits. Under this approach (and using upper 75`h percentile pH and temperature), the summer NH3-N limits would be 1.3 mg/I monthly average and 9.7 mg/I weekly average. The wintertime limits would be 2.4 and 22 mg/I, monthly and weekly. Again, considering the use of conservative 75`h percentile values for both the pH and temperature input variables, these resulting NH3- N limits will be highly conservative and protective of aquatic life. This has been confirmed by our extensive W ET testi ng. EPA's TSD alternate statistical procedure for limits calculations generally produces similar numeric values to the direct use of wasteland allocations/criteria. We have not calculated those alternate values but it generally appears that in this case the permit limit values would be comparable. Total Copper limits. As the copper data below demonstrates, we had issues in the second half of 2020, especially during December that were construction related. We strongly believe the December V 2020 and December 22"d 2020 copper results were related to three things. I. One of the three final clarifiers being off-line due to the plant upgrade. 2. 1&1 due to heavy rain. 3. In anticipation of the Oxidation Ditch coming on-line, the contractors installed an influent diversion box in August of 2020. This diversion box allows influent flow to the OD through a 36" pipe and flow to the equalization basins through a 24" telescoping valve. Since installation and currently the 36" pipe to the OD is plugged so all of ourflow since August of 2020 goes through the 24" telescoping valve to the existing activated sludge basins which eventually become equalization basins after the OD comes on-line. The 24" telescoping valve was not designed to carry all the influent flow so during heavy rain events it creates a "funnel" effect and water backs up. With the installation of the influent diversion box in August of 2020 there was a learning curve for our staff that resulted in two bypass events from the diversion box and how they had to manage heavy rain events like those from December 2020. Since that time, we have had heavy rain that resulted in high flows on many occasions but we haven't had another bypass or copper result anywhere near the 32 ug/I from 12/1/2020. Since that time, you can see that our copper average has come down steadily and our maximum value since 1/1/21 is 10 ug/L. We do not believe there is reasonable potential if DEQ would simply base the review on the data since 1/1/21. We believe these data are the more representative data because the 2020 data came when the facility was in an upset condition due to the construction issues mentioned above. Thus, we ask DEQto rerun the RP calculations using data from 1/1/21 and with recognition of the significant downward trend since 1/1/21 in both the max and annual values. That trend is due to the lessons learned and the management strategies applied as a result of high flows during heavy rain events after the influent diversion box tie-in and the resulting stabilization of the operation of the facility. We believe this stabilization of operation will continue to improve with the Oxidation Ditch & Final Clarifier coming online and the completion of the WWTP upgrade. Again, the second half of 2020 copper data are not representative of the plant performance going forward. Date ug/I Date ug/I Date ug/I Date ug/I 1/7/2020 6 1/5/2021 8 1/5/2022 3.6 1/10/2023 6 2/4/2020 9 2/3/2021 6 2/1/2022 7 2/7/2023 5 3/3/2020 8 3/2/2021 8 3/8/2022 5 3/7/2023 6 4/7/2020 11 4/6/2021 8 4/5/2022 6 4/4/2023 6 S/8/2020 8 5/10/2021 10 5/4/2022 7 5/2/2023 6 5/18/2020 10 6/7/2021 6 6/5/2022 5 Avg. 5.8 6/3/2020 7 7/5/2021 8 7/5/2022 7 Max. 6 7/7/2020 8 8/3/2021 6 8/2/2022 6 8/4/2020 11 9/14/2021 9 9/13/2022 7 9/22/2020 7 10/5/2021 8 10/4/2022 6 10/6/2020 8 11/2/2021 6 11/8/2022 9 11/3/2020 10 12/9/2021 S.6 12/6/2022 7 12/1/2020 32 Avg. 7.383333 Avg. 6.3 12/8/2020 13 Max. 10 Max. 9 12/10/2020 12 12/11/2020 12 12/22/2020 18 12/29/2020 8 Avg. 11 Max. 32 Fact Sheet NPDES Permit No. NCO021024 6.6. Mercury Statewide TMDL Evaluation pg. 7 & 8 of 11 We disagree with including an annual limit of 12ng/I because of the reported maximum conc. of 51.9 ng/l from August 2018 monitoring. This 51.9 ng/l was reported on the August 2018 eDMR as instructed the RRO (Raleigh Regional Office), the original lab result of 92.8 ng/I was averaged with a second analysis on the same sample which came back as 11.0 ng/I. Please see the attached file (LLHG August 2018 5 26 23), it includes email correspondence between Roxboro WWTP Supt. Derek Clayton and NCDENR Environmental Program Consultants Vanessa Manuel and Danny Smith. Additional emails (attached) between the Division of Water Resources PERCS Unit Supervisor Deborah Gore and City of Roxboro W WTP Lab Supervisor / PT Coordinator Crystal Shotwell indicate that she had talked to Teresa Rodriguez who issued our current NPDES permit and concluded there was plenty of historical data showing the original lab result for the August 2018 sample of 92.8 was an anomaly. Also; in the attached file is a copy of the comments submitted with version 4.0 of our August 2018 eDMR. We believe that PERCS Unit Supervisor Deborah Gore and permit writer Theresa Rodriguez were correct and the original sample result of 92.8 was indeed an anomaly based on the historical data and therefore should have been considered invalid. Based on the information provided here and in the attached file we request the LLHG 12 ng/I annual limit be removed from the final permit. Upstream and Downstream DO, Temp., and Conductivity. Since the instream sampling is not required under the federal program nor by any other State the we are aware of and the City has been doing this monitoring for years we don't feel that it is necessary to continue it in the new permit. Therefore, we request that this requirement be removed from the final permit. Chronic Toxicity. The Roxboro WWTP passed 17 of 17 Chronic Toxicity and all four second species WET test during the last permit cycle, based on these results we request that this monitoring requirement be removed from the final permit. Thank you for taking the time to consider the above requests, we look forward to your assistance in continuing to protect our local environment. Sincerely, Allen Brooks Lockhart City Manager City of Roxboro "mum. Viueea ...... 6 HE: iErterrmg Fbeb" V%rVM lnw L&VW M0rawy ••,�.sl•.. Odober 2. 2018 09.03 AM t- Derek CloyFon • :..,a, . :. SrnM, nervy :. C e . Tammy Wprran i ....:. Cryitel SIfOt�retl Vs:._... :. - -- - . Andrew Oakley Derek — Because permittees are required to report all monitoring data from samples collected from the effluent, you should revise the eDMR to include the additional monitoring data, add a comment to the eDMR noting your concerns with the data result(s) and attach a copy of your email to the signed eDMR (2 copies) you submit to Central Files. Your comments and attachment, as included on the eDMR, will be part of the final record for the monitoring report. If you have additional questions, please feel free to contact me. Vanessa I— Manuel Environmental Program consultant Division of water Resources — Raleigh Regional Office Department of Environmental Quality 919 791-4255 office vanesm snug-4> ckmggy Physical: 380D Barrett Drive. Raleigh, NC 27609 Making: 1628 Mail Service Center, Raleigh. NC 27689-1628 =i tc7e: r' �'�5,►ivP?:J '?'�:c !G &�rc!'�•cr^ :re'S is?:�`C'S� `F 5i1:'.'c','.r ! � �j'r,', From: Derek Clayton <dciayton@eltyofroxbora.eom> Sent: Tuesday, October 02, 2018 7:26 AM To: Manuel, Vanessa <vanessa-manuel@nedenrgov>; Smith, Danny <dannysmith@nedenrgav> CC: Tommy Warren <twarren@cityofroxboro.eom>; Crystal Shotwell <eshotwell@cFtyofroxboro_com>; Andrew Oakley <aoakley@cityofroxboro.eom> Subject: (External] Roxboro WWTP Low Level Mercury Good morning Vanessa and Danny, On 9/20/181 had a phone conversation with Danny concerning bath influent and effluent low ;MM Hg samples that were taken in mid August. I folbwed up the phone CM with an email on the saute day. As a result we subrrritbed our August 2018 edam without those resuU iurowi V that once we did get then we wouid kxk de therm in a v+tvsion 2.0 edmc Due to uVoing lab e**xrient issues our convnerial Lab (Mmitech Inc.) was unable to analyze the samples so they shed dram to Pam Analytical. I received the results of these samples via email on 9/27118 while on vacation and forwarded the results to oar Lab Supervisor (crystal Shotvveli) asiclrrg her to Check with our commercial lab because the effluent rwere 3OX highs than average. Please review the lfoiiowirg as to why we feel tie results are not valid. L Wp were tali that we were not the only munkipality that received msuit5 way higher than nonml an samples that Mertbwh Inc— had forwarded to trace Analytical during the same tkne frame. 2. Field U3nks higher than norms. 3. Raxboro low Lewd Hq pram tirsbory..1012 am. 1.67 ng/l, 2013 avg. 2.13 ng/l, 2014 avg. 371 n0/4 2015 avg. 3.16 rrg/& Ml5 mq. 5i.4tZ nalk 2017 avg. 3.71 r9/4 3/4/1tl...Lti2 ng/L The 2012 - 3/2018 average dritiat mercury for our facility Is 3A7 ng/t and the maximum for the same period was 10.9 nq/l so when I saw an effluent low *-,d Hg result from 8/13/18 at US ng/1 I was and still am very d6eitkai. An influent Sample v+ras tahm on the same date and It was repod W at 42.3 nq/t Based an this infq radon I would Bice to brow how NOOM would like me to use Owse resins. Strould I report them in a version 2 0 edw as we had planned and attach a dopy of this email? Or is these somethlrg else we shoukl do? Our Lab Supervisor / PT C'Qovdk&*or will also be consu" with her HCDENR Pretrwitrz t CWAaCts to get guidance on using or not using this effluent result in our Pretreatment LTMP. We oonlaCtBd Pace labs yesterday and asired if our 8/13/18 samples were still there and informed than OWK we would Glee bo halve them bade if they are. W fe sti8 yr king to ftncl out v 4WW lhay are or noL We also have anadw sea of Influent and EffhxN t low fr vel ffwr ury samples taken on 9/11/18 that weir sent to Mew frtc.. These samples have been shipped to Summit labs in Ohio fur analysis. I lode forward to your nesporue eonceft this matter and if you treed additional mformation please don't hesbte to 00. Derek Clayton W WTP Suet City of ftoodxuo 336 999 8232 From: Crystat Shotvaa crbo►4es0caycrroxboro cosh Subject: Find: [Etdertmq Low Lmd HD for August LTM Date. October 25, 2018 at 855 AM To: Derek Ctayfon eldaytonOcityofroxboro.com Begin forwarded message_ Fion "Gore, Deborah' <detwrah.9ore4nW6nr.vwv_> Subject: RE: [External] Low Level Hg for August LTM Dale: October 26. 201 Bat 8.06:35 AM EDT Tw Crystal ShnotweN <r�,pyves 0y9frorl2rc.com>, "Hassan, Monti' <monjl.hassongncdenr.agy> CC:'2rharhg, Chang" <oheng.zhana�na�lenr.guv>, 'Manuel, Vanessa' <vaneSSa.man{t�l;;ncders.g5�v_> Cgood Morning, As faf as using the data in the HWA t would allow the use of the second value. 1 t.0 ugA, based on historical data. Now as to what to report on the DMA... I m not sure. There is no limit for mercury, but the rambars are used in the APA. Teresa Rodriguez just issued the permit so I talked to her about how they use the numbers and she said that the permit would probably decide the sarne as PERCS would for the HWA_ Plenty of historical data showrirN that the 928 Is an anomaly. WE she didn't reatry know the a ewer to what to put on the DMR. It possible I would put both numbers In the Cell and explain on the batik 111 192.81. But 1 doubt the system will allow that So then, my recommendation is that Roxboro report the average on the 0 MR with an explanation and bath values on the back I have copied the RRO to see if they have an alternate suggestion since they are the ones who really review the data and take the action. Delwrah Gore PERCS Unit Supervisor Division of Water Resources Department of Environmental Quality 919-707-3624 ofriee 979-807-6489 tact Qebolah, oorg 2 n%len r. goy 1617 Mait Service Center Raleigh, NC 27699-1617 Email correspondence to and from this address Is subject to the North Carolina Public Records Law and may be disdosed to third parties. -----Onginel Message ---- From: Crystal Shotwell ecrboww0dtyofroxboro.corn> Sent: Thursday, October 25, 2018129 PM To: Hassan, Alonli -anofW hessanQncdenr.gov> Cc: Gore, Deborah <debor;ah.gor"noJw.gov> Subod: "ema►j Low Level Hg for August LTM CAUTION- External email. Do not dick links or open attachments w t w verified. Send all suspicious email as an of ec hmert to Report Sporn <mmfto:report.sparn 9nc_gov> Good afternoon Monti. l orAected my LTM samples in August and shgpW them to Mertech to have thrarn analyzed. They were hawM iesuvs with their Low Level fig madxre and were not able to run our samples. Without d*ck69 with us, they srxpped our samples to Pace Arnaiytiaed and had tern to analyze tha samples and we received a 92.8 ng& on our effluent sample. yft Wnnv +atety knew this ooutd riot be right and argued this with Meritech and Pace. Pecs stood by It, So me had MarteGh got our sample track from Pace and shge it to Summit Labs and have them analyze A. Summit analyzed tt and the result vets 11.0 ngA_, which is still higher than rnor 4 but more believabio than the first. My question to you is, can I throw, out that first number and use 11.0 ng& or do I have to average the two numbers Would this be considered a split sample? Crystal Shotwak Pretreatment Coordktazor/lAboratory Supervisor City of Roxboro W WTP M599-8232 MPM PERMIT NO.: Nt^_M1024 PERMIT VERSION_ 4.0 PERMIT STATUE Expeed FACILITY NAME: Roxbum WWW CLAM: WW4. COUNTY: Pcmn OWNER NAME City of Roxboro ORe. Daeit L m o" ORC CERT NUMWAO 926/ GRAD& WWA ORCIIAS CHANCM No `— eDMIR PERIOD- 09,201 /(AMSa 2018) VERS Mt 4.0 STATU& huaesnad Rep" i hog ph= ommm. m .rm Dom smith of NcDENit on 9awl a am kaowcd dQpwFthvwcTwldmd"t were ' two ww %ve1 ISS..Pkfbf calm, wdEMLFmd. Theta one am NPDES pamit mgmmd but part of otr Ifcat tams LmS roar ka� PWL Our mmmateid kb had as t uiysrertt haste ant had ro 2md the e5 to ara,ate. � tar eea.ee of this and me on .awios sort wedc tsid !Dodd tnd submit vesson I.a.t�ih tivs „ale. A sccard odor {mgor, 2.0} rill be strb.rined with the otam aroeired_ Vet3iw 2.0 Addad low k 4 jS rc $u)% for 1dbCW sari %lliamt Corttroeoe. s io no belkne Ae ddomm tam k rd its tesdt in version 20 is vW0. E! n we att■chn"3* nrcludad w+dt ortpits ttal went arrrised a2 DC Vasioa 3 a lbe EEk"'I litg taawfie (oat !_*i atnpk}was reurered tlr m dre fiM wm r=CW lab who fcPN d de rmAl WX hetttpt tho lre hislomW ar& fa on kai a Olt W and at ow request s iMW the our* go secterd iab who a+dyar+c! it VW rttgocaad i 1.0 MI. Our P dmftwA Coordwuw I lAb Sttporisor cxu&d the wale PERa Unit and Deborah Gore swd in tsgpae tti ME rMluld be aiiowed b we the samod whc bsaod an at wwwo cf himtwiai der tlrtrwt_Mth n a a on am naly Sic alto nikcd k Taw RadrV= (peas rsiars} toad site acid tlrt they rrutrid decide ttx mm as FERCS fewAso amched) Havre rs err RRO contact Vwcm Maori has iralrrdeed toe to fVw al tbt; so bolt fire influa+t sad E kwa I sw(Vie rcw& Gust all Yl II kreltrded irl this vrlaiae 3.0 we anacwes etf tk two lab nm2lb an the am saopki Gam V 13/18 1 an TE!!� do "Isu at ._.... _ svearaeaors 1.4 as irntrrcicd bat F oae� Npn rvilh VER.CS Ow baW aw accost of hiwo and din mmiahk to neilha trio 42.E af11 or the S 19 ncA the staw traoum of agruy in tarciilwi*tasit13111 DC ttwyj9Vasim4.aa&wrridoelrt L41ft%a1otieckrdodin PmTm wraam DC Roxboro WWTP Fact Sheet Addendum NCO021024 Comments to the draft permit NC0021024, which was public noticed for 30-day comment period on 5/25/2023, were provided by the City of Roxboro with several requests. No comments were received from any other party. Individual comments by the City and Division responses (in blue) are provided below. 1. Change in Permittee Contact a. Mr. Kenneth Griffin is the new City Public Services Director. Response: requires completion of Permit Name/Ownership form, received on 8/15/2023; updated contact noted; will address in future letters. 2. Supplement to Permit Cover Sheet (page 2 of 11) a. Add 1.5 sludge drying beds (sludge dewatering facility utilized one of these beds and the two new aerobic digestors used % of the other). Response: added as requested. 3. PFAS Monitoring a. The City requests to be notified when the USEPA publishes 40 CFR part 136 Final PFAS Method for wastewater in the Federal Register in order to meet delayed monitoring requirement. Response: comment noted. 4. Conductivity a. The City requests reduction of monitoring frequency to weekly based on slight increase in downstream concentrations Response: monitoring frequency reduced to weekly as requested to better match instream monitoring frequency. 5. Ammonia a. The City requests to reinstate and extend the compliance schedule through March 2024. Response: Ammonia data were evaluated from 12/1/2022, when the compliance schedule ended, through May 2023 and found no exceedences of either the monthly average or weekly average limits, demonstrating compliance (see figure below). Effluent Ammonia W k Avg ■ Mo Avg WA Limit — — MA Limit 6.0 5.0 4.0 J n� 3.0 - 2.0 1.0 ■00 7 — ■ 0.0 61�' IN Based on this review, extension of the compliance schedule is not needed and will not be reinstated. b. The City objects to the proposed Ammonia limits and propose alternate limits be developed based on EPA's 2013 criteria with stream -specific pH and temperature data, set at the upper 75th percentile values. Response: a recalculation was made for site - specific ammonia limit development using available effluent and upstream data and Roxboro WWTP Fact Sheet Addendum NCO021024 applying default values where data are not available. Available data were obtained from submitted DMRs from August 2018 — February 2023. For those parameters where data are available, the 90th percentile was used, following recommendations in the EPA Technical Support Document (EPA 1991, page 18) to provide adequate protection against chronic toxicity stream impacts. The resulting inputs are as follows: Parameter Summer Winter Effluent Temperature, °C (90th percentile) 25.2 16.6 Effluent pH, SU (90th percentile) 7.3 7.1 Upstream Temperature, °C (90th percentile) 24.07 13.7 Upstream pH, SU (default) 6.8 7.5 Upstream Ammonia, mg/L (default) 1.16 2.25 Calculating these inputs with the facility design flow of 5.0 MGD and the receiving stream flows of 7Q10 = 0.0 cfs summer and winter, and applying a 2.5 X multiplier to the chronic allowable concentration (i.e., monthly average) to obtain an acute allowable concentration (i.e., weekly average) resulted in the following ammonia limits: Monthly Average Weekly Average Summer 1.2 2.9 Winter 2.3 5.6 which are comparable to the current limits: Monthly Average Weekly Average Summer 1.0 3.0 Winter 1.8 5.4 Furthermore, as stated in the response to Comment 5 above, the facility is consistently meeting compliance with the current limits. Because the differences between the site - specific and current limits are negligible and the facility's ability to comply with current limits, no changes were made to the ammonia limits. 6. Copper a. The City requests that the RPA be run using effluent data beginning 1/1/2021 as older data resulted in the proposed limits. Response: Considering the data are valid and there is a decrease in concentrations beginning 1/1/2022, a footnote will be added to the permit effluent requirements sheet stating that the Permittee may request a re- evaluation of copper limits after 24 months of sampling for potential monitoring frequency from monthly to quarterly. 7. Mercury a. The City requests removal of the annual limit as it is based on a single high value of 51.9 ng/L in 2018, which was previously determined to be an anomaly and thus considered invalid. Response: The mercury datum in question is found to be over 4.5 yrs old. The evaluation was rerun using data not older than 4.5 yrs (i.e., from 11/30/2018 to present), resulting in no limits required. The limit identified in the draft fact sheet was not added to the permit; therefore, no changes are made to the permit. Roxboro WWTP Fact Sheet Addendum NC0021024 8. Instream Monitoring a. The City requests removal of instream monitoring for DO, Temperature and Conductivity. Response: instream monitoring requirements for the above parameters are based on rule 15A NCAC 02B .0508, and thus will remain in the permit. 9. Chronic Toxicity a. The City requests removal of Chronic Toxicity monitoring, based on all tests passing. Response: chronic toxicity is a necessary screening tool of water quality, and is required by rule 15A NCAC 02B .0508; it will remain in the permit. Based on the removal of the Mercury annual limit, which represents a relaxion in permit requirements, the permit will be sent to a second Public Notice, during which the Permittee may submit additional comments.