NCS000057_Renewal Application_20161031

g'�mC 11) lnll4
October 27, 2016
Mr. Bradley Bennett
Supervisor Stormwater Permitting Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Subject: NPDES Stormwater Permit Coverage Renewal
Chemical Specialties, Inc
Permit Number: NCS000057
Dear Mr. Bennett:
Chemical Specialties, Inc. (CSI) is submitting the attached supplemental information for renewal of an
individual National Pollutant Discharge Elimination System (NPDES) stormwater permit. Included in this
package are two copies of the following:
Site maps: SP-000-01, Drain 2008, Drain 2008-2
Summary of Analytical Monitoring results
Summary of Visual Monitoring results
Summary of Best Managment Practices
• Signifiant changes in industrial activities
• Certification of the development and implementation of a Stormwater Pollution Prevention Plan
Along with this permit renewal package, CSI respectfully requests a reevaluation of the current
benchmark values for copper and zinc. An extensive effort has been made to reduce the discharge
values of these two parameters. CSI has implemented both physical Best Management Practices (BMPs)
and procedural BMPs, however, sample results remain variable for both. Due to the large quantity of
galvanized roofing and chain link fence, as well as tire dust from fork trucks and tanker trailers, zinc is
ubiquitously present throughout our facility. Based on historical empirical data, the implementation of
various BMPs during the previous nine year period did not correlate to any decreases in the discharge
values for copper or zinc. CSI's stormwater discharges are into the Rocky River in the Yadkin-PeeDee
river basin via Outfall #1 and Outfall #2.
PO Box 1330 • 5910 Pharr Mill Road • Harrisburg, NC 28075. 704-455-5181
Main Fax [phone] • Purchasing and Transportation Fax [phone]
Lab Fax [phone] • Accounting and PoleCare Fax [phone]
Engineering Fax [phone]

Currently, there are not any established TDMI.s for copper and zinc in this part of the Yadkin-PeeDee
river basin. The Rocky River (stream index 13-17) is designated a Class C waterway. Previous water
samples collected by CSI from the Rocky River indicate higher values for copper and zinc upstream of
our facility than downstream. In efforts to achieve continuous compliance with our stormwater
discharge permit and to prevent any quantitative water quality exceedances, CSI would like to request
an increase of the copper benchmark value to 150 micrograms per liter and 300 micrograms per liter for
zinc.
If you have any questions or need additional information, please contact me at [phone].
Sincerely,
Jeffrey Bruening
EHS Manager

Supplemental Information
Chemical Specialties Inc
NCS000057
Supplemental Information Item No. 4
Best Management Practices Utilized at the Facility
Because CSI is a chemical manufacturer, most of the facility Best Management Practices (BMP)
revolve around the concept of minimizing chemical contact with stormwater. In that effort, the
CSI facility uses the following BMPs:
• Indoor storage of product and raw materials where practical.
• Redundant tank level indication.
• Indoor & outdoor tank storage has secondary containment.
• Inorganic secondary containment stormwater goes to WWT system.
• Wood preservative secondary containment stormwater is collected and returned to the
operating process.
• Preventative maintenance to minimize leaks and drippages from the piping systems.
• Tanker, railcar and hose inspection program.
• Full tanker parking area drains to a lined spill lagoon which is part of the WWT system.
• Concrete paved driveways sloped to catch basins which are piped to lined spill lagoon
which is part of WWT system.
• Series of stormwater system drains to minimize erosion.
• Series of stormwater gate valves to divert stormwater from river in the event of a spill.
• Curbing and riprap to minimize impact of sheet flow.
• Railside track pans.
• No on -site maintenance of trucks or vehicles.
• Curbing along the south side of driveway to contain potential tanker leaks/spills.
• Nonhaz waste minimization program decreased waste generation from 48 tons to 12
tons/year due to recycling effort and less waste such as raw material product storage
bags was placed in dumpsters.
• Oil water separators to collect oil from air compressors to eliminate possible oil
contamination to stormwater.
• Written operating procedures and operator training.
• Spill kits with drain blankets.
• Semi-annual inspection of secondary containments and stormwater collection drains and
production areas.
• Annual employee stromwater training.
• Copper handling and management program.
Please find attached a table indicating materials manufactured, handled or stored and the
associated BMP for each specific product. This table is intended to comply Item # 4 on the
Supplemental Information Checklist.

Supplemental Information
Chemical Specialties Inc
NCS000057
Supplemental Information Item No. 5
Changes in Industrial Activity
In order to minimize stormwater exposure to copper, CSI is now receiving approximately 80
percent of our copper in "chopped" form and transported in super sacks. CSI believes the
implementation of this Best Management Practice (BMP) will significantly reduce stormwater
copper exposure. CSI continues to be a chemical manufacturer that produces inorganic
products for industrial and agricultural applications and wood preservatives.
Inorganics include metal nitrates such as calcium, magnesium, aluminum, manganese, copper,
lithium and zinc. Metal chlorides including aluminum, magnesium, zinc and manganese are also
produced. Other products produced by the inorganic branch of the business also include metal
acetates, such as magnesium, lithium and zinc. While product mix does vary, the product
offering in this product line has remained relatively constant since the last permit issuance.
Organic biodegradables manufactured include organic biocide, alkaline copper quaternary
(ACQ), chromated copper arsenate (CCA), DBlaze fire retardant (phosphor -ammonium boron
compound) and water repellants (wax based products). While these products have been
manufactured or handled at the facility for many years the wood preservative industry has
transitioned from metal based chemistries to organic based chemistries based on biodegradable
biocides called ITAs or chloroisothiazolinones. Hence the volumes of CCA and arsenic acid are
minimal with the launch of the new organic products. The production of these organic based
products includes the storage and handling of new organic chemicals including; castor oil and
derivatives, emulsifiers and the organic pesticides Imidicloprid and Tebuconazole.
CSI has discontinued handling the following organic based products since issuance of the
previous Stormwater permit: Dowanol, Tergitol andTexanol.
N

Supplemental Information Required for a Renewal of Individual Stormwater Permit
BMP Summary
Chemical Specialties Inc.
NCS000057
Material
Storage Location
Usage
Qty Stored
BMPs Utilized
Arsenic trioxide bags
Indoor
Waste
Bags washed 3 times.
Material stored indoors.
Stored outside and under roof.
Equip. is deconed prior to
Abandoned equipment
Used equipment/Bone yard
NA
Varies
storage. New storage shed in
bone yard (2009) to minimize
contact with rain and major
equipment cleanup.
Stored outside in tanks w/
secondary containment.
Acetic Acid
Indoor &outdoor tanks
Raw Material
40,000 Ibs
Stormwater back to process.
Containment repairs made in
October of 2010 during scrubber
installation.
Main production areas/storage
ACQ
under roof with secondary
Tank farm that is under roof
Product
<500,000 Ibs
containment. High volume of
tankers transported across site.
Stormwater back to process.
Ammonia 19%
Raw
Tanks have secondary
(ammonium hydroxide)
Outside tank storage
Material
90,000 Ibs
containment. Stormwater back to
process.

Material
Storage Location
Usage
Qty Stored
BMPs Utilized
Stored inside in drums, used
Antifoam (silicone)
Indoor & minimal outdoor
Raw
Material
<100,000 Ibs
outside in areas w/secondary
containment.Small vol.
transferred.
Arsenic acid
Indoor &outdoor (some process
Product
<1,000,000
Stored outside in tanks under roof w/seconds containment.
tanks not under roof)
Ibs
All stormwater back to process.
Stored outside in silos within
Arsenic Trioxide
Indoor & Outdoor
Raw
<1,000,000
containment. Bags stored
Material
Ibs
indoors. All stormwater back to
process.
Boric acid
Indoor & outdoor
Raw
Stored inside. Only in small
Material
70,000 Ibs
volumes outside.
Stored outside in tanks but
Carbon Dioxide
Raw maVI/indoor & outdoor
Raw
60,000 Ibs
becomes gas at ambient temp
Material
and pressure
Stored outside in new tank
CCA
<1,000,000
w/containment and level
(60%)
Indoor &outdoor
Product
Ibs
indication. All stormwater back to
process.
Chromic acid
Indoor
Raw
< 500,000 Ibs
Stored inside in drums
Material
Copper Ammonium
Stored outside in tanks w/
Carbonate (Compsol)
Outdoor
Product
575,000 Ibs
secondary containment. All

Material
Storage Location
Usage
Qty Stored
BMPs Utilized
Stored outside in tanks
Copper Count N
Indoor & outdoor
Product
<99,000 lbs
w/secondary containment. Small
(Copper Ammonium
consumer commodities stored
Acetate)
inside. All SW back to process.
Copper metal
Indoor
Raw
Material
120,000 lbs
Stored indoors at all times.
Rinse filters prior to disposal to
minimize chemical content. Use
hard topped covered roll -offs to
Copper wastes
Indoor & outdoor
Waste
30,000 lbs.
minimize contact with rain. Only
empty totes are stored outdoors.
Routine inspection by
operations.
D-blaze
Stored outside in tanks w/
Outdoor
Product
100,000 lbs
secondary containment.
Stormwater back to process.
Filter media
(diatomaceous earth,
Indoor & minimal outside (spill kits)
Raw
60,000 lbs
Stored indoors. Spill kits covered
clay)
Material
w/plastic
Fuel Oil
<10,000 gal
Stored outside in double wall
LLoil
Outdoor
tank.

Material
Storage Location
Usage
Oty Stored
BMPs Utilized
Stored outside in silos. Hydrated.
Hydrated lime &
Outdoor & minimal indoor storage
Raw
350,000 Ibs
Hydrated lime area drains to
Calcium Hydroxide solid
of bags
Material
WWT Unloading procedure in
place
Stored outside in tanks
Hydrochloric Acid
Outdoor
Raw
300,000 Ibs
w/secondary containment
Material
structure. All captured SW to
VWNT.
Hydrogen Peroxide
Outside
Raw
Material
<100,000 Ibs
Tank has secondary
containment.
Imidacloprid &
Tebuconazole
Indoor
Raw
Material
50,000 Ibs
Stored indoors.
Raw
Tank has secondary
Magnesium Hydroxide
Outdoor
Material
850,000 Ibs
containment. Stormwater to
VWIIT.
Reactors controlled with weigh
Metal Acetates (Mg, Li
cells and PLC. Outside area
& Zn)
Indoor & outdoor
Product
180,000 Ibs,
sloped to drains. All stormwater
drains to WWT system. Totes
stored indoors. Operator
training.
Metal Carbonates (Cu,
Li, Mn, Na)
Indoor
Raw
material
<100,000 Ibs
Stored inside in containers.

Material
Storage Location
Usage
Qty Stored
BMPs Utilized
Reactors controlled with weigh
cells and PLC. Outside area
Metal Chlorides (Al, Mg,
Zn, & Mn)
Indoor &outdoor
Product
900,000 Ibs
sloped to drains All stormwater
drains to WWT system. Totes
stored indoors. Operator
training.
Reactors controlled with weigh
cells and PLC. Outside area
Metal Nitrates (Ca, Mg,
Al, Mn, Cu, Li, & Zn)
Indoor &outdoor
Product
1,670,000 Ibs
sloped to drains All stormwater
drains to WWT system. Totes
stored indoors. Operator
training. Secondary
containment for tanks.
Containers stored inside. Zinc
Metal Oxides (Cu, Al,
Raw
1,060,000 Ibs
oxide empty raw material bags
Mg, & Zn)
Indoor
Material
are placed in plastic bags prior
to disposal in com acter.
Stored in tank farm under roof
Monoethanol-amine
Indoor & outdoor
Raw
<1000000 lbs
with secondary containment.
Material
Collected water goes back to
process.
Raw
Tank has level indicator and
Nitric Acid
Indoor &outdoor
Material
500,000 Ibs
secondary containment.
Stormwater goes to WWT.
Bulk storage tanks under roof
Raw
with secondary containment.
Oils and waxes (linseed,
Indoor and outdoor
Material
<100,000 Ibs
Most production indoors. Some
mw 2, castor, pine)
&
containers stored inside but used
Products
outside in areas with secondary
containment.
Oxygen
outdoor
Raw
65,000 Ibs
Stored outside in tank but
Material
becomes gas at ambient temp.

Material
Storage Location
Usage
Qty Stored
BMPs Utilized
Raw
Stored outside in tank with
Phosphoric Acid
outdoor
Material
80,000 Ibs
secondary containment.
Stormwater goes to WWT.
Raw
Outside storage is in tank farm
Quaternary Ammonium
Material
that is under roof with secondary
Compounds (Q-50C, Q-
Indoor and Outdoor
<1000,000 Ibs
containment. Collected water
5097, CTAC)
Product
goes back to process. Smaller
containers stored indoors.
Sodium Hydroxide
Outdoor
Raw
Material
<100,000 Ibs
Stored outside in tanks, all
stormwater goes to WWT
system.
(Isothiazolinones or
Raw
Bulk storage in indoor tanks
ITAs)
Material
<500,000 Ibs
w/containment. Process area
Indoor
& Prod.
indoors.
Timber rubbish & debris
(PPE & misc. debris)
Waste material/indoor
Waste
24,000 Ibs.
Stored indoor in containers.
Timbersaver
Indoor
Product
<100,000 Ibs
Stored inside
Bulk transfers have ceased.
Ultrawood
Indoor & outdoor
Product
<100,000 Ibs
Product is only transferred to
totes indoors.
Most pallets on recycle trailer.
Some stored outside. Prod.
Wood pallets
Recycled indoor (trailer) & outdoor
Waste
Multiple
contamination minimal. Pallets
decon'd prior to recycling.

J.
STORMWATER' POLLUTION PREVENTION PLAN
DEVELOPMENT AND IMPLEMENTATION
CERTIFICATION
North Carolina Division of Energy, Mineral, and Land Resources — Stormwater Permitting
Facility Name:
Chemical Specialties Incorporated
Permit Number: NCS000057
Location Address: 5910 Pharr Mill Rd
Harrisburg, NC 28075
County:
Cabarrus
"I certify, under penalty of law, that the Stormwater Pollution Prevention Plan (SPPP) document and all attachments were
developed and implemented under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gather and evaluate the information required by the SPPP. Based on my inquiry of the
person or persons who manage the system, or those persons directly responsible for gathering the information, the
information gathered is, to the best of my knowledge and belief, true, accurate and complete."
And
"I certify that the SPPP has been developed, signed and retained at the named facility location, and the SPPP has been
fully implemented at this facility location in accordance with the terms and conditions of the Stormwater discharge
permit."
And
"I am aware that there are significant penalties for falsifying information, including the possibility of fines and
imprisonment for knowing violations."
Sign (according to permit signatory requirements) and return this Certification. DO NOT
SEND STORMWATER POLLUTION PREVENTION PLAN WITH THIS CERTIFICATION.
Signature
Shawn Turner
Print or type name of person signing above
Date k-7 (o
Site Manager
Title
SPPP Certification 10/13

1 2 3 4 5 6 7 8 9 1 11 1 13 14. 15 16 17
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18" DRAIN TO 16 20'X12" TRACK PANS TO DRAIN % UNDER TRACK TO 10
NORTH _ U_ �- INTO TANK FARM CONTAINMENT
NEW 24"X36" CATCH BASIN W/T.F. ROOF DRAINS
NEW 12" RCP TO
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BLD BLDG COP O O -189 �1 NIS----------------
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STORMWATER DRAIN TO 20
YELLOW HANDLE - SCREW CLOCKWISE
TO PLUG TEE INTO STORM DRAIN LINE
FRENCH DRAIN -"- FRENCH DRAIN
( OVERFLOW LINES
TO LINED LAGOON
FROM C.B. #11
TO STORM WATER.
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LINES TO WASTE WATER TREA MENT
SPILL SUPPLIES LISTING
A OVEGROUND STORMWATER DRAINS
ROOF DRAINS)
LOCATION
USW UNDERGROUND STORMWATER TO WWT VIA LINED LAGOON
A. MAIN DOCK BLDG. 14 - (ONE DRUM WITH PADS AND ABSORBENT PIGS)
B. NORTH END S-8 BLDG 1 (TWWO DRUMS WITH ABSORBENT PADS AND PIGS)
---- STORM WATER LINES TO RIVER
C. SPILL SUPPLIES BLDG. #17 (ABSORBANT CLAY,
REDUCING AGENTS,NEUTRALIZING CHEMS,
SHOVELS AND SQUEEGEES)
D. SPILL KIT #3 DRIVEWAY (ONE DRUM WITH CLAY
ABSORBENT PADS AND PIGS)
�-- UNDERGROUND STORMWATER
E. #4 WAREHOUSE BLDG. 230 (CLAY ABSORBENT
, PADS, PIGS)
LINE W/CATCH BASIN
F. TEXTILE PLANT BLDG. 42 (ONE DRUM WITH A DRAIN
BLANKET AND PALLET OF ABSORBENT)
G. ACQ TANK R AND A
ABSORBENT)
� � BACK TO PROCESS
BACK
NTAINENCESHOPHOVELS
H. MAIBLDG 4 (ONE DRUMTWIOTH
ADS)
SW TRENCH
SWAIL DITCH TO RIVER
CATCH BAD IN LISTING
LOCATION
1. BACK ROAD SOUTHWEST OF LIME PIT
2. BACK 0 - S-8 BY BLOWER SHED
3. NORTH OF S-8 AT LOADING DOCK
4. ACROSS DRIVE NORTH OF S-8
5. S-8 BE"WEEN ADMIN. BLDG. © S-8
6. ADMIN FARKING NEAR S-8
7. PARKINC LOT IN ADMIN BUILDING #2 SOUTH OF S-8
_x-x-x-x----x-x ,�-w--,`
8. MANAGERS TRAILER UNDER STAIRS
-1
9. TRASH COMPACTOR AT S-8
+�
10. PARKIN] LOT OF ADMIN BUILDING #2 SOUTH OF S-8
+�
11. SIDEWALK NEAR HANDICAPPED PARKING AT SIDE OF ADMIN.
12. SOUTH OF LIME SILOS BETWEEN RR TRACKS AND BACK ROAD.
T.-40P NI ✓ T-4� T-S .,�'� 13. MAIN DOCK AT PALLET TRAILER
+\ x/ /X�
14. MAIN DOCK STAIRS
*� 15. LIME SI.URRY PIT
x-w-
1 16. MGoH • ANK SUMP AND COVERED SUMP
lax -'max- 17. #2 DRI' /EWAY TWO SUMPS
!
2 18. 198 MCC ROOM
2 AC-21 19. BEHIND ACQ PLANT
20. RIVER )RAIN AT TEXTILE PLANT
21. 198 GFAVITY TANK COVERED
O 22. OXYGEII TANK AT 198 PLANT
awl 23. PETTIB )NE PARKING
°-' 24. SIDE E JRANCE #4 WAREHOUSE
O 25. SMALL DRAIN END OF #2 DRIVEWAY
26. MAIN f RVEWAY SCALE TRENCH DRAl 1
5 WASTE WA _ER SUMPS
_ WW1. RAIL`.IDE COLLECTION SUMP.
WW2. BETV EEN T-95 & T-50 (HYDROXIDE SUMP)
WW3. S.S. SUMP AT DRIVE #2
1
WW4. BOILER ROOM SUMP
WW5. LAB BASEMENT ROOM SUMP
BLDG 7
30
IA
I
C
H
\ SPILL KITS TO WASTE WATER TREATMENT
PLANT
8 �.\ LOADIZ AREA
� LOADING DOCK TC STORMWATER n
_0
BLDG 4
I
IEo
u A I N T E N A N CE
BUILDING
BLDG 101
ENGINEERING
EtISTING BUILDING
66'x28'
Ka
m 'RR
TO LINED LAGOON /
WRGE KSY SW -OFF VALVE
4" CPVC
PRE -CAST CONCRETE SUMP
NOTES:
1.) 198 COOLING TOWER BLOWDOWN IS
PIPED TO WASTE WATER LINE. FROSTORM DRAIN
M LOADING DOCK
2.) 1 1 /2" HOSE CONNECTIONS TO PUMP PIT WATER TO T-34. 12' RCP
TO EITHER STORM OR WASTE W/ TER SYSTEMS.
(SEE DETAIL #3)
_DETAIL #1
-° ROOM SUMP DETAIL
O; O O O O OO /CIj�F 1;IFtgfl
3 14 15 16 17 18 19 0 21 22
16\ T�\ 18\ 19 \20\ 21 \22 \23 \24 \25 \/16 \27 \28 \29 \30
1 \2 �3 T4 T5 \6 \7 �8 �9 �10�11 \12 \1�
EXISTING GRAVEL ROAD
DRAWING UPDATES
DRAWING UPDATES
REV PER 2007 SITE SURVEY
AS -BUILT PER 2006
4 REVISED SPILL KIT LOCATIONS
SITEPLAN 2004 UPDATE
SITEPLAN 2002 UPDATE
1 AS PER COMMENTS (D.C.)
PRELIMINARY
N0. REVISIONS
I
IN
I
10
CHEMICAL SPECIALITIES, INC.J8/05/11 WLM R
03/19/10 TBC is =PAS' HARRISBURG) NORTH CAROLINA
/14/08 ATJ JS (r Da..
9/19/06 DSW JS CSI MASTER SITE PLAN
6/23/05 DSW TR ROOF DRAINAGE, WASTE WATER S
/13/04 DSW TR
0/23/02 DSW HH 8r UNDERGROUND STORM WATER
11 /17/00 DSW H H MRD CAD NO. SCALE DATE
11 1"=50' 1/01/95
5/9/00 DSW PFZ
PROJECT NO. DRAWING NUMBER REV.
DATE BY CKD. S-1 TE. DRAIN-2008 8 T

1 21 31 41 51 6
9
10
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CHERCAL SPEDAUTES, W.
CSI HARRISBURG, NORTH CAROLINA
CHEMICAL SPECIALTIES, INC. S
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A PRELIMINARY 05/03/2012 WLM 12
PROJECT NO. DRAWNG NUMBER REV.
N0. REVISIONS DATE BY CKD. 3000 S P- 0 0 0— 0 01 P L A N O T
CAD FILE: VAULT/DRAWING /HARRISBURG/3000 MAIN SITE PLAN/SP-000-GO1-PLANT

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AS DRAWN 03/19/10 TBC JS C'S' HARRISBURG2 NORTH CAROLINA R
/6\ CONTINGENCY PLAN REVISIONS 08/14/09 TBC JS
AS —BUILT PER 2006 09/19/06 DSW JS CSI MASTER SITE PLAN
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/6\ 5/9/00 DSW I-DFZ I
PROJECT No. DRAWING NUMBER REV
N 0. 1 REVISIONS DATE BY CKD. S 1 TE DRAIN - 2 0 0 8- 2 9 T