Loading...
HomeMy WebLinkAboutNC0004774_Permit Renewal Application_20230501(' DUKE ENERGY. May 1, 2023 Mr. Doug Dowden Supervisor— NC NPDES Industrial Permitting NC Division of Water Resources 1617 Mail Services Center Raleigh, NC 27699-1617 Subject: Duke Energy Carolinas, LLC Buck Combined Cycle Station NPDES Permit No. NC0004774 Rowan County Permit Renewal Application Dear Mr. Dowden: Duke Energy Buck Combined Cycle 1385 Dukeville Road Salisbury, NC 28146 REC EIVED 'ViQ� 01 202D NCDEQ/DWH/NPD S Duke Energy Carolinas, LLC, (Duke) requests the subject permit be renewed and reissued. The above referenced permit expires on October 31, 2023. As mandated by North Carolina Administrative Code 15A NCAC 2H.0105(e), this permit is being submitted at least 180 days prior to expiration of the current permit. Please find enclosed in this application the following items: • EPA Form 1 • Location Map • EPA Form 2C for outfalls 001A, 007 and 117 • Outfall Location Map • Flow Diagram • Narrative — Supplemental Information for Station Description • Fish Tissue Sampling • Instream Sampling Data • Mixing Zone Study Report • 316(b) Study Report • Groundwater Waste and Geographic Limitation Boundaries Map A Form 2C and sampling analysis for Outfall 111, an engineered seep, was not provided with this renewal application, ash basin dewatering has lowered the water level within the basin and there has not been a discharge from the Outfall in over 2 years, the last discharge was April 6, 2021. Closure of the former coal-fired generating facility is complete. Based upon current station operations and the review of data from this permit term the following changes are requested for the current NPDES permit. Buck CTCC requests to report all temperature measurements required by permit in Celsius degrees only. Supplement to Permit Cover Sheet 1. Remove all references to the Buck Steam Station including the following: • Discharge treated wastewater, including, water treatment wastes, stormwater and contaminated groundwater seepage from the BSS. • Yard Sump emergency overflows though Outfall 002A • Filter screenings from raw water intake through Outfall 004 to the Yadkin River 2. Remove all references to the Coal Ash Beneficiation Plant (Outfall 008), as the outfall for this facility was not constructed, due to its closed loop system. A.(1) Effluent Limitations and Monitoring Requirements (Outfall 001A-CTCC Operations) 1. Based on DMR data, reduce the monitoring frequency for the following: • Temperature, pH and flow monitoring from daily to 2/month • Total Residual Chlorine and Total Suspended Solids monitoring from 2/month to quarterly • Total Nitrogen and Phosphorus monitoring from monthly to quarterly • Total Aluminum, Total Arsenic, Total Selenium, Total Mercury, Total Antimony, Total Copper, total Nickel, and Total Zinc monitoring from quarterly to semi-annual. • Total Chromium from 2/month to quarterly • Elimination of the monitoring requirement for Chloroform • Elimination of footnote (h) "When High Rock Lake, as measured, at the intake of the Buck Combined Cycle station, is drawn down 10 feet or greater, the permittee shall on a daily average basis ensure that the minimum unheated daily average stream flow does not fall below one third of the 7-day 10-day year flow (7Q10). The footnote is no longer needed, it is a relic that was in previous permits pertaining to the old steam station, and inappropriately applied to the combined cycle. The combined cycle uses less water per day that the steam station. A.(3). Effluent Limitations and Monitoring Requirements (Internal Outfall 008 — Coal ash Beneficiation Plant) 1. Elimination of condition A. (3) the Outfall as the infrastructure required for discharge of the outfall was never constructed. A.(4). Effluent Limitations and Monitoring Requirements (Outfall 007 — Ash Pond Dewatering) 1. Based on DMR data, reduce the monitoring frequency for the following: • pH monitoring from Daily to Weekly • Total Dissolved Solids, Total Suspended Solids, Turbidity from weekly to monthly • Oil and Grease and Chlorides from weekly to monthly • Hardness from weekly to monthly • Total Selenium, Total Antimony, Total Lead, Total Chromium, Total Mercury, Total Thallium, Total Copper, and Total Nickel, monitoring from weekly to monthly. • Chronic Toxicity from monthly to quarterly 2. Footnote 5. requires "The discharge from this facility shall not cause turbidity of the receiving stream to exceed 25 NTU. If the instream turbidity exceeds 25 NTU due to natural background conditions, the discharge shall not cause turbidity to increase in the receiving stream. Therefore, the if the effluent turbidity exceed 25 NTU, the permittee shall sample upstream and downstream turbidity in the receiving water body, within 24 hours, to determine whether the turbidity level in the receiving waterbody was increased. All data shall be reported on the DMR's. (See 15A NCAC 26 .0211 (21)). This footnote should be eliminated from the permit, if it cannot be eliminated then the instream turbidity limit should be increased to 50 NTU to reflect the current water quality standard and be consistent with other Duke facilities. 3. Footnote c. requires "If any of these pollutants (As, Se, Hg, Sb, Cu, Pb, Ni, and TI). Reaches 85% of the allowable monthly average effluent discharge concentration during dewatering, the permittee shall immediately discontinue discharge of the wastewater and report the event to DWR Mooresville Regional office and Complex NPDES Permitting Unit via telephone and e-mail. This nonstandard permit language should be eliminated based upon the data from the last permit term. 3. Footnote d. requires" In the event that additional waters accumulate in the pond(s), the rate for lowering the liquid level in the coal ash pond shall not exceed one (1) foot per day unless a higher rate is supported to the satisfaction of DEMLR and in accordance NCAC Title 15A, Subchapter 2K. The facility shall use a floating suction pipe with free water skimmed from the basin surface using adjustable weir. See also paragraph (a), Footnotes 2 and 4, above". This footnote should be eliminated based upon the data from the last permit and permission from Dam Safety to lower the ash basin level more than 1 foot per day. A.(5) Effluent Limitations and Monitoring Requirements (Outfall 111— Constructed Seep) 1. Ash basin dewatering has lowered the water level within the basin. There has not been a discharge from the Outfall in over 2 years, the last discharge was April 6, 2021. Since this outfall appears to be no longer discharging monitoring should be reduced from quarterly to semiannually. A.(6) Effluent Limitations and Monitoring requirements (Outfall 117 — Constructed Seep) 1. Based on DIVIR data, reduce the monitoring frequency for the following: • Temperature, pH Oil and Grease, Total Suspended Solids, Nitrate/Nitrite, sulfates and hardness from quarterly to semiannually • Copper and nickel from quarterly to semiannually • Elimination of the monitoring requirement for Conductivity, Total Arsenic, Total Selenium, Total Mercury, Total Aluminum, Total Barium, Total Cadmium, Total Chromium, Total Lead, Total Manganese, Total Thallium, and Total Zinc. A.(11). Biocide Condition 1. This facility has a chronic toxicity requirement; therefore, the biocide condition is not warranted because any use of a chemical in toxic amounts would cause a failure of the toxicity test. Duke requests its removal from the permit. A.(13) Priority Pollutant Analysis 1. The plant does not add any of the 126 priority pollutants for cooling tower maintenance. The facility performs priority pollutant analysis, for required parameters, during Form 2C sampling for permit renewal. This condition should be removed from the permit. A.(15). Waste Treatment Modifications 1. With the closure and demolition of the coal-fired steam station the facility has completed all waste treatment modifications needed to for operations of the combined cycle plant. No further major modifications are needed to sustain current operations; therefore, this condition is no longer needed and should be removed from the permit. A.(17) Instream Monitoring 1. Based upon data from the last permit term and lack of impact from ash basin dewatering as documented in the provided upstream and downstream data, Duke request that instream monitoring be revised from monthly to quarterly and the removal of sampling requirement for temperature, turbidity, bromide, dissolved lead, and dissolved zinc, dissolved cadmium, total selenium, total chromium, and total arsenic. 2. Duke request removal of the requirement for the instream monitoring to be submitted with permit renewal application based upon this data is reported with the DMRs. A.(18). Fish Tissue Monitoring Near Ash Pond Discharge 1. Based upon data from the last permit term, Duke requests that monitoring frequency be changed from annually to once per permit term. A.(21). Ash Pond operations and Maintenance 1.b. Working Capacity — Discharges to the ash basins ceased with the demolition of the Buck Steam Station, dewatering and ash excavation within the basins has lowered the water level within the basins to a level that provides sufficient free water volume. Duke request removal of the Ash Pond Working Operations requirement. The Buck Station submitted a Mixing Zone Report to the Division for review on April 25, 2022, a copy of that submittal is attached to the permit renewal application. Duke requests the Division remove the 316(a) thermal variance for the site and incorporate the thermal mixing zone. Should you have any questions regarding this submittal or require additional information, please contact Joyce Dishmon at 336-394-5524 or email Jovice.Dishmon@duke-energy.com. I certify under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations Sincerely, Kris Eisenrieth GM II Regulated Stations Buck Combined Cycle Plant Attachments Cc: Joyce Dishmon/CastPro — EHS Permitting & Compliance Dale Wooten — EHS Field Support via email Mailed by USPS 7019 0140 00010794 0647 Return Receipt USPS: 9590 9402 5350 91541987 81 Buck Station NPDES Wastewater Permit Renewal Application Attachment 1 EPA Form 1 RECEIVED MAY 01 20D NCDEQIDWR/NPDES EPA Identification Number NPDES Permit Number Facility Name Form Approved 030119 NCD043678929 NC0004774 Buck Combined Cycle Station OMB No. 2040-0004 Form U.S. Environmental Protection Agency 1 %SER C�/'1 Application for NPDES Permit to Discharge Wastewater NPDES GENERAL INFORMATION SECTION• • r 1.1 1 Applicants Not Required to Submit Form 1 1.1.1 s the facility a new or existing publicly owned 1.1.2 Is the facility a new or existing treatment works treatment works? treating domestic sewage? If yes, STOP. Do NOT complete 0 No If yes, STOP. Do NOT 0 No Form 1. Complete Form 2A. complete Form 1. Complete Form 2S. 1.2 Applicants Required to Submit form 1 1.2.1 Is the facility a concentrated animal feeding 1.2.2 Is the facility an existing manufacturing, operation or a concentrated aquatic animal commercial, mining, or silvicultural facility that is i production facility? currently discharging process wastewater? o❑ Yes 4 Complete Forth 1 0 No ✓0 Yes 4 Complete Form ❑ No i and Form 2B. 1 and Form 2C. 1.2.3 Is the facility a new manufacturing, commercial, 1.2.4 Is the facility a new or existing manufacturing, c mining, or silviculture] facility that has not yet commercial, mining, or silvicultural facility that — commenced to discharge? discharges only nonprocess wastewater? d ❑ Yes 4 Complete Form 1 0 No Yes 4 Complete Form No and Form 2D. 1 and Form 2E. H 1.2.5 Is the facility a new or existing facility whose '— discharge is composed entirely of stonnwater a associated with industrial activity or whose discharge is composed of both stormwater and non-stormwater? 0 Yes 4 Complete Form 1 ❑ No and Form 2F unless exempted by 40 CFR 122.26(b)(14)(x) or SECTION 2.1 rr• • • r Facility Name Buck Combined Cycle Station `0 2.2 EPA Identification Number q U 0 J NCD043678929 a A 2.3 Facility Contact N d Name (first and last) Title Phone number Kris Eisenrieth Gm II Regulated Stations (704) 630-3015 m Email address kris.eisenrieth@duke-energy.com d 2.4 Facility Mailing Address E Street or P.O. box z 1385 Dukeville Rd City or town State ZIP code Salisbury NC 28146 EPA Form 3610-1 (revised 3-19) Page 1 EPA Identification Number NPDES Permit Number Facility Name Form Approved 03 05119 NCD043678929 NC0004774 Buck Combined Cycle Station OMB No. 2040-0004 " d 2.5 Facility Location d .o « Street, route number, or other specific identifier Q o U 1385 Dukeville Rd o County name County code (if known) 6 Rowan 0 J V City or town State ZIP code z m Salisbury INC 28146 SECTION• NAICS CODES 3.1 SIC Code(s) Description (optional) 4911 Electric Power Generation N N 9 O U N U z 3.2 NAICS Code(s) Description (optional) v r= 1° 221112 Electric Power Generation, fossil fuel (gas) U N Name of 0 erator 4.1 Duke Energy Carolinas, Inc. `0 4.2 Is the name you listed in Item 4.1 also the owner? E 0 ❑� Yes ❑ No .E 4.3 Operator Status 0 ❑ Public —federal ❑ Public —state Other public (specify) utility p ❑ Private ❑ Other(specify) 4.4 Phone Number of Operator (704)630-3015 4.5 Operator Address Street or P.O. Box .6 526 S. Church St S City or town State ZIP code 0 o Charlotte NC 28202 m U a Email address of operator kris.eisenreith@duke-energy.com SECTION• • 40 a 5.1 Is the facility located on Indian Land? _ c ❑ Yes ❑� No EPA form 3510-1 (revised 3-19) Page EPA Identificafion Number NPDES Permit Number Facility Name Form Approved 0305119 NCD043678929 NC0004774 Buck Combined Cycle Station OMB No. 2040-0004 SECTION• r 6.1 Existing Environmental Permits (check all that apply and print or type the corresponding permit number for each) a m NPDES (discharges to surface m RCRA (hazardous wastes) ❑ UIC (underground injection of o water) fluids) r A NC0004774 NCO043678929 c w a 0PSD (air emissions) ❑ Nonattainment program (CAA) ❑ NESHAPs (CAA) Mo. 03786T37 X ❑ Ocean dumping (MPRSA) ❑ Dredge or fill (CWA Section 404) ❑ Other (specify) SECTIONr 7.1 Have you attached a topographic map containing all required information to this application? (See instructions for specific requirements.) 0 Yes ❑ No ❑ CAFO—Not Applicable (See requirements in Form 2B.) SECTIONOF r 8.1 Describe the nature of your business. Electric Power Generation N N W C N J m O N J _A SECTION•• r 9.1 Does your facility use cooling water? v ❑� Yes ❑ No + SKIP to Item 10.1. A 9.2 Identify the source of cooling water. (Note that facilities that use a cooling water intake structure as described at o 40 CFR 125, Subparts I and J may have additional application requirements at 40 CFR 122.21(r). Consult with your NPDES permitting authority to determine what specific information needs to be submitted and when.) O y tj c Yadkin River SECTION1 VARIANCE REQUESTSI r 10.1 Do you intend to request or renew one or more of the variances authorized at 40 CFR 122.21(m)? (Check all that N apply. Consult with your NPDES permitting authority to determine what information needs to be submitted and when.) d ❑ Fundamentally different factors (CWA ❑ Water quality related effluent limitations (CWA Section Ic Section 301(n)) 302(b)(2)) ❑ Non -conventional pollutants (CWA ❑ Thermal discharges (CWA Section 316(a)) Section 301(c) and (g)) ❑� Not applicable EPA Form 3510-1 (revised 3-19) Page 3 EPA Identification Number NPDES Permit Number - - - Facility Name Form Approved 030119 NCD043678929 NC0004774 Buck Combined Cycle Station OMB No. 2040-0004 SECTION• 11.1 CERTIFICATION STATEMENT (40 In Column 1 below, mark the sections of Form 1 that you have completed and are submitting with your application. For each section, specify in Column 2 any attachments that you are enclosing to alert the permitting authority. Note that not all applicants are required to provide attachments. Column 1 Column 2 Section 1: Activities Requiring an NPDES Permit ❑ w/ attachments ❑� Section 2: Name, Mailing Address, and Location ❑ w/ attachments ❑� Section 3: SIC Codes ❑ wl attachments © Section 4: Operator Information ❑ w/ attachments Section 5: Indian Land ❑ w/ attachments ❑� Section 6: Existing Environmental Permits ❑ w/ attachments m E A ❑� Section 7: Map w/ topographic ❑� ❑ w/ additional attachments ma o Section 8: Nature of Business ❑ w/ attachments w ❑� Section 9: Cooling Water Intake Structures ❑ w/ attachments �' ❑ Section 10: Variance Requests ❑ w/ attachments a c Section 11: Checklist and Certification Statement ❑ w/ attachments Y 11.2 Certification Statement U I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete./ am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. Name (print or type first and last name) Official title Kris Eisenreith General Manager II - Regulated Stations Signature Date signed q(25/Z3 EPA Form 3510-1 (revised 3-19) Page 4 Buck Station NPDES Wastewater Permit Renewal Application Attachment 2 Location Map RECEIVED MAY 01 2023 NCDEQ/DWR/NPDES Buck Station NPDES Wastewater Permit Renewal Application Attachment 3 Form 2C Outfalls 001A, 007 and 117 RECEIVED MAY 01 2023 NCDEQIDWRINPDES EPA Identification Number NPDES Permit Number Facility Name Form Approved 03105/19 NCD043678929 NC0004774 Buck Combined Cycle OMB No. 2040-0004 Form U.S. Environmental Protection Agency Application for NPDES Permit to 2C r-WEPA EXISTING MANUFACTURING, COM ERCIAL,sMINING,I arge Wastewater NPDES ND SILVICULTURE OPERATIONS SECTIONOUTFALL LOCATIONr 1.1 Provide information on each of the facility's outfalls in the table below. c ° Outfall Receiving Water Name Latitude Longitude o Number 001A Yadkin River 35 42' 49.946"N 80 42' 31.277"W 3 O SECTIOND' 1 c Z. I Have you attached a line drawing to this application that shows the water flow through your facility with a c .3 water balance? (See instructions for drawing requirements. See Exhibit 2C-1 at end of instructions for E example.) 0 Yes ❑ No SECTION• 3.1 For each outfall identified under Item 1.1 provide average flow and treatment information. Add additional sheets if necessary. *'Outfall Number" 001A c o Operations E Operation Average Flow Cooling Tower Blowdown 0.58 mgd c m 3 Oil/Water Seperator 0,007 mgd 0 LL Ultra Filtration Backwash 0.014 mgd m rn Reverse Osmosis Reject 0.022 mgd < Treatment Units Description Code from Final Disposal of Solid or Liquid Wastes Other Than (include size, flow rate through each treatment Table 2C-1 Li q unit, retention time, etc.) by Discharge oxidation, sedimentation 2-13, 1-1.1 oxidation, sedimentation 2-B, 1-1.1 multimedia filtration 1-Q Reverse Osmosis 1-S **Outfall Number** 31 Cont Operations Operation Average Flow mgd mgd mgd mgd Treatment Description Units Code from Final Disposal of Solid or _ (include size, flow rate through each treatment Table 2C-1 Liquid Wastes Other Than by o unit, retention time, etc.) Discharge U _ m E Y d L **Outfall Number** N 30 Operations LL m Operation Average Flow M mgd d Q mgd mgd mgd Treatment Description Units Code from Final Disposal of Solid or (include size, flow rate through each treatment Table 2C-1 Liquid Wastes Other Than by unit, retention time, etc.) Discharge 3.2 Are you applying for an NPDES permit to operate a privately owned treatment works? E [I Yes No SKIP to section 4. Nj 3.3 Have you attached a list that identifies each user of the treatment works? ❑ Yes ❑ No Except for storm runoff, leaks, or spills, are any discharges described in Sections 1 and 3 intermittent or 4.1 seasonal? ❑ yes 0 No y SKIP to section 5 4.2 Provide information on intermittent or seasonal flows for each applicable outfall. Attach add. pages if necessary Outfall Frequency Flow Rate Operation Number (List) Average Average Long -Term Maximum Duration Days/Week MonthsNear Average �g Daily days/ months/ d mgd mgd g days y s td week year 001A days/ months/ mgd mgd days .9 week year days/ months/ mgd mgd days t. week year days/ months/ mgd mgd days week year days/ months/ mgd mgd days week year days/ months/ mgd mgd days week year days/ months/ mgd mgd days week I year days/ months/ mgd mgd days week year days/ months/ mgd mgd tlays week year SECTION 6. •D • , 5.1 Do any effluent limitation guidelines (ELGs) promulgated by EPA under Section 304 of the CWA apply to your facility? ❑ yes ❑ No ♦SKIP to Section 6. yt 5.2 Provide the following information on applicable ELGs. ELG Category ELG Subcategory Regulatory Citation w m steam electric 40 CFR 423 power generation Are any of the applicable ELGs expressed in terms of production (or other measure of operation)? �+ c 5.3 ❑ yes ❑ No * SKIP to Section 6. 0 Provide an actual measure of daily production expressed in terms and units of applicable ELGs. E Outfall -� Operation, Product, or Material Quantity per Unit of 0 Number Day Measure d N R m 5.4 c 0 U 7 O 0 a` Are you presently required by any federal, state, or local authority to meet an implementation schedule for constructing, upgrading, or operating wastewater treatment equipment or practices or any other environmental 6.1 programs that could affect the discharges described in this application? ❑ Yes No SKIP to Item 6.3. m d 6.2 Briefly identify each applicable project in the table below. m Affected m Brief Identification Final Compliance Dates w'o and Description of Outfalls Source(s) of (list outfall Discharge Required Projected a E Project number) q / Have you attached sheets describing any additional water pollution control programs (or other environmental 6.3 projects that may affect your discharges) that you now have underway or planned? (optional item) ❑ Yes Q No ❑ Not Applicable SECTION. r See the instructions to determine the pollutants and parameters you are required to monitor and, in turn, the tables you must complete. Not all applicants need to complete each table. Table A. Conventional and Non -Conventional Pollutants y Are you requesting a waiver from your NPDES permitting authority for one or more of the Table A pollutants for LJ 7.1 any of your outfalls? N_ ❑ Yes Q No SKIP to Item 7.3. 7.2 If yes, indicate the applicable outfalls below. Attach waiver request and other required information to the z application. m Outfall Number: Outfall Number: Outfall Number: Y A Have you completed monitoring for all Table A pollutants at each of your outfalls for which a waiver has not been 7.3 requested and attached the results to this application package? m y ❑� Yes ❑ No A Waiver has been requested from my NPDES permitting authority for all pollutants at all outfalls. l+l Table B. Toxic Metals, Cyanide, Total Phenols, and Organic Toxic Pollutants 7.4 Do any of the facility's processes that contribute wastewater fall into one or more of the primary industry categories listed in Exhibit 2C-3? (See end of instructions for exhibit.) Q Yes ❑ No SKIP to Item 7.8. 7.5 Have you checked "Testing Required" for all toxic metals, cyanide, and total phenols in Section 1 of Table B? ❑ yes ❑ No 7 6 List the applicable primary industry categories and check the boxes indicating the required GC/MS fraction(s) identified in Exhibit 2C-3. Required GC/MS Fraction(s) Primary Industry Category (Check applicable Boxes) Steam Electric Generation Q volatile Q Acid ❑ BaWNeutrdl ❑ Pesticide ❑ Volatile ❑ Acid ❑ Base/Neutral ❑ Pesticide ❑ Volatile ❑ Acid ❑ Base/Neutral ❑ Pesticide 7 7 Have you checked "Testing Required" for all required pollutants in Sections 2 through 5 of Table B for each of the GC/MS fractions checked in Item 7.6? Q Yes ❑ No 7.8 Have you checked "Believed Present' or "Believed Absenr for all pollutants listed in Sections 1 through 5 of Table B where testing is not required? 41 Yes ❑ No Have you provided (1) quantitative data for those Section 1, Table B, pollutants for which you have indicated testing is 7.9 required or (2) quantitative data or other required information for those Section 1, Table B, pollutants that you have indicated are "Believed Present" in your discharge? ❑ Yes ❑ No 7.10 Does the applicant qualify for a small business exemption under the criteria specified in the instructions? ❑Yes Note that you qualify at the top of Table 8, then SKIP to item 7.12 ❑� No v Have you provided (1) quantitative data for those Sections 2 through 5, Table B, pollutants for which you have determined 7.11 testing is required or (2) quantitative data or an explanation for those Sections 2 through 5, Table B, pollutants you have — indicated are "Believed Present" in your discharge? c U ❑ Yes ❑ No N U Table C. Certain Conventional and Non -Conventional Pollutants m 7.12 Have you indicated whether pollutants are "Believed Present' or "Believed Absent' for all pollutants listed on Table C for all r outfalls? U y Q' Yes No ❑ Y A .S Have you completed Table C by providing (1) quantitative data for those pollutants that are limited either directly or a 7.13 indirectly in an ELG and/or (2) quantitative data or an explanation for those pollutants for which you have indicated @ "Believed Present"? c °' ❑� Yes ❑ No r w Table D. Certain Hazardous Substances and Asbestos 7.14 Have you indicated whether pollutants are "Believed Present" or "Believed Absent" for all pollutants listed in Table D for all outfalls? Q Yes ❑ No 7.15 Have you completed Table D by (1) describing the reasons the applicable pollutants are expected to be discharged and (2) by providing quantitative data, if available? ❑ Yes ❑ No Table E. 2,3,7,8-Tetrachlorodibenzo-p-Dioxin (2,3,7,8-TCDD) 7.16 Does the facility use or manufacture one or more of the 2,3,7,8-TCDD congeners listed in the instructions, or do you know or have reason to believe that TCDD is or may be present in the effluent? ❑ Yes Complete Table E ❑ No SKIP to section 8 7.17 Have you completed Table E by reporting qualitative data for TCDD? ❑ Yes Q No SECTION• OR • TOXICS (40 x8 1 Is any pollutant listed in Table B a substance or a component of a substance used or manufactured at your facility as an o intermediate or final product or byproduct? H ❑ Yes No SKIP to section 9 8.2 List the pollutants below. A 1. 4. 7. m 0 2. 5. 8. a m 3. 6. 9. SECTIONBIOLOGICAL T• 40 Do you have any knowledge or reason to believe that any biological test for acute chronic toxicity has been made 9.1 within the last three years on (1) any of your discharges or (2) on a receiving water in relation to your discharge? ,N ❑� Yes ❑ No SKIP to section 10. 9.2 Identify the tests and their purposes below. Test(s) Purpose of Test(s). .Submitted to'NPDES'„ ' Date Submitted 'o Permitting-Authofity. . 0 ❑✓ Yes ❑ No Chronic Toxicity Quarterly 0 m ❑ Yes ❑ No ❑ Yes ❑ No SECTION• -. .0 Were any of the analyses reported in section 7 performed by a contract laboratory or consulting firm? 10.1 ❑� Yes ❑ No SKIP to section 11. Provide information to each contract laboratory or consultin firm below. 10.2 Laboratory Numbe�1 Laboratory Number 2;. _: ;. Laboratory Number 3' Name of Laboratory/firm Pace Analytical Q. Laboratory address 9800 Kincey Avenue #100 HuntersviIle NC 28078 o V - Phone number 704 875 9092 Pollutant(s) analyzed All SECTIONADDITIONAL INFORMATION 11.1 Has the NPDES permitting authority requested additional information? ❑ Yes 0 No SKIP to section 12. 11.2 List the information requested and attach it to this application. .c 3. c 2 :a `0 2. 4. ..a 3. 5. SECTION CHECKLIST AND CERTIFICATIONt 12.1 In Column 1 below, mark the sections of Form 2C that you have completed and are submitting with your application. For each section, specify in Column 2 any attachments that you are enclosing to alert the permitting authority. Note that not all applicants are required to complete all sections or provide attachments. Column 1 Column 2 ❑ Section 1: Cutfall Location ❑� w/ attachments ❑' Section 2: Line Drawing ❑' w/ line drawing ❑ w/ additional attachments ❑� Section 3: Average Flows and Treatment ❑� w/ attachments ❑ w/ list of each user of privately owned treatment works ❑ Section 4: Intermittent Flows ❑ w/ attachments ❑ Section 5: Production ❑ w/ attachments ❑ Section 6: Improvements P w/ optional additional sheets describing ❑ w/ attachments ❑ any additional pollution control plans .,., w/ request for a waiver and supporti ❑information U] w/ explanation for identical outfalls y mw/ small business exemption ❑ Elw/ other attachments request c p O Section 7: Effluent and Intake ❑� w/Table A w/Table B Characteristics ❑� w/ Table C ❑ w/ Table D U k ❑ w/ Table E ❑ w/ analytical results as an attachment m U ED Section 8: used or Manufactured Toxics w/ attachments A ❑ Section 9: Biological Toxicity Tests ❑ w/ attachments s V N t ❑Section lO: Contract Analyses ❑ w/attachments U ❑� Section 11: Additional Information w/ attachments ❑� Section 12: Checklist and Certification Statement ❑� w/ attachments 12.2 Certification Statement l certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel property gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. Name (print or type first and last name) Official title &%f-o Get t13Qnf,"c�(. GMII Pr 5�,( o�y Signature Date signed This page intentionally left blank. Units (specify) Effluent Intake (optional) Pollutant Waiver Requested (if applicable) Maximum Daily Discharge (required) Maximum Monthly Discharge (if available) Long -Term Average Daily Discharge (if available) Number of Analyses Long Term Average Value Number of Analyses ❑ Check here if you have applied to your NPDES permitting authority for a waiver for all of the pollutants listed on this table for the noted outfall. 1 Biochemical oxygen demand (BODS) ❑ Concentration mg/L <2.0 Mass lb/Day 2. Chemical oxygen demand (COD) j=1, Concentration mg/L 30.5 Mass Ib/Day 3. Total organic carbon (TOC) Concentration mg/L 9.4 Mass lb/Day 42.6 4. Total suspended solids (TSS) ❑ Concentration mg/L <2.5 Mass lb/Day <11.3 5. Ammonia (as N) ❑ Concentration mg/L <0.10 Mass lb/Day <0.453 6. Flow ❑ Rate MGD 0.543 Temperature (winter) ❑ °C °C 21.1 7. Temperature (summer) ❑ °C °C pH (minimum) ❑ Standard Units S.U. 7.8 8. pH (maximum) ❑ Standard Units SM. Enter INTAKE flow below if you want to calculate lb/Day 0.543 This page intentionally left blank. Presence or Absence (check one) Effluent Intake (optional) Pollutant/Parameter (and CAS Number, it available Required Units (specify) Believed Present Believed Absent Maximum Daily Discharge Maximum Monthly Discharge m Long -Term Average Daily Discharge Number of Analyses L on9 Term Average Value Number of Analyses (required) (if available) (if available) Check here if you qualify as a small business per the instructions to Form 2C and, therefore, do not need to submit quantitative data for any of the organic toxic pollutants in Sections 2 ' through 5 of this table. Note, however, that you must still indicate in the appropriate column of this table if you believe any of the pollutants listed are present in your discharge. Section 1. Toxic Metals, Cyanide, and Total Phenols Concentration ug/L 5.93 1 1.1 Antimony, total (7440-36-0) ❑ Mass lb/Day 0.0269 1 1.2 Arsenic, total (7440-38-2) 0 ❑ 21 Concentration ug/L <1 1 Mass lb/Day <0.00453 1 1.3 Beryllium, total (7440-41-7) ❑ Concentration ug/L <1 1 Mass lb/Day <0.00453 1 1.4 Cadmium, total (7440-43-9) [a ❑ ❑ Concentration ug/L <0.1 1 Mass lb/Day <0.000453 1 1.5 Chromium, total (7440-47-3) 0 ❑ E) Concentration ug/L <1 1 Mass lb/Day <0.00453 1 Concentration ug/L 19.7 1 1.6 Copper, total (7440.50.8) El El ElMass lb/Day 0.0893 1 1.7 Lead, total (7439-92-1) ❑ Concentration ug/L <1 1 Mass Ib/Day <0.00453 1 1.8 Mercury, total (7439-97-6) ❑ Concentration ng/L 4.89 1 Mass lb/Day <0.00002 1 Concentration ug/L 3.62 1 1.9 Nickel, total (7440-02-0) ElO ❑ Mass lb/Day 0.0164 1 1.10 Selenium, total (7782-49-2) ❑ Concentration ug/L <1 1 Mass lb/Day 1 <0.00453 1 Concentration I ug/L I <1 I1 1.11 Silver, total (7440-224) 0 ❑ ❑, Mass lb/Day 1 <0.00453 1 Effluent Intake (optional) Presence or Absence (check one) Believed Present Believed Absent Maximum Daily Discharge Maximum Monthly Discharge Long -Term Average Daily Discharge Number of Analyses Lon 9 Term Average Valugy Value Number of Analyses Pollutant/Parameter (and CAS Number, if available) Testing g Required Units (specify) (required) (if available) (if available) Concentration ug/L <0.2 1 1.12 Thallium, total (7440-28-0) 0 ❑ Mass lb/Day <0.000906 1 Concentration mg/L 0.018 1 1.13 Zinc, total(7440-66-6) 0 ❑ Mass Ib/Day 0.0816 1 Concentration mg/L <0.0080 1 1.14 Cyanide, total(57-12-5) ❑, ❑ Mass lb/Day <0.0363 1 Concentration ug/L <4.3 1 1.15 Phenols, total ❑ Mass lb/Day 10.0195 1 Section 2. Organic Toxic Pollutants (GC/MS Fraction - Volatile Compounds) Concentration ug/L <5.0 1 2.1 Acrolein (107-02-8) ❑, ❑ 0 Mass lb/Day <0.0227 1 Concentration ug/L <5.0 1 2.2 Acrylonitrile (107-13-1) Q ❑ El Mass lb/Day <0.0227 1 Concentration ug/L <1.0 ? 2.3 Benzene (7143-2) ❑, ❑ ❑ Mass lb/Day <0.00453 Concentration ug/L <2.0 2.4 Bromoform (75-25-2) ❑� ❑ 0 Mass Ib/Day <0.00906 1 Concentration ug/L <2.0 1 2.5 Carbon tetrachloride (56-23-5) 0 ❑ 0 Mass lb/Day <0.00906 I Concentration ug/L <2.0 1 2.6 Chlorobenzene (108-90-7) ❑, ❑ ❑, Mass Ib/Day <0.00906 1 2.7 Chlorodibromomethane (12448-1) 0 El Concentration ug/L <2.0 ? Mass lb/Day <0.00906 Concentration ug/L <2.0 1 2.8 Chloroethane (75-00-3) ❑ Mass lb/Day <0.00906 1 Presence or Absence (check one) Effluent Intake (optional) Pollutant/Parameter (and CAS Number, if available) Testing Required gelievet Present Believed Absent Units (specify) Maximum Daily Discharge Maximum Monthly Discharge Long -Term Average Daily Discharge Number of Analyses Term Term Average Value Number of Analyses (required) (if available) (if available) 2.9 2-chloroethylvinyl ether (110-75-8) ❑ Concentration ug/L <5.0 1 Mass Ib/Day <0.0227 1 2.10 Chloroform (67-66-3) ❑ Concentration ug/L 2.1 1 Mass lb/Day 0.00952 1 2.11 Dichlorobromomethane (75-27-4) Concentration ug/L <2.0 1 Mass lb/Day <0.00906 1 2.12 1,1-0ichlorcethane (75-34-3) ❑ ❑ Concentration ug/L <2.0 1 Mass lb/Day <0.00906 1 2.13 1,2-dichloroethane (107-06-2) ❑' [l O Concentration ug/L <2.0 1 Mass Ib/Day <0.00906 1 2.14 1,1-0ichloroelhylene (75-354) ❑ '� Concentration ug/L <2.0 1 Mass lb/Day <0.00906 1 2.15 1,2-0(78-87-5) LEI Elichloropropane Concentration ug/L <2.0 1 Mass lb/Day <0.00906 1 2.16 1,3-0ichloropropylene (542-75-6) ❑ ❑ ❑ Concentration ug/L <2.0 1 Mass lb/Day <0.00906 1 2.17 Ethylbenzene (100d1-4) ❑ Concentration ug/L <1.0 1 Mass lb/Day <0.00453 1 2.18 Methyl bromide (74-83-9) 0 ❑ Concentration ug/L <2.0 1 Mass lb/Day <0.00906 1 2.19 Methyl chloride (74-87-3) Q ❑ 0 Concentration ug/L <2.0 1 Mass Ib/Day <0.00906 1 2.20 Methylene chloride (75-09-2) ❑ ❑ 0 Concentration ug/L <2.0 1 Mass Ib/Day <0.00906 1 2.21 1,1,2,2- tetrachloroethane (79-34-5) ❑ 0 ❑ Concentration ug/L <2.0 1 Mass lb/Day <0.00906 1 ..- Effluent „ Intake (optional) Presence or Absence (check one) Pollutant/Parameter (and CAS Number, if available Testing Required Units (specify) Believed Present Believed Absent Maximum Daily Discharge Maximum Monthly Discharge Long -Term Average Daily Discharge NumberofTerm Analyses Long - Average Value Number of Analyses (required) (if available) (if available) 2.22 Tetrachlomethylene (127-184) 0 ❑ Concentration ug/L <2.0 1 Mass Ib/Day <0.00906 1 Concentration ug/L <1.0 1 2.23 Toluene (108-88-3) P ❑ E) Mass Ib/Day <0.00453 1 2 24 1,2-trans-dichloroethylene (156-60-5) ❑ Concentration ug/L <2.0 1 Mass Ib/Day <0.00906 1 1,11-trichloroethane Concentration ug/L <2.0 1 2.25 (71-55-6) ❑ El 0 Mass lb/Day <0.00906 1 1,1,2-tdchloroethane Concentration ug/L <2.0 1 2.26 (79-00-5) � ❑ � Mass lb/Day <0.00906 1 Concentration ug/L <2.0 1 2.27 Trichloroethylene (79-01-6) ❑ ❑ Mass lb/Day <0.00906 1 Concentration ug/L <2.0 1 2.28 Vinyl chloride (75-01-4) ❑ ❑ Mass lb/Day <0.00906 1 Section 3. Organic Toxic Pollutants (GC/MS Fraction - Acid Components) Concentration ug/L <4.3 1 3.1 Z-chlorophenol (95-57-8) ❑ Mass lb/Day <0.0195 1 3 2 2,4-dichlorophenol (120-83-2) ❑ ❑ ❑ Concentration ug/L <4.3 1 Mass Ib/Day <0.0195 1 3.3 2,4-dimethylphenol (105-67-9) 0 ❑ Concentration ug/L <8.7 1 Mass lb/Day <0.0394 1 3.4 4,6-dinitro-o-cresol (534-52-1) �' ❑ Concentration ug/L <8.7 1 Mass lb/Day <0.0394 1 Concentration ug/L <43.5 1 3.5 2,4-dinitrophenol (51-28-5) ❑ Mass lb/Day <0.197 1 TABLE B. TOXIC METALS, CYANIDE, TOTAL PHENOLS, .. Effluent Intake Presence or Absence (check one) (optional) Pollutant/Parameter Units Long -Term (and CAS Number, if Testing (specify) Maximum Maximum Average Lon g Number available Required Believed Believed Daily Monthly Daily Number of Term of P3.6(88 Present Absent Discharge Discharge Discharge Analyses Average Analyses Value (required) (if available) (if available) 2-nitrophenol Concentration ug/L <4.3 1 75-5) 7 ❑ Mass lb/Day <0.0195 1 4-nitrophenol Concentration ug/L <8.7 ? 3.7 (100-02-7) ❑ ❑' Mass lb/Day <0.0394 ? p-chloro-m-cresol Concentration ug/L <4.3 1 3.8 (59-50-7) 0 ❑ Mass lb/Day <0.0195 ? Pentachlorophenol Concentration ug/L <8.7 1 3'9 (87-86-5) ❑ Mass lb/Day <0.0394 1 Phenol Concentration mg/L <0.020 1 3.10 ❑� C, ❑' (108-95-2) Mass lb/Day <.091 1 2,4,6-tdchlorophenol Concentration ug/L <8.7 1 3.11 (88-05-2) 21 ��� Mass lb/Day <0.0394 1 Section 4. Organic Toxic Pollutants (GC/MS Fraction - Base /Neutral Compounds) Acenaphthene Concentration ug/L <4.3 1 4.1 (83-32-9) ❑' ❑, '❑' Mass lb/Day <0.0195 1 Acenaphthylene Concentration ug/L <4.3 1 4.2 (208-96-8) J Mass lb/Day <0.0195 1 Concentration ug/L <4.3 1 4.3 Anthracene (120-12-7) r-) 0 Mass lb/Day <0.0195 1 Concentration ug/L <43.5 1 4.4 Benzidine (92-87-5) r] ❑ Mass lb/Day <0.197 1 Benzc (a) anthracene Concentration ug/L <4.3 1 4.5 (56-55-3) L�1 ❑ ❑ Mass lb/Day <0.0195 1 Benzo (a) pyrene Concentration ug/L <4.3 1 4.6 (50-32-8) ElMass lb/Day <0.0195 1 • • • • • - • • I Effluent Intake Presence orAbsence (check one) (optional) meter Poif FCAIS Testin 9 Units Long -Term Long- available) Required Believed Believed (specify) Maximum Maximum Average Number of Term Number Present Absent Daily Monthly Daily Analyses Average of Analyses Discharge Discharge Discharge Value (required) (if available) (if available) 3,4-benzofluoranthene Concentration ug/L <4.3 1 4.7 (205-99-2) �-� Mass lb/Day <0.0195 1 Concentration ug/L <4.3 1 4.8 Benzo (ghi) perylene (191-24-2) 0 Mass lb/Day <0.0195 1 Benzo (k) fluoranthene (207-08- Concentration ug/L 44.3 1 Mass Ib/Day, '0.0195 1 4.9 9) ❑' L'!! Bis (2-chloroethoxy) methane Concentration ug/L <8.7 1 Mass lb/Day 10.0394 1 4.10 (111 91 1) rl - � Bis (2-chloroethyl) ether (111-44- Concentration ug/L <4.3 1 Mass lb/Day <0.0195 1 4.11 4) C `-' Bis (2-chloroisopropyl) ether (102 Concentration ug/L <4.3 1 Mass lb/Day <0.0195 1 4.12 80.1) GEl Bis (2-ethylhexyl) phthalate (117- Concentration ug/L <4.3 1 Mass lb/Day <0.0195 1 4.13 817) '❑-- 4-bromophenyl phenyl ether (101 Concentration ug/L <4.3 1 4.14 55-3) J -- Mass lb/Day <0.0195 1 Concentration uglL <4.3 1 4.15 Butyl beri l phthalate (85-68-7) Mass lb/Day <0.0195 1 Concentration ug/L <4.3 1 4.16 2-chloronaphthalene (91-58-7) Mass lb/Day <0.0195 1 4-chlorophenyl phenyl ether Concentration ug/L <4.3 1 Mass lb/Day <0.0195 1 4.17 (7005-72-3) L� I_l O Concentration ug/L 14.3 1 4.18 Chrysene (218-01-9) El J 0 1 Mass Ib/Day <0.0195 Dibenzo (a,h) anthracene (53-70- Concentration ug/L <4.3 1 Mass lb/Day <0.0195 1 4.19 3) 7 .. Presence or Absence -. „ Intake (check one) Effluent (optional) Pollutant/Parameter ing Test7elievedB Units Long -Term (and CAS Number, if Required (specify) Maximum Maximum Average Number Long - Long- Term Number available) Daily Monthly Daily of Analyses Average of Discharge Discharge Discharge Value Analyses (required) (if available) (if available) 1,2-dichlorobenzene Concentration ug/L <2.0 1 420 (95-50-1) n ❑ 2 Mass lb/Day <0.00906 1 1,3-dichlorobenzene Concentration ug/L <2.0 1 4 21 (541-73-1) D Mass lb/Day <0.00906 1 1,4-dichlorobenzene Concentration ug/L <2.0 1 4.22 (10646-7) rl ❑ ❑ Mass lb/Day <0.00906 1 3,3-dichlorobenzidine Concentration ug/L <8.7 1 4.23 (91.94-1) ❑ ❑ ❑ Mass lb/Day <0.0394 1 Diethyl phthalate Concentration ug/L <4.3 1 4 24 (84-66-2) ❑ ❑ Mass lb/Day <0.0195 1 Dimethyl phthalate Concentration ug/L <4.3 1 4.25 (131-11-3) D ❑ ❑ Mass lb/Day <0.0195 1 Di-n-butyl phthalate Concentration ug/L <4.3 1 4.26 (84-74-2) n ❑ ❑ Mass lb/Day <0.0195 1 2,4-dinitrotoluene Concentration u <4.3 1 4.27 (121-14-2) E ❑ E Mass lb/Day <0.0195 1 2,6-dinitrotoluene Concentration ug/L <4.3 1 4.28 (606-20-2) El' ❑ Mass lb/Day <0.0195 1 Di-n-octyl phthalate Concentration ug/L <4.3 1 429 (117-84-0) ❑ 0 Mass lb/Day <0.0195 1 1,2-Diphenylhydrazine Concentration ug/L <4.3 1 4.30 (as azobenzene)(122-66-7) ❑ 121 s [Mas lb/Day <0.0195 1 Fluoranthene Concentration ug/L <4.3 1 4.37 (206-44.0) ❑ Mass Ib/Day <0.01t 1 Fluorene Concentration ug/L <4.3 1 432 (86-73-7) , ❑ ❑ , ❑ Mass lb/Day <0.0195 1 Presence or Absence Effluent (check one) (optional) Pollutant/Parameter Units Long -Term 7Value (and CAS Number, if Testing g (specify) Maximum Maximum Average available) Required Believed Believed Daily Monthly Daily Number of Present Absent Discharge Discharge Discharge Analyses (required) (if available) (if available) Hexachlorobenzene Concentration ug/L <4.3 1 4.33 (118-741) ❑-- Mass lb/Day <0.0195 Hexachlorobutadiene Concentration ug/L <4.3 t 4.34 (87-68 3) ❑'' ❑ - ' Mass lb/Day <0.0195 1 Hexachlorocyclopentadiene Concentration ug/L <8.7 4.35 (77-47-4) ❑ ❑ G Mass lb/Day <0.0394 1 Hexachloroethane Concentration ug/L <4.3 1 4.36 (67-72-1) ❑ ❑ r= Mass lb/Day <0.0195 1 Indeno (1,2,3-cd) pyrene Concentration ug/L <4.3 1 4.37 (193-39-5) ❑' ❑ C' Mass lb/Day <0.0195 1 Isophomne Concentration ug/L <8.7 1 Mass lb/Day <0.0394 1 4.38 (78-59-1) 0 ❑ Naphthalene Concentration ug/L <4.3 1 4.39 (91 20 3) ❑v ❑ 0 Mass lb/Day <0.0195 1 Nitrobenzene Concentration ug/L <4.3 1 4.40 (98 95 3) ❑ Mass lb/Day <0.0195 1 N-nitrosodimethylamine Concentration ug/L <4.3 4.41 (62-75-9) ❑ = I Mass lb/Day <0.0195 t N-nitrosodi-n-propylamine Concentration ug/L <4.3 1 4.42 (621-64-7) 0 ❑ Ll Mass lb/Day <0.0195 1 N-nitrosodiphenylamine Concentration ug/L <8.7 1 4.43 (86-30-6) 21 ❑ 0 Mass lb/Day <0.0394 1 Phenanthrene Concentration ug/L <4.3 1 4.44 (85-01-8) ❑o ❑ ❑o Mass Ib/Day <0.0195 1 Pyrene Concentration ug/L <4.3 1 Mass lb/Day <0.0195 1 4.45 (129-00-0) 0 El Presence or Absence Intake (check one) Effluent (optional) Long -Term Pollutant/Parameter Units Testing Long - (and CAS Number, if Required Believed Believed (specify) Maximum Maximum Average Number of Term Number available) Present Absent Daily Monthly Daily Analyses Average of Discharge Discharge Discharge Value Analyses (required) (if available) (if available) 1,2,4-trichlorobenzene Concentration ug/L <4.3 1 4.46 (120821) LEI ❑ Mass I lb/Day <0.0195 1 Section 4. Organic Toxic Pollutants (GC/MS Fraction - Base /Neutral Compounds) Aldrin Concentration ug/L <0.042 1 51 (309-00-2) ❑ G D Mass lb/Day <0.00019 1 o-BHC Concentration ug/L <0.042 1 5,2 (319-84-6) Mass Ib/Day <0.00019 1 (i-BHC Concentration ug/L <0.042 1 5.3 (319 85 7) ;— — U Mass lb/Day <0.00019 1 y-BHC Concentration ug/L <0.042 1 5 4 (58-89-9) ❑ U Mass Ib/Day <0.00019 1 b-BHC Concentration ug/L <0.042 1 5.5 (319-86-8) U Mass lb/Day <0.00019 1 Chlordane Concentration ug/L <0.42 1 5.6 (57 74 9) ❑ ❑ Mass lb/Day <0.0019 1 4,4'-DDT Concentration ug/L <0.042 1 5.7 (50-29-3) U Mass lb/Day <0.00019 1 4,4'-DDE Concentration ug/L <0.042 1 5,8 (72-55-9) ❑ L.1 P) Mass lb/Day <0.00019 1 4,4'-DDD Concentration ug/L <0.042 1 5.9 (72-54-8) L-) C' Mass lb/Day <0.00019 1 Dieldrin Concentration ug/L <0.042 1 5,10 (60-57-1) Mass lb/Day <0.00019 1 a-endosulfan Concentration ug/L <0.042 1 5.11 (115-29-7) U C� Mass Ib/Day <0.00019 1 Presence or Absence Effluent Intake (check one) (optional) Pollutant/Parameter Units Long -Term (and CAS Number, if Testing Required (specify) Maximum Maximum Average Lon 9 Number available) Believed Believed Daily Monthly Daily Number of Term of Present Absent Discharge Discharge Discharge Analyses Average Analyses Value (required) (if available) (if available) P-endosulfan Concentration ug/L <0.042 1 512 (115-29-7) ❑ ❑ 21 Mass lb/Day <0.00019 1 Endosulfan sulfate Concentration ug/L <0.042 1 5.13 (1031-07-8) ❑ ❑ Mass lb/Day <0.00019 1 Endrin Concentration ug/L <0.042 1 514 (72-20-8) ❑ ❑ F11 Mass lb/Day <0.00019 1 Endrin aldehyde Concentration ug/L <0.042 1 5.15 (7421 93 4) ❑ ❑ El Mass lb/Day <0.00019 1 Heptachlor Concentration ug/L <0.042 1 5.16 (76-44 8) ❑ ❑ ❑' Mass lb/Day <0.00019 1 Heptachlor epoxide Concentration ug/L <0.042 1 5.17 (1024-57-3) ❑ ❑ 2 Mass Ib/Day <0.00019 1 PCB-1242 Concentration ug/L <0.42 1 5.18 (53469-21-9) ❑ ❑ Mass lb/Day <0.0019 1 PCB-1254 Concentration ug/L <0.42 1 519 (11097-69-1) ❑ ❑ Mass lb/Day <0.0019 1 PCB-1221 Concentration ug/L <0.42 1 5.20 (11104-28-2) ❑ ❑ 0 Mass lb/Day <0.0019 1 PCB-1232 Concentration ug/L <0.42 1 5.21 (11141-16-5) ❑ ❑ El Mass lb/Day <0.0019 1 PCB-1248 Concentration ug/L <0.42 1 5.22 (12672-29-6) ❑ ❑ Mass lb/Day <0.0019 1 PCB-1260 Concentration ug/L <0.42 1 5.23 (11096-82-5) ❑ ❑ ❑' Mass Ib/Day <0.0019 1 PCB-1016 lConcentration ug/L <0.42 1 5 24 (12674-11-2) ❑ ❑ Mass lb/Day <0.0019 1 TOXICTABLE B. •E. TOTAL PHENOLS,ORGANIC Presence or Absence TOXIC• 1 CFR OUTFALL 1 1 Intake (check one) Effluent (optional) Pollutant/Parameter Units Long -Term (and CAS Number, if Testing Required (specify) Maximum Maximum Average Long - Long - Number available) 15.25 Believed Believed Daily Monthly Daily Number of Term of Present Absent Discharge Discharge Discharge Analyses Average Analyses Value (required) (if available) (if available) Toxaphene Concentration ug/L <0.42 1 Mass I lb/Day <0.0019 1 (8001-35-2) ❑ ❑ ❑� This page intentionally left blank. Presence or Absence (check one) Effluent Intake (optional) Poilutant/Parameter=BelievedBelieved Units Long -Term (and CAS Number, if available)(specify) Maximum Daily Discharge Maximum Monthly Discharge Average Daily Discharge Number of Analyses Long- Termof Average Value Number ses Anal y (required) (if available) (if available) ❑ Check here if you believe all pollutants on Table C to be present in your discharge from the noted outfall. You need not complete the "Presence or Absence" column of Table C for each pollutant. ❑ Check here if you believe all pollutants on Table C to be absent in your discharge from the noted outfall. You need not complete the "Presence or Absence" column of Table C for each pollutant. 1. Bromide (24959-67-9) ED ❑ Concentration mg/L 1.1 1 Mass lb/Day 4.98 1 2 Chlorine, total residual ❑ ❑ Concentration ug/L 10 1 Mass Ib/Day <.045 1 Concentration <25.0 1 3. Color ❑ ❑ Mass 1 Concentration CFU/100mL <1.0 1 4. Fecal Coliform ❑ Mass lb/Day 1 5. Fluoride (16984-48-8) El ❑ Concentration mg/L 0.38 1 Mass lb/Day 1.72 1 Concentration mg/L 7 1 6. Nitrate -nitrite 0 ❑ Mass lb/Day 1 7' Nitrogen, total organic (as N) 0 ❑ Concentration mg/L 8.7 1 Mass lb/Day 1 Concentration mg/L <5 1 8. Oil and Grease ❑ Mass lb/Day <22.7 1 9' Phosphorus (as P), total (7723-14-0) 0 ❑ Concentration mg/L 0.89 1 Mass lb/Day 4.03 1 10. Sulfate (as SO4) (14808-79-8) El ❑ Concentration mg/L 99 1 Mass lb/Day 449 1 Concentration mg/L <0.10 1 11. Sulfide (as S) ❑ ID Mass lb/Day <0.453 1 1 1 Effluent •1 1Presence Intake or Absence one) o tional(check (p� ) Long -Term Parameter Units 17n,V (and CAS Number, if (specify) Maximum Maximum Average Long- Number avilable) Believed Believed Daily Monthly Daily Number of Term of Present Absent Discharge Discharge Discharge Analyses Average Value Analyses y (required) (if available) (if available) Sulfite (as SO3) Concentration ug/L <3000 1 12. (14265-45-3) n Mass lb/Day <13.6 1 Concentration mg/L <0.1 1 13. Surfactants E 0 Mass Ib/Day 1 Aluminum, total Concentration mg/L 0.025 1 14. (7429-90-5) 0 Mass lb/Day 0.113 1 Barium, total Concentration mg/L 0.144 1 15. (7440-39-3) F41 ❑ Mass lb/Day 0.653 Boron, total Concentration mg/L 0,057 1 16. (7440-42-8) 0 Mass lb/Day 0.258 1 Cobalt, total Concentration ug/L <1 1 17. (7440-48-4) Mass Rh/Day <0.00453 1 Iron, total Concentration mg/L 0.104 1 18. (7439-89-6) 0El Mass lb/Day 0.471 1 Magnesium, total Concentration mg/L 15.1 1 19 (7439-95-4) 0El Mass lb/Day 68.4 1 Molybdenum, total Concentration ug/L 4.11 1 20. (7439-98-7) El Mass lb/Day 0.0186 1 Manganese, total Concentration mg/L <0.005 1 21. (7439-96-5) Mass lb/Day <0.0227 1 Tin, total Concentration mg/L <0.01 1 22 (7440-31-5) El 1-1 Mass lb/Day <0.0453 1 Titanium, total Concentration mg/L <0.005 1 23. (7440-32-6) ❑ Mass lb/Day <0.0227 1 TABLE C. CERTAIN CONVENTIONAL AND NON CONVENTIONAL Presence or Absence (check one) POLLUTANTS (40 CFR 122.21(g)(7)(v))' Effluent OUTFALL ,r Intake (optional) Pollutant/Parameter Units Long -Term (and CAS Number, if available) Believed Present Believed Absent (specify) Maximum Daily Discharge Maximum Monthly Discharge Average Daily Discharge Number of Analyses Long- Term Average Value Number of Analyses (required) (if available) (if available) 24. Radioactivity Concentration Alpha, total Mass Concentration Beta, total n Mass Concentration Radium, total ❑ G Mass Concentration Radium 226, total 0 Mass This page intentionally left blank. . L Presence or Absence (check one) Reason Pollutant Believed Present in Discharge Available Quantitative Data (specify units) Believed Present Believed Absent 1.7712Acetalclehycle ❑ El ❑ 0 3. Allyl alcohol ❑ 0 4. Allyl chloride ❑ I 0 5. Amyl acetate ❑ 0 6. Aniline ❑ 0 7. Benzonitrile ❑ El 8. Benzyl chloride ❑ ❑� 9. Butyl acetate ❑ D 10_ Butylamine ❑ ❑� 11. Captan ❑ 121 12. Carbaryl ❑ ❑ 13. Carbofuran ❑ El 14. Carbon disulfide ❑ M 15. Chlorpyrifos ❑ F±1 16. Coumaphos ❑ 0 17. Cresol ❑ ❑� 18. Crotonaldehyde ❑ El 19. Cyclohexane I ❑ I El HAZARDOUSTABLET. CERTAIN AND ASBESTOS Reason Pollutant Believed Present in Discharge Available Quantitative Data (specify units) IDiazinon Pollutant Presence or Absence (check one) Believed Present Believed Absent 2+13 (2,4-dichlorophenoxyacetic acid) El 0 ❑ 21 22. Dicamba ❑ 21 23. Dichlobenil ❑ Ej 24. Dichlone ❑ 0 25. 2,2-dichioropropionic acid ❑ F11 26. Dichlorvos ❑ El 27. Diethyl amine ❑ 0 26 Dimethyl amine ❑ El 29. Dintrobenzene ❑ El M Diquat ❑ 31. Disulfoton ❑ 32. Diuron ❑ 33. Epichlorohydrin ❑ ❑� 34. Ethion ❑ 0 35. Ethylene diamine ❑ El 36. Ethylene dibromide ❑ ❑� 37. Formaldehyde ❑ ❑� 36. Furfural ❑ .. .. Presence or Absence (check one) Reason Pollutant Believed Present in Discharge Available Qu7- (speci IGuthion Pollutant Believed Present Believed Absent ❑ 0 40. Isoprene ❑ FA 41 . Isopropanolamine ❑ 0 42. Kelthane ❑ 0 43. Kepone ❑ ID 44. Malathion ❑ El 45. Mercaptodimethur ❑ El 46. Methoxychlor ❑ 7 47. Methyl mercaptan ❑ El 48. Methyl methacrylate ❑ 0 49. Methyl parathion ❑ Z 50. Mevinphos ❑ 0 51. Mexacarbate ❑ n 52. Monoethyl amine ❑ 0 53. Monomethyl amine ❑ 0 54. Naled ❑ 0 55. Naphthenic acid ❑ ❑� ss. Nitrotoluene ❑ 0 57 IParathion ❑ P� HAZARDOUSTABLE D. CERTAIN .. Presence or Absence (check one) Reason Pollutant Believed Present in Discharge 0r Available Quantitative Data (specify units) Pollutant Believed Present Believed Absent 58. Phenolsulfonate ❑ 2 59. Phosgene ❑ '❑ 60. Propargite ❑❑ 61. Propylene oxide ❑❑ 62. Pyrethrins ❑ El 63. Quinoline ❑ Q 64. Resorcinol ❑ ❑.� 65. Strontium ❑ ❑� 66. Strychnine ❑ 0 67. Styrene ❑ ❑� 68. 2'4'5-T (2'4'5- trichlorophenoxyacetic acid) ❑ ❑� 69. TDE (tetrachlorodiphenyl ethane) ❑ ❑� 70 2,4,5-TP [2-(2,4,5-trichlorophenoxy) propanoic acid] ❑ O 71. Trichlorofon ❑ ❑� 72. Triethanolamine ❑ ❑� 73. Triethylamine ❑ ❑� 74. Trimethylamine ❑ ❑� 75. Uranium ❑ ❑ 76. Vanadium ❑ ❑� Presence or Absence Pollutant (check one) Reason Pollutant Believed Present in Discharge Available Quantitative Data Believed Believed (specify units) Present Absent 77. Vinyl acetate ❑ PI 78. Xylene ❑ 79. Xylenol ❑ P 80. Zirconium ❑ Q ' Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter 1, subchapter N or O. See instructions and 40 CFR 122.21(e)(3). This page intentionally left blank. • • C • -• TCDD a D 1 Presence or Absence • 1 1 Pollutant Congeners Used or (check one) Results of Screening Procedure Believed Believed Manufactured Present Absent 2,3,7,8-TCDD ❑ Li ❑� ' Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I, subchapter N or O. See instructions and 40 CFR 122.21(e)(3). EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCD043678929 NC0004774 Buck Combined Cycle OMB No. 2040-0004 Form U.S. Environmental Protection Agency 2C Application for NPDES Permit to Discharge Wastewater WSWNPDES EPA EXISTING MANUFACTURING, COMMERCIALS MINING, AND SILVICULTURE OPERATIONS SECTIONOUTFALL LOCATIONr 1.1 Provide information on each of the facility's outfalls in the table below. c 0 Outfall m Receiving Water Name Latitude Longitude 0 0 Number J m 007 Yadkin River 35° 42' 57.54" N li 21' 53.54" W w O SECTION•' r rn 2'1 Have you attached a line drawing to this application that shows the water flow through your facility with a = 3 water balance? (See instructions for drawing requirements. See Exhibit 2C-1 at end of instructions for example.) 0 ❑ Yes ❑ No SECTION• 3.1 For each outfall identified under Item 1.1, provide average flow and treatment information. Add additional sheets if necessary. .Outfall Number" 007 Y c C Operations dOperation Average Flow Evoqua Treatment Unit 0.747 mgd c 3 mgd 0 U. mgd m a mgd Treatment Units Description Final Disposal of Solid or Code from Liquid Wastes Other Than (include size, flow rate through each treatment Table 2C-1 Li q unit, retention time, etc.) by Discharge Multimedia filtration, coagulation, declorinazation nuetralization 1-O, 2-D, 2-E, 2-K **Outfall Number** 3.1 Cont Operations Operation Average Flow mgd mgd mgd mgd Q Treatment Description Units Code from Final Disposal of Solid or (include size, flow rate through each treatment Table 2C-1 Liquid Wastes Other Than by 0 unit, retention time, etc.) Discharge U c v E m d F- F **Outfall Number** m N 0 Operations LL d Operation Average Flow rn R mgd d Q mgd mgd mgd Treatment Description Units Code from Final Disposal of Solid or (include size, flow rate through each treatment Table 2C-1 Liquid Wastes Other Than by unit, retention time, etc.) Discharge 3,2 Are you applying for an NPDES permit to operate a privately owned treatment works? w � ❑ Yes E] No SKIP to section 4. N3.3 Have you attached a list that identifies each user of the treatment works? ❑ Yes ❑ No Except for storm runoff, leaks, or spills, are any discharges described in Sections 1 and 3 intermittent or 4.1 seasonal? ❑� ❑ No y SKIP to section 5 Yes 4.2 Provide information on intermittent or seasonal flows for each applicable outfall. Attach add. pages if necessary Outfall Frequency Flow Rate Number Operation Average Average Long -Term Maximum Duration (List) Days/Week MonthsNear Average Daily 2 5 days/ g months/ 0.747 mgd 0.8 mgd 100 days week year 007 days/ months/ mgd mgd days • week year days/ months/ m mgd mgd s days y — week year days/ months/ mgd mgd days week year days/ months/ mgd mgd days week year days/ months/ mgd mgd days week year days/ months/ mgd mgd days week year days/ months/ mgd mgd days week year days/ months/ mgd mgd days week year SECTION•. • 5.1 Do any effluent limitation guidelines (ELGs) promulgated by EPA under Section 304 of the CWA apply to your facility? ❑� Yes ❑ No ♦ SKIP to Section 6. W 5.2 Provide the following information on applicable ELGs. ELG Category ELG Subcategory Regulatory Citation W m Power Generation steam Electric 40 CFR423 Are any of the applicable ELGs expressed in terms of production (or other measure of operation)? c 5.3 ❑ Yes ❑ No ♦ SKIP to Section 6. 0 r Provide an actual measure of daily production expressed in terms and units of applicable ELGs. Outfall Quantity per Unit of E Operation, Product, or Material Day Measure o Number d N N m 5A c 0 c+ 0 0 a Are you presently required by any federal, state, or local authority to meet an implementation schedule for constructing, upgrading, or operating wastewater treatment equipment or practices or any other environmental programs that could affect the discharges described in this application? F6.2 El Yes No SKIP to Item 6.3. ,c ca `m Briefly identify each applicable project in the table below. mBrief v > Identification Affected Outfalls (s ) Sof Source(s) Final Compliance Dates o m` and Description of Project (list outfali Discharge Required q Projected I number) Have you attached sheets describing any additional water pollution control programs (or other environmental 6.3 projects that may affect your discharges) that you now have underway or planned? (optional item) ❑ Yes Q No ❑ Not Applicable SECTION. t See the instructions to determine the pollutants and parameters you are required to monitor and, in turn, the tables you must complete. Not all applicants need to complete each table. Table A. Conventional and Non -Conventional Pollutants Are you requesting a waiver from your NPDES permitting authority for one or more of the Table A pollutants for .y 7.1 any of your outfalls? .� ❑ Yes ❑' No SKIP to Item 7.3. If yes, indicate the applicable outfalls below. Attach waiver request and other required information to the s 7.2 application. n m Outfall Number: Outfall Number: Ouffall Number. s m = Have you completed monitoring for all Table A pollutants at each of your outfalls for which a waiver has not been 7.3 requested and attached the results to this application package? n ❑� Yes ❑ No A Waiver has been requested from my NPDES permitting authority for all pollutants at all m outfalis. `w Table B. Toxic Metals, Cyanide, Total Phenols, and Organic Toxic Pollutants Do any of the facility's processes that contribute wastewater fall into one or more of the primary industry 7.4 categories listed in Exhibit 2C-3? (See end of instructions for exhibit.) n Yes ❑ No SKIP to Item 7.8. 7.5 Have you checked "Testing Required" for all toxic metals, cyanide, and total phenols in Section 1 of Table B? ❑+ Yes ❑ No List the applicable primary industry categories and check the boxes indicating the required GC/MS fraction(s) 7.6 identified in Exhibit 2C-3. Required GC/MS Fraction(s) Primary Industry Category '. (Check applicable Boxes) Steam Elecric Power Plants ❑ volatile ❑+ Acid ❑ Base/Neutral ❑ Pesticide ❑ Volatile ❑ Acid ❑ Base/Neutral ❑ Pesticide ❑ Volatile ❑ Acid ❑ Base/Neutral ❑ Pesticide 7 7 Have you checked "Testing Required" for all required pollutants in Sections 2 through 5 of Table B for each of the GC/MS fractions checked in Item 7.69 0 Yes ❑ No 7.8 Have you checked "Believed Present" or "Believed Absent" for all pollutants listed in Sections 1 through 5 of Table B where testing is not required? ❑ Yes ❑ No Have you provided (1) quantitative data for those Section 1, Table 8, pollutants for which you have indicated testing is 7.9 required or (2) quantitative data or other required information for those Section 1, Table B, pollutants that you have indicated are "Believed Present" in your discharge? Q Yes ❑ No 7.10 Does the applicant qualify for a small business exemption under the criteria specified in the instructions? El Yes Note that you qualify at the top of Table 8, then SKIP to item 7.12 ❑' No a Have you provided (1) quantitative data for those Sections 2 through 5, Table B, pollutants for which you have determined 7.11 testing is required or (2) quantitative data or an explanation for those Sections 2 through 5, Table B, pollutants you have — indicated are "Believed Present" in your discharge? c 0 U ❑Yes ❑ No 0 a Table C. Certain Conventional and Non -Conventional Pollutants m 7.12 Have you indicated whether pollutants are "Believed Present" or "Believed Absent" for all pollutants listed on Table C for all r outfalls? U ❑ Yes ❑ No Y R c Have you completed Table C by providing (1) quantitative data for those pollutants that are limited either directly or c 7.13 indirectly in an ELG and/or (2) quantitative data or an explanation for those pollutants for which you have indicated "Believed Present"? C �' a ❑+ Yes ❑ No W Table O. Certain Hazardous Substances and Asbestos 7.14 Have you indicated whether pollutants are "Believed Present" or "Believed Absent" for all pollutants listed in Table D for all outfalls? ❑ Yes ❑ No 7.15 Have you completed Table D by (1) describing the reasons the applicable pollutants are expected to be discharged and (2) by providing quantitative data, if available? Q Yes ❑ No Table E. 2,3,7,8-Tetrachlorodibenzo-p-Dioxin (2,3,7,8-TCDD) 7 16 Does the facility use or manufacture one or more of the 2,3,7,8-TCDD congeners listed in the instructions, or do you know or have reason to believe that TCDD is or may be present in the effluent? ❑ Yes Complete Table E El No SKIP to section 8 7.17 Have you completed Table E by reporting qualitative data for TCDD? Q Yes ❑ No SECTIONOR K8 1 Is any pollutant listed in Table B a substance or a component of a substance used or manufactured at your facility as an o intermediate or final product or byproduct? ❑ Yes ❑ No SKIP to section 9 ' u 8.2 List the pollutants below. m 1. 4. 7. R a 2. 5. 8. a m 3. 6. 9. SECTIONBIOLOGICAL T• 1 ^ Do you have any knowledge or reason to believe that any biological test for acute chronic toxicity has been made 9.1 within the last three years on (1) any of your discharges or (2) on a receiving water in relation to your discharge? 0 Yes ❑ No SKIP to section 10. d F-'.. 9.2 Identify the tests and their purposes below. s PrpoeoTest(s) Sub Itted to NPDES Date SubmittedTst(, :o . . AutoPermtting A "� •'' ❑� Yes ❑ No 7 co Chronic Toxicity Monthly o. m❑ Yes ❑ No ❑ Yes ❑ No SECTION1 CONTRACT ANALYSES (40 • 10.1 Were any of the analyses reported in section 7 performed by a contract laboratory or consulting firm? Q Yes ❑ No SKIP to section 11. Provide information to each contract laboratory or consultin q firm below. 10.2 Laboratory Number 1'.: ` Laboratory Number 2 Laboratory Number 3 N. Name of Laboratory/firm Pace Anlytical c a Laboratory address 9800 Kincy Avenue #100 ' Huntersville NC28078 °.0,, Phone number 704 875 9092 Pollutant(s) analyzed All SECTION.11. ADDITIONAL INFORMATION (40CFR122.21(g)(13)) Has the NPDES permitting authority requested additional information? 11.1 0 ❑ Yes 0 No SKIP to section 12. 11.2 List the information requested and attach it to this application. w ,.c,. c,. 1. 3. 0 V a 2. 4. Q 3. 5. SECTION 12. CHECKLIST AND CERTIFICATION STATEMENT r r 12.1 In Column 1 below, mark the sections of Form 2C that you have completed and are submitting with your application. For each section, specify in Column 2 any attachments that you are enclosing to alert the permitting authority. Note that not all applicants are required to complete all sections or provide attachments. Column 1 Column 2 Q Section 1: Outfall Location w/ attachments ❑� Section 2: Line Drawing w/ line drawing ❑ w/ additional attachments ❑� Section 3: Average Flows and Treatment w/ attachments ❑ w/ list of each user of privately owned treatmentworks ❑ Section 4: Intermittent Flows ❑ w/ attachments ❑ Section 5: Production ❑ w/ attachments ❑ Section 6: Improvements ❑ w/ attachments ❑ w/ optional additional sheets describing any additional pollution control plans ❑w/ request for a waiver and supporti �❑ w/ explanation for identical outfalls m information yw/ small business exemption ❑request Elw/ other attachments }a, u) c 0 O Section 7: Effluent and Intake ❑v w/ Table A ❑� w/ Table B Characteristics ❑� w/ Table C ❑ w/ Table D U Y ❑ w/ Table E ❑ w/ analytical results as an attachment d U 'o ❑ Section 8: used or Manufactured Toxics ❑ w/ attachments c m N ❑ Section 9: Biological Toxicity Tests ❑ w/ attachments s U U❑ Section V.Contract Analyses Elw/ attachments ❑� Section 11: Additional Information Q w/ attachments ❑✓ Section 12: Checklist and Certification Statement ❑✓ w/ attachments 12.2 Certification Statement 1 certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. if am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. Name (print or type first and last name) Official title Vf s,f 0(4,0r n'c.fG GMZI -R� E*A. 3 Signature Date signed This page intentionally left blank. Waiver Requested (if applicable) Units (specify) Effluent Intake (optional) Pollutant Maximum Daily Discharge (required) Maximum Monthly Discharge (if available) Long -Term Average Daily Discharge (if available) Numberof Analyses Long Term Average Value Number of Analyses ❑ Check here if you have applied to your NPDES permitting authority, for a waiver for all of the pollutants listed on this table for the noted outfall. 1' Biochemical oxygen demand (BOD5) ❑ Concentration mg/L <2.0 1 Mass lb/Day 2. Chemical oxygen demand (COD) ❑ Concentration mg1T <25,0 1 Mass lb/Day 3. Total organic carbon (TOC) ❑ Concentration mg/L 2.8 1 Mass lb/Day 15.9 4. Total suspended solids (TSS) ❑ Concentration mg/L 3.8 1 Mass Ib/Day 21.6 5. Ammonia (as N) ❑ Concentration mg/L <0.10 1 Mass lb/Day <0.567 6. Flow ❑ Rate MOD 0.68 Temperature (winter) ❑ °C °C 11.3 1 7. Temperature (summer) ❑ °C 'C pH (minimum) ❑ Standard Units s.u. 8.2 1 8. pH (maximum) ❑ Standard Units s.U. Enter INTAKE flow below if you want to calculate lb/Day 0.68 This page intentionally left blank. Presence or Absence (check one) Effluent Intake (optional) Pollutant/Parameter (and CAS Number, if (and available Testing Required Believed Present Believed Absent Units (specify) Maximum Daily Discharge Maximum Monthly Discharge Long -Term Average Daily Discharge Number of Analyses Lon Long - Term Average Value of Analyses (required) (if available) (if available) ❑ Check here if you qualify as a small business per the instructions to Form 2C and, therefore, do not need to submit quantitative data for any of the organic toxic pollutants in Sections 2 through 5 of this table. Note, however, that you must still indicate in the appropriate column of this table if you believe any of the pollutants listed are present in your discharge. Section 1. Toxic Metals, Cyanide, and Total Phenols ug/L 2.05 1 1.1 Antimony, total (7440-36-0) 0 El ElConcentration Mass lb/Day 0.0116 1 1.2 Arsenic, total (7440-38-2) 0 0 ❑ Concentration ug/L 34.2 1 Mass b/Day 0.194 1 Concentration ug/L <1 1 1.3 Beryllium, total (7440-41-7) ❑ ❑, Mass lb/Day <0.00567 1 Concentration ug/L <0.1 1 1.4 Cadmium, total (7440-43-9) ❑ ❑, Mass IblDay <0.000567 1 Concentration ug/L <1 1 1.5 Chromium, total (7440-47-3) ❑, ❑ 0 Mass lb/Day <0.00567 1 1.6 Copper, total (7440-50-8) ❑ Concentration ug/L 2.07 1 Mass lb/Day 0.0117 1 Concentration ug/L <1 1 1.7 Lead, total(7439-92-1) ❑ El Mass Ib/Day <0.00567 1 Concentration nglL 0.579 1 1.8 Mercury, total (7439-97-6) ❑ ❑ ❑ Mass lb/Day 0.0000033 1 1.9 Nickel, total (7440-02-0) M ❑ Concentration ug/L 3.75 1 Mass lb/Day 0.0213 1 Concentration ug/L 2.42 1 1.10 Selenium, total (778249-2) ❑ Mass lb/Day 0.0137 1 1.11 Silver, total(7440-22-4) p ❑ Concentration ug/L <1 1 Mass lb/Day <0.00567 1 • r • • • •• • •• -i Effluent • �� Intake Presence or Absence (check one) (optional) Long -Term Long - Pollutant/Parameter TestingUnits (and CAS Number, if available) Required (specify) Maximum Maximum Average Number of Term Number Believed Believed Daily Monthly Daily of Present Absent - Discharge Discharge Discharge Analyses Average Value Analyses (required) (if available) (if available) Concentration ug/L 0.243 1 1.12 Thallium, total (7440-28-0) ❑, ❑ 1 Mass lb/Day 0.00138 Concentration mg/L <0.005 1 1.13 Zinc, total(7440-66-6) 0 ❑ 1 Mass lb/Day <0.0284 Concentration mg/L <0.0080 1 1.14 Cyanide, total (57-12-5) El ❑ 0 1 Mass lb/Day <0.0454 Concentration ug/L 1 <4.3 11 1.15 Phenols, total 71 ❑ 21 Mass lb/Day 1<0.0244 11 Section 2. Organic Toxic Pollutants (GCIMS Fraction -Volatile Compounds) Concentration ug/L <5.0 1 2.1 Acrolein (107-02-8) ❑ ❑ El Mass lb/Day <0.0284 1 Concentration ug/L <5.0 1 2.2 Acrylonitrile(107-13-1) F±1 ❑ 21 1 Mass lb/Day <0.0284 Concentration ug/L <1.0 1 2.3 Benzene (7143-2) ❑, ❑ El Mass lb/Day <0.00567 1 Concentration ug/L <2.0 1 2.4 Bromoform (75-25-2) ❑ ❑ 1 Mass lb/Day <0.0113 Concentration ug/L <2.0 1 2.5 Carbon tetrachloride (56-23-5) El ❑ 0 Mass lb/Day <0.0113 1 Concentration ug/L <2.0 1 2.6 Chlorobenzene (108-90-7) 0 ❑ ❑, Mass lb/Day <0.0113 1 Chlorodibromomethane Concentration ug/L <2.0 1 2.7 (12448-1) ❑' ❑ ❑' Mass lb/Day <0.0113 1 Concentration ug/L <2.0 1 2.8 Chloroethane (75-00-3) ❑ 1 Mass lb/Day <0.0113 • r • • r 1 • • 1 • 1 1 Presence or Absence (check one) Effluent Intake (optional) Pollutant/Parameter (and CAS Number, if available) Testing Required Believed Present Believed Absent Units (specify) Maximum Daily Discharge Maximum Monthly Discharge Long -Term Average Daily Discharge Number of Analyses Lon 9 Term Average value Number of Analyses (required) (if available) (if available) 2'9 2-chloroethylvinyl ether (110-75-8) ❑ ❑ Concentration ug/L <5.0 1 Mass lb/Day <0.0284 1 2.10 Chloroform (67-66-3) ❑ Concentration ug/L <2.0 1 Mass lb/Day <0.0113 1 211 Dichlorobromomethane (75-27-4) ❑ ❑ Concentration ug/L <2.0 1 Mass lb/Day <0.0113 1 2.12 1,1-dichloroethane (75-34-3) ❑ Concentration ug/L <2.0 1 Mass lb/Day <0.0113 1 2.13 1,2dichloroethane (107-06-2) El El1 Concentration <2.0 Mass lb/Day <0.0113 1 2.14 1,1 dichloroethylene(75-35-4) ❑ Concentration ug/L <2.0 1 Mass lb/Day <0.0113 1 2.15 1,2dichloropropane (78-87-5) ❑ Concentration ug/L <2.0 1 Mass lb/Day <0.0113 1 2.16 1,3dichloropropylene (542-75-6) ❑ Concentration ug/L <2.0 1 Mass lb/Day <0.0113 1 Concentration ug/L <1.0 1 2.17 Ethylbenzene (100-41-4) ❑ Mass lb/Day <0.00567 1 Concentration ug/L <2.0 1 2.18 Methyl bromide (74-83-9) ❑ ❑ Mass Ib/Day <0.0113 1 Concentration ug/L <2.0 1 2.19 Methyl chloride (74-87-3) ❑' ❑ ❑ Mass lb/Day <0.0113 1 Concentration ug/L <2.0 1 2.20 Methylene chloride (75-09-2) ❑ ❑ 2 Mass Ib/Day I <0.0113 1 2.21 1.1,2,2- tetrachloroethane (79-34-5) ❑ ❑ 0 Concentration I ug/L 1 <2.0 1 Mass lb/Day 1 <0.0113 1 TOXICTABLE B. •PHENOLS.ORGANIC TOXIC• 1 Effluent OUTFALL 007 Intake Presence or Absence (check one) (optional) Long -Term Long - lutent/Parameter Testing 9 Units (and CAS Number, if Required gelieved believed (specify) Maximum Maximum Average Number of Term Number available) k Present Absent Daily Monthly Daily Analyses Average of Discharge Discharge Discharge Value Analyses y (required) (if available) (if available) oroethylene Concentration ug/L <2.0 1 Mass lb/Day <0.0113 i -4) 0 Concentration ug/L <1.0 1 2.23 Toluene (108-88-3) ❑ Mass lb/Day <0.00567 1 1,2-trans-dichloroethylene Concentration ug/L <2.0 1 2 24 (156-60-5) ❑ Mass lb/Day <0.0113 1 1,1,1-trichloroethane Concentration ug/L <2.0 1 2.25 ❑ El 0 (71-55-6) Mass lb/Day <0.0113 1 1,1,2-trichloroethane Concentration ug/L <2.0 1 2.26 (79-00-5) ❑ ❑ Mass lb/Day <0.0113 1 Concentration ug/L <2.0 1 2.27 Trichloroethylene (79-01-6) F] ❑ Mass Ib/Day <0.0113 i Concentration ug/L <2.0 1 2.28 Vinyl chloride (75-01-4) Mass lb/Day <0.0113 1 Section 3. Organic Toxic Pollutants (GC/MS Fraction -Acid Components) Concentration ug/L <4.3 1 3.1 2-chlorophenol(95-57-8) ❑, ❑ Mass Ib/Day <0.0244 1 2,4-dichlorophenol Concentration ug/L <4.3 1 3.2 (120-83-2) ❑ Mass lb/Day <0.0244 1 2,4-dimethylphenol Concentration ug/L <8.7 1 3.3 (105 67-9) ❑ Mass lb/Day <0.0494 1 4,6-dinitro-o-cresol Concentration ug/L <8.7 1 3.4 (534-52-1) Mass lb/Day <0.0494 1 Concentration ug/L <43.5 1 3.5 2,4-dinitrophenol (51-28-5) ❑ 0 1 Mass lb/Day <0.247 Presence or Absence Intake (check one) Effluent (optional) Pollutant/Parameter Units Long -Term (and CAS Number, if Testing Required (specify) Maximum Maximum Average Long - Number available) Believed Believed Daily Monthly Daily Number of Term of Present Absent Analyses Average Discharge Discharge Discharge value Analyses (required) (if available) (if available) 2-nitrophenol Concentration ug/L <4.3 1 3.6 (88-75-5) `71 ❑ F11 Mass Ib/Day, <0.0244 1 4-nitrophenol Concentration ug/L <8.7 1 3.7 (100-02-7) ❑ Mass lb/Day <0.0494 1 p-chloro-m-cresol Concentration ug/L <4.3 1 3.8 (59-50-7) Mass Ib/Day <0.0244 1 Pentachlorophenol Concentration ug/L <8.7 1 3.9 (87-86-5) (J Mass lb/Day <0.0494 1 Phenol Concentration mg/L <0.020 1 3.10 (108-95-2) Mass lb/Day <0.113 1 2,4,6-trichlorophenol Concentration ug/L <8.7 1 3.11 (88-05-2) 0 U Mass Ib/Day <0.0494 1 Section 4, Organic Toxic Pollutants (GC/MS Fraction - Base /Neutral Compounds) Acenaphthene Concentration ug/L <4.3 1 4A (83-32-9) ❑ L] 2 Mass lb/Day <0.0244 1 Acenaphthylene Concentration ug/L <4.3 1 42 (208-96-8) ❑ 'J E Mass Ib/Day <0.0244 1 Concentration ug/L <4.3 1 4.3 Anthracene(120-12-7) Ell_1 Mass lb/Day <0.0244 1 Concentration ug/L <43.5 1 4.4 Benzidine (92-87-5) ❑ ,� Mass lb/Day <0.247 1 Benzo (a) anthracene Concentration ug/L <4.3 1 4.5 (56-55-3) IJ Mass lb/Day <0.0244 1 Benzo (a) pyrene Concentration ug/L <4.3 1 4.6 (50-32-8) ❑ ❑ Mass lb/Day <0.0244 1 .. Effluent Intake Presence or Absence (check one) (optional) rameter 7CAS Testing Units Long -Term Long- , if available) Required 9 Believed Believed (specify) Maximum Maximum Average Number of Term Number Present Absent Daily Monthly Daily Analyses Average of Analyses y Discharge Discharge Discharge Value (required) (if available) (if available) 3,4-benzofluoranthene Concentration I ug/L <4.3 1 Mass Ib/Day <0.0244 1 4.7 (205-99-2) ❑ ❑ ❑� Concentration I ug/L <4.3 1 4.8 Benzo (ghi) perylene (191-24-2) ❑ ❑ Mass lb/Day <0.0244 1 Benzo (k) fluoranthene (207-08- Concentration ug/L <4.3 1 Mass lb/Day <0.0244 1 4.9 9) ❑ ❑ 0 Bis (2-chloroethoxy) methane Concentration ug/L <8.7 1 Mass lb/Day <0.0494 1 4.10 (111-91-1) ❑ ❑ Bis (2-chloroethyl) ether (11144- Concentration ug/L <4.3 1 Mass lb/Day 10.0244 1 4.11 4) ❑ �' Bis (2-chloroisopropyl) ether (102 Concentration ug/L <4.3 1 Mass lb/Day <0.0244 1 4.12 80-1) Fi ❑ Bis (2-ethylhexyl) phthalate (117- Concentration ug/L <4.3 1 Mass lb/Day <0.0244 1 4.13 817) ❑ ❑ ❑ 4-bromophenyl phenyl ether (101 Concentration ug/L <4.3 1 Mass lb/Day <0.0244 1 4.14 55-3) r-1 Concentration ug/L <4.3 1 4.15 Butyl benzyl phthalate (85-68-7) ❑ ❑ Mass lb/Day <0.0244 1 Concentration ug/L <4.3 1 4.16 2-chloronaphthalene (91-58-7) ❑ ❑ 1 Mass lb/Day <0.0244 4-chlorophenyl phenyl ether Concentration ug/L <4.3 1 Mass lb/Day <0.0244 1 4.17 (7005-72-3) ❑ Concentration ug/L <4.3 1 4.18 Chrysene (218-01-9) 0 Mass lb/Day <0.0244 1 Dibenzo (a,h) anthracene (53-70- Concentration ug/L <4.3 1 Mass lb/Day <0.0244 1 4.19 3) ❑ ❑ B. TOXICTABLE •E, TOTAL PHENOLS,AND ORGANIC TOXIC-• 40 OUTFALL 00 Presence or Absence Intake (check one) Effluent (optional) Pollutant/Parameter Units Long -Term (and CAS Number, if Testing Required (specify) Maximum Maximum Average Long - Number available) Believed Believed Daily Monthly Daily Number of Term of Present Absent Analyses Average Discharge Discharge Discharge Value Analyses (required) (if available) (if available) 1,2-dichlorobenzene Concentration ug/L <2.0 1 4.20 (95-50-1) ❑ ❑ Mass lb/Day <0.0113 1 1,3dichlorobenzene Concentration ug/L <2.0 1 4.21 (541-73-1) ❑ ❑ Mass lb/Day <0.0113 1 1,4dichlorobenzene Concentration ug/L <2.0 1 422 (106-46-7) ❑ ❑ 0 Mass Ib/Day <0.0113 1 3,3-dichlorobenzidine Concentration ug/L <8.7 1 4.23 (91-94-1) El❑ 0 Mass Ib/Day 10.0494 1 Diethyl phthalate Concentration ug/L <4.3 1 4.24 (84-66-2) ❑ ❑ ❑� Mass lb/Day <0.0244 1 Dimethyl phthalate Concentration ug/L <4.3 1 4.25 (13111-3) ❑ ❑ Mass lb/Day <0.0244 1 Di-n-butyl phthalate Concentration ug/L <4.3 1 4.26 (8474-2) ❑ ❑ ❑' Mass lb/Day <0.0244 1 2,4dinitrotoluene Concentration ug/L <4.3 1 4.27 (121-14-2) ❑ ❑ Mass lb/Day <0.0244 1 2,6dindrotoluene Concentration ug/L <4.3 1 428 (606-20-2) ❑ ❑ 0 Mass lb/Day <0.0244 1 Di-n-octyl phthalate Concentration ug/L <4.3 1 4.29 (117-84-0) ❑ ❑ ❑� Mass lb/Day <0.0244 1 1,2-Diphenylhydrazine Concentration ug/L <4.3 1 4.30 (as azobenzene) (122-66-7) ❑ ❑ Mass lb/Day <0.0244 1 Fluoranthene Concentration ug/L <4.3 1 4.31 (206-44-0) ❑ ❑ Mass Ib/Day <0.0244 1 Fluorene Concentration ug/L <4.3 1 4.32 (86 73 7) ❑ ❑ ❑' Mass lb/Day <0.0244 1 • -•I Effluent • Intake Presence or Absence one) (P ) o tional(check Long-TermTestinger, ong eter F(adA Units if Required Believed Believed (specify) Maximum Maximum Average Number of Term Number Present Absent Daily Monthly Daily Analyses Average of Analyses y Discharge Discharge Discharge Value (required) (if available) (if available) Hexachlorobenzene Concentration ug/L <4.3 1 Mass lb/Day <0.0244 1 4.33 (118 74 1) ❑ ❑ ❑ Hexachlorobutadiene Concentration ug/L <4.3 1 Mass lb/Day <0.0244 1 4.34 (8768 3) ❑ ❑ Hexachlorocyclopentadiene Concentration ug/L <8.7 1 Mass lb/Day <0.0494 1 4.35 (77-47-4) ❑ ❑ ❑' Hexachloroethane Concentration ug/L <4.3 1 4.36 (67-72-1 ❑ ❑ ❑' Mass lb/Day <0.0244 1 Indeno (1,2,3-cd) pyrene Concentration ug/L <4.3 1 Mass lb/Day <0.0244 1 4.37 (193-39-5) ❑ ❑ ❑� Isophorone Concentration Concentration ug/L <8.7 1 lb/Day <0.0494 1 4.38 (78-59-1) ❑ ❑ El Naphthalene Concentration ug/L <4.3 1 Mass lb/Day <0.0244 1 4.39 (91-20-3) ❑ ❑ Nitrobenzene Concentration ug/L <4.3 1 4.40 (98-95-3) ❑ ❑ Mass lb/Day <0.0244 i N-nitrosodimethylamine Concentration ug/L <4.3 1 Mass lb/Day <0.0244 1 4.41 (62-75-9) ❑ ❑ N-nitrosodi-n-propylamine Concentration ug/L <4.3 1 Mass lb/Day <0.0244 1 4.42 (621-64-7) ❑ ❑ N-nitrosodiphenylamine Concentration ug/L <8.7 1 Mass lb/Day <0.0494 1 4.43 (86-30-6) ❑ ❑ Phenanthrene Concentration ug/L <4.3 1 Mass lb/Day <0.0244 1 4.44 (85-01-8) Pyrene Concentration ug/L <4.3 1 Mass lb/Day <0.0244 1 4.45 (129-00-0) ❑ ❑ 0 • r • • • ' • • 1 • 1 1 Presence or Absence Intake check one ( ) Effluent (optional) Long -Term Pollutant/Parameter Units Testing Long - (and CAS Number, if Required Believed Believed (specify) Maximum Maximum Average Number of Term Number available) Present Absent Daily Monthly Daily Analyses Average of Discharge Discharge Discharge Value Analyses (required) (if available) (if available) Concentration ug/L <4.3 1 446 11,2,4-trichlorobenzene (120-82-1) ❑ ❑ ❑ Mass I lb/Day <0.0244 1 Section 4. Organic Toxic Pollutants (GC/MS Fraction - Base /Neutral Compounds) Aldrin Concentration ug/L <0.045 1 5.1 (309-00-2) ❑ ❑ Mass lb/Day <0.000255 1 a-BHC Concentration ug/L <0.045 1 52 (319-84-6) ❑ ❑ 0 Mass lb/Day <0.000255 1 R-BHC Concentration ug/L <0.045 1 5.3 (319-85-7) ❑ ❑ ❑ Mass lb/Day <0.000255 1 y-BHC Concentration ug/L <0.045 1 54 (58-89-9) ❑ ❑ Mass lb/Day <0.000255 1 5-BHC Concentration ug/L <0.045 1 5.5 (319 86 8) ❑ ❑ El Mass lb/Day <0.000255 1 Chlordane Concentration ug/L <0.45 1 5.6 (57 74 9) ❑ ❑ 0 Mass lb/Day <0.00255 1 4,4'-DDT Concentration ug/L <0.045 1 5.7 (50-29-3) ❑ ❑ ❑ Mass lb/Day <0.000255 1 4,4'-DDE Concentration ug/L <0.045 1 5 8 (72-55-9) ❑ ❑ 1'] Mass lb/Day <0.000255 1 4,4'-DDD Concentration ug/L <0.045 1 5,9 (72-54-8) ❑ ❑ ❑ Mass lb/Day <0.000255 1 Dieldrin Concentration ug/L <0.045 1 5.10 ( 60-57-1) ❑ ❑ U Mass lb/Day <0.000255 1 a-endosulfan Concentration ug/L <0.045 1 5.11 (115-29-7) ❑ ❑ ❑ Mass lb/Day <0.000255 1 Pol Iutant/Parameter (and CAS Number, if available Testing Required Presence or Absence (check one) Units (specify) Effluent Intake (optional) Believed Present Believed Absent Maximum Daily Discharge (required) Maximum Monthly Discharge (if available) Long -Term Average Daily Discharge (if available) Number of Analyses Lon 9 Term Average Value Number of Analyses 512 O-endosulfan (115-29-7) Concentration ug/L <0.045 1 Mass lb/Day <0.000255 1 5.13 Endosulfan sulfate (1031-07-8) F-1 ❑ Concentration ug/L <0.045 1 Mass Ib/Day <0.000255 1 5.14 Endrin (72-40-8) D ❑ E Concentration ug/L <0.045 1 Mass lb/Day <0.000255 1 5.15 Endrin aldehyde (7421 93-4) I C ❑ ❑ ' Concentration ug/L <0.045 1 Mass Ib/Day <0.000255 1 5.16 Heptachlor 76-44-8 ( ) ❑ ❑ ❑ Concentration ug/L <0.045 1 Mass Ib/Day <0.000255 1 5.17 Heptachlor epoxide (1024-57-3) ❑ ❑' Concentration ug/L <0.045 1 Mass lb/Day <0.000255 1 5.18 PCB-1242 (53469-21-9) ❑ ❑ ❑ Concentration ug/L <0.45 1 Mass lb/Day <0.00255 1 5.19 PCB-1254 (11097-69-1) ❑ ❑ ❑ Concentration ug/L <0.45 1 Mass lb/Day <0.00255 1 5.20 PCB-1221 (11104-28-2) ❑ C Concentration ug/L <0.45 1 Mass lb/Day <0.00255 1 521 PCB-1232 (11141-16-5) '-JI ❑ ❑ Concentration ug/L <0.45 1 Mass lb/Day <0.00255 1 522 PCB-1248 (12672-29-6) ❑ ❑ 0 Concentration ug/L <0.45 1 Mass lb/Day <0.00255 1 5.23 PCB-1260 (11096-82-5) 11 E ❑ Concentration ug/L <0.45 1 Mass Ib/Day <0.00255 1 524 PCB-1016 (12674-11-2) Concentration ug/L <0.45 1 Mass lb/Day <0.00255 1 mill • • • • ' Presence or Absence • • 1 Effluent • 1 1 Intake (check one) (optional) Long -Term Long - Pollutant/Parameter Testing Units (and CAS Number, if Required Believed Believed (specify) Maximum Maximum Average Number Term Number available) Present Absent Daily Monthly Daily Analyses s Analyses Average of Discharge Discharge Discharge Value Analyses (required) (if available) (if available) Toxaphene Concentration ug/L <045 Mass I lb/Day -0.00255 1 5.25 (8001-35-2) This page intentionally left blank. Presence or Absence (check one) Effluent Intake (optional) Long -Term Pollutant/Parameter Units (and CAS Number, if available) Believed Present Believed Absent (specify) Maximum Daily Discharge Maximum Monthly Discharge Average Daily Discharge Number of Analyses Long- Term Average Value Number of Analyses (required) (if available) (if available) ❑ Check here if you believe all pollutants on Table C to be present in your discharge from the noted outfall. You need not complete the "Presence or Absence" column of Table C for each pollutant. ❑ Check here if you believe all pollutants on Table C to be absent in your discharge from the noted outfall. You need not complete the "Presence or Absence' column of Table C for each pollutant. 1 Bromide (24959-67-9) ❑ ❑ Concentration mg/L <0.1 1 Mass lb/Day <0.567 1 2' Chlorine, total residual ❑ ❑ Concentration ug/L <10 1 Mass lb/Day 0.057 1 3. Color ❑ El Concentration <25.0 1 Mass 1 4. Fecal Coliform 0 ❑ Concentration CFU/100mL 2 1 Mass Ib/Day 1 5' Fluoride (16984-48-8) E ❑ Concentration mg/L 0.13 1 Mass Ib/Day 0.738 1 6. Nitrate -nitrite ❑ El Concentration mg/L <0.04 1 Mass lb/Day 0.227 1 7 Nitrogen, total organic (as N) 0 ❑ Concentration mg/L 1.5 1 Mass lb/Day 8.51 1 8. Oil and Grease ❑ Concentration mg/L <5 1 Mass lb/Day <28.4 1 9' Phosphorus (as P), total (7723-14-0) ❑ 0 Concentration mg/L <0.050 1 Mass lb/Day <0.284 1 10 Sulfate (as SO4) (14808-79-8) ❑ Concentration mg/L 65 1 Mass lb/Day 369 1 11. Sulfide (as S) ❑ Concentration mg/L <0.10 1 Mass lb/Day <0.567 1 arkrawanewlenwo Effluent Intake Presence or Absence (check one) (optional) Long -Terre Long Pollutant/Parameter Units (and CAS Number, if (specify) Maximum Maximum Average Number available) Believed Believed Daily Monthly Daily Number of Term of Present Absent Discharge Discharge Discharge Analyses Average Value Analyses y (required) (if available) (if available) Sulfite (as SO3) Concentration ug/L <3000 Mass lb/Day <17 1 12. (14265-45-3) ❑ 0 Concentration mg/L <0.1 1 13. Surfactants ❑ El 1 Mass lb/Day Aluminum, total Concentration mg/L 0.065 14. (7429-90-5) ❑ Mass lb/Day 0.369 1 total Concentration mg/L 0.124 1 1..Barium, (7440-39-3) ❑ Mass lb/Day 0.704 1 Boron, total Concentration mg/L 0.404 1 16. (7440-42-8) 0 ❑ Mass lb/Day 2.29 Cobalt, total Concentration ug/L <1 1 17. (7440-48-4) ❑ Mass lb/Day <0.00567 Iron, total Concentration mg/L 0.352 1 18. (7439-89-6) E Mass lb/Day 2 1 Magnesium, total Concentration mg/L 9.05 1 Mass lb/Day 51.4 1 19' (7439-95-4) E21 ❑ Molybdenum, total Concentration ug/L 26.9 20. (7439-98-7) E21 ❑ Mass lb/Day 0.153 1 Manganese, total Concentration mg/L 0.074 1 21. (7439-96-5) ❑ Mass lb/Day 0.42 1 Tin, total Concentration mg/L <0.01 1 22' (7440-31-5) ❑ Mass lb/Day <0.0567 Titanium, total Concentration mg/L <0.005 1 Mass 1Ib/Day <0.0284 1 23. (7440-32-6) ❑ 0 TABLE C. CERTAIN CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS r 0r Presence or Absence check one ( ) Effluent Intake (optional) Pollutant/Parameter Units Long -Term (and CAS Number, if available) Believed Present Believed Absent (specify) Maximum Daily Discharge Maximum Monthly Discharge Average Daily Discharge Number of Analyses Long- Term Average Value Number of Analyses (required) (if available) (if available) 24. Radioactivity Concentration Alpha, total El 0 Mass Concentration Beta, total ❑ 0 Mass Concentration Radium, total ❑ Mass Concentration Radium 226, total Mass This page intentionally left blank. RECEIVED MAY 01 2023 NCDEQ/DWR/NPDES HAZARDOUSTABLE D. CERTAIN .. Presence or Absence (check one) Reason Pollutant Believed Present in Discharge 00 Available Quantitative Data (specify units) Pollutant Believed Present Believed Absent Asbestos ❑ 21 2. Acetaldehyde ❑ 0 3_ Allyl alcohol ❑ F-1 4. Allyl chloride ❑ 0 5. Amyl acetate ❑ 0 6. Aniline ❑ 0 7. Benzonitrile ❑ ❑� 8. Benzyl chloride ❑ ❑� 9. Butyl acetate ❑ 0 10. Butylamine ❑ 0 11. Caplan ❑ El 12. Carbaryl ❑ 0 13. Carbofuran ❑ 0 14. Carbon disulfide ❑ P-1 15. Chlorpyrifos ❑ El 16. Coumaphos ❑ F-1 17. Cresol ❑ 0 18. Crotonaldehyde ❑ ❑ 119. Cyclohexane I ❑ HAZARDOUS— LE D. CERTAIN Reason Pollutant Believed Present in Discharge 00 Available Quantitative Data (specify units) I21. Pollutant Presence or Absence (check one) Believed Present Believed Absent 2,4-D (2,4-dichlorophenoxyacetic acid)LiDiazinon ❑ El 22. Dicamba ❑ 0 23. Dichlobenil ❑ 24. Dichlone ❑ El 25. 2,2-dichloropropionic acid ❑ ❑ 26. Dichlorvos ❑ 0 27. Diethyl amine ❑ 0 28 Dimethyl amine ❑ ❑� 29. Dintrobenzene ❑ ❑� 30 1 Diquat ❑ 7 31. Disuffoton ❑ 0 32. 1 Diuron ❑ El 33. Epichlorohydrin ❑ ❑' 34. Ethion ❑ ❑� 35. Ethylene diamine ❑ ❑ 36. Ethylene dibromide ❑ El 37. Formaldehyde ❑ n 38. Furfural ❑ F±1 140. .. Pollutant ..-&AILS141-MOMMUNIMIUM Presence or Absence (check one) Reason Pollutant Believed Present in Discharge Available Quantitative Data (specify units) Believed Present Believed Absent 39. Guthion El0 Isoprene ❑ 41. Isopropanolamine ❑ 42. Kelthane ❑ 0 43. Kepone ❑ 0 44. Malathion ❑ El 45. Mercaptodimethur ❑ 21 46. Methoxychlor ❑ ED 47. Methyl mercaptan ❑ F] 48. Methyl methacrylate ❑ 0 49. Methyl parathion ❑ 0 50. Mevinphos ❑ PI 51. Mexacarbate ❑ El 52. Monoethyl amine ❑ 0 53. Monomethyl amine ❑ D 54. Naled ❑ F-I 55. Naphthenic acid ❑ ED 56. Nitrotoluene ❑ 7 57 Parathion 0 M HAZARDOUSTABLE D. CERTAIN Reason Pollutant Believed Present in Discharge Available Quantitative Data (specify units) IPhosgene Pollutant Presence or Absence (check one) Believed Present Believed Absent Phenolsulfonate El RI ❑ ❑� 60. Propargite ❑ ❑� 61. Propylene oxide ❑ ❑� 62. Pyrethrins ❑ ❑� 63. Quinoline ❑ ❑� 64. Resorcinol ❑ Q 65. Strontium ❑ ❑� 66. Strychnine ❑ ❑� 67. Styrene ❑ ❑� 68. 2,4,5-T (2,4,5 trichlorophenoxyacetic acid) ❑ ❑� 69. TDE (tetrachlorodiphenyl ethane) ❑ ❑' 70 2,4,5-TP [2-(2,4,5-trichlorophenoxy) propanoic acid] ❑ ❑ 71. Trichlorofon ❑ ❑� 72. Triethanolamine ❑ ❑� 73. Triethylamine ❑ ❑� 74. Trimethylamine ❑ ❑� 75. Uranium ❑ 76. Vanadium ❑ HAZARDOUSTABLE D. CERTAIN Presence or Absence (check one) Available Quantitative Data Pollutant Reason Pollutant Believed Present in Discharge Believed Believed (specify units) Present Absent 77. Vinyl acetate ❑ E 78. Xylene ❑ ❑� 79. Xylenol El 1z 80. Zirconium ❑ 0 ' Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I, subchapter N or O. See instructions and 40 CFR 122.21(e)(3). This page intentionally left blank. TCDD Presence or Absence Pollutant Congeners (check one) Used or Believed Believed Results of Screening Procedure Manufactured Present Absent 2,3,7,8-TCDD ❑ ❑ ' Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I, subchapter N or O. See instructions and 40 CFR 122.21(e)(3). EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCD043678929 NC0004774 Buck Combined Cycle OMB No. 2040-0004 Form U.S. Environmental Protection Agency Ni2C Application for NPDES Permit to Discharge Wastewater �rEPA EXISTING MANUFACTURING, COMMERCIAL, MINING, AND SILVICULTURE OPERATIONS SECTIONOUTFALL LOCATIONr 1.1 Provide information on each of the facility's outfalls in the table below. c ° Outfall m Receiving Water Name Latitude Longitude 0 Number w 117 Yadkin River 350 42' 21.31"N 80" 22' 30.88"W 5 O SECTION• r rn z' 1 Have you attached a line drawing to this application that shows the water flow through your facility with a 3 water balance? (See instructions for drawing requirements. See Exhibit 2C-1 at end of instructions for example.) 0 ❑ Yes ❑ No SECTION• AND r 3.1 For each outfall identified under Item 1.1, provide average flow and treatment information. Add additional sheets if necessary. "Outfall Number" 117 c d Operations Contributing to Flow E Operation Average Flow Seepage from ash basin 0,0016 mgd L N 3 mgd 0 LL mgd m m mgd QTreatment Units Description Final Disposal of Solid or Code from Liquid Wastes Other Than (include size, flow rate through each treatment Table 2C-1 Li q unit, retention time, etc.) by Discharge sedimentation, discharge to surface water 1-U, 4-A **Outfall Number** 3 t Cont. Operations Contributing to Flow Operation Average Flow mgd mgd mgd mgd Treatment Description Units Code from Final Disposal of Solid or (include size, flow rate through each treatment Table 2C-1 Liquid Wastes Other Than by = o unit, retention time, etc.) Discharge U c m E A m L **Outfall Number** _ N Operations LL d Operation Average Flow rn @ mgd d Q mgd mgd mgd Treatment Description Units Code from Final Disposal of Solid or (include size, flow rate through each treatment Table 2C-1 Liquid Wastes Other Than by unit, retention time, etc.) Discharge 3.2 Are you applying for an NPDES permit to operate a privately owned treatment works? aEi ❑ Yes ❑� No SKIP to section 4. 3.3 Have you attached a list that identifies each user of the treatment works? 0 Yes ❑ No SECTION 4. INTERMITTENT FLOWS r Except for storm runoff, leaks, or spills, are any discharges described in Sections 1 and 3 intermittent or 4.1 seasonal? El yes ❑ No y SKIP to section 5 4.2 Provide information on intermittent or seasonal flows for each applicable outfall. Attach add. pages if necessary Outfall Frequency Flow Rate Operation Number (List) Average Average Long -Term Maximum Duration DaystWeek Months/Year Average Daily Seepage from Ash Basin 5 days/ 12 months/ 0.0016 mgd 0.0027 mgd 260 days week year 117 days/ months/ mgd mgd g days y s V week year days/ months/ mgd g mgd g days y week year days/ months/ mgd mgd days week year days/ months/ mgd mgd days week year days/ months/ mgd mgd days week year days/ months/ mgd mgd days week year days/ months/ mgd mgd days week year days/ months/ mgd mgd days week year SECTION•• • r 5.1 Do any effluent limitation guidelines (ELGs) promulgated by EPA under Section 304 of the CWA apply to your facility? ❑ yes ❑ No »SKIP to Section 6. R 5.2 Provide the following information on applicable ELGs. ELG Category ELG Subcategory Regulatory Citation W power generation team electric 40 CFR 423 Are any of the applicable ELGs expressed in terms of production (or other measure of operation)? 5.3 ❑ yes 0 No ♦ SKIP to Section 6. 0 a Provide an actual measure of daily production expressed in terms and units of applicable ELGs. E Outfall Operation, Product, or Material Quantity per Unit of 0 Number Day Measure 0 M A to 5.4 c 0 U 7 0 0 a Are you presently required by any federal, state, or local authority to meet an implementation schedule for constructing, upgrading, or operating wastewater treatment equipment or practices or any other environmental 6-� programs that could affect the discharges described in this application? ❑ Yes ❑ No SKIP to Item 6.3. a „ n y 6.2 Briefly identify each applicable project in the table below. m m Brief Identification Affected Outfalls Source(s) of Final Compliance Dates c as and Description of Pro ect I (list outfall Discharge Required Projected mE m number) Have you attached sheets describing any additional water pollution control programs (or other environmental 6.3 projects that may affect your discharges) that you now have underway or planned? (optional item) ❑ Yes Q No ❑ Not Applicable SECTION■ r See the instructions to determine the pollutants and parameters you are required to monitor and, in turn, the tables you must complete. Not all applicants need to complete each table. Table A. Conventional and Non -Conventional Pollutants Are you requesting a waiver from your NPDES permitting authority for one or more of the Table A pollutants for 7.1 any of your outfalls? y .� ❑ Yes ❑Q No SKIP to Item 7.3. F If yes, indicate the applicable outfalls below. Attach waiver request and other required information to the r 7.2 application. d Outfall Number: Outfall Number: Outfall Number: s m = Have you completed monitoring for all Table A pollutants at each of your outfalls for which a waiver has not been 7.3 requested and attached the results to this application package? L� Yes ❑ No A Waiver has been requested from my NPDES permitting authority for all pollutants at all 2 outfalls. `w Table B. Toxic Metals, Cyanide, Total Phenols, and Organic Toxic Pollutants Do any of the facility's processes that contribute wastewater fall into one or more of the primary industry 7.4 categories listed in Exhibit 2C-3? (See end of instructions for exhibit.) ❑' Yes ❑ No SKIP to Item 7.8. 7.5 Have you checked "Testing Required" for all toxic metals, cyanide, and total phenols in Section 1 of Table B? ❑ Yes ❑ No List the applicable primary industry categories and check the boxes indicating the required GC/MS fraction(s) 7.6 identified in Exhibit 2C-3. Required GC/MS Fraction(s) Primary Industry Category (Check applicable Boxes) Q volatile ❑' Acid ❑ Base/Neutral ❑ Pesticide ❑ Volatile ❑ Acid ❑ Base/Neutral ❑ Pesticide ❑ Volatile ❑ Acid ❑ Base/Neutral ❑ Pesticide 7 7 Have you checked "Testing Required" for all required pollutants in Sections 2 through 5 of Table B for each of the GC/MS fractions checked in Item 7.6? ❑ Yes ❑ No 7.8 Have you checked "Believed Present" or "Believed Absent" for all pollutants listed in Sections 1 through 5 of Table B where testing is not required? Q Yes ❑ No Have you provided (1) quantitative data for those Section 1, Table B, pollutants for which you have indicated testing is 7.9 required or (2) quantitative data or other required information for those Section 1, Table B, pollutants that you have indicated are "Believed Present' in your discharge? ❑ Yes ❑ No 7.10 Does the applicant qualify for a small business exemption under the criteria specified in the instructions? ❑' Yes Note that you qualify at the top of Table 8, then SKIP to item 7.12 No a Have you provided (1) quantitatve data for those Sections 2 through 5, Table B, pollutants for which you have determined 7.11 testing is required or (2) quantitative data or an explanation for those Sections 2 through 5, Table B, pollutants you have — .c indicated are "Believed Present" in your discharge? 0 U n Yes ❑ No H u Table C. Certain Conventional and Non -Conventional Pollutants w 7,12 Have you indicated whether pollutants are "Believed Present" or "Believed Absent" for all pollutants listed on Table C for all r outfalls? U y Q Yes ❑ No s m Have you completed Table C by providing (1) quantitative data for those pollutants that are limited either directly or c 7.13 indirectly in an ELG and/or (2) quantitative data or an explanation for those pollutants for which you have indicated m 'Believed Present"? c ❑ Yes ❑ No W Table D. Certain Hazardous Substances and Asbestos 7.14 Have you indicated whether pollutants are "Believed Present" or "Believed Absent" for all pollutants listed in Table D for all outfalls? ❑ Yes ❑ No 7.15 Have you completed Table D by (1) describing the reasons the applicable pollutants are expected to be discharged and (2) by providing quantitative data, if available? ❑ Yes ❑ No Table E. 2,3,7,8-Tetrachlorodibenzo-p-Dioxin (2,3,7,8-TCDD) 7.16 Does the facility use or manufacture one or more of the 2,3,7,8-TCDD congeners listed in the instructions, or do you know or have reason to believe that TCDD is or may be present in the effluent'? ❑ Yes Complete Table E ❑ No SKIP to section 8 7.17 Have you completed Table E by reporting qualitative data for TCDD? ❑ Yes ❑ No SECTION■ K8 1 Is any pollutant listed in Table B a substance or a component of a substance used or manufactured at your facility as an o intermediate or final product or byproduct? r ❑ Yes 0 No SKIP to section 9 8.2 List the pollutants below. 1. 4. 7. m 0 2 5. 8. 0 3. 6. 9. SECTION• • • 1 Do you have any knowledge or reason to believe that any biological test for acute chronic toxicity has been made 9.1 within the last three years on (1) any of your discharges or-(2) on a receiving water in relation to your discharge? ❑ Yes 0 No SKIP to section 10. In ..' 9.2 Identify the tests and their purposes below. _ 'x Tests ! Pur ose of Tests P (, SU'—' I ed'to NPDES Date Submitted o .:< :. Permltting Authority ❑ Yes ❑ No 'im A ,`. ❑ Yes ❑ No El Yes ❑ No '.` SECTIONI CONTRACT • • 1 Were any of the analyses reported in section 7 performed by a contract laboratory or consulting firm? 10.1 Q Yes ❑ No SKIP to section 11. Provide information to each contract laboratory or consultin q firm below. 10.2 Laboratory,Number 1 ' Laboratory Number 2 Lrat aboory Number 3;',: . Name of Laboratory/firm Pace Analytical tl1' m , Laboratory address 9800 Kincy Avenue #100 m c ` Huntersville NC 28078 Phone number 0 "' 704 875 9092 Pollutant(s) analyzed All SECTION•NAL INFORMATION (41 Has the NPDES permitting authority requested additional information? 11.1 c ❑ Yes 0 No SKIP to section 12. ' 11.2 List the information requested and attach it to this application. �0- . c �0 1. 3. 0 ' 2. 4. a 3. 5. SECTION 12. CHECKLIST AND CERTIFICATION STATEMENT r 12.1 In Column 1 below, mark the sections of Form 2C that you have completed and are submitting with your application. For each section, specify in Column 2 any attachments that you are enclosing to alert the permitting authority. Note that not all applicants are required to complete all sections or provide attachments. Column 1 Column 2 ❑� Section 1: outfall Location w/ attachments El Section 2: Line Drawing Q w/ line drawing ❑ w/ additional attachments Q Section 3: Average Flows and Treatment w/ attachments ❑ w/ list of each user of privately owned treatment works ❑ Section 4: Intermittent Flows ❑ w/ attachments ❑ section 5: Production ❑ w/ attachments ❑ Section 6: Improvements El w/ attachments ❑ w/ optional additional sheets describing any additional pollution control plans ❑ w/ request for a waiver and supportir❑ w/ explanation for identical outfalls information m y❑ w/ small business exemption Elw/other attachments wrequest y c ❑� w/ Table A w/ Table B o O Section 7: Effluent and Intake Characteristics❑ w/ Table C ❑ w/ Table D u ❑ w/ Table E ❑ w/ analytical results as an attachment m U ❑Q Section 8: used or Manufactured Toxics w/ attachments A ❑ Section 9: Biological Toxicity Tests ❑ w/ attachments s u t ❑ Section 10: Contract Analyses ❑ w/ attachments U 0 Section 11: Additional Information w/ attachments ❑� Section 12: Checklist and Certification Statement w/ attachments 12.2 Certification Statement I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. Name (print or type first and last name) Official title xri)fo ie Ei5enr 'Cil- 6AI1IL R � Signature Date signed N2523 This page intentionally left blank. Effluent Intake (optional) Maximum Daily Discharge Maximum Monthly Discharge Long -Term Average Daily Discharge of Analyses Long Term Average Value Number of Analyses PollutantNumber Waiver Requested Units (if applicable) (specify) (required) (if available) (if available) ❑ Check here if you have applied to your NPDES permitting authority for a waiver for all of the pollutants listed on this table for the noted outfall. 1' Biochemical oxygen demand (BOD5) ❑ Concentration mg/L <2.0 1 Mass lb/Day 1 Concentration mg/L <20 1 2. Chemical oxygen demand (COD) ❑ Mass lb/Day 1 Concentration mg/L 0.655 1 3. Total organic carbon (TOC) ❑ Mass lb/Day 0.00875 1 Concentration mg/L <2.5 1 4. Total suspended solids (TSS) ❑ Mass lb/Day <0.0334 1 Concentration mg/L <0.10 1 5. Ammonia (as N) ❑ Mass lb/Day 1 B. Flow ❑ Rate MOD 0.0016 1 Temperature (winter) ❑ °C °C 17.2 1 7. Temperature (summer) ❑ °C °C pH (minimum) ❑ Standard Units S.U. 6.6 1 8. pH (maximum) ❑ Standard Units S.U. Enter INTAKE flow below if you want to calculate lb/Day Intake Flow Here This page intentionally left blank. ..- Presence or Absence (check one) Effluent Intake (optional) Believed Present Believed Absent Maximum Daily Discharge Maximum Monthly Discharge Long -Term Average Daily Discharge Number of Analyses Long- Term Average Value Number of Analyses Pollutant/Parameter (and CAS Number, if available) Testing Required Units (specify) (required) (if available) (if available) ❑ Peck Check here if you qualify as a small business per the instructions to Form 2C and, therefore, do not need to submit quantitative data for any of the organic toxic pollutants in Sections 2 5 of this table. Note, however, that you must still indicate in the appropriate column of this table if you believe any of the pollutants listed are present in your discharge. Section 1. Toxic Metals, Cyanide, and Total Phenols 1.1 Antimony, total (7440-36-0) F] ❑ ❑, Concentration ug/L <1 1 Mass lb/Day <0.0000134 1 1.2 Arsenic, total (7440-38-2) ❑, ❑ 0 Concentration ug/L <1 1 Mass lb/Day <0.0000134 1 1.3 Beryllium, total (7440-41-7) 21El11 Concentration ug/L <1 1 Mass lb/Day <0.0000134 1 1.4 Cadmium, total (7440-43-9) ❑ Concentration ug/L <0.1 1 Mass lb/Day <0.00000134 1 1.5 Chromium, total (7440-47-3) El ❑ Concentration ug/L <1 1 Mass Ib/Day <0.0000134 1 1.6 Copper, total (7440-50-8) 0 21 ❑ Concentration ug/L 3.53 1 Mass lb/Day 0.0000471 1 1.7 Lead, total (7439-92-1) ❑ Concentration ug/L <1 1 Mass lb/Day <0.0000134 1 1.8 Mercury, total (7439-97-6) ElIDConcentration ng/L <5.00 1 Mass r lb/Day <0.000000066 1 1.9 Nickel, total (7440-02-0) 21 ❑' ❑ Concentration ug/L 6.83 1 Mass lb/Day 0.0000912 1 1.10 Selenium, total (7782-49-2) El ❑' Concentration ug/L <1 1 Mass lb/Day <0.0000134 1 1.11 Silver, total (7440-22-4) ❑ Concentration ug/L <1 1 Mass lb/Day <0.0000134 1 I ABLE B. TOXIC METALS, CYANIDE, TOTAL PHENOLS, ..- Effluent intake (optional) (oP ) Presence or Absence (check one) Pollutant/Parameter (and CAS Number, if available) Testing Required golioved Present Believed Absent Units (specify) Maximum Daily Discharge Maximum Monthly Discharge Long -Term Average Daily Discharge Number of Analyses Long- Term Average Value Number of Analyses (required) (if available) (if available) Concentration ug/L <0.2 1 1.12 Thallium, total (7440-28-0) ❑ ❑ 0 Mass Ib/Day <0.00000267 1 Concentration mg/L <0.005 1 1.13 Zinc, total (7440-66-6) ❑ 0 Mass lb/Day <0.0000668 1 Concentration mg/L <0.010 1 1.14 Cyanide, total (57-12-5) ❑ ❑ 0 Mass lb/Day <0.000134 1 Concentration ug/L <1.6 1 1.15 Phenols, total r; �,] Mass lb/Day 1 <0.0000214 1 1 Section 2. Organic Toxic Pollutants (GCIMS Fraction - Volatile Compounds) Concentration ug/L <5.0 1 2.1 Acrolein (107-02-8) ❑ El Mass Ib/Day <0.0000668 1 Concentration ug/L <5.0 1 2.2 Acrylonitrile(107-13-1) ❑ Mass lb/Day <0.0000668 1 Concentration ug/L <1.0 1 2.3 Benzene (7143-2) ❑, ❑ El Mass lb/Day <0.0000134 1 Concentration ug/L <1.0 1 2.4 Bromoform (75-25-2) ElMass Ib/Day <0.0000134 1 Concentration ug/L <1.0 1 2.5 Carbon tetrachloride (56-23-5) 0 ❑ Mass lb/Day <0.0000134 1 Concentration ug/L <1.0 1 2.6 Chlorobenzene (108-90-7) ❑ Mass lb/Day <0.0000134 1 2.7 Chlorodibromomethane (12448-1) 0 ❑ Concentration ug/L <1.0 1 Mass lb/Day <0.0000134 1 Concentration ug/L <2.0 1 2.8 Chloroethane (75-00-3) El ❑ ❑, Mass I lb/Day 1 <0.0000267 1 1 .. Presence or Absence (check one) Effluent Intake (optional) Pollutant/Parameter (and CAS Number, IF available) Testing Required Required Believed Present Believed Absent Units (specify) Maximum Daily Discharge Maximum Monthly Discharge Long -Term Average Daily Discharge Number of Analyses Lon Long - Term Average Value of Analyses (required) (if available) (if available) 2'9 2-chloroethylvinyl ether (110-75-8) Concentration ug/L <5.0 1 Mass lb/Day <0.0000668 1 Concentration ug/L <1.0 1 2.10 Chloroform (67-66-3) ❑ 0 Mass lb/Day <0.0000134 1 2.11 Dichlorobromomethane (75-27-4) ❑ Concentration ug/L <1.0 1 Mass lb/Day <0.0000134 1 Concentration ug/L <1.0 1 2.12 1,1-dichloroelhane (75-34-3) ❑ ❑� Mass lb/Day <0.0000134 1 2.13 1,2-dichloroethane (107-D6-2) Concentration ug/L <1.0 1 Mass lb/Day <0.0000134 1 2.14 1,1-dichloroethylene (75-35-4) ❑ ill Concentration ug/L <1.0 1 Mass lb/Day <0.0000134 1 2.15 1,2-dichloropropane (78-87-5) 0 Concentration ug/L <1.0 1 Mass lb/Day <0.0000134 1 2.16 1,3-dichloropropylene (542-75-6) rl ❑ ❑ Concentration ug/L <1.0 1 Mass lb/Day <0.0000134 1 2.17 Ethylbenzene (100-414) ❑ ❑ Concentration ug/L <1.0 1 Mass lb/Day <0.0000134 1 Concentration ug/L <2.0 1 2.18 Methyl bromide (74-83-9) ❑ Mass lb/Day <0.0000267 1 Concentration ug/L <2.0 1 2.19 Methyl chloride (74-87-3) ❑ Mass lb/Day <0.0000267 1 Concentration ug/L <1.0 1 2.20 Methylene chloride (75-09-2) 0 El 0 Mass lb/Day <0.0000134 1 2.21 1,1,2,2- letrachloroethane (79-34-5) 0 ❑ ❑ Concentration ug/L <1.0 1 Mass lb/Day <0.0000134 1 Presence or Absence Effluent Intake (check one) (optional) Pollutant/Parameter TestingUnits Long -Term Lon 9 (and CAS Number, if Required Believed Believed (specify) Maximum Maximum Average Number of Term Number available) Present Absent Daily Monthly Daily Analyses Average of Discharge Discharge Discharge Value Analyses (required) (if available) (if available) Tetrachloroethylene Concentration ug/L <1.0 1 Mass lb/Day <0.0000134 1 222 (127-18-4) C Concentration ug/L <1.0 1 2.23 Toluene (108-88-3) F1 0 Mass lb/Day <0.0000134 1 1,24rans-dichloroethylene Concentration ug/L <1.0 1 2.24 0 o (156-60-5) Mass lb/Day <0.0000134 1 1,1,1-trichloroethane Concentration ug/L <1.0 1 2.25 ❑ ❑ (71-55-6) Mass lb/Day <0.0000134 1 1,1,2-trichloroethane Concentration ug/L <1.0 1 2.26 (79-00-5) 0 ❑ ❑ Mass lb/Day <0.0000134 1 Concentration ug/L <1.0 1 2.27 Trichloroethylene (79-01-6) ❑.� ❑ ❑' Mass lb/Day <0.0000134 1 Concentration ug/L <1.0 1 2.28 Vinyl chloride (75-01-4) ❑, ❑ Mass Ib/Day <0.0000134 1 Section 3. Organic Toxic Pollutants (GCIMS Fraction -Acid Components) Concentration ug/L <1.6 1 3.1 2-chlorophenol (95-57-8) ❑, ❑ Mass lb/Day <0.0000214 1 2,4-dichlorophenol Concentration ug/L <1.6 1 3.2 (120-83-2) ❑ ElMass El lb/Day <0.0000214 1 2,4-dimethylphenol Concentration ug/L <1.6 1 3.3 (105-67-9) ❑' ❑ Mass IblDay <0.0000214 1 4,6-dinilro-o-cresol Concentration ug/L <8.0 1 Mass lb/Day <0.000107 1 3.4 (534-52-1) ❑ Concentration ug/L <8.0 1 3.5 2,4-dinitrophenol (51-28-5) ❑ 0 Mass lb/Day <0.000107 1 ..- Presence or Absence Intake (check one) Effluent (optional) Pollutant/Parameter Units Long -Term (and CAS Number, if Testing Required (specify) Maximum Maximum Average Lon 9 Number available Believed Believed Daily Monthly Daily Number of Term of Present Absent Analyses Average Discharge Discharge Discharge Value Analyses (required) (if available) (if available) 2-nitrophenol Concentration ug/L <3.2 1 3.6 (88 75 5) 0 ❑ Mass lb/Day <0.0000427 1 4-nitrophenol Concentration ug/L <8.0 1 3.7 (100-02-7) FA❑ 0 Mass lb/Day <0.000107 1 p-chloro-m-cresol Concentration ug/L <1.6 1 3.8 (59-50-7) 0 ❑ 0 Mass Ib/Day c0.0000214 1 Pentachlorophenol Concentration ug/L <8.0 1 3.9 (87-86-5) 0 ❑ Mass lb/Day <0.000107 1 Phenol Concentration mg/L <0.0050 1 3.10 ❑ (108-95-2) Mass lb/Day <0.0000668 1 2,4,6-trichlorophenol Concentration ug/L <1.6 1 3.11 (88-05-2) 0 ❑ Mass Ib/Day <0.0000214 1 Acenaphthene Concentration ug/L <1.6 1 4.1 (83-32-9) 21 ❑ 0 Mass lb/Day <0.0000214 1 Acenaphthylene Concentration ug/L <1.6 1 42 (208-96-8) 0 ❑ 0 Mass lb/Day <0.0000214 1 Concentration ug/L <1.6 1 4.3 Anthracene (120-12-7) ❑, ❑ Mass lb/Day <0.0000214 1 Concentration ug/L <8.0 1 4.4 Benzidine (92-87-5) ❑ Mass lb/Day <0.000107 1 Benzo (a) anthracene Concentration ug/L <1.6 1 4.5 (56-55-3) R] ❑ ❑� Mass lb/Day <0.0000214 1 Benzo (a) pyrene Concentration ug/L <1.6 1 4.6 (50-32-8) ID ❑ El Mass lb/Day <0.0000214 1 - ..111-11 Presence or Absence Effluent Intake (check one) (optional) Long -Term Lon 9 rameter 7CAS TestingUnits , if available) Required Believed Believed (specify) Maximum Maximum Average Number of Term Number Present Absent Daily Monthly Daily Analyses Average of Discharge Discharge Discharge Value Analyses (required) (if available) (if available) 3,4-benzofluoranthene Concentration ug/L <1.6 1 47 (205-99-2) El lb/Day <0.0000214 1 Concentration ug/L <1.6 1 4.8 Benzo (ghi) perylene (191-24-2) ❑, ❑ ,❑ Mass lb/Day <0.0000214 1 Benzo (k) fluoranthene (207-08- Concentration ug/L <1.6 1 4.9 9) ❑ Mass Ib/Day <0.0000214 1 Bis (2-chloroethoxy) methane Concentration ug/L <1.6 1 4.10 (111-91-1) ❑ F1 Mass lb/Day <0.0000214 1 Bis (2-chloroethyl) ether (111-44- Concentration ug/L <1.6 1 4.11 4)71 ❑ F1 Mass lb/Day <0.0000214 1 Bis (2-chloroisopropyl) ether (102 concentration ug/L <1.6 1 4.12 80-1) El❑ Mass lb/Day <0.0000214 1 Bis (2-ethylhexyl) phthalate (117- Concentration ug/L <8.0 1 4.13 81-7) 91 ❑ Mass lb/Day <0.000107 1 4-bromophenyl phenyl ether (101 Concentration ug/L <1.6 1 4.14 55-3) ❑ Mass lb/Day <0.0000214 1 Concentration ug/L <1.6 1 4.15 Butyl benzyl phthalate (85-68-7) ❑ Mass lb/Day <0.0000214 1 Concentration ug/L <1.6 1 4.16 2-chloronaphthalene (91-58-7) El Mass lb/Day <0.0000214 1 4-chlorophenyl phenyl ether Concentration ug/L <1.6 1 4.17 (7005-72-3) ❑ 0 Mass lb/Day <0.0000214 1 Concentration ug/L <1.6 1 4.18 Chrysene (218-01-9) ❑ ❑ ❑ Mass lb/Day <0.0000214 1 Dibenzo (a,h) anthracene (53-70- Concentration ug/L <1.6 1 4.19 3) 0 ❑ Mass I lb/Day <0.0000214 1 TABLE B. TOXIC METALS, CYANIDE, TOTAL PHENOLS, ..- Presence or Absence Effluent Intake (check one) (optional) Poll utant/Parameter Units Long -Term (and CAS Number, if Testing Required (specify) Maximum Maximum Average Lon 9 Number available Believed Believed Daily Monthly Daily Number of Term of Present Absent Discharge Discharge Discharge Analyses Average Analyses Value (required) (If available) (if available) 1,2-dichlorobenzene Concentration ug/L <1.0 1 4.20 (95.50-1) Mass lb/Day <0.0000134 1 1,3-dichlorobenzene Concentration ug/L <1.0 1 4.21 (541-73-1) 0 ❑ ❑' Mass lb/Day <0.0000134 1 1,4-dichlorobenzene Concentration ug/L <1.0 1 4.22 (106-46-7) ❑ Id Mass lb/Day <0.0000134 1 3,3dichlorobenzidine Concentration ug/L <8.0 1 4.23 (91-94-1) Fwl ❑ El Mass lb/Day <0.000107 1 Diethyl phthalate Concentration ug/L <1.6 1 4.24 (84-66 2) 0 ❑ 0 Mass lb/Day <0.0000214 1 Dimethyl phthalate Concentration ug/L <1.6 1 425 (131-11-3) ❑ ❑' Mass lb/Day <0.0000214 1 Di-n-butyl phthalate Concentration ug/L <1.6 1 4.26 (84-74-2) ❑' ❑ ❑ Mass VDay <0.0000214 1 2,4-din@rotoluene Concentration ug/L <3.2 1 4.27 (121-14-2) 2) ❑ 0 Mass lb/Day <0.0000427 1 2,6dinitrotoluene Concentration ug/L <3.2 1 4.28 (606-20-2) El Mass Ib/Day <0.0000427 1 Di-n-octyl phthalate Concentration ug/L <1.6 1 4.29 (117-84-0) ❑ Mass lb/Day <0.0000214 1 1,2-Diphenylhydrazine Concentration ug/L <1.6 1 4.30 (as azobenzene)(122-66-7) 0 ❑ Mass lb/Day <0.0000214 1 Fluoranthene Concentration ug/L <1.6 1 4.31 (206-"-0 ❑ Mass lb/Day <0.0000214 1 Fluorene Concentration ug/L <1.6 1 4.32 (86-73-7) ❑' ❑ Mass lb/Day <0.0000214 1 ..- Effluent Presence or Absence (check one) (optional) Pollutant/Parameter TestingUnits Long -Term Long - 7Value (and CAS Number, if Required Behaved Believed (specify) Maximum Maximum Average Number of available) Present Absent Daly Monthly Daily Analyses Discharge Discharge Discharge (required) (if available) (if available) Hexachlorobenzene Concentration ug/L <1.6 1 4.33 (118-74-1) 21 ❑ �' Mass lb/Day <0.0000214 1 Hexachlorobutadiene Concentration ug/L <1.6 1 4.34 (87-68 3) Mass lb/Day <0.0000214 1 Hexachlorocyclopentadiene Concentration ug/L <8.0 1 Mass Ib/Day <0.000107 1 4.35 (77-474) Hexachloroethane Concentration ug/L <1.6 1 4.36 (67721) ❑ Mass lb/Day <0.0000214 1 Indeno (1,2,3-cd) pyrene Concentration ug/L <1.6 1 Mass IblDay <0.0000214 1 4.37 (193-39-5) 0 Isophorone Concentration ug/L <1.6 1 Mass Ib/Day <0.0000214 1 4.38 (78-59-1) Naphthalene Concentration ug/L <1.6 1 Mass lb/Day <0.0000214 1 4.39 (9120-3) ❑' ❑ Nitrobenzene Concentration ug/L <1.6 1 4.40 (98-95-3) ❑ Mass lb/Day <0.0000214 1 N-nitrosodimethylamine Concentration ug/L <1.6 1 4.41 (62 75-9) ❑ 0 Mass Ib/Day <0.0000214 1 N-nitrosodi-n-propylamine Concentration ug/L <1.6 1 4.42 (621-64-7) 0 ❑ ❑ Mass lb/Day <0.0000214 1 N-nitrosodiphenylamine Concentration ug/L <1.6 t 4.43 (86-30-6) Mass lb/Day <0.0000214 1 Phenanthrene Concentration ug/L <1.6 1 4.44 (85.01-8) F] ❑ '❑ Mass IblDay <0.0000214 1 Pyrene Concentration ug/L <1.6 1 Mass IblDay <0.0000214 1 4.45 (129 00 0) ❑ Intake Presence or Absence (check one) Effluent (optional) Long -Term Pollutant/Parameter Units Testing Long - (and CAS Number, if Required Believed Believed (specify) Maximum Maximum Average Number of Term Number available) Present Absent Daily Monthly Daily Analyses Average of Discharge Discharge Discharge Value Analyses (required) (if available) (If available) 1,2,4-trichlorobenzene Concentration ug/L <1.6 4.46 (120-82-1) ❑ ❑ ❑ Mass I lb/Day <0.0000214 Section 4. Organic Toxic Pollutants (GC/MS Fraction - Base ]Neutral Compounds) Aldrin Concentration 5.1 (309-00-2) ❑ ❑ ❑ Mass a-BHC Concentration 5.2 (319-84-6) ❑ ❑ ❑ Mass 3-BHC Concentration 5.3 (319-85-7) ❑ ❑ ❑ Mass y-BHC Concentration 54 (58-89-9) ❑ ❑ ❑ Mass b-BHC Concentration Concentration 5.5 (319-86-8) ❑ ❑ El Chlordane Concentration 5.6 (57-74-9) ❑ ❑ ❑ Mass 4,4'-DDT Concentration 5.7 (50-29-3) El❑ ❑ Mass 4,4'-DDE Concentration 5.8 (72-55-9) ❑ ❑ ❑ Mass 4,4'-DDD Concentration 59 (72-54-8) ❑ ❑ ❑ Mass 5.10 Dieldrin Concentration Mass (60571) ❑ ❑ ❑ a-endosulfan Concentration 5.11 (115-29-7) ❑ ❑ ❑ Mass Effluent Intake Presence or Absence (check one) (optional) Pollutant/Parameter Testing Units Long -Term Long (and CAS Number, if Required Believed Believed (specify) Maximum Maximum Average Number of Term Number available) Present Absent Daily Monthly Daily Analyses Average of Analyses y Discharge Discharge Discharge Value (required) (if available) (if available) p-endosulfan Concentration❑ Mass 5.12 (115-29-7) ❑ ❑ Endosulfan sulfate Concentration Mass 5.13 (1031-07-8) ❑ El ❑ Endrin Concentration Mass 5.14 (72-20-8) -�-1 ❑ Endrin aldehyde Concentration Mass 5.15 (7421-934) ❑ ❑ ❑ Heptachlor Concentration Mass 5.16 (7�_8) ❑ f I ❑ Heptachlor epoxide r Concentration Mass 5.17 (1024-57-3) El ❑ PCB-1242 Concentration ug/L <0.40 1 Mass lb/Day <0.00000534 1 5.18 (53469-21-9) ❑' ❑ ❑' PCB-1254 Concentration ug/L <0.40 1 Mass lb/Day <0.00000534 1 5.19 (11097-69-1) ❑' �' ❑ PCB-1221 Concentration ug/L <0.40 Mass lb/Day <0.00000534 5.20 (11104-28 2) ❑'' ❑ PCB-1232 Concentration ug/L <0.40 1 5.21 (11141-16-5) ❑ 0 Mass lb/Day <0.00000534 1 PCB-1248 Concentration ug/L <0.40 1 Mass lb/Day <0.00000534 1 5.22 (12672-29-6) ❑ ❑ ❑ PCB-1260 Concentration ug/L <0.40 Mass lb/Da y <0.00000534 1 5.23 (11096-82-5) ❑ ❑ ❑ PCB-1016 Concentration ug/L <0.40 1 Mass lb/Day <0.00000534 1 5.24 (12674-11 2) [-' ❑ ❑ Presence or Absence Intake (check one) Effluent (optional) Poll utant/Parameter Testing Units Long -Term (and CAS Number, if Required (specify) Maximum Maximum Average Long - Number available Believed Believed Daily Monthly Daily Number of Term of Present Absent Analyses Average Discharge Discharge Discharge Value Analyses (required) (if available) (if available) Toxaphene 5.25 Concentration Cc (8001-35-2) ❑ El This page intentionally left blank. Presence or Absence (check one) Effluent Intake (optional) Pollutant/Parameter Units Long -Term (and CAS Number, if available) Believed Present Believed Absent (specify) ximum aily charge :D, Maximum Monthly Discharge Average Daily Discharge Number of Analyses Long Term Average Value Number of Analyses yquired) (if available) (if available) ❑ Check here if you believe all pollutants on Table C to be present in your discharge from the noted outfall. You need not complete the "Presence or Absence" column of Table C for each pollutant. ❑ Check here if you believe all pollutants on Table C to be absent in your discharge from the noted outfall. You need not complete the "Presence or Absence" column of Table C for each pollutant. 1' Bromide (24959-67-9) ❑ Concentration mg/L 0.32 1 Mass lb/Day 0,00427 1 2' Chlorine, total residual ❑ El mg/L <0.028 1 Mass Mass lb/Day 1 Concentration color units <5.0 1 3. Color ❑ El Mass lb/Day 1 Concentration CFllnoomL <1.0 1 4. Fecal Coliform ❑ Q Mass lb/Day 1 5' Fluoride (16984-48-8) El ❑ Concentration mg/L 0.18 1 Mass lb/Day 0.0024 1 Concentration mg/L 0.023 1 6. Nitrate -nitrite 0 ❑ Mass lb/Day 0.000307 1 7' Nitrogen, total organic (as N) 0 ❑ Concentration mg/L 0.02 1 Mass lb/Day 0.00027 1 Concentration mg/L <5 1 8. Oil and Grease ❑ El Mass lb/Day <0.0668 1 9' Phosphorus (as P), total(7723-14-0) El ❑ Concentration mg/L 1 0.053 1 Mass lb/Day 0.000708 1 10. Sulfate (as SO4) (14808-79-8) ❑ Concentration mg/L 42 1 Mass lb/Day 0.561 1 Concentration mg/L <1.0 1 11. Sulfide (as S) ❑ F] Mass lb/Day <0.0134 1 Presence or Absence Effluent Intake (check one) (optional) Pollutant/Parameter Units Long -Term (and CAS Number, if (specify) Maximum Maximum Average Long- Number available) Believed Believed Daily Monthly Daily Number of Term of Present Absent Discharge Discharge Discharge Analyses Average Value Analyses (required) (if available) (if available) Sulfite (as S03) Concentration mg/L 2.0 1 12. (14265-45-3) Mass lb/Day 0.0267 1 Concentration mg/L <0.1 1 13. Surfactants ❑ 0 Mass lb/Day 1 Aluminum, total Concentration mg/L 0.098 14. (7429-90-5) '] ❑ Mass lb/Day 0.00131 1 Barium, total Concentration mg/L 0.034 15. (7440.39-3) Mass lb/Day 0.000454 Boron, total Concentration mg/L 0.731 1 Mass lb/Day 0.00976 16. (7440-42-8) C Cobalt, total Concentration ug/L <1 1 17. (7440-48-4) Mass lb/Day <0.0000134 1 Iron total Concentration mg/L 0.081 1 18. (7439-89-6) Mass lb/Day 0.00108 1 Magnesium, total Concentration mg/L 14.5 1 19. (7439-95A) Mass lb/Day 0.194 1 Molybdenum, total Concentration ug/L 13.8 1 20. (7439-98-7) Masslb/Day 0.000184 1 Manganese, total Concentration mg/L 0.054 1 21. (7439-96-5) 2 Mass lb/Day 0.000721 1 Tin, total Concentration mg/L <0.01 1 22. (7440-31-5) Mass lb/Day <0.000134 Titanium, total Concentration mg/L <0.005 23. (7440-32-6) Mass lb/Day <0.0000668 Presence or Absence (check one) Effluent Intake (optional) Pollutant/Parameter Units Long -Term (and CAS Number, if available) Believed Present Believed Absent (specify) Maximum Daily Discharge Maximum Monthly Discharge Average Daily Discharge Number of Analyses Long- Term Average Value Number of Analyses (required) (if available) (if available) 24. Radioactivity Concentration Alpha, total El Mass Concentration Beta, total C Mass Concentration Radium, total I El El Mass Concentration Radium 226, total El 11 Mass This page intentionally left blank. .. .. Presence or Absence (check one) Reason Pollutant Believed Present in Discharge Available Quantitative Data (specify units) Pollutant Believed Present Believed Absent 1. Asbestos ❑ El 2 Acetaldehyde ❑ PI 3. Allyl alcohol ❑ F11 4. Ally] chloride ❑ ❑� 5. Amyl acetate ❑ 0 6. Aniline ❑ 0 7. Benzonitrile ❑ ED 8. Benzyl chloride ❑ EI 9. Butyl acetate ❑ F-1 10. Butylamine ❑ El 11. Captan ❑ ❑� 12. Carbaryl ❑ 0 13. Carbofuran ❑ ED 14. Carbon disulfide ❑ El 15. Chlorpyrifos ❑ F-1 16. Coumaphos ❑ ❑ 17. Cresol ❑ ❑� 16. Crotonaldehyde ❑ El 19 1 Cyclohexane ❑ El HAZARDOUSTABLE D. CERTAIN Reason Pollutant Believed Present in Discharge Available Quantitative Data (specify units) IDiazinon Pollutant Presence or Absence (check one) Believed Present Believed Absent 2,4-D (2,4-dichlorophenoxyacetic acid) ❑ ❑ ❑ 22_ Dicamba ❑ 23. Dichlobenil ❑ ❑ 24. Dichlone ❑ 25. 2,2-dichloropropionic acid ❑ 26. Dichlorvos ❑ ❑ 27. Diethyl amine ❑ 0 26 Dimethyl amine ❑ F±1 29. Dintrobenzene ❑ PI 30. Dicluat ❑ 0 31. Disulfoton ❑ ❑� 32. IDiuron ❑ 33. Epichlorohydrin ❑ ❑� 34. Ethion ❑ 0 35. Ethylene diamine ❑ ❑ 36. Ethylene dibromide ❑ 37. Formaldehyde ❑ 38. Furfural 0 Ilsoprene HAZARDOUSTABLE D. CERTAIN Pollutant .. Presence or Absence (check one) Reason Pollutant Believed Present in Discharge Available Quantitative Data (specify units) Believed Present Believed Absent Guthion El 1-1 ❑ 0 41. 1 Isopropanolamine ❑ 0 42. Kelthane ❑ 0 43. Kepone ❑ 0 44. Malathion ❑ 21 45. Mercaptodimethur ❑ n 46. Methoxychlor ❑ 0 47. Methyl mercaptan ❑ 0 48. Methyl methacrylate ❑ 21 49. Methyl parathion ❑ n 50. Mevinphos ❑ 21 51. Mexacarbate ❑ El 52. Monoethyl amine ❑ 0 53. Monomethyl amine ❑ 0 54. Naled ❑ ❑ 55. Naphthenic acid ❑ F±1 56. Nitrotoluene ❑ P 57 Parathion ❑ 0 TABLE HAZARDOUS- D. CERTAIN .. Reason Pollutant Believed Present in Discharge Available Quantitative Data (specify units) lPhosgene Pollutant Presence or Absence (check one) Believed Present Believed Absent Phenolsulfonate El 7 ❑ 21 60. Propargite ❑ ❑� 61. Propylene oxide ❑ ❑� 62. Pyrethrins ❑ ❑� 63. Quinoline ❑ ❑� 64. Resorcinol ❑ ❑ 65. Strontium ❑ 0 66. Strychnine ❑ ❑� 67. Styrene ❑ ❑� 68. 2,4,5-T (2,4,5- trichlorophenoxyacetic acid) ❑ ❑ 69. TDE (tetrachlorodiphenyl ethane) ❑ ❑� 70 2,4,5-TP [2-(2,4,5-trichlorophenoxy) propanoic acid] ❑ O 71. Trichlorofon ❑ ❑Q 72. Triethanolamine ❑ ❑� 73. Triethylamine ❑ ❑Q 74. Trimethylamine ❑ ❑� 75. Uranium ❑ ❑✓ 76. Vanadium ❑ ❑� .. . Presence or Absence (check one) r Reason Pollutant Believed Present in Discharge Available Quantitative Data (specify units) Pollutant Believed Present Believed Absent 77. Vinyl acetate 0 78. Xylene ❑ ❑� 79. Xytenol ❑' 80, Zirconium ❑ Q ' Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I, subchapter N or O. See instructions and 40 CFR 122.21(e)(3). This page intentionally left blank. TCDD Presence or Absence Pollutant Congeners Used or (check one) Results of Screening Procedure Believed Believed Manufactured Present Absent 2,3,7,8-TCDD ❑ ❑ 21 Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter], subchapter N or O. See instructions and 40 CFR 122.21(e)(3). Buck Station NPDES Wastewater Permit Renewal Application Attachment 4 Outfall Location Map jOutfall 007 jOutfall 001A AI►h/ s Dukeville • �_-Steam ;> uckStahon " 117 Buck Combined Cycle Plant Duke Energy Buck Station NPDES Wastewater Permit Renewal Application Attachment 5 Flow Diagram Wastewater Source Flows Combines cycle station NpOfSWartewater M. khe.atm O CombineE Cycle 1.10.58MGD/400gpm CooOng Tower:D it OM7 MGD/5gpm 0/W Separator 3.) 0.014 MGD/10 gpm Uigxgwasb 4.I 0.O71 MGD/18 gpm WRejM 5.10.63MGD/4339pm Wastewater5ump Buck Station NPDES Wastewater Permit Renewal Application Attachment 6 Narrative I. General Information The Buck Combustion Turbine Combined Cycle Station (CTCC) consists of one 2 x 1 configuration, 620-megawatt natural gas -fired combined cycle electric generating plant located in Rowan County approximately three miles east of Spencer, North Carolina. The CTCC property encompasses approximately 643 acres that border the southern shore of the Yadkin River in the upper reaches of High Rock Lake. The station is accessed from Buck Station Road off Long Ferry Road. The CTCC maintains an up-to-date Spill Prevention Control and Countermeasure (SPCC) Plan in place in accordance with the U.S. Environmental Protection Agency (USEPA) Oil Pollution Prevention Regulation 40 CFR Part 112. Also co -located on the CTCC site are the Buck Tie Station, the ash beneficiation facility and three ash basins, (the last remnants of the demolished steam station). Neither the tie station nor the ash beneficiation facility discharge wastewater. Coal ash beneficiation facility uses a process where ash is excavated from a basin and in essence re -burned to remove carbon to make the material suitable for reuse as a product in cement. The ash beneficiation system is a closed loop system and does not discharge. It does have an NPDES general stormwater permit, NCG130090. Three active ash settling basins (Cells 1, 2, and 3) located at CTCC (the new primary cell, the old primary cell, and the secondary cell) are generally east of the CTCC Power block. These three basins are interconnected and have a combined total natural drainage area of approximately 372 acres. These basins have been dewatered and ash from these basins is allowed to dry, then sent to the ash beneficiation facility for processing and after processing is taken offsite to either landfill or used for beneficial purpose. Stormwater that naturally drains to these basins is treated by a wastewater treatment system and is discharged to Outfall 007. II.OUTFALL 001A Combustion Turbine Combined Cycle Plant — Wastewater Sump The wastewater sump can either discharge to the wastewater holding basin, directly to outfall 001A, or recirculated back through the clarifier from the wastewater holding basin. The basin located east of the CTCC facility, is a lined basin approximately 4 acres, 6 feet deep, and a capacity of 10 million gallons. Process wastewater treated by the basin include all flows from the CTCC wastewater sump, as described below. Treatment options would include coagulants, flocculants, and pH control as needed to meet surface water quality standards. • Service Water Influent Make up water from the Yadkin River is sent through 3 raw water pumps to a Graver clarifier. pH is adjusted with caustic. Coagulant, polymer and sodium hypochlorite are also added. Sludge is removed via sludge pumps and sent through a thickener where more polymer is added. Ultimately, the sludge is sent to a plate and frame filter press for dewatering. Water from the clarifier is further treated by the gravity filters and sodium hypochlorite is added for biological control. The filtered water is stored in the Fire Water/Service Water Tank. This filtered water feeds the plant fire main and supplies the service water pumps. Every 3 to 5 years, the clarifier is drained,for maintenance. Flows from this activity are currently sent to the wastewater holding basin for treatment and discharge to the Yadkin River through Outfall 001A. • Boiler Make -Up Water / Condensate Boiler make up water is fed from the Fire/Service Water Tank (363,000 gallon tank) and sent through the Reverse Osmosis (RO) system to the demineralizer cells. An anti-scalant and pH control is added to the make-up boiler feedwater. The auxiliary boiler feed water is treated with ammonia and an oxygen scavenger. Sodium bisulfite is also injected to remove any residual chlorine at the RO inlet. Citric acid & sodium hypochlorite are used in the Ultra Filtration (UF) system for cleaning. Small volumes of wastewater from this process are currently sent to the wastewater holding basin and discharged to the Yadkin River through Outfall 001A. Citric acid is used in the reverse osmosis (RO) system to remove scale and mineral deposits. Anti-scalant is added to RO inlet to reduce scale formation. Small volumes of wastewater from this process are currently sent to the wastewater holding basin for treatment and discharged to the Yadkin River through Outfall 001A. Boiler water/condensate is further treated at the Heat Recovery Steam Generator (HRSG) with the addition of phosphates to protect from corrosion and ammonia for pH control. Waste streams from the water purification processes are directed to the Combined Cycle wastewater sump. • Condenser Cooling Water Condenser Cooling Water (CCW) is supplied through filtered water sent to the ten -cell cooling tower. This water is recirculated and cycled with approximately 5% make up added hourly to account for blowdown and evaporation loss. CCW water is treated with a dispersant corrosion inhibitor, sodium hypochlorite and a non -oxidizing biocide. Cooling tower blow down is treated with sodium bisulfite for residual chlorine removal prior to the water being sent to the waste water sump. Effluent from the wastewater sump is discharged to the wastewater holding basin and discharged to the Yadkin River. The CCW pumps circulate 94,000 gpm per pump. There are 2 CCW pumps installed on this system. The cooling tower blow down rate: averages 816 gpm. The maximum capacity of the cooling tower is approximately 197,500 ft3 or 1,477,620 gallons. At the normal water level, the capacity is 151,600 ft3 or 1,133,870 gallons. • Chiller Cooling Towers The eight inlet air chillers will have cooling water that is treated with a dispersant, corrosion inhibitor, sodium hypochlorite and a non -oxidizing biocide. Blow down water will be sent to the 2 chiller sumps. Ultimately the chiller tower blow -down water is pumped to the cooling tower basin. • HRSG, Boiler Cleaning and Auxiliary Boiler Blow Down All blow down from the HRSG drains, auxiliary boiler, demineralizer water treatment and the boiler blow down tank are routed to the boiler blow down sump. This sump discharges to the cooling tower basin. Boiler cleaning activities are envisioned to be necessary approximately once every 10 years. Boiler cleaning will involve the use of citric acid or a similar product. Waste from boiler cleaning activities will typically be collected and disposed of off -site. • Closed Loop Cooling System The closed loop cooling system blow down is also routed to the cooling tower basin. • Gas turbine wash water Approximately twice per year, turbine washes generated 8,000 gallons of wastewater. Online turbine washes are evaporated. Wastewater that is generated from washes that take place while the unit is offline are directed to the turbine wash water sump. Wash water is collected and either sent offsite for disposal or held in the wash water sump and slowly released to the Yadkin River while the unit is online to avoid any potential foaming. • Sanitary Waste System In September of 2017, the CTCC installed an onsite septic system and nitrification field permitted by Rowan County, to handle domestic waste replacing the old package plant. • Plant Drainage System All yard and floor drains from the generation equipment areas and auxiliary systems are routed to a common drain system and through an Oil Water Separator (OWS). The OWS discharges to the wastewater collection sump. Drains from the water treatment building area, fire protection system, condenser circulating system and cooling tower blow down are routed to a wastewater collection sump. This effluent is pumped to the Wastewater holding basin. Containments for all transformers, the ammonia tank and unloading area, are routed to the storm drain system. Drains from the cooling tower chemical feed sumps and unloading areas are also routed to the plant drain system. Table 1. BUCK CTCC Chemical and Tank Information Condensate/Feed water/Boiler Feed Rate HRSG11 Phosphate 300 gal tank 0 - 250 gpd HRSG12 Phosphate 300 gal tank 0 - 250 gpd Aqueous Ammonia 300 gal tote 0 — 25 gpd Auxiliary Boiler Aqueous Ammonia 330 gal tote 0 - 0.5 gpd Oxygen Scavenger 75 gal tote 0 - 0.5 gpd Cooling Tower/ Chiller A/B Dispersant/Corrosion Inhibitor 3DT487 2000 gal tank 0 - 50 gpd Sodium Hypochlorite 6000 gal tank 0 - 500 gpd Sodium Bisulfite 330 gal tote 0 - 3 gpd Corrosion Inhibitor 3DT-199 110 gal tote Closed Cooling Corrosion Inhibitor C-4710 22,000 gallon system pot feeder in loop —manual dosage as needed Glycol 22,000 gallon system pot feeder in loop —manual dosage as needed Filtered Water System Sodium Hypochlorite 6000 gal tank 0 - 576 gpd Clarifier and Thickener Polymer 400 gal tote 0 -108 gpd Coagulant 5000 gal tank 0 - 576 gpd Caustic 3000 gal tank daily feed as needed OF/RO/Demin Citric Acid 350 gal tote 0 - 48 gpd Sodium Hypochlorite 330 gal tote 0 - 48 gpd Anti-scalant PC-191T 110 gal tote 0 -16 gpd Caustic 330 gal tote 0 -16 gpd Sodium Bisulfite* 330 gal tote 0 -16 gpd *Chemical feed tote is shared with Cooling Tower SCR Aqueous Ammonia 20,000 gal tank III.Outfall 007 —Ash Basin The ash basin at CTCC accommodates storm water flows from rainfall run-off from the basin watershed area. The average rainfall run-off flows are based on 44 inches of rain per year with 100% run-off from the pond surfaces and 50% run-off from other areas. The average run-off for the ash basin watershed area is 0.299 MGD. 44 inches of rain per year with 50% run-off. Averaged over a typical year, the total storm water run-off that goes to the ash basin, is approximately 0.364 MGD. All stormwater from within the basin is routed to an Evoqua treatment system, which monitors the stormwater for pH and TSS prior to discharge from the outfall. The Evoqua water treatment system is located within basin 3 and provides pH adjustment to within 6-9 range for discharge, chemical additions of sodium hypochlorite, sodium bisulfate and ferric chloride to aid with mechanical filtration to remove algae. This is a decanting treatment system with water levels maintained to keep in decanted state. III. Outfall 111 and Outfall 117 Engineered Seeps The Buck Combined Cycle Station has 2 engineered seeps, associated with the ash basin. These are outfall 111 and 117 in the current NPDES permit. Outfall 111 does not have regular flow, and has not had flow in several years, Outfall 117 does have regular flow. Both outfalls would discharge overland prior to discharging to the Yadkin River. IV. Table 2c-3 Hazardous and Toxic Substances At Buck Combined Cycle, the potential for a toxic and/or hazardous substances being discharge is very low. In reference to Item V-D of Form 2-C, the substances identified under Table 2c-3 that may be in the ash basin discharge are as follows: • Cyclohexanone: Cyclohexanone is contained in thinners and solvents. The amount of cyclohexanone on -site in 2023 was less than 15 pounds. Therefore, any cyclohexanone in the ash basin would be at very low concentrations. • Xylene: Xylene is primarily at CTCC in gasoline and diesel fuel. Secondary containment systems are in place in order to prevent xylene from reaching the ash basin. If any xylene did reach the ash basin, it would be at very low concentrations. • Others: During the course of the year, products such as commercial cleaners and laboratory reagents may be purchased which contain very low levels of a substance found in Table 2c-3. Thus, any discharge of these products to the ash basin would be at very low concentrations. V. 40 CFR 117 and CERCLA Hazardous Substances The Hazardous Substance Table below identifies hazardous substances located on -site that may be released to the ash basin during a spill in quantities equal to or greater than the reportable quantity (RQ) levels as referenced in 40 CFR 117, 302 and 355. This list is being provided in order to qualify for the spill reportability exemption under 40 CFR 117 and the Comprehensive, Environmental, Response, Compensation and Liability Act. Hazardous Substance Table Substance Quantity (lbs.) Sodium Hypochlorite 499,300 Sodium Hypochlorite 499,300 Ferric Sulfate 499,200 Dispersant/Corrosion 21,600 Caustic 280,800 Ammonium Hydroxide 1,148,000 Source Sodium Hypo Tank (Cooling Tower) Sodium Hyp Tank (Clarifier) Ferric Sulfate Tank (Clarifier) Dispersant/Corrosion Tank (Cooling Tower) Caustic Storage Tank (Clarifier) Ammonium Hydroxide Tank Note: The dispersant/corrosion inhibitor is stored in a 2,000-gallon tank and includes 9.3% Phosphoric Acid, 18%Tagged High Stress Polymer, and 9% Phoshinosuccinic Oligomer. VI. Ash Basin Capacity No wastewater from the CTCC or the decommissioned Buck Steam station, including ash has been sent to the ash basin since 2019. The only input to the basin is stormwater that falls on it and runoff from the surrounding area. No calculation for capacity of the basin has been provided. VII. Buck Combined Cycle Station Balanced and Indigenous Population The BSS operating experience, under the thermal limitations imposed in NPDES Permit No. NC0004774 and field data collected (see attached report), substantiates the discharge from BSS is such that the protection and propagation of a balanced indigenous aquatic community in the Yadkin River is assured. However, Duke Energy Carolinas, LLC requests that the thermal variance for Outfall 001A, as allowed under NC Administrative Code 15A NCAC 02B .0208 (b) and also section 316 (a) of the Clean Water Act, be discontinued at this time. The Variance is no longer needed with the retirement of the Buck Steam Station. Duke Energy Carolinas, LLC also requests that the restriction under A (1) for Outfall 001, which limits stream flow usage, be eliminated. Duke Energy conducted a mixing zone study and submitted the report to the Division in April 2022. The report showed that a year-round temperature limit of 98' F was sufficient to protect the aquatic community as indicated by the attached 2022 Thermal Mixing Zone Modeling Report. Buck Station NPDES Wastewater Permit Renewal Application Attachment 7 Fish Tissue Sampling Report Fish Tissue Monitoring of the Yadkin River and High Rock Lake Near Buck Combined Cycle Station (2018-2022) Buck Combined Cycle Station Salisbury, North Carolina NPDES Permit # NC0004774 Duke Energy Water Resources Huntersville, NC 28078 January 2023 DUKE ENERGY Fish Tissue Monitoring of the Yadkin River and High Rock Lake Near Buck Combined Cycle Station (2018-2022) Buck Combined Cycle Station Contents 1 Introduction and Background......................................................................................................1 2 Methods.....................................................................................................................................1 2.1 Study Site...........................................................................................................................................1 2.2 Field Collection..................................................................................................................................2 2.3 Laboratory Analysis...........................................................................................................................3 3 Results and Discussion................................................................................................................3 3.1 Arsenic...............................................................................................................................................4 3.2 Selenium............................................................................................................................................4 3.3 Mercury .............................................................................................................................................4 4 Summary ....................................................................................................................................6 5 References.................................................................................................................................6 Tables Table 3-1. Numbers and total length ranges (mm) of different species of fish collected for element analyses in the three sampling areas of the Yadkin River and High Rock Lake during 2018-2022.3 Figures Figure 2-1. Sampling areas for monitoring trace elements in fish tissue within the Yadkin River and High RockLake..........................................................................................................................................2 Figure 3-1. Box plots of trace element analysis of fish muscle tissue for sunfish and black bass collected from three areas of the Yadkin River and High Rock Lake during 2018-2022. Boxes and whiskers show the 10th, 25th, 50th, 75th, and 90th percentiles. Individual outliers are represented by points. Values under each element are USEPA screening values for recreational anglers.............5 Appendices Appendix A Arsenic, selenium, and mercury concentrations (fresh weight) in axial muscle of fish from the Yadkin River and High Rock Lake during 2018-2022 Appendix B Arsenic, selenium, and mercury concentrations (fresh weight) in axial muscle of fish from the Yadkin River and High Rock Lake during 2014 Fish Tissue Monitoring of the Yadkin River and High Rock Lake Near Buck Combined Cycle Station (2018-2022) Buck Combined Cycle Station 1 Introduction and Background Duke Energy Carolinas (DEC) owns and operates the Buck Combined Cycle Station (Buck) located on the Yadkin River in Rowan County, Salisbury, North Carolina. The National Pollutant Discharge Elimination System (NPDES) Wastewater Permit for Buck (No. NC0004774, Section C.12) requires DEC to: "...conduct fish tissue monitoring annually and submit the results with the NPDES permit renewal application. The objective of this monitoring is to evaluate potential uptake of pollutants by fish tissue near the ash pond discharge. The parameters analyzed in fish tissue shall include arsenic, selenium, and mercury. The monitoring shall be conducted in accordance with the sampling plan approved by the Division." Monitoring is required due to the discharge of waters from a coal ash basin associated with the previous coal-fired steam plant at the site, and these three metals are commonly associated with coal ash and can have fish and human health impacts. A study plan was originally submitted to and approved by the North Carolina Department of Environmental Quality (NCDEQ) in 2013 (Duke Energy 2013), and an updated study plan was submitted and approved in 2019 (Duke Energy 2019). 2 Methods 2.1 Study Site Fish were collected from two areas on the Yadkin River and one in upper High Rock Lake (Figure 1-1) for trace element analysis of muscle tissue. Area UP was located at least 3.2 km upstream of the Buck ash basin discharge to serve as a reference to monitor background trace element concentrations in fish muscle tissue. Area DI was located between 0.8 km and 2.0 km downstream from the Buck ash basin discharge to monitor potential near -field uptake of trace elements in fish muscle tissue. Area DN was located in upper High Rock Lake, approximately 8.0 km downstream of the ash basin discharge, to monitor far -field uptake of trace elements in fish muscle tissue. Fish Tissue Monitoring of the Yadkin Rivera nd High Rock lake Near Buck Combined Cycle Station (2018-2022) Buck Combined Cycle Station AN uv BUCK OUIRLLI WI 19 COMBINED O ALL ON CYCLE $WnON Trace Element Fishing Area ♦ Duke Facility Outfall 0 2.5 5 Kilometers DN • Buds Com6lned Cycle Station DUKE ENERGY. Figure 2-1. Sampling areas for monitoring trace elements in fish tissue within the Yadkin River and High Rock Lake. 2.2 Field Collection Fish were collected for trace element tissue monitoring following the appropriate Duke Energy procedures under Duke Energy's North Carolina Biological Laboratory Certification (Huntersville, NC certification 008). Fish were collected using boat electrofishing, identified to species, measured for total length to the nearest millimeter, weighed to the nearest gram, and marked with a unique tag identifier. Fish were then placed in a labeled (sample date, sample location, facility, etc.) bag on ice while in the field. Bags were sealed and transferred to a deep freezer at the end of the sampling day until processed for analysis. Sunfish (Lepomis) and black bass (Micropterus) were targeted for collection based on prior sampling experience, likely availability, potential for human consumption, and general trophic level. Other similar genera of fish were collected when the primary target genera were unavailable. Duke Energy personnel collected six individuals of each taxa from each sampling area. Individuals retained for analysis were those considered of sufficient size for human consumption (z60 g). As recommended by the US Environmental Protection Agency (USEPA), fish were retained such that the size of the smallest Fish Tissue Monitoring of the Yadkin River and High Rock Lake Near Buck Combined Cycle Station (2018-2022) Buck Combined Cycle Station individual would not be less than 75% of the total length of the largest fish within each genus group when possible (USEPA 2000). 2.3 Laboratory Analysis Fish were processed for metals analysis at the Duke Energy Trace Element Laboratory located in New Hill, NC. Fish were thawed and skeletal muscle was fileted off using a carbon -steel scalpel. Muscle tissue from each individual fish was homogenized, weighed to the nearest 0.001 g, completely dried in a desiccator. The dried weight was recorded and used to calculate a dry weight to fresh weight ratio for that fish. Approximately 0.1 g of dried tissue was analyzed for each fish using X-ray fluorescence. Quality control was achieved utilizing analytical standards, replicates, and certified reference materials. 3 Results and Discussion During the study period (2018-2022), 180 individuals representing eight species were captured and analyzed from the Yadkin River and High Rock Lake (Table 3-1). These species included Alabama Bass Micropterus henshalli, Largemouth Bass M. salmoides, Black Crappie Pomoxis nigromoculatus, Bluegill Lepomis macrochirus, Green Sunfish L. cyanellus, Redbreast Sunfish L. auritus, Redear Sunfish L. microlophus, and Warmouth L. gulosus. A full list of individual fish and associated trace element concentrations is presented in Appendix A. Table 3-1. Numbers and total length ranges (mm) of different species of fish collected for element analyses in the three sampling areas of the Yadkin River and High Rock Lake during 2018-2022. UP DI DN Total Total length Total length Number Number Number length range range range Alabama Bass 2 293-410 — — Black bass Largemouth 26 276-499 30 247-515 30 288-471 (Micropterus) Bass Black Crappiel 2 272-278 — — Bluegill 22 140-178 20 142-176 28 146-183 Green Sunfish — 1 175 — Sunfish Redbreast (Lepomis) Sunfish — 1 177 1 171 Redear Sunfish 7 159-183 8 155-250 1 186 Warmouth 1 191 — — 1 Black Crappie were kept as a surrogate for black bass because these species are in the same feeding guild (NCDENR 2006). 3 Fish Tissue Monitoring of the Yadkin River and High Rock Lake Near Buck Combined Cycle Station (2018-2022) Buck Combined Cycle Station 3.1 Arsenic All fish collected during 2018-2022 were below the USEPA screening value for recreational anglers of 1.2 µg/g (fresh weight) for arsenic (USEPA 2000; Figure 3-1). 3.2 Selenium All fish collected during 2018-2022 were below USEPA screening value for recreational anglers of 20 µg/g (fresh weight) for selenium (USEPA 2000; Figure 3-1). 3.3 Mercury Sunfish collected during 2018-2022 were below the USEPA screening value for recreational anglers of 0.4 µg/g (fresh weight) for mercury (USEPA 2000; Figure 3-1). Of the 88 black bass sampled during the five-year study period, one exceeded the mercury screening value. Mercury concentrations generally increased with fish size, regardless of the collection area. This individual was in the top quartile of size for all black bass collected. Therefore, this elevated mercury concentration was a function of bioaccumulation. RECEIVED MAY 01 2023 NCDEQIDWRINPDES C! Fish Tissue Monitoring of the Yadkin River and High Rock take Near Buck Combined Cycle Station (2018-2022) Buck Combined Cycle Station Sunfish Black bass 1-0 1 0 0.6 0.6 04 0.2 0.0 V.J 0.4 0.3 02 0.1 0.0 0-6 0.6 04 0.2 00 UP DI DN UP DI DN 12 1a 08 O6 CA 02 00 UP DI DN UP DI DN Mercury 0.4 Vgr9 CA 03 • 02 • � 0.1 0-0 UP DI DN UP DI DN Figure 3-1. Box plots of trace element analysis of fish muscle tissue for sunfish and black bass collected from three areas of the Yadkin River and High Rock Lake during 2018-2022. Boxes and whiskers show the loth, 25th, 5Oth, 75th, and 9Oth percentiles. Individual outliers are represented by points. Values under each element are USEPA screening values for recreational anglers. 5 Fish Tissue Monitoring of the Yadkin River and High Rock Lake Near Buck Combined Cycle Station (2018-2022) Buck Combined Cycle Station 4 Summary All fish collected during the 2018-2021 study period were below the USEPA screening levels for recreational anglers for arsenic and selenium. One black bass exceeded the screening level for mercury. However, mercury concentrations in black bass collected at the DI area were not elevated compared to those collected upstream of the Buck ash basin discharge when accounting for size of fish. These patterns match samples reported from the same areas in 2014 (Appendix B; Duke Energy 2014). 5 References Duke Energy. 2013. Trace elements monitoring in fish tissue study plan. Duke Energy Corporation. Charlotte, NC. Duke Energy. 2014. Arsenic, selenium, and mercury monitoring in fish muscle tissue from upper,High Rock Lake, NC. Duke Energy Corporation. Charlotte, NC. Duke Energy. 2019. Fish tissue monitoring of the Yadkin River. Duke Energy Corporation. Charlotte, NC. NCDENR. 2006. Standard operating procedure. Biological monitoring. Stream fish community assessment program. Environmental Sciences Section, Division of Water Quality, North Carolina Department of Environmental and Natural Resources. Raleigh, NC. USEPA. 2000. Guidance for assessing chemical contaminant data for use in fish advisories. Vol. 1. Fish sampling and analysis. Third edition. EPA 823-B-00-007. United States Environmental Protection Agency, Office of Water, Washington, DC. Fish Tissue Monitoring of the Yadkin River and High Rock Lake Near Buck Combined Cycle Station (2018-2022) Buck Combined Cycle Station Appendix B Arsenic, selenium, and mercury concentrations (fresh weight) in axial muscle of fish from the Yadkin River and High Rock Lake during 2014 Dry -to - fresh Collection Length Weight As Se Hg weight Fish species Location month (mm) (g) W/O (µg/g) W/O ratio Largemouth Bass UP June 2014 380 984 <0.04 0.32 0.06 0.21 Largemouth Bass UP June 2014 367 805 <0.04 0.32 <0.06 0.21 Alabama Bass UP June 2014 359 604 <0.04 0.36 0.08 0.21 Alabama Bass UP June 2014 425 1431 <0.05 0.35 0.23 0.23 Largemouth Bass UP June 2014 448 1674 <0.04 0.27 <0.06 0.21 Largemouth Bass UP June 2014 468 1707 <0.04 0.31 0.08 0.20 Bluegill UP June 2014 175 122 <0.04 0.58 <0.06 0.21 Bluegill UP June 2014 166 101 <0.04 0.37 <0.05 0.18 Bluegill UP June 2014 167 97 <0.04 0.52 <0.05 0.19 Bluegill UP June 2014 168 97 <0.04 0.48 <0.05 0.20 Bluegill UP June 2014 156 92 <0.04 0.53 <0.05 0.20 Bluegill UP June 2014 159 97 0.04 0.38 <0.06 0.21 Largemouth Bass DI June 2014 454 1538 <0.04 0.41 <0.06 0.21 Largemouth Bass DI June 2014 454 1425 <0.04 0.33 0.08 0.20 Largemouth Bass DI June 2014 354 698 0.04 0.39 <0.06 0.22 Largemouth Bass DI June 2014 369 718 <0.04 0.26 <0.05 0.20 Largemouth Bass DI June 2014 355 634 <0.04 0.32 <0.06 0.21 Largemouth Bass DI June 2014 318 483 <0.04 0.40 <0.06 0.21 Bluegill DI June 2014 161 88 0.06 0.56 <0.05 0.19 Bluegill DI June 2014 172 119 0.06 0.64 <0.05 0.20 Bluegill DI June 2014 136 99 0.10 0.88 <0.05 0.20 Bluegill DI June 2014 158 85 <0.04 0.53 <0.05 0.19 Bluegill DI June 2014 162 91 <0.04 0.45 <0.05 0.20 Bluegill DI June 2014 162 89 0.04 0.42 <0.06 0.21 Largemouth Bass DN June 2014 402 1069 0.06 0.23 <0.06 0.21 Largemouth Bass DN June 2014 137 1292 <0.04 0.18 0.06 0.20 Largemouth Bass DN June 2014 352 643 0.04 0.23 <0.06 0.21 Largemouth Bass DN June 2014 416 1066 0.04 0.21 <0.06 0.21 Largemouth Bass DN June 2014 352 703 <0.04 0.21 <0.06 0.21 Largemouth Bass DN June 2014 322 452 0.06 0.23 <0.06 0.21 Bluegill DN June 2014 182 131 <0.04 0.31 <0.05 0.19 Bluegill DN June 2014 176 108 0.04 0.25 <0.05 0.19 Bluegill DN June 2014 164 84 <0.03 0.25 <0.05 0.17 Bluegill DN June 2014 160 78 0.10 0.23 <0.05 0.19 Bluegill DN June 2014 157 77 <0.04 0.29 <0.06 0.20 Bluegill DN June 2014 157 76 <0.04 0.21 <0.06 0.21 B-5 Buck Station NPDES Wastewater Permit Renewal Application Attachment 8 Instream Sampling Data 0o e�"s�eestia ��s=�"sw�ti"'espap"4p's"4p'eN"'ea osoo�e�oo o$ c S A A A n A A A n n A A n Y A n.A A A A A A A A A A n n n nn A n A A A A A A A n n A A 8 y � S n n r r n n r r n n r r n n r r n n r n n n n n n n n r n n r r n n r r n n r r n n r n A n r n n n n r AAA n n n r r n n r r n n r r n n r r n n r r n n r r n n r r n n n n n n n n n n n r n n r n n n r r Fg g F' v Sr n A A A A A A A A A A n A A Fg [y3 A A A A A A A A A A A A A A A A A A A A= A A A A A A A A A A A A A A A A A A A A A A A A A A n 8 m o m o p o 0 o m o p o e g AAAIA n A n n n A n n n n n n n n n n n n n n n n A n A n A A n n n n n n n n n Z 8 �l p p o o p r o r r e o r r m r i- r r n n .- n r r r r r r r r n n n n r r r r r r r r m r r p o S g 3 S r A A A A A A A n A n A A A A A A A A A A C A A n n n N n n n n n n n A An A n n A n A A n N n n " n n n A n n n A n A n n A n n A Ag 8 A A A N A N N g N A A A AN A A A A A A A A A A YA A A& A A Aw n A A A a A A A A A A A A r r 8 �V pq0 n n n n N "" n � n V n n n N n n n n 2r £ m c AA�'✓�"m r&n n A�A J'�rEmn nn n$N AnAYng �$ Y y n g A A A$$ w A A e A n :' " A A A A A A A A A :' A N n n Y .rR Y R A R 3 g an a x tl a W gAg3 3 € r " n A n A A AN p A A A A A AA' n n a dim c 8 A A A A A P e gi: A P A A wppu A A �. �ie.� A A A A A A A A A A w O A S O A .Pw A A O A G".e, A A A A A A u A w A A A A A A A A A A mom A A r�io„40.'AO 3 ' 8 AAA n o p n o 4,Ael n n A e o- n A n o n n n o n n A A e n n aL,Ao n n n A n A n A o n n n o000oe n n n n n n O n wyo n n a o e e v d. V �,� o poN �oo,^.oe N�,Aa i N �o W r pycc�8 n o A A w n n o A n A n n n n Z m i §§;;;;;;•;;••;;§;!;§ (§ /\§ ;;§;;;§;;§;;;;;.;;�;;a;;I®;;§E;;§;;;§;;;;;;;;§ |°! \§ §;;;;;;;;;;•;§;;;§;!];;A- V . .,�����,��������,��.�,����a���: ;. : ;; z ________________ 6§ __ 1=====____________________________ `__;....V,.,.��.. �..... .....,. §:! / __ !| / .. _:__;;____:___ \ ! IV IV IV IV IV IV IV IV IV IV IV IV IV - }§ _;IV I I I I I I V 7 V I z V v §§ ;,!„ r;!! „ r<;,�!#;■ !§ .....�. .........�� ||| !. Ilza /!! !!!!f!!!2-2!!!!m!,!•®;®;lm, ■,«!!m!m! !\\mmm!■!m...c6 !§§■|;;■44■9 „!!B;■!B!)\!!!B!B§!§!§!§■§BBmmBa;BB■. f* §§§§)§{(/|(|§(\(§§(\)()\[(§\§t)§)t(\)t§§\tt __.. �.�.m22;�,���:_=,.,�5.�.;,,,:T_ „ !�■.,.;,�,,0to |) , RR,_:. 4..��1===.��.,.�..�l��:=�.,,;�;_,=.zils.:.R:! |°§ .,-=.;E;.,:t:9�-:.-: )§ |! ,. |®/ t 2!!!E!,l��r•!l=�E!`� j/ -tt_it- - - - - - -