NCS000282_Monitoring Data_20141120

Attachment B
Explanation of QC Qualifier Codes
Qualifier Meaning
T8 (ESC) - Additional method/sample information: Sample(s) received past/too
close to holding time expiration.
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC.
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods,it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
"unless qualified as 'R' (Rejected)."
Definitions
Accuracy - The relationship of the observed value of a known sample to the
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
Precision - The agreement between a set of samples or between duplicate samples.
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Surrogate - Organic compounds that are similar in chemical composition, extraction,
and chromotography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
TIC - Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
Page 4 of 4

Total Event Precipitation (inches): . to
Was this a Representative Storm Event? (See information below) Yes ❑ No
Please check your permit to verify if Qualitative Monitoring must be. performed during:a representative
storm event (requirements vary).
A "Representative Storm Event" is a storm event that measures greater than 0.1 'inches of rainfall and that
is preceded by at least 72hours (3 days) in which no storm event measuring greater than 0. l inches has
A occurred. . single storm event may contain upjg 10 consecutive hoursof rio,preclpitation.
_ Ate.
f
By this Signature, certify that this report is accurate and complete to the best of my knowledge:;
afore of Permittee or Designee)
/ 1. O Description':
Outfall N spoor r Spn4 f'etu {xpe, tiicl}�t
iZeixetvtr�g Strd r . ,..o , r r +. ib
Describe the industrial activities .tU,. t occur within . eputfai drainage area,
2. Color: Describe the color of th its harge rising' sic colors (red, ter .Wn, blip, etc.) art tint
(light,, dium, dark) as de c 'ptors r G' / ,
- Cd q r� r
3. Odor: Desen any dis 'nct od s that the 'schar e may have (i.e., smells s ongly of oil, weak
chlorine odor, etc.): , . or
Page 1 of 2
SWU-242-112608

4. Clarity: Choose the number which best describes the clarity of the discharge; where 1 is clear
and 5 is very cloudy: Ire
1 3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the
stormwater discharge, where l is no solids and:5 is the:surface:covered with floating solids:''
1. n 34 5
6: Suspended Solids: Choose thenumberwhich. best describes, the amount of suspended solids in
the stormwater discharge, where 1 is no'solids'and 5 is extremely muddy:
�1 2 3 4 5
7. Is there,any foam in the stormwater discharge?' Yes No
8. Is there an oil sheen. in the stormwater discharge? Yes, No
9. Is, there; evidence of erosion or deposition at the outfall? Yes No
v
Note: Low clarity, high' solids, and/or the presence of foam, oil sheen; or erosion/deposition maybe
indicative of pollutant exposure: These conditions warrant further investigation.
Page 2 of 2
SWU-242-I 12608

Grain & Oilseeds Supply Chain North America
1400 South Blount Street
Raleigh, NC 27603
March 20, 2014
Attn: Bradley Bennett, Supervisor
Stormwater Permitting
NC Department of Environment and Natural Resources
1601 Mail Service Center
Raleigh, NC 27699-1601
RE: Cargill, Incorporated, Raleigh, NC — NPDES Stormwater Permit NCS000282
Facility Operational Change Notification
Dear Mr. Bennett,
The Cargill, Incorporated (Cargill) facility is submitting this notification under Section E(5) of the
facility's NPDES Stormwater permit to communicate planned process changes. In early April of
2014, the Soybean Extraction Process will be shut down and placed in an idle capacity. The time
period of this idled process is unknown at this time. The facility will be operating a Soybean Trans -
Loading operation in which raw soybeans will be received via truck, temporarily stored in the
existing Soybean tanks, and loaded out in Rail cars for further processing at other Cargill facilities.
As part of this operation, Soybeans will not be cleaned or dried on site.
The table in Appendix A highlights the expected exposed materials and pollutants that will be
associated with the Trans -Loading operation. Those materials and pollutants associated with the
Soybean Extraction process will not be a characteristic of our stormwater discharges during the idle
period.
Because the facility will be in an idle operating scenario with our Soybean Extraction process, and
since we have not made any determinations as to the long term future of ongoing operations at the
facility, Cargill would like to retain all elements of our current permit. Please note, this permit is
currently pending renewal with the renewal application received by NCDENR on December 3, 2013
Cargill will continue to comply with the current stormwater permit requirements. Should you have
any questions or comments, I can be reached at [phone].
Sincer ly,
ZcPael Klauke
Facility Superintendent

r
cc: Dave Parnell — NCDENR Stormwater — Raleigh Regional Office
John Holley — NCDENR Stormwater — Raleigh Regional Office
Scott Schuelke — Cargill Regional EHS Coordinator
Attachment

P
APPENDIX A - Facility Exposed Materials
Northeast corner of the facility
TSS, BOD,
Raw Soybeans
and west of the main bean
COD
Monthly Housekeeping
dump
Soybean Meal and Hulls
y
East of the meal load -out
TSS BOD,
Secondary Containment Area
scale
COD, O & G
Hexane
USTs located south of the
O & G, BOD,
Secondary Containment Area
Rotocel
Hexane
AST in dike around the
O & G, BOD,
Soybean Oil
extraction area and in diked
COD
Secondary Containment Area
area south of the shop
Coolingtower chemicals
North of the extraction control
pH
Secondary Containment Area
room
Boiler feedwater
chemicals
Boiler room
pH
Secondary Containment Area
Glycol
y
East of the dryer cooler glycol
hothouse
BOD, COD
Secondary Containment Area
No. 2 Fuel Oil
ASTs in diked area south of
O & G, BOD,
Secondary Containment Area
the shop
COD
Diesel Fuel
Drums in the diked area south
O & G, BOD,
Secondary Containment Area
of the shop
COD
Mixed hexane solvent
and soybean oil
Process extraction area
O & G, BOD,
COD
Secondary Containment Area
(miscella)
Hydraulic fluid
Truck dump reservoir
COD BOD,
Secondary Containment Area
Lubrication oil
55-gallon drums in the
Muskogee House
O & G, BOD,
COD
Secondary Containment Area

C141*11M�
Division of Water Quality
Attn: Dave Parnell
1617 Mail Service Center
Raleigh, NC 27699-1617
January 21, 2014
RE: Cargill, Incorporated, Raleigh, NC— Stormwater Discharge Permit NCS000282
Written Notification of missed Monitoring and Reporting
Mr. Parnell,
During a recent internal audit of the Cargill, Raleigh facility, it was noted that the location had missed
taking stormwater samples and submitting monthly reports for the months of January, July and
October of 2013. This was verbally reported to Mitch Hayes, Surface Water Protection Section, via
telephone on January 15tn
The missing samples occurred during a time of significant employment transition for certain jobs and
roles at the plant due to attrition and business conditions. When the missing samples were discovered,
we immediately implemented a process to ensure the required information will have 2 verification
steps in place to eliminate nonconformance with the requirements.
hi an effort to prevent this from happening in the future, we have included future stormwater
monitoring and reporting requirements into an EHS Task Database. This database has the ability to
send reminders to facility personnel at the beginning of the month, and a follow-up reminder in the
middle of the month. These reminders have been established for the facility EHS Coordinator as well
as our Regional EHS Coordinator.
I certify, under penalty of law, that this document and all attachments were prepared under my
direction or supervision in accordance with a system designed to assure that qualified personnel
properly gather and evaluate the information submitted. Based on my inquiry of the person or
persons who manage the system, or those persons directly responsible for gathering the
information, the information submitted is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations.
1400 S. Blount Street
Raleigh, NC 2 76032506

f
If there are any questions regarding this submittal please feel free to contact me at [phone].
Sincerely,
Will Graham
Plant Superintendent
Cargill, Incorporated
Raleigh, NC
0 Page 2

i
RECE��rEp
a'` SZA7t "
MAR - R 2011
�. bCtJt�uR
Raleigh PT-
. rna! Office
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
For guidance on filling out this forrn, please visit: http://h2o.env.state,nc,iis/su/Forms Documents.htm#misefonns
Permit No.: NICI-5/ 0l �0l 0l?I ! 1 or Certifi ate of Coverage No.: N/C/G/ f_l A/ l_l
-_ Facility Name:'
County: Phone No. �'l `� 8` 9 loco 0�
Inspector
Date of Inspection: I J.5 11
Time of Inspection: / G : CAA
_ Total Event Precipitation (inches): , 5`
Was this a Representative Storm Event? (See information below) ®"Yes ❑ No
Please check your permit to verify zf Qualitative Monitoring must be performed during a representative
storm event (requirements vary).
A "Representative Storm Event' is a storm event that measures greater than 0.1 inches of rainfall and that
is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has
i
occurred. A single storm event may contain up to 10 consecutive hours of no precipitation.
By this
this report is accurate and complete to the best of my knowledge:
(Signaturelf P"ffee or Desi
1. Outfall Descrlutjvn.
Outfall No:-VOOF Qr SaPo2 S
Receiving Stream: _J
Describe the industrial activities
e (pipe, ditch, etc.)
occur within /the outl
/
'C4 . ✓+ ! t 040
drainage area: `
-,, a,- lln pa K�
O
2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint
(light, medium, dark) as descriptors: ffiisud Lgalt
3. Odor: Describe any distinct
chlorine odor, etc.): il, S ,) e J Jc
SWU-242-112608
that the discharge may have (i.e., smells strongly of oil, weak
Page 1 of 2

4. Clarity: Choose the number which best describes the clarity of the discharge, where I is clear
and 5 is very cloudy:
5. Floating Solids: Choose the number which best describes the amount of floating solids in the
stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids:
2 3 4 5 /�, � ) e � -i «✓ Pk
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in
the stormwater discharge, where 1 is no solids and 5 is extremely muddy:
1 2 3 4 5 F4,53eJ
7. Is there any foam in the stormwater discharge? Yes (No)
&. Is there an oil sheen in the stormwater discharge? Yes No
9. Is there evidence of erosion or deposition at the outfall? Yes No
10. Other Obvious Indicators of Stormwater Pollution:
List and describe r s Zc l ;._, g2IC- :j;
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be
indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
SWU-242- i 12608

Tier 2 Checklist
n addition to repeating the steps for Tier 1, monthly sampling is required tor all parameters at
every outfall where an exceedance was recorded until 3 consecutive sampling events results
are below benchmarks.
Sampling Event Number SD000282
Sample Date 1/25/2011
Sampler missed sample
Outfall Number RNC-SD001 or RNC SDO02
Contract Laboratory ESC Lab Sciences
Results
Paramotar 11 Initcl
vali,P Benchmark Values Benchmark Exceedance?
BOD
missed sample
30 mg/L
NO
COD
missed sample
120 mg/L
NO
pH
missed sample
Standard (6-9)
NO
Nitrate -Nitrite
missed sample
10 mg/L
NO
Phosphorus,Total
missed sample
2 mg/L
NO
Kjeldahl Nitrogen, TKN
missed sample
20 mg/L
NO
Suspended Solids(TSS)
missed sample
100 mg/L
NO
Results
Pnrnmotar /1 Initcl
valiiP Benchmark Values Benchmark Exceedance?
BOD
N/A
30 mg/L
N/A
TSS
N/A
100 mg/L
N/A
Total Kjeldahl Nitrogen
N/A
20 mg/L
N/A
Nitrate -Nitrite
N/A
10 mg/L
N/A
Total Phosphorus
N/A
2 mg/L
N/A
COD
N/A
120 mg/L
N/A
pH
N/A
Standard
N/A
* Keep a record of all Tier 1 actions with facility SWPPP
S:\sharedoc\EHS\BR 3.0 Environmental\BR 3.2 Surface Water Protection\G - Surface Water Protection - Indirect
Discharge-Stormwater\Tier 11 Checklist.xlsx

Sampling Event Number
Sample Date
Sampler
Outfall Number
Contract Laboratory
Results
Do -fnr /1 Initcl
Tier 1 Checklist
SD000282
1/25/2011
missed sample
RNC-SDO01 or RNC SDO02
ESC Lab Sciences
VnIllp Renrhmark Values Benchmark Exceedance?
BOD
missed sample
30 mg/L
no
COD
missed sample
120 mg/L
no
PH
missed sample
Standard (6-9)
no
Nitrate -Nitrite
missed sample
10 mg/L
no
Phosphorus,Total
missed sample
2 mg/L
no
Kjeldahl Nitrogen, TKN
missed sample
20 rng/L
no
Suspended Solids(TSS)
missed sample
100 mg/L
no
Tier I Checklist
Stormwater inspection
conducted within 2 weeks? missed sample
List of possible Causes
missed sample
Potential Solutions
missed sample
Actions Taken (include
dates of implementation) missed sample
Keep a record of all Tier 1 actions with tacility SWNNN
S:\sharedoc\EHS\BR 3.0 Environmental\BR 3.2 Surface Water Protection\G - Surface Water Protection - Indirect
Discharge-Stormwater\Tier I Checklist.xlsx

March 7, 2011
To whom it may concern:
For the month of JAN 2011 we did not have a discharge from outfall SD002.
The following apply to outfall SD001
Event on Jan 10th came as snow/freezing rain so no sample was collected. Event on Jan 25, we missed
collecting the sample due to miscommunication. This has been addressed and resolved.
If there are any questions regarding this submittal please feel free to contact me at 919-899-6604.
Since
JosJhleanasky
Facility Superintendent
Cargill, Incorporated
Raleigh, NC
1400 S. Blount Street
Raleigh, NC 27603-2506

bc
0
a
W
o:
O
Z
R
O
Z
O
Iq
�
o
o
� =
�
N
�
N L
M b
m '-
W
�'
O a
c E
a
o
d
'In
W
y
G
> 41
� N
J
G)
N ?
tD LU
t0 >
U
ate+41
G1
pop W
UJ
L a
as j
.r
O Zt7
V
L a; o
> Z to
rW-I
J
OG 41
C O
W W
to
o s a
M it
0= J
Ln
c E
Vaa
J
a
O O a
E %L Y
E
O
�6
ta/S
4=
R*
O
n
N
0
L
n
CAQ
Z Z
Z
W
Z
ft �I
J J
tG
O
N V
00
N Z
.6 Q
o O
Z
cn .� Z
UJ
a
Q W
V
= J CA I
O.
_ UJ
aL
Z �
pq N
3
a
>
Z O
V (D 0
Z Q
0:
to
~ u
I cc
5
=
u-
cc O
W O
W m
o
++
W W
0.
Q J J
o
Ja
2
}Zuo
Lij
O
Z 0~C
U C~C
41
C9 u
LL. CL U
(A
C \
o�
a
a
E
E
3
0
O
In
O
Q
aN-I
0
z
E E
�_
Z
w
a
E
3
a
M
O
Q
z
to
--a
0
C
N
z
y
N
a
�
Q
E
3
o.E�
O
Z
N
h
r
'C
a
U
a
a
y 'tea
cn
OLZ
Q
0
O
Z
L
Z
N
�
a
m
Y
N
L
Mp
E
O
O
z
o
o
a
z
w
0)z
z
CO41
0
J
:E, 5
a
£
a
C)
M
.0
O
Q
Y OaA
N
a,
O
z
O
N
Z
0 41
Z
to
a
E
Z
m
o
z
y Z
a
O
+
i M
N
z
Z Z
ul
�
a
G
Q
s
CL
m
o
Q
O to
s E
N
v
u-
O
z
a
In
Z
t6
1
of
t-
C
a -i
Y!
a
a
O
1Eo
to
o
LL
Q
_
;C
M
'o
Z
t
o
Z
.;E
.0
a
V
a
a
O">-
V
m
O
Q
o
z
E
D
Z
N
a
m
C
O
Y
s
tC
O
O
s
cc)
o
Q
o
z
0
co
cc

%
�
E�k
2 \ _
S 2 k
k/k
\ o £ _
S § E 0
�w o2
k 1 IA
M CA
0
0
o £
c §
\ E u
� 0
aka/
2 2 E
# o
$ E 7
�4,
E E 4
—
—
�
— � ■
#
c c - a
/ m41
E
wm E
■ 2
� 3 k 0
tee:
cu 41 e IA
■ e £ =
1 # q 2
ƒ 3 k
§©©.0
2°0'
a ®
f to
>. §
E 0
8 m
2 r -
4-1 § k.
E
0
f _ e ■ j
q o W to
0 cr41
2 2 0 § 2
§ w E
CL IMA
J
2 ■ § §
t % 2tn
�.
r 2 E _ f

History: Weather Undet --round Page 1 of 1
1
Actual:
63139
Precip:
0.28
Average:
50130
Precip:
0.12
2
�•
3
D
4
5
..
6
�
y`.r
7
'"
8
Actual:
62137
Actual:
45126
Actual:
54123
Actual:
46126
Actual:
48132
Actual:
46131
Actual:
44124
Precip:
0.17
Precip:
0.00
Precip:
0.00
Precip:
0.00
Precip:
0.15
Precip:
T
Precip:
T
Average:
50130
Average:
50130
Average:
50130
Average:
50130
Average:
50130
Average:
50130
Average:
50130
Precip:
0.12
Precip:
0.12
Precip:
0.12
Precip:
0.12
Precip:
0.13
Precip:
0.13
Precip:
0.13
9r='
10
11
12
13
14
=
15
Actual:
35119
Actual:
34 126
Actual:
32128
Actual:
38126
Actual:
42 120
Actual:
411 19
Actual:
50126
Precip:
0.00
Precip:
0.12
Precip:
0.08
Precip:
0.00
Precip:
0.00
Precip:
0.00
Precip:
0.00
Average:
50130
Average:
49130
Average:
49130
Average:
49130
Average:
49129
Average:
49129
Average:
49129
Precip:
0.13
Precip:
0.13
Precip:
0.13
Precip:
0.13
Precip:
0.13
Precip:
0.13
Precip:
0.13
17
18
19
`..
20
'
21
22
"`
16';
>
Actual:
53125
Actual:
46130
Actual:
47 132
Actual:
61 142
Actual:
51 128
Actual:
47128
Actual:
32 117
Precip:
0.00
Precip:
0.03
Precip:
T
Precip:
0.00
Precip:
0.00
Precip:
T
Precip:
0.00
Average:
49129
Average:
49129
Average:
49129
Average:
50129
Average:
50129
Average:
50129
Average:
50129
Precip:
0.13
Precip:
0.13
Precip:
0.13
Precip:
0.14
Precip:
0.14
Precip:
0.14
Precip:
0.14
24
rvn'
25
'"
26
27
28
29
23
Actual:
46116
Actual:
40125
Actual:
51 130
Actual:
43138
Actual:
48128
Actual:
56128
Actual:
58124
Precip:
0.00
Precip:
0.00
Precip:
0.17
Precip:
0.37
Precip:
0.00
Precip:
0.00
Precip:
0.00
Average:
50129
Average:
50129
Average:
50130
Average:
50130
Average:
50130
Average:
50130
Average:
51130
Precip:
0.13
Precip:
0.13
Precip:
0.13
Precip:
0.13
Precip:
0.13
Precip:
0.13
Precip:
0.13
30
31
Actual:
69135
Actual:
47135
Precip:
0.00
Precip:
0.00
Average:
51130
Average:
51130
Precip:
0.13
Precip:
0.13
http://www.wunderground.com/history/airport/KRDU/201I/i/l/MonthlyHistory.html 3/7/2011

Stormwater Discharge Outfall (SDQ)
Qualitative Monitoring Report
For guidance on filling out this forni, please visit: httn://h2o.eni-.state.nc,iis/su/Forms Docu,ments.htnL#miscfonns
Permit No.: N/C/-S/ a/ 0/ O/ ! el -I-/ or Certificate of Coverage No.;
Facility Name: l/
County: Phone No. %19 — 899 lain 0
Inspector: _j (7kn — -
_- Date of Inspection:Time of Inspection: % G1 : t S A
Total Event Precipitation (inches): =_5 `7r
Was this a Representative Storm Event? (See information below) 1/Yes ❑ No
Please check your permit to verb, if Qualitative Monitoring must be performed during a representative
storm event (requirements vary).
.._.------_._—..---......
A "Representative Storm Event" is a storm event that measures greater than 0.1 inches of rainfall and that
is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has
occurred_ A single storm event may contain up to 10 consecutive hours of no precipitation. i
By this ature, I certi that this report is accurate and complete to the best of my knowledge:
(Signa re 01 Perrmttee or D
rnl,�
1. Outfall Description:
Outfall No?0001 °r -c4°OZ S ctu e (pipe, ditch, etc.)
Receiving Stream: v
Describe the industrial activities tikt occur within the outfall drainage area:
2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint
(light, medium, dark) as descriptors: N , F l ,
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak
chlorine odor, etc.): F( J
Page i of 2
SWU-242-112608

4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear
and 5 is very cloudy:
1 2 3 4 5 0
5. Floating Solids: Choose the number which best describes the amount of floating solids in the
stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids:
1 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in
the stormwater discharge, where 1 is no solids and 5 is extremely muddy:
1 2 3 4 5
7. Is there any foam in the stormwater discharge? Yes No
S. Is there an oil sheen in the stormwater discharge? Yes No
9. Is there evidence of erosion or deposition at the outfall? Yes C'No
10. Other Obvious Indicators of Stormwater Pollution:
List and describe fV h E-- Z Nc Pf- J
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be
indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
S WU-242-112608

Sampling Event Number
Sample Date
Sampler
Outfall Number
Contract Laboratory
Tier 1 Checklist
SD000282
1/25/2011
No Flow
RNC-SD001 &RNC SDO02
ESC Lab Sciences
Results
Paramatar Mnitrl Value Benchmark Values Benchmark Exceedance?
BOD
no flow
30 mg/L
NO
COD
no flow
120 mg/L
NO
pH
no flow
Standard (6-9)
NO
Nitrate -Nitrite
no flow
10 mg/L
NO
Phosphorus,Total
no flow
2 mg/L
NO
Kjeldahl Nitrogen, TKN
no flow
20 mg/L
NO
Suspended Solids(TSS)
no flow
100 mg/L
NO
Tier I Checklist
Stormwater inspection
conducted within 2 weeks? No Flow
List of possible Causes
No Flow
Potential Solutions
No Flow
Actions Taken (include
dates of implementation) No Flow
Keep a record of all Tier 1 actions with facility SWPPP
S:\sharedoc\EHS\BR 3.0 Environmental\BR 3.2 Surface Water Protection\G - Surface Water Protection - Indirect
Discharge-Stormwater\Tier I Checklist.xlsx

Tier 2 Checklist
[In addition to repeating -the steps or Tier , mont y sampling is require or a parameters at
every outfall where an exceedance was recorded until 3 consecutive sampling events results
are below benchmarks.
Sampling Event Number SD000282
Sample Date 1/25/2011
Sampler No Flow
Outfall Number RNC-SD001 or RNC SDO02
Contract Laboratory ESC Lab Sciences
Results
VaI11n Ranrhmark Values Benchmark Exceedance?
BOD
no flow
30 mg/L
NO
COD
no flow
120 mg/L
NO
pH
no flow
Standard (6-9)
NO
Nitrate -Nitrite
no flow
10 mg/L
NO
Phosphorus,Total
no flow
2 mg/L
NO
Kjeldahl Nitrogen, TKN
no flow
20 mg/L
NO
Suspended Solids(TSS)
no flow
100 mg/L
NO
Results
Dr h Initcl
Values Renchmark Values Benchmark Exceedance?
BOD
N/A
30 mg/L
N/A
TSS
N/A
100 mg/L
N/A
Total Kjeldahl Nitrogen
N/A
20 mg/L
N/A
Nitrate -Nitrite
N/A
10 mg/L
N/A
Total Phosphorus
N/A
2 mg/L
N/A
COD
N/A
120 mg/L
N/A
pH
N/A
Standard
N/A
* Keep a record of all Tier 1 actions with facility SWPPP
S:\sharedoc\EHS\BR 3.0 Environmental\BR 3.2 Surface Water Protection\G - Surface Water Protection - Indirect
Discharge-Stormwater\Tier 11 Checklist.xlsx

Carr ►ll.M
g
March 7, 2011
To whom it may concern:
For the month of JAN 2011 we did not have a discharge from outfall SDOO2.
The following apply to outfall SDOO1
Event on Jan 1O1h came as snow/freezing rain so no sample was collected. Event on Jan 25, we missed
collecting the sample due to miscommunication. This has been addressed and resolved.
If there are any questions regarding this submittal please feel free to contact me at 919-899-6604.
epn F. veanas
F ility Superint dent
Cargill, Incorporated
Raleigh, NC
1400 S. Blount Street
Raleigh, NC 27603-2506

v
v
Z
D
D
CD
Z
D
cn v
O
c
m
3
G
O
m v
(D
•�+
E
.�+
m
m z
Z (D
m
3
=
m
0
D ((DD
x
'0
Ln
3
.-.
_
m
n
-a
O
m
O
�
n
S
�
C
M
M
v
3
'*
v
3
fD
(-� D q 3
(D V 7 v+
S � Cp � O
Z — < O— OQ
0 (A '0 g 3
m n D±
ov
n F, 3
w rD p a
a) ( n
rn �
LD 0
O
z
z
m
c
N
D
00
po
3
3
—
O
O
fu
Z
0
N
N
N
v
N
Lq
D
N
0
N
0
�.
ff
o
m
m�
3
z
v
w
lu n
D
u,
o
3 x
1 on
r m
7
0
v
O
O
D
rn
o
N
'�
r y
0
c
(A
Z Z
0
+v
D
o
00
O
C
Z
}
rn
N
Z
rY 0
0 0!
Z
!''
N
N
0
m `C
D
w
m
O.
OC lu
3
r —
0.
Z
z
m
v
z
n
n
n
=
D
o
o
3
0
O
O
�+
N
I—
�
0
fD
0
0
v
z
vim,
�'_,
a ,3a
D
N
N
\ m
O
o
C
(D
rni
(D
CL
n
v
c
D
w
O
r
O
N
0
G.
cn
G.
z
rn
rn
ar
�
'O. 2
C
3
m m
d
Z
W
W
N
3 ass
D
`Q Q
x
�q
r 3
f`: 0
m m -
J r
m M
0
0Z
< Z
O
D Z
� A
m jg
z o `,
O O
Z N
co
O
Z O
D
cn
m 0 o
r
A
3 3
rn
V1
DOC
y Z
Z
0
r
m m
ao
r
yZ
t
O Mrn
� rD M
oI
s 0
z
m
m
v
of
Z to
D
^• 0.
C
2 pIm,
m
Q m
tm
;a
M
A e+
(D
A
< Q+
:m
D
rn O
0
v
rrn
(A
m
A
s �.
Z
v
(D
v
d
7Do
0
m
D
OrQ
r.
C DS1
N
o �
3 -Di

g i—
M
�
�
- � ] 2r
2 \OIQ
2�R=;
§ R f C
J Q E 0 §
f � � m
ff c
o- \ M 2
0 n - / W
k 2 } r+ r+
OnM o $
/ M M k E
W W M
\ 2 = 2 r+
CL k /
CL
R
c
M
-
2 § � §
f CL
k f ] r+
2 R
M $ ƒ
7 ® °
¢ M - $
f 0
� B ) 2
7 \ CL
r+ 2 o c
� M § /
f .cam
m/ J
E § g a
7WE�
] o
- o
0 c CL
2 o °
.] 3
/mJm
CL -
E2ƒƒ
® r+ R E
=r
2ƒ��
g R
gr+-0 °
= o ■ ƒ
o J § )
f g o
� q M
L k IA
°
fu
]
CL E
Cr
4h

Qi4rillW
DEMLR — Storm water Permitting Program
Attn: Storm water Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
October 15, 2014
RE. Cargill, Incorporated, Raleigh, NC — Stortn water Discharge Perfnit NCS000282
Year 5, Period 2 - Analytical Monitoring Results
In accordance with the Cargill, Raleigh facility's Storm water Discharge Permit NCS000282, Part I11,
Section E, Cargill is submitting Discharge Monitoring Reports for the Year Five, Period Two
monitoring period. The monitoring was completed on September Bch 2014 during characteristic storm
event.
SDO0.1
Characteristic
Benchmark
Lab
Results
Tier
10/152014
COD
120 mg/L
38
2
10/15/2014
BOD
30 mg/L
9.5
2
10/15/2014
Total Phosphorus
2 mg/L
0.30
2
10/15/2014
TKN
20 mg/L
2.3
2
SD002
Characteristic
Benchmark
Lab
Results
Tier
10/15/2014
COD
120 mg/L
30
2
10/15/2014
BOD
30 mg/L
7
2
10/15/2014
Total Phosphorus
20 mg/L
0.56
2
10/15/2014
TSS
100 mg/L
53
2
If there are any questions regarding this submittal please feel free to contact me at [phone].
Sincerely,
Michael Klauke x
Plant Superintendent
Cargill, Incorporated
Raleigh, NC
1400 S. Blount Street
Raleigh, NC 27603-2506
NOV 2 0 2014
DENR-LkJ\1D Qi i;11TY
S T CRNINA1IER PER10ITTING

0
.`
::7r
r41
w a
{
CL
4D
�
w
-d
-s
41 3 a
,.s
—4
tYe T S
o
�
C�7
32, Cr
(75
IN
T : I x 'I -Liter HOPE w1no pre erv.
.t,
B&b:, 1 x i- .iter,HOPE w1no preserv.
phi: 1 x 126 tnl HDIPE wino preserv.
Nitrate/Nitrfte "I x a�tnf Hpl'l� val rrtl sulfuric Ord' preserv.
g
COD, (Combine wfNitrate/Nitrite Bottle)
1
TKN- (Combine wiNitratei litrite Bottle)
Total Phosphorous. (Combine w/Nitrate
Nitrite Bottle)
co
z AA
79
{
r !
2
kv
`�
Cr

_,
c�
,
" p
'
—..
2
Am LT
0
cw
M
)
?,
r
r
rw
�.
0
m �`
G 4
orEL
'5:
1 x-Ater HD PE wino preserv.
i fix -Liter D ,w/,no preserv.
'
4pEH: t x 12 =ml� DPE a=lno preserv.Ic
'
1VltratelNitrlte: '1 x 600mf HDw /Sml Sulfuric Acid preserv.
�+
COD: (Combine wNitrate/Nitrit€* Bottled
"4>
i`KN: (Combine vwflwtitrate/Nitrite Bottle)
Total Phosphorous: (Combine w/Nitrate0fdltrite attfe
Ct
> 4
R Li.
_
_
Iva
r
Sk14
mm`
Ltt - Cp w 0
z �'
ss�
';
4wCL
cz
`
o CDCL
o
£i
t
G