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HomeMy WebLinkAboutNC0058815_Renewal (Application)_20230828 (2)ROY COOPER Governor ELIZABETH S. BISER Secretary RICHARD E. ROGERS, JR. Director Angela Morrow, Director Hope Valley Inc PO Box 467 Dobson, NC 27017 Subject: Permit Renewal Application No. NCO058815 Hope Valley WWTP Surry County Dear Permittee: NORTH CAROLINA Environmental Quality August 28, 2023 The Water Quality Permitting Section acknowledges the August 28, 2023 receipt of your permit renewal application and supporting documentation. Your application will be assigned to a permit writer within the Section's NPDES WW permitting branch. Per G.S. 150E-3 your current permit does not expire until permit decision on the application is made. Continuation of the current permit is contingent on timely and sufficient application for renewal of the current permit. The permit writer will contact you if additional information is required to complete your permit renewal. Please respond in a timely manner to requests for additional information necessary to allow a complete review of the application and renewal of the permit. Information regarding the status of your renewal application can be found online using the Department of Environmental Quality's Environmental Application Tracker at: https•//dgg nc govlpermits-regulations/permit-quidance/environmental-application-tracker If you have any additional questions about the permit, please contact the primary reviewer of the application using the links available within the Application Tracker. ec: WQPS Laserfiche File w/application Sincerely, An� Cynthia Demery Administrative Assistant Water Quality Permitting Section QE North Carolina Department of Environmental Quality I Division of Water Resources Winston-Salem Regional office 1 450 West Hares MRI Road State 300 1 Winston-Salem. North Carolina 27105 336.776.9800 NPDES Permit Number Facility Name Modified Application Form 2A NCO058815 Hope Valley, Inc. Modified March 2021 m NC Deparbnent of Envim ental Quality - Application for NPDES Permit to Discharge Wastewater :F0rm MINOR SEWAGE FACILITIES (Before compWV this form. please read the Instruction. Failure to follow DES the instrudlons gM result in denial of the SECTION 1. BASIC APPLICATION INFORMATION FOR ALL APPLICANTS (40 CFR 122.21(j)(1) and (9)) Facility name 1.1 Hope Valley, Inc. Mailing address (street or P.O. box) PO Box 467 City or town State ZIP code o Dobson NC 27017 € Contact name (first and last) Title Phone number Email address w Angie Morrow Director (336) 386-8511 amorrow@hopevalleytreatme c Location address (street, route number, or other specific identifier) ❑ Same as mailing address 105 County Home Road U. City or town State ZIP code Dobson NC 27017 1.2 Is this application for a facility that has yet to commence discharge? ❑ Yes + See instructions on data submission 0 No requirements for new dischargers. 1.3 Is applicant different from entity listed under Item 1.1 above? ❑ Yes ❑ No SKIP to Item 1.4. Applicant name Applicant address (street or P.O. box) 0 eo oCity State ZIP or town code c C cc Contact name (first and last) Title Phone number Email address a a a 1.4 Is the applicant the facility's owner, operator, or both? (Check only one response.) 21 Owner ❑ Operator ❑ Both 1.5 To which entity should the NPDES permitting authority send correspondence? (Check only one response.) ❑ Facility ❑ Applicant Facility and applicant (they are one and the same) 1.6 Indicate below any existing environmental permits. (Check all that apply and print or type the corresponding permit number for each. € Existing Environmental Permits a ❑ NPDES (discharges to surface ❑ RCRA (hazardous waste) ❑ UIC (underground injection water) control) E NCO058815 ❑ PSD (air emissions) ❑ Nonattainment program (CAA) ❑ NESHAPs (CAA) c w M y ❑ Ocean dumping (MPRSA) ❑ Dredge or fill (CWA Section ❑ Other (specify) w 404) Page 1 NPDES Permit Number Facility Name -1 Modified Application Form 2A NC0058815 F Hope Valley, Inc. Modified March 2021 1.7 Provide the collections stem information requested below for the treatment works. Municipality Population Collection System Type Status Served Served indicatepercentage)Ownership None Varies (est. 20-30) 100 % separate sanitary sewer El Own ❑ Maintain % combined storm and sanitary sewer ❑ Own ❑ Maintain ❑ Unknown ❑ Own ❑ Maintain U) % separate sanitary sewer ❑ Own ❑ Maintain ° % combined storm and sanitary sewer ❑ Own ❑ Maintain ❑ Unknown ❑ Own ❑ Maintain a % separate sanitary sewer ❑ Own ❑ Maintain % combined storm and sanitary sewer ❑ Own ❑ Maintain E ❑ Unknown ❑ Own ❑ Maintain ;; % separate sanitary sewer ❑ Own ❑ Maintain % combined storm and sanitary sewer ❑ Own ❑ Maintain rn ❑ Unknown ❑ Own ❑ Maintain Total Varies (est.20-30) Population 0 Served Separate Sanitary Sewer System Combined Storm and Sanitary Sewer Total percentage of each type of 100 /q o /o 0 sewer line in miles 1.8 Is the treatment works located in Indian Country? o' ❑ Yes 0 No U 1.9 Does the facility discharge to a receiving water that flows through Indian Country? ❑ Yes No 1.10 Provide design and actual flow rates in the designated spaces. Design Flow Rate 0.004 mgd Annual Average Flow Rates Actual N Two Years Ago Last Year This Year c c 0.00195 mgd 0.0023 mgd 0.0022 mgd Maximum Daily Flow Rates Actual Two Years Ago Last Year This Year 0.0023 mgd 0.0024 mgd 0.0027 mgd 1.11 Provide the total number of effluent discharge points to waters of the State of North Carolina by type. Total Number of Effluent Discharge Points by Type T Combined Sewer.- Constructed tm I Treated Effluent Untreated Effluent Overflows Bypasses Emergency s Overflows y 0 1 0 0 0 0 Page 2 NPDES Permit Number Facility Name Modified Application Form 2A NCO058815 Hope Valley, Inc. Modified March 2021 Outfalls Other Than to Waters of the State of North Carolina 1.12 Does the POTW discharge wastewater to basins, ponds, or other surface impoundments that do not have outlets for discharge to waters of the State of North Carolina? ❑ Yes ❑✓ No + SKIP to Item 1.14. 1.13 Provide the location of each surface impoundment and associated discharge information in the table below. Surface Im oundment Location and Dischar a Data Average Daily Volume Continuous or Intermittent Location Discharged to Surface (check one) Impoundment_ ❑ Continuous gpd ❑ Intermittent ❑ Continuous gpd ❑ Intermittent ❑ Continuous gpd H ❑ Intermittent s 1.14 Is wastewater applied to land? ❑ Yes ❑✓ No 4 SKIP to Item 1.16. c 1.15 Provide the land application site and discharge data requested below. Land Application Site and Discharge Data o 0 Average Daily Volume Continuous or Location Size Applied Intermittent check one acres d gpd ❑ Continuous N 0 ❑ Intermittent ❑ Continuous Y acres gpd ❑ Intermittent acres d gpd ❑ Continuous ❑ Intermittent 1.16 Is effluent transported to another facility for treatment prior to discharge? o ElYes © No 4 SKIP to Item 1.21. 1.17 Describe the means by which the effluent is transported (e.g., tank truck, pipe). 1.18 Is the effluent transported by a party other than the applicant? ❑ Yes ❑ No -+ SKIP to Item 1.20. 1.19 Provide information on the transporter below. Trans orter Data Entity name Mailing address (street or P.O. box) City or town State ZIP code Contact name (first and last) Title Phone number Email address Page 3 NPDES Permit Number Facility Name -1 Modified Application Form 2A NC0058815 F Hope Valley, Inc. Modified March 2021 1.20 In the table below, indicate the name, address, contact information, NPDES number, and average daily flow rate of the receiving facility. ReceivinQ F cilitv Data Facility name Mailing address (street or P.O. box) d City or town State ZIP code 0 U U) Contact name (first and last) Title 0 d Phone number Email address o NPDES number of receiving facility (if any) ❑ None Average daily flow rate mgd a 1.21 Is the wastewater disposed of in a manner other than those already mentioned in Items 1.14 through 1.21 that do 0 not have outlets to waters of the State of North Carolina (e.g., underground percolation, underground injection)? rn W ❑ Yes 0 No + SKIP to Item 1.23. 0 1.22 Provide information in the table below on these other disposal methods. Information on Other Disposal Methods o Disposal Location of Size of Annual Average Continuous or Intermittent Method Disposal Site Disposal Site Daily Discharge (check one) Description Volume acres gpd ❑ Continuous ❑ Intermittent acres gpd ❑ Continuous ❑ Intermittent acres gpd ❑ Continuous ❑ Intermittent 1.23 Do you intend to request or renew one or more of the variances authorized at 40 CFR 122.21(n)? (Check all that apply. Consult with your NPDES permitting authority to determine what information needs to be submitted and when.) ❑ Discharges into marine waters (CWA ❑ Water quality related effluent limitation (CWA Section Er Section 301(h)) 302(b)(2)) ❑✓ Not applicable 1.24 Are any operational or maintenance aspects (related to wastewater treatment and effluent quality) of the treatment works the responsibility of a contractor? ❑✓ Yes ❑ No +SKIP to Section 2. 1.25 Provide location and contact information for each contractor in addition to a description of the contractor's operational and maintenance responsibilities. Contractor Information Contractor 1 Contractor 2 Contractor 3 Contractor name Martin Semones 0 (company name E Mailing address c street or P.O. box)130 Square St 0 City, state, and ZIP Mt. Airy, NC 27030 R code vICo� tact name (first and as Martin Semones Phone number (336) 755-7845 Email address msemonesl@triad.rr.com Operational and Maintain that chlorine & maintenance dechor tablets are kept in responsibilities of system and perform contractor , 4 r Page 4 NPDES Permit Number Facility Name Modified Application Form 2A NCO058815 Hope Valley, Inc. Modified March 2021 SECTION1 1 • ' 1 o Outfalls to Waters of the Stale of North Carolina 2.1 Does the treatment works have a design flow greater than or equal to 0.1 mgd? o ❑ Yes ❑ No 4 SKIP to Section 3. 0 2.2 Provide the treatment works' current average daily volume of inflow Average Dailly Volume of Inflow and Infiltration and infiltration. gpd Indicate the steps the facility is taking to minimize inflow and infiltration. -a 3 0 c 2.3 Have you attached a topographic map to this application that contains all the required information? (See instructions for CL specific requirements.) C og ❑ Yes ❑ No Fo 2.4 Have you attached a process flow diagram or schematic to this application that contains all the required information? c:° (See instructions for specific requirements.) a, b o ❑ Yes ❑ No 2.5 Are improvements to the facility scheduled? ❑ Yes ❑ No + SKIP to Section 3. Briefly list and describe the scheduled improvements. 0 W d E d a. 2. E 0 0 (n d 3. 4. a 2.6 Provide scheduled or actual dates of completion for improvements. Scheduled or Actual Dates of Completion for Im rovements E a) Scheduled Affected Begin End Begin Attainment of > o Improvement Outfalls (list o Construction Construction Discharge Operational Level � (from above) number number) (MM/DDIYYYY) (MM/DD/YYYY) (MM/DD/YYYY) MM/DDIYYYY d v d s 2. 3. 4. 2.7 Have appropriate permits/clearances concerning other federal/state requirements been obtained? Briefly explain your response. ❑ Yes ❑ No ❑ None required or applicable Explanation: Page 5 NPDES Permit Number Facility Name Modified Application Form 2A NCO058815 Hope Valley, Inc. Modified March 2021 SECTION 3. INFORMATION ON EFFLUENT DISCHARGES (40 CFR 122.216)(3) to (5)) 3.1 Provide the following information for each outfall. (Attach additional sheets if you have more than three outfalls.) Outfall Number 001 Outfall Number Outfall Number State NC H m County Surry O 0 City or town Dobson Distance from shore N/A ft. ft. ft. 2- Depth below surface N/A ft. 0 Average daily flow rate 0.0021 mgd mgd mgd Latitude 3e 2`; 06" " Longitude 86 42 41r " 3.2 Do any of the outfalls described under Item 3.1 have seasonal or periodic discharges? o ❑ Yes ❑ No + SKIP to Item 3.4. d cc 3.3 If so, provide the following information for each applicable outfall. N Outfall Number Outfall Number Outfall Number 0 Number of times per year C L discharge occurs ri Average duration of each 0 discharge (specify units o Average flow of each mgd mgd an g d W discharge � , Months in which discharge occurs 3.4 Are any of the outfalls listed under Item 3.1 equipped with a diffuser? ❑ Yes ❑✓ No-* SKIP to Item 3.6. 3.5 Briefly describe the diffuser type at each applicable outfall. CL Outfall Number Outfall Number Outfall Number 0 ui 3 6 Does the treatment works discharge or plan to discharge wastewater to waters of the State of North Carolina from d -i one or more discharge points? 3 y ❑ Yes ❑ No 4SKI P to Section 6. Page 6 NPDES Permit Number Facility Name Modified Application Form 2A NCO058815 Hope Valley, Inc. Modified March 2021 3.7 Provide the receiving water and related information if known for each outfall. Outfall Number Outfall Number Outfall Number Receiving water name Fisher River Name of watershed, river, 0 or stream system Fisher River U.S. Soil Conservation C Service 14-digit watershed 030401010702 c code Name of state managementlriver basin Yadkin Pee Dee L °= 3 U.S. Geological Survey 8-digit hydrologic 03040101 rY cataloging unit code Critical low flow (acute) unknown cfs cfs cfs Critical low flow (chronic) unknown cfs cfs cfs Total hardness at critical mg/L of mg/L of mg/L of low flow unknown CaCO3 CaCO3 CaCO3 3.8 Provide the following information describing the treatment pr vided for discharges from each outfall. Outfall Number 001 Outfall Number Outfall Number Highest Level of 0 Primary ❑ Primary ❑ Primary Treatment (check all that ❑ Equivalent to ❑ Equivalent to ❑ Equivalent to apply per outfall) secondary secondary secondary ❑ Secondary ❑ Secondary ❑ Secondary ❑ Advanced ❑ Advanced ❑ Advanced ❑ Other (specify) ❑ Other (specify) ❑ Other (specify) c 0 c. Design Removal Rates by Outfall d BODs or CBOD5 % % % c m E CU TSS % % % f- 0 Not applicable ❑ Not applicable ❑ Not applicable Phosphorus % % % 0 Not applicable ❑ Not applicable ❑ Not applicable Nitrogen % % % Other (specify) 0 Not applicable ❑ Not applicable ❑ Not applicable Page 7 NPDES Permit Number Facility Name -1 Modified Application Form 2A NC0058815 r Hope Valley, Inc. Modified March 2021 3.9 Describe the type of disinfection used for the effluent from each outfall in the table below. If disinfection varies by season, describe below. d c 0 c Outfall Number 001 Outfall Number Outfall Number 0 Disinfection type Chlorine c Seasons used All d 8 LDcc Dechlorination used? ❑ Not applicable ❑ Not applicable ❑ Not applicable ❑✓ Yes ❑ Yes ❑ Yes ❑ No ❑ No ❑ No 3.10 Have you completed monitoring for all Table A parameters and attached the results to the application package? 21 Yes ❑ No 3.11 Have you conducted any WET tests during the 4.5 years prior to the date of the application on any of the facility's discharges or on any receiving water near the discharge points? ❑ Yes 0 No 4 SKIP to Item 3.13. 3.12 Indicate the number of acute and chronic WET tests conducted since the last permit reissuance of the facility's discharges by outfall number or of the receiving water near the discharge points. Outfall Number Outfall Number Outfall Number Acute Chronic Acute Chronic Acute Chronic �o G Number of tests of discharge Im water Number of tests of receiving water d W 3.14 Does the POTW use chlorine for disinfection, use chlorine elsewhere in the treatment process, or otherwise have reasonable potential to discharge chlorine in its effluent? ✓❑ Yes 4 Complete Table B, including chlorine. ❑ No -* Complete Table B, omitting chlorine. 3.15 Have you completed monitoring for all applicable Table B pollutants and attached the results to this application package? ❑ Yes 0 No Have you completed monitoring for all applicable Table D pollutants required by your NPDES permitting authority and 3.18 attached the results to this application package? ❑ Yes 21 No additional sampling required by NPDES permitting authority. Page 8 NPDES Permit Number Facility Name Modified Application Form 2A NCO058815 Hope Valley, Inc. Modified March 2021 3.19 Has the POTW conducted either (1) minimum of four quarterly WET tests for one year preceding this permit application or (2) at least four annual WET tests in the past 4.5 years? ❑ Yes ❑ No + Complete tests and Table E and SKIP to Item 3.26. 3.20 Have you previously submitted the results of the above tests to your NPDES permitting authority? ❑ Yes ❑ No + Provide results in Table E and SKIP to Item 3.26. 3.21 Indicate the dates the data were submitted to your NPDES permitting authority and provide a summary of the results. Date(s) Submitted Summary of Results MWDD 7j c_ 0 3.22 Regardless of how you provided your WET testing data to the NPDES permitting authority, did any of the tests result in o toxicity? c Y ❑ Yes ❑ No SKIP to Item 3.26. 3.23 Describe the cause(s) of the toxicity: c m 3 W 3.24 Has the treatment works conducted a toxicity reduction evaluation? ❑ Yes ❑ No + SKIP to Item 3.26. 3.25 Provide details of any toxicity reduction evaluations conducted. 3.26 Have you completed Table E for all applicable outfalls and attached the results to the application package? ❑ Yes © Not applicable because previously submitted imim information to the NPDES permitting authority. Page 9 NPDES Permit Number Facility Name Modred Application Form 2A NCO058815 Hope Valley, Inc. Modified March 2021 SECTION • 1 and • 6.1 In Column 1 below, mark the sections of Form 2A that you have completed and are submitting with your application. For each section, specify in Column 2 any attachments that you are enclosing to alert the permitting authority. Note that not all applicants are required to provide attachments. Column 1 Column 2 Section 1: Basic Application ❑ wl variance request(s) ❑ w/ additional attachments Information for All Applicants ❑ Section 2: Additional wl topographic map ❑ wl process flow diagram Information ❑ w/ additional attachments © w/ Table A ❑ w/ Table D ❑ Section 3: Information on ❑ wl Table B ❑ w/ additional attachments Effluent Discharges E ❑ wl Table C w3 iG Section 4: Not Applicable c 0 Section 5: Not Applicable d c� a Section 6: Checklist and ❑ 0 w/attachments Certification Statement Y 6.2 Certification Statement 1 certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. Name (print or type first and last name) Official title Angela Morrow Director S nature Date signed 08/24/2023 Page 10 NPOES Permit Number Facility Name Outrall Number NCO058815 Hope Valley, Inc. Modified Application Form 2A Modified March 2021 Pollutant Maximum Daily Discharge Average Daily Discharge Analytical Number of Value Units Samples Method' ML or MDL (include units) Value Units Biochemical oxygen demand o BODs or ❑ CBOD5 (report one 43.4 mg/1 13.8 mg/1 23 SM521OB-2016 OML El MDL Fecal coliform 2420 MPN/100ML Geome 2.05 Geometric Mean 24 Colilert-18 ❑ ML ❑ MDL Design flow rate 0.0027 MGD 0.0022 MGD 12 months pH (minimum) 6.8 Standard Units pH (maximum) 7.1 Standard Units Temperature (winter) 23 •C 15.9 'C 30 Temperature (summer) 30 °C 25.2 T 29 Total suspended solids (TSS) 8.9 mg/I 4.34 mg/I 24 SM2540D-2015 0 ML ❑ MDL 1 Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I, subchapter N or 0. See instructions and 40 CFR 122.21(e)(3). Page 11 SCALE 1:24000 etude: 36'25'06" Sub -Basin: 03-07-02 Longitude: 80°42'48 •• fund ;a: B16MV Strcnn) Class: WS-II CA Reccivine Strcam: Fisher Rivcr Permitted Flow: 0.004 MGD Facility Location tc� , Hope Valley, Inc. NC0058815 Dobson Facility Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 July 26, 2023 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Inc Pace Project No.: 92676977 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on July 12, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones PCCRF��� �eOttAro REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 15 Project: Hope Valley Inc Pace Project No.: 92676977 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 15 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley Inc 92676977 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92676977001 Outfall 001 SM 2540D-2015 VLG 1 PASI-E SM 521OB-2016 LRB 1 PASI-E Colilert-18 VLG 1 PASI-E TKN+NO3+NO2 Calculation KDF1 1 PASI-A EPA 350.1 Rev 2.0 1993 EGC 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 KDF1 1 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A PASI-A = Pace Analytical Services -Asheville PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 15 ANALYTICAL RESULTS Project: Hope Valley Inc Pace Project No.: 92676977 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 bample: Uuttall 001 Lab ID: 92676977001 Collected: 07/12/23 13:00 Received: 07/12/23 15:18 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 254OD-2015 Pace Analytical Services - Eden Total Suspended Solids ND mg/L 2.5 1 07/14/23 14:26 5210B BOD, 5 day EDN Analytical Method: SM 521 OB-2016 Preparation Method: SM 521 OB-2016 Pace Analytical Services - Eden BOD, 5 day 3.7 mg/L 2.0 1 07/13/23 11:34 07/18/23 09:58 R6 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms ND MPN/100ml- 1.0 1 07/12/23 18:17 07/13/23 14:10 Total Nitrogen Calculation Analytical Method: TKN+NO3+NO2 Calculation Pace Analytical Services - Asheville Total Nitrogen 42.6 mg/L 0.040 1 07/26/23 12:52 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Ammonia 41.0 mg/L 0.60 6 07/26/23 09:01 7664-41-7 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Kjeldahl, Total 42.0 mg/L 2.5 5 07/25/23 16:42 07/26/23 04:10 7727-37-9 353.2 Nitrogen, NO2/NO3 pres. Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, NO2 plus NO3 0.56 mg/L 0.040 1 07/26/23 07:40 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville Phosphorus 6.0 mg/L 0.10 2 07/24/23 18:34 07/24/23 22:56 7723-14-0 Date: 07/26/2023 12:53 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 15 QUALITY CONTROL DATA Project: Hope Valley Inc Pace Project No.: 92676977 UU hatch: 786814 Analysis Method: SM 2540D-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92676977001 METHOD BLANK: 4079251 Matrix: Water Associated Lab Samples: 92676977001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 07/14/23 14:18 LABORATORY CONTROL SAMPLE: 4079252 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 4079253 Parameter Units Total Suspended Solids mg/L Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 238 95 90-110 92676932001 Dup Result Result RPD Qualifiers 2230 2200 1 SAMPLE DUPLICATE: 4079254 92676947001 Dup Parameter Units Result Result Total Suspended Solids mg/L 905 820 RPD Qualifiers 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:53 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 15 QUALITY CONTROL DATA Project: Hope Valley Inc Pace Project No.: 92676977 UU Batch: 786484 Analysis Method: SM 521 OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210B BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92676977001 METHOD BLANK: 4077656 Associated Lab Samples: 92676977001 Parameter Units BOD, 5 day mg/L LABORATORY CONTROL SAMPLE: 4077657 Parameter Units BOD, 5 day mg/L Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 07/18/23 09:15 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 198 170 86 84.6-115 SAMPLE DUPLICATE: 4077659 92676807001 Dup Parameter Units Result Result BOD, 5 day mg/L 1180 1480 RPD Qualifiers 22 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:53 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 15 Project: Hope Valley Inc Pace Project No.: 92676977 QC Batch: 786408 QC Batch Method: Colilert-18 Associated Lab Samples: 92676977001 SAMPLE DUPLICATE: 4077377 Parameter Units Fecal Coliforms MPN/100mL QUALITY CONTROL DATA Analysis Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden 92676977001 Dup Result Result RPD Qualifiers ND ND Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:53 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 15 QUALITY CONTROL DATA Project: Hope Valley Inc Pace Project No.: 92676977 QC Batch: 788937 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92676977001 METHOD BLANK: 4089440 Associated Lab Samples: 92676977001 Parameter Units Nitrogen, Ammonia mg/L LABORATORY CONTROL SAMPLE: 4089441 Parameter Units Nitrogen, Ammonia mg/L Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.10 07/26/23 08:36 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 5 5.2 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4089442 4089443 MS MSD 92677977001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 1.2 5 5 6.3 6.3 102 102 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4089444 4089445 MS MSD 92677978001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 14.9 5 5 19.9 20.1 101 105 90-110 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:53 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 15 -- f ce, Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Inc Pace Project No.: 92676977 QC Batch: 789047 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92676977001 METHOD BLANK: 4089866 Matrix: Water Associated Lab Samples: 92676977001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Kjeldahl, Total mg/L ND 0.50 07/26/23 02:42 LABORATORY CONTROL SAMPLE: 4089867 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg/L 10 10.1 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4089868 4089869 MS MSD 92678089002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 0.91 10 10 11.9 11.5 110 106 90-110 4 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4089870 4089871 MS MSD 92678089003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 1.3 10 10 11.6 11.2 103 99 90-110 4 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:53 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 15 Project: Hope Valley Inc Pace Project No.: 92676977 wt, tsatcn: (58829 QC Batch Method: EPA 353.2 Rev 2.0 1993 Associated Lab Samples: 92676977001 METHOD BLANK: 4088736 Associated Lab Samples: 92676977001 Parameter Units Nitrogen, NO2 plus NO3 mg/L LABORATORY CONTROL SAMPLE: 4088737 Parameter Units Nitrogen, NO2 plus NO3 mg/L Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Analysis Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved Laboratory: Pace Analytical Services -Asheville Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.040 07/26/23 07:16 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 2.5 2.5 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4088738 4088739 MS MSD 92678110001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L 0.53 2.5 2.5 2.8 2.8 92 92 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4088740 4088741 MS MSD 92678126001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L 1.3 2.5 2.5 3.7 3.7 97 97 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:53 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 15 Project: Hope Valley Inc Pace Project No.: 92676977 QC Batch: 788799 QC Batch Method: EPA 365.1 Rev 2.0 1993 Associated Lab Samples: 92676977001 METHOD BLANK: 4088563 Associated Lab Samples: 92676977001 Parameter Units Phosphorus mg/L QUALITY CONTROL DATA Analysis Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.050 07/24/23 22:22 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 LABORATORY CONTROL SAMPLE: 4088564 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg/L 2.5 2.5 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4088570 4088571 MS MSD 92677342001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 5.6 2.5 2.5 7.9 8.2 90 101 90-110 3 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4088572 4088573 MS MSD 92677132001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 2.2 2.5 2.5 4.7 4.7 99 100 90-110 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:53 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 15 rice, Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Hope Valley Inc Pace Project No.: 92676977 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS R6 The RPD between valid sample dilutions exceeded 30%. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:53 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 15 twe Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Hope Valley Inc Pace Project No.: 92676977 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92676977001 Outfall 001 SM 2540D-2015 786814 92676977001 Outfall 001 SM 521OB-2016 786484 SM 521OB-2016 786777 92676977001 Outfall 001 Colilert-18 786408 Colilert-18 786409 92676977001 Outfall 001 TKN+NO3+NO2 789369 Calculation 92676977001 Outfall 001 EPA 350.1 Rev 2.0 1993 788937 92676977001 Outfall 001 EPA 351.2 Rev 2.0 1993 789047 EPA 351.2 Rev 2.0 1993 789225 92676977001 Outfall 001 EPA 353.2 Rev 2.0 1993 788829 92676977001 Outfall 001 EPA 365.1 Rev 2.0 1993 788799 EPA 365.1 Rev 2.0 1993 788881 Date: 07/26/2023 12:53 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 15 LAB USE ONLY- Affix Workorder/Login Labe[ Here or list Pace Workorder Number or MTJL Lox -in Number Here IQ# ' 92676977 ALL SHE Container Preservative I J 1 —1 " Preservative Types: (l) nitric acid, 92678977 d, (2) tG) methanol, (7) sodium bisulfate. (8) sodlrm thiosunare, toy ii Num hydroxide, (D) TSP, (U) Unpreserved, (0) Other ustomer PMieCt Name/Number: State:i 1�ovntyjCiW;F et ed: . �. / l i j CT (�Kf Phone: 3 F6-755- 7pr tc-Site/Facility ID #; g?Email: O`f J Collected By (print : Purchase Order #: DW PWS ID #: jvt q jn�, Ctuote #; DW Local on Code: Collected By (signature)• T r,-?f PaceAnalytical' Company: CHAIN -OF -CUSTODY Analytical Request Document Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevent fields Billing Information: �G. o: urnaroind Date Required: Imme late y Packed on ice: :* o it ]Yes } No ( ` Sample Disposal: Rush: Field Filtered (if applicable;: C )Dispose as appropriate ( I Return ( I Same Day [ ) Next Day Yes ( ) [ 1 Na " f` ( I Archive: i ± Ho d. [ 2 Day ( ) 3 Da s Y [ I a Day ( 1 - Day Analysis: t7 L} O L C L% (Expedite Charges Apply) t ' Matrix Codes (insert in Matrix box below): Drinking Water (DW), Ground Water. GW), Wastewater (WW) Product (P), Soli/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (81, Vapor (V), Other (OT) �f? rq V Customer Sample i0 Matrx ` Comp / Grab Collected (or Composite Start) Compos to End Res # of CI Ctns Nate Time Date Time u- Lab Profile/line: Sample.Receipt Checklist: Custody Seals Present/intact Y NA Custody Signatures Present N NA Collector'Signature Present N NA Bottles Intact N NA .Correct Bottles N NA Sufficient volume N NA Samples Received on Ice N N VOA - Headspace Acceptable Y N USDA Regulated -soil. r.au Samples in Holding Time /W..l KA Residual Chloring��reae t Y(PNA -Ci strip.; tb? Sample pH Acceptable Y NA PH Strips: r Sulfide Present Y N,G.\. Lead Acetate Strips: L�JJ LAB USE ONLY: Lab Sample N / Consents: UP-5- Fecal Ary'ilYVaQ%n -r l Tod• Customer Remarks / Special Conditions / Possible Hazards: Type of Ice Used: Wet Blue Dry None - SHORT HOLD$ PRESENT-(<72 hours): _ Y..' N,: - N/A lab Sample Temperature Info: Packing Material Used: Lab Tracking #:.I.Temp Blank Received: Y N NA Therm iD#: o O y Cooler 1 Temp Upon Receipt: -L•LOC 2. Radchem sample(s) screened (<500 cpm): Y N NA Samples received via: Cooler 1 Therm Corr, Factor:oC FEDEx UPS Clien Courier' Pace Courier Cooler 1 Corrected Temp: oC Relinquished by/Company: (Signature) Date/Time: Rec d by; Compan {Signature) Date/Time: MTJL LAB USE ONLY Comments: Q m - Q J r (iL f $3 j� (� Table#: i' Relinquished b Com any: (Si nature Acctnum: 0 q Y/ p g ) Date/Time: Received by/Co pa .( nature) Date/Tirne: Template: Relinquished by/Company: (Signature) Received by/Company:(Signature) Date/Time: PM: Trip Blank Received: Y N NA HCL McOH TSP Other Non Conformancef.0- Pape: S CD a 5 Matrix c Aj j j Hem# 3 : HP4U 125 mL Plastic Unpreserved (N/A t (Cl li _ . 1 N SP3U-25C mL Plastic Unpreserved (N/A) ' BPZU-SM mL Plastic Unpreserved (N/A) C { -I liter Plastic Unpreserved (N/A) 21 I < - SMS 12S rrtL Plastic H2SO4 (pH < 2) tCl ; n y _ �' ( W13N M rri plastic HNO3 (PH < 2) c j j BP4Z-I25 mL Plastic ZN Acetate & NaOH (>9) BP48-125 mL Piast c NaOH (pH > 12) Lf WGFU- ide-mouthed Glass jar Unpreserved v n .* i ( AG1U-2 II;erAmbeC tnpreserved (N/A) (CH A61H-1 liter Amber HO (pH < 2; j € A69U•25{1 mL Amber Unpreserved (N/A) ! i fl ! E % Z AG25 2 Iiter Amber N2SO4 (PH < 2) _.._ .� AG35 25Q m.. Amber 1-12504 (PH < 2) _.... AG3A(063A(-250 rr.L Amber NH40 N/Ai(C) �D a � j c rs p, ' � I � D69t3 4i# rn1,VOA HCl (N/A) c � { V69T-40 mL VOA Na2S W (WAi 06 V 9U-ail mL VOA Unprew Yed (N/A) t ! OG9P 40 mL VOA H3PO4 (NiAl 7 VOAK (3 viab per kit( 5635 kit (N/A) { 0 V/Gk (3 vials per kit�VP4/Gas kit M/A) j j — i e^ SP51 25 mC Sterile P aS tic (NIA - lab( SP2T•2.aQQ rr°L :t rUo P astK OVA-- tab) 1! 9P3A ZSC mL P as* c (N142).604 0.3.9.7) ' 1 Aiai?U mw Amber UnpreServetS vials {NIA} ! � VSGU20 r L Scirti lation vrats (NIA", 1 j DM-40 mL Amber Unpreserved vials (N/A) M raceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 June 27, 2023 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92673353 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on June 20, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones pCGQ r REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 r' 1aceAnalytical - www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92673353 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley 92673353 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92673353001 Outfall 001 SM 2540D-2015 MWF 1 PASI-E SM 521OB-2016 MWF 1 PASI-E Colilert-18 SRS 1 PASI-E PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 rw rraceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92673353 Sample: Outfall 001 Lab ID: 92673353001 Collected: 06/20/23 11:00 Received: 06/20/23 12:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua] 2540D Total Suspended Solids Analytical Method: SM 254OD-2015 Pace Analytical Services - Eden Total Suspended Solids 2.8 mg/L 2.5 1 06/20/23 15:59 5210B BOD, 5 day EDN Analytical Method: SM 521 OB-2016 Preparation Method: SM 521 OB-2016 Pace Analytical Services - Eden BOD, 5 day 6.6 mg/L 2.0 1 06/21/23 11:28 06/26/23 14:33 R6 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms 8.6 MPN/100ml- 1.0 1 06/20/23 15:02 06/21/23 09:27 Date: 06/27/2023 08:12 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 11 PaceAnalytical { www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92673353 QC Batch: 781771 Analysis Method: SM 254OD-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92673353001 METHOD BLANK: 4055821 Matrix: Water Associated Lab Samples: 92673353001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 06/20/23 15:57 LABORATORY CONTROL SAMPLE: 4055822 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 256 102 90-110 SAMPLE DUPLICATE: 4055823 92673417001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 34.8 19.7 56 D6 SAMPLE DUPLICATE: 4055824 92673418002 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 29.6 30.4 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/27/2023 08:12 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 11 G. �aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92673353 QC Batch: 781946 Analysis Method: SM 521OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210B BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92673353001 METHOD BLANK: 4056332 Matrix: Water Associated Lab Samples: 92673353001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg/L ND 2.0 06/26/23 13:01 LABORATORY CONTROL SAMPLE: 4056333 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day mg/L 198 174 88 84.6-115 SAMPLE DUPLICATE: 4056335 92673297002 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 217 234 8 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/27/2023 08:12 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 r0aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92673353 QC Batch: 781754 Analysis Method: Colilert-18 QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92673353001 SAMPLE DUPLICATE: 4055751 Parameter Units Fecal Coliforms MPN/100mL SAMPLE DUPLICATE: 4055752 Parameter Units Fecal Coliforms MPN/100mL 92673366001 Dup Result Result RPD Qualifiers ND ND 92673414001 Dup Result Result 2420 2420 RPD Qualifiers 0 El Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/27/2023 08:12 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 ,1041 �aceAnalyticalJo www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Hope Valley Pace Project No.: 92673353 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. El Reported value should be considered a minimum estimate since it is the maximum reportable number for this method based on the sample volume used. The true value is likely greater than the value reported. R6 The RPD between valid sample dilutions exceeded 30%. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/27/2023 08:12 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 11 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Hope Valley Pace Project No.: 92673353 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92673353001 Outfall 001 SM 254OD-2015 781771 92673353001 Outfall 001 SM 521OB-2016 781946 SM 521OB-2016 92673353001 Outfall 001 Colilert-18 781754 Colilert-18 Date: 06/27/2023 08:12 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch 782369 781756 Page 9 of 11 PaceAnalytrcal - Company: l Addr} f b Repo�TTo• w� �J Copy T : t Customer P Ject Nam -,Number: CHAIN -OF -CUSTODY Analytical Request Dricumel Chain -of -Custody is a LEGAL DOCUMENT -Complete a retevent Pelds 8i(ling Informat on: Ema'To ;,Lountty; -- ity: ' Time Zone Co,(ect'ed: A0 05el7 [ l PT [ I MT ( ) CT 4,KT Phone; 3 -78q!5 Site/Fac,i ty ID q. � ompliance Monitoring? Email: 0'7 (�.Kes j ]No Collected By (print : Purchase Order #: DW PWS ID #: le Quote #: DW Location Code: Collected By (signature); Turnaround Date Required- Immediate y Pac a on Ice: ( ) Yes ( j No Sample Disposal Rush l ( Field Filtered {if applicable}; Dispose as ap propriate ( ) Return (J Same Day j )Next Day ( J Yes [ J No ( j Archive. [ ) 2 Day ( j 3 Day [ J 4 Da Y ( ISDay I I Hold: (Expedite Charges Apply) Analysis: " Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), Product (P), Soil/Solid (SL), Oil (OL), W;pe (WP), Air (AR), Tissue ITS), Bioassay (B), Vapor (V), Other (OT) Comp / Collected (or Customer Sample ID Matrix' Grab Composite Start) Composite End Date Time Date Tlme W • USE ONLY- Affix Workorder/Login Label Here or List Pace Workorder Number or wd# a 926 f 3353 ALL SHAD Container Preservative T • • Preservative Types: (1) nitric acid, (2) sulft, 92673353 1 (6) methanol, (7) sodium b'sulfr.te, (R) -,odium thiosu fate, {9) hexane, (A) ascorbic acid, (B) ammonium sulfate, (C;-pnrrnonium hydroxide, (0) TSP, (U) Unpreserved, (0) Other F 1 � Res # of Icy V Cl Ctns CO Li. Customer Remarks / Special Conditions / Possible Hazards: Type of Ice Used: WeY Blue Dry None Packing Material Used:�r Or) Ice, I t , , Relinquished by/Company: {Signature) Relinquished by/Company: (Signature) 0 0 Relingpuished by/Company: (Signature) Radchem sample(s) screened (<500cpm): Y N NA 'Time: Received by/Company: (Signature's Date/Time: I Received by/Company: (Signature, --- —,,v— nCG pL cnecxJlst: Custody Seals Present/intact 61NA Custody Signatures Present g NA Collector Signature Present NA Bottles Intact N NA Correct Bottles NA Sufficient Volume 0 N NA Samples Received on Ice (9N NA VOA - Headspace Acceptable Y N USDA Regulated soi18 �-�;.rr Samples in Holding Time (ram NA Residual Chlorine Present Y t)NA Cl Strips: ,;i 9 qq " 'Sample pH Acceptable y N/k�ii` PH Strips: (,,��JJ Sulfide Present 24 V Lead Acetate Strips: LAB USE ONLY: Lab Sample X / Comments: SHORT HOLDS PRESENT (<72 hours) Y N N/A Lab Tracking #: v 2610299 Samples received vi FEDEX UPS Client Courier Pace Courier Darime- b MTJ_ LAB USE ONLY Table #: Date/Time: Acctnum• `emp(ate: Prelogin: gate/T me- PM. M f Lab Sample Temperature Info: Temp Blank Received Y NA Therm ID#• 1� t'C C L Cooler 1 Temp Upon Receipt: oC Cooler 1 Therm Corr. Factor: oC Cooler 1 Corrected Temp: oC Comment,, - Tr p Blank Received- Y N NA HCL McOH TSP Other Non Conformance(s): m CD m it z 3 "Cf 7 A � U i o G 0 !i! i K 0 1 v � ' i n m i t � s x r c 3 fa � v m us r A ro ! A th A 0 d A � Q �I � I `Cti a M til 3 tit d M C Lt. 6A Q IY I p � 3 � I I 0 � 0- rao � � a 2 .00. A i Matrix C Item# ZZ/VXX zz—zz BP4U-125 ml Plastic Unpreserved (N/A) (CI-) BP3U-250 ml Plastic Unpreserved (N/A) SP210•500 mL Plastic Unpreserved (N/A) SPiU-1 liter Plastic Unpreserved (N/A) SM-125 ml Plastic H25O4 (pH < 2) (Cl-) BP3N•250 mL plastic HNO3 (pH < 2) zAll BP42-125 mL Plastic 2N Acetate & NaOH (>9) BP46-125 mL Plastic NaOH (pH > 12) (Cl-) WGFU-Wide-mouthed Glass jar Unpreserved AG1U-1 liter Amber Unpreserved (NIA) (CI-) zzzzzzz AGiH-1 liter Amber HCI (pH < 2) ! I AG3U-250 mL Amber Unpreserved (N/A) (CI-) E { t AG1S-1 liter Amber H2SO4 (pH < 2) j AG35-230 mL Amber H2SO4 (pH < 2) AG3A(DG3A)-250 mL Amber NH4Cl (N/A)(CI-) OG9H-40 mL VOA HCI (N/A) 3 VG9T-40 ml. VOA Na252O3 (N/A) i I V69U-40 mi. VOA Unpreserved (N/A) DG9P-40 mL VOA H3PO4 (N/A) VOAK (3 vials per kit)-5035 kit (NJA) WGK (3 vials per kit)-VPH/Gas kit (N/A) SPST-125 mL Sterile Plastic (N/A — lab) `-- SP2T-250 mL Sterile Plastic (N/A — lab) i BP3A-250 ml. Plastic (NH2)25O4 (9.3.9.7) I j ( AGOU-100 ml Amber Unpreserved vials (N/A) I I VSGU-20 mL Scintillation vials (N/A) I DG9U-40 mL Amber Unpreserved vials (N/A) * x o, 0 rt o O Wu w D w. n Cr O o 0 0 n � n O � a� 0 ro N D 0 C'Y ac �4 n 3L tt1 � S r► Z+ S} 0 0 x 0* -n M v C O ti. M O O CL M 13 w � O Awl _R 0 O "t9 O M 4t 6 ceAnalytical ,t www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 April 27, 2023 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92662556 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on April 17, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones �PP.pCCf�F�'� 1 11411 t REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 15 laceAnalXical { www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92662556 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 15 aceAnalytical� www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92662556 Lab ID Sample ID 92662556001 O u tfa I I 001 PASI-A = Pace Analytical Services - Asheville PASI-E = Pace Analytical Services - Eden SAMPLE ANALYTE COUNT Method Analysts Analytes Reported Laboratory SM 2540D-2015 VLG 1 PASI-E SM 521OB-2016 AED 1 PASI-E Colilert-18 VLG 1 PASI-E TKN+NO3+NO2 Calculation MDW 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 EGC 1 PASI-A EPA 365.1 Rev 2.0 1993 Zip 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 15 ' Pace Analytical Services, LLC Pi®figt} QQ //fi�nnq / 1377 South Park Drive c /"111Q'XICal Kernersville, NC 27284 www.pacelabs.com (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92662556 Sample: Outfall 001 Lab ID: 92662556001 Collected: 04/17/23 13:30 Received: 04/17/23 15:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 254OD-2015 Pace Analytical Services - Eden Total Suspended Solids ND mg/L 6.2 1 04/18/23 13:01 5210B BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521 OB-2016 Pace Analytical Services - Eden BOD, 5 day 10.1 mg/L 2.0 1 04/18/23 10:42 04/23/23 11:27 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms 2.0 MPN/100mL 1.0 1 04/17/23 18:07 04/18/23 12:21 D6 Total Nitrogen Calculation Analytical Method: TKN+NO3+NO2 Calculation Pace Analytical Services -Asheville Total Nitrogen 45.6 mg/L 0.040 1 04/25/23 15:56 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Ammonia 27.3 mg/L 0.60 6 04/27/23 11:41 7664-41-7 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Kjeldahl, Total 42.1 mg/L 2.5 5 04/24/23 16:08 04/25/23 04:05 7727-37-9 353.2 Nitrogen, NO2/NO3 pres. Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, NO2 plus NO3 3.5 mg/L 0.040 1 04/24/23 14:32 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville Phosphorus 5.6 mg/L 0.10 2 04/19/2315:10 04/20/2310:50 7723-14-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2023 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 15 _ FlaceAnalXical � www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92662556 QC Batch: 768651 Analysis Method: SM 254OD-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92662556001 METHOD BLANK: 3990672 Matrix: Water Associated Lab Samples: 92662556001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 04/18/23 13:00 LABORATORY CONTROL SAMPLE: 3990673 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 236 94 90-110 SAMPLE DUPLICATE: 3990674 92662578001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 5250 5870 11 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2023 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 15 PaceAnalytical{ www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92662556 QC Batch: 768606 Analysis Method: SM 521 OB-2016 QC Batch Method: SM 521 OB-2016 Analysis Description: 5210E BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92662556001 METHOD BLANK: 3990441 Matrix: Water Associated Lab Samples: 92662556001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg/L ND 2.0 04/23/23 10:59 LABORATORY CONTROL SAMPLE: 3990442 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day mg/L 198 194 98 84.6-115 SAMPLE DUPLICATE: 3990444 92662446002 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 342 334 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2023 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 15 RaceAnalXical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92662556 QC Batch: 768537 Analysis Method: Colilert-18 QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92662556001 SAMPLE DUPLICATE: 3990245 92662556001 Dup Parameter Units Result Result RPD Qualifiers Fecal Coliforms MPN/100mL 2.0 4.1 69 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2023 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 15 15 J . PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92662556 QC Batch: 770413 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92662556001 METHOD BLANK: 3999308 Matrix: Water Associated Lab Samples: 92662556001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 04/27/23 11:14 LABORATORY CONTROL SAMPLE: 3999309 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.0 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3999310 3999311 MS MSD 92663919002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 101 5 5 107 107 123 121 90-110 0 M1,P4 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4000276 4000277 MS MSD 92663349001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 1.1 5 5 6.1 6.0 99 98 90-110 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2023 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 15 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92662556 QC Batch: 769925 QC Batch Method: EPA 351.2 Rev 2.0 1993 Associated Lab Samples: 92662556001 METHOD BLANK: 3997027 Associated Lab Samples: 92662556001 Parameter Units Nitrogen, Kjeldahl, Total mg/L LABORATORY CONTROL SAMPLE: 3997028 Parameter Units Nitrogen, Kjeldahl, Total mg/L QUALITY CONTROL DATA Analysis Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Laboratory: Pace Analytical Services - Asheville Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.50 04/25/23 02:37 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 10 10 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3997029 3997030 MS MSD 92663314002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 1.0 10 10 11.2 11.3 102 102 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3997031 3997032 MS MSD 92663314003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 1.1 10 10 11.9 11.6 107 104 90-110 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2023 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 15 �. raceAnalytical� www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92662556 QC Batch: 769836 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92662556001 METHOD BLANK: 3996637 Matrix: Water Associated Lab Samples: 92662556001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, NO2 plus NO3 mg/L ND 0.040 04/24/23 14:03 LABORATORY CONTROL SAMPLE: 3996638 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, NO2 plus NO3 mg/L 2.5 2.4 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3996639 3996640 MS MSD 92662898001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L 0.41 2.5 2.5 2.8 2.7 94 94 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3996641 3996642 MS MSD 92662961001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L 0.057 2.5 2.5 1.6 1.6 60 60 90-110 0 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2023 01:47 PM without the written consent of Pace Analytical Services, LLC, Page 10 of 15 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92662556 QC Batch: 768917 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365A Phosphorus, Total Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92662556001 METHOD BLANK: 3992014 Associated Lab Samples: 92662556001 Parameter Units Phosphorus mg/L LABORATORY CONTROL SAMPLE: 3992015 Parameter Units Phosphorus mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.050 04/20/2310:16 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 2.5 2.6 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3992016 3992017 MS MSD 92662179001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 3.4 2.5 2.5 6.3 6.2 117 114 90-110 1 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3992018 3992019 MS MSD 92662276001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 1140 2.5 2.5 3.8 3.7 106 102 90-110 3 ug/L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2023 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 15 . PaceAnalytical� www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Hope Valley Pace Project No.: 92662556 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as 'Total' may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. P4 Sample field preservation does not meet EPA or method recommendations for this analysis. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2023 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 15 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Hope Valley Pace Project No.: 92662556 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92662556001 Outfall 001 SM 254OD-2015 768651 92662556001 Outfall 001 SM 521OB-2016 768606 SM 521OB-2016 768871 92662556001 Outfall 001 Colilert-18 768537 Colilert-18 768538 92662556001 Outfall 001 TKN+NO3+NO2 770310 Calculation 92662556001 Outfall 001 EPA 350.1 Rev 2.0 1993 770413 92662556001 Outfall 001 EPA 351.2 Rev 2.0 1993 769925 EPA 351.2 Rev 2.0 1993 770067 92662556001 Outfall 001 EPA 353.2 Rev 2.0 1993 769836 92662556001 Outfall 001 EPA 365.1 Rev 2.0 1993 768917 EPA 365.1 Rev 2.0 1993 769055 Date: 04/27/2023 01:47 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 15 CHAIN -OF -CUSTODY Analytical Request Document LAB USE ONLY -Affix Workorder/Login Labe} Here or List Pace Workorder Nt,mher.+- c�ha:ry-?°-C_ •=tally :: LEGAL DOCUMENT - Camp ete a i re'event fields Company: _., ? ng information: ._ 6 D e ; " // / '-_ t ALL SI l Addre s 11111 � 11111 rL"`.^.t3tner P.,..,,:, rat Repo,, To Email To 9ZB6525g6 • * Preservative Types: (1) nitric acid, (. I . _ -_.,,. .. , , J — un nyarox+ae :5) zinc acetate, -rv�y -f_ (6) metham.+l, (7) sodium bisulfate, (8) sodium thiosulFate, (9+hexane, (A) ascorbic acid, (8) amm_n <m suI{.-te, + `:+te Col action Info Address: �9 r (f -v ^ramium hydroxide, (D) TSP, (U) Urpreserved, (0) Other Customer P Analyses Loh Profile/Line: jest Name Numtrer; State: C`Countyr -ity: Time Zone Coi(e-:.ell: n /I j PT f I MT CT kKT Lab Sample he elpt Checklist: In Custody Phare: ""'` Y... ..sue L%�` SiteiFaCl itylpit: �,��*',;,i.€anCeManitarin...3 a Y Seals PresentE'Inta.^..t Y�tiNA nail. ` 4 ✓ g' eZy Custody Signatures Present N NA S ( ]No (° Collector Signature Present N NA v Bottles Intact Collected By (Pr ntr. Purchase Order d DW PWS ID {i N NA E � Correct Bottles �ON NA Mote ft: OW Locat on Code Gx Sufficient volume N NA Samples Received on Ice N :`'=e tea By (signature) Turnaround Date Rewired: imrne lately ec; on ice: "9 VOA - Headspaae Aon Ice Y � Lr ( ] Yes ( ] No USDA Regulated Soils: ( pp &' N NA �Sampe Disposal: hush; Field Filtered if a ii.abl..a t� Samples in Holding Time r ( ) Dispose as appropriate ( ) Return ( ] Same Day ( ] Next Day [ ] Yes ( ] No Residual ReStrips: (sidual Chlorine P e ent Y j�NA } Artnive. ( ) 2 Day ( 13 Day t ] 4 Day f ] S DaY t, G P s s �, �^- 1 wt i( )Hold (Expedite Charges Apply) Analysis: Sample pH Acceptable N NA PH Strips:n(1 ^...•,.- -.. .:,�_.. Sulfide Present rryy Matrix Codes (insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW),.y Nl Lead Acetate Strips: �j Product (P), Soli/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Sioassay (B), Vapor (V), O&..er £OT) �(% "'•' u ""' • LAB USE ONLY: Comp/-Comp/-r Collected (or Res # of i Customer Sample ip Matrix ° Composite End Lab Sample # I Comments: Grab Composite Start) C° Ctns ] U _ Date Time Date me "� f t"�d aft i3 Gt f t"+-%`l1` 3df �"} -- Ord 4 -1' -,; l> Cuswmer Remarks/ Special Conditions 1 Possible Hazards: -ype of ice Usedd: Wet plop ft f r,.unc SHORT HOUfC72 N N,A Lab Sample Temperature nfc:; Packing Material Used: 1 . Lab Tracking H: 2610299 Temp Blank Received: Y N NA Therm ID#: r a t✓1`� ° _ 01 - + r Cooler 1 Temp Upon Receipt) - 2,0C m Radchesamples) screened (<500 cpm): Y N NA Samples received via: FEDEX .�""'"" �, Cooler 1 Therm Corr. Factor: -' ✓/ oC Re _ UPS Client. = Courier Pace Cour er Cooler 1 Corrected Temp: .squished by/Company (Signature; Dat2:''ime: Re ived by/Company: (S gnature) Date%Time: M":L LAB i. E ONLY _aC Comments: Relinipished by'Companv� (Signature) Ct to^Time. Received bull. om'.an f5i nature' Y• g i Date/Time: Acctnum: A Template: Trip S ank Received: Y N NA r-e}ing0,ishe'b ILompary:(Si (Signature) y R DateJTime: eceived bylCompany: (Signature, DatejTime Preiagim HCL McOH TSP Other cn PM; Non Canfarmance(s): Page: ,_ . 1 .. _ _.._ _ __ n3 YES J NO of- S r f ..g .... i »,,. ...w,. N 69AU / _ 8P3U _r rA rr,4, O O co m CD 1 f sPZJ 0 rn F as e Una,eserrf d :WA) � 0 c Oi � O fw7 3 '� c ID FtU I itt to A Q T O 0 �# : ta Past -a es���re w fl 3 f �r � i y 'J ! ,r - € ° � � � / f fi ]�`"� v'Y�l s'Iv] !e �'i � B (Tt"� <: a7 aft"+ Nl � !1 T � � � %�► 3P3t� 0m_past, t 3t t. Z A X I t9 A im rzr — CD I f �j M 8P4E "� m Dias: c' Acew 3 3Ci i�3u€ t{ BP4 �.,°s rn9.!a iC "iat' 3! t cr • i ff �" EG ro Z CL lovineT66t{Ea .t `3gS U.. �'SH�'7_t� O o N c g y E — alU . er Ambes l�rMr�s e f tv A3 (CI-) G Z _ ( A•I t :r uher ,t !G3 r u AG3U-2SO tnt Arnbe. i3r s, s2t�•€• >'� �t-i O ,�.r. .Ss At31z 1 rEntb� G1 t oQ G%j w fn% YCAt3 i'N"A] O ht i YG47.40 qiL kJCA Fat"3 ! N :n, n t a m € t I VG91J 40 nLL'C3� n reserve t� tAs "GS i x i i j OG9V-4J r"L ,'C'A "3r'G" N/A) Ij h it DG9S-4G <.r,t'~GA 1fi25€;4 ih;/Aj tit`GK =3 vials per M i SPST-!7� Mi S5en e Piz.V. (NIA ab; I s j mm i r Sr,"27-250 ml itcnie Plastic (NiA )ab HP3R 2 0 m€- Ptasttc NH2QW4 t9 a � n Serve IN? ' � I t • (!p ��a�� ' �(.; i i i` - .ire` .._. "1 }E _,_.._ _... i P ! i Rt L'SCiIJ L"u ml Sc ntt1i1no t vtais (N/A) !! DM-40 n-rt Arrbe= L 3 eser,eF i a i t:xr'Y , 7 ft �aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 April 05, 2023 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92659730 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on March 30, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones Q pCCgkb REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92659730 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 raceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Hope Valley Pace Project No.: 92659730 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92659730001 Outfall 001 SM 254OD-2015 VLG 1 PASI-E SM 521OB-2016 SRS 1 PASI-E Colilert-18 SRS 1 PASI-E PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 PalceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92659730 Sample: Outfall 001 Lab ID: 92659730001 Collected: 03/30/23 13:00 Received: 03/30/23 15:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 254OD-2015 Pace Analytical Services - Eden Total Suspended Solids 3.9 mg/L 2.8 1 03/31/23 13:20 5210B BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521OB-2016 Pace Analytical Services - Eden BOD, 5 day 10.8 mg/L 2.0 1 03/31/23 10:47 04/05/23 10:17 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms 14.6 MPN/100mL 1.0 1 03/30/23 18:12 03/31/23 12:15 D6 Date: 04/05/2023 01:49 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 11 FaceAnalXical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92659730 QC Batch 765137 Analysis Method: SM 254OD-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92659730001 METHOD BLANK: 3972909 Associated Lab Samples: 92659730001 Parameter Units Total Suspended Solids mg/L LABORATORY CONTROL SAMPLE: 3972910 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 3972911 Parameter Total Suspended Solids SAMPLE DUPLICATE: 3972912 Parameter Total Suspended Solids Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.5 03/31/2313:17 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 246 98 90-110 92659715001 Dup Units Result Result mg/L 131 128 92659598001 Dup Units Result Result mg/L 38.5 39.4 RPD Qualifiers 2 RPD Qualifiers 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2023 01:49 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 11 PaceAnalytical� www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92659730 QC Batch: 765138 Analysis Method: SM 521OB-2016 QC Batch Method: SM 521 OB-2016 Analysis Description: 5210E BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92659730001 METHOD BLANK: 3972913 Matrix: Water Associated Lab Samples: 92659730001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg/L ND 2.0 04/05/23 09:07 LABORATORY CONTROL SAMPLE: 3972914 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day mg/L 198 192 97 84.6-115 SAMPLE DUPLICATE: 3972916 92659715001 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 261 239 9 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2023 01:49 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 a" M or, aceAnalyical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92659730 QC Batch: 765041 Analysis Method: Colilert-18 QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92659730001 SAMPLE DUPLICATE: 3972581 Parameter Units Fecal Coliforms MPN/100mL 92659715003 Dup Result Result RPD Qualifiers 1.0 ND D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2023 01:49 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 1 � aceAnalyfiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Hope Valley Pace Project No.: 92659730 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2023 01:49 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 11 �aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Hope Valley Pace Project No.: 92659730 Lab ID Sample ID QC Batch Method QC Batch 92659730001 Outfall 001 SM 254OD-2015 765137 92659730001 Outfall 001 SM 521OB-2016 765138 92659730001 Outfall 001 Colilert-18 765041 Date: 04/05/2023 01:49 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Method SM 521OB-2016 Colilert-18 Analytical Batch 765388 765042 Page 9 of 11 CHAIN -OF -CUSTODY Analytical Request Document PaceAnaVical' Chain -of -Custody s a LEGAL DOCUMENT Complete all relevent fields Company: Addr Repo, To Email To: -opy T Site Collect on lnfo!Address -) et I 40'T eeif Customer P ect Namei'N,,mber: _�tate:ffCCoun T ml�7zrne jy/C y 7- —Collf?c' ed b44, 1 JPT I 'MT[ 'CT Phone, may_site " -3r!'ty]D#: Compliance Monitoring? Emaik V-1e, No Collected By (print Purchase Order N. DW PWS ID it:I o)I e-1 :Quote DW Location Code: Mar:6 _ o iected Br'sigrawre). Turnaround Date Requir,,,. Immediati-y Pa6ke.0 onice)Yes )No Sample Disposal: Rush Field F Itered (if apphr,able) ibis S , i I le F% I I M LAB USE ONLY- Affix Workorder/Login Label Here or List Pace Worko-rder Numbor MTJt Log -in Number 14,--- 730 ALL SHE Wo#-.926591- a 111il Ili _ m . _ .._� Cuntainer Presery tive "rLservative Types: (1) nitric acid 01 Sl 926159730 ,1 11ric acetate, ;' sod t6l methanol, (7) sodium hisuffate, ( I , , . _-, JHi ascorbic acid, (9) ammonium sulfate, him hydroxide, (D) TSP, (0) Unpreserved, (0) Other po ea appropfate i Ineturn ay ext ay I Yes I j No V) Arch ve; ( )2Day ( )3 Day ( )4 Day j 15 Day Ch [Expedite ar;L Anafysis. Apply) Matrix Codes (Insert in Matrix box belom: Drink fig Water: DW), Ground Water (GW), L­-ste-weriww), Product f,P), (SQ, 011 (OL), W'pe (WP), A (AR), T ss-2e (TS) Bioassay (8), Vapor (V), Other (OT) I comp Co lected (or Res # of A� Custorner Same IN E Motrix Grab omposite Start) Composite rid Cl Ctns 1 I '(3 lij D.I I I I co k1L Date 1 11" e , ­­­ I -"—,I - ate me - I I Cumerner Remarks / Special Cond t ons /Poss b e Hazards; type of)ceUsed: Wet ' glue Dry N- iwe packing Material Used: Radchem sample(s) screened (<500 cpm): Y N NA inq.ished by(Comparty: [Signature) jDaate(T me: qeceived by/Company; (5 gnat -ire) IX-- kt, ktcluished by/'Company: (S.gnature) atsl'trne .-IReceived by Lao "mpie Receipt Checklist: Custody Seals Present,'Intact Y 6hA Custody Signatures Present <3X NA Collector Signature Present N NA ?)N Bottles Intact NA Correct Bottles NA Sufficient volume §14 , 'A Samples Received on ice VOA - Headapace Acceptable y Y N N y N Ilk USDA Regulated Soils Samples in Folding -ime 6NO K NA Residual Chlorine Prese YtVNA Cl Strips, J�t Sample pH Acceptable Y ill PH Strips. Sulfide Present Lead Acetate Strips. LAS USE 011ry: Lab Sample # / Comriients: SHORT HOLDS PRESENT (<72 hours!.<a,, A N/A Lab Tracking N: 2610299 Samples received via: FEDEX UP Client ourier Pace Courier IOat ime: X MTJ . LAB USE ONLY b /1, j J S 4 6 Tab e lf: Date�/Tirne: Acctnum: Template: PfeloR n. Lab Sample Temperature Info: Temp Blank Received- Y N NA Therm ID#. 9- '� Q Cooler I Temp Upon Receipt:1:fLoc Cooler 1 Therm Corr. Factor: -:::.j 0'r Cooler I Corrected Temp-__Z.A ciC Comments: Trip Blank Received: Y N NA HCL MeOH TSP Other by,Company: 6.gnatire Date/lime; ('Received byi'Company: f5ignature) Date/Time: IPM: IPG. Non Conformance(s): Page: YES / NO lof a M N cc m 0 1z 6P4U 'rS rtPlastic Unpres r erS (N/A} (CH I P3U 2.50 rnt Plastic Uttprese• ved (N/A) rW2U-5 mL Plastic iSnprt erved (F!/#} i i ! PIU-' ii€er Plastic Unpreserved INJA) Pt ` mL Plastic H2504 [.pH < 2j iCi') . �3N-250mat pt3stic HNO3 ipH < 2) t ; M-125 mL Nsii, ZN Acewe & NaCH (>9) lW SN;""125 ini PiaStit iYZC„tM (pH > IZj (C3•) { i WGFU•Wide-mouthed Glass jar Vripreseraed AGiti-d liter Amber Ur preserved (NtA) (Cl- ' Ai7.25i rC mbar 3r G Sur ad tA, (Cl-} ✓ / AGIS-i titer Amber H2SO4 (pH < 2) AG3S-250mL Amber H25C 4 (pH < 2) � t}G9A•25G mL AmI`ih WOO(N/A)(CI•) DG9H-40 rnL VQA HCl (N,'A) VWT-410 mL VOA Na2S203 (NIA) j ( i 3 V 9U-40 mL VOA Unpreserved (NI/A) ` DG9V-4,0 mt VGA H3PO4 (NSA} i t QG95"wit mL VOA H2SCi4 (N/A) i V/GK (3vials per k€t)_VPHlGas kit (N/A) 1 S?57-22SmLSterile Plastic (ty/A--lab) SP21`-250 mi, Sterile Plastic (N/A -- lab) I > WIR-250 mL Plastic (NH212SO4 (9<3-9<7) � AGOr,} t._yAmber Unpreserved ;N/A) (Cl-) VSGU-20 m€. Scintillation vials (N/A) � I I i _ ............ OG9V-4G mL Amber Unpreserved vials (N/A) , „.° IVI o !!i ` ( €„-? p 6. 3 (( 0 0 Cr M t t i PaceAnalytical� www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 March 29, 2023 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92657736 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on March 20, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones �yPQ ACCRt geOFA"f��. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 12 .aceAnalytical www.pacelabs.com Project: Hope Valley Pace Project No.: 92657736 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 12 aceAnalytical k. www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley 92657736 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92657736001 Outfall 001 SM 2540D-2015 VLG 1 PASI-E EPA 350.1 Rev 2.0 1993 SRS 1 PASI-E SM 521 OB-2016 AED 1 PASI-E Colilert-18 LRB 1 PASI-E PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 12 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92657736 Sample: Outfall 001 Lab ID: 92657736001 Collected: 03/20/23 12:00 Received: 03/20/23 15:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 254OD-2015 Pace Analytical Services - Eden Total Suspended Solids 8.7 mg/L 3.3 1 03/21/23 13:14 350.1 Ammonia EDN Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Eden Nitrogen, Ammonia 49.5 mg/L 1.0 10 03/23/2317:08 7664-41-7 5210B BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521OB-2016 Pace Analytical Services - Eden BOD, 5 day 21.4 mg/L 2.0 1 03/21/23 14:41 03/26/23 15:31 B3 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms ND MPN/100ml- 1.0 1 03/20/23 18:02 03/21/23 12:46 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/29/2023 05:25 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 12 -aceAnalytrcal www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92657736 QC Batch: 762618 Analysis Method: SM 254OD-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92657736001 METHOD BLANK: 3960504 Associated Lab Samples: 92657736001 Parameter Units Total Suspended Solids mg/L LABORATORY CONTROL SAMPLE: 3960505 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 3960506 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 3960769 Parameter Total Suspended Solids Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.5 03/21/2313:13 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 240 96 90-110 92657705002 Dup Result Result RPD Qualifiers 75.9 77.1 2 92657769002 Dup Units Result Result mg/L 32.3 30.5 RPD Qualifiers 6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/29/2023 05:25 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 12 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92657736 QC Batch: 763374 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia, EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92657736001 METHOD BLANK: 3964688 Associated Lab Samples: 92657736001 Parameter Units Nitrogen, Ammonia mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.10 03/23/2315:47 LABORATORY CONTROL SAMPLE: 3964689 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.0 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3964690 3964691 MS MSD 92657780001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.3 5.2 104 104 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3964692 3964693 MS MSD 92658378001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.1 5.1 103 102 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/29/2023 05:25 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 12 PaceAnalytical� www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92657736 QC Batch: 762708 QC Batch Method: SM 521OB-2016 Associated Lab Samples: 92657736001 METHOD BLANK: 3961037 Associated Lab Samples: 92657736001 Parameter Units BOD, 5 day mg/L LABORATORY CONTROL SAMPLE: 3961038 Parameter Units BOD, 5 day mg/L QUALITY CONTROL DATA Analysis Method: SM 521OB-2016 Analysis Description: 5210B BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 03/26/2314:53 B3 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 198 205 104 84.6-115 B3 SAMPLE DUPLICATE: 3961040 92657651001 Dup Parameter Units Result Result BOD, 5 day mg/L 2660 2730 RPD Qualifiers 3 B3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/29/2023 05:25 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 12 0keAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92657736 QC Batch: 762554 Analysis Method: Colilert-18 QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92657736001 SAMPLE DUPLICATE: 3960352 92657736001 Dup Parameter Units Result Result RPD Qualifiers Fecal Coliforms MPN/100mL ND ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/29/2023 05:25 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 12 fPace Analytical Services, LLC aceAnalytical 1377 South Park Drive Kernersville, NC 27284 www.pacelabs.com (704)977-0981 QUALIFIERS Project: Hope Valley Pace Project No.: 92657736 0149I.111111[d.6'] DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS B3 The dissolved oxygen depletion of the dilution water blank exceeded 0.2 mg/L. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/29/2023 05:25 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 12 'f} .PaceAnalXical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Hope Valley 92657736 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92657736001 Outfall 001 SM 254OD-2015 762618 92657736001 Outfall 001 EPA 350.1 Rev 2.0 1993 763374 92657736001 Outfall 001 SM 521 OB-2016 762708 SM 521OB-2016 762926 92657736001 Outfall 001 Colilert-18 762554 Colilert-18 762555 Date: 03/29'2023 05:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 12 0-7 CHAIN -OF -CUSTODY Analytical Request Document aceAnalytical' Chain -of -Custody is a LEGAL DOCUMENT -Complete all reievent fie ds OW USE ONLY -Affix Workorder/Login Label Here or List Pate Workorder Number ne - �- ALL SHADi to Container Preservative T yp 82637735 •• Preservative Types: {i) nitric acid, (2) sulfur _ ;,y,,uxrue, i .i z,nc acetate, (6) methanol, (7) sodium bisulfate, (9) sodium thiosulfate, (9) hexane, (A) ascorbic acid, {B) ammonium s0ate, ()oniu,n hydroxide, (D) TSP, (t,) Unpreserved, (0) Other Company: a fie- e- , Billing information: Addre s: Repor To Email To: i + +rr, C.1477 Copy T , Site 1ection Info Address: 1D �� Customer P ject Name/Number: State: icounty/City: I Time Zone Colec ed. tf, �p tSSttf� [ ) PT ( J MT [ ) CT p, 4,fT Anaiysas lab Prof'le/Erne: �' ` f •. 0 CD ti' U I-L LdO Sample Receipt Checklist: n '.Custody Seals PresentlIntact y(9 NA Custody Signat :res PresentINNA Collector signature Present NA Hvttles Intact NA NA suffgcientct tVolume tlesNA samples Received on ice NA V0A - Readspace Acceptable USDA Regulated Suit$ ,/���,,+cN Samples in Holding Time -%'G3V Res ;rual Chl nine Present r NA Sample pH Acc ptable N NA pH Strips; Sulfide Present Y N(.. Lead Acetate Strips: LAB USE :'NLY: Lai S +rap e # Phone' ira'�TJ�` t8 Jr Erna:,: rteiFaciaity ID q. Compliance Monitor ng? es ( No Co' ected By (print . ��, Pur, hase Order p: Quote if: DW PWS ID q: DW Location Code: Collected By (sgnature): Sample Disposal: ( ] Dispose as appropriate [ ) Return J Archive: ! )Hold ..„,.,,�.,. Turnaround Date Required: immediately ace on ice: [ ) Yes [ ; No Rush: ) ] Same Day f J Next Day [ ) 2 Day [ J 3 Day ( j 4 Day [ J 5 Day {Expedite Charges Apply) Field Filtered (if applicable): [ J yes [ J No Analysis: Matrix Codes (Insert in Matrix box below). Drinking Water (DW), Ground Water (GW), Wastewater (WW), Product (P), Sol/Solid (SQ, Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (e), Vapor (V), Other (OT) Customer Sample =0 Matrix ` Camp / Grab Collected (or Composite Start) Composite End Res CI N of Ctnz Date Time Date Time f o o t bra 4 a :,Y, �- 8 DID `5" ra? - i Customer Remarks (Special Conditions /Possible Hazards: Type of ice Used.tW_.1.,,f Blue Dry None SHORT. HOLDS PRESENT•1<72 flours) N N/A Lab Sample Temperature Info: Temp Blank Received: Y N NA Therm ION u 2 Cooler 1 Temp Upon Receipt- oC Cooler 1 Therm Corr. Factor: c Cooler 1 Corrected Tempe Com: entF Packing Material Used: ,.� ,; } �} Q' Lab Tracking lt; 2610299 L 6 1 {� V L 9 9 Radchem sample(s) screened (<500 cpm): Y N NA Samples received via: FEDEX UPS dient Courier Pace Courier Relinquished by/Company: (Signature) + Date/Time: Date/Time: Recei d by/Company: (Sign re) Received by/Comp y: (Signat e) Oat//gg/Time: firTab`.eN: 11111 0atefTime: MT)L LAB USE ONLY Reinquished by/Company: (Signature) Acctnum: Template: Prelogin: Pivi. FHB. Trip Blank Received: Y N NA HCL Me''CH TSP Other R'nquished by/Company: (Signature) ry Date/Time. Received by/Company: (Signature; DatefTime. Non Conformance(s); YES / N Page: f, _ _ , I a m m IV 0 r1P4U 125 ml, FUS r [€cP s Serrr+7 rNt (C. ) i I BP3 250:-11 Plastic (N/AI I ! apzu.5L60 m Plasuc Unp-ese ve9 ;N/A PPIts-1 liter P wic Jnp esen ed (NIA) 471­ 7I / ! /1 i /d I f ! /a BP41,-12SmLPtazd-, H2SO4 PFI':);rl- 1 j i l j j ( e rO ;€ +tz 8P3NV 53 mL p'a�!,- HM, (P Acetate CiaGk-, F48112S mt Nash-, aO ; ors 4 > 22) ?CI- I �s U•v'.j ld2•r?tOUt"i£C Glass jar i.l TiprAl2ti:e S 4, ........_..sty{ � ; I � t AGIU-3 i.t2t Amber i;nPreSarved .'4iA) CI-) 1 t AGIN-' -ter Amber F{i3 (P< A63U•250 mt Amber 0r' €. rrv�,d IN k) `,-I ) %7iX �a AGiS Titer ArnSer WSC PH 2) I / !. s I % A,her H2SO4 [ >N < �< Aia35 250 rnl.r.2: E i Ot,94-250rtiI AmiC­r dt- 1'A(C s i r-- } m VG9T-40 rnL VOA Na2S2031N/ ) 1 1 i E I �ei `.1Q f`.lLl��A t�"1 `€,:C e`SerY(:u (Nq!s) ���.,...,.,_.........-�.�...-.�.... i I i oGgv.4, mL VOA H3PO ;" I 1 GG55.47 ml VOA H2504 (.;A, I � E ` /Gk, s3 vials per kR)-V"/Ga<. kit P4 A_ $PST-1725 rnL Sterile Plas'ic tN/A - labi I 5Pz7.250 mt Sterile Ptas t€ {tires lab 9P3R k'�0 rnLslas.+..itiH2f gt'7 (930'•3 1 € F 1 A OU•100 mL Amber Ur,e served (NJAi iC VSGU- 0 ml. Sclnullat€ n v€als a � � � ) i d3£i9Ei-4{7 rnl iamDer Unpresarvv?G; vials {id/A; AO 01- ace, Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 August 04, 2023 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92679615 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on July 27, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones Q NCCI?to 4BOWOW REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC, Page 1 of 11 Project: Hope Valley Pace Project No.: 92679615 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, INC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley 92679615 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92679615001 Outfall 001 SM 2540D-2015 RZB 1 PASI-E SM 521OB-2016 DAW 1 PASI-E Colilert-18 RZB 1 PASI-E PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 A 00'� if rice: ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92679615 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Sample: Outfall 001 Lab ID: 92679615001 Collected: 07/27/23 13:00 Received: 07/27/23 15:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D-2015 Pace Analytical Services - Eden Total Suspended Solids 2.8 mg/L 2.5 1 08/01/23 08:24 5210E BOD, 5 day EDN Analytical Method: SM 521 OB-2016 Preparation Method: SM 521 OB-2016 Pace Analytical Services - Eden BOD, 5 day 7.6 mg/L 2.0 1 07/28/23 12:38 08/02/23 13:41 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms ND MPN/100ml- 1.0 1 07/27/23 18:32 07/28/23 14:17 D6 Date: 08/04/2023 01:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 11 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92679615 QC Batch: 790050 Analysis Method: SM 254OD-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92679615001 METHOD BLANK: 4094782 Associated Lab Samples: 92679615001 Parameter Units Total Suspended Solids mg/L LABORATORY CONTROL SAMPLE: 4094783 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 4094784 Parameter Total Suspended Solids SAMPLE DUPLICATE: 4094785 Parameter Total Suspended Solids Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.5 08/01/23 08:21 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 226 90 90-110 92679278001 Dup Units Result Result mg/L 169 186 92679582001 Dup Units Result Result mg/L 117 112 RPD Qualifiers 9 RPD Qualifiers 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/04/2023 01:57 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 11 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92679615 QC Batch: 789956 Analysis Method: SM 521OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210E BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92679615001 METHOD BLANK: 4094091 Associated Lab Samples: 92679615001 Parameter Units BOD, 5 day mg/L LABORATORY CONTROL SAMPLE: 4094092 Parameter Units BOD, 5 day mg/L Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 08/02/2312:33 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 198 185 94 84.6-115 SAMPLE DUPLICATE: 4094094 92679582001 Dup Parameter Units Result Result BOD, 5 day mg/L 349 326 RPD Qualifiers 7 R6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/04/2023 01:57 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92679615 QC Batch: 789912 Analysis Method: Colilert-18 QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92679615001 SAMPLE DUPLICATE: 4093886 Parameter Units Fecal Coliforms MPN/100mL 92679582003 Dup Result Result RPD Qualifiers 1.0 3.1 102 D6 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/04/2023 01:57 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Hope Valley Pace Project No.: 92679615 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. R6 The RPD between valid sample dilutions exceeded 30%. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/04/2023 01:57 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 11 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Hope Valley Pace Project No.: 92679615 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92679615001 Outfall 001 SM 254OD-2015 790050 92679615001 Outfall 001 SM 521OB-2016 789956 SM 521OB-2016 92679615001 Outfall 001 Colilert-18 789912 Colilert-18 Date: 08/04/2023 01:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch 790294 789913 Page 9 of 11 PkeAnalytical' Company: Addre��/!�� ReporLToy�� Copy TA: _ ,i vL�l`e Customer PFG *t Name/Number: I~A:n:-:%i -U1ti i vv i Analytical nequeyi Du(.utrfien'c Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevent fields Billing Information: Email To: Site Collection InfotAddress: StatelVoCountty/City: Time Zone Collet ed: PT ( j MT [ j CT (- Phone: 3 36-75. -5- -r q5 Site/Facility iD N: Compliance Monitoring? Ema-i O Collected By (print : Purchase Order #: OW PINS ID #: `�i e- 14;,3 sC� Quote N: DW Location Cod to iected By (signature). Turnsr;fund Date Require,::: Im ee,iate q Par a on ( I Yes ( I No `:ample Dl3posa:: Rush, Field Filtered (if applicable): I I Dispose as appropriate I I Return [ ) Same Day [ I Next Da ` LA- USE GNL i'- Ainx workorcier/Login Label Here or List Pace Workorder Number or MT1L Log -in Number Here AL WO# : 92679615 Contain€r Pres � 92657 sill (6) methanol, (7) : d um brsutfate, , (£ La on um hydr aide, 1 D) TSP, (U) Unpreserved, (0) Other l 'a yses !Lab Protile/L ne: ( )Archive: Y [ 12 Day I ) 3 Day [ 14 Day I Is Da y ( ) Yes ( I No ( j Hold: (Expedite Charges Apply) Analysis: Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) N Customer Sample ID Matrix ` Comp J Grab Collected (or Composite Start) Composite End Res Cl # Df 1 � 41 Ctns V- Date Time Date Time Ftl r44 71J- 1 — znmpie xeceipt checklist: Custody Seals Present/Intact y ONA Custody Signatures Present NA Collector Signature Present N NA Bottles Intact NA Correct Bottles /y��. NA Sufficient Volume tS'n NA Samples Received on Ice /r/,N NA VCA - Headspace Acceptable --Y N � USDA Regulated Soils Y N Samples in Holding Time �.N A Residual Chlorine Present Y� Cl Strips: Sample pH Acceptable Y N N pH Strips: Sulfide Present y Lead Acetate Strips: LAB USE ONLY: Lab Sample # r` Comments: F Customer Remarks / Special Conditions J Possible Hazards. Type of Ice Used: Wet Blue Dry None SHORT HOLDS PRESENT (<72 hours): LN N/A Packing Material Used: Lab Tracking #: 2610299 Radchem Sample(s) screened (<500 cpm): Y N NA Samples received via: FED(X UPS Clien Cc,wier Pace Courier Relinquished by/Company: (Signature) F Date/Time: Recei d by/Company ignature) Date/Timf , }(�'i /Z� S 5 MT1L LAB USE ONLY Table H: Relif4ttuished by/Company: {Signature} 0 ate/Time: Received by/C m r {Si ature) Date/Time: Acctnum: Template: Prelogm: PM: Re(ig(uished by/Company: (Signature) Date/Time: Received by/Company: (Signature) Date/T me Lab Sample Temperature Info: Temp Blank Received: Y N NA Therm 104: it -r C Cooler 1 Temp Upon Receipt: _JLZoC Cooler I Therm Corr Factor: a / oC Cooler 1 Corrected Temp: "-?- - / oC Comments: Trip Blank Received. Y N NA HCL McOH TSP Other Non Conformance (sy: Page: V. 3za ------------I CL r. 0 V CL V M Jay z 3 Matrix Item# 9P4U-125 mL Plastic Unpreserved (N/A) (Cf.) BP3U-250 mL Plastic Vnpreserved (N/A) SP2U-500 ml. Plastic Unpreserved (N/A) BPI U I liter Plastic Unpreserved (N/A) RNS-125 mL Plastic H2SO4 (pH < 2) (Cf-) 9P3N-250 ml. plastic HNO3 (pH < 2) SP42-125 mL Plastic ZN Acetate & NaOH (>9) Plastic 748-125 ML Plastic NaOH (pH > 12) (Cf-) WCFU-Wide-mouthed Glass jar Unpreserved J AGIU-1 liter Amber Unpreserved (NIA) JO-) A61H-1 liter Amber HC1 (PH < 2) A53U-250ml. Amber Unpreserved (N/A) (CI-) Z, A1G1S-1 liter Amber H.SC4 (pH < 2) A.1335-250 ml. Amber 1-12504 (PH < 2) AG3A(DG3A)-250 ML Amber NH4CJ (N/A)(Cl-) D (;g G91H-40 mL VOA HCI (N/A) �— SI LV6T-40 mL VOA Na25203 (N/A) -- ------- V69V-40 mL VOA Unpreserved (N/A) ---------- DG9P4D mL VOA H3PD4 (N/A) VOAK (3 vials per kit)-5035 kit {N/A) V/GK (3 vials per kit)-VPH/Gas kit (N/A) i SPST-125 mL Sterile Plastic (N/A- tab) SP27-250 ml. Sterile Plastic (N/A - lab) BP3A-250 mL Plastic (NH2)25C4 (9.3-9,7) AGOU-100 ml, Amber Unpreserved vials (N/A) VSGU-2C mL Scintillation vials (N/A} DG9U-40 mL Amber Unpreserved vials (N/A) M jA e) 0 < 0 0 0 0 0 M Cr 0 X 0 Z7 CL 0 < rd > 0 0 0 ja F z f FaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 June 16, 2023 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92671382 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on June 08, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones ��Pe PCCRF�'J` `7eoRAtOQ`y REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 J, faceAnalytical� www.pacelabs.com Project: Hope Valley Pace Project No.: 92671382 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 fllaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley 92671382 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92671382001 Outfall 001 SM 254OD-2015 VLG 1 PASI-E EPA 350.1 Rev 2.0 1993 AED 1 PASI-E SM 521OB-2016 LRB 1 PASI-E Colilert-18 SRS 1 PASI-E PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92671382 Sample: Outfall 001 Lab ID: 92671382001 Collected: 06/08/23 13:00 Received: 06/08/23 15:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D-2015 Pace Analytical Services - Eden Total Suspended Solids 3.1 mg/L 2.8 1 06/12/23 12:58 350.1 Ammonia EDN Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Eden Nitrogen, Ammonia 44.8 mg/L 1.0 10 06/12/2313:39 7664-41-7 5210E BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521OB-2016 Pace Analytical Services - Eden BOD, 5 day 6.3 mg/L 2.0 1 06/09/23 14:48 06/14/23 13:35 133,R6 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms ND MPN/100mL 1.0 1 06/08/23 18:26 06/09/23 12:27 D6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/16/2023 11:19 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 11 �111 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92671382 QC Batch 779943 Analysis Method: SM 254OD-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92671382001 METHOD BLANK: 4045694 Matrix: Water Associated Lab Samples: 92671382001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 06/12/23 12:54 LABORATORY CONTROL SAMPLE: 4045695 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 242 97 90-110 SAMPLE DUPLICATE: 4045696 92671338001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 194 251 25 SAMPLE DUPLICATE: 4045697 92671501002 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 30.0 31.6 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/16/2023 11:19 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 11 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92671382 QC Batch: 779925 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia, EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92671382001 METHOD BLANK: 4045604 Matrix: Water Associated Lab Samples: 92671382001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 06/12/23 13:02 LABORATORY CONTROL SAMPLE: 4045605 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.1 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4045606 4045607 MS MSD 92671319001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.3 5.3 104 103 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4045608 4045609 MS MSD 92671302001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.2 5.2 103 103 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/16/2023 11:19 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 11laceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92671382 QC Batch: 779668 Analysis Method: SM 521OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210B BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92671382001 METHOD BLANK: 4044598 Matrix: Water Associated Lab Samples: 92671382001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg/L ND 2.0 06/14/23 12:59 B3 LABORATORY CONTROL SAMPLE: 4044599 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day mg/L 198 206 104 84.6-115 B3 SAMPLE DUPLICATE: 4044601 92671548001 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 442 476 7 B3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/16i2023 11:19 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 raceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92671382 QC Batch: 779471 Analysis Method: Colilert-18 QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92671382001 SAMPLE DUPLICATE: 4043759 92671326002 Dup Parameter Units Result Result RPD Qualifiers Fecal Coliforms MPN/100mL ND 1.0 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/16/2023 11:19 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 11 f .raceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Hope Valley Pace Project No.: 92671382 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS B3 The dissolved oxygen depletion of the dilution water blank exceeded 0.2 mg/L. D6 The precision between the sample and sample duplicate exceeded laboratory control limits. R6 The RPD between valid sample dilutions exceeded 30%. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/16/2023 11:19 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 11 0 r, Pace Analytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Hope Valley Pace Project No.: 92671382 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92671382001 Outfall 001 SM 254OD-2015 779943 92671382001 Outfall 001 EPA 350.1 Rev 2.0 1993 779925 92671382001 Outfall 001 SM 521OB-2016 779668 SM 521OB-2016 92671382001 Outfall 001 Colilert-18 779471 Colilert-18 Date: 06/16/2023 11:19 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch 779976 779472 Page 10 of 11 ' CHAIN -OF -CUSTODY Analytical Request Document PjcMnalytica/' Chain -of -Custody is a LEGAL DOCUMENT - Complete al'. relevent fields LAB USE ONLY -Affix Workorder/Login Label Here or List Pace Workorder Number or MTJL Log -in Number Here ALL SHADEC WO# . 92671382 ..._... _ ......-....._ .__ Container Preservative T pe • ���� •• Preservative Types: (1) nitric acid, {2) sulfuric I (6) methano , (7) sodium bisu fate, 18) sodium IN 92671382 (C onium hydroxide, (0) TSP, (U) Unpreservt Company: l a _� Ile. �, ! n G Billing information Addre s: �c Q Repor TO _ Email To: jr T r CopyT^: Site Collection Info Address: 1d$ �� r Customer P ject Name/Number: State: 'ounty/Gty: Time Zone Collec ed: 4Y l�4 65d/� 1 i PT ( J MT J I CT ( T Analyses Lab Profile Profile/Line: {� �fi -r /.7 'Cy � S.} "J i _ Lab Sample Receipt Checklist: ' Custody Seala Present/Intact Y �htA Y Custody Signatures Present N NA Collector Signature Present N NA Bottles Intact N NA Correct Bottles ,,,YYYY,GGGG??^^}^^? NA N Sufficient Volume N NA Samples Received on Ice N NA VOA - 8eadapece Acceptat,le Y N USDA Regulated Soils Y N tCr?t+ Samples in Holding Time N NA Residual Chlor:rte Pre e tb NA Cl Strips: Sample PH AC-0 t b' NA pit Strips: 'LL-2 x,,.0 Y NA Sulfide PresentLead Acetate Strips: LAB USE ONLY: Lab Sample / Comments, Phone: �^ �t�/ 3lo-7J�J `7tU"f� Email: Site FacifityiDit: / �Com�p`liance Monitoring? tV' `ez ( ]No Collected By (print L r7 �� Purchase Order d: �uOte It: OW PWS 1D R: DVd Location Code: Collected By (signature): Turnaround Date Required: Immediate y Pac e on lce: f (Yes f JNo Sample Disposal: ( j Dispose as appropriate ( 1 Return I ) Archive: i )}?old: Rush: [ J Same Day j J Next Day ; J 2 Day ( 1 3 Day J 1 4 Gay [ j 5 Da Y (Expedite Charges Apply' Field Filtered (f applicable) ( )Yes JNo Analysis: ' Matrix Codes {insert it Matrix box below}: Drinking Water (OW), Ground Water (GW), Wastewater (W'W}, Product (P), Soif/Solid (St}, Oil {OL), Wipe (WP), Air (AR), Tissue (TS}, Bioassay (B), Vapor (V), Other (07) Customer Sample IO Matrix • Comp / Grab Collected (or Cam, pasite Start) Composite End Res Ct 9 of Ctns Date Time Date Time co f ll oo a Grad 2 ✓ $07i-� TSS Customer Remarks / Special Conditions / Possible hazards: Type of Ice Used; Hlet Blue Dry None SHORT HOLDS PRESENT (02 hours) - Y N/A Lab Sample Temperature Info: Temp Blank Received: Y, N NA Therm'D#: �i� Cooler 1 Temp Upon Receipt: oC Cooler 1 Therm Corr. Factor: — oC Comments: Packing Material Used: Lab Tracking #t: Q Q 2610299 Radchem sample(s) screened (a500 cpm): Y N NA Samp es received via- RBlinqui<hed byjCompany_ {Signature) ns P Date/nme: ® Receive b /Com an 1 p y (' natuwc; Date me. 1a { n� t MT_L LAB USE ON, Y Tr,ke P: Iinqu(zhed by/Company: (Signature) D to/Time: k ceived by/Com an ignam, I A.ct-,um: Template: Preiogin: Trip Plark Received Y N NA HCL McOH TSP Other Relinquished by/Company: {Signature) Date/time: Received by/Company: (Signature! PM Na- Con#ormancetsPage FaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 May 30, 2023 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92668585 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on May 22, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones �QQ PCcft TNI ! 0' geORA'� REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 'F raceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92668585 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 flaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley 92668585 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92668585001 Outfall 001 SM 254OD-2015 VLG 1 PASI-E SM 521OB-2016 MWF 1 PASI-E Colilert-18 SRS 1 PASI-E PAS I-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 Pace Analytical Services, LLC 1�aceAnalytical South Park Drive Kernernersville, NC 27284 www.pacelabs.com (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92668585 Sample: Outfall 001 Lab ID: 92668585001 Collected: 05/22/23 13:00 Received: 05/22/23 15:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 254OD-2015 Pace Analytical Services - Eden Total Suspended Solids ND mg/L 2.5 1 05/24/23 12:38 5210E BOD, 5 day EDN Analytical Method: SM 521 OB-2016 Preparation Method: SM 521OB-2016 Pace Analytical Services - Eden BOD.. 5 day 6.9 mg/L 2.0 1 05/23/23 10:52 05/28/23 10:05 R6 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms 3.1 MPN/100mL 1.0 1 05/22/23 18:11 05/23/23 12:52 D6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/30/2023 08:43 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 11 �aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92668585 QC Batch 776462 Analysis Method: SM 254OD-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92668585001 METHOD BLANK: 4028520 Matrix: Water Associated Lab Samples: 92668585001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 05/24/23 12:32 LABORATORY CONTROL SAMPLE: 4028521 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 244 98 90-110 SAMPLE DUPLICATE: 4028522 92668819001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 118 125 5 SAMPLE DUPLICATE: 4028523 92668523001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 360 383 6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/30/2023 08:43 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 11 raceAnalyticalR, www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92668585 QC Batch: 776284 Analysis Method: SM 521OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210B BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92668585001 METHOD BLANK: 4027551 Associated Lab Samples: 92668585001 Parameter Units BOD, 5 day mg/L LABORATORY CONTROL SAMPLE: 4027552 Parameter Units BOD, 5 day mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 05/28/23 09:53 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 198 185 94 84.6-115 SAMPLE DUPLICATE: 4027554 92668523001 Dup Parameter Units Result Result BOD, 5 day mg/L 1300 1270 RPD Qualifiers 2 R6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/30/2023 08:43 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92668585 QC Batch: 776183 QC Batch Method: Colilert-18 Associated Lab Samples: 92668585001 SAMPLE DUPLICATE: 4027226 Parameter Units Fecal Coliforms MPN/100mL QUALITY CONTROL DATA Analysis Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden 92668585001 Dup Result Result RPD Qualifiers 3.1 ND D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/30/2023 08:43 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 ✓W i.. PaceAnalytical A. www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Hope Valley Pace Project No.: 92668585 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. R6 The RPD between valid sample dilutions exceeded 30%. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/30/2023 08:43 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 11 aceAnalytical�� www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Hope Valley Pace Project No.: 92668585 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92668585001 Outfall 001 SM 254OD-2015 776462 92668585001 Outfall 001 SM 521OB-2016 776284 SM 521OB-2016 92668585001 Outfall 001 Colilert-18 776183 Colilert-18 Date: 05/30/2023 08:43 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch 776598 776184 Page 9 of 11 r � PaceAnalwical Company: __ 1� Address: Lr1AllY-vf--LUaIUUY Analytical) Request Doct ni , Chain -of -Custody is a LEGAL DOCUMENT - Complet.- a' r t ,4avent ]ti;''hl; tcrmauo, — - Imail To: Copy T-.- + Site Co section InfoiAddress /1J 'i4,' � L'rrJ Customer P ject Name Number. :.fate:ountyJC:ty: Time Zone CoUec(ed: ' { jIT[ jMT( )CT kjIET , Phone: 3 66-75•5_ 794.a Site/Facility ID N. `0 1-;arize Monitoring? Email: s J No C�ollrected By (print : Purchase Order #. DW PWS ID q fvt ar t41t �tw Quote #: DW Location Code Collected By (s gnature): Turnaround Date Required- mme 71-a e y PacFe on Ice• l Yes ( J No Sample Disposal Rush: Field filtered (J appficabie)}: ( j Dispose as appropriate ( ) Return (J Same Day j j Next Day y LAB USE ONLY- Affix Workorder/Login Label Here or list Pace Workorder Number or 266858 ALL SHAC CerL,=ner P ,.�.,,, "Preservative �`— p 92568585 }pes` (ii ili? li. (6) methanol, (7) sodium bisulfate, ($) sodium thiosulfare, (�; hexane, (Ai ascoru t acid, (S) ammonium sulfate, ;'r)rromum hydroxide, (D) TSP, (U) Unpreserved, (0) Other Ijes (INO V) ( )HoldArchive; 1 J2Day ( 13Day f jaDa iSDa I Hold (Expedite Charges Apply) ( Y Andiy5:s: L Matrix Codes (insert in Matrix box below): Drink'ng Water (DW), Ground Water (GW), Wastewater (WW), Product (P), Sot /Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (T5), Bioassay (B), Vapor (V), Other (OT) l() ^� Camp./ Colected (or Res # if Customer5amp"e(j3 Matrix" Grab �Co—mptoS �os—tart) Composite End CI Ctns �i t_ oat e ( i me Date T7cr3e CD U. 04 a 6-1-4 Customer Remarks / Special Conditions / Possibr,' Hazards: Type of Ice Used; Packing Material Used: Relinquished by/Company: (Signature) L t<q_e; A-;�J Rehli@uished by/Company: (Signature) 0 by/Company: (Signature) lue D,V None SHORT HOLDS PRESENT (<72hourx;:( y Lab Tracking #: 2610299 --- ....«k. ­­P, —evni],SL: Custody Seals Present/Intact Y NA Custody Signatures Present NA Collector Signature Present N NA Bottles Intact NA b"orrect Bottles P" N NA Sufficient Volume NA Samples Received .n -ce ®Y N NA VOA - Headspace A=ceptable Y N{R� USDA Regulated Soils (�`� •�r^�, Samples in <°ulding --ime Residual chlorine Present Y N NA4 C1 Strips: Sample pH Acceptable Y Ni IN Stripat Sulfide Present Y NA Lead Acetate Strips: LAB USE ONLY; Lab Sample # t Comments: isamp es received vla. -, Radchem sample(s) screened (<500 cpm): Y N NA a —I- FEDEX UPS � Clieni :Courier Pace Courier Date/Time: Recel ed by/Company (Signature) Date/Time: MT/L LAB USE ONLY C' Table #! Acctnum: Date/Time: rReceivedby/Comp ny: ignatur l t3ate/J m: Date/Time: IReceived WComoany; (Signature) Lab Sample Temperature Info: Temp Blank Received: Y N NA Therm ID#: o o Z Cooler 1 Temp Upon Receipt:9-ci— oC Cooler I Therm Corr. Factor: — t oC Cooler I Corrected Temp: _..2-'R_oC Comments: Template. Trip Blank Received: y N NA ?Prelog:n: HCL McOH TSP Other Me: EPM. Non Conformdnce(s): Page: 0 : Matrix Itemtr BP4U-125 mi. Plastic Unpreserved (N/A) (C:•) OP3U.250 ml. Plastic Unpreserved (N/A) h BP2U 500 ml, Plastic Unpreserved (N/A) w 8P]U-1 ;jter Plastic .npreserved (N(A) _ - f BP45 125 mL PlaWc H2SO4 (pH < 2; (C! ) l w8P3N-250mL / pia•,ts HNC3 [pH < 2� a3 - � I r► d�r i E � N E# V - p a. t3 � � f l SP4Z-125 mL Plastic ZN Acetate & NaOH P X j 81"48425 ml. P'.astic NaOH PH . 12 'C1-) WGFU-Wide mouthed Glass 3ar Unpreserved AG1U-1 liter Amber Unpreserved (N/A) (Cl-) AG1ii 1 Itter Amber HO (pH < 2) AG3U-250 ML Amber npreservecl(NfA ,G-'S AG15 1 liter Amber H2SO4 (pH c 2) AG3S-250 mt Amber H2SO4 (pH < 2) AG3A(OG3A)-250 mL Amber NH4C! (N,fA){Cj, D69H-40 mL VOA HCl N/A! VG9T-40 mL VOA Na2S203 (N/A) VG9U-40 mL VOA Unpreserved (NIA) OG9P-40 mi. VOA H3PO4 (N/A)� } VOAK (3 vials Per kil)-5035 kit (N/A) V/GK (3 vials pe(kit)-VPH/Gas kit (N/A) SPST 125 ml. Sterile Plastic (N/A jab) - SPIT-250 mL Ste-iie Plastic (N/A - lab) 8P3A-2S0 ml. Plastic (NH212SO4 (9.3.9.7) A60U-100 mL Amber Unpreserved vials (N/A) VSGU-20 ml. Scintillation vials (N/A) DG9U-40 mL Amber Unpreserved vials (N/A) "'tea AaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 May 04, 2023 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92664524 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on April 27, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 'raceAnal�J�ical J' www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92664524 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC, Page 2 of 11 I aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley 92664524 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92664524001 Outfall 001 SM 2540D-2015 VLG 1 PASI-E SM 521OB-2016 SRS 1 PASI-E Colilert-18 AED 1 PASI-E PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92664524 Sample: Outfall 001 Lab ID: 92664524001 Collected: 04/27/23 13:00 Received: 04/27/23 15:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D-2015 Pace Analytical Services - Eden Total Suspended Solids 4.7 mg/L 2.9 1 04/28/23 12:29 5210B BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521 OB-2016 Pace Analytical Services - Eden BOD, 5 day 7.0 mg/L 2.0 1 04/28/23 12:15 05/03/23 14:20 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms 2.0 MPN/100mL 1.0 1 04/27/23 18:22 04/28/23 12:24 Date: 05/04/2023 10:16 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. W Page 4 of 11 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92664524 QC Batch: 771038 Analysis Method: SM 2540D-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92664524001 METHOD BLANK: 4002659 Associated Lab Samples: 92664524001 Parameter Units Total Suspended Solids mg/L LABORATORY CONTROL SAMPLE: 4002660 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 4002661 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 4002662 Parameter Units Total Suspended Solids mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.5 04/28/2312:22 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 226 90 90-110 92664372001 Dup Result Result 48.3 44.3 92664221001 Dup Result Result 1640 1410 RPD Qualifiers 9 RPD Qualifiers 15 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/04/2023 10:16 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 11 aceAnalytical =. www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92664524 QC Batch: 771098 Analysis Method: SM 521OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210B BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92664524001 METHOD BLANK: 4002894 Associated Lab Samples: 92664524001 Parameter Units BOD, 5 day mg/L LABORATORY CONTROL SAMPLE: 4002895 Parameter Units BOD, 5 day mg/L SAMPLE DUPLICATE: 4002897 Parameter Units BOD, 5 day mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 05/03/2312:55 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 198 185 93 84.6-115 92664498001 Dup Result Result RPD Qualifiers 215 233 8 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/04/2023 10:16 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 - PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92664524 QC Batch: 770966 Analysis Method: Colilert-18 QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92664524001 SAMPLE DUPLICATE: 4002472 Parameter Units Fecal Coliforms MPN/100mL 92664498003 Dup Result Result RPD Qualifiers 1.0 ND D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/04/2023 10:16 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Hope Valley Pace Project No.: 92664524 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/04/2023 10:16 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 11 FlaceAnalytical� www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Hope Valley Pace Project No.: 92664524 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92664524001 Outfall 001 SM 254OD-2015 771038 92664524001 Outfall 001 SM 521OB-2016 771098 SM 521 OB-2016 92664524001 Outfall 001 Colilert-18 770966 Colilert-18 Date: 05/04/2023 10:16 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch 771182 770967 Page 9 of 11 CHAIN -OF -CUSTODY analytical Request Document PaceAna"ica' Chain of Custody is a LEGAL DOCUMENT Complete all relevent fields LAB USE ONLY- Affix Workorder/Login Label Here or List Pace Workorder Number or WO# ' 92664524 ALL sHa Container PreservativrAde�111111111111111111111111 92664524 __ ._._.._-- °" Preservative types (1) n Inc acid, (2) sue.._... _ , , (b) urethan , (7) sodium btsu fate (S) sod um thiosulFate, (>} hexane, (A) ascorb c acid ;ti; ammon +m sulfate (C onium hydroxide, (D) TSP, :'U! Unpreserved, (0) Other , _ _ Company ll� 8 rig informat on -Uo Rep ar To , Ema: To �� t Copy T joa t rte Col ection In Address: /O c l : f"-X tqvm�Analyses Lab Profile/Line: f� Customer P :ect Name/Number: State:Countty/City: Time Zone Collet ed: �r 1S5a/7 ( I PT I I MT ( I CT h6,KT & t� r b cc `i (} 4a � Lab Sample Receipt Checklist: ._ — -"'- Custody Seals Present Intact Y QNR Cv t, dy Signatures Present N NA Collector Signature Present N NA BottFes Intact N NA Correct Bottles N NA Sufficient Volume N NA Samples Received on ce (,4ix NA VOA - Headspace Acceptable Y N JE USDA Regulated Soils Y N Samples in -iolding Time ii::PN NA Residual Chlorine, P e nt Y 67NA C1 Strips: 0 L Sample pit Acceptable Y N a9 pH Strips: Sulfide_ Present Y NO Lead Acetate Strips: LAB USE ONLY: Lab Sample # :, Comments: Phone: 3 34, 755 76g5 Erna" Site/Fac ty D N. Compi ante Monitoring? '�e,5 ( ) No Collected By (print J ('} .JC' -/ :4 ?i-j�l Purchase Order #. Quote#. DW PWS ID N: DW Location Code Collected By (signature) ( Turnaround Date Re u red: q Imme 'ate y Pace on Ice: j )Yes ( )No Sample Disposal ( I D'--pose as appropriate ( I Return I Arch ve ��.... Rush: f I Same Day j ) Next Day ( 12 Day 1 1 3 Day ( j 4 Day ( I S Day xpedite Charges Apply} Field Filtered (if applicable): I I Yes ( I No Analysis: Y • Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), Prodw, t (P), Soil/Solid (SQ, Oil (OL), W pe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) Customer Sample O Matrix' Comp j Grab Col ected (or Composite Start) Composite End Res Cl N of Ctns Date Time Date Time 27-0 !'fop 2 ✓ $ D11 5 T5S -� ___- ac ' uz.tomer Remarks / Speua Condit on'. Possible Hazards. % f Type of Ice Used: Wet Blue Dry None SHORT HOLDS PRESENT (<72 hours): N N/A lab Sample Temperature info: Temp Blank Received: Y NA Therm IDN: _1!4 - 0 Cooler 1 Temp Upon Receipt: ,�oc Cooler 1 Therm Corr. Factor: oC Cooler 1 Corrected Temp: _ oC Comments: Packing Material Used: Lab Tracking N: 2610299 Radthern sample(s) screened (<500 cpm): Y N NA Samples received via: FEDE4 0 NpClient Courier Pace Courier Relinquished by/Company: (Signature) P Date/Time: J/ Date/Time: Received by/C any (Signature) �,f. eceived by/Company: ignature) Date i e: "Ly •� 's(sTableN: Date/Time: MTJL LAB USE ONLY Acctnum: Template; Prelogin: PM: Pill: Rel�lquished by/Company (Signature) Trip Blank Received: Y N NA HCL McOH TSP Other Re ulquished by/Company: (Signature) Date/Time. Received by/Company: (Signature) Date/Time: Non Confor......... . _­­­mance(s): YES / NO Page: of: FaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 March 06, 2023 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92654116 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on February 27, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones pCCRe45 TNI <' REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 PaceAnallfical J` www.pacelabs.com Project: Hope Valley Pace Project No.: 92654116 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 633 VirginiaNELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley 92654116 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92654116001 Effluent SM 2540D-2015 VLG 1 PASI-E SM 5210B-2016 MWF 1 PASI-E Colilert-18 SRS 1 PASI-E PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92654116 Sample: Effluent Lab ID: 92654116001 Collected: 02/27/23 13:00 Received: 02/27/23 15:25 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 254OD-2015 Pace Analytical Services - Eden Total Suspended Solids 2.9 mg/L 2.5 1 02/28/23 13:34 5210B BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521OB-2016 Pace Analytical Services - Eden BOD, 5 day 15.0 mg/L 2.0 1 02/28/23 11:24 03/05/23 10:55 R6 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms 1.0 MPN/100mL 1.0 1 02/27/23 18:09 02/28/23 12:33 Date: 03/06/2023 10:50 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 11 / �r rOaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92654116 QC Batch 758531 Analysis Method: SM 254OD-2015 QC Batch Method: SM 2540D-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92654116001 METHOD BLANK: 3940018 Matrix: Water Associated Lab Samples: 92654116001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 02/28/23 13:31 LABORATORY CONTROL SAMPLE: 3940019 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 256 102 90-110 SAMPLE DUPLICATE: 3940020 92654066002 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 79.6 86.4 8 SAMPLE DUPLICATE: 3940084 92654260002 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 3140 3040 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/06/2023 10:50 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 11 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92654116 QC Batch: 758457 Analysis Method: SM 521 OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210E BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92654116001 METHOD BLANK: 3939589 Associated Lab Samples: 92654116001 Parameter Units BOD, 5 day mg/L LABORATORY CONTROL SAMPLE: 3939590 Parameter Units BOD, 5 day mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 03/05/2310:38 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 198 226 114 84.6-115 SAMPLE DUPLICATE: 3939592 92654127001 Dup Parameter Units Result Result BOD, 5 day mg/L 1070 1030 RPD Qualifiers 4 R6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/06/2023 10:50 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 FaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92654116 QC Batch 758368 Analysis Method: Colilert-18 QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92654116001 SAMPLE DUPLICATE: 3939345 92654116001 Dup Parameter Units Result Result RPD Qualifiers Fecal Coliforms MPN/100mL 1.0 1.0 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/06/2023 10:50 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 14, dace Analytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Hope Valley Pace Project No.: 92654116 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS R6 The RPD between valid sample dilutions exceeded 30%. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/06/2023 10:50 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 11 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Hope Valley Pace Project No.: 92654116 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92654116001 Effluent SM 2540D-2015 758531 92654116001 Effluent SM 5210B-2016 758457 SM 5210B-2016 92654116001 Effluent Colilert-18 758368 Colilert-18 Date: 03/06/2023 10:50 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch 758682 758369 Page 9 of 11 CHAIN -OF -CUSTODY Analytical Request Document LAB USE ONLY- Affix Warkorder/Loy:^ `- a^..•—i:..0".tarnrl. A.,rj—h—nr Pat:eAna"Jcai MT1L WO :92654 116 Chain-of•Custody is a LEGAL DOCUMENT complete all reievera fields Company Billing Informat on- 0� r , �` LAC- ALL SHADED AR i + f t Lontarner Preservat ,, T,:;I2t 921554116 1 " Preservative 'ypes i1, nitric 1 i2; sulfur acid, (3) hydrochloric ac d,14) sodium hydroxide, (5) zin: acetate Addre s f C to e7 Re a, .ro P .r fi s U Email To. % " j "' rf � (6j methanol, (71 sodium bisulfate, (8) sod um thfosulfate. (4) hexane, (A) ascorbic ac d. (B) amm n um sulfate, (C r� on um hydroxide, (b{ T: P, (U) Unpreserved, (0) Other Copy T t " to Cot(ecGon Info "Adc re;s: nit �': - - Analyses Lab Profile/Line: j 1 / ✓� Cr rra ff..r Cu tomerF e tName,^ltimber 'n VI (r. fate: [bounty/City Time ZoneCo)e: ed• I Lab Sample Receipt Checklist: Custody Seals Present,lntact Y N A Cu,t„ dy Signatures Present N NA a it ! ( )PT( JMT` 'I CT (y,KT �GO Cn _ Phone' yy // J;�6p` ��,�"7�'�f5 Sitet atility tO i7 von pliance Monitonng'' Email: (tKes ( 'No Collector Signature Present N NA Bottles intact N NA Correct Bottles N NA Collected By (print?: Purchase Order # DW PWS iD g. ll + �t er ft) �(e6 : ` QU0te q: DW Locatron Code, Sufficient volume N NA Samples Received nn "ce N NA v:rA - Headspaae A:csptable Y N N Collected By (signature)- n----•- Turnaround Date Re uir=:0: q ;>r' ate y Pactee' on Ice: � 1 Yes f ) No USDA Regulated So Is Y td t� Samples _n folding lme t(3 N NA Residual Ch10 " Y 4 } NA Sample Disposal Rush; •».= Field filtered {if applicable): Dispose as appropriate ( ► Return ( )Same Day ( j Next Day ( J Yes [ J No { } pent C2 strips: ! l Archive _ ( ) 2 Oa 3 Da 4 Da V (1 Y i 3 y() S Day j�j Sam le H Ac¢q>?Yr HA P P . Hold: r � =:r r��^ IteChargesAppy, Analysis: � pH Strips: C Sulfide Present Y ;3 NA Lead Acetate Strips: ' Matrix Codes (Insert n Matrix box below): Drinking Water (DW), Ground tiNater (GW), Wastewater (WW), Product (P), Soil/Solid (SQ, Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) �.,__•..: i '.Y LAB USE ONLY: Comp / Collected (cir Res 4 of Composite End � , U Lab Sample # roament 3 : Customer Sample 10 Matrix ' P Grab Composite Start} � Ctns .4 4u Date Time Date T me Cc ✓ Ll t 0z} 5 76, GraZt 2 z7- /'*� 2- r-K :eo • F c( G I i . • i .ustcmer Remarks -` Special Conditions ' Possib e Hazards: Type of ice Used: t'vet Blue Dry SNORT HOLDS PRESENT hours). h' N N/A L afa Sample Temperature Info: }None �' Packing Material Used: � �Vlr, Lab Tracking lt: 2610299 6 1 O Temp Blank R c bed N NA Therm IDit.� f G J .3 00 C �.G''- / , .... Cooler 2 7e p Upon Receipt:.. aC i Radchem sample(s) screened (<SDD cpm): Y N NA Samples received via: ��._., Cooler 1 Therm Corr Factor-- - oC FEDEX UPS Clier Courier Pace Courier Cooler 1 Corrected Temp: —•_ 0-pc Rel'n uished b tCom an (Signature) Date Time: Recei <d b /Conn an q Y P Y ( g ) / Y p V: (" Igo rture) Date/Time: MT3L LAB USE ONLY Comments ��,Z � Table tt: f° i Reli shed by/Company (Signature) Date/Time: f. , . , •a l y(Company- ;,'signature) Date/Time: Acctnum Template; Trip Blank Received: Y N NA oPrelogin: HCL !cOH TSP Other Relint(bished by/Company (Signature) Date/rime: Received by/Company (Signature) r�— DateJTime: PM: Non Conformarce(sj PB: YES f No r, f d CD m Matrix +-.-- cc 4 ; m I N D w`-' Item# ZZA//xZ zzzzz BP41.1-125 ml Plastic Unpreserved (N/A) (Cl-) { BP3U•250 mL Plastic Unpreserved (N/A) MU-500 rnl Plastic Unpreserved (N/A) BPIU-1 liter Plastic Unpreserved (N/A) BP45-125 mL Plastic 1-12504 (pH < 2) (Cl-) MN-250 mL plastic HNO3 (pH < 2) BP4Z-125 mL Plastic ZN Acetate & NaOH (>9) ��Jzz BP48-125 mL Plastic NaOH (pH > 12) (Cl-) i WGFU-Wide-mouthed Glass jar Unpreserved AGIU liter Amber Unpreserved (N/A) (Cl-) AG1H-1 liter Amber HCI (pH < 2) AG3U-250 ml. Amber Unpreserved (N/A) (Cl-) AG15-I liter Amber H2SO4 (pH < 2) AG3$-250 mL Amber H2SO4 (pH < 2) AG3A((>G3A)-250 ml. Amber NH4Ci (N/A)(CI-) DG9H-40 ml. VOA HCI (N/A) I VG9T 40 ml VOA Na2S203 (N/A) VG9U40 mL VOA Unpreserved (N/A) DG9P-40 ml. VOA H3PO4 (N/A) I I � VOAK (3 vials per kit}5035 kit (N/A) i WGK (3 vials per kit)-VPH/Gas kit (N/A) i SP57-125 mL Sterile Plastic (N/A — lab) i SPIT-250 ml. Sterile Plastic (N/A — lab) zzzz —Z MA-250 mL Plastic (NH2)2504 (9.3-9.7) AGOU-100 mL Amber Unpreserved vials (N/A) V5GU-20 ml. Scintillation vials (NIA) OG9U-40 ml Amber Unpreserved vials (N/A) : 7� .0 � t3 0 !U s -« rn td 0 Zl so Ms -' 4 Ln A n •�► O Ga N M A ot it 1I PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 February 06, 2023 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92649329 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on January 30, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones Q pCCRFO, `BOW REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 �aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92649329 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 . PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley 92649329 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92649329001 Effluent SM 2540D-2015 VLG 1 PASI-E SM 5210B-2016 MWF 1 PASI-E Colilert-18 AED 1 PASI-E PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92649329 Sample: Effluent Lab ID: 92649329001 Collected: 01/30/23 11:00 Received: 01/30/23 13:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 254OD-2015 Pace Analytical Services - Eden Total Suspended Solids ND mg/L 2.5 1 01/31/23 11:55 5210E BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521OB-2016 Pace Analytical Services - Eden BOD, 5 day 23.4 mg/L 2.0 1 01/31/23 10:17 02/05/23 11:59 R6 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms ND MPN/100ml- 1.0 1 01/30/23 15:21 01/31/23 09:48 Date: 02/06/2023 08:12 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 11 Fa nceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92649329 QC Batch: 752829 Analysis Method: SM 2540D-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92649329001 METHOD BLANK: 3911285 Matrix: Water Associated Lab Samples: 92649329001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 01/31/23 11:53 LABORATORY CONTROL SAMPLE: 3911286 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 242 97 90-110 SAMPLE DUPLICATE: 3911287 92648868005 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 25.4 26.3 3 SAMPLE DUPLICATE: 3911288 92649286001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 178 167 6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/06/2023 08:12 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 11 0411- raceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92649329 QC Batch: 752819 Analysis Method: SM 521 OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210E BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92649329001 METHOD BLANK: 3911228 Associated Lab Samples: 92649329001 Parameter Units BOD, 5 day mg/L LABORATORY CONTROL SAMPLE: 3911229 Parameter Units BOD, 5 day mg/L SAMPLE DUPLICATE: 3911231 Parameter Units BOD, 5 day mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 02/05/2311:42 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 198 208 105 84.6-115 92649247001 Dup Result Result RPD Qualifiers 1280 1280 0 R6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/06/2023 08:12 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 '[ �aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92649329 QC Batch: 752669 Analysis Method: Colilert-18 QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92649329001 SAMPLE DUPLICATE: 3910737 Parameter Units Fecal Coliforms MPN/100mL 92649329001 Dup Result Result RPD Qualifiers ND ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/06/2023 08:12 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 r PaceAnalXical www.pacelabs.com Project: Hope Valley Pace Project No.: 92649329 DEFINITIONS QUALIFIERS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS R6 The RPD between valid sample dilutions exceeded 30%. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/06/2023 08:12 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 11 f r.. aceAnalytica! www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Hope Valley Pace Project No.: 92649329 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92649329001 Effluent SM 2540D-2015 752829 92649329001 Effluent SM 5210B-2016 752819 SM 5210B-2016 92649329001 Effluent Colilert-18 752669 Colilert-18 Date: 02l06i2023 08:12 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch 753177 752671 Page 9 of 11 CHAIN -OF -CUSTODY Analytical Request Document LAB USE CINLY- Affix Workorder/Logic, I abel Here or List Pace Workorder Number „r rr PaceAnalytical ` Company: Address: Report To: Copy To: Customer Project Name/Number: m-of-Custody is a LEGAL DOCUMENT -Complete all rzhevont fields WO#:92649329 Billing Information: L Phone: 5 5e —Ieq-c' Site/Facility ID tt: Email: j Collected By (print): Purchase Order # � ,�r // II" c „ rvCr �-Y'in t�.�, J c',YtL%F1,�,-4uote ff: Email To: Site Collection Info/Addr Stat AtrCounty/City: Date Required: � %'✓� 4.�-f� • � ci �"ijtt�c.e.,�/'r(._ _._ _.._..____. _.._ _.._. _ . _ _ ____._ _.....__ _._ Sample Disposal: — Rush: Field Filtered (if applicable): ( J Dispose as appropriate ( J Return i [ ] Same Day [ ] Next Day [ ] Yes [ ] No 4 [ ] Archive: [ ] 2 Day ( ] 3 Day [ ] 4 Day ( ] 5 Day v, [ ) Hold: Ex ectite Char es A I Anal 515 F, A LSHADED erreservativ IIIIIIiI IIIIIIIIIIIIII ContainPe Type _ - - - 92649329 vl,w 1, ! p-, �. _^ _ Preservative Types: (1) nitric acid, (2) sulfuric acid, (3) hydrochloric acid, (4) sodium hydroxide, (S) zinc acetate, — --- ess0) methanol, (7) sodium bisulfate, (8) sodium thiosulfate, (9) hexane, (A) ascorbic acid, (B) ammonium sulfate, ammonium hydroxide, (D) TSP, (U) Unpreserved, (0) Other Analyses 1 11) Profile/Lin(.: Time Zone Collected: LjPT,[_]MT_[-IC fi-J T— Compliance Monitoring? ["-Yes [ ] No DW_location _Code: _ Immediately Packed on Ice: f ' Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), i Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (.AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) Customer Sample ID P Matrix * i Comp /i � Grab i Collected (or Composite � Composite Starts—( Date Time � Date End _ ( Time Res ' Cl q of Ctns J 1 i } 1 Customer Remarks / Special Conditions / Possible Hazards: t i Relinquished by/Co pa y: (Signature) Reffiq uished by/Company: (Signature) in CD 0 Reiiquished by/Company: (Signature) ___ ._. _ .. ° — � Type of Ice Used: We Blue Dry None SHORT HOLDS PRESENT (.72 hour:, )N N/A LAB Sample f temperature Info Packing Material Used: r [ Lab Tracking N:r !Samples received v�> ) Radchem sample(s) scre nned (_500 cpm): Y N ryk / j FEDEX UPS Client urfer Pace Courier "'I ' > _.J,�. ' Decelyed­by/ y: Igo ure) I Date im onto Inn uer nNl v Date/Time: jfR ��r Z Table 4: Date/Time: Date/Time: Received by/Company.(Signature) Date/Time: — lAcctnum: ETemplate: _ Prelogin: Date/Time:IPM: %PB: Trip Blank Received: Y N NA HCL McOH TSP Other Non Conformance(%): Page: _ YES / NO of: rV9,nnx < x Il!'Iriri fY -7 fu (p / `/ / /� - nrl. 1''laslir. Ih)(ae;irrvt rl (rJIA) (C'I-) i 3 . • v' r� 3 Ix" X r A/ / ! /_ / /_ / iiZ' Z V V — _) n) RP311•? ;O nIL Pl,ntir UnPO w,v(•d (r1•/n) lrP?U-S00InL Pln;ti( IJill nr^sc1Vr,I (NIA)-717 T ra r� r I.• (` - i- w .., I , ttPlll-1 their Plastic I1` jm-,&rvcll (N/A) X_( r - 1, a BM-12S fill. Plastic 112504 (!)It < 2) (Cf) 0 / fi1131`4-? SO ml pfasl is I1PdO1 (l,l l < 2) r D- RP4Z-12 n)I. f"Iiaic 7rJ ncc;:rlr 7; tlaOI I ('•`)) 3 j lIP•111-125 ml Pl;i;tirICI) -- (U Q) r J tL - 4VG(U-Widv_mnntl,clf Ghs•. j.,r lfnf,r( scrvwf __...__._—..___.... . .........._._..__.._.__ rl �. nG1U-1 liter An)I)cr Unprv•.ervrd (N/A) (U) r;) i ry r; AG111-1 liter Arnf,er It(] (fill < ?} u a n - C � AG3U-?;0 nit. A,nf•er tlulerr;r,vc,1 (NIA) (CI) AG1S-11iti•rAnilnvll (11f1,f1 6, () r, c w ' ) AG3S-2SO rill. Amhor 101SO.1 (III1 < 2) / nG3n(nG3n)-� ;n nit. Arldll•r r:Ilac1(r1/n)(cL) � I «, U rl t) vc9r-10 mf. vnn Na?r,()3 (rJ//%) VG90-40 ml VOA Unpr...... tvrd (N/A) ___ _ . DG9P••10 mL VOA 1131104 (N/A) I, lu VOAK (3 vial, per kit)-rO ; Fit (N/A) w ; V/GK (3 vials per kit)•1(I'I I/G:rs ht (NIA) Sf)ST-125 nil- (wrilc r'lastir (iI/A-I'll.) -- SP2T-250 mL Sterif(r t'I.,slir (r11.1 -lab) ' n RP3A-210 mL Plastic (N112)21;04 (9.3-9.7) AGOU-100 mL Amber Unprewrvoll vial•' (N/A) VSGU-20 mL Srintillafinn vials (rl/A) DG911•40 nit, Andu,r Unl,rrsarvc•d vials (N/A) FaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 January 30, 2023 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Inc Pace Project No.: 92646995 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on January 16, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 15 f 1RaceAnalytical www.pacelabs.com Project: Hope Valley Inc Pace Project No.: 92646995 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 15 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Hope Valley Inc Pace Project No.: 92646995 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92646995001 Outfall 001 SM 254OD-2015 VLG 1 PASI-E SM 521 OB-2016 SRS 1 PASI-E Colilert-18 SRS 1 PASI-E TKN+NO3+NO2 Calculation MDW 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 KDF1 1 PASI-A EPA 365.1 Rev 2.0 1993 Zip 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 15 PaeeAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Inc Pace Project No.: 92646995 Sample: Outfall 001 Lab ID: 92646995001 Collected: 01/16/23 13:00 Received: 01/16/23 15:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D-2015 Pace Analytical Services - Eden Total Suspended Solids ND mg/L 2.5 1 01/17/23 17:23 5210E BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521OB-2016 Pace Analytical Services - Eden BOD, 5 day 43.4 mg/L 2.0 1 01/17/23 13:58 01/22/23 08:30 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms ND MPN/100mL 1.0 1 01/16/23 18:05 01/17/23 13:48 Total Nitrogen Calculation Analytical Method: TKN+NO3+NO2 Calculation Pace Analytical Services -Asheville Total Nitrogen 55.8 mg/L 0.040 1 01/25/23 14:47 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia 44.7 mg/L 0.50 5 01/24/23 13:27 7664-41-7 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Kjeldahl, Total 55.5 mg/L 2.5 5 01/23/23 18:22 01/24/23 05:00 7727-37-9 353.2 Nitrogen, NO2/NO3 pres. Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, NO2 plus NO3 0.32 mg/L 0.040 1 01/23/23 13:13 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 6.2 mg/L 0.10 2 01/26/2315:07 01/27/2314:01 7723-14-0 Date: 01/30/2023 08:55 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 61 M1,R1 Page 4 of 15 raceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Inc Pace Project No.: 92646995 QC Batch: 749919 Analysis Method: SM 254OD-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92646995001 METHOD BLANK: 3898247 Matrix: Water Associated Lab Samples: 92646995001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 01/17/23 17:21 LABORATORY CONTROL SAMPLE: 3898248 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 3898249 Parameter Units Total Suspended Solids mg/L Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 242 97 90-110 92647207001 Dup Result Result RPD Qualifiers 2780 2740 2 SAMPLE DUPLICATE: 3898348 92647026001 Dup Parameter Units Result Result Total Suspended Solids mg/L 2190 2330 RPD Qualifiers 6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /30/2023 08:55 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 15 nceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Inc Pace Project No.: 92646995 QC Batch: 749829 Analysis Method: SM 521OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210B BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92646995001 METHOD BLANK: 3897764 Associated Lab Samples: 92646995001 Parameter Units BOD, 5 day mg/L LABORATORY CONTROL SAMPLE: 3897765 Parameter Units BOD, 5 day mg/L SAMPLE DUPLICATE: 3897767 Parameter Units BOD, 5 day mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 01/22/23 08:05 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 198 204 103 84.6-115 92647062002 Dup Result Result RPD Qualifiers 145 172 17 R6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/30/2023 08:55 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 15 fpaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Inc Pace Project No.: 92646995 QC Batch: 749679 QC Batch Method: Colilert-18 Associated Lab Samples: 92646995001 SAMPLE DUPLICATE: 3897103 Parameter Units Fecal Coliforms MPN/100mL QUALITY CONTROL DATA Analysis Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden 92646995001 Dup Result Result RPD Qualifiers ND ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/30/2023 08:55 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 15 y PaceAnalytical n www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Inc Pace Project No.: 92646995 QC Batch: 750927 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92646995001 METHOD BLANK: 3902724 Associated Lab Samples: 92646995001 Parameter Units Nitrogen, Ammonia mg/L LABORATORY CONTROL SAMPLE: 3902725 Parameter Units Nitrogen, Ammonia mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.10 01/24/2312:46 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 5 5.0 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3902726 3902727 MS MSD 92647597002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.1 5.1 100 100 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3902728 3902729 MS MSD 92647597003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.1 5.1 102 102 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /30/2023 08:55 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 15 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Inc Pace Project No.: 92646995 QC Batch: 751089 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92646995001 METHOD BLANK: 3903371 Associated Lab Samples: 92646995001 Parameter Units Nitrogen, Kjeldahl, Total mg/L LABORATORY CONTROL SAMPLE: 3903372 Parameter Units Nitrogen, Kjeldahl, Total mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.50 01 /24/23 03:31 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 10 10.3 103 90-110 MATRIX SPIKE S MATRIX SPIKE DUPLICATE: 3903373 MS 92647597004 Spike Parameter Units Result Conc. Nitrogen, Kjeldahl, Total mg/L 0.50 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3903375 MS 92647597005 Spike Parameter Units Result Conc. Nitrogen, Kjeldahl, Total mg/L ND 10 3903374 MSD Spike MS MSD MS MSD % Rec Conc. Result Result % Rec % Rec Limits RPD Qual 10 10.5 11.0 100 105 90-110 5 3903376 MSD Spike MS MSD MS MSD % Rec Conc. Result Result % Rec % Rec Limits RPD 10 10.5 10.4 101 100 90-110 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /30/2023 08:55 AM without the written consent of Pace Analytical Services, LLC. Qual Page 9 of 15 t.. PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Inc Pace Project No.: 92646995 QC Batch: 751028 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92646995001 METHOD BLANK: 3903024 Matrix: Water Associated Lab Samples: 92646995001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, NO2 plus NO3 mg/L ND 0.040 01/23/23 12:52 LABORATORY CONTROL SAMPLE: 3903025 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, NO2 plus NO3 mg/L 2.5 2.5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3903026 3903027 MS MSD 92647609004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L 8.5 2.5 2.5 10.8 10.7 95 89 90-110 1 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3903028 3903029 MS MSD 92647614001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L 0.10 2.5 2.5 2.5 2.5 97 94 90-110 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /30/2023 08:55 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 15 FaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Inc Pace Project No.: 92646995 QC Batch: 751909 QC Batch Method: EPA 365.1 Rev 2.0 1993 Associated Lab Samples: 92646995001 METHOD BLANK: 3907012 Associated Lab Samples: 92646995001 Parameter Units Phosphorus mg/L QUALITY CONTROL DATA Analysis Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.050 01/27/2311:48 LABORATORY CONTROL SAMPLE: 3907013 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg/L 2.5 2.5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3907014 3907015 MS MSD 92646995001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 6.2 2.5 2.5 9.1 10.4 113 166 90-110 14 M1,R1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3907030 3907031 MS MSD 92647065001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L ND 2.5 2.5 2.7 2.7 109 109 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/30/2023 08:55 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 15 � ceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Hope Valley Inc Pace Project No.: 92646995 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS B1 Less than 1.0 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. R6 The RPD between valid sample dilutions exceeded 30%. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/30/2023 08:55 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 15 r0aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Hope Valley Inc Pace Project No.: 92646995 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92646995001 Outfall 001 SM 254OD-2015 749919 92646995001 Outfall 001 SM 521OB-2016 749829 SM 521OB-2016 750060 92646995001 Outfall 001 Colilert-18 749679 Colilert-18 749680 92646995001 Outfall 001 TKN+NO3+NO2 751728 Calculation 92646995001 Outfall 001 EPA 350.1 Rev 2.0 1993 750927 92646995001 Outfall 001 EPA 351.2 Rev 2.0 1993 751089 EPA 351.2 Rev 2.0 1993 751235 92646995001 Outfall 001 EPA 353.2 Rev 2.0 1993 751028 92646995001 Outfall 001 EPA 365.1 Rev 2.0 1993 751909 EPA 365.1 Rev 2.0 1993 752029 Date: 01 /30/2023 08:55 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 15 err j CHAIN -OF -CUSTODY Analytical Request Document LAB USE pNLY- Affix Workorder/Loein Label Here or List Pace Workorder Number or >GaceAnaiyticai` Chain -of -Custody is a LEGAL DOCUMENT -Complete all relevent fields �`'O +9264Vc99 + W' '�' + mpanY: Billing Information: v �. if � � aLL sHAaE i ���� III Container Preservative Typr 92646993 dre s: 5 e o n o ' Preservative Types: (1) nitric acid, (2) sulfuric acid, (3) nyorUL111 ,. por To , Email To: j 6 r _ f? ' 6e . C ') (6) methanol, (7) sodium bisulfate, (8) sodium thiosuifate, (9) hexane, (A) ascorbic acid, (B) ammonium sultate, (C moniuni hydroxide, (D) TSP, (U) Unpreserved, (o) Other pY 1 i Site Collection Info Address: r 1 t/( f. D /C$ Lei t ; 'f /�lBr1 t Analyses Lab Profile/Line: ,tomer PrJjject Name/Number: State: 'Ccounty/City: Time Zone Coiled ed: Lab Sample Receipt checklist: ' '.:� ( ] PT ( ] MT [ ] CT ]�T /) 6 � �'�� s) .Custody Seals Present/intact Y N NA Custody Signatures Present Y N NA Y g me: ' 1 3 tv l SS 76q!5 Site/Facility ID !t: Compliance Monitoring? ail: 4,.] s ( ] No i` Collector Signature Present Y N N;, °+i 'l> C Bottles Intact Y N NA correct Bottles Y N NA leered By (print Purchase Order N: DW PWS ID ##: / Quote #: DW Location Code: r: -t- Sufficient volume Y N NA ived on Ice Y N NA Samples Recediately VOA - Headspace Acceptable Y N NA lected By (signature): Turnaround Date Re aired: l ImmePacked Ped on Ice: i ( ]Yes ( ]No `;.„�> "USDA Regulated Soils Y N NA Samples in Holding Time Y N NA Residual Chlorine Present Y N NA nple Disposal: Rush: Field Filtered (if applicable): Dispose as appropriate ( ) Return ( j Same Day I ) Next Day ( j yes ( ] No h. i .. r� V Cl Strips: _ Archive: _ [ ] 2 D2y ( ] 3 Day [ ] 4 Day ( ] 5 Day -- �� Sample pH Acceptable Y N NA Hoicl: _ (Expedite Char7;es Apply) Analysis: !' !' -- pit Strips; Sulfides Present _---_ v N NA Lead Acetate Strips: )atrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water(GW), Wastewater (WW), •oduct (P), Soil/Solid (51.), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) 'a � j _ -LAB USE ONLY: Lab sample # / Comments: Comp i Collected (or Composite End Res # of >tomer Sample ID p Matrix " Grab Composite Start) Cl Ctns Q 'U (Y1 lL Date Time Date Time 1G / DO / G-rab I-I-23 lit.lid• 2— ) HOD TSS ; Tel -- —.......... .._ ........ _ tourer Remarks / Special Conditions / Possible Hazards: Type of Ice Used; Wet Blue Dry None, SHORT HOLDS PRESENT(<72 hours): , ,'' N N/A Lab Sample Temperature Info: 'Temp Blank Received: Y N, NA Therm IDq: u- ¢ ti Packing Material Used: Lab Tracking g O°� k Cooler 1 Temp Upon Receipt �_oC Radchem samples) screened (<SOQ cpmj: Y ." N NA Samples received via: ,. C j Cooler 1 Therm Corr, Factor. Z oC FEDEX UPS . lien Courie ace Co )er Cooler 1 Corrected Temp: .? i oC Comments: squished by/Company: (Signature) Djate/7ime: Rec ' ed by/Company�Signature) Date/Time: MTJL LAB USE ONLY )! Table k: 'j,' Ez U l Acctnum: nqui d by/Company: (Signature) Date/Time: Rec ived by/Co any: (Signature) Date/Time: Template: P Trip Blank Received: Y N NA _ A Prelogin: HCL McOH TSP Other squish— d by/Company: (Signature) Date/Time: Received by/Company: (Signature) Dace/Thee: PM: Non Conformante(s): Page: cn PB: YES / NO of: —___-- N g N O U O_ 0 N fD a T} 7 o 2 7 AL Matrix N 1-• Itemit _— BPaU-125 mL Plastic Unpreserved (N/A) (CI) BP3U-250 nil, Plastic Unpreserved (N/A) Bf'2V-500 mL Plastic Unpresolve(I (N/A) BPIU-1 liter Plastic Unpreserved (N/A) J Bras-1.25 mL Plastic 111104 (pi I < 2) (CI-) l BP3N-250 ant- plastic I INO3 (fill < 2) BP4Z-125 mL Plastic ZN Acetate & NaON (>9) BNB-125 mL Plastic Na011 (pit > 12) (CI-) '_FWGFU-Wide-mouthetrl Glassjar Unpreserved AGW-1 liter Amber Unpreserved (PJ/A) (Cl AG711-1 liter Amber I ICI (f)l I < 2) AG3U-250 rnf. Amber Unpreserved (N/A) (Cl-) AGIS-1 liter Amber 112504 (pU < 2) AG3S-250 mL AmIier 112SO.1 (pl1 < 2) / A63A(DG3A)-250 mLAmher N114C1 (N/A)(CI ) DG9N-40 mL VOA IICI (tJ/A) MT-40 mL VOA Na2520:i (N/A) VG%J-40 mL VOA Unpr+ served (N/A) DG9P-40 mL VOA 113PO4 (N/A) VOAK (3 vials per kit)-SO35 kit (rJ/A) V/GK (3 vials per kit)-VPl I/C,as E,it (N/A) SPST-125 mL Sterile Plastic (N/A— lah) SP2T-250 mL Sterile Plastic (N/A — Iih) BP3A-250 mL Plastic (NI12)2SO4 (9.3-11.7) AGOU-100 mL Amber Unpreserved vials (N/A) VSGU-20 mL Scintillation vials (N/A) DG90-40 mL Amber Unpreserved vials (PI/A) x m N IJ ru n -T- -- �r O ro n w C, -3 ZJ O T3 O x C) ru O O 0 0 Cr (n rU x �. CS 0 c n <` N � tT , 3 ru fj O rr 0- O O (:.y rr-rr l73 0 -0 {1 C U ro c� V7 rvR) ` �. T Y ti 1 (Il 0 N c o -% N• 3 C7 r� u CV ;� W O. N U n T r �w (U o it j� haceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 January 03, 2023 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92644014 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on December 27, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones �QQ pccRF��,� , P, I �eORAft REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 IceAnalytical " www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 CERTIFICATIONS Project: Hope Valley Pace Project No.: 92644014 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Wastewater Certification #: 633 North Carolina Drinking Water Certification #: 37738 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 raceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley 92644014 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92644014001 Outfall SM 254OD-2015 VLG 1 PASI-E SM 521OB-2016 MWF 1 PASI-E Colilert-18 SRS 1 PASI-E PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92644014 Sample: Outfall Lab ID: 92644014001 Collected: 12/27/22 11:00 Received: 12/27/22 12:35 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 254OD-2015 Pace Analytical Services - Eden Total Suspended Solids 2.5 mg/L 2.5 1 12/28/22 12:39 5210B BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521 OB-2016 Pace Analytical Services - Eden BOD, 5 day 13.2 mg/L 2.0 1 12/28/22 10:37 01/02/23 10:57 R6 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms ND MPN/100mL 1.0 1 12/27/22 14:55 12/28/22 09:51 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/03/2023 02:13 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 11 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92644014 QC Batch: 746161 Analysis Method: SM 254OD-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92644014001 METHOD BLANK: 3880711 Associated Lab Samples: 92644014001 Parameter Units Total Suspended Solids mg/L LABORATORY CONTROL SAMPLE: 3880712 Parameter Units Total Suspended Solids mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.5 12/28/22 12:36 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 230 92 90-110 SAMPLE DUPLICATE: 3880713 92644019001 Dup Parameter Units Result Result Total Suspended Solids mg/L 790 855 SAMPLE DUPLICATE: 3880714 92644019004 Dup Parameter Units Result Result Total Suspended Solids mg/L 102 102 RPD Qualifiers 8 RPD Qualifiers 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /03/2023 02:13 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 11 1 aweAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, INC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92644014 QC Batch: 746126 Analysis Method: SM 521 OB-2016 QC Batch Method: SM 521 OB-2016 Analysis Description: 5210E BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92644014001 METHOD BLANK: 3880571 Associated Lab Samples: 92644014001 Parameter Units BOD, 5 day mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 01 /02/23 10:25 LABORATORY CONTROL SAMPLE: 3880572 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day mg/L 198 191 96 84.6-115 SAMPLE DUPLICATE: 3880574 92643981002 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 121 129 6 R6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /03/2023 02:13 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 VaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92644014 QC Batch: 745987 QC Batch Method: Colilert-18 Associated Lab Samples: 92644014001 SAMPLE DUPLICATE: 3880227 Parameter Units Fecal Coliforms MPN/100mL QUALITY CONTROL DATA Analysis Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden 92644053001 Dup Result Result RPD Qualifiers 2.0 2.0 0 Results presented on this page are in the units indicated by the "Units' column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/03/2023 02:13 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Hope Valley Pace Project No.: 92644014 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS R6 The RPD between valid sample dilutions exceeded 30%. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/03/2023 02:13 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 11 GO dace Analytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Hope Valley Pace Project No.: 92644014 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92644014001 Outfall SM 254OD-2015 746161 92644014001 Outfall SM 521OB-2016 746126 SM 521 OB-2016 92644014001 Outfall Colilert-18 745987 Colilert-18 Date: 01/03/2023 02:13 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch 746295 745988 Page 9 of 11 . CHAIN -OF -CUSTODY Analytical Request DOCLlment Pacek7c lyfiCc?l Chain -Of -Custody is a LEGAL DOCUMENT - Complete all re event fields LAB USE ONLY- Affix Workorder/Login Label Here or List Pace Workorder Number or MTJL Log -in Numhor tag,,.. Wp : 92s44�D 14 ALL SHADE[ 'It Container Preservative lype I�' II� II I I II I I'll'I Preservative Types: (1) nitric acid, (2) sWfuric 92644014 (S) methanol, (7) sodium bisulfate, (P.) sodium thin..-..._.�, ,.,, „�,,,, �e, (q) ascorbic acid, (!3) ammonium sullate. (C rr onium hydroxide, (D) TSP, (U) Unpreserved. (0) Other �' Analyses Lab Profile/Line: Company: . o ,, (le,. V / G.: Billing Information: Add re s: �P Repor To' r • Email 1'0: m ` e. •' ` • �' fr�� �.., Copy T a �I n r Site Collection Info/Address: �f L ?• r !O j l�C'r1: t i4 yq,, 1 Customer Pr ject Name/Number ^ !State: cCounty/City: Time Zone Collec ed: �Soi7 [ 1 PT [ 1 IT [ ] CT [�}^ET �+t i V? :.. � cc ':Z ;; 4J I-L Lab sample Receipt. Checklist.: Custody Seals Present/Tntact X HA - Custody Signatures Present Ci' 7 NA Collector Signature Present NA Correct Intact NA Correct Bottles _lN NA Sufficient Volume (y N NA Cam! Samples Received on Ice 15N NA VOA - Headspace Acceptable Y N i USDA Regulated Soils t N Samples in Holding 'rime X1N_[�A.J Residual Chlorine Pre}earl Y �i%NA Cl Strips: G` !`( 4 _ Sample pH Acceptable t tl pH Strips: Sulfide Present Lead Acetate Strips: LAD USE ONLY: Lab Sample tJ / Comments: ..,. Phone: . t ll r'- — ` 5 3 , t✓' �5:% /O -i J Email: Site/Facility ID H: Compliance Monitoring' j�,.j�'Fes [ j No Collected By (print : r Purchase Order It: Quote H: DW PWS ID it: DW Location Code' Collected B (signature): Y l t; ) / ,� f Turnaround Date Required: / Immediate! Packed On Ice: V ( )Yes [ (No Sample Disposal: ( ]Dispose as epprnpriate ( ]Return I ) Archive: ( Ilintd: �...__.. Rush: ( ]Same Day ( )Next Day ( ) _ Day ( j 3 Day [ ) 4 Day (j 5 Day (Expedite Chartres APPIV) Field Filtered (if applicable): Yes No [ ) [ ) Analysis: * Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), Product (P), Soil/Solid (SQ, Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) Customer Sample ID I Matrix ` Comp / Grab Collected (or Composite Start) Composite End Res Cl it of Ctns Date I Time Dale Time Peca Customer Remarks / Special Conditions J Possible Hazards >/7 {cc- I / ..... _ - Type of Ice Used: Wet Blue Dry None SHORT HOLDS PRESENT (<72 hours)[ Y•/ N N/A Lab Sample Temperature Info: Temp Blank Received: Y . N NA Therm IDII: tz- f b t Cooler ]. Temp Upon Receipt: _____oC Cooler 1 Therm Corr. Factor: _ oC Cooler 1 Corrected Temp:. oC p Packing Material Used: Lab Tracking Ii: 26 10299 Radchem sample(s) screened (<51)0 cpm): Y N NA Samples received via: FEDEX UPS Q Oleo Courier Pace Courier Relinquished by/Company: (Signature) Date/Time: ReiVed by/Company: Signature) Date/Time: f 7�7 3`�1 L ( t) 7 MTJL LAB USE ONLY . —� Comments: Table II: Acctnurn: Template: Prelogin: PM: PB: I R quished by/Company: (Signature) _ Date/Time: Received b Co n Y/ y: (Sig e) / Date, Time: Trip Blank Received: Y N NA HCL McOH TSP Other Rem quished by/Company: (Signature) Date/l im^: Received b /Coni r,m•• 11l'� ti, { ,.,�,�natura) DatzJTre: Non COnformance(s): YES / NO - -- I Page: of: T m CD o 4 r e o -C re v v 4 r J r Oµ W Oo V �r_..__ M LitS: ( . LU ( IT I t•� r Matrix Ile mN BP4U-125 mL Plastic Unpreserved (N/A) (Cl.) BP3U-250 mi. Plastic Unpreserved (rJ/A) BP2U-500 mL Plastic Unpreserved (rd/n) O � O N '^ 3 :3 ry r. Q t" t t Ls -' Cr fit• -0 u 2 I tiplu-1 liter Plastic Unpreserved (N/A) BP4S-125 mi. Plastic H2SO4 (pli < 2) (CI-) 0 x 1-1 fu O (j 0 — rD ? c� Di — — BP3N-250 mL plastic I IN03 (pl l < 2) e v o ` �— / I eP4z-125 mL Plastic 7N Acetatet; N, ot{ (>9) C Cl :3 ( CD CT a -. C2 --- — /� BP4B-125 mL Plastic r.'am (pit > 1') (CI-) IVGFUAVidc-mouthod Glass jar Unprescrved elli O (J GU 0 0 Q ti % AGIU-1 liter Amber Un trescrvi•d tilA(Cl-) i Jr)i I to rD 7 rID� O Q4 O 77 Ltou rCr AG3U-250 mL Amber Unpreserved (N/A) (CI-) o' AG1S-1 liter Amber I I'SO4 (pH <?) N / / / / AG35-2;0 mL Amber H25O4 (fill < 2) rD <3 ID I I/ / 'IX l /I / AG3A(DG3A)-250 mL Ani',jrr r:l1.1CI (h!/A)(CI-) ! J X' j DG91i-40 mL VOA HCI (P:/A) MT- 40 mL VOA Na2S2O3 RV;,) OrD — VG9U-^O fill. von Unpreserved (N/A)___ I I OG9P 10 int. VOA 143PO4 (NIA) VOAK (3 vials per kit)-5035 t.it (rJ/A) — 3 � o Q M v � C;. V/GK (3 vials per kit)-vpll/Gas [it (N/A) SPST-125 ml Sterile Plastic (N/A - lah) -- j I r„ SPIT-250 ml. Sterile Plastic (N/A - lab) AZ MA-250 mL Plastic (NH2)2SO4 (9.3.9.7) a AGOU-100 mL Amber Unpreserved vials (rJ/A) VSGU-20 mL Scintillation vials (N/A) 1 ! 7 1 j� DG9U-10 mL Amber I,JnprL•ser•r:-d vials (N/A) ,PaceAnalytical � www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 December 23, 2022 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92642356 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on December 15, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 12 or, PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92642356 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 12 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley 92642356 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92642356001 Outfall 001 SM 254OD-2015 VLG 1 PASI-E EPA 350.1 Rev 2.0 1993 SRS 1 PASI-E SM 521OB-2016 AED 1 PASI-E Colilert-18 SRS 1 PASI-E PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 12 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92642356 Sample: Outfall 001 Lab ID: 92642356001 Collected: 12/15/22 13:00 Received: 12/15/22 14:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 254OD-2015 Pace Analytical Services - Eden Total Suspended Solids 5.2 mg/L 4.0 1 12/16/22 14:34 350.1 Ammonia EDN Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Eden Nitrogen, Ammonia 33.9 mg/L 1.0 10 12/21/22 15:05 7664-41-7 5210E BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521 OB-2016 Pace Analytical Services - Eden BOD, 5 day 38.2 mg/L 2.0 1 12/16/22 10:18 12/21/22 12:37 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms ND MPN/100mL 1.0 1 12/15/22 18:36 12/16/22 13:03 Date: 12/23/2022 10:44 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 12 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92642356 QC Batch: 743942 Analysis Method: SM 2540D-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92642356001 METHOD BLANK: 3870541 Associated Lab Samples: 92642356001 Parameter Units Total Suspended Solids mg/L LABORATORY CONTROL SAMPLE: 3870542 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 3870543 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 3870544 Parameter Units Total Suspended Solids mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.5 12/16/2214:29 Spike LCS Conc. Result 250 236 92642365002 Dup Result Result 408 388 92641984001 Dup Result Result 43.2 43.2 LCS % Rec % Rec Limits Qualifiers 94 90-110 RPD Qualifiers 5 RPD Qualifiers 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/23/2022 10:44 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 12 4 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92642356 QC Batch: 744944 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia, EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92642356001 METHOD BLANK: 3875430 Associated Lab Samples: 92642356001 Parameter Units Nitrogen, Ammonia mg/L LABORATORY CONTROL SAMPLE: 3875431 Parameter Units Nitrogen, Ammonia mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.10 12/21/2213:49 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 5 5.0 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3875432 3875433 MS MSD 92643341001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 0.21 5 5 5.4 5.4 103 103 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3875434 3875435 MS MSD 92642820001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.2 5.2 104 104 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/23/2022 10:44 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 12 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92642356 QC Batch: 743911 Analysis Method: SM 521OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210B BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92642356001 METHOD BLANK: 3870285 Matrix: Water Associated Lab Samples: 92642356001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg/L ND 2.0 12/21/22 10:40 LABORATORY CONTROL SAMPLE: 3870286 Parameter Units BOD, 5 day mg/L SAMPLE DUPLICATE: 3870288 Parameter Units BOD, 5 day mg/L Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 198 177 89 84.6-115 92642341001 Dup Result Result RPD Qualifiers 174 171 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/23/2022 10:44 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 12 FaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92642356 QC Batch: 743928 QC Batch Method: Colilert-18 Associated Lab Samples: 92642356001 SAMPLE DUPLICATE: 3870406 Parameter Units Fecal Coliforms MPN/100mL QUALITY CONTROL DATA Analysis Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden 92642345001 Dup Result Result RPD Qualifiers ND ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/23/2022 10:44 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 12 PRaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Hope Valley Pace Project No.: 92642356 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/23/2022 10:44 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 12 FaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Hope Valley Pace Project No.: 92642356 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92642356001 Outfall 001 SM 254OD-2015 743942 92642356001 Outfall 001 EPA 350.1 Rev 2.0 1993 744944 92642356001 Outfall 001 SM 521OB-2016 743911 SM 521OB-2016 92642356001 Outfall 001 Colilert-18 743928 Colilert-18 Date: 12/23/2022 10:44 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch 744577 743929 Page 10 of 12 G' Pace Analytical ' Company: Ad CHAIN -OF -CUSTODY Analytical Request Document Chain -of -Custody is a LGGAL DOCUMENT- Complete all relevent fields Billing Information: P,epor T / Email To: Copy T Site Collection Info Address: ecc14 Il/�Gtr Customer PrAect Name/Nurnber State: aountty/City: Time Zone Collec ed: p, r itKe f I PT [ I MT I I CT ((,,]'ETPhone: 3 3�"I SS- 7O `f 5Site/Facility ID q: Compliance Monitoring' Email: fs [ ) No Collected By (print): Purchase Order H: DW PWS ID Y,: l^✓C al �7i1 Sle' , Quote H: DW Location Code: Collected By (signature): Turnaround Date Required: Immediately Packed on Ice: rrA.l! f IYes f )No Sample Disposal Rush: Field Filtered (if applicable): I ) Dispose as appropriate I I Return I ) Same Da ( ) N t D LAB USE ONLY- Affix Workorder/Login Label Here or List Pace Workorder Number or WO#:92642356 ALLSHP 111111 Jill 111111111 Container Preservative 92542356 ** Preservative Types: (1) nitric acid, (2) su,.,..."., -, ,,,, ,,,,,,,,,,,,,,,,,...... t4i ,wmu- iryuluxiue, i:)l zinc acetate, (6) methanol, (7) sodium bisulfate, (8) sodium thiosulfate, (9) hexane, (A) ascorbic acid, (B) ammonium sulfate, (CRZonium hydroxide, (D) TSP, (U) Unpreserved, (0) Other / Analyses Lab Profile/Line: I ) Archive: Y ex, ay [) 2 Day [ 13 Day I) a Day [ ] 5 Day I I Yes [ ] No h (Expedite Charges Apply) Analysis: ' Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) � Customer Sample ID Matrix u Comp / Grab Collected (or Composite Start) Composite End Res CI 4 of Ctns 'O 41 t'I' Date I Time Date Time r r 5 a- 5-A 1.'0"o 1 ©' Customer Remarks / Special Conditions / Possible Hazards: Type of ice Used: Wet . Blue Dry None Packing Material Used: r Radchem sample(s) screened (c500 cpm): Y N NA Relinquished by/Company: (Signature) Date/Time: Received by/Compan : (Signature) R*quished by/Company: (Signature) Dat ./Time: Received by/C pan nature) ReRiquished by/Company: (Signature) Date/Time: Received by/Company: (Signature) N .+ ..."y— -'—pc unec Kllst: Custody Seals Present/Intact Y<jD_NA Custody SignaturesPresent 'N NA Collector Signature i Present N NA Bottles Intact QN NA Correct Bottles �N NA Sufficient Volume I�I NA Samples Received on Ice N NA VOA - Headspace Acceptable Y N USDA Regulated Soils Y N , Samples in Holding Time Qj N NA Residual Chlorine Pr , t Yt)NA C1.Strips F� Sample PH Acceptable N NA pit strips: Sulfide Present Y N ,JA Lead Acetate Strips: LAB USE ONLY: Lab Sample # / Comments: SHORT HOLDS PRESENT (02 hours): f Y A N/A .' Lab Tracking H;- 2610299 Samples received via: FEDEX UPS Client Courier Pace Courier Date/Time: 2/1 S/z 7 Vf 5 7> MTJL LAB USE ONLY Table k: Acctnum: Date/Time: Prelogin: PM: DPI - J. CCIT i1 i Lab Sample Temperature Info: Temp Blank Received: Y N NA Therm IDH: -C itz d Z 1> 'Cooler I Temp Upon Receipt: Z • -zuC Cooler 1 Therm Corr, Factor: — • .Z oC Cooler I Corrected Temp: , Z 1 oC Comments: Trip Blank Received: Y N NA HCL McOH TSP Other Non Conformance(s): Page: YES / No I of: N O X, o ro �- I t in I Matrix Itemff r O BP4U-125 nil- Plastic Unlueservetf (hJ/A) (Cl-) BP3U-250 mL Plastic Unpreserved (N/A) v D BP2U-500 ml- Pla�lic Unpreserved (N/A) 8P1U•1 liter Plastic Unpreserved (N/A) / / / / / . _ BP4S-125 mL Plastic WSO4 (pH < 2) (Cl-) / / BP3N-250 mL plastic I IN03 (pit < 2) -- i z_ o / / BP47-125 mL Plastic 7N Acetate. & NaOH (>9) /// S 2 BP413L-125 mPlastic NaOli (pH > 12) (Cl-) WGFU-Wide mouthed Class jar Unpreserved j f m AG1U-1 liter Arnber Unpreserved (N/A) (Cl-) " � ro � AGiH-lliterAmberliCl (pit <,.) rr r O — AG3U-250 ml Amber Unpreserved (N/A) (Cl-) - C, n 0 Az z AG1S-1 liter Amber 112SO4 (111 < 2) H m / , / / / AG3S-250 ml Amber 112504 (p1I < 2) m — AG3A(DG3A)- �0 mL nrnier N114C1 (hJ/A)(CI-) 25 a m < Q —. DG911-40 ml- VOA HCI (N/A) a v C ru " h fD '1 LA VG9T-40 mL VOA Na25203 (N/A) VG9U-40 mL VOA Unpreserved (N/A) o ra LA DG9P-40 mL VOA 113PO4 (N/A) VOAK (3 vials per kit)-5035 kit (N/A) D 3 0 C V/GK (3 vials per kit)-VPH/Gas kit (N/A) w O a ro' N SPST-125 mL Sterile Plastic (N/A - lab) SP2T-250 mL Sterile Plastic (N/A - lab) BNA-250 mL Plastic (NI12)2504 (9.3-9.7) AGOU-100 mL Amber Unpreserved vials (N/A) r tt VSGU-20 mL Scinfilla(ion vials (N/A) i DG9U-40 mL Amber Unpreserved vials (N/A) O 1 t v O ro xt ro a CJ Co r, oO it 3 w PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 December 05, 2022 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92638468 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on November 28, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones �Q,Q pCCRF�'� eORA011 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 i FaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92638468 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 014 i RanceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley 92638468 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92638468001 Outfall 001 SM 254OD-2015 VLG 1 PASI-E SM 521OB-2016 AED 1 PASI-E Colilert-18 SRS 1 PASI-E PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 G. { raceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92638468 Sample: Outfall 001 Lab ID: 92638468001 Collected: 11/28/22 13:00 Received: 11/28/22 15:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D-2015 Pace Analytical Services - Eden Total Suspended Solids 5.3 mg/L 2.8 1 11/29/22 15:15 5210B BOD, 5 day EDN Analytical Method: SM 521 OB-2016 Preparation Method: SM 521OB-2016 Pace Analytical Services - Eden BOD, 5 day 9.7 mg/L 2.0 1 11/29/22 11:17 12/04/22 14:17 R6 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms 1.0 MPN/100ml- 1.0 1 11/28/22 18:10 11/29/22 12:48 D6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/05/2022 04:05 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 11 FaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92638468 QC Batch: 739773 Analysis Method: SM 254OD-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92638468001 METHOD BLANK: 3849027 Matrix: Water Associated Lab Samples: 92638468001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 11/29/22 15:13 LABORATORY CONTROL SAMPLE: 3849028 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 232 93 90-110 SAMPLE DUPLICATE: 3849029 92638395001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 196 184 6 SAMPLE DUPLICATE: 3849428 92638442001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 126 127 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/05/2022 04:05 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 11 m , PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92638468 QC Batch 739764 Analysis Method: SM 521 OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210B BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92638468001 METHOD BLANK: 3848923 Matrix: Water Associated Lab Samples: 92638468001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg/L ND 2.0 12/04/22 13:42 LABORATORY CONTROL SAMPLE: 3848924 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day mg/L 198 192 97 84.6-115 SAMPLE DUPLICATE: 3848926 92638395001 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 2390 2230 7 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/05/2022 04:05 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 FaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92638468 QC Batch: 739633 QC Batch Method: Colilert-18 Associated Lab Samples: 92638468001 SAMPLE DUPLICATE: 3848547 Parameter Units Fecal Coliforms MPN/100mL QUALITY CONTROL DATA Analysis Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden 92638468001 Dup Result Result RPD Qualifiers 1.0 2.0 67 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/05/2022 04:05 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 aceAnalytical www.pacelabs.com Project: Hope Valley Pace Project No.: 92638468 DEFINITIONS QUALIFIERS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TIN accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. R6 The RPD between valid sample dilutions exceeded 30%. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/05/2022 04:05 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 11 ti. anceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Hope Valley 92638468 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92638468001 Outfall 001 SM 2540D-2015 739773 92638468001 Outfall 001 SM 521OB-2016 739764 SM 521OB-2016 740016 92638468001 Outfall 001 Colilert-18 739633 Colilert-18 739634 Date: 12/05/2022 04:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 11 p CHAIN -OF -CUSTODY Analytical Request Document PaceAnalXical ' Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevent fields Company: Billing Information: Addre s: Repor To- - Email To: _ ir copy Site Collection Info/Address: Customer Pr jest Name/Number: State: (✓County/City: Time Zone Collected: PT [ 1 MT I 1 CT jV]'ET Phone: 3 j ., j✓ ',. PU��J Site/Facility ID H. Compliance Monitoring? Email: ["''Yes [ ] No Collected By (print : Purchase Order N: DW PWS ID q: "' + 0/"7 ,,,j sr'. - Quote N: DW Location Code: Collected By (signature): Turnaround Date Required: Immediately Packed on Ice: = ^ E [ 1 Yes [ ] No Sample Disposal: Rush: Field Filtered (if applicable): I I Dispose as approtxiate ( I Return [ ) Same Day [ ] Next Di y . I ] Archive: _.. y I 1 2 Day [ ] 3 Day I 1 4 Day ( ] 5 Day [ ] Es [ ] No [ 1 Hold: (Expedite Charges Apply) Analysis: ' Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue ITS), Bioassay (B), Vapor IV), Other (OT) iC; "�- Customer Sample ID Matrix ` Comp / Grab Collected (or Composite Start) Composite End Res CI # of Ctns r 't�J 'U cc I-L Date 'I ime Date Time t Customer Remarks / Special Conditions / Possible Hazards: Type of Ice Used: WetBlue Dry None Packing Material Used: On I c e. r � �-��- -- Radchem sample(s) screened (<Soo cpm): Y N NA Relinquished by/Company: (Signature) Date/Time: Received by/Company: (Signature) A / / 0 : III/.. I i r - . , __4_- - ished by/Company: (Signature) uished by/Company: (Signature) Date/Time: I Received Date/Time: I Received by/Company: (Signature) LAB USE ONLY- Affix Workorder/Login Label Here or List Pace Workorder Number or MTJL Log -in Number Here ALL S WO#:92638468 Container Preserve ` Preservative Types: (1) nitric acid, 9263a46S I (6) methanol, (7) sodium bisulfate, (8 (�i�onium hydroxide, (D) TSP, (U)hydroxide, (0) TSP, (U) ab Profile/line: Lab Sampie Receipt Checklist: ��-r� Custody Seals Present/intact'•(_ Custody Signatures Present NA Collector Signature Present �t NA Bottles Intact �J IJA Correct Bottles N NA Sufficient Volume �1�1 a I,Samples Received on :ice J NA VOA - Heacispace Acceptable y N USDA Regulated Soils Y N Samples in Holding Time � N NA Residual. Chlorine Present Ye,) NA Cl Strips: Sample pH Acceptable y tJ PH Strips: Sulfide Present Y N Fj Lead Acetate Strips: LAa USE ONLY: Lab Sample # / Comments: SHORT HOLDS PRESENT (<72 hours): Y N/A Lab Tracking #: 2610299 iamples received via: FEDEX UPS Clier Courier Pace Courier Datte/Time: MTJL LAB USE ONLY 1 1/7 S j,7 -7 I S Trade H: Acctnum: Date/Time: Template: Prelogin: PM: — Date/Time: IPB. ap .. -1 cil l Lab Sample Temperature Info: Temp Blank Received: Y N NA Therm IDII:_ r U 4 Cooler 1 Temp Upon Receipt: 62 ci oC Cooler 1 Therm Corr. Factor: - • = of_ Cooler 1 Corrected Temp: •,_=oc Comments: Trip Blank Received: Y N NA HCL McOH TSP Other Non Conformance(s): I Page: YES / NO of vocument Name: Bottle Identification Form (BIF) Document No.: F•CAR-CS-043-Rev.01 *check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliforrn, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottles Project # Document Issued: November 15, 2021 Page i of 1 Issuing Authority: Pace Carolinas Quality Office Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 11 of 11 µ aJceAnal tical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 December 07, 2022 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92637228 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on November 17, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 PaceAnalytical� www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92637228 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley 92637228 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92637228001 Outfall 001 SM 2540D-2015 VLG 1 PASI-E EPA 350.1 Rev 2.0 1993 SRS 1 PASI-E Colilert-18 SRS 1 PASI-E PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 Pace Analytical Services, LLC j1377 South Park Drive PaceAn aly fical Kernersville, NC 27284 www.pacelabs.com (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92637228 Sample: Outfall 001 Lab ID: 92637228001 Collected: 11/17/22 11:00 Received: 11/17/22 12:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D-2015 Pace Analytical Services - Eden Total Suspended Solids 3.4 mg/L 2.5 1 11/21/22 13:43 350.1 Ammonia EDN Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Eden Nitrogen, Ammonia 21.6 mg/L 0.50 5 11/17/22 17:24 7664-41-7 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms 8.5 MPN/100ml- 1.0 1 11/17/22 17:23 11/18/22 11:28 D6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 11:13 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 11 faceAnalAcal www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92637228 QC Batch: 738485 Analysis Method: SM 2540D-2015 QC Batch Method: SM 2540D-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92637228001 METHOD BLANK: 3843043 Matrix: Water Associated Lab Samples: 92637228001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 11/21/22 13:37 LABORATORY CONTROL SAMPLE: 3843044 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 230 92 90-110 SAMPLE DUPLICATE: 3843045 92637476001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 194 199 3 SAMPLE DUPLICATE: 3843720 92637690001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 200 210 5 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 11:13 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 11 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92637228 QC Batch: 737811 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia, EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92637228001 METHOD BLANK: 3839785 Matrix: Water Associated Lab Samples: 92637228001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 11/17/22 14:24 LABORATORY CONTROL SAMPLE: 3839786 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.2 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3839787 3839788 MS MSD 92637153001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.1 5.2 103 103 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3840299 3840300 MS MSD 92637214001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.3 5.2 105 105 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 11:13 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 r0aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92637228 QC Batch: 737907 QC Batch Method: Colilert-18 Associated Lab Samples: 92637228001 SAMPLE DUPLICATE: 3840550 Parameter Units Fecal Coliforms MPN/100mL QUALITY CONTROL DATA Analysis Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden 92637228001 Dup Result Result RPD Qualifiers 8.5 5.2 48 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 11:13 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Hope Valley Pace Project No.: 92637228 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. WORKORDER QUALIFIERS WO: 92637228 [1) BOD analysis could not be completed due to laboratory issue. SJK 12/7/22 ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 11:13 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 11 NaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Hope Valley 92637228 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92637228001 Outfall 001 SM 254OD-2015 738485 92637228001 Outfall 001 EPA 350.1 Rev 2.0 1993 737811 92637228001 Outfall 001 Colilert-18 737907 Colilert-18 737910 Date: 12/07/2022 11:13 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 11 `J CHAIN -OF -CUSTODY Analytical Request Document y q Pc1CL'Al1r?%J/t/Ccil LAB USE ONLY- Affix Workordet g /Lo in Label Here or List Pace Workorder Number or MT1L Log -in Number Here Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevent fields _ Company: Billing Information: re-/e Ile- AL WO# • 92637228 Container Pres. —Preservative Types: (1}ta, nitric 111111111111111111111111 (51 methanol, (7} sodiumbi� (C onium hydroxide, (�) T<_ 92637228 Yses t.ab Profile/Line:Customer Addre �10 7 a Rep or Ta Email To: rt `-,�)�/"� ? , Copy 7 : , Site• Collection Info Address_ L `� L /D C, 1- [q01M. Pr 1eft Name/Number: State: CCounty/City: Time Zone Collet ed: �PT [ ] MT ( ] CT �T Lab Sample Receipt ecklis: r_ht Custody seals Present/intact Y; tj Custody Signatures Present ,'Y Pt NA :. Collector signature t='N Phase: Ito" t S`�r `fS Email:/ Site/Facility ID p: ' i it M li Compliance Monitoring' ]V}�fes ( ] No � (� _ Present NA Bottles Intact {`Y,' N CIA correct softies ;' k tt >„A Sufficient Volume N NA Samples Received on roc C:N NA VOA - Headspace Acceptable Y N ?Qf -USDA Regulated Soils Y N Samples in Holding Time N NA Residual Chlorine Presort Y W)NA v Sample Strips: _ r s _ Sample pH Acceptable to raA pU Stripy_ f Sulfide Present Y t+,'°f;ifc•_, bead Acetate Strips: Collected By (print): %{� / ' , s, Cl/'"T-tt) C.i " Purchase Order #: Quote tt: DW PWS ID it: DW Location Code: Collected By (signature): Turnaround Date Required: immediately Packe en Ice: ] Yes [ ] No Sample Disposal: ( j Dispose as appropriate [ j Return ( 1 Archive: I )Hold:_ Rush: [ ) Same Day f ] Next Day ( ) 2 Day ( ] 3 Day [ ] 4 Day ( ] S Day (Expedite uhartes Apply) Field Filtered (if applicablel: Yes [ ] [ ] No Analysis: _ ` Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), Prodt,ct (P). Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) +� 4c) Co rj LAB USE ONLY: - Lab Sample / Comments Customer Sample ID Matrix ` Comp / Grab Collected (Ur Composite Start) Composite End Res Cl fJ of Ctns Date Time Date Time } 67 l c f% 0 c i G rQ tS r',°°` i ia.C1? 2 ✓ t TSS t� !! t f 7 -'7 Z f, Customer Remarks / Special Conditions / Possible Hazards: Type of Ict Used: .: Wet Blue Dry None ` SHORT HOLDS PRESENT-(<72 hours): Y N N/A .. Lab Sample Temperature Info: Packing Material Used: ;, .. Lab Tracking N:- 261099 f 1 t ------------ Temp Blank Received Y N NA Therm IDN: Cooler 1 Temp Upon Receipt. &OC Cooler 1 Therm Corr. Factor oC Cooler 1 Corrected Temp: , oC Radchem sample(s) screened (<500 cpm): Y NA N Samples received via --: FEDEX UPS t Client Courier Pace Courier Relinquished by/Company: (Signature) r � Date/Time: Received by/Company (Signature) Date/Time: MTJL LAB USE ONLY ----4 Comments: 'Fable N: Rel�quished by/Company: (Signature) CD Date/Time: Received by/Con pally: (Si' a ure) - Date/Time: Acctnum: Template:'Trip Blank Received: Y N NA O Prelogin: PM: HCL McOli TSP Other Rel9quished by/Company: (Signature) Date/Time: Received by/Company: (Signature) Date/Time: Non Conformance(s): Page: PB: YES / NO of: _, V 9 i c� 7, 3• D 0 U3 N Ilcn,ll Itl'41417'i fill f•Rr.rir 11nln r;rtvrll {ft!.;) (ff ) ItI':111-"dl nd I'Lelir lhgn c•.c1 v,•II (11!A) ---- Ith?11'd111nd Iq.r.litlNlfnrsrlvl•,l(IIlA) Itl'l I I- I h1 vt Hx.lic l hq+r r•.r r,ril {I11fQ Ill'•1 ; I1', lilt I'I.I IIC II1`,111 i•1111 ((1 I lil'7f1.'r,(11141.III.I;IIc' Illlri 1 (lilt � :'} hill! _1.'ifi111'latlir flAr,•1.0v ,fl.1011(-'I) I11'•111.1:' :nil I'l.vAir tl.trll l (1,11 lvt.rill^.tn6-•nuntlhlvlGlr,-Ilr (till nlc•tvl•;I "- AGM-1 I'll'( Andli'r Ihgltl•'.1 t I I (I),/A) (i l i A6111- I lilr•r AnJa•f Ilk 1 (1111 : ) At; ill-''.0 nd Anrin•r 11nIn1••.1"v-1 (I f/A) (fI )- AG1S-I fifvr Amber I01;0-i (fill r:') AG11 l-l'';fl III Afldwr II?StI1 (1,1 c 7) AG lA(liG'IA)-. "JI fill And -I Ill1-V I rlG�In 11) lilt : iA Iif I (11/P.) - ----- Vt-,t)r-4u 11.1 V(1:1 t1.1?•:?I Yt {rl!: ) VG9U -Ili n11 MA tlnlu)••Irlveil y'I1fAj 11G9P-•Iil till VOA 11 IN).1 (rl/i,) V11AM (I vi,.I, pet I,i1)-'Al lb Iif V/61i f i vi•IA I -Of Gil) VI'1I/I__is 111 (11lA) Jill 'JrlilcNx.lir'(rl.%;- I'll.) I �1 ?Sl)nti >II ti±,)1 L1•Ilr {f1,,F LI•) AG1111.1f)f) n0 Andll•Y Ilnlrrrulvrll vt.;l: (f 1i=i} VSfll-'11 till `.r i nlill.ltinn vial•, f(1ld.l 013911 •If) fell Allilivt Unlnrsrlv,•;f vial'; (I1L1) k N N II CI .r iU -•, � r `u r7 i- -r 0 i • r. A: ' cr ril , ll� U l 1��1 �• t- t r;1 4 1 l,l 'rl t Ij f 11 I I PaceAnalXicaf www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 November 04, 2022 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92633153 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on October 26, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc. Martin Semones 2��Q,Q pCCRF�'�O TINT /` �-1 ge0RAiO� REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 PaceAnalXical � www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92633153 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 r0aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley 92633153 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92633153001 Outfall 001 SM 254OD-2015 LRB 1 PASI-E SM 521OB-2016 AED 1 PASI-E Colilert-18 AED 1 PASI-E PASI-E= Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 0aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92633153 Sample: Outfall 001 Lab ID: 92633153001 Collected: 10/26/22 13:30 Received: 10/26/22 15:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D-2015 Pace Analytical Services - Eden Total Suspended Solids 2.9 mg/L 2.5 1 10/31/22 09:16 5210E BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521OB-2016 Pace Analytical Services - Eden BOD, 5 day ND mg/L 2.0 1 10/27/22 11:38 11/01/22 11:53 B2 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms ND MPN/100ml- 1.0 1 10/26/22 18:32 10/27/22 13:32 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/04/2022 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 11 FaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, INC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92633153 QC Batch: 733570 Analysis Method: SM 254OD-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92633153001 METHOD BLANK: 3818293 Matrix: Water Associated Lab Samples: 92633153001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 10/31/22 09:12 LABORATORY CONTROL SAMPLE: 3818294 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 268 107 90-110 SAMPLE DUPLICATE: 3818295 92633096001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 138 145 5 SAMPLE DUPLICATE: 3818296 92633283001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 36.5 34.9 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /04/2022 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 11 FaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92633153 QC Batch: 733139 Analysis Method: SM 521OB-2016 QC Batch Method: SM 521 OB-2016 Analysis Description: 5210B BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92633153001 METHOD BLANK: 3815694 Matrix: Water Associated Lab Samples: 92633153001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg/L ND 2.0 11/01/22 11:05 LABORATORY CONTROL SAMPLE: 3815695 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day mg/L 198 200 101 84.6-115 SAMPLE DUPLICATE: 3815697 92633031001 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 2330 2270 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /04/2022 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 fy_ aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92633153 QC Batch: 733223 Analysis Method: Colilert-18 QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92633153001 SAMPLE DUPLICATE: 3816262 Parameter Units Fecal Coliforms MPN/100ml- 92633101003 Dup Result Result RPD Qualifiers 22.2 7.1 103 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /04/2022 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 raceAnalyfiical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Hope Valley Pace Project No.: 92633153 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC -Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TN I accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS B2 Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. D6 The precision between the sample and sample duplicate exceeded laboratory control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /04/2022 01:48 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 11 aceAnalytical '�o www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Hope Valley 92633153 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92633153001 Outfall 001 SM 254OD-2015 733570 92633153001 Outfall 001 SM 521OB-2016 733139 SM 521OB-2016 733707 92633153001 Outfall 001 Colilert-18 733223 Colilert-18 733225 Date: 11/04/2022 01:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 11 ,� CHAIN -OF -CUSTODY Analytical Request Document .f aceAnalytical �O g2633153 "ice Workorder Number or . Chain -of -Custody is a LEGAL DOCUMENT - Conrplei e all rca v'ili fields Company:f'y� - Billing information: IJNy 1SE ONLY Address:92633153 { r. Report To !Email To: i" Preservative Types (1) niiiir acid, (2) sul„ uric acid, (3) hydrochloric acid, (4) sodium hydroxide, (5) zinc acetate, _.._° Copy To: 'Site Collection Info/Address' i r, f? yy 1(5) methanol, (7) sodium bisulfate, (8) sodium thiosulfate, (9) hexane, I(C) ammonium hydroxide, (D) TSP, (U) Unpreserved, (0) Other (A) ascorbic acid, (B) ammonium sulfate, �ff _ Customer Project Name/Number. jState:f%'CCounty/City: Time Zone Collected: Analyses l ---;— - Lab Prchi.�. C�n _ [ i i Phone.3c Site/Facility ID #: ' [Compliance Monitoring? Email:;Wes [ ]No i Collected! By (pant): ) Purchase Order # : DW PWS ID 4 lu a Quote #: DW Location Code: : Collected By ( igature): Turnaround Date Required: Immediately Packed on Ice:]Yes ( ) ;F No =° Sample Disposal: jRush: Field Filtered (if applicable): ( ] Dispose as appropriate [ I Return i [ ) Same Day { ) Next Day [ ]Yes [ ] No ( ) Archive: [ ) 2 Day ( 13 Day ( 14 Day ( ) 5 Day [ ) Hold:_ Anal _ Ex _edde Char es A I sis' * Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor IV), Other (OT) €� Comp J Collected (or ( Res # of i i Composite End p § L) Customer Sample ID ( Matrix * Grab Com osite Start _ CI Ctns �m )__ --_1 t Da I te Time 1 Date Time # -; Custorner Remarks / Special Conditions / Possible Hazards: Relinquished by/Company: (Signature) 0 by/Company: (Signature) Typo of ice Used: Wej� Blue Dry N.rrl SHORT 1,101 7S PRESENT (<:72 hour ,) : N N/A ,LAB Srunplo Te npr=rature Info: _ ._ . ._—- r Pricking Material Used: Lab Tracking >a: „^; t 'Sar idles received via Radchem sampie(s) scrc oned (<500 cpm): Y N FEDEX UPS lirar Courier Puer! Courer )ate Time IReceived by/Company (Signature) IDate/Time: � Sr tvtT11 i An i lgr nrl f ` ived by/Company: J$ignature) Date/Time: by/Company: (Signature) JDate/Time: IReceived by/Company: (Signature) Date/Time: Prelogin: P tvl: PB: Trip Blank Rec< ivrd: Y N tom I FICL McOH TSP Other Non Conformance(sl Page: YES J of: r4 IL a LA I Uendt......._.-,... 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VOA Ita&;-)03 (ri/A) VG911-10 fill VOA tfopwr ,g rvi•Il (NN DC.91'-40 nit VOA I HPO,I (IIIA) V17AK 13 vials per Idl)-50:1 , lit (i=J/n) — V/GK (3 vials per Hit) Vf,lt/r u I.it (rJ/A)-�. .,PST-] -. Inl. `iiellle PIaS1ic (FJ/A .._ I,II•) lilt.:terile Phstic (rl;n - I'll.) fIP3A-.":O fill, !'Idstic (I1112)2S0.1 AGIIU-101`1 rill Nnbrr UnJlresrsn•cd vi;71S (rJ/A) VSGU-20 fill. Sdiriitldlicu) VUS (N/A) M,90-40 rn1. Amlwr IhlJlmsr!rvrd vidL ((dlA) i[ rn in M le , � n7 n7 (•3 CA it !� tU V1 GW O S rt L3 CU f �i- 1, 01 p 3 _ - C7 (� r'i _ u M r�i 71 r_.3 T3 A: cr I ° ru ' -3 � •� � 1 L IJ O �•7 u (, -- l 1 n I C'_ sy 111 rn v, a n3 L 1(0 T ri U C 7 LJ r ,IJ c 7 �. r, r}• I, r•3 r •, U W 11 n t�J HJ• �� I tr I. PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 October 21, 2022 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92630249 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on October 10, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones pCCft,,t0 , TNI 4 Q �/A �9eQRA'ip�. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 15 PaceAnalytical www.pacelabs.com Project: Hope Valley Pace Project No.: 92630249 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 North Carolina Wastewater Certification #: 633 VirginiaNELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 15 PaceAnalXical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92630249 Lab ID Sample ID 926 30249001 O u tfa I I 001 PASI-A= Pace Analytical Services -Asheville PASI-E= Pace Analytical Services - Eden SAMPLE ANALYTE COUNT Method Analysts Analytes Reported Laboratory SM 2540D-2015 LRB 1 PASI-E SM 521OB-2016 MWF 1 PASI-E Colilert-18 MWF 1 PASI-E TKN+NO3+NO2 Calculation MAB2 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 KDF1 1 PASI-A EPA 365.1 Rev 2.0 1993 SMT 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 15 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92630249 Sample: Outfall 001 Lab ID: 92630249001 Collected: 10/10/22 13:00 Received: 10/10/22 15:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 254OD-2015 Pace Analytical Services - Eden Total Suspended Solids ND mg/L 2.5 1 10/11/22 10:27 5210B BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521 OB-2016 Pace Analytical Services - Eden BOD, 5 day ND mg/L 2.0 1 10/11/22 09:51 10/16/22 11:38 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms ND MPN/100ml- 1.0 1 10/10/22 18:58 10/11/22 13:01 Total Nitrogen Calculation Analytical Method: TKN+NO3+NO2 Calculation Pace Analytical Services - Asheville Total Nitrogen 47.4 mg/L 0.040 1 10/21/22 14:07 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Ammonia 39.9 mg/L 0.60 6 10/14/22 14:36 7664-41-7 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Kjeldahl, Total 44.1 mg/L 2.5 5 10/14/22 18:15 10/15/22 04:42 7727-37-9 353.2 Nitrogen, NO2/NO3 pres. Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, NO2 plus NO3 3.3 mg/L 0.040 1 10/21/22 08:41 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville Phosphorus 3.6 mg/L 0.050 1 10/20/22 23:10 10/21/22 20:02 7723-14-0 Date: 10/21/202211:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. B2 Page 4 of 15 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92630249 QC Batch: 729001 Analysis Method: SM 254OD-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92630249001 METHOD BLANK: 3796334 Matrix. Water Associated Lab Samples: 92630249001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 10/11/22 10:23 LABORATORY CONTROL SAMPLE: 3796335 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 238 95 90-110 SAMPLE DUPLICATE: 3796336 92629760001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L ND ND SAMPLE DUPLICATE. 3797688 92630162001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L ND ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/21 /2022 11:11 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 15 s PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92630249 QC Batch: 729262 Analysis Method: SM 521OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210B BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92630249001 METHOD BLANK: 3797724 Matrix: Water Associated Lab Samples: 92630249001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg/L ND 2.0 10/16/22 11:16 LABORATORY CONTROL SAMPLE: 3797725 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day mg/L 198 196 99 84.6-115 SAMPLE DUPLICATE: 3797727 92630136001 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 1230 1260 3 R6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10121 /2022 11:11 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 15 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92630249 QC Batch 729213 Analysis Method: Colilert-18 QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92630249001 SAMPLE DUPLICATE: 3797596 Parameter Fecal Coliforms 92630249001 Dup Units Result Result RPD Qualifiers MPN/100mL ND ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/21 /2022 11:11 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 15 I PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92630249 QC Batch: 730233 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92630249001 METHOD BLANK: 3802304 Matrix: Water Associated Lab Samples: 92630249001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 10/14/22 12:51 LABORATORY CONTROL SAMPLE: 3802305 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.4 109 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3802306 3802307 MS MSD 92630683002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.3 5.3 105 106 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3802308 3802309 MS MSD 92630683004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.3 5.3 105 105 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/21 /2022 11:11 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 15 raceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92630249 QC Batch: 730324 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92630249001 METHOD BLANK: 3802757 Matrix: Water Associated Lab Samples: 92630249001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Kjeldahl, Total mg/L ND 0.50 10/15/22 04:08 LABORATORY CONTROL SAMPLE: 3802758 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg/L 10 9.8 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3802759 3802760 MS MSD 92630790002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 0.74 10 10 10.7 9.9 99 92 90-110 7 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3802761 3802762 MS MSD 92630790003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L ND 10 10 9.7 9.5 93 92 90-110 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/21/2022 11:11 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 15 FaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92630249 QC Batch: 731521 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92630249001 METHOD BLANK: 3808277 Associated Lab Samples: 92630249001 Parameter Units Nitrogen, NO2 plus NO3 mg/L LABORATORY CONTROL SAMPLE: 3808278 Parameter Units Nitrogen, NO2 plus NO3 mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.040 10/21 /22 08:17 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 2.5 2.5 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3808279 3808280 MS MSD 92631271003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L ND 2.5 2.5 1.5 1.6 61 62 90-110 1 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3808281 3808282 MS MSD 92631271005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L 0.063 2.5 2.5 2.5 2.5 96 97 90-110 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/21/2022 11:11 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 15 FllaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92630249 QC Batch: 731489 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92630249001 METHOD BLANK: 3808207 Associated Lab Samples: 92630249001 Parameter Units Phosphorus mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.050 10/21/2219:53 LABORATORY CONTROL SAMPLE: 3808208 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg/L 2.5 2.6 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3808209 3808210 MS MSD 92629853001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 0.17 2.5 2.5 2.6 2.6 98 98 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3808211 3808212 MS MSD 92629853002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 0.16 2.5 2.5 2.6 2.7 98 103 90-110 4 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/21/2022 11:11 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 15 fj FaceAnalytical www.pacelabs.com Project: Hope Valley Pace Project No.: 92630249 DEFINITIONS QUALIFIERS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TN I accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS B2 Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R6 The RPD between valid sample dilutions exceeded 30%. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/21 /2022 11:11 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 15 paceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Hope Valley Pace Project No.: 92630249 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92630249001 Outfall 001 SM 254OD-2015 729001 92630249001 Outfall 001 SM 521 OB-2016 729262 SM 521OB-2016 729563 92630249001 Outfall 001 Colilert-18 729213 Colilert-18 729214 92630249001 Outfall 001 TKN+NO3+NO2 732023 Calculation 92630249001 Outfall 001 EPA 350.1 Rev 2.0 1993 730233 92630249001 Outfall 001 EPA 351.2 Rev 2.0 1993 730324 EPA 351.2 Rev 2.0 1993 730495 92630249001 Outfall 001 EPA 353.2 Rev 2.0 1993 731521 92630249001 Outfall 001 EPA 365.1 Rev 2.0 1993 731489 EPA 365.1 Rev 2.0 1993 732111 Date: 10/21/202211:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 15 CHAIN -OF -CUSTODY Analytical Request Document Pace Analytical' Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevent fields LAB USE ONLY- Affix Workorder/Login Label Here or List Pace Workorder Number or , i� w • 9263024 9 SHADEC Container Preservative - 92630249 — " Preservative Types: (1) nitric acid, (2) sulfuric aciu, t_,l r (6) methanol (7) sodium bisulfate, (R) sorlium thiosulfate, (9) hexane, (A) ascorbic acid, (B) ammonium sulfate, (c nnium hydroxide, (D) TSP, (D) Unpreserved, (0) Other Company: b Ile-r Lolling Information: Address: S I.4� , 0 1; Rep or To Copy T Email To: - Geri r C Site Collection Info Address: �p L Customer Pr ect Name Number. 1 / State: County/City: Time Zone Collec ed: U��SCra [ ] IT [ ] MT [ ] CT h,KT Analyses lab Profile/Line: b Pr ' ,a� r3 {) ej v ("- ? z y` Xl �y+ ` -� sample Receipt Checklist: Custody Seals Present./Intact 't 0NA Custody Signatures Present N NA Collector Signature Present N NA Bottles Intact N NA Bottles NA N Sufficient Volume N NA Samples Received on Ice N NA VOA - Headspace Acceptable N USDA Regulated Soils Y N Samples in Holding Time QN NA Residual chlorin resent Y 0 NA 'Cl Stripe: _ - -- Sample pti Acc pt 1 ly e� N NA pH' Stripe : ��___.._ y N�' Sulfide PresentLead Acetate Strips: `- LAB USE ONLY: Lab Sample # / comments: Phone: 3 36_ 75•-5-.7 q!5 Email: O t Site/Facility ID 9: Compliance Monitoring? ( e5 [ ]No Collected By (print): /i/l pi Purchase Order H: Quote H: DW PWS ID q: DW Location Code: Collected By (signature): 7 Turnaround Date Required: Immediately Packed on Ice: ]Yes [ ]No Sample Disposal f ] Dispose as appropriate [ ] Return ( I Archive: ( ) Hold: - Rush: [ ] Same Day f ] Next Day [ [ 2 Day ( ] 3 Day [ ) 4 Da Y [ 1 S Day (Expedite Charges Apply) Field Pilfered (if applicable}: [ ] Yes ( ] NO Analysis: Y $� -- Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) Customer Sample ID Matrix * Comp / Grab Collected (or Composite Start) Composite End Res Cl Hof Ctns Date Time Date Time U r f A G-ri l? 2 DQ..C' TSS L-lYJl� i� l ZT cct Customer Remarks / Special Conditions J Possible Hazards: Type of Ice Used: Wet Blue Dry None SHORT HOLDS PRESENT(<72 hours): N N/A Lab Sample Temperature Info: !e • ' Temp Blank Received: Y N NA ThermlD11:��,...0�7i Cooler 1 Temp Upon Receipt: oC Cooler 1 Therm Corr. Factor:''-, oC ! Cooler 1 Corrected Temp: � Packing Material. Used: Lab Tracking It: (� 261 0299 Radchem sample(s) screened (<500 cpm): Y N NA Samples received via: FEDEX UPS Client Courier Pace Courier Relinquished by/Company: (Signature) Re(@quished by/Company: (Signature) m A Date/Time: Date/Time: Received by/Company: (Si at to) t� Received by/Company: Signature) Daterr/Time: I D/j 7/ Date/Time: MTJL LAB USE ONLY .�oC Comments: Table H: .. Acctnum: Template: Prelogin: PM: Trip Blank Received: Y N NA HCL McOH TSP Other Rel wished by/Company: (Signature) Ln Date/Time: Received by/Company: (Signature) Dale/Time: Non Conformance(s): Page: F D: YES / NO of: E111111to a J z W U a PO at I ix U, w V G, ul Remit 13P.111-1 ?r, int- Plastic Unpr,. -1. X X, 7 1 (N/A) (0.) Plastic LJF1pfcwAv(-'d (H/A) BV211-S00 niL Plastic lh,presewt,,l (N/A) Pf"111-1 liter Plastic Lhipresc-tvotl (rl/A) - z Z: Z /7Z UP-4S-125 ml, Plastic 112,10.1 (pI I < 2) (Cl-) Z LIX. It 1 ' BP3N-250tj)Lplasliclltlo3((,if < 2) /7 BPIZ-1?5 ml- 111wlic 7N Aret.jiL- P� NaO11 (>q) NaO1 I (III i > 12) m-ml-Wide-nimitherl Glass jar thiliceserve(l AG11.1-1 liter Amber LJnprwtrvvd (NIA) (Cl-) /-X AG 111-1 liter Amber I ICI (lit I < 2) 77 ;1z AG311-?50mt. Amber linlifest,.Ivt.lI (N/A) (CI-) , AGIS-1 liter Arriber 112SO.1 (p[ I < 2) AM5-2S0 ml. Amber 112SO I (III I < AG3A(DG3A)-'50 mL Amber PJl HCA (N/A)(CI) f)G91 1-40 int VOA IICl (PJ/A) VG9T-40 mI. vnA I'la.15201 (N/A) VG90-40 ml- VOA thipiesem-d (N/A) DG9P-40 ml, VOA I M104 (ri/A) VOAK (3 vials per kit)-5031; hit (N/A) V/GK (3 vials per hit) WHIGas hit (ri/A) SPS7-12S mt. Sterile PlaUir (NIA — lah) OPM-250 ml. Mimic (tJI12)2',O.l (9.3 9.7) AGOU -3 00 rul- Amber I Jnpreservoil vials (N/A) VSGQ-?0 m1_1cintillation vials (N/A) F)G9(.140 III[ Amber ihipr0Sf,'fVefl ViJ)S (N/A) In < fu n C) CL Eu LxI 0 NQ L -1 0 -1 CU I-) rU 0 r) C, 'U It, rui EU O 0 01-4 0 ru cr CA 0 0 0 fU 03 C. to (D 0 k. ru :2. D — F It, W 0 0 uu L:4 0 z 3 rt It, er 7) 4 1:, 'U ra Ali rl`�WeAnalytical www.pace]abs.com October 03, 2022 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92627627 Dear Accounts McHone: Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Enclosed are the analytical results for sample(s) received by the laboratory on September 26, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 r0aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92627627 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley 92627627 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92627627001 Outfall 001 SM 254OD-2015 LRB 1 PASI-E SM 521OB-2016 SRS 1 PASI-E Colilert-18 SRS 1 PASI-E PAS I-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 f�aceAnalytical� www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92627627 Sample: Outfall 001 Lab ID: 92627627001 Collected: 09/26/22 12:00 Received: 09/26/22 15:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D-2015 Pace Analytical Services - Eden Total Suspended Solids 6.8 mg/L 2.5 1 09/27/22 15:25 5210B BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521 OB-2016 Pace Analytical Services - Eden BOD, 5 day 31.4 mg/L 2.0 1 09/27/22 10:48 10/02/22 11:19 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms ND MPN/100ml- 1.0 1 09/26/22 18:26 09/27/22 12:41 Date: 10/03/2022 08:15 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 11 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92627627 QC Batch: 725981 Analysis Method: SM 254OD-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92627627001 METHOD BLANK: 3781734 Associated Lab Samples: 92627627001 Parameter Units Total Suspended Solids mg/L LABORATORY CONTROL SAMPLE: 3781735 Parameter Units Total Suspended Solids mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.5 09/27/2215:19 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 246 98 90-110 SAMPLE DUPLICATE: 3781736 92627467001 Dup Parameter Units Result Result Total Suspended Solids mg/L 103 90.0 SAMPLE DUPLICATE: 3781737 92627466002 Dup Parameter Units Result Result Total Suspended Solids mg/L 21.6 21.2 RPD Qualifiers 14 RPD Qualifiers 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/03/2022 08:15 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 11 r FRaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92627627 QC Batch: 726034 Analysis Method: SM 521OB-2016 QC Batch Method: SM 521 OB-2016 Analysis Description: 5210B BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92627627001 METHOD BLANK: 3781851 Associated Lab Samples: 92627627001 Parameter Units BOD, 5 day mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 10/02/2210:42 LABORATORY CONTROL SAMPLE: 3781852 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers BOD, 5 day mg/L 198 204 103 84.6-115 SAMPLE DUPLICATE: 3781854 92627534001 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 1500 1410 6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/03/2022 08:15 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 ti laaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92627627 QC Batch: 726078 Analysis Method: Colilert-18 QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92627627001 SAMPLE DUPLICATE: 3781978 Parameter Units Fecal Coliforms MPN/100mL 92627627001 Dup Result Result RPD Qualifiers ND ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/03/2022 08:15 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 I" RaceAnalXical www.pacelabs.com Project: Hope Valley Pace Project No.: 92627627 DEFINITIONS QUALIFIERS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC -Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. REPORT OF LABORATORY ANALYSIS (704)977-0981 This report shall not be reproduced, except in full, Date: 10/03/2022 08:15 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 11 aceAnalytical wWw.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Hope Valley Pace Project No.: 92627627 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92627627001 Outfall 001 SM 254OD-2015 725981 92627627001 Outfall 001 SM 521OB-2016 726034 SM 521OB-2016 92627627001 Outfall 001 Colilert-18 726078 Colilert-18 Date: 10/03/2022 08:15 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch 726335 726079 Page 9 of 11 r CHAIN -OF -CUSTODY Analytical Request Document LAB USE ONLY Affix Workorder/Login Label Here or List Pace Workorder Number or Pace Analytical' Chain-Ofis a LEGAL DOCUMENT NT -Complete all relevent fields 627 6N OIII# 9II Company: Billing Information: �o.. d� ALL SHADI Container Preservative T - IWI I I I:II I2I I I2I I7II 1, Addrs: {/ -1 192627627 Preservative Types: (1) nitric acid, (21 sulfunc......., .........., G methanol, 7 sodium bisulfate. R sot mm xa ascorbic acid, mmnmurn sulfate, ( ) n eth , O (.) f' thtc sulfate, (9) hexane, (A) a ' - id, (R) a u ate, (C nniuni hydroxide, (Dt T . , (U) Unpreserved, (0) Other Repor�,To' r Email To: 1 _t : " '� �- �-_f iiC r- . ' ... ' Copy T �, Site Collection Info/Address: rmlysps 11-ab Profile/Line: Customer Pr jest Name/Number, Staten, cCounty/City: Time Zone Collec ed: Lab Sample Receipt Checklist: Custody Seals Present/Intact 'i DNA Castody Signatures Present f_TtA IT( ] MT [ ] CT fT 7 �p Phone: ��_ 5'_ •! 9-7 5 Site/Facility ID ft: Compliance Monitoring? Email [�es ( ) No ,?��1�', NA Collector Signature Present Bottles _ntact Y'' NA Correct Bottles �N NA By (prin� Puf chQuotease Order H: DW PWS ID H:Collected C7! ifs) Jt,iDW Location Code: Sufficient Volume ,N NA Samples Received on Ice %N NA :Y VOA - Ileadspace Acceptable Y N (,m Collected By (signature): Turnaround Date Required: Immediately Packed on Ice Yes [ ] No USDA Regulated Soils Y PJ 147v Samples in Holding Time �S t7 NA r- Residual Chlorine Prcaen� Y".t�.NA Sample Disposal: Rush: Field Filtered (if applicable): ( ( Dispose as appropriate ( ] Return [ ] Same Day [ ] Next Day [ ) Yes ( ]No Cl Strips: Archive: — ( ] 2 Day [ ) 3 Day [ 1 4 Day [ ] 5 Day 1-5 Sample pH Acceptable Y N ( ] Hnlrl: —_ (Expedite Charges Apply) Analysts: � I P it strips: Sulfide Present Y to pA Lead Acetate Strips: _ _ Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), Product (P), Soil/Solid (SQ, Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) •41 I A `v t} LAB USE ONLY: Lab Sample # / Conuner.ts: " Comp / Collected (or Composite End Res tl of Customer Sample ID Matrix Grab Composite Start) Cl Ctns '© Q cc-p- Date Time Date Time Ci ........... Customer Remarks / Special Conditions / Possible Hazards: IYPe of Ice Used: Wet Blue Dry None SHORT HOLDS PRESENT (<72 hours):(Y` N N/A Lab Sample Temperature Info: Temp Blank Received: Y N NA Therm IDH: C Packing Material Used: Lab Tracking 0: 2610299 }/7 f G C- ! ( Cooler 1 Temp Upon RcceipC L1_ oC Radchem sample(s) screened (<50U cpm): Y N NA Samples received via: ` C Cooler 1 Therm Corr. Factor: - 1 oC - _ FEDEX UPS r iI ent ourier Pace Courier Cooler 1 Corrected Temp: !( 4 nC Relinquished by/Company: (Signature) Date/Time: Rec ived by/Company: (Signature) Date/Time: r MTJL LAB USE ONLY Comments: ,�_ t C} � Table €f: Acctnum: r ,� `� l - Rel/ uished by/Company: (Signature) Date/Time: Received gy/Company: (Signature) Date/Time: _ Template: Trip Blank Received: Y N NA Prelogin: PM: HCL McOfl TSP Other Relinnuished by/Company: (Signature) Date/Time: Received by/Company: (Signature) Date/Time: — - Non Canformance(s): Page: PB: YES / NO of 3 CD m `9 v S 9 n 1 —i � ry O � - 9 7 u m r� K m < a c V o_ 3 � n � m i O w• r � 1 N r � rt t 0 O o" m o. c 0 -s m � a fD in - ro '? C 3 rD m m 0- °' v Ln yCj ro � DJ 3 Z (D 3 N D 3 c m o a v m a v. 2 <' rn 0 a Matrix IlemB BP4U-125 mL Plastic Unpreserved (PJ/A) (Cl-) BP3U-250 mL Plastic Unpreserved (N/A) q BP2U-S00 ml- Plastic Unpreserved (N/A) i� 13PIU-1 liter Plastic Unpreserved (PI/A) BP45-125 mL Plastic 112SO4 (pll < 2) (Cl-) BP3N-250 mi. plastic IIN03 (pll < 2) BP4Z-125 mL Plastic. ZN Acetate & Na011 (>9) zzzz,zzz Z77-Z BP413-125 ml- Plastic NaOH (pl I > 12) (CI-) WGFU-Wide-mouthed Glass jar Unpreserved AGIU-1 liter Amber Unpreserved (N/A) (Cl-) AGllt-I liter Amber I1CI (pil < 2) AG3U-250 mL Amber Unpreserved (N/A) (Cl-) AG1S-1 liter Amber H2SO4 (pli < 2) AG3S-250 mL Amber 112SO4 (pH < 2) zzzzzzAG3A(DG3A)-250 mL Amber N114CI (N/A)(CI-) DG9H-40 mL VOA HCI (N/A) VG9T-40 mL VOA Na2S203 (N/A) VG9U-40 mL VOA Unpreserved (N/A) DG9P-40 mL VOA H3PO4 (hJ/A) VOAK (3 vials per kit)-S035 kit (N/A) V/GK (3 vials per kit)-VPII/Gas kit (N/A) SPST-125 mL Sterile Plastic (N/A — lab) SPZT-250 mL Sterile Plastic (N/A — lal)) 0P3A-250 mL Plastic (Nl12)2SO4 (9.3-9.7) AGOU-100 mI. Amber Unpreserved vials (N/A) VSGU-20 ml- Scintillation vials (N/A) DG9U.40 ml. Amber Unpreserved vials (N/A) * rn 41 < N ao ro 3 s ro oCL fD n X 3 v =- O 0- a \ w y + n O G ;q rt O cr V in O tD O O n Cr m O x D 0- 3 (U rl °' tT ro w CID z O O 0- -+, aq O o wo ro ^ Q a o ro EA a ro O N � _. T n < Cu 0 Cu ^. � i O O N bn c. - -V 0 m U RaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 September 23, 2022 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92625020 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on September 12, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, C" J Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones REPORT OF LABORATORY ANALYSIS ITMI �gecRac This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 RaceAnalXical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92625020 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 F�aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley 92625020 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92625020001 Outfall (001) SM 2540D-2015 ATR 1 PASI-E EPA 350.1 Rev 2.0 1993 SRS 1 PASI-E SM 521OB-2016 MWF 1 PASI-E Colilert-18 LRB 1 PASI-E PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 -PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92625020 Sample: Outfall (001) Lab ID: 92625020001 Collected: 09/12/22 12:00 Received: 09/12/22 15:47 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D-2015 Pace Analytical Services - Eden Total Suspended Solids 8.9 mg/L 2.7 1 09/13/22 13:14 350.1 Ammonia EDN Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Eden Nitrogen, Ammonia 36.7 mg/L 0.50 5 09/22/22 15:01 7664-41-7 5210B BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521 OB-2016 Pace Analytical Services - Eden BOD, 5 day 2.8 mg/L 2.0 1 09/13/22 09:22 09/18/22 10:58 R6 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms ND MPN/100ml- 1.0 1 09/12/22 18:19 09/13/22 13:28 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/23/2022 11:26 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 11 I raceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92625020 QC Batch: 722856 Analysis Method: SM 254OD-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92625020001 METHOD BLANK: 3766350 Associated Lab Samples: 92625020001 Parameter Units Total Suspended Solids mg/L LABORATORY CONTROL SAMPLE: 3766351 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 3766352 Parameter Total Suspended Solids SAMPLE DUPLICATE: 3766353 Parameter Total Suspended Solids Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.5 09/13/2213:09 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 228 91 90-110 92624655002 Dup Units Result Result mg/L 607 593 92624655001 Dup Units Result Result mg/L 56.9 59.5 RPD Qualifiers 2 RPD Qualifiers 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/23/2022 11:26 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 11 r' S PaceAnalytical � www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92625020 QC Batch: 724091 QC Batch Method: EPA 350.1 Rev 2.0 1993 Associated Lab Samples: 92625020001 METHOD BLANK: 3772859 Associated Lab Samples: 92625020001 Parameter Units Nitrogen, Ammonia mg/L QUALITY CONTROL DATA Analysis Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia, EDN Laboratory: Pace Analytical Services - Eden Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.10 09/22/22 10:37 LABORATORY CONTROL SAMPLE: 3772860 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 4.9 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3772861 3772862 MS MSD 92625808002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 0.72 5 5 5.6 5.6 98 98 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3772863 3772864 MS MSD 92626105003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 4.9 4.9 98 98 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/23/2022 11:26 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 AaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92625020 QC Batch: 722859 QC Batch Method: SM 521OB-2016 Associated Lab Samples: 92625020001 METHOD BLANK: 3766377 Associated Lab Samples: 92625020001 Parameter Units BOD, 5 day mg/L LABORATORY CONTROL SAMPLE: 3766378 Parameter Units BOD, 5 day mg/L QUALITY CONTROL DATA Analysis Method: SM 521 OB-2016 Analysis Description: 5210B BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 09/18/2210:47 Spike LCS Conc. Result 198 205 SAMPLE DUPLICATE: 3766380 92624874001 Dup Parameter Units Result Result BOD, 5 day mg/L 901 883 LCS % Rec % Rec Limits Qualifiers 103 84.6-115 RPD Qualifiers 2 R6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/23/2022 11:26 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 -PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92625020 QC Batch: 722974 QC Batch Method: Colilert-18 Associated Lab Samples: 92625020001 SAMPLE DUPLICATE: 3766832 Parameter Units Fecal Coliforms MPN/100mL QUALITY CONTROL DATA Analysis Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden 92625020001 Dup Result Result RPD Qualifiers ND ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/23/2022 11:26 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 11 -PaceAnalytical www.pacelabs.com Project: Hope Valley Pace Project No.: 92625020 DEFINITIONS QUALIFIERS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as 'Total' may vary slightly from the sum of the reported component parameters. Pace Analytical is TIN accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS R6 The RPD between valid sample dilutions exceeded 30%. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/23/2022 11:26 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 11 IaceAnalytrcal www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Hope Valley 92625020 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92625020001 Outfall (001) SM 254OD-2015 722856 92625020001 Outfall (001) EPA350.1 Rev 2.0 1993 724091 92625020001 Outfall (001) SM 521OB-2016 722859 SM 521OB-2016 723487 92625020001 Outfall (001) Colilert-18 722974 Colilert-18 722975 Date: 09/23/2022 11:26 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 11 PaceAnalytical ' Company: Addre}s:�r f d S L�OUl7 Report.Toi CHAIN -OF -CUSTODY Analytical Request Document Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevent fields Billing Information: Email To: I Copy T t Site Collection Info Address: y E - /off Customer P ject Name/Number: State: CCCountty/City: rime Zone Collec ed: Syr IJOOSEfa [ ) PT [ ) MT [ 1 CT [y-ET Phone: 3 36- l5 _ 78 lC Site/Facility ID 4: Compliance Monitoring' Email: IO`T J es [ 1 No Collected By (print): Purchase Order N: DW PWS ID 9: 44 drf-4;Z? Quote tt: DW Location Code Collected By (signature): Turnaround Date Required: Immediately Packed on Ice: e / ( 1 Yes [ ]No Sample Disposal: Rush: Field Filtered (if applicable): I I Dispose as appropriate ( ) Return ( 1 Same Day [ 1 Next Da r Archive: Y ( I Yes [ J No t1 ( ) ( 1 2 Day ( 13 Day f 14 Day (1 s Da [ J Hold (Expedite Charr;es Apply) Y Analysis: v Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) s Comp / Collected (or Res # of q Q Customer Sample ID Matrix ' Grab Composite Start) Composite End Cl Ctns 4l Date. Time cc are Timo t`L 6r4b '—t22 c=ra�i t 7a Customer Remarks / Special Conditions / Possible Hazards: Type of Ice Used: Wet Blue Dry None Packing Material Used: Ors �Le 1 � Radchem sample(s) screened (<500 cpm); Y N NA Relinquished by/Company: (Signature) pate/Time: Received by/Company: Signature) Rel'CDquished by/Company: (Signature) Date/Time: Received by/Com ar y: (Si ature) Reli uished by/Company: (Signature) Date/rime: Received by/Company: (Signature) LAB USE ONLY- Affix Workorder/Login Label Here or List Pace Workorder Number or u WO#:92625020 ALI.SHAD' III III I ill 111 l Container Preservative i' III I IIII - — 92625020 " Preservative Types: (1) nitric acid, (2) sulfu, (6) methanol, (7) sodium bisulfate, (8) sodium thiosulfate.. (9) hexane, (A) ascorbic acid, (8) ammonium sultare, (C n opium hydroxide, (D) TSP, (U) Unpreserved, (0) Other Analyses lab Profile/Line: Lab Sample Receipt Checklist: Custody Seals Present/Intact Y N NA Custody Signatures Present Y N NA Collector Signature Present Y N NA Bottles Intact Y N NA Correct Bottles Y N NA Sufficient Volume Y N NA Samples Received on ice Y N NA VOA - Headspace Acceptable Y N NA USDA Regulated Soils Y N NA Samples in Holding Time Y N NA Residual Chlorine Present Y N NA CI.Strips: _ Sample. pil Acceptable Y N NA pHstri.ps: _. Sulfide Present---- Y N NA Lead Acetate Strips: LAB USE ONLY: Lab Sample # / Comments: `' Soy-5 TSs F c V SHORT HOLDS PRESENT(<72 hours): ° Y N N/A .. Lab Sample Temperature Info: Temp Blank Received: Y N NA Therm IDN: 'Cooler 1 Temp Upon Receipt: oC Cooler 1 Therm Corr. Factor: oC Cooler 1 Corrected Temp: oC Comments: Lab Tracking k: O Samples received via: FEDEX UPS Client Courier Pace Courier Date/Time: �1 11212 2 I S i � Date/Time: MTJL LAB USE ONLY Table #: Acctnum: Template: Pretogin: PM: P1's: Trip Blank Received: Y N NA HCL McOH TSP Other Date/lime: Non Conformance(s): Page: YES / NO of: �l ceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 September 08, 2022 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Inc Pace Project No.: 92623051 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on August 30, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, C�Fir� Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 f°JaceAnalytical www.pacefabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Inc Pace Project No.: 92623051 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 Face Analytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley Inc 92623051 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92623051001 Outfall 001 SM 2540D-2015 AED 1 PASI-E Colilert-18 ATR 1 PASI-E SM 521OB-2016 TFD 1 PASI-A PAS [-A = Pace Analytical Services - Asheville PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 PaceAnalytical�� www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Inc Pace Project No.: 92623051 Sample: Outfall 001 Lab ID: 92623051001 Collected: 08/30/22 12:30 Received: 08/30/22 15:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 254OD-2015 Pace Analytical Services - Eden Total Suspended Solids 7.8 mg/L 2.5 1 09/01/22 10:13 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms ND MPN/100mL 1.0 1 08/30/22 18:24 08/31/22 12:49 5210B BOD, 5 day Analytical Method: SM 521OB-2016 Pace Analytical Services -Asheville BOD, 5 day 13.6 mg/L 2.0 1 09/01/22 07:40 09/06/22 09:57 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/08/2022 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 11 — "I AaceAnalVtical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Inc Pace Project No.: 92623051 QC Batch: 720574 Analysis Method: SM 2540D-2015 QC Batch Method: SM 2540D-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92623051001 METHOD BLANK: 3754729 Matrix: Water Associated Lab Samples: 92623051001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 09/01/22 10:04 LABORATORY CONTROL SAMPLE: 3754730 Spike LCS LIDS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 236 94 90-110 SAMPLE DUPLICATE: 3754805 92623023002 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 380 340 11 SAMPLE DUPLICATE: 3754816 92623026002 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 27.2 21.6 23 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/08/2022 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 11 Pace Analytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Inc Pace Project No.: 92623051 QC Batch: 720615 Analysis Method: Colilert-18 QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92623051001 SAMPLE DUPLICATE: 3754839 92623051001 Dup Parameter Units Result Result RPD Qualifiers Fecal Coliforms MPN/100mL ND 1.0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/08/2022 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Inc Pace Project No.: 92623051 QC Batch: 720838 Analysis Method: SM 521OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210B BOD, 5 day Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92623051001 METHOD BLANK: 3756196 Matrix: Water Associated Lab Samples: 92623051001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg/L ND 2.0 09/06/22 09:43 LABORATORY CONTROL SAMPLE: 3756198 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day mg/L 198 191 97 84.6-115 SAMPLE DUPLICATE: 3756199 92623243001 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 2070 1970 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/08/2022 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 �aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Hope Valley Inc Pace Project No.: 92623051 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as 'Total' may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/08/2022 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 11 FaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Hope Valley Inc Pace Project No.: 92623051 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92623051001 Outfall 001 SM 2540D-2015 720574 92623051001 Outfall 001 Colilert-18 720615 Colilert-18 720616 92623051001 Outfall 001 SM 521OB-2016 720838 SM 521OB-2016 720876 Date: 09/08/2022 10:53 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 11 p CHAIN -OF -CUSTODY Analytical Request Document LAB USE ONLY- Affix Workord, I it Pace Workorder Number or Face Analytical WO# : 92623051 Chain-of-Custudy is a LEGAL DOCUMENT -Complete. all rc lcvent fields - Company: Billing Information ALL SHADE[ Co III ���` IN Container Preservative Type 92623051 Address: Preservative 7 es: 1 nitric acid, 7 ,uiluric acid, 3 hydrochloric acid, ! soaiuni n (s) methanol, (7) sodium bisulfate, (8) sodium thiosulfate, (9) hexane, (A) ascorbic acid, (B) ammc iium sulldta, (C) a manh,rn hydroxide, (pJ TSP. u r)ther Rep or' 1`0 Email To: e Copy T51: Site Collection Info/Address t r } , 7 -f !"G„ e t .'i,' ' traG's'9, (U) p serv=d, {D) ,dip' Analyses Lab Profile/Line: Customer Pr jest Name/Number: State:, CCounty/City: Time Zone Collet ed: L.,t, sample Receipt Checklist: Custody Seals present: Intact YY A custody Signatures Present Y taA ]PT[ ]MT[ ]CT [4;ET Phone 1 C' Site/FacilitylD#: Compliance Monitoring? Email [],, "Its [ ] No Collector Signature Present ti t{A Bottles intact P7 HA Correct Bottles 11 NA Collected By (print): P Purchase Order N: DW PWS ID 9: } � f`ra'le`'•ids'�.:,Quote #: DW Location Code: Sufficient volume to !aA Samples Received or. Ice Y iJ tdA Collected By (signature): Turnaround Date Required: Immediate) P y Packed on Ice: VOA - aeadspace Acceptable a <1 X s t . 7 . i' ( ] Yes [ ] No USDA Regulated Soils Y to Samples in Holding Time �t7 ?", Residual Chlorin r sent Y("'v *IA Sample Disposal: flush: Field Filtered (if applicable): [ ] Dispose as appropriate ( ] Return ( ] Same Day [ ] Next Day [ ] Yes ( ] No Cl Strips; -_ e [ ] Archive: ( [ 2 Day [ ] 3 Day [ ] 4 Day [ ] 5 Day _ Sample PH Acc� nl Y N ea. Hald: {Expedite Charges App1V) Analysis: �""�'-'-- �., H Straps: _ P P............ Sulfide Present " Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), lead Acetate Strips: Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) a r �" .� LAP USE ONLY: Lab sample l Comments * Comp / Collected (or Composite End Res » of Customer Sample I❑ Matrix Grab Composite Start) Cl Ctns lu Date Time Date Time ?Z (Z' / ✓' ]n-'a y Customer Remarks / Special Conditions / Possible Hazards: Type of Ice Used: <jvVet ' Blue Dry None SHORT HOLDS PRESENT (<72 hours : Y tJ N/A. Lab Sample Temperature Into: Temp Blank Received: Y INL NA Therm 10,1:,je. 002- Packing M.iterial U, ,& t r'b Trdck'ing tt: 10299 Csf r f Cooler l Temp Upon Receipt: 1 .� oC ,r I"mold (<'"'00 cpril): Y N Nth `Simples rec:,ivod vi:r " Cooler 1 Therm Corr. Faetot:-�,joC - I I DI x UP Client ouri+,r Pace Courier Cooler 1 Corrected Temp: oC Comments: _ Relinquished by/Company (Signature) - Date/Time: Received by/Company: (Signature) Date/Time: MT1L LAB USE ONLY f p- b ti� �I (� Table 4: Acctnum: 1 Reli%uished by/Company: (Signature) Date/Time: Received by/ ti parry: ignature) Date/Time: Template: Trip Blank Received: Y N NA Prelogin: HCL McOH TSP Other Relin'Auished by/Company: (Signature) Date/Tirne: Received by/Company: (Signature) PMB T7�� Non Conformance(s]: Page: PD: YES ( P10 of: ...._..._._......__. L Cl Of 1`13 Jill Ill, Ir I)m ....... $­d (111A) (H/A) '",11VI'd (fi/Al fill Ph Ill 112',( 1.1 (1.11 fill H.11 Ilc Ill Af L.01 I(,,)) .1 it 12, fill Ill.v lir I1-01 I fill I 0I I AGIII I ((l) . . . . . ........ AG S-I lilor Aml,t r if?, < fill -ICI vc;,) r-lo ,,I VM Ha?1;:If1j (I.'/A) Vi -911 "10 1111 VC14 111 ipwlwi ­- I (O!A) I I(VIV, -11) fill. MA I 'I lq) I (11/1,) f)G'J';,4fI lilt. VOA If.),.:0.1 (f)/A) VIGK I I vi..Is til.l'-I it (11p) Ph'Aw (fl/A - 1,,I,) 111711-2rr) mI N.".14 I (fllop%c)-1 pI 'I 7.7j Aro(IIJI-100 Jill. AlOw V,611-2f) 11.1 !;I haill, Jim VIA'. (11/,1) 116,111 -M ml. Amlwt hilawrivo.1 vi.ds Ill, A) (II 1L (U - C) b JrU to lu U c) <` 17 :laceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 August 25, 2022 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92620645 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on August 16, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones 2��QQ pCcpk� TNI !' �eOpA�� REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 12 RaceAnalytical www.pacelabs.com Project: Hope Valley Pace Project No.: 92620645 Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 12 Pace Analytical Services, LLC 'FaceAnalytical 1377 South Park Drive Kernernersville, NC 27284 www.pacelabs.com (704)977-0981 SAMPLE ANALYTE COUNT Project: Hope Valley Pace Project No.: 92620645 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92620645001 Outfall 001 SM 2540D-2015 LRB 1 PASI-E EPA 350.1 Rev 2.0 1993 SRS 1 PASI-E SM 521OB-2016 AED 1 PASI-E Colilert-18 MWF 1 PASI-E PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 12 I% R-aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92620645 Sample: Outfall 001 Lab ID: 92620645001 Collected: 08/16/22 11:00 Received: 08/16/22 12:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 254OD-2015 Pace Analytical Services - Eden Total Suspended Solids 2.5 mg/L 2.5 1 08/18/22 16:13 350.1 Ammonia EDN Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Eden Nitrogen, Ammonia 45.4 mg/L 1.0 10 08/17/22 10:15 7664-41-7 521013 BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521OB-2016 Pace Analytical Services - Eden BOD, 5 day 4.8 mg/L 2.0 1 08/17/22 21:32 08/22/22 17:09 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms ND MPN/100ml- 1.0 1 08/16/22 14:56 08/17/22 09:00 Date: 08/25/2022 05:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 12 I Facekialytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92620645 QC Batch: 718163 Analysis Method: SM 254OD-2015 QC Batch Method: SM 2540D-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92620645001 METHOD BLANK: 3743767 Matrix: Water Associated Lab Samples: 92620645001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 08/18/22 16:13 LABORATORY CONTROL SAMPLE: 3743768 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 242 97 90-110 SAMPLE DUPLICATE: 3743769 92620766002 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 132 116 13 SAMPLE DUPLICATE: 3743770 92620727001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 62.0 72.4 15 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/25/2022 05:01 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 12 {�aceAnai�ical J' ` www.pacelabs.com i Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92620645 wl— tiaicn: 717716 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia, EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92620645001 METHOD BLANK: 3741305 Matrix: Water Associated Lab Samples: 92620645001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 08/17/22 09:30 LABORATORY CONTROL SAMPLE: 3741306 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 4.9 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3741307 3741308 MS MSD 92619953002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/ L 2.2 5 5 6.9 6.9 93 93 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3741309 3741310 MS MSD 92620780002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 2.8 5 5 7.5 7.5 94 94 90-110 0 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/25/2022 05:01 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 12 PaceAnalXical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92620645 QC Batch 717876 Analysis Method: SM 521OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210B BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92620645001 METHOD BLANK: 3742260 Matrix: Water Associated Lab Samples: 92620645001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg/L ND 2.0 08/22/22 16:11 LABORATORY CONTROL SAMPLE: 3742261 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers BOD, 5 day mg/L 198 210 106 84.6-115 SAMPLE DUPLICATE: 3742263 92620727001 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 107 114 6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/25/2022 05:01 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 12 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92620645 QC Batch: 717560 Analysis Method: Colilert-18 QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92620645001 SAMPLE DUPLICATE: 3740683 Parameter Units Fecal Coliforms MPN/100mL 92620730001 Dup Result Result 1.0 ND RPD Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/25/2022 05:01 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 12 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Hope Valley Pace Project No.: 92620645 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/25/2022 05:01 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 12 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Hope Valley 92620645 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92620645001 Outfall 001 SM 254OD-2015 718163 92620645001 Outfall 001 EPA 350.1 Rev 2.0 1993 717716 92620645001 Outfall 001 SM 521OB-2016 717876 SM 521OB-2016 718095 92620645001 Outfall 001 Colilert-18 717560 Colilert-18 717561 Date: 08/25/2022 05:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 12 oswl- .` CHAIN -OF -CUSTODY Analytical Request Document® 92620645 trderNumber or PaceAnalytical' Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevent fields 11111111111111111 11111 Company: Billing Information: b Ile- L' %/ ' NLY 92620645 Addre s: Repo- To' Email To: / `—'�T I—/ C. 't " Preservative Types: (1) nitric acid, (2) sulfuric acid, (3) hydrochloric acid, (4) sodium hydroxide, (5) zlnc acetate, (6) methanol, (7) sodium bisulfate, (8) sodium thiosulfate, (9) hexane, (A) ascorbic acid, (H) ammonium sulfate, (C hydroxide, Copy T r Site Collection Info Address: �f /0 �i2r' �Cr n nonium (D) TSP, (U) Unpreserved, (0) Dther Analyses Lab Profile/Line: Customer P ject Name/Number. State: County/City: Time Zone Collec ed: Lab Sample Receipt Checklist: '..Custody Seals Present/intact Y (�7 }tlA Custody Signatures Present Y PT [ ] MT [ ) CT T Lt V�VSC� Phone: 3 36_.•7 Jr'S'._ 8q!5 Site/Facility ID 4: Compliance Monitoring' Email: [ e5 ( )No �X!/}`7A Collector Signature Present N NA Bottles Intact NA Correct Bottles NA Collected By (print : A4{ ,� Purchase Order tt: Quote N: DW PWS ID 4: ar-/ I�) C+7 DW Location Code: n Sufficient VolumeCollected samples Received on ice N R By (signature): Turnaround Date Required: Immediately Pace on Ice: VOA- Headspace Acceptable Y N C I )Yes [ ]No ,USDA Regulated Soils y N Samples in Ifol.di.ng Time Residual ChtLor' ne Pr PI NA Y NA Sample Disposal: ( ) Dispose as appropriate ( ) Return Rush: [ j Same Day [ ) Next Day Field Filtered (if applicable): [ Yes ] [ j No Cl . Strips: t,t l 1 Archive: [ ] 7 Day [ ) 3 Day [ ) 4 Da Y l) 5 Day Analysis: Sampje, pFi AccP,pt 1 N NA I 1 Hoid: __ (Expedite Charles Apply) _ PH Sulfide Present Y N NA Lead Acetate Strips: Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), Product (P), Soil/Solid (SQ, Oil (OL), Wipe (WP), Air (AR), Tissue ITS), Bioassay (B), Vapor (V), Other (OT)-- ' A ' V tj N - LAB USE ONLY: Lab Sample # / Comments: Customer Sample. ID Matrix' Comp / Grab Collected (or Composite Start) Composite End Res Cl 4of tins Date Time Date Time 0 f Ja f/ ion ; G-ra b rL- �? r'; Oo ' . I 2 ''� — — TSS ra i 1/'Pe e- na l Customer Remarks / Special Conditions / Possible Hazards: Type of Ice Used: Wet Glue < Dry None Packing Material Used: Relinquished by/Company: (Signature) quis .• r .� ciT-yt hed by/Company: (Signature) ro #quished by/Company: (Signature) N Radchem sample(s) screened (<500 cqm): Y N NA Date/Time: Received by/Co/ ny: (Signa Lire) Date/Time: Receiv b /Comps y: (Sig ature Date/rime: Received by/Company: (Signature) SHORT HOLDS PRESENT (<72 hours): ' Y N N/A Lab Tracking#: 2610299 Samples received via: FEDEX UPS Client Courier Pace Courier Dat Tim MTJL LAB USE ONLY 1 % / able p: ( : (� Acctnum: D to/Ti e: Template: Prelogin: Date/Time: PM: 1PB: Lab Sample Temperature Info: Temp Blank Received: Y 62 NA Therm Cooler i Temp Upon Receip ; r oC Cooler 1 Therm Corr. Factor— —O, [—oc Cooler 1 Corrected Temp: —5j _aC Comments: 'Trip Blank Received: CY,-' N NA HCL McOH TSP Other Non Conforma�ce(s): Page YES of: m a ti rr 73- iu CL 0 lu U, - tr 0 ' IL ul U'l rL PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 August 10, 2022 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Pace Project No.: 92617243 Dear Accounts McHone: Enclosed are the analytical results for sample(s) received by the laboratory on July 28, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 13 115taceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92617243 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 13 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Pace Project No.: 92617243 Lab ID Sample ID 92617243001 Outfal 1001 PASI-A = Pace Analytical Services -Asheville PASI-E = Pace Analytical Services - Eden SAMPLE ANALYTE COUNT Method Analysts Analytes Reported Laboratory SM 254OD-2015 DAW 1 PASI-E SM 521OB-2016 MWF 1 PASI-E Colilert-18 AED 1 PASI-E TKN+NO3+NO2 Calculation MDW 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 SMT 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 13 { P. WeAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Pace Project No.: 92617243 Sample: Outfall 001 Parameters Lab ID: 92617243001 Collected: 07/28/22 11:00 Received: 07/28/22 12:10 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D-2015 Pace Analytical Services - Eden Total Suspended Solids 4.7 mg/L 2.5 1 08/01/22 16:00 5210B BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521OB-2016 Pace Analytical Services - Eden BOD, 5 day ND mg/L 2.0 1 07/29/22 14:24 08/03/22 16:31 B2 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms ND MPN/100mL 1.0 1 07/28/22 17:00 07/29/22 11:24 Total Nitrogen Calculation Analytical Method: TKN+NO3+NO2 Calculation Pace Analytical Services - Asheville Total Nitrogen 18.4 mg/L 0.040 1 08/10/22 22:29 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Kjeldahl, Total 17.9 mg/L 0.50 1 08/03/22 18:23 08/04/22 03:58 7727-37-9 353.2 Nitrogen, NO2/NO3 pres. Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, NO2 plus NO3 0.49 mg/L 0.040 1 08/10/22 03:01 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville Phosphorus 2.5 mg/L 0.050 1 08/03/2218:08 08/04/2218:41 7723-14-0 Date: 08/10/2022 10:30 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 13 . aceAnalytrcal www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92617243 QC Batch: 713575 Analysis Method: SM 254OD-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92617243001 METHOD BLANK: 3720456 Matrix: Water Associated Lab Samples: 92617243001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 08/01/22 15:53 LABORATORY CONTROL SAMPLE: 3720457 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 254 102 90-110 SAMPLE DUPLICATE: 3720459 92617163001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 72000 68400 5 SAMPLE DUPLICATE: 3723524 92617023001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 369 366 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 10:30 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 13 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92617243 QC Batch: 713802 Analysis Method: SM 521OB-2016 QC Batch Method: SM 521 OB-2016 Analysis Description: 5210B BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92617243001 METHOD BLANK: 3721493 Matrix: Water Associated Lab Samples: 92617243001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg/L ND 2.0 08/03/22 15:47 LABORATORY CONTROL SAMPLE: 3721494 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day mg/L 198 196 99 84.6-115 SAMPLE DUPLICATE: 3721496 92617267001 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 122 119 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 10:30 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 13 RaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92617243 QC Batch: 713730 Analysis Method: Colilert-18 QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92617243001 SAMPLE DUPLICATE: 3721188 Parameter Units Fecal Coliforms MPN/100mL 92617203003 Dup Result Result RPD Qualifiers 2420 2420 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 10:30 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 13 RaeeAnalytieal www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92617243 QC Batch: 714678 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92617243001 METHOD BLANK: 3726098 Associated Lab Samples: 92617243001 Parameter Units Nitrogen, Kjeldahl, Total mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.50 08/04/22 03:29 LABORATORY CONTROL SAMPLE: 3726099 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg/L 10 10.0 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3726100 3726101 MS MSD 92617538001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 0.44J 10 10 10.2 10.4 98 100 90-110 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3726102 3726103 MS MSD 92617538002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L ND 10 10 10.4 10.9 102 107 90-110 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 10:30 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 13 FaceAnalX cal www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92617243 QC Batch: 715835 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92617243001 METHOD BLANK: 3731739 Matrix: Water Associated Lab Samples: 92617243001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, NO2 plus NO3 mg/L ND 0.040 08/10/22 02:26 LABORATORY CONTROL SAMPLE: 3731740 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, NO2 plus NO3 mg/L 2.5 2.5 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3731741 3731742 MS MSD 92615956008 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L 0.18 2.5 2.5 2.9 2.9 108 108 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3731743 3731744 MS MSD 92618432002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L 32.0 2.5 2.5 37.4 36.1 218 167 90-110 3 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 10:30 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 13 I-aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Pace Project No.: 92617243 QC Batch: 714544 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92617243001 METHOD BLANK: 3725423 Matrix: Water Associated Lab Samples: 92617243001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phosphorus mg/L ND 0.050 08/04/2218:39 LABORATORY CONTROL SAMPLE: 3725424 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg/L 2.5 2.5 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3725425 3725426 MS MSD 92617243001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 2.5 2.5 2.5 5.0 5.1 101 104 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3725427 3725428 MS MSD 92617278001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 3.1 2.5 2.5 5.0 6.3 75 127 90-110 23 M 1. R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 10:30 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 13 FaceAnalytical www.pacelabs.com Project: Hope Valley Pace Project No.: 92617243 DEFINITIONS QUALIFIERS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenyihydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS B2 Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 10:30 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 13 hceAnalytical �' www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Hope Valley Pace Project No.: 92617243 Lab ID Sample ID QC Batch Method 92617243001 Outfall 001 SM 2540D-2015 92617243001 Outfall 001 SM 521OB-2016 92617243001 Outfall 001 Colilert-18 92617243001 Outfall 001 TKN+NO3+NO2 Calculation 92617243001 Outfall 001 EPA 351.2 Rev 2.0 1993 92617243001 Outfall 001 EPA 353.2 Rev 2.0 1993 92617243001 Outfall 001 EPA 365.1 Rev 2.0 1993 Date: 08/10/2022 10:30 PM Analytical QC Batch Analytical Method Batch 713575 713802 SM 521OB-2016 714076 713730 Colilert-18 713731 716431 714678 EPA 351.2 Rev 2.0 1993 714876 715835 714544 EPA 365.1 Rev 2.0 1993 714849 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 13 CHAIN -OF -CUSTODY Analytical Request Document Pc?CfeA vlyfical ' Chain -of Custody i; a LEGAL DOCUMENT - Complete all relevent fields Company: Billing Information: Address: Repor 70 9�r - Email To: 16 Copy T Site Collection Info/Address y L Customer Pr jest Name/Number: State"�:'� �[ '°County/City: Time Zone Collec ed: IT ( ] MT [ ) CT T Phone:_ "�-� 'Email: ,J Site/Facility ID If: Compliance Monitoring? f),.}-kes [ ] No Collected By (print : Mat-! -. "�:./:>-t.,_.. Purchase Order ft: Quote DW PWS ID #: //) #: DW Location Code: Collected By (signature): % Turnaround Date Required: Immediately y Packed an Ice: t / f [ ( Yes ( (No Sample Disposal: Rush: Field Filtered (if applicable): I I Dispose as appropriate [ I Return [ ) Same Day [ ] Next Day [ )Yes [ ]No ( I Archive: [ 1 2 Day I 1 3 Day [ ) 4 Day [ ] 5 Day (Expedite Charges Apply) Analysis: Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), Product (P), Soil/Solid (51L), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) Customer Sample ID Matrix " Collected (or Start) Composite End Res CI Date lime Date Tune qGrabComposite a + , �" "may' fir,' LAB USE ONLY- Affix Workorder/l ' , • ... - - -- , :-. ,,,,.,, ,,, —1,-14— NumhPr or MT wo# : V zs 1 7243 . ALL Stjv 1111111111111111111111Container — Preservative T "f:re � 92617243 ' Preservative Types: (1) nitric acid, (2) sulfuric acid, (3) hydrochloric acid, (4) sodium hydroxide, (S) zinc acetate, (6) methanol, (7) Sodium bisulfate, (8) sodium thinsulfate, (9) hexane, (A) ascorbic acid, (8) ammonium sulfate, (C.an maniirm hydroxide, (D) TSP, (U) Lhtpreserved, (0) Other J Analyses Lab Profile/line: Lah. Sampl.e- Receipt Checklist: Custody Seals Present!IntaCt `t 1"1NA Custody Signatures Present 1' NA Collector Signature Present N NA - Bottles Intact N NA Correct Bottles lY7N NA5'lfficient Volume YEN NA samples Received on Ice (—Y N' NA VOA - eeadspaee Acceptable `l N cn USDA Regulated Soils Y t7 i.� C.N"8 Samples in Holding Time l';N NA etesidual. Chlorine Pi ese v h VA Cl Strips f.( J I.,. Sample pit A-C_ce t..i'�lf 14 NA <1 pit Strips :y Sulfide Present Y Fi Lead Acetate Strips: v z LAB USE ONLY: # of Q J fab Sample # / Comments: Ctns rc L L, Customer Remarks / Special Conditions / Possible Hazards: Type of ice Used: Wet Blue Dry None Packing Material Used: Radchem sample(s) screened (<500 cpm): Y N NA Relinquished by/Company: (Signature) Date/'rime: Rece( ,d by/Company: 'gnature) Reli@quished by/Company: (Signature) Date/Time: Received by/Comk iylsrgnahn'e) is Rel9quished by/Company: (Signature) Date/Time: Received by/Cornpany: (Signature) w SHORT HOLDS PRESENT (<72 hours): Y,)N N/A Lab Tracking #: 2610299 iamples received via:��� FEDEX UPS Client ., Courier Pace Courier Date/Time: MT11 LAB USE ONLY Table #: b Arc ctnum: Date/7 ime: Template: Prelogin: PM: 1'Il: Do- i' Lab Sample Temperature Info: Temp Blank Received: Y N NA Therm IDff: q 'c Cooler 1 Temp Upon Receipt:• i oC Cooler 1 Thern Corr. Factor:;__ OC Cooler 1 Corrected Temp: =—e C Comments: Trip Blank Received: Y N NA HCL McOH TSP Other Non Conformance(-,): Page: •� yts / NO of FaceAnalytical www.pacelabs.com July 05, 2022 Accounts Payable/Tim McHone Hope Valley, Inc. P.O. Box 467 Dobson, NC 27017 RE: Project: Hope Valley Inc Pace Project No.: 92611846 Dear Accounts McHone: Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Enclosed are the analytical results for sample(s) received by the laboratory on June 27, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures cc: Martin Semones REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 PiceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 Project: Hope Valley Inc Pace Project No.: 92611846 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 FaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Pace Project No.: Hope Valley Inc 92611846 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92611846001 Outfall 001 SM 2540D-2015 LRB 1 PASI-E SM 521OB-2016 DAW 1 PASI-E Colilert-18 SRS 1 PASI-E PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Hope Valley Inc Pace Project No.: 92611846 Sample: Outfall 001 Lab ID: 92611846001 Collected: 06/27/22 12:00 Received: 06/27/22 15:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[ 2540D Total Suspended Solids Analytical Method: SM 254OD-2015 Pace Analytical Services - Eden Total Suspended Solids 2.7 mg/L 2.5 1 06/29/22 09:48 5210B BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521 OB-2016 Pace Analytical Services - Eden BOD, 5 day 11.8 mg/L 2.0 1 06/28/22 10:12 07/03/22 16:05 Colilert-18 Fecal Coliform EDN Analytical Method: Colilert-18 Preparation Method: Colilert-18 Pace Analytical Services - Eden Fecal Coliforms 2.0 MPN/100ml- 1.0 1 06/27/22 18:48 06/28/22 13:15 Date: 07/05/2022 02:49 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 11 PkeAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Inc Pace Project No.: 92611846 QC Batch: 707470 Analysis Method: SM 254OD-2015 QC Batch Method: SM 2540D-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92611846001 METHOD BLANK: 3690096 Associated Lab Samples: 92611846001 Parameter Units Total Suspended Solids mg/L LABORATORY CONTROL SAMPLE: 3690097 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 3690098 Parameter Total Suspended Solids SAMPLE DUPLICATE: 3690099 Parameter Total Suspended Solids Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.5 06/29/22 09:42 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 248 99 90-110 92611794001 Dup Units Result Result mg/L 521 529 92611795001 Dup Units Result Result mg/L 96.6 89.6 RPD Qualifiers 2 RPD Qualifiers 7 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 11 waceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Inc Pace Project No.: 92611846 QC Batch: 707335 Analysis Method: SM 521OB-2016 QC Batch Method: SM 521 OB-2016 Analysis Description: 5210E BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92611846001 METHOD BLANK: 3689408 Matrix: Water Associated Lab Samples: 92611846001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg/L ND 2.0 07/03/22 15:20 LABORATORY CONTROL SAMPLE: 3689409 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day mg/L 198 198 100 84.6-115 SAMPLE DUPLICATE: 3689411 92611797001 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 1950 1880 4 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 AaceAnalytical � www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Hope Valley Inc Pace Project No.: 92611846 QC Batch: 707262 Analysis Method: Colilert-18 QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92611846001 SAMPLE DUPLICATE. 3689253 92611846001 Dup Parameter Units Result Result RPD Qualifiers Fecal Coliforms MPN/100mL 2.0 ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 FaceAnalytrcal { www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Hope Valley Inc Pace Project No.: 92611846 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TN I accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 11 6 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Hope Valley Inc 92611846 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92611846001 Outfall 001 SM 254OD-2015 707470 92611846001 Outfall 001 SM 521OB-2016 707335 SM 521 OB-2016 707578 92611846001 Outfall 001 Colilert-18 707262 Colilert-18 707263 Date: 07/05/2022 02:49 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 11 CHAIN -OF -CUSTODY Analytical Request Document PacekulWical ' Chain-ef-Custody is il LEGAL DOCUMENT -Complete all relevent fields LAB USE ONLY- Affix Workorder/Login Label Here or List Pace Wnrl-- MTJL Lno-i- •r.. ^ � � � ��Cv { O 9 L W �/ ALL SI-,p II�IIII111 Container Presei vative 'IIII"I I'II • Preservative types: (1) nitric acid, (2) su 92611846 .,viunl nydroxide, (S) zinc acetate, (6) methanol, (7) sodium bisulfate, (8) sodiu. .... v, ly) hexane, (A) dscor hm ic acid, (B) ammoniusulfate. (C a rnonirnn hydroxide, (D) TSP, (U) Unpreserved, (0) Other ' Company: 'mac Billing Information: Addre s: o ! Repor to - Email To: es ) Copy T ^ �S / �i) _ o AtCollection InfAddress: y L ' L 97e,,, r ? LCt LiY',�;- Customer Pr ject Name/Number. State:/], LC1ounty/City: I Time Zone Collet ed: PT ( ] MT f J CT Analyses el, Profile/Line: � r^y "�j CC < j L-1- l a 5amp).e Receipt- 2hecklist: Custody Seals Present/IntacC Y J NA Custody Signatures Present Y N .�1A Collector Signature Present N NA Bottles intact (N NA correct. Bottles N NA Sufficient Volume IT"N NA samples Received on ice N ' A VIDA - Readspace Acceptable Y ti �NA -USDA Regulated Soils �-Y NtNlr, Samples in tiolcling 'Lime \yJN tft Residual Chlorine Preseril, r :4,14A ClC1 strips: sample pH Acceptable y ;l pit Strips: Sulfide Present Lead Acetate Strips: I.AB USE ONLY: Lab Sample n / Comments: Phone: 3 7s'S 7� �f5 Email: Site/Facility ID st: Compliance Monitoring? f�es [ ] No Collected 6 �r [y (print : ( `�Li<'7 iy!) ..}t' - - Purchase Order It: QuoteH: DW PWS ID It: DW Location Code: Collected By (signature): < , Turnaround Date Required: r Immediately Parked on Ice: [ ]Yes ( ]No Sample Disposal: Dispose as appropriate I ) Return I 1 Hold:_ I 1 wort:.. _ Rush: f ) Same Day f ] Next Day ( ] 2 Day ( ] 3 Day l 1 A Day [ j 5 Day (ExpediteChaq;esApi�ily) Field Filtered (if applicable): Yes ( ] ( ] No Analysis: Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), Product (P), Soil/Solid (SQ, Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) Customer Sample ID P Matrix " Comp / Grab Collected (or Composite Start) Composite End Res CI It of Ctns Date Time Date Time 4 '_ > h - tw;—tBlue Customer Remarks / Special Conditions / Possible Hazards: V f) (G �'- ✓ ( Type of Ice Used: Dry None SHORT HOLDS PRESENT (<72 huurs): Y N N;,� Lab Sample Temperature Info: Temp Blank Re Qived: Y N NA Therm IDft: F Cooler ] Temp Upon Receiptc�pC Cooler 1 Therm Corr. FactoiT0 I oC Cooler, 1 Corrected Tempi oC Comments: Packing Material Used: Lab Tracking k: 2610299 Radchem sample(s) screened (<500 cpnt): Y N NA Samples received via,,,,---., Ff_DEX UPS Client Courier Pare Courier Relinquished by/Company: (Signature) l n Date/rime: ( 1 Re d by/Company: (Signature) Dale/Time: I MT1L LAB USE ONLY Table It. Relir4juished by/Company: (Signature) Da e/Time: Ret:erve v ontpany: (Signature) Date/TimTi Acclnum:e: Template: Pralogin: — Trip Blank Received: Y N NA HCL McOH TSP Other � Rehnlo ished by/Company: (Signature) Date/Time: Received by/Company: (Signature) Date/Time: PM: pl": Non Conformance(s): YES / NO Page: 10f.- _.-_._..._ DC Ti;;e: EI` V-FFN!-HU;vt-OC:4 v01 Te h Spec S ' c Upon F.eceipt ,.••cam.,. _. —:;dC;:._r.%3._. �. 7.�i �. .�.'��_ `Cr.__.'< r7,-r'k tc h3!= Ccx IS V?raCC?l 'S_`3�IC-2 r3r'e f . ' preser,3: or samples, "cc, cm F_!f of box is to list nurr,ber of he-,Ies z "Check a'i unpres=_ried Nitrates for chlcrine V _ , I <I! t. \I i l \\ C C I I\I C ` i I\ I\I ( l: ► I � � 1 - I\� I I I \`\\C\ j l► 1 I�\,,\I I i i I \\\ I I I NNN III\ I Sarr l= Ti,:., of Pr sarvat,r•' j PH. urcn rec>ipi (j Ca:? pr_seri3ti acjui I I 1I___ — _ y3`_-;rz.`1:. Caric.;cc .;r _ a C .t cf,.c! , irczuic: preser,aro>, cut of temp, inccrrec, ccnta.n_. sj oua?:'axD-1cument ID: 70677 Page 2 of 2 Page 11 of 11