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HomeMy WebLinkAboutNC0004987_Initial Certification Statement Discharge Bottom Ash Transport Water_20211013 Julie K.Turner,Vice President •k DUKE Carolinas Coal Generation 410 S.Wilmington Street ENERGY Raleigh, NC 27601 o:919.546.6227 Julie.Turner@duke-energy.com Sergei Chernikov,Ph.D. North Carolina Department of Environmental Quality Division of Water Resources Industrial NPDES Permitting Unit 1617 Mail Service Center Raleigh,NC 27699-1617 RECEIVED Reference: Duke Energy Progress,LLC O C T 13 2021 Duke Energy Carolinas,LLC Initial Certification-40 CFR§423.19(c) NCDEQIDWRINPDES Dear Dr. Chernikov: On November 3, 2015,the U.S. Environmental Protection Agency (EPA) issued the Federal Steam Electric Power Generating Effluent Limit Guidelines and Standards (ELG Rule). The 2015 rule addressed discharges from a number of sources, including bottom ash transport water. On October 13, 2020,the rule was reconsidered by EPA and revisions were effective as of December 14, 2020. The final rule revised limitations and standards for bottom ash transport water. Specifically,the final rule established Best Available Technology Economically Achievable(BAT) as a high recycle rate system with a site-specific volumetric purge which cannot exceed 10 percent of the bottom ash transport water system's volume on a 30-day rolling average. The enclosed documents provide the initial certification statement of the bottom ash system capacity as required by 40 CFR §423.19(c). Affected facilities include the following: • Allen Steam Station—Permit No.NC0004979 • Belews Creek Steam Station—Permit No.NC0024406 • Marshall Steam Station—Permit No.NC0004987 • Roxboro Steam Electric Plant—Permit No.NC0003425 In addition to providing the initial certification,this correspondence provides notification under NPDES Permit Standard Condition II.E.8: "Where the Permittee becomes aware that it failed to submit any relevant facts in a permit application, or submitted incorrect information in a permit application or in any report to the Director, it shall promptly submit such facts or information [40 CFR 122.41(1)(8))." Specifically, during the course of 2021,the referenced NPDES permits were modified to include updated language based on the October 13, 2020 revisions. Preliminary information on the capacity of the bottom ash transport systems was used to develop the applications and Sergei Chernikov,Ph.D. Initial Certification Page 2 subsequent permit revisions. As detailed in the attached documents,these values have changed permits are modified,this information will be corrected. In the interim,As we have stations to ensure that theywill comply with the updated values in worked with our generating p y p lieu of those shown in the permit. Closing If you have any questions or concerns about the information provided in this submittal,please do not hesitate to reach out to Ms. Cynthia Winston, PE at(919) 210-1931 or Cynthia.Winston@duke-energy.com. I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Sincerel , Julie K. urner Vice President, Carolinas Coal Generation Enclosures cc: Scott LaSala, Marshall Don Safrit,NCRH Robert Howard, Roxboro Lori Tollie, Lewisville Randy Gantt,Allen Elizabeth Glenn, Energy Center Brenda Johnson, Belews Creek Shannon Langley,NCRH Derek Henderson,NCRH Cynthia Winston,NCRH BURNS &MSDONNELL.. Marshall Steam Station Initial Certification Statement to Discharge Bottom Ash Transport Water e& DUKE lry RECEIVED ENERGY® OCT 13 2021 Duke Energy NCDEQIDWRINPDES Marshall Steam Station Project No. 133406 Revision 0 October 8, 2021 Marshall Steam Station Initial Certification Statement to Discharge Bottom Ash Transport Water Prepared for Duke Energy Marshall Steam Station Project No. 133406 Catawba County, North Carolina Revision 0 October 8, 2021 Prepared by Burns & McDonnell Consultants, Inc. Kansas City, Missouri INDEX AND CERTIFICATION Duke Energy Marshall Steam Station Initial Certification Statement to Discharge Bottom Ash Transport Water Report Index Chapter Number Number Chapter Title of Pages 1.0 Executive Summary 2 2.0 High Recycle System Description 8 Appendix A Bottom Ash Equipment System Volumes and Water Balance 12 Appendix B Bottom Ash Piping Detailed Build-Up 2 Certification I hereby certify,as a Professional Engineer in the State of North Carolina,that the information in this document was assembled under my direct personal charge. This report is not intended or represented to be suitable for reuse by Duke Energy or others without specific verification or adaptation by the Engineer. I hereby certify that this initial certification was prepared for the Duke Energy Marshall Steam Station in accordance with standard engineering practices and based on my knowledge, information,and belief,the content of this Certification when developed in October 2021 is true and meets the requirements of 40 CFR§ 423.191. I hereby certify that I am familiar with the ELG regulation requirements and Duke Energy's Marshall Steam Station. P FES /O,i, �/ 9j 4949 Dave Guinta, P.E. ` ;/ 360 - (North Carolina License No. PE045360) 10/08/2021 O,F Date: 10/8/2021 Owner's Certification of Compliance - 40 CFR 122.22 Pursuant to 40 CFR 122.22, I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is,to the best of my knowledge and belief,true, accurate,and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. On behalf of Duke Energy: ie K. Turner (Printed Name) Vice President, Carolinas Coal Generation (Title) October 12,2021 (Date) Marshall Steam Station Certification Letter Table of Contents TABLE OF CONTENTS Page No. 1.0 EXECUTIVE SUMMARY 1-1 2.0 HIGH RECYCLE SYSTEM DESCRIPTION 2-1 2.1 Bottom Ash System Description 2-1 2.2 List of All Potential Discharges under 40 CFR § 423.13(k)(2)(i)(A)(1)—(4) 2-3 2.2.1 Closed loop bottom ash chemistry considerations 2-5 2.3 Wastewater treatment systems at Marshall 2-7 APPENDIX A— BOTTOM ASH EQUIPMENT SYSTEM VOLUMES AND WATER BALANCE APPENDIX B — BOTTOM ASH PIPING DETAILED BUILD-UP Duke Energy—Marshall Steam Station TOC-1 Burns&McDonnell October 2021 Rev 0 Marshall Steam Station Certification Letter Table of Contents LIST OF TABLES Page No. Table 2-1: Marshall's Active Wetted Volume Summary 2-3 Table 2-2: Marshall's Purge Discharges 2-4 Table 2-3: Key to Scaling Indexes 2-5 Table 2-4: Scaling Indexes for Purge Calculations 2-6 Table 2-5: Marshall's Wastewater Treatment Systems 2-8 Duke Energy—Marshall Steam Station TOC-2 Burns&McDonnell October 2021 Rev 0 Marshall Steam Station Certification Letter List of Abbreviations LIST OF ABBREVIATIONS Abbreviation Term/Phrase/Name BA bottom ash BAT Best Available Technology Economically Achievable BMcD Burns&McDonnell Marshall Marshall Steam Station CCR Coal Combustion Residual CFR Code of Federal Regulations Duke Duke Energy ELG Rule Effluent Limitations Guidelines and Standards for the Steam Electric Power Generating Point Source Category EPA U.S.Environmental Protection Agency FGD flue gas desulfurization gpm gallons per minute LRBS Lined Retention Basin System SFC Submerged Flight Conveyor Duke Energy—Marshall Steam Station i Burns&McDonnell October 2021 Rev 0 Marshall Steam Station Certification Letter Executive Summary 1.0 EXECUTIVE SUMMARY On November 3,2015,the U.S.Environmental Protection Agency(EPA)issued the federal Steam Electric Power Generating Effluent Limit Guidelines and Standards (ELG); see 80 FR 67838. The 2015 rule addressed discharges from flue gas desulfurization(FGD)wastewater, fly ash transport water, bottom ash (BA) transport water, flue gas mercury control wastewater, gasification wastewater, combustion residual leachate,and non-chemical metal cleaning wastes. The 2015 rule was reconsidered by EPA, with updates finalized on October 13, 2020 (see 85 FR 64650), and effective as of December 14, 2020. The final rule revises limitations and standard for two of the waste streams addressed in the 2015 rule: BA transport water and FGD wastewater. For BA transport water,the final rule establishes Best Available Technology Economically Achievable (BAT) as a high recycle rate system with a site-specific volumetric purge (defined in the final rule as BA purge water) which cannot exceed 10 percent of the BA transport water system's volume where the purge volume and associated effluent limitations are established by the permitting authority. EPA selected a 95th percentile of total system volume as representative of a 30-day rolling average, which results in a limitation of 10 percent of total system volume and requires the NPDES permitting authority to develop a site-specific purge percentage that is capped at 10 percent. EPA recognizes that some plants may need to improve their equipment, process controls, and/or operations to consistently meet the limitations included in this final rule; however,this is consistent with the Clean Water Act, which requires that BAT discharge limitations and standards reflect the best available technology economically achievable. This document serves as the initial certification statement required by 40 CFR § 423.19(c). On behalf of Duke Energy(Duke),this initial certification seeks to discharge BA transport water pursuant to 40 Code of Federal Regulations (CFR) § 423.13(k)(2)(i) at the Marshall Steam Station (Marshall), located in Terrell, Catawba County,North Carolina.As required by the ELG Rule,this plan includes the following: A. A statement that the professional engineer is a licensed professional engineer. (refer to Index& Certification page) B. A statement that the professional engineer is familiar with the regulation requirements. (refer to Index&Certification page) C. A statement that the professional engineer is familiar with the facility. (refer to Index& Certification page) D. The primary active wetted bottom ash system volume in 40 CFR§ 423.11(aa). (refer to table 2-1) Duke Energy—Marshall Steam Station 1-1 Burns&McDonnell October 2021 Rev 0 Marshall Steam Station Certification Letter Executive Summary E. Material assumptions, information,and calculations used by the certifying professional engineer to determine the primary active wetted bottom ash system volume.(Refer to Appendices A and B) F. A list of all potential discharges under 40 CFR§ 423.13(k)(2)(i)(A)(1)through(4),the expected volume of each discharge,and the expected frequency of each discharge. (refer to Table 2-2) G. Material assumptions, information,and calculations used by the certifying professional engineer to determine the expected volume and frequency of each discharge, including a narrative discussion of why such water cannot be managed within the system and must be discharged. (refer to Table 2-2) H. A list of all wastewater treatment systems at the facility currently,or otherwise required by a date certain under this section. (refer to Table 2-5 and Section 2.4) I. A narrative discussion of each treatment system including the system type,design capacity,and current or expected operation. (refer to Table 2-5 and Section 2.4) Marshall consists of four operating coal-fired units: Unit 1 is a 400 MW pulverized coal fired unit built in 1965,Unit 2 is a 400 MW pulverized coal fired unit built in 1966,Unit 3 is a 700 MW pulverized coal fired unit built in 1969, and Unit 4 is a 700 MW pulverized coal fired unit built in 1970. These units were modified in 2020 and are now able to operate with either coal or natural gas as their fuel supply.Marshall's existing BAT high recycle system utilizes wet sluicing to transport bottom ash(when the units operate on coal) from each operating unit to a remote dewatering conveyor system to dewater the bottom ash. The system can be operated as a closed loop or as a high recycle rate system. Duke is requesting to purge up to 10 percent of the total system volume (up to 95,000 gallons per day) related to system water chemistry as allowed under 40 CFR§423.13(k)(2)(i). Duke Energy—Marshall Steam Station 1-2 Burns&McDonnell October 2021 Rev 0 Marshall Steam Station Certification Letter High Recycle System Description 2.0 HIGH RECYCLE SYSTEM DESCRIPTION As required by 40 CFR§423.19(c)(3)(D)through(I),the following is a description of the existing bottom ash system at Marshall, including the assumptions, information, and calculations used by the certifying professional engineer to determine the primary active wetted bottom ash system volume and the expected volume and frequency of each discharge. This section also includes a description of the wastewater treatment systems at Marshall. 2.1 Bottom Ash System Description Units 1, 2, 3 &4 each have one bottom ash hopper.After combustion, ash that accumulates in the bottom of the boiler(referred to as bottom ash) is captured in these bottom ash hoppers located directly beneath the boilers. Bottom ash is then crushed into small pieces by the crushers in each hopper before being sluiced by jet pumps to a system of remote dewatering conveyors. Each unit has a dedicated sluicing pipeline to convey bottom ash to the three remote dewatering conveyors. Bottom ash particles are settled in the operating conveyors with the assistance of lamella assemblies. The settled ash particles are then dragged out of the wetted portion of the conveyors and emptied into dewatering bunkers before being transported via truck to the CCR landfill for disposal. Transport water from the dewatering process overflows the operating conveyors into a single surge tank before being pumped back to the bottom ash system for recycling. The water from the surge tank is recycled for use as sluicing water for each bottom ash hopper, as well as to supply water to each hoppers seal trough and cooling water system. The hopper cooling and seal trough water supplied to each bottom ash hopper overflows into a hopper overflow tank,one dedicated to each hopper. This water collected in the overflow tanks is then conveyed to the operating remote dewatering conveyors. A Submerged Flight Conveyor(SFC) Sump is located near the remote dewatering conveyors which collects drainage from the bottom ash dewatering bunkers,and other drains and overflows from the bottom ash dewatering system. This water is then returned to the three remote dewatering conveyors. Major equipment for Marshall's bottom ash system consists of four boiler hoppers,three dewatering conveyors,three process overflow troughs, one surge tank,four bottom ash hopper overflow tanks,and the SFC sump. The sluice supply piping and the water return piping has been included in the system calculation as well,while the miscellaneous interconnecting piping throughout the system has been excluded. Duke Energy—Marshall Steam Station 2-1 Burns&McDonnell October 2021 Rev 0 Marshall Steam Station Certification Letter High Recycle System Description A summary of pertinent system data is provided in Table 2-1. A site plan can be found below on Figure 1. -i' ' 7 r ' , I I Iq Io / / 1 ( el t . l �I ��r■ttr I l 1 � r f1L „ " - „ .,„.�.„. i. � ./.+ ir . „.s.,,,..„ \ , __ _ _ „,,,t,,,i,, , _ ::4,/, BFCS X3 ( wl y ''r� 2 L''---------- A si. , - ' \ ' ��, 1 it ��T st r^ Surge �� !; it. Tank \// ✓ —""'_ I '7",0401 rir" Or .. BA Pipe T.O W� M� � Rack rc.w,wxwma • „/",/ 7-7'''''''',7:. -7/// /f \ 1 f/ / .. . .. . ,A'''' '''''':—.1/ I: ,,,,2://: .. ,..."'"',• ,t' i Narpi,'••••••‘11! I' , ,,, i L. ',.. •• • • ----••• ..,i..... ,'"'"—V0ii/ • • Units 1 -4 Boiler %' 'i%' - r( / Building/Bottom Ash '!,/ .1, [1 Hopper Area * /' y (� . • . 40 R- , 46'...:\''''(7. ; ' ' ' ! r,.w iL 1 1 nn I -t_ 1' Figure 1 -Marshall Steam Station Plan Drawing Duke Energy—Marshall Steam Station 2-2 Burns&McDonnell October 2021 Rev 0 r Marshall Steam Station Certification Letter High Recycle System Description Table 2-1: Marshall's Active Wetted Volume Summary Description Qty Qty Total Component Cumulative Units Component Volume Volume System Volume (Gal) (Gal) (Gal) Unit 1 Bottom Ash Hopper 1 ea 21,692 21,692 21,692 Unit 2 Bottom Ash Hopper 1 ea 21,692 21,692 43,384 Unit 3 Bottom Ash Hoppers 1 ea 36,652 36,652 80,036 Unit 4 Bottom Ash Hoppers 1 ea 36,652 36,652 116,688 Unit 1 Bottom Ash Hopper 1 ea 2,003 2,003 118,691 Overflow Tank Unit 2 Bottom Ash Hopper 1 ea 2,003 2,003 120,694 Overflow Tank Unit 3 Bottom Ash Hopper 1 ea 2,003 2,003 122,698 Overflow Tanks Unit 4 Bottom Ash Hopper 1 ea 2,003 2,003 124,701 Overflow Tanks Dewatering Conveyors 3 ea 147,130 441,389 566,089 Process Overflow Trough 3 ea 5,028 15,085 581,174 SFC Sump 1 ea 7,719 7,719 588,894 Surge Tank 1 ea 221,759 221,759 810,653 Piping* 1 lot 138,993 138,993 949,646 Total Nominal Volume 949,650 10% gallon/day 94,965 10% gallon/hour 3,957 10% gallon/min 66 *For a detailed breakdown of the piping quantity see Appendix B. 2.2 List of All Potential Discharges under 40 CFR § 423.13(k)(2)(i)(A)(1) - (4) Table 2-2 summarizes the discharges from the bottom ash system at Marshall: Duke Energy-Marshall Steam Station 2-3 Burns&McDonnell October 2021 Rev 0 Marshall Steam Station Certification Letter High Recycle System Description Table 2-2: Marshall's Purge Discharges Discharge Average Stream Flow Description Frequency (gpm)" Following significant storm events. The system was designed to manage a 25-year/24-hour storm event Precipitation-related inflows equivalent to 6"of rainfall atop open generated from storm events top tanks and sump,or 25,100 gallons. exceeding a 10-year storm event of This volume would replace up to 17.4 (A)(1) 24-hour or longer duration(e.g.,30- gpm of makeup water during the once Stormwater NA day storm event)and cannot be in 25-year event.In the event of a managed by installed spares, large enough storm,or repeated redundancies,maintenance tanks, events,excess water would be and other secondary bottom ash managed within the maintenance tank system equipment and spares to the extent possible,but ultimately some water would have to be removed to prevent overtopping. (A)(2) Regular inflows from wastestreams Additional wastestreams are not other than bottom ash transport comingled with the bottom ash system Process NA water that exceed the ability of the at Marshall and,therefore,will not Wastestreams bottom ash system to accept require discharge. recycled water Makeup water is very soft and very corrosive.Water within the bottom To maintain system water ash system also has strong corrosive chemistry where installed tendencies that increase over time (A)(3) equipment at the facility is unable when the system is operating. Sulfate Water to manage pH,corrosive concentrations are about 117 times 66 substances, substances or higher than the lake water that feeds Chemistry conditions causing scaling,or fine the system when operating closed Purge particulates to below levels which loop.A minimum 10%purge is impact system operation or needed along with pH adjustment to maintenance help address corrosion concerns during the intermittent operating periods. To conduct maintenance not otherwise included in(A)(1),(2), The system includes a Maintenance or(3)of this table and not tank. If the system must be drained (A)(4) exempted from the definition of for maintenance,the water is Maintenance NA transport water in§423.11(p), and transferred to the maintenance tank when water volumes cannot be and will be either returned to the Flows managed by installed spares, system or purged in accordance with redundancies,maintenance tanks, the 10%discharge restrictions. and other secondary bottom ash system equipment Duke Energy—Marshall Steam Station 2-4 Burns&McDonnell October 2021 Rev 0 Marshall Steam Station Certification Letter High Recycle System Description 2.2.1 Closed loop bottom ash chemistry considerations Marshall has been operating as a closed-loop system since 2019. During that time, the bottom ash system has experienced corrosion. Duke installed pH and alkalinity control equipment in 2020 to mitigate the effects of the chemistry concerns, but the system continues to exhibit high concentrations of dissolved solids,with sulfate concentrations averaging 117 times that of the incoming lake water. Several scaling indices can be used to model the scaling and corrosive properties of the water. These are the Puckorius Scaling Index(PSI),The Ryznar Scaling Index(RSI),the Langelier Scaling Index(LSI), and the Larson-Skold index(L-SI). The PSI,RSI, and LSI all use alkalinity,hardness,temperature, and pH to estimate calcium scale and corrosivity, comparing the pH of the system to the equilibrium pH and the pH of saturation.The L-SI looks at the concentrations of carbonate,bicarbonate, sulfate, and chloride to estimate the tendency for sulfate and chloride to interfere with scale formation and to support corrosion due to sulfate and chloride chemistry. The target ranges for these indices are shown in Table 2-3. Table 2-3: Key to Scaling Indexes PSI RSI LSI L-SI Extreme Corrosion >9.0 >9.0 <-2 >4.0 >7.5-9.0 >7.5-9.0 -2.0- -0.5 1.2-4.0 Slight Corrosion >7.0-7.5 >7.0-7.5 >-0.5-0.0 0.8-<1.2 In range >6.0-7.0 >6.0-7.0 >0.0-0.5 <0.8 Slight Scaling 5.0-6.0 5.0-6.0 >0.5-2.0 NA Heavy Scaling <5.0 <5.0 >2.0 NA Burns&McDonnell prepared a model of the bottom ash system to simulate existing conditions and to predict future conditions under a variety of operating scenarios.For comparison,the model showed a makeup water rate of 62 gpm to achieve the same bottom ash water quality that was observed in the system.The model was then used to calculate the index values and show the potential for scale formation or corrosion. Table 2-4 below provides a summary of these results for several potential operating scenarios. Duke Energy-Marshall Steam Station 2-5 Burns&McDonnell October 2021 Rev 0 Marshall Steam Station Certification Letter High Recycle System Description Table 2-4: Scaling Indexes for Purge Calculations 10%+ 2021 10%Purge Index Current Condition gpm* Makeup Makeup GPM 62 87 107 Dragout or Purge GPM 41 66 66 Purge% 6.20% 10% 10% pH 7.67 7.67 8.50 TDS mg/L 706 350 219 Calcium mg/L 95 51 31 Sulfate mg/L 374 224 131 Chloride mg/L 29.03 9.13 6.99 Puckorius SI 9.05 7.39 6.74 Ryznar SI 7.15 6.12 Langelier SI (0.12) 0.26 1.19 Larson-Skold Index 22.92 0.77 * pH control is assumed According to the design basis,the system is expected to operate at 1.59 cycles of concentration with 16 gpm of makeup. Both the makeup rate and the observed circulating concentrations are higher than the design basis would suggest. The current makeup rate is 62 gpm, about 4 times higher than the design basis,and the observed circulating concentrations range from 4.58 to 117 times higher than the source water. These observations suggest that either evaporation,dragout, and/or other system losses are higher than the design anticipated. The best fit predictor of sulfate concentrations was to assume that the system was operating at the lowest observed cycles of concentration(4.58). The system is operating as a closed loop,meaning that there is no active blowdown or purge. As ash is removed from the system,water adheres to the ash particles via surface tension,and then drains through the ash pile. Excess water is captured in drains,but a substantial portion of the water that has adhered to the ash evaporates or remains with the ash,rather than being returned to the system. The 2021 data shows that for the 2021 Condition case despite the current operation of pH and alkalinity control equipment the system water is corrosive to severely corrosive for all indexes. The 10%Purge column of Table 2-4 represents a scenario with a total purge volume of 10%or 66 gpm assuming that the current dragout rate represents a portion of the purge flow,and assuming that the system would operate with pH control to maintain the pH near current levels. It shows that this purge rate does not remove enough sulfate to bring all the indexes into a green or blue condition, which is desirable. Further adjustment to the chemistry is needed to meet scaling and corrosion indexes. Adding the 10% Duke Energy—Marshall Steam Station 2-6 Burns&McDonnell October 2021 Rev 0 Marshall Steam Station Certification Letter High Recycle System Description purge volume to the current dragout rate(considering current operations are closed loop) shows that a 10%purge plus pH control brings the system chemistry into acceptable ranges(see the 10%+Current Makeup column in Table 2-4).No further optimization is needed beyond the pH control. To achieve the index values shown in Table 2-4 for the 10%+Current Makeup column it was necessary to assume that the pH was adjusted to 8.5 by increasing both the bicarbonate and carbonate alkalinity within the system. It is therefore expected that even with a 10%blowdown,which will improve system chemistry, further chemical treatment will be needed to protect the materials of construction. 2.3 Wastewater treatment systems at Marshall Table 2-5 summarizes the existing water treatment systems at Marshall. Duke Energy—Marshall Steam Station 2-7 Burns&McDonnell October 2021 Rev 0 Marshall Steam Station Certification Letter High Recycle System Description Table 2-5: Marshall's Wastewater Treatment Systems System Design Capacity Current Operation Expected Operation Type Physical/chemical treatment with pH adjustment, coagulant, organosulfide, Discharge to Lined FGD clarification, sand filtration, Retention Basin System Wastewater 550 gpm (excluding and solids handling. (LRBS)with eventual Treatment cooling water) Downstream of discharge via NPDES System physical/chemical treatment Outfall 005. is a biological treatment system with polishing ultrafiltration. Coal pile runoff,misc. stormwater flows, various plant sump discharges,non- chemical metal cleaning wastes,effluent from the Intermittent polymer FGD WW treatment system, Low addition followed by settling bottom ash purge from the Volume 10 MGD and pH adjustment if needed submerged flight conveyors, Wastewater in Lined Retention Basin boiler blowdown, oily waste System treatment effluent, wastes/backwashes from raw water treatment system, equipment heat exchanger water,and landfill leachate. Recirculation in holding Coal Pile pond for pH adjustment and 1500 gpm polymer addition prior to Coal pile runoff Runoff discharging to the Lined Retention Basin System The Marshall facility operates a wet FGD scrubber and treats up to 550 gpm of FGD wastewater in a physical/chemical treatment system followed by selenium reduction bioreactors and polishing ultrafiltration. Following the FGD wastewater treatment system the effluent is routed(after internal Outfall 004)to the LRBS. The LRBS also receives other low volume wastewater from the plant along with coal pile runoff after being stored and treated in a holding basin with polymer and caustic. The feed lines to the LRBS can also be treated with polymer to assist in settling solids in the basin and caustic on the inlet or acid on the effluent to adjust pH before discharge via Outfall 005.No other wastewater treatment systems are in use at the facility. Duke Energy—Marshall Steam Station 2-8 Burns&McDonnell October 2021 Rev 0 r 141 APPENDIX A - BOTTOM ASH EQUIPMENT SYSTEM VOLUMES AND WATER BALANCE Burns& McDonnell World Headquarters 9400 Ward Parkway Kansas City, MO 64114 O 816-333-9400 F 816-333 3690 www.burnsmcd.com BURNsaIsDoNNELL Marshall Steam Station 133406 Initial Certification Letter Appendix A — Bottom Ash Equipment Volumes and Water Balance Rev Date By Checked Description A 10/7/2021 LAS DRG INITIAL ISSUE 0 10/8/2021 LAS DRG ISSUED FINAL BURNS`1SDONNELL -------------- 71,IIIIi11 I 2 I 3 I 4 I 5 $ 6 I 7 I 8 I 9 I 10 1RAR�A..T feNDI� w oe . raw Y16Mt11 Ni RJPWMOICII 8DI1314}1-tA.14.0811 IOCA10N4Evg3A0NL AVIDDAIL OorATN18M IOIDEAvw1P.SA1c81N (,)sc tIP TO 4Ax1ExADE TANx vNN:,B' ....11.t VALVE•RVODIN.f. .M..IA LOCKOUT Nrt.AC.R4ACG BUTTERFLY VALVE.X/C AR GENDER OPERATED, A 1 tRI0pOL1 VALVEJALLT AC,9AV.f1W,NC.iNOC.LcoYW! 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NCH CONE EIER V CwP3RN AT aC.:n,v i lo._ A ano r, 4, 71.17 N MM...MAY STATION THE maALLATIONG CI F`e""-`,..4.1 mTM rRY ti nfi o1wn.L INr B 1EflRF1�NOUN CIAIXIXA a`.wAacTR4aNN o5>`v°M"'a UNITED CONVEYOR CORPORATION - 70 Te AAne1m..a.Av'a°=me=`+PAA.,e.I.r e•afto 104Gm.u.ai 6 mi - 1 REMSFO PER FREEZE PR01ECTw MO DC WWI IN S.Alf NV N - k�$YSIEM4NC�PRaEc15�54Ie1V�MC�L1-a81.ORc 0 I411ET FN CONSTRUCTION �A1 O1R GCL ME OF xw[0 NIw-16 � P s M-54183-084 1 I 2 I 3 I 4 I 5 4 .6 _- -- � 8874 I 9 I Ml.,n, L,.I., /.I 5 . A o-w AM a r 1 I I b'MPIPE MO12 CUT N HALF(GALT) - (3)t?MKY S-0. 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Industrial Landfill ► Retention Basin 10 MGD lea chafe Lake Norman. ► Coal pile Runoff ► Boiler Maintenance s Wash APPENDIX B - BOTTOM ASH PIPING DETAILED BUILD-UP • Burns& McDonnell World Headquarters 9400 Ward Parkway Kansas City, MO 64114 Ojjjj m I BURNS &ISDON NELL Marshall Steam Station i n 133406 Initial Certification Letter Appendix B — Bottom Ash Piping Detailed Build-Up Rev Date By Checked Description A 10/7/2021 LAS DRG INITIAL ISSUE 0 10/8/2021 LAS DRG ISSUED FINAL BURNS 1 DONNELL Qty Size Component Component Line Name/Description Qty Length(If) Volume Units (in) Volume(Cu.ft) (gal) Unit 1 Sluice Header to SFCs 1 ea 306.7 12 ID 240.9 1,801.7 EIP Unit 1 Sluice Header 1 ea 1,490.8 10 ID 813.1 6,082.2 Unit 2 Sluice Header to SFCs 1 ea 283.0 12 ID 222.3 1,662.6 EIP Unit 2 Sluice Header 1 ea 1,633.4 10 ID 890.9 6,664.1 Unit 3 Sluice Header to SFCs 1 ea 299.9 12 ID 235.5 1,761.7 EIP Unit 3 Sluice Header 1 ea 1,800.9 10 ID 982.2 7,347.6 Unit 4 Sluice Header to SFCs 1 ea 292.1 12 ID 229.4 1,716.0 EIP Unit 4 Sluice Header 1 ea 1,986.7 10 ID 1,083.6 8,105.8 Common LP Supply Pump Suction Header 1 ea 32.5 14 ID 31.1 232.7 Common LP Supply Pump Suction Header 1 ea 350.7 24 ID 1,033.9 7,733.8 Common LP Supply Pump Suction Header 1 ea 67.5 10 ID 37.0 276.5 Common LP Supply Pump Discharge Segments 1 ea 94.5 10 ID 51.7 387.1 Unit 1 LP Supply Header 1 ea 1,467.7 12 ID 1,152.8 8,623.2 Unit 2 LP Supply Header 1 ea 1,436.0 12 ID 1,127.8 8,436.5 Unit 3 LP Supply Header 1 ea 2,567.7 12 ID 2,016.7 15,085.9 Unit 4 LP Supply Header 1 ea 2,594.1 12 ID 2,037.4 15,241.0 Unit 1 LP Supply Header 1 ea 375.2 8 ID 130.4 975.1 Unit 2 LP Supply Header 1 ea 534.8 8 ID 185.8 1,389.9 Unit 1 LP Supply Header 1 ea 102.0 6 ID 20.5 153.0 Unit 1 LP Supply Header 1 ea 14.8 6 ID 3.0 22.1 Unit 1 LP Supply Header 1 ea 30.2 4 ID 2.7 19.9 Unit 2 LP Supply Header 1 ea 58.0 6 ID 11.6 87.0 Unit 2 LP Supply Header 1 ea 22.6 6 ID 4.5 33.9 Unit 2 LP Supply Header 1 ea 55.7 4 ID 4.9 36.8 Unit 1 LP Water to BA Hopper Overflow Tank 1 ea 68.0 4 ID 6.0 45.0 Unit 2 LP Water to BA Hopper Overflow Tank 1 ea 72.8 4 ID 6.4 48.1 Unit 3 BA Hopper Overflow Pump Suction 1 ea 39.7 8 ID 13.8 103.1 Unit 3 BA Hopper Overflow Pump Discharge 1 ea 3,088.0 8 ID 1,072.8 8,025.0 Unit 4 BA Hopper Overflow Pump Suction 1 ea 38.8 8 ID 13.5 100.7 Unit 4 BA Hopper Overflow Pump Discharge 1 ea 2,791.7 8 ID 969.9 7,255.1 Unit 1 BA Hopper Overflow Pump Discharge 1 ea 2,104.7 8 ID 731.2 5,469.6 Unit 1 BA Hopper Overflow Pump Suction 1 ea 32.2 8 ID 11.2 83.6 Unit 2 BA Hopper Overflow Pump Discharge 1 ea 2,201.2 8 ID 764.7 5,720.5 Unit 2 BA Hopper Overflow Pump Suction 1 ea 32.7 8 ID 11.3 84.9 Unit 3 LP Supply Header 1 ea 578.0 8 ID 200.8 1,502.2 Unit 3 LP Supply to Hopper Overflow Tank 1 ea 108.1 4 ID 9.6 71.5 Unit 3 LP Supply Header 1 ea 23.7 6 ID 4.7 35.5 Unit 4 LP Supply Header 1 ea 261.0 8 ID 90.7 678.2 Unit 4 LP Supply to Hopper Overflow Tank 1 ea 120.5 4 ID 10.6 79.7 Unit 4 LP Supply Header 1 ea 111.2 6 ID 22.3 ,166.8 Unit 1 LP Pump Discharge Min Flow Recirc 1 ea 127.2 6 ID 25.5 190.8 Unit 2 LP Pump Discharge Min Flow Recirc 1 ea 121.4 6 ID 24.4 182.2 Unit 3 LP Pump Discharge Min Flow Recirc 1 ea 115.9 6 ID 23.3 173.9 Unit 4 LP Pump Discharge Min Flow Recirc 1 ea 110.3 6 ID 22.1 165.5 SFC Sump Discharge Header 1 ea 415.7 61D 83.4 623.9 U1/2 Common HP Header 1 ea 35.5 12 ID 27.9 208.6 U1 HP Supply Header 1 ea 447.7 12 ID 351.6 2,630.3 U2 HP Supply Header 1 ea , 610.8 12 ID 479.7 3,588.7 U1 HP Supply Header 1 ea 72.3 10 ID 39.6 296.2 Ui HP Supply Header 1 ea 28.9 6 ID 5.8 43.4 U2 HP Supply Header 1 ea 45.7 10 ID 25.0 187.0 U2 HP Supply Header 1 ea 32.5 6 ID 6.5 48.8 U3/4 Common HP Header 1 ea 34.3 12 ID 27.0 201.7 U3 HP Supply Header 1 ea 613.8 12 ID 482.1 3,606.0 U4 HP Supply Header 1 ea 453.2 12 ID 356.0 2,662.9 U3 HP Supply Header 1 ea 22.1 10 ID 12.1 90.5 U3 HP Supply Header 1 ea 133.8 8 ID 46.5 347.8 U4 HP Supply Header 1 ea 91.7 10 ID 50.2 375.5 U4 HP Supply Header 1 ea 15.8 6 ID 3.2 23.7 Total Piping Volume 1 LOT 138,993.1 11141 BURNS M_C DONNELL. CREATE AMAZING. i Burns& McDonnell World Headquarters 9400 Ward Parkway Kansas City, MO 64114 O 816333-9400 F 333-3690 www.burnsmcd.com