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NCS000329_MONITORING INFO_20160114
STORMWATER DIVISION CODING SHEET NCS PERMITS PERMIT NO. Cs (ood -�>Z9 DOC TYPE ❑FINAL PERMIT MONITORING REPORTS-- - --- - ---- --- ❑ APPLICATION ❑ COMPLIANCE 0 OTHER DOC DATE ❑ �I�. ol• YYYYMMDD STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT Permit Number: NC-S I) g6.32 q or SAMPLES COLLECTED DURING CALENDAR YEAR: -0—/5 Certificate of Coverage Number: NCG (This monitoring report shall be received by the Division no later than 30 days from J the date the facility receives the sampling results from the laboratory.) FACILITY NAME S I f r COUNTY PERSON COLLECTING SAMPLEO)rdz PHONE O. ' CERTIFIED LABORATORY(S) Lab #�� Lab # (SIGNATURE 08 PERM&rEE OR DESIGNEE) By this signature, I certify that this report is accurate complete to the best of my knowledge. Part A: Specific Monitoring Requirements T_ s ,Dateii Collected ,. Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? — yes Vno (if yes, complete Part B) Part B: Vehicle Maintenance Activity Monitorinit Requirements Outfall No. Date Sample Collected 50050 00556 00530 00400 Total Flow Oil and Grease Total Suspended Solids pH New Motor Oil Usage moldd/ r MG m m unit allmo Form SWU-246-051100 Page l of 2 h STORM EVENT CHARACTERISTICS: Date /, = /%-/S ,, Total Event Precipitation (inches): A ,Z5 Event Duration (hours): _412) (if more than one storm event was sampled) Date Total Event Precipitation (inches): Event Duration (hours): Mail Original and one copy to., Division of Water Quality Attn: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." /-//� 1-16 (Signature of Perntittee (Date) Form SWU-246-051100 Page 2 of 2 January 20, 2016 Attn: Central Files N.C. Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 Central Files: RECEIVED JAN 2 6 2016 CEN7'RAf FILES BwR SECTION OATI P.O. Box 5030 2020 AshcraA Avenue Monroe, NC 281 l 1-5030 Phone: (704) 289-4511 Fax: (704) 290-5194 Eanail: joe.hinkle(a?atimetals.com Attached, please find stormwater monitoring data for Permit No NCS000329. The originals and one copy are included. The monitoring data is for the following monitoring schedule: Monitoring Period Sample Number I Start I End Year 6 — Period 2 12 1 September 1, 2015 1 February 29, 2016 Analytical monitoring includes: • Outfall #01 (B), commingled stormwater • Outfall #02 (B), non -commingled stormwater • Outfall #03 (B), non -commingled stormwater • Non Contact Cooling Water #1 - #8 If you have any questions or need additional information, please contact me at 704-289-4511. Thank you. Sincerely, Joe Hinkle Environmental Manager IM fi �� AO w�'.� NCDENR Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling out this form, please visit. http://portal.ncdenr.org/web/wQ/ws/su/npdessw#tab-4 Permit No.: ly/C/L; Facility Name: A County: d? i d Inspector: - Date of Inspection:' Time of inspection: OPi!AM J/ or Certificate of Coverage No.: Phone No. '74'/ W-A�/ Total Event Precipitation (inches): 0. 9,55 Was this a "Representative Storm Event" or "Measureable Storm Event" as defined by the permit? (See information below.) ® Yes ❑ No Please verify whether Qualitative Monitoring must be performed during a "representative storm event" or "measureable storm event" (requirements vary, depending on the permit). Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be performed during a "representative storm event" or during a "measureable storm event." However, some permits do not have this requirement. Please refer to these definitions, if applicable. A "representative storm event' is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no precipitation. A "measurable storm event' is a storm event that results in an actual discharge from the permitted site outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local storm events during the sampling period, and the permittee obtains approval from the local DWQ Regional Office. By this signature, I cej-tify that this report is accurate and complete to the best of my knowledge: (Signature of Permittee or Vgsignee) Page 1 of 2 4 SWU-242, Last modified 10/25/2012 1. Outfall M Outfall No. ,'� Receiving Stream: Describe the indw Structure (pipe, ditc , etc.) SjiI_I_ ja- U _ I agtivities that occur within the outfall drainage area: 2. Color: Describe the color of the (light, medium, dark) as descriptors: --� using basic colors (red, brown, blue, etc.) and tint 3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): /IOi?C 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 3 4 5 5. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: O 2 3 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: O 2 3 4 5 7. Is there any foam in the stormwater discharge? Yes No B. Is there an oil sheen in the stormwater discharge? Yes No 9. Is there evidence of erosion or deposition at the outfall? Yes No 10. Other Obvious Indicators of Stormwater Pollution: List and describe eye /j ea — Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. w SWU-242, last modified 10/25/2012 Page 2 of 2 NCDENR Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report Forguidance on filling out this form, please visit: http://12ortal.ncdenr.org/web/wg/ws/su/npdessw#tab-4 Permit No.: N/L/,S/6/0/Q/.3/�/1/ or Certificate of Coverage No.: Facility Name: &7 Z /-///Vac— County: /1/? n Phone No. Inspector: Date of Ins Time of In: Total Event Precipitation (inches): D 9-5 Was this a "Representative Storm Event" or "Measureable Storm Event" as defined by the permit? (See information below.) 0 Yes ❑ No Please verify whether Qualitative Monitoring must be performed during a "representative storm event" or "measureable storm event" (requirements vary, depending on the permit). Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be performed during a "representative storm event" or during a "measureable storm event." However, some permits do not have this requirement. Please refer to these definitions, if applicable. A "representative storm event" is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no precipitation. A "measurable storm event' is a storm event that results in an actual discharge from the permitted site outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local storm events during the sampling period, and the permittee obtains approval from the local DWQ Regional Office. By this signature, I certify that this report is accurate and complete to the best of my knowledge: (Signature of Permitt9for Des Page 1 of 2 SWU-242, Last modified 10/25/2012 1. Outfall Description: Outfall No. . Sbj dam( Struqure Receiving Stream: Describe the indystrip] acti ,ities that occur within the outfall drainage area: 2. Color: Describe the color of the (light, medium, dark) as descriptors: _ using basic colors (red, brown, blue, etc.) and tint 3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): _,004ef_ _ 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 O 3 4 5 5. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: 2 3 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: 1 2S 3 4 5 7. Is there any foam in the stormwater discharge? Yes No 8. Is there an oil sheen in the stormwater discharge? Yes 9. Is there evidence of erosion or deposition at the outfall? Yes No 10. Other Obvious Indicators of Stormwater Pollution: List and describe / VOAe Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 SWU-242, Last modified 10/25/2012 .i ALIE-WA NCDENR Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling out this form, please visit: http_j/nortal.ncdCnr.orgf web/wq jwsjsu%nj2de55w#tab-4 Permit No.: N&/�2 U/L)/ Facility Name: County: d7 loll Inspector: Date of Inspection: %, -k_ Time of Inspection: / °3-5 PA _2/ or Certificate of Coverage No.: Phone No. Total Event Precipitation (inches): n5 Was this a "Representative Storm Event" or "Measureable Storm Event" as defined by the permit? (See information below.) X Yes ❑ No Please verify whether Qualitative Monitoring must be performed during a "representative storm event" or "measureable storm event" (requirements vary, depending on the permit). Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be performed during a "representative storm event" or during a "measureable storm event." However, some permits do not have this requirement. Please refer to these definitions, if applicable. A "representative storm event" is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no precipitation. A "measurable storm event" is a storm event that results in an actual discharge from the permitted site outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local storm events during the sampling period, and the permittee obtains approval from the local DWQ Regional Office. By this signature, I certify that this report is accurate and complete to the best of my knowledge: (Signature of Permittee or Desig4ee) SWU-242, Last modified 10/25/2012 Page 1 of 2 I 1. Outfall Description: Outfall No. S/1)6.3 Receiving Stream: �� Describe the industrial actki e, ditc , etc.) ZZ, rC/� eG that occur within the outfall drainage area: 2. Color: Describe the color of the (light, medium, dark) as descriptors: —z sing basic colors (red, brown, blue, etc.) and tint 3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): 1%me- 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 0 3 4 5 S. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: 1 3 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: 1 0 3 4 5 7. Is there any foam in the stormwater discharge? Yes No B. Is there an oil sheen in the stormwater discharge? Yes 9. Is there evidence of erosion or deposition at the outfall? Yes No 10. Other Obvious Indicators of Stormwater Pollution: List and describe /Y0/7e Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. SWU-242, Last modified 10/25/2012 Page 2 of 2 1 Allvae - Bakers Plant 40ATI Allvac Stormwater Monitoring Report Form Sample Date: _ "� / '�.5 Sample Time: , a5a- Sample Location: Person Collecting Samples: Laboratory Performing Analysis: Analytical Techniques and Methods: Results of Sample Analysis: Stormwater Discharge Outfall #01 (Commingled) Drainage Area = 2,915,470sq.. ft. = 69 acres % Impervious = 34% /amr►? a c e � /Yjos c r y 7 40 CFR Part 136 Parameter Results (mg/l) Benchmark Values (mgll) BOD D 30 COD 120 TS S , 100 Cadmium 0.001 Chromium, total recoverable 1 Copper, total recoverable 0.007 Nickel, total recoverable NO 0.26 Zinc, total recoverable NO0.067 Oil and Grease AO20 Temp (effluent) (deg C) n/a Temp (downstream) (deg C) n/a Temp (upstream) J` (deg C) n/a Total Residual Chlorine Q 0.017 pH (std units) 6-9 (std units) Storm Date: a9 - 7-/ Storm Duration: �� (Hrs.) Inches of Rainfall: /, Z " Duration of time preceding rain event exceeding 0.1": 31:;� (Hrs.) Estimated Flow Calculation: Q = CIA Q(Total) = Q(Pervious Area) + Q(Impervious Area) Q(tot., cfs) = (A x inches rain/I2 inches/ft. x 69 acres x .66) + .9 x inches rain/] 2inches/ft. x 69 x .34) Q(Total, cfs) = 1.5180 x �. dS " (Inches of rain) + 1.7595 x /J 5 `J1 (Inches of rain) _ , Q cfs aceAnalyflcal wwwpecsfab:cavn December 29, 2015 Mr. Joe Hinkle Allvac RE: Project: BAKERS STORMWATER Pace Project No.: 92280445 Paco Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Dear Mr. Hinkle: Enclosed are the analytical results for sample(s) received by the laboratory on December 17, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com Project Manager Enclosures cc: Mr. Preston Baucom, Allvac Mr. Tommy Long, Allvac REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 14 aceAnalytrcal wwwpemlebs.com Project: BAKERS STORMWATER Pace Project No.: 92280445 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Charlotte Certification IDs 9800 KinceyAve, Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #; 37712 CERTIFICATIONS FloridalNELAP Certification #: E87627 Kentucky UST Certification #: 84 West Virginia Certification #: 357 VrginiaNELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 VrginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 14 0 aceAnalytical www.pecefebs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9U92 Project: Pace Project No.: BAKERS STORMWATER 92280445 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92280"5001 8SW01 EPA 1664E JMS 1 PASI-C EPA 200.7 JMW 5 PASI•A SM 2540D MDW 1 PASI-A SM 4500-CI G MLS 1 PASI-A SM 5210E BRJ 1 PASI-A SM 5220D WRC 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 14 aceAnalytrcal® wwwpacWabs.com ANALYTICAL. RESULTS Project: BAKERS STORMWATER Pace Project No.: 92280445 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)8759092 Sample: BSW01 Parameters Lab ID: 92280445001 Collected: 12/17/15 08:25 Results Units Report Limit DF Received: 12/17/15 14:35 Matrix: Water Prepared Analyzed CAS No. Qual Field Data Analytical Method: Collected By DPJ 1 12117/15 08:21 Collected Date 12/17/16 1 12117/15 08:21 Collected Time 08:21 1 12/17/15 08:21 Field pH 7.4 Std, Units 0.10 1 12117/15 08:21 Field Temperature 15.2 deg C 0.50 1 12/17/15 08:21 HEM, Oil and Grease Analytical Method: EPA 1664E Oil and Grease ND mg1L 5.0 1 12124/15 05:52 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Cadmium ND ug1L 1.0 1 12/18/15 21:00 12/22/15 01:31 7440-43.9 Chromium ND ug1L 5.0 1 12/18/15 21:00 12/22/15 01:31 7440-47-3 Copper ND ug1L 5.0 1 12/18/15 21:00 12/22/15 01:31 7440-50-8 Nickel ND ug1L 5.0 1 12/18/15 21700 12/22/15 01:31 7440-02-0 Zinc ND ug1L 10.0 1 12118/15 21:00 12/22115 01:31 7440-66-6 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 12.3 mg/L 3.3 1 12/22/15 15:30 4600CL G Chlorine, Residual Analytical Method: SM 4500-Cl G Chlorine, Total Residual 0.046 mg/L 0.024 1 12/21/15 14:35 7782-50-5 5210B BOD, 5 day Analytical Melhod: SM 5210B BOD, 5 day 2.0 mg/L 2.0 1 12/19/15 05:30 12/24115 01:00 6220D COD Analytical Method: SM 5220D Chemical Oxygen Demand ND mg/L 25.0 1 12/23115 15:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/29/2015 05:38 PM without the written consent of Pace Analytical Services, Inc.. Page 4 of 14 acmnalytical o www.pscelabs.com QUALITY CONTROL DATA Project: BAKERS STORMWATER Pace Project No.: 92280445 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: GCSV123652 Analysis Method: EPA 1664E QC Batch Method: EPA 1664B Analysis Description: 1664 HEM, Oil and Grease Associated Lab Samples: 92280445001 METHOD BLANK: 1637137 Matrix: Water Associated Lab Samples: 92280445001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Oil and Grease mg/L ND 5.0 12/24/15 05:49 LABORATORY CONTROL SAMPLE: 1637138 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Oil and Grease mg/L 40 37.6 94 78-114 MATRIX SPIKE SAMPLE: 1637139 92280414001 Spike MS MS % Rec Parameter Units Result Cone. Result % Rec Limits Qualifiers Oil and Grease mg/L ND 40 39.8 100 78-114 Results presented on this page are In fire units Indicated by the "Untie" column except where an alternate unit Is presentee to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/29/2015 05:38 PM without the written consent of Pace Analytical Services, Inc,. Page 5 of 14 aceAnalytical® www.a�acalahs.mm QUALITY CONTROL DATA Project: BAKERS STORMWATER Pace Project No.: 92280445 QC Batch: MPRP120326 Analysis Method: EPA 200.7 QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET Associated Lab Samples: 92280445001 METHOD BLANK: 1633268 Matrix: Water Associated Lab Samples: 92280445001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Cadmium ug1L ND 1.0 12/22115 00:16 Chromium ug1L ND 5.0 12/22/15 00:16 Copper ug1L ND 5.0 12/22/15 00:16 Nickel ug/L ND 5.0 12/22/15 00:16 Zinc uglL ND 10.0 12/22/15 00:16 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huniersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1633269 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cadmium ug1L 500 481 96 85-115 Chromium uglL 500 501 100 85-115 Copper ug1L 500 501 100 85-115 Nickel ug1L 500 481 96 85-115 Zinc uglL 500 433 87 85-115 MATRIX SPIKE 8, MATRIX SPIKE DUPLICATE: 1633270 1633271 MS MSD 92279970001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Cadmium ug1L ND 500 500 519 474 104 95 70-130 9 Chromium ug1L ND 500 500 551 460 110 91 70-130 18 Copper ug1L 15.9 500 500 566 514 110 100 70-130 9 Nickel ug1L 7.7 500 500 524 473 103 93 70-130 10 Zinc ug1L 151 500 500 621 605 94 91 70-130 3 MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 1633272 1633273 MS MSD 92280423001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Cadmium ug1L ND 500 500 511 472 102 94 70-130 8 Chromium ug1L 17.2 500 500 568 520 110 100 70-130 9 Copper ug1L 213 500 500 759 714 109 100 70-130 6 Nickel ug1L 11.2 500 500 521 479 102 94 70-130 8 Zinc uglL 68.8 500 500 525 481 91 82 70-130 9 Results presented on this page are In the unite indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shell not be reproduced, except in full, Date: 1212912015 05:38 PM without the written consent of Pace Analytical Services, Inc.. Page 6 of 14 acmnalytical® www,pacekbs.com Project: BAKERS STORMWATER Pace Project No.: 92280445 QC Batch: WET142129 QC Batch Method: SM 2540D Associated Lab Samples: 92280445001 METHOD BLANK: 1635435 Associated Lab Samples: 92280445001 Parameter Units Total Suspended Solids mg1L LABORATORY CONTROL SAMPLE: 1636436 Parameter Units Total Suspended Solids mg1L Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Analysis Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.5 12/2211515:22 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 262 105 90-110 SAMPLE DUPLICATE: 1635437 92280412001 Dup Parameter Units Result Result Total Suspended Solids mg1L 5.4 5.8 SAMPLE DUPLICATE: 1635439 92280443001 Dup Parameter Units Result Result Total Suspended Solids mg1L 31.0 30.2 RPD Qualifiers 7 D6 RPD Qualifiers 3 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/29/2015 05:38 PM without the wntten consent of Pace Analytical Services, Inc. Page 7 of 14 6Analytical wwtv.Aactiki .cam QUALITY CONTROL DATA Project: BAKERS STORMWATER Pace Project No.: 92280445 QC Batch: WETI42113 Analysis Method: SM 4500-CI G QC Batch Method: SM 4500-CI G Analysis Description: 4500CL G Chlorine, Total Residual Associated Lab Samples: 92280445001 METHOD BLANK: 1634727 Associated Lab Samples: 92280445001 Parameter Units Chlorine, Total Residual mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0,024 12/21/1614:35 SAMPLE DUPLICATE: 1634728 92280445001 Dup Parameter Units Result Result Chlorine, Total Residual mg/L 0.046 0.041 RPD Qualifiers 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are In the uniis Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/29/2015 05:38 PM without the written consent of Pace Analytical Services, Inc., Page 6 of 14 leAnalytical trww.paookiftcom QUALITY CONTROL DATA Project: BAKERS STORMWATER Pace Project No.: 92280445 QC Batch: WETl42081 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210B GOD, 5 day Associated Lab Samples: 92280445001 METHOD BLANK: 1633869 Matrix: Water Associated Lab Samples: 92280445001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers GOD, 5 day mglL ND 2.0 12/24/15 01:00 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1633870 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers GOD, 5 day mg1L 198 176 89 84.6-115.4 SAMPLE DUPLICATE: 1633871 92280376001 DUp Parameter Units Result Result RPD Qualifiers GOD, 5 day mg1L 3.5 3.3 6 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12129/2015 05:38 PM without the written consent of Pace Analytical Services, Inc- Page 9 of 14 aceMaIXiml www.pacelab aom QUALITY CONTROL DATA Project: BAKERS STORMWATER Pace Project No.: 92280445 QC Batch: WETA125892 Analysis Method: SM 5220D QC Batch Method: SM 5220D Analysis Description: 5220D COD Associated Lab Samples: 92280445001 METHOD BLANK: 1635385 Matrix: Water Associated Lab Samples: 92280445001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chemical Oxygen Demand mg/L ND 25.0 12/23/15 15:30 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1635386 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg1L 750 771 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1635387 1635388 MS MSD 92280414002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc, Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mglL ND 750 750 733 733 96 96 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1635389 1635390 MS MSD 92279854001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % ReC % Rec Limits RPD Qual Chemical Oxygen Demand mg/L 31.0 750 750 763 763 98 98 90-110 0 Results presented on fts page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/29/2015 05:38 PM without the written consent of Pace Analytical Services, Inc.. Page 10 of 14 laneAnalytical" www.pecelabs.com QUALIFIERS Project: BAKERS STORMWATER Pace Project No.: 92280445 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. POL - Practical Quantitation Limit. RL - Reporting Limit. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, Date: 12129/2015 05:38 PM without the written consent of Pace Analytical Services, Inc.. Page 11 of 14 leAnalyfical www.pacebbs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: BAKERS STORMWATER Pace Project No.: 92280445 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Hunlersville, NC 28078 (704)875-9092 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 9228D445001 BSW01 FLD1 92280445001 BSW01 EPA 1664B GCSVI23652 9228D445001 BSW01 EPA 200.7 MPRP120326 EPA 200.7 92280445001 BSW01 SM 2540D WET142129 92280445001 BSW01 SM 4500-CI G WET142113 92280445001 BSW01 SM 5210B WET142081 SM 5210B 92280445001 BSW01 SM 5220D WETA125892 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP118344 WET142082 Page 12 of 14 Document Name: ondition Upon Recel Document No.: F-CHR-CS-003-rev.17 Client Name: Project #: Courier: Fed Ex EJUPS Elusps = pent ❑Commercial []Pace ❑Other: Document Revised: 215OC72015 Page l of 2- ' issuing Authority: Pace Huntersville Qdality Office woo: ezzsoaas 11111111111111111111� Custody Seal on Cooler/Box Present? Oyes []Nt� Seals Intact? []Yes❑No Packing Material: ❑Bubble Wrap ❑ uB bbie Bags ❑None ❑Other: Thermometer 1505 / _' Used: Type of tce: (]Wet ❑ Blue ❑None copies on Ice, tooting process has begun Cooler Temp Corrected ('C)c ? Biological Tissue Frozen? • ❑Yes :.:.❑No_ -❑N/A _ Temp should be above freezing to 6'C Correction Factor. 0.0'C Date and Initials of Person Examining.Cgntbnts:: USDA Regulated Soil (❑ N/A, water sample) Old samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a for+iign source (Internationally, ❑Yes []NO--- Including Hawaii and Puerto Rfc:ow .. Oyes Na If Yes to either question, fill out a Regulated Soil Checklist and include withSCUR/C0C paperwork. / COMMENTS:: Chain of Custody Present? es No N/A 1. Chain of Custody Filled Out? Dyes No ❑N/A 2. Chain of Custody Relinquished? ❑ es No N/A 3. Sam ler Name and/or Signature on COC? 12es No NIA 4. Samples Arrived within Hold Time? ales ❑No []N/A 5. Short Hold Time Anat sis (<72 hr)? Yes [:]No ❑N/A 6. Rush Turn Around Time Requested? [[--]]Yes o N/A 7. Sufficient volume? ❑ es ❑No [I N/A g, Correct Containers Used? ❑ es No ❑N/A 9. -Pace Containers Used? Yes No N/A Containers Intact? es ❑No N/A 10. Filtered Volume Received for Dissolved Tests? ❑Yes ❑No ❑K A 11, Note if sediment is visible In the dlssolved container Sample Labels Match COC? - Yes ❑No []N/A 12. -Includes Date/Tlme/ID/Analysis Matrix: t ✓ .Y All containers needing acid/base preservation have been 13. checked? 13Yes ❑No ❑N/A All containers needing preservation are found to be In compliance with EPA recommendation? Z'sONO (HNO3, HtSO4, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide) ❑N/A Exceptions; VOA, Coliform, TOC, Oil and Grease, DRO/6015 (water) DOC,LLH ©es ❑No ❑N/ Samples checked for dechlorization ❑Yes No N/ 14, Heads ace in VOA Vials >5.6mm)? QYes []No ❑NI 15. Trip Blank Present? ©Yes ❑No N/A 16. Trip Blank Custody Seals Present? ❑Yes ❑No /A Pace Trip Blank Lot # (if urchased): CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Field Data,Regyired? Oyes []No Date/Time: . Project Manager SCURF Review: _ L/67}�( Date: 1 7r✓�+r �h� Note: Whenever there is a discrepancy affecting N�ofma tompllance samples, a copy of this form will be sent to the N rth Carolina DEHNR Certification Office (i.e. Out of hold, Incorrect preservative, out of temp, incorrect containers). . Page 13 of 14 vo? PaceAnalytical' 11�r-piel170S.COm CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain-cf-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section A Section $ Section C Page: of Required Client Information: Required Project Information: Invoice Iniormation- Repot To:. Attention: 1883510 • z % IS , n _ Lr ;'A UA ddr i Copy L � � To: 1 Co �1uy-Nar:re: .� fGIIi �S Cll4 REGULATORY AGENCY Addma ,S 7, �r .sG 30 ��mea, e- NPDES F_ GROUND WATER DRINKING WATER UST r RGRA (� OTHER Email To: Purchase Order No.: Paco C]uoro Raicrtmca: SII Fa., Projnci Nam , ' ��T )er P.lfxl P.ycc1 Site Location - L% i e c Marow: STATE: _ Roquostod Due DateITAT; Project Number: Pace Pmr.w is i F Requested Analysis Filtered jYIN) Stttior D Maui. Codes z Regalred Cl.,,l Irtk—,!_ MATRIX r CODE — z COLLECTED Preservatives r` Dnnkiry Wale, DW O z = Water WT WEstS[! Water WW V m OoawuSrtE conmosrrt V Product P — slant [rma1ua J Z So+VSow SL �c ij } SAMPLE ID wipe �; r w N V c „°„PL (A—Z. D 9!,-j Air AR p w a < a F '$ t Sample IDS MUST BE UNIOUE Tissue TS O U a � m to `�77!! y s! Other OT x w w o C) �= o eaV G 2 u_ Q Q rn L L C y ~ DATE TIME DATE TIME N 7 2 S z z to O Q m IX Pace Project Nod Lab I.D. St,�c�1 x 1 wf X 3 vi a93wol UlfG I7 y5 1 s s u? 01 r s: 31,E-- I xly 01r__ c 7 8 9 10 11 12 - ADDITIONAL COMMENTS REUNQUISNED"Y I(AFFILIATION DATE TIME n ACCEPTED BY I AFFILIATION DATE TIME SAMPLE CONDITIONS S � '1/ate � '�'ca� ��� �' 3 i ��`� •.` � � � /G� ,3{Sf -{l � .: z 7 -0 - 5,c cc ORIGINAL SAMPLER NAME AND SIGNATURE PRINT Name of SAMPLER: '� f p G:� — %GYMS. M-VFse ✓!,l,`GL O .vi ,� E z m o a y' c i DATE Signed A SIGNATURE of SAMPLER: E — (MmmonrY). -Imrrar6 a1 Nolm [Iy :ir-91Ns form you are a—Ti,imn Pace's NET 30 day ry,ymani terns and :vpruinrl to We ctnrpus d 1,5 A rK* rrwnlh for arc m,o,cfi r'it pait..Jh.3e days. f ��J_� F-ALL-0-020rev.07• 1 S-May-2007 ATlahaz Allvac - Bakers Plant Stormwater Monitoringport Form Sample Date: la�'/ 7."1,5 Sample Location: Person Collecting Samples: Laboratory Performing Analysis: Analytical Techniques and Methods: Results of Sample Analvsis: Sample Time: Q 16 z2t7l Stormwater Discharge_Outfall #02 (Non -Commingled) Drainage Area w 212,952sq. ft. = 4.9 acres % Impervious = 12% JrMIn VL 0 /) a -D&V;J 8ilf fUS� r A/ 40 CFR Part 136 Parameter Results (mg/l) Benchmark Values (mg/l) BOD 0 �7j 30 COD 376 120 TSS 76 100 Cadmium Af0.001 Chromium, total recoverable �' 1 Copper, total recoverable 0.007 Nickel, total recoverable QI 0.26 Zinc, total recoverable / 0.067 pH (std units) 6-9 (std units) Storm Date: Storm Duration: - 6 (Hrs.} Inches of Rainfall: US" Duration of time preceding rain event exceeding 0.1": (Hrs.) Estimated Flow Calculation: Q=CIA Q(Total) = Q(Pervious Area) + Q(Impervious Area) Q(tot., cfs) = (A x inches rain/12 inches/ft. x 4.9 acres x .88) + .9 x inches rain/12inches/ft. x 4.9 x. 12) Q(Total, cfs) = 0.1437 x 1,115 � � (Inches of rain) + 0.0441 x 3 cfs (Inches of rain) aceAnalytical WWW-; efabscom December 29, 2015 Mr. Joe Hinkle Allvac RE: Project: BAKERS STORMWATER Pace Project No., 92280423 Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Dear Mr. Hinkle: Enclosed are the analytical results for sample(s) received by the laboratory on December 17, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com Project Manager Enclosures cc: Mr. Preston Baucom, Allvac Mr. Tommy Long, Allvac REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 12 Pace Analytical Services, Inc. aceMalyticalo 9800KineyAve. 2 078 100 Huntersville, NCC8078 ww¢pecelabs oom (704 )875-9092 CERTIFICATIONS Project: BAKERS STORMWATER Pace Project No.: 92280423 Charlotte Certification IDs 9800 Kinsey Ave. Ste 100, Huntersville, NC 28078 Florida/NELAP Certification #: E87627 North Carolina Drinking Water Certification #; 37706 Kentucky UST Certification M 84 North Carolina Field Services Certification #: 5342 West Virginia Certification #: 357 North Carolina Wastewater Certification #: 12 VirginiaNELAP Certification #: 460221 South Carolina Certification #: 99006001 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 North Carolina Wastewater Certification #; 40 Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001 Massachusetts Certification #: M-NCO30 West Virginia Certification #: 356 North Carolina Drinking Water Certification #: 37712 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 12 laneAnalyfical" wwwpacslabicom SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: BAKERS STORMWATER Pace Project No.: 92280423 Analytes Lab ID Sample 1D Method Analysts Reported Laboratory 92280423001 BSW02 EPA 2007 JMW 5 PASI-A SM 2540D MDW 1 PASI-A SM 5210B BRJ 1 PASI-A SM 5220D WRC 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 12 leAnalytical" www.paoWabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)8759092 Project: BAKERS STORMWATER Pace Project No.: 92280423 Sample: BSW02 Lab ID: 92280423001 Collected: 12/17/15 08:43 Received: 12/17/15 14:35 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Collected By DPJ 1 12/17/15 08:44 Collected Date 12117/15 1 12/17/15 08:44 Collected Time 06:44 1 12/17/15 08:44 Field pH 7.3 Std. Units 0.10 1 12/17/15 08:44 Field Temperature 14.2 deg C 0.50 1 12/17/15 08:44 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Cadmium ND ug1L 1.0 1 12/18/1521:00 12/22M501A9 7440-43-9 Chromium 17.2 ug1L 5.0 1 12/18/15 21:00 12/22/15 01:19 7440-47.3 Capper 213 ug1L 5.0 1 12/18/15 21:00 12/22/15 01719 7440-50.8 Nickel 11.2 ug/L 5.0 1 12/18/15 21:00 12122/15 01:19 7440-02-0 Zinc 68.8 ug1L 10.0 1 12/18/15 21:00 12122/15 0119 7440-66-6 2540D Total Suspended Solids Analytical Method: SM 25401) Total Suspended Solids 70.0 mg1L 12.5 1 1Z122/15 1528 5210B BOD, 5 day Analytical Method: SM 5210B BOD, 5 day 7.3 mg1L 2.0 1 12/19/15 05:30 12/24/15 01:00 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 37.0 mglL 25.0 1 12/23/15 15:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12129/2015 05:25 PM without the written consent of Pace Analytical Services, Inc.. Page 4 of 12 laneAnalyficalo www.pacefabs.00rn QUALITY CONTROL DATA Project: BAKERS STORMWATER Pace Project No.: 92280423 OC Batch: MPRP120326 Analysis Method: EPA 200.7 OC Batch Method: EPA 200.7 Analysis Description: 200.7 MET Associated Lab Samples: 92280423001 METHOD BLANK: 1633268 Matrix: Water Associated Lab Samples: 92280423001 Blank Reporting Parameter Units Result Limit Analyzed Cadmium ug1L NO 1.0 12/22/15 00:16 Chromium ug1L NO 5.0 12/22/15 00:16 Copper ug1L NO 5.0 12/22/15 00:16 Nickel ug1L NO 5.0 12/22/15 00:16 Zinc ug1L NO 10.0 12/22/15 00:16 LABORATORY CONTROL SAMPLE: 1633269 Parameter Units Cadmium ug1L Chromium ug/L Copper ug/L Nickel ug1L Zinc ug/L Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Spike LCS LCS % ReC Cone. Result % Rec Limits Qualifiers 500 481 96 85-115 500 501 100 85-115 500 501 100 85-115 500 481 96 85-115 500 433 87 85.115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1633270 MS 92279970001 Spike Parameter Units Result Cone. Cadmium ug1L NO 500 Chromium ug1L NO 500 Copper ug1L 15.9 500 Nickel uglL 7.7 500 Zinc ug1L 151 500 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1633272 MS 92280423001 Spike Parameter Units Result Conc. Cadmium ug1L ND 500 Chromium ug1L 17.2 500 Copper ug1L 213 500 Nickel ug1L 11.2 500 Zinc uglL 68.8 500 1633271 MSD Spike MS MSD MS MSD % Rec Cone. Result Result % Rec % Rec Limits RPD Qual 500 519 474 104 95 70-130 9 500 551 460 110 91 70-130 18 500 566 514 110 100 70-130 9 500 524 473 103 93 70-130 10 500 621 605 94 91 70-130 3 1633273 MSD Spike MS MSD MS MSD % Rec Cone, Result Result % Rec % Rec Limits RPD 500 511 472 102 94 70-130 8 500 568 520 110 100 70-130 9 500 759 714 109 100 70-130 6 500 521 479 102 94 70-130 8 500 525 481 91 82 70-130 9 Results presented on this page are In the unite indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/29/2015 05:25 PM without the written consent of PaceAnalytical Services, Inc.. Qual Page 5 of 12 aceAnapical® www.paceleba rwm QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Hun,,ersvilte, NC 28078 (704)875-9092 Project: BAKERS STORMWATER Pace Project No.: 92280423 QC Batch: WET142129 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92280423001 METHOD BLANK: 1635435 Matrix: Water Associated Lab Samples: 92280423001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 12/22/15 15:22 LABORATORY CONTROL SAMPLE: 1635436 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 262 105 90-110 SAMPLE DUPLICATE: 1635437 92280412001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg1L 5.4 5.8 7 D6 SAMPLE DUPLICATE: 1635439 92280443001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg[L 31.0 30.2 3 Results presented on thle page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the dght of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 1212912015 05:25 PM without the written consent of Pace Analytical Services, Inc.. Page 6 of 12 Iac ( eAnalytical snvwpacelaha.txtm QUALITY CONTROL DATA Project: BAKERS STORMWATER Pace Project No.: 92280423 QC Batch: WET/42081 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210E SOD. 5 day Associated Lab Samples: 92280423001 METHOD BLANK: 1633869 Matrix: Water Associated Lab Samples: 92280423001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg/L ND 2.0 12/24/15 01:00 Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1633870 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day mg1L 198 176 89 84.6-115.4 SAMPLE DUPLICATE: 1633871 92280376001 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 3.5 3.3 6 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/29/2015 05:25 PM without the written consent of Pace Analytical Services, Inc.. Page 7 of 12 laneAnalytical" www.pacela4com Project: BAKERS STORMWATER Pace Project No.: 92280423 QC Batch: WETAJ25892 QC Batch Method: SM 5220D Associated Lab Samples: 92280423001 METHOD BLANK: 1636385 Associated Lab Samples: 92280423001 Parameter Units Chemical Oxygen Demand mglL QUALITY CONTROL DATA Analysis Method: SM 5220D Analysis Description: 5220D COD Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 25.0 12/23/15 15:30 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1635386 Spike LCS LCS % Rec Parameter Units Cane. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg/L 750 771 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1635387 1635388 MS MSD 92280414002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg1L ND 750 750 733 733 96 96 90.110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1635389 1635390 MS MSD 92279854001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Conc. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg1L 31.0 750 750 763 763 98 98 90-110 0 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/29/2015 05725 PM without the written consent of Pace Analytical Services, Inc.. Page 8 of 12 aceAnalytical wvw.pecelaes.ow QUALIFIERS Project: BAKERS STORMWATER Pace Project No.: 92280423 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. POL - Practical Quantitation Limit. RL - Reporting Limit. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unfounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/29/2015 05:25 PM without the written consent of Pace Analytical Services, Inc.. Page 9 of 12 aceAnalytical® *W.p8cW8h&0= QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: BAKERS STORMWATER Pace Project No.: 92280423 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)8759092 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92280423001 BSW02 FLDI 92280423001 BSW02 EPA200.7 MPRPI20326 EPA2007 ICP118344 92280423001 BSW02 SM 2540D WETI42129 92280423001 BSW02 SM 5210B WET142081 SM 52102 WET142082 92280423001 BSW02 SM 5220D WETAI25892 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/29/2015 05:25 PM without the written consent of Pace Analytical Services, Inc.. Page 10 of 12 Document Name: ZI, 10 1,1, ed • Sample Condition Upon Recel aceAnalytical Document No.: F-CHR-CS-003-rev.17 (i911 Client Name: I Project #: A�1✓ur (, Courier: Fdx UPS LISPS tet []Commercial 00ther: Document Revised: 2§OCT2015 Page i of 2, Issuing Authority: Pace Huntersvllle Quality Office WO# : 92280423 11111111111111111111111�@ Custody Seal on Cooler/Box Present? ❑Yes []No Seals Intact? ❑Yes []No Packing Material: ❑Bubble Wrap ❑Bubble Bags []None Mother: Thermometer ❑ T1505 = Used Type of Ite: ❑Wet ❑Blue ❑None ❑Samp[es on ice, cooling process has begun Cooler Temp Corrected ('C): 7 , , Biological Tissue Frozen? ❑ Yes =-.❑No []N/A Temp should be above freezing to 6°C Correction Factor: 0.0'C Date and Initials of Person Examining.t ont)snts:: /a(� ��•%7 f� USDA Regulated Soil (❑ N/A, water sample) Did samples origina th a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from"a foreign source (internationally, []Yes❑N Including Hawait and Puerto Rlcci)'V Des flNo If Yes to either question, fill out a Regulated Soil Checklist and include with $CUR/COC paperwork. COMMENTS: Chain of Custody Present? [:]Yes Na ❑N/A 1. Chain of Custody Filled Out? C Yes ❑No ❑N/A 2. Chain of Custody Relinqulshed7 MYes ❑No ❑N/A 3. Sampler Name and/or Signature on COC? - es,'ONO ❑N/A 4. Samples Arrived within Hold Time? Yes No ❑N/A 5. Short Hold Time Analysis (02 hr)? CfYes ONG ❑N/A 6. Rush Turn Around Time Requested? Dyes ZN6 ❑N/A 7. Sufficient Volume? es ❑No ❑N/A 8. Correct Containers Used? Yes ❑No ❑N/A 9. -Pace Containers Used? Yes No nNIA Containers Intact? OYes ❑No ❑N/A 4 10. Filtered Volume Recelved for Dissolved Tests? Yes Na /A 11. Note If sediment Is visible In the dissolved container Sample Labels Match COC? Elves [:]No ❑N/A 12. f -Includes Date/Time/kD/Analysis Matrix: �� } All containers needing acid/base preservation have been 13 checked? Yes ❑No ❑N/A All containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, HIS04, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanlde) Yes ❑No ❑N/A Exceptions: VOA, Coliform, TOC, Olt and Grease, DRO/8015 (water) DOC,LLH Oyes ❑No �� 04/ Samples checked for dechlorizatlon OYes QN6 QNL 14. Headspace in VOA Vials (>5.6mm)? ❑Yes ❑No dNIV IS. Trip Blank Present? Elves ❑No N/ 16. Trip Blank Custody Seals Present? Elves ❑No /A Pace Trip Blank Lot q if purchased): CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Field Data;Requlred?• ❑Yes ❑No Date/Time: ' J Project Manager SCURF Review: ' Ilk Date. Note: whenever there is a discrepancy affecting North Carolini compliance samples, a copy of this form will be sent to the North Carolina EHNR Certificatlon Office (i.e. out of hold, incorrect preservative, out of temp, Incorrect containers). /� l PkeAnalytical' irrkr.bacelabs.cbm CHAIN -OF -CUSTODY / Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section A Section B Section C ¢t Page: of m Required Client Information; Required Protect Information: Invoice Information: r Repon To: Ailention. / 1903275 -5 0 't- Ad Copy /G To. `/r� /j/ Companyf} 7 [' ' �1� REGULATORY AGENCY GIC � !i fl lT J C tic %Oe- Address:. n `3 �� C `� [./ NPDES F GROUNDWATER I— DRINKING WATER r UST r RCiZP r OTHER Finail To: Purchase Order No.: Paw Oeote Reference: S! Fax: Pr I Nam ` Paco P cta Site Location Y r7 / �f rrl J<<�� r Manauf STATE: - Requested Due DateITAT: Project Number: Par Prorde x; 2 J Requested Analysis Filtered (YIN) Section D Matrix Codes -- -.. Z RuquiroOClleot tnlp u— MATRIX I coD,F. o Q. COLLECTED Preservatives > Drinking Water DW 00 z O Water WT $ U Waste Water WW, Product P _ ra In CoM,,o nE START W �� J Z SolllSabd SL SAMPLE ID 4 ,Oii'pe °P _ Lu N E (A-Z. 0.9 t: ) Air AR p w a 2 `a Sample IDs MUST BE UNIOuE Tissue TS O U a H Z Z rn 1:1 [LJ Other OT x w r w O h O $ c In } O� n to = O tIj L m M a w ue ~ rn DATE TIME DATE TIME # S 2 2 Z z 2 r_ t] IY Pace Project No./ Lab I.D. 1 0 - r U X IX X.' 2 LJ D 12- V rX1 I I 1 ''Vim Y 4 r i "-11-1 �:'y3 5 6 7 B 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY JfFFILIATION DATE TIME f ACCEPTED BY t AFFILIATION DATE TIME SAMPLE CONDITIONS c R �.r`�`/�- �7 %7-17 %� ?3 Kr / �� j 1 `✓ III 73S L ORIGINAL SAMPLER NAME AND SIGNATURE U o — c (�]] PRINT Name of SAMPLER; I "O a — SIGNATURE of SAMPLER: DATEy Signed _ F U v y _ mAIL 'Imponani note: By sign'ur9Ibis fwm you are a�epuxj Pnce'; HET 30 day WylmM ucmn acid ;,j—ng la sale U+arges or 1.5% P^ mm�lh far any mvJ•ce: n°7"''"' wdtun 3o anys. � � F-ALL-0-020rev.07, ia-May-200 i ATlaliva< Allvac - Bakers Plant Stormwater Monitoring Report Form Sample Date: a Y 7-I Sample Location: Person Collecting Samples: Laboratory Performing Analysis: Analytical Techniques and Methods: Results of Sample Analysis: Sample Time: 911156 m Stormwater Discharge Outfall #03 (Non -Commingled) Drainage Area = 336,580sq. ft. = 7.8 acres ��% Impervious = 15%I /vrrrvrJ✓�O,IG a 0 D, J, L-01e- 0-,;er� L I 6 40 CFR Part 136 Parameter Results (mg/1) Benchmark Values (mg/1) BOD 30 COD 11 120 TSS O 100 Cadmium 0A01 Chromium, total recoverable 1 Copper, total recoverable 0.007 Nickel, total recoverable 0.26 Zinc, total recoverable 0 O Q 0.067 pH (std units) 6-9 (std units) Storm Date %�` Storm Duration: � _ _ - (Hrs.) Inches of Rainfall: I �S Duration of time preceding rain event exceeding 0.1": --31a (Hrs.) Estimated Flow Calculation: Q=CIA Q(Total) = Q(Pervious Area) + Q(Impervious Area) Q(tot., cfs) = (A x inches rain/12 inches/ft. x 7.8 acres x .85) + .9 x inches rain/] 2inches/ft. x 7.8 x .15) Q(Total, cfs) = 0.2210 x , v�.5 (Inches of rain) + 0.0878 x .S (Inches of rain) D cfs lacieAnalyticale wwwpecabba.cm December 29, 2015 Mr. Joe Hinkle Allvac RE: Project: BAKERS STORMWATER Pace Project No.: 92280443 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Dear Mr. Hinkle: Enclosed are the analytical results for sample(s) received by the laboratory on December 17, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com Project Manager Enclosures cc: Mr. Preston Baucom, Allvac Mr. Tommy Long, Allvac REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 12 Pace Analytical Services, Inc. acmnalytrcal® 9600 KineyAve. Suite 100 hluntersville, NC 28076 wmpm*ebs.mn (704)875-9092 CERTIFICATIONS Project: BAKERS STORMWATER Pace Project No.: 92280443 Charlotte Certification lDs 9800 Kincey Ave. Ste 100, Huntersvi Ile, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 West Virginia Certification #: 357 VirginiafVELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 12 (�55'cieAnalyfical* www.pacalaes.00m SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 98DO Kincey Ave, Suite 100 Huntersville, NC 28078 (704)875-9092 Project: BAKERS STORMWATER Pace Project No.: 92280443 Analytts Lab ID Sample ID Method Analysts Reported Laboratory 92280443001 BSW03 EPA200.7 JMW 5 PASI-A SM 2540D MDW 1 PASI-A SM 5210B BRJ 1 PASI-A SM 5220D WRC 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Anatytical Services, Inc.. Page 3 of 12 leAnalyticale www.pratMeLs.oarn ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Hunlersville, NC 28078 (704)875-9092 Project: BAKERS STORMWATER Pace Project No.: 92280443 Sample: BSW03 Lab ID: 92280443001 Collected: 12/17/16 08:55 Received: 12/17/15 14:35 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Collected By DPJ 1 12/17/15 08:48 Collected Date 12/17/15 1 12/17/15 08:48 Collected Time 08:48 1 12/17115 08:48 Field pH 7 Std. Units 0.10 1 12/17/15 08:48 Field Temperature 13.8 deg C 0.50 1 12/17/15 08:48 200.7 MET ICP Analytical Method: EPA 2003 Preparation Method: EPA 2003 Cadmium ND ug1L 1.0 1 12/18/15 21:00 12/22/15 01:27 7440.43.9 Chromium 30.7 ug1L 5.0 1 12/18/15 21:00 12/22/15 01:27 7440-47-3 Copper 40.9 ug1L 5.0 1 12/18115 21:00 12/22/15 01:27 7440.50.8 Nickel ND ug1L 5.0 1 12/18/15 21:00 12/22/15 01:27 7440-02-0 Zinc 56.7 ug/L 10.0 1 12/18115 21:00 12/22/15 01:27 7440-66-6 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 31.0 mg1L 5.0 1 12/22/15 15:30 5210B BOD, 5 day Analytical Method: SM 5210B BOD, 5 day ND mg/L 2.0 1 12/19/15 05:30 12/24/15 01:00 52200 COD Analytical Method: SM 5220D Chemical Oxygen Demand 44.0 mg1L 25.0 1 12/23/15 15:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 1212912015 05:26 PM without the written consent of Pace Analytical Services, Inc.. Page 4 of 12 lacmnalyfical wwwpacefahs.ccm QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 2BO78 (704)875.9092 Project: BAKERS STORMWATER Pace Project No.: 92280443 QC Batch: MPRP120326 Analysis Method: EPA200,7 QC Batch Method: EPA200.7 Analysis Description: 200.7 MET Associated Lab Samples: 92280443001 METHOD BLANK: 1633268 Matrix: Water Associated Lab Samples: 92280443001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Cadmium ug1L ND 1.0 12/22/15 00:16 Chromium uglL ND 5.0 12/22/15 00:16 Copper uglL ND 5.0 12/22/15 00:16 Nickel uglL ND 5.0 12/22/15 00:16 Zinc uglL ND 10.0 12/22/15 00:16 LABORATORY CONTROL SAMPLE: 1633269 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cadmium ug1L 500 481 96 85-115 Chromium uglL 500 501 100 85-115 Copper uglL 500 501 100 85-115 Nickel uglL 500 481 96 85-115 Zinc uglL 500 433 87 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1633270 1633271 MS MSD 92279970001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Cadmium uglL ND 500 500 519 474 104 95 70-130 9 Chromium uglL ND 500 500 551 460 110 91 70-130 18 Copper ug1L 15.9 500 500 566 514 110 100 70-130 9 Nickel ug1L 7.7 500 500 524 473 103 93 70-130 10 Zinc uglL 151 500 500 621 605 94 91 70-130 3 MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 1633272 MS 92280423001 Spike Parameter Units Result Conc. Cadmium uglL ND 500 Chromium uglL 17.2 500 Copper uglL 213 500 Nickel uglL 11.2 500 Zinc uglL 68.8 500 1633273 MSD Spike MS MSD MS MSD % Rec Conc. Result Result % Rec % Rec Limits RPD 500 511 472 102 94 70-130 8 500 568 520 110 100 70-130 9 500 759 714 109 100 70-130 6 500 521 479 102 94 70-130 8 500 525 481 91 82 70-130 9 Results presented on this page are In the units Indicated by the "Units' column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/29/2015 05:26 PM without the written consent of Pace Analytical Services, Inc.. Qual Page 5 of 12 aceAnalytrcal" w►w.pacelfi oom QUALITY CONTROL DATA Project: BAKERS STORMWATER Pace Project No.: 92280443 QC Batch: WET142129 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92280443001 METHOD BLANK: 1635435 Matrix: Water Associated Lab Samples: 92280443001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mglL ND 2.5 12/22/15 15:22 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1635436 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg1L 250 262 105 90-110 SAMPLE DUPLICATE: 1635437 92280412001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 5.4 5.8 7 D6 SAMPLE DUPLICATE: 1635439 92280443001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 31.0 30.2 3 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/29/2015 05:26 PM without the written consent of Pace Analytical Services, Inc.. Page 6 of 12 lacieAnalyficalo www,pecekbs.corn QUALITY CONTROL DATA Project: BAKERS STORMWATER Pace Project No.: 92280443 QC Batch: WET142081 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 92280443001 METHOD BLANK: 1633869 Matrix: Water Associated Lab Samples: 92280443001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg1L ND 2.0 12/24/15 01:00 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1633870 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day mg1L 198 176 89 84.6-115.4 SAMPLE DUPLICATE: 1633871 92280376001 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 3.5 3.3 6 Results presented on this page are In the units Indicated by the "Unite" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/29/2015 05:26 PM without the written consent of Pace Analytical Services, Inc.. Page 7 of 12 aceAnalytical wrw,peoeI&b&ixlm QUALITY CONTROL DATA Project: BAKERS STORMWATER Pace Project No.: 922804,43 Pace Analytical Services, Inc. 9800 Kinsey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: WETAf25892 Analysis Method: SM 5220D QC Batch Method: SM 5220D Analysis Description: 5220D COD Associated Lab Samples. 92280443001 METHOD BLANK: 1635385 Matrix: Water Associated Lab Samples: 92280443001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chemical Oxygen Demand mg1L NO 25.0 12/23/15 15:30 LABORATORY CONTROL SAMPLE: 1635386 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg1L 750 771 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1635387 1635388 MS MSD 92280414002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cana Conc. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg/L ND 750 750 733 733 96 96 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1635389 1635390 MS MSD 92279854001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg/L 31.0 750 750 763 763 98 98 90-110 0 Results presented on this page are in the units Indicated by the 'Units' column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/29/2015 05:26 PM without the written consent of Pace Analytical Services, Ina. Page 8 of 12 aceAnalytrcal® wwwpecelahsoom QUALIFIERS Project: BAKERS STORMWATER Pace Project No.: 92280443 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. M DL -Adjusted Method Detection Limit. POL - Practical Quantitation Limit. RL - Reporting Limit. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 S - Surrogate 1,2•Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unfounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. Aseparate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenyla mine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/29/2015 05:26 PM without the written consent of Pace Analytical Services, Inc.. Page 9 of 12 aceAnapical" www.paoelebaoo 1 QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, Inc. 9800 Kinsey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: BAKERS STORMWATER 92280443 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92280443001 BSW03 FLDI 92280443001 BSW03 EPA 200.7 MPRP120326 EPA 200.7 ICP118344 92280443001 BSW03 SM 2540D WET142129 92280443001 BSW03 SM 5210B WET142081 SM 5210B WETI42082 92280443001 BSW03 SM 5220D WETA125892 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 1212912015 05:26 PM without the written consent of Pace Analytical Services, Inc.. Page 10 of 12 Document Name: Document Revised: Z§OCT2015 Analytical` Sample Condition Upon Receipt(SCUR) Page i of Z Document No.: Issuing Authority: F-CHR-CS-003-rev.17 Pace Huntersvlile Qdallty Office Client Name: Project WV# . 922804 43 P I I o;k Courier: Fed E UPS USPS Client []Commercial ace ❑Other: 92280443 Custody Seal on Cooler/Box Present? ❑Yes No Seals Intact? []Yes ❑No Packing Material: []Bubble Wrap ❑Bubble Bags ❑ oiV ne [-]Other: Thermometer Used: F-IT1505 Type of Ice: ❑Wet❑Blue []NoneSamples on ice, cooling process has begun Cooler Temp Corrected ('CJ: i Biological Tissue Frozen? ❑Yes=.:.:.ONo, _-I3N/A Temp should be above'freezing to 6'C Correction Factor: 0.0'C Date and Initials of Person Exam_ ining.Ctint�hts: lxll; �L USDA Regtfiated Soil •❑ N/A, water sample} ' Did samples origin +n a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from'a foreign source {internationally, []Yes o Including Hawaii and Puerto RIr'oj?; .: Dyes Q7� If Yes to either question, fill out a Regulated Soil Checklist and Include with SCUR/COC paperwork . COMMENTS:: Chain of Custody Present? Yes ONo ❑N A 1. Chain of Custody Filled Out? es No ❑N/A 2. Chain of Custody Relin uished? es No [I N/A 3. Sampler Name and/or Signature on COC? es No N/A 4, Samples Arrived within Hold Time? es ❑No El MIA S. Short Hold Time Analysis (c72 hr)? es QNo QN/A 6. Rush Turn Around Time Requested? Yes o N A 7. Sufficient Volume? es ❑No [I N/A 8. Correct Containers Used? Yes - []No❑N/A 9. -Pate Containers Used? es ❑No ❑N/A Containers Intact? es []No_ N/A 10. \ Filtered Volume Received for Dissolved Tests? ❑Y r]No ❑N/A 11. Note if sediment Is visible In the dissolved container Sample Labels Match COC? Yes 11 [:]No ❑N/A 12. -Includes Date/Time/ID/Anaiysls Matrix: All containers needing acid/base preservation have been 13. checked? ❑Yes [:]No ❑N/A All containers needing preservation are found to be in compliance with EPA recommendation? / (HNO3, H3SO,, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide) ❑Yes []No []N/A Exceptions: VOA, Colifo rm, TOC, 011 and Grease, DRO/8015 (water DOC,LLH ❑Yes No ©E(/A Samples checked for dechlorization []Yes []No ❑Nf 14. - Headspace In VOA Vials (>5-6mm)? Yes ❑No Dril 15. Trip Blank Present? ❑Yes []No ❑Nw 16. Trip Blank Custody Seals Present? (]Yes ❑No ❑NN/A Pace Trip Blank Lot d (ifpurchased): CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Field Data Required? ]Yes []No r �t 1 Project Manager SCURF Review: i f lU� Date: L ( () i c1f L'f .I f ,Note: Whenever there Is a discrepancy affecting North CarollAa compliance samples, a copy of this form will be sent to the Carolina DEHNR Certification Office (Le. Out of hold, incorrect preservative, out of temp, incorrect containers). Page 11 of 12 �w� .PaceAnalytical' uutr.eacelatuxam CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain-of-Cuslody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section A Section B Section C Page: of Required Client Information; Requfred Project lnfOrma[ion: Invoice Information: C - [ Report TO: Att fflmn: ' O b i i T /, r1�'yt o /7 C� i t- 4 o/L rrpp��,s5 iT !' Copy / To: I G� / Cdan .yamc' •'r C't I J /i t l i 4 T ii REGULATORY AGENCY Address: ? SG . r N?DES r GROUND WATER I- DRINKING WATER L, („ UST )- RCRA {- OTHER Email To: Purchase Order No.: P1we Ouwn Rc[cresxr. p+, Fax: Projecl Na mC: 17 P— map Site Location STATE. f Raquoatetl Duo DatofrAT: Project Number. Pace Praf 1. u: -1 Requested Analysis Filtered (YIN) Section 0 Matrix Codes a z Requhed Ckanl tnlw txm MATRIX I CODE s COLLECTED Preservatives Drinking water DW QU O ` Water wT Waste Water VJIN U C6krPOSiTE Wrtd,uinBE w C _ Product P m START J Soivsoid SL t7 p rn +♦ } SAMPLE ID Od OL Wipe wP = Q a cc w _ m j 1 (A-Z. 0-9 ! : ) Air AR p w a 4 y F V „ V ° L �!r� j/�; "` �� Sample IDS MUST BE UNIQUE Tissue TS O U a N - 1 U "i L3 ",� Other OT X w r w OZ � p N A +� L a 2 rn a p O 11:4 1n += c- V a m N 0 y ~ DATE TIME DATE TIME _ 2 Z Z O v Pace Project ND.! Lab J.D. 2 &L W ^ ^ 'ri G l"Iy $:St 3 S LL) 3 a .5 t�L? � • J S 1 / S s r s s tg it. tz ADDITIONAL COMMENTS RELINQUISHED i / AFFILIATION DATE TIME n , ACCEPTED BY f AFFILIATION DATE TIME SAMPLE CONDrT,ONS �: • 1. 9� i i �� D 5 c,- SAMPLER NAME AND SIGNATURE % ORIGINAL c o ao 'Ti N PRINT Name of SAMPLER: t— 5 o y o u z �_ z w ) - $iGNATURE of SAMP ER X2cc , s [DMT Drgned lYY N lmrx,rtw Nor,, Ry:.w 'M tr kxm yra, P.—O. A>ET 30 d.',y 1,iV -1 1am,5 :,na.W-,9 r° kite t-r_, ar 1.5% per —,th 1w amJ nw jn(rpnid -11- 30 days. 7y� F-ALL-O.020rev.07 • 15-May-2007 4 %/ I Sample Location: Person Collecting Samples: Laboratory Performing Analysis: Analytical Techniques and Methods: Results of Sample Analysis: n OATIAIIN Allvac - Bakers Plant Stormwater Monitoring Report Form Non -Contact Cooling Wastewater f p /yrn� iZon�.L�lV_1 4 Jr Ja-IresAser _]EE_ 1466 !, I 40 CFR Part 136 Non -Coat Sample Location =Effluent Cool Water Sampling Date Sampling Time Estimated Flow (MGD) Total Res Chlorine Temperature pH (deg C) (std. units) m / A. I t i f 3 - 7 �-� ,77.5 4 ���QM of UU �p 1 0�- U o r 5 6 - a �3j 8 . 7 8 8 8 - -� 01641 There are no discharges of air compressor condensate. Benchmark value for Total Res Chlorine = 0.017 mg/L. aceAnalyfical wwwpK*labs.corn December 16, 2015 Mr. Joe Hinkle Allvac RE: Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Pace Ana lytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Dear Mr. Hinkle: Enclosed are the analytical results for sample(s) received by the laboratory on December 08, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com Project Manager Enclosures cc: Mr. Preston Baucom, Allvac Mr. Tommy Long, Allvac REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wntten consent of Pace Analytical Services, Inc.. Page 1 of 26 acmnalytical www.peoe4sb&oom Pace Analytical Services, tnc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)8759092 Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NCO30 North Carolina Drinking Water Certification M 37712 CERTIFICATIONS Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 West Virginia Certification #: 357 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification M 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 26 aceAnalytical www.paceteh&WM SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersvitle, NC 28078 (704)875-9092 Project: Pace Project No.: BAKERS NONCONTACT COOLING 92278853 Analytes Lab ID Sample ED Method Analysts Reported Laboratory 92278863001 NON CONTACT #1 EPA 16646 JMS 1 PASI-C 92278853002 NON CONTACT 01 RC SM 4500-CI G MLS 1 PASI-A 92278853003 NON CONTACT #2 EPA 1664B JMS 1 PASI-C 92278853004 NON CONTACT #2 RC SM 4500-CI G MLS 1 PASI-A 92278853005 NON CONTACT #3 RC SM 4500-CI G MLS 1 PASI-A 92278853006 NON CONTACT #3 EPA 1664B JMS 1 PASI-C 92278853007 NON CONTACT 04 EPA 1664B JMS 1 PASI-C 92278853008 NON CONTACT 94 RC SM 4500-CI G MLS 1 PASI-A 92278853009 NON CONTACT #5 EPA 1664B JMS 1 PASI•C 92278853010 NON CONTACT #5 RC SM 4500-CI G MLS 1 PASI-A 92278853011 NON CONTACT #6 EPA 1664E JMS 1 PASI-C 92278853012 NON CONTACT #6 RC SM 4500-CI G MLS 1 PASI-A 92278863013 NON CONTACT #7 EPA 1664E JMS 1 PASI-C 92278853014 NON CONTACT #7 RC SM 4500-CI G MLS 1 PASI-A 92278853015 NON CONTACT #8 EPA 1664B JMS 1 PASI-C 92278853016 NON CONTACT #8 RC SM 4500-CI G MLS 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 26 (�IacleAnalyfical" www.peoelahsoom ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Hunlersville, NC 28078 (704)875.9092 Project. BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Sample: NON CONTACT #1 Lab ID: 92278853001 Collected: 12/07/15 09:30 Received: 12/08115 08:09 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No, Qual HEM, Oil and Grease Analytical Method; EPA 1664B Oil and Grease NO mg1L 5.0 1 12/15/15 05:42 Cate: 12/16/2015 09:39 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc._ Page 4 of 26 aceAnalytical www.yacelahs.cam ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Sample: NON CONTACT #1 RC Lab ID: 92278853002 Collected: 12/07115 09:33 Received: 12/08/15 08:09 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 4500CL G Chlorine, Residual Chlorine, Total Residual [�Ffi�iFaf[:IY���iI.3�);l[ck7l��il Analytical Method: SM 4500-CI G 0.079 mg/L 0.024 1 REPORT OF LABORATORY ANALYSIS This report shall not 5e reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 12/09/1512:10 7782-50-5 Page 5 of 26 aceAnalytical wwwp&Wbba.com ANALYTICAL RESULTS Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 2807E (704)875-9092 Sample: NON CONTACT #2 Lab ID: 92278853003 Collected: 12107/15 09:50 Received: 12/08115 08:09 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mg1L 5.0 1 12/15/15 05:43 Date: 1211612015 09:39 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc,. Page 6 of 26 aceAnalytical" wW..pecamiciom ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875.9092 Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Sample: NON CONTACT #2 RC tab ID: 92278853004 Collected: 12/07/15 09:52 Received: 12/08/15 08:09 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 4500CL G Chlorine, Residual Chlorine, Total Residual Date: 12/16/2015 09:39 AM Analytical Method: SM 4500-CI G ND mg/L 0.024 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 12109I1512:10 7762-50-5 Page 7 of 26 1ac6Analj4ka( wwwpncelebs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Sample: NON CONTACT #3 RC tab ID: 92278853005 Collected: 12/07/15 10:38 Received: 12/08/15 08:09 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Quaf 4500CL G Chlorine, Residual Chlorine, Total Residual Date: 12116/2015 09:39 AM Analytical Method: SM 4500-CI G 0.028 mg1L 0.024 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wntten consent of Pace Analytical Services, Inc.. 1210911512:10 7782-50-5 Page 8 of 26 IeAnalyticato www.pecefebs.com ANALYTICAL RESULTS Project. BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)8759092 Sample: NON CONTACT #3 Lab ID: 92278853006 Collected: 12107115 10:36 Received: 12/08/15 08:09 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Clual HEM, Oil and Grease Analytical Method: EPA 16648 Oil and Grease ND mg1L 5.0 1 12/15/15 05:43 Date: 12/16/2015 09:39 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 26 le Analj&,al www.pacdebs.00m ANALYTICAL RESULTS Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (7G4)875-9092 Sample: NON CONTACT #4 Lab ID: 92278853007 Collected: 12/07/15 11:00 Received: 12/08/15 08:09 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual ITEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mg1L 5.0 1 12/15/15 05:43 Date: 12/16/2015 09:39 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 26 acMnalyiiaal www.pacelebs.com ANALYTICAL RESULTS Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875.9092 Sample: NON CONTACT 94 RC Lab I17: 92278853008 Collected: 12107115 11:02 Received: 12/08/15 08:09 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 4500CL G Chlorine, Residual Chlorine. Total Residual Date: 12/16/2015 09:39 AM Analytical Method: SM 4500-CI G 0.40 mg/L 0.024 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 12109/1512:10 7782-50-5 Page 11 of 26 (�Iac71lytica! rww.pacelabscom ANALYTICAL RESULTS Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Pace Analytical Services, tnc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: NON CONTACT #5 Lab ID: 92278853009 Collected: 12/07/15 11:25 Received: 12/08/15 08:09 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease 00 and Grease Date: 12/1612015 09:39 AM Analytical Method: EPA 1664B ND mg1L 5.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 12/15/15 05:44 Page 12 of 26 aceAnalytical wmpacalabs oom ANALYTICAL RESULTS Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: NON CONTACT #5 RC Lab ID: 92278853010 Collected: 12/07/15 11:27 Received: 12/08/15 08:09 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. 4ual 4500CL G Chlorine, Residual Chlorine, Total Residual l9JgMiYaiGilr.11I7r1.1111 9.1.1zlu Analytical Method: SM 4500-CI G 0.053 mg1L 0.024 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 12/09/151210 7782-50-5 Page 13 of 26 laceAnalytical" www.pwelebs com ANALYTICAL RESULTS Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Pace Analytical Services, Inc. 9800 Kincey Ave, Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: NON CONTACT #6 Lab ID: 92278853011 Collected: 12107115 11:50 Received: 12/08/15 08:09 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No, Qual HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease NO mglL 5.0 1 12/15115 05:44 Date: 1211612015 09:39 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 26 lemalytica!® wmpaoams com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersvitle, NC 28078 (704)875-9092 Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Sample: NON CONTACT #6 RC Lab ID: 92278853012 Collected: 12/07/15 11:52 Received: 12/08115 08:09 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 4500CL G Chlorine, Residual Chlorine, Total Residual Date: 12/16/2015 09:39 AM Analytical Method: SM 4500-CI G 0.033 mg1L 0.024 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 12109/1512:10 7782-50-5 Page 15 of 26 aceAnalytical` www.pacelahs.00m ANALYTICAL RESULTS Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: NON CONTACT #7 Lab ID: 92278853013 Collected: 12/07/15 12:20 Received: 12/08/15 08:09 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mg1L 5.0 1 12115/15 05:45 Date: 12/1612015 09:39 AM REPORT OF LABORATORY ANALYSIS This report shah not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 26 Pace Analytical Services, Inc. 9800 aCeMalXical Huntersvlle, NC128078 VL+ ��ay`ftco (704)875-9092 ANALYTICAL RESULTS Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Sample: NON CONTACT #7 RC Lab IC: 92278853014 Collected: 12/07/15 12:22 Received: 12108115 08:09 Matrix: Water Parameters 4S00CL G Chlorine, Residual Chlorine, Total Residual Results Units Report Limit DF Prepared Analyzed CAS No. Qua] Analytical Method: SM 4500-CI G 0.28 mglL 0.024 1 REPORT OF LABORATORY ANALYSIS 12/09/1512:10 7782-50-5 This report shall not be reproduced, except in full. Date: 12/16/2015 09:39 AM without the written consent of Pace Analytical Services, Inc.. Page 17 of 26 aceAnalyticat o www.pacdabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875.9092 Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Sample: NON CONTACT #8 Lab ID: 92278853015 Collected: 12/07/15 12:45 Received: 12108/15 08:09 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Oil and Grease Date: 12/16/2015 09:39 AM Analytical Method: EPA 1664B ND mg1L 5.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc., 12115115 06A5 Page 18 of 26 aceAnalytircal www.pecefabacom ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kinsey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Sample: NON CONTACT #8 RC Lab ID: 92278853016 Collected: 12/07115 12:47 Received: 12/08/15 08:09 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G Chlorine, Total Residual 0.041 mg/L 0.024 1 12/09/15 12:10 7782-50.5 Date: 12/1612015 09:39 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 26 1aceAnalyfcal wn►w.peoelahs.cam QUALITY CONTROL DATA Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: GCSV123536 Analysis Method: EPA 1664E QC Batch Method: EPA 1664B Analysis Description: 1664 HEM, Oil and Grease Associated Lab Samples: 92278853001, 92278853003, 92278853006, 92278853007, 92278853009, 92278853011, 92278853013, 92278853015 METHOD BLANK: 1628811 Matrix: Water Associated Lab Samples: 92278853001, 92278853003, 92278853006, 92278853007, 92278853009, 92278853011, 92278853013, 92278853015 Biank Reporting Parameter Units Result Limit Analyzed Qualifiers Oil and Grease mg1L ND 5.0 12/15/15 05:38 LABORATORY CONTROL SAMPLE: 1628812 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Oil and Grease mg1L 40 35.2 88 78-114 MATRIX SPIKE SAMPLE: 1628813 92279258001 Spike MS MS % Rec Parameter Units Result Cant. Result % Rec Limits Qualifiers Oil and Grease mg/L ND 40 33.2 83 78-114 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/16/2015 09:39 AM without the written consent of Pace Analytical Services, Inc.. Page 20 of 26 aceAnalyfical" tvww.pecelabsoam QUALITY CONTROL DATA Project: BAKERS NONCONTACT COO LING Pace Project No.: 92278853 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Hontersville, NC 28078 (704)875-9092 QC Batch: WET141848 Analysis Method: SM 4500-CI G QC Batch Method: SM 4500-CI G Analysis Description: 4500CL G Chlorine, Total Residual Associated Lab Samples: 92278853002, 92278853004, 92278853005, 92278853008, 92278853010, 92278853012, 92278853014, 92278853016 METHOD BLANK: 1623761 Matrix: Water Associated Lab Samples: 92278853002, 92278853004, 92278853005, 92278853008, 92278853010, 92278853012, 92278853014, 92278853016 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chlorine, Total Residual mg1L ND 0,024 12/09/15 12:10 SAMPLE DUPLICATE: 1623762 92278853002 Dup Parameter Units Result Result RPD Qualifiers Chlorine, Total Residual mg1L 0.079 0.066 18 Results presented on Ws page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the resuh. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/1612015 09:39 AM without the written consent of Pace Analytical Services, Inc Page 21 of 26 leAnalytical wWw.pect0slo.canr QUALIFIERS Project. BAKERS NONCONTACT COOLING Pace Project No.: 92278853 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantilalion Limit. RL - Reporting Limit. Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 S - Surrogate 1,2-Diphenythydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services -Asheville PASI-C Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shalf not be reproduced, except in full, Date: 1211612015 09:39 AM without the written consent of Pace Analytical Services, Inc,. Page 22 of 26 71 aceAnalj6cal www.pecelobs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: BAKERS NONCONTACT COOLING Pace Project No.: 92278853 Lab ID 92278853001 92278853003 92278853006 92278853007 92278853009 92278853011 92278853013 92278853015 92278853002 92278853004 92278853005 92278863008 92278853010 92278853012 92278853014 92278853016 Sample ID QC Batch Method NON CONTACT #1 EPA 1664E NON CONTACT #2 EPA 1664B NON CONTACT #3 EPA 1664B NON CONTACT #4 EPA 1664B NON CONTACT #5 EPA 1664B NON CONTACT #6 EPA 1664E NON CONTACT #7 EPA 1664B NON CONTACT #8 EPA 1664B Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch Analytical Method GCSV123536 GCSV123536 GCSV123536 GCSV123536 GCSV123536 GCSV123536 GCSV123536 GCSV123536 NON CONTACT #1 RC SM 4500-CI G WETI41848 NON CONTACT #2 RC SM 4500-CI G WETI41848 NON CONTACT #3 RC SM 4500-CI G WETI41848 NON CONTACT 94 RC SM 4500-CI G WET141848 NON CONTACT #5 RC SM 4500-CI G WET14184B NON CONTACT #6 RC SM 4500-CI G WET141848 NON CONTACT #7 RC SM 4500-CI G WET141848 NON CONTACT #8 RC SM 4500-CI G WET141848 IbFiLt4ff�]iGlf��+i6i1�!Ac)•r7JA�] REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch Page 23 of 26 Document Name: Document Revised: November 17, 2015 Condition Utson Recelnt tSCUR? Page 1 of 2i ceknalytical Client Name: - I lv�, Document Number: F-C H R-CS-003-rev.1 B.1 Pace hiuntersville Qualitv Office ' Page 2 of 2 is for Internal Use Only Courier: ❑ Fed 60 UPC]USP❑ Clier=CommerciC ace Other Q tlonelt t :- K Custody Seal on Cooler/Box Present: ❑ yes ❑ no Seals intact: ❑ yes ❑ no Pro)4Du8 Date Prolr Narnta Packing Material: ❑ Bubble Wrap 0 Bubble Bags ❑ None ❑ Other Thermometer Used: IR Gun IS' Type of Ice: (Wet Blue None ❑ Samples on ice, cooling process has begun Temp Correction Factor No Correction (� L Date and Initials of person examining Corrected Cooler Temp.: •C Biological Tissue is Frozen: Yes No fflA contents: Temp should be above freezing to VC Comments: 11�Chain of CustodyPresent: Oyes No ❑NIA 1. Chain of CustodyFilled Out: ❑Yes ❑No ❑N/A 2. Chain of Custodv Relinquished: ❑YssONO ❑N!A 3 Sampler Name & Signature on COC: EKs ONO ❑NIA 4. Samples Arrived within Hold Time: DYes []No ❑NIA 5, Short Hold Time Analysis a72hr : Oyes ❑Noo QNIA 6, Rush Turn Around Time Requested: Dyes ❑No ❑N/A 7, Sufficient Volume: GYee ❑No ❑NIA 8. Correct Containers Used: -Pace Containers Used: EIYes ❑No ❑ Yaa ❑No ❑N/A ❑NIA 9. Containers Intact: OYes ❑No ❑NIA 10. Filtered volume received for Dissolved tests ❑Yes ONO ❑NIA 11, Sample Labels match COC: -Includes date/time/ID/Analysis Matrix; ElYs ONO ❑NIA 12. All containers needing preservation have been checked. ❑Yes ONO I ❑N!A ' 13. All containers needing preservation are found to be In ❑Yes ONO. ❑N1A compliance with EPA recommendation, excepilons: VOA coliform, TOC, O&G, WI-DRO (water) ❑Yea ONO Sarre les checked for dechlorination: ❑Yes ONO ❑NrA 14. Meads ace In VOA Vials >6mm : ❑Yes ❑No ❑N A 15. Trip Blank Present: ❑Yes ONO ONA 16, Trip Blank Custody Seals Present ❑Yes ONO ❑NIA Client Notification/ Resolution: Field Data Required? Y / N Person Contacted: Date/rime: Comments/ Resolution: SCURF Review: V\A5 Date: 17 j r.�l' I� SRF Review: ]Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( !.a out of hold, incorrect preservative, out of temp. Incorrect containers) Place label here WOp..92278853 ignalfiVIIA Page 24 of 26 v� r .PaceAnaVical' rrww-aaulahs_mm CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain-oi-Custody is a LEGAL DOCUMENT. Ail relevant fields must be completed accurately. Section A Section B Section C Page: Of M Required CFent Information: Required Project Information: Invoice Information: �•. Report To: A:tentiom. ' 1903 b O ! ! c- l om Lan r " n Atld 4 Q ,ID LJ Copy To: O C ! J q14REGULATORY AGENCY on �G re, e Ad f, Q� 50' p8nCQ i NPDES r GROUND WATER f- DRINKING WATER F- UST r RCRA OTHER Email To: Purchase Order No.: Pace ouolo Relamnco: P Fa : Project p Pace aropa sire Location STATE:J / V V Requested Due DaIaITAT: Project Number; Paw Pio"a e; Requested Analysis Filtered (YIN) Section 0 Matrix Codes - z x,guirad Cbeat lnlan bon MATROK r CODE s COLLECTED Preservatives > Drinking Water DW - $ U Oz 4% WaterWT11 Waste Water WW rJ COUPots,1E CAMI-=1C `t PrOduCt P - Q START ENDC-qAB w t - Z_ SOIVSOIId SL ^ 0 m r� } SAMPLE I❑ wipe - 6 L) W -� BOLL 1A-Z.0.91.•I Air AR w < a z d Sample Ips MUST BE UNIQUE TO to O w Lu .0 ? U i Z 7 7 ther OT z 2.ra ' 7sQ J J U m c - a v_ W N DATE TIME DATE TIME D = x z z z 2O L + fY Pace Project No! Lab I.D. 1 G l27-IS 4•. a 29. G��t 2 / LL C r C,T 15 : 33 24. rr' 7 s Co '�74•G � � G •1.7-IS R : so a f . is c_ ? a IVad C 44 01,AL12 7 14 ID 6 G�� I 5 2-1-1S 10:56 w 17.3 { r 5 a-7-1518:3Q I I x - 7 G 7- 11.00 rrn34AI X a n ;� 1-1 b a 7.15 -c,a* t I X YI G G Y 9 » S r, G 7-15 1t:]5arrl f•1 i to •7-15 IX- Gr G tt E7 1-1-15 i t 3va,.r ll.4 I L iylr 12 I A101VwT G I 14 I:52aa1 t2-4 I1XI I I I , ' ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE TIME ACCEPTED BY (AFFILIATION DATE TIME SAMPLE CONDITIONS ORIGINAL SAMPLER NAME AND SIGNATURE ? /%� C t1- n E E, } PRINT Name of SAMPLER: • f TQ , rlrr �i � J Arnlf o5 er �� o C ~ m er u U a r P1 H Y DATE Signed SIGNATURE of SAMKL _ - /� / 1MMtDD1YY1: 'imPemanl Nao: By syninn this lam you are arr ,p" Paco's NET 30 aay payment 14 rq: and agreuirg to Lane Cartes or 1.5% per rwnth 1 any i, - V1 $A 30 tL ss F•ALL-0-020rev.07. 15-May2007 CHAIN -OF -CUSTODY 1 Analytical Request Document o� ' The Chain -of -Custody is a LEGAL DOCUMENT. AN relevant fields must be completed accurately. `~ PaceAnalytical Itnr.aaeelaw.eem Section A Section B Section C Page: of10 Required Client Information: Required Project Information; Invoice Information: Attention: }�� 0 Co Report To: - , r ' e , / ` [/� G qr �< D Addres QU COPY To: �� t �� Com - mma� MA REGULATORY AGENCY /C L ,Alt Al r. a J Addr UO Q Q n , T NPDES F GROUNDWATER r DRINKING WATER Emoil To: Purchase Order NO.: Pxe o„ote i UST r" RCRA ( OTHER Rekzurrrn; rpm ! yJ �1 Fax: Project Na / '7 �L'%% i Paco Prgcu Site Location gq- n/ C� - n t�r. Requested Duo DatwTAT: PrvjeU Number: Pace Prorilu u; c� STATE: /j /'/ ALL Requested Analysis Filtered (YIN) Section D Matrix Codes - r z Raqulr.d CLr tkdormaLnn MATRIX !CODE $ COLLECTED Preservatives `- Drinking Water DVy U 11 O Water WT C� a 17 M,TE rsm—TE wastewater Product 4 P m START ENDCRAB µ) L r- Z Soi$Sdid SL D 0 y O } SAMPLE ID wa " U w ei C (A-Z. o-s [,-I wi P AirAR o 4 Z eN1 F- o Sample cps MUST BE UNIQUE Tissue TS O V Q. i Z •iq Other OT xw J o N ..� o p !, _ z H a a u- �'O 2N Q =N O 2 Y m G '� y ~ N s z z DATE TIME DATE TIME = o Cr Pace Project No.! Lab I.D. •IS 12: OA a L �z/ A D• 7 2 2.7-13 law yl 3 CT ]: P : X C 4 J11n.A (_a n r !I- 0 l� t.t7 rr r�.7-1i 1] :t17P c Ity AC I Y ADDITIONAL COMMENTS EUNQUISNED BY! AFFIUATIO�Nj1 TIME ACCEPTED BY I AFFILIATION DATE TIME SAMPLE CONDITIONS JnDATE /] =!,zz61 j,)=s-( I jug/ , ORIGINAL SAMPLER NAME AND SIGNATURE PRINT Name of SAMPLER: SIGNATURE of SAMPLER: 'UrV mtrl Note- By W wV Iran corm you am aorept.g Ries NET 30 payment lemn .we a.7ce. 9 to We ctwges of 1.5% tali recur Iw any.rvo/cs not D /lia +e 1�td �Q. DATE Signed l _ /�-� `—' U '� E — / IY MWD Yj: / N r a Bays. F-ALL-0-020rev.07. 15-May-2007