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NC0004961_Renewal (Application)_20190727
�art i; ), _0,.,..„,N Tkilo ItROY COOPER 24 Gavernor " x� -"y MICHAEL S.REGAN .�,- o..� •• Secretary �`4x"''u LINDA CULPEPPER NORTH CAROLINA Director Environmental Quality August 28, 2019 Tim Hill, Station Manager Duke Energy Carolinas LLC 400 S Tryon St Charlotte, NC 28202 Subject: Permit Renewal Application No. NC0004961 Riverbend Steam Station Gaston County Dear Applicant: The Water Quality Permitting Section acknowledges the August 27, 2019 receipt of your permit renewal application and supporting documentation. Your application will be assigned to a permit writer within the Section's NPDES WW permitting branch. Per G.S. 150E-3 your current permit does not expire until permit decision on the application is made. Continuation of the current permit is contingent on timely and sufficient application for renewal of the current permit. The permit writer will contact you if additional information is required to complete your permit renewal. Please respond in a timely manner to requests for additional information necessary to allow a complete review of the application and renewal of the permit. Information regarding the status of your renewal application can be found online using the Department of Environmental Quality's Environmental Application Tracker at: https://deq.nc.gov/permits-regulations/permit-guidance/environmental-application-tracker If you have any additional questions about the permit, please contact the primary reviewer of the application using the links available within the Application Tracker. Sincerely, i(116 .12v..._4.... "- Wren Thedford Administrative Assistant Water Quality Permitting Section ec: WQPS Laserfiche File w/application Nortl.CaroLrss Department of Environmental Qua1ty I Divs-on of Water Reao rroes . Ene D� F✓'A 1ia�reav3 a Regbona9 Office I CID Eat Center Avanuz,Sute 3Q1 I MooTeav�e,North Caro Fins 23115 +n'v�N N-e A{ a�,,.,.�aZ..,,....ae.;, 7O4$o3-1839 tDUKE ENERGY. CAROLINAS August 23, 2019 Ms. Julie Grzyb State of North Carolina Division of Water Resources NPDES Complex permitting RECEIVED/NODEQ/DWI 1617 Mail Service Center Raleigh, NC 27699-1617 AUG 2 7 2019 Subject: Duke Energy Carolinas, LLC Water Quality Permitting Section NPDES Permit Application Riverbend Steam Station Permit#: NC0004961 Gaston County Dear Ms. Grzyb, Duke Energy Carolinas, LLC (Duke Energy) hereby submits this NPDES permit renewal package for the existing NPDES permit NC0004961. As mandated by North Carolina Administrative Code 15A NCAC 2H.0105(e), this permit application for renewal is being submitted at least 180 days prior to expiration of the current permit. Electric power generation operations ceased on April 1, 2013 at the Riverbend facility. The facility is in the process of completing post-closure activities. Demolition of the steam generation plant is complete. Duke Energy completed excavation efforts of the primary and secondary ash basins, ash stack and cinder pit at site on March 16, 2019. Duke Energy anticipates the potential for future groundwater extraction and/or remediation activities on the site and requests continued coverage under this existing permit for those activities as further described in this submittal. Due to the discontinuing of all steam generation processes at the Riverbend facility, Duke Energy requests the following modifications to the new permit: 1. Condition A. (1), Outfall 001 - Removal of Outfall 001. All plant structures associated with the steam generation plant were decommissioned and demolished. The Riverbend facility no longer operates a plant chiller system. This condition is no longer applicable to the site. 2. Condition A. (2), Outfall 002 - Removal of Outfall 002. The excavation of the ash basin was completed in accordance with the North Carolina Coal Ash Management Act (CAMA) of 2014, HB 630 of 2016 and the Senate Bill 716: Mountain Energy Act of 2015. None of the discharges associated with historic fa cility acility operations will continue due to the decommissioning of the plant, therefore this condition is no longer applicable to the site. The groundwater remediation system discharge (GW Remediation Oil/Water Separator system) was removed in approximately 2001. Duke Energy also requests the Page 2 removal of conditions, A.5 throughA.15, associated with the former plant and ash basin operations. 3. Condition A. (4), Outfall 002A—Discharge from the yard sump overflow will no longer be discharged from Outfall 002A. The yard sump overflow was removed along with the site decommissioning. Duke Energy requests the modification of this outfall to accommodate focused groundwater extraction and discharge determined necessary after the submittal of the Riverbend Groundwater Correction Action Plan (CAP) update. (Additional information about specific characteristics of the potential future discharge detailed in attachment 3). 4. Condition A. (10) - Groundwater Monitoring Well—Duke requests the removal of the groundwater monitoring requirements to make the Riverbend permit consistent with other Duke Site Permits. These compliance wells will continue to be monitored through the CAMA groundwater monitoring program. 5. Condition A. (16)—Removal of Outfalls 101, 103, 104, 105, 106, 109, 110, 111, 112 which corresponds to seeps S-1, S-3, S-4, S-5, S-6, S-9, S-10, S-11, and S-12. This is requested due to these flows having ceased. In accordance with the terms of Consent Order EMC SOC WQ S 16-005, completion of the closure activities referenced in subparagraph 1.f. of the consent order will eliminate the seeps from the ash basins at the Riverbend Steam station. Only outfalls 102,107 and 108 still flow after excavation. These flows meet all water quality standards and requirements in the SOC. Duke Energy is requesting continued coverage for these flows to be assured they are covered, if needed, in the interim however, Duke Energy believes the best way to handle these flows is in accordance with the procedure used for Duke Energy coal fired permits in North Carolina issued subsequent to the Riverbend permit. Duke requests concurrence that these remaining flows, previously identified as wastewater seeps, can be addressed in site Corrective Action Plans, as needed, and continuing NPDES permit coverage is not needed. Attachment 5, is analytical data from seep sampling from 2017 —2019. Upon receiving concurrence that these flows can be addressed in the CAP for the site, Duke Energy would withdraw request for continuing coverage of outfall 102, 107 and 108. 6. Duke Energy requests removal of Appendix A, "Plan for identification of new discharges" to make the Riverbend permit consistent with other Duke Energy permits. 7. Duke Energy requests inclusion of a groundwater compliance boundary map in the reissued permit. Please find enclosed in triplicate, the renewal application, which includes the following items: • EPA Form 1 • EPA Form 2C • Attachment 1 —NPDES Outfalls Map • Attachment 2—Form 2C Item IIA Flow Diagram Page 3 • Attachment 3 —Form 2C Item IIB Descriptions of Flows • Attachment 4—Outfall Analytical Data • Attachment 5 —Fish tissue monitoring results • Attachment 6—Compliance Boundary map If you have any questions or need additional information or clarification, please contact Brad Loveland at (980) 373-2820. "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Sincerely, Tim Hill, General Manager CCP Regional Operations and Maintenance Enclosure CC: Please print or type in the unshaded areas only. Form Approved.OMB No.2040-0086. FORM U.S.ENVIRONMENTAL PROTECTION AGENCY I.EPA I.D.NUMBER 1 4-/EPA GENERAL INFORMATION Consolidated Permits Program s F NC0004961 • GENERAL (Read the"General Instructions"before starting.) INSTRUCTIONSGENERAL LABEL ITEMS prepnneenprovthssignated space.Review the information carefully,if any of it I. EPA I.D.NUMBER is incorrect.cross through it and enter the corred data in the appropriate fill-in area below.Also,ir any of the preprinted data is absent (the area to the lett of the label space lists the III. FACILITY NAME PLEASE PLACE LABEL IN THIS SPACE information that should appear).please provide it in the proper fill-in area(s)below. If the label is complete and awed, you V. FACILITY MAILING need not complete Items I, III. V, and VI(except VI-B which ADDRESS must be completed regardless).Complete all items if no label has been provided.Refer to the instructions for detailed item descriptions and for the legal authorizations under which this VI. FACIUTY LOCATION data is collected. II.POLLUTANT CHARACTERISTICS submit this forrn and the supplemental form listed in the parenthesis following the question.Mark"X"in the box in the third column if the supplemental form is attached.If you answer"no"to eadi question,you need not submit any INSTRUCTIONS:Complete A through J to deterrnine whether you need to submit any perrnit application forms to the EPA.If you answer'yes"to any questions,you must instructions.See also.Section • . definitions QUESTIONS NO FORM YES NO FORM SPECIFIC QUESTIONS ATTACHED ATTACHED A.Is this facility a publicly owned treatment works which B. Does or will this facihty (either existing or proposed) results in a discharge to waters of the U.S.?(FORM 2A) X include a concentrated animal feeding operation or aquatic animal production facility which results in a 16 17 16 discharge to waters of the U.S.?(FORM 2B) 19 20 21 C.Is this a facility which currently results in discharges to ‘, D.Is this a proposed facility(other than those descnbed in A waters of the U.S.other than those described in A or B 7\ X or B above)which will result in a discharge to waters of X above?(FORM 2C) the U.S.?(FORM 2D) E. Does or will this fadlity treat, store, or dispose of F. Do you or will you inject at this facility industrial or hazardous wastes?(FORM 3) X municipal effluent below the lowermost stratum containing, within one quarter mae of the well bore, 28 29 30 underground sources of drinking water?(FORM 4) 31 32 n G.Do you or will you inject at this facility any produced water H.Do you or will you inject at this facility fluids for special or other fluids which are brought to the surface in ‘, processes such as mining of sulfur by the Frasch process, connection vAth conventional oil or natural gas production, A solution mining of minerals. in situ combustion of fossil inject fluids used for enhanced recovery of oil or natural fuel,or recovery of geothermal energy?(FORM 4) gas, or inject fluids for storage of liquid hydrocarbons? l. Is this facility a proposed stationary source which is one J. Is this facility a proposed stationary source which is of the 28 industrial categories listed in the instructions and X NOT one of the 28 industrial categories listed in the which will potentially emit 100 tons per year of any air instructions and which will potentially emit 250 tons per X pollutant regulated under the Clean Air Act and may affect year of any air pollutant regulated under the Clean Air Act or be located in an attainment area?(FORM 5) ,, ", ,, and may affect or be located in an attainment area? 4, " 45 III. NAME OF FACILITY ® SKIP Riverben. Steam Station 15 16 -25 30 5 IV. FACILITY CONTACT A.NAME&TITLE(last,first,&tale) B.PHONE(area code&no.) I III I III 1 7516 45 u; .t5 51 52- 55 V.FACILTY MAILING ADDRESS A.STREET OR P.O.BOX c 1 I 1 1 1 1 1 I I I I I I I I I I I I I I I I I 1 I I I 1 3 P.O. Box 1006 1 15 16 45 B.CITY OR TOWN C.STATE D.ZIP CODE 4 Charlotte I I I I I I I I I l l l l l l l l l i l NC 242d1 11 75 16 b 41 42 47 St VI. FACILITY LOCATION A.STREET,ROUTE NO.OR OTHER SPECIFIC IDENTIFIER I I I I I I I 1 I I l 1 1 1 1 1 I I 1 1 I 1 I I I I 1 5 175 Steam Pi ant Road ^15 16 45 _ B.COUNTY NAME Gaston I I I I I I I I I 1 I 1 I I 1 I I 1 I I I I u6 70 C.CITY OR TOWN D.STATE E.ZIP CODE F.COUNTY CODE Of-known) s Mobur]t IH�liy 1 1 1 I I I I I I I l l 1 1 1 1 1 1 1 ziC 2>31J0 I I I I 15 16 40 41 62 .; 51 52 hi EPA Form 3510-1(8-90) CONTINUE ON REVERSE CONTINUED FROM THE FRONT VII.SIC CODES 4-di.it,in order of.riorit A.FIRST B.SECOND c I I I (iprcif) - I II (spec1 fy') 7 4911 Electric Power Services 7 15 16 - 19 15 06 - +9 C.THIRD D.FOURTH I I I (spec't/i) ? I I I (specify) 15 16 19 15 16 • 19 VMATION A.NAME B.Is the name listed in Item c I I I I I I I I I I I I I I I I I I I I I i I I I I I 1 I 1 I I I I I 1 I I VIII-A also the owner? 8 Duke Energy Carolinas, LLC ©YES ❑NO 15 16 55 86 C.STATUS OF OPERATOR(Enter the appropriate letter into the answer box:if"Other,"specth-.) D.PHONE(area code cC no.) F=FEDERAL (sp f?) I I I I i I I I I M=PUBLIC(other than federal or stair) vc? S=STATE O=OTHER(spedfi) P A (704) 382-4309 P=PRIVATE 56 15 6 - 18 j 19 - 2,1 2? 26 E.STREET OR P.O.BOX LILT IIIIIIIIIItIIILIIIIIIIII P.O. BOX 100 26 55 F.CITY OR TOWN G.STATE H.ZIP CODE IX.INDIAN LAND I I I I I I I I I I 1 I I 1 1 I I I I I 1 I I I I i I I I Is the facility located on Indian lands? B Charlotte NC 28201 OYES ONO 52 15 16 .p 41 42 47 - 51 X.EXISTING ENVIRONMENTAL PERMITS A.NPDES(Discharges to Surf ice Ifater) D.PSD(Air Emissions from Proposed Sources) c r l I I i I I 1 i I 11 I I c r 1 I 1 I I I i I I I I i 1 9 N NC0004961 9 P 15 16 117 18 .30 15 16 17 18 30 B.UIC((I'ndertround In/ecuon o/7'luids)) E.OTHER(specif) c 7 I I ( i I I I I I I 1 l I C T 1 Wd0000452 I i I I i I I I (,pertt.1) 9 U 9 Distribution of Residual Solids 15 16 17 18 30 15 16 17 18 30 C.RCRA(Hazardous Wastes) E.OTHER(srectri) c i l l I 1 ( I I I I 1 1 I I c * I 1 I I I 1 I I I I i I l (specif;.) 9 R NCD024717423 9 15 16 17 18 310 15 16 17 18 30 XI.MAP Attach to this application a topographic map of the area extending to at least one mile beyond property boundaries. The map must show the outline of the facility. the location of each of its existing and proposed intake and discharge structures,each of its hazardous waste treatment,storage,or disposal facilities,and each well where it injects fluids underground.Include all springs,rivers,and other surface water bodies in the map area.See instructions for precise requirements. XII.NATURE OF BUSINESS .rovide a brief descn.tion Coal fired steam electric generation (generation operations ceased and been demolished 4/1/2013) , continuing post closure activities. XIII.CERTIFICATION(see instructions) I certify under penalty of law that I have personally examined and am familiar with the information submitted in this application and all attachments and that, based on my inquiry of those persons immediately responsible for obtaining the information contained in the application. I believe that the information is true, accurate, and complete. I am aware that there are significant penalties for submitting false information,including the possibility of fine and imprisonment A.NAME&OFFICIAL TITLE(type or print) B.SIGNATURE C.DATE SIGNED /0-4 /44h4k 67AA 1-D3-j, COMMENTS FOR OFFICIAL USE ONLY I C 15 16 55 EPA Form 3510-1 (8-90) 1 EPA I.D.NUMBER(convfrom Item l of Form l) Form Approved. NC0004961 OMB No.2040-0086. Please print or type in the unshaded areas only. Approval expires 3-31-98. FORM U.S.ENVIRONMENTAL PROTECTION AGENCY APPLICATIO FOR PERMIT TO DISCHARGE WASTEWATER 2C �"iEPA EXISTING MANUFACTURING,vCOMMERCIAL,MINING AND SILVICULTURE OPERATIONS NPDES Consolidated Permits Program I.C,1.11111.11.1..111111 LOCATION For each outfall,list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A.OUTFALL NUMBER B.LATITUDE C.LONGITUDE (l"it) 1.DEG. 2.MIN. 3.SEC. 1.DEG. 2.MIN. 3.SEC. D.RECEIVING WATER(name) 002A 35 21 55.44 -80 58 10.92 Catawba River 102 35 21 54 -80 57 57.6 Catawba River 107 35 22 1.2 -80 57 25.2 Catawba River 108 35 21 55.6 -80 57 21.2 Catawba River II.FLOWS,SOURCES OF POLLUTION,AND TREATMENT TECHNOLOGIES A. Attach a line drawing showing the water flow through the facility.Indicate sources of intake water,operations contributing wastewater to the effluent,and treatment units labeled to correspond to the more detailed descriptions in Item B.Construct a water balance on the line drawing by showing average flows between intakes,operations, treatment units,and outfalls.If a water balance cannot be determined(e.g.,for certain mining activities),provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures. B. For each outfall, provide a description of:(1)All operations contributing wastewater to the effluent,including process wastewater,sanitary wastewater,cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3)The treatment received by the wastewater. Continue on additional sheets if necessary. 1.OUT- 2.OPERATION(S)CONTRIBUTING FLOW 3.TREATMENT FALL b.AVERAGE FLOW b.LIST CODES FROM NO.(list) a.OPERATION(list) (include units) a.DESCRIPTION TABLE 2C-1 Groundwater Remediation Discharge NA 002A 0.04 MGD (estimated) NA NA (Future) Non-Engineered Seeps NA 102 0.001 MGD NA NA Non-Engineered Seeps 0.89 MGD NA 107 NA NA Non-Engineered Seeps NA 108 0.008 MGD NA NA OFFICIAL USE ONLY(e(fluentguidelines sub-categories) EPA Form 3510-2C(8-90) PAGE 1 of 4 CONTINUE ON REVERSE r CONTINUED FROM THE FRONT C.Except for storm runoff,leaks,or spills,are any of the discharges described in Items II-A or B intermittent or seasonal? ❑YES(complete the following table) IZI NO(go to Section 111) 3.FREQUENCY 4.FLOW a.DAYS PER B.TOTAL VOLUME 2.OPERATION(s) WEEK b.MONTHS a.FLOW RATE(in mgd) (specify with units) 1.OUTFALL CONTRIBUTING FLOW (specify PER YEAR 1.LONG TERM 2.MAXIMUM 1.LONG TERM 2.MAXIMUM C.DURATION NUMBER(list) (list) average) (specify average) AVERAGE DAILY AVERAGE DAILY (in days) III.PRODUCTION A.Does an effluent guideline limitation promulgated by EPA under Section 304 of the Clean Water Act apply to your facility? YES(complete Item 111-B) ❑NO(go to Section IV) B.Are the limitations in the applicable effluent guideline expressed in terms of production(or other measure of operation)? ❑YES(complete Item IZI NO(go to Section IV) C.If you answered"yes"to Item III-B,list the quantity which represents an actual measurement of your level of production,expressed in the terms and units used in the applicable effluent guideline,and indicate the affected outfalls. 1.AVERAGE DAILY PRODUCTION 2.AFFECTED OUTFALLS a.QUANTITY PER DAY b.UNITS OF MEASURE c.OPERATION,PRODUCT,MATERIAL,ETC. (list outfall numbers) (specify) NA IV.IMPROVEMENTS A. Are you now required by any Federal, State or local authority to meet any implementation schedule for the construction, upgrading or operations of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application?This includes,but is not limited to, permit conditions,administrative or enforcement orders,enforcement compliance schedule letters,stipulations,court orders,and grant or loan conditions. ®YES(complete the following table) ❑NO(go to Item IV-B) 1 IDENTIFICATION OF CONDITION, 2.AFFECTED OUTFALLS 3.BRIEF DESCRIPTION OF PROJECT 4.FINAL COMPLIANCE DATE AGREEMENT,ETC. a.NO. b.SOURCE OF DISCHARGE a.REQUIRED b.PROJECTED SOC No. S16-005 101-112 Seeps B. OPTIONAL: You may attach additional sheets describing any additional water pollution control programs (or other environmental projects which may affect your discharges)you now have underway or which you plan.Indicate whether each program is now underway or planned,and indicate your actual or planned schedules for construction. ❑MARK"X"IF DESCRIPTION OF ADDITIONAL CONTROL PROGRAMS IS ATTACHED EPA Form 3510-2C(8-90) PAGE 2 of 4 CONTINUE ON PAGE 3 1 EPA I.D.NUMBER(copy from Item I of Form I) CONTINUED FROM PAGE 2 NC0004961 V.INTAKE AND EFFLUENT CHARACTERISTICS A,B,&C: See instructions before proceeding—Complete one set of tables for each outfall—Annotate the outfall number in the space provided. NOTE:Tables V-A,V-B,and V-C are included on separate sheets numbered V-1 through V-9. D. Use the space below to list any of the pollutants listed in Table 2c-3 of the instructions,which you know or have reason to believe is discharged or may be discharged from any outfall.For every pollutant you list,briefly describe the reasons you believe it to be present and report any analytical data in your possession. 1.POLLUTANT 2.SOURCE 1.POLLUTANT 2.SOURCE Coal fired steam electric generation (operations ceased) VI.POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS Is any pollutant listed in Item V-C a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? ❑YES(list all such pollutants below) NO(go to Item VI-B) NA EPA Form 3510-2C(8-90) PAGE 3 of 4 CONTINUE ON REVERSE CONTINUED FROM THE FRONT VII.BIOLOGICAL TOXICITY TESTING DATA Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? ©YES(identify the test(s)and describe their purposes below) ❑NO(go to Section VIII) chronic toxicity tests were conducted quarterly per calendar year on NPDES outfall 002 (dewatering phase) . These test used Ceriodaphnia as the test organism. Test results indicated that the discharge of outfall 002 is non-toxic. The chronic toxicity test were ended after March 22, 2019. VIII.CONTRACT ANALYSIS INFORMATION Were any of the analyses reported in Item V performed by a contract laboratory or consulting firm? ®YES(list the name,address,and telephone number of,and pollutants analyzed by, ❑NO(go to Section IX) each such laboratory or firm below) A.NAME B.ADDRESS C.TELEPHONE D.POLLUTANTS ANALYZED (area code&no.) (list) Shealy Environmental Services, 106 Vantage Point Drive, West Columbia, 803-791-9700 Ammonia - N Inc SC 29172 BOD COD TOC Oil and Grease Mercury TDS TSS Chloride Fluoride Nitrate Sulfate Barium Calcium Iron Magnesium Manganese Total Harness Zinc Arsenic Cadmium Chromium Copper Lead Nickel Selenium IX.CERTIFICATION I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief true,accurate,and complete.I am aware that there are significant penalties for submitting false information,including the possibility of fine and imprisonment for knowing violations. A.NAME&OFFICIAL TITLE(type or print) B.PHONE NO.(area code&no.) / �' enri,.l MAr,.GaL� CCP Q fCm7rotiS go- 373 ' C( ,C C.SIGNATURE D.DATE SIGNED EPA Form 3510-2C(8-90) PAGE 4 of 4 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY.You may report some or all of this information EPA I.D.NUMBER(copy,/rum lien,I of lormn I) on separate sheets(use the same format)instead of completing these pages. NC0004961 SEE INSTRUCTIONS. OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 002A (Future/estimated) PART A—You must provide the results of at least one analysis for every pollutant in this table.Complete one table for each outfall.See instructions for additional details. 3.UNITS 4.INTAKE 2.EFFLUENT (.+pecijylfhlank) (optional) b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.VALUE a.LONG TERM a.MAXIMUM DAILY VALUE (if available) (if available) AVERAGE VALUE (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF 1.POLLUTANT CONCENTRATION (2)MASS CONCENTRATION (2)MASS (1)CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES a.Biochemical Oxygen Demand(BOD) b.Chemical Oxygen Demand(COD) c.Total Organic Carbon (ion 1.00 77 mg/L d.Total Suspended Solids(1SR) 5.01 75 mg/L e.Ammonia(as Al) VALUE VALUE VALUE VALUE f.Flow g.Temperature VALUE VALUE VALUE VALUE (winter) 17 2 0 °C h.Temperature VALUE VALUE VALUE VALUE (.runner) 2 7 3 °C MINIMUM MAXIMUM MINIMUM MAXIMUM i.pH 3.2 8.3 STANDARD UNITS PART B— Mark"X"in column 2-a for each pollutant you know or have reason to believe is present.Mark"X"in column 2-b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.VALUE a.LONG TERM AVERAGE AND a. b a.MAXIMUM DAILY VALUE (if available) (if available) VALUE CAS NO. BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF Of available) PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION _ (2)MASS ANALYSES a.Bromide (24959-67-9) b.Chlorine,Total Residual c.Color d.Fecal Coliform e.Fluoride (16984-48-8) f.Nitrate-Nitrite (as M EPA Form 3510-2C(8-90) PAGE V-1 CONTINUE ON REVERSE ITEM V-B CONTINUED FROM FRONT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.VALUE a.LONG TERM AND a b. a.MAXIMUM DAILY VALUE ((Jurm/oh/e) (i/aradahle) AVERAGE VALUE CAS NO. BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (i/aradahle) PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES g.Nitrogen, Total Organic(us M h.Oil and Grease i.Phosphorus (as P),Total (7723-14-0) j.Radioactivity (1)Alpha,Total (2)Beta,Total (3)Radium, Total (4)Radium 226, Total k.Sulfate (u.+SO,) (14808-79-8) 1400 79 mg/L I.Sulfide (us S) m.Sulfite (as SO,) (14265-45-3) n.Surfactants o.Aluminum, Total (7429-90-5) 5480 81 ug/L p.Barium,Total (7440-39-3) X 42.8 76 ug/L q.Boron,Total (7440-42-8) X 82.7 83 ug/L r.Cobalt,Total 209 79 ug/L (7440-48-4) s.Iron,Total (7439-89-6) 44900 82 ug/L t.Magnesium, Total (7439-95-4) 86.6 77 mg/L u.Molybdenum, Total (7439-98-7) 1.18 84 ug/L v.Manganese, Total u 14200 83 ug/L (7439-96-5) w.Tin,Total (7440-31-5) x.Titanium, Total (7440-32-6) EPA Form 3510-2C(8-90) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(co'v/rmu hem/of Form I) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004961 002A PART C- If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides,and total phenols. If you are not required to mark column 2-a(secondary industries, nonprocess wastewater ouffalls, and nonrequired GC/MS fractions), mark"X"in column 2-b for each pollutant you know or have reason to believe is present. Mark"X"in column 2-c for each pollutant you believe is absent. If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c. a.MAXIMUM DAILY VALUE (ifarailable) VALUE(if available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) - (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (i/arailable) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES METALS,CYANIDE,AND TOTAL PHENOLS 1M.Antimony,Total (7440-36-0) X 1.34 84 ug/L 2M.Arsenic,Total (7440-38-2) X 1.47 82 ug/L 3M.Beryllium,Total (7440-41-7) X 7.63 84 ug/L 4M.Cadmium,Total (7440-43-9) X 1.83 75 ug/L 5M.Chromium, Total(7440-47-3) X 4.74 83 ug/L 6M.Copper,Total (7440-50-8) X 33.6 71 ug/L 7M.Lead,Total X(7439-92-1) 0.965 73 ug/L 8M.Mercury,Total X (7439-97-6) 9M.Nickel,Total X 158 81 ug/L (7440-02-0) Total Selenium, Total(7782-49-2) X 2.84 75 ug/L 11 M.Silver,Total (7440-22-4) 12M.Thallium, X 0.262 82 ug/L Total(7440-28-0) 13M.Zinc,Total (7440-66-6) X 275 73 ug/L 14M.Cyanide, Total(57-12-5) 15M.Phenols, Total DIOXIN 2,3,7,8-Tetra- X DESCRIBE RESULTS chlorodibenzo-P- Dioxin(1764-01-6) EPA Form 3510-2C(8-90) PAGE V-3 CONTINUE ON REVERSE ) CONTINUED FROM THE FRONT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c. a.MAXIMUM DAILY VALUE (4/available) VALUE(if available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF ((/aratlahle) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—VOLATILE COMPOUNDS 1V.Accrolein \/ (107-02-8) �\ 2V.Acrylonitrile (107-13-1) 3V.Benzene (71-43-2) n,et/typ Ether (542-88-1) 5V.Bromoform (75-25-2) 6V.Carbon Tetrachloride X (56-23-5) 7V.Chlorobenzene (108-90-7) 8V.Chlorodi- bromomethane /X\ (124-48-1) 9V.Chloroethane (75-00-3) 10V.2-Chloro- ethylvinyl Ether X (110-75-8) 11V.Chloroform (67-66-3) 12V.Dichloro- bromomethane (75-27-4) 13V.Dichloro- difluoromethane X (75-71-8) 14V.1,1-Dichloro- ethane \/ ethane(75-34-3) X\ 15V.1,2-Dichloro- ethane(107-06-2) 16V.1,1-Dichloro- ethylene(75-35-4) 17V.1,2-Dichloro- propane(78-87-5) l,3-Dichloro- prop propylene (542-75-6) 19V.Ethylbenzene (100-41-4) 20V.Methyl X Bromide(74-83-9) 21V.Methyl Chloride(74-87-3) EPA Form 3510-2C(8-90) PAGE V-4 CONTINUE ON PAGE V-5 CONTINUED FROM PAGE V-4 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(apnanal) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c. a.MAXIMUM DAILY VALUE ({/available) VALUE(if available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (if available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES( TRATION b.MASS CONCENTRATION (2)MASS (ANALYSES GC/MS FRACTION—VOLATILE COMPOUNDS(can!uwed) 22V.Methylene Chloride(75-09-2) 23V.1,1,2,2- Telrachloroethane X (79-34-5) 24V.Tetrachloro- ethylene(127-18-4) 25V.Toluene (108-88-3) 26V.1,2-Trans- ` , Dichloroethylene X (156-60-5) 27V.1,1,1-Trichloro- Xethane(71-55-6) 28V.1,1,2-Trichloro- X ethane(79-00-5) 29V Trichloro- ethylene(79-01-6) 30V. h fluoromemelhaneane X (75-69-4) 31V.Vinyl Chloride X (75-01-4) GC/MS FRACTION—ACID COMPOUNDS 1 A.2-Chlorophenol (95-57-8) 2A.2,4-Dichloro- Xphenol(120-83-2) 3A.2,4-Dimethyl- phenol(105-67-9) 4A.4,6-Dinitro-O- Cresol(534-52-1) 5A.2,4-Dinitro- Xphenol(51-28-5) 6A.2-Nitrophenol (88-75-5) 7A.4-Nitrophenol X(100-02-7) 8A.P-Chloro-M- Cresol(59-50-7) 9A.Pentachloro- phenol(87-86-5) 10A.Phenol (108-95-2) 11 A.2,4,6-Trichloro- phenol(88-05-2) EPA Form 3510-2C(8-90) PAGE V-5 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(apawurl) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a b c. a.MAXIMUM DAILY VALUE (i/available) VALUE((1 available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (it available) REQUIRED PRESENT ABSENT (1) (1) (1) d.NO.OF a.CONCEN- 111 b.NO.OF CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—BASE/NEUTRAL COMPOUNDS 1B.Acenaphthene X(83-32-9) 2B.Acenaphtylene (208-96-8) 3B.Anthracene (120-12-7) 4B.Benzidine (92-87-5) 5B.Benzo(a) Anthracene �/ (56-55-3) /� 6B.Benzo(u) Pyrene(50-32-8) 7B.3,4-Benzo- fluoranthene �/ (205-99-2) /� 8B.Benzo(gin) Perylene(191-24-2) 9B.Benzo(k) Fluoranthene X (207-08-9) 10B.Bis(2-('hluro- edw.n')Methane X (111-91-1) 11 B.Bis(2-('hlura- eNvi)Ether (111-44-4) 12B.Bis 12- ('hlaratraprup l) Ether(102-80-1) 13B.Bis(2-Ednl- hexe0 Phthalate (117-81-7) 14B.4-Bromophenyl Phenyl Ether �/ (101-55-3) /� 15B.Butyl Benzyl �/ Phthalate(85-68-7) /� 16B.2-Chloro- naphthalene �/ (91-58-7) /� 17B.4-Chloro- phenyl Phenyl Ether >/ (7005-72-3) /� 18B.Chrysene X (218-01-9) 19B.Dibenzo(uh) Anthracene >/ (53-70-3) /� 20B.1,2-Dichloro- �/ benzene(95-50-1) /< 21 B.1,3-Di-chloro- benzene(541-73-1) EPA Form 3510-2C(8-90) PAGE V-6 CONTINUE ON PAGE V-7 CONTINUED FROM PAGE V-6 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c. a.MAXIMUM DAILY VALUE (if available) VALUE(if available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) ' d.NO.OF a.CONCEN- (1) b.NO.OF (ifararlable) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—BASE/NEUTRAL COMPOUNDS(continued) 22B.1,4-Dichloro- benzene(106-46-7) 23B.3,3-Dichloro- benzidine(91-94-1) 24B.Diethyl Phthalate(84-66-2) 25B.Dimethyl Phthalate X (131-11-3) 26B.Di-N-Butyl X Phthalate(84-74-2) 27B.2,4-Dinitro- toluene(121-14-2) 28B.2,6-Dinitro- toluene(606-20-2) 29B.Di-N-Octyl Phthalate(117-84-0) 30B.1,2-Diphenyl- hydrazine(as Azo- benzene)(122-66-7) 31B.Fluoranthene (206-44-0) 32B.Fluorene (86-73-7) 33B.Hexachloro- benzene(118-74-1) • 34B.Hexachloro- butadiene(87-68-3) • 35B.Hexachloro- cyclopentadiene X (77-47-4) 36B Hexachloro- ethane(67-72-1) 37B.Indeno (1,2,3-cd)Pyrene (193-39-5) 386.Isophorone (78-59-1) 39B.Naphthalene (91-20-3) 408.Nitrobenzene (98-95-3) 418.N-Nitro- sodimethylamine (62-75-9) 42B.N-Nitrosodi- N-Propylamine (621-64-7) EPA Form 3510-2C(8-90) PAGE V-7 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(apnanal) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b c. a.MAXIMUM DAILY VALUE (it available) VALUE(i/available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF Of available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—BASE/NEUTRAL COMPOUNDS(coniinuen/) 43B.N-Nitro- sodiphenylamine X (86-30-6) 448.Phenanthrene (85-01-8) 45B.Pyrene \ (129-00-0) n 468.1,2,4-Tri- chlorobenzene (120-82-1) GC/MS FRACTION—PESTICIDES ( (309-00-2) X 2P.a-BHC (319-84-6) 3P -BHC (31 (- (319-85-7)-7) 4P.y-BHC (58-89-9) 5P.S-BHC (319-86-8) 6P.Chlordane X(57-74-9) 7P.4,4'-DDT (50-29-3) 8P.4,4'-DDE (72-55-9) 9P.4,4'-DDD (72-54-8) 10P.Dieldrin (60-57-1) 11P.a-Enosulfan (115-29-7) 12P.13-Endosulfan (115-29-7) 13P.Endosulfan Sulfate X (1031-07-8) 14P.Endrin (72-20-8) 15P.Endrin Aldehyde X (7421-93-4) 16P.Heptachlor X (76-44-8) EPA Form 3510-2C(8-90) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item I of Form I) OUTFALL NUMBER NC0004961 002A CONTINUED FROM PAGE V-8 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c. a.MAXIMUM DAILY VALUE (if available) VALUE(rfavailable) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (if available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—PESTICIDES(coniinuecl) 17P.Heptachlor ` , Epoxide X (1024-57-3) 18P.PCB-1242 (53469-21-9) 19P.PCB-1254 (11097-69-1) 20P.PCB-1221 (11104-28-2) 21P.PCB-1232 (11141-16-5) 22P.PCB-1248 (12672-29-6) 23P.PCB-1260 \ (11096-82-5) n 24P.PCB-1016 ` (12674-11-2) /X\ 25P.Toxaphene \ (8001-35-2) n EPA Form 3510-2C(8-90) PAGE V-9 1 ll PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY.You may report some or all of this information EPA I.D.NUMBER(copy from Item/ofForn,1) on separate sheets(use the same format)instead of completing these pages. NCO 0 04 961 SEE INSTRUCTIONS. OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 102 PART A—You must provide the results of at least one analysis for every pollutant in this table.Complete one table for each outfall.See instructions for additional details. 3.UNITS 4.INTAKE 2.EFFLUENT (specify if-blank) (optional) b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.VALUE a.LONG TERM a.MAXIMUM DAILY VALUE (i/available) (if available) AVERAGE VALUE d.NO.OF 1.POLLUTANT F (1) 111 ANALYSES aTRATION b.MASS 11) ANALYSES.CONCEN- b. a. CONCENTRATION (2)MASS CONCENTRATION (2)MASS (1)CONCENTRATION (2)MASS CONCENTRATION (2)MASS a.Biochemical Oxygen < 2.0 mg/L Demand(HOD) b.Chemical Oxygen < 20 mg/L Demand(COD) c.Total Organic Carbon < 1.0 mg/L ('rot') d.Total Suspended Solids(1SS) 5.22 18 mg/L e.Ammonia(as N) <0.10 mg/L I VALUE VALUE VALUE VALUE f.Flow 0.001 18 cfs g.Temperature VALUE VALUE VALUE VALUE (Hinter) 11.8 5 °C h.Temperature VALUE VALUE VALUE VALUE (summer) 24.9 3 °C MINIMUM MAXIMUM MINIMUM MAXIMUM i.pH 6.3 7.5 18 STANDARD UNITS PART B— Mark"X"in column 2-a for each pollutant you know or have reason to believe is present.Mark"X"in column 2-b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.VALUE a.LONG TERM AVERAGE AND a b. a.MAXIMUM DAILY VALUE (if available) (damnable) VALUE CAS NO. BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (if available) PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION_ (2)MASS ANALYSES TRATION b.MASS_CONCENTRATION (2)MASS ANALYSES a.Bromide (24959-67-9) b.Chlorine,Total Residual c.Color d.Fecal Coliform e.Fluoride (16984-48-8) X 0.10 18 mg/L f.Nitrate-Nitrite(asN) X\/ 3.13 18 mg/L EPA Form 3510-2C(8-90) PAGE V-1 CONTINUE ON REVERSE ITEM V-B CONTINUED FROM FRONT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.VALUE a.LONG TERM AND a. b. a.MAXIMUM DAILY VALUE (if available) (if available) AVERAGE VALUE CAS NO. BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (if available) PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES g.Nitrogen, Total Organic(as M h.Oil and Grease < 5 18 mg/L i.Phosphorus (as P),Total (7723-14-0) j.Radioactivity (1)Alpha,Total (2)Beta,Total (3)Radium, Total (4)Radium 226, Total k.Sulfate (as O) X 5.39 18 mg/L (14808-79-8) I.Sulfide (as S) m.Sulfite (as SO,) (14265-45-3) n.Surfactants o.Aluminum, Total (7429-90-5) p. 3 Total (7440-39-3) X 0.02 18 mg/L q.Boron,Total X (7440-42-8) 0.05 1 mg/L r.Cobalt,Total (7440-48-4) s.Iron,Total (7439-89-6) X 0.12 18 mg/L t.Magnesium, Total X 5.79 18 mg/L (7439-95-4) u.Molybdenum, Total (7439-98-7) v.Manganese, Total X 0.44 18 mg/L (7439-96-5) w.Tin,Total (7440-31-5) x.Titanium, Total (7440-32-6) EPA Form 3510-2C(8-90) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(copy from lien I a/Form 1) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004961 102 PART C- If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides,and total phenols. If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls, and nonrequired GC/MS fractions), mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c a.MAXIMUM DAILY VALUE (i)available) VALUE(ijavailable) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED d.NO.OF a.CONCEN- ' b.NO.OF (ilavailable) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES METALS,CYANIDE,AND TOTAL PHENOLS 1M.Antimony,Total (7440-36-0) 2M.Arsenic,Total(7440-38-2) �\�/ < 1 19 ug/L 3M.Beryllium,Total (7440-41-7) 4M.Cadmium,Total (7440-43-9) X < 1 18 ug/L 5M.Chromium, �/ Total(7440-47-3) X < 1 18 ug/L 6M.Copper,Total \/ (7440-50-8) �\ 1.02 18 ug/L 7M Lead,Total X < 1 18 ug/L (7439-92-1) �\ 8M.Mercury,Total \/ (7439-97-6) �\ 0.83 18 ng/L 9M.Nickel,Total(7440-02-0) u 1.10 18 ug/L 10M.Selenium, �/ Total(7782-49-2) X < 1 18 ug/L 11 M.Silver,Total (7440-22-4) 12M.Thallium, Total(7440-28-0) 13M.Zinc,Total (7440-66-6) X 0.006 18 mg/L 14M.Cyanide, Total(57-12-5) 15M.Phenols, Total DIOXIN 2,3,7,8-Tetra- X DESCRIBE RESULTS chlorodibenzo-P- Dioxin(1764-01-6) EPA Form 3510-2C(8-90) PAGE V-3 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c. a.MAXIMUM DAILY VALUE (if available) VALUE(el available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (01 available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—VOLATILE COMPOUNDS 1V.Accrolein (107-02-8) 2V.Acrylonitrile (107-13-1) 3V.Benzene (71-43-2) 'Moro- /net/IA Ether (542-88-1) 5V.Bromoform (75-25-2) 6V.Carbon \ , Tetrachloride x (56-23-5) 7V.Chlorobenzene (108-90-7) bromomethane (124-48-1) 9V.Chloroethane (75-00-3) 1 oV.2-Chloro- ethylvinyl Ether X (110-75-8) 11V.Chloroform (67-66-3) 12V.Dichloro- bromomethane (75-27-4) 13V.Dichloro- difluoromethane X (75-71-8) 14V.1,1-Dichloro • - ethane(75-34-3) 15V.1,2-Dichloro- ethane(107-06-2) 16V.1,1-Dichloro- ethylene(75-35-4) 17V.1,2-Dichloro- propane(78-87-5) 8 Dichloro- p propylenpylon e (542-75-6) 19V.Ethylbenzene X(100-41-4) • 20V.Methyl Bromide(74-83-9) 21V.Methyl X Chloride(74-87-3) EPA Form 3510-2C(8-90) PAGE V-4 CONTINUE ON PAGE V-5 • CONTINUED FROM PAGE V-4 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c. a.MAXIMUM DAILY VALUE (i/avadahle) VALUE(i/available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (if available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—VOLATILE COMPOUNDS(continued) 22V.Methylene X Chloride(75-09-2) Tetrachloroethane X (79-34-5) 24V.Tetrachloro- ethylene(127-18-4) 25V.Toluene (108-88-3) 26V.1,2-Trans- ` , Dichloroethylene X (156-60-5) 27V.1,1,1-Trichloro- ethane(71-55-6) 28V.1,1,2-Trichloro- ethane(79-00-5) 29V Trichloro- ethylene(79-01-6) 30V.Trichloro- fluoromethane ` , X (75-69-4) 31V.Vinyl Chloride X (75-01-4) GC/MS FRACTION—ACID COMPOUNDS 1A.2-Chlorophenol X (95-57-8) 2A.2,4-Dichloro- X phenol(120-83-2) 3A.2,4-Dimethyl- X phenol(105-67-9) 4A.4,6-Dinitro-0- Cresol(534-52-1) 5A.2,4-Dinitro- phenol(51-28-5) 6A.2-Nitrophenol (88-75-5) 7A.4-Nitrophenol >/ (100-02-7) 8A.P-Chloro-M- Cresol(59-50-7) 9A.Pentachloro- phenol(37-86-5) 10A.Phenol (108-95-2) 11 A.2,4,6-Trichloro- phenol(88-05-2) EPA Form 3510-2C(8-90) PAGE V-5 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a b. c. a.MAXIMUM DAILY VALUE ({/available) VALUE((/available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (i/available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—BASE/NEUTRAL COMPOUNDS 1 B.Acenaphthene >/ (83-32-9) /� 2B.Acenaphtylene �/ (208-96-8) /� 3B.Anthracene (120-12-7) 4B.Benzidine (92-87-5) 58.Benzo(a) Anthracene (56-55-3) 6B.Benzo(a) �/ Pyrene(50-32-8) /� 7B.3,4-Benzo- fluoranthene (205-99-2) 8B.Benzo(gin) Perylene(191-24-2) 9B.Benzo(k) Fluoranthene >/ (207-08-9) /� 10B.Bis(?('blare- elhaxr)Methane �/ (111-91-1) /� 118.Bis(2-('hlnrn- eihrl)Ether X(111-44-4) 12B.Bis(2- ('hlarweviprepyl) Ether(102-80-1) 138.Bis beryl)Phthalate Phthalate (117-81-7) 14B.4-Bromophenyl Phenyl Ether X (101-55-3) 15B.Butyl Benzyl �/ Phthalate(85-68-7) /� 16B.2-Chloro- naphthalene >/ (91-58-7) /� 17B.4-Chloro- phenyl Phenyl Ether (7005-72-3) 18B.Chrysene X (218-01-9) 19B.Dibenzo(a,h) Anthracene (53-70-3) 20B.1,2-Dichloro- benzene(95-50-1) 21 B.1,3-Di-chloro- �/ benzene(541-73-1) /( EPA Form 3510-2C(8-90) PAGE V-6 CONTINUE ON PAGE V-7 CONTINUED FROM PAGE V-6 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c. a.MAXIMUM DAILY VALUE (i)available) VALUE(if available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (i)available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—BASE/NEUTRAL COMPOUNDS(continued) 22B.1,4-Dich loro- benzene(106-46-7) 23B.3,3-Dichloro- benzidine(91-94-1) 24B.Diethyl X Phthalate(84-66-2) 25B.Dimethyl Phthalate (131-11-3) 26B.Di-N-Butyl Phthalate(84-74-2) 27B.2,4-Dinitro- toluene(121-14-2) 28B.2,6-Dinitro- toluene(606-20-2) 29B.Di-N-Octyl X Phthalate(117-84-0) 30B. phenyl- hydrazinezine(as Azo- benzene)(122-66-7) 31B.Fluoranthene (206-44-0) 32B.Fluorene (86-73-7) 33B.Hexachloro- benzene(118-74-1) 34B.Hexachloro- butadiene(87-68-3) 358.Hexachloro- cyclopentadiene X (77-47-4) 36B Hexachloro- ethane(67-72-1) 37B.Indeno (1,2,3-cd)Pyrene (193-39-5) 38B.Isophorone X (78-59-1) 39B.Naphthalene X (91-20-3) 40B.Nitrobenzene (98-95-3) 41B.N-Nitro- sodimethylamine X (62-75-9) 426.N-Nitrosodi- N-Propylamine (621-64-7) EPA Form 3510-2C(8-90) PAGE V-7 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(apnnnal) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c. a.MAXIMUM DAILY VALUE Of available) VALUE(II-available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF Of-available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—BASE/NEUTRAL COMPOUNDS(cannnued) 43B.N-Nitro- sodiphenylamine X (86-30-6) 44B.Phenanthrene (85-01-8) 45B.Pyrene \ (129-00-0) n 46B.1,2,4-Tri- chlorobenzene (120-82-1) GC/MS FRACTION—PESTICIDES 1P.Aldrin (309-00-2) 2P.a-BHC (319-84-6) 3P.p-BHC (319-85-7) 4P.y-BHC X (58-89-9) 5P.b-BHC (319-86-8) 6P.Chlordane (57-74-9) 7P.4,4'-DDT (50-29-3) 8P.4,4'-DDE (72-55-9) 9P.4,4'-DDD (72-54-8) 10P.Dieldrin (60-57-1) 11P.a-Enosulfan (115-29-7) 12P.p-Endosulfan (115-29-7) 13P.Endosulfan Sulfate X (1031-07-8) 14P.Endrin (72-20-8) 15P.Endrin Aldehyde (7421-93-4) 16P.Heptachlor (76-44-8) EPA Form 3510-2C(8-90) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy/romllem I o/Form I) OUTFALL NUMBER NC0004961 102 CONTINUED FROM PAGE V-8 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a b. c. a.MAXIMUM DAILY VALUE (i/available) VALUE(Javailable) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (II available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION-PESTICIDES(continued) 17P.Heptachlor ` , Epoxide X (1024-57-3) 18P.PCB-1242 (53469-21-9) 19P.PCB-1254 (11097-69-1) 20P.PCB-1221 (11104-28-2) 21P.PCB-1232 (11141-16-5) 22P.PCB-1248 \ (12672-29-6) n 23P.PCB-1260 \ (11096-82-5) n 24P.PCB-1016 \ ' (12674-11-2) /X\ 25P.Toxaphene \ (8001-35-2) n EPA Form 3510-2C(8-90) PAGE V-9 n ao m a .. C m 0t" z c n rn g PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY.You may report some or all of this information EPA I.D.NUMBER(cnpv/rom liem I at Farm I) on separate sheets(use the same format)instead of completing these pages. NCO 0 04 961 SEE INSTRUCTIONS. OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 107 PART A—You must provide the results of at least one analysis for every pollutant in this table.Complete one table for each outfall.See instructions for additional details. 3.UNITS 4.INTAKE 2.EFFLUENT (epeci/y if blank) (upiiunal) b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.VALUE a.LONG TERM a.MAXIMUM DAILY VALUE (if available) (if available) AVERAGE VALUE d.NO.OF a.CONCEN- (1) b.NO.OF 1.POLLUTANT CONCENTRATION (2)MASS CONCENTRATION (2)MASS (1)CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES a.Biochemical Oxygen <2.0 1 mg/L Demand(BOD) b.Chemical Oxygen < 20 1 mg/L Demand(('O1)) c.Total Organic Carbon (TO(.) 1.5 1 mg/L • d.Total Suspended Solids(7 SS) 6.90 12 mg/L e.Ammonia(us N) <0.10 1 mg/L VALUE VALUE VALUE VALUE f.Flow 0.004 12 cfs g.Temperature VALUE VALUE VALUE VALUE (wirier) 11.7 1 °C h.Temperature VALUE VALUE VALUE VALUE (summer) 2 0.6 3 °C MINIMUM MAXIMUM MINIMUM MAXIMUM i.pH 6.3 7.8 12 STANDARD UNITS PART B— Mark"X"in column 2-a for each pollutant you know or have reason to believe is present.Mark"X"in column 2-b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.VALUE a.LONG TERM AVERAGE AND a. b a.MAXIMUM DAILY VALUE (if available) (if available) VALUE CAS NO. BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (if available) PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES a.Bromide (24959-67-9) b.Chlorine,Total Residual c.Color d.Fecal Coliform e.Fluoride (16984-48-8) X < 0.10 12 mg/L f.Nitrate-Nitrite X 0.23 12 mg/L (as N) �\ EPA Form 3510-2C(8-90) PAGE V-1 CONTINUE ON REVERSE ITEM V-B CONTINUED FROM FRONT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(up,ronul) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.VALUE a.LONG TERM AND a. b. a.MAXIMUM DAILY VALUE (?1 available) (,/available) AVERAGE VALUE CAS NO. BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (,(available) PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES g.Nitrogen, Total Organic(as N) h.Oil and Grease < 5 < 5 12 mg/L i.Phosphorus (as P),Total (7723-14-0) j.Radioactivity (1)Alpha,Total (2)Beta,Total (3)Radium, Total (4)Radium 226, Total k.Sulfate (14808-79-8) 4.02 12 mg/L I.Sulfide (as S) m.Sulfite (as so 3) (14265-45-3) n.Surfactants o.Aluminum, Total (7429-90-5) p.Barium,Total \ (7440-39-3) n 0.02 12 mg/L q.Boron,Total (7440-42-8) X 0.06 1 mg/L r.Cobalt,Total (7440-48-4) s.Iron,Total (7439-89-6) X 0.66 12 mg/L t.Magnesium, Total X (7439-95-4) 4.59 12 mg/L u.Molybdenum, Total (7439-98-7) v.Manganese, Total (7439-96-5) 0.14 12 mg/L w.Tin,Total (7440-31-5) x.Titanium, Total (7440-32-6) EPA Form 3510-2C(8-90) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(copy/ram Item I a/7•'orm I) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004961 107 PART C- If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides, and total phenols. If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls, and nonrequired GC/MS fractions), mark"X"in column 2-b for each pollutant you know or have reason to believe is present. Mark"X"in column 2-c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table(all 7 pages)for each outfall. See instructions for additional details and requirements. 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. - a.LONG TERM AND a. b. c. a.MAXIMUM DAILY VALUE (if available) VALUE QJavailable) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (i/available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES METALS,CYANIDE,AND TOTAL PHENOLS 1M.Antimony,Total (7440-36-0) 2M.Arsenic,Total (7440-38-2) X < 1 12 ug/L 3M.Beryllium,Total (7440-41-7) 4M.Cadmium,Total < (7440-43-9) 1 12 ug/L 5M.Chromium, X 1.90 12 ug/L Total(7440-47-3) 6M.Copper,Total (7440-50-8) X 1.17 12 ug/L Lead,Total (7439-92-1) X < 1 12 ug/L 8M.Mercury,Total (7439-97-6) X 1.60 13 ng/L 9M.Nickel,Total (7440-02-0) X 2.61 12 ug/L Total Selenium, X < 1 12 ug/L Total(7782-49-2) 11 M.Silver Total (7440-22-4) 12M.Thallium, Total(7440-28-0) 13M.Zinc,Total (7440-66-6) X 0.01 12 mg/L 14M.Cyanide, Total(57-12-5) 15M.Phenols, Total DIOXIN 2,3,7,8-Tetra- X DESCRIBE RESULTS chlorodibenzo-P- Dioxin(1764-01-6) EPA Form 3510-2C(8-90) PAGE V-3 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(oplumal) 1.POLLUTANT I b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c a.MAXIMUM DAILY VALUE (if available) VALUE(/uianlable) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (if available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—VOLATILE COMPOUNDS 1V.Accrolein X (107-02-8) 2V.Acrylonitrile (107-13-1) 3V.Benzene (71-43-2) 4Vvl) ((hilr nie ` irrerlrvQ Ether X (542-88-1) 5V.Bromoform (75-25-2) 6V.Carbon Tetrachloride X (56-23-5) 7V.Chlorobenzene (108-90-7) 8V.Chlorodi- bromomethane X (124-48-1) 9V.Chloroethane (75-00-3) 10V.2-Chloro- ethylvinyl Ether (110-75-8) 11V.Chloroform (67-66-3) 12V.Dichloro- bromomethane V (75-27-4) 13V.Dichloro- difluoromethane (75-71-8) 14V.1,1-Dichloro- ethane(75-34-3) 15V.1,2-Dichloro- Xethane(107-06-2) 16V.1,1-Dichloro- ethylene(75-35-4) 17V.1,2-Dichloro- propane(78-87-5) 18V, n-Dichloro- prop propyll ene (542-75-6) 19V.Ethylbenzene X (100-41-4) 20V.Methyl X Bromide(74-83-9) 21V.Methyl Chloride(74-87-3) EPA Form 3510-2C(8-90) PAGE V-4 CONTINUE ON PAGE V-5 CONTINUED FROM PAGE V-4 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(upiiunal) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a- b. c. a.MAXIMUM DAILY VALUE (if available) VALUE(i/available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) ' b.NO.OF Of available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—VOLATILE COMPOUNDS(coniuiued) 22V.Methylene Chloride(75-09-2) Tetrachloroethane X (79-34-5) 24V.Tetrachloro- ethylene(127-18-4) 25V.Toluene �/ (108-88-3) 26V.1,2-Trans- ` Dichloroethylene X (156-60-5) 27V.1,1,1-Trichloro- ethane(71-55-6) 28V.1,1,2-Trich loro- ethane(79-00-5) 29V Trichloro- ethylene(79-01-6) 30V.Trichloro- fluoromethane fluoromemethane ane X (75-69-4) 31V.Vinyl Chloride (75-01-4) GC/MS FRACTION—ACID COMPOUNDS 1 A.2-Chlorophenol (95-57-8) 2A.2,4-Dichloro- -- X _ phenol(120-83-2) 3A.2,4-Dimethyl- phenol(105-67-9) 4A.4,6-Dinitro-O- Cresol(534-52-1) 5A.2,4-Dinitro- phenol X (51-28-5) 6A.2-Nitrophenol X (88-75-5) 7A.4-Nitrophenol (100-02-7) 8A.P-Chloro-M- Cresol(59-50-7) 9A.Pentachloro- phenol(87-86-5) 10A.Phenol (108-95-2) 11 A.2,4,6-Trich loro- phenol(88-05-2) EPA Form 3510-2C(8-90) PAGE V-5 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(uphanal) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c a.MAXIMUM DAILY VALUE (if available) VALUE(if available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (i/available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—BASE/NEUTRAL COMPOUNDS 1B.Acenaphthene �/ (83-32-9) /� 2B.Acenaphtylene X (208-96-8) 3B.Anthracene (120-12-7) 4B.Benzidine \ (92-87-5) n 5B.Benzo(a) Anthracene >/ (56-55-3) /� 6B.Benzo(a) X Pyrene(50-32-8) 7B.3,4-Benzo- fluoranthene >/ (205-99-2) /� 8B.Benzo(gin) Perylene(191-24-2) 9B.Benzo(k) Fluoranthene �/ (207-08-9) /� 10B.Bis(24'hloro- eihoxy)Methane (111-91-1) 11 B.Bis(2-(71loro- eihtJ)Ether (111-44-4) 12B.Bis(2- ('hlormsupropvl) Ether(102-80-1) 13B.Bis(2-Eihvl- hexvl)Phthalate >/ (117-81-7) 14B.4-Bromophenyl Phenyl Ether �/ (101-55-3) /� 15B.Butyl Benzyl �/ Phthalate(85-68-7) /� 16B.2-Chloro- naphthalene X(91-58-7) 17B.4-Chloro- phenyl Phenyl Ether >/ (7005-72-3) /� 18B.Chrysene X(218-01-9) 19B.Dibenzo(all) Anthracene X(53-70-3) 20B.1,2-Dichloro- X benzene(95-50-1) 21 B.1,3-Di-chloro- benzene(541-73-1) EPA Form 3510-2C(8-90) PAGE V-6 CONTINUE ON PAGE V-7 CONTINUED FROM PAGE V-6 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(uptianul) - 1. POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a b c a.MAXIMUM DAILY VALUE (it available) VALUE(if available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (if available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—BASE/NEUTRAL COMPOUNDS(eonnnued) 22B.1,4-Dichloro- benzene(106-46-7) 23B.3,3-Dichloro- benzidine(91-94-1) 24B.Diethyl X Phthalate(84-66-2) 25B.Dimethyl Phthalate X (131-11-3) 26B.Di-N-Butyl Phthalate(84-74-2) 27B.2,4-Dinitro- toluene(121-14-2) 28B.2,6-Dinitro- toluene(606-20-2) 29B.Di-N-Octyl X Phthalate(117-84-0) 30B.1,2-Diphenyl- hydrazine(as Azo- benzene)(122-66-7) 31 B.Fluoranthene (206-44-0) 32B.Fluorene (86-73-7) 33B.Hexachloro- benzene(118-74-1) 34B.Hexachloro- butadiene(87-68-3) 35B.Hexachloro- cyclopentadiene X (77-47-4) 36B Hexachloro- ethane(67-72-1) 37B.Indeno (1,2,3-cd)Pyrene (193-39-5) 38B.Isophorone (78-59-1) 39B.Naphthalene (91-20-3) 40B.Nitrobenzene (98-95-3) 41B.N-Nitro- sodimethylamine (62-75-9) 42B.N-Nitrosodi- N-Propylamine (621-64-7) EPA Form 3510-2C(8-90) PAGE V-7 CONTINUE ON REVERSE I J CONTINUED FROM THE FRONT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(u/inunal) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c a.MAXIMUM DAILY VALUE (Javailable) VALUE(i/available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (i1 available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—BASE/NEUTRAL COMPOUNDS(cnnnnned) 43B.N-Nitro- sodiphenylamine (86-30-6) 44B.Phenanthrene (85-01-8) 45B.Pyrene \ (129-00-0) >< 468.1,2,4-Tri- chlorobenzene (120-82-1) GC/MS FRACTION—PESTICIDES (309-00-2) \ n 2P.a-BHC \� (319-84-6) �\ 3P.p-BHC X (319-85-7) 4P.y-BHC (58-89-9) 5P.8-BHC (319-86-8) 6P.Chlordane (57-74-9) 7P.4,4'-DDT (50-29-3) 8P.4,4'-DDE (72-55-9) 9P.4,4'-DDD (72-54-8) 10P.Dieldrin \ (60-57-1) n 11 P.a-Enosulfan (115-29-7) 12P.0-Endosulfan \ (115-29-7) n 13P.Endosulfan Sulfate X (1031-07-8) 14P.Endrin (72-20-8) 15P.Endrin Aldehyde (7421-93-4) 16P.Heptachlor (76-44-8) EPA Form 3510-2C(8-90) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item I at Earm I) OUTFALL NUMBER NC0004961 107 CONTINUED FROM PAGE V-8 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c. a.MAXIMUM DAILY VALUE (!/available) VALUE(tf available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) ' b.NO.OF (if available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—PESTICIDES(continued) 1o.Heptachlor ` , Epoxide X (1024-57-3) 18P.PCB-1242 \/ (53469-21-9) X\ 19P.PCB-1254 (11097-69-1) 20P.PCB-1221 \� (11104-28-2) �\ 21P.PCB-1232 (11141-16-5) 22P.PCB-1248 (12672-29-6) 23P.PCB-1260 (11096-82-5) 24P.PCB-1016 (12674-11-2) 25P.Toxaphene \ (8001-35-2) n EPA Form 3510-2C(8-90) PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY.You may report some or all of this information EPA I.D.NUMBER(copy from Item 1 of harms 1) on separate sheets(use the same format)instead of completing these pages. NCO 004961 SEE INSTRUCTIONS. OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 108 PART A—You must provide the results of at least one analysis for every pollutant in this table.Complete one table for each outfall.See instructions for additional details. 3.UNITS 4.INTAKE 2.EFFLUENT (specify if blank) (opuonal) b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.VALUE a.LONG TERM a.MAXIMUM DAILY VALUE (if available) (if available) AVERAGE VALUE 1 1 d.NO.OF a.CONCEN- 1) b.NO.OF 1.POLLUTANT CONCENTRATION (2)MASS CONCENTRATION (2)MASS (1)CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES a.Biochemical Oxygen < 2 0 1 mg/L Demand(ROD) b.Chemical Oxygen < 20 1 mg/L Demand(('OD) c.Total Organic Carbon 2 9 1 mg/L (TO(') d.Total Suspended Solids(1;s) 5.38 19 mg/L e.Ammonia(cis N) < 0.10 1 mg/L VALUE VALUE VALUE VALUE f.Flow 0.02 20 cfs g.Temperature VALUE VALUE VALUE VALUE (winter) 11.7 1 °C h.Temperature VALUE VALUE VALUE VALUE (summer) 2 0.6 3 °C MINIMUM MAXIMUM MINIMUM MAXIMUM i.pH 6.0 7.6 20 STANDARD UNITS PART B— Mark"X"in column 2-a for each pollutant you know or have reason to believe is present.Mark"X"in column 2-b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(opuonal) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.VALUE a.LONG TERM AVERAGE AND a b. a.MAXIMUM DAILY VALUE (if available) (ijavailable) VALUE CAS NO. BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (if available) PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES a.Bromide (24959-67-9) b.Chlorine,Total Residual c.Color d.Fecal Coliform e.Fluoride (16984-48-8) X < 0.10 20 mg/L f.Nitrate-Nitrite(as N) X 0.37 12 mg/L EPA Form 3510-2C(8-90) PAGE V-1 CONTINUE ON REVERSE ITEM V-B CONTINUED FROM FRONT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optuma) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.VALUE a.LONG TERM AND a. b. a.MAXIMUM DAILY VALUE available) CAS NO. BELIEVED BELIEVED (� ({faradahlr") AVERAGE VALUE available) PRESENT ABSENT (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES g.Nitrogen, Total Organic(u., M h.Oil and < 5 .00 20 mg/L Grease i.Phosphorus (as P),Total (7723-1 a-0) j.Radioactivity (1)Alpha,Total (2)Beta,Total (3)Radium, Total (4)Radium 226, Total k.Sulfate (as SO.) X (14808-79-8) 1.08 20 mg/L I.Sulfide (ac.S) m.Sulfite (rr.,SO,) (14265-45-3) n.Surfactants o.Aluminum, Total (7429-90-5) p.Barium,Total (7440-39-3) X 0.02 20 mg/L q.Boron,Total (7440-42-8) X < 0.05 1 mg/L r.Cobalt,Total (7440-48-4) s.Iron,Total (7439-89-6) X 1.71 20 mg/L t.Magnesium, Total X 2.41 20 mg/L (7439-95-4) u.Molybdenum, Total (7439-98-7) v.Manganese, Total (7439-96-5) 0.04 20 mg/L w.Tin,Total (7440-31-5) x.Titanium, Total (7440-32-6) EPA Form 3510-2C(8-90) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(copy from Item I of Form I) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NCO 004961 108 PART C- If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides,and total phenols. If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls, and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present. Mark"X"in column 2-c for each pollutant you believe is absent. If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c. a.MAXIMUM DAILY VALUE (if available) VALUE(i/aruilable) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF Of available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES METALS,CYANIDE,AND TOTAL PHENOLS 1M.Antimony,Total (7440-36-0) 2M.Arsenic,Total(7440-38-2) X < 1.00 20 ug/L 3M.Beryllium,Total (7440-41-7) 4M.Cadmium,Total \/ (7440-43-9) �\ < 1.0 0 20 ug/L Tot.Chromium,Total(7440-47-3) X < 1.00 20 ug/L Copper,Total(74X 1.04 20 ug/L (7440-50-50-8) Lead,7M Total (7439-92-1) X < 1 20 ug/L 8M.Mercury,Total (7439-97-6) X 1.14 20 ng/L 9M.Nickel,Total(7440-02-0) X < 1.00 20 ug/L total Selenium,Total(7782-49-2) X < 1.00 20 ug/L 11M.Silver,Total (7440-22-4) 12M.Thallium, Total(7440-28-0) 13M.Zinc,Total (7440-66-6) X < 0.01 20 mg/L 14M.Cyanide, Total(57-12-5) 15M.Phenols, Total DIOXIN 2,3,7,8-Tetra- X DESCRIBE RESULTS chlorodibenzo-P- Dioxin(1764-01-6) EPA Form 3510-2C(8-90) PAGE V-3 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(opimnul) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. o. a.MAXIMUM DAILY VALUE (iJavailable) VALUE(if available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- 1 b.NO.OF Of available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—VOLATILE COMPOUNDS 1 V.Accrolein (107-02-8) 2V.Acrylonitrile (107-13-1) 3V.Benzene (71-43-2) 4V B ine yls)Ether meih}�l)Ether (542-88-1) 5V.Bromoform (75-25-2) Te.Carbon X Tetrachloride (56-23-5) 7V.Chlorobenzene (108-90-7) 8V.Chlorodi- bromomethane(124-48-1) 9V.Chloroethane (75-00-3) 10V.2-Chloro- ethylvinyl Ether X (110-75-8) 11V.Chloroform \ (67-66-3) n 12V.Dichloro- bromomethane X (75-27-4) 13V.Dichloro- difluoromethane (75-71-8) 14V.1,1-Dichloro- ethane(75-34-3) 15V.1,2-Dichloro- ethane(107-06-2) 16V.1,1-Dichloro- ethylene(75-35-4) 17V.1,2-Dichloro- X propane(78-87-5) 18V.l, -Dichloro- prop propylenne (542-75-6) 19V.Ethylbenzene (100-41-4) 20V.Methyl X Bromide(74-83-9) 21V.Methyl Chloride(74-87-3) EPA Form 3510-2C(8-90) PAGE V-4 CONTINUE ON PAGE V-5 CONTINUED FROM PAGE V-4 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c. a.MAXIMUM DAILY VALUE Warm/able) VALUE(iJarailahle) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (iJarailahle) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—VOLATILE COMPOUNDS(continued) 22V.Methylene Chloride(75-09-2) Tetrachloroethane X (79-34-5) 24V.Tetrachloro- ethylene(127-18-4) 25V.Toluene (108-88-3) 26V.1,2-Trans- ` , Dichloroethylene X (156-60-5) 27V.1,1,1-Trich loro- Xethane(71-55-6) 28V.1,1,2-Trich loro- ethane(79-00-5) 29V Trichloro- ethylene(79-01-6) 30V.Trichloro- fluoromethane \ X (75-69-4) 31 V.Vinyl Chloride X(75-01-4) GC/MS FRACTION—ACID COMPOUNDS 1A.2-Chlorophenol (95-57-8) 2A.2,4-Dichloro- phenol(120-83-2) 3A.2,4-Dimethyl- phenol(105-67-9) 4A.4,6-Dinitro-0- Cresol(534-52-1) 5A.2,4-Dinitro- phenol(51-28-5) 6A.2-Nitrophenol (88-75-5) 7A.4-Nitrophenol (100-02-7) 8A.P-Chloro-M- Cresol(59-50-7) 9A.Pentachloro- phenol(87-86-5) 10A.Phenol (108-95-2) 11 A.2,4,6-Trichloro- phenol(88-05-2) EPA Form 3510-2C(8-90) PAGE V-5 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. e. a.MAXIMUM DAILY VALUE ({favadohle) VALUE((I available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) (if available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION b.NO.OF (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—BASE/NEUTRAL COMPOUNDS 1 B.Acenaphthene X (83-32-9) 2B.Acenaphtylene �/ (208-96-8) /� 3B.Anthracene (120-12-7) 4B.Benzidine \ (92-87-5) n 5B.Benzo(a) — Anthracene (56-55-3) 6B.Benzo(a) �/ Pyrene(50-32-8) /� 7B.3,4-Benzo- fluoranthene X (205-99-2) 88.Benzo(gin) Perylene(191-24-2) 9B.Benzo(k) Fluoranthene �/ (207-08-9) /� 108.Bis(2-('hlora- ethor))Methane X (111-91-1) 11 B.Bis(24'hloro- ethyl)Ether (111-44-4) 12B.Bis(2- ('hloraisopropt'l) Ether(102-80-1) 13B.Bis(2-Ethrl- hexii)Phthalate X (117-81-7) 14B.4-Bromophenyl Phenyl Ether �/ (101-55-3) /� 15B.Butyl Benzyl \/ Phthalate(85-68-7) �\ 16B.2-Chloro- naphthalene �/ (91-58-7) /� 17B.4-Chloro- phenyl Phenyl Ether >/ (7005-72-3) /� 18B.Chrysene (218-01-9) 19B.Dibenzo(a.h) Anthracene (53-70-3) 20B.1,2-Dichloro- benzene(95-50-1) 21 B.1,3-Di-ch loro- benzene(541-73-1) EPA Form 3510-2C(8-90) PAGE V-6 CONTINUE ON PAGE V-7 CONTINUED FROM PAGE V-6 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c. a.MAXIMUM DAILY VALUE Ware/liable) VALUE(i/available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (i/available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—BASE/NEUTRAL COMPOUNDS(continued) 22B.1,4-Dichloro- benzene(106-46-7) 238.3,3-Dichloro- benzidine(91-94-1) 24B.Diethyl Phthalate(84-66-2) 25B.Dimethyl Phthalate X (131-11-3) 268.Di-N-Butyl X Phthalate(84-74-2) 27B.2,4-Dinitro- toluene(121-14-2) 28B.2,6-Dinitro- toluene(606-20-2) 29B.Di-N-Octyl X Phthalate(117-84-0) 30B.1,2-Diphenyl- hydrazine((ass Azo- benzene)(122-66-7) 31B.Fluoranthene (206-44-0) 32B.Fluorene (86-73-7) 338.Hexachloro- benzene(118-74-1) 34B.Hexachloro- butadiene(87-68-3) 35B.Hexachloro- cyclopentadiene X (77-47-4) 36B Hexachloro- ethane(67-72-1) 378.Indeno (1,2,3-cd)Pyrene (193-39-5) 38B.Isophorone (78-59-1) 39B.Naphthalene (91-20-3) 40B.Nitrobenzene (98-95-3) 41B.N-Nitro- sodimethylamine X (62-75-9) 42B.N-Nitrosodi- N-Propylamine X (621-64-7) EPA Form 3510-2C(8-90) PAGE V-7 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c. a.MAXIMUM DAILY VALUE (i/'available) VALUE(il available) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF Of available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—BASE/NEUTRAL COMPOUNDS(continued) 43B.N-Nitro- sodiphenylamine X (86-30-6) 4413.Phenanthrene (85-01-8) 45B.Pyrene ` (129-00-0) >< 46B.1,2,4-Tri- chlorobenzene (120-82-1) GC/MS FRACTION—PESTICIDES 1P.Aldrin (309-00-2) 2P.a-BHC (319-84-6) 3P.p-BHC X (319-85-7) 4P.y-BHC (58-89-9) 5P.S-BHC (319-86-8) 6P.Chlordane (57-74-9) 7P.4,4'-DDT (50-29-3) 8P.4,4'-DDE (72-55-9) 9P.4,4'-DDD (72-54-8) 10P.Dieldrin (60-57-1) 11P.a-Enosulfan (115-29-7) 12P.)1-Endosulfan \/ (115-29-7) n 13P.Endosulfan Sulfate (1031-07-8) 14P.Endrin (72-20-8) 15P.Endrin Aldehyde X (7421-93-4) 16P.Heptachlor (76-44-8) EPA Form 3510-2C(8-90) PAGE V-8 CONTINUE ON PAGE V-9 1 EPA I.D.NUMBER(cony/ran Item 1 of Form l) OUTFALL NUMBER NC0004961 108 CONTINUED FROM PAGE V-8 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a, b. c. a.MAXIMUM DAILY VALUE (if available) VALUE(lb-available) AVERAGEVALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (it available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—PESTICIDES(coniinuecl) 17P.Heptachlor ` , Epoxide X (1024-57-3) 18P.PCB-1242 (53469-21-9) 19P.PCB-1254 (11097-69-1) 20P.PCB-1221 (11104-28-2) 21P.PCB-1232 (11141-16-5) 22P.PCB-1248 — (12672-29-6) 23P.PCB-1260 (11096-82-5) 24P.PCB-1016 (12674-11-2) 25P.Toxaphene (8001-35-2) EPA Form 3510-2C(8-90) PAGE V-9 Duke Energy Carolinas, LLC Riverbend Stream Electric Plant National Pollutant Discharge Elimination System Permit Number NC0004961 Attachment 1 NPDES Outfalls Map r E:A00GIS\DukeEner NPDESGIS\MXDARrverbendWlllSM Ifr2�m REVISED 08,�2 2201 SCALE. 2,000 when/printed at 8.5x11 _ _ DRAWN BY-Amanda Fre(4,.....\147er arv. 9Y v �.r r'.mat" . s ,I f s (.../ ti a f y,. a. rr y , r ,• .,-1:-Idelittift-#—M4 "'. ..t..., --'::// \ ' f �4 < { A . • � - fig.t y '1 , 7;...% '', \N"`"\ .4."‘"*A.:1%.4 : t I \ \ ,..,. ,,,, \\,.... ,, ' i -i'' N E9- 1 . is � M. S � Outfall107 \-\ r Outfall 002A �� i .� . --..., r f Outfall 102 `� Outfall 108 �' • - ,....°4"*-'..'--./:--"-*\''..:- ''- 'i VI- -;.-' .1 i,-'t 4( I 4e1P-' , 0 ... `....-,0 , i ''' i 'Y'r fril i •. Powerplant �. 1 3 e--ram .». , ' % �.! }r • i y � - » 6 \_,..v,a'!.�. i f '' I ; * NNA. USGS Quad: Mountain Island Lake ''r �` Receiving Stream: Catawba River Outfall Latitude Longitude ,', • • Stream Class: WS-IV, B;CA 002A 35°21'55.44"N 80°58'10.92"W It To,1',w; Sub Basin: 03 08 33 , 102 35°21'54.00"N 80°57'57.60"W __ ` 107 35°22'1.20"N 80°57'25.20"W OVJ - 04 y g£` r�,` River Basin: Catawba River 108 35°21'55.65"N 80°57'21.21"W •° �" Hydrogeologic Unit: 030501 11 _ - Legend N Attachment 1 # ANPDES Outfalls NPDES Outfall Location NPDES Permit No. NC00004961 0 1000 2.000 Duke Energy Carolinas, LLC ::' Environmental Resources Management Feet Riverbend Steam Station „:0: ERM wwwerm.com 1 12,000 1 inch= 1,000 feet Gaston County, North Carolina Source:Copyright:02013 National Geographic Society,i-cubed Coordinate System.NAD 1983 StatePlane North Carolina FIPS 3200 Feet L P Duke Energy Carolinas, LLC Riverbend Stream Electric Plant National Pollutant Discharge Elimination System Permit Number NCOOO4961 RECEIVED/NCDEQ/DWIt AUG 27 2019 Water Quality Permitting Section Attachment 2 Form 2C Item II — A Line Drawing for Flows, Sources of Pollution and Treatment Technologies FORMER RIVERBEND STEAM STATION FLOW SCHEMATIC Future Non-Engineered Non-Engineered Non-Engineered Groundwater Seep Seep Seep Remediation S-2 S-7 S-8 Discharge Flow A Flow B Flow C Flow D(Future) Outfall 102 Outfall 107 Outfall 002A Outfall 108 0.001 MGD 0.89 MGD 0.04 MGD 0.008 MGD Catawba River Attachment 2—Form 2C—Item IIA Flows, Sources of Pollution and Treatment Technologies Duke Energy Carolinas LLC Flows are approximated averages which have a high variability on a daily Former Riverbend Steam Electric Plant(NC0004961) basis Gaston County, North Carolina Duke Energy Carolinas, LLC Riverbend Stream Electric Plant National Pollutant Discharge Elimination System Permit Number NC0004961 Attachment 3 Form 2C Item IIB Description of Flows National Pollutant Discharge Elimination System Permit# NCOOO4961 Duke Energy Carolinas, LLC Riverbend Stream Electric Plant Attachment 3 Form 2C - Item II-A Flow, Sources of Pollution, and Treatment Technologies Stream Name Average Flow A Non-Engineered Seep S-2 (Outfall 102) 0.001 MGD B Non-Engineered Seep 5-7(Outfall 107) 0.89 MGD Non-Engineered Seep S-8 (Outfall 108) 0.008 MGD D Future Groundwater Remediation Discharge 0.04 MGD Duke Energy Carolinas, LLC Riverbend Stream Electric Plant National Pollutant Discharge Elimination System Permit Number NC0004961 Attachment 4 Outfall Anal tical Data Y OUTFALL 002A I Outran 002:k 12/20/2018 02/18/2019 05/09/2019 12/20/2018 02/18/2019 05/09/2019 12/17/2018 02/18/2019 05/09/2019 12/17/2018 02/18/2019 05/09/2019 12/12/2018 02/19/2019 05/08/2019 12/12/2018 02/19/2019 O5/08/2019 12/21/2018 Constituent - CPA-OlD CPA-01D CPA 01D CPA-OIS CPA-OIS CPA-OIS CPA-02D CPA-02D CPA-02D CPA-02S CPA-02S CPA-02S CPA-03D CPA-03D CPA-03D CPA-03S CPA-03S CPA-03S CPA-04S pH(S.U.) 5.8 6.3 6.1 3.6 4.0 3.8 4.2 4.2 3.9 3.8 4.1 3.8 5.8 5.8 5.7 5.7 5.7 5.8 3.2 Water Level(ft) 25.72 26.14 26.25 25.97 26.33 26.50 29.25 29.04 29.12 29.07 28.89 28.98 21.48 20.78 - 22.65 21.08 19.94 21.90 27.52 Temperature(Deg C) 18 17 22 18 18 21 21 19 22 22 20 24 16 13 22 12 13 23 15 Specific Conductance(umhos/cm) 3788 3708 3800 3327 3562 3605 2922 2823 2833 2873 2895 2959 3103 3039 3037 1866 1944 1859 5617 Dissolved Oxygen(mg/L) 0.01 0.38 1.20 0.30 0.29 0.42 0.10 0.41 0.28 0.40 0.39 0.56 1.20 0.21 0.24 2.80 0.27 0.35 0.90 Oxidation Reduction Potential(mV) 21 -95 163 309 179 416 87 71 428 349 13-. 537 49 87 282 174 21 245 318 Eh(mV) 226 110 368 514 384 621 292 276 633 554 340 742 254 292 487 379 226 450 523 Turbidity(NTUs) 1.4 9.1 4.0 1.9 8.7 2.2 3.2 9.1 6.6 9.0 8.7 4.2 6.0 2.2 3.1 2.2 1.1 2.4 5.3 Alkalinity(mg/L) 36.9 61.2 58 <5 <5 <5 <5 <5 <5 <5 <5 <5 33 26 25 41.3 32.4 43.5 <5 Bicarbonate Alkalinity(mg/L) 36.9 61.2 58 <5 <5 <5 <5 <5 <5 <5 <5 <5 33 26 25 41.3 32.4 43.5 <5 Methane(ug/L) NA NA NA NA NA NA NA NA NA NA NA NA NA NA ;NA NA NA NA NA Sulfide(mg/L) <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 1<0.1 0.1 <0.1 <0.1 <0.1 <0.1 <0.1 t <0.1 <0.1 <0.1 <0.1 Total Organic Carbon(mg/L) 1.3 1.4 1.3 2 2.1 2.2 <1 0.568 0.471 1 0.776 0.697 0.64 0.616 p.584 0.57 0.527 0.647 1.8 Total Suspended Solids(mg/L) 21.9 SI 12 5 <5 16 6 <2.5 7 7 8.3 8 <5 <2.5 <5 <5 <2.5 <5 <5 6.8 t Boron(ug/L) 27.2 j <50 17.983 j <500 D3 <100 44.486 j 93.2 <100 101 71.7 25.577 j 98 38.3 j 44.654 j 50 28.2 j 28.255 j 26.471 j <50 Calcium(mg/L) 572 585 614 405 M6 498 509 435 Ml 490 M4 520 447 518 567 529 528 528 267 306 273 426 Chloride(mg/L) 22 22 21 9.9 9.9 13 11.4 11 11 11.5 11 12 7.4 6.4 0.73 j 6.6 6.2 8.1 22.2 Strontium(ug/L) 5000 5190 5250 2900 3530 3550 2550 Ml 3160 3320 2360 3390 3340 2910 3420 3520 1490 1760 1480 3520 Sulfate(mg/L) 2820 2900 3400 2350 M6 4200 4900 1910 2600 3400 1880 M6 2900 3500 1990 2100 2900 1090 1200 1300 4330 Total Dissolved Solids(mg/L) 4050 3900 3800 3880 4100 4000 3300 2900 2900 3080 3000 3000 3230 3100 _ 3200 1670 1800 1800 7210 Aluminum(ug/L) 140 82 89 51800 55000 45900 18500 Ml 23500 22300 _ 16600 26300 25300 <100 128 92 <100 15 212 16600 Antimony(ug/L) 0.12 j <5 <1 0.15 j <5 <1 0.21 j <5 <1 0.53 <5 <1 0.12 j <5 <I • 0.21 j <5 <1 0.16 j Arsenic(ug/L) 0.39 1.534 j 1.16 6.4 6.5 6.01 3.7 3.357 j 2.94 4.6 3.093 j 3.06 0.2 <5 <1 0.22 <5 0.558 j 3.8 Barium(ug/L) 60 49 43 50 D3 17 14 16.4 18 15 35.8 36 22 39.1 27 27 81.6 39 39 <5 Beryllium(ug/L) <1 D3 <5 <1 66.4 51.8 57.3 18.6 20.3 22.1 22.8 22.9 25.5 <0.1 <5 <1 0.036 j <5 <1 20.9 Cadmium(ug/L) <0.8 D3 <5 <1 11.1 9.12 8.3 4.3 6.34 5.21 4.6 4.965 j 5.21 0.48 <5 0.605 j 0.19 <5 <I 4.8 Chromium(VI)(ug/L) <0.025 <0.025 <0.025 <0.025 P4,R0 0.069 P4,R0 0.035 P4 <0.025 <0.025 Ml <0.025 P4 0.22 <0.025 <0.025 <0.025 <0.025 <0.025 <0.025 <0.025 <0.025 <1.2 P4,D3,R0_ Chromium(ug/L) 13.9 0.746 j 0.847 j 6.8 4.613 j 3.16 j 6.7 8.21 3.32 5.9 5.21 2.06 84.7 1.896 j 0.548 j 12.2 <5 0.783 j 6 Cobalt(ug/L) 14.8 9.09 44 1050 1140 1330 699 M6 659 619 550 518 M4 545 M4 41.4 35.5 41.1 12 8.68 13.7 _ 2870 Copper(ug/L) 0.67 <5 <I 284 228 215 65.7 118 340 139 127 172 3.6 SI 0.767 j 1.76 1.1 SI 0.516 j 2.74 _ 122 Iron(ug/L) 2720 11400 10800 34900 133000 164000 66200 M1 79200 M4 72600 25300 61600 63300 897 536 407 164 155 2260 820000 Lead(ug/L) <1 D3 <5 <1 2.4 2.987 j 2.09 0.64 0.939 j 0.483 j 1.5 1.124 j 0.656 j <0.1 <5 <1 <0.1 <5 <1 5.5 • Lithium(ug/L) 13.5 j,D3 11 12 128 120 107 141 171 175 137 187 186 10.1 14 15 2.2j <5 2.255j 38.2 Magnesium(mg/L) 241 242 257 148 M6 202 203 98.3 MI 116 M4 III 81.4 110 110 184 193 . .190 97.1 116 101 264 7 Manganese(ug/L) 13000 9160 9490 48900 M6 64900 63000 28700 Ml 27500 28100 20000 23000 22300 33800 46200 47300 18700 24200 17400 82800 Mercury(ug/L) <0.2 <0.05 <0.05 <0.2 <0.05 <0.05 <0.2 <0.05 <0.05 <0.2 <0.05 <0.05 <0.2 <0.05 <0.05 <0.2 <0.05 <0.05 <0.2 Molybdenum(ug/L) 3.1 2.549 j 1.7 0.12 j 0.112 j <1 0.13 j 0.177 j 0.111 j 0.12 j 0.107 j <1 3.1 0.491 j 0.323 j 0.84 - 0.44 j 0.4 j 0.14 j Nickel(ug/L) 81.2 39.1 68 843 781 853 767 M6 788 767 689 648 M4 681 M4 204 232 282 68.2 84.7 53.8 709 Nitrate(as N)(mg-N/L) NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Nitrate+Nitrite(mg-N/L) 0.096 0.03 0.029 M2 0.09 0.34 0.383 <0.02 0.257 0.187 0.02 j 0.135 0.169 <0.02 0.0049 j <0.01 0.72 0.73 0.118 <0.02 Potassium(mg/L) 10.4 12.3 11.5 <50 4.64 3.99 5.72 7.06 7.2 4.39 j 7.08 6.76 16.6 15.6 15.2 8.96 9.96 8.35 11.1 Selenium(ug/L) 4 <5 0.566 j 10.3 3.101 j 2.52 j 6.4 2.642 j 4.354 j 7.4 3.301 j 3.878 j 1.1 1.291 j 1.18 3.8 3.413 j 1.12 1.7 Silver(ug/L) NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA _ Sodium(mg/L) 178 137 153 49.9 j,M6 57 52.6 40.7 M1 47.4 45.9 34.8 54.7 53.4 57.6 54.7 55.9 39.6 41.1 38.2 171 Thallium(ug/L) <1 D3 <1 <0.2 0.36 j,D3 0.564 j 0.565 0.093 j 0.264 j 0.143 j 0.092 j 0.155 j <2 <0.1 <1 0.127 j <0.1 <1 0.09 j 0.2 Vanadium(ug/L) 0.63 <1.5 0.409 2.1 j,D3 6.68 10 9.1 10.4 9.25 2.1 SI 5.06 6.59 1.3 1.249 j 1.32 0.79 0.992 j 0.777 19 Zinc(ug/L) 7.4 j 3.5 j 5 1530 1520 1240 904 M1 1300 1250 666 1290 1150 14.9 11 15 10.6 9 7 1020 Aluminum(ug/L) 86.3j 43 15 42400 59800 51500 17600 MI 23600 24200 18600 24200 24900 <100 7 5.904j <100 16 7.366j 17900 Antimony(ug/L) <0.5 <1 <1 0.12 j <5 <I 0.12 j <5 <1 0.22 j <5 <1 <5 D3 <5 <1 0.15 j <5 <1 <0.5 Arsenic(ug/L) 0.38 1.67 1.04 7.4 6.64 6.59 3.7 2.95 j 2.88 5.1 3.097 j 3.04 0.41 j,D3 <5 <1 0.4 <5 Q 3.8 Barium(ug/L) 59 48 39 <25 D3,M1 15 14 15 18 M2 15 39.7 32 21 36.4 28 27 73.8 43 37 <10 Beryllium(ug/L) 0.026 j <1 <1 42.7 58.6 63.8 19.2 21.4 20.8 25.5 24 27.4 0.012 j <5 <1 0.046 j <5 <1 23.3 R1,M6 Boron(ug/L) <50 <100 17.79 j <250 D3 100 53 69.5 <100 102 59.2 23.303 j 96 34.5 j 39.868 j 49.366 j 25.3 j 24.216 j 25.289 j <100 M1 N "S4Zrg-. o � ZZ000 ,0oZ �r' Z, Z = o °DoZZZZZZZZZZZZZZZZZZZZZZZZZZZZZzzz `o 00 CO 0, 00 r. vN W ,p r O i a u o et v ^ v " V co v 1 N § c ', c g p 00 m o T oo a d d d a d d d d a d d d d ¢ d d d d Q d d d d d d d d N _ o, ,o cv c a O V M = ? 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Z Z Z Z Z Z ,.V" > r a a A > > > a > > > > a > S r:L f Outrall 002:1 02/18/2019 05/08/2019 01/04/2019 02/26/2019 05/13/2019 12/12/2018 02/19/2019 05/08/2019 12/12/2018 02/26/2019 05/08/2019 02/25/2016 06/28/2016 09/30/2016 11/11/2016 02/06/2017 05/22/2017 - 08/01/2017 11/08/2017 Constituent - - CPA-04S CPA-04S CPA-05D CPA-05D CPA-05D CPA-05S CPA-05S CPA-05S CPA-06S CPA-06S CPA-06S GWA-I1D GW'A-IlD GWA-11D GWA-11D GW'A-IID GWA-liD GW'A-11D GWA-11D pH(S.U.) 4.1 3.7 6.2 6.3 6.5 4.8 4.7 4.6 4.1 4.2 4.1 6.7 8.3 7.1 7.3 7.3 7.1 7.5 7.2 Water Level(ft) 24.86 24.15 76.53 24.31 26.05 28.72 23.44 25.51 16.95 15.30 15.10 NM NM NM NM NM 27.95 27.37 27.84 Temperature(Deg C) 19 23 20 19 22 18 11 27 19 19 20 19 21 24 23 19 27 25 12 Specific Conductance(tmthos/cm) 5536 5668 3285 3280 3376 3194 3283 3353 2521 2631 2466 2306 299 2903 28 282 2886 2887 2986 Dissolved Oxygen(mg/L) 0.39 0.90 2.60 0.77 0.74 0.30 0.27 0.68 0.10 0.39 0.24 3.36 1.49 0.40 0.30 0.30 0.50 0.40 0.60 Oxidation Reduction Potential(mV) 146 478 95 130 183 117 130 416 67 187 250 107 -159 -169 -186 -198 -156 -118 -161 Eh(mV) 351 683 300 335 388 322 335 621 272 392 455 312 46 36 19 7 49 87 44 Turbidity(NTUs) 5.5 2.1 9.0 3.1 5.8 2.6 0.7 1.6 2.7 3.1 5.9 7.34 0.83 7.5 6.8 9.6 9.8 8.5 3.6 Alkalinity(mg/L) <5 <5 46 63.3 72.7 <5 <5 <5 <5 <5 <5 66.8 127 112 127 120 121 121 114 Bicarbonate Alkalinity(mg/L) <5 <5 46 63.3 72.7 <5 <5 <5 <5 <5 <5 66.8 127 112 127 120 121 121 114 Methane(ug/L) NA NA NA NA NA NA NA NA NA NA NA 2.2 j <10 <10 13.4 <10 N2 <10 NA NA Sulfide(mg/L) <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.44 <0.1 0.15 MI 0.34 0.97 0.14 Total Organic Carbon(mg/L) 1.8 1.8 1.1 1.2 1.1 1.4 1.5 1.6 <1 0.355 0.358 <1 1.2 0.92 0.56 0.54 0.66 1.3 <1 Total Suspended Solids(mg/L) 6 <5 5.3 <5 <5 3.2 7 <5 <2.5 <5 <5 <5 9.1 6.4 4.8 4.3 3.8 5.8 4.5 Boron(ug/L) <1000 24.103j <50 MI,R1 <50 <50 138 143 142 106 104 136 26j <50 <50 <50 <50 <50 <50 <50 Calcium(mg/L) 468 452 542 Ml 594 M4 614 528 555 556 468 543 528 M2 410 532 554 554 546 M6 554 M6 543 529 Chloride(mg/L) 22 25 17.9 17 19 4 4.5 5.9 3.5 MI 5 6.2 19.1 21.1 21.9 22.1 21.5 21.2 18.3 20.8 Strontium(ug/L) 5680 5670 3380 MI 3460 3600 <5 7590 7790 2480 3430 3310 1800 2080 1960 2010 2140 2150 1950 2020 Sulfate(mg/L) 6600 8000 1900 M6 3000 2300 2200 2600 2200 I600 M6 3800 2900 1550 1710 1880 1740 1840 M6 1780 1670 1760 Total Dissolved Solids(mg/L) 6800 6500 3770 2800 3000 3670 3500 3500 2720 2300 2300 3240 2760 2470 2890 2660 D6 2770 2920 2890 Aluminum(ug/L) 27200 22500 432 MI 6 15 638 827 687 27600 34500 31300 200 106 144 134 160 130 108 78.4 Antimony(ug/L) <10 <1 0.61 <1 <10 0.96 <5 <1 0.19 j <1 <1 (10 <5 <0.5 <0.5 0.13 j 0.2 j 0.25 j <0.5 Arsenic(ug/L) 4.211 j 4.6 0.3 0.364 j 0.82 j 0.46 0.387 j 0.339 j 2.2 1.73 1.9 <2 1.4 1.3 1.2 1.1 1 0.94 0.8 Barium(ug/L) 15.893 j 8.278 j 60.1 51 47 40.8 35 34 21.6 23 21 66 78 71.3 68.6 66.5 63.2 55.3 53 Beryllium(ug/L) 24.6 24 <0.1 1 <10 23.5 31.1 32.9 16.4 24.1 26.6 2.1 0.15 j 0.17 0.052 j 0.067 j 0.082 j 0.098 j <0.1 Cadmium(ug/L) 4.78 j 3.67 0.089 <1 <10 6 5.26 4.43 5.2 0.753 j 0.3411 <1.6 <0.8 <0.08 0.11 <0.08 <0.08 <0.08 <0.08 Chromium(VI)(ug/L) <1.2 P4,D3,R0 <1.2 D3 <0.025 Ml <0.025 <0.025 0.1 M1,Rl,S I <0.025 <0.025 <0.025 P4,R0 <0.025 <0.025 0.076 <0.03 <0.15 <0.5 <0.12 D3 <0.12 D3 0.015 j <0.12 D3 Chromium(ug/L) 2.137 j 1.91 2.3 <1 <10 4.6 0.888 j 0.477 j 8.6 19 13.5 <10 1 j 1.3 0.94 1.8 3.2 2.2 0.4 j Cobalt(ug/L) 3090 3050 M4 9.6 8.28 8.616 j 860 969 983 584 712 M4 714 10.5 1.9 1.4 1.4 1.1 1 0.98 0.76 Copper(ug/L) 53.7 46.5 3.1 <1 0.46 j 12.6 8.6 8.07 181 1.97 1.5 45.5 5.4 1.6 5.7 4.1 7.1 5.8 0.4 j Iron(ug/L) 1040000 1040000 930 Ml 1050 4380 607 494 348 17400 27000 29700 270 1990 1690 2110 2090 2570 2240 2570 Lead(ug/L) 2.604 j 1.76 0.11 <1 <10 0.15 <5 <1 0.54 0.343 j 1 <2 <1 <1 <0.1 <0.1 <1 <0.1 <0.1 Lithium(ug/L) 59.507 j 41.508 j 8.6 8 7 38.9 49 47 172 240 224 NA NA NA NA NA NA NA NA Magnesium(mg/L) 300 294 184 M1 193 M4 198 183 212 209 51 76.3 72.3 M2 104 126 130 130 132 M6 132 M6 133 127 Manganese(ug/L) 106000 99700 1050 1750 2450 <5 112000 111000 16800 18800 20000 81 1840 1150 1740 1400 1370 1140 1210 Mercury(ug/L) <0.05 <0.05 <0.2 <0.05 <0.05 <0.2 <0.05 <0.05 <0.2 0.017 j <0.05 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 Molybdenum(ug/L) 0.095 j <1 4.5 2.09 2.28 j 0.39 j 0.247 j 0.157 j 0.2 j 0.097 j <1 3.4 j 1.9 j 0.55 1.5 1 1.8 1.6 1.1 Nickel(ug/L) 728 737 M4 23.8 16.3 4.207 j 730 819 843 583 698 677 <10 <5 0.66 0.94 1.3 3 1.7 <0.5 Nitrate(as N)(mg-N/L) NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA - Nitrate+Nitrite(mg-N/L) 2.2 2.2 1.1 0.58 0.074 0.06 0.048 0.021 <0.02 0.046 0.06 M2 0.066 <0.02 <0.02 <0.02 <0.02 <0.02 0.014 j 0.014 j Potassium(mg/L) 16.2 15.6 12.6 Ml 13.3 17.3 8.05 8.52 8.74 4.46 j 5.31 5 9.53 12.6 12.2 12.6 12.2 12.4 12.7 12 Selenium(ug/L) 1.105 j 1.01 9.2 4.55 0.598 j 19.7 15.9 11.4 3.1 0.414 j <I 6.5 j <5 0.4 j 0.48 j <0.5 M1 <0.5 <0.5 0.18 j,B Silver(ug/L) NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Sodium(mg/L) 196 192 117 M1 82.2 M4 77.4 49 54.4 54.9 17.8 20.8 19.1 31.8 36.9 38.6 44.7 48 47.9 51.2 54.2 Thallium(ug/L) 0.142 j 0.204 <0.1 <0.2 <2 <0.1 <1 0.096 j 0.044 j <0.2 <0.2 1 j <1 <1 <0.1 <0.1 0.34 j <0.1 <0.1 Vanadium(ug/L) 31.3 14.8 1.9 BC 0.88 <3 0.62 0.661 j 0.473 4 10.6 10.8 <10 <3 0.74 0.24 j 0.19 j 0.26 j,B 0.31 B 0.12 j 1 Zinc(ug/L) 2010 1870 5.7j <5 2.386 j 363 396 340 808 881 831 25 <10 27.8 8.7 j 9.6 j 6.9 j 60.1 27.5 Aluminum(ug/L) 23700 22000 161 2.09 j 4.411 j 721 777 732 25700 32800 29800 54 j 71.3 j 77.9 j 101 116 109 j,D3 63.4 j <100 Antimony(ug/L) <10 <1 0.87 <1 <1 <5 D3 <5 <1 <5 D3 <1 <1 <10 <5 <0.5 <0.5 <0.5 <0.5 0.11 j <0.5 Arsenic(ug/L) 4.111 j 4.31 0.51 BC 0.509 j 0.493 j 0.6 j,D3 <5 0.372 j 2 1.83 1.8I <2 1.2 1.4 1 1.5 1.1 0.77 0.74 Barium(ug/L) 14.116 j 9.758 j 55.8 55 42 34.3 34 33 19.5 23 18 65 73.1 72 63.3 62.6 64.1 49.3 42.4 Beryllium(ug/L) 25.9 24.1 <0 1 <1 <1 29 34.2 33.5 20.1 22.9 23.6 1.3 j <1 0.12 0.053 j 0.042 j 0.046 j 0.058 j <0.1 Boron(ug/L) <1000 <1000 <50 <50 <50 125 134 144 98.7 104 134 <50 <50 <50 <50 <50 <100 D3 <50 <50 b c C 84 C C C C -3 y g a c C c c c 'c N o �, �' r o 0 o a o ?• 3 N E. 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FT O `/' O J OUTFALL 102 OUTFALL 102 Constituent 4292014 5/1/2015 7/6/2015 7/7/2015 11/13/2015 12/16/2015 2/17/2016 2/222016 2/242016 229/2016 Alkalinip(mg"L(CCaC0311 35 Alkalinity(mg/L) 592 39.7 ` Alkalinity,Carbonate(CaCO3)(mg/L) <5 <5 Alkalinity,Bicarbonate(CaCO3)(mg/L) 59.2 39.7 Aluminum(Al)(mg/L) 0.034 0.0a 5 <0.1 _ Aluminum(Al)(ug/L) <100 Aluminum,Dissolved(mg/L) <0.1 Ambient Mercury(ng/L) "0 Antimony(Sb)(ug/L) I -I <0.5 0 Antimony,Dissolved(ug/L) <0.5 _ Arsenic(As)(ug/L) <I <I 0.121 _ <0.5 <I <I <I i Arsenic,Dissolved(ug/L) 0.121 _ <I <I <I Barium(Ba)(mg/L) 0.039 0.043 0.03 0.0256 0.037 0.036 0.034 no;I Barium,Dissolved(mg/L) 0.03 0.035 0.036 0.031 Beryllium(Be)(ug/L) <0.2 Beryllium,Dissolved(ug/L) <0.2 Boron(B)(mg/L) 0.3`I 0.438 0.48 0.188 _ 0.201 Boron,Dissolved(mg/L) 0.5 0.203 Bromide(mg/L) 0.116 Cadmium(Cd)(ug/L) I <I <0.08 •0.08 <1 <0.1 <0.1 <I Cadmium(Cd)Low Level(ug/L) _ <0.1 Cadmium,Dissolved(ug/L) <0.08 <I <0.1 <0.1 Calcium(Ca)(mg/L) 40.9 37.3 43 _ 25 32.9 36.4 22.8 30.8 Calcium,Dissolved(mg/L) 32.8 36.3 22.7 Chloride(mg/L) .-- 5.613 6.8 3a 4.9 5.4 3.6 4.9 Chromium(Cr)(ug/L) -I I 0.53 .0.• <I <I <1 I Chromium,Dissolved(ug/L) 0.31 <1 <I <1 Chromium,Hexavalent(ug/L) Cobalt(Co)(ug/L) 1.4 _ , Cobalt,Dissolved(ug/L) 0.89 COD(mg/L) <20 -20 Copper(Cu)(ug/L) <I --1 0.571 I 1.09 <I 1.75 100 Copper,Dissolved(ug/L) 0.551 1.22 3.64 3.17 Flow(cfs) 0.00818 NR NR \1t '0 NO ,NR NR NR Fluoride(mg/L) <I <0.1 0.1 <0.1 <0.1 <0.1 <0.1 Hardness(mg/L(CaCO3)) 131 123 109 `120 76.3 J 99.1 Iron(Fe)(mg/L) 0.078 0.228 0.09 0.091 1 1.03 0.213 0.878 0.14 Iron,Dissolved(mg/L) 0.0371 0.754 0.065 0.335 Lead(Pb)(ug/L) <I <I <0.1 <0.1 ,<I <1 <I <I Lead,Dissolved(ug/L) <0.1 _ - Magnesium(Mg)(mg/L) 7.09 7.35 7.93 4.59 6A7 7 4.72 5.76 Manganese(Mn)(mg/L) 0.597 0.934 0.3 0.696 0.972 0.709 1.1 0.79 Manganese,Dissolved(mg/L) 0.28 Mercury(Hg)(ng/I.) <50 0.668 <200 0.507 0.773 uS 0.967 0.89 +2.76 Mercury(ng/L) 1.72 Mercury Average(ng/L) Mercury,Dissolved(ng/L) <200 , Methane(ug/L) 14.9 Molybdenum(Mo)(ug/L) <I <I 0.12J _0.5 • A - OUTFALL 102 _ , Cooatitaent 4292014 5/1/2015 7/62015 7)7/2015 11/132015 12/16/2015 2/17/2016 2/22/2016 2/24/2016 2/29/2016 Molybdenum,Dissolved(ug/L) 0.161 Nickel(Ni)(ug/L) -I 1.31 0.82 11.85 1.2 <I 1.18 <I Nickel,Dissolved(ug/L) 011 Nitrate(mg/L) 1.9 1.5 1.9 1.8 Nitrate as N(mg-N/L) 0.42 0.34 0.42 0.4 Nitrite+Nitrate(Colarimetric)(mg-N/L) 0.287 Nitrogen,Nitrate(mg/L) Nitrogen,NO2 plus NO3(mg/L) 0.31 0.89 Oil and Grease(mg/L) <5 <5 <5 <5 <5 = pH(Std.Units) 6.76 6.11 6.99 7.2 l 6.9 6.6 6.i Phosphorus(P)(mg/L) <0.02 Potassium(K)(mg/L) 5.18 <5 _ Selenium(Se)(ug/L) <I <I <0.5 <0.5 <I `I <I I Selenium,Dissolved(ug/L) <0.5 Sodium(Na)(mg/L) 5.85 <5 Specific Conductance O 296 - Specific Conductance(umhoslcm) , Specific Conductance(uS/cm) 292 0 2I 1 252 284 459 i,16 Strontium(Sr)(mg/L) 0.28 Strontium,Dissolved(mg/L) 0.28 _ Sulfate(mg/L) 76 85.94 89.3 40S 65 72 44 57 Sulfide(mg/L) <0.1 TDS(mg/L) 190 180 195 160 160 200 130 150 Temperature O 16.8 Temperature(°C) 14.6 16.I 12.5 15.2 14.9 18.I Temperature(deg C) Thallium(TI)Low Level(ug/L) .II 2 <0.2 <0.1 0-I Thallium,Dissolved(ug/L) <0.1 TOC(mg/L) 0.681 Total Kjeldahl Nitrogen(Colorimetric)(mg-N/L) <0.15 TSS(mg/L) 26 <5 <2.5 <5 - . Turbidity(NTU) I Vanadium(V)(ug/L) <I 0331 Vanadium,Dissolved(ug/L) 0.31 Zinc(Zn)(mg/L) <0.005 0.006 <0.01 ..p01 <0.005 <0.005 <0.005 O.Oiii Zinc,Dissolved(mg/L) 0.00411 <0.005 0.006 0.005 OUTFALL 102 Constituent 4/19/2016 5/11/2016 627/2016 10/182016 12/92016 1/16/2017 2/1/2017 3/62017 4/11/2017 Alkalinity(mg/L(CaCO3)) Alkalinity(mg/L) 61 57.7 58 Alkalinity,Carbonate(CaCO3)(mg/L) <10 <5 <10 Alkalinity,Bicarbonate(CnCO3)(mg/L) 61 57.7 58 Aluminum(Al)(mg/L) 0.382 0.237 0.028 Aluminum(Al)(ug/L) l Aluminum,Dissolved(mg/L) <0.1 _ _ Ambient Mercury(ng/L) Antimony(Sb)(ug/L) <I <0.5 <I Antimony,Dissolved(ug/L) <5 . Arsenic(As)(ug/L) <0.1 <I 0.32 <I ....I I <I I <I Arsenic,Dissolved(ug/L) <I Barium(Be)(mg/L) 0.0289 0.046 0.0305 0.032 1uC9 will; 0.035 0 03x 0.03 Barium,Dissolved(mp/L) 0.0278 Beryllium(Be)(ag/L) <0.1 Beryllium,Dissolved(ug/L) <I Boron(B)(mg/L) 05I 9 0.524 0.47 Boron,Dissolved(mg/L) 0.562 Bromide(mg/L) Cadmium(Cd)(ug/L) <0.08 -.I <0.08 <I -I I <I <I 1 Cadmium(Cd)Low Level(ug/L) _ _ Cadmium,Dissolved(ug/L) <0.8 Calcium(Ca)(mg/L) 39.2 40.7 47.2 40.7 14 33.7 42.6 3,.I Calcium,Dissolved(mg/L) Chloride(mg/L) 6 4 7.3 6.6 5.6 -t.y 7 4 4.7 5.9 4.8 Chromium(Cr)(ug/L) .0.5 .I 0.411 <I I -I <1 <1 `1 Chromium,Dissolved(ug/L) 4.81 Chromium,Hexavalent(ug/L) <0.6 Cobalt(Co)(ug/L) 5 Cobalt,Dissolved(ug/L) 1.2 COD(mg/L) Copper(Cu)(ug/L) n 3 7.I 1.3 <I <I 14 <1 <I <I Copper,Dissolved(ug/L) 1.51 Flow(cfs) NR 0.016 0.001 0.001166 0.00132 0.00044 0.00044 0.0055 Fluoride(mg/L) <0.1 0 12 <0.1 _<0.1 <0.1 <0.1 <0.1 <0.1 Hardness(mg/L(CaCO3)) 125 130 121 113 109 140 108 Iron(Fe)(mg/L) 0.0799 1.15 0.67 0.084 0.028 0.373 0.534 0.151 0.105 Iron,Dissolved(mg/L) <0.05 Lead(Pb)(ug/L) <0.1 <I 0.17 <I I :1 <I <I <I Lead,Dissolved(ug/L) <I Magnesium(Mg)(mg/L) 6.72 7.37 7.98 6.83 11' 0., 6.06 8.08 6.17 Manganese(Mn)(mg/L) 0.503 1.17 0.567 0.636 a 000 11_ 0.989 1.05 0.975 Manganese,Dissolved(mg/L) 0.364 - Mercury(Hg)(ng/L) 0.% 1.79 3.15 <0.5 i 0 tt'o 1.24 1.08 1.1 1.17 Mercury(ng/L) _ I Mercury Average(ng/L) Mercury,Dissolved(ng/L) Methane(ug/L) 36.5 Molybdenum(Mo)(ug/L) <I 0.211 <I _ OUTFALL 102 Constituent 4/192016 S/11/2016 6/27/2016 10/182016 12/9/2016 1/162017 2/1/2017 3/6/2017 4/11/2017 - Molybdenum.Dissolved(ng/L) <5 Nickel(Ni)(ug/L) 0.88 1.4 0.98 1.5> 1.24 1.93 I.I q 1.16 1.22 Nickel,Dissolved(ug/L) <5 Nitrate(mg/L) 6.5 ,4.1 1 '8 3.3 Nitrate as N(mg-N/L) Nitrite+Nitrate(Colorimetric)(mg-N/L) 0.32 1 Nitrogen,Nitrate(mg/L) 0.25 - Nitrogen,NO2 plus NO3(mg/L) 0.23 Oil and Grease(mg/L) <5 <5 <5 - <5 <5 <5 pH(Std.Units) 7 6.9 7.2 - 6.5 7 7.2 6.7 Phosphorus(P)(mg/L) Potassium(K)(mg/L) 6.77 5.8 5.25 Selenium(Se)(ug/L) <0.5 <1 <0.5 <I I <I I I <l Selenium,Dissolved(ug/L) 6 Sodium(Na)(mg/L) 5.71 6.51 4.94 Specific Conductance 0 Specific Conductance(umhos/cm) 277 270.2 251.5 120.9 244.1 li Specific Conductance(uS/cm) 66.7 1111 305 Strontium(Sr)(mg/L) 0.28 Strontium,Dissolved(mg/L) 0.293 Sulfate(mg/L) 83.4 84 83.2 77 61 68 64 78 59 Sulfide(mg/L) <0.1 _ TDS(mg/L) 219 200 171 190 170 170 180 1,0 170 Temperature 0 Temperature("C) 22 21 22.8 Temperature(deg C) 10.4 _12.1 13 11 6 17.6 Thallium(TI)Low Level(ug/L) <0.2 0.0261 <0.2 Thallium,Dissolved(ug/L) <I TOC(mg/L) 0.951 Total Kjeldahl Nitrogen(Colorimetric)(mg-N/L) TSS(mg/L) <2.5 ,17 18.7 <5 <5 - - Turbidity(NTU) 1.87 2.44i, Vanadium(V)(ug/L) 12 Vanadium,Dissolved(ug/L) 0.741 Zinc(Zn)(mg/L) <0.0I 0.00' <0.01 0.007 <0.005 I)r11 0 on, I)0116 <0.005 Zinc,Dissolved(mg/L) 0.00491 �'. Ol7 FALL 11)2 Constituent 6/82017 7/122017 822017 9/52017 9/182017 10/4/2017 11/62017 12/112017 4/2/2018 2/5/2019 4/302019 7/112019 Alkalinit)(mg 1_(CIC03)) Alkalinity(mg/L) , Alkalinity,Carbonate(CaCO3)(mg/L) A lkal in ity,Bicarbonate(CaCO3)(mg/L) _ Aluminum(Al)(mg/L) Aluminum(Al)(ug/L) Aluminum,Dissolved(mg/L) Ambient Mercury(ng/L) Antimony(Sb)(uglL) _ Antimony,Dissolved(ug/L) , Arsenic(As)(ug/L) .,1 <1 <1 <1 <1 <1 <I .1 -1 •i I Arsenic,Dissolved(ug/L) Barium(Ba)(mg/L) 0 021 <0.025 0.021 0.019 0.O 18 0.02 0.022 0.016 o 02_I I)02 a 112 Barium,Dissolved(mg/L) ' Beryllium(Be)(ug/L) I _ Beryllium,Dissolved(ug/L) Boron(B)(mg/L) 0.05 Boron,Dissolved(mg/L) Bromide(mg/L) Cadmium(Cd)(ug/L) -I i I •I <I t I <I <I -I <I -I •I Cadmium(Cd)Low Level(ug/L) Cadmium,Dissolved(ug/L) _ Calcium(Ca)(mg/L) 25 9 30 4 15 4 28.7 _ 36.4 24.5 29.5 29.6 36.6 Calcium,Dissolved(mg/L) Chloride(mg/L) 13 3.8 4.8 3 y 4.5 4 2.8 2.5 2 5 _. Chromium(Cr)(ug/L) •I •I •I <I ..I 1 <I -I I -I I Chromium,Dissolved(ug/L) Chromium,Hexavalent(ug/L) Cobalt(Co)(ug/L) Cobalt,Dissolved(ug/L) , COD(mg/L) Copper(Cu)(ug/L) 1.1 2 <I <I <I <I .:1 <I <I <I <I -I 1 Copper,Dissolved(ug/L) , Flow(cfs) 0.0011 0.000588577779 0.0002942888895 0.0047 0.001 0.0012 ,0.0005 0.00058 0.001177155558 0.0002943 0.0004 Fluoride(mg/1.) <0.1 0.11 <0.1 0.1 <0.1 0.1 <0.1 <0.1 <0.) <0.1 -0.I Hardness(mg/L(CaCO3)) 82.6 97.1 126 91.5 120 120 121 81.2 94.3 93.5 115 Iron(Fe)(mg/L) 0.037 0.023 0.053 0.049 0.093 0.233 0.081 0.061 `0.06 0.025 0.062 Iran,Dissolved(mg/L) _ _ Lead(Pb)(ug/L) <I <I <I <1 ,.1 <1 <I <I '<1 <I <I Lead,Dissolved(ug/L) _ ` Magnesium(Mg)(mg/L) 4.35 5.12 6.63 4.79 6.3 6.51 7.23 4.87 5.01 4.73 5.66 Manganese(Mn)(mg/L) 0327 0.151 0.41 0.158 0.174 0.171 0.291 0.135 0.055 0.067 0.194 Manganese,Dissolved(mg/L) - _ _ Mercury(Hg)(ng/L) 0.671 0.641 <0.5 <0.5 <0.5 0.641 <0.5 0.536 <0.5 0.538 Mercury(ng/L) 1.12 Mercury Average(ng/L) <0.5 Mercury,Dissolved(ng/L) Methane(ug/L) Molybdenum(Mo)(ug/L) OUTFALL 102 Contitant 6/8/2017 7/12/2017 8/2/2017 9/5/2017 9/182017 - . ._ 10/4/2017 z�c. 11/62017 12/11/2017 4/2/2018 2/5/2019 4/30/2019 7/11/2019 Molybdenum,Dissolved(ug/L) _ _ _ Nickel(Ni)(ug/L) <I <I ..1 <I <I <I <I <I <I <1 Nickel,Dissolved(ug/L) Nitrate(mg/L) 3.8 4.1 I 4.7 2.5 2.9 2 8 2.2 1.1 13 1.1 Nitrate as N(mg-N/L) 019 0.24 Nitrite+Nitrate(Colorimetric)(mg-N/L) Nitrogen,Nitrate(mg/L) Nitrogen,NO2 plus NO3(mg/L) Oil and Grease(mg/L) <5 <5 <5 = <5 <5 <5 <5 <5 <5 pH(Std.Units) 6.4 7.2 7_ 7 = 73 73 6.9 7.3 7.5 7.3 Phosphorus(P)(mg/L) Potassium(K)(mg/L) Selenium(Se)(ug/L) <I <I <I <I <I <I <I <I <I Selenium,Dissolved(ug/L) Sodium(Na)(mg/L) Specific Conductance)) ~ Specific Conductance(umhos/cm) 221.7 229.7 162 220 2-8.! 282.2 271.7 292 208 411.4 258.9 Specific Conductance(uS/cm) _ Strontium(Sr)(mg/L) Strontium,Dissolved(mg/L) Sulfate(mg/L) 41 50 '4 41 63 59 56 40 38 35 44 Sulfide(mg/L) TDS(mg/L) 100 110 190 120 180 170 160 00 140 130 169 Temperature U Temperature(°C) Temperature(deg C) 22.2 26.8 25 6 _15 199 19.8 8.8 18.1 14.5 24.3 25.9 Thallium(TI)Low Level(ug/L) Thallium,Dissolved(ug/L) TOC(mg/L) Total Kjeldahl Nitrogen(Colorimetric)(mg-N/L) TSS(mg/L) <5 <5 _ _ 9 <._5 _ <5 Turbidity(NTU) Vanadium(V)(ug/L) Vanadium,Dissolved(ug/L) Zinc(Zn)(mg/L) <0.005 <0.005 <0.005 <0.005 -.11.M05 <0.005 .0.005 <0.005 -61.905 a9.005 <0 005 Zinc,Dissolved(mg/L) 1t, OUTFALL 107 OUTFALL 107 Constituent 4/29/2014 , c/1/201 ` 7/3/2015 11/13/2015 12/16,2015 2/17/2016 2/22'2016 2/24/2016 4/19/2016 5/11/2016 6/27/2016 Alkalinity(mg/L(CaCO3)) <20 Alkalinity(mg/L) 22.4 12.7 24 23.1 Alkalinity,Carbonate(CaCO3)(mg/L) <5 <5 <10 <5 Alkalinity,Bicarbonate(CaCO3)(mg/L) 22.4 12.7 24 23.1 Aluminum(Al)(mg/L) 0.I w i i I a; 2.7 0.461 0.422 , Aluminum(Al)(ug/L) <100 i Aluminum,Dissolved(mg/L) <0.1 <0.1 Antimony(Sb)(ug/L) <I I <0.5 <0.5 <1 <0.5 Antimony,Dissolved(ug/L) <0.5 <0.5 Arsenic(As)(ug/L) <1 <1 0.38J <0.5 <1 <1 <I 0.1 <1 0.088J Arsenic,Dissolved(ug/L) <0.5 <I <1 <1 <0.1 Barium(Ba)(mg/L) 0.024 0.024 0.1 0.0282 0.022 0.023 0.023 0 019 0.025 0.0181 Barium,Dissolved(mg/L) 0.011 0.017 0.018 0.017 0.0115 Beryllium(Be)(ug/L) 0.1J 0.036J Beryllium,Dissolved(ug/L) <0.2 0.026J Boron(B)(mg/L) 0.082 0.057 0.06 0.0607 0.051 005; 0.0458J Boron,Dissolved(mg/L) 0.055 <0.05 0.0479J Bromide(mg/L) <0.1 Cadmium(Cd)(ug/L) <1 <1 <0.08 •0.06 <1 <0.1 <0.1 a 06 I <0.08 Cadmium,Dissolved(ug/L) <0.08 <1 <0.1 <0.1 <0.08 Calcium(Ca)(mg/L) 3.76 3.49 3.42 2.97 1.92 1.97 1.73 I-96 25 2.51 Calcium,Dissolved(mg/L) 1.78 1.89 1.68 Chloride(mg/L) 5.2 i- 86 6.1 4.4 4.7 4.7 4.1 6.1 5.9 • Chromium(Cr)(ug/L) <1 I 10.4 1.3 1.98 2.33 2.46 I 2.32 3.4 Chromium,Dissolved(ug/L) 0.6 1.34 2.1 1.37 1 Chromium,Hexavalent(ug/L) 0.55J Cobalt(Co)(ug/L) I 1 7 2.2 Cobalt,Dissolved(ug/L) 0.261 0.16 COD(mg/L) <20 0 Copper(Cu)(ug/L) <1 I 2.9 <1 <1 <1 I . 0.5 I 0.74 Copper,Dissolved(ug/L) 0.541 8.4 5.44 829 0.57 Date(s)0 Flow(cfs) 0.05137 NR NNI: 0.76 A'R NR NR NR NR 0.044 Fluoride(mg/L) <1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 Hardness(mg/L(CaCO3)) 26.1 28.4 18.2 18.6 14.8 20.5 Iron(Fe)(mg/L) 0.88 1.32 19.2 0 244 0.521 0.566 `1.09 0.432 122 1.47 Iron,Dissolved(mg/L) <0.05 0.045 0.039 0.09 <0.05 Lead(Pb)(ug/L) <1 I 1.1 0 I <1 <1 <1 o.I I 0.26 Lead,Dissolved(ug/L) <0.1 <0.1 Magnesium(Mg)(mg/L) 4.05 4.79 5.98 4.16 3.24 3.32 2.53 2 s 5.78 Manganese(Mn)(mg/L) 0.345 0.54 2.3 0.126 0.059 0.077 0.087 0.1 13 0.248 0.166 Manganese,Dissolved(mg/L) 0.098 0.0469 Mercury(Hg)(ng/L) <50 0.568 1.14 0.642 . 0: I.08 0.812 2.42 I I s 3.34 3.14 Mercury(ng/L) Mercury Average(ng/L) - - OUTFALL 107 Constituent 4/29/2014 5/1/2015 , 7/3/2015 11/13/2015 12/16/2015 2/17/2016 2/22/201 ' /24/2016 4/19/2016 5/11/2016 6/27/2016 Methane(ug/L) 1.5J <10 Molybdenum(Mo)(ug/L) <1 1 <0.5 <0.5 I <0.5 Molybdenum,Dissolved(ug/L) 0.099J <0.5 Nickel(Ni)(ug/L) 2.07 2.57 10.5 2.2 2.3 I 2.24 2.59 3 3 4.38 3.5 Nickel,Dissolved(ug/L) 1.4 1.1 Nitrate(mg/L) <0.1 <0.1 <0.1 Nitrate as N(mg-N/L) <0.023 <0.023 <0.023 Nitrite+Nitrate(Colorimetric)(mg-N/L) <0.01 0 02 Nitrogen,Nitrate(mg/L) <0.02 Nitrogen,NO2 plus NO3(mg/L) 0.012 I 0.024 4 0.0 39 Oil and Grease(mg/L) <5 <5 <5 ,s <5 <5 <, pH(Std.Units) 6.62 6.55 6.76 6.2 6.5 7 6.9 7.;I Phosphorus(P)(mg/L) <0.02 Potassium(K)(mg/L) <5 <5 0.283 <5 Selenium(Se)(ug/L) <1 I <0.5 <0.5 <1 . I <I <0.5 <1 <0.5 Selenium,Dissolved(ug/L) <0.5 <0.5 Sodium(Na)(mg/L) <5 . 5 2.82 2.72J Specific Conductance 0 70 Specific Conductance(umhos/cm) Specific Conductance(uS/cm) 72 0.077 51.8 55.2 99.5 68.3 7_2 7 Strontium(Sr)(mg/L) 0.028 0.0175 Strontium,Dissolved(mg/L) 0.02 0.0172 Sulfate(mg/L) 3.t 1 358 1.4 8 I 3.9 3.6 4 I 1.5 1.7 1.2 Sulfide(mg/L) <0.1 <0.1 TDS(mg/L) 51 56 29 6s 58 54 52 64 56 38 Temperature 0 15 71 Temperature(°C) 13.3 13.1 10.2 1 2.8 16.5 17.1 16 Temperature(deg C) Thallium(TI)Low Level(ug/L) 0? <0.2 0.023J 0.I 0' <0.1 Thallium,Dissolved(ug/L) <0.1 <0.1 TOC(mg/L) 0.64J 11 Total Kjeldahl Nitrogen(Colorimetric)(mg-N/L) <0.15 TSS(mg/L) 7 <5 146 <2.5 5 5 14 7.3 67 2 3.3 Turbidity(NTU) 25 5 84 Vanadium(V)(ug/L) - I 62 1.6 Vanadium,Dissolved(ug/L) 0.41J 0.16J Zinc(Zn)(mg/L) 0.005 <0.005 0.022 0.01 <0.005 <0.005 <0.005 '0.01 <_0(1(15 0.0031J Zinc,Dissolved(mg/L) <0.01 0.014 0.011 0.013 0.0029J OUTFALL 107 Constituent 5/4/2017 6/8/2017 7/12/2017 8/2/2017 9/5/2017 10/4/2017 11/6/2017 4/2/2018 2/6/2019 4/30/2019 7/11/2019 Alkalinity(mg/L(CaCO3)) Alkalinity(mg/L) Alkalinity,Carbonate(CaCO3)(mg/L) Alkalinity,Bicarbonate(CaCO3)(mg/L) Aluminum(Al)(mg/L) Aluminum(Al)(ug/L) Aluminum,Dissolved(mg/L) Antimony(Sb)(ug/L) Antimony,Dissolved(ug/L) Arsenic(As)(ug/L) <I <1 <1 <1 <1 <1 <1 <I <1 <1 <I Arsenic,Dissolved(ug/L) Barium(Ba)(mg/L) 0.023 0.03 0.018 0.015 0.018 0.013 0.016 0.029 0.031 0.037 0.046 Barium,Dissolved(mg/L) Beryllium(Be)(ug/L) Beryllium,Dissolved(ug/L) Boron(B)(mg/L) 0.055 Boron,Dissolved(mg/L) Bromide(mg/L) Cadmium(Cd)(ug/L) <1 <I <1 <I <1 <1 <1 <1 <1 <1 <I Cadmium,Dissolved(ug/L) Calcium(Ca)(mg/L) 2.72 2.8 2.55 2.34 2.54 2.58 2.86 2.18 2.31 3.6 4.36 Calcium,Dissolved(mg/L) Chloride(mg/L) 5.1 4.7 5.5 5.3 5.4 5.5 5.5 4.5 3.3 5.2 5.1 Chromium(Cr)(ug/L) 2.52 1.66 1.62 2.03 1.33 1.25 <1 2.84 1.64 1.53 1.35 Chromium,Dissolved(ug/L) Chromium,Hexavalent(ug/L) Cobalt(Co)(ug/L) Cobalt,Dissolved(ug/L) COD(mg/L) Copper(Cu)(ug/L) <1 <1 2.98 <1 <1 <I <1 <1 <I <1 <1 Copper,Dissolved(ug/L) Date(s)() 43192 Flow(cfs) 0.0033 0.0044 0.0002942888895 0.002942888895 0.0012 0.00056 0.0009 0.0035 0.00044143333425 0.02354 0.0047 Fluoride(mg/L) <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 Hardness(mg/L(CaCO3)) 26.8 25.5 27.6 26.9 27.7 28.8 30.4 23.8 15.2 22.2 30.1 Iron(Fe)(mg/L) 0.642 0.725 0.446 0.761 0.468 0.45 0.299 0.864 1.04 0.621 1.75 Iron,Dissolved(mg/L) Lead(Pb)(ug/L) <I <1 <1 <I <1 <1 <1 <1 <1 <1 <1 Lead,Dissolved(ug/L) Magnesium(Mg)(mg/L) 4.86 4.5 5.16 5.1 5.2 5.42 5.64 4.46 2.29 3.2 4.66 Manganese(Mn)(mg/L) 0.167 0.237 0.15 0.121 0.147 0.072 0.1 0.173 0.073 0.14 0.97 Manganese,Dissolved(mg/L) Mercury(Hg)(ng/L) 0.805 1.56 0.694 1.12 0.807 0.609 1.01 2.45 1.82 1.76 Mercury(ng/L) 1.41 Mercury Average(ng/L) 1.12 0.555 1.05 1.38 2.43 1.81 1.75 OUTFALL 107 _ Constituent 5/4/2017 6/8/2017 7/12/2017 8/2/2017 9/5/2017 10/4/2017 11/6/2017 4/2/2018 2/6/2019 4/30/2019 7/11/2019 Methane(ug/L) Molybdenum(Mo)(ug/L) Molybdenum,Dissolved(ug/L) Nickel(Ni)(ug/L) 3.31 3.74 2.5 1.79 1.99 1.42 1.53 3.57 2.12 2.08 4.37 Nickel,Dissolved(ug/L) Nitrate(mg/L) 0.19 <0.1 0.22 0.36 0.17 <0.1 <0.1 0.15 0.51 0.43 0.25 Nitrate as N(mg-NIL) 0.1 0.06 Nitrite+Nitrate(Colorimetric)(mg-N/L) Nitrogen,Nitrate(mg/L) Nitrogen,NO2 plus NO3(mg/L) Oil and Grease(mg/L) <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 pH(Std.Units) 6.7 6.6 7.3 7.4 7.2 7.6 7 6.7 6.3 6.3 6.8 Phosphorus(P)(mg/L) Potassium(K)(mg/L) Selenium(Se)(ug/L) <I <I <1 <1 <1 <1 <1 <1 <1 <1 <I Selenium,Dissolved(ug/L) Sodium(Na)(mg/L) Specific Conductance 0 Specific Conductance(umhos/cm) 70.4 66.4 70.1 70.9 70.4 73.8 83.9 61.8 49.9 82.9 _82.2 Specific Conductance(uS/cm) Strontium(Sr)(mg/L) Strontium,Dissolved(mg/L) Sulfate(mg/L) 4.3 5.5 2.3 1.2 2.7 1.7 2.7 4.6 5.8 4.8 2.4 Sulfide(mg/L) TDS(mg/L) 75 53 45 53 41 53 41 38 51 52 70 Temperature 0 Temperature(°C) Temperature(deg C) 16.8 17.6 23.3 20.9 20.4 16 19.3 14.9 11.7 17.2 22.1 Thallium(TI)Low Level(ug/L) Thallium,Dissolved(ug/L) TOC(mg/L) Total Kjeldahl Nitrogen(Colorimetric)(mg-N/L) TSS(mg/L) 7 7 <5 10 <5 10 <5 8 6 5.8 11 Turbidity(NTU) Vanadium(V)(ug/L) Vanadium,Dissolved(ug/L) Zinc(Zn)(mg/L) <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 Zinc,Dissolved(mg/L) 4 OUTFALL 108 OUTFALL 108 Constituent 4/29/2014 5/1/20I5 7/3/2015 1 I/13/2015 12/l 6/2015 2/18/2014 2/22/2016 2/24/2016 4/19/2016 5/11/2016 Alkalinity(mg/L(CaCO3)) 20 _ Alkalinity(mg/L) 43.1 25.4 47 Alkalinity,Carbonate(CaCO3) <5 <5 <10 (mg/L) _ . Alkalinity,Bicarbonate(CaCO3) 43.1 25.4 47 (m8/L) - Aluminum(Al)(mg/L) 0:no 0 541 0.11 0.459 Aluminum(Al)(ug/L) 282 Aluminum,Dissolved(mg/L) <0.1 Antimony(Sb)(ug/L) <1 I <0.5 <0.5 <1 Antimony,Dissolved(ug/L) <0.5 Arsenic(As)(ug/L) <1 <1 0.21J <0.5 <1 <1 <I 0.26 <1 Arsenic,Dissolved(ug/L) ! 0.12J <1 <1 <1 Barium(Ba)(mg/L) 0.019 0.021 0.018 0.0223 0.018 0.017 0.021 0.0161 0.028 Barium,Dissolved(mg/L) 0.017 0.014 0.015 0.015 Beryllium(Be)(ug/L) <0.2 Beryllium,Dissolved(ug/L) <0.2 Boron(B)(mg/L) <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 Boron,Dissolved(mg/L) <0.05 <0.05 Bromide(mg/L) <0.1 Cadmium(Cd)(ug/L) <1 <1 <0.08 <0.08 <1 <0.1 <0.1 0.08 <1 Cadmium,Dissolved(ug/L) <0.08 <1 <0.1 <0.1 Calcium(Ca)(mg/L) ,-19 7.22 8.52 rr.03 5 5.6 3.83 6.6 9.22 Calcium,Dissolved(mg/L) 4.91 5.72 3.68 Chloride(mg/L) 2.7 2.042 1.3 2.3 2.2 2.2 2.2 I 1.8 Chromium(Cr)(ug/L) I <1 0.33J <0.5 1.05 <1 1.05 0.5 <1 Chromium,Dissolved(ug/L) 0.63 <1 <1 <1 Chromium,Hexavalent(ug/L) Cobalt(Co)(ug/L) 0.28J Cobalt,Dissolved(ug/L) <0.5 COD(mg/L) <20 20 Copper(Cu)(ug/L) <1 I 0.8J I ; 1.32 <1 1.66 1.1 <1 Copper,Dissolved(ug/L) 0.9J 9.98 4.64 8.31 Flow(cfs) 0.0379 NR NR 1IZ NR NR NR NR 0.131 Fluoride(mg/L) <1 <0.1 0 I <0.1 <0.1 <0.1 <0.1 <0.1 Hardness(mg/L(CaCO3)) 29.3 28.4 19.9 21.8 15.4 24.9 Iron(Fe)(mg/L) 2.15 3.04 1.4 2O0 2.66 2.14 3 2.73 3.92 Iron,Dissolved(mg/L) 0.071 0.622 0.516 0.616 Lead(Pb)(ug/L) <1 <1 0.15 0.19 1.13 <1 <1 0.1 <1 Lead,Dissolved(ug/L) <0.1 Magnesium(Mg)(mg/L) 2.58 2.52 2.73 1.98 1.8 1.94 1.41 2.05 2.87 Manganese(Mn)(mg/L) 0.028 0.063 0.092 0.0741 0.03 0.033 0.051 0.0526 0.59 Manganese,Dissolved(mg/L) 0.04 Mercury(Hg)(ng/L) <50 1.53 2.1 2.11 0081 2.93 1.22 7.35 1.41 1-5 Mercury(ng/L) Methane(ug/L) 4.6J OUTFALL 108 Constituent 4/29/2014 5/1/2015 7/3/2015 11/13/2015 12/16/2015 2/18/2016 2/22/2(116 I - .4/2016 4/19/2016 5/1112016 Molybdenum(Mo)(ug/L) <I <1 0.096J <0.5 _ I Molybdenum,Dissolved(ug/L) 0.13J Nickel(Ni)(ug/L) <1 <1 0.18J <0.5 <1 <1 <1 <0.5 <I Nickel,Dissolved(ug/L) 0.38J Nitrate(mg/L) 0.14 <0.1 0.64 Nitrate as N(mg-N/L) 0.03 <0.023 0.14 Nitrite+Nitrate(Colorimetric) 0.04 0.03 (mg-N/L) _ 0.04 Nitrogen,Nitrate(mg/L) Nitrogen,NO2 plus NO3 (mg/L) 1.5 <0.02 Oil and Grease(mg/L) <5 <5 <5 <5 <5 <5 <5 pH(Std.Units) 6.76 6.75 8.48 9 6.8 7.3 6.9 6.98 Phosphorus(P)(mg/L) 0.036 Potassium(K)(mg/L) <5 <5 1.16 Selenium(Se)(ug/L) <1 I <0.5 <0.5 I <1 I <0.5 <1 Selenium,Dissolved(ug/L) <0.5 Sodium(Na)(mg/L) 6.83 <5 6.77 Specific Conductance 0 83 Specific Conductance (umhos/cm) Specific Conductance(uS/cm) 81 u_n7,i 231 72 -3' I 8U_7 106 Strontium(Sr)(mg/L) 0.082 Strontium,Dissolved(mg/L) 0.083 Sulfate(mg/L) 1.5 0.9117 <1 ? I S I I .1 0.47 Sulfide(mg/L) <0.1 - TDS(mg/L) 81 82 62 _- ,0 101 92 - Temperature() 17.23 Temperature(°C) 14.4 12.3 6/ 12 5 I.7 IS 2 17.9 Temperature(deg C) Thallium(T1)Low Level(ug/L) <0.2 <0.2 <0.1 <0.1 <0.2 Thallium,Dissolved(ug/L) <0.1 TOC(mg/L) 2 Total Kjeldahl Nitrogen (Colorimetric)(mg-N/L) <0.15 TSS(mg/L) <5 88 8.1 2.8 _ - 1; 5 4 11 Turbidity(NTU) 8 15.2 Vanadium(V)(ug/L) 1.55 1.5 Vanadium,Dissolved(ug/L) 0.59J Zinc(Zn)(mg/L) <0.005 <0.005 <0.01 <0.01 <0.005 <0.005 <0.005 <0.01 <0.005 0.0041J 0.014 0.007 0.012 Zinc,Dissolved(mg/L) _ L. OUTFALL 108 Constituent 6/27/2016 0/18/2016 12/9/2016 1/16/2017 2/1/2017 3/6/2017 4/11/2017 5/4/2017 6/8/2017 7/12/2017 8/2/2017 °9/5/2017 10/4/2017 ' 11/6/2017 Alkalinity(mg/L(CaCO3)) Alkalinity(mg/L) 44.2 51 Alkalinity,Carbonate(CaCO3)(mg/L) <5 <10 Alkalinity,Bicarbonate(CaCO3)(mg/L) 44.2 51 Aluminum(Al)(mg/L) 0.223 0.292 Aluminum(Al)(ug/L) Aluminum,Dissolved(mg/L) <0.1 Antimony(Sb)(ug/L) <0.5 I Antimony,Dissolved(ug/L) <0.5 Arsenic(As)(ug/L) 0.26 <1 <1 <1 <1 <1 I <1 I <1 <1 <1 I I Arsenic,Dissolved(ug/L) 0.15 Barium(Ba)(mg/L) 0.018 0.022 0.017 0.016 0.015 0.016 0-0 19 0.022 0-1 021 0.022 0.016 0.019 O 0 I S ((n2 I Barium,Dissolved(mg/L) 0.0145 Beryllium(Be)(ug/L) <0.1 Beryllium,Dissolved(ug/L) 0.OIJ Boron(B)(mg/L) <0.05 n 0 Boron,Dissolved(mg/L) <0.05 Bromide(mg/L) Cadmium(Cd)(ug/L) <0.08 I I <1 <1 <1 1 I 1 I <1 I I I Cadmium,Dissolved(ug/L) <0.08 Calcium(Ca)(mg/L) 9.17 a 87 )s 6.14 5.6 6.45 7.17 s 66 6.9 9(16 8.31 781 8.58 9.13 Calcium,Dissolved(mg/L) Chloride(mg/L) 1.8 2 l __ ' 2.3 1.9 I 2 2.1 I S 1.6 I h 1.9 2.6 Chromium(Cr)(ug/L) 0.28J I 1 I <1 <1 1 <1 <1 I <I I <1 I Chromium,Dissolved(ug/L) 0.53 Chromium,Hexavalent(ug/L) <0.6 Cobalt(Co)(ug/L) 0.36 Cobalt,Dissolved(ug/L) 0.097J COD(mg/L) I Copper(Cu)(ug/L) 0.93 I 1 I I I 1 I <1 I <I I - I 1 Copper,Dissolved(ug/L) 1.3 Flow(cfs) 0.021 0.00462 0 0726 a 00396 0.022 0.0066 0.0066 0.0176 0.00588577779 0.018834488928 0.0059 0.001 0.0071 Fluoride(mg/L) <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 Hardness(mg/L(CaCO3)) 33.4 27.7 23 7 21.7 24.9 27.4 32.3 26 33.6 31.1 29.5 32 34.7 Iron(Fe)(mg/L) 2.2 1.51 2.25 1.87 2.19 2.1 2.02 1.99 2.09 2.22 0.875 0.813 1.36 1.31 Iron,Dissolved(mg/L) 0.212 Lead(Pb)(ug/L) 0.18 I I <1 <1 <1 <1 <I <1 <1 <1 <1 <1 Lead,Dissolved(ug/L) <0.1 Magnesium(Mg)(mg/L) 2.74 2.74 2.4 2.02 1.86 2.13 2.3 2.6 2.12 2.67 2.5 2.38 2.57 2.88 Manganese(Mn)(mg/L) 0.119 0.043 0.025 0.046 0.036 0.034 0.037 0.125 0.036 0.038 0.028 0.016 0.032 0.021 Manganese,Dissolved(mg/L) 0.0353 Mercury(Hg)(ng/L) 3.46 1.24 1.12 0.967 0.876 0.958 1.45 1.51 2.04 1.12 1.19 0.999 0.844 0.805 Mercury(ng/L) Methane(ug/L) <10 OUTFALL 108 Constituent 6127/'_1116 8/2016 12/9/2016 1l16/2017 211/2017 316/2017 4/11/2017 5/4/2017 ./8/2017 7/12/2017 8/2/2017 9/5/2017 10/4/2017 11/6/2017 Molybdenum(Mo)(ug/L) 0.13J I Molybdenum,Dissolved(ug/L) <0.5 Nickel(Ni)(ug/L) <0.5 <1 <1 <I I <1 I I <1 I <1 I <1 <1 Nickel,Dissolved(ug,'L) <0.5 Nitrate(mg/L) <0 I <0.I n L 0.14 , I 0.58 0.32 HU, '_._ u_! q 39 <0.1 Nitrate as N(mg-N/L) + 2 Nitrite Nitrate(Colorimetric)(mg-N/L) 0.0_ Nitrogen,Nitrate(mg/L) Nitrogen,NO2 plus NO3(mg/L) a use+ Oil and Grease(mg/L) <5 s . _ > <5 <5 5 <5 s s s, 5 pH(Std.Units) 7.6 7 r, I 7 I 7 2 7.2 6.8 6 7.1 7 7-I 7; 7-I Phosphorus(P)(mg/L) Potassium(K)(mg/L) <5 194 Selenium(Se)(ug/L) <0.5 I I I I I <1 <1 I <1 I I I I Selenium,Dissolved(ug/L) <0.5 Sodium(Na)(mg/L) 7.64 t,;5 Specific Conductance 0 Specific Conductance(umhos/cm) eS I 1;_ 6,)> 80 I 78.5 89.6 72.5 3)0 I ,5s 2 6 1 3 o--I 104.4 Specific Conductance(uS/cm) 0- I Strontium(Sr)(mg/L) 0.0865 Strontium,Dissolved(mg/L) 0.0821 Sulfate(mg/L) 0.68J 0.47 0_91 0.91 14 0.7 0.95 6 I " 0.65 0.43 0.59 u 1 0.26 Sulfide(mg/L) <0.1 TDS(mg/L) 61 110 63 89 60 76 85 ;0 70 75 65 78 80 Temperature 0 Temperature(°C) 17.6 Temperature(deg C) 6 7 1 18 I;; 11.6 17 18.6 18 r, 25.2 22.1 2 15 IS 5 18.6 Thallium(TI)Low Level(ug/L) <0.1 <0.2 Thallium,Dissolved(ug/L) <0.1 TOC(mg/L) 1.9 Total Kjeldahl Nitrogen(Colorimetric)(mg- N/L) . TSS(mg/L) 11.9 - - _ <5 - <5 Turbidity(NTU) ,,„) Vanadium(V)(ug/L) 1.6 Vanadium,Dissolved(ug/L) 0.34 Zinc(Zn)(mg/L) <0.01 a 00,, <0.005 <0.005 <0.005 <0.005 a im5 <0.005 o uus a nu5 <0.005 <0.005 a 005 <0.005 Zinc,Dissolved(mg/L) 0.0069J OUTFALL 108 Constituent 12/11(2017 1/4/2018 4/2/2018 7/2/2018 10/1/2018 I' " 4/30/2019 7/11/2019 Alkalinity(mg/L(CaCO3)) Alkalinity(mg/L) Alkalinity,Carbonate(CaCO3) (mg/L) Alkalinity,Bicarbonate(CaCO3) (mg/L) Aluminum(Al)(mg/L) Aluminum(Al)(ug/L) Aluminum,Dissolved(mg/L) Antimony(Sb)(ug/L) Antimony,Dissolved(ug/L) Arsenic(As)(ug/L) <1 <1 I <1 1 <1 I <1 Arsenic,Dissolved(ug/L) Barium(Ba)(mg/L) 0.013 0.012 0_02 0.019 0.023 0.017 0.02 I 0.018 Barium,Dissolved(mg/L) Beryllium(Be)(ug/L)Beryllium,Dissolved(ug/L) Boron(B)(mg/L) 0.0 5 Boron,Dissolved(mg/L) Bromide(mg/L) Cadmium(Cd)(ug/L) <l I <1 I <1 1 I I Cadmium,Dissolved(ug/L) Calcium(Ca)(mg/L) 5 9>; r,.61 6.02 9.12 10.6 5.97 7 58 SoS Calcium,Dissolved(mg/L) Chloride(mg/L) 2 __ 2.2 1.6 2 '- ' 1 17 Chromium(Cr)(ug/L) <1 I '<I <1 <1 1 I I Chromium,Dissolved(ug/L) Chromium,Hexavalent(ug/L) Cobalt(Co)(ug/L) Cobalt,Dissolved(ug/L) COD(mg/L) Copper(Cu)(ug/L) <I <1 1.4 3 <-1 <1 1 4 <1 I Copper,Dissolved(ug/L) Flow(cfs) 0.0118 0.0147 0.0082 0.00588577- 9 0.01177155558 0.02354311116 0.03531 0.0265 Fluoride(mg/L) <0.1 0 1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 Hardness(mg/L(CaCO3)) 23.4 25.4 24.9 34.2 39.3 23.2 30.4 32.4 Iron(Fe)(mg/L) 1.47 0.749 2.41 1.11 0.785 1.8 3.5 1.32 Iron,Dissolved(mg/L) Lead(Pb)(ug/L) <I <1 <1 <1 <1 <1 <1 <1 Lead,Dissolved(ug/L) Magnesium(Mg)(mg/L) 2.08 2.16 2.39 2.78 3.12 2.02 2.61 2.61 Manganese(Mn)(mg/L) 0.016 0.016 0.032 0.085 0.063 0.026 0.107 0.055 Manganese,Dissolved(mg/L) Mercury(Hg)(ng/L) 0.619 0.602 1.43 1.38 1.24 1.27 1.14 Mercury(ng/L) 1.21 Methane(ug/L) LABORATORY FLAGS < -concentration not detected at or above the adjusted reporting limit. A - Federal MCL. *- Interim Maximum Allowable Concentrations(IMACs)of the 15A NCAC 02L Standard,Appendix 1,April 1, 2013. lg- Result confirmed by second analysis performed out of hold. 2g-The concentration in the Blank QC is less than the reporting limit but greater than 1/2 the reporting limit. B-Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in sample is less than 10X the concentration in the method blank. Analyte concentration in sample could be due to blank contamination. B1 -Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in sample was greater than l0X the concentration in the method blank. Analyte concentration in sample is not affected by blank contamination. B2-Target analyte was detected in blank(s)at a concentration greater than 1/2 the reporting limit but less than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes. B3-Target analyte was detected in Continuing Calibration Blank(s)at a concentration greater than 1/2 the reporting limit but less than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes. B4-Target analyte was detected in Continuing Calibration Blank(s)at or above the reporting limit. B5-Target analyte was present in blank(s)above the method detection limit but less than the reporting limit. Data is valid for compliance purposes. B6-Target analyte was detected in Continuing Calibration Blank(s) at a concentration greater than the reporting limit. BC-The same analyte was detected in an associated blank at a concentration above 1/2 the reporting limit but below the laboratory reporting limit. CO- Result confirmed by second analysis. CR-The dissolved metal result was greater than the total metal result for this element. Results were confirmed by reanalysis. CU -The continuing calibration for this compound is outside of Pace Analytical acceptance limits. Analyte presence below reporting limits in associated samples. Results unaffected by high bias. D3 -Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. D4-Sample was diluted due to the presence of high levels of target analytes. D6-The precision between the sample and sample duplicate exceeded laboratory control limits. E-Analyte concentration exceeded the calibration range. The reported result is estimated. H -Sample analyzed past the recommended holding time. H1 -Analysis conducted outside the EPA method holding time. H2- Extraction of preparation conducted outside EPA method holding time. H3-Sample was received or analysis requested beyond the recognized method holding time. H6-Analysis initiated outside of the 15 minute EPA required holding time. HS- Results are from sample aliquot taken from VOA vial with headspace(air bubble greater than 6 mm diameter). j+ - Estimated concentration, biased high. Ll -Analyte recovery in the laboratory control sample(LCS) was above quality control (QC) limits. Results may be biased high. L2-Analyte recovery in the laboratory control sample(LCS)was below QC limits. Results for this analyte in associated samples may be biased low. L3-Analyte recovery in the laboratory control sample(LCS)exceeded quality control (QC) limits. Analyte presence below reporting limits in associated samples. Results unaffected by high bias. M - Matrix spike/ matrix spike dup failure. M1 - Matrix spike recovery was high: the associated Laboratory Control Spike(LCS)was acceptable. M2- Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS)was acceptable. M4-The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to the spike level. M6- Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2-The lab does not hold accreditation for this parameter. P2- Re-extraction or re-analysis could not be performed due to insufficient sample amount. P4-Sample field preservation does not meet EPA or method recommendations for this analysis. P8-Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. RO-The data are unusable.The sample results are rejected due to serious deficiencies in meeting QC criteria. The analyte may or may not be present in the sample. R1 - Relative Percent Difference(RPD)value was outside control limits. S-Associated calibration check did not meet specified criteria. S1 - Data review findings indicate result may be unreliable. Use with caution. U-Analyte was analyzed for, but not detected above the MDC. OUTFALL 108 Constituent 12/11/2017 1/4/2018 4/2/2018 7/2/2018 111/1/2018 2/5/2019 4/30/2019 7/11/2019 Molybdenum(Mo)(ug/L) Molybdenum,Dissolved(ug/L) Nickel(Ni)(ug/L) <1 <1 I <1 1 <1 <1 <1 Nickel,Dissolved(ug/L) Nitrate(mg/L) <0.1 <0.1 0 13 0.65 0 3 I <0.1 0.27 0.72 Nitrate as N(mg-N/L) 0.06 0.16 Nitrite+Nitrate(Colorimetric) (mg-N/L) , Nitrogen,Nitrate(mg/L) Nitrogen,NO2 plus NO3 (mg/L) _ Oil and Grease(mg/L) <5 <5 <5 <5 <5 <5 pH(Std.Units) 7.6 6 6.3 7.37 7.15 6.8 6 7 7 I Phosphorus(P)(mg/L) Potassium(K)(mg/L) Selenium(Se)(ug/L) <1 I <1 I <1 <1 I I Selenium,Dissolved(ug/L) Sodium(Na)(mg/L) Specific Conductance() Specific Conductance 72.8 109.6 79 105.1 107.6 69-1 86 I 752 (umhos/cm) Specific Conductance(uS/cm) Strontium(Sr)(mg/L) Strontium,Dissolved(mg/L) _ Sulfate(mg/L) 0.88 0.76 17 0-l9 0.32 16 0.9 0.48 Sulfide(mg/L) TDS(mg/L) 76 78 55 110 81 6- 90 82 Temperature O Temperature(°C) Temperature(deg C) 3.9 2 14 S 25.7 21.6 9`< 17.7 24.2 Thallium(TI)Low Level(ug/L) Thallium,Dissolved(ug/L) TOC(mg/L) Total Kjeldahl Nitrogen (Colorimetric)(mg-N/L) TSS(mg/L) <5 5 9 6 5 _ 6.2 6 Turbidity(NTU) Vanadium(V)(ug/L) Vanadium,Dissolved(ug/L) _ Zinc(Zn)(mg/L) <0.005 0_005 <0.005 0 n05 0.0i05 <0.005 <0.005 <0.005 Zinc,Dissolved(mg/L) Duke Energy Carolinas, LLC Riverbend Stream Electric Plant National Pollutant Discharge Elimination System Permit Number NC0004961 Attachment 5 Fish Tissue Monitoring Results Fish Tissue Monitoring Results Trace element concentration means(ppm) in sunfish and largemouth bass muscle tissue from three locations at Mountain Island Lake (2014-2017). Se Hg As Year Species UP DI DN UP DI DN UP DI DN Sunfish 0.81 1.14 0.60 0.06 0.04 0.09 0.20 0.20 0.16 2014 I Bass 0.67 0.72 0.49 0.11 0.12 0.07 0.18 0.18 0.23 Sunfish 0.42 0.34 0.49 0.09 0.11 0.11 0.05 0.05 0.03 2015 Bass 0.51 0.56 0.40 0.12 0.20 0.12 0.03 0.02 0.00 Sunfish 0.57 0.69 0.57 0.09 0.09 0.07 0.02 0.01 0.01 2016 Bass 0.39 0.46 0.47 0.11 0.13 0.09 0.00 0.02 0.01 Sunfish 0.61 0.62 0.51 0.04 0.03 0.01 0.00 0.00 0.00 2017 Bass 0.42 0.42 0.50 0.04 0.08 0.12 0.00 0.00 0.00 . UP` Qr DI o ir 9 Rivertiend SS ~� . - .-.,.� i s- h . to* Caen ksl tars, ak{ * 4 4 �� '+ 7 �t mountain IsIac�d �� ;. t : • + o DN IN mot* '` 4 1-A. .°;;,-N Nik., or,,:\ 7,-,f,,,'t,;,/ , '"' '• , � , a *" � - , 'If 44L,--,..".-:':I' 10.ki- e ..„: ..,,,- 4 ' 'tt...)009/ie tpall :i0'6A 0 Duke Energy Carolinas, LLC Riverbend Stream Electric Plant National Pollutant Discharge Elimination System Permit Number NC0004961 Attachment 6 Compliance Boundary Map WIC 151TE AERIAL ORTNOVN •. ..^.SV GATED 2014 - � 1-•• °•.. •A' . •�.- '` t 4. loop % / t 6 I • • j l • ACTNE ASH BASIN PRIMARY CELL r / if It • i• • .?14#'C=y ! I -y ,r - - ASHSTORAGE — •,1 - / i 1. ,,* t Ni. t ;`, f r t .,. • -.! z fir tr.� j • „, .., ,.. or ,,, , . 4 r •.,,,, I ... , it 4`y/' t '�4 i '' zso us 0 o soO FIGURE 1 LEGEND > VV. i y GRAPHIC SCALE IN FEET WASTE AND COMPLIANCE BOUNDARIES �J ASH BASIN WASTE BOUNDARY �'.' '• - • 3AR RrvER SRREETHIC SCAO 1 �� GREENVLLE SOUTH CAROLINA 19RU1 RIVERBEND STEAM STATION Q ASH BASIN COMPLIANCE BOUNDARY �,__ R{,.� PRONE 06 a 9sso ' *c Terra DUKE ENERGY CAROLINAS,LLC ©ASH AND CINDER STORAGE BOUNDARY - OL ME Rz/R1/1RER MOUNT HOLLY,NORTH CAROLINA r ,PLANT BOUNDARY n v. EAvuER Ene mrR•�aR,n.�O]fl500 c.w�Anome.^•rrew�RR nu sriEs�cisRr.e�w�u Nmn.o v,aoNt m.a