NC0000272_Analytical Results TOC Wastewater and Landfill Leachate_20230419

Pace Analytical Services,LLC
leac, yficalAnal 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
April 04, 2023
Mr. Phil Teague
Evergreen Packaging
175 Main Street
P.O. Box 4000
Canton, NC 28716
RE: Project: CITY SEWER&LEACHATE
Pace Project No.: 92658861
Dear Mr.Teague:
Enclosed are the analytical results for sample(s)received by the laboratory on March 24, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual,where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services-Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Ariel S Fitzgerald
[e-mail]
[phone]
Project Manager
Enclosures
cc: Cintya Bailey, Evergreen Packaging
Charles Howell, Evergreen Packaging
Mr.Tracy Willis, Evergreen Packaging
�pQ AC�FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
9eU �y without the written consent of Pace Analytical Services,LLC. Page 1 of 19

Pace Analytical Services,LLC
leac, yficalAnal 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
CERTIFICATIONS
Project: CITY SEWER&LEACHATE
Pace Project No.: 92658861
Pace Analytical Services Asheville
2225 Riverside Drive,Asheville,NC 28804 South Carolina Laboratory ID:99030
Florida/NELAP Certification#: E87648 South Carolina Certification#:99030001
North Carolina Drinking Water Certification#:37712 Virginia/VELAP Certification#:460222
North Carolina Wastewater Certification#:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 2 of 19

Pace Analytical Services,LLC
leac, yficalAnal 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
SAMPLE ANALYTE COUNT
Project: CITY SEWER&LEACHATE
Pace Project No.: 92658861
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92658861001 CITY SEWER EPA 160.4/SM2540D-2011 MA62 2 PASI-A
SM 521OB-2016 MDM 1 PASI-A
EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A
EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
SM 4500-P E-2011 JP1 1 PASI-A
SM 5220D-2011 JMH1 1 PASI-A
SM 5220D-2011 JP1 1 PASI-A
92658861002 LEACHATE EPA 160.4/SM2540D-2011 MA62 2 PASI-A
SM 521OB-2016 MDM 1 PASI-A
EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A
EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
SM 4500-P E-2011 JP1 1 PASI-A
SM 5220D-2011 JMH1 1 PASI-A
SM 5220D-2011 JP1 1 PASI-A
PASI-A=Pace Analytical Services-Asheville
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 3 of 19

Pace Analytical Services,LLC
leac, yficalAnal 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project: CITY SEWER&LEACHATE
Pace Project No.: 92658861
Sample: CITY SEWER Lab ID: 92658861001 Collected: 03/23/23 09:00 Received: 03/24/23 09:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D TSS/TVSS Analytical Method: EPA 160.4/SM2540D-2011
Pace Analytical Services-Asheville
Total Suspended Solids 85.0 mg/L 25.0 1 03/25/23 15:31
Volatile Suspended Solids 62.0 mg/L 25.0 1 03/25/23 15:31
5210B BOD,5 day Analytical Method:SM 521OB-2016
Pace Analytical Services-Asheville
BOD,5 day 108 mg/L 2.0 1 03/25/23 03:13 03/30/23 01:42
350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia 152 mg/L 2.5 25 04/01/23 12:58 7664-41-7 P4
351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, Kjeldahl,Total 227 mg/L 25.0 50 03/30/23 19:31 04/01/23 06:27 7727-37-9 P4
353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, Nitrate 0.74 mg/L 0.040 1 03/25/23 03:03 14797-55-8
SM4500P-E,Phosphate,Ortho Analytical Method:SM 4500-P E-2011
Pace Analytical Services-Asheville
Orthophosphate as P 2.4 mg/L 0.50 10 03/25/23 03:48 F6,M1
5220D COD Analytical Method:SM 5220D-2011 Preparation Method:SM 5220D-2011
Pace Analytical Services-Asheville
Chemical Oxygen Demand 484 mg/L 25.0 1 03/30/23 10:52 03/30/23 16:34
5220D COD,Soluble Analytical Method:SM 5220D-2011 Preparation Method:SM 5220D-2011
Pace Analytical Services-Asheville
COD,Soluble 93.7 mg/L 25.0 1 04/01/23 02:28 04/01/23 06:06
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/04/2023 05:30 PM without the written consent of Pace Analytical Services,LLC. Page 4 of 19

Pace Analytical Services,LLC
leac, yficalAnal 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project: CITY SEWER&LEACHATE
Pace Project No.: 92658861
Sample: LEACHATE Lab ID: 92658861002 Collected: 03/23/23 09:00 Received: 03/24/23 09:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D TSS/TVSS Analytical Method: EPA 160.4/SM2540D-2011
Pace Analytical Services-Asheville
Total Suspended Solids 98.0 mg/L 10.0 1 03/25/23 15:32
Volatile Suspended Solids 17.6 mg/L 10.0 1 03/25/23 15:32
5210B BOD,5 day Analytical Method:SM 521OB-2016
Pace Analytical Services-Asheville
BOD,5 day 118 mg/L 2.0 1 03/25/23 03:13 03/30/23 01:46
350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia 8.6 mg/L 0.10 1 04/01/23 12:26 7664-41-7
351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, Kjeldahl,Total 17.8 mg/L 0.50 1 03/30/23 19:31 04/01/23 05:41 7727-37-9
353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, Nitrate 0.084 mg/L 0.040 1 03/25/23 03:04 14797-55-8
SM4500P-E,Phosphate,Ortho Analytical Method:SM 4500-P E-2011
Pace Analytical Services-Asheville
Orthophosphate as P 12.2 mg/L 1.2 25 03/25/23 03:49 F6
5220D COD Analytical Method:SM 5220D-2011 Preparation Method:SM 5220D-2011
Pace Analytical Services-Asheville
Chemical Oxygen Demand 238 mg/L 25.0 1 03/30/23 10:52 03/30/23 16:42 M1
5220D COD,Soluble Analytical Method:SM 5220D-2011 Preparation Method:SM 5220D-2011
Pace Analytical Services-Asheville
COD,Soluble 327 mg/L 25.0 1 04/01/23 02:28 04/01/23 06:07
REPORT OF LABORATORY ANALYSIS
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Date:04/04/2023 05:30 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 19

Pace Analytical Services,LLC
leac, yficalAnal 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CITY SEWER&LEACHATE
Pace Project No.: 92658861
QC Batch: 763839 Analysis Method: EPA 160.4/SM2540D-2011
QC Batch Method: EPA 160.4/SM2540D-2011 Analysis Description: 2540D TSS/TVSS
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92658861001,92658861002
METHOD BLANK: 3966939 Matrix: Water
Associated Lab Samples: 92658861001,92658861002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Suspended Solids mg/L ND 2.5 03/25/23 15:29
Volatile Suspended Solids mg/L ND 2.5 03/25/23 15:29
LABORATORY CONTROL SAMPLE: 3966940
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Suspended Solids mg/L 250 252 101 90-110
SAMPLE DUPLICATE: 3966941
92658229001 Dup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids mg/L 6640 6660 0
Volatile Suspended Solids mg/L 4720 4760 1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/04/2023 05:30 PM without the written consent of Pace Analytical Services,LLC. Page 6 of 19

Pace Analytical Services,LLC
leac, yficalAnal 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CITY SEWER&LEACHATE
Pace Project No.: 92658861
QC Batch: 763801 Analysis Method: SM 521 OB-2016
QC Batch Method: SM 521OB-2016 Analysis Description: 5210E BOD,5 day
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92658861001,92658861002
METHOD BLANK: 3966871 Matrix: Water
Associated Lab Samples: 92658861001,92658861002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
BOD,5 day mg/L ND 2.0 03/30/23 01:31
LABORATORY CONTROL SAMPLE: 3966874
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
BOD,5 day mg/L 198 207 105 84.6-115
SAMPLE DUPLICATE: 3966875
92658782001 Dup
Parameter Units Result Result RPD Qualifiers
BOD,5 day mg/L 2710 2800 3
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/04/2023 05:30 PM without the written consent of Pace Analytical Services,LLC. Page 7 of 19

Pace Analytical Services,LLC
leac, yficalAnal 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CITY SEWER&LEACHATE
Pace Project No.: 92658861
QC Batch: 765350 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92658861001,92658861002
METHOD BLANK: 3973992 Matrix: Water
Associated Lab Samples: 92658861001,92658861002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Ammonia mg/L ND 0.10 04/01/23 11:46
LABORATORY CONTROL SAMPLE: 3973993
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 5.0 100 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3973994 3973995
MS MSD
92659783001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L ND 5 5 5.4 5.4 107 107 90-110 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3973996 3973997
MS MSD
92659783002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L 0.15 5 5 5.2 5.2 100 100 90-110 0
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/04/2023 05:30 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 19

Pace Analytical Services,LLC
leac, yficalAnal 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CITY SEWER&LEACHATE
Pace Project No.: 92658861
QC Batch: 764878 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92658861001,92658861002
METHOD BLANK: 3971586 Matrix: Water
Associated Lab Samples: 92658861001,92658861002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Kjeldahl,Total mg/L ND 0.50 04/01/23 05:12
LABORATORY CONTROL SAMPLE: 3971587
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen, Kjeldahl,Total mg/L 10 9.1 91 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3971588 3971589
MS MSD
92659011001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen, Kjeldahl,Total mg/L ND 10 10 10 10.2 97 100 90-110 2
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3971590 3971591
MS MSD
92659011002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen, Kjeldahl,Total mg/L ND 10 10 10.5 10.1 103 99 90-110 4
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/04/2023 05:30 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 19

Pace Analytical Services,LLC
leac, yficalAnal 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CITY SEWER&LEACHATE
Pace Project No.: 92658861
QC Batch: 763797 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate+Nitrite, Unpres.
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92658861001,92658861002
METHOD BLANK: 3966855 Matrix: Water
Associated Lab Samples: 92658861001,92658861002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.040 03/25/23 02:57
LABORATORY CONTROL SAMPLE: 3966856
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 1.5 1.5 100 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3966857 3966858
MS MSD
92658665001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 0.12 1.5 1.5 1.6 1.6 100 101 90-110 1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date:04/04/2023 05:30 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 19

Pace Analytical Services,LLC
leac, yficalAnal 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CITY SEWER&LEACHATE
Pace Project No.: 92658861
QC Batch: 763811 Analysis Method: SM 4500-P E-2011
QC Batch Method: SM 4500-P E-2011 Analysis Description: SM450OP-E Phosphorus,Ortho
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92658861001,92658861002
METHOD BLANK: 3966893 Matrix: Water
Associated Lab Samples: 92658861001,92658861002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Orthophosphate as P mg/L ND 0.050 03/25/23 03:38
LABORATORY CONTROL SAMPLE: 3966894
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Orthophosphate as P mg/L 0.25 0.24 96 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3966895 3966896
MS MSD
92658861001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Orthophosphate as P mg/L 2.4 0.25 0.25 2.9 2.9 232 232 90-110 0 F6,M1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date:04/04/2023 05:30 PM without the written consent of Pace Analytical Services,LLC. Page 11 of 19

Pace Analytical Services,LLC
leac, yficalAnal 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CITY SEWER&LEACHATE
Pace Project No.: 92658861
QC Batch: 764854 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92658861001
METHOD BLANK: 3971476 Matrix: Water
Associated Lab Samples: 92658861001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chemical Oxygen Demand mg/L ND 25.0 03/30/23 16:33
LABORATORY CONTROL SAMPLE: 3971477
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Chemical Oxygen Demand mg/L 750 760 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3971478 3971479
MS MSD
92658683002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Chemical Oxygen Demand mg/L 559 100 100 666 659 108 101 90-110 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3971480 3971481
MS MSD
92658970001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Chemical Oxygen Demand mg/L 58.2 100 100 168 168 110 110 90-110 0
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/04/2023 05:30 PM without the written consent of Pace Analytical Services,LLC. Page 12 of 19

Pace Analytical Services,LLC
leac, yficalAnal 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CITY SEWER&LEACHATE
Pace Project No.: 92658861
QC Batch: 764857 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92658861002
METHOD BLANK: 3971486 Matrix: Water
Associated Lab Samples: 92658861002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chemical Oxygen Demand mg/L ND 25.0 03/30/23 16:41
LABORATORY CONTROL SAMPLE: 3971487
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Chemical Oxygen Demand mg/L 750 746 99 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3971488 3971489
MS MSD
92658861002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Chemical Oxygen Demand mg/L 238 100 100 351 351 112 112 90-110 0 M1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3971490 3971491
MS MSD
92658906001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Chemical Oxygen Demand mg/L 161 100 100 287 287 126 126 90-110 0 M1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/04/2023 05:30 PM without the written consent of Pace Analytical Services,LLC. Page 13 of 19

Pace Analytical Services,LLC
leac, yficalAnal 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CITY SEWER&LEACHATE
Pace Project No.: 92658861
QC Batch: 765330 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD,Soluble
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92658861001,92658861002
METHOD BLANK: 3973958 Matrix: Water
Associated Lab Samples: 92658861001,92658861002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
COD,Soluble mg/L ND 25.0 04/01/23 06:05
LABORATORY CONTROL SAMPLE: 3973959
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
COD,Soluble mg/L 750 756 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3973960 3973961
MS MSD
92658269001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
COD,Soluble mg/L 731 100 100 816 818 85 88 90-110 0 M1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/04/2023 05:30 PM without the written consent of Pace Analytical Services,LLC. Page 14 of 19

Pace Analytical Services,LLC
leac, yficalAnal 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
QUALIFIERS
Project: CITY SEWER&LEACHATE
Pace Project No.: 92658861
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous To Count
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting.Therefore,calculated parameters that are typically reported as
"Total"may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
F6 Sample was not filtered within 15 minutes of collection and does not meet sampling and/or regulatory requirements.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
P4 Sample field preservation does not meet EPA or method recommendations for this analysis.
REPORT OF LABORATORY ANALYSIS
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Date:04/04/2023 05:30 PM without the written consent of Pace Analytical Services,LLC. Page 15 of 19

Pace Analytical Services,LLC
leac, yficalAnal 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: CITY SEWER&LEACHATE
Pace Project No.: 92658861
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92658861001 CITY SEWER EPA 160.4/SM2540D- 763839
2011
92658861002 LEACHATE EPA 160.4/SM2540D- 763839
2011
92658861001 CITY SEWER SM 5210B-2016 763801 SM 5210B-2016 763817
92658861002 LEACHATE SM 5210B-2016 763801 SM 5210B-2016 763817
92658861001 CITY SEWER EPA 350.1 Rev 2.0 1993 765350
92658861002 LEACHATE EPA 350.1 Rev 2.0 1993 765350
92658861001 CITY SEWER EPA 351.2 Rev 2.0 1993 764878 EPA 351.2 Rev 2.0 1993 765334
92658861002 LEACHATE EPA 351.2 Rev 2.0 1993 764878 EPA 351.2 Rev 2.0 1993 765334
92658861001 CITY SEWER EPA 353.2 Rev 2.0 1993 763797
92658861002 LEACHATE EPA 353.2 Rev 2.0 1993 763797
92658861001 CITY SEWER SM 4500-P E-2011 763811
92658861002 LEACHATE SM 4500-P E-2011 763811
92658861001 CITY SEWER SM 5220D-2011 764854 SM 5220D-2011 764986
92658861002 LEACHATE SM 5220D-2011 764857 SM 5220D-2011 764987
92658861001 CITY SEWER SM 5220D-2011 765330 SM 5220D-2011 765339
92658861002 LEACHATE SM 5220D-2011 765330 SM 5220D-2011 765339
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/04/2023 05:30 PM without the written consent of Pace Analytical Services,LLC. Page 16 of 19

aC#—Title: ENV-FRM-HUNI.0083 02 Sample Condition Upon Receipt
I AyE�IC.SI E,EiS
Effective Date: 11/14/2022 8:18:30 AM
Laboratory rec ving samples:
Asheville LtJ Eden❑ Greenwood❑ Huntersville❑ Raleigh❑ Mechanicsvilip" A41-1.-71
{'E • Client Name: Project It: Wa# ' 92658861
Courlet: ��'�'��Fed E, UPS ❑r SP Client 11111111111111111111
❑ Commercial ty�PaCe ❑Other; gZ&58861
Custody Seal Present? Dyes ❑No Seals Intact? ❑Yes eNo
�� Date/InItIalsPerson Exan3lrsingContents:_�_1i����_6�
Packing Material: El Bubble Wrap ❑Rubble bags LJ Nnne ❑ Other Biological Tissue Frozen?
Thermometer: ❑Yes ❑No ❑-9/A
Cl IR Gun ID:
Type of lee: � !et El Blue ❑Nnne
(` Correction Factor;
Cooler Temp: --L— Adcl/Subtract ('C) �1 Temp should be:above freezing to Vc
❑Sampie scut of temp criteria.Samples on ice,cooling process
Cooler Temp Corrected ('C); has begun
USDA Regulated Soll(❑ N/A,water sample)
Did samples originate in a quarantine zone within the United States:CA, NY,or SC Did saniplesoriginate from a foreign source finternatiowilly,
(check Maps)?❑Yes El No including Hawaii and Puerto Rico)?❑Yes El No
CommentsjEalscieparlcy:
Chain of Custody Present? r�s ❑No D N/A 1.
Samples Arrived within Hold Time? Yes ❑No ❑N/A 7.
Short Hold Time Analysis (02 hr.)? ❑Yes UK) ❑N/A 3.
Rush Turn Around Time Requested? ❑Yes UK'o C1N/A 4.
Sufficient Volume? ,i,,, yes ❑Na ❑N/A 5,
C
Correct Containers Used? �Y/Yes ❑No El NIA
ne 6.
-Pace Containers used? Mies ❑No ❑NIA
Containers Intact? (11 cs ONO ❑NIA 7.
Dissolved analysis:Samples Field filtered? ❑Yes ❑Na NIA B.
Sample Labels Match COC? ` t-I Yes ❑No ❑NIA 9.
-includes Date/Time/ID/Analysis Matrix: V _\r----___
Headspace in VOA Vials(>S.Smm)? ❑Yes El No 1IN/A 10.
Trip Blank Present? ❑Yes ❑t:o M N/A 11.
Trip Wank Custody Seals Present? El Yes ❑No C]N/A _
COMMENTS/SAMPLE DISCREPANCY _ -- Field Data Required? ❑Yes ❑No
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: bate/Time:
Project Manager SCURF Review: Date:
Project Manager SRF Review: pate;
Page 17 of 19

DC# Title: ENV-FRM-HUN1-0083 v02 Sample Condition Upon Receipt
ace,
Effective Date: 11/14/2022 8:18:30 AM
*Check mark top half of box if pH and/or dechlorination is verified and project# Wa# ' 92658861
within the acceptance range for preservation samples. PM: ASF Due Date: 04/07/23
Exceptions:VON Coliform,TOC,Oil and Grease,DRO/8015(water)DOC, f.t.11g CLIENT. 93-BRPP
**Bottom half of box is to list number of bottles
***Check pli unpreserved Nitrates for chlorine —
U 0 ai
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ry z iz a Z N ¢ ry � M ,ro
V y Cd A ell N V
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EX A = M rr>
ai w a v a z ? ? ro z zr
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e c n Ln p d O '° n g c O d d a N N N CL
ry v ry Z ra ro a a z c a
U U u u _� 'S _ z x Z v r n CL > a n, , a
m eta " to m L Y a n n £n �i n Z 7 7 v a G
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J J J ❑.. �.1 ` -.! 7 0. _ & J In d
E E E v E E E E & E F a J > J J en J , E J
Ln 0 0 o in vl = !� o ' E E E E E 7d E E E a E E
N a = N N ry n _ uy 0 0 0 0 0 0 > V1
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pH Adjustment Lag for Preserved Samples
Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot#Y
adjusted added
Note: Whenever there is a discrepaixy affecting North Carolina compliance samples,a copy of this formwill be sent to the North Carolina DFNn Certification Office (i.e.
Out of hold,incorrect PrMervative,out of temp,incarrva containers,
Page 18 of 19

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Page 19 of 19