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HomeMy WebLinkAboutWQ0018352_Residual Annual Report 2014_20150302. 9 0--r' I� 3 Town of Boiling Springs P.O. BOX 1014 BOILING SPRINGS, NC 28017 Telephone 704434-2357 Fax 704-434-2358 www.boilingspringsnc.net February 24, 2015 NCDENR-Division of Water Quality Aquifer Protection Section Land Application Unit 1636 Mail Service Center Raleigh, NC 27699-1636 RE: 2014 Annual Land Application of Residuals Town of Boiling Springs Permit # WQ0018352 To Whom It May Concern: Please find enclosed the original and (2) copies of all applicable forms and test results for the Annual Land Application Report for the Town of Boiling Springs. Aerobic digested biosolids continue to be land applied to permitted fields for beneficial reuse as a soil conditioner and a fertilizer supplement. Please give me a call if you have any questions or if additional information is needed at (704) 434-2357. Sincerely, '/;L c. Tom Hart Town Manager RECEIVEDIDENRI®WR MAR - 2 2015 cc: File Permitting Section Enclosures ,i A, ANNUAL LAND APPLICATION OF RESIDUALS 2014 ANNUAL REPORT TOWN OF BOILING SPRINGS Permit No. WQ0018352 CERTIFICATION FORM s ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit#: WQ0018352 County: Cleveland Year:. 2014 Facility Name (as shown on permit): Town of Boiling Springs Land Application Operator: Mike Gibert Phone: 704-434-2357 Land application of residuals as allowed by the permit occurred during the past calendar year? 0 Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A - Residuals Application Summaa.- Total number of application fields in the permit: 3 Total number of fields utilized for land application during the year: 2 Total amount of dry tons applied during the year for all application sites: 14.63 Total number of acres utilizes for land application during the year: 26.2 Part B - Annual Compiance Statement: Facility was compliant during calendar year 2014 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Resources. 0 Yes ❑ No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pH was adjusted, as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities). 7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Resources. 10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are . attached to include appropriate actions and remediations. 11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified in the permit. 12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application of residuals. Part C - Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Tom Hart Town Manager C. Permittee Name and Title (type or print) Signature of Permittee Date Signature of Preparer* Date Signature of Land Applier Date (if different from Permittee) (if different from Permittee and Preparer) * Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM WQ PERMIT #: WQ0018352 FACILITY NAME: Town of Boiling Springs PHONE: 704-434-2357 COUNTY: Cleveland OPERATOR: Mike Gibert FACILITY TYPE (please check one): Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C) Distribution and Marketing (complete Parts A, B, and C) Was the facility in operation during the past calendar year? Yes No --► If No skip parts A, B, C and certify form below Part A*: Part B*: Month Sources(s) (include NPDES # if applicable) Volume (dry tons) Recipient Information Amendment/ Bulking Agent Residual In Product Out Name(s) Volume (dry tons) Intended use(s) January NC 0071943 0 February NC 0071943 0 March NC 0071943 3.22 April NC 0071943 4.23 May NC 0071943 0 June NC 0071943 0 July NC 0071943 ~ 2.24 August NC 0071943 2.52 September NC 0071943 l 0 October NC 0071943 0 November NC 0071943 2.42 December NC 0071943 0 Total from FORM DMSDF (su)�. Totals: I Annual (dry tons):,.,.,, - 0" ' 14 63 0- _ 0; Amendment(s) used: Bulking Agent(s) used: * If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp) Part C: Facility was compliant during the past calendar year with all conditions of the land application permit '✓Yes (including but not limited to items 1-3 below) issued by the Division of Water Resources: No 0, If No, Explain in Narritive 1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached. 2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Resources. No contravention of Ground Water Quality Standards occurred at a monitoring well. "I certify, .under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." v Signature of Permittee Date Signature of Preparer** (if different from Permittee) **Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) rx445 Date DENR FORM DMSDF (12/2006) RESIDUALS SAMPLING FORM k ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: WQ0018352 Facility Name: Town of Boiling Springs Residual Source WQ # or NPDES #: NC 0071943 WWTP Name: Town of Boiling Springs WWTP Residual Analvsis Data Laboratory: 1) Pace Analytical Services 2) 3) 4) 5) Parameter (mg/kg) Conc. Limit m /k a Sample or Composite Date 8-20-14 Percent Solids (%) NA 2.3 Arsenic 75 <37.9 Cadmium 85 <3.8 Copper 4,300 179 Chromium NA <25 Lead 840 <19 Mercury 57 ND Molybdenum 75 <19 Nickel 420 <19 Selenium 100 <37.9 Zinc 7,500 523 Total Phosphorus NA 848 TKN NA 27700 Ammonia -Nitrogen NA <423 Nitrate and Nitrite NA 6600 a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 1,--,1 �z .,� Signature of Preparer * Date 0-1 *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T..1102 (26) DENR FORM RSSF (12/2006) tW� ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: WQ 0018352 Facility Name: Town of Boiling Springs Residual Source NPDES # or WQ#: WWTP Name: Residual Analvsis Data NC 0071943 Town of Boiling Springs WWTP Laboratory: 1) 2) 3) 4) 5) Pace Analytical Services Parameter (mg/kg) Sample or • •• Date 1 I • 1 ---------- Potassium ------------ ---------- ------------ ---------- "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Preparer *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) Date DENR FORM RSSF - B (12/2006) METALS FIELD LOADING SUMMARY olp LAND APPLICATION FIELD SUMMARY FORMS 1 ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON Facility Name: Town of Boiling Springs Land Owner: James Petty Operator: Mike Gibert Crop 1 Name: Fescue PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. WQ Permit #: WQ0018352 Field #: 1 Annual Dry Tons Applied: Site Site #: JPI Predominant Soil Series: Pacolet-Bethlehem Crop 1 Max. PAN: 250 Crop 2 Name: Acres Utilized: 9.84 Acres Permitted: 22.41 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: o L o Q Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry' Moist Precip. Past 24 Hrs. inches > q ' 0 a o w w * 7 _w -, CD w * w TKN mg/kg Z Y o E9 ao o w mg/kg Nitrate and Nitrite mg/kg PAN Applied (-lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 3-11-14 28600 2.7 0.32T.:.. NCO071943 Dry 0 S 0.5 0.3 27700 423 6600 =9,814'- . ; �NA, fescue 4-2-14 12900 2.5 0.137'.'- NCO071943 Dry 0 S 0.5 0.3 27700 423 6600 '4:099 � ." "Nk fescue 4-3-14 25600 2.7 ;0.193 .-. NCO071943 Dry 0 S 0.5 0.3 27700 423 6600 .8."-784 NA-: fescue 7-1-14 23400 2.3 6.228, NCO071943 Dry 0 S 0.5 0.3 27700 423 6600 :6.840v,` fescue 8-28-14 25200 2.4.,.�.0.256," NC0071943 Dry 0 S 0.5 0.3 27700 423 66007:686 _NA,' fescue ° `0.000- `-'0.000-_ - 000z o:000 0.000` 000. 0.0oo, : 0:000':- o:000a �. "0:000-.� 0.000.. Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form) TOTAi : = �a'.;, ��:o � .Ii5700 ;n.%- ,-- , As Cd Cu Cr Pb Hg Mo Ni Se Zn P 1, 3.7.223 ''.0:000, Lime Applied Annual lbs/acre 0.094". °, 0.327 6A21 `; ° °� 36 _::0.00,9'<; 0.049 ;0".058 ; 34 , 0.444`; 1.931 - 2.375.;. 1338 0:062„: � 0.215 "; 4.277 n/a ,0.047 ; 0.251 ::'0.298,.,' 267 , O.000;; 0.008 ;A.608 15 ; ;O:Q47r ` 0:252 '6 _ `0"209, n/a : 0.047:, ; 0.252 :A.299' � 374 .0 094 " 0.505 -�0.599' , 89 :;,1:298 : 5.898 , 7:196 2498,. ; 2 105 F :b " ` ,°,. . `.. , Date lbs/ac Prior Years Cumulative lbs/ac t>na/ia 3417 Current Cumulative lbs/ac Permitted C. P. L. R.**** Permit PAN Limit 1 st/2nd Crop`nj . 4 _r 2s "°I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation '77 ?tt ;2- ' 2-`'�— « **Volatilization Rate: Surface - 0.5. Iniection/Incomoration - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant LoadinL- Rate DENR FORM FSF (12/2006) `) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Town of Boiling Springs WWTP Total Dry Tons Applied (Annual): WQ0018352 Cation Exchange Capacity (non 503 only): Mike Gibert Owner: James Petty Predominant Soil Series: 9.84 Acres Permitted: Site #: JP 1 Paco let -Beth lehem Field #: 1 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kff. % Solids use Raw Percent 41: Sample or Com- posite Date 8-20-14 8-20-14 8-20-14 8-20-14 8-20-14 % Solids 2.3 2.3 2.3 2.3 2.3 Arsenic 37.9 37.9 37.9 37.9 37.9 Cadmium 3.8 3.8 3.8 - 3.8 3.8 Copper 179 179 179 179 179 Chromium 25 25 25 25 25 Lead 19 19 19 19 19 Mercury 0.2 0.2 0.2 0.2 0.2 Molyb- 19 19 19 19 19 Nickel 19 19 19 19 19 Selenium 37.9 37.9 37.9 37.9 37.9 Zinc 523 523 523 523 523 Total Phos- horus 848 848 848 848 848 Annual eavy Metal Field Loa din s Calculated in lbs/acre : Total DT/Ac./- App. Event 0.33 0.14 0.29 0.23 0.26 H 0 y Arsenic = 0.025 '-'A'010', -'. 022 ' ' :0:017 °,.0:0-19� " 0.000' ,. 0:000 ; "0:000 0:000 `0:000 0:000' 0.000 0:094� Cadmium '0.002 . '0.001- ' `.0.002 0.002 ' 0.002 0:000 .6.000. , 0:000 . 0.000 : 0:000 0:000. 0.000 '0 000 . Copper „� 0.1:17 -..0:049 - ..;0.1�05 ' 0.082 ; ,0 092��.' _O:a000�, �000��� 0:0,00�,: � 0`600 .�0:00.0��. "0:000�'� , 0:000�, .0:4'44°. Chromi ' `_0.016, ` ' A.00T '`0:015" 0.011 ° 0.013 ' ',0.000 0,000 - " 0 000: 6000 : " 0.000. 0-.000 : 0:000- '0:062 Lead ='0012 . . 0.005 A.011 0.009 „ 0:010 0.000 0.000 0000. 0.400 0.000 '. OA000 , '0,.000.�� . `0.047__ Mercury 0;:000 0:000 '�,0:000. ,M0:000 Fl _0.000 0:000 o "�0.000 0:000� 0.,000: `,0.000 A:00.0 0.000' _.0000 Molyb- �0:012, 0.005 4011 0.009 -0.010 0.000 0.000' 0.000' 0.000demim a ' .0.000 0:000 0.00.0 0047 Nickel `; 0:012 �. A:005 � 0.011. ',n0:009 0.010 0.00�0, . A.00�0� .. 0,�000., . "0�000, _ .�;0:000 _ . �ro0.000 0:0W ' O:047� ; Selenium .0.025' ,�0:010 `,0:022 "0:01:7. 0.019 a000 0:000 �A:000 0:000�,� 0.00,0'�. "0.000, 0.000` �0:094. Zinc 0342 :0.143 0.106 0.238 0:268 ' 0.000 "0.000, 0.000 0.000 '-O:000 0:000 - p.000` .1.298 `. Total Phos- horus it 0;555 , 0.232 1 0:497 0387 O' 34 �_0:000 0.000 0 000' °0'000 ' 0.600 0.000 0:000 - 2.105 I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Town of Boiling Springs WQ Permit #: WQ0018352 Field #: 2 Acres Utilized: 16.36 Land Owner: James Petty Operator: Mike Gibert Crop 1 Name: Fescue Annual Dry Tons Applied: 2.4169 Site #: JP2 Acres Permitted: Predominant Soil Series: Pacolet-Bethlehem Cation Exchange Capacity (non 503): Crop 1 Max. PAN: 250 Crop 2 Name: Crop 2 Max. PAN: o � Q Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry' Moist) Precip. Past 24 Hrs. inches a 4.6 CD 'a 0 R * o w * �. w Q E. N' * K Z TKN mg/kg Z % o B o R. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop I Crop 2 Crop 1 Crop 2 11-12-14 25200 2.3 -0.148 NCO071943 Dry 0 S 0.5 0.3 27700 423 6600 4.430 NA fescue 0.000 0.000 . 0.000 0.000 0.000 " '0.000- 0.000 0.0.00 0.000 0.000 0.000 `0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000. 0.000, ' A000 0.000 0.000 .0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALSI 01 25200 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 4.430 0.000 Lime Applied Annual lbs/acre 0.011 0.001 0.053 0:007 0.006 ` 0.000 0.006 . 0.006 0.011 0.155. . 0.251 Date Ibs/ac Prior Years Cumulative lbs/ac 0.1 0.019 0.522 0.008 0.091 0.001 0.091 0.091 0.181 1.31 Current Cumulative lbs/ac 0.111 0.020 0.575 0.015 0.097 0.001 0.097 0.097 0.192 1.465, Permitted C. P. L. R.**** 36 34 1338 n/a 1 267 1 15 1 n/a 1 374 89 2498 Permit PAN Limit 1 st/2nd Crop 250. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier Date *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Iniection/Incorporation - 1.0 *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant LoadinLy Rate DENR FORM FSF (12/2006) Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Town of Boiling Springs Total Dry Tons Applied (Annual): Permit #: Operator: Acres Used: WQ0018352 Mike Gibert Owner: 9.84 Acres Permitted: Cation Exchange Capacity (non 503 only): James Petty Predominant Soil Series: Pacolet-Bethlehem Site #: JP2 Field #: Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample 1 2 3 4 5 6 7 8 9 10 1 12 or Com- posite Date 8-20-14 % Solids 2.3 Arsenic 37.9 Cadmium 3.8 Copper 179 Chromium.25 Lead 19 Mercury 0.2 Molyb- 19 denum Nickel 19 Selenium 37.9 Zinc 523 Total Phos- 848 phorus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". - z Signature of sand Applier Date RE: Residuals Generated But Not Land Applied The Town of Boiling Springs WWTP land applied 14.63 dry tons of biosolids to permitted fields in 2014. The remainder of the biosolids, were hauled to the Cliffside Sanitary District WWTP permit # NC0004405 during periods of wet weather. These biosolids were introduced at the headworks of the plant and treated through the facilities processes. 1 RESIDUALS ANALYSIS LAB SHEETS r-g,o i t_.� • / WIN ter- z�raw. .ate mac sac r TC L P LABORATORY SHEETS Inalytical wwpamiabs.com ANALYTICAL RESULTS Project: TCLP Sludge Analysis Pace Project No.: 92214172 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: TCLP Sludge Lab ID: 92214172001 Collected: 08/20/14 08:30 Received: 08/20/14 14:34 Matrix: Solid Results reported on a "dry -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides, TCLP Analytical Method: EPA 8081 Preparation Method: EPA 351.0 Leachate Method/Date: EPA 1311; 08/21/14 17:00 gamma-BHC (Lindane) ND ug/L 0.50 1 08/22/14 10:27 08/26/14 04:42 58-89-9 Chlordane (Technical) ND ug/L 3.0 1 08/22/14 10:27 08/26/14 04:42 57-74-9 Endrin ND ug/L 0.50 1 08/22/14 10:27 08/26/14 04:42 72-20-8 Heptachlor epoxide ND ug/L 0.50 1 08/22/14 10:27 08/26/14 04:42 1024-57-3 Methoxychlor ND ug/L 1000 1 08/22/14 10:27 08/26/14 04:42 72-43-5 Toxaphene ND ug/L 3.0 1 08/22/14 10:27 08/26/14 04:42 8001-35-2 Surrogates Decachlorobiphenyl (S) 65 % 10-138 1 08/22/14 10:27 08126/14 04:42 2051-24-3 Tetrachloro-m-xylene (S) . 60 % 10-110 1 08/22/14 10:27 08/26/14 04:42 877-09-8 8151 Chlorinate Herbicide TCLP Analytical Method: EPA 8151 Preparation Method: EPA 3510 2,4-D ND mg/L 0.44 1 08/28/14 08:20 08/29/14 02:12 94-75-7 2,4,5-TP (Silvex) ND mg/L 0.44 1 08/28/14 08:20 08/29/14 02:12 93-72-1 Surrogates 2,4-DCAA (S) 91 % 42-142 1 08/28/14 08:20 08/29/14 02:12 19719-28-9 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 6510 mg/kg 379 1 08/22/14 19:20 08/27/14 23:42 7429-90-5 Arsenic ND mg/kg 37.9 1 08/22/14 19:20 08/2911413:44 7440-38-2 Cadmium ND mg/kg 3.8 1 08/22/14 19:20 08/27/14 23:42 7440-43-9 Calcium 31500 mg/kg 379 1 08/22/14 19:20 08/27/14 23:42 7440-70-2 Copper 179 mg/kg 19.0 1 08/22/14 19:20 08/27/14 23:42 7440-50-8. Lead ND mg/kg 19.0 1 08/22/14 19:20 08/27/14 ?3:42 7439-92-1 Magnesium 1760 mg/kg 379 1 08/22/14 19:20 08/27/14 23:42 7439-95-4 Molybdenum ND mg/kg 19.0 1 08/22/14 19:20 08/27/14 23:42 7439-98-7 Nickel ND mg/kg 19.0 1 08/22/14 19:20 08/27/14 23:42 7440-02-0 Potassium ND mg/kg 19000 1 08/22/14 19:20 08/27/14 23:42 7440-09-7 Selenium ND mg/kg 37.9 1 08/22/14 19:20 08/27/14 23:42 7782-49-2 Sodium ND mg/kg 19000 1 08/22/14 19:20 08/27/14 23:42 7440-23-5 Zinc 523- mg/kg 37.9 1 08/22/14 19:20 08/27/14 23:42 7440-66-6 6010 MET ICP, TCLP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Leachate Method/Date: EPA 1311: 08/25/14 20:00 Arsenic ND mg/L 0.050 1 08/26/14 15:00 08/26/14 22:50 7440-38-2 Barium 0.40 mg/L 0.25 1 08/26/14 15:00 08/26/14 22:50 7440-39-3 Cadmium ND mg/L 0.0050 1 08/26/14 15:00 08/26/14 22:50 7440-43-9 Chromium ND mg/L 0.025 1 08/26/14 15:00 08/26/14 22:50 7440-47-3 Lead ND mg/L 0.025 1 08/26/14 15:00 08/26/14 22:50 7439-92-1 Selenium ND mg/L 0.10 1 08/26/14 15:00 08/27/14 14:06 7782-49-2 Silver ND mg/L 0.025 1 08/26/14 15:00 08/26/14 22:50 7440-22-4 7470 Mercury, TCLP Analytical Method: EPA 7470 Preparation Method: EPA 7470 Leachate Method/Date: EPA 1311; 08/25/14 20:00 Mercury ND ug/L 0.20 1 08/26/1415:30 08/27/14 11:55 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/04/2014 03:33 PM without the written consent of Pace Analytical Services, Inc.. Page 4 of 27 .y aceAnalytical f www.pacelabs.com j ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: TCLP Sludge Analysis Pace Project No.: 92214172 Sample: TCLP Sludge Lab ID: 92214172001 Collected: 08/20/14 08:30 Received: 08/20/14 14:34 Matrix: Solid Results reported on a "dry -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 7471 Mercury Analytical Method: EPA7471 Preparation Method: EPA7471 Mercury 0.18 mg/kg 0.17 1 08/26/14 13:15 08/26/14 16:40 7439-97-6 8270 MSSV TCLP Sep Funnel Analytical Method: EPA 8270 Preparation Method: EPA 3510 Leachate Method/Date: EPA 1311; 08/21/14 17:00 1,4-Dichlorobenzene ND ug/L 50.0 1 08/22/14 10:27 08/24/14 23:03 106-46-7 2,4-Dinitrotoluene ND ug/L 50.0 1 08/22/14 10:27 08/24/14 23:03 121-14-2 Hexachlorobenzene ND ug/L 50.0 1 08/22/14 10:27 08/24/14 23:03 118-74-1 Hexachloroethane ND ug/L 50.0 1 08/22/14 10:27 08/24/14 23:03 67-72-1 2-Methylphenol(o-Cresol) ND ug/L 50.0 1 08/22/14 10:27 08/24/14 23:03 95-48-7 3&4-Methylphen6l(m&p Cresol) ND ug/L 50.0 1 08/22/14 10:27 08/24/14 23:03 Nitrobenzene ND. ug/L 50.0 1 08/22/14 10:27 08/24/14 23:03 98-95-3 Pentachlorophenol ND ug/L 100 1 08/22/14 10:27 08/24/14 23:03 87-86-5 Pyridine ND ug/L 50.0 1 08%22/14 10:27 08/24/14 23:03 110-86-1 2,4,5-Trichlorophenol ND ug/L 50.0 1 08/22/14 10:27 08/24/14 23:03 95-95-4 2,4,6-Trichlorophenol ND ug/L 50.0 1 08/22/14 10:27 08/24/14 23:03 88-06-2 Surrogates Nitrobenzene-d5 (S) 54 % 12-102 1 08/22/14 10:27 08/24/14 23:03 4165-60-0 2-Fluorobiphenyl (S) 73 % 13-107 1 08/22/14 10:27 08/24/14 23:03 321-60-8 Terphenyl-d14(S) 80 % 21-132 1 08/22/14 10:27 08/24/14 23:03 1718-51-0 Phenol-d6 (S) 21 % 10-110 1 08/22/14 10:27 08/24/14 23:03 13127-88-3 2-Fluorophenol (S) 35 % 10-110 1 08/22/14 10:27 08/24/14 23:03 367-12-4 2,4,6-Tribromophenol (S) 73 % 27-108 1 08/22/14 10:27 08/24/14 23:03 118-79-6 8260 MSV TCLP Analytical Method: EPA 8260 Leachate Method/Date: EPA 1311; 08/21/14 14:30 4 Benzene ND ug/L 5.0 1 09/04/14 06:43 71-43-2 2-Butanone (MEK) ND ug/L 10.0 1 09/04/14 06:43 78-93-3 Carbon tetrachloride ND ug/L 5.0 1 09/04/14 06:43 56-23-5 Chlorobenzene ND ug/L 5.0 1 09/04/14 06:43 108-90-7 Chloroform ND ug/L 5.0 1 09/04/14 06:43 67-66-3- 1,4-Dichlorobenzene ND ug/L 5.0 1 09/04/14 06:43 106-46-7 1,2-Dichloroethane ND ug/L 5.0 1 09/04/14 06:43 107-06-2 1,1-Dichloroethene ND ug/L 5.0 1 09/04/14 06:43 75-35-4 Hexachloro-1,3-butadiene ND ug/L 5.0 1 09/04/14 06:43 87-68-3 Tetrachloroethene ND ug/L 5.0 1 09/04/14 06:43 127-18-4 Trichloroethene ND ug/L 5.0 1 09/04/14 06:43 79-01-6 Vinyl chloride ND ug/L 5.0 1 09/04/14 06:43 75-01-4 Surrogates 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 09/04/14 06:43 17060-07-0 Toluene-d8 (S) 99 % 67-135 1 09/04/14 06:43 2037-26-5 4-Bromofluorobenzene (S) 101 % 70-130 1 09/04/14 06:43 460-00-4 Percent Moisture -Analytical Method: ASTM D2974-87 Percent Moisture 97.7 % 0.10 1 08/28/14 08:48 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/04/2014 03:33 PM without the written consent of Pace Analytical Services, Inc.. Page 5 of 27 Analytical mmpacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 1o0 Huntersville, NC 28078 (704)875-9092 Project: TCLP Sludge Analysis Pace Project No.: 92214172 Sample: TCLP Sludge Lab ID: 92214172001 Collected: 08/20/14 08:30 Received: 08/20/14 14:34 Matrix: Solid Results reported on a "dry -weight' basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No 254OG Total Percent Solids Analytical Method: SM 254OG Total Solids 2.3 % 0.000010 1 08/27/14 14:12 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 7.1 Std. Units 0.10 1 08/22/14 12:17 Plant Available Nitrogen Analytical Method: SM 2710B Plant Available Nitrogen 14900 mg/kg 0.12 1 09/03/14 17:23 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/kg 423 1 08/28/14 15:39 7664-41-7 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Nitrogen, Kjeldahl, Total 27700 mg/kg 1570 1 09/02/14 11:34 7727-37-9 353.2 Nitrogen, NO2iNO3 Analytical Method: EPA 353.2 Nitrogen, Nitrate Nitrogen, Nitrite 6600 mg/kg 86.1 1 08/26/14 15:09 Nitrogen, NO2 plus NO3 ND mg/kg 6600 mg/kg 43.1 1 08/26/14 15:09 86.1 1 08/26/14 15:09 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Phosphorus 848 mg/kg 84.6 1 08/29/14 13:55 7723-14-0 Date: 09/04/2014 03:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qual N2 Page 6 of 27 „V `44 HA9 -d F-CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUh4ENT, All relevant Fields mint be completed accurately- -PaceA j i www.paeeiabs.cam Page: °f Section f3 Section C t� y , n Section A Invoice InFonnallon: 1 4 � � ,A' Required Project Informxliorr, i Required Client Information: tantrnn. Repor9To „„........ ,r5"1`_' i;;�^%'?Y��itsie�: At ... ^..� ::•..,; be'� L7 : r G1�1i4�1'OFiY;AGENGY:�t%„,<::'. "`,';";'�`•'` r � Company Name: RE Copy To: _ S' • "�}/ { DRINKING WATER cadre pp nj j . `; j JJ n r , NPDES i GROUhtD N ATER , }� 1. UST 1 W RCIZA Tm'- --._..--------.�._. OTHCR t >Z.3, t d _ l"9 a. N., j,K ..73 "c C.ti' Par:�Quata ¢ Purchase OMer No fYeferenca: Emwl T ,�y ro d d' � g"[,QCa-lion 7-!Pow Project F:SI Project Name: Phone: Pax:ParaProgke,Y: ` Protect Number. Requested Due DateITAT: ;3 YIN ':.Requisteti;!1eia6ysis:filterel( ,j,. >::; ` Section D Matrix Codes 5 a Preserv8Uves _ _ COLLECTED ti tF%I ,C4Jt. 0 0 •_ RequiredGlient Lilerma�ai � Y'-.d � 7 ”. . Drinking Water DINL: 4 Weter `NT U cae<, o.ttE. carxrosrr= r'"' z,; -, , z WastaW'aier WVt m %Thg7 etacwoaao r - PrOiloduct P I Kzy j/J j r✓ SoWSolid SL K t°iz " o i SAMPLE ID Wipa OL v � a3 WP e, z f .V .� (A-Z. rkI-1 A Alr AR 0 9C7 Samplo IDs MUST BE UNIQUE Tissue TS O ° 'N` J v z a Other 0'1 o O c 0 N, z c5 w Pace project No.1 Lab I.D. w2 in DATE TIME DATE TIME m a = S Z Z fir, y ., .. J 1 REWNCIUI5HEC1.6Y7AFFILWTI4N . DATE• TIME:::, ACCEPTED`SYl;AFILIATtt)N iFA7E' SIh1E. . SAMPLE CONDITIONS � S(`� ++f/`��''� a. ..--""'�,• ; c��G,r`^'c' 1 r" �'"' l �y,�/'�'j' /� /W� vyD *�/ i j o�/�,r� d'""....+' i ._� i.. i�. .w"". ...•..mow �} Y ti ".�"',r.`( l 8 L°' Y/ !s� 7'-f 4 "T t� rAa y — w ( :SAMPLERNAIVSE'ANaSIGNATURE ` �. a ci`z' Z ORIGINAL lam. - . ... t9, .n PRINT Name of SAMPLER: �� ��„„;,, ti , � a r m � E .. i-.."�11 DATE Signed z�-�,c,.�r!'%,r t- rr v ra SIGNATURE of SAMPLER: <- Y� .�r� IMMIDDtYY)' — FF.ALL-0-020rev.07, 15-itfay-2007 Important rdo;a: By signing IMz 101m you a+u acca )fing Paces NET 3n dTy payment torn and agrea:ng [01a4s eY�arge;s ni t.5k. per merrih to arty rrvntces r<a1=F d wilh7n 3U +ays. PATHOGEN & VECTOR ATTRACTION REDUCTION FORMS • ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (503 Rules) Facility Name: Town of Boiling Springs WQ Permit Number: WQ0018352 WWTP Name: Town of Boiling Springs WWTP NPDES Number: NCO071943 Monitoring Period: From 1/1/2014 To 12/31/2014 Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed: Class A: Alternative 1 ❑ Alternative 2 ❑ Alternative 3 ❑ Alternative 4 ❑ Alternative 5 ❑ Alternative 6 ❑ If applica le to a ternative pelrform d (Class I only) indic to "Prot s to Furtl er Reduc4 Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray ❑ Gamma Ray ❑ Pasteurization ❑ Class B: Alternative 1 ❑x Alternative 2 ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying❑ Composting ❑ Aerobic Digestion ❑x Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density Number of Excee- dences Frequency of Analysis Sample Type Analytical Tech - ni ue Minimum Geo. Mean Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN <1266 1486 !27140 MPN/g 0 7/year Grab SM92210E CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed: Alt.1 (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. 02 uptake) ❑x Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ Alt. 8 (Drying -Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) ❑ No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Mike Gibert Mike Gibert Public Works Director Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print) 1• � 7Ll - � -z4-r s Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) ( r Y Annual Pathogen and Vector Reduction Summary Town of Boiling Springs permit # WQ0018352 Fecal Coliform - Class B There were seven (7) test results provided by Pace Analytical Services in Huntersville. The calculated Geo Mean for the Fecal Coliform samples was 1486 MPN/g. Vector Attraction Reduction Option 4 - Sour test results are reported in the attached data showing seven (7) test results at 0.12 mg Oxygen/g/hr or less for Specific Oxygen Uptake Rate. End temperature for each test result was under 30 Degrees Celsius and the percent solids were under 2% for each result. '_1 , -- Analytical Results Pace Analytical 9800 Kincey Suite 100 Huntersville NC 28078 Entered 8/28/2014 Reported: 9/2/2014 For: 92215108 Aerobic Dig 8/27 Sample ID Parameter Cust ID Result Units Method Date Analyzed Analyst 140828-10.1 % Solids 001 1.52 % SM254013- 8/28/14 WL 140828-10.1 Fecal Coliform MTF 001 16 MPN/g SM9221 CE- 8/28/14 WL 140828-10.1 Geometric Mean 001, 1486 MPN/g dry wt. basis 9/2/14 CL-... 140828-10.2 % Solids 602 1.58 % SM25406- 8/28/14 WL 140828-10.2 Fecal Coliform MTF 002 <1266 MPN/g SM9221 CE- 8/28/14 WL 140828-10.3 % Solids 003 1.46 % SM254013- 8/28114 WL 140828-10.3 Fecal Coliform MTF 003 2740 MPN/g SM9221 CE- 8/28/14 WL 140828-10.4 % Solids 004 1.37 % SM254013- 8/28/14 WL 140828-10.4 Fecal Coliform MTF 004 1460 MPN/g SM9221 CE- 8/28/14 WL 140828-10.5 % Solids 005 1.49 % SM254013- 8/28/14 WL 140828-10.5 Fecal Coliform MTF 005 1342 MPN/g SM9221 CE- 8/28/14 WL 140828-10.6 %° Solids 006 1.55 % SM254013- 8/28/14 WL 140828-10.6 Fecal Coliform MTF 006 1290 MPN/g 'SM9221 CE- 8/28/14 WL 140828-10.7 % Solids 007 1.44 % SM2540B- 8/28/14 WL 140828-10.7 Fecal Coliform MTF 007 1389 MPN/g SM9221 CE- 8/28/14 WL Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, EPA NCO0909 P.O. Box 228 * Statesville, North Carolina 28687 * 704/872/4697 Page 11 of 11 Specific Oxygen Uptake Rate SOUR Facility Name Biosolids Permit Number Date Digester Temperature Sampling Date/Time Sampled By Analysis DatelTime Analyzed By Sample Volume Total Solids Beginning Temperature End Temperature Time Dissolved Oxygen Level Town of Boiling S rin s,NC WQ0018352 82714 26.1 8 27 14 1000 TERRY 8 27 14 1001 TERRY 1000 1.52 26.1 26 (minutes) m /1) 0 1 6.97 2 6.94 3 6.93 4 6.90 5 6.88 6 6.87 7 6.85 8 6.82 9 6.80 10 6.79 11 6.78 12 6.76 13 6.74 14 6.72 15 6.71 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: 0.0 7.0 1.0 milliliters Yo Dry Solids Degrees Celsius Degrees Celsius 1.12 mg Oxygen/hr 0.07 mg Oxygen/g/hr 26 degrees Celsius 0.746215397 Temperature Corrected Specific Oxygen Uptake Rate: 0.06 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Cl) 2 3 4 5 6 7 Circle Test # Specific Oxygen Uptake Rate SOUR Facility Name Biosolids Permit Number Date Digester Temperature Sampling Date/Time Sampled By Analysis Date/Time Analyzed By Sample Volume Total Solids Beginning Temperature End Temperature Time Dissolved Oxygen Level (minutes) (m /I) 0 7.02 1 7.00 2 6.97 3 6.97 4 6.95 5 6.93 6 6.90 7 6.87 8 6.85 9 6.82 10 6.80 11 6.78 12 6.76 13 6.75 14 6.73 15 6.70 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Town of Boiling S rin s,NC WO0018352 82714 26.1 8 27 14 1015 TERRY 8 27 14 1016 TERRY 1000 1.58 26.1 25.9 0.0 7.0 1.0 milliliters % Dry Solids degrees Celsius degrees Celsius 1.30 mg Oxygen/hr 0.08 mg Oxygen/g/hr 26 degrees Celsius 0.746215397 Temperature Corrected Specific Oxygen Uptake Rate: 0.06 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. 1 20 3 4 5 6 7 Circle Test # Specific Oxygen Uptake Rate SOUR Facility Name Biosolids Permit Number Date Digester Temperature Sampling Date/Time Sampled By Analysis Date/Time Analyzed By Sample Volume Total Solids Beginning Temperature End Temperature Time Dissolved Oxygen Level (minutes) m /I) 0 7.01 1 6.99 2 6.95 3 6.91 4 6.89 5 6.85 6 6.83 7 6.80 8 6.78 9 6.75 10 6.71 11 6.71 12 6.68 13 6.66 14 6.63 15 5.99 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Town of Boiling S rin s,NC WO0018352 82714 26.1 8 27 14 1030 TERRY 8 27 14 1031 TERRY 1000 1.46 26.1 26.1 0.0 7.1 0.8 milliliters Yo Dry Solids Degrees Celsius Degrees Celsius 2.42 mg Oxygen/hr 0.17 mg Oxygen/g/hr 26 degrees Celsius 0.746215397 Temperature Corrected Specific Oxygen Uptake Rate: 0.12 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. 1 2(1 4 5 6 7 Circle Test # 0 , , 1 Specific Oxygen Uptake Rate SOUR Facility Name Biosolids Permit Number Date Digester Temperature Sampling Date/Time Sampled By Analysis Date/Time Analyzed By Sample Volume Total Solids Beginning Temperature End Temperature Time Dissolved Oxygen level (minutes) m /1) 0 6.97 1 6.93 2 6.89 3 6.85 4 6.85 5 6.82 6 6.80 7 6.78 8 6.75 9 6.73 10 6.71 11 6.69 12 6.65 13 6.64 14 6.61 15 5.98 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Town of Boiling Sprin s,NC WO0018352 82714 26.1 8 27 14 1045 TERRY 827141046 TERRY 1000 1.37 26 26 0.0 7.0 0.8 milliliters Yo Dry Solids Degrees Celsius legrees Celsius 2.25 mg Oxygen/hr 0.16 mg Oxygen/g/hr 26 degrees Celsius 0.746215397 Temperature Corrected Specific Oxygen Uptake Rate: 0.12 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. 1 2 3 g 5 6 7 Circle Test # Specific Oxygen Uptake Rate SOUR Facility Name Biosolids Permit Number Date. Digester Temperature Sampling Date/Time Sampled By Analysis Date/Time Analyzed By Sample Volume Total Solids Beginning Temperature End Temperature Time Dissolved Oxygen Level (minutes) (m /I 0 6.97 1 6.93 2 6.90 3 6.90 4 6.87 5 6.85 6 6.82 7 6.80 8 6.77 9 6.75 10 6.72 11 6.70 12 6.68 13 6.66 14 6.65 15 6.63 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Town of Boiling Sprin s,NC WO0018352 82714 26.1 827141100 TERRY 8 27 14 1101 TERRY 1000 1.49 26.1 26 0.0 7.0 1.0 milliliters Yo Dry Solids Degrees Celsius legrees Celsius 1.36 mg Oxygen/hr 0.09 mg Oxygen/g/hr 26 degrees Celsius 0.746215397 Temperature Corrected Specific Oxygen Uptake Rate: 0.07 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. 1 2 3 4CY 6 7 Circle Test # Specific Oxygen Uptake Rate SOUR Facility Name Biosolids Permit Number Date Digester Temperature Sampling Date/Time Sampled By Analysis Date/Time Analyzed By Sample Volume Total Solids Beginning Temperature End Temperature Time Dissolved Oxygen Level (minutes) m /I 0 6.95 1 6.93 2 6.90 3 6.88 4 6.87 5 6.85 6 6.81 7 6.79 8 6.76 9 6.73 10 6.70 11 6.67 12 6.64 13 6.61 14 6.58 15 6.56 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Town of Boiling Sprin s,NC WO0018352 82714 25.9 8 27 14 1115 TERRY 8 27 15 1116 TERRY 1000 1.55 25.9 25.8 0.0 7.0 1.0 milliliters % Dry Solids degrees Celsius degrees Celsius 1.60 mg Oxygen/hr 0.10 mg Oxygen/g/hr 26 degrees Celsius 0.746215397 Temperature Corrected Specific Oxygen Uptake Rate: 0.08 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. 1 2 3 4 5 6` 7 Circle Test # t 4 , 1 Specific Oxygen Uptake Rate SOUR Facility Name Biosolids Permit Number Date Digester Temperature Sampling Date/Time Sampled By Analysis Date/Time Analyzed By Sample Volume Total Solids Beginning Temperature End Temperature Time Dissolved Oxygen Level Town of Boiling Sprin s,NC WO0018352 82714 25.9 8 27 14 1130 TERRY 8 27 14 1131 TERRY 1000 1.44 25.9 25.8 (minutes) (m /I 0 6.93 1 6.90 2 6.88 3 6.85 4 6.81 5 6.78 6 6.75 7 6.71 8 6.68 9 6.65 10 6.62 11 6.60 12 6.57 13 6.55 14 6.51 15 6.49 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: milliliters % Dry Solids degrees Celsius degrees Celsius 1.80 mg Oxygen/hr 0.13 mg Oxygen/g/hr 26 degrees Celsius 0.746215397 Temperature Corrected Specific Oxygen Uptake Rate:1 0.09 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. 1 2 3 4 5 6 Circle Test # A" ( )� y SOIL ANALYSIS REPORT go A&L EasternLaboratories 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-6446 www,aleastern.com l+All A\IAI V JUDmlttea t3y: IAW I r'IA UAI.AL -- I- Client: Grower: Report No: 14-241-0575 PACE ANALYTICAL CHARLOTTE (for 92215122 Cust No: 05755 Tabitha Dacal) SAMPLING 8/26 Date Printed: 09/02/2014 TABITHA M DACAL Date Received : 08/29/2014 9800 KINCEY AVE - STE 100 Date Analysis : 09/02/2014 HUNTERSVILLE NC 28078 Page : 1 of 2 PO: TMD13658 Lab Number: 07815 Field Id : Sample Id: JOHN PETTY Test Results SOIL TEST RATINGS Calculated Caton Exchange Capacity e Medium 0' .. Soil pH 5.5 10.2 meq/100g Buffer pH 6.67 Phosphorus (P) 171 ppm M. :•,• w-F. raj m Calculated Cation' Saturation Potassium (K) Calcium (Ca) Magnesium (Mg) 365 ppm 1000 ppm 176 ppm %K 9.2 %Ca 49.0 %Mg 14.4 %H 25.7 Hmeq 2.6 %Na 1.4 Sulfur (S) 24 ppm Boron (B) Copper (Cu) 0.9 ppm 3.2 ppm Iron (Fe) 125 ppm _ ff-swimm § Winn -WE Manganese (Mn) 13 ppm K:,MgRatio a Zinc (Zn) 8.4 ppm 0.64 Sodium (Na) 33 ppm Ca : Mg Ratio' Soluble Salts 3.40 Organic Matter 6.9 % ENR 150 Nitrate Nitrogen SOIL FERTILITY GUIDELINES ram.,.. • l \Alf INPW1 Rec Units: LB/1000 SF jibs) LIME (tons) N PQ 05 K 20 Mg ' S B Cu Mn Zn Fe 71 3.5 0 0 0 0.23 0 0 1 0.05 1 0 0 Crop : Rec Units: Comment: Analysis prepared by: A&L Eastern Laboratories, Inc. Page 5 of 6 Pauric McGroary A &L Eastern Laboratories Llk! J 7621' Whitepine Road Richmond, Virginia 23237 (804) 7434401 Fax (804) 271-6446 www.aleastem.com 1uomltrea tiy: IAbl I HA UAGAL VIZIZU14 JUIL ANALT010 Client: Grower: Report No: 14-241-0575 PACE ANALYTICAL CHARLOTTE (for ' 92215122 Cust No: 05755 Tabitha Dacal) SAMPLING 8/26 Date Printed: 09/02/2014 TABITHA M DACAL Date Received : 08/29/2014 9800 KINCEY AVE - STE 100 Date Analysis : 09/02/2014 HUNTERSVILLE NC 28078 Page : 2 of 2 _ PO: TMD13658 , Lab Number: 07815 Field Id: Sample Id: JOHN PETTY SUGGD_�FERTILIZATION._PROGRAM�: First A' licationSecond PP Application; : Third Applicatiop; . " .. - Fourth Application Mob Ft. ­. Ft`; Fertilizes #lAOOO;Sq Ft:: :Fertilizer #/1000.Sq. Ft.' Fert)lizer : #/1000 Sq. Ft.. Fertilizer. 6 21-0-0 6 21-0-0 6 21-0-0 Comments: Lawn(New) Limestone application is targeted to bring soil pH to 6.2. Apply the amount of lime recommended in first page to raise pH For existing lawns, lime applications should NOT exceed 50 pounds per 1000 sq. feet per application. Split and apply every 4 to 6 month until the recommended amount is completed. --I -• Lime is insoluble in water thus move very slowly downward in the soil to raise the pH: For new Lawn,, the best result -is -to broadcast all the recommended lime over the surface, incorporate and mix 6 inches into the soil. If lime is not incorporated and mixed into the soil, lime application should NOT exceed 50 pounds per 1000 sq. feet per application. Split and apply every 4 to 6 month until the recommended amount is completed. • The amount of fertilizer recommended on the first page is the total amount needed for the entire growing season. Split into 3-4 applications to keep the lawn green and prevent fertilizer loss. You should not apply more than 0.7 Ibs of soluble nitrogen per 1000 square feet in a 30 day period. Or more than 0.9 Ibs of nitrogen per 1000 square feet if you are using a slow or controlled release product in a 30 day per)od.Custom blend is best to meet exactly the requirement, if this is impossible, the above specific fertilizer application is a general guideline, if the specified grades can not be found, replace with fertilizer having similar N:P:K ratio. The best time to apply fertilizer for cool season grass (bluegrass, fescue, ryegrass) is in the Fall when the grass is growing. For Mid -Atlantic region the time is from late August to November. For Northeast region the time is from mid August to October. Fall application should start as soon as the day time high temperature is below 80-85F, apply with the interval of one month. If you start application late in the Fall and do not finish all three applications, repeat the same applications in the Fall of next year. Spring application is recommended when exceptional fertilizer loss due to heavy spring rain leaching and the grasses look pale green. Spring application can start as soon as the grass starts to grow in April. In the case of exceptional warm spring, the application can be made earlier. • For a more in depth explanation of the soil test and recommendations, go to our website www.aleastern.com and select the "Lawn and Garden" tab at the top of home page. Under the "How to Understand a Soil Test Report". header you will find the _link to the article "Soil Test Report & Fertilizer Recommendation Explained". Page 6 of 6 Analysis prepared by: A&L Eastern Laboratories, Inc. Pauric McGroary