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HomeMy WebLinkAboutNCS000329_MONITORING REPORT_20210122 (2)trATI N January 15, 2021 l P.O. Box 5030 2020 Ashcroft Avenue Monroe, NC 28111-5030 PhoDivision of Energy Mineral and Land Resources Fax: (704) 290-5191 - Fax: (704) 290-5194 Attn: Central Files Email: tyler.mercer@atimetals.com 1617 Mail Service Center Raleigh, NC 27699-1617 Central Files: Tier 2 Monthly Monitoring -December 2020 Attached, please find stormwater monitoring data for Permit No NCS000329. The originals and one copy are included. The monitoring data is for the following monitoring schedule: Analytical monitoring includes: • Outfall #01 (B), commingled stormwater • Outfall #02 (B), non -commingled stormwater • Outfall #03 (B), non -commingled stormwater • Non Contact Cooling Water #1 - #8 If you have any questions or need additional information, please contact me at 704-289-4511 x3823. Thank you. Sincerely, Tyler Mercer EHS Manager =•;�ATI SlItun jlty rulallwmA ATI (Allvac) — Bakers Campus (BNO) Stormwater Monitoring Report Form Sample Date: 7-1 ere? -XiA lje, Ace4r Sample Time: Sample Location: Stormwater Discharge Outfall # 02 (Non - Commingled) Drainage Area= 212,952 sq. ft. = 4.9 Acres % Impervious= 12% Person Collecting Samples: Laboratory Performing Analysis: 9 Analytical Techniques and Methods: 40 CFR Part 136 Results of Sample Analysis: Parameter Results (mg/1) Benchmark Values (mill) TSS 100 BOD F/o 30 COD 120 Cadmium 0.003 Chromium Flow 0.905 Total Calcium 915 Total Copper a 0.01 Total Nickel /a N/ 0.335 Total Zinc 0.126 PH (std units) 6-9 Temperature Deg. Celsius Storm Date: Storm Duration: Duration of time preceding rain event exceeding 0.1": Estimated Flow Calculation: (Hrs.) Inches of Rainfall: (Hrs.) Q=CIA Q (Total) = Q (Pervious Area) + Q (Impervious Area) Q (Tot., cfs) = (A x inches rain/12 inches/ft. x 4.9 acres x .88) + (.9 x inches rain/12 inches/ft. x 4.9 x .12) Rev.01 Date of Rev.: 1/22/2020 0ATI ATI (Allvac) — Bakers Campus (BNO) Stormwater Monitoring Report Form Q (Total, cfs) = 0.1437 x (Inches of rain) + 0.0441 x (Inches of rain) cfs Rev. 01 Date of Rev.: 1/22/2020 zATI Specialty Materials ATI (Allvac) — Bakers Campus (BNO) Stormwater Monitoring Report Form Sample Date• fey 0 D Sample Time: Sample Location: Stormwater Discharge Outfall # 03 (Non - Commingled) Drainage Area= 336,580 sq. ft. = 7.8 Acres % Impervious=15% Person Collecting Samples: Laboratory Performing Analysis: Analytical Techniques and Methods: 40 CFR Part 136 Results of Sample Analysis: Parameter Results (mg/1) Benchmark Values (mg/1) TSS Ne 100 BOD dw 30 COD 120 Cadmium 0 0.003 Chromium 0.905 Total Calcium 915 Total Copper Ald 0.01 Total Nickel 0.335 Total Zinc 0.126 pH (std units) 6-9 Temperature Deg. Celsius Storm Date: Storm Duration: (Hrs.) Inches of Rainfall: Duration of time preceding rain event exceeding 0.1": (Hrs.) Estimated Flow Calculation: Q=CIA Q (Total) = Q (Pervious Area) + Q (Impervious Area) Q (Tot., cfs) = (A x inches rain/12 inches/ft. x 7.8 acres x .85) + (.9 x inches rain/12 inches/ft. x 7.8 x .15) Rev. 01 Date of Rev.: 1/22/2020 40 -wwrATI Specialty Materials ATI (Allvac) — Bakers Campus (BNO) Stormwater Monitoring Report Form Q (Total, cfs) = 0.2210 x (Inches of rain) +0.0878 x (Inches of rain) cfs Rev. 01 Date of Rev.: 1/22/2020 STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT Permit Number NCS 0/14 .°ig FACILITY NAME !ii'! .lnecig/iv %%%afuin�S, Ba.ti`C�s S%ft PERSON COLLE-TING M PL � (S� L ) CERTIFIED LABORATORY(S) Lab # Lab # Part A: Specific Monitoring Requirements SAMPLES COLLECTED DURING CALENDAR YEAR: (This monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) COUNTY CG--ion PHONE NO. 9 V SIGNATURE OF PERMITTEE OR DESIGNEE REQUIRED ON PAGE 2. Oat{all Date 50050 No. Sample Collected Total Flow if a Total Rainfall mo/dd/ r MG inches N D o swoa 0 3W03 o No ow ow Flo w - -i -----� Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? Oyes *no (if yes, complete Part B) A t' ' M 'torin Re uirements rarr B: Vehicle Outfall No. Maintenance c UVU Date Sample Collected om 50050 00556 00530 00400 Total Flow (if applicable) Total Rainfall Oil & Grease (if appl.) Non -polar O&G/TPH (Method 1664 SGT-HEM), if Total Suspended Solids PH pH r rUsage mo/dd/ r MG inches m ma Unit Form SWU-247, last revised 6112/200 Page 1 of;: STORM EVENT CHARACTERISTICS: Date Total Event Precipitation (inches): Event Duration (hours): (only if applicable — see permit.) (if more than one storm event was sampled) Date Total Event Precipitation (inches): Event Duration (hours): (only if applicable — see permit.) Mail Original and one copy to: Division of Energy Mineral and Land Resources Attn: Central Files 1617 Mail Service Center Raleigh, North Carolina 27-699-1617 "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in acizordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Eased on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." (Signature of (Date) Form SWU-247, last revised 611212015 Page 2 of 2 Sample Location: Person Collecting Samples: Laboratory Performing Analysis: Analytical Techniques and Methods: Results of Sample Analysis: ATI (Allvac) — Bakers Campus (BNO) Stormwater Monitoring Report Form Non -Contact Cooling Wastewater 9ayi°Q Poet Tk. P0.CG An4-hea1 40 CFR Part 136 -OATI Specialty Materials Non -Contact Sampling Sampling Estimated Total Temperature pH (std. Effluent Downstream Upstream Cooling Date Time (am/pm Flow (MGD) Residual units) Water # or military Chlorine time) (mg/1) 1 - /0 o 17 V5- . OOs' 0.0.2 8 0,?8. 5 °` 7°c OU. 4 cc 74 2 8 0� 0.00/y 0.10 ..s°` °° a °` 2111 3 0- 0 8 : 3s� 0 . 00 0. �r5 Z &. 70` Ou. s 1124?. 4 °` . Y 4 - 0 Os°_ 6,6036 0. D s 18.30c .7't s 7°` 7 6 / - 0- 0 /0.00. .D AO 16. 15M 9 °c .7" 7 / 0- 67,9 /O :349 . P. 00 irs 0.084 S °c °c 7• S s 0- o H :Or— 0. 6079 0. 0 •0 .7°f IM.Y°` 7-7 Rev. 01 Date of Rev.: 1/22/2020 i FaceAnaWical www.pa[elabsxcm December 21, 2020 Scott Ryan Allvac Monroe, NC RE: Project: Bakers South Pace Project No.: 92511321 Dear Scott Ryan: Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on December 11, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard mafthew.brainard@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Tyler Mercer, ATI Specialty Materials Rick Moore, ATI Specialty Materials David Pope, Allvac REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. I.L.C. Page 1 of 19 IUvAnalyiical WM.pacslibs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 South Carolina Certification M 99006001 Louisiana/NELAP Certification* LA170028 Florida/NELAP Certification M E87627 North Carolina Drinking Water Certification M 37706 Kentucky UST Certification M 84 North Carolina Field Services Certification M 5342 VrginiaNELAP Certification M 460221 North Carolina Wastewater Certification M 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification M E87648 North Carolina Drinking Water Certification M 37712 North Carolina Wastewater Certification M 40 South Carolina Certification M 99030001 VrginiaNELAP Certification M 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 19 aceAnalytical crww pacelsbs.com SAMPLE ANALYTE COUNT Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92511321001 Non -Contact #1 EPA 1664B HH 1 PASI-C SM 4500-CI G-2011 MDW 1 PASI-A 92511321002 Non -Contact #2 EPA 1664E HH 1 PASI-C SM 4500-CI G-2011 MDW 1 PASI-A 92511321003 Non -Contact #3 EPA 1664E HH 1 PASI-C SM 4500-CI G-2011 MDW 1 PASI-A 92511321004 Non -Contact #4 EPA 1664E HH 1 PASI-C SM 4500-CI G-2011 MDW 1 PASI-A 92511321005 Non -Contact #5 EPA 1664B HH 1 PASI-C SM 4500-CI G-2011 MDW 1 PASI-A 92511321006 Non -Contact #6 EPA 1664E HH 1 PASI-C SM 4500-CI G-2011 MDW 1 PASI-A 92611321007 Non -Contact #7 EPA 1664B HH 1 PASI-C SM 4500-CI G-2011 MDW 1 PASI-A 92511321008 Non -Contact #8 EPA 1664E HH 1 PASI-C SM 4500-CI G-2011 MDW 1 PASI-A PASI-A = Pace Analytical Services - Asheville PAST-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 19 aceAnalyircal �rw�w.pacelsDs.cara ANALYTICAL RESULTS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Non -Contact #1 Lab ID: 92511321001 Collected: 12/10/20 07:45 Received: 12111/20 09:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664E Pace Analytical Services - Charlotte Oil and Grease ND mg/L 5.0 1 12/20/20 11:06 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G-2011 Pace Analytical Services - Asheville Chlorine, Total Residual 0.028 mg/L 0.024 1 12/18/20 18:42 7782-50-5 H3 Date: 12/21/2020 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 19 aceaAnalytrcal www.pacelabs.com ANALYTICAL RESULTS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Non -Contact #2 Lab ID: 92511321002 Collected: 12/10/20 08:10 Received: 12/11/20 09:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664E Pace Analytical Services - Charlotte Oil and Grease ND mg/L 5.0 1 12/20/20 11:06 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G-2011 Pace Analytical Services - Asheville Chlorine, Total Residual 0.10 mg/L 0.024 1 12/18/20 18:46 7782-50-5 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/21/2020 07:29 AM without the written consent of Pace Analytical Services. LLC. Page 5 of 19 1aLc)EeAna1j6ca1 www.pacelabs.cam ANALYTICAL RESULTS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Non -Contact #3 Lab ID: 92611321003 Collected: 12/10/20 08:35 Received: 12/11/20 09:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Oil and Grease ND mg/L 5.0 1 12/20/20 11:08 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G-2011 Pace Analytical Services - Asheville Chlorine, Total Residual 0.55 mg/L 0.096 4 12/18/20 18:56 7782-50-5 H3 Date: 12/21/2020 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. LLC. Page 6 of 19 IfteAr�alytrcal www.pacelab3.COM ANALYTICAL RESULTS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Non -Contact #4 Lab ID: 92511321004 Collected: 12/10/20 09:05 Received: 12/11/20 09:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Oil and Grease ND mg/L 5.0 1 12/20/20 11:06 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G-2011 Pace Analytical Services - Asheville Chlorine, Total Residual 0.075 mg/L 0.024 1 12/18/20 19:01 7782-50-5 H3 Date: 12/21/2020 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 19 aceAnalytical www pace!=ba.cam f ANALYTICAL RESULTS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Non -Contact #5 Lab ID: 92511321005 Collected: 12/10/20 09:30 Received: 12/11/20 09:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664E Pace Analytical Services - Charlotte Oil and Grease ND mg/L 5.0 1 12/20/20 11:10 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G-2011 Pace Analytical Services - Asheville Chlorine, Total Residual 0.36 mg/L 0.024 1 12/18/20 19:05 7782-50-5 H3 Date: 12/21 /2020 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 19 aceAnafyical www.pacaiabs.com ANALYTICAL RESULTS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Non -Contact #6 Lab ID: 92511321006 Collected: 12/1012010:00 Received: 12/11/20 09:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Oil and Grease ND mg/L 5.0 1 12/20/20 11:06 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G-2011 Pace Analytical Services - Asheville Chlorine, Total Residual ND mg/L 0.024 1 12/18/20 19:09 7782-50-5 H3 Date: 12/21/2020 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9of19 aCXAMalyfical www.pacalabsxam ANALYTICAL RESULTS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Non -Contact #7 Lab ID: 92511321007 Collected: 12/10/2010:30 Received: 12/11/20 09:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 16648 Pace Analytical Services - Charlotte Oil and Grease ND mg/L 5.0 1 12/20/20 11:07 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G-2011 Pace Analytical Services - Asheville Chlorine, Total Residual 0.086 mg/L 0.024 1 12/18/20 19:14 7782-50-5 H3 Date: 12/21/2020 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 19 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Non -Contact #8 Lab ID: 92611321008 Collected: 12/10/20 11:05 Received: 12/11/20 09:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Oil and Grease ND mg/L 5.0 1 12/20/20 11:07 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G-2011 Pace Analytical Services - Asheville Chlorine, Total Residual 0.10 mg/L 0.024 1 12/18/20 19:19 7782-50-5 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/21/2020 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 19 aceAnalytical wwwpacelabs.eam QUALITY CONTROL DATA Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: 588391 Analysis Method: EPA 1664E QC Batch Method: EPA 1664E Analysis Description: 1664 HEM, Oil and Grease Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92511321001, 92511321002, 92511321003, 92511321004, 92511321005, 92511321006, 92511321007, 92511321008 METHOD BLANK: 3109109 Matrix: Water Associated Lab Samples: 92511321001, 92511321002, 92511321003, 92511321004, 92511321005, 92511321006, 92511321007, 92511321008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Oil and Grease mg/L ND 5.0 12/20/2011:03 LABORATORY CONTROL SAMPLE: 3109110 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Oil and Grease mg/L 40 31.7 79 78-114 MATRIX SPIKE SAMPLE: 3109111 92511294002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Oil and Grease mg/L ND 40 46.0 104 78-114 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/21 /2020 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 19 aceArralytrcal www.patelabs.com QUALITY CONTROL DATA Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: 588239 Analysis Method: SM 4500-CI G-2011 QC Batch Method: SM 4500-CI G-2011 Analysis Description: 4500CL G Chlorine, Total Residual Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92511321001, 92511321002, 92511321003, 92511321004, 92511321005, 92511321006, 92511321007, 92511321008 METHOD BLANK: 3108436 Matrix: Water Associated Lab Samples: 92511321001, 92511321002, 92511321003, 92511321004, 92511321005, 92511321006, 92511321007, 92511321008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chlorine, Total Residual mg/L ND 0.024 12/18/20 18:37 SAMPLE DUPLICATE: 3108437 Parameter Chlorine, Total Residual 92511321001 Dup Units Result Result mg/L 0.028 0.026 RPD Qualifiers 7 H3 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/21/2020 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 19 aceAna/j 6ca ® www.pacdabs.com QUALIFIERS Project: Bakers South Pace Project No.: 92511321 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 9800 Wncey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS H3 Sample was received or analysis requested beyond the recognized method holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date. 12/21 /2020 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 19 aceAnalytical www.pacehbs.eam QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Bakers South Pace Project No.: 92511321 Lab ID Sample ID 92511321001 Non -Contact #1 92511321002 Non -Contact #2 92511321003 Non -Contact #3 92511321004 Non -Contact #4 92511321005 Non -Contact #5 92511321006 Non -Contact #6 92511321007 Non -Contact #7 92611321008 Non -Contact #8 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersviile, NC 28078 (704)875-9092 QC Batch Method QC Batch Analytical Method EPA1664B 588391 EPA1664B 588391 EPA 1664B 588391 EPA1664B 588391 EPA1664B 588391 EPA1664B 588391 EPA 1664B 588391 EPA1664B 588391 92511321001 Non -Contact #1 SM 4500-CI G-2011 588239 92511321002 Non -Contact #2 SM 4500-CI G-2011 588239 92511321003 Non -Contact #3 SM 4500-CI G-2011 588239 92511321004 Non -Contact #4 SM 4500-CI G-2011 588239 92511321005 Non -Contact #5 SM 4500-CI G-2011 588239 92511321006 Non -Contact #6 SM 4500-CI G-2011 588239 92511321007 Non -Contact #7 SM 4500-CI G-2011 588239 92511321008 Non -Contact #8 SM 4500-CI G-2011 588239 REPORT OF LABORATORY ANALYSIS Analytical Batch This report shall not be reproduced, except in full, Date: 12/21/2020 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 19 Document Name: Document Revised: October 28, 2020 _� aeeAnalyfieal Sample Condition Upon Receipt(SCUR) Pa e 1 of 2 Document No.: Issuing Authority: / F-CAR-CS-033-Rev.07 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville 1Raleigh[] Mechanicsville❑ Atlanta❑ Kernersville❑ Client Name: Projects -WO#:92511321 r Courier: ❑ d Ex ❑UPS ❑USPS []Client ❑ commercial [Pace ❑Other:_ Custody Seal Present? ❑Yes No Seals Intact? ❑Yes i v No i Packing Material: []Bubble Wrap ❑Q Bubble Bags ❑None ❑ Other Thermom XGun i E]Wet ❑Blue lD: 92T064 Type of Ice: 3- 5? qF Correction Factor: Cooler Temp: Add/Subtract(°C) -0.1 Cooler Temp Correctedr,Ul: . USDA Regulated Soil ( N/A, water sample) Did samples origg fsete in a quarantine zone within the United States: CA, NY, or SC (check maps)? n _ 141ni 1111111111111111111111 92511321 Date/Initials Person Examining Ccntems:�//�' l - Biological Tissue Jnzen? []None ❑Yes [)No ON/A Temp should be above freezing to 6'C ❑Samples out of temp criteria. Samples on ice, cooling process hasbegun Did samples originate from a foreign source (internationally, ineludina Hawaii and Puerto Ricoi? nYes FlNo Comments/Discrepancy: Chain of Custody Present? L`7Yes Na N/A 1. Samples Arrived within Hold Time? ffle N/A 2. Short Held Time Analysis 472 hr.)? ❑Yes QNo - No N/A 3. Rush Turn Around Time Requestedt []Yes ENo CINIA a. Sufficient Volume? yes No N/A S. Correct Containers Used? -Pace Containers Used? des ves ❑Ne No '�N/A N/A 6. . Containers Intact? []Yes No ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes No N/A 8. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: es W []NO ❑N/A 9. Heads ace in VOA Vials >5-6mm)? Yes QNO N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? []Yes yes []NO nNo N/A d/A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Field Date Required? []Yes ❑Nb Person contacted: Date/Time: Project Manager SCURF Review: Date: Project Manager SRF Review: _ Date:- - Page 16 of 19 f aceAnalytieal Document Name: Sample Condition Upon Recel Document No.: F•CAR•CS•033-Rev.07 *Check mark top half of box if pH and/or dechlorination is Project a verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom -half of box is to list number of bottles Document Revised: October 28, 2020 Page 2 of 2 Issuing Authority: Pace Carolinas Quality Office WO#:92511321 PM: MWB Due Date: 12/22/20 CLIENT: 92-Allvae NC x Z Gi c d .J E eN-1 Coo Z a c a J E N z M a)a c a J QQE Co a z Z d a 3 a CD V N _a O .. .��. J E 0 N a p Z a J 1Q/E� o ' O ro w a J E m 7•� a T M ° o. J E d CM Z-. Q .. o E 6 Z7 1616 3 Z e E a V .-1 l7 NIL a a a ... .-� t7 a U ? a a Q J E o N a N aG. �f '^ ►. wl a V a �' ,�' E a E L•j yrQ 17 a u z .0 E N eat. ��Q„ t7 a O > J �E V t9 C Z '^ to z� a O ..J E q t7 > O > .J E t7 > Q _ z 0 O >66 J E $ l7 o 2 y m A *r " 0 > zr'J �4 y > N i v > 2 3 A _J �. �n a eA�O a z !� u�i J E o N a N `' N Z d .c+ C a N a M z ... Z a (: eel z V R o �' N z d C E E c O 1 -\N � X, 2 \N 3 I 4_ 5 � 6 I 7 8 10 11 12 INN\N V__ N�sN pH Adjustment Log for Preserved Samples Sample io Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added lot q Note: Whenever there is a discrepancy artecting nortn i-arouna comp{iance ydiniplub, O 11.Vr/y VI 9,II{] IVI III W4481 VC MIIt:N UIC IMUI LII %.a; UM 90 4L1 111P %.C1 %if 91601,6W$. r• ��b �••"• Out of hold, incorrect preservative, out of temp, incorrect containers. Page 17 of 19 Stormwater Monitoring (NON CONTACT) Bakers North Chain of Custody Record `1'n.) IS, A t Project Number/Name: Non Contact Cooling Water Project Location: ATI-SM - Bakers Sampler's Signature: a�7� Date: as Ono a � j ,� > a, �, y V Requested Test A o. ° Parameters a� V Non -Contact # 1 .• G G HCl Y . �- Oil & Grease Non -Contact #2 : � G G HCl Y �, Oil & Grease Non -Contact #3 :� G G HCl Y Oil & Grease Non -Contact #4 G G HCl Y �.•� Oil & Grease Non -Contact #5 •• G G HCl Y Q, a Oil & Grease Non -Contact #6 p:p�,, G G HCl Y Q, Oil & Grease Non -Contact #7 p:3A G G HCl Y Oil & Grease Non -Contact #8 .•ate G G HC1 Y J7.7 Oil & Grease Meter Calibrated: &/ N Thermometer Calibrated: MI N Sampling and Field analysis completed by: Relinquished by: Received by:,-- r J Date: Time: .' Date: % _ •f Tjyp e:� Relinquished by: - -' `"- -'' Received by: Date: �; �i..�'< Time: J- I Date: I;a ,Za Time: 1 o Stormwater Monitoring -Non Contact Cooling Water Chain of Custody (Oil & Grease) Rev. 03 6/2/2020 Page 18 of 19 Stormwater Monitoring (NON CONTACT) Bakers North Chain of Custody Record Project Number/Name: Non Contact Cooling Water Project Location: ATI SM - Bakers Sampler's Signature: Date: � 8„ D 0 a O M L A � •y r L Requested Test Parameters 8 CI 'r, .. +r C c C G as CAI Ox � Non -Contact #1 - G P None Y Residual Chlorine ec j Non -Contact #2 G P None Y , 9' Residual Chlorine : t, Non -Contact #3 G P None Y 7. 1A. 7 Residual Chlorine &Z.) Non -Contact #4 : p,Z,,. G P None Y 174 148JResidual Chlorine b C Non -Contact #5 G P None Y Residual Chlorine Non -Contact #6 G P None Y 7, A 109* /0 Residual Chlorine w 1-0 Non -Contact #7 G P None Y Residual Chlorine r;tJ Non -Contact #8 : G P one Y .7 Residual Chlorine �' b Meter Calibrated: / N Thermometer Calibrated: / N Sampling and Field analysis completed by: Relinquished by: Received by; Date: 1,R • 1-adTime: •�.5'd�.. Date: Relinquished by: : -<" Received by: Date: Time: ' Date: l L V Time: ;2-3 o 5tormwater monitoring -Non uo�tact uooltng water unain of custody (Kesiauai uniorine) Kev. U3 61ZI2020 Page 19 of 19 ATw (Allvac) — Bakers Campus (SNO) Stormwater Monitoring Report Corm Sample Date: .l /iCro�-/KaRil�� eetAbe Sample Time: Sample Location: Stormwater Discharge Outfall ## 01 (Commingled) Drainage Area= 2,915,470 sq. ft. = 69 Acres % Impervious= 34% Person Collecting Samples: 2 Laboratory Performing Analysis: Analytical Techniques and Methods: 40 CfR Part 136 Results of Sample Analysis: Parameter Results (mg/1) Benchmark Values (mg/1) TSS 0 100 BOD Id w 30 COD 120 Cadmium 0 0.003 Chromium 0 0.905 Total Calcium 915 Total Copper 0 0.01 Total Nickel )rlOW 0.335 Total Zinc 0.126 pH (std units) 6-9 Temperature Deg. Celsius Total Residual Chlorine .017 Oil and Grease 15 Storm Date: Storm Duration: (Hrs.) inches of Raanfall: Duration of time preceding rain event exceeding 0.1": (Hrs.) Estimated Raw Calculation: Q=CIA Q (Total) = Q (Pervious Area) + Q (Impervious Area) �j Rev. 01 Date of Rev.: 1/22/2020 ATI (Allvac) -- Bakers Campus (BNO) 5tormwfatier Monitoring Report Form Q (Tat., cfs) = (A x inches rain/12 inches/it. x 59 acres x .66) + (.9 x inches rain/12 inches/ft. x 69 ); .34) Q (%faf, cfs)=1.15180 x ({aches of rain) + 1.7595 x (inches of rain) cfs Rev. 01 Date of Rev.: 1/22/2020 0 �y� 1� ATI (Allvac) — Bakers Campus (BNO) Stormwater Monitoring Report Form Sample Date:7er-/)faag1 Sample Time: Sample location: Stormwater Discharge Outfall # 02 (Non - Commingled) Drainage Area= 212,952 sq. ft. = 4.9 Acres % Impervious=12% Person Collecting Samples: Laboratory Performing Analysis: Analytical Techniques and Methods: 40 CFR Part 136 Results of Sample Analysis: Parameter Results (mg/1) Benchmark Values (mg/1) TSS 100 BOD /41:/o 30 COD 120 Cadmium 0.003 Chromium IOW 0.905 Total Calcium 915 Total Copper 0.01 Total Nickel 4W 0.335 Total Zinc 0.126 PH (std units) 6-9 Temperature Deg. Celsius Storm Date: Storm Duration: (Hrs.) Inches of Rainfall: Duration of time preceding rain event exceeding 0.1": (Hrs.) Estimated Flow Calculation: Q=CIA Q (Total) = Q (Pervious Area) + Q (Imperviuus Ai ea) Q (Tot., cfs) = (.4 x inches rain/12 inches/ft. x 4.9 acres x .88) + (.9 x inches rain/12 inches/ft. x 4.9 x .12) Rev. 01 Date of Rev.: 1/22/2020 `w WA ATI (AIIvac) — Bakers Campus (BNO) Stormwater Monitoring Report Form Q (Total, cfs) = 0.1437 x (Inches of rain) + 0.0441 x (Inches of rain) cfs Rev. 01 Date of Rev.: 1/22/2020 0 AT Sim salty hlaf miss ATI (Allvac) — Bakers Campus (BNO) Stormwater Monitoring Report Form Sample Date• lei#/ 0 Sample Time: Sample Location: Stormwater Discharge Outfall # 03 (Non - Commingled) Drainage Area= 336,580 sq. ft. = 7.8 Acres % Impervious= 15% Person Collecting Samples: Laboratory Performing Analysis: Analytical Techniques and Methods: 40 CFR Part 136 Results of Sample Analysis: Parameter Results (mg/1) Benchmark Values (mg/1) TSS No 100 BOD op/ 30 COD 120 Cadmium 0 0.003 Chromium 0.905 Total Calcium 915 Total Copper 1Y n/0 0.01 Total Nickel 0.335 Total Zinc 0.126 pH (std units) 6-9 Temperature Deg. Celsius Storm Date: Storm Duration: (Hrs.) Inches of Rainfall: Duration of time preceding rain event exceeding 0.1": (Hrs.) Estimated Flow Calculation: Q=CIA Q (Total) = Q (Pervious Area) + Q (Impervious Area) Q (Tot., cfs) _ (A x incheS t din/12 inches/fl. )(7.8 du eS x .85) + (.9 x IncheS tdln/12 Inches/fl. x 7.8 x .1S) Rev.01 Date of Rev.: 1/22/2020 tir AT l liamaity 41RiBrIals ATI (Allvac) — Bakers Campus (BNO) Stormwater Monitoring Report Form Q (Total, cfs) = 0.2210 x (Inches of rain) + 0.0878 x (Inches of rain) cfs Rev. 01 Date of Rev.: 1/22/2020 STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT Permit Number NCS 0164 le FACILIT41NA1MfI: A SoIC/a/�y%11afu/el/sr�a�[rs Sift PERSON COLLECTING S'AMPL E ( CERTIFIED LABORATORY(S) Lab i3 Lab :3 Pani'. A: Specific Monitoring Requirements SAMPLES COLLECTED DURING CALENDAR YEAR: (This monitoring report shall be received by the Division no ➢ iter thou 366 Ram y;, i"V oo, she date the facility receives the sampling results from the ➢aborAtorry.) COUNT' &A-16' n _ PHONE NO. 99V auf SIGNATURE OF PERMITTEE OR DESIGNED REQUIRED ON PAGE 2. ontfall No. Date SaiAAple Collectesa 50050 1 Total Flow if a Total Rainfall -- BL✓o swot An2/d61 T I /Vo MG o w inches noes this racilitY periornn Vehicic Maintenance Activities using more than 55 gallows or new motor oil per month? Qyes *no (if yes, complete Pail B) T, if h` ➢ M . twnnuce Activi MOWtOrin Re nlrements r Mn a. . e Ac a (irentfa➢I No. aAn DAsm Sample Collet&W 50050 100556 00530 00400 Total Flow (if applicable) Total T Rainfall Oil & Grease (if appl.) Non -polar O&G/TPH (Method 1664 SGT-HEM), if Total Suspended Solids pH New Mokor OII iUsAge mo/Od/yr MG Inches MO m l unit gal/mo I i I - Form SWU-247, Iasi revised 6/12120i_', STORM EVENT CHARACTERISTICS: Date Total Event Precipitation (inches): Event Duration (hours): (only if applicable — see permit.) (if more than one storm event was sampled) Date Total Event Precipitation (inches): Event Duration (hours): (only if applicable — see permit.) Mail Original and one copy to: Division of Energy Mineral and Land Resourccs Attn: Central Files 1617 Mail Service Center Raleigh, North Carolina 27-699-1617 "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with as system designed to assure that qualified personnel properly gather and evaluate the information submitted. Eased on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. H am aware that there are significant penalties for submitting false information, including the possibility of tines and imprisonment for knowing violations." (Signature of (Date) Form SWU-247, last revised 611212015 Page 2 of 2 Sample Location: Person Collecting Samples: Laboratory Performing Analysis: Analytical Techniques and Methods: Results of Sample Analysis: ATI (Allvac) — Bakers Campus (BN®) Stormwater Monitoring Report Form Non -Contact Cooling Wastewater ,VdUiye Poet alp. Pace An*hc„ >' 40 CFR Part 136 11�ATI :,prr..ialty Mt;tirra:r9s Non -Contact Sampling Sampling Estimated Total Temperature pH (std. Cooling Date Time (am/pm Flow (MGD) Residual units) Effluent Downstream Upstream Water # or military Chlorine time) (mg/1) 1 -/0 0 %' S.� . 460-ro 0.0.7-8 ds. 5 ZZ7°' .G'' 7G 3 - o- o 0 • 00 0. S.7°` s•� °� 7• Y 4 - O 10,40031, 0.07S 3'' 7'' .8°` • 6 5 •30, 40.606?9 7'° 7 6 7 R 0. 0079 0 • o Z 7. 71c a .7°' a. Y°` 7 Rev. 01 Date of Rev.: 1/22/2020 aceAnalytical ww.penhhssem December 21, 2020 Scott Ryan Allvac Monroe, NIC RE: Project: Bakers South Pace Project No.: 92511321 Dear Scott Ryan: Pace Analytical services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on December 11, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, al - Matthew Brainard mafthew.brainard@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Tyler Mercer, An Specialty Materials Rick Moore, ATI Specialty Materials David Pope, Ailvac REPORT OF LABORATORY ANALYSIS This report shall not oe reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 19 aceAnalyiical www.pacdabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 South Carolina Certification #: 99006001 Louisiana/NELAP Certification # LA170028 Florida/NELAP Certification #: E87627 North Carolina Drinking Water Certification M 37706 Kentucky UST Certification M 84 North Carolina Field Services Certification M 5342 VrginiaNELAP Certification #: 460221 North Carolina Wastewater Certification M 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 North Carolina Wastewater Certification #: 40 Florida/NELAP Certification* E87648 South Carolina Certification M 99030001 North Carolina Drinking Water Certification #: 37712 VrginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 19 1�5a'tcciveAnalyfical www.pgcelabs.com I Project: Bakers South Pace Project No.: 92511321 Lab ID Sample ID 92511321001 Non -Contact #1 92511321002 Non -Contact #2 92511321003 Non -Contact #3 92511321004 Non -Contact #4 92511321005 Non -Contact #5 92511321006 Non -Contact #6 92511321007 Non -Contact #7 92511321008 Non -Contact #8 PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte SAMPLE ANALYTE COUNT Method EPA 1664B SM 4500-CI G-2011 EPA1664B SM 4500-CI G-2011 EPA 1664B SM 4500-CI G-2011 EPA 1664B SM 4500-CI G-2011 EPA 1664B SM 4500-CI G-2011 EPA 1664E SM 4500-CI G-2011 EPA 1664E SM 4500-CI G-2011 EPA 1664E SM 4500-CI G-2011 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytes Analysts Reported Laboratory HH 1 PASI-C MDW 1 PASI-A HH 1 PASI-C MDW 1 PASI-A HH 1 PASI-C MDW 1 PASI-A HH 1 PASI-C MDW 1 PASI-A HH 1 PASI-C MDW 1 PASI-A HH 1 PASI-C MDW 1 PASI-A HH 1 PASI-C MDW 1 PASI-A HH 1 PASI-C MDW 1 PASI-A Page 3 of 19 aceAnalytrcal 41) www.pscdabs.com ANALYTICAL RESULTS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Non -Contact #1 Lab ID: 92511321001 Collected: 12/10/20 07:45 Received: 12/11/20 09:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Oil and Grease ND mg/L 5.0 1 12/20/20 11:06 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G-2011 Pace Analytical Services - Asheville Chlorine, Total Residual 0.028 mg/L 0.024 1 12/18/2018:42 7782-50-5 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/21/2020 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 19 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersviile, NC 28078 (704)875-9092 Sample: Non -Contact #2 Lab ID: 92511321002 Collected: 12/10/20 08:10 Received: 12/11/20 09:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664E Pace Analytical Services - Charlotte Oil and Grease ND mg/L 5.0 1 12/20/20 11:06 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G-2011 Pace Analytical Services - Asheville Chlorine, Total Residual 0.10 mg/L 0.024 1 12118/2018:46 7782-50-5 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/21/2020 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 19 aceAnalyiical www.pacalab"am ANALYTICAL RESULTS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Non -Contact #3 Lab ID: 92511321003 Collected: 12/10/20 08:35 Received: 12/11/20 09:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664E Pace Analytical Services - Charlotte Oil and Grease ND mg/L 5.0 1 12/2012011:08 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G-2011 Pace Analytical Services - Asheville Chlorine, Total Residual 0.56 mg/L 0.096 4 12/18/20 18:56 7782-50-5 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/21/2020 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 19 aceAnalytical www.p:c�ises.com i ANALYTICAL RESULTS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Non -Contact #4 Lab ID: 92511321004 Collected: 12/10/20 09:05 Received: 12/11/20 09:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Oil and Grease ND mg/L 5.0 1 12/20/20 11:06 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G-2011 Pace Analytical Services - Asheville Chlorine, Total Residual 0.075 mg/L 0.024 1 12/18/20 19:01 7782-50-5 H3 Date: 12/21/2020 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 19 aceArfalytical www.pecelabs.com ANALYTICAL RESULTS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kinsey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Non -Contact #5 Lab ID: 92511321005 Collected: 12/10/20 09:30 Received: 12/11/20 09:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664E Pace Analytical Services - Charlotte Oil and Grease ND mg/L 5.0 1 12/20/20 11:10 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G-2011 Pace Analytical Services - Asheville Chlorine, Total Residual 0.36 mg/L 0.024 1 12/18/20 19:05 7782-50-5 H3 Date: 12/21/2020 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 19 IeAnalXical www.pacelabs.cam ANALYTICAL RESULTS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Non -Contact #6 Lab ID: 92511321006 Collected: 12/10/20 10:00 Received: 12/11/20 09:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method. EPA 1664B Pace Analytical Services - Charlotte Oil and Grease ND mg/L 5.0 1 12/20/20 11:06 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G-2011 Pace Analytical Services - Asheville Chlorine, Total Residual ND mg/L 0.024 1 12/18/20 19:09 7782-50-5 H3 Date: 12/21 /2020 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 19 ;a'uccivaAnalyfical j www.pacslabs.cam I ANALYTICAL RESULTS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Non -Contact #7 Lab ID: 92611321007 Collected: 12/10/20 10:30 Received: 12/11/20 09:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664E Pace Analytical Services - Charlotte Oil and Grease ND mg/L 5.0 1 12/20/20 11:07 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G-2011 Pace Analytical Services - Asheville Chlorine, Total Residual 0.086 mg/L 0.024 1 12/18/2019:14 7782-50-5 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/21 /2020 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 19 aceArlalyircal arMnEv pacelabs.cam E ANALYTICAL RESULTS Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Non -Contact #8 Lab ID: 92611321008 Collected: 12/10/20 11:05 Received: 12/11/20 09:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Oual HEM, Oil and Grease Analytical Method: EPA 1664E Pace Analytical Services - Charlotte Oil and Grease ND mg/L 5.0 1 12/20/20 11:07 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G-2011 Pace Analytical Services -Asheville Chlorine, Total Residual 0.10 mg/L 0.024 1 12/18/2019:19 7782-50-5 H3 Date: 12/21/2020 07:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 19 liVaAnalyticalo www.pacalaDs.eam QUALITY CONTROL DATA Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: 588391 Analysis Method: EPA 1664B QC Batch Method: EPA 1664B Analysis Description: 1664 HEM, Oil and Grease Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92511321001, 92511321002, 92511321003, 92511321004, 92511321005, 92511321006, 92511321007, 92511321008 METHOD BLANK: 3109109 Matrix: Water Associated Lab Samples: 92511321001, 92511321002, 92511321003, 92511321004, 92511321005, 92511321006, 92511321007, 92511321008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Oil and Grease mg/L ND 5.0 12/20/20 11:03 LABORATORY CONTROL SAMPLE: 3109110 Oil and Grease MATRIX SPIKE SAMPLE Parameter Oil and Grease mg/L Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 40 31.7 79 78-114 3109111 92511294002 Spike MS Units Result Conc. Result mg/L ND 40 46.0 MS % Rec % Rec Limits Qualifiers 104 78-114 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 12/21/2020 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 19 aceAnaljftal www.pacolsbs.com i QUALITY CONTROL DATA Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: 588239 Analysis Method: SM 4500-CI G-2011 QC Batch Method: SM 4500-CI G-2011 Analysis Description: 4500CL G Chlorine, Total Residual Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92511321001, 92511321002, 92511321003, 92511321004, 92511321005, 92511321006, 92511321007, 92511321008 METHOD BLANK: 3108436 Matrix: Water Associated Lab Samples: 92511321001, 92511321002, 92511321003, 92511321004, 92511321005, 92511321006, 92511321007, 92511321008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chlorine, Total Residual mg/L ND 0.024 12/18/20 18:37 SAMPLE DUPLICATE: 3108437 Parameter Chlorine, Total Residual 92511321001 Dup Units Result Result mg/L 0.028 0.026 RPD Qualifiers 7 H3 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 12/21/2020 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 19 aceAnalytical www pactltbs.cam I QUALIFIERS Project: Bakers South Pace Project No.: 92511321 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 9800 Kfncey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS H3 Sample was received or analysis requested beyond the recognized method holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/21/2020 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 19 aceArlalytrcat www.pacalabsccm QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Bakers South Pace Project No.: 92511321 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 92511321001 Non -Contact #1 EPA 1664E 588391 92511321002 Non -Contact #2 EPA 1664B 588391 92511321003 Non -Contact #3 EPA 1664E 588391 92511321004 Non -Contact #4 EPA 1664E 588391 92511321005 Non -Contact #5 EPA 1664B 588391 92511321006 Non -Contact #6 EPA 1664E 588391 92611321007 Non -Contact #7 EPA 1664B 588391 92511321008 Non -Contact #8 EPA 1664E 588391 92511321001 Non -Contact #1 SM 4500-CI G-2011 588239 92511321002 Non -Contact #2 SM 4500-CI G-2011 588239 92511321003 Non -Contact #3 SM 4500-CI G-2011 588239 92511321004 Non -Contact #4 SM 4500-CI G-2011 588239 92511321005 Non -Contact #5 SM 4500-CI G-2011 588239 92511321006 Non -Contact #6 SM 4500-CI G-2011 588239 92611321007 Non -Contact #7 SM 4500-CI G-2011 588239 92511321008 Non -Contact #8 SM 4500-CI G-2011 588239 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 12121 /2020 07:29 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 19 Document Name: Document Revised: October 28, 2020 • aeeAnalytieal Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.07 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville E] Raleigh❑ Mechanlcsville❑ Atlanta❑ Kernersville❑ Cllent��t Project IfWO# • 92511321 Courfer: FlEed Ex ❑UPS ❑USPS ❑Client ❑ Commercial ✓ Pace []Other:_ Custody Seal Present? ❑Yes " No Seals Intact? ❑Yes ❑v No Packing Material: []Bubble Wrap QBubble Bags ❑Non % ❑ Other Thermometer- tiWet ❑Blue j R Gun 10: 92TO64 Type of Ice: Correction Factor: Cooler Temp: 3- 5p Add/Subtract ('C) -0.1 Cooler Temp Corrected (' ): 3 7, `f USDA Regulated Sall N/A, water sample) Did samples orlg pite in a quarantine zone within the United States: CA, NY, or SC (check maps)? 92511 92611321 Date/Initials Person Examining Contems:�/11A 0 Biological Tissue F azen? []Nonee [:]Yeses []No U/A Temp should be above freezing to 6'C []Samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source (internationally, including Hawaii and Puerto Ricol? bVI yes NO Comments/Discrepancy: Chain of Custody Present? Dyes Eho N/A 1. Samples Arrived within Hold Time? ves N/A 2. Short Hold Time Analysis (02 hr.)? r1yes �No No N/A 3. Rush Turn Around Time Requested? []Yes No EINJA 4. Sufficient Volume? yes No 5. Correct Containers Used? -Pace Containers Used? ��s 4es ❑No No r❑yN/A [�N/A N/A 6. Containers intact? Yea No ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑ves QNo F N/A a. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: es V'L ❑No ❑N/A 9. Heads ace in VOA Vials >S-6mm)7 QYeS QN0 N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? []Yes Yes ❑No LINO N/A 19d/A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION - Person contacted! Project Manager SCURF Review: Date/Time: Date: Field Data Required? ❑Yes ❑No Project Manager SRF Review: Date: Page 16 of 19 Document Name: Sample Condition Upon Recel Analytical Document No.: F-CAR-CS-033-Rev.07 *Check mark top half of box if pH and/or dechlorination is Project # verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottles Document Revised: October 28, 2020 _ Page 2 of 2 Issuing Authority: Pace Carolinas Quality Office WO#:92511321 PM: MWB Due Date: 12/22/20 CLIENT: 92-Allvae NC .� ai > j4r! E 3 eo z igs �i >6. .� E pp nJ1 M Co z 0 a yr E Qg vN7 N m _ Q 2 y m {r7 N a a .�' '° E N Q o. m r V a rn u Q E • M a m n' M 3 E N N a Co .u�•. 'N' a 2 Na` a44; E d m m ho o d, �_ y ,7j+' r" 3 Z 0 E = e-I r/ �7 a '° as rr l7 a U Z d °' o Q E Ln N M t7 a ^� a 0 _ a a`i e / .�•i t9 a v a N E *J M t7 a u \ z 14 ? -J N ni �Q fK l7 a u O E o O1 .., Z M 'N° p E $ Q~1 t7 > .. I a c O E C=1 l� > a en E 01 l9 o .. 2 x M! ''" a O >> z > ?' •'� ' v Ur ' Nazs ,a1� E eel I�f1 o. V1 .. I�0 Q ti d E yob N N M N u E Ln N M d \ •� d ° a a E r1 0 l7i .-. 2. a .� E 0 N ` N f0 a .. E 0g 7 G1 t7 1 . � 2 3 I 4 _ 5 6 8 � 9 10 it 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Bate preservation adjusted Time preservation adjusted Amount of Preservative added Lot # Note: Whenever there is a discrepancy affecting worth carouna compnance sampies, a copy or tors rorm wan oe sent to ine rvarcn t.aroana ucnnn t-ertnncauon unto tr.c. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 17 of 19 Stormwater Monitoring (NON CONTACT) Bakers North Chain of Custody Record Project Number/Name: Non Contact Cooling Water Project Location: ATl-SM - Bakers Sampler's Signature: ��d� Date: a� a > so U Requested Test A F• �, •a w° Parameters Non -Contact #1 .• G G HC1 Y ,,$- Oil & Grease Non -Contact #2 : q G G HCl Y �, Oil & Grease Non -Contact #3 :3„• G G HCl Y Oil & Grease Non -Contact #4 G G HC1 Y 8,� Oil & Grease Non -Contact #5 .• G G HCl Y D• o? Oil & Grease Non -Contact #6 p:pa. G G HC1 Y Q, Oil & Grease Non -Contact #7 p:,� G G HCl Y Oil & Grease Non -Contact #8 .•off„ G G HCl Y Oil & Grease Meter Calibrated: / N Thermometer Calibrated: / N Sampling and Field analysis completed by: Relinquished b Received b Date: Time: .' Date: Relinquished by:.--, : ";�... 9�z. . , s Received by: aC� Date: 17- /­t'­ Time: Date: la/rr ,?a Time: 1 Stormwater Monitoring -Non Contact Cooling Water Chain of Custody (oil & Grease) Rev. 03 6/2/2020 Page 18 of 19 Stormwater M®nit�rin (NON CONTACT) Bakcrs North Chain of Custody Record Project Number/Name: Non Contact Cooling Water Project Location: ATl SM - Bakers Sampler's Signature: Date: �„ D C6 aj 04 c, O V H H V 0 ,,,, y �' Requested Test Parameters 9 6 0 4 > p V t H H Non -Contact #1 �, G P None Y 'y a ,S' Residual Chlorine ev i Non -Contact #2 G P None Y Residual Chlorine ct, Non -Contact #3 G P None Y # Residual Chlorine o: ) Non -Contact #4 : p,Z,,,, G P None Y 7.,6g.;3 Residual Chlorine Non -Contact #5 G P None Y 21017 Residual Chlorine c'u Non -Contact #6 G P None Y p, Residual Chlorine vv � Non -Contact #7 G P None 1 Y Residual Chlorine e- 3 Non -Contact G I P None I Y , 9 Residual Chlorine :' Meter- Calibrated: fD I N Thermometer Calibrated: I N Sampling and Field analysis completed by: Relinquished by: Received by: . • �Da+... Date. 1 aQTime. �� Date: ' '� T'me: .; Relinquished by:_ 4 Received by: Date: Time: ' Date: l 1 z Time: ja3o ,tormwater monitoring -won co9taei cooing water chain of Gummy (Kestouai cntonne) Kev. u3 61212o2o Page 19 of 19