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HomeMy WebLinkAboutNCS000251_COMPLETE FILE - HISTORICAL_20200124- .,,..,..,...:::: - -. STORMWATER=DIVISION CODING -SHEET... RESCISSIONS - PERMIT NO.. N, [DOCTYPE COMPLETE FILE = HISTORICAL DATE OF RESCISSION ❑ . YYYYMMDD Georgia-Pacific Chemicals LLC Conway Resins Plant P.O. Box 368 Conway, NC 27820 Phone (252) 585-1232 Fax (252) 585-1754 January 20, 2020 Certified Mail — 7014 2120 0004 5521 1593 North Carolina Department of Envieonmental Quality Division of Water Quality Surface Water Protection Section; i1 1617 Mail Service CcnD ter V � ATTENTION: Central files JAN 2 4 2020 Raleigh, NC 27699-1617 CENTRAL FILES DWR SECT10N I Z I Stormwatcr Permit NCS000251 Georgia-Pacific Chemicals LLC Northampton County Stormwater: Monitoring - August 1, 2019 —January 31, 2020 - R1 VISED Conway, NC Ms. McCoy; During a recent document review, Georgia-Pacific Chemicals LLC discovered that a portion of the data was incorrectly documented on our Stormwater Discharge Outfall (SDO) Monitoring RCpOrt (Form SWU-246-051 100) originally submitted to your office on December 23, 2019. In summary, the contract lab reported the analytical results for Cresols and Phenol as ug/L. When filling the 1=orm SWU-246-051 100, these results were not converted to mg/L, the units shown on the form, and therefore results of the analysis were overstated. Note that all parameters were within the compliance limits and are supported by the enclosed contract lab analysis (enclosed Order ID: 191 1258). Although only page 2 of the Form SWU-246-051 100 was revised, the entire package for the monitoring period (August 1, 2019 — January 31, 2020) is being resubmitted for the sake of completeness. We helieve that the corrected report will meet with your approval. Should you have any questions, please feel free to contact Tim Riddick at (252) 585-3819. Sincerely, A /� �. VV ✓ v� Ronald E?. Walls Regional Manufacturing Manager w/attachments: cc: Tim Riddick, Georgia-Pacific Chemicals I'I,C STORNINVATER DISCHARGE OUTFALL (SDO) \IONTTORING REPORT Permit Number: NC NCS000251 or Certificate of Cos•erage Number: NCG FACILITY NAME? Georgia-Pacific Chemicals LLC PLRSON COLLECTING SAMPLE(S) Tim Riddick CERTIFIED LARORATORY(� Universal Laboratories Lab# 543 Summit Environmental Labe# 631 Georgia-Pacific Chemicals LLC Lab# 5464 Part A: Specific Monitoring Requirements SAMPLES COLLECTED DURING CALENDAR YEAR: 2019 (This monitoring report shall be received be the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) COUNTY No rthampton PHONE , -123 (SIGNATURE OF PERMTTTE F, OIL DESIGNEE) By this signature. 1 certify that this report is accurate complete t0 the best of nry knowledge Outfall No. Date Sample Collected 50050 00556 00310 00340 00601) 00665 00400 Total Flow Oil and Grease RODS COD Total Nitrogen Total Phosphorus PH moldd/ yr 11G m /l m /l m /I m dl mg/1 S.U. 001 11/01/19 0.(140 <5 5 46.9 1.40 0.45 7.2 002 11/01/19 0.188 <5 3 28.5 2.64 0.12 8.9 003 11/01/19 0.021 <5 8 56.2 1.69 0.32 7.1 004 11/01/19 0.029 <5 3 23.8 0.86 0.12 6.9 002 12/09/19 0.063 nla n/a n/a n/a nla 8.1 Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?_\ yes _no (If yes, complete Part R) Part It: Vehicle Maintenance Activity Monitorin-, Requirements Outfall No. Date Sample Collected 50050 00556 00530 00400 Total Flow Oil and Grease Total Suspended Solids PH New Motor Oil Usage moldd/vr 11G m ll m 1l S.U. Ra1/mo 002 11/01/19 0.188 <5 11.0 8.9 100 002 12/09/19 (1.063 nta n/a 8.1 100 Form SNYU-246-051 100 Page I of3 STOR,NINYATER DISCIIARGL OUFFALL (SDO) MONITORING REPORT PermitNumber: NC NCS000251 or Certificate of Coverage Number: NCG FACILITY NAME Georgia-Pacific Chemicals LLC PERSON COLLECTING SAMPLE(S) Tim Riddick CERTIFIFI) LABORATORY(S Universal Laboratories Lab# 543 Summit Environmental Lab# 631 Georgia-Pacific Chemicals LLC Lab# 5464 Part A: Specific Monitoring Requirements SAMPLES COLUCTED DURING CALENDAR YEAR: 2019 ("this monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) COUNTY Northampton PIIONE . . J 25 585- 2 2 (SIGNATURE OF PERMITTEE OR DESIGNEE) By this signature, 1 certify that this report is accurate complete t0 the best of my knowledge Outfall IN Date Sample Collected 50050 Total Flow -cresol o-cresol m-cresol Cresol Phcnol Formaldehyde NI'DES Flow re, Wier moldd/yr \IG m =/I m I m g/I m /I m /I mall MGD 002 11/01/19 0.188 nIa n/a n/a n/a nla 0,0939 n/a 002 12/09/19 0.063 <0.005 <0.005 <0.005 <0.005 41.005 nla n/a Form .SNN'ti-246-051100 Page 2 of 3 STORM EVENT CHARACTERISTICS: flail Original and one copy to: Division of Water QUalit,, Date: 11/01/2019 Attn: Central Filcs Total Event Precipitation (inches): 1.2 1617 Mail Service Center Event Duration (hours): 1.5 (only if applicable — see permit.) Raleigh. North Carolina 27699-1617 (if more than one storin event was Sampled) Date Total Event Precipitation (inches): Event Duration (hours): (only if applicable — see permit.) "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a System designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information. the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." kuZ� (Signature of Permrttee) (Date) Form SWU-247. last revised 21212012 Pate 3 of 3 Input total inches during storm event Input storm event duration Calculated rainfall intensity Outfall 001 Stormwater Flow Estimate Drainage Area Runoff {acres) Coefficient (c) 0.49 0.2 1.26 0.9 1.75 0.7 Calculated Flow 0.99 cfs 37 810 Gallons mmPG 0.040 Q = ciA, where Fall Event - 2019 11/01/19 1.2 inches 90 Iminutes 0.800 inlhr Q = Flow (cfs) c = runoff coefficient i - rainfa€I intensity (in/hr) A = area (acres) Outfall 002 Stormwater Flow Estimate Drainage Area Runoff (acres) Coefficient (c) 6.48 0.9 6.48 0.9 Calculated Flow 4.67 cfs 188 453 Gallons 0.188 Outfall 003 Stormwater Flow Estimate Drainage Area Runoff (acres) Coefficient (c) 1.30 0.2 0.45 0.9 1.8 0.38 Calculated Flow 0.53 cfs IIIF2—i 4-89-= Gallons 0.021 Outfall 004 Stwrwater Flow Estimate Drainage Area Runoff (acres) Coefficient (c) 1.01 0.9 1.0 0.90 Calculated Flow 0.73 cfs jjj29 373 Gallons 0:029 STORM EVENT CHARACTERISTICS. - Date: 12/09/2019 Total Event Precipitation (inches): 0.4 Event Duration (hours): 7. 0 (only if applicable —see permit.) (if more than one storm event was sampled) Date Total Event Precipitation (inches): Event Duration (hours): (only if applicable— see permit.) Mail Original and one copy to: Division of Water Quality Attn: Central files 1617 ,Mail Service Center Raleigh, North Carolina 27699-1 G 17 "1 certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquire of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." M& I /Z°Iza (Signature of Permittee) (Date) Form SWU-247_ Iasi revised 21212012 Page 3 of 3 Input total inches during storm event Input storm event duration Calculated rainfall intensity Outfall 001 Stormwater Flow Estimate Drainage Area Runoff (acres) Coefficient (c) 0.49 0.2 1.26 0.9 1,75 0.7 Calculated Flow 0.07 cis 111IF-72-7,51M Gallons mmPG 0.013 O = ciA, where Fall Event - 2019 12/09/19 0.4 inches 420 minutes 0,057 in/hr O = Flow (cfs) c = runoff coefficient i = rainfall intensity (inthr) A = area (acres) Outfall 002 Stormwater Flow Estimate Drainage Area Runoff (acres) Coefficient (c) 6.48 0.9 6.48 0.9 Calculated Flow 0.33 cfs 62 818 Gallons pA63 Outfall 003 Stormwater Flow Estimate ❑rainage Area Runoff (acres) Coefficient (c) 1.30 0.2 0.45 0.9 1.8 0.38 Calculated Flow 0.04 cfs 7163 Gallons OA07 Outfall 004 Stormwater Flow Estimate Drainage Area Runoff (acres) Coefficient (c) 1,01 0.9 1.0 0.90 Calculated Flow 0.05 cfs 9 791 Gallons Universal Laboratories 20 Research Drive Hampton, VA 23666 Phone: 1.800-695-2162 Fax: 767-865-8014 Client Report For: Georgia Pacific Attention: Mr. Tim Riddick Client Address: P.O. Box 368 Conway, NC 27820 Project: Semi -Annual Stormwater Order Number: 1910289 Report Date: 12/03/2019 Lab Receipt Date: 11/01/2019 Comment: This report contains the analytical results for the indicated Project and Order. The results contained in this report relate only to the samples identified In this Order. The analytical results meet all requirements of the 2009 TNI Standard, unless specifically stated or laboratory floes not hold accreditation as seen in the Cert # column. This report shall not be reproduced except in full. } /J � The data in this report has been reviewed and validated by:- ���,,,a-..cJ Signature .-. ._ f� _/ 1-1-a- n e— Nama tPl/ nt1I�Z, TIUe Repoli Smut rt. loinlGC Page 1 of 6 Repon Tym Oipinal Universal Laboratories �Cli t gGeorgiafPacific '' + '11+r c r -: -� f -"-VTY-T-r?—_- Clienrrinle,ID: F,001f I .� - �7' ♦S, / 1 ';i?'li]:?'19,10289r00,1( .,5. ., r] 1 .' Y •., I+ts`, z';";;, ���y '4 1 r I✓ �l •�� k "i�... :r'�.''4!'.' 1., : a,�l, ,' �CollaCtionlDate.,,191011�01901.101 , � i r v t erml Dar ;j c . t ` 4ii �I .f..,,i 1 1 �.',�Qu�CEU�I IM iriX I ! Analyses Btochernkal Oxygen Demand (BOD) 5 Day SM 5210 B (2011) Holding Time Met Sample Receipt Temperature Biochemical Oxygen Demand Chemical Oxygen Demand Sample Preservation pH Holding Time Met Sample Receipt Temperature Chern'cal Oxygen Demand Nitrogen, Total Sample Preservation pH Holding Time Met Sample Receipt Temperature Nitrogen, Total Oil and Grease (SGT•HEM) Sample Preservation pH Holding Time Met Sample Receipt Temperature Petroleum Oil Hydrocarbons (SGT- HEM) Phosphorus, Total Sample Preservation pH Holding Time Met Sample Receipt Temperature Phosphorus, Total Test Result Unit Yes Yes/No 1 C 5 mg1L HACH 8000 Test Result lJni_t 1 pH Units Yes Yes/No 1 C 46.9 mg1L EPA 351.21 EPA 353.2 Test Result Unit 1 pH Units Yes Yes/No 1 C 1.40 mg1L EPA 1664A Test Result unit 2 pH Units Yes Yes1No 1 C ND mg1L EPA 365.1 Test Result Unit 1 pH Units Yes YesINO 1 C 0.45 mg+L RL Analysis date Analysis 13y _QUaliiier cert ## 11/011201915:49 LS 11/011201015:49 LS 2 111011201915:49 LS 460036 RL Analysls Date Analysis BV Qualiffler Cert # 111051201913:06 LS 11105/201913:06 LS 1110512019 13:06 LS 20 11/051201013:06 LS 460036 RL Analysis Date Analysis By Quallifier Cert # 11105120i9 i5:07 AS 1110512019 15:07 AS 1110512019 15:07 AS 0.2 1110512019 15:07 AS RL Analysis Date Analysis By Quallifler Cert 1111312019 12:37 LS 111131201912:37 LS 111131201912:37 LS 5 111131201912:37 LS 460036 RL AnPIYW.% Date Analysis By 9yalffler Cert 1110512019 14:59 AS. 111051201914:69 AS. 11/05/2019 14:59 AS, 0.02 11105/2019 14:59 AS. 460036 Repod Serial a: 10MIALo Page 2 of 6 Repon TW9' Odginsl Universal Laboratories Cliert;YC3eorgia,F'acific ;4 '�r,, r Client:Sar7i ID:[OF,1002fy >° ^. .• yr. i A.•r1 `, !- 'A f.. �•..1�t[�. [WIQ-- e1910289-002�' € '` [ [�Gollect�gn'Date �,11101720,19,00 301 r L �ti--� -v1v rr �, •� [ jS �J .I - r_ ,�' [ ..S J T "rt r'rr"�k J•� a �€�� �• '[ �• �,., IPe"mtilD� r };: '{ ;+� r .,' a `'''r� ";.r ' at UEOUS[f.'' Analyses Blochemical Oxygen Demand (BOD) 5 Day SM 5210 B (2011) Holding Time Met Sample Receipt Temperature Biochemical Oxygen Demand Chemical Oxygen Remand Sample Preservation pH Holding Time Met Sample Receipt Temperature Chemical Oxygen Demand Nitrogen, Total Sample Preservation pH Holding Time Met Sample Receipt Temperature Nitrogen. Total Oil and Grease (SGT-HEM) Sample Preservation PH Holding Time Met Sample Receipt Temperature Petroleum Oil Hydrocarbons (SGT- HEM) Phosphorus, Total Sample Preservation PH Holding Time Met Sample Receipt Temperature Phosphorus, Total Solids, Total Suspended Holding Time Met Sample Receipt Temperature Solids, Total Suspended Test Result Unit Yes Yes/No 1 C 3 mglL HACH 8000 Test Result Unit 1 pH Units Yes YeslNo 1 C 28.5 mglL EPA 351.21 EPA 353.2 Test Result Unit 1 PH Units Yes Yes/No 1 C 2.64 MO. EPA 1664A Test Result Unit 1 pH Units Yes Yes/No 1 C ND mglL EPA 365.1 Test Result Unit 1 pH Units Yes YeslNo 1 C 0.12 mglL SM 2640D (2011) Test Result Unit Yes YeslNo 1 C 11.0 mg1L RL Analysis Date Analysis By. Quallifler 111011201915:49 LS 111011201915:49 LS 2 11101/201915:49 LS RL Analvsls Date Analysis By quallfler 11105/201913:05 LS 111051201913:06 LS 111051201913;06 LS 20 11106/201913:06 LS RL Analysis Date Analysls By Qualifler 11/051201915:07 AS 111051201915:07 AS 111051201015:07 AS 0.2 111051201915:07 AS RL Analysis Date Analysis By Quallifie 111131201912:37 LS 111131201912;37 LS 111131201912:37 LS 5 111131201912:37 LS RL Analvsls Date Analysis By Qtwiffler 111051201914:59 AS. 111051201914:59 AS. 111051201914:50 AS. 0.02 111051201914:59 AS. RL, Analysis Date Analysis By Qualifier 11107/2019 20:09 EK 11107/2019 20:09 EK 1 11107/2019 20:09 EK ReW &60 p: so,noaa Page 3 of 6 Rapo6 Type; odg!nal Cert 460036 Cert 460036 Cert Al Cert 1t 460036 Ce 460036 Cart Al 460036 Universal Laboratories 4 9aP, ac c ,: , ClfentSamule'IQ�, OF,-q , Uab 1 '',1990289 003? ,. Collect{ori�D�te:�,9;1I01l2019i00'.a,� 1 lY J i]� r' �l 7�" i +� a •6'R s 11•1' IVY lr r' t ` 11 ,. ,ill. er nit r_` .-r'tttettt _-�....—._r .-+J+1Sll �.�.�rr{l�ili� •i .� r1 # tr ..AQU>=OUS __1__., _��. �Nr _��._.-.��+�.r. _.�w+}.+�lL' _ Y�.�—�_�-_._—.�_• — al ses Biochemical Oxygen Demand (SOD) 5 Day SM 5210 B (2011) Test Resul# Unit RL Analysis Date Anal sis By Qualifle Cert # Holding Time Met Yes Yes1No 11101/201915:49 LS Sample Receipt Temperature 1 C 11101/201915:49 LS Biochemical Oxygen Demand a mg1L 2 111011201915:49 LS 460036 Chemical Oxygen Demand . HACH 8000 Test Result Unit RL Analysis Date Analysis B Quallfier Cert # Sample Preservation pH 1 pH Units 11105/2019 13:06 LS Holding Time Met Yes Yes/No 11105/2019 13:06 LS Sample Receipt Temperature 1 C 11/05/201913:06 LS Chemical Oxygen Demand 56.2 mg1L 20 11105/201913:06 LS 460036 Nitrogen, Total EPA 351.21 EPA 353.2 Test Result Unit RL Analysis Date Analvols By Qualifle Cort # Sample Preservation pH 1 pH Units 1110512019 15:07 AS Holding Time Met Yes Yes/No 11/05/201915:07 AS Sample Receipt Temperature 1 C 11/05/2019 15:07 AS Nitrogen, Total 1.69 mg1L 0.2 11/0512019 15:07 AS Oil and Grease (SGT-HEM) EPA 1664A Test Resin Unit RL Analysis Date Analysis 8 Qualifier Cert Al Sample Preservation pH 1 pH Units 11/1312019 12:37 LS Holding Time Met Yes Yes1No 11/131201912:37 LS Sample Receipt Temperature 1 C 11113/201912:37 LS Petroleum Oil Hydrocarbons (SGT- ND m01 5 1111312019 12:37 LS 460036 HEM) Phosphorus, Total EPA 365.1 Test Result Unit QL3 Analysis Date Analysis 0 Qualifier Cert # Sample Preservation pH 1 pH Units 11/0512019 14:59 AS. Holding Time Met Yes Yes/No 11/051201914:59 AS. Sampla Receipt Temperature 1 C 11/05/201914:69 AS, Phosphorus, Total 0.32 Mg1L 0.02 11105/201914:59 AS. 460036 Repmd SedsI p: IGIMAm Page 4 of 6 Raporr Tjvc Odpinal Universal Laboratories �C Ie rt: G pe rg a1 Pacificl �- �rClie tr1 S ma loll -woF'0041 iL6llD:i9910289-004i" ��lr r r lec o dilate-i"'I910,1720,190i 30; 1. 'I, M., 1r1 ,''^"1--" a �.`• i+ .,_,. � yyCri .`l Y,1 Vy11kX"ti rri. r�4 4 ", IlPeirnitlil]'' ,,: k jMatrix:'AGIUEOUS Analyses Blochemlcal Oxygen Demand (BOD) 5 Day SM 5210 a (2011) Holding Time Mel Sample Receipt Temperature plocherrical Oxygen Demand Chemical Oxygen Demand Sample Preservation pH Holding Time Met Samp% Receipt Temperature Chemical Oxygen Demand Nitrogen, Total Semple Preservation pH Holding Time Met Semple Recelpt Temperature Nitrogen, Total Oil and Grease (SGT-HEM) Sample Preservation pH Holding Time Met Sample Receipt Temperature Petroleum Oil Hydrocarbons (SGT- HEM) Phosphorus, Total Sample Presem Ean pH Holding Time Met Sample Receipt Temperature Phosphorus, Total Test Result Unit RL Analysis Date Analysis By gualifier Cert # Yes YWNo 111011201915:49 LS 1 C 11/01/201915:49 t•S 3 mg1L 2 1110 1/2019 15:49 LS 460030 HACH 8000 Test Result Unit 1 pH Units Yes YeslNo 1 C 23.8 mgfL EPA 351.21 EPA 353.2 Test Result U� i pH Units Yes Yes/No 1 C 0.86 mg1L EPA 1664A Test Result Unit 1 pH Units Yes Yes/No 1 C ND mg1L EPA 365.1 Test Result Y919 1 pH Units Yes YeslNo 1 C 0.12 mg1L RL Analysis Date, Analysis By Quallifier curt # 11/05/201913:06 LS 11105/2019 13:96 LS 1110512019 13;06 LS 20 11105/201913;06 LS 46OD36 RL Analysis Date Analysts By Qualifie CeEj 111051201915:07 AS i t10512019 15:07 AS 111/0512019 15:07 AS 0.2 11/051201915:07 AS RL Analysis Date Analysis sy Qualifier Ce 11113/2019 12:37 LS 11113120t912:37 LS 11113/201912:37 LS 5 111131201912:37 LS 460036 RL 0.02 Analysis Date Analysis B Quallfier Cart Al 111051201914:59 AS. 111051201914:59 AS. 1110512019 14:59 AS. 1110512019 14:59 AS, 460036 Reppn Serial k 161r1 0 page 5 of 6 liepekt Type: Original Glossary of Terms and Abbreviations ND No analyte dslecled al or above the RL (Reporting 1-161) listed NR No Results available, analyte not in instrument calibration (Reporting L1mll) The minimum levels, concentrations, or quantities of a target analyle that can be reported within a specified degree of confidence. Generally, this number Is equal to or just above the lowest calibration standard run wilh the analytical batch, RL Ii f B Analyle was found In the method blank Ji �p H RPD outside acceptable limits Holding lime excooWod [is Internal standard outside acceptable limits f �J Result above calibration curvo - results are approximate L LC Outside acceptable limits ~ Matrix tnterence Matrix spike recovery outside acceptable limits )MI [MS 1QC Method OC criteria not met Surrogate outside acceptable limits S IV LCS ICVICCVIFCV outside acceptable limits (Laboratory Control Sample) A sample matrix, free from The analytes of Interest, spiked with verified known amounts of analytes or a material containing known and verified amounts of anafytes. Method Detection Llmitis is an estimate of the minimum amount of a substance that an analyllcal process can reliably detect IMDL j RPD (Relative Percent Difference) The difference between a set of duplicates or sample spike duplicates. M SIMSD (Matrix Spike or Matrix Spike Duplicate) A sample prepared by adding a known mass of target analyto to a specified amount of matrix sample for which an Independent estimate of target onalytes concentration is available. Matrix Spikes are used, for example, to determine the effect of the matrix on a method's recovery efficiency. ICalibratlon Verficatlon (Initial. Continuing, or Final) A standard analyzed at different times to verify that the Initial calibration curve Is still valid. The maximum time that samples may be held prior to analysis and still be considered valid or not compromised. lHolding Time (Internal standard A -known amount of standard added to a test portion of a sample as a reference for evaluating and controlling the precision and bias of the applied analytical method. Method Blank A sample of a matrix similar to the batch associated samples (when available) that is free from the enalytes of interest and is processed slmulatanouslywith and under the same conditions as samples. Surrogate A substance with properties that mimic the anadyte of interest. It is unlikely to be found In environmental samples and is added to them for quality control purposes in Organics. _ Exceeds Permit Limit. This Is a qualifier to denote that the result exceeds the permit limit of the sample location, EPL. Exceeds Benchmark I Concentration Result Exceeds Benchmark concentration listed in the General Permit. Benchmark Concentrations are primarily used to determine the overall affectivenss of the Siormwater pollution prevention plan. Excedence of Benchamrk concentrations does NOT constitute a violation of this permit and does NOT indicate that violation of a water quality standard has occured. yr It present under the "Cart #" column, Indicates that the laboratory does not have 2009 TNt accreditation in Virginia. These analytes should not be reported for Virginia Air, Water, or Waste Laws or the Safe Drinking Water Act to meet their requirements. 460036 if present under the "Cent #' Column, Indicates that the laboratory holds accreditation under the 2009 TNI Standard in Virginia. SM 521 OB-2011 7.b. Test replicates show more than 30efe difference between high and low values R Report sodAI M. to,n,.o Page 6 of 6 Report Types Original Georgia Pacific P.O. Box 368 Conway,NC,27820 C,ontact:Tim Riddick,252- 585-123Z (c)252-395- 1625,TARIDDIC®GAPAC.Com Universal Laboratories CHAIN OF CUSTODY ID: 1910289 Semi -Annual Starer water 20 Research Drive Hampton, VA 23666 1-800-695-2162 http://www.universallaboratohes.net Page 1 of 2 ' Saiteple:Narne_' - 11L'%Sample`, :ID Matrix; Sample DateJTiiiseAnitials_ _ BattlelD Sample.' 'Container Prjeservation Testing. j OF-M11 1 1910289-001 AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS q 6,10 a'^ 001A 2501GIass H2SO4/<6°C r vrdste'TRANS, SOD, COD, TN, OGN,T.PHOS 001E 5oOMOPE H2SO4c6°7 ODIC I/HOPE <WC 0010 1/Glass H2SO41-cVC 001E 1/Glass H2SO41<6°C IOF-002 1910289-M AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS lq � }0 0.+M ,� OD2A 250/Glass H2SO4/<6°C T6V waste, BOD, COD, TN. OGN, T.PHOS. TSS, 625 002B 500/HDPE H2SO4/<6°C OD2C 1/HOPE <6'0 002D 1/Glass H2SO4/<6°C 002E 1/Glass H2SO41<6°C 002F 1/Glass <6'C 002G 2/HDPE <6°C 002H 1/Glass <61C OF-003 1910289.003 AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS I , q / p V^ ��' ` 7 003A 2501GIass H2SO41<6•C :ql< waste, SOD, COD. TN, OGN, T.PHOS 0038 500/HDPE H2SOW S-C O03C 1/HDPE <6°C 003D 11Gtas5 M2SO41<6'C 003E 1/Glass H2SO41<6`C OF-004 1910289-004 AQUEOUS AQUEOUS AQUEOUS AQUEOUS IAOUEOUSI {�+ j�� O l 0\10 1004E 004A 250/Giass H2SO4/<WC waste, BOD, COD, TN, OGN, .PHOS t f 0048 SOO/HDPE H2SO4/<6=C 004C 11HDPE <6'C 004D VGlass H2504/<6°C 1 11GIass H2SO4/<e C NOTES: CoolerTernp C Phenol int checK- CN int check BOD int check NH3 int check TRANSFER SIGNATURE DATEITIME TRANSFER SIGNATURE DATE/TIME Georgia Pacific P.O. Box 368 Conway,NC,27820 Contact:Tim Riddck,252- 585-1232, (c)252-395- 1625,TARtDDIC@ GAPAC,=n Universal Laboratories CHAIN OF CUSTODY ID. 1910289 Semi Annual S$ormwater 20 Research Drive Hampton, VA 23666 1-800-695-2162 http:tlwww.universa iaboratodes.net Page 2 of 2 Relinquished by��c* j I-�t4 1 Received by Relinquished by Received by I(-�1415( Relinquished by Received by Relinquished by Received by S, r - e I�j -S'moerir Dwironmenmi 7eclurologhm Inc. ZN� k �� L� 3310 Win St. E;;inlGlllaE'14rnL7Fcno"01,orm ir:r Cuyahoga Frrlls,Ohio 44223 Almiyrlcaf Lnbormorl6s THL (330) 25.3-8211 I:LY: (330) 253.4.189 1Vebsire: 11irU:/ltrrrrrse!!ed'.cour November 12, 2019 Tim Riddlek Georgia Pacific hic. 27820 �Q�g 1 200 Ampac Rd.P.O. Box 368 1�0V Conway, NC 27820 TEL: (252) 585-1232 FAX: (252) 585-1754 REi: Water Formaldehyde test Dear Tim Riddick: Order No.: 19110070 Summit Environmental Technologies, Inc. received 1 sample(s) on 11/2/2019 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, ]-lolly Florea Project Manager 3310 Will St. Cuyahoga Falls, Ohio 44223 Arkansas 88.0735, Cnlifomia 07256CA, Colorado, Connecticut f H-0108, Dclnware, Florida NFI.AC F87688, Georgia F87688, Idaho O1100923, Illinois 200061. fndiana C-011-13, Knusas E-10347, Kcutucky (Underground Storage Tank) 3, Kcnlucky 901.16, Louisiana 04061, Maryland 339. Nlinnesola 409711, New Hompsldre 2996, New Jersey 01,1006, New York 11777, North Carolina 39705 nod 631, North Dakota R-201, Ohio DW, 016o VAP CL0052, Oklahoma 9940, Oregon OH200001, Pcmtsyfcania 010, Rhode Island LA000317, Smah Carolina 91016001, Texas T104704466.11-5, Ulah OH009232011-I, Virginia VELAP9.156, WnslungtonC891 Page 1 of 9 'T7,J r struruut Ern.1r-o..... rtn! Teclurola�ies, hrc. t: : ,%��y'� ������j�t Case Narrative E,`NIIII)fIMOJ1'hLTfi1:HNO1OnIF M'r.. C+rydreigaFolls.Ohio 44223 11to/: 19110070 hrJ,dyflcal I abounfoiles TEL (.330) 253-82111•i1X: (330) 253-4439 Website: h j.-Mvinvaeltekmrr Date: 11/12/2019 CLIENT: Georgia Pacific Ills. 27820 Project: Water Formaldehyde test This report in its entirety consists of the following dOe1.1111C tS: Cover I.cttei•, Case Narrative, Analytical Results, QC SLlnlmary Report, Applicable Accreditation 111FOl'mati011, Chalil-Of-CLIstody, Cooler Receipt Form, and other applicable forms as necessary. All dOCLIInCntS contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Surnmi( Lilvii-ollilletltal'l'ccllllologies, Inc., holds the,iccreditatioiis/certifications listed at the bottom of the cover, letter that may or may not pertain to this report, Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit I3'nvirollmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental 'Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Suminit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation On the reporting U111tS. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated'with this report are, noted below. Original Page 2 of 9 +-- .SumsUft lir4rir•oirutcouil7eclauilogies, Asc. ] , l. I9 (, , S:4 IJ LJ 33I0 ii'irr Sl. 1 EhYll3allr 0jl'n�irmiumonir.-n,tr•� Cis)alragaFalls,Oldo44223 Sample. Summary AmmfyoIcal t aboralwioe TEL (330) 253-8211 FWX. (330) 253-4489 w01l: 19110070 Wcbsile: bujj;1A is,ir.seuck.cU?u 12-Aot+-19 CLIENT: Georgia Pacific Inc. 27820 Project: Water Formaldehyde test Lab Snmplell) Clicai Sample 1D Tag No Datc collected Dnle Received \lalris 191 10070.001 O -002 11/1/2019 12:30:00 PM l 1/2/2019 10:00:00 AM Iron -Potable Water Page 3 of 9 f .•-� Summit Enviromneural 7echnologies. 6rc.u-1, ��[�r'_ 3310 ►insr. Analytical Report £PA11110r11AUMAL Tf,VJNJOI OMP ., IN!: Cit yrhoga Falls, Olrm ,1d213 (consolidated) Ilnalyrlerrl TEL. (330) 253-8211 PAX; (330) 253-4489 1V0I1: 19110370 II'ebsire: Date Reported: 11/12/2019 Lab ID: 19110070-001 Collection bate: 1 I/1/2019 12:30:00 I'M Client Sample ID OF-002 Matrix: NON-POTABIA" WATER Analysis Resull MDI, PQL Qual Units Dilution 13 itch Date Analyzed ALDEHYDES (EPA 8315A) Formaldehyde 0.0939 0.0164 0.222 3 Qnalifrers: R Attalyte detected in the associated Method 131:mk H Holding times for preparation or analysis exceeded MC V11l,e is below Minimum Compound Limit. ND Not Detected 111, Pennillimit EPA 8315 A Analyst: PGP rng/L 1 40428 11/4/2019 1 1:15:00 AM F Value ubovc gwintitation range M Manual Integration used to detenninc arcs response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limils Page 4 of 9 4 �f t + ITS Summil Firrirownenral 7ichnulogies, hw. 3J101Pfrr.S'r. QC SUMMARY REPORT c:VutolntDITAticC.n:lnlnrtFS.MC (:n3TJrogerFnlle,Oldv44223 won1911 OU70 Allalyfkal lrrbMnlorr¢e' 71u7.: (330) 253-8211 EAV. 030) 253-4489 If'rbsin: hfm�%•trruserreR.rnm 12-Nar,19 Client; Georgia Pacific Inc. 27820 Project: Water Fonnaldehgde test Rarehlll: 40428 Sample ID MBA0428 SampType: MBLK TeslCode: svov-8315 n Units: mg1L Prep Dale: 111312019 RunNo: 105643 Client ID: PBW Balch ID: 40428 TestNo: SWO316A SW8316A Analysis DaW 111412019 SegND: 2469916 Analyte Result PQL SPK valua SPK Rat Val %REC LavLimil H &LImil RPD Rel Val %RPD RPOUrnit Quol Forrnaldahyde ND 0.200 Sample ID LCS40428 SampType: LCS TeslCode: svoc-8315_n. Units: mg1L Prep Date: 111312019 RunNo: 105643 Client ID: LCSW Batch ID: 40428 TestNo: SWO315A SW8315A Analysis Date: 111412019 SegND: 2469917 Anatyle Result PQL SPK value SPK Raf Val %REC LmvLimit HghLimit RPD Rer Vol °%RPD RPDLimil Qual Formaldehyde 0.151 0.2D0 0.15D 0 101 70 130 .1 Sample ID LCSD-40428 SampType: LCS❑ TeslCode: svoc-8315 n Unila! mg1L Prep Date: 111312019 RunND: 105643 Client ID; LC8802 Balch ID; 40428 TestNo: MOMSWO316A Analysis DaW 111412019 SegND: 2459910 Analyle Result PQL SPK va!uo SPK Ref Val Y.REC Lc vLImIL HghLimlt RPD Ref Vol %RPD RPDLImll Qual Formaldehyde 0.148 0,200 0,150 0 98.6 70 130 DAM 2.07 20 J Qualifiers; 13 Analyse detected in the associated Method Blank E Value above quanthation range H Holding fines ror preperalion or anal! 1 Analyic detected below quanii{alien li mils .1 Manual rntegrafion used to determine area response M Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PI. Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detrciion Limit S Spit:e Recovery outside accepted reco Page 5 of 9 '? lCt^t Summit Euvirwmrerual7echnologies, h, PS`�� �_� Qualifiers and Acronyms 4 Lt�1 + 1 J 331011'in 4 Eit1'1ft0tJ1.1U'H1'AL IF-VIIN ni1f11F , SPtr., C'uy'ahognFalls, Ohio442i Wolf: 19110070 rt,l,�fyllctrf f.nbornturk': 77i1: (330) 253-8211 FAX, (330) 253.446 tPebsite: lu1V.11 va a'.seuek.ca I)atc: 1 1/12/2019 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualiticrs U 9'lte compound was analyzed for but was not detected, .1 'Elie reported value is greater than the Method Detection Limit but less than the Reporting Limit. IT "fhe (told tine for sample preparation and/or analysis was exceeded. 1) 'I'hc result is reported frown dilution. 1; 'I'hc result exceeded the linear range of the calibration or is estimated due to interference. 1�TC 'I'hc result is below the Minimum Compound Limit. t 'Elie result exceeds Il►c Regulatory Limit or Maximum Contamination Limit. n1 Manual integration was used to determine the area response. d Manual integration in which peak was deleted N 'I Ile result Is presumptive based on a Mass Spectral library search assuming a 1:1 response. 1' 'fho second calunua confirmation exceeded 25%differencc. C 'I'hc result has been confirmed by GC/MS, X 'file result teas not confirmed when CC/MS Analysis was performed. 1 AMB+ The analyle was detected in the nssocialed blank. G 'fhe ICl3 or CCI3 coninined reportable amounts ofanalyte. QC-1+ The CCV recovery failed low (-) or high(+), R/QDIt The Rl'D was outside of accepted recovery limits. QL-/+ 'file LCS or LCSD recovery failed low (-) or high (+). QL1Z The LCSILCSD Rill) was outside ofaccepted recovery limits. Q\I-1+ The MS or MST) recovery failed low (-) or high (+). QNIR The MS/MSD R111) was outside of accepted recovery limits, QV-/+ 'Elie ICV recovery flailed low (-) or high (4), S "fhe spike result was outside of accepted Recovery limits. z Deviation; A deviation front the metlrod was performed; Please refer to (lie Case Narrative for additional infomlalion Acronyms ND Not Detected Ill, Reporting Limit QC Quality Control tNIDL Method Detection Limit rM R Method Blank 1101) Level of Detection LCS Laboratory Control Sample LOQ Level of Quanlitation LCSD Laboratory Control Sample Duplicate I'QI, Practical Quanlitation limit QCS Quality Control Sample CRQL Contract Required Quamlatioaa Umil DUI' Duplicate PL Permit Limit MS Matrix Spike RegLA Regulatory Limit D1SD Matrix Spike Duplicate AICI, Maximum Contamination Limit RI'D Relative Percent Different MinCI, Mininxan Compound Limit ICV Initial Calibration Verification RA Reanalysis ICI3 Initinl Calibration 131ank RE Recxtmclion CCV Condoning Calibration Verification 'HC fcn1a1ivcly Idenlilicd Compound CC13 Continuing Calibration Blank ItT Retention Time RLC Reporting Limit Check CI., Calibration Factor DF Dilution Factor RF Response Factor 'I'his list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Original Page 6 of 9 { ,, �M6, fr Srunnrirlirrsiromnemn!'I'echnologies,Inc. /1CC1'CC�llrili 0ll h1'OgI'R)1] �� 11 l=:f �11i(�ilf [�d �J l�! 3310 11'in .SY. EN%'IIK)1It.1LrJfAL i :ctl\1Ulctc �r:,t;;! Cuyrrhogal�alls.Ohio4422.i 1�rl�liyfCS Re�Io�'f rlrralyfical Ujborntorlve• TF.l.: (330j 253-8211 FAX: (330) 253-4489 WOtt: 0110070 Websile: h1rn;//wu wscrfek.coul 12-Nor-19 Client: Georgia Pacific [tic. 27820 State: NW Project: Water Formaldehyde test Program Dame: NC_WW_SCM Sample 111 Alnlrix Test Nnme rinnlyte 81111rs 191 10070-001 A Non -Potable Water Aldehydes (EIIA 831 SA) Formnldchyde N NC WW SCM N Not Accredited Original ill Page 7 of 9 E-MRONAPENTA TECHtiOLOG1ES.:rrC. 321 n W:n Srrcer Cuycbce AM11e. bhao -'-223 800.278-0140 Analysis Request / Chain of Custody For SRmmi1 Environmem.;11 Technolocics_ Inc. use only C1:.-t;N.rn P%,i: :!f:i;i::. :n� �':rF `w 7:_•e� �^ ^ ; T s � •�,� ,_ r` � v v V C1�emiralsLLC Georgia-PacificWa:crFormaldeh Ydetes; 3i" �r.� r '•'-� +.t,•,, � w�ti I'3111etC>-C '�: •�' j � d fy.Y �r..,r jz, �'/j� R. 'Q �, L. :� s {y� ,y .• L� f��+ �! 1 'S�' +,�w> s � � , -t�1 �j j� ��.♦.•L ��� �.=�-n a �t. 1V'�Ri ll;•4J it ��lf�� �y f ?•a1 jr•-.^^F-w�.r.+•y�SS \I'C;1l :lt�lrc" ZyIi tt C: i:CGLr��C k1 i n4 k3''.p .? � �. ! h r• �.,..^ ti , . _.- rti�. _'- .:.�... �1.- w�_ 1-C,w7.ai.. 200 Arnpac Road 200 Arnpac Road 'Conway, NC 27820 Conway, NC 27820 n ,' w ;' o (252)-585.3819 I Tim Riddick ij; rt -ni a, s� ,:, .^: C:: c. t?•: it:il: i'C 1":: •. !'.'.\LT.:;+c• e (2521-595.1754 P552190585 V t., ' fr:••XC C.r.:;x;::4t:] \:I-:^c: _,�§ ,y Tim RiddicR � I Lj !• if Ohio VAP Samplesaa rr 'i.�ni fCdiKtti 1C:1ftt3C ,F '�-`� � �TSO• r t; U �y� _, !.:.'�:--..�ay.�;__.•�-m :.�•-.--.-- •�� _ �:.:_:� if:nl�cctcti� ',Ga11ec!ed v. ,�� '�r:,t"�1:, .� ���>u� zk "�� J A 12:30am --.Fi liiigni+lreil_Dr^ 'Jiir : "—Tiro^_ : rZecciti_i�i!'b:_ -_' tDatr: ''��7ime- Walter Lee 11/1/2014 1300 RuSh Requcsted: :.1u,: 4 C�:i;�e!,hv [.:m: t':r� •c: /I L i 1(1 3 (D co O t0 Fedex tracking no. - 409338969615 Ix Srrnoair nriromnewal7echnologies, hrc. 0 1T 3310 Win St, EIAIIRON61ENCAL 1['uluv110r+IF:, wC., Cuyahogah'alls, Ohia44223 Sample Log -in Check List AwflyfhSof f:oborwor'lvr TE'L, (330) 253-5211 h?I.Y: (330) 253-4489 lI ebsire: !s!(!r./hs a uasellek.cons Client Name: GEO-NC-27820-A Work Order Number: 19110070 RcptNo: 1 .�.rk •G,z.F Logged by: Jacqueline Rasile 111212019 10:00:00 AM l�r.ru •�ti1 Completed By: Jacquelino Rasile 111212019 12:37:06 PM / 1 Reviewed By: Holly Florea 1114/2019 7:56:17 AM Chain of Custody 1, Is Chain of Custody complete? 2, How was the sample delivered? Lop In 3. Coolers are present? 4. Shipping container/cooler in good condition? Custody seals intact on shipping container/cooler? No. Seal Date: 5, Was an attempt made to cool the samples? 6. Were all samples received at a temperature of >0" C to 6.0'C 7, Sample(s) in proper container(s)? $. Sufficient sample volume for indicated lesl(s)? 9, Are samples (except VOA and ONG) properly preserved? 10. Was preservative added to bottles? 11. Is the headspace In the VOA vials less Ihan 114 Inch or 6 mm? 112. Were any sample containers received broken? 13. Does paperwork match bottle labels? (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? 15. Is it clear what analyses were requested? 16. Were all holding limes able to be met? (If no, notify customer for authorization.) Special Handling (if applicable) 17. Was client notified of all discrepancies with this order? Yes I0 No Not Present ❑ FedEx Yes W No ❑ NA ❑ Yes o No ❑ Yes 0 No ❑ Not Present (] Signed By: Yes IV]No 0 NA ]J Yes W No ❑ NA ❑ Yes 96 No ❑ Yes No ❑ Yes IV] No ❑ Yes ❑ No Fvfj NA 0 Yes ❑ No ❑ No VOA Vials Yes ❑ No n Yes rrR No ❑ Yes W71 No ❑ Yes IiJ No ❑ Yes r] No ❑ Yes ❑ No ❑ NA W Person Notified: Date By Whom: Via: ❑ eMall ❑ Phone ❑ Fax ❑ In Person Regarding: T Client Instructions: 18. Additional remarks: Only reed one vial Cooler Information Cooler No I Temp °C I Condition I Seal Intact I Seal No I Seal Date I Signed By 4 I K2 1 Goodl Not Present I I} Page 9 of 9 Universal Laboratories 20 Research Drive, Hampton, VA 23666 TFLEPHONE: (757)865.4880 TOLL FAEC: (800)695.2162 PAX: (757)865.8014 REPORT OF ANALYSIS TO: Georgia Pacific Order ID: COC Name: Mr. Tim Riddick Receive Date: P.O. Box 368 Report Dale: Conway, NO 27820 1911258 Semi -Annual Stormwater 12/09/2019 12/18/2019 This report contains the analytical results for the indicated Project and Order. The results contained in this report relate only to the samples Identified in this Order. The analytical results meet all requirements of the 2009 TNI Standard, unless specifically stated or laboratory does not hold accreditation as seen in the Cert # column. This report shall not be reproduced except in full. pcc The data in this report has been reviewed and validated by:, tJ Signature Nuno 74( TEt1e RRpoR $$61 c 1911258 Page 1 of 3 Lob low } '.#�� }p$Q.QQ'� Collecllon Date: 12J0912019 02:40 jamiL ii• Matrix. AQUEOUS Sarni Volatile organics EPA 625.7 ResultUnit Analvsls Dat Analyst Qual. RL Cert# Holding Time Met Yes Yes/No 12118/201913:10 GH Sample Recelpt Temperature 2 C 1?J1812019 13:10 GH Cresols, Total ND ugA. 12/10/20191310 GH 6 460036 rn,p-Cresols ND ug1L 12/101201913:10 GH 5 460036 o•Crosol ND ugtL 12/18/201013:10 QI.1 5 460030 Phenol NO ugtL 121IM01913:10 GH 5 460036 surrogate 2,4,6- 54 % 121i012019 13:10 GH 9.5.123.4 Tribromophenol (R. Recovery) surrogate 2-Fluorophenol (% 33 % 12J18/2019 13:10 GH 2O.6-110.5 Recovory) surrogate Phenol-d5 (% 20 % 12/t9l2019 13:10 GH 9.5.110.5 Recovery) 1 Ouality Control Results PREP SVGA AQ 62513510 Batch: 121319-0091 Ltilts /a Toot PAramerer Result R4 Outil Accuracy Predolon Control control t21319.009•M0.01 SVOA 625 - AQ MB m,p,Cresols 0 ugrL 0 Phenol 0 u1[L 0 V surrogale 2•Fluorophenol (% Recovery) 38.5 % 20.6 - 110.5 surrogate Phenol-d5 (% Recovery) 23.3 % 0.5. 110.5 surrogate 2,4,6-Tdbromophenol (% Recovory) 0 % e 115. 193 4 121319-009.LCS•01 SVGA 625 - AQ LCS surrogate 2•Fluorophenol (% Recovery) 50 % 13 - 69 surrogate Phenol-d5 (% Recovery) 24 % 10.68 sullogats 2,4,6•T11b(omophenol (% Recovery) 70 % 42. 122 Phenol J% Recovory) 33 % 17 - 120 1911258-002 SVOA 625 - AO MS surrogate 2• Fluorophenol (% Recovery) 40 % 13.60 smogala Phenol•d5 (% Recovery) 20 % 10.50 surrogate 2,4,6-Trlbromophenol t% Recovory) 70 % 50 - l26 Phenol (% Recovery) 28 % 10 - 120 SVOA. 625 - AQ MSO surrogalo 2•Ftuorophon01 (% Recovery) 47 % 20.6 - l 10.5 sunogale Phenol-0 (% Recovery) 23 % 9.5. 110.5 surrogate2,4,6-Trlbromophonol1%Rccoveiy) 69% 9,5.1234 Phenol (% Recovery) 33.6 % 10 . 120 Phenol (RPD) ND % 0.64 m,p-Crosols (% 110covery) 51.3 % MS rU - M m,p-Cresols (RPD) ND % 0.30 0-cresol (% Rocovoiy) 0 % MS 70 • I:KI o-Cresol (RPD) ND % 0. 30 Rapod sorlal 1: 191125tr Page 2 of 3 4ualliler Codes * If present under the "Cart 4' column, indicates that the laboratory does not have 2009 TN accreditation In Virginia. Thaso analytos should not be reporled for Virginia Air, Water, or Waste Laws or ilia Salo Drinking Water Act to meet their roquiroments. B Analyto was found in the method blank D RPD outsido acceptable limits EPL Exceeds Permit Limit. This Is a qualifier to donote that the result exceeds the permit Ilmll of the samplo location. H Holding time oxceeaded is Internal standard outside acceptable limits J Result above calibration curve - results are approximala MI Matrixlnloronce Ms Matrix spike recovery outside acceptable Ilmlts ND No anatyte detected at or above the RL (Reporting 'Limn) listed NR No Results available, analyse not in Instrument calibration QC Method QC criteria not met; GGA or LCS Failure R SM 5210B•201 17.b. Test replicales show more than 30%difference between high and low values S Surrogate outside acceptable limits V ICViCCV1FCV pulside acceptable limits Glossary of Terms 460036 if present under the'Cert d" Cotumn, Indicalas Thal the laboratory holds accreditation under the 2009 TNI Standard in Virginia. Calibration (initial, Continuing, or Final) A standard analyzed at different times to verify that the initial calibration curve Is still valid. Verficetion Exceeds Res ull Exceeds Benchmark concentration listed in the General Permit, Benchmark Coneaniralions aro primarily used to Benchmark determine the overall effeclivenss of ilia Sturniwater pollution pievonllon plan. Excedonco of Barschamrk co-tcenlrallons duos Concentration NOT constitute a violation of this permit and does NOT Indicate that violation of a water quality standard has occ tired. Holding Time The maximum time thal samples may be hold prior to analysis and still be considered valid or not compromised. Internal Standard A known amount of standard added to a lest portion of a sample as a reference for evaluating and controRing the precision and bias of the applied analytical method. LCS (Laboratory Control Sample) A sample matrix, free from the anafyles of interest, spiked wills verlfled known amounts of analytos or a material containing knrn-m and verified amounts of analylos. M DL Method Detection Limltis Is an estimate of the minimum amount of a substance that an analytical' prncess can rellably detect Method Blank A sample of a matrix simllar tolhe batch associated samples (when available) that Is free from the analytos of interest and is processed simutatanously with and under the same conditions as samples. MSIMSD (Matrix Spike or Matrix Spike Duplicate) A sample prepared by adding a known mass of target anafyta to a specified amount of matrix sample for which an independent estimate of target analytos conceniratlon Is available. Malflx Spikes are used, for example, to determine the eflect of the matrix on a method's recovery efficiency. RL (Reporting Limit) The minimum levels, concentrations, or quantities of a target analyte that can be reported within a specified degree of confidence. Generally, this number Is equal to or just abovo the lowest calibration standard run with the analytical batch. RPD (Relative Percent Difference) The difference between a sot of duplicates or sample spike duplicates. Surrogate A substance with propertios that mimic the analylo of interest. It Is unlikely to be found in onuironrnonial samples and Is added to them for quality control purpos as In Org anics. Reportsed8r.: 191r25a Pogo 3 of 3 Georgia Pacific P.O. Box 368 Conway,NC,27820 Contact tun RiddiCk252- 585-1232. (c)252.395- 1625.TARIOOIC O GAPAC.corn Universa9 Laboratories CHAIN OF CUSTODY ID: 1911258 Semi -Annual Stormwater 20 Research OrKe Hampton. VA=669 1-800-695-2162 http:t/www.universailaboratories.net Page 1 0l 1 Sample Name Ui_Santple-, 113 - Matrix Sample DateTime/lnitials SottlelD - Sample Container _ Preservation Testing OF-002 1911258.002 AQUEOUS AQUEOUS 12. .9.19 Cz t fd pv'/s ff =r 1/Glass <5°C waWle. 625 002H 1/Glass <M 40TES: CoolerTemp— —Z _,__C 3henol int check,. Cr1 int check BOD int check HH3 irft cheek TRANSFER SIGNATURE DATEITIME TRANSFER SIGNATURE DATEITIME Relinquished by j2'9•l4 i(!q Received by Z Gl I Relinquished by -IC171,�L5 Received by Relinquished by Received by 7-4 Relinquished by Received by STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT Permit Number. NC NCS000251 or Certificate of Coverage Number: NCG FACILITY NAME Georgia-Pacific Chemicals LLC PERSON COLLECTING SAMPLE(S) Tim Riddick CERTIFIED LARORATORY(S Universal Laboratories Labll 543 Summit Environmental LabN 631 Georgia-Pacific Chemicals LLC Lab# 5464 Part A: Specific Monitoring Requirements SAMPLES COLLECTED DURING CALENDAR YEAR: 2019 (This monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling; results from the laboratory.) COUNTY Northampton P110IN, E , . 52 _85-123 (SIGNATURE OPI, PERMITTEE OR DESIGNEE) By this signature, 1 certify that this report is accurate complete t0 the best of my knowledge Outfall No. Date Sample Collected 50050 00556 00310 00340 00600 00665 00400 Total Flow Oil and Crease BOD5 COD Total Nitrogen Total Phosphorus PH me/ddlyr MG m /I mg/1 m /I m 1l m !I S.U. 001 11/01/19 0.040 <5 5 46.9 1.40 0.45 7.2 002 11/01/19 0.188 <5 3 28.5 2.64 0.12 8.9 003 II101119 0.021 <5 8 56.2 1.69 0.32 7.1 004 11/01/19 0.029 <5 3 23.8 0.86 0.12 6.9 002 12/09/19 0.063 Wit n/a nIn n/a n/a 8.1 Does this facility perform Vehicle Maintenance Activities using; more than 55 gallons of new motor oil per month? _%_yes __-_no (If yes, complete Part B) Part B: Vehicle Maintenance Activity Monitoring Requirements Outran No. Date Sample Collected 50050 00556 00530 00400 .total Flow Oil and Grease Total Suspended Solids pH New Motor Oil Usage g mo/dd/ r MG m /l mg/1 S.U. gallmo 002 11/01/19 0.188 <5 11.0 8.9 100 002 12/09/19 0.063 n/a n/a 8.1 i0o Form SWU-246-051100 Page I of 3 STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT Permit Number: NC NCS000251 or Certificate of Coverage Number: NCG FACILITY NAiv1E Georgia-Pacific Chemicals LLC PERSON COLLECTING SAMPLE(S) Tim Riddick CERTIFIED LABORATORY(S Universal Laboratories Lab# 543 Summit Environmental Lab# 631 Georgia-Pacific Chemicals LLC Lab# 5464 Part A: Specific i<Ionitoring Requirements SAMPLES COLLECTED DURING CALENDAR YEAR: 2019 (This monitoring report shall be received by the Division no later than 30 days fUUFT] the date the facility receives the sampling results from the laboratory.) COUNTY Northampton PHONE (25 585-t2321� �7LE-�L-11 (SIGNATURE OF PERiIIITTEE OR DESIGNEE) By this signature, I certify that this report is accurate complete t0 the best of my knowledge Date 50050 Outfall No. Sample Collected Total hiow -cresol a -cresol m-cresol Cresol Phenol Formaldehyde NPDES Flow (a� Wier mo/ddlyr MG mg/1 m /l mg/1 m /l m /I m /I MG❑ 002 11/01/19 0.188 n/a n/a n/a n/a ills 0.0939 n/a 002 12/09/19 0.063 <0.005 <0.005 <0.005 <0.005 <0.005 nla n/a I,orm SWU-246-051100 Page 2 of 3 STOPUM EVENT CIIARACTERISTICS: i`lail Original and one copy to: Division of Water Quality Date: 11/01/2019 Attn: Central Files Total Event Precipitation (inches): 1.2 1617 Mail Service Center Event Duration (hours): 1 . 5 (only if applicable — see permit.) Raleigh, North Carolina 27699-1617 (if more than one storm event was sampled) Date Total Event Precipitation (inches): Event Duration (hours): (only if applicable-- see permit.) "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." f/Zo 1 (Signature of Perm ttee) (Date) Form SWU-247, last revised 21212012 Page 3 of 3 Input total inches during storm event Input storm event duration Calculated rainfall intensity Outfall 001 Stormwater Flow Estimate Drainage Area Runoff (acres) Coefficient (c) 0.49 0.2 1.26 0.9 1.75 0.7 Calculated Fiow 0.99 cfs 39 814 Gallons mmPG 0.044 Q = ciA, where Fall Event - 2019 11/01/19 1.2 inches 90 minutes 0.800 inlhr Q = Flow (cfs) c = runoff coefficient i = rainfall intensity (inlhr) A = area (acres) Outfall 002 Stormwater Flow Estimate Drainage Area Runoff (acres) Coefficient (c) 6.48 0.9 6.48 . 0.9 Calculated Flow 4.67 cfs 188 453 Gallons 0.188 Outfall 003 Stormwater Flow Estimate Drainage Area Runoff (acres) Coefficient (c) 1.30 0.2 0.45 0.9 1.8 0.38 Calculated Flow 0.53 cfs jjj21489 Gallons 0.021 Outfall 004 Stormwater Flow Estimate ❑rainage Area Runoff (acres) Coefficient (c) 1.01 0.9 1.0 0.90 Calculated Flow 0.73 cfs 29 373 Gallons STOR]VI EVENT CHARACTERISTICS: Date: 12/09/2019 Total Event Precipitation (inches): 0.4 Event Duration (hours): 7.0 (only if applicable — see permit.) (if more than one storm event was sampled) Date Total Event Precipitation (inches): Event Duration (hours): (only if applicable —see permit.) Mail Original and one copy to: Division of Water Quality Attn: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 "1 certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." KA 1 / Z ° / z a (Signature of Permittee) (Date) Form 5WU-247, last revised 21212012 Page 3 of 3 Input total inches during storm event Input storm event duration Calculated rainfall intensity Outfall 001 Stormwater Flow Estimate Drainage Area Runoff (acres) Coefficient (c) 0.49 0.2 1.26 0.9 1.75 0.7 Calculated Flow 0.07 cfs O3 270 Gallons mmPG Q = ciA, where Fall Event - 2019 12/09/19 0.4 linches 420 minutes 0.057 inlhr Q = Flow (cfs) c = runoff coefficient i = rainfall intensity (inlhr) A = area (acres) Outfall 002 Stormwater Flow Estimate Drainage Area Runoff (acres) Coefficient (c) 6.48 0.9 6.48 0.9 Calculated Flow 0.33 cfs tit 818 Gallons 0.063 Outfall 003 Stormwater Flow Estimate Drainage Area Runoff (acres) Coefficient (c) 1.30 0.2 0.45 0.9 1.8 0.38 Calculated Flow 0.04 cfs 7163 Gallons 0.007 Outfall ON Stormwater Flow Estimate Drainage Area Runoff (acres) Coefficient (c) 1.01 0.9 1.0 0.90 Calculated Flow 0.05 cfs '9'791 Gallons Universal Laboratories 20 Research Drive Hampton, VA 23666 Phone; 1-000-695-2162 Fax: 757-865-t30'14 Client Report For: Georgia Pacific Attention. Mr. Tim Riddlck Client Address: P.O. Sox 368 Conway, NC 27820 Project: Semi -Annual Stormwater Order Number. 1910289 Report Date: 12/03/2019 Lab Recelpt Date: 11/0112019 Comment: This report contains the analytical results for the indicated Project and Order. The results contained in this report relate only to the samples identified in this Order. The analytical results meet all requirements of the 2009 TNI Standard, unless specifically stated or laboratory does not hold accreditation as seen in the Cert # column. This report shall not be reproduced except in full. f The data In this report has been reviewed and validated by: 7 Signature .._ . / Name Title Roporisadeln: +nin.)ao Page 1 of 6 RepotlrWe: (kiginal Universal Laboratories r lam/ .. ^T: �i• Y.i' -�.- '[ i - - 7 r T •-ti=.^f�a r""' c iCI�B.L{GeorglaiF',a_ciftc'+ �` .{Et}r'��, ,�' f M� $; Y,rCifent'Samnld,ID: O_F7009D';L << >r; {`31 t !�.rrr r Id,19,10289 0411p ' '� >> 't 'rx,r•i;�,�l,v; ��, 'a} ir,:.l',, o D t1,110112079,01:10 •�1._'..r �+, .�--"J 1 t. L 11` i 11 -:t, 1pe1r�11t'1ib�r �3 �,rf;- 1 �41j { t ;:on Y l�r�, ssr;T'...111 ; ! ) 1.. 'inc �`d atr' :tAQIJf Ol15�i,,` f' ; c i, .cu va»w•••ai .r k� , ._ 'J �L:4.1r+.i.ir..x�t�l:`''h. r!- '. £-�i _.. n} Ya�ranui�T-2r►u:. tsF .ijr`�! ..AiK' Analyses 6lochemlcal Oxygen Demand (BOD) 5 Day 5M 5210 B (2011) Holding Time Met Sample Recelpl Temperature Biochemical Oxygen Demand Chemical Oxygen Demand Sample Preservation pH Holding Time Met Sample Recelpt Temperature Chemical Oxygen Demand Nitrogen, rota! Sample Preservation pH Holding Time Met Sample Receipt Temperature Nitrogen, Total Off and Grease (SGT--HEM) Sample Preservation pH Holding Time Met Sample Receipt Temperature Petroleum Oil Hydrocarbons (SGT- HEM) Phosphorus, Total Sample Preservation pH Holding Time Met Sample Receipt Temperature Phosphorus, Total Test Result Unit RL Analysis Date Anaivsis ByQualifie Cart # Yes YeslNo 11/01/2019 15:49 LS 1 C 111011201915:49 LS 5 mg1L 2 11/011201915:49 LS 460036 HACH 6000 Test Result unit RL Analysis Date Analvsia By Quallfler Cert # 1 pH Units 111051201913:06 LS Yes YeslNo 1N051201913:08 LS 1 C 111051201913:06 LS 46.9 mg1L 20 111051201913:06 LS 460036 EPA 351.2/ EPA 353.2 Test Result Unit 1 pH Units Yes YeslNo 1 C 1.40 mg t. EPA 1664A Test Result Unit 2 pH Units Yes YeslNo 1 C ND mg& EPA 365.1 Test Result Unit 1 pH Units Yes YeslNo 1 C 0.45 mgk RL Analysis Date Analysis By ualifler Cert # ___ 11/051201915:07 AS 11/0512019 15:07 AS 111051201915:07 AS 0.2 111051201915:07 AS RL Analysis Date Analysis By Quallfler Cert # 111131201912:37 LS 111131201912:37 LS W1312019 112:37 LS 5 11113120€9 i2:37 LS 460036 RL 0.02 Analysis Date Analysis By Quallfier Cert 1110512019 14:59 AS. 1110512019 14:69 AS. 111051201914:59 AS. 111051201914:69 AS. 460036 Repal Sodal a: 10iMA4 page 2 of 6 RapeA T�pw Wgh31 Universal Laboratories . nr..?'r".;�Im•r cis-cr,•�-�+c.- -c,-. -r� ,t.-j. • - . ; tr^- �- ice-, rxr�..�,�.y, .,r .r �; �.,.--•-- x t---F -'r- ,st•, �, i . �� • Oeor is Iilc•:� t�� t, � .�, �� ��.� ?r'� ,.Client. 9EaP c q Rti ,� ;. 9 ; Ci;erlt Sampla Fb'TOR, r.��. li ni�rii lDCotla tionate y,11I0i12019 s a +' �I: 1 , -A � !Si 1 - ��,A, c.� .SL r�, rn r f 1� t ti. AQUEOUS � t � 7 .., '4.`�. Matr}x �rPe t r�J::.:i,. `.:5. _ `.`."... z'�.V_. `E t' •`i _1 rs:a, y r14n,' ._ - a J Analyses Biochemical Oxygen Demand (BOD) 5 Day SM 5210 B (2011) Holding Time Met Sample Receipt Temperature Blochemlcal Oxygen Demand Chemical Oxygen Demand Sample Preservation pH Holding Timo Mot Sample Recelpt Temperature Chemical Oxygen Demand Nitrogen, Total Sample Preservation pH Holding Time Met Sample Receipt Temperature Nitrogen, Total Oil and Grease (SOT -HEM) Sample Presemlion pH Fielding Time Mel Sample Receipt Temperature Petroleum Olt Hydrocarbons (SGT- HEM) Phosphorus, Total Sample Preservation pH Holding Time Met Sample Receipt Temperature Phosphonrs, Total Solids, Total Suspended Holding Time Met Sample Receipt Temperature Solids, Total Suspended Test Result Unit Yes Yes1N0 1 C 3 mglL MACH 8000 Test Result Unit 1 pH Units Yes YeslNo 1 C 28.5 mg1L EPA 351.21 EPA 353.2 Test Result Unit 1 pH Units Yes Yes/No 1 C 2.64 mg.1L EPA 1664A Test Result Unit 1 pH Units Yes Yes/No 1 C ND mg/L EPA 365.1 Test Result Unit 1 pH Units Yes Yes/No 1 C 0.12 mg/L SM 2540D (2011) Test Result Unit Yes Yes1No i C 11.0 mg1L RL Analysis Date Analysis BM Quallfler Cert # 11101/201915:49 LS 111011201916:49 LS 2 111011201916:49 L5 460036 RL Analysis Date Analysis By ualifier Cert 111051201913:06 LS 1110512019 13:06 LS 11105/201913:06 LS 20 111051201913:05 LS 460036 RL Analysis Date Analysis By Quallfier Cert # 111051201915:07 AS 11105/2019 i 5:07 AS 111051201915:07 AS 0.2 11105/201915:07 AS ' RL Analysis Date Analysis By Quallifier Cert # 11113/201912:37 LS 11 It 3/2019 12:37 LS 11113/201912:37 LS 5 111431201912:37 LS 460036 RL Analysis Date Analysis Bx Qualifier Cert 111051201914:59 AS, 111051201914:59 AS, 111051201914:50 AS. 0,02 111051201914:59 AS. 460036 Analysis Date Analysis B Qualliffe Cart # 11/07/2019 20:09 EK 11/07/2019 20:09 EK 1 11/07/2019 20:09 EK 460036 Rgpon sous n: 1 OWDAD Page 3 of 6 ROPOrt Typal Uipinal universal Laboratories '�1..^' ♦. w. s"�i, F.iL T':' �Yf'"'r"77i. r"hCe".^ 'd. r `7', ��� iClEer�t; Gt o►gla Paclflc d �, , , CIIerIk alnnle-Ib:IOF 003 3�, ; �abf {d• ,1910289 003 1 1a"1I01126i - 0`45S , 0- ¢ i ,.i Y�" � cr 4r �o. rr'i r - s1� 'sr R a 'AQUEous. sC1G Analyses Biochemical Oxygen Demand (130D) 5 Day 5M 5210 B (2011) Holding Time Met Sample Receipt Temperature Biochemical Oxygen Demand Chemical Oxygen Demand Sample Preservation pH Holding Time Met Sample Receipt Temperature Chemical Oxygen Demarod Nitrogen, Total Sample Preservation pH Holding Time Met Sample Receipt Temperature Nitrogen, Total Oil and Grease (SGT-HEM) Sample Preservation pH Holding Time Met Sample Receipt Temperature Petroleum Oil Hydrocarbons {SGT- HBM) Phosphorus, Total Sample Preservation pH Holding Time Met Sample Receipl Temperature Phosphorus, Total rt'est Result A119 Yes Yes1No 1 C 6 mglL HACH 8000 Test Result Unit 1 pH Units Yes Yes/Na 1 C 56,2 mg1L EPA 351.21 EPA 353.2 Test Result Uni 1 pH Units Yes Yes1No 1 C 1.69 mgiL EPA 1664A Test Result unit 1 pH Units Yes Yes1No 1 C NO mg1L EPA 365.1 Test Result Unit 1 pH Units Yes Yes/No 1 C 0.32 mg1L RL Apalysis Date Analysls BY Quallfler Cert # 111011201915:49 LS 11101/2019 15:49 LS 2 111011201915:49 LS 460036 HL Analysis Date Analysis By Qualifier Cert # 11105120101106 LS 11/05/2019 13:06 LS 111051201913:06 LS 20 11/051201913:06 LS 460036 RL Analysis Date Analysls By Quallifi Cori 11/0512019 15:07 AS 11/05/2019 15:07 AS 1110512019 15:07 AS 0.2 111051201915:07 AS RL Anal s-s Rate Analysis Ily QuAliflerCert 11113/2019 12:37 LS 11/131201912;37 LS 11/131201912:37 LS 5 111131201912:37 LS 460030 RL 0.02 Analysis Date Analysis By Qualliflo Cert # 11/051201914:59 AS. 111051201914:59 AS, 11/051201914:59 AS. 11105/201914:59 AS, 460036 ReporiSadslft IOMIOo Page 4 of 6 HeportT)ve: Odglnal Universal Laboratories -,', rClienfi Georg aiai ',Pacific,T•e T'-l'z ' :, ,;i' s lCllen lamp s�.. + r•rrr..,Lr-"ln�i it , 1 rr irk r ��r. J i..... �' 19 r�tN...�y._T,r-•�"'I'�;nk"Y' „nr.t' �Y►1i rh icy) bi° .,r�- r 1'i. 910289 W41r,'{ Co lee o `- fa� � 1/011201901 3 ■ yL i% { �, tt', sk t' In c/SY. ti'Yr� rt y.I ttl! ! I'!r ,1.� , r4e �1. S1 `Pe it• b � ,', �r .,� � , '•r, 5 ,� .,F �y � • � atrlx�AQUEOUS � , ., ,�, , ,, . ....,a.oror.:ao.r..r!... .... _.. .. .. .,..... ,,.. , _.,.r...._.{._.r.1t...�J.��ar:�.�i+n't'}Irr•,`: _ ?•_ .�;n..�. _. _. :!it.sla•. Analyses BlochemlCal Oxygen Demand (BOD) 5 Day SM 5210 B (2011) Holding Time Met Sample Receipt Temperature Blochemlcal Oxygen Demand Chemical Oxygen Demand Sample Preservation pH Holding Time Mot Sample Receipt Temperature Chemical Oxygen Demand Nitrogen, Total Sample Preservation pH Holding Time Met Sample Receipt Temperature Nitrogen, Total Oil and Grease (SGT-HEM) Sample Preservation pH Holding Time Met Sample Receipt Temperature Petroleum Oil Hydrocarbons (SGT- HEM) Phosphorus, Total Sample Preservation pH Holding Time Met Sample Receipt Temperature Phosphorus, Total Teo Rywit Unit Yes YeslNo 1 C 3 mglL HACH 8000 Test Result Unit 1 pH Units Yes YesfNo 1 C 23.8 mg1L EPA 351.21 EPA 353.2 Test Result Unit 1 pH Units Yes YesfNo 1 C 0.86 mglL EPA 1664A Test Result unit 1 pH Units Yes YesfNo 1 C ND mgfL EPA W5.1 Test Result unit 1 pH Units Yes YesINO 1 C 0.12 mg1L RL Analysis Date Analvsis� ualifier Cert 11101/201915:49 LS 11/0112019 15:49 LS 2 111011201915:49 LS 46C036 RL Analysis Date Analysis By guallifier Cert # 111051201913:06 LS 111051201913:06 LS 111051201913:06 LS 20 111051201913:06 LS 460036 RL Analysis Date Analvals By. Qualifie Cert 1110512019 15:07 AS 111051201916:07 AS 111051201915:07 AS 0.2 111051201915:07 AS ' RL Analysis Date Analysts B-y Qualiffe Cert At 11/131201912:37 US 11/13/2019 12:37 LS 11113/2019 12:37 LS 5 11/131201912:37 LS 460036 Rh Analysis Date Analysis 8 Qualifier Cert # 11105/201914:59 AS. 11105120i9109 AS. 111051201914;59 AS, 0.02 11 f0512019 14:59 AS. 460036 naponsesialrt. ,o+moo Page 5 of 6 ReponTypo: Original Glossary of Terms and Abbreviattons ND No analyte detected al or above lie RL (Reporting Lfmit) listed No Results available, analyte not in instrument calibration (Reporting Limit) The minimum levels, concentrations, or quantities of a target analyze that can be reported within a specified — NR RL degree of confidence, Generally, this number Is equal to or just above tie lowest calibration standard run with the analytical batch. ! B� Analyte was found in the method blank D RPD outside acceptable limits H M Holding time excoceded Internal standard outside acceptable limits ' IS ?,i e_ Result above calibration curve- results are approximate L LCS Outside acceptable limits Matrixinterence Matrix spike recovery outside acceptable limits ;MIM M5 QC Method QC criteria not met Surrogate outside acceptable limits i S V ICVICCVIFCV outside acceptable limits LCS (Laboratory Control Sample) A sample matrix, free from the analyles of Interest, spiked with verified known amounts of analyles or a material containing known and verified amounts of analytes, Method Detection;_Imilis is an estimate of the minimum amount of a substance that an analytical process can MDL reliably detect ' RPD _ (Relative Percent Difference) The difference batween a set of duplicates or sample spike duplicates. M SIMSD (Matrix Spike or Matrix Spike ❑uplicate) A sample prepared by adding a known mass of target analyto to a specified amount of u malr€x sample for whtGh an Independent estimate of target analytes concentration Is avaliab'.e. Matrix Spikes are used, for example, to determine the effect of the matrix on a method's recovery efflctency. `Calibration (Initial, Continuing, or Final) A standard analyzed at different times to verify (hat the Initial calibration curve is still valid, _ •Vertication Holding Time The maximum time that samples may be held prior to analysis and still be considered valld or not compromised. `Internal Standard A known amount of standard added to a test portion of a sample as a reference for evaluating and controlling the precision end hlas of the applied analytical method, 'Method Blank A sample of a matrix similar to the batch associated samples (when available) that is free from the analyzes of Interest and is _ processed simulatanouslywith and under the same conditions as samples, A substance with properties that mimic the analyze of interest. It is unlikely to be found In environmental samples and Is added to Surrogate them for quality control purposes in Organics, Exceeds Permit Limit. This Is a qualifier to denote that (he result exceeds the permit limit of the sample location. ^� EPL Exceeds Result Exceeds Benchmark ooncentral€on listed in the General Permit, Benchmark Concentrations are primarily used to i Benchmark determine the overall effectivenss of the Stormwaterpoltution prevention plan. Extedence of Benchamrk cancentratlons does (Concentration NOT conslittle a violation of this permit and does NOT indicate that violation of a water quality standard has occured. * — — 1I present under the "Cart #" Column, indicates that the laboratory does not have 2009 TNI accreditation in Virginia. These analyzes should not bo reported for Virginia Air, Water, or Waste Laws or the Sale Drinking Water Act to meet their requirements. 460036 If present under (he "Geri ft' Column. Indicates that the laboratory holds accreditation under the 2000 TN Standard in Virginia, SM 5210E-20t 1 TI.). Test replicates show more than 30% difference between high and tow vafuesnv j3 Report Soriel k 101MAe page 6 of 6 Roporl Typo; Original Georgia Pacific P.O. Box 368 Corrvvay,NC,27820 Ccntact:Tim Ridciick,252- 585-1232, (c)252-395- 1625,TARIDDIC@ GAPAC.Corn Uniyersag Laboratories 20Research Drive CHAIN OF CUSTODY Hampton, VA236% 'I-800-695-2162 1 D: 1910289 httpJ/www.universallaboratodes.net Semi -Annual Stairmwrater Page 1 of 2 Sample'.Nance' UL_Sarnple AID. Matrix..-: Sample DatelTiinellnitials...= _ Bottlell) :Sample., . ;!Container Preservation Testing OF-001 i 1910289.001 AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS \�� Q 4 \0 0.'^ ` V 001A 250/Glass H2SO41<6°C r waste, TRANS, SOD, COD, TN, OGN, T.PHOS i 001B SOOIHOPE H2SO4k6'C 001C 1/HOPE c6°C 001D 1/Glass H2SO4!<6°C 001E 1/Glass H2SO4/<6"C ,OF-002 i j 19102S9.002 AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS 2'0 �Q O 0. ,r't U 002A 250fGlass H2SO41<6°C waste, SOD, COD, TN, OGN, T.PHOS, TSS, 625 002B 5001HDPE H2SO4/<6°C O02C 1/HDPE c6'C 002D 1/Glass H2SO4/<6'C 002E 11G1ass H2SO4/<6`C 002F 11Glass <61C 002G 21HDPE <SIC 002H 1161ass <6'C OF-003 1910289-W3 AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS , p / p Vvl ��^ ' 7 003A 250/Glass H2SO4t<6•C :ql< waste, SOD, COD. TN, OGN, T.PHOS 003E 500/HDPE H2SO4/c6'C 003C 1/HDPE <6`C 003D 1lGlass H2SO41<6'C 003E 1/Glass H2SO4/-c6'C JOF-004 i 1910289-004 AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS ji �- �a ct b \30 a� 004A 2501GIass H2SO4/a6'C waste, BOD, COD, TN, OGN, PHDS � t i 004E 50on-0PE H2SO4/-4T-C 004C 1/HDPE <61C 004D 1/Glass H2SO4/<6°C 004E 1/Glass H2SO41<6 C NOTES: CoolerTernp C Phenol int check CN int check SOD int check _ NH3 int check TRANSFER SIGNATURE DATEMME TRANSFER SIGNATURE DATEITIME Georgia pacific P.O. Box 368 Conway, NC,27820 Comacf:Tim Riddick,252-585-1232, (c)252-395- 1625,TA R i o e f C'9GA PA C, can Universa6 Laboratories CHAIN OF CUSTODY I D : 1910289 Semi -Annual Storer water 20 Research Drive Hampton, VA 23666 1-800-695-2162 http:/Iwww.universallaboratodes.net Page 2 of 2 Relinquished by W0.1�t; Le.L deceived by Relinquished by Received by Relinquished by Received by Relinquished by Received by 3 '"ail jj r E I Ina Summit Environs+e+rml 7cclmologies. l+rc. PMl 31r _,�1 �41/l� f 3�v/LI3310Win A tP;4litr�111.1rt17IH-1L1710201nmrF-"lu-- Cujohogrr Fails, Ohio,14223 AI.rllyficaf TV.: (330) 253-8211 FAA, (330) 253-4489 li'cbsuc: hrru://unrrsarlck.co+d November 12, 2019 Tim Riddick Georgia Pacific Inc, 27820 200 Ampac Rd.P.O. Box 368 Conway, NC 27820 TEL: (252) 585-1232 FAX: (252) 585-1754 RE: Water Foi-maldehyde test Deal -Tim Riddick; Order No.: 19110070 Summit Environmental Technologies, Inc. received 1 sample(s) on 11/2/2019 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative, Quality control data is within laboratory defined or method specified acceptance [it -nits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, (Vue-A-67&1 Holly Florea Project Malrager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735. California 07256CA, Colorado, Connecticut M-0108, DClaware, Florida NEiLAC U97688, Gcorgin E87688,1daho OH00923, Illinois 200061. lnditnw C,OH• 13, Kansas E-103-17, Kentucky (Undergomid Slnrage Tank) 3, Kmuucky 90146, Louisinun 04061, Mlarylnud 339, hlimmsota 409711, New Hampshire 2996, New Jersey OH006, New York 11777, Nm16 Carolina 39705 and 631, North Dakota K-201, 01tio DW, 011io VAP C1.0052, Oklnhairm 9940, Oregon 0142O0001, Pennsylvania 010, Rhode Island LA000317, Sau111 Cnrolinn 92016001, Texas T] 04704466.11-5, U1111 011009232011-1. Virginia VELAP 9456, Washington C891 Page 1 of 9 PME�;t4�1{Jr1r.4PrlrnL 1CC'.�ltdoLOn�F$, sr:r. rtrr��lurlcn7! at�nrGlurles CLIENT: Geargia Pacific Inc. 27820 Project: Water Formaldehyde test Sroumil Eimirorrmculal'lcchnologics, Inc. 3310 i3 ra Sr. CiUvhoga falls, Ohio 44223 TEL: (330) 253.8211 FAX, (330) 253-4159 !i'cLsirc: Irrrr�://,�:�tirselrek. corn Case Narrative Wolf: 19110070 Date: 11112/2019 This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental 'Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc, and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc, or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated `with this report are noted below. Original Page 2 of 9 r Suawrit Enriroinueutal Teclu+ologles, Inc. r � u 3310Will St. DWI1lrJt1 AUNTAL TGCHN01 OGIFR, INr, Cuyahoga Falls, Ohio 4,1213 Allafltdlcnl I fltlarafurfn�' TEL: (330) 253-8211 FAX: (330) 253-4489 fl ebsite: lrrtlt://iru rrsctlek.cam CLIENT: Georgia Pacific Inc. 27820 Project: Water Formaldehyde test Sample Summary WWI: 19110070 12-Nor-19 Lab SnmpleIl) Client Sample It) Tng No Dnic Collected Date Rcccivcd 1IatrN 19110070-0O1 OF-002 11/1/2019 12:30:00 PM l 1/2/2019 10:00:00 AM Non-1101able Water Page 3 of 9 summil Emironllrcrunl Technologies. 11rc. ;� r 1�Analytical Report .� i...'� ��? 4i.j:?�.J 1.1,�'� !' J f,� t.! �:� L:l � 3310 fli,r Sr. 1?NV111UNI1[:Nir1L 1fC1sN01 oGir-S.,Ir:r Ciryahoga Falls, 01do 44223 (consolidated) P11.11yr"On/ t jbor0IU19,v 7I;L; (330) 253-8211 FAX: (330) 253-4489 WOII: 19110070 ll'ebsite: Ir1!pWirumtseack.c°Nr Date lkeporled: 11112/2019 Lab Ill: 19110070-001 Collection pate: 1 1/1/2019 12:30:00 I'M Client Sample ID Or-002 Matrix: NON -POTABLE WATER Analysis Result MDI, PQL Qual Units Dilution Batch Datc Analyzed ALDEHYDES (EPA 83115A) Fonnaldchyde 0.0939 0.0164 0.222 1 Qualifiers: B Analyle detecled in the associated Method Blank H Holding times for preparaliort of analysis cxccedcd MC Valuo is below Minimlan Compound Limil. ND Not Detecled PL Permit Limit EPA 8315 A Analyst: PGP mg/L 1 40429 1 11-012019 1 1:15'00 AM E Valuc above gtranlitation range M Manual Inlegration used to detenninc area response N Tentatively identified compounds P Second cOAattn confirmation exceeds R Rt'D outside accepled recovery lintils Page 4 of 9 uouraiu-i Sinwnir frn•;ru n,+crrr l T chnoingie.k, Ne, 33100,111ST. QC SUMMARY REPORT Ct:Y111qt161Uri rA1-7Gmisnt�.^.I�S.e;r; Cayedrog(i Falls, Ohio 44223 LVOB: 191100T0 A ualprlcal LAGOrPfnrlas 71:1.: (330) 25.14211 !•'.1.Y: (330) 253-4489 F) e8silr: hrrp;! iru}rsrrlrk, rmrr 12-A'0st19 Client: Georgia Pacific hie. 27820 ProJeel: Water Formaldehyde test Hilchil): 40428 Sample iD NiB40428 SampType: h1BLK TeslCods: svoc-8311b_n Units: ang1L Prep Data: 111312019 RunND, 105643 Client ID: PBW Belch 10: 40428 TesiNo: SWB315A SW0315A Analysis Date: 111412019 SegNo: 2459916 Analyle Result PQL SPK vaius SPK Ret Val IV REC LrnaLimit HlghLlmit RPD F2ef Val %RPD RPDLImit Qual Formaldehyde ND 0.2D0 Sample ID LCS40428 SampType: LCS TeslCods: svoc.9315 n Units: mg1L Ptep Date: 111312019 RunNo: 105643 Client ID: LCSW Batch ID: 40428 TeslNw SWO315A SW8315A Analysis Date: 11/412019 SegNo: 2459917 Analyto Result PQL SPK value SPK Rel Val %RLC [.=Urnil HighUmil RPD Ref Vel %RPD RPOLWI Quel Formaldehyde 0151 0.200 0.150 0 101 7D 130 3 Sample ID LCSD-40428 SampType: LCSU TaslCodo: svoc•8315 n Units: mg1L Prep Dale: 111312019 RunNo: 105643 Client ID: LCS502 Balch ID: 40428 TeslNm SW9315A SW8315A Analysis Dole: 111412019 SegNo: 2459918 Analyle Result PQL SPK value SPK Ref Val %REC LrnvLimit highl-imit RPD Ref Val %RPD RPDLFmll Dual Formaldehyde 0.148 0.21X1 0.150 0 98.6 70 130 0.151 2.07 20 3 Quntificrs: B Analytic detected in the associated Mcthed Blank Ei Value above quentitatien range H Holding limes for preparation or anal; J.Utaly1edetected bclmvquan6talionlimits \1\fanuallntegrationused [adeterminearearesponse MC Value is Wow Minimum Compound NO Not Detected E' Second column confirmation exceeds PL Pemtit LindI Original R RPD outside Accepted tecoveq• limits RL Reporting Detwian Limit S Spike Recovery outside accepted reca Page 5 of 9 C�m i('t T r:'', 'Swrnnitlinriroim;emal7echnologies.ln f ! l Qualifiers and Acronyms °:1� 3310 Win PIVlt;nlJ1AL' t)'liL ll:l:tilmiomr,",, iF;! Cn)-aliognI-alls, Ohio442� WO#: 19110070 An,ifyflcal i.ubornlvrh-,s '1''T/.: (330) 253-8211 EefX: (330) 253.446 Websire: lrlro:1Ann tr.serrek.co Dnte: 11112/2019 I'ltese commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers I3 The compound was analyzed for bnt was not detected. d The reported valtnc is grenler than the Method Detection Limit but less than the Reporting Limit. 11 The hold time for sample preparntion and/or analysis was exceeded. f) The result is reported from a dilution. L The result exceeded the linear range of the calibration or is eslinaated due to interference. Al The I-Mdt is below the Minimum Compound Limit. The resull exceeds the Regulatory Limit or Maximum Contamination Limil, nt Manual integralion was used to determine the area response. d Manual integration in which penk was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 respotasc. 1' The second cohnnm confirmation exceeded 25%difference. C The result has been confirmed by GUMS. X The result was not confirmed when GC/MS Analysis was performed. B/A'IB+ The analyte was detected in lbe associated blank. G The ICB or CCB contained reportable amounts of analyse. QC-/+ The CCV recovery failed low () or high (+). It/QDR The RPD was outside of accepted recovery li mils. QL-1+ The LCS or LCSD recovery failed low (-) or high (a). QLR The LCSILCSD Rl'D was outside oflaccepted recovery limits. Qi1,I-/+ The MS or MSD recovery failed low (-) or high (+). QXIR The MS/MSD RID was outside of accepted recovery limits. QV-/+ The ICV recovery failed low (-) or high (A). S The spike resell was outside of accepted recovery limits. z Deviation; A deviation fionl the method was performed; Please refer to the Case Narrative for additional infomintion Acronyms ND Not Detected RL Reporting Limit QC Quality Control ,IIDL Method Detection Limit N111 Method Blank LOD Level ofDelcclion I,CS Laboratory Control Sample I.OQ Level of Quaulilation LCSD Laboratory Control Sample Duplicate I"QL Practical Quantization Limit QCS Quality Control Sample CRQL Contract Reqnired Quantization Limit Dull Duplicate FL Permit Limit PIS Matrix Spike RegLv1 Regulatory Limit AISD Matrix Spike Dtiplicate A1CL Maximum Contamination Limit III') Relative Percent Different kliuCl, ivlinfnaim Compound Limit ICI' Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Contiuniug Calibration Verification TIC Tentatively identified Compound CCB Coninuing Calibration Blank 1tT Retention Time RLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifier's and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data, Original Page 6 of 9 SIllmNil Enviionmental Technologies, lnc• Accreditation Program fil �t ,+ l E J ��• } t 33lO11'in5l. 1�4,�rj �•Y { Anal tes Report E;:VU,otdi,it:n'nt trrtitcslnrirg t;;c Cul�nhognFalls. Ohio 14223 y Annity0ca/ 1_abc}rare es TEL: (330) 253.8211 FAX: (330) 253-4,169 WON: I9110070 fl'eLsife: hrlo://iv,v„,serrek,co�n 12-Nor-19 Client: Georgia Pacific Inc. 27820 State: NW Project: Water Formaldehyde test Program Dante, NC_W W_SCM Sample ID Matrix Test Nance Analyte Slnh,s 191 10070-001 A Non-Polable Writer Aldehydes (EPA 8315A) Formaldchyde N NC WW SCM N Not Accredited Original #1 Page 7 of 9 JENVIRONMENTAL TECHNOLOGIES. INC. Ur7ahcCo �;:s, ONa .44223 SO4-?78-014C Ana'lYsis Request Chain of Custody Fbr Summit Environmcnlal Tcchnalo,gies. Inc. LLse O;jh, Pace , Of 0-`,nt N=-: -J L 4 - I Georgia-Paciric ChernicAls LLC Watcr Forrnafdehyde test 4 r %IJ 3 200AMpac Road 200 Ampac Road V, Conway, NC 27820 Conway, NC 27820 C;:Lcn! Phr"Ic ::To (252)-585-3819 Tim Riddick 0 10 'NC, U (252)-595-1754 U P552190585 3 Tim Riddick 1, if Ohio-VAP Samples Trio. 1AN, MIMMOMMEEMPM M-UM IN MIN 11MMUM iIMi IM ON M M. MMI1MM M IN IN MEN a IN IMIN IM IN on M11MM11M IN �MMIM MM IN IMMUMIN V­ - -0- Walter Lee 11/112019 1300 L the Rush Requested; Da,. Ll G1 Co 0 1 QD Fedex tracking no. - 409338969615 )I Swim!( EriNronarenrnl71 chrrologies, Lrc. 331011'MS1, PAIIH011Plt:nrnLirmmoionir-5,irrG. CuynhogaFalls, ohro,1d223 Sample Log -in Check List Analyllcal Laborarrrn& TEL: (330) 253-8111 I-AX: (i30) 253-4,189 !1'ebsire: hrflL/Annr.sel!ek.covrr Client Name: GEO-NC-27820-A Work Order Number: 19110070 RcptNo: 1 Logged by: Jacqueline Raslle 11/212019 10:00:00 AM �♦'s'Fti.F Completed By: Jacqueline Rasilo 11/2/2019 12:37:06 PM Reviewed By: Holly Florea 11/4/2019 7:56:17 AM ! Chain of Custod 1 • Is Chain of Custody complete? Yes 0 No ❑ Not Present ❑ 2. Flow was the sample delivered? FedEx Login 3. Coolers are present? Yes No ❑ NA ❑ 4, Shipping container/cooler in good condition? Yes No ❑ Custody seals intact on shipping containerlcooler? Yes ❑ No ❑ Not Present 91 No. Seal Date: Signed By: 5, Was an attempt made to cool the samples? Yes 0 No ❑ NA ❑ 6. Were all samples received at a temperature of >0° C to 6.0°C Yes 11/1 No ❑ NA ❑ 7, Sample(s) in proper container(s)? Yes © No ❑ 8, Sufficient sample volume for indicated lest(s)? Yes EVI No ❑ 9. Are samples (except VOA and ONG) properly preserved? Yes No ❑ 10. Was preservative added to bottles? Yes ❑ No © NA ❑ 11. Is the headspace in the VOA vials less than 114 inch or 6 mm? Yes ❑ No ❑ No VOA Vials 12. Were any sample containers received broken? Yes ❑ No S� 13. Does paperwork match bottle labels? Yes FV1 No ❑ (Note discrepancies on chain of Custody) 14, Are matrices correctly identified on Chain of Custody? Yes {] No ❑ 15. Is it clear what analyses were requested? Yes No ❑ 16. Were all holding times able to be met? Yes No ❑ (If no, notify customer for aulhorization.) Special Handling [if applicable) 17, Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA W Person Notified; Date By Whom; Via: ❑ eMall ❑ Phone ❑ Fax ❑ In Person Regarding: Client Instructions; 18. Additional remarks: Only reed one vial Cooler Information Cooler No I Temp °C I Condition 19eal Intact Seal No Seal Date Signed By t 14.2 1 Goodl Not Present Page 9 of 9 f Universal Laboratories 20 Research Drive, Hampton, VA 23666 Z t7 1 ELEPHONE: (757)865.0880 TOLL. FREE: (800)095.2162 rnx: (757)8G5.8014 REPORT OF ANALYSIS TO: Georgia Pacific Order ID: 1911258 COC Name: Semi -Annual Slormwater Mr. Tim Riddlok Receive Date: 12/09/2019 P.O. Box 368 Report Date: 12/18/2019 Conway, NC 27820 This report contains the analytical results for the indicated Project and Order. The results contained In this report relate only to the samples identified in this Order. The analytical results meet all requirements of the 2009 TNI Standard, unless specifically stated or laboratory does not hold accreditation as seen in the Cert # column. This report shall not be reproduced except in full. The data in this report has been reviewed and validated by:,.._f;�t1,-���.r� Signature Name TIVe ROP011606414: 1911258 Page t 01 3 OF-002�r��"�i�•,"ar"r Lae Irl ; f -14v 8.002• Collection Deter MOT20te 02:40 Permit: --- —Malr(X; AQUEOUS Semi Volatilo arganks EPA 625.1 Holding Time Met Sample Receipt Temperature Cresols, Total m,p-Cresols o-Cresol Phenol surrogate 2,4,6- Tribromophenot (% Recovery) surrogate 2-Fluorophenol (7 Recovery) surrogate Phenol-db (% Recovery) Reaut " AnalVals Dat Artalyst Qual. RL Certtl Yes Yes/No 12IW01913:10 GH 2 C 1W181201013:10 GH ND ug/L 12/181201913:10 GH 6 460036 ND uWL 121181201913:10 GH 5 460030 ND uglL 12I8120191110 Gil 5 460036 ND uglL 12118/20191110 GH 5 466036 54 % 121181201913:10 GH 9.5.123A 33 % 12/181201913:10 GH 2O.6.110.5 20 % 1211812019 1310 GH 915.110.5 Analytical Ouality Control Results Report PREP SV_O_ A AO 62513510 Batch: 121319-0091 LIMSIV - Test Parameter Result RL Gunt �Accurvcy Pra91at0n Control control 121319.009-MB•01 SVGA 625 - AQ MB m,p•Cresols 0 ugrL tl Phenol 0 ugR 0 V Surrogate 2-Fluoraphenoi (% Recovery) 38.5 %. 20.6 • 110.5 6urrogato Phanol•d5 (% Recovery) 23.3 % 0.5 - 110,5 Surrogate 2,4,6-Trlbramephenol (% Recovery) 0 % 5 9 S • 17..1 4 121310.00n,LC$01 SVOA 625 - AQ LCS surrogate 2-Fluoraphenol (% Recovory) 50 % 13.69 surrogate Phenol•0 (% Recovery) 24 % 10. 68 surrogate 2,4,6,Trlbremoph0nol (% Recovery) 70 % 42 - 122 Phanol (% Recovery) 33 % 17. 120 1911258,002 SVGA 625 - AO MS Surrogate 2-Fluoraphenol (% Recovery) 40 % 13 - 60 surrogate Phenol-d5 (% Recovery) 20 % 10. 50 surrogate 2,4,6•Tr+bromophenol(%Recovery) 70% 50-126 Phenol (%. Recovery) 26 % 10. 120 MA. 625 - AQ M30 surroguto 2-Ftuorophenol (% Recovery) 47 % 20.6. 110.5 surrogate Phenol-d5 (°% Recovery) 23 %e 9,5 - 110.5 surrogate 2,4,6•Tr1hrornophenol (% Recovery) 69 % 9.5 • 123.4 Phenol (% Recovery) 33.6 %, to. 120 Phenol (RPD) ND % 0. 64 m,p-Cresols (% Rocovery) : /; s 7. MS 10. 13'1 m,p-Crasdr (RPD) NO % 0. 30 o-Cresol (% Recovery) 0 % MS 70, 11-) o-Cresol (RPD) ND % 0.30 napoa $wlal Y: 101126B Pag1) 2 Ot 9 Quallf ler Codes * II present under the "Carl 11' column, indicalos that the laboratory does not have 2009 TN accreditation In Virginia. These analyles should not be reported for Virginia Air, Water, or Waste Laws or the Sale Orinking Water Act to meet their requirements. S Analyto was found in the method blank D RPD outside acceptable llmlls EPL Exceeds Permit Limit, This Is a qualliler to denote that the result exceeds the permit limit of the sample location. H Holding lime excoaeded IS Internal standard outside acceptable limits J Result abovecallhrallon curve - results are appro dmale MI Matrixlnlerence Ms Matrix spike mcoveryouWde accaplabla limits ND No analyle defected at or above the RL (Reporting Limit) listed NR No Results available, analyla not In Instrument calibration QC Method OC criteria not met; GGA or LCS Failure R SM 52109.2011 7.b. Test replicates shall more than 30% differenco between high and low values S Surrogale outside acceptable limits V ICVICCWFCV outside acceptable limits Glossary of Terms 460036 If present under the'Cert t1" Column, Indicates that the laboratory holds accreditation under the 2009 TNI Standard In Virginia. Calibration (Inllial, Continuing, or Final) A standard analyzed at different times to verify that the Initial calibration curve Is slip valid. Verlication Exceeds Result Exceeds Benchmark concentralion listed in the General Permit, Boncismark Concenitaiions are primarily used to Benchmark determine the overall effectivenss of the Stonnwaler pollution prevention plan. Excedenco of Senchamrk concentrations (loos i concentration NOT constitute a violation of this permit and does NOT Indicate that violation of a water quality standard has occurad. Holding Time The ma)dmum lima that samples may be held prior to analysis and still be considered valid or not compromised. Internal Standard A known amount of standard added 10 a lest portion of a sample as a reference for evaluating and controlling the precision and bias of the applied analytical method. LCS (Laboratory Conlrol Sample) A sample matrix, frog from the analyzes of interest, spiked with verified knorm amounts of analyzes or a material containing known and verified amounts of analyis. MOIL Method Detection Llmitis is an estimate of the minimum amount of a substance that an analytical process can reliably detecl Methed Blank A semplo of a matrix simllar to the batch associated samples (whan available) that Is lroo from the anaiylas of interosz and is processed slrnuialanously with and under the same conditions as samples. MS/MSD (Malri)(Spike or Matrix Spike Duplicate) A sample prepared by adding a known mass of target analyze to a specilied amount of matrix sample for which an Independent osllmato of target analylers concentration is available. MalOx Spikes are used, for oxamplo, to delermina the effect of the matrix on a method's recovery efficiency, AL (Reporting LIrnl1) The minimum levels, concentrations, or quantilies of a target analyze that can be reported within a specilled degree of confidence. Generally, this number Is equal to or Just above the lowest calibration standard run wilh the analytical batch. RPD (Relative Percent Difference) The difference between a sot of duplicates or sample spike duplicates. Surrogato A subs lance with properties that mimic the analyle of Interest. It is unlikely to be found in environments! samples and Is added to them for quality control purposes In Organics. R7porrsedaIN: 1911258 Page 3 of 3 Georgia Pacific P.O. Box 368 Conrvay,NC,27820 Contact:Tirn Riddick252-585-1232, (c)252-395- 1525,TARIDDIC 0 GAPAC-Corn Universa0 Laboratories CHAIN OF CUSTODY I®: 1911258 Semi -Annual Stormwatetr 20 Research Drive Hampton, VA 23666 1-800-695-2162 hitpJ/mvw.un iversallaboratories.nei Page 1 of 1 Sample Name UL Sample, ID Matrix ' Sample Daterrime/Initials BDttlelD Sample Container _ Preservation Testing OF-002 i911256002 AQUEOUS AQUEOUS q_t 0�tir7 /� i/ 002G 110ass <6°C waste.625 002-H 11Giass <6°C VdTES_ CoolerTemp--,Z:-c 'henot Int check CN int check BOD int check- NH3 int check TRANSFER SIGNATURE DATEITIME TRANSFER SIGNATURE; DATEMME Relinquished by VAI I;Z414 f('bd Received by Relinquished by G S Received by Relinquished by Received by Relinquished by Received by