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HomeMy WebLinkAboutNC0036269_NOV-2019-LV-0572 Response_20190822August 22, 2019 CERTIFIED MAIL RETURN RECEIPT REQUESTED Mr. W. Corey Basinger, Regional Supervisor Water Quality Regional Operations Section Mooresville Regional Office Division of Water Resources, NCDEQ 610 E. Center Avenue, Suite 301 Mooresville, NC 28115 WATER & SEWER AUTHORITY OF CABARRUS COUNTY Administrative Offices 232 Davidson Hwy, Concord, NC 28027 704.786.1783 ♦ 704.795.1564 Fax Rocky River Regional WWTP 6400 Breezy Lane, Concord, NC 28025 704.788.4164 ♦ 704.786.1967 Fax www.wsacc.org SUBJECT: NOTICE OF VIOLATION & INTENT TO ASSESS CIVIL PENALTY TRACKING #: NOV-2019-LV-0572 PERMIT: NCO036269 — ROCKY RIVER REGIONAL WWTP, CABARRUS COUNTY Dear Mr. Basinger: This is in response to the subject letter issued by your office on August 6, 2019 and received by the Water and Sewer Authority of Cabarrus County (WSACC) Administrative Office on August 12, 2019. WSACC acknowledges the exceedance of the NPDES permit parameters for Nitrogen, Ammonia Total (as N) for the Rocky River Regional Waste Water Treatment Plant (RRRWWTP) as described in the Notice of Violation. WSACC has already taken remedial actions to correct this problem and prevent further occurrences. WSACC also contacted the Mooresville Regional Office (MRO) at the onset of this event, even scheduling a meeting with the MRO staff on April 17, 2019 to discuss plant performance issues. We have remained in contact as we've progressed through this event. WSACC experienced a plant upset at RRRWWTP starting in January 2019. It is our belief that a toxic substance came into the plant and inhibited the nitrification process. Since that time we have intensified efforts to identify the source(s) that may have contributed to the plant upset. We were able to identify a major industrial site being decommissioned that discharged a significant amount of cooling tower water which may have contained algaecides that could have contributed to the loss of nitrification. During this same period of time, there were mechanical and maintenance issues at the aeration basins, and with the weakened state of the plant, we believe the plant could not effectively treat the influent load. From January to June 2019, the RRRWWTP struggled to full nitrification. Page 2 NOV-2019-LV-0572 August 22, 2019 Starting in February 2019, WSACC contracted with industry experts Maryland Biochemical Company, Inc. and Brown and Caldwell to assist in identifying the cause of the process upset and to determine appropriate process enhancements. As part of this effort, WSACC performed extensive testing on various influent and plant -process related samples to identify potential sources and influences of toxicity, and WSACC has implemented significant process enhancements in the last several months to create a more robust set of operating conditions at the plant. WSACC offers the attached Technical Memorandum from Brown and Caldwell titled "Loss of Nitrification and Recovery Summary," which includes more specific details as to the events surrounding the loss of nitrification at the RRRWWTP and the efforts undertaken to restore the plant to compliance. WSACC is pleased to inform you that RRRWWTP was in full compliance with all permit parameters during the month of July 2019 and passed its bioassay that occurred the week of August 5, 2019 at greater than 100% chronic value. Please let me know if there is additional information you or your staff need to complete your evaluation of this unfortunate event. We appreciate any consideration you can give for the resources, time and effort WSACC invested to resolve the plant nitrification issues we have been experiencing. Sincerely, Mark Fowler Facilities Director M F/TH/blc Encl. Loss of Nitrification and Recovery Summary ecc: Roberto Scheller (Mooresville Regional Office) Mike Wilson (WSACC) file =Bnweltldwelt 309 E Morehead St., Suite 160 Charlotte, NO 28202 Tel: 704-358-7204 Fax: 704.358-7205 Prepared for: Water and Sewer Authority of Cabarrus County (WSACC) Project Title: Operations Assistance at the Rocky River Regional Wastewater Treatment Plant (RRRWWiP) Project No.: 153530 Technical Memorandum No. 3 Subject: Loss of Nitrification and Recovery Summary Date: To: From: Copy to: Prepared by: Reviewed by: Limitations: August 20, 2019 Chad VonCannon, PE, Acting Engineering Director George Anipsitakis Thomas Hahn, PE, Utility Systems Engineer Mark Miller, PhD, PE, Process Engineer, License No. 045265, Exp. 12/31/2019 >>tttlllll/tt .cL SEAL f 036485 ! tt�tltlill1111\l�\ George Anipsitakis, PhD, PE, BCEE, Project Manager, License No. 036485, Exp. 12/31/2019 This document was prepared solely for WSACC In accordance with professional standards at the time the services were performed and In accordance with the contract between WSACC and Brown and Caldwell dated April 4, 2019. This document Is governed by the specific scope of work authorized by WSACC; It Is not intended to be relied upon by any other party except for regulatory authorities contemplated by the scope of work. We have relled on Information or Instructions provided by WSACC and other parties and, unless otherwise expressly Indicated, have made no independent Investigation as to the validity, completeness, or accuracy of such Information. Loss of Nitrification and Recovery Summary Executive Summary This Technical Memorandum 3 (TM-3) summarizes the analyses performed trying to identify the cause of ni- trification loss at the RRRWWTP and the changes implemented that ultimately led to nitrification recovery and restoring plant performance. Summaries of investigations, analytical testing, and operational changes are provided. Recent testing within the plant and out in the collection system suggested that the plant had been receiving nitrification inhibiting compounds both internally (recycle streams) and externally. These compounds could not be identified with certainty. It is believed that a plant upset occurred in January 2019 when a recently decommissioned industrial facility (Philip Morris) discharged large volumes of cooling water over a long pe- riod to the sewer system. This slug, which ultimately reached the treatment plant and believed to have con- tained algaecides, upset the activated sludge biology at the plant. Given the cold temperatures and the fact that the plant had been operating in a single step (parallel mode) without any protection offered by pretreat- ment led to a complete loss of nitrification from which the plant could not recover. Late March 2019, WSACC contacted Brown and Caldwell (BC) requesting assistance since up to that point no significant improvement in plant performance was realized despite the significant efforts by operating personnel. BC mobilized early April 2019 and together with WSACC performed a series of tests and opera- tional changes in an attempt to identify the cause of the upset and restore plant performance as soon as possible. Finally recovering from this upset took some time as the focus was initially on prevention by identi- fying the inhibitory compound(s) and removing them or their source from the system. Throughout this period, WSACC implemented significant analysis and process improvements trying to restore the plant performance. In late May 2019 it became apparent that the cause of this upset was not going to be easily identified, the focus was shifted to controls and more drastic actions (changing plant configuration from parallel to partially series) were taken. The plant was reconfigured to a partially series (two-step) mode with a flow split at a ratio of 60/40 between Step 1 and 2 on June 3, 201-9. Unfortunately, the plant suffered from nitrite lock for the majority of June and, even though performance was improved, the weekly ammonia permit limits were still not met. This nitrite lock condition was identified on June 26, 2019 at which point the flow split was in- creased to 70/30 between Step 1 and 2 and the Step 1 SRT was reduced to 2 days. These actions elimi- nated this nitrite lock, restored full nitrification in Step 2 and stabilized the plant's performance. The plant has been operating without a notable issue for the whole month of July 2019 up to this date. A timeline of important events is provided in Table ES-1 and final effluent total ammonia nitrogen concentra- tions for 2019 are provided in Figure ES-1. Next, it is important that the plant be prepared for the upcoming winter or the future to be able to handle possible additional upsets that may be the result of lower temperatures and inhibitory compounds that will continue to be received. Recommendations for future operations are therefore provided in the last section of this TM-3. �rown�oCaldwel! 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary Date went January 2019 Recently decommissioned industrial facility (Philip Morris) discharges large volumes of cooling water over a long period to the sewer system. Three sub -basins of Step 2 bioreactor are also drained (one at a time) and brought back online within a period of seven days to address clogging issues with the aeration mixers. Treatment declines rapidly resulting in effluent permit violations for ammonia and fecal coliforms (weekly limit) and high daily concentrations of effluent total suspended solids (no permit violation). Ability to nitrify is almost completely lost. March 15, 2019 Bioreactors are seeded with a blend of nitrifying bacteria by Novozymes. March 25, 2019 WSACC contacts Brown and Caldwell (BC) requesting assistance. March 27, 2019 Novozymes' representative Kin Ferrell visits the plant fortesting and devising additional seeding plan. April 1, 2019 Bioreactors are re -seeded with blend of nitrifiers by Novozymes (3-day event). April 3, 2019 BC visits the plant for the first time. April 10, 2019 First activity test is performed. April 25, 2019 -July 10, 2019 More rigorous activity test program is implemented. May 13, 2019 Plant starts adding polymer upstream of the secondary clarifiers using existing dated equipment. June 3, 2019 Plant is reconfigured to a partially series (two-step) mode with a flow split at a ratio of 60/40 between Steps 1 and 2. June 6, 2019 Jartesting is conducted using emulsion polymer. June 11, 2009 to date Plant starts renting and testing skid -mounted dry and emulsion polymersystems. June 13, 2019 Jartesting is conducted using dry polymer. June 26,2019 Nitrite lock is identified. Flow split is increased to 70/30 between Step 1 and 2. June 27, 2019 Step 1 SRT is reduced to 2 days. July 5, 2019 Weekly ammonia limit of 3.6 mg/L is met forthe first time since initial plant upset. a FE TAN 30-day TAN 30 1 25 E 20 0 E 15 E c 10 N 5 w c 0 u- 1/1/19 1/31/19 3/2/19 4/1/19 5/1/19 5/31/19 6/30/19 Figure ES-1. Final Effluent (FE) Total Ammonia Nitrogen (TAN) Concentrations BIOWt� +o "atdW�At 7/30/19 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary Section 1: Background The RRRWWTP is a high purity oxygen (HPO) activated sludge system rated for 26.5 million gallons per day (MGD) that is currently treating 17-20 MGD of medium to high strength wastewater. In the last two years, the RRRWWTP has been experiencing performance fluctuations. Beginning in January 2019, treatment de- clined rapidly resulting in effluent permit violations for ammonia (Figure 1) and fecal coliforms (weekly limit; Figure 2). Uncharacteristically high daily concentrations of total suspended solids (TSS; Figure 3) were also measured in the effluent, though no permit limit was violated for that parameter. Suppression of nitrification due to lower temperatures during winter has been observed regularly (at least in winters 2007-8, 2008-9, 2016-17, 2018-19) with multiple reports written by consultants (Hazen, Gilligan, Black & Veatch) trying to address the problem. In January 2019, the ability to nitrify was almost completely lost at the RRRWWTP and the plant did not re- cover when process temperature increased in April and May. Brown and Caldwell (BC) was initially contacted on March 25, 2019 to mobilize and assist with resolving this situation and visited the plant for the first time on April 3, 2019. 30 i .CO 25 0 E 20 i Q J 4F \ 15'aO ga. 23 E �a Uj RS C: 5 I ®� Apr-16 Oct-16 May-17 Nov-17 Jun-18 Dec-18 Jul-19 ewe] a 7,000 J E 6,000 5,000 0 4,000 y- U w 3,000 c_ 0 2,000 LL 6 V 1,000 0 1-Apr Figure 1. Historical Final Effluent Ammonia 18-Oct 6-May 22-Nov 10-Jun 27-Dec 15-Jul Brown-Catdwett 3 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary Figure 2. Historical Final Effluent Fecal Coliform Figure 3. Historical Final Effluent TSS Initial investigations revealed the lack of higher life forms and filamentous bacteria within the biological flocs, which indicated the presence of toxic compounds in the influent. The lack of filamentous bacteria that form the backbone of strong flocs resulted in pin flocs with poor flocculation leading to high effluent TSS, particularly in Step 2. High solids in the effluent often leads to high fecal coliform counts when the disinfect- ant dose is too low. Early in 2019, WSACC added polymer upstream of the aeration basins at the recommen- dation of the polymer supplier and, later in spring, switched the feed location to upstream of the each Step 2 secondary clarifier to improve flocculation. Unfortunately, success was limited because of the high dose re- quired and the limitation of the polymer make down equipment. Nitrification was consistently inhibited with only short periods where the process seemed to recover. This in- dicated that the influent toxicity was not constantly entering the plant or at least not at the concentrations that would cause inhibition. Mechanical and process issues did not appear to be the cause since the efflu- ent had enough alkalinity for nitrification and the dissolved oxygen (DO) in the HPO basins was high. Carbo- naceous oxidation appeared to be unaffected suggesting the substance(s) causing the toxicity was(were) not in high enough concentrations to completely kill the entire biological process. There have also been concerns about the high usage of pure oxygen and chemical for alkalinity and pH con- trol. The plant also operates a multiple hearth incinerator, which returns a liquid stream from the scrubber system back to the main process with high constituent concentrations known to suppress the biological ac- tivity of the activated sludge process. BrownANpGatdwett 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary Section a Site Visits and Data Review Several initial and follow-up site visits were conducted by BC personnel to assist the RRRWWTP operations and lab staff with identifying potential causes of treatment issues. Plant operational data and discharge data for significant industrial users (SIUs) was requested and reviewed to identify potential sources. Results and observations from the site visits and data review are provided herein. 2.1 Initial Observations During the initial site visits it was demonstrated that the activated sludge system did not contain nitrifiers. Short-term recommendations included dropping the mixed liquor suspended solids (MLSS) down to 3,000- 3,500 mg/L and attempting to regrow the nitrifiers. In addition, BC recommended reducing DO in the oxy- genation tanks down to approximately 10 mg/L from the observed 20 to 30 mg/L and perform additional and more frequent testing in the collection system for total Kjeldahl nitrogen (TKN). The focus during the initial site visits was on the following possible causes for the plant upsets: 1. External or internal constituents causing acute or chronic toxicity to the biomass including: — Heavy metals. — Cyanide from the incinerator scrubber blowdown water. — TKN and organic compounds including quaternary amines (quats) from industrial activity or cleaning and disinfection products. Literature suggests that as low as 1-2 mg/L of quats are toxic to the bio- mass. The RRRWWTP had measured once at least 9 mg/L of total quats in the biomass. The RRRWWTP also receives septage, which may contain substantial amounts of these quats. The RRRWWTP also receives landfill leachate that has a pretreatment pond that is known to lose nitrifi- cation during winter. — Soluble phosphorus deficiency. The RRRWWTP receives water plant sludge containing alum and powder activated carbon (PAC). Alum can bind soluble phosphorus to a degree that causes defi- ciency of that nutrient limiting biomass growth. 2. Operational issues that may have been caused by the following: — Switching to a parallel (single step) operation (October 2016) when literature recommends partially series (two-step) operation for plants that require year-round nitrification and may receive toxic ma- terials and organic surges. — Difficulty in controlling wasting from Step 2 because of hydraulic limitations associated with the par- allel (single step) operation. — The draining of several HPO basins in quick succession for cleaning and maintenance of mixers that had been clogged with rags limiting the oxygen transfer in those basins. WSACC drained several of these basins in quick succession causing excessive wasting. — MLSS instead of solids retention time (SRT) control of the biological process resulting in excessive swings in SRT from one day to the next. — Operating at a sludge age below the critical SRT for nitrification. — Limited alkalinity and pH control as demonstrated by insufficient alkalinity (bicarbonate). The following historical records were reviewed to.document trends and identify any abnormalities: BrownANo Caldwell 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary 1. Laboratory data to include influent, primary effluent, secondary effluents, and final effluent constituents and flows. 2. Operational records and process control data to include incinerator temperatures, HPO DO levels, SRT, processes in/out of service, and solids concentrations. 3. SIUs' laboratory data, flow contribution, primary business function, and any changes to current opera- tions. 4. Review of previous reports by Hazen, Black & Veatch (B&V), and Tom Gilligan. 2.2.1 Influent Flows The annual average influent flow has increased by approximately 57% since 2016 and is approaching the design capacity of the plant as shown in Figure 4. The combined influent flow includes the Cold Water and Irish Buffalo (CW+IB) and the Lower Rocky River Pump Station (LRRPS) interceptors. The fall and winter of 2018-2019 had significant rainfall events including two hurricanes and higher than average precipitation, so some of the high flow values in the year are the result of extreme wet weather events and not necessarily growth within the sewer basin. a Combined Influent ® Flow 30-day ® Flow 365-day 70 60 050 75 3 40 0 LL .., 30 c a� 20 c 10 141 Apr-16 Oct-16 May-17 Nov-17 Jun-18 Dec-18 Figure 4. Historical Combined Influent Flows 2.2.2 Influent Constituents Plant operating data for a three-year period from April 2016 through April 2019 were tabulated and were reviewed. Figure 5 provides a graphical illustration of the influent biological oxygen demand (BOD5), chemi- cal oxygen demand (COD), TSS, and total ammonia nitrogen (TAN) loads. Influent loads have been climbing mainly due to an increase in flows. However, TAN has the steepest upward trend as shown in Figure 5. The same was observed by Hazen in their 2015 BioWin update report. gown-o Cal.dweit 6 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary 185,000 165,000 U) 1 145,000 to a O M 125,000 c c� r7 85,000 c 0 0 4- S 65,000 0 c 45,000 0 v 25,000 - Apr-16 TSS Load a COD Load ® BOD5 Load a TAN Load 40 Oct-16 May-17 Nov-17 Jun-18 Dec-18 —r 12,000 i I i 10,000 S 4 II Memo 4,000 2,000 H] 0 z 0 W v— c 0 c E 0 0 Figure 5. Historical Influent Loadings Plant influent without recycles, primary influent with recycles, and primary effluent average concentrations establishing primary clarifier removal efficiency for the same period are summarized in Table I. Influent Primary Influent Primary Effluent Percent Removal BOD5(mg/L) 313 286 153 46% COD(mg/L) 722 680 332 45% TSS(mg/L) 313 320 74 77% TAN (mg-N/L) 1 36 28 1 27 1 No removal TKN (mg-N/L) Limited data t 52 No data The recycle streams are less concentrated, at least in the constituents listed. For TKN, review of limited data suggests that the recycle stream contains almost the same concentration as the RRRWWTP influent. From the primary influent dataset, the COD to BOD ratio has been 2.4-2.5 and the TKN to TAN 1.8-1.9 on average when more typical values are 2 and 1.3, respectively. This is an indication of higher organic nitrogen compounds than typical. This could include such compounds as quats. �rown�oCaldwet! 7 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary 2.2.2.1 Influent TKN High concentrations of TKN have been measured sporadically in the collection system and in the RRRWWTP influent. TKN has been historically measured once a month, but additional data was collected recently for this evaluation to identify potential sources of inhibition. The LRRPS interceptor historically has higher con- centrations and flows than the CW+IB side of the collection system. Figure 6 summarizes recent TKN data. High spikes of TKN can be observed while TAN concentrations remained relatively stable. TKN ®TAN 180 160 140 120 100 80 60 40 20 Apr-16 Oct-16 May-17 Nov-17 Jun-18 Dec-18 Figure 6. Combined Influent TKN and TAN Concentrations Additional sampling of the CW+IB and LRRPS interceptors was conducted and higher than normal TKN con- centrations were detected in both interceptors (Figure 7). The spikes in the CW+IB were not as sustained as the LRRPS. Due to these abnormally high TKN concentrations, it was suspected that the inhibition issues were indeed coming into the plant through the collection system. However, high TKN in the influent was not a new issue. Figure 8 below from the 2011 Hazen Rerate Report shows some limited TKN data in the influ- ent from September 2007 to June 2009. Some high values were also observed during this period. 140 120 100 E 80 Z 60 Fes- 40 20 I 3/1/19 ® -CW+IB TKN -LRRPS TKN 3/11/19 3/21/19 3/31/19 4/10/19 4/20/19 4/30/19 5/10/19 5/20/19 5/30/19 Figure 7. Collections System TKN Concentrations BrownAw Catdwelt t„v mmnmis�a�nssemm 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary 140 12P ion E no [.a 40 YD 110010 18000 a nauo goad 6454 4"C'm 10011 6 a _ -_._._ 4, ___ -__. __ -, - -, -____.— U aid-06 4ap-01Q fYec" M -Dy hua.031 Sert-Iky Ur -0t t.9ar-ON J. -9M Wpdou O -tvt! M -99 Sun-09 +hill!+ArIt ThH t�nnt�rer silz?i Ize tnit�I:W�tTK�LcarltrS�R�it� Figure 8. Influent TKN Data from September 2007 through June 2009 (Figure 3-5 from Hazen Report) 2.2.3 SRT A comparison of final effluent ammonia and the aerobic SRT (aSRT) for each HPO step is provided in Figure 9. The aSRTs have been too low historically and changed erratically from one day to the next because WSACC has historically been adjusting wasting to maintain a certain MLSS concentration and solids inven- tory rather than aiming for a certain SRT, When there are performance issues, the plant seems to be wasting less leading to an increase in the aSRTs, but this reaction is too late. As shown in Figure 10, the aSRT of Step 1 has been particularly low, even after switching to a parallel operation. Step 1 may have been perform- ing better at lower aSRTs because it was underloaded, its primaries had higher hydraulic retention times (HRT) and had more secondary clarifier capacity for the portion of flow it received (longer overall SRT and HRTs). Note that the SRT of both Step 1 and Step 2 were higher (red rectangle) than historically in the winter of 2017-18 when ammonia bleed through was suppressed unlike the winters of 2016-17 and 2018-19. gown o C ildweIt 9 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary 30 J 25 Z ao E 20 r� 0 4/1/2016 2.2.4 Metals o NH3-N a MCRT Stp I A MCRT Stp II 10/18/2016 5/6/2017 11/22/2017 6/10/2018 12/27/2018 Figure 9. Comparison of Final Effluent Ammonia and WWTP Aerobic SRTs 30 25 Metals data for the plant influent, effluent, mixed liquor, and SIUs was reviewed. Additional mixed liquor samples were collected from Steps 1 and 2 to investigate possible heavy metal inhibition. Zinc (2.3-1.6 mg/L) and copper (0.7-0.8 mg/L) were found to be elevated but were not significant enough to raise any concerns. Historical data that was reviewed also had elevated concentrations of zinc and copper during nor- mal operational conditions. Additionally, SIUs' metals data were all similar to historical concentrations. Additional sampling of plant recycles including scrubber blowdown, thickener overflow, and ash pond water was conducted but none of the streams contained concentration of metals that would be of concern for inhi- bition. 2.2.5 Cyanide Cyanide that is present in incinerator scrubber blowdown water is a known inhibitor of nitrification at concen- trations as low as 0.3 mg/L. Previous reports (2017) included analysis of the scrubber water that ranged from 4.6 to 14.8 mg/L as total cyanide. During the previous winters, the treatment plant had struggled to maintain complete nitrification and this can likely be attributed to cyanide inhibition that is more severe at colder temperatures. Based on previous plant experience, nitrification rates would improve when the inciner- ator was taken out of service for maintenance. 2.3 SIUs The SIUs (Table 2) were contacted by WSACC to determine if any changes in production, chemical usage, or operations were made. For certain industries additional data was requested including receiving logs. It was identified that in January 2019, during decommissioning, a Phillip Morris site discharged in the sewer large quantities of cooling tower water. It was believed that this initial event is what caused the first loss of nitrifi- cation since cooling water often contains biocides for algae control. Algae die off was also noted in the sec- ondary clarifiers and effluent channels at the plant. No further discharges were reported from this site. Brown-oCaldwell 10 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary Americhem Color resin 44,000 BFI Waste Systems Landfill 150,000 Charlotte -Meek. Municipal 4,000,000 Charlotte -Meek. Municipal 2,000,000 CHS-Northeast Hospital 85,000 CHS-Northeast Hospital 70,000 City of Concord Water Plant 1,600,000 Galvan Industries Galvanizing 3,000 HeiQ Chem -Tex Textile 20,000 Heritage Crystal Clean CWi-Oil 86,000 Organic Dyes & Pigments Dyes & Pigments 3,000 Owens Corning Furnace Parts Mfg. 4,000 Perdue Farms Poultry 500,000 Star America Textile 75,000 Stericycle Medical Waste 32,000 Stericycle Medical Waste 13,000 The highest flow contributor on the LRRPS interceptor is Charlotte Water (4.9 MGD) with some of its wastewater containing higher than typical COD and ammonia loads (CMUD-05). Other lower flow contributors on the LRRPS side include the BFI landfill (0.055 MGD), solids from the City of Concord water plant (0.15 MGD) and Heritage Crystal Clean (0.045 MGD), a centralized waste treatment facility that also treats oily wastewater. All contain high COD and/or high ammonia concentrations, but the mass loadings are relatively low. In the past, no TKN data was collected from the SIUs, but for this recent evaluation, TkN data was col- lected from selected SIUs. Heritage Crystal Clean (HCC) did not initially report treatment issues at their facility, but later reported treat- ment process upsets occurring on and off in April 2019 with high effluent TSS and ammonia concentrations. HCC was able to identify the customer that was causing treatment issues and switched from liquid treatment to pit solidification. By switching the treatment method, the customer's waste would no longer be present in HCC's discharge. However, no improvement at the RRRWWTP occurred after HCC's treatment processes re- covered. 2.4 Previous Reports The previous reports completed by other consultants were reviewed and the primary findings and recom- mendations are provided here. 2.4.1 Thomas Gilligan, Evaluation Report, August 2017 The driver for this report was to investigate the effluent limit violations in December 2016 through February 2017. Main findings of this report included the following: Brown-DCaldwett 11 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary Previous operation of wasting from Step 2 to Step 1 had the benefit of keeping the nitrifiers in the sys- tem. Reasons for excursion included insufficient oxygen transfer due to impeller clogging/blockage, too high nitrifier waste rate (i.e., low SRT), and too low reactor pH (<6). The report summarized data in a tabular monthly average format of several operating parameters from July 2015 through May 2017. The report had a few recommendations including replacing the older mixers that had been prone to clogging. This recommendation has been implemented in phases and was recently com- pleted. Another recommendation was to reduce the vent oxygen purity to 45-50 % to reduce operation costs. This recommendation was recently implemented following discussions with BC. 2.4.2 B&V, Nitrification Discussion, March 8, 2017 The driver for this report was also to investigate the effluent limit violations in December 2016 through Feb- ruary 2017. The report discussed the switching from a partially series to a parallel operation, the limiting SRT, and a possible inhibitory compound as the reasons for the ammonia limit exceedances. The data plots in that report clearly show that the ammonia increase in the effluent started in early November 2016 imme- diately after the process configuration was changed. Longer SRTs did not help with nitrification but the SRTs never exceeded 10 days. The report recommended increasing SRTs to 15 days. BC also recommended in- creasing the SRTs to values greater than 10 days. B&V's recommendations also included checking for cya- nide and metals and increasing the bioreactor pH to values above 6.5. 2.4.3 Hazen, RRRWWTP BioWin Model Update, November 9, 2015 The Hazen rerate report and model (original and update) discusses partially series operation with an 85/15 split (always for dry weather) and even a 90/10 split if ammonia and TKN were still an issue. In this mode, Step 1 would receive 85 or 90 percent of the plant influent flow whereas Step 2 would receive the remaining influent portion plus all the effluent from Step 1. To combat the high solids in the secondaries of Step 2, Step 2 needs to run at a lower MLSS of 2,200-2,800 mg/L. Until June 2019, WSACC had never implemented a two -stage process that went beyond a 60/40 influent flow split between the two steps. Brawn -a Catdwett 12 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary Section 3: Recommendations and Steps to Recovery This section outlines the initial recommendations made prior to the process recovering and the steps that were taken to implement these recommendations. 3.1 Plant Re -seeding In an attempt to rapidly recover the treatment process, plant staff purchased Novozymes bioaugmentation products based on the recommendations of Kin Ferrell (Maryland Biochemical Co.) and reseeded the pro- cess. A blend of dry heterotrophic bacteria (BioRemove 5100) and liquid autotropic nitrifiers (BioRemove 5805) were added to Step 1 and 2 on two occasions; once on March 15, 2019 and on April 1 through 3, 2019. Each day nitrifiers were added, the effluent ammonia would improve, but only temporarily suggesting that inhibitory compounds were preventing the process from recovering. 3.2 Supplemental Alkalinity and pH Control Due to the configuration of HPO processes, carbon dioxide becomes elevated in the headspace of the reac- tors and as a result increases the fraction that is dissolved in solution, which depresses the pH. Since low pH (<6.5) can inhibit nitrification, it was recommended to increase supplemental alkalinity addition to ensure excess alkalinity was available for nitrification and the pH was maintained >6.5 in all of the reactor cells at all times. The plant staff followed this recommendation by dosing supplemental alkalinity to obtain 100-200 mg/L of alkalinity as calcium carbonate in the final effluent. 3.3 SRT Control To assist the plant with operating using SRT control instead of MLSS control, BC developed an SRT calcula- tion spreadsheet that could be used by staff to estimate the daily pounds of solids to be wasted from each Step. This SRT calculation spreadsheet was sent to WSACC on April 25, 2019 to be used in implementing the recommendation for a minimum SRT of 15 days in each step when operated in parallel mode. The plant staff implemented this recommendation but struggled to maintain a consistent SRT at first because of highly variable effluent TSS. 3.4 Outside Liquid and Solid Wastes To help narrow down the source of inhibition in the plant, it was recommended to stop receiving all outside liquid and solid wastes where feasible. Prior to this recommendation, the plant had already stopped receiv- ing all septage waste, water treatment plant solids (discharged via collection system), and ERCO sludge slurry (rendering plant). No improvement in plant performance was observed several weeks after stopping all imports of liquid and solid wastes. The imported solids that were not cut off were from the Rock Hill WWTP. Since these solids arrive as de - watered sludge and are fed directly to the incinerator, it was assumed that there would be little to no impact on the liquid treatment processes. The Rock Hill WWTP also did not report any treatment issues. Prior to recovering, water treatment plant solids were allowed to be discharged again. Since these solids contained activated carbon it was assumed that these solids may actually help the plant recover by absorb- ing any potentially toxic organic chemicals. Septic haulers were also allowed to resume discharging at the plant since no improvement to the process was observed. Brown-Ceidweii 13 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary 3.5 Sampling and Testing It was recommended by BC that additional sampling and bench top testing be conducted to try and track the source of inhibition. This included sampling of internal recycle streams (i.e., scrubber blowdown water), SIUs, and different sites within the collection system. 3.5.1 Nitrogen Monitoring It was recommended to continue testing more frequently for TKN in the influent and secondary effluents in order to determine the organic nitrogen contribution. Typical municipal effluent organic nitrogen concentra- tions vary from 1-3 mg-N/L. Reviewing historical organic nitrogen data revealed that plant experiences peaks as high as 5-10 mg-N/L. This was also observed in the additional sampling data. It was suspected that an inhibitory compound that was organic in nature was entering the plant. A few samples were sent off for vola- tile organic compounds (VOCs) and organo-pesticides analysis, but the results did not show influence from those compounds. 3.5.2 Phosphorus Monitoring After reviewing historical data, it was determined that soluble phosphorus was not limiting the process. The average final effluent total phosphorus was almost always >2 mg-P/L. Several secondary effluent grab sam- ples also confirmed that there was sufficient ortho-phosphate present in the secondary effluent. 3.5.3 Metals Additional sampling of plant recycles including scrubber blowdown, thickener overflow, and ash pond water did not contain metals concentrations that would be of concern for inhibition. 3.5.4 Cyanide Additional samples were taken from the CW+IB and LRRPS interceptors and analyzed for cyanide. All the re- sults were below the detection limit (0.005 mg/L total cyanide) for the method. Incinerator scrubber blow - down samples varied between 0.7 to 9.7 mg/L with an average concentration of 3.4 mg/L. Primary effluent concentrations varied between 0.03 to 0.55 mg/L with an average concentration of 0.21 mg/L. While this level of cyanide likely causes chronic reduced nitrification rates, the process should have been able to han- dle these concentrations after the temperature increased from the winter lows. However, this was not the case. BC recommended increasing the incinerator afterburner temperatures to limit the production of cyanide but after reviewing this recommendation with plant staff, it was determined that this what not a viable option because of the condition and reliability of the existing equipment. Operational experience had only shown a modest increase in afterburner temperature while using an excessive amount of supplemental fuel. BC also investigated alternative recycle locations for the scrubber water to dampen the inhibitory effects, for example to the gravity thickeners. However, no alternatives were viable because of the quantity of scrubber blowdown water (1-1.5 MGD) and lack of alternative piping. 3.5.5 Batch Activity Testing To determine the source of nitrification inhibition, batch activity tests were performed for several months us- ing Muddy Creek WWTP mixed liquor and various samples collected from internal plant recycle streams, sites within the collection system, and samples directly from the SIUs. The first activity test was performed on April 10, 2019. A more rigorous activity test program was implemented on April 25, 2019 and lasted until July 10, 2019. The nitrification rates from these tests were compared to control rates measured using Muddy Creek mixed liquor and influent. The observations from these are summarized below: BrownAND( wetE 14 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary Scrubber blowdown water was acutely toxic to the Muddy Creek mixed liquor. Since Muddy Creek does not have incinerators, the activated sludge process has never been exposed to cyanide and therefore was not expected to be acclimated to treat cyanide. These results confirmed that the scrubber blow - down water was inhibitory. Primary influent and effluent samples were also inhibitory to the Muddy Creek mixed liquor although not to the extent of just scrubber blowdown water. These results indicated that cyanide was causing chronic inhibition in both treatment steps. All other internal plant recycles (i.e., ash pond water, dewatering centrate) did not inhibit nitrification in the batch activity tests. The CW+IB interceptor did not appear to be inhibitory but could not be completely ruled out because some samples did appear to cause inhibition. Inhibition was observed on the LRRPS line although not to the extent of the primary influent. High TKN values were also observed in the LRRPS influent that appeared to occur on a weekly basis which sug- gests it is associated with an industry. These observations led to additional activity testing using differ- ent samples collected from the lines that feed into the LRRPS. Of these, the Coddle Creek interceptor was identified as a potential source of inhibition. Additional sampling was conducted on the lines that feed the Coddle Creek interceptor to continue to track the source of inhibition. This included taking samples from the collection system just down stream of the SIUs that discharge to the Coddle Creek interceptor. From this testing, Heritage Crystal Clean (HCC) and S&D Coffee and Tea (not an SIU) were identified as possible inhibition sources. • S&D Coffee and Tea samples were inhibitory, but it was due to the low pH, which was corrected with pH control and dilution of the sample. Heritage Crystal Clean exhibited inhibition that was at times severe. The HCC samples were also prone to foaming suggesting high surfactants and possibly disinfectants or emulsifiers that can cause inhibi- tion. This inhibition was reduced when the HCC samples were blended with Muddy Creek influent to a more realistic dilution based on HCC's flow contribution to the LRRPS interceptor. BFI landfill leachate samples did not appear to have any adverse effects on nitrification. The most recent batch activity tests using mixed liquor from Step 2 after the process recovered indicates that the LRRPS line still contains inhibitory compounds that are likely causing some chronic inhibition. However, since the plant has been reconfigured to a partially series operation and Step 1 is now treating most of the influent flow, any toxic compounds, including cyanide, are getting reduced prior to Step 2. 3.5.6 Whole Effluent Toxicity Testing Additional final effluent samples were submitted to Environmental Testing Solutions for toxicity testing using various treatment methods to reduce the toxic effects of ammonia, metals, oxidizers, and organic com- pounds. These tests indicated that effluent toxicity could be reduced if the sample was treated for metals or oxidizers. A second round of testing found similar results, but the effluent toxicity increased when subjected to filtration for the ammonia and organics removal treatments. It was speculated that filtration released the toxic compounds from the solids or changed the composition of the toxic compound(s) into a more toxic form. 3.5.7 Foaming When the treatment process first started to decline, white foam appeared on the effluent troughs of the sec- ondary clarifier. A defoamer agent had to be added to several manholes where this foam would accumulate. The foam was not biological in nature and was suspected to be a result of surfactants that were not getting removed in the treatment process. Brownmo Caldwett 15 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary As the process began to recover, nuisance foaming became an issue in both treatment steps but more so in Step 1. Foam samples had to be sent off for microscopic inspection and filament identification because the plant lab's microscope does not have the magnification and phase contrast capabilities to visualize fila- ments. The microscopic results found that the foam was caused by Nocardia. To reduce foaming, BC recom- mended lowering the SRT of Step 1 to washout the filaments. 3.6 Polymer Addition Due to high effluent solids, which has been a recent issue, flocculation and settling issues were evaluated to identify the cause. Settling and flocculation tests were conducted that demonstrated the process was floccu- lation limited and the high effluent solids were not the results of poor settling (i.e., high SVI) or secondary clarifier issues. Microscopic observations of the flocs also supported the testing observations. Although the HPO process was operated at high SRTs, the flocs were small and appeared to lack the backbone of fila- ments. However, the lab's microscope was not good enough to clearly identify filaments due to lack of mag- nification and phase contrast. The lack of filaments and higher life forms also suggested the presence of in- hibitory compounds. The high effluent solids also had a significant impact of the plant's ability to maintain a high SRT. At times, wasting was stopped completely to allow solids to build within the process. While it was not confirmed, stop- page of wasting can allow the accumulation of inhibiting compounds if they accumulate in the solids. For ex- ample, heavy metals can accumulate in the solids. To improve solids capture, the plant added polymer to the secondary clarifiers. Jar testing was conducted on June 6 (emulsion polymer) and June 13, 2019 (dry polymer) to identify the optimal dosing rate and polymer make up concentration. To achieve the optimal target dosing rate, the plant had to increase the polymer make up concentration until the limit of the existing equipment was met. This resulted in excessive man hours to make up polymer and keep the equipment running. As a result, the plant has been renting and test- ing skid -mounted dry and emulsion polymer systems since June 11, 2019 to date. The goal is to compare the two types of polymer feed systems and implement the one that meets the plant's need in a permanent installation. These rental polymer feed systems have been used to obtain the polymer doses necessary to meet effluent TSS limits. 3.7 Preliminary Modeling To evaluate whether the process was overloaded from an influent TKN and ammonia load standpoint and that this was causing treatment issues, biological process modeling was performed utilizing an existing BioWin model of the plant. The model was also used to compare series operation to parallel operation since parallel operation had never been simulated before. BC received the BioWin model file from Hazen that was calibrated and validated during their work as reported in TM titled Rocky River Regional WWTP BioWin Model Update (November 9, 2015). Effluent and influent loads used in that effort are summarized in Table 3. Condition Flow (MGD) CBOD5 (mg/0 COD (mg/L) TSS (mg/L) TKN (mg-N/L) ` TAN (mg-N/L) TP (mg-P/L) Min Day 16.4 28,800 93,900 40,000 7,080 3,540 1,100 Average Day 19.7 49,700 157,000 78,500 9,270 4,800 1,610 Max Month 21.1 58,800 - 101,000 - 5,210 - MaxWeek 1 26.6 1 85,700 1 - 138,000 6,370 Max Day 44.9 104,000 292,000 184,000 14,800 9,440 1,900 Brown-oGaldvueil o 16 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary The model Hazen provided was calibrated when the plant was operating in a partial series mode and the ni- trification maximum growth rate of Step 1 was reduced from 0.9 to 0.5 d-1 to account for inhibition caused by the sidestreams and recycles at the plant. Without making significant modifications to the model, parallel operation was simulated using the same reduced nitrifier growth rate in both steps. The results from this model run suggests that the process should be able to fully nitrify at warmer temperatures. At lower temper- atures, ammonia excursions were predicted but the weekly and monthly averages were below the winter per- mit limits. Since higher than expected TKN values have been measured in the influent and the average influent flows have been high for the past year, the influent itinerary was modified to account for these observations. This included increasing the average influent flow from 19 to 25 MGD and decreasing the influent ammonia to TKN fraction from 75% to 50% by keeping the same average influent ammonia and increasing the influent TKN. This run resulted in more effluent ammonia excursions during both warm and cold temperatures and the weekly and monthly average effluent ammonia often exceeded the permit limits. This run indicates that the RRRWWTP, if operated in a parallel mode, cannot treat the influent TKN and ammonia loads with the same level of inhibition determined by Hazen's work. Using the same elevated influent flows and TKN concentrations, partially series operation was simulated at three different influent splits: 1) 60% Step 1 and 40% Step 2; 2) 70% Step 1 and 30% Step 2; and 3) 80% Step 1 and 20% Step 2. The previous modeling by Hazen demonstrated that the RRRWWTP should be able to treat 30 mg/L ammonia and 26.5 MGD at 85:15 and 90:10 splits assuming only a reduced nitrification growth rate in Step 1. To include some conservatism, a slightly reduced growth rate was also used in Step 2 since a larger portion of influent will be sent to Step 2 than what was assumed in the Hazen work. Nitrification reliability increased as the split of influent to Step 1 increased with best performance at 80:20. At the 60:40 split, some nitrification occurred in Step 1 because a longer SRT (5 days) could be obtained. Note Step 2 waste solids were not directed to Step 1 in the model. As the flow to Step 1 increases, the SRT must decrease to maintain a manageable MLSS concentration. Reducing the organic carbon load to Step 2 then allows to operate at a higher SRT which benefits nitrification. Other than for hydraulic purposes, it is beneficial to send some influent to Step 2 to maintain a healthy biomass that settles well. Based on the field observations to date and the preliminary modeling work performed, Brown and Caldwell's recommendation was that the RRRWWTP transition back to operate in a partially series mode (two-step) from parallel mode so that the toxic compounds, both internally generated and those present in the influent, are treated in Step 1. On June 3, 2019, It was recommended that the plant first start with a 60:40 split since operations staff have experience only up to this split with this mode of operation. This was immediately im- plemented. Once the plant staff is comfortable with the 60:40 split, it was recommended to increase the in- fluent split to Step 1 gradually until a split closer to 85:15 is obtained if possible based on known hydraulic bottlenecks. As the plant transitions and adjusts to this partially series mode, it was recommended to continue activity testing and source tracking to identify the source of external inhibition, 3.8 Switching to Partially Series Operation The plant staff implemented all the following recommendations in an attempt to recover full nitrification: m Maintained 100-200 mg/L as calcium carbonate in the final effluent to ensure alkalinity was not lim- iting. Targeted a minimum SRT of 15 days in both steps while in parallel mode by utilizing the SRT calcula- tor spreadsheet provided by BC. 0 Maintained a minimum DO of 10 mg/L in all cells. =rownA.oCa�ldwell 8?L 17 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary ® Reduced vent oxygen purity. ® Maintained consistent and stable incinerator operation. It was apparent after following BC's initial recommendations that the plant was not going to recover. There- fore, it was recommended to convert the plant from a parallel operation back to a partially series operation. The following actions were therefore taken, and the following results were observed: 1. On June 3,2019, the plant implemented an initial split of influent flow between the two steps at a 60/40 ratio as had been done in the past. The plant seemed to stabilize with this modification, but ammonia was stuck at approximately 9 mg-N/L. A target SRT of 5 days for Step 1 and >15 days for Step 2 was recommended. 2. Next, the team agreed to increase contributions to Step 1 by 10 percent increment per week and ob- serve plant performance. As a result, on June 26, 2019, the plant implemented a flow split of 70/30 between the two steps. On the same day, grab samples from secondary effluent indicated nitrite had accumulated in the first step resulting in a condition known as nitrite lock. Under this condition, the pro- cess becomes self -inhibiting. Typically, nitrite lock is identified when a disinfection system becomes taxed because of the additional chlorine demand associated with oxidizing the nitrite to nitrate. In the presence of ammonia, chlorine reacts with ammonia and forms chloramines. These chloramines reduce the impact of nitrite on chlorine demand so the disinfection system at the plant was never fully taxed. Nitrite present in the effluent from Step 1 was also resulting in nitrite lock in Step 2. Once this was iden- tified, WSACC and BC discussed decreasing the SRT of Step 1 to 1.5-2 days to effectively washout the nitrifiers and reduce the concentration of nitrite sent to Step 2. This was implemented on June 27, 2019. As soon as nitrification was lost in Step 1, Step 2 transitioned to full nitrification and ammonia was reduced below the permit limits. Significant foaming that was observed. in the Step 1 RAS piping network was also suppressed to manageable levels once the Step 1 SRT and the RAS flowrate was re- duced. Lime addition for alkalinity control to Step 1 was also reduced significantly in an attempt to dis- rupt nitrification and control foaming in Step 1. The plant has been performing well and meeting all per- mit limits ever since as shown in Figure 10. 3 J0 25 E 0 20 .E 0 E 15 E Q 10 N 5 W 0 u- 1/1/19 e FE TAN 30-day TAN 1/31/19 3/2/19 4/1/19 5/1/19 5/31/19 6/30/19 Figure 10. Historical Final Effluent Total Ammonia Nitrogen Concentrations BrownAND( we[t 18 7/30/19 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery Loss of Nitrification and Recovery Summary Section 4: Final Recommendations Currently, the RRRWWTP is performing well as also aided by the higher summer temperatures that increase biological activity. To prepare the plant for cold weather when nitrification is suppressed and to avoid inhibi- tion or complete loss of nitrification again, it is important that certain measures be considered and possibly undertaken in the short and longterm. In the short-term, the following actions should be evaluated and possibly implemented: 1. Continue to operate a two-step process (partial series mode) and address any possible hydraulic bottle- necks that may prevent an even greater flow split between the two steps in the future. In winter, once temperatures drop and nitrification rates reduce, the plant may have to implement an even greater split, to 80/20 or more, between Step 1 and Step 2. It is therefore important to be able to prepare for this higher split and address any hydraulic limitations (i.e., foaming) that the plant may experience. A de- tailed analysis of the foam in Step 1 may offer insights on ways (i.e., chemicals) that can suppress or eliminate it. 2. If signs of nitrification inhibition continue to persist even after a greater influent flow split between Step 1 and 2 is implemented, consider increasing Step 2 SRT further; specifically targeting biodegradation of cyanide. Relatively simple tests and calculations can be performed to determine the minimum SRT for cyanide removal. 3. Assess secondary clarifier performance and capacity. The secondary clarifiers are peripherally fed and may not be currently optimized. Computational fluid dynamic (CFD) modeling may reveal possible en- hancements in the form of additional baffles that could improve the sedimentation process. 4. Construct a permanent polymer feed system and evaluate the current location and possible need for mixing of the polymer fed to the secondary clarifiers. 5. Correct the WAS metering and control limitations currently experienced at Step 2. 6. Upgrade microscopic inspection capabilities for filament identification and quantification. 7. Evaluate process instrumentation to detect treatment issues. For example, install an ammonia analyzer at the effluent flume to detect process upsets early on. 8. Modify routine sampling plan to include critical parameters at greater frequency and more locations (i.e., TKN). Long-term options that could be considered for implementation alone or under a greater plant expansion project include the following: 1. Add additional venting capabilities in the last zone of the aerated bioreactors to reduce or eliminate the carbon dioxide buildup and improve pH control. 2. Divert scrubber blowdown water or additional recycle flows to Step 1 only. 3. Implement side stream biological treatment to incinerator scrubber, centrate, thickener overflow or all recycle streams combined. 4. Construct permanent foaming control structures like classifying selectors that would allow wasting foam from the activated sludge process directly into the gravity thickeners or centrifuges. 5. Add powdered activated carbon (PAC) to Step 2 bioreactor or elsewhere (i.e., primary clarifiers) to target organics if further testing reveals that such compounds cause nitrification inhibition problems. PAC will be removed with the sludge. Some effects of abrasion to piping and equipment should be expected. 6. Construct offline flow equalization facilities for wet weather control. 7. Construct anoxic tanks upstream of the aerated bioreactors and provide internal mixed liquor recycle pumping to improve sludge settling, recover alkalinity and increase the biomass inventory. 8. Switch to another intensified treatment technology that does not rely on aeration with pure oxygen. 2019-8-20 TM-3 RRRWWTP Loss of Nitrification and Recovery