NCS000223_MONITORING INFO_19941207

STORMWATER DIVISION CODING SHEET
PERMIT NO.
�JC
DOC TYPE
❑FINAL PERMIT
`�. MONITORING INFO
❑ APPLICATION
❑ COMPLIANCE
❑ OTHER
DOC DATE
❑ laqq,
YYYYMMDD

r-r
I. Facility Information:
Annual Pollutant 'Analysis Monitoring Requirement
Reporting Form A
(Revised June 1990)
NPDES Permit No: Discharge (Pipe) NO:
Facility Name: Class: County:
Person(s) Collecting Samples:
Status of facility wastewater treatment operation
If no, explain briefly:
Analytical Laboratory:
Year:
on day of sampling: typical: Yes No
iI. Samplin
for main sample 1 grab sample for purgeable traction
Page 1 of 9
Date Sampled: (composite sample) Corresponding sample taken for toxicity testing:
Sampling begun (date, time): Yes
Sampling finished (date, time): No
Date andiime sampled (grab sample):
Instructions
The purpose of this document and the accompanying memo is to standardize the sampling, analysis and reporting procedures to be used
for the Annual Pollutant Analysis Monitoring (APAM) Requirement as described in the permit.
Sampling 0r.,k rtlpre C-./-;PYQht
1 - Take a sample from the final effluent during . Collect a grab sample for the volatile
organic fraction when collection of the 241
1
0
ur�anposrtt? sample is completed. Follow any other sampling instructions provided by the laboratory
performing the analysis. 1, f^
2 - Indicate in the space provided at the top of this page whether a corresponding sample for toxicity testing was taken.
3 - Make note of any unusual wastewater treatment operating conditions occurring on the day of sampling in the space provided on form.
Analysis 0
4 - Analyze the effluent for pollutants listed on the APAM form, including those to be identified and approximately quantif� undethe 10
significant peaks rule, using appropriate EPA -approved methods for each of the analytic fractions. Other analytical methods ca a subAlituted
only with prior, written approval of the Director of the Division of Environmental Management (DEM). Read and distribute totthe lap*ratory
performing the analysis the accompanying memo (Tedder, October 1990) clarifying analytical requirements. .J
5 • Identify chemicals to be analyzed for according to the 10 significant peaks rule (as described in item 2 of the Annual Pgbtant imalysis
Monitoring Requirement in the permit) using a GCIMS library search. Tentative identification is all that is required; confirmatm by srtandard
injection is not necessary. Estimate the concentration of each based on an internal standard having the closest retention time.
Reporting
6 - Ouantitation Limit Targets that should be met are listed on this Revised APAM Reporting Form A. Report the use of any higher quantita-
tion limit and an explanation as to why the listed quantization limit target could not be met. Examples of acceptable reasons for not meeting
a quantization limit target could be high background concentrations in a sample, or the necessity for sample fraction dilution to bring a chemical
to within a quantifiable concentration. List any quantitation limit differtent (whether higher or lower] from the target in the column provided
for this purpose.
7 - If a chemical is found to be below the quantitation limit, report the concentration detected as less than (or'<') the qua ntitation limit
in the appropriate space. Provide a concentration estimate for chemicals detected in concentrations greater than the detection limit and less
than the quantitation limit. Enter the detection limit in parentheses beside the estimate. Chemicals detected In concentrations above the quan-
titation limits must be quantified. Ouantitatlon limit and detection limit are defined in the accompanying memo (Tedder, October 1990). Enter
the total number of peaks detected in each analytic fraction In the appropriate space on this Revised APAM Form A. Report all concentrations
in units of micrograms per liter (ug11) and metals as total recoverable metal. If no peaks to be identified under the 10 significant peaks rule
are observed, enter "none" in the space provided for "other" compounds in each appropriate analytic fraction section. Provide the concentra-
tion estimate and retention time for "unknowns" as well as for "significant peaks" for which a structural assignment can be made.
8 - if "significant peaks" are found, provide probable molecular weight, library match probability, retention time, •identification basis, and
MS scan number for each. In addition, list internal standards and their retention times.
9 - In the section labeled "Organic Analytical Information" (p. 9), include for each organic fraction the method, extraction technique, GC
operating conditions, and surrogate recovery. Report the size of the GCIMS library being utilized in the appropriate space.
10 - Use copies of this Annual Pollutant Analysis Monitoring Revised Form A to report the results of the analysis. Both the analytical laboratory
representative and the facility operator in responsible charge should sign completed forms (last page).
11 - Mail two completed copies of the form (and the laboratory report, if submitted to the facility on a different form) to: ATTN: Central Files,
Division of Environmental Management, NC DEHNR, P.O. Box 27687, Raleigh, NC 27611. Mail the APAM form separately from Discharge Monitoring
Reports.

A. Purgeable (Volatile Organic) Fraction, EPA Method. Page 2 of 9
Number of chemicals detected in Fraction
Fraction STORET Number 84085
STORET Compound
Number
Cluentitation
Limit Target
Ouantitation
Limit*
Concentration
Detected
GC1MS
Confirmation?
1. Pollutants to be analyzed for:
(ugll)
(ugll)
(ug11)
Yes
No
34210
Acrolein
100
34215
Acrylonitrile
100
34030
Benzene
5
32101
Bromodichloromethane
5
32104
Bromoform
5
34413
Bromomethane
10
32102
Carbon tetrachloride
5
34301
Chlorobenzene
6
34311
Chloroethane
10
34576
2-Chloroethyl vinyl ether
10
32106
Chloroform
5
34418
Chloromethane
10
32105
Dibromochloromethane
5
34496
1,1-Dichloroethane
5
34531
1,2-Dichloroethane
5
34501
1,1-Dichloroethyiene
5
34546
trans-1,2-Dichloroethylene
5
34541
1,2-Dichloropropane
6
34704
cis 1,3-Dichloropropene
5
34699
trans 1,3-Dichloropropene
5
34371
Ethylbenzene
8
34423
Methylene chloride
5
34516
1,1,2,2-Tetrachloroethane
7
M
34475
Tetrachloroethyiene
5
34010
Toluene
6
34506
1,1,1-Trichloroethane
5
34511
1,1,2-Trichloroethane
5
39180
Trichloroethylene
5
34488
Trichlorofiuromethane
10
39175
1 Vinyl chloride
10
' if different from quantitation limit target

Compound
Probable
Molecular
Weight
Estimated
Concentration
(ugll)
Library Match
Probability
M
Retention
Time (RT)
(Min)
Identification Basis
(Check all that apply)
Scan
Number
Library
Match
Manual
Interpretation
RT
Complete only if non -targeted compounds are present:
Retention
Internal Standard Time
(Min)
AU i
N
O
w
o_
to

B. Acid Extractable Fraction, EPA Method
Page 4 of 9
Number of chemicals detected In Fraction
Fraction STORET Number 45582
STORET Compound
Ouantitation
+Quentitation
Concentration
GC1f1AS
Number
Limit Target
Limit'
Detected
Confirmation?
1. Pollutants to be analyzed for:
(ug11)
(ugll)
(ug/1)
Yes
No
34452
4-Chloro-3-meth I phenol
10
34586
2-Chloro henol
10
34601
2 4-Dichloro henol
10
34606
2 4-Dimeth I henoi
10
34616
2 4-Dinitro henoi
50
34657
2-Meth I-4 6-dinitro henoi
50
34591
2-Nitrophenol
10
34646
4-Nitrophenol
50
`
39032
Pentachloro henol
50
34694
Phenol
10
34621
2 4 6-TrichIoro phenol
10
' If different from quantitation limit target
v
c-) n
1 r*
.D
F
rm-

Compound
Probable
Molecular
Weight
Estimated
Concentration
(ug11)
Library Match
Probability
M
Retention
Time (RT)
(Min)
Identification Basis
(Check all that apply)
Scan
Number
Library
Match
Manual
Interpretation
RT
Complete only if non -targeted compounds are present:
Retention
Intemal Standard Time
(Min)
16 L- 33
N
F
r7

C. Base/Neutral Fraction, EPA Method Page 6 of 9
Number of chemicals detected in Fraction
Fraction STORET Number 45583
STORET Compound
Number
Ouantitation
Limit Target
Ouantitation
Limit'
Concentration
Detected
GCIMS
Confirmation?
1. Pollutants to be analyzed for:
(ug/1)
(ug11)
(ug11)
Yes
No
3405
Acena hthene
10
34200
Acena hth lene
10
34220
Anthracene
10
39120
Benzidine
50
34526
Benzo a anthracene
10
34247
Benzo a rene
10
34230
Benzo b fluoranthene
10
34521
Benzo hi) perylene
10
34242
Benzo k fluoranthene
10
34278
Bis 2-chloroethox methane
10
34273
Bis 2-chloroeth I ether
10
34283
Bis 2-chloroiso ro I ether
10
39100
Bis 2-eth lhex Iphthalate
10
34636
4•Bromo hen l phenyl ether
10
34292
But I bent i phthalate
10
34581
2•Chlorona hthalene
10
34641
4-Chloro hen I phenyl ether
10
34320
Chrysene
10
34556
Dibenzo a h anthracene
10
34536
1 2-Dichlorobenzene
10
34566
1 3-Dichlorobenzene
10
34571
14-Dichlorobenzene
10
v
34631
3 3-Dichlorobenzidine
20
n
0
34336
Diethyl phthalate
10
-y
34341
Dimeth I phthalate
10
y
39110
Di-n-but I phthalate
10
34611
2 4-Dinitrotoluene
10
Fn
34626
2 6-Dinitrotoluene
10
34596
Di-n-oct I phthalate
10
34346
1 2-Di hen Ih drazine
10
34376
Fluoranthene
10
34381
Fluorene
10
39700
Hexachlorobenzene
10
34391
Hexachlorobutadiene
10
34386
Hexachloroc clo entadiene
10
34396
Hexachloroethane
10
34403
lndeno 1 2 3-cd rene
10
34408
Iso horone
10
34696
Naphthalene
10
34447
Nitrobenzene
10
34438
N-nitrosodimeth lamine
10
34428
N-nitroso•di•n ro lamine
10
34433
N-nitrosodi hen lamine
10
34461
Phenanthrene
10
34469
P rene
10
34551
1,2,4-Trichlorobenzene
10
If different from quantitation target

Compound
Probable
Molecular
Weight
Estimated
Concentration
(ug/1)
Library Match
Probability
(%}
Retention
Time (RT)
(Min)
Identification Basis
(Check all that apply)
Scan
Number
Library
Match
Manual
Interpretation
RT
Complete only If non -targeted compounds are present:
Retention
Internal Standard Time
(Min)
s
m
Cr
m
0
CD
cu
c
m
N
C
P
u
0
in
m
N
41
N
v
0
to

D. Organochlorine/Organophosphorus Pesticides and PCB's Page 8 of 9
Number of chemicals detected in Fraction
Fraction STORET Number 00188
STORET Compound
Number
Ouantitation
Limit Target
Ouantitation
Limit*
Concentration I
Detected
Confirmation?
Dual Column GCIMS
1. Pollutants to be analyzed for: (ug11)
Organochlorine PesticidesIPCB's: EPA Method
(ugfl)
(ug/1)
Yes
No
Yes
No
39330
Aldrin
0.05
39337
al ha-BHC
0.05
39338
Beta-BHC
0.05
34259
Delta-BHC
0.1
39340
Gamma-BHC Lindane
0.05
39350
Chlordane
0.2
39310
4 4'-DDD
0.1
-39320
4 4'-DDE
0.1
39300
4 4'-DDT
0.1
39380
Dieldrin
0.02
34361
Endosulfan I (alpha)
0.1
34356
Endosulfan II beta
0.1
34351
Endosulfan sulfate
0.7
39390
Endrin
0.06
34366
Endrin aldehyde
0.2
39410
Heptachlor
0.05
39420
Heptachlor epoxide
0.8
39480
Methox chlor
0.5
39755
Mirex,
0.2
39400
Toxa tiene
2.4
34671
PCB 1016
0.5
39488
PCB 1221
0.5
39492
PCB 1232
0.5
39496
PCB 1242
0.5
39500
PCB 1248
0.5
39504
PCB 1254
1.0
39508
PCB 1260
1.0
r �
r
Organophosphorus Pesticides: EPA Method
39560
Oemeton 2.5
39540
Parathion (ethyl) 0.6
E. Herbicides, EPA Method
Number of chemicals detected In Fraction
Fraction STORET Number 00148
STORET Compound
Number
Ouantitation
Limit Target
Ouantitation
Limit'
Concentration
Detected
Confirmation?
Dual Column
1. Pollutants to be analyzed for:
(ug/1)
(ug")
(ug/1)
Yes
No
39730
2 4-D
12
39045
Silvex
2
39740
2,4,5-T
2
If different from quantitation limit target

Organic Analytical Information: Page 9 of 9
Organic Fraction
Method
Extraction
GC Operating Conditions
Column Description
Surrogates (Spikes)
Batch
Continuous
Compound
Recovery
Length X ID, Film Thickness,
Column Type, Carrier Gas & Flow
Rate, Temperature Program
Purgeabie
Acid Extractable
Base/Neutral Extractable
Example: Acid Extractable
625
X
30m x 0.25mm, 0.25um, 1018.5,
He, 30 cm/sec, 40°C (4 min)
270°C, 1001min
d5 • phenol
s0
GCIMS Library size (number of reference spectra):
F. Metals and Other Chemicals
Number of Metals and Other Chemicals (as listed below) detected in Sample
Fraction STORET Number 78240
STORET Compound i
Number
Quantitatlon
Limit Target
Quantitation
Limit"
Concentration
Detected
1. Pollutants to be analyzed for:
WWII)
(ug")
(ug11)
01104
Aluminum
50
01097
Antimony
50
01002
Arsenic
10
v
01012
Beryllium
25
c-)
01027
Cadmium
2
01034
Chromium
5
01042
Copper
2
01051
Lead
10
71900
Mercury
0.2
01067
Nickel
10
01147
Selenium
5
01077
Silver
5
01092
Zinc
10
2. Other inor anics:
01007
Barium
500
00940
Chloride
1000
00720
Cyanide
20
00951
Fluoride
100
If different from quantitation limit target
Analytical Laboratory Representative:
Signed: _ Date:
Facility Operator in Responsible Charge (ORC):
I certify that this report is accurate and complete to the best of my knowledge.
Signed:_ Date:

. WABL.Z Lr—reVtlAM&L, aarea►. a v.......... ...
IN EACH of FOUR FRAMONs IN
ANALTSM BY OAS CHROUATOGRAPHY/
MAW SPJilr 201I17OPY (aa+MS)
sarolsta
60710nitrlle
bensom
brornoform
carbon tstrochloride
ahlorobaaeene•
e hlorodibroraonmWwws
chloroethano
3-cWorooWlrinyl other
ohloroform
dlchlorobramomoLbaas
1.1dichlo"ALha.oe
1.4-dia.loroeLbaas
1.1-diworretbylone
1.9-dlcbJ^Vr0P&D*
14-dlchloropro➢yleas
ethylbensens
methyl bromide
methyl chloride
methylsns chlorlde
1.1.1.3-tetmchloroethaae
trtracLloroethylene
toluene
1ltrana-dl chloroathy1eas
1.13-trichl orosthane
1,1.1-trl cbloroethans
trlcb)crwthylow
rind chloride
S-chloropbeool
1."Ichloropheno)
9,4-dirn*WIPhenol
4,6-dir,1Lro-c-Q1"ol
it.4-dinitrophsaol
S-nitrophenol
4-ni trophenol
P-chloro-m-crawl
peatachloropbsuol
Phenol
3.4.6tricb1Oroph43101
Ba"Cu tral
IB aceaaphtbsne
SB acanaphthyleae
38 anthraceno
4B bsnsJdine
6B benso(s)anthmosns
® benao(a)Dynne
TB 3.4-bousonuorantbeas
AB beoxo(shl)psrylehs
9B bsaso(k)fluoraathsne
lOB bie(2-0hloroeth0:ylmeLhaae
11B bls(9-chlorostbyl)ether
12B bia(7-0hlorolwpropyl)eLher
1SB Me (2-et.hy1h*rY1)Pbthalate
14B 4-bromopbsnyl pbenyl ether
15B butylbenxy) Phthalate
1AB 9-chloroaaphumlene
17B 4-chloropbenyl phenyl ether
16B chryssne
19B dlbenzo(a,hrinthmcens
30B 1.941chlorobensens
SIB 1.3-dlch3orobenseae
22B 1.4d1cb1orobenaene
33B 3.3'dlch3orobe=dlns
StB diethyl phthalate
1SB dlmethyl phthalate
36B di-o-butyl phthalate
27B 1.4dinitrotoluens
1t9B 2A4Lnlu0L0lusae
39B dl-a-0ctyl phthalate
30B 1.1-41pheny1hydrizins (as Lwbsaxano)
31B OuroranLhsne
32B fiuorens
33B box-&e lombeamoo
34B hexacblorobutadlsos
3SB haxachlorocyc)opentadisne
36B hexachloroethane
87B Sndeao(1.2.3-0d)PYrsne
MB
naptbalens
40B
nitrobensene
41B
N-nLroaodimstbylarnlne
42B
N-n1trosod1-a-Pr'op71-ffWns
40
N-niuosodlpbenyLsnina
UB
pbsnaatbnsne
46B
pyrene
4J18
.
1,1.4-trlchlaro0sassw
l�CJdQ
1P
aldrla
IF
alpha-13HC
V
beta-BHC
4P
Wamma-BHC
GP
delta-BHC
4P
chlordane
TP
4,4'-DDT
IF
4.4'-DDE
OF
4.4'-DDD
&OP
dleldrin
11P
alpha-0adosttlfan
12P
beta♦ndoaultaa
113P
endosulfan sallata
14P
sndrin
I&P
eodria aldehyde
lap
heptachlor
17P
baptacblor opaside
IAP
PCB-1242
19P
PCB-1151
311P
PCB-1111
31P
PCB-1132
UP
PCB-1240
33p
PC11-1780
UP
P'C13-1016
UP
UM&Dhoa*
Tan& M-4),� To= PoLwTAm
(MirrALS AND CTANMZ) AND TOTAL
PUMOL6
AnUmoay. Tots)
Arsenic. Total
Beryllium. Total
Cadmium; Total
Chromium, Total
Copper, Total
Lad. Total
Mercw7. Total
Nickel, Total
selenium. Total
Oliver. Total
Thalilum, Toni
iinc. Total
Cyanide, Total
PDsools. Tots)
TABLE IV--00tiVz n-loNAL AND
NONOONV)I:I+rrIONAL PO1.t..uTANTB Rt-
QZiUM To BE TzsTED BY ExLo77 VO
DLwHA wzu lF ExrocrED To B3
PPJMWM
8romtds
Chlorlas. Total Aasidual
color
real Collfarm
Pluorlds
Nitrate -Nitrite
Nluroren, Total orTaalc
Oil and Ores."
Phosphorus, Total
Radioactivity
Sulfata
Sulfide
Sulfite
Surfsctsnts
AlumJottm, Total
Barlum. Total
Boron. Total
Cobalt. Total
iron, Total
Useneelum, Total
Molybdenum. Total
Man4aaess, Total
T'ia, Total
INUMIum. Total
ARDOu5 rSUMTAMUNS XMQUMW -M
BE ID=M7 i>'uw BY $><1P UM Dw-
CHABaSRB EF RXFWM oft Bi
" PBsasNr .
Took l+sffufaefs
Asbestos
Haaardow Sub"aaap
Acetaldehyde
AllYI alcohol
A11yl cbloride
Amyl acetate
Anlllas
Beaeonitrils
Betar,I] chlorlds
Butyl awwa
Butylaralbs
Ckpt"
Carbaryl
Carbon disul1ds
Chlorpyrifos
Coum:pbos
Cresol
Crotonaldehyde
Cyclobexaae
3,4-D (2.4-DJchloropbsaoo acetic eaid)
DJWI=
Dicambs.
Dichlobenll
Dichlone
1,2-DJchlo. Vionic acid
Dichlorros
Diethyl amine
DimeLbyl amino
DiaLrobemene
Diquat
Dlsulfoton
DJnron
Bplchlorohydrin
tthion
Ethylene dlaailne
*Lbylens dlhromlda
Formaldehyde
Furfural
OuLhlon
lsoprsne
Isopr'opanol .m1ne Dodecylbensanesaliows
Keltbans
Kepone
MAIALhJon
lliercaptodJrr»ihur n
McLboxychlor p
Methyl mercaptan p CD
ldethyl methacrylat -n
Methyl PLMLblon C-'>
Mwiapbw 1 � .
Mexacarbate y
Manoethyl grains
MonomeLhy1 amine tJD
Naled F`
NapLbsnic acid 'rJ
NJtrotoluese
Pamt.hlon
phenoleulfa.aats
Pbosyeno
ProparclLe
Propylene oade
Pyasthrins
Quiacltns
Rasorcinol
Strontium
Btrychnlne
Btyrons
13.5-T (2,4,6-Ttlchi orophanory acetic said)
TIDE (TeLracblorodJphenyJethans)
2.4.5-77 [1{2,4.6-Tr1cblorophsAwW) pro.
paoolc acid)
TrJchlorofaa
Trlettianolamins dodecylbetrrisnesulfonate
TrleLhylamias
Trimathylamine
Uranium
Vanadium
Vinyl acetate
Pylons
Xylenol
161 rconl um