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NCS000329_MONITORING INFO_20170321
STORMWATER DIVISION CODING SHEET NCS PERMITS PERMIT NO. A�C bc��2°I DOC TYPE ❑ FINAL PERMIT MONITORING REPORTS.-_--....-- _ _..__...._..._.-_-.- ❑ APPLICATION ❑ COMPLIANCE ❑ OTHER DOC DATE I'k YYYYM M DD t March 16, 2017 Attn: Central Files N.C. Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 Central Files: RECEIVED MAR 21 2017 CENTRAL FILES DWR SECTION 4* AT I P.O. Box 5030 2020 Ashcraft Avenue Monroe, NC 28111-5030 Phone: (704) 28 9-4511 Pax: (704) 290-5194 l.1 ail: joe.hinkle(a7atimetals.com Attached, please find stormwater monitoring data for Pen -nit No NCS000329. The originals and one copy are included. The monitoring data is for the following monitoring schedule: Moniforir Period SampleNumber ;_4 w ' „ •Staff t �. ;j, �p .grid' «. Year 7 — Period 2 14 September 1, 2016 Februar y 28, 2017 Analytical monitoring includes: • Outfall #01 (B), commingled stormwater • Outfall #02 (B), non -commingled stormwater • Outfall #03 (B), non -commingled stormwater • Non Contact Cooling Water #1 - #8 If you have any questions or need additional information, please contact me at 704-289-451 1. Thank you. Since ely, At;U{- Jo inkle Environmental Manager 4r t� Alivae -- Bakers Plank -OATI Allvac Stormwater Monitoring Report Form Sample Date: o? _8 /7 Sample Time: a •' 416a... Sample Location: Stormwater Discharge Outfall #01 (Commingled) Drainage Area = 2,915,470sa. ft. = 69 acres % impervious = 34% Person Collecting Samples: aw1cQ Canoe 7R • _ Laboratory Performing Analysis: Pas Cam° /�na�ca T Analytical Techniques and Methods: 40' CFR Part 136 Results of Sams)Ie Analvsis: Parameter Results (mg/1) Benchmark Values (mg/1) BOD q.3 30 COD 38.6 120 TSS a 100 Cadmium 0.001 Chromium, total recoverable 1 Copper, total recoverable 0.007 Nickel, total recoverable 0.26 Zinc, total recoverable 0.51a8 0.067 Oil and Grease Alp 20 Temp (receiving stream) (deg C) 32 (deg C) Total Residual Chlorine D Q a 0.017 pH r% Q (std units) 6-9 (std units) Storm Dater Storm Duration: . a?S (Hrs.) Inches of Rainfall: Q6O Duration of time preceding rain event exceeding 0.I ": S60 (Hrs.) )Estimated Flow Calculation: Q=CIA Q(Total) = Q(Pervious Area) + Q(Impervious Area) Q(tot., cfs) _ (A x inches rain/12 inches/ft. x 69 acres x .66) + .9 x inches rain/12inches/ft. x 69 x .34) Q(Total, cfs) = 1.5180 x Q (Inches of rain) + 1.7595 x D. (o Q _ (Inches of rain) aceAnalytical www.pacefaLscarr February 15, 2017 Mr. Joe Hinkle Allvac RE: Project: BAKERS STORMWATER Pace Project No.: 92329088 Dear Mr. Hinkle: Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 HuntersvUle, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on February 08, 2017. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNIINELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com Project Manager Enclosures cc: Mr. Preston Baucom, Allvac Mr. Tommy Long, Allvac David Pope, Allvac REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 15 Pace Analytical Services, LLC ,, _ aceAnalytical s 9600 Kinsey Ave. Suite 100 1 Huntersville, NC 28078 wwwpecelebscom (704)875-9092 i CERTIFICATIONS Project: BAKERS STORMWATER Pace Project No.: 92329088 Charlotte Certification IDS 9800 Kincey Ave. Ste 100, Huntersviile, NC 28078 North Carolina Drinking Water Certification M 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification iDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 South Carolina Certification #: 99006001 FloridalNELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40- South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shah not be reproduced, except in foil, without the written consent of Pace Analytical Services, LLC. Page 2 of 15 r ` aceAnaljdical www.pecelab&com SAMPLE ANALYTE COUNT Project: BAKERS STQRMWATER Pace Project No.: 92329088 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92329088001 8SW01 EPA 1664E JMS 1 PASI-C EPA200.7 SER 5 PASI-A SM 2540D ALC 1 PASI-A SM 4500-CI G MDW 1 PASI-A SM 5210B CJH1 1 PASI-A SM 5220D MDW 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 15 Pace Analytical Services, LLC _ aceAnaly�ical® 9800 KinceyAve. Suite 100 Huntersville, NC 28078 wwwpacema:cam (704)875-9092 ANALYTICAL RESULTS Project: BAKERS STORMWATER Pace Project No.: 92329088 Sample: SSW01 Lab ID: 92329088001 Collected: 02/08/17 02:40 Received: 02/08/17 11:15 Matrix: Water Field Data Parameters Collected By Collected Date Collected Time Field pH Field Temperature HEM, Oil and Grease Oil and Grease 200.7 MET ICP Cadmium Chromium Copper Nickel Zinc 2540D Total Suspended Solids Total Suspended Solids 4500CL G Chlorine, Residual Chlorine, Total Residual 52108 BOD, 5 day BOD, 5 day 5220D COD Chemical Oxygen Demand Results Units Report Limit DF Prepared Analyzed CAS No. Qua] Analytical Method: DPJ 1 02/09/17 11:38 02/08117 1 02/09/17 11:38 02:55 1 02/09/17 11:38 7.0 Std. Units 0.10 1 02/09/17 11:38 13.8 deg C 0.50 1 02/09/17 11:38 Analytical Method: EPA 16648 ND mg/L 5.0 1 02115/17 0735 Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 ND ug1L 1.0 1 02/09/17 21:00 02/13/17 18722 7440.43-9 ND ug1L 5.0 1 02/09/17 21:00 02/13/17 18:22 7440-47-3 18.4 ug1L 5.0 1 02/09/17 21:00 02/13/17 18:22 7440-50-8 ND ug1L 5.0 1 02/09/17 21:00 02/13/17 18:22 7440-02-0 12.8 ugIL 10.0 1 02/09/17 21:00 02/13/17 18:22 7440-66-6 Analytical Method: SM 2540D 7.2 mg/L 2.5 1 02/10/1714:36 Analytical Method: SM 4500-CI G 0.092 mg/L 0.024 1 02/09/17 20:45 7782-50-5 Analytical Method: SM 5210B 4.3 mg/L Analytical Method: SM 5220D 38.0 mg1L 2.0 1 02/09/17 03:25 02/13/17 23:40 25.0 1 02109/17 22:59 H1 Date: 0211512017 07:45 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 15 s e t aceAnalXical u tnvw,pei:ala6s.txun QUALITY CONTROL DATA Project: BAKERS STORMWATER Pace Project No.: 92329088 QC Batch: 348256 Analysis Method: EPA 1664E QC Batch Method: EPA 1664E Analysis Description: 1664 HEM, Oil and Grease Associated Lab Samples: 92329088001 METHOD BLANK: 1932211 Associated Lab Samples: 92329088001 Parameter Units Oil and Grease mglL Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 5.0 02/15/17 07.32 Pace Analytical Services, LLG 9800 KInoey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1932212 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Oil and Grease mg/L 40 36.9 92 78-114 MATRIX SPIKE SAMPLE: 1932213 35293826002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Oil and Grease mg1L 1.1 U 40 36.0 90 78-114 Results presented on this page are in the units Indicated by the "Units' column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, Dale: 02/15/2017 07:45 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 15 aceAnaljftal *WW.pacefab cam f QUALITY CONTROL DATA Project: BAKERS STORMWATER Pace Project No.: 92329088 QC Batch: 347561 Analysis Method: EPA 200.7 QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET Associated Lab Samples: 92329088001 METHOD BLANK: 1928166 Associated Lab Samples: 92329088001 Parameter Cadmium Chromium Copper Nickel Zinc Matrix: Water Units Blank Result Reporting Limit Analyzed ug/L ND 1.0 02/13/1717:01 ug/L ND 5.0 02/1311717:01 ug/L ND 5.0 .02113/1717:01 ug/L NO 5.0 0211311717:01 ug/L ND 10.0 02/13/1717:01 Qualifiers • Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 1 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1928156 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cadmium ug/L 500 556 ill 85.115 Chromium ug/L 500 554 111 85-115 Copper ug/L 500 573 115 85-115 Nickel uglL 500 547 109 85-115 Zinc ug/L 500 558 112 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1928157 MS 92329043019 Spike Parameter Units Result Conc. MSD Spike Cont. 1928158 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Qual Cadmium ug/L ND 500 500 537 540 107 108 70-130 1 Chromium ug/L ND 500 500 521 538 104 108 70-130 3 Copper uglL NO 500 500 546 559 109 112 70-130 2 Nickel ug/L ND 500 500 518 528 104 106 70-130 2 Zinc ug/L NO 500 500 528 539 105 108 70-130 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1928159 1928160 MS MSD 92328962003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua[ Cadmium ug/L ND 500 500 561 559 112 112 70-130 0 Chromium ug/L 0.013 500 500 552 544 108 106 70-130 2 mg/L Copper uglL 0.011 500 500 593 589 116 116 70.130 1 mg/L Nickel ug/L 0.012 500 500 548 544 107 106 70-130 1 mg/L Zinc ug/L 0.085 500 500 634 621 110 107 70-130 2 mg/L Results presented on this page are In the units Indicated by the "units' column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2017 07:45 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 15 6 � aceAnaljftal www.pacelabs com QUALITY CONTROL DATA Project: BAKERS STORMWATER Pace Project No.: 92329088 QC Batch: 347724 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92329088001 METHOD BLANK; 1929058 Associated Lab Samples: 92329088001 Parameter Units Total Suspended Solids mg/L LABORATORY CONTROL SAMPLE: 1929059 Parameter Units Total Suspended Solids mg/L Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.5 02/101171418 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 240 96 90-110 SAMPLE DUPLICATE: 1929060 92328982003 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 14.5 13.8 5 SAMPLE DUPLICATE: 1929061 92329112001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L ND ND Results presented on this papa are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 02/15/2017 07:45 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 15 aceAnal0cal wltw.patelab1WM I QUALITY CONTROL DATA Project: BAKERS STORMWATER Pace Project No.: 92329088 QC Batch: 347682 Analysis Method: SM 4500-CI G QC Batch Method: SM 4500-CI G Analysis Description: 4500CL G Chlorine, Total Residual Associated Lab Samples: 92329088001 METHOD BLANK: 1928900 Matrix: Water Associated Lab Samples: 92329088001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chlorine, Total Residual mglL ND 0.024 02/09/17 20:45 SAMPLE DUPLICATE: 1928901 92328999001 Cup Parameter Units Result Result RPD Qualifiers Chlorine, Total Residual mg/L ND NC H1 � r Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are In the units Indicated by the "Units' column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 0211512017 07:45 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 15 aceAnalytical. wwwpacelaba.txan QUALITY CONTROL DATA Project: BAKERS STORMWATER Pace Project No.: 92329088 QC Batch: 347491 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 92329088001 METHOD BLANK: 1927949 Matrix: Water Associated Lab Samples: 92329088001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg1L ND 2.0 02I13117 23:40 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Hurtersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1927950 Units Spike LCS LCS Conc. Result % Rec % Rec Limits Qualifiers BOD, 5 day mg1L 198 170 86 84.6-115.4 SAMPLE DUPLICATE: 1927951 92329036001 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg1L ND ND Results presented on this page are in the units Indicated by the -Units' column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2017 07:45 PM without the written consent of Pace Analytical Services, LLC, Page 9 of 15 aceAnalytical nww.pecefabscdm QUALITY CONTROL DATA Project: BAKERS STORMWATER Pace Project No.: 92329088 QC Batch: 347683 Analysis Method: SM 5220D QC Batch Method: SM 5220D Analysis Description: 5220D COD Associated Lab Samples: 92329088001 METHOD BLANK: 1928918 Matrix: Water Associated Lab Samples: 92329088001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chemical Oxygen Demand mg/L NO 25.0 02/09/17 22:59 . r Pace Analytical Services, LLC .. 9800 KinceyAve. Suile 100 Huntersville, NO 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1928919 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg/L 750 754 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1928920 1928921 MS MSD 92329195001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg/L 2110 750 750 2600 2600 66 66 90-110 0 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1928922 1928923 MS MSD 92329088001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Cone. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg/L 38.0 750 750 798 795 101 101 90-110 0 Results presented on this papa are In the units Indicated by the "Units' column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2017 07:45 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 15 Pace Analytical Services, LLC + aceAnalytical a 9800 Kincey Ave, Suite 100 1 Huntersville, NC 28078 WWW.paoefabs.cam (704)875-9092 ) QUALIFIERS Project: BAKERS STORMWATER Pace Project No.: 92329088 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quanlitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethytvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260, N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyle is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASt-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS H1 Analysis conducted outside the EPA method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2017 07:45 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 15 aceAnalytical —paceWftcom f QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 9800 KlnceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: BAKERS STORMWATER Pace Project No.: 92329088 Analytical Lab ID Sample ID QC Batch Method GC Batch Analytical Method Batch 92329088001 BSW01 92329088001 BSW01 EPA 1664B 348256 92329088001 BSW01 EPA 200.7 347561 EPA 200.7 347718 92329088001 BSW01 SM 2540D 347724 92329088001 BSW01 SM 4500-CI G 347682 92329088001 BSW01 SM 5210B 347491 SM 5210B 347499 92329088001 8SW01 SM 5220D 347683 Date: 02/15/2017 07:45 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 15 aceAnalytical' laboratory receiving samples: Asheville ❑ Edeno uvcumem iname: I Uocument Revised: Sept. 21, 2016 Sample Condition Upon Recel t SCUR Page 1 of 2 Document No.: Issuing Authority: FCAR-CS-033-Rev.01 Pace Quality Office Greenwood ❑ Huntersvllle E],"" Raleigh[] Mechanicsville❑ • Client Name: LJO#: 92329088- Project N., Courier: Fed Ex UPS ❑LISPS eclient ❑ Commercial ❑Pace ❑Other: 9232 p88 Custody Seal Present? ❑Yes No Seals Intact? ❑Yes ENo Date/Inttfals Person Examining Contents:. b" 1-7 Packing Material: ❑Bubble Wrap Bubble Bags []None ❑Other:, Thermomets:r �1Wet ❑Blue ❑None• arnpies on Ice, cooling process has begun iR Gun ID: J 1 W) Type of toe• ,� Coirectlon Factor: Cooler Temp Corrected ('C): ��� ! Biological Tissue Frozen? []Yes�,gtvo ❑N/A Temp should be above fre zing to VC USDA Regulate 'Soil ((i] N/A, water sample) Did samples gtnate in a quarantine zone wlthln the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (Inte tonally, []Yes o Including Hawaii and Puerto Rico)? []Yes . U No Chain of Custody Present? es ❑No N/A 1. Sam les Arrived within Hold Time? as ONO QNLA 2. Short Hold Time Analysis 02 hr.)? QN. []NIA 3. Rush Turn Around Time Requested? OYes o OWA 4. Sufficient Volume?' Mfes ❑No N/A S. 'orrect Containers Used? M<11 Off, ©N/A :ontainers Intact? es ONO N 7. ;am les Field Flitered? , Yes No A S. Note If sediment Is visible In the dissolved container_ '- .. .. ample Labels Match COC? es ONO ❑N/A 9. -Includes Date/Time/ID/Analysis Matrix: leadspace in VOA Vials >5-6mmj7 Yes No 1A 10. 'rip Blank Present? ❑Yes [:]No 11. 'rip Blank Custody Seals Present? QYes No N/A CLIENT NOTIFICATION/RESOLUTION Field Data Required? []Yes []No Person Contacted: Date/nme: Comments/Sample Discrepancy: Project Manager SCURF Review: Date::�� f Project Manager SRF Review: Date: fo / I-) Ste: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be. sent to the North Carolina DEHNR Certification Office (Le ut of hold, tncorr&.- Preservative, out of temp, Incorrect containers) Page 13 of 15 m m A O rL N 3 0 -4 A e m 2 m 0 s s 0 3 A A 9 O m C• (A m v M � m d ,,r a r � m n C � N a M ro L a� e « y n m CL b � w D O c m a m n A m d ro 0 u NZZZZZZ7VXz F~+ 1p V O1 [Jt A W N a y � � � n 3 BP4U-125 mL Plastic Unpreserved (NIA) (0-) BP3U-25O mL Plastic Unpreserved (N/A) BP2U-500 mL Plastic Unpreserved (N/A) v Q. ,�. BP1U-1 liter Plastic Unpreserved (N/A) Cutr O 0 'ts Cr.� � BP3S-250 mL Plastic H2SO4 (pH < 2) (C6) 0 F. 3 N =n S O BP3N-250 mL plastic HNO3 (pH < 2) Cr N n x BP32-250 ml. Plastic 7-N Acetate & NaOH (>9) 7 r z7vC BP3C 250 mL Plastic NaOH (pH > 12) (CI-) 3 n 0► O f9 C C. WGFU-Wide-mouthed Glass jar Unpreserved p Cr go AG1U-1 liter Amber Unpresmved (N/A) (CI-) O to CL ;177ZZZ77f7y-z7 p 7 to AG1H-1 liter Amber HCl (pH < 2) 4A O AG3U-250 mL Amber Unpreserved (N/A) (C,) AG1S-1 liter Amber H2504 (pH < 2) N -s AG3S-250 mL Amber H2504 (pH < 2) AGM(DG3A)-250 mL Amber NH4Ci (N/A)(CI-) DG9H-40 mL VOA HCI (N/A) z ZZ47 VG9T-40 mL VOA Na25203 (N/A) CIO VG9U-40 mL VOA Unp (NIA) C) 3 DG9P 40 mL VOA H3PO4 (N/A) i CD ft VOAX (6 vials per kit)-5035 kit (N/A) m •• N V/GK (3 vials per kftj VPH/Gas kit (NIA) 30 f SPST-125 mL Sterile Plastic (N/A — lab) SPIT-25O ml. Sterile Plastic (N/A —lab) Z N tS 'D, Np Q; A Co BP3A-250 mL Plastic (NH2)2SO4 (9.3-9.7) O Co N Cubitainer r. V VSGU-20 mL Santillation Vials (N/A) v GN r in 0 n' 0no M n � 3 w M C'a w .a. 0 7t 2 = W M HE PaceAnaVical" in ii.Wcelah:.rtam Section A Required Client Information: CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section B Section C Required Project Information: Invoice lnformalion: Page: of Company: , t Repon TO: : y� AttentionS! -f-� 1�C6inle/1 t V G Andress: nn GL' �Q 6✓ Copy To: J OC i nXie Company Namrr�e// REGULATORY AGENCY /�^re+�r,� N� Address: Ply Bn soS44/'&co ,4e at/c X NPDES GROUND WATER r UST - RCRA �� DRINKING WATER r OTHER Email To: Purcnase Order No.: Pd G.W. RMerer,[e: Phone: FSs: Project Name; Farn PfO Site Location STATE: Requested Due Date/TAT: Project Number: "80 Profile e: Requested Analysis Filtered (YIN) Section D Matrix Codes Rpulred Cli-It W-11on MATRlx I CODS s o COLLECTED Preservatives r 2 3- Drinking water Dw 1 u � Water WasteW3tor WT WIN v V a1 CdMPMTE D0169- rr START EHO,CMe Q _ � Product SoillSolid SAMPLE !D SL • y C ` Y ,� I W,,'Ile (A-Z, 0.97,-) Air VVPL AR w" p w a w o. m F— yr v o Sample IDs MUST BE UNIQUE Tissue TS O u w tA. U Other OT X +- w w O U. JD G O o'er rn L m T = 1�w'44 -L Q 2 q `j o Q z � ro m mt a i Q~ o L V N ,v _ in DATE TIME DATE TIME rn a U S S Z Z Z O �y ff Pace Project Not Lab I.D. -V -.l �:ya- U 21 14� s W! ,Z""ia- s 95rJv i s 5 1W i KteIr it !I 6 a� j Y T B g J12 ADDITIONAL COMMENTS RELINQUISHED BY t AFFILIATION DATE TIME ACCEPTED BY I AFFILIATION DATE TIME SAMPLE CONDITIONS ,J/h--2:>e-- ro CRiGEt��'-.x SAMPLER NAME AND SIGNATURE PRINT Name of SAMPLER: Pml- JCr e J-R a m z g ? mTSIGNATURE a of SANPLER� ' ESigned d y r y v t rt -gnpmL' i Nola: By %Krwlg thm Iorm you :ve: cvtp•1 Pxr s NFT 30 day payment Ilrms and w.p—ffM to late chm9ns d IS% per rnardh rw, , trrvero "G paid -thin 30 days. F-ALL-0-020rev.07, 15-May-2007 OATIA11vac A llvac - Bakers Plan: Stormwater Monitorin Report Form Sample Date: P? -8-/ Sample Location: Person Collecting Samples: Laboratory Performing Analysis: Analytical Techniques and Methods: R exults of Sample AnaIvsis: Sample Time: a? 3� Stormwater Discharge Outfall #02 (Non -Commingled) Drainage Area = 212,952sa. ft. = 4.9 acres % Impervious = 12% 40 CFR Part 136 Parameter Results (mg/1) Benchmark -Values (mg/1) BOD 30 COD © 120 TSS 9 100 Cadmium 0.001 Chromium, total recoverable j 1 Copper, total recoverable a 0.007 Nickel, total recoverable 0.26 Zinc, total recoverable 40,1-31 0.067 pH (std units) 6-9 (std units) Storm Date: A -8 /7 Storm Duration: S. o2S (Hrs.) Inchoes of Rainfall: D• 64 Duration of time preceding rain event exceeding 0.1": J60 (Hrs.) Estimated Flow Calculation: Q=CIA Q(Total) = Q(Pervious Area) + Q(Irmpervious Area) Q(tot., cfs) _ (A x inches rain/12 inches/ft. x 4.9 acres x .88) + .9 x inches rain/ I 2inches/ft. x 4.9 x .12) Q(Total, cfs) = 0.143 7 x 6). 6 0 (Inches of rain) + 0.0441 x _ O • (P4 (Inches of rain) 4. / / 1 _ cfs leftlyiical wew.peaetaftizim February 15, 2017 Mr. Joe Hinkle Allvac RE: Project: Bakers Stormwater Pace Project No.: 92329090 Pace Analytical Services. LLC 9800 Kircey Ave. Suite 100 Nuntersville, NC 28078 (704)875-9092 Dear Mr. Hinkle: Enclosed aie the analytical results for sample(s) received by the laboratory on February 08, 2017. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NE!_AC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com Project Manager Enclosures cc: Mr. Preston Baucom, Allvac Mr. Tommy Long, Allvac David Pope, Allvac REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in lull, without the written consent of Pace Analytical Services, LLC. Page 1 of 13 aceAnalytical www.pao�s rom CERTIFICATIONS Project: Bakers Stormwater Pace Project No.: 92329090 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 ' Huntersville, NC 28078 (704)875.9092 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, H u ntersville, NC 28078 South Carolina Certification #: 99006001 North Carolina Drinking Water Certification #: 37706 Florida/NELAP Certification #: E87627 North Carolina Field Services Certification #: 5342 Kentucky UST Certification #: 84 North Carolina Wastewater Certification #: 12 VirginiaNELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 North Carolina Wastewater Certification #: 40 Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001 Massachusetts Certification #: M-NC030 VirginiaNELAP Certification #: 460222 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, I.I.C. if y Page 2 of 13 ` aceAnalytical. wmw,pdc#hft M SAMPLE ANALYTE COUNT Project: Bakers Stormwater Pace Project No.: 92329090 Pace Analytical Services, LLG 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Anatytes Lab ID Sample ID Method Analysts Reported Laboratory 92329090001 BSW02 EPA 200.7 SER 5 PASI-A SM 25400 ALC 1 PASI-A SM 5210B CJH1 1 PASI-A SM 5220D MDW 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 13 aceAnalytical wwwP&Dwkbs.cam ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 " Huntersville, NC 28078 (704)875-9092 Project: Bakers Stormwater Pace Project No.: 92329090 Sample: BSW02 Lab ID: 92329090001 Collected: 02/08/17 02:15 Received: 02/08/17 11:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Quai Field Data Analytical Method: Collected By DPJ 1 02/09/17 12:11 CollectedDate 02/08/17 1 02/09/17 12:11 Collected Time 02:29 1 02/09/17 12:11 Field pH 7.2 Sid. Units 0.10 1 02/09/17 12:11 Field Temperature 14.3 deg C 0,50 1 02/09/17 12:11 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Cadmium ND uglL 1.0 1 02109M 7 21:00 02/13/17 18:25 7440-43-9 Chromium 13.9 ug/L 5.0 1 02/09/17 21:00 02/13/17 18:25 7440-47-3 Copper 422 ug/L 5.0 1 02/09/17 21:00 02/13/17 18:25 7440-50-8 Nickel 14.2 ug/L 5.0 1 02/09/17 21:00 02/13/17 18:25 7440-02-0 Zinc 131 ug/f, 10.0 1 02/09/17 21:00 02/13/17 18:25 7440-66-6 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended, Solids 48.9 mg/L 3.5 1 02/10/17 14:36 5210B BOD, 5 day Analytical Method: SM 52108 BOD, 5 day 14.8 mg/L 2.0 1 02/09/17 03:25 02/13/17 23:40 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 66.0 mg/L 25.0 1 02/09/17 22:59 Date: 02/15/2017 07:45 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 13 wmxpecafebs.com QUALITY CONTROL DATA Project: Bakers Stormwatef Pace Project No.: 92329090 QC Batch: 347561 Analysis Method: EPA200.7 QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET Associated Lab Samples: 92329090001 METHOD BLANK: 1928155 Matrix: Water Associated Lab Samples: 92329090001 Pace Analytical Services, LLC 9800 Kincey Ave, Suite 100 Huntersville, NC 28078 (704)875-9092 Blank Reporting Parameter Units Result Limit • , Analyzed Qualifiers Cadmium ug/L ND 1.0 02113/1717:01 Chromium uglL ND 5.0 02/13/1717:01 Copper uglL ND 5.0 02113117'17:01 Nickel uglL ND 5.0 02/1311717:01 Zinc uglL ND - 10.0 02/1311717:01. LABORATORY CONTROL SAMPLE: 1928156 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers, . Cadmium uglL 500 556 111 85-115 Chromium uglL 500 554 111 85-115 Copper uglL 500 573 115 85-115 Nickel ug1L 500 547 .109 85-115 Zinc uglL 500 558 112 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1928157 1928458 MS MSD 92329043019 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Conc. Result Result % Rec % Rec Limits RPD Qual Cadmium uglL ND 500 500 537 540 107 108 70-130 1 Chromium uglL ND 500 500 521 538 104 108 70-130 3 Copper uglL ND 500 500 546 559 109 112 70-130 2 Nickel ug1L NO 500 500 518 528 104 106 70-130 2 Zinc ug1L ND 500 500 528 539 105 108 70-130 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1928159 1928160 MS MSD 92328962003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Cadmium uglL ND 500 500 561 559 112 112 70-130 0 Chromium ug1L 0.013 500 500 552 544 108 106 70-130 2 m g1L Copper uglL 0.011 500 500 593 589 116 116 70-130 1 mg1L Nickel uglL 0.012 500 500 548 544 107 106 70-130 1 mg1L Zinc ug1 0.085 500 500 534 621 110 107 70-130 2 mglL Results presented on this page are In the units indicated by the 'Units' column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 02/1512017 07:45 PM without the written consent of Pace Analytical Services, t.t.C. Page 5 of 13 "Anal] cal www.peceildblc m QUALITY CONTROL DATA Project: Bakers Stormwater Pace Project No.: 92329090 • t Pace Analytical Services, LLC 9B00 KinceyAve. Suite 100 ' Huntersvifle, NC 28078 (704)875-9092 QC Batch: 347724 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92329090001 METHOD BLANK: 1929056 Matrix: Water Associated Lab Samples: 92329090001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg1L ND 2.5 02/10/17 14:18 LABORATORY CONTROL SAMPLE: 1929059 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids m91L 250 240 96 '90-110 SAMPLE DUPLICATE: 1929060 92328982003 Dup r Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg1L 14.5 13.8 5 SAMPLE DUPLICATE: 1929061 92329112001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mglL ND ND Results presented on this page are In the units indicated by the "Units- column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2017 07:45 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 13 aceAnalytical wtrw.pacefeb�rxtm QUALITY CONTROL DATA Project: Bakers Stormwaler Pace Project No.: 92329090 OC Batch: 347491 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210B BOD, 5 day Associated Lab Samples: 92329090001 METHOD BLANK: 1927949 Matrix: Water Associated Lab Samples: 92329090001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg/L ND 2.0 02/13/17 23:40 Pace Analytical Services, LLC 9B00 Kincey Ave. Suite 100 HuntersviGe, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1927950 Spike LCS LCS % Rec Parameter I Units CQnc. Result %'Rec Limits Qualifiers BOD, 5 day mglL 198 170 86 84.6-115.4 SAMPLE DUPLICATE: 1927951 � .'rl = " ". '•• 92329036001 Dup Parameter Units Result'' Result RPD Qualifiers SOD, 5 day mglL ND ND. 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2017 07:45 PM without the written consent of Pace Analytical Services, LLC, Page 7 of 13 IReAnalytical —pacelebs.cortl Project: Bakers Stormwater Pace Project No.: 92329090 QC Batch: 347683 QC Batch Method: SM 5220D Associated Lab Samples: 92329090001 METHOD BLANK: 1928918 Associated Lab Samples: 92329090001 Parameter Units Chemical Oxygen Demand mglL QUALITY CONTROL DATA Analysis Method: SM 52200 Analysis Description: 5220D COD Matrix: Water Blank Reporting ResultLimit Analyzed Qualifiers NO f 25.0 02109117 22:59 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 ' Huntersville. NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1928919 F; f Spike LCS • LCS % Rec Parameter .,�Units ,Conc, Result %,Rec Limits Qualifiersq, -, -------------------- Chemical Oxygen Demand mg/L 750 754 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE:. 1928920 MS MSD '.-92329195001 Spike Spike Parameter Units . 'Result Cone. Conc, Chemical Oxygen Demand mglL 2110 750 750 1928921 MS MSD �MS MSD % Rec,-,,,, Result Result % Rec % Rec Limits' l RPD Qual 2600 2600 66 66 90-110 0 M1 MATRIX SPIKE S MATRIX SPIKE DUPLICATE: 1926922 1928923 MS MSD 9232908800"1 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone, Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mglL 38.0 750 750 798 795 101 101 90-110 0 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02115/2017 07:45 PM without the written consent of Pace Analytical Services, I.I.C. Page 8 of 13 aceAnalytical WWWpapdabscam QUALIFIERS Project: Bakers Stormwater Pace Project No.: 92329090 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted_ reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. - Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA Method 8260, N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270, The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services -Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded OC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 02/15/2017 07:45 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 13 auvAnalytiol wwrvpeowabs corn QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Bakers Stormwater Pace Project No.: 92329090 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID QC Batch Method GC Batch Analytical Method Analytical Batch 92329090001 BSW02 92329090001 BSW02 EPA 200.7- 347561, EPA 200.7 347718 92329090001 BSW02 SM 2540D 347724 92329090001 BSW02 SM 5210B 347491 SM 5210B 347499 ' 92329090001 BSW02 SM 5220D 347683 Date: 02/15/2017 07:45 PM iir REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 13 �aceAnalj&al Laboratory receiving_ samples: Asheville ❑ Eden[] uucumenc Warne: Uocument Revised: Sept. 21, 2016 Condition U on Recel t SCUR PaLe 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.01 Pace Quality_Office Greenwood ❑ Huntersville Q Raleigh[] Mechanicsville❑ �Ciierit Name: ITT Projectli WOV92329090 'Courier. OFed Ex MUPS ❑USPS lent (I I1� I A�III�I 4II El Commercial ❑Pace []Other: Il 1 92329390 Custody Seal Present? QYes (flo Seals Intact? []Yes io i?ate/initlah Person Examining Contents: Packing Material: ❑bubble Wrap. ubble Bags. -QNone ❑other: Thermometer: Guri 1D: �T 11 D Type of ice;"` ❑glue ❑�1ona ampler on ice, cooling process has begun Correction Factor. Coo.ler.Temp Corrected ('C): Biological T#ssue Froxen? QYes Bko ❑N/A Temp should be above free g to 61C USDA Regulated Soil ( /A, water sample) Did samples o hate fn a quarantine zone within the United States. CA, NY, orSC (check maps)? Did samples originate from a foreign source (€ntematlonally, Yes Including Hawaii and Puerto Rico)? []Yes -Ejko Comments/DlsereoancJ: Chain ofCustod Present? es ONO OXIA. 1 1. Samples Arrived within Hold Time? 534, No NIA 2. Short Hold Time Ana sls ,cn hr.)? Wes QN. n N A 3. Rush Turn Around Tlme Requested? Yes o N A 4. Sufficient Volume?' DY6 ❑No []NIA S. =orrect Containers Used? -P.ac : ntalners Used? es es []No Na ❑N/A N A 6. :ontatners'lntact? esEIN. N A 7. yarn fes Field Filtered? , Y No /A a. Note if sediment Is visible In the dissolved container ample labels Match CDC? -includes Dat me/ID/Ana) sls Matrix-. es ON, ❑N/A 9. leads ace In VOA Vials >5•6mm ? yes Q14o Ira 10. 'rip Blank present? ,rip Blank Custody Seals Present? ©Yes ❑Yes ❑No []No rNNI N/A 11. CUENTNOTIFICA71ON/RESOLLMON Person Contacted: Comments/Sample Discrepancy: 'Field Data Required? ❑Yes []No Date/Time: Project Manager SCURF Review: `r - Project Manager SRF Review: Date: aLA ote: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certlf cats, .Office (i.e. ut of hold, incorrect preservative, out of temp, fncorrect contaters) Page 11 of 13 m CD W N O W 3 9 m 0 0 N a A a x c ti 5 m � 4. Q � a '�•r m c � d rr o r r m n `c ^1 a M m fG 3 f�D m Q M � o gyp` D a c 4 06 A �. a rD d m r Itemk f"� :0* M � , or rt Q. 3 � r0„ CL _zzzz z BP4U-125 mL Plastic Unpreserved (N/A) (CI-) BP3U-250 mL Plastic Unpreserved (N/A) BPZU-500 mL Plastic Unpreserved (N/A) BP1U-1 liter PlasticUnpreserved (N/A) d O 10 3 rr S BP35-250 mL Plastic H2SO4 (pH c 2) (CI-) N- X C o _ ID O X BP3N-250 mL plastic HNO3 (pH c 2) '903Z-250 mL Plastic ZN Acetate & NaOH (>9)zzz 3 BP36250 mL Plastic NaOH (pH > 12) (C-) Cr n Cu M Q- WGIIJ41de-mouthed Glass jar Unpreserved 4� 3 O 00 Cr A Q. 0 M AG1U-I'liter Amber Unpreserved (N/A) (Cl-) ZZ Z Z Z Z Z 7 :7 AG IN-1 liter Amber HCl (pH c 2) IA q 3 w v O 0 AG3U-250 mL Amber Unpreserved (N/A) (Cl-) AGO-1 liter Amber H2SO4 (pH c 2) AG35-250 mL Amber H2SO4 (pH < 2) --gzz AG3A(DG3A)-250 mL Amber NH4CI'(N/A)(CI-) DG9H-40 mLVOA HCI (N/A) V69T-40 mL VOA Na2S203 (N/A) O V69U-40 mL VOA Unp,(N/A) DG9P-40 mL VOA H3PO4 (N/A) r -0 ■������MMMMM MENEM V/GlK (3 vials perkit)-VPH/Gas kit (N/A) PAN 0MOO IVA ME-MEV&W-20mLScin-tillationvials (N/A) M�■�MEN G PaceAna/yticai" www.pmxatsU-Urn Section A Required Client Wormabon: CHAIN -OF -CUSTODY I Analytical Request Document The Chaln-ol-Custody is a LEGAL DOCUMENT. A6 relevard fiieids must be completed accurately. Section B Section C Required Project Information: Invoice Information: r 0 M Page: ... �f pi m Comparry_ r RePon TC: Allonlien: V V V 70 . Address: • , Copy ToO;Z Company Name' REGULATORY AGENCY n Address: o-C NPDES !- UST 7 GROUND i- RGRA WATER r DRINKING WATER 3'- Orli1=R--- Email To: Pufchase Order No.: Pern Owte Reignq>t e: Phonm - inn: Projoel Nome: gp I/ / 4 /mitt SIZ 1^ ll , r P r project r�rmvo- Site Location STATE. Requested Due Date1TATt Protect Number: Pace Prosue a: Requested Analysis Filtered (YIN) Section D Mabix Codes -- z R.geuaCGenl Inlormainn MATPPK.r GODS 5 COLLECTED Preservatives 3,.: Dunking Water DW - �' Water. WT Waste Water YrMf C.1. Co cumpwnE cuwV405nE o W Produel P e * STARTSTART E Z soaked SL s t .}.. SAMPLE ID Oil .8 W ipel. (A•209!;jAir AR 0 W 0. m H o Sample IDs MUST BE UNIQUE Tissue TS Q U p. la.. w U Other OT zLu O h 0. m IL a iL Q O p =O to `m c i'1 0 0 _�'z cc n� a v m DATE TIME DATE TIME H 7C Z 2 M w Pace Project NoJ Lab I.D. 1 Sint ,rr r✓ S� ) 2 135 pJo=i, S ,3swe-,t w; C- Y% A.'/$� ! 4 -pi;, dqw .� S 6 7 8 9 10 71 42 ADDITIONAL COMMENTS RELINQUl3HED BY N AFFILIATION DATE TIME ACCEPTED BY I AFFILIATION DATE TIME SAtdPLE CONDITIONS J1y.3*'C-p1AJ4 -V. :rs C ORIGINAL SAMPLER N"E AND SIGNATURE U n ^ m a m n PRINT Nano of SAMPLER: �CW,,�� •SK a ' " v } m > t: - SIGNATURE of SAMPLER• t p (MMDONYY); 'Important Note, By MDrwV mis mean yru .teeaccepurvl Parr.. NFT so aty par wa term+ wWprevJ m i:no cluit Bf or 1.5% per mow+ for army -voe & ata paid .0n 30 days. F-ALLY-020rev.07. S SMay-2007 OATIAIIvac AllVac — Bakers Plant Stormwater Monitoring Deport Form Sample Date: a? -817 Sample Time: Sample Location: Person Collecting Samples: Laboratory Performing Analysis: Analytical Techniques and Methods: ILS welts of Sample Anaivsis: d -&Rd� Stormwater Discharge Outfall #03 ftn-Commie ed) Drainage Area = 336,580sq. ft. = T8 acres % Impervious = 15% 1��w,aP Pdae �R. t l�c�v;�i�Pa'i e pace Amedyf'ca.!_ 40 CFR Part 136 Parameter Results (mg/1) Benchmark Values (mg/1) BOD 30 COD 120 TSS 7 100 Cadmium NO 0.001 Chromium, total recoverable 0 . D /B1 1 Copper, total recoverable 0. 6 ? 0.007 Nickel, total recoverable 0.26 Zinc, total recoverable 41 0.067 pH (std units) 6-9 (std units) Storm Date: ,,Z — 8 -Z;? Storm Duration: J..2.f- I (Hrs.) Inches of Rainfall: 6 -6 d Duration of time preceding rain event exceeding 0.1 ": 266 (Hrs.) Estimated Flow Calculation: Q=CIA Q(Total) = Q(Pervious Area) + Q(Impervious Area) Q(tot., cfs) _ (.4 x inches rain/12 inches/ft. x 7.8 acres x .85) + .9 x inches rain/! 2inches/ft. x 7.8 x. 15) Q(Total, cfs) = 0.2210 x 0 . &0 (Inches of rain) + 0.0878 x ' • 6 D (Inches of rain) 19. /8-f " cfs aceAnalytical www.pace7ebs.com 1 February 15, 2017 Mr. Joe Hinkle Allvac RE: Project: Bakers Stormwater Pace Project No.: 92329091 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Dear Mr. Hinkle: Enclosed are the analytical results for sample(s) received by the laboratory on February 08, 2017, The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com Project Manager Enclosures cc: Mr. Preston Baucom, Allvac Mr. Tommy Long, Allvac David Pope, Allvac REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC, Page 1 of 16 Pace Analytical Services, LLC aceAmIXical * 9800 KinceyAve, Suite 100 HuntersviileNC 28078078 wwx`Pscefaftcom (704)875.9092 CERTIFICATIONS Project: Bakers Stormwater Pace Project No.: 92329091 Charlotte Certification IDs 9800 KinceyAve. Ste 100, Hunlersville, NC 28078 North Carolina Drinking Water Certification M 37706 North Carolina Field Services Certification M 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 FloridalNELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification M 37712 South Carolina Certification #: 99G06001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 VirginiWVELAP Certification #: 460221 North Carolina Wastewater Certification M 40 South Carolina Certification #: 99030001 VirginiwVELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 16 aceAnalytical wNw.pacelabacom SAMPLE ANALYTE COUNT Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Bakers Stormwater Pace Project No.: 92329091 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92329091001 BSW03 SM 2540D ALC 1 PASI-A 92329091002 BSW03 SM 5210B CJH1 1 PASI-A 92329091003 8SW03 SM 5220D MDW i PASI-A 92329091004 SSW03 EPA 200.7 SER 5 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 16 aceAnalj cal www.pscelebs.00m I ANALYTICAL RESULTS • 1 Pace Analytical Services, LLC , 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875r9092 Project: Bakers Stormwater Pace Project No.: 92329091 Sample: BSW03 Lab ID: 92329091001 Collected: 02/08/17 02:38 Received: 02/08/17 11:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 25400 Total Suspended Solids Total Suspended Solids Date: 02/15/2017 07:45 PM Analytical Method: SM 2540D 17.2 mg/L 2.5 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/10/17 14:37 Page 4 of 16 ac6Analytical www.pacelab&cam ANALYTICAL RESULTS Pace Analytical Services, LLC 98DO Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Bakers Stormwater Pace Project No.: 92329091 Sample: BSW03 Lab lD. 92329091002 Collected: 02/08/17 02:40 Received: 02108/17 11:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[ 5210E SOD, 5 day BOD, 5 day Analytical Method: SM 5210B 4.7 mg/L 2.0 1 02/09/17 03:25 02/13/17 23:40 Date: 02/15/2017 07:45 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 16 aceAnalytical —pa *abimn i ANALYTICAL RESULTS Project: Bakers Stormwater Pace Project No.: 92329091 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Hunlersviile, NC 28078 (704)875-9092 Sample: BSW03 Lab ID: 92329091003 Collected: 02/08/17 02:41 Received: 02108117 11:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 36.0 mg1L 25.0 1 02/09/17 22:59 Date: 02/15/2017 07:45 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced; except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 16 aceAna1j cal wwwpecelebs eam I ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Bakers Stormwater Pace Project No.: 92329091 Sample: BSW03 Lab [D: 92329091004 Collected: M08/17 02:43 Received: 02/08/17 11:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Collected By DPJ 1 02/09/17 12:01 Collected Date 02/08/17 1 02/09/17 12:01 Collected Time 02:55 1 02/09/17 12:01 Field pH 7.3 Sid. Units 0.10 1 02/09/17 12:01 Field Temperature 14.1 deg C 0.50 1 02/09/17 12:01 200.7 MET ICP Analytical Method: EPA 200,7 Preparation Method: EPA 200.7 Cadmium ND ug1L 1.0 1 02/09/17 21:00 02/13/17 18:28 7440-43-9 Chromium 18.6 ug1L 5.0 1 02/09/17 21:00 02/13/17 18:28 7440-47-3 Copper 76.7 ug1L 5.0 1 02/09/17 21:00 02/13/17 18:28 7440-50.8 Nickel ND ug/L 5.0 1 02/09/17 21:00 02113/17 18:28 7440-02-0 Zinc 66.4 ug1L 10.0 1 02/09/17 21:00 02/13/17 18:28 7440-66-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: =15/2017 07:45 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 16 m aceAnaljftal wwwpacelabacom I QUALITY CONTROL DATA Project: Bakers Stormwater Pace Project No.: 92329091 QC Batch: 347561 Analysis Method: EPA 200.7 QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET Associated Lab Samples: 92329091004 METHOD BLANK: 1928155 Associated Lab Samples: 92329091004 Matrix: Water Blank Reporting Parameter Units Result Limit Analyzed Cadmium ug/L ND 1.0 0211311717:01 Chromium ug/L ND &0 02I1311717:01 Copper ug1L ND 5.0 02/13/1717:01 Nickel ug1L ND 5.0 02/1311717:01 Zinc ug1L ND 10.0 02/1311717:01 LABORATORY CONTROL SAMPLE: 1928156 Parameter Units Cadmium ug1L Chromium ug/L Copper ug/L Nickel ug1L Zinc ug1L • f Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 500 556 111 85-115 500 554 111 85-115 500 573 115 85-115 500 547 109 85-115 500 558 112 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1928157 1928158 MS MSD 92329043019 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Cadmium ug1L ND 500 500 537 540 107 108 70-130 1 Chromium ug/L ND 500 500 521 538 104 108 70-130 3 Copper ug/L NO 500 500 546 559 109 112 70-130 2 Nickel ug1L ND 500 500 518 528 104 106 70-130 2 Zinc ug/L ND 500 500 528 539 105 108 70-130 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1928159 1928160 MS MSD 92328962003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Cadmium uglL ND 500 500 561 559 112 112 70-130 0 Chromium uglL 0.013 500 • 500 552 544 108 106 70-130 2 mg/L Copper uglL 0.011 500 500 593 589 116 116 70-130 1 mg1L Nickel ug1L 0.012 500 500 548 544 107 106 70-130 1 mg1L Zinc ug1 0.085 500 500 634 621 110 107 70-130 2 mg/L Results presented on this page are In the units indicated by the "Units' column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 02/15/2017 07:45 PM without the written consent of Pace Analytical Services, LLC, Page 8 of 16 aceAnalytir'cal n><w.psoslabs.00m f QUALITY CONTROL DATA Project: Bakers Stormwater Pace Project No.: 92329091 QC Batch: 347724 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92329091001 METHOD BLANK: 1929058 Matrix: Water Associated Lab Samples: 92329091001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg1L ND 2.5 02/10/17 14:18 Pace Analytical Services, LLC 9800 KlnceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1929059 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 240 96 90-110 SAMPLE DUPLICATE: 1929060 92328982003 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 14.5 13.8 5 SAMPLE DUPLICATE: 1929061 92329112001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L ND ND Results presented on this page are In the units Indicated by the 'Units- column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2017 07:45 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 16 aceAna1j cal www.pacglabs can I Project: Bakers Stormwater Pace Project No.: 92329091 QC Batch: 347491 OC Batch Method: SM 52108 Associated Lab Samples: 92329091002 METHOD BLANK: 1927949 Associated Lab Samples: 92329091002 Parameter BOD. 5 day QUALITY CONTROL DATA Analysis Method: SM 5210B Analysis description: 5210B BOD, 5 day Matrix: Water Blank Reporting Units Result Limit Analyzed Qualifiers mg/L ND 2.0 02/13/17 23:40 LABORATORY CONTROL SAMPLE: 1927950 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits BOD, 5 day mg1L 198 170 86 84.6-115.4 SAMPLE DUPLICATE: 1927951 92329038001 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L ND ND Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are In the units Indicated by the "Units" column except where an altemate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2017 07:45 PM without the written consent of Pace Analytical services, LLC. Page 10 of 16 Pace Analytical Services, LLC • aceAnalytical ® 9800 KinceyAve. Suite 100 Huntersville, NC 28078 wtvw.P8Ct*6s.cam 1 (704)875-9092 QUALITY CONTROL DATA Project: Bakers Stormwater Pace Project No.: 92329091 QC Batch: 347683 Analysis Method: SM 5220D QC Batch Method: SM 5220D Analysis Description: 5220D COD Associated Lab Samples: 92329091003 METHOD BLANK: 1928918 Matrix: Water Associated Lab Samples: 92329091003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chemical Oxygen Demand mg/L ND 25.0 02/09/17 22:59 LABORATORY CONTROL SAMPLE: 1928919 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg/L 750 754 101 90-110 MATRIX SPIKE d MATRIX SPIKE DUPLICATE: 1928920 1928921 MS MSD 92329195001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg/L 2110 750 750 2600 2600 66 66 90-110 0 M1 MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 1928922 1928923 MS MSD 92329088001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg/L 38.0 750 750 798 795 101 101 90-110 0 Results presented on this page are In the units Indicated by the "Unite" column except where an alternate unit is presented to the right of the resull. REPORT OF LABORATORY ANALYSIS This report shall net t)e reproduced. except in tull. Date: 02/1512017 07:45 PM without the written consent at Pace Analytical Services, LLC. Page 11 of 16 Pace Analytical Services, LLC aceAnalytical ® 9800 Ir KinceyAve. Suite 100 Huntersville, NC 28078 www.pgcolirbs.com (704)875-9092 i QUALIFIERS Project: Bakers Stormwater Pace Project No.: 92329091 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethyivinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services -Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 0211512017 07:45 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 16 4 C aceAnaljftal wrw.pacelaLs.mm QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Bakers Stormwater Pace Project No.: 92329091 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92329091004 BSW03 92329091004 BSW03 EPA200.7 347561 EPA200.7 347718 92329091001 BSW03 SM 2540D 347724 92329091002 BSW03 SM 5210B 347491 SM 5210B 347499 92329091003 BSW03 SM 5220D 347683 9 Date: 02115/2017 07:45 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 16 n aceAnayical Laboratory receiving samples: Asheville ❑ Eden[] uuLument ivame: vocument Revised: Sept. 21, 2016 Sample Condition U on Rece! t(SCUR) -PaLe i of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.01 Pace Quality Office Greenwood ❑ Huntersville [% Raleigh❑ Mechanicsville❑ • Client Name: Project # WO# : 92329091 1L -Courier: FedEx UPS USPS lent IIIIII I 11111111111111111 ❑ Commercial ❑Pace / []Other: 92329a93 Custody Seal Present? []Yes [jXo Seals Intact? ❑Yes EaNlo Date/lnitlah Person Examining Contents Packing Material: ❑Bubble Wrap Q4bble Sags E]None ❑other: Thermometer IR Gun ID: 'l I L ^'['�;� V� ❑ Type of ice: et 8lue ❑None "'pies on Ice, cooling prbce'ss has begun Correction Factor: Cooler Temp Corrected ('C): Bfological Tissue Frozen? ❑Yes ZNo ❑N/A Temp should be above fre ing to 6'C USDA Regulated soil ( N/A, water sample) Did samples Onate Ina quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a Foreign source (inter onally, ]Yes o including Hawaii and Puerto Rico)? []YesNo Chain of Custody Present? EVes ❑No N A 1. Samples Arrived within Hold Time? No N A 2. Short Hold Time Analysis 42 hr.? es No UNIA 3. Rush Turn Around Time Requested? Yes o ❑N A 4• Sufficient Volume?' es ❑No ❑N/A S. _orrect Containers Used? :QKs []No ❑N/A 6.. -Pece.Contalners Used? f"]Y'es nNn nNIA ;amples Field Filtered? ;ample Labels Match COC? -includes Date/'fime/ID/Anal sis Matrix: `!+ Leads ace In VOA Vials (>5-6mm)? 'rip Blank Present? r1p Blank Custody Seals Present? CLIENT NOTIFICATi0N/RESOLImt)N Person Contacted: Comments/Sample Discrepancy: Project Manager SCURF Review; Project Manager SRF Review: No N/A 7. No A S. Note If sediment is visible In the dissolved container. ❑No ❑N/A 9. Yes ❑Na %/A 30. ❑Yes []NO 01,91111. Field Data Required? ❑Yes ONO Date/nme: Date: ) ote: Whenever there Is a discrepancy affecting North Carolina compliance samples, a copy of this form wail be sent to the North Carolina DEHNA Certification Office li.e. ut of hair:; i .lcprrett preservative, out of temp, Incorrect containers) Page 14 of 16 Ln 0 Ch m a G m A 2 m 4 2 C 9 0 n ro Z ^ D C m (A m a ro A 3 �• O W c Q � A a � w s9 1 C 3 � a m Q EL p w m n 41 a m 5 IA a 0 n -0 m m 0 a ro r� at Itemn 7zzzzzzzzz-",L7z BP413-12S mL Plastic Unpreserved (N/A) (CI-) BP311-2S0 mL Plastic Unpreserved (N/A) BPZU-500 mL Plastic Unpreserved (N/A) BP1U-1 liter Plastic Unpreserved (N/A) XZ777ZL—,I<ZxI BP3S-2S0 mL Plastic HM4 (pH < 2) (Cl-) BP3N-2S0 mL plastic HNO3 (pH < 2) X1 7Z BPH--250 mL Plastic ZN Acetate &.NaOH (>9) BP3C-250 mL Plastic NaOH (pH a 12) (CI-) WGFU-Wide-mouthed Glass jar Unpreserved AG1U-1 liter Amber Unpreserved (N/A) (Cl-) 7—,Zzz—z/zV7z jz Z AGiH-1 liter Amber HCI (pH < 2) AG3U-ZS0 mL Amber Unpreserved (N/A) (CI-( AG15-1 liter Amber HZSO4 (pH < 2) AG3S-250 mL Amber H2SO4 (pH c 2) AG3A(DG3A)-2S0 mL Amber NH4CI {N/A)(CI-) DG9H-40 ml.VOA HCI (N/A) VG9T-40 mL VOA Na2S203 (N/A) VG9U-40 mL VOA Unp (N/A) � M MITI%III%% DG9P-40 mL VOA H3PO4 (N/A) VOAK (6 vials per kit)-503S kit (N/A) V/GK (3 vials per kit}VPH/Gas kit (N/A) SPST-12S ml. Sterile Plastic ( N/A —lab) SP2T-2S0 mt Sterile Plastic (N/A —lab) O 3 °* CL 3 =r O pL- 1� N a A -%3 " - Er C 6f x LSD C, N a, a a tD Cr CLIM O x ••., = n C Cr w nr O k Cr go a- �-h O Pf d � S � � O m n � .w► r1 v 0 ^ c o nt C 7 w o r. :a 7-7 co c A a c ^ ro � N n C A at = r6-0 � z O m c Co _ ran w 1 m c z a JpQA c n .0 N o N w N 72 a •� µ m N (AD O ♦ Q1 N r J PiceAnalytical' e .psnlstts.mm Section A Required Client informalion: CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section B. Section C Required Project Information: Invoice Inlom+atiom Pegs: of Company t r Report To: �unr°�c[/I Altenl'ron'. �e/�ltison Address: Copy To: ,� In4, Company Name: , f'c'i« l' r,�r% REGULATORY AGENCY Address: .� `db SC /Yrcnro� .;UC X NPOES GROUND r-- UST RCRA WATER !❑RINKING WATER. i OTHER Email To. Purchase Order No.: Toe �e RefCrronw Phpie' �!� _ r Fax; Project Name: 'L KFrs 57tt, jPr (✓f Pay Reprt Mana9m; Site Location STATE. NG RequrroMd Due DaielTAT: Project Number, Pace proilo u; Requested"Analysis Filtered (YIN) Section D Matrix Codas — 2 Requited Cliunt lniaroatton MATRI. (.,CODE — e COLLECTED Preservatives .—y Drinarq Wale. DW p O Wale, WT _ Waste Product WW �� g� Fcompos"W _ z } = .r► SAMPLE ID oil wP — Cr n 03 c {A-Z.0-91,-I Air AR p Lu a a Z m F G L Sample IDs MUST BE UNIQUE Tissue TS O a H Z • ul C7 a Other m X w ~ O J U u°Vi O c w Q' V is � w a s Q O �`«z C1 m� = w DATE TIME DATE TIME ra a _ = 2 Z z 2 O V tY Pace Project NoJ Lab I.D. z j3 i,l as !fr G - A: 9&- % 1 oo-L a g15 ; -"7'� //19,1 D03 a 55W05 L= -F z ig s s 7 s 9 to tz LL ADDITIONAL COMMENTS RELiNOUISNED BY f AFFILIATION DATE TIME ACCEPTED BY I AFFTLIATION DATE TIME SAMPLE CONDITIONS f i, 1, -A 3Sc&.- !, 3 ORIGHNAL SAMPLER NAME AND SIGNATURE c o a PRINT Name of SAMPLER: 11 T SIGNATURE of SAMPLER: DATE S;g"edv 1MM1DON!YY)t �l Y} Or �._ L U rY r1 N r j 'Impmlanl Nolu: By skrnm this form yort orc ncra O q Poce s NET 30 day payment Como and t .7wi g to Cite. chnrin nl 1.5% per month for any invoices nrr'prod w;min 30 Tan F-ALL-0-020rev.07, 15-May-2o07 Allvac - Bakers Plant Stormwater Monitoring Report Form Sample Location: Person Collecting Samples: Laboratory Performing Analysis: Analytical Techniques and Methods: Results of Sample Analysis: Non-ContactCooling Wastewater 40 CFR Part 136 iirATI Non- Total Temperature Contact Sampling Sampling Estimated Residual pH (std. units) Cooling Date Time Flow(MGD) Chlorine Effluent Downstream Upstream Water # (mg/L) jfojac .SSA 3 - - -s. a,. D. ooa �..� 3, �'� s s soot 7 5 ,0 a 19. 0036 41.0 °4- ids °0- 6 3- D-' .� . DD .3 .3°� 3 Ir. 0% /4 .�. . Duo .10C 5 �E s' 3°� 8 -I3- �s's�. . 04930 49.3/ 19, o°G Ar 64 6. r°� % STORM EVENT CHARACTERISTICS: Date .1 $ -17 Total Event Precipitation (inches): 0.66 Event Duration (hours): 3 . a s (if more than one storm event was sampled) Date TOW Event Precipitation (inches): Event Duration (hours): Mall Original and one copy to: Division of Water Quality Attu: Central Fifes 1617 Mail Service Center Raleigt4 North Carolina 27699-1617 "I certify, under penalty of law, that this document and aft attachments were prepared under my direction or supervision in accordance with a system designed to -assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the Information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete- I am aware that there are significant penalties for submitting false information, Including the possibility of fines and imprisonment for knowing violations." 4----'9-2�qnA Av�r—l? (Signature of Permittee) (Date) Fors SWCS-246-051100 Page 2 of 2 STORMWATER DISCHARGE OUTFA.LL (SDO) MONITORING REPORT Permit Number. NC. _ S0QQ_?aZ 9 or Certificate of Coverage Number: NCG FACILTTY NAME ✓Q.G PERSON COLLECTING SAMP i_P PA& VA c CERTIFIED LABORATORY(S) sae Lab #-- .2 - - Lab # Part A: Specific Moultoring Requirements SAMPLES COLLECTED DURING CALENDAR YEAR: Q701T (This monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) COUNTY &A4�A FHONFlqq.. - S (SI(;NATURE ERMTITER OR DESIGNEE) By this signature, I certify that. this report is accurate complete to the best of my knowledge. Outfall Date No, Sample 050 talCollected rFlow molddlyr I MG 3 Wb3 Id-08-/7A- 5- Does this facility perform Vehicle Maintenance Activities using more than SS galions of new motor oil per month? —yes --no (if yes, complete Part B) Part B: Vehicle Maintenance Acd MorAtorliag Requirements Outfail Date 50050 005% 1 Dos" FO 00 No. Sample Total Flow Oil and Total pH New Motor Collected Grease Suspended 011 Usage Pam SWU-246-051100 Page I of 2 Pace Analytical Services, LLC a� f� f� 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 w wpacew&mn (704)675-9092 February 21, 2017 Mr. Joe Hinkle Allvac N RE: Project: NONCONTACT COOLING WATER Pace Project No.: 92329851 Dear Mr. Hinkle: Enclosed are the analytical results for sample(s) received by the laboratory on February 14, 2017. The results relate only to the samples included in this. report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com Project Manager Enclosures cc: Mr. Preston Baucom, Allvac Mr. Tommy Long, Allvac David Pope, Allvac REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. LLC. Page 1 of 19 Pace Analytical Services, LLC acemalyticale 980D ney Ave. Suite 100 Muntersville, NC 28078078 www4mceAftcora (704)875-9092 CERTIFICATIONS Project: NONCONTACT COOLING WATER Pace Project No.: 92329851 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 South Carolina Certification #: 99006001 North Carolina Drinking Water Certification #: 37706 Florida/NELAP Certification #: E87627 North Carolina Field Services Certification #: 5342 Kentucky UST Certification #: 84 North Carolina Wastewater Certification #: 12 VirginiaNELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, INC 28804 North Carolina Wastewater Certification #: 40 Florida/NEIAP Certification #: E87648 South Carolina Certification #: 99030001 Massachusetts Certification #: M•NCO30 VirginiaNELAP Certification #:'460222 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not he reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 19 aceAnaiXical wnw.AWOroru SAMPLE'ANALYTE COUNT Project: NONCONTACT COOLING WATER Pace Project No.: 92329851 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID Method Analysts Analyses Reported Laboratory 92329851001 BAKERS NON CONTACT #1 EPA 1664B JMS 1 PASI-C SM 4500-Cl G ''MDW 1 PASI-A 92329851002 BAKERS NON CONTACT #2 EPA 16648, JMS 1 PASI-C SM 4500-CI G " MDW y, 1 .PASI-A 92329851003 BAKERS NOWCONTACT #3 EPA 1664E JMS 1 PASI-C SM 4500-Cl G "MDW 1 PASI-A 92329851004 BAKERS NON CONTACT #4 EPA 1664E JMS 1 PASI-C SM 4500-CI G MDW 1 PASI-A 92329851005 BAKERS NON CONTACT #5 EPA 1664E JMS 1 PASI-C 5M 4500-CI G MDW ' 1 PASI-A 92329851006 BAKERS -NON CONTACT #6 EPA 1664B JM5 1 PASI-C SM 45007C1 G MDW 1 PASI-A 92329851007 BAKERS NON CONTACT #7 EPA 1664E JMS 1 PASI-C SM 4500-Cl G ' MDW 1 PASI-A 92329851008 BAKERS NON CONTACT #8 EPA 1664E JMS 1 PASI-C SM 4500-CI G MDW .1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC, Page 3 of 19 aceAnaljftal` wwwpecelebsoorn ANALYTICAL RESULTS Project: NONCONTACT COOLING WATER Pace Project No.: 92329851 Pace Analytical Services, LLC 9800 KlnceyAve. Suite 100 I Huntersville, NC 28078 (704)875-9092 Sample: BAKERS NON CONTACT Lab ID: 92329851001 Collected: 02/13/17 09:20 Received: 02/14/17 10:36 Matrix: Water #1 Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mg/L 5.0 1 ',T '1-02121117 D8:D1 +,1' . 4500CL G Chlorine, Residual Analytical Method: SMA500-CI G Chlorine, Total Residual 0.22 mg lL 0.024 1 i 02/15117 00'36 7782 50-5 D6,H3 r Date: 02/21/2017 06:19 PM REPORT OF LABORATORY ANALYSIS This report shall not he reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 19 • aceAnalytical" www.pacwftow ANALYTICAL RESULTS Project: NONCONTACT COOLING WATER Pace Project No,: 92329851 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersviffe, NC 28078 (704)875.9092 Sample: BAKERS NON CONTACT Lab ID: 92329851002 Collected: 02/13/17 09:41 Received: 02/14/17 10:36 Matrix: Water #2 Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Oual HEM, Oil and Grease Analytical Method: EPA 16646 Oil and Grease ND mglL 5.0 1 02/21/17 08:02 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G ,, ry,.• Chlorine, Total Residual ND mglL 0,024 1 02/15/17 00:36 7782-50-5 H3 Date: 02/21/2017 06:19 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wntten consent of Pace Analytical Services, LLC. Page 5 of 19 aeeAnalyiical wracpacam ANALYTICAL RESULTS Project: NONCONTACT COOLING WATER Pace Project No.: 92329851 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: BAKERS NON CONTACT Lab Il): 92329851003 Collected: 02/13117 09:55 Received: 02/14/17 10:36 Matrix: Water #3 Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua] HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mglL 5.0 1 02/21/17 08:02 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G Chlorine, Total Residual 1.3 mg1L 0.24 10 02/15/17 00:36 7782-50-5 H3 Date: 02/21/2017 06:19 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 19 .• aceAnafytical K+vw.patalebstam ANALYTICAL RESULTS Project: NONCONTACT COOLING WATER Pace Project No.: 92329851 Pace Analytical Services, LLC 9800 Kincey Ave, Suite 100 Huntersvilte, NC 28078 (704)875-9092 Sample: BAKERS NON CONTACT Lab ID: 92329851004 Collected: 02/13/17 10:12 Received: 02/14/17 10:36 Matrix: Water #4 Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Oual HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mglL 5.0 . 1 . 02/21/17 08:02 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G Chlorine, Total Residual 0.83 mg/L 0.096 4 02/15/17 00:36 7782-50-5 H3, Date: 02/21/2017 06:19 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 19 aceAnalytical e www.pecefebs.00m ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersyille, NC 28078 (704)875-9092 Project: NONCONTACT COOLING WATER Pace Project No.: 92329851 Sample: BAKERS NON CONTACT Lab ID: 92329851005 Collected: 02/13/17 10:27 Received: 02/14/17 10:36 Matrix: Water #5 Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mg1L 5.0 1 02/21/17 08:04 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G Chlorine, Total Residual 4.0 mg/L 0,48 20. 02/15/17 00:36 7782-50-5 H3 Date: 02/21 /2017 06:19 P M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 19 27XAnalytical »aw.pacelabs cam ANALYTICAL RESULTS Project: NONCONTACT COOLING WATER Pace Project No.: 92329851 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: BAKERS NON CONTACT Lab ID: 92329851006 Collected: 02/13/17 10:45 Received: 02/14/17 10:36 Matrix: Water #6 Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mg1L 5.0 1 0212i117 08:04 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G ChlorineJotal Residual 2.3 mglL 0.24 10 02/15/17 00:36 7782-50-5 ,., H3 Date: 02121/2017 06:19 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 19 aceAnalytica! www.patala mm ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NG 28078 (704)875.9092 Project: NONCONTACT COOLING WATER Pace Project No.: 92329851 Sample: BAKERS NON CONTACT Lab ID: 92329851007 Collected: 02/13/17 10:57 Received: 02/14/17 10:36 Matrix: Water #7 Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua] HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mg1L 5.0 1 02/21/17 08:04 4500CL G Chlorine, Residual Analytical Method: SM 450"1 G Chlorine, Total Residual 2.4 mg1L 0.48 20 02/15/17 00:36 7782-50-5 H3 Date: 02/21/2017 06:19 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 19 aceftiXical »tivw.pacmftcom ANALYTICAL RESULTS Project: NONCONTACT COOLING WATER Pace Project No.: 92329851 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: BAKERS NON CONTACT Lab ID: 92329851008 Collected: 02/13/17 11:15 Received: 02/14/17 10:36 Matrix: Water #8 Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mg1L 5.0 1 02/21/17 08:05 4500CL G Chlorine, Residual Analytical Method: SM 4500-Cl G Chlorine, Total Residual 0.31 mg/L 0.024 1 02115/17 00:36 7782-50-5 1-11 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced• except in full, Date: 02l2112017 06:19 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 19 aeeAnalytical www.pamistis.com QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: NONCONTACT COOLING WATER Pace Project No.: 92329851 QC Batch: 349110 Analysis Method: EPA 1664E QC Batch Method: EPA 1664B Analysis Description: 1664 HEM, Oil and Grease Associated Lab Samples: 92329851001, 92329851002, 92329851003, 92329851004, 92329851005, 92329851006, 92329851007, 92329851008 METHOD BLANK: 1936691 Matrix: Water Associated Lab Samples: 92329851Gt}1, 92329851002, 92329851003, 92329851004, 92329851005, 92329851006, 92329851007, 92329851008 < Blank Reporting Parameter Units Result Limit 'Analyzed Qualifiers Oil and Grease mg/L ND 5.0 02/21/17 07:51 LABORATORY CONTROL SAMPLE: 1936692 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Oil and Grease mg/L 40 37.4 94 78-114 MATRIX SPIKE SAMPLE: 1936693 92330121001 . Spike MS MS % Rec Parameter Units Result Conc. Result %Rec Limits Qualifiers Oil and Grease mglL ND 40 35.7 89, 78-114 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/21/2017 06:19 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 19 • Pace Analytical Services, LLC • aceAnaly�ical to 9800 Kinsey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: NONCONTACT COOLING WATER Pace Project No.: 92329851 QC Batch: 348230 Analysis Method: SM 4500-CI G QC Batch Method: SM 4500-CI G Analysis Description: 45006L G Chlorine, Total Residual Associated Lab Samples: 92329851001, 92329851002, 92329851003, 92329851004, 92329851005, 92329851006, 92329851007, 92329851008 METHOD BLANK: 1932083 Matrix: Water Associated Lab Samples: 92329851001, 92329851002, 92329851003, 92329851004, 92329851005, 92329851006; 92329851007, 92329851008 I' Blank Repotting Parameter Units Result Limit Analyzed Qualifiers Chlorine, Total Residual mg1L 'ND 0A24 02I15117 00:36 ' SAMPLE DUPLICATE: 1932084 .92329851001 Dup Parameter Units Result Result RPD Qualifiers Chlorine, Total Residual mg/L 022 0.30 29 D6,H3 4 f Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 02/21/2017 06:19 PM without the written consent of Pace Analytical Services, LLC. 0 Page 13 of 19 acMnaljftal www.pacelahscarrr QUALIFIERS Project: NONCONTACT COOLING WATER Pace Project No.: 92329851 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated"corcentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. POL - Practical Quantitation Limit. , Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, 128078 (704)875-9092 RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is, a combined concentration. ,Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and li values. LCS(D) - Laboratory Contiol Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Ctean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 isrecommended in SW846 Chapter 4 for the analysis of Acroiein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is'a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/21/2017 06:19 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 19 a aCeAnalytlCal wwwwallbbs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: NONCONTACT COOLING WATER Pace Project No.: 92329851 Pace Analytical Services, LLC 9800 Kincey Ave, Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92329851001 BAKERS NON CONTACT #1 EPA.1664B 349110 , 92329851002 BAKERS NON CONTACT•#2 EPA 1664B 349110 92329851003 BAKERS NON CONTACT #3 EPA 1664B ., 349110 ; . '` • Y i 92329851004 BAKERS NON.CONTACT 04 EPA 1664E 349110 92329851005 ' ' BAKER&N— dN CONTACT #5 ' EPA 16641i' 349110 92329851006 BAKERS NON CONTACT,#6 . EPA 1664B 34911(1, 92329851007 BAKERS NO CONTACT #7 EPA 1664B 349110 a 92329851008 BAKERS NON CONTACT #8 EPA 1664B 349110 923298510011° BAKERS NON CONTACT.#1' SM 4500 CI G 348230 92329851002 ;BAKERS NOWCONTAlit#2: SM 4500-CI G 348230 92329851003 BAKERS'N6Nr60NTACT.#3 SM 4500-CI G 348230 - 92329851004 BAKERS NON CONTACT #4 SM 4500,CI G 348230 92329851005 BAKERS NON -CONTACT #5 SM 4500-C! G 348230 + 92329851006 BAKERS NON CONTACT•06 — - - SM 45'00-CI G 348230 �� 92329851007 -BAKERS NON CONTACT #7 SM 4500-',CI G ; 348230 • . ''? ° " t ` A rF: '. ''� 985:348230 92321008 T BAKERS NON CONTACT #8 SM 4500-CI G ; 348230 r REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/21 /2017 06:19 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 19 �OA1780k8le uocument Name: Document No.: F-CAR-CS-033-Rev.01 Document Revised: Sept. 21, 2016 Page 1 of 2 Issuing Authority: Pace Quality Office Laboratory receiving samples: Asheville ❑ Eden[] Greenwood[] HuntersvillJRaleigh❑ Mechanicsville[] Client N me: Wp#.. 922 29851 g f Project . , . 7 u !! o tier:. C F Ex ilent ❑ ed UP5 LISPS ❑C ElCommercial g0ace ❑Other. 92329651 ' Custody Seal Present? ❑Yes N0 Seals Intact? ❑Yes `{JNci Date/Initials Person Examining Contents:' Packing Material: ❑Bubble Wrap O#ubble Bags ❑None ❑Other: Thermometer: OGun Ia: -�C� Type of Ice- 01+ t ❑Blue ❑None `- asrn pies on Ice, cooling process has begun Correction Factor: Cooler Temp Corrected (T): I A 1_ Blological Tlssue Frozen? []Yes \goNo ❑N/A Temp should be above freezing to VC USD A Regulated S01.1 � �i/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? old samples originate from a foreign source (Int m tionally, Yes ON6 including Hawaii and Puerto Rito)?,❑Yes ' Comments/Discreoancv: . Chain of Custody Present? e: QNO ❑N/A J 1. Sam es Arrived within. Hold Time? s No Q N/A . 2. Short Hold Time Anal is <72 hill? Yes o N A 3. I• Rush Turn Around Time Requested? ❑Yes o N A 4. Snffkient Volume?' Ves No ❑ti/A 5. Correct Containers Used? toes ©No ❑N/A 6. -Pace Containers Used? C91s. No N%A Contalners Intact?. QN. ❑N/A 7, Sam les Field Filtered? . yes Na }A 8. Note if sediment Is Visible In the dissolved container., Sample Labels Match COC? fel []No ❑N/A 9. -Includes Dak me/ID/Anal sis Matrix: NL 1 `- Heads ace In VOA Vials (>5-6mm)? []Yes No figIA 10. Trip Blank Present? Oyes ❑N/A 11. Trip Blank Custody Seals Present? Yes \ No /A CLIENT NOTIFICATION/RESOLUTION Field Data Required? []Yes ❑No Person Contacted: _ _ Date/Time: Comments/Sample Discrepancy: Project Manager SCURF Review: �� r`7 Date: 1` Project Manager SRF Review: C-C Date: a Note: whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, Incorrect preservative, out of temp, Incorrect containers) Page 16 of 19 1+ Y O~ iC Q7 V Ol lA L W !J M Af F+ item# 7ZZZZZZZZZ77 BMU-125 mL Plastic Unpreserved (N/A).(O-) BP31)-250 mL Plastic Unpreserved (N/A) BPZU-S00 mL Plastic Unpreserved (N/A) 8PIU-1 liter Plastic Unpreserved (N/A) 8P3S-250 mL Plastic H2W4 (PH < 2) (CI-) 8P3N-250 ml. plastic HNO3 (PH < 2) BP32-250 mL Plastic ZN Acetate & WON (>9) zzzMC-250 mL Plastic NaOH (pH > 22) (CI-) WGial-Wide-mouthed Glass jar Unpreserved 7zz AGIU-I liter Amber Unpreserved (N/A) (CH AGIN- L liter Amber HCI (pH < 21 A63U-250 mL Amber Unpreserred (N/A) (CI-) AGiS-i liter Amber H2SO4 (PH < 2) AG35-2S0 mL Amber H2SO4 (pH c 2) AGM(DGU)-2S0 mL Amber NH4CI (N/A)(CI-) DGSH-40 nil. VOA HCI (NIA) VG97-40 mL VOA Na2S203 (N/A) V69U-40 mL VOA Unp (N/A) DG9P-40 mL VOA H3PO4 (N/A) VOAK (b vials per kit)-5035 kit (NIA) V/GK 13 vials per kit}VPH/Gas kit (N/A) SPST-315 ml. Sterile Plastic (N/A — lab) SPZT-250:mLSterilePlastic (NIA —lab) 13P3A-250 mL Plastic (NH2)2SO4 (93-9.7) Cubitainer ML1U 20 mL Scintillation vials (N/A) GN 0 Storm Water Monitoring (NON CONTACT) Baker north Chal rof Custody Record jw ATI Specially Materials page #2 Project Number/Name: NonContact Cooling Water Project location: AIIvac Baker Sampler's Signature: „v n Ui tc� Date: �2 - ♦' w c w lL d d 4 �, ' a +� a �aa u 9 i+ a g O Requested Test Parameters: CIO-Zc�1 G G HCL Y ,3'r Oil &Grease fl, G G HCL Y `` Oil & Grease G G HCL . Y :3, o oil & Grease G G HCL Y Ad,6`< Oil & Grease G G HCL Y ' 13 Oil St Grease !! G G HCL Y 3`` oil &Grease ' ,cLf "' •'s7, G G HCL Y /L" oil & Grease /�'ryNrjPCaf% 4 �'� G G HCL Y Oil & Grease Meter Calibrated: K/ N IThermometer Calibrated: / N Sampling and Field analysis completed by: 2c , Relinquished B : !F Relinquished e : Date rime: jDate : Time: 10 3 tE., Relinquished By: „ ° ,,1r... _ Reiin uished r ; ' Date.,-? - Time: J 3 Date: -7 LI Q I Time: ENS Baker South SW REV # 2 5/10/2016 Page 18 of 19 Storm Water Monitorine (NON CONTACT) Baker North Chain of Custody Record ATI Spoewty MMUIS page 101 Project Number/Name: NonContact Cooling Water. Project Location: Allvac Baker Sampler's Signature:. ,v 4, -. II% Date;'R - J- % CL E a) a w i= a E i a a 49 c �' 2 � 0 a h a 2 Av O u Iv aRequdsted a •' C Test Parameters dt-13 G G/,V None Y LQ3%,3°` Residual Chlorine .. Gp- None Y Z 9, °c- Residual Chlorine G G/$ None Y 3. '6 Residual Chlorine G G None Y 3L',;`x Residual Chlorine G 6/0 None Y 9, Residual Chlorin , r,.., G I G/Ip None Y 2, e ljq Residual Chlorin G GAP None Y °c Residual Chlorine i Naar:� % ems, G GA None Y 9, C c`' Residual Chlorine Meter Calibrated: / N Thermometer Caiibirated j N Sam ling and Field analysis completed by: .v Relinquished By: Received By: •� i,__ ; r✓+L Date: .3 - y -2 ITIme: d, .' 1 ,w Date: Time: Relinquished By: , �,,,, ;_ cf Received By , . .• i Date : - _ Time: '; Date: Time: 7�10 EHS Baker South SW REV # 2 5/10/2016 Page 19 of 19 AI IF, NCDENR Stormwater Discharge Outfall (SDO) Qualitative monitoring Report Forguidance on filling out thisform, please visit: http://nortal.ncdenr.oi•gfwcbj g/ws/su%pdessw##tab-4 Permit No.: ]+�/�/3/O/Q/Q//,�/Q/ or Certificate of Coverage No.: Facility Name: County: ' A Phone No.Dy aZ89� �l Inspector: lava Date of Inspection: Time of Inspection: 4,,194--„_—__.__.�.,. Total Event Precipitation (inches): 0 .60 Was this a "Representative Storm Event" or "Measureable Storm Event" as defined by the permit? (See information below.) Z<Yes ❑ No Please verify whether Qualitative Monitoring must be performed during a "representative storm event" or "measureablestorm event" (requirements vary, depending on the permit). Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be performed during a "representative storm event" or during a "measureable storm event." However, some permits do not have this requirement. Please refer to these definitions, if applicable. A "representative storm event" is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred: A single storm event may contain up to 10 consecutive hours of no precipitation. A "measurable storm event" is a storm event that results in an actual discharge from the permitted site outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local storm events during the sampling period, and the permittee obtains approval from the local DWQ Regional Office. By this signature, 1 certify that this report is accurate and complete to the best of my knowledge: 1. Outfall Description: Outfall No. S_W01— Structure (pipe, ditch, etc.) Spar Receiving Stream: Pry 669- reee,,K Describe the industrial activities that occur within the outfall drainage area: 2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: _ 3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): A(DI✓G I _ _ 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: ® 2 3 4 5 S. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: ® 2 3 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: ® 2 3 4 5 7. is there any foam in the stormwater discharge? Yes 8. Is there an oil sheen in the stormwater discharge? Yes 9. Is there evidence of erosion or deposition at the outfall? Yes 10. Other Obvious Indicators of Stormwater Pollution: List and describe ADge Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 5WU-242, Last modified 10/25/2012 A yc"W, NCDENR Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance onfillingout thisform,please visit: http_//12orW.nccicnr.oWweb/wg/w-s/su/npdessw#ftab-4 Permit No.: or or Certificate of Coverage No.: Facility Name: ATr,A([/.c-BaXerr „ County: _ 467;an ___ __ _ Phone No. Inspector: 3K • _ _ Date of Inspection: o fV7 _ _T Time of Inspection: a? - ; ort Total Event Precipitation (inches): _ _.a. 40 Was this a "Representative Storm Event" or "Measureable Storm Event" as defined by the permit? (See information below.) �es ❑ No Please verify whether Qualitative Monitoring must be performed during a "representative storm event" or "measureahle storm event" (requirements vary, depending on the permit). Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be performed during a "representative storm event" or during a "measureahle storm event." However, some permits do not have this requirement. Please refer to these definitions, if applicable. A "representative storm event" is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred: A single storm event may contain up to 10 consecutive hours of no precipitation. A "measurable storm event" is a storm event that results in an actual discharge from the permitted site outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local storm events during the sampling period, and the permittee obtains approval from the local DWQ Regional Office. By this signature, I certify that this report is accurate and complete to the best of my knowledge: Pd 4 I. Outfall Description: Outfall No. W(9-? Structure Receiving Stream: AZ 116-71-0 pe, ditch, etc) Describe the industrial activities that occur within the outfall drainage area: 2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: 3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): AIWAle 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 2 b 4 5 S. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: 1 ® 3 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: 2 3 4 S 7. Is there any foam in the stormwater discharge? Yeso 8. Is there an oil sheen in the stormwater discharge? Yes 9. Is there evidence of erosion or deposition at the outfall? Yes 10. Other Obvious Indicators of Stormwater Pollution: List and describe /YDiz e Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation Page 2 of 2 SM-242, Last modified 10/25/2012 �`r'.`+ NCDENR Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report Forguidance on filling out thisform, please visit: h t t 2://aortal.ncdenr.ore/web/wq/ws/su,Lnpdessw#tab-4 Permit No.: or Certificate of Coverage No.: Facility Name: _ .� 411A C -Bak&7-- County: ahl+on Phone No. Joy-aBi��IS// Inspector: 1.4✓ia Date of Inspection: Time of Inspection: SR Total Event Precipitation (inches): D • 610 Was this a "Representative Storm Event" or "Measureable Storm Event" as defined by the permit? (See information below.) f✓J Yes ❑ No Please verify whether Qualitative Monitoring must be performed during a 'representative storm event" or "measureable storm event" (requirements vary, depending on the permit). Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be performed during a "representative storm event" or during a "measureable storm event." However, some permits do not have this requirement. Please refer to these definitions, if applicable. A "representative storm event" is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no precipitation. A "measurable storm event" is a storm event that results in an actual discharge from the permitted site outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local storm events during the sampling period, and the permittee obtains approval from the local DWQ Regional Office. By this signature, I certify that this report is accurate and complete to the best of my knowledge: 1. - Outfall Description: Outfall No. _ 5-AW03 _ Stru Receiving Stream: Describe the industrial activities ditch, etc.) that occur within the outfall drainage area: 2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: 3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): 1✓me- _ 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: ® 2 3 4 5 5. FIoating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: 2 3 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: 1 © 3 4 5 7. Is there any foam in the stormwater discharge? Yes S. Is there an oil sheen in the stormwater discharge? Yes 6 9. Is there evidence of erosion or deposition at the outfall? Yes 10. Other Obvious indicators of Stormwater Pollution: List and describe Aloo e- Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 Sw1J-242, Last modified 10/25/2012