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HomeMy WebLinkAboutNC0004987_Worksheets - Outfall 005_20220514 (2)Dissolved Metals & Hardness Determination v. 5/27/2010 I. How to Determine Hardness for use with Dissolved Freshwater Standards for Permitting Purposes HARDNESS - Use 25 mg/L, expressed as CaCO3 or Ca+Mg, as the default Hardness OR To determine a Hardness value for permit limit development, use the following equation: Hardness (Hardness instream(a), mg/L * 7Q10, MGD)+(Hardness effluent(b), mg/L* Plant flow, MGD) (mass balance) (7Q10, MGD + Plant flow, MGD) (a) Use the median instream Hardness value of the ambient 8-digit HUC data collected by the Division of Water Quality. To find the 8-digit HUC hardness value for your facility Click Here. (b) For the purpose of this estimation, use the facility's median effluent Hardness value, if available. The Division will request the permittee to sample effluent hardness once/month and submit one to two years of data with the permit renewal application. If no effluent hardness data is submitted, a default of 25 mg/L will be applied. II. To Develop Dissolved Metal concentrations for permitting purposes use the Freshwater Standards for Hardness Dependent Metals listed in Table A below. Table A: Dissolved Freshwater Standards for Hardness Dependent Metals Metal pg/L Cadmium, Acute {1.136672-[In hardness](0.041838)} • e^{0.9151 [In hardness]-3.1485} Cadmium, Acute (Trout Waters) {1.136672-[In hardness](0.041838)} • e^{0.9151[In hardness]-3.6236} Cadmium, Chronic {1.101672-[In hardness](0.041838)} • e^{0.7998[In hardness]-4.4451} Chromium III, Acute 0.316 • e^{0.8190[In hardness]+3.7256} Chromium III, Chronic 0.860 • e^{0.8190[In hardness]+0.6848} Copper, Acute 0.960 • e^{0.9422[In hardness]-1.700} Copper, Chronic 0.960 • e^{0.8545[In hardness]-1.702} Lead, Acute {1.46203-[In hardness](0.145712)} • e^{1.273[In hardness]-1.460} Lead, Chronic {1.46203-[In hardness](0.145712)} • e^{1.273[In hardness]-4.705} Nickel, Acute 0.998 • e^{0.8460[In hardness]+2.255} Nickel, Chronic 0.997 • e^{0.8460[In hardness]+0.0584} Silver, Acute 0.85 • e^{1.72[In hardness]-6.59} Silver, Chronic Not applicable Zinc, Acute 0.978 • e^{0.8473[In hardness]+0.884} Zinc, Chronic 0.986 • e^{0.8473[In hardness]+0.884} Complete information on all the proposed Surface Water Quality Standards can be viewed at: http://h2o.enr.state.nc.us/csu/trirev SW.html. US EPA Translators using Default Partition Coefficients (DPC) Translator equation using Default Partition Coefficients = 1 v. 6/2/2010 [1 + (Kpo * TSS (l+a) * 10-6)1 Kpo and a are constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A default value of 10 mg/L Total Suspended Solids (TSS) will be used. Table A contains the Default Partition Coefficients for the equation. Table B contains the calculated translators using the default partition coefficients for streams. TABLE A. Default Partition Coefficients STREAMS Metal (1) Kpo a Cu 1.04E+06 -0.7436 Zn 1.25E+06 -0.7038 Pb 2.80E+06 -0.8 Cr (III) (2) 3.36E+06 -0.09304 Cd 4.00E+06 -1.1307 Ni 4.90E+05 -0.5719 (1) Delos, C.G., et al. Technical Guidance for Performing Waste Load Allocations. Book II: Streams and Rivers. Chapter 3: Toxic Substances, For the U.S. EPA. (EPA-440/4-84-022) (2) Linear partition coefficients shall not apply to the Chromium VI numerical criterion. The approved analytical method for Chromium VI measures only the dissolved form. Therefore, TABLE B. US EPA Translators PARAMETER US EPA Translators Using stream Default Partition Coefficients TSS = 10 mg/L Cadmium 0.252 Chromium III 0.202 Chromium VI 1 Chromium, Total N/A Copper 0.348 Lead 0.184 Nickel 0.432 Silver 1 Zinc 0.288 Example for Cadmium (streams) Given: TSS = 10 mg/L Kpo = 4.00E + 06 a =-1.1307 Translator = 1 [1 + (Kpo * TSS (1-')* 10 6)] [1 + (4.00x106 * 101-1.1307) * 10-6)] [1+2.960465] = 0.252 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 1. Project Information ❑ CHECK IF HQW OR ORW WQS Facility Name WWTP/WTP Class NPDES Permit Outfall Flow, Qw (MGD) Receiving Stream Marshall Steam Station C I NC0004987 Outfall 005 5.100 Lake Norman 8 Digit HUC Number 03010103 Stream Class WS-IV 0 Apply WS Hardness WQC 7Q10s (cfs) 7Q1Ow (cfs) 30Q2 (cfs) QA (cfs) 1 Q10s (cfs) 60.00 60.00 60.00 C 60.00 I I 49.15 Effluent Hardness (Median) HUC Hardness (Median) Combined Hardness Chronic Combined Hardness Acute 25 mg/L default 25 mg/L (HUC Hard Med = 21.5 mg/L) 25 mg/L 25 mg/L Data Source(s) Renewal Application and DMRs CHECK TO APPLY MODEL CHECK WQS Table 2. Parameters of Concern Par01 Par02 Par03 Par04 Par05 Par06 Par07 Par08 Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Par18 Par19 Par20 Par21 Par22 Par23 Par24 Name WQS Type Chronic Modifier Acute PQL Units Arsenic Aquactic Life C 150 FW 340 ug/L Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L Beryllium Aquatic Life NC 6.5 FW 65 ug/L Cadmium Aquatic Life NC 0.5899 FW 3.2396 ug/L Chlorides (AL) Aquatic Life NC 230 FW Chlorinated Phenolic Compounds Water Supply NC 1 A ug/L yTotal Phenolic Compounds Aquatic Life NC 300 A ug/L Chromium III Aquatic Life NC 117.7325 FW 905.0818 ug/L Chromium VI Aquatic Life NC 11 FW 16 pg/L Chromium, Total Aquatic Life NC N/A FW N/A pg/L Copper (AL) Aquatic Life NC 7.8806 FW 10.4720 ug/L Cyanide Aquatic Life NC 5 FW 22 10 ug/L Fluoride Aquatic Life NC 1,800 FW ug/L Lead Aquatic Life NC 2.9416 FW 75.4871 ug/L Mercury Aquatic Life NC 12 FW 0.5 ng/L Molybdenum Human Health NC 2000 HH ug/L Nickel Aquatic Life NC 37.2313 FW 335.2087 pg/L Nickel Water Supply NC 25.0000 WS N/A pg/L Selenium Aquatic Life NC 5 FW 56 ug/L Silver (AL) Aquatic Life NC 0.06 FW 0.2964 ug/L Zinc (AL) Aquatic Life NC 126.7335 FW 125.7052 ug/L Aluminum Water Supply NC 6500 WS pg/L Boron Water Supply NC 7 WS mg/L Sulfate Water Supply NC 250 WS mg/L NC0004987_Worksheets_20220414 (3).xlsm, input 4/18/2022 REASONABLE POTENTIAL ANALYSIS H Effluent Hardness (monthly average) Date Data BDL=1/2DL Results 1 25 25 Std Dev. 2 Mean 3 C.V. 4 n 5 10% value 6 Median Value 7 Max. Value 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL• Values" then "COPY" . Maximum data points = 58 Par01 & Par02 Arsenic N/A 25.0000 0.0000 1 25.00 mg/L 25.00 mg/L 25.00 mg/L Date Data BDL=1/2DL Results 1 < 1 0.5 Std Dev. 2 < 1 0.5 Mean 3 < 1 0.5 C.V. 4 < 1 0.5 n 5 < 1 0.5 6 < 1 0.5 7 < 1 0.5 8 < 1 0.5 9 < 1 0.5 10 < 1 0.5 11 < 1 0.5 12 < 1 0.5 13 < 1 0.5 14 < 1 0.5 15 < 1 0.5 16 < 1 0.5 17 < 1 0.5 18 < 1 0.5 19 < 1 0.5 20 < 1 0.5 21 < 1 0.5 22 < 1 0.5 23 < 1 0.5 24 < 1 0.5 25 < 1 0.5 26 < 1 0.5 27 < 1 0.5 28 < 1 0.5 29 < 1 0.5 30 < 1 0.5 31 < 1 0.5 32 < 1 0.5 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL• Values" then "COPY" . Maximum data points = 58 0.0000 0.5000 0.0000 32 Mult Factor = 1.00 Max. Value 0.5 ug/L Max. Pred Cw 0 DETECTS ug/L NC0004987_Worksheets_20220414 (3).xlsm, data - 3 - 4/18/2022 REASONABLE POTENTIAL ANALYSIS Par03 Beryllium Date Data BDL=1/2DL Results 1 < 1 0.5 Std Dev. 2 Mean 3 C.V. 4 n 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL• Values" then "COPY" . Maximum data points = 58 Par04 Cadmium N/A 0.5000 0.0000 1 Mult Factor = 1.00 Max. Value 0.50 ug/L Max. Pred Cw 0 DETECTS ug/L Date Data BDL=1/2DL Results 1 < 1 0.5 Std Dev. 2 < 1 0.5 Mean 3 < 1 0.5 C.V. 4 < 1 0.5 n 5 < 1 0.5 6 < 1 0.5 7 < 1 0.5 8 < 1 0.5 9 < 1 0.5 10 < 1 0.5 11 < 1 0.5 12 < 1 0.5 13 < 1 0.5 14 < 1 0.5 15 < 1 0.5 16 < 1 0.5 17 < 1 0.5 18 < 1 0.5 19 < 1 0.5 20 < 1 0.5 21 < 1 0.5 22 < 1 0.5 23 < 1 0.5 24 < 1 0.5 25 < 1 0.5 26 < 1 0.5 27 < 1 0.5 28 < 1 0.5 29 < 1 0.5 30 < 1 0.5 31 < 1 0.5 32 < 1 0.5 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL• Values" then "COPY" . Maximum data points = 58 0.0000 0.5000 0.0000 32 Mult Factor = 1.00 Max. Value 0.500 ug/L Max. Pred Cw 0 DETECTS ug/L NC0004987_Worksheets_20220414 (3).xlsm, data - 4 - 4/18/2022 REASONABLE POTENTIAL ANALYSIS Par05 Chlorides (AL) Date Data 5.9 7.3 7.9 150 600 510 850 510 470 500 510 560 550 150 480 53 140 230 320 300 280 120 140 630 490 770 110 71 370 430 180 310 BDL=1/2DL Results 5.9 Std Dev. 7.3 Mean 7.9 C.V. 150 n 600 510 Mult Factor = 850 Max. Value 510 Max. Pred Cw 470 500 510 560 550 150 480 53 140 230 320 300 280 120 140 630 490 770 110 71 370 430 180 310 Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 Par06 Chlorinated Phenolic Compounds 231.0116 337.7 0.6842 32 1.2 850.0 mg/L 1,020.0 mg/L Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SF Values" then "I . Maximum c points = 5 NO DATA NO DATA NO DATA 0 Mult Factor = N/A Max. Value N/A Max. Pred Cw N/A NC0004987_Worksheets_20220414 (3).xlsm, data - 5 - 4/18/2022 REASONABLE POTENTIAL ANALYSIS 'ECIAL• COPY" lata ;8 Par07 Total Phenolic Compounds Date Data BDL=1/2DL Results 1 < 1.6 0.8 Std Dev. 2 Mean 3 C.V. 4 n 5 6 ug/L 7 ug/L 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL• Values" then "COPY" . Maximum data points = 58 N/A 0.8000 0.0000 1 Mult Factor = 1.00 Max. Value 0.8 ug/L Max. Pred Cw 0 DETECTS ug/L Par08 Use "PASTE SF Values" then "I . Maximum c points = 5 Date Data BDL=1/2DL Results 1 Std Dev. NO DATA 2 Mean NO DATA 3 C.V. NO DATA 4 n 0 5 6 Mult Factor = N/A 7 Max. Value N/A 8 Max. Pred Cw N/A 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Chromium III NC0004987_Worksheets_20220414 (3).xlsm, data - 6 - 4/18/2022 REASONABLE POTENTIAL ANALYSIS 'ECIAL• COPY" lata ;8 Par09 Chromium VI Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = fag/L 7 Max. Value fag/L 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL• Values" then "COPY" . Maximum data points = 58 Par10 Chromium, Total NO DATA NO DATA NO DATA 0 N/A N/A fag/L N/A fag/L Date Data BDL=1/2DL Results 1 < 1 0.5 Std Dev. 2 < 1 0.5 Mean 3 < 1 0.5 C.V. 4 < 1 0.5 n 5 < 1 0.5 6 < 1 0.5 Mult Factor = 7 < 1 0.5 Max. Value 8 < 1 0.5 Max. Pred Cw 9 < 1 0.5 10 1.28 1.28 11 < 1 0.5 12 < 1 0.5 13 < 1 0.5 14 < 1 0.5 15 < 1 0.5 16 < 1 0.5 17 < 1 0.5 18 < 1 0.5 19 < 1 0.5 20 < 1 0.5 21 < 1 0.5 22 < 1 0.5 23 < 1 0.5 24 < 1 0.5 25 < 1 0.5 26 < 1 0.5 27 < 1 0.5 28 < 1 0.5 29 < 1 0.5 30 < 1 0.5 31 < 1 0.5 32 < 1 0.5 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SF Values" then " . Maximum c points = 5 0.1379 0.5244 0.2630 32 1.08 1.3 1.4 NC0004987_Worksheets_20220414 (3).xlsm, data - 7 - 4/18/2022 REASONABLE POTENTIAL ANALYSIS 'ECIAL• COPY" lata ;8 Pal 1 Copper (AL) Date Data BDL=1/2DL Results 1 2.74 2.74 Std Dev. 2 2.18 2.18 Mean 3 1.32 1.32 C.V. 4 1.67 1.67 n 5 3.8 3.8 6 1.56 1.56 Mult Factor = fag/L 7 3.2 3.2 Max. Value fag/L 8 3.46 3.46 Max. Pred Cw 9 2.28 2.28 10 2.95 2.95 11 2.24 2.24 12 1.24 1.24 13 2.37 2.37 14 1.8 1.8 15 1.69 1.69 16 1.8 1.8 17 3.38 3.38 18 2.45 2.45 19 2.41 2.41 20 1.91 1.91 21 4.44 4.44 22 1.89 1.89 23 2.39 2.39 24 2.52 2.52 25 3.18 3.18 26 2 2 27 2.39 2.39 28 2.88 2.88 29 2.4 2.4 30 2.94 2.94 31 4.02 4.02 32 2.6 2.6 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL• Values" then "COPY" . Maximum data points = 58 0.7717 2.5031 0.3083 32 1.09 4.44 ug/L 4.84 ug/L Par12 Use "PASTE SF Values" then "I . Maximum c points = 5 Date Data BDL=1/2DL Results 1 19 19 Std Dev. N/A 2 Mean 19.00 3 C.V. 0.0000 4 n 1 5 6 Mult Factor = 1.00 7 Max. Value 19.0 8 Max. Pred Cw 19.0 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Cyanide NC0004987_Worksheets_20220414 (3).xlsm, data - 8 - 4/18/2022 REASONABLE POTENTIAL ANALYSIS 'ECIAL• COPY" lata ;8 Par13 Fluoride 1 2 3 4 5 6 ug/L 7 ug/L 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Date Data BDL=1/2DL 200 200 210 480 1300 1100 500 1100 500 1000 1300 1200 1600 1100 1200 180 480 640 1100 800 700 250 250 1100 1100 1200 500 250 500 1200 500 900 200 200 210 480 1300 1100 < 1000 1100 < 1000 1000 1300 1200 1600 1100 1200 180 480 640 1100 800 700 < 500 < 500 1100 1100 1200 < 1000 < 500 < 1000 1200 500 900 Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL• Values" then "COPY" . Maximum data points = 58 Par14 Lead 417.0403 770.0000 0.5416 32 1.16 1600.0 ug/L 1856.0 ug/L Date Data BDL=1/2DL 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Use "PASTE SF Values" then "I . Maximum c points = 5 Results Std Dev. 0.0000 Mean 0.5000 C.V. 0.0000 n 32 Mult Factor = 1.00 Max. Value 0.500 Max. Pred Cw 0 DETECTS NC0004987_Worksheets_20220414 (3).xlsm, data - 9 - 4/18/2022 REASONABLE POTENTIAL ANALYSIS 'ECIAL• COPY" lata ;8 Par15 Mercury Date Data BDL=1/2DL Results 1 1.28 1.28 Std Dev. 2 2.14 2.14 Mean 3 2.19 2.19 C.V. 4 1.18 1.18 n 5 1.59 1.59 6 < 0.5 0.25 Mult Factor = ug/L 7 < 0.5 0.25 Max. Value ug/L 8 0.667 0.667 Max. Pred Cw 9 1 1 10 1.72 1.72 11 < 2 1 12 2.14 2.14 13 1.89 1.89 14 2 2 15 1.14 1.14 16 0.759 0.759 17 1.23 1.23 18 0.717 0.717 19 0.67 0.67 20 2.33 2.33 21 < 0.5 0.25 22 < 0.5 0.25 23 0.888 0.888 24 0.98 0.98 25 0.536 0.536 26 < 2 1 27 0.764 0.764 28 0.765 0.765 29 0.84 0.84 30 1.03 1.03 31 1.31 1.31 32 < 0.5 0.25 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL• Values" then "COPY" . Maximum data points = 58 Par16 Molybdenum 0.6215 1.0939 0.5682 32 1.17 2.3 ng/L 2.7 ng/L Date Data BDL=1/2DL Results 1 8840 8840 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SF Values" then " . Maximum c points = 5 N/A 8840.0000 0.0000 1 1.00 8840.0 8840.0 NC0004987_Worksheets_20220414 (3).xlsm, data - 10 - 4/18/2022 REASONABLE POTENTIAL ANALYSIS 'ECIAL• COPY" iata ;8 Par17 & Par18 Nickel Date Data BDL=1/2DL Results 1 21.0 21 Std Dev. 2 8.3 8.3 Mean 3 11.0 11 C.V. 4 5.7 5.67 n 5 23.4 23.4 6 24.9 24.9 Mult Factor = ug/L 7 9.9 9.93 Max. Value ug/L 8 13.5 13.5 Max. Pred Cw 9 7.1 7.13 10 4.0 3.98 11 11.2 11.2 12 3.7 3.67 13 6.7 6.68 14 14.1 14.1 15 11.3 11.3 16 5.0 5.02 17 6.5 6.53 18 5.9 5.85 19 4.7 4.73 20 3.0 2.95 21 16.0 16 22 19.4 19.4 23 5.4 5.35 24 4.98 4.98 25 33.5 33.5 26 8.87 8.87 27 10.7 10.7 28 10.1 10.1 29 5.6 5.6 30 4.67 4.67 31 2.69 2.69 32 2.71 2.71 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL• Par19 Values" then "COPY" . Maximum data points = 58 Selenium 7.3685 10.1691 0.7246 32 1.22 33.5 fag/L 40.9 fag/L Date Data BDL=1/2DL Results 1 1.38 1.38 Std Dev. 2 4.05 4.05 Mean 3 1.72 1.72 C.V. 4 2.99 2.99 n 5 5.32 5.32 6 3.95 3.95 Mult Factor = 7 3.43 3.43 Max. Value 8 2.7 2.7 Max. Pred Cw 9 2.62 2.62 10 2.58 2.58 11 4.48 4.48 12 3.24 3.24 13 2.86 2.86 14 2.6 2.6 15 2.9 2.9 16 1.6 1.6 17 2.71 2.71 18 1.92 1.92 19 1.67 1.67 20 1.38 1.38 21 1.4 1.4 22 1.04 1.04 23 1.5 1.5 24 1.93 1.93 25 7.74 7.74 26 2.2 2.2 27 1.84 1.84 28 2.46 2.46 29 1.76 1.76 30 < 1 0.5 31 1 1 32 1.12 1.12 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 NC0004987_Worksheets_20220414 (3).xlsm, data - 11 - 4/18/2022 REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL• Values" then "COPY" . Maximum data points = 58 Par20 Silver (AL) 1.4450 2.5184 0.5738 32 1.17 7.7 ug/L 9.1 ug/L Date Data BDL=1/2DL Results 1 < 1 0.5 Std Dev. 2 < 1 0.5 Mean 3 < 1 0.5 C.V. 4 < 1 0.5 n 5 < 1 0.5 6 < 1 0.5 7 < 1 0.5 8 < 1 0.5 9 < 1 0.5 10 < 1 0.5 11 < 1 0.5 12 < 1 0.5 13 < 1 0.5 14 < 1 0.5 15 < 1 0.5 16 < 1 0.5 17 < 1 0.5 18 < 1 0.5 19 < 1 0.5 20 < 1 0.5 21 < 1 0.5 22 < 1 0.5 23 < 1 0.5 24 < 1 0.5 25 < 1 0.5 26 < 1 0.5 27 < 1 0.5 28 < 1 0.5 29 < 1 0.5 30 < 1 0.5 31 < 1 0.5 32 < 1 0.5 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL• Values" then "COPY" . Maximum data points = 58 Par21 Zinc (AL) 0.0000 0.5000 0.0000 32 Mult Factor = 1.00 Max. Value 0.500 ug/L Max. Pred Cw 0 DETECTS ug/L Date Data BDL=1/2DL Results 1 81.7 81.7 Std Dev. 2 52.7 52.7 Mean 3 19.7 19.7 C.V. 4 53.8 53.8 n 5 122 122 6 27.9 27.9 Mult Factor = 7 17.8 17.8 Max. Value 8 15.5 15.5 Max. Pred Cw 9 20.2 20.2 10 16 16 11 37.5 37.5 12 24.9 24.9 13 27.8 27.8 14 49.8 49.8 15 19.6 19.6 16 19.4 19.4 17 27.8 27.8 18 21.6 21.6 19 17.1 17.1 20 23.6 23.6 21 35 35 22 49.7 49.7 23 26.3 26.3 24 28 28 25 98.1 98.1 26 49.3 49.3 27 49.7 49.7 28 44.7 44.7 29 38.7 38.7 30 28 28 31 14.5 14.5 32 13 13 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 NC0004987_Worksheets_20220414 (3).xlsm, data - 12 - 4/18/2022 REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL• Values" then "COPY" . Maximum data points = 58 Par22 Aluminum 24.8999 36.6063 0.6802 32 1.20 122.0 ug/L 146.4 ug/L Date Data BDL=1/2DL Results 1 127 127 Std Dev. 2 Mean 3 C.V. 4 n 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL• Values" then "COPY" . Maximum data points = 58 Par23 Boron N/A 127.0000 0.0000 1 Mult Factor = 1.00 Max. Value 127.000000 fag/L Max. Pred Cw 127.000000 fag/L Date Data BDL=1/2DL 1 7.92 7.92 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 NC0004987_Worksheets_20220414 (3).xlsm, data - 13 - 4/18/2022 REASONABLE POTENTIAL ANALYSIS Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL• Values" then "COPY" . Maximum data points = 58 Par24 Sulfate N/A 7.9200 0.0000 1 1.00 7.920000 mg/L 7.920000 mg/L Date Data BDL=1/2DL Results 1 140 140 Std Dev. 2 100 100 Mean 3 150 150 C.V. 4 99 99 n 5 310 310 6 280 280 7 330 330 8 160 160 9 150 150 10 150 150 11 210 210 12 210 210 13 230 230 14 160 160 15 240 240 16 65 65 17 140 140 18 130 130 19 130 130 20 130 130 21 140 140 22 130 130 23 88 88 24 200 200 25 260 260 26 280 280 27 94 94 28 110 110 29 140 140 30 160 160 31 79 79 32 120 120 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL• Values" then "COPY" . Maximum data points = 58 Par25 Barium 69.3190 166.0938 0.4173 32 Mult Factor = 1.13 Max. Value 330.000000 mg/L Max. Pred Cw 372.900000 mg/L Date Data BDL=1/2DL 1 0.049 0.049 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 NC0004987_Worksheets_20220414 (3).xlsm, data - 14 - 4/18/2022 REASONABLE POTENTIAL ANALYSIS Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL• Values" then "COPY" . Maximum data points = 58 N/A 0.0490 0.0000 1 1.00 0.049000 mg/L 0.049000 mg/L NC0004987_Worksheets_20220414 (3).xlsm, data - 15 - 4/18/2022 Marshall Steam Station NC0004987 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 Qw (MGD) = 5.10 1 Q 10S (cfs) = 49.15 7Q 1 OS (cfs) = 60.00 7Q 1 OW (cfs) = 60.00 30Q2 (cfs) = 60.00 Avg. Stream Flow, QA (cfs) = 60.00 Receiving Stream: Lake Norman HUC 03010103 WWTP/WTP Class: IWC% @ 1 Q 10S = 13.85505214 IWC% @ 7Q 10S = 11.64126353 IWC% @ 7Q 1 OW = 11.64126353 IWC% @ 30Q2 = 11.64126353 IW%C @ QA = 11.64126353 Stream Class: WS-IV Outfall Outfall 005 Qw = 5.1 MGD COMBINED HARDNESS (mg/L) Acute = 25 mg/L Chromic = 25 mg/L YOU HAVE DESIGNATED THIS RECEIVING STREAM AS WATER SUPPLY Effluent Hard:0 val > 100 mg/L 0 val < 25 mg/L Effluent Hard Med = 25 mg/L PARAMETER TYPE (1) STANDARDS & CRITERIA (2) _1 a N H Z m REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION NC WQS / Applied 1/2 FAV / Chronic Standard Acute n # Det. Max Pred Cw Allowable Cw Arsenic Arsenic C C 150 FW(7Q10s) 340 10 FIH/WS(Qavg) ug/L ug/L 32 0 NO DETECTS Acute (FW): 2,454.0 _ _ __ ___ Chronic (FW)_1,288.5 Max MDL= 1_________ Chronic (HH): 85.9 Max MDL = 1 no limit ____________________________ ____________________________ Beryllium NC 6.5 FW(7Q10s) 65 ug/L 1 0 Note: n < 9 Limited data set NO DETECTS Acute: 469.14 _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 55.84 Max MDL = 1 no limit ____________________________ Cadmium NC 0.5899 FW(7Q10s) 3.2396 ug/L 32 0 NO DETECTS Acute: 23.382 -- _ _ _ _ Chronic: ---- 5.067 -- Max MDL = 1 no limit ---—-—-—-—-—-—-—-—-—-— - — - — -— Chlorides (AL) NC 230 FW(7Q10s) mg/L 32 32 1,020.0 Acute: NO WQS Chronic:----1,975.7-- No value > Allowable Cw no limit ---------------------------- Chlorinated Phenolic Compounds NC 1 A(30Q2) ug/L 0 0 N/A Acute: NO WQS -- Ch_ _ ronic: - — - —- 8.6--- n/a -- - — - — - — - — - — - — - — - — - — - — - — - — - — Total Phenolic Compounds NC 300 A(30Q2) ug/L 1 0 Note: n < 9 Limited data set NO DETECTS Acute: NO WQS Chronic:----2,577.0-- Max MDL = 1.6 no limit ---------------------------- Chromium III NC 117.7325 FW(7Q10s) 905.0818 fig/ 0 0 N/A Acute: 6,532.5 Chronic:----1,011.3-- no limit ---------------------------- Chromium VI NC 11 FW(7Q10s) 16 µg/L 0 0 N/A Acute: 115.5 Chronic:-----945 -- no limit ---------------------------- Chromium, Total NC µg/L 32 1 1.4 no limit Page 16 of 28 NC0004987_Worksheets_20220414 (3).xlsm, rpa 4/18/2022 Marshall Steam Station NC0004987 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Outfall Outfall 005 Qw = 5.1 MGD Copper (AL) NC 7.8806 FW(7Q10s) 10.4720 ug/L 32 32 4.84 Acute: 75.58 _ _ _ _ -- Chronic: - - -- 67.70 -- No value > Allowable Cw no limit --------------------------- Cyanide NC 5 FW(7Q10s) 22 10 ug/L 1 1 Note: n < 9 Limited data set 19.0 Default C.V. Acute: 158.8 ___ _ __________ Chronic: 43 0 No value > Allowable Cw no limit ___________________________ Fluoride NC 1800 FW(7Q10s) ug/L 32 25 1,856.0 Acute: NO WQS _ _ _ _ _ -- Chronic: - -- 15,462.2 - No value > Allowable Cw n/a --------------------------- Lead NC 2.9416 FW(7Q10s) 75.4871 ug/L 32 0 NO DETECTS Acute: 544.834 -_ _ ---_ _ -Chronic:-25.269 -- Max MDL = 1 no limit --------------------------- Mercury NC 12 FW(7Q10s) 0.5 ng/L 32 25 2.7 Acute: NO WQS _ _ _ _ --Chronic: - - - - --- -- 103 No value > Allowable Cw no limit --------------------------- Molybdenum NC 2000 HH(7Q10s) ug/L 1 1 Note: n < 9 Limited data set 8,840.0 Default C.V. Acute: NO WQS ___ _ ____ _ Chronic: 17,180.3 No value > Allowable Cw n/a ___________________________ Nickel Nickel NC NC 37.2313 FW(7Q10s) 335.2087 25.0000 WS(7Q10s) µg/L µg/L 32 32 40.9 Acute (FW): 2,419.4 _ _ _ __ _ __ Chronic (FW)_319.8 No value >_ Allowable Cw__ Chronic (WS) 214.8 No value > Allowable Cw no limit ___________________________ ___________________________ Selenium NC 5 FW(7Q10s) 56 ug/L 32 31 9.1 Acute: 404.2 _ _ --Chronic:-----43-0 -- No value > Allowable Cw no limit --------------------------- Silver (AL) NC 0.06 FW(7Q10s) 0.2964 ug/L 32 0 NO DETECTS Acute: 2.139 --Ch_ _ ronic: - - -- 0.515__ -- Max MDL = 1 no limit --------------------------- Zinc (AL) NC 126.7335 FW(7Q10s) 125.7052 ug/L 32 32 146.4 Acute: 907.3 _ _ _ _ --Chronic:----1,08 -- No value > Allowable Cw no limit --------------------------- Aluminum NC 6500 WS(7Q10s) µg/L 1 1 Note: n < 9 Limited data set 127.00000 Default C.V. Acute: NO WQS ___ _ __ _ _ Chronic: 55835.86338 No value > Allowable Cw no limit ____________________________ Boron NC 7 WS(7Q10s) mg/L 1 1 Note: n < 9 Limited data set 7.92000 Default C.V. Acute: NO WQS __Ch_ _ ____ _ ronic: 60.13093 No value > Allowable Cw no limit ___________________________ IAcute: NO WQS r,,, ';m;+ Page 17 of 28 NC0004987_Worksheets_20220414 (3).xlsm, rpa 4/18/2022 Marshall Steam Station NC0004987 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Outfall Outfall 005 Qw = 5.1 MGD Sulfate NC 250 WS(7Q10s) mg/L 32 32 372.90000 — Chronic: --- 515.40797 No value > Allowable Cw --------------------------- Barium NC 1 WS(7Q10s) mg/L 1 1 Note: n < 9 Limited data set 0.04900 Default C.V. Acute: NO WQS _ _ _ _ ___ ___ Chronic: 8.59013 No value > Allowable Cw no limit ___________________________ Page 18 of 28 NC0004987_Worksheets_20220414 (3).xlsm, rpa 4/18/2022 Monitoring Frequencies 2B .0500 Effluent Limited pH Temp, C BOD5 TSS NH3-N Fecal Col. TN TP E E I, E I, E E E E E 2/Month 1/Week 2/Month 2/Month 1/Month 2/Month Water Quality Limited Parameter Location Class I D.O. D.O. pH Temp, C Temp, C BOD5 TSS NH3-N TRC Fecal Col. Fecal Col. Conductivi Conductivi TN TP U. E E U, D I, E I, E E E E U, D E U, D E E 1/Week 1/Week 1/Week 1/Week 3/Week 3/Week 3/Week 3/Week 2/Month 1/Week 1/Week 3/Week See notes below. See notes below. Frequency Daily Daily Daily Daily 3/Week Daily 1/Week 1/Week 2/Month Daily 1/Week 2/Month 2/Month 1/Month 2/Week 2/Month 2/Month 1/Week 1/Week Class II Class III 1/Week 3/Week 1/Week 3/Week' 1/Week 3/Week Daily Daily 1/Week 3/Week` 1/Week 3/Week 1/Week 3/Week 2/Month 1/Week 2/Week 3/Week 1/Week 3/Week 1/Week 3/Week' 1/Week 3/Week 1/Week 3/Week' See notes below. See notes below. Class IV Daily 3/Week' Daily Daily 3/Week' Daily Daily 3/Week Daily Daily 3/Week' Daily 3/Week' Notes: Upstream and downstream monitoring in WQ-limited waters is to be conducted 3/Week during Jun, Jul, Aug, and Sep; and 1/Week during the rest of the year. TN, TP Monitoring All facilities >= 0.05 MGD will monitor TN and TP Those < 0.05 MGD will monitor if discharging to NSW For the Neuse, Tar -Pamlico, and any other river basins classifed as NSW, use limits and monitoring requirements according to the basin's permitting strategy. For French Broad, Broad, Savannah, New Watauga, Little Tennessee, and Hiwassee: - >= 0.05 M: - monitor semiannually - >= 1.0 MG - monitor quarterly For all other river basins: - >= 0.05 M: - monitor quarterly - >= 1.0 MG - monitor monthly Per Memo Dated 7-15-2010 RPA Condition Permit Monitoring Frequency LRPA Exists Monitor Monthly and add Permit Limit 2.RPA Exists but Action Levels (Cu, Zn, Ag ,Fe. CI) Monitor Quarterly in conjunction with Tox Test 3aRPA Exists but Damsel Limited (o<g samples) 3b. RPA exists, dataset limited, but 2 values > allowable Cw Monitor Quarterly Monitor Monthly and add Pewit Limit 1.No RYA (Predicted Max > 5014 of Allowable) Monitor Quarterly (or defer to Pretreat LTMP) 5.No RPA (Predicted Max < MM% Allowable) No Monitoring 6a.Na Data (New Permit, New Waste Stream) 6b. New Greensand or Conventional WTP Monitor Monthly for Toxic Pollutants of Concern Monitor Quarterly for Toxic Pollutants of Concern password all sheets = rpa2016 Msg00 Msg01 Msg02 Msg03 Msg04 Msg05 Msg06 Msg07 Msg08 Msg09 Msg10 < No Data Entered > MaxPredCw < Acute MaxPredCw < Chronic MaxPredCw « Acute MaxPredCw « Chronic MaxPredCw > Acute MaxPredCw > Chronic MaxPredCw » Acute MaxPredCw» Chronic No acute standard or 1/2 FAV No chronic standard or criterion NO DATA MONITOR? MONITOR? REMOVE? REMOVE? DAILY MAX LIMIT? MO AVG LIMIT? DAILY MAX LIMIT? MO AVG LIMIT? N/A N/A Sample recommendations: Daily max limit Monitor 1/month Monitor 1/week Monitor2/month Monitoring not necessary in permit No limit No limit - assuming no tox (Action Level parameter) No limit (Action Level parameter) Continue to monitor at 2/month Mo. avg. limit (keep wk. avg. if existing) Revise daily max. limit River Basin HUC Hardness Total Suspended Solids (TSS) Stations Samples 10th Percentile Median Mean Stations Samples 10th Percentile Median Mean 03010102 4 188 28 90.5 83.4 1 8 6.2 6.2 8.8 Roanoke 03010103 12 720 14 21.5 24.3 5 40 6.2 6.9 45.6 03010104 18 851 24 35 36.6 4 32 6.2 6.2 18.0 River 03010106 5 118 18 29 32.3 1 8 6.2 6.2 7.9 03010107 11 856 24 30 33.6 6 47 6.2 6.2 11.5 03010201 0 0 NA NA NA 0 0 NA NA NA 03010202 1 73 28 38 42.6 1 8 6.2 6.2 6.6 :howan Rive 03010203 12 633 18 28 36.2 5 40 6.2 6.2 6.4 03010204 3 146 20 30 31.6 2 16 6.2 6.2 8.9 03010205 21 252 40 96 203.2 2 15 6.2 6.2 7.2 03020101 17 1021 19 28 31.8 9 72 6.2 6.2 9.3 Tar- 03020102 3 172 20 26.5 29.5 1 8 6.2 6.2 6.2 Pamlico 03020103 12 818 23 35 60.2 6 47 6.2 6.2 9.8 03020104 1 88 10 16 20.9 7 293 6.2 6.2 15.9 River 03020105 0 0 NA NA NA 0 0 NA NA NA 03020106 1 120 30 60 153.1 1 9 6.2 6.2 7.5 03020201 48 2361 20 34 43.8 17 136 6.2 6.2 9.7 Neuse 03020202 9 643 20 30 35.7 6 41 6.2 7.2 13.2 River 03020203 14 573 16 26 31.3 4 32 6.2 6.2 6.2 03020204 6 147 32 60 68.9 1 8 6.2 6.2 6.2 White Oak 03020301 0 0 NA NA NA 0 0 NA NA NA River 03020302 3 221 45.2 93 357.0 2 18 6.2 6.2 6.2 03030002 56 2695 26 44 48.8 17 315 6.2 7.8 14.8 03030003 33 1637 24 43 53.4 9 65 6.2 6.2 38.8 Cape Fear 03030004 22 1240 6 19 21.4 7 55 6.2 6.2 10.0 River 03030005 16 1054 18 26 83.6 6 49 6.2 7.2 12.3 03030006 17 760 12 23 33.1 7 57 6.2 6.2 6.5 03030007 17 657 24 40 56.0 8 63 6.2 6.2 6.6 03040101 22 1380 10 20 25.8 12 187 6.2 8.8 25.6 03040102 7 473 16 34 33.9 5 68 6.2 13 29.1 Yadkin -Pee 03040103 42 1527 22 42 78.4 9 84 6.2 11 19.3 Dee River 03040104 14 563 11.4 22 26.5 4 31 6.2 6.2 10.2 03040105 24 875 31 46 51.3 9 97 6.2 6.2 26.6 03040201 10 329 11.64 22 23.6 4 31 6.2 6.2 10.5 03040202 0 0 NA NA NA 0 0 NA NA NA Lumber 03040203 58 1346 5 12 15.2 8 61 6.2 6.2 7.5 03040204 23 362 5 7 15.0 2 16 6.2 6.2 6.7 River 03040206 25 503 7 20 31.1 3 27 6.2 6.2 7.1 03040208 0 0 NA NA NA 1 8 8.8 16 15.9 Catawba 03050101 63 2861 7 14 26.2 15 91 6.2 6.2 19.6 03050102 18 1230 8 22 27.4 9 72 6.2 6.35 21.1 River 03050103 14 966 38 67 67.2 5 40 6.2 6.2 9.6 Broad River 03050105 24 1011 9 17 21.2 8 63 6.2 6.2 13.0 Savannah 03060101 1 116 3 5 5.7 1 10 6.2 6.2 6.3 River 03060102 0 0 NA NA NA 0 0 NA NA NA New River 05050001 9 707 12 20 22.1 8 46 6.2 6.2 33.8 ✓atauga RivE 06010103 6 322 12 20 21.8 2 15 6.2 6.2 6.5 French 06010105 30 1854 4 10 11.3 14 91 6.2 6.2 18.6 Broad 06010106 13 982 3 9 23.0 6 49 6.2 6.2 8.1 River 06010108 12 744 3 12 12.3 5 34 6.2 6.2 16.2 Little 06010202 12 567 4 8 8.2 3 24 6.2 6.2 11.5 Tennessee 06010203 7 310 4 7 8.9 1 8 6.2 6.2 8.2 River 06010204 7 152 5 9 10.0 1 8 6.2 6.2 9.0 Hiwassee 06020002 13 272 5 10 12.5 3 17 6.2 6.2 8.5 River 06020003 0 0 NA NA NA 0 0 NA NA NA notes: 816 37,496 273 2,660 1. The Practical Quanitation Limit (PQL) for TSS is 6.2 mg/L. The PQL for Hardness is 1 mg/L. 2. Some questionable data (recorded as zero but with no PQL given) was removed from the database. 3. This table was constructed using all available data in STORET for the State of North Carolina, 12/20/10. Date: 4/18/2022 Dissolved to Total Metal Calculator Do NOT enter any data directly into this spreadsheet. Enter data onto "Table 1" under the Input Sheet and enter "Effluent Hardness" under the Data Sheet. In accordance with 40 CFR 122.45 (c ), permits are, have and must be written as total metals. This calculator has been inserted into the RPA to calculate Total Metal allowable allocations once Table 1 has been completed (Input Sheet) and Effluent hardness has been entered (Data Sheet). 1) Following the spreadsheet from left to right. First the allowable allocations for the dissolved metals will appear for all the metals listed once Table 1 is complete and effluent hardness entered. Use a default value of 25 mg/L if no hardness data is available. Second, the Dissolved Metal allocations are divided by the Translators to determine the Total Metals that can be allocated to the Permittee. These Total Metals values are automatically inserted into Table 2 and are the allowable Total Metal allocations determined for the Permittee prior to allowing for dilution. See Input sheet Table 2. The final acute and chronic values shown under the RPA sheet are the Total Metal values listed in Table 2 divided by the acute and chronic IWC, respectively. 2) The Translators used in the freshwater RPA are the Partition Coefficients published by US EPA in 1984. They are TSS dependent equations and can be found listed with the WQS hardness dependent equations under the sheet labeled Equations. A fixed TSS value of 10 mg/L is used to calculate the Translator values. 3) Pretreatment Facilities - PERCS will need a copy of the Dissolved to Total Metal Calculator spreadsheet and the RPA sheet along with the Final Permit. Pretreatment Facilities are required to renew their Headwords Analysis after renewal of their permits. Since all their metal allocations are likely to change PERCS needs to see any new metal permit limits and the allowable allocations for the dissolved metals to assess Maximum Allowable Headworks Loading (MAHL) numbers for each metal based on the Combined Hardness values used in the permit writers RPA calculations. 4) For Cadmium, Lead, Nickel, Chromium and Beryllium, if all the effluent sampling data for the last three to five years shows the pollutant at concentrations less than the Practical Quantitative Level (PQL), it is not likely a limit or monitoring will be put in the permit. However, if the estimated NPDES permit limit is less than the Practical Quantitative Limit (particularly, Cadmium and Lead) and the pollutant is believed to be present, to assess compliance with the new standards and for future permit limit development, monitoring for the pollutant will be required. If the facility is monitoring for the pollutant in its Pretreatment LTMP, no monitoring is needed in the permit. 5) For monitoring and compliance purposes if Total Chromium FACILITY: Marshall Steam Station NPDES PERMIT: NC0004987 Dissolved to Total Metal Calculator In accordance with Federal Regulations, permit limitations must be written as Total Metals per 40 CFR 122.45(c) HUC = 03010103 Receiving Stream summer 7Q10 (CFS) Receiving Stream summer 7Q10 (MGD) Rec. Stream 1Q10 [MGD] NPDES Flow Limit [MGD] Total Suspended Solids -Fixed Value- (mg/L) Combined Hardness chronic (mg/L) Combined Hardness Acute (mg/L) Instream Wastewater Concentration (Chronic) Instream Wastewater Concentration (Acute) 8-digit H U C Hardness Median (mg/L) Effluent Hardness Median (mg/L) 60.0000 38.7097 31.7097 5.1000 10 25.000 25.000 11.6413 13.8551 25 25 PARAMETER Dissolved Metals Chronic Acute [ug/I] [ug/I] US EPA Translators- using Default Partition Coefficients (streams) Maximum Allowable Effluent Concentration (MAEC) as a Total Metal =Dissolved Metal Translator Chronic Acute HUC Hard Med (mg/L) = 21.5 EFF Hard Med (mg/L) = 25 [ug/I] [ug/I] Cadmium (d) Cd -Trout streams Chromium III (d)(h) Chromium VI (d) Chromium, Total (t) Copper (d)(h) Lead (d)(h) Nickel (d)(h) Ni - WS streams (t) Silver (d)(h,acute) Zinc (d)(h) 0.15 0.15 24 11 2.7 0.54 16 0.06 36 0.82 0.51 183 16 3.6 14 145 0.30 36 0.252 0.252 0.202 1.000 0.348 0.184 0.432 1.000 0.288 0.59 0.59 117.73 11.00 N/A 7.88 2.94 37.23 3.24 2.01 905.08 16.00 N/A 10.47 75.49 335.21 25 N/A 0.06 0.30 126.73 125.71 Beryllium Arsenic (d) 6.5 150 65 340 1.000 1.000 6.5 150 65 340 COMMENTS (identify parameters to PERCS Branch to maintain in facility's LTMP/STMP): (d) = dissolved metal standard. See 15A NCAC 02B .0211 for more information. (h) = hardness -dependent dissolved metal standard. See 15A NCAC 02B .0211 for more information. (t) = based upon measurement of total recoveable metal. See 15A NCAC 02B .0211 for more information. The Human Health standard for Nickel in Water Supply Streams is 25 mg/L which is Total Recoverable metal standard. The Human Health standard for Arsenic is 10 µg/L which is Total Recoverable metal standard. Reasonable Potential Multiplying Factors -Calculator 95.0% 95.0% Confidence Level Upper Boundary of the Effluent Distribution (Percentile Value Not To Exceed) Coefficient of Variation Coefficient of Variation n 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2.0 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 2.9 3.0 3.1 3.2 3.3 3.4 3.5 3.6 3.7 3.8 3.9 4.0 4.1 4.2 1 1.00 1.39 1.92 2.63 3.55 4.73 6.20 7.98 iu.11 1L.b0 15.47 18.72 22.35 26.38 30.78 35.57 40.73 46.26 52.14 58.37 64.94 71.84 79.06 86.58 94.41 102.53 110.94 119.62 128.56 137.76 147.21 15b.i 166.84 177.00 187.38 197.98 208.78 219.79 231.00 242.40 253.99 265.76 277.71 2 1.00 1.27 1.61 2.03 2.53 3.11 3.79 4.57 5.43 6.38 7.41 8.51 9.69 10.94 12.25 13.61 15.03 16.49 18.00 19.55 21.14 22.75 24.40 26.08 27.79 29.51 31.26 33.03 34.82 36.63 38.45 40.28 42.13 43.99 45.86 47.74 49.64 51.54 53.44 55.36 57.28 59.21 61.15 3 1.00 1.22 1.48 1.79 2.15 2.55 3.00 3.49 4.03 4.60 5.20 5.84 6.49 7.17 7.87 8.59 9.32 10.06 10.81 11.58 12.34 13.12 13.90 14.68 15.46 16.25 17.04 17.83 18.62 19.41 20.21 21.00 21.79 22.58 23.36 24.15 24.94 25.72 26.50 27.28 28.06 28.84 29.61 4 1.00 1.19 1.40 1.65 1.93 2.25 2.59 2.95 3.34 3.74 4.16 4.60 5.04 5.50 5.96 6.42 6.89 7.36 7.84 8.31 8.79 9.26 9.73 10.20 10.68 11.14 11.61 12.07 12.54 13.00 13.45 13.91 14.36 14.81 15.25 15.70 16.14 16.58 17.01 17.44 17.87 18.30 18.72 5 1.00 1.16 1.35 1.56 1.80 2.0c 2.32 2.61 2.91 3.23 3.55 3.87 4.21 4.54 4.88 5.21 5.55 5.89 6.22 6.56 6.89 7.22 7.54 7.87 8.19 8.51 8.82 9.13 9.44 9.75 10.05 10.36 10.65 10.95 11.24 11.53 11.82 12.10 12.38 12.66 12.94 13.21 13.48 6 1.00 1.15 1.31 1.50 1.70 1.9. 2.14 ?.38 2.63 2.88 3.14 3.40 3.66 3.92 4.18 4.44 4.70 4.96 5.21 5.46 5.71 5.96 6.20 6.44 6.68 6.91 7.14 7.37 7.60 7.82 8.04 8.25 8.47 8.68 8.89 9.10 9.30 9.50 9.70 9.90 10.09 10.29 10.48 7 1.00 1.13 1.28 1.45 1.62 1.81 2.01 2.21 2.42 2.63 2.84 3.06 3.27 3.48 3.69 3.90 4.11 4.32 4.52 4.72 4.91 5.10 5.29 5.48 5.67 5.85 6.02 6.20 6.37 6.54 6.71 6.88 7.04 7.20 7.36 7.51 7.67 7.82 7.97 8.12 8.26 8.41 8.55 8 1.00 1.12 1.26 1.40 1.56 1.73 1.90 2.07 2.25 2.44 2.62 2.80 2.98 3.16 3.33 3.51 3.68 3.85 4.01 4.17 4.33 4.49 4.64 4.79 4.94 5.09 5.23 5.37 5.51 5.64 5.78 5.91 6.03 6.16 6.29 6.41 6.53 6.65 6.77 6.88 6.99 7.11 7.22 9 1.00 1.11 1.24 1.37 1.51 1.66 1.81 1.97 2.17 2.28 2.44 2.60 2.7F 2.90 3.05 3.20 3.34 3.49 3.62 3.7F 3.89 4.02 4.15 4.27 4.40 1.52 4.63 4.75 1-.86 4.97 5.08 5.19 5.29 5.40 5.50 5.60 5.69 5.79 5.88 5.98 6.07 6.16 6.25 10 1.00 1.10 1.22 1.34 1.47 1.60 1.74 1.88 2.02 2.16 2.30 2.43 2.57 2.70 2.83 2.95 3.08 3.20 3.32 3.43 3.55 3.66 3.77 3.87 3.97 4.07 4.17 4.27 4.36 4.46 4.55 4.64 4.72 4.81 4.89 4.97 5.06 5.13 5.21 5.29 5.36 5.44 5.51 11 1.00 1.10 1.20 1.32 1.43 1.55 1.68 1.80 1.93 2.05 2.18 2.30 2.41 2.53 2.64 2.75 2.86 2.97 3.07 3.17 3.27 3.36 3.46 3.55 3.63 3.72 3.80 3.89 3.97 4.05 4.12 4.20 4.27 4.34 4.41 4.48 4.55 4.62 4.68 4.75 4.81 4.87 4.94 12 1.00 1.09 1.19 1.29 1.40 1.51 1.63 1.74 1.85 1.96 2.07 2.18 2.29 2.39 2.49 2.59 2.68 2.78 2.87 2.95 3.04 3.12 3.20 3.28 3.36 3.43 3.50 3.57 3.64 3.71 3.78 3.84 3.90 3.97 4.03 4.09 4.15 4.20 4.26 4.31 4.37 4.42 4.47 13 1.00 1.09 1.18 1.27 1.37 1.48 1.58 1.68 1.79 1.89 1.99 2.08 2.18 2.27 2.36 2.45 2.53 2.61 2.69 2.77 2.84 2.92 2.99 3.06 3.12 3.19 3.25 3.31 3.37 3.43 3.49 3.55 3.60 3.66 3.71 3.76 3.81 3.86 3.91 3.96 4.00 4.05 4.09 14 1.00 1.08 1.17 1.26 1.35 1.44 1.54 1.63 1.73 1.82 1.91 2.00 2.08 2.17 2.25 2.32 2.40 2.47 2.54 2.61 2.68 2.74 2.81 2.87 2.93 2.98 3.04 3.09 3.15 3.20 3.25 3.30 3.35 3.39 3.44 3.48 3.53 3.57 3.61 3.66 3.70 3.74 3.77 15 1.00 1.08 1.16 1.24 1.33 1.41 1.50 1.59 1.68 1.76 1.84 1.92 2.00 2.07 2.15 2.22 2.29 2.35 2.41 2.48 2.54 2.59 2.65 2.70 2.76 2.81 2.86 2.91 2.95 3.00 3.04 3.09 3.13 3.17 3.21 3.25 3.29 3.33 3.36 3.40 3.44 3.47 3.51 16 1.00 1.07 1.15 1.23 1.31 1.39 1.47 1.55 1.63 1.71 1.78 1.85 1.93 1.99 2.06 2.12 2.19 2.24 2.30 2.36 2.41 2.46 2.51 2.56 2.61 2.65 2.70 2.74 2.78 2.83 2.86 2.90 2.94 2.98 3.01 3.05 3.08 3.12 3.15 3.18 3.21 3.24 3.28 17 1.00 1.07 1.14 1.21 1.29 1.36 1.44 1.51 1.59 1.66 1.73 1.79 1.86 1.92 1.98 2.04 2.10 2.15 2.20 2.25 2.30 2.35 2.39 2.44 2.48 2.52 2.56 2.60 2.64 2.67 2.71 2.74 2.78 2.81 2.84 2.87 2.90 2.93 2.96 2.99 3.02 3.05 3.08 18 1.00 1.06 1.13 1.20 1.27 1.34 1.41 1.48 1.55 1.62 1.68 1.74 1.80 1.86 1.91 1.97 2.02 2.07 2.11 2.16 2.20 2.25 2.29 2.33 2.36 2.40 2.44 2.47 2.51 2.54 2.57 2.60 2.63 2.66 2.69 2.72 2.75 2.77 2.80 2.83 2.85 2.88 2.90 19 1.00 1.06 1.12 1.19 1.26 1.32 1.39 1.45 1.51 1.58 1.64 1.69 1.75 1.80 1.85 1.90 1.95 1.99 2.03 2.08 2.12 2.15 2.19 2.23 2.26 2.30 2.33 2.36 2.39 2.42 2.45 2.48 2.51 2.53 2.56 2.58 2.61 2.63 2.66 2.68 2.70 2.72 2.75 20 1.00 1.06 1.12 1.18 1.24 1.30 1.36 1.42 1.48 1.54 1.59 1.65 1.70 1.75 1.79 1.84 1.88 1.92 1.96 2.00 2.04 2.07 2.11 2.14 2.17 2.20 2.23 2.26 2.29 2.31 2.34 2.37 2.39 2.42 2.44 2.46 2.48 2.51 2.53 2.55 2.57 2.59 2.61 21 1.00 1.05 1.11 1.17 1.23 1.29 1.34 1.40 1.45 1.51 1.56 1.61 1.65 1.70 1.74 1.78 1.82 1.86 1.90 1.93 1.96 2.00 2.03 2.06 2.09 2.12 2.14 2.17 2.19 2.22 2.24 2.27 2.29 2.31 2.33 2.35 2.37 2.39 2.41 2.43 2.45 2.47 2.49 22 1.00 1.05 1.11 1.16 1.22 1.27 1.32 1.38 1.43 1.48 1.52 1.57 1.61 1.65 1.69 1.73 1.77 1.80 1.84 1.87 1.90 1.93 1.96 1.99 2.01 2.04 2.06 2.09 2.11 2.13 2.15 2.18 2.20 2.22 2.24 2.25 2.27 2.29 2.31 2.33 2.34 2.36 2.37 23 1.00 1.05 1.10 1.15 1.20 1.25 1.31 1.35 1.40 1.45 1.49 1.53 1.57 1.61 1.65 1.68 1.72 1.75 1.78 1.81 1.84 1.87 1.89 1.92 1.94 1.97 1.99 2.01 2.03 2.05 2.07 2.09 2.11 2.13 2.15 2.16 2.18 2.20 2.21 2.23 2.24 2.26 2.27 24 1.00 1.05 1.09 1.14 1.19 1.24 1.29 1.33 1.38 1.42 1.46 1.50 1.54 1.57 1.61 1.64 1.67 1.70 1.73 1.76 1.78 1.81 1.83 1.86 1.88 1.90 1.92 1.94 1.96 1.98 2.00 2.02 2.03 2.05 2.07 2.08 2.10 2.11 2.13 2.14 2.16 2.17 2.18 25 1.00 1.04 1.09 1.14 1.18 1.23 1.27 1.32 1.36 1.40 1.43 1.47 1.51 1.54 1.57 1.60 1.63 1.66 1.68 1.71 1.73 1.76 1.78 1.80 1.82 1.84 1.86 1.88 1.90 1.91 1.93 1.95 1.96 1.98 1.99 2.01 2.02 2.04 2.05 2.06 2.08 2.09 2.10 26 1.00 1.04 1.09 1.13 1.17 1.21 1.26 1.30 1.34 1.37 1.41 1.44 1.48 1.51 1.54 1.56 1.59 1.62 1.64 1.66 1.69 1.71 1.73 1.75 1.77 1.79 1.80 1.82 1.84 1.85 1.87 1.88 1.90 1.91 1.93 1.94 1.95 1.97 1.98 1.99 2.00 2.01 2.02 27 1.00 1.04 1.08 1.12 1.16 1.20 1.24 1.28 1.32 1.35 1.39 1.42 1.45 1.48 1.50 1.53 1.55 1.58 1.60 1.62 1.64 1.66 1.68 1.70 1.72 1.73 1.75 1.77 1.78 1.80 1.81 1.82 1.84 1.85 1.86 1.88 1.89 1.90 1.91 1.92 1.93 1.94 1.95 28 1.00 1.04 1.08 1.12 1.15 1.19 1.23 1.26 1.30 1.33 1.36 1.39 1.42 1.45 1.47 1.50 1.52 1.54 1.56 1.58 1.60 1.62 1.64 1.66 1.67 1.69 1.70 1.72 1.73 1.74 1.76 1.77 1.78 1.79 1.81 1.82 1.83 1.84 1.85 1.86 1.87 1.88 1.89 29 1.00 1.04 1.07 1.11 1.15 1.18 1.22 1.25 1.28 1.31 1.34 1.37 1.40 1.42 1.44 1.47 1.49 1.51 1.53 1.55 1.56 1.58 1.60 1.61 1.63 1.64 1.66 1.67 1.68 1.70 1.71 1.72 1.73 1.74 1.75 1.76 1.77 1.78 1.79 1.80 1.81 1.82 1.83 30 1.00 1.03 1.07 1.10 1.14 1.17 1.20 1.24 1.27 1.29 1.32 1.35 1.37 1.39 1.42 1.44 1.46 1.48 1.49 1.51 1.53 1.54 1.56 1.57 1.59 1.60 1.61 1.63 1.64 1.65 1.66 1.67 1.68 1.69 1.70 1.71 1.72 1.73 1.74 1.75 1.76 1.76 1.77 31 1.00 1.03 1.06 1.10 1.13 1.16 1.19 1.22 1.25 1.28 1.30 1.33 1.35 1.37 1.39 1.41 1.43 1.45 1.46 1.48 1.50 1.51 1.52 1.54 1.55 1.56 1.57 1.59 1.60 1.61 1.62 1.63 1.64 1.65 1.66 1.66 1.67 1.68 1.69 1.70 1.71 1.71 1.72 32 1.00 1.03 1.06 1.09 1.12 1.15 1.18 1.21 1.24 1.26 1.28 1.31 1.33 1.35 1.37 1.39 1.40 1.42 1.43 1.45 1.46 1.48 1.49 1.50 1.51 1.53 1.54 1.55 1.56 1.57 1.58 1.59 1.60 1.60 1.61 1.62 1.63 1.64 1.64 1.65 1.66 1.66 1.67 33 1.00 1.03 1.06 1.09 1.12 1.14 1.17 1.20 1.22 1.24 1.27 1.29 1.31 1.33 1.34 1.36 1.38 1.39 1.41 1.42 1.43 1.45 1.46 1.47 1.48 1.49 1.50 1.51 1.52 1.53 1.54 1.55 1.56 1.56 1.57 1.58 1.59 1.59 1.60 1.61 1.61 1.62 1.63 34 1.00 1.03 1.05 1.08 1.11 1.14 1.16 1.18 1.21 1.23 1.25 1.27 1.29 1.31 1.32 1.34 1.35 1.37 1.38 1.39 1.41 1.42 1.43 1.44 1.45 1.46 1.47 1.48 1.49 1.49 1.50 1.51 1.52 1.53 1.53 1.54 1.55 1.55 1.56 1.57 1.57 1.58 1.58 35 1.00 1.03 1.05 1.08 1.10 1.13 1.15 1.17 1.20 1.22 1.23 1.25 1.27 1.29 1.30 1.32 1.33 1.34 1.36 1.37 1.38 1.39 1.40 1.41 1.42 1.43 1.44 1.45 1.45 1.46 1.47 1.48 1.48 1.49 1.50 1.50 1.51 1.51 1.52 1.53 1.53 1.54 1.54 36 1.00 1.02 1.05 1.07 1.10 1.12 1.14 1.16 1.18 1.20 1.22 1.24 1.25 1.27 1.28 1.30 1.31 1.32 1.33 1.34 1.35 1.36 1.37 1.38 1.39 1.40 1.41 1.42 1.42 1.43 1.44 1.44 1.45 1.46 1.46 1.47 1.47 1.48 1.48 1.49 1.49 1.50 1.50 37 1.00 1.02 1.05 1.07 1.09 1.11 1.13 1.15 1.17 1.19 1.21 1.22 1.24 1.25 1.26 1.28 1.29 1.30 1.31 1.32 1.33 1.34 1.35 1.36 1.36 1.37 1.38 1.39 1.39 1.40 1.41 1.41 1.42 1.42 1.43 1.43 1.44 1.45 1.45 1.45 1.46 1.46 1.47 38 1.00 1.02 1.04 1.06 1.08 1.10 1.12 1.14 1.16 1.18 1.19 1.21 1.22 1.23 1.25 1.26 1.27 1.28 1.29 1.30 1.31 1.32 1.32 1.33 1.34 1.35 1.35 1.36 1.37 1.37 1.38 1.38 1.39 1.39 1.40 1.40 1.41 1.41 1.42 1.42 1.43 1.43 1.43 39 1.00 1.02 1.04 1.06 1.08 1.10 1.12 1.13 1.15 1.16 1.18 1.19 1.21 1.22 1.23 1.24 1.25 1.26 1.27 1.28 1.29 1.29 1.30 1.31 1.31 1.32 1.33 1.33 1.34 1.34 1.35 1.36 1.36 1.37 1.37 1.37 1.38 1.38 1.39 1.39 1.40 1.40 1.40 40 1.00 1.02 1.04 1.06 1.07 1.09 1.11 1.12 1.14 1.15 1.17 1.18 1.19 1.20 1.21 1.22 1.23 1.24 1.25 1.26 1.26 1.27 1.28 1.29 1.29 1.30 1.30 1.31 1.31 1.32 1.32 1.33 1.33 1.34 1.34 1.35 1.35 1.35 1.36 1.36 1.37 1.37 1.37 41 1.00 1.02 1.03 1.05 1.07 1.08 1.10 1.12 1.13 1.14 1.15 1.17 1.18 1.19 1.20 1.21 1.21 1.22 1.23 1.24 1.24 1.25 1.26 1.26 1.27 1.27 1.28 1.29 1.29 1.29 1.30 1.30 1.31 1.31 1.32 1.32 1.32 1.33 1.33 1.33 1.34 1.34 1.34 42 1.00 1.02 1.03 1.05 1.06 1.08 1.09 1.11 1.12 1.13 1.14 1.15 1.16 1.17 1.18 1.19 1.20 1.21 1.21 1.22 1.23 1.23 1.24 1.24 1.25 1.25 1.26 1.26 1.27 1.27 1.28 1.28 1.28 1.29 1.29 1.29 1.30 1.30 1.30 1.31 1.31 1.31 1.32 43 1.00 1.01 1.03 1.04 1.06 1.07 1.09 1.10 1.11 1.12 1.13 1.14 1.15 1.16 1.17 1.18 1.18 1.19 1.20 1.20 1.21 1.21 1.22 1.22 1.23 1.23 1.24 1.24 1.25 1.25 1.25 1.26 1.26 1.26 1.27 1.27 1.27 1.28 1.28 1.28 1.28 1.29 1.29 44 1.00 1.01 1.03 1.04 1.05 1.07 1.08 1.09 1.10 1.11 1.12 1.13 1.14 1.15 1.15 1.16 1.17 1.17 1.18 1.18 1.19 1.20 1.20 1.20 1.21 1.21 1.22 1.22 1.22 1.23 1.23 1.23 1.24 1.24 1.24 1.25 1.25 1.25 1.25 1.26 1.26 1.26 1.26 45 1.00 1.01 1.03 1.04 1.05 1.06 1.07 1.08 1.09 1.10 1.11 1.12 1.13 1.13 1.14 1.15 1.15 1.16 1.16 1.17 1.17 1.18 1.18 1.19 1.19 1.19 1.20 1.20 1.20 1.21 1.21 1.21 1.22 1.22 1.22 1.22 1.23 1.23 1.23 1.23 1.24 1.24 1.24 46 1.00 1.01 1.02 1.03 1.05 1.06 1.07 1.08 1.08 1.09 1.10 1.11 1.11 1.12 1.13 1.13 1.14 1.14 1.15 1.15 1.16 1.16 1.17 1.17 1.17 1.18 1.18 1.18 1.19 1.19 1.19 1.19 1.20 1.20 1.20 1.20 1.21 1.21 1.21 1.21 1.21 1.22 1.22 47 1.00 1.01 1.02 1.03 1.04 1.05 1.06 1.07 1.08 1.08 1.09 1.10 1.10 1.11 1.12 1.12 1.13 1.13 1.13 1.14 1.14 1.15 1.15 1.15 1.16 1.16 1.16 1.16 1.17 1.17 1.17 1.17 1.18 1.18 1.18 1.18 1.19 1.19 1.19 1.19 1.19 1.19 1.20 48 1.00 1.01 1.02 1.03 1.04 1.05 1.05 1.06 1.07 1.08 1.08 1.09 1.09 1.10 1.10 1.11 1.11 1.12 1.12 1.12 1.13 1.13 1.13 1.14 1.14 1.14 1.14 1.15 1.15 1.15 1.15 1.16 1.16 1.16 1.16 1.16 1.17 1.17 1.17 1.17 1.17 1.17 1.18 49 1.00 1.01 1.02 1.03 1.03 1.04 1.05 1.05 1.06 1.07 1.07 1.08 1.08 1.09 1.09 1.10 1.10 1.10 1.11 1.11 1.11 1.12 1.12 1.12 1.12 1.13 1.13 1.13 1.13 1.13 1.14 1.14 1.14 1.14 1.14 1.14 1.15 1.15 1.15 1.15 1.15 1.15 1.15 50 1.00 1.01 1.01 1.02 1.03 1.04 1.04 1.05 1.05 1.06 1.06 1.07 1.07 1.08 1.08 1.08 1.09 1.09 1.09 1.10 1.10 1.10 1.10 1.11 1.11 1.11 1.11 1.11 1.12 1.12 1.12 1.12 1.12 1.12 1.13 1.13 1.13 1.13 1.13 1.13 1.13 1.13 1.14 51 1.00 1.01 1.01 1.02 1.03 1.03 1.04 1.04 1.05 1.05 1.06 1.06 1.06 1.07 1.07 1.07 1.08 1.08 1.08 1.08 1.09 1.09 1.09 1.09 1.09 1.10 1.10 1.10 1.10 1.10 1.10 1.10 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.12 1.12 1.12 52 1.00 1.01 1.01 1.02 1.02 1.03 1.03 1.04 1.04 1.04 1.05 1.05 1.05 1.06 1.06 1.06 1.06 1.07 1.07 1.07 1.07 1.07 1.08 1.08 1.08 1.08 1.08 1.08 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.10 1.10 1.10 1.10 1.10 1.10 53 1.00 1.00 1.01 1.01 1.02 1.02 1.03 1.03 1.03 1.04 1.04 1.04 1.04 1.05 1.05 1.05 1.05 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.08 1.08 1.08 1.08 1.08 1.08 1.08 1.08 1.08 1.08 54 1.00 1.00 1.01 1.01 1.01 1.02 1.02 1.02 1.03 1.03 1.03 1.03 1.04 1.04 1.04 1.04 1.04 1.04 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.07 1.07 55 1.00 1.00 1.01 1.01 1.01 1.01 1.02 1.02 1.02 1.02 1.02 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 56 1.00 1.00 1.00 1.01 1.01 1.01 1.01 1.01 1.01 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 57 1.00 1.00 1.00 1.00 1.00 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 58 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2.0 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 2.9 3.0 3.1 3.2 3.3 3.4 3.5 3.6 3.7 3.8 3.9 4.0 4.1 4.2 RPM Fs as f(n,CV,Confidence,UpperBound) 400.00 350.00 300.00 0 mu 250.00 u_ c 0 1 200.00 V Z. 5 150.00 100.00 n 350.00-400.00 L 300.00-350.00 ❑ 250.00-300.00 ❑ 200.00-250.00 150.00-200.00 100.00-150.00 ❑ 50.00-100.00 ❑ 0.00-50.00 Coefficient of Variation 4.3 4.4 4.5 4.6 4.7 4.8 4.9 5.0 5.1 5.2 5.3 5.4 5.5 5.6 5.7 5.8 5.9 6.0 6.1 n 289.83 302.12 314.57 327.19 339.96 352.88 365.95 37,.1, 39z.53 406.03 41,o6 433.43 447.33 461.35 475.50 489.76 DU,-LD 518.65 533.27 1 63.09 65.03 66.98 68.93 70.89 72.85 74.81 76.78 78.75 80.72 82.69 84.67 86.64 88.62 90.60 92.58 94.56 96.54 98.52 2 30.38 31.15 31.92 32.68 33.44 34.20 34.96 35.72 36.47 37.22 37.97 38.71 39.46 40.20 40.93 41.67 42.40 43.13 43.86 3 19.14 19.56 19.98 20.39 20.80 21.21 21.61 22.02 22.42 22.82 23.21 23.61 24.00 24.39 24.77 25.16 25.54 25.92 26.30 4 13.75 14.02 14.28 14.55 14.81 15.06 15.32 15.57 15.82 16.07 16.32 16.56 16.81 17.05 17.29 17.53 17.76 18.00 18.23 5 10.66 10.85 11.04 11.22 11.40 11.58 11.76 11.93 12.10 12.28 12.45 12.62 12.78 12.95 13.11 13.28 13.44 13.60 13.76 6 8.69 8.83 8.96 9.10 9.23 9.37 9.50 9.63 9.75 9.88 10.01 10.13 10.25 10.37 10.49 10.61 10.73 10.85 10.96 7 7.33 7.43 7.54 7.65 7.75 7.85 7.95 8.05 8.15 8.25 8.34 8.44 8.53 8.63 8.72 8.81 8.90 8.99 9.08 8 6.34 6.42 6.51 6.59 6.67 6.76 6.84 6.9` 6.99 7.07 7.15 7.22 7.30 -7.37 7.44 7.52 7.59 7.66 7.73 9 5.58 5.65 5.72 5.79 5.86 5.93 5.99 6.06 6.12 6.19 6.25 6.31 6.37 6.43 6.49 6.55 6.61 6.66 6.72 10 5.00 5.05 5.11 5.17 5.23 5.28 5.34 5.39 5.44 5.50 5.55 5.60 5.65 5.70 5.75 5.80 5.85 5.89 5.94 11 4.52 4.57 4.62 4.67 4.72 4.77 4.81 4.86 4.90 4.95 4.99 5.03 5.08 5.12 5.16 5.20 5.24 5.28 5.32 12 4.14 4.18 4.22 4.26 4.30 4.35 4.38 4.42 4.46 4.50 4.54 4.57 4.61 4.65 4.68 4.72 4.75 4.78 4.82 13 3.81 3.85 3.89 3.92 3.96 3.99 4.03 4.06 4.10 4.13 4.16 4.19 4.22 4.26 4.29 4.32 4.35 4.37 4.40 14 3.54 3.57 3.60 3.64 3.67 3.70 3.73 3.76 3.79 3.82 3.84 3.87 3.90 3.93 3.95 3.98 4.00 4.03 4.05 15 3.30 3.33 3.36 3.39 3.42 3.44 3.47 3.50 3.52 3.55 3.57 3.60 3.62 3.65 3.67 3.69 3.71 3.74 3.76 16 3.10 3.13 3.15 3.18 3.20 3.23 3.25 3.27 3.30 3.32 3.34 3.36 3.38 3.40 3.42 3.44 3.46 3.48 3.50 17 2.92 2.95 2.97 2.99 3.01 3.03 3.06 3.08 3.10 3.12 3.14 3.16 3.17 3.19 3.21 3.23 3.25 3.26 3.28 18 2.77 2.79 2.81 2.83 2.85 2.87 2.89 2.90 2.92 2.94 2.96 2.97 2.99 3.01 3.02 3.04 3.06 3.07 3.09 19 2.63 2.65 2.66 2.68 2.70 2.72 2.73 2.75 2.77 2.78 2.80 2.81 2.83 2.84 2.86 2.87 2.89 2.90 2.91 20 2.50 2.52 2.54 2.55 2.57 2.58 2.60 2.61 2.63 2.64 2.66 2.67 2.68 2.70 2.71 2.72 2.74 2.75 2.76 21 2.39 2.41 2.42 2.44 2.45 2.46 2.48 2.49 2.50 2.52 2.53 2.54 2.56 2.57 2.58 2.59 2.60 2.61 2.63 22 2.29 2.30 2.32 2.33 2.34 2.36 2.37 2.38 2.39 2.40 2.42 2.43 2.44 2.45 2.46 2.47 2.48 2.49 2.50 23 2.20 2.21 2.22 2.23 2.25 2.26 2.27 2.28 2.29 2.30 2.31 2.32 2.33 2.34 2.35 2.36 2.37 2.38 2.39 24 2.11 2.12 2.13 2.15 2.16 2.17 2.18 2.19 2.20 2.21 2.22 2.23 2.24 2.25 2.25 2.26 2.27 2.28 2.29 25 2.03 2.04 2.06 2.07 2.08 2.09 2.09 2.10 2.11 2.12 2.13 2.14 2.15 2.16 2.16 2.17 2.18 2.19 2.20 26 1.96 1.97 1.98 1.99 2.00 2.01 2.02 2.03 2.04 2.04 2.05 2.06 2.07 2.07 2.08 2.09 2.10 2.10 2.11 27 1.90 1.91 1.91 1.92 1.93 1.94 1.95 1.96 1.96 1.97 1.98 1.99 1.99 2.00 2.01 2.01 2.02 2.03 2.03 28 1.84 1.84 1.85 1.86 1.87 1.88 1.88 1.89 1.90 1.90 1.91 1.92 1.92 1.93 1.94 1.94 1.95 1.95 1.96 29 1.78 1.79 1.79 1.80 1.81 1.82 1.82 1.83 1.84 1.84 1.85 1.85 1.86 1.87 1.87 1.88 1.88 1.89 1.89 30 1.73 1.73 1.74 1.75 1.75 1.76 1.77 1.77 1.78 1.78 1.79 1.80 1.80 1.81 1.81 1.82 1.82 1.83 1.83 31 1.68 1.68 1.69 1.70 1.70 1.71 1.71 1.72 1.72 1.73 1.74 1.74 1.75 1.75 1.76 1.76 1.76 1.77 1.77 32 1.63 1.64 1.64 1.65 1.65 1.66 1.66 1.67 1.67 1.68 1.68 1.69 1.69 1.70 1.70 1.71 1.71 1.72 1.72 33 1.59 1.59 1.60 1.60 1.61 1.61 1.62 1.62 1.63 1.63 1.64 1.64 1.65 1.65 1.65 1.66 1.66 1.67 1.67 34 1.55 1.55 1.56 1.56 1.57 1.57 1.58 1.58 1.58 1.59 1.59 1.60 1.60 1.60 1.61 1.61 1.61 1.62 1.62 35 1.51 1.51 1.52 1.52 1.53 1.53 1.53 1.54 1.54 1.55 1.55 1.55 1.56 1.56 1.56 1.57 1.57 1.57 1.58 36 1.47 1.48 1.48 1.49 1.49 1.49 1.50 1.50 1.50 1.51 1.51 1.51 1.52 1.52 1.52 1.53 1.53 1.53 1.54 37 1.44 1.44 1.45 1.45 1.45 1.46 1.46 1.46 1.47 1.47 1.47 1.48 1.48 1.48 1.48 1.49 1.49 1.49 1.50 38 1.41 1.41 1.41 1.42 1.42 1.42 1.43 1.43 1.43 1.43 1.44 1.44 1.44 1.45 1.45 1.45 1.45 1.46 1.46 39 1.38 1.38 1.38 1.38 1.39 1.39 1.39 1.40 1.40 1.40 1.40 1.41 1.41 1.41 1.41 1.42 1.42 1.42 1.42 40 1.35 1.35 1.35 1.35 1.36 1.36 1.36 1.37 1.37 1.37 1.37 1.37 1.38 1.38 1.38 1.38 1.39 1.39 1.39 41 1.32 1.32 1.32 1.33 1.33 1.33 1.33 1.34 1.34 1.34 1.34 1.34 1.35 1.35 1.35 1.35 1.35 1.36 1.36 42 1.29 1.29 1.30 1.30 1.30 1.30 1.31 1.31 1.31 1.31 1.31 1.32 1.32 1.32 1.32 1.32 1.32 1.33 1.33 43 1.27 1.27 1.27 1.27 1.28 1.28 1.28 1.28 1.28 1.28 1.29 1.29 1.29 1.29 1.29 1.29 1.30 1.30 1.30 44 1.24 1.24 1.25 1.25 1.25 1.25 1.25 1.26 1.26 1.26 1.26 1.26 1.26 1.26 1.27 1.27 1.27 1.27 1.27 45 1.22 1.22 1.22 1.22 1.23 1.23 1.23 1.23 1.23 1.23 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.25 46 1.20 1.20 1.20 1.20 1.20 1.21 1.21 1.21 1.21 1.21 1.21 1.21 1.21 1.22 1.22 1.22 1.22 1.22 1.22 47 1.18 1.18 1.18 1.18 1.18 1.18 1.18 1.19 1.19 1.19 1.19 1.19 1.19 1.19 1.19 1.19 1.20 1.20 1.20 48 1.16 1.16 1.16 1.16 1.16 1.16 1.16 1.16 1.17 1.17 1.17 1.17 1.17 1.17 1.17 1.17 1.17 1.17 1.17 49 1.14 1.14 1.14 1.14 1.14 1.14 1.14 1.14 1.14 1.15 1.15 1.15 1.15 1.15 1.15 1.15 1.15 1.15 1.15 50 1.12 1.12 1.12 1.12 1.12 1.12 1.12 1.12 1.12 1.13 1.13 1.13 1.13 1.13 1.13 1.13 1.13 1.13 1.13 51 1.10 1.10 1.10 1.10 1.10 1.10 1.10 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.11 52 1.08 1.08 1.08 1.08 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 53 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 54 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.06 1.06 1.06 1.06 55 1.03 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 56 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 57 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 58 4.3 4.4 4.5 4.6 4.7 4.8 4.9 5.0 5.1 5.2 5.3 5.4 5.5 5.6 5.7 5.8 5.9 6.0 6.1 9/11/2013 rdb New freshwater RPA based on 95% probability/95% confidence Statistically 58 points are the maximum number of points allowed under this RPA program. Data fields were estbalished to allow only 58 data point entries. Additional messages will appear to alert user if more than 58 data points were enter and no predicted values will be calculated All worksheets are "Protected" The "mf calculator" is password "Protected" OTHER CHANGES FROM PREVIOUS RPA PROGRAM: A. When Model is applied (Check box activated): 1) assumes only chroinc dilution known 2) assumes user will insert appropriate flow values for "7Q10s (cfs)", "7Q10w (cfs)", "30Q2 (cfs)", "QA (cfs)" to define chronic dilution in terms of "IWC %", "IWC %" is the same for all stream flows 3) automatically assigns the entered chronic IWC % to the "IWC @ 7Q10s", "IWC @ 7Q10w", "IWC @ 30Q2", "IWC @ QA" values used in chronic WQS calculations (See "RPA" page) 3) "1 Q10s (cfs)" automatically defaults to no acute dilution, acute IWC = 100% ,"IWC @ 1 Q10s" = 100% which is used in acute WQS calculatons (See "RPA" page) B. When Model is not applied (Check box NOT activated): 1) assumes user will insert appropriate flow values for "7Q10s (cfs)", "7Q10w (cfs)", "30Q2 (cfs)", "QA (cfs)" , "Flow Qw (MGD)" for chronic IWC % calculations, IWC % will vary according to flows 3) automatically calculates chronic -based IWC % for the "IWC @ 7Q10s", "IWC @ 7Q10w", "IWC @ 30Q2", "IWC @ QA" values used in chronic WQS calculations (See "RPA" page) 3) "1 Q10s (cfs)" is automatically calculated bases on entered "7Q10s (cfs)" flow 4) automatically calculates acute -based IWC% for the "IWC @ 1 Q10s" value used in acute WQS calculations (See "RPA" page) C. When paremeter's "Impaired?" check box is activated: 1) automtically activtes the "IMPAIRED" message alert on the "RPA" page for that parameter 2) does NOT make any automatic adjustements to WQS calculations NOTE: If new or expanding discharge and receiving stream impaired, will need to evaluate if additional waste load is allowed 10/30/2013 rdb 1) Amended cRR" alert on data sets entreies to activate if "<" entered but no value entered, does not effect RPA calculation, ERR message only 2) Added new calculation feature to count nondetects when both "<" and a value are entered for each data set, used to calculate detected entries 3) Amended "Comments" drop down menu - per Juile 4) Turned the Chronic toxicity concentration message off on the RPA page - per Julie 2/10/14: ON "data" page changed highlighted area from blue shades to gray 5/2/14 rdb 1) Increased rounding factor on all calculated IWC% to 7 decimals 2) Increased display for all calkculated to 6 decimals places. 5/5/14 rdb Increased rounding factor on all calculated IWC% to 9 decimals 5/21 / 14 rdb Removed ROUND function from all IWC% calculations 7/31/14 rdb Moved RPA page tile blocks down one row so header text was separated 9/9/15: COMPLETED REVISIONS FOR METAL TRANSLATOR FEATURE 1) Added tabs for "HUC Hardness" (lookup table for HUC hardness values), "Hardness Equations" (summary of translator formulas, metals impacted, general info), "Dss to Total Hardness Calculator" (calcution sheet for metal translator, impacted chronic and acute wqs) 2) Revised "Input" page Table 1: - New user input for "8 Digit HUC Number" uisng drop down menu for lookup HUC Hardness, required entry, brown highlight - New display only for calculated "Effluent Hardness (Median)" including conditional method for info display, brown highlight - New display only for designed "HUC Hardness (Median)" incuding conditionla method for info display, brown highlight - New display only for calculated "Combined Hardness Chronic" for metal translator application, brown highlight - New display only for calculated "Combined Hardness Acute" for metal translator application, brown highlight - Assigned name for "HUC Number" 3) Revised "Input" pade Table 2: - Removed "Impaired ?" column, conditional display, references - Added new column for "WQS" designation incuding assigning applicable WQS where fixed - Added new error message "CHECK WQS", conditonal control based on "WQS" entry for Cadmium, Chlorides, Molybdeum, Nickel - Revised text in error message - Added new brown highlight "Metal Translator Data Entry" label box - Removed Par01 "Arsenic" line - Revised Par02 " Arsenic" line to reflect Human Health and Water Supply criterion, Chronic = 10 mg/L, Acute = "N/A" - Revised Par04 "Cadmium" line: a) "WQS" input with drop down menu to select applicable criterion b) "Chronic" and "Acute" inputs to display calculated metal translator values including conditional method for info display based on "WQS" selection, no rounding c) "Modifier" input display only based on "WQS" selection including conditional method for info dispaly d) Conditonal controls to activate error nessages, brown highlight - Revised Par05 "Chloride (AL)" line: a) "WQS" input with drop down menu to select applicable criterion b) "Chronic" display only for applicable value including conditional method for info display based on "WQS" selection c) "Modifier" input display only based on "WQS" selection including conditional method for info dispaly d) "Name" display only based on "WQS" selection including conditional metdod fro info display e) Conditonal controls to activate error nessages - Revised "Chromium, Total" line: a) Removed Par08 label b) "Chronic" and "Acute" inputs to display calculated metal translator values, no rounding c) brown highlight - Added new "Chromium III" line: a) Assigned applicable text in "WQS", "Type", Modifier", Units" b) "Chronic" and "Acute" inputs to display calculated metal translator values, no rounding c) brown highlight - Added new Par08 "Chromium VI" line: a) Assigned Par08 label, applicable text in "WQS", "Type", Modifier", Units" b) "Chronic" and "Acute" inputs to display calculated metal translator values, no rounding c) brown highlight - Revised Par09 "Copper (AL)" line: a) "Chronic" and "Acute" inputs to display calculated metal translator values, no rounding b) brown highlight - Revisd Par12 "Lead" line: a) "Chronic" and "Acute" inputs to display calculated metal translator values, no rounding b) brown highlight - Revised Par14 "Molybdenum" lime: a) "WQS" input with drop down menu to select applicable criterion b) "Chronic" display only for applicable value including conditional method for info display based on "WQS" selection c) "Modifier" input display only based on "WQS" selection including conditional method for info dispaly d) Conditonal controls to activate error nessages - Revised Par15 "Nickel" line: a) "WQS" input with drop down menu to select applicable criterion b) "Chronic" and "Acute" inputs to display calculated metal translator values including conditional method for info display based on "WQS" selection, no rounding c) "Modifier" input display only based on "WQS" selection including conditional method for info dispaly d) Conditonal controls to activate error nessages, brown highlight - Revised Par17 "Silver (AL)" line: a) "Chronic" and "Acute" inputs to display calculated metal translator values, no rounding b) brown highlight - Revised Par18 "Zinc (AL)" line: a) "Chronic" and "Acute" inputs to display calculated metal translator values, no rounding b) brown highlight 3) Revised "Data" page: - Revised Par01 "Arsenic" entry, text, and calculations ("1") - all effluent hardness data to be entered in this section for used to calculate eflluent hardness factors a) Reference to Par01 "Arsenic" removed b) New label "Effluent Hardness (monthly average)" added c) "Mult Factor =" and "Max. Pred Cw" removed, text and calcuation d) "10% value" and "Median value" added, text and calculation including conditional method for info display e) Assigned name "Effluent_Median" and "effluent_10" to calculated values f) PQL condition removed from calculation method for data displayed 4) Revised "RPA" page: - Removed all features assocaited with "Impairment" - Added new display only for calculated "COMBINED HARDNESS (mg/L)", Chonic and Acute, conditional method for info display - Revised "Receiving Stream" display to include selected HUC Number in text - Removed unused display features for WET % (previouly hidden) - Revised "Arsenic" lines: a) Par01 "Arsenic" line removed b) Par02 "Arsenic" references used for display to calculate "Acute" and Chronic" allowable Cw - Revised "Cadmium", "Chromium VI", "Copper (AL)", "Lead", "Nickel", "Silver (AL)", "Zinc (AL)" (lines: a) "NC WQS/Chronic" and 1/2 FAV/Acute" conditional method revised for info display, no rounding b) "Allowable Cw" Acute" and "Chronic" conditional metfhod revised fro info display inculding rounding value 5) Revised "Dss to Total Metal Hardness Calculator" page - Assigned names for: a) "CdMAE_AC' - Cadmium calculated metal translator Acute value b) "CdMAE_CH' - Cadmium calculated metal translator Chronic value c) "CuMAE_AC" - Copper calculatd metal translator Acute value d) "CuMAE_CH" - Copper calculated metal translator Chronic value e) "Cr_Total_AC' - Total Chromium calculated meat) translator Acute value f) "Cr_Total_CH' - Total Chromium calculated metal translator Chronic value g) "CrIIIMAE_AC" - Chromium III calculated metal translator Acute value. h) "CrIIIMAE_CH' - Chromium III calculated metal tramslator Chronic value i) "CrVIMAE_AC' - Chromium VI calculated metal translator Acute value j) "CrVINAE_CH' - Chromium VI calculatd metal translator Chronic value k) "PbMAE_AC' - Lead calculated metal translator Acute value m) "PbMAE_CH' - Lead calculated metal translator Chronic value n) "NiMAE_AC' - Nickel calculated metal translator Acute value o) "NiMAE_CH' - Nickel calculated metal translator Chroniv value p) "AuMAE_AC' - Silver calculated metal translator Acute value q) "AuMAE_CH" - Silver calculated metal translator Chronic value r) "ZnMAE-AC" - Zinc calculated metal translator Acute value s) "ZnMAE_CH' - Zinc calculated metal translator Chronic value t) "tss" - assigned TSS harness factor u) "CHA" - calculated combined acute hardness value v) "CHC" - calculated combined chronic hardness value - Added conditional methods to formulas for info display and to incorporate names, no rounding 6) Set up passwortd to protect all pages 'rpa2015' 1/12/16 ADDED ARSENIC AQUATIC LIFE PARAMETER BACK TO ACTIVE RPA EVALUATION 1) Inserted "Aresenic, Aquatic Life, C, 50, FW, N/A, pg/L" in first row "INPUT" Table 2, Par01 2) Updated program names to reflect addition of new Arsenic Aquatic Life parameter 3) Inserted "Arsenic" Aquatic Life parameter and cell programming in Arsenic section "RPA" as Chronic and added drop down menu feature 4) Amended labels on "Data" to show H for hardnes and Par01-Par22 for paremeters 1/12/16 REVISED IWC CALCULATIONS TO SHOW FULL DISPLAY on "RPA" 1) Reformatted IWC calculation cells to show caculated value as general (number value will always be displayed) 2) Revised IWC calculation formula to x by 100 to mimic % 3) Revised IWC calculation labels to include "%" 4) Revised all calculations using IWC values "Acute", "Chronic" to divide by 100 to correct for IWC % value 1/12/16 REVISED SPREADSHEET TO INDICATE NO DETECT AND MDL 1) Revised "Data" Par01-Par22 Max Value cell conditional statement to display "NO DETECTS" when data set has all no detects 2) Revised "RPA" all parameters Max Pred CW cell formatting to display "NO DETECTS" when required to display no detects 3) Revised "RPA" alert message (under Chronic labels) conditional statement to display "Max MDL = <2 x max adjusted data set value>" when data set has all no detects 4) Revised "RPA" drop menu to add "No detects" to list and display 1/12/16: Corrected formula error in mf formula Par01 to use corrected data set ("Data") Revised "RPA" Cadmium, Copper, Lead, Nickel, Silver, Zinc Acute and Chronic cell conditional statements to have cell display blank if WQS is blank or WQS displays "NO DATA" 1/21-29/16: 1) Expanded parameter list and program features to add two additional parameters, (Par08) "Chromium III" & (Par09) "Chromium VI". This included adding two new data input sections on "Data" tab with new corresponding RPA evalutaion, non -detect evaluation, formulas for each new data input section; adding two new parameter summary sections to "RPA" tab; revising exsiting parameter designation to new assigned name (Par10 - Par24), data set (_Data08 - _Data24), non -detects (_ND08 - _ND24). 2) For consistency rearranged display, "Input" & "RPA" tabs, to be "Chromium III", "Chromium VI", "Chromium, Total". All features and programing unique to each display was revised accordingly. 3) Corrected Arsenic - Aquatic Life, Berylium Chronic and Acute values on "Input" tab to be exported from metal translator table. 4) Revised "Input" tab HUC Hardness (median) display conditional formula to display "default 25 mg/L (HUC Hard Med = NA mg/I)" when HUC hardness is NA. 5) Revised combined hardness acute (CHA) and combined hardness chronic (CHC) conditional formulas to assign 25 as hardness value when HUC hardness is NA. 6) Revised "RPA" tab Chromium, Total Reasonable Potential Results section to remove Acute and Chronic labels and allowable Cw calulation/display, area now blank except for MDL feature display. 7) Revised "RPA" tab Chromium III and Chromium VI Reasonable Potential Results sectons to remove display of values for n, #Det, Max Pred Cw, area blank except for display features from added condtional formulas that reference Chromium, Total display and data. NOTE: All RPA evaluation data is generated on each parameter "Data" section and imported to that parameter's "RPA" section, thus, RPA evaluation data can be displayed/used when programmed to do so. 8) Revised "RPA" tab Acute and Chronic conditional formulas for active parameters to display either "IWC?" or "IWC/DATA?" as default until appropraite data is provided. 9) Removed label from "Input" tab. 10) Corrected chlorinated list ("Input" & "Data" tabs) lists, now shows correct 2,4,6-trichlorophenol for Method 625. See task notes 2/3/16: Revised "input"page model feature to a- Add new model 1 Q10S input cell that is visible on;y when model feature is activated b- Revise cell formula 1 Q10s (cfs) to display 1 Q10s flow when model feature activated or calculate from 7Q10s flow when model feature NOT activated and 7Q10s flow displayed c- Revised instructions narrartive that is visible only when model feature is activated 2/9/16: Revised "input" page Effluent Hardness (Median) cell formula to display "default 99 mg/L (Efflunet Hard Med = <actual value> mg/L)" when stream class is WS and Effluent Hard Med is greater than 99.999 mg/L Revised "data" page Effluent Hardness (Median) cell formula to display 99 whenstream class is WS and Effluent Hard Med is greater than 99.999 mg/L Added new display messages to "rpa" page that are visible only when the steam class is water supply 2/16/16: 1) Revised "Diss to Total Metal Calculator" page: added new cells to display actual calculated Effluent & HUC Median values and to display "Apply Water Supply Criterion" when applicable (stream class is Water Supply based and Efflunet Hard Med exceeds 99.999 mg/L) revised the existing calculation input/display cells for Effluent & HUC Hardness Median to show the applied hardness value based on new conditional formula as follows a- If HUC Hard Med = NA or less than 25 mg/L then default HUC Hard Med to 25 mg/L b- If Effluent Hard Med less than 25 then default Effluent Hard Med to 25 mg/L c- If stream class is WS and Effluent Hard Med is greater than 99.9999 mg/L then default Effluent Hard Med to 99 mg/L 2) Revised "input" page dipplay HUC Hardness (Median) to show NA when HUC table value is NA. 2/19/16 Added new WS WQC button to "input" page, activates effluent hardness to apply WS WQC standards, does NOT set parameter modifiers, still must do modifers individually Added Nickel WS parameter to "input" page Added Nichel WS to "rpa" page, revised both Nickel parametesr to share commom data, Nickel WS has no Acute standard so only list acute for FW Set up both Nickel Par17 & Par18 to use same data entries Changed Par22-25 modifier cells to be set automtically based on WQS entry. Changed display font color phenols, chlorinared phenols menus 2/22/16: Make text changes per Julie direction. 2/24/16: Added to " Diss to Total Metal Calculator" page: 1) Comment section for PERCS info or other to allow user to add commentary 2) Added Facility name to display based on input page 3) Added NPDES permit# to display based on input page 4) Set up new Name "PERCS_page" as print area for table and other PERCS info for GOTO use. NOTE: User can either highlight desire print area or use GOTO feature to set up desired print arae. When in print mode set up, will need to designate "Print Selection".