NC0003417_Application Update_20190607

4> DUKE
ENERGY
October 27, 2016
Mr. Jeffrey O. Poupart
North Carolina Department of Environment and Natural Resources
Division of Water Resources, Wastewater Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Subject: Duke Energy Progress, LLC.
HF Lee Energy Complex NPDES Permit NC0003417
NPDES Application Update
Wayne County
Dear Mr. Poupart:
Harry K. Sideris
Senior Vice President
Environmental, Health & Safety
526 S. Church Street
Mail Code. EC3XP
Charlotte, NC 28202
[phone]
The rains from Hurricane Matthew were significant at the HF Lee Energy Complex (HF
Lee) and the areas of the Neuse River downstream of Goldsboro. The Neuse River
level rose high enough to enter the cooling pond at HF Lee through outfall 002 and also
by over -topping the cooling pond dike. The site has not seen a flooding event like this
since Hurricane Floyd in 1999. As a result of the severe weather conditions from the
hurricane, the dike of cooling pond breached in the southeast corner of the pond. A
temporary repair has been completed and most of the discharge from the breach has
been eliminated.
Duke Energy would like to add a new emergency outfall at the site of the breach in the
current NPDES permitting process. Although a permanent solution for the breach repair
is still being developed, we think this emergency outfall would be valuable during severe
weather events to allow for the discharge of the pond in instances where the river rises
and flows into the pond via Outfall 002 or from over -topping the dike. The addition of
the new emergency outfall would avoid a scenario where the pond breaches because of
the influx of water from the river. The new outfall would be located at approximate
coordinates 350 22' 18" N and 780 03' 54" W, and would only be used during severe
weather events or maintenance. Duke Energy also thinks appropriate limits at this new
outfall would mirror the limits at Outfall 002.
Enclosed for your consideration and use are analytical monitoring results from the
cooling pond during the breach and a topographic map showing the approximate
location of the breach.
If there are any questions regarding this request, please contact Mr. Steve Cahoon via
phone at [phone] or via email at [e-mail].

I certify, under penalty of law, that this document and all attachments were prepared under my
direction or supervision in accordance with a system designed to assure that qualified personnel
properly gather and evaluate the information submitted. Based on my inquiry of the person or
persons who manage the system, or those persons directly responsible for gathering the
information, the information submitted is, to the best of my knowledge and belief, true, accurate,
and complete. 1 am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations.
Sincerely,
f� 1r" 4,C
Harry K. Sideris
Senior Vice President
Environment, Health and Safety
Enclosures

Certificate of Laboratory Analysis
This report shall nol 6e reproduced, except in full.
Order # J1 fit 00336
Site, COOLING POND
Collection Date 12-Oct-16 5:46 PM
Analyte
Result
Unite
Qualifiers RDL
OIL AND I WA
PHASE
Oil and Grease
< 5
m91L
5
MERCURY
Mercury(Hg)
<0.05
U91L
0.05
TOTAL REC9YERABLE MIFF"
Iron (Fe)
BY ICP
1.67
mg1L
0.01
Antimony (Sb)
< 1
u91L
1
Amenic (As)
< 1
u91L
1
BerytOum (Be)
< i
uglL
1
Cadmium (Cd) Low Level
< 0.1
u91L
0.1
Chromium (Cr)
1.65
u911.
1
Copper (Cu)
3.39
U911-
1
Lead (Pb)
1.37
u911.
1
Nickel (NQ
< 1
u911.
1
Selenium (Se)
< 1
Ug1L
1
SlIver (Ag) Law Level
< 0.3
U911.
0.3
ThaWum (TI) Law Level
< 0.2
u911.
0.2
Zinc (Zn)
7.13
u91L
5
TO M - (Anft!ls-Porfonnad
by ETT EnvIronmanjjQ
Vendor Parameter
T-OTAL-SyffENDED SOL1113
TSS
16
MA
5
Sample #: 2016033099
Matrix, NPDES
Analytical lab
Page 5 of 13
DF
Method
Analysis Datarrime
Analyst
1
EPA 15548
10113/2016 09.30
CJELL10
1
EPA 245.1
1W1412016 09.19
DMFRANC
1
EPA200.7
1W141201610.01
JJMACKE
1
EPA 200.8
14113r2016 2013
CWSPEN3
1
EPA 200.8
10113=16 20'13
CVVSPEN3
1
EPA 200.8
1011312018 20:13
CVJSPEN3
1
EPA 200.8
1011312016 20:13
CWSPEN3
1
EPA 200.8
1 W1312018 20-13
CWSPEN3
t
EPA 200.8
10113r2016 20;13
CWSPEN3
1
EPA 200.8
10r13r2016 20;13
CWSPEN3
1
EPA 200.8
1011=016 20.13
CWSPEN3
1
EPA 200.8
1 W1312016 20.13
CWSPEN3
1
EPA 200.8
101132016 20.13
CWSPEN3
1
EPA 200.8
10113/2016 2013
CWSPEN3
1
EPA 200 8
10113r2016 20.13
CWSPEN3
1
Vendor Malhod
V ETT
1
SM2540D
10111=01619;17
HGRUVER

ANALYTICAL RESULTS
Protect. JISID03M
Pace Analytical 8erAms, LLC
9800 KlnoeyAve Suite 100
Huntersvile, NC 23078
(704)87St1092
Pace Project Na,- 923161M
Sample: 2016033236 Lab ID: 92316133001 Collected. 1011311616:20 Received: 10114/1614:00 Maldw Water
Paramelers Results Units Report Lhrdl OF Prepared Analyzed CAS No. Qual
608 GCS Pesticides and PCBs AnalykW Method EPA608 Preparation Method- FPA3510
Aldrin
NO
u91L
0 050
1
10114/1617:30 10/17/16 11:38 309.00.2
atpha-BHC
NO
ug1L
0.050
1
1011411617:30 1011711611:38 319434.6
beta-BHC
NO
u91L
0.050
1
1011411617:30 1011711011:38 31MS-7
delta-SHC
NO
U91L
0.050
1
1011411617:30 1011711611:38 319.86.8
gamma-BHC (Lindane)
NO
u91L
0.050
1
1011411617:30 1011711611:38 58.89.9
Chlordane (%chrican
NO
ug1L
0.50
1
10114116 17:30 1011711611:38 57-74-9
4,4'4)DD
NO
uglL
0050
1
10N411617:30 1011711611:38 72-54-8
4X-DOE
NO
LKI&
0.050
1
1011411617:30 10117fi811:38 72-55.9
4,4'-DDT
NO
uglL
0 050
1
1011411617:30 1011711611.38 50.29.3
Dleldrin
NO
ug1L
0.050
1
1011411617:30 1011711611:38 60.57-1
Endosulfan I
NO
u911L
Dow
1
10I1411817:30 1011711611:38 959.98.9
Endosutfan II
NO
U91L
0.050
1
1011411617:30 i0f1711611:38 33213.66.9
Endosulfen sulfate
NO
ug1L
0.050
1
10114I1517:30 1011711611:38 1031-07-8
Enddn
NO
ug1L
0.050
1
1011411517:30 101171151138 72-20.8
Enddn aldehyde
ND
ug1L
0 050
1
1011411617:30 1011711611:38 7421-93-4
Heptachlor
NO
ug1L
0.050
1
1011411617:30 10/1711611:38 76-44-8
Heptachlor epoxide
NO
U911-
000
1
1011411617:30 1011711611:38 1024-57-3
PCB-1016 (Amcler 1016)
ND
U91L
0.60
1
1011411617:30 1011711611:38 12674-11-2
PCB-1221 (Aroclar 1221)
ND
uglL
0.50
1
1011411617:30 10117116 11:36 11104-28-2
PCB-1232 (Aroclor 1232)
ND
u91L
0.50
1
1011411617:30 MY1711611:36 11141-16-5
PCB-1242 (Arodor 1242)
ND
u911-
0.50
1
1011411617:30 10117116 11:38 53469-21-9
PCB-1248 (Arodor 1248)
ND
U91L
0.60
1
1011411617:30 10117116 11:35 12672-2M
PCB-1254 (Arodor 1254)
ND
U91L
0.50
1
1011411617:30 10117116 1138 11097-69-1
PCB-1260 (Arador 1260)
ND
ug1L
0.50
1
1011411617:30 10/171161138 11096-82-5
Toxaphene
NO
uglL
0.50
1
1011411617:30 1011711611,38 8001-35-2
Surrugefes
Tetrachloro-m-xylene (S)
90
%
20.110
1
10114/16 17:30 10117116 11:36 877-09-8
Decachlorobipherlyl (S)
46
%
20-138
1
10114/16 17:30 1011711611:38 2051-24-3
200.7 MET ICP
Analytical Method EPA 200.7 Preparation Method EPA 200.7
Antlmarly
ND
UwL
5.0
1
1011511501:00 1011511611:46 7440-35.0
Araenlc
ND
ug1L
10.0
1
1011511601:00 1011511611:46 7440.38.2
Beryllium
ND
U911-
1.0
1
1011511601:00 1011511611:46 7440-41-7
Cadmium
ND
uglL
1.0
1
1011511601.00 IOIIW1611:46 7440.43.9
Clvornium
ND
u911-
5.0
1
10115/16 01.00 10115116 11,A6 7440-47-3
Copper
5.9
UwL
5.0
1
1011511601:00 1011511611:46 7440.50.8
Iron
1660
U91L
50.0
1
.10115116 01:00 1011511611A6 7439419.6
Lead
ND
u911-
5.0
1
10115/16 01:00 1011511611:46 7439-92-1
Nickel
ND
Ug1L
5,0
1
10115/16 01:00 10115116 11:46 7440.02-0
Selenium
NO
U91L
10.0
1
10115/16 01:00 10115116 11:46 7782-49-2
Sllver
NO
ug1L
5.0
1
10/15/16 01:00 10115116 11:48 7440-22-4
Thatiium
NO
ug1L
10.0
1
10115115 01.00 10115/16 11:46 7440-2B-0
Zinc
NO
UwL
10.0
1
10115116 01:00 101t5116 11:40 7440-68.8
245.1 Marcury
Analytical Method EPA 2451 Preparation Method EPA245.1
Mercmuy
NO
U91L
0.20
1
10115/16 01:45 10117/1611:01 7439.97.8
REPORT OF LABORATORY ANALYSIS
This capon shall not be repmdumd. except In full,
Date: 1011712016 04:29 PM without 8re written emsent of Paco Analytiml Servkm, LLC
Page 12 of 42

2aceAnalydcalo
wAwPN3bK, mm
ANALYTICAL RESULTS
Project. J16100360
Pace Project No,; 92316133
Pus AnaNical SmIces. LLC
9900VJnceyAve Suitelu0
HuntomAb NC 28011
(704)2759092
Sample: 2016033236
Parameters
Lob 10: 92316133001
Results Units
Collected 1D113116 16 20
Report Limit OF
Received: 10/14116 14:00 Matrix Water
Prepared Analyzed CAS No. Oual
625USSV
Analytical Method EPA625 Preparation Method: EPA625
Acenaphthene
ND
ug1L
5.0
1
1011411617:D0 10117/1611:19 83-32-9
Acenaphthylene
NO
u911-
5.0
1
1011411617:00 1011711611:19 2t18.W8
Anthracene
NO
u911-
5.0
1
1011411617:D0 1011711611:19 120-12.7
Hentidine
NO
u91L
50.0
1
1011411517:00 1011711611.19 92-87-5 L2
Benza(a)anttvacene
NO
uglL
5.0
1
1011411617:00 1011711611:19 56-55.3
Senzo(s)pyrene
NO
u91L
5.0
1
10114116 17.00 10/17/16 11:19 50.32-8
Benza(b)Auoranthene
NO
ug1L
5.0
1
1011411617:00 1011711611:19 205.99.2
9enzo(g,h,l)perylene
NO
u91L
5.0
1
11Y1411617.DD 1011711611:19 191-24-2
Bemo(k)nuoranthene
NO
trglL
5.0
1
1011411617;00 10117/1611:19 207-M9
443romophenylphertyl ether
NO
ug1L
5.D
1
10/14116 17:00 1D11711611:19 101-56-3
Butylbenzylphthalate
NO
uglL
5.0
1
1011411617:00 1011711611:19 85-68-7
bis(2-Chloraelhoxy)melhane
NO
ug1L
10A
1
1011411517:00 1011711611:19 111-91-1
bis(2-Chbraethyt) ether
NO
ugA-
5.0
1
1011411617:00 1011711611:19 11144.4
2-Chloronaphlhalene
NO
u911-
50
1
1011411617:00 1011711611:19 91-68-7
2-CNomphenol
NO
ug1L
5.0
1
1011411517:00 101171t611:19 95-67-8
4-Chlorophenylphenyl ether
NO
u911-
5.0
1
10114116 17:00 1011711611:19 7005-72-3
Chryume
ND
u9/1-
5.0
1
1011411617:00 1011711611:19 218-01-9
Dlbenz(a,h)anlhracene
NO
ug/L
5.0
1
10114116 17:00 10117/16 11:19 53-70-3
30-01ddarobenzidine
ND
u91L
25.0
1
1011411617:D0 1011711611:10 91-94-1
2,4-Dichlorophenal
ND
u9/L
5.0
1
1011411517:00 10/17/1611:19 120.63.2
Dielhylphthalate
ND
u911-
5.0
1
10/1411617:00 10117I1511:19 84.16-2
2,4-Dkrtethylphenol
NO
u911-
10.0
1
1011411517:00 1011711511:19 105-67--9
Dimethylphthalale
ND
u911-
5.0
1
10114MO 17:00 10117/15 11-19 131-11.3
DI-n-butylphihalate
ND
u911-
5.0
1
10/1411617:00 10/17/1611:19 84-74-2
4,0-01Nlro-2-methylphenol
ND
U911-
20.0
1
1011411817:00 1011711611:19 534-52-1
2,4-Dkiftmphenol
ND
tr91L
50.0
1
1011411617:00 1011711611:19 51-28-5
24-Dktilrolaluene
ND
u911-
5.0
1
1011411617;00 101171161119 121-14-2
2,6-3inilroloiuene
ND
u91L
5.0
1
1011411617.00 1011711611:19 606-20.2
DI-rwctylphthalate
ND
uglL
5.0
1
1011411517.00 1011711611:19 117.84-0
1,2-Dipheny1hydrazine
ND
ug1L
5.0
1
1011411617:00 1011711611:19 122.66.7
bis(2-E1Whexyl)phlhalate
ND
u91L
5.0
1
1011411517:00 1WI711611:19 117-817
I"luoranthene
ND
u91L
5.0
1
1011411617:00 1011711611:19 20644.0
Fiuorene
ND
u101-
5.0
1
1011411617.00 1011711611:19 W73-7
1-1exachloro-1,3-butadiene
ND
u91L
5.0
1
1011411617.00 1011711611:19 87.68-3
HexaMorobenzene
ND
ug1L
5.0
1
1011411617:00 1011711611:19 11844-1
Hexachlorocyclopentadiene
ND
u91L
10.0
1
1gN411617:00 10/1711611*19 77-474
HexacHomethane
NO
u91L
5.0
1
10/14116 17:00 10/1711611:19 67 72-1
1ndeno(1,2,3-cd)pyrene
ND
u91L
5.0
1
1011411617:00 1011711811:19 193-39.5
Isophorone
NO
u91L
10.0
1
11Y1411617:00 1011711611:19 78.59.1
3&4-Methylphenol(map cresol)
ND
ug1L
10.0
1
10/14116 17.00 1011711511:19
Naphthalene
ND
U91L
50
1
10/14116 17:00 10117/i6 11:19 91-20-3
Nitrobenzene
ND
u91L
5.0
1
1011411617.00 1011711611:19 98-95.3
2-Nkrropherd
ND
ugA-
5.0
1
1011411617:00 10117/16 11:19 OB-75.5
4-Nkrophenol
NO
U911
50.0
1
1011411617:00 1011711811:19 100-027
N-Nitrosodlmethylamine
ND
uglL
50
1
1011411617:00 1011711511:19 62.75.9
N-Nilroso-di-n-propylamine
ND
uWL
5.0
1
1011411617:00 1011711511:19 521.64-7
N-Nitrosodlphenylamine
NO
u91L
10.0
1
1011411617.00 10/1711611,19 W30-6
REPORT OF LABORATORY ANALYSIS
This report sha0 not be reproduced, ascepl In full
Dale: 10117/2016 04 29 PM w *wut are wridea consent or pace Mdrlical Ser d=- LLC Page 13 of 42

1�l5aceAnalyfical.
eaaimm
ANALYTICAL RESULTS
PaceAnslydral Services, LLC
991501ttno"Ave 5WIe 1D0
HwneravNle, NC M79
(7W )e75.9D92
Protect J 16100360
Pace Project No: 92316133
Sample: 2016033236 Lab 10: 92316133001 Collected. 10f1311516:20 Received 1011411014.01) Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No Oual
625 MSSV Analytical Method EPA 625 Preparation Method; EPA 625
ZZ-Oxybis(1-Ch1oropropane)
NO
ugll.
5.0
1
1011411617:00 1011711611:19
106.80.1
Pentachlorophenol
NO
u91L
10.0
1
1011411617:00 101171161119
a7.86-5
Phenanthrene
NO
u911-
5.0
1
10114116 17,00 10117116 1119
85-01-8
Phenol
NO
u9fL
5.0
1
1011411617,00 1011711611.19
Pyrene
NO
ugfL
so
1
10/1411617:00 10117115 11;19
129.OD-0
2,4,8-Trichlorophenol
NO
ugfL
10.0
1
1011411617.00 1011711811:19
884)6-2
sunnogates
Nitrobenzene-d5 (S)
65
%
10-120
1
10/14116 17;00 1011711611,19
4165.80.0
2-Fluomblphenyl (S)
56
%
15.120
1
1011411617.00 1011711611,19
321.60.8
Terphenyl-d14 (5)
77
%
11-131
1
10114116 17-00 10117116 11:19
17i8.51-0
PhanoWS (5)
23
%
10-120
1
10f1411617,00 10117116 1119
131274MI-3
2-Ftuomphenol (S)
33
%
10-120
1
l(V1411617.00 10117116 11,19
357-12-4
2,4.6-Tribromophenol (S)
55
%
1D-137
1
1011411617.'00 10/17116 11,19
118-79-5
624 Volatile organics
Analytical Method. EPA 624
Acrokln
NO
ug1L
so
1
10/15/16 23.31
107-02-8
Acrylondrile
NO
ug1L
60.0
1
10/16/16 23.31
101-13.1
Benzene
NO
ug1L
20
1
10/15/16 23 31
71-43.2
Bromodichloromelhane
NO
uglL
20
1
10/15/16 23-31
75-27.4
BromGform
NO
u91L
2.0
1
10/15116 23.31
75.25-2
Bromomethans
NO
ug1L
2.0
1
10115116 23:31
74-83.9
Carbon tetrachloride
NO
ug1L
2.0
1
10/15116 23,31
56-23.5
CNorobenzene
NO
is&
2 0
1
10115115 23:31
108.90.7
CNoroethane
NO
ug1L
2.0
t
10/15115 23:31
75-00-3
2-Chloroethylvinyl ether
ND
u911-
5.0
1
10/15115 23:31
110.75.8 C2
Chloroform
NO
u911-
2.0
1
10115116 23:31
67466-3
Chloromethane
NO
u911-
2.0
1
10/15116 23:31
74-87-3
Dlbromochloromelhane
NO
u911-
2.0
1
10115116 23:31
124.48-1
1,2-Dlchlorobenzene
ND
ug1L
2.0
1
10/15116 23:31
95-b0-1
1,3-Dichlorobenzene
ND
ug1L
2.0
1
10/15116 23:31
541-73-1
1,4-Dlchtorobenzene
NO
ug1L
2.0
1
10115116 23:31
108.46-7
1,1-01cfdornelhane
NO
ug1L
2.0
1
1011511623:31
75-34-3
1,2-Di&4oroethane
NO
u911-
2.0
1
1011511623:31
107.06.2
1,1-Dlchloroaffiene
NO
u911-
2.0
1
1011511623,31
75.35.4
trans-1,2-Dichiaroethene
NO
u911-
2.0
1
10115/16 23 31
156.60.5
1,2-Dlchlompropane
NO
ugfL
2.0
1
10115/16 23 31
78-87-5
cis-1,3-Dichloropmpene
ND
ug1L
2.0
1
10115116 23 31
10061-01-5
trans-11,3-01chloropropene
NO
ugfL
2.0
1
10115/16 23-31
10061-02-6
Ethylherrzene
ND
uglL
2.0
1
10115/16 23 31
100-41-4
Methylene Chloride
NO
u91L
2.0
1
10116/16 2331
75-09-2
1,1,2,2-TetracNoroethane
NO
u91L
2.0
1
10115/16 23 31
79.34-5
Tetrachloroelhene
NO
ugfL
2.0
1
10/15/16 23:31
127-18.4
Toluene
NO
uglL
2.0
1
10115/16 23:31
IDS-88.3
1,2,4•TrkNorobenzene
NO
u911-
2.0
1
10/15/16 23.31
120.82-1
1,11-Tdchlowethene
ND
ugfL
2.0
1
1011511523:31
71-55-6
1,1,2-Trio hloroethane
NO
u911-
2 0
1
10f15116 23-31
79-00.5
Trichloroethene
NO
u91L
2.0
1
10f15f1623:31
79-01-6
REPORT OF LABORATORY ANALYSIS
This report shag not be ropm duced. except In fill.
Date, 10117/2016 04--29 PM wilml the written consent of pace Analytical Services. LLC Page 14 of 42

IcleAnalyfical
(�
r+rrr-0sart�iaxn
ANALYTICAL RESULTS
Project. J16100360
Pace Project No,, 92318133
Pan Anatlrtinl ServIen, LLC
9300 K1n=yAve Suite 100
Hunts %*a. HC 240715
[phone]
Sampla: 2016033236
Lab ID: 92316133001
Collected- 1011311616.20
Received- 10114110 14 00 Mahitr Waler
Parameters
Results Units
Report Umh DF
Prepared Analyzed CAS No Qual
624 Volatile Organics
Analytical Method: EPA 624
Trichloralluoromethane
ND ug1i.
2.0 1
10/15116 23 31 7"9-4
Vinyl chloride
ND ug1L
20 1
10/15/16 23 31 76.01-4
Surrogates
4-13romolluorobenzene (S)
94 %
70-130 1
10/15/16 23 31 460-00-4
Toluene -do (S)
104 %
70-130 1
10/15116 23 31 2037-26-5
1,2-Dkhlomethane-d4 (S)
95 %
7D-130 1
10I15116 23 31 17060-07-0
450OCNE Cyanide, Total
Analytical Melhod. SM 4500-CN-E
Cyanide
ND m91L
00080 1
1011511614:47 57-12.5 M1,R1
REPORT OF LABORATORY ANALYSIS
'This report shall not be mproduted, exmpl In volt,
Dale 10/1712015 04 29 PM without the wriStw mnsent of peas Analytical Services, UC. Page 15 of 42

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16100404
Site: Cooling Pond
CallecUan Date: 16-00-16 10:03 AM
Anelyte Result Units Qualifiers ROL
Vendor Parameter
Dioxin by EPA 1613 - (Analvsls
Performed by Pace
Laboratorlgs1
Vendor Parameter
MERCURY (COLD VAPOR) IN
WATER
Mercury (Hg)
c 0.05
u91L
0.05
TOTAL RECOVEIIABLE METALS
BY JCP
Iron (Fe)
1.52
mglL
0.01
T METALS
SY I
Antimony (Sb)
c 1
ug/L
1
Arsenic (As)
1.18
ug1L
1
Beryllium (80)
c 1
ug/L
1
Cadmium jCd) Low Level
a 0.1
ug1L
0.1
Chromium (Cr)
1.37
ug/L
1
Copper (Cu)
6.99
ug1L
1
Lead (Pb)
1.32
ug1L
1
Nickel (NI)
c 1
u94-
1
Selenium (Se)
c 1
ug1L
1
Sliver (Ag) Low Level
c 0.3
u911-
0.3
Thallium (R) Low Level
c 0.2
ug/L
0.2
Zinc (Zn)
5.34
u911-
5
PCOS - tAneiysls Pedormed
Vendor Parameter
by Pace LabomiRdes)
Complete
SEMIVOLATILES - (AnslVW9
Pedpand by Pace Laboratories]
Vendor Parameter
Complete
Page 7 of 55
Sample #: 2016033482
Matrix: NPDES
OF Method Analysls DateMme Analyst
1 Vendor Method
V. PACE
1 Vendor Method
V, PACE
1 EPA 245.1
101171201611.57
DMFRANC
1 EPA200.7
IDII O1611:56
MHH7131
1 EPA 200.6
10/17/2016 1933
CWSPEN3
1 EPA 200.8
1CY17120161933
CWSPEN3
1 EPA 200.8
10/1712016 19:33
CWSPEN3
1 EPA 200.8
10/1712016 19:33
CWSPEN3
1 EPA 200.8
10/17/2016 19:33
CWSPEN3
1 EPA 200.8
10/1712016 19:33
CWSPEN3
1 EPA200.8
101171201619:33
CWSPEN3
1 EPA 200.8
10/17/2016 19:33
CWSPEN3
1 EPA 200.8
10/17/20161933
CWSPEN3
1 EPA 200.8
10/17i201619:33
CWSPEN3
1 EPA 200.8
10117=16 19:33
CWSPEN3
1 EPA 200.8
10/17/2016 19:33
CWSPEN3
Vendor Method V_PACE
Vendor Method V_PACE

11!2COAnalyffcalo
wvwrmobbrmm
ANALYTICAL RESULTS
Pace Aaalocol Sarvkes, LLC
Is Sure 100
Hunianvite. NC 20078
(104)675-9a92
Project: J16100404
Pace Project No.: 92316201
Sample: 2015033482 Lab ID: 92316201002 Collected* 10116116 10 03 Received- 10117116 08:30 Matdx: 1Naler
Parameters Results Units Report Unit OF Prepared Analyzed CAS No Oual
608 OCS Pesticides and PCBs Analytical Method: EPA 608 Preparation Method EPA 3510
Alddn
NO
ug/L
0.D50
1
1011911610:24
1011911613:51 309.00.2
alpha-SHC
NO
ug/L
0.050
1
1011911610:24
1011911613:51 319-84-6
beta-BHC
NO
U9/L
0.050
1
1011911610:24
1D/191161151 319-65-7
deha-BHC
NO
U91L
0.050
1
1011911610:24
1D1191151351 3194WO
gamma-BHC (Undone)
NO
ug/L
0,050
1
1011911510-24
1011911513,51 58-89-9
Chlordane (Technical)
NO
U91L
0.50
1
1011911610-24
10119/15 13 51 57 74-9
4,4'-ODD
NO
u91L
0.050
1
1011911610:24
1011911513 51 72-54-8
4,4'-DDE
NO
k4A
0.050
1
1011911610:24
10119/16 13 51 72-SS-9
4,4'-DDT
NO
ug/L
O.D50
1
10119116 10;24
10/19116 13 51 SD-29.3
Dletdrin
NO
u91L
0.050
1
1011911610:24
1011911613.51 60.57-1
Endosulfan I
ND
U911.
0.050
1
1011911B 10:24
10/19/16 13.51 959.98.8
Endosutian II
ND
U91L
0.050
1
10119115 10:24
10119/1613.51 33213-65.9
Endosullan sulfate
NO
t$9&
0.050
1
1011911810:24
UV1911613.51 1031-07-8
Enddn
ND
U911-
0.050
1
1011911610:24
10119/1613.51 72-20.8
Enddn aldehyde
ND
U911-
0.050
1
1011911610:24
10119116 13.51 7421-93-4
HeptacNar
NO
ug/L
0.050
1
1011911810:24
1011911613.51 7644-8 L3
Heptachlorepoxide
NO
Ug1L
0.050
1
101191%810:24
1011911613.51 1024-57-3
PCB-1016 (Anxiar 1016)
NO
u91t-
0.50
1
10119118 10,24
10119116 13.51 12674-11.2
PCB-1221 (Arociar 1221)
NO
ug/L
0.60
1
1011911610:24
10/19116 13.51 11104-25-2
PCB-1232 (Aroclor 1232)
ND
ug1L
0.50
1
10119/16 1024
1011911613:51 11141-16.5
PCB-1242 (Aracior 1242)
NO
U91L
0.50
1
10119/16 10:24
1OIIW1613:51 53459-21-9
PCB-1248 (Aroclor 1248)
NO
U91L
0.50
1
10119116 10:24
1011911613:51 12672-29.6
PCB-12S4 (Aroclor 1254)
NO
u91L
0.50
1
10119/18 10:24
10119/161311 11097-69-1
PCB-1260 (Aradar 1260)
NO
ug1L
0.50
1
10/19116 10:24
1011911613:51 11OM82-S
Toxaphene
NO
u91L
0.50
1
1011911610:24
1011911613;51 8001.3S-2
Surrogates
Tetrachloro-m-xylene (S)
91
%
20-110
1
10/19116 10:24
10119/16 13:51 877-09.8
Decachlorobiphenyl (S)
29
%
20-138
1
1D11911610:24
10/19/15 13:51 2051-24-3
625 MSSv
Analytical Method: EPA 625 Preparation Method: EPA 625
Aceraphitme
NO
ug1L
5.0
1
01711612:01
1011811612:16 8332-9
Acensphthylene
NO
ug1L
5.0
1
1011711612:01
10118/1612:18 206-96-B
Anthracene
NO
ug/L
5.0
1
1W1711612:01
1011811612:16 120.12.7
BerWdine
NO
ug1L
50.0
1
1011711612.01
1011811612:16 92.87-5 L2
Senza(a)anthracene
NO
ug/L
5.0
1
1011711612:01
1011811612:16 56.55.3
Senza(a)pyrene
ND
U911-
5.0
1
10/17116 12.01
10118/16 12:15 S0-32.8
Benzo(b)Auoranthene
ND
ug1L
5.0
1
1011711612:01
10118/1612.16 205.99.2
Benzo(g,h,i)perylene
ND
U911.
5.0
1
1011711612:01
1011811612:16 191-24-2
Bermo(k)Iluoranthene
NO
U911.
5.0
1
1011711612-01
1011811612:16 207-08-9
4-Bromophenylpherlyl ether
ND
U91
5.0
1
10117/16 12 01
10118/1612:16 101.55-3
Butytbenzylphthalate
NO
u91L
6.0
1
10117116 12 01
1011511612:16 85-08-7
4-Chios-3-methylphenot
NO
U91L
5.0
1
10117/16 12 01
10/18116 12:16 59.50-7
bis(2-Chlomethaxy)melhane
ND
ug/L
10.0
1
1011711812.01
1011811612:16 111-91-1
b1s(2-Chlo Whyl) ether
NO
UWL
6.0
1
1011711612:01
10118116 12:16 111-444
2-Chloronaphlhalene
NO
Ug/L
5.0
1
101171161101
1011811612:16 91-58-7
2-Chlarophenol
NO
u911.
6.0
1
1011711612:01
1011811612,16 W57-8
4-Chlorophenylphenyl ether
NO
U91L
5.0
1
1011711612:01
1011811612:16 7005-72-3
REPORT OF LABORATORY ANALYSIS
This rayon that not be reproduced. eaoepl in tut,
Dale: 10/2012015 07:43 AM without the water consent or Pace Analytical SarW=, LLC
Page 11 of 27

aceAna4 ca!'
www WCOM:mrn
ANALYTICAL RESULTS
Project J16100404
Pace Project No - 92316201
Paco Analytical 9uvieaa, LLC
PAN&D Suite 100
Hunlanvit . NC 28078
[phone]
Sample: 2016033462 Lab ID: 92316201002 Cokvled- 1011611610.03 Received'. 10117116 08 30 Matrix. Water
Parameters Results Unlls Report Limit OF Prepared Analyzed CAS No. Qual
625MSSV AnalybW Method EPA625 Prepamilon Method. EPA 625
Chrysene
NO
u9&
50
1
10117116 1211
10118116 1216 2111-m-9
Dthenz(a,h)anthracene
NO
u91L
50
1
1Oil 7116 12V
10/18118 12,16 53.70.3
3,Y-Dirhlorobenzldine
NO
u91L
25.0
1
10117/1612:01
10118/1612:16 91-94-1
2,4-Dlchlomphenol
NO
tr94-
5.0
1
10/17/16 12 01
101111/16 12,16 1204 3.2
Dielhylphthatale
NO
u91L
5.0
1
1011711612:01
1011811612,16 84-66-2
2,4-131methylphenol
NO
ug1L
10.0
1
1011711612:01
1011511612.16 105.67.9
Dimethy4"halale
NO
u9A-
6.0
1
1011711612.01
1011811612,16 131-11-3
Di-n-butylphthalate
NO
ug1L
so
1
HY1711612:01
1011811612.16 84.74-2
4.6-Dirdiro-2-methylphenol
NO
ugrL
20.0
1
10IMS 12-01
1011811612 1E 534-52-1
2,4d?ktilroow"
NO
ugll
50.0
1
UY11711612:01
10118/1612:16 51.28-5
2,4-Dinilrololuene
NO
ug/L
5.0
1
1011711612:01
1011811612:16 121-14-2
2,6.OlnUmtoluene
NO
ug1L
5.0
1
1011711612:01
101181181216 806-20.2
Ol-n-octylphlhalale
NO
uglL
5.0
1
UY1171161201
1011811612,16 117.84.0
1,2-Dlphenylltydrazine
NA
uglL
5.0
1
1011711612:01
10118115IZ18 122.66.7
b1S(2•ElhyOtexyQphthalale
NO
u911
5.0
1
10H711612:01
1011811612:16 117.91-7
Fluoranthene
NO
u91L
5.0
1
10H711612,01
1011811612-16 206-44-0
Fluorene
NO
ug1L
5.0
1
1011711612.01
101181161216 86-73-7
Hexarhloro-1,3-butadlene
NO
ug1L
5.0
1
1011711612,01
1011011012:16 87-H-3
Hexachlombenzene
NO
uglL
5.0
1
10117116 12-01
1011811812.1E 118-74.1
Hexachlorocyclopentadiene
NO
ugll.
IM0
1
VY1711612:01
1011WIS 1215 77-47-4
Hexachloreathane
NO
ug1L
5.0
1
VY1711812:01
101181161216 67-72-1
Inden0(1,2,3-cd)pyrane
NO
UA
6.0
1
1011711612.01
101181161216 193-39-5
Isophorone
NO
ug1L
10.0
1
1011711812:01
1011B116 12 16 78-59-1
384-Melhyiphenol(map Cresd)
NO
ug1L
10.0
1
10117/10 lZ01
1011811612.16
Naphthalene
NO
ug1L
5.0
1
10117/1612:01
10/1811612.16 91-20-3
Nitrobenzene
NO
ug1L
5.0
1
1011711612:01
1011811612.16 98.95-3
2-Nltrophenol
NO
ug1L
5.0
1
1011711512DI
1011811612,:15 68.75.5
4-Nitroplwal
NO
uglL
50.0
1
1011711612:01
1011811612:16 IM-02-7
N-Nitrasodimethylamine
NO
ugfL
5.0
1
1011711612:01
101181161216 62-76-9
N-141bos".n-propylamine
ND
uglL
5.0
1
1011711612.01
1011811612:16 621-64-7
N-Nitrosodiphenylamine
NO
UWL
10.0
1
1011711612,01
1011811612:16 86-30-6
2,Z-0xyb1s(1-ch1oropropane)
NO
ug1L
5.0
1
1CY171161201
1011011612,16 108.60-1
Pentachloraphenol
ND
u91L
10.0
1
1011711612.01
1011811612.1E 87-55-5
Phenanthrene
ND
u91L
5.0
1
10117/1612 01
1011811612.16 85.01-8
Phenol
NO
u91L
5.0
1
101171161201
10118116IZ16
Pyrene
NO
U91L
5.0
1
ICV1711612.01
10118116 12 16 129.00.0
2.4,8 Trlrhkxophenot
NO
u91L
10.0
1
10117/16 12:01
10/18/16 1216 68.06-2
surrogates
Nltrobenzene-d5 (S)
73
%
ID-120
1
10/17116 UZI
10/18/16 1216 4165-60-0
2-FluombOmyl (5)
62
%
16-120
1
10/17/1612 01
1011811612-16 321.60.E
Terpheny1-d14 (S)
82
%
11-131
1
=1711612.01
10/16/16 1216 1718-51.0
Phenol-d6 (S)
29
%
10-120
1
1011711612.01
10118/16 12:16 1312741&3
2-Fluomphenal (S)
39
%
10-120
1
1011711a 12-01
10/18116 12.16 357-12-4
2,4,6-Tribromophenal (S)
85
%
10-137
1
10/1711612 01
1GI18116 12.16 118-79-6
450OCNE Cyanide, Total
Analytical Method., SM 4500-CN-E
Cyande
NO
1114111-
0,0080
1
1011811612 04 57-12-5
REPORT OF LABORATORY ANALYSIS
This report sW rat be reproduced, except In Ut
Dale- 10MM016 07.43 AM wOmut the written anent of Pace Aratylical Servit:ea, LLC Page 12 of 27

Certificate of Laboratory Analysis Page 7 of62
This report shall not be reproduced, except in lull.
Order # J16100443
Site: Coating Pond
Collection Date: 17-Oct-16 3:37 PM
Anelyte Result Units Qualifiers ROL
Vendor Parameter
Oloxin by EPA 1113 - (Analysis
Performed by Pace
Laboratories)
Vendor Parameter
MERCURY (CQLO VAPORi IN
WATER
Mercury (Hg)
c 0.05
ug1L
0.05
TOTAL RECOVERABLE METALS
BY ICP
Iron (Fe)
1.28
mg1L
0.01
TOT& RECOVERABLE METALS
BY 1CP-IIifS
Antimony (Sb)
c 1
ug1L
1
Arsenic (As)
1.22
ug1L
1
Beryllium (Be)
c 1
ug1L
1
Cadmium (Cd) low Level
c 0.1
ug1L
0.1
Chromium (Cr)
1.04
ug1L
1
Copper (Cu)
6.64
ug1L
1
Lead (Pic)
c 1
u91L
1
Mckel (NI)
c 1
u91L
1
Selenium (Se)
c 1
uofL
1
Silver (Ag) Low Level
t 0.3
u91L
0.3
Thalllum (TI) Low Level
c 0.2
uglL
02
Zinc (Zn)
45
ug1L
5
PCBS -(Analysis Performed by
Vendor Parameter
Page ijiftratorlest
Complete
Vendor Parameter
Complete
V s Psrformod
by Pwo Laboratories)
Vendor Parameter
Complete
Sample #: 2016033541
Matrix,. NPDES
OF
Method
Analysis Dalernme
Analyst
1
Vendor Method
V PACE
1
Vendor Method
V_PACE
1
EPA 245.1
10118120161123
OMFRANC
1
EPA 200.7
10118/2016 15:31
MHH7131
1
EPA 200.E
10118201617:13
CWSPEN3
1
EPA 200.8
10/182016 17:13
CWSPEN3
1
EPA 200.8
10/181201617:13
CWSPEN3
t
EPA 200.8
1011812016 17:13
CWSPEN3
t
EPA 200.8
1011NO1617:13
CWSPEN3
1
EPA 200.8
10111i12016 17:13
CWSPEN3
1
EPA 200.E
101182G16 17:13
CWSPEN3
1
EPA 200.8
101182016 17:13
CWSPEN3
1
EPA 200.8
10/182016 17:13
CWSPEN3
1
SPA 200.8
101IM01617:13
CWSPEN3
1
EPA 200.8
10/18/2016 17:13
CWSPEN3
1
EPA 200.8
10/I81201617:13
CWSPEN3
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V PACE

aceAna�ytical
�p.�oen
ANALYTICAL RESULTS
Pace AnslylMal Servkn, LLC
I1O Sufle 100
Hunlersvise, NC 2ea7a
(704075.9022
Project: J16100443
Parma Project No. 92316307
Sample: 2016033541
Lab ID: 92316307002
Collected 101171161537
Received 10118116 0919 Matdx, Water
Paramelers
Results
Units
Report Lim*
OF
Prepared
Analyzed CAS No chwi
608 GCS Pesticides and PCBs
Analytical Method. EPA 608 Preparation Method EPA 3510
Aldrin
AID
ug1L
0.050
1
101191161024
1011911518.03 309.00-2
a0ha-SHC
NO
U91L
0 050
1
1011911610;24
101191 a 1a,03 31943"
bola-BHC
NO
ugfl
0.050
1
1011911610:24
1011911618 03 319-85-7
de*a-BHC
NO
u¢L
0.050
1
10119116 1024
10119116 18 03 319-86.8
gamma-BHC (Llndane)
NO
ugfL
0.050
1
101191161024
10119116 18 03 5849.9
Chlordane (TedWcaq
NO
u9fL
0.50
1
10/19116 10:24
10119116 18.03 67-74-9
4,4'-ODD
NO
U91L
0.050
1
VY19115 10:24
10119116 18 03 72-54-6
4,4'-ODE
NO
ugfL
0.050
1
101191t8 1024
10119116 18 03 72-55-9
4,4'-DDT
NO
ugfL
0.050
1
1011911510-24
1011911618,03 50-20.3
Di ddrin
NO
u91
0 050
1
10f19115 10.24
1011911618 03 60.67-1
EndosuNan I
NO
u91L
0 050
1
101121161024
10119116 t8 03 959.98-8
Endosultan It
NO
ugfl-
0.050
1
10/19/16 1024
1011911018;03 33213-05-9
Endosullan sulfate
NO
ugtL
0.050
1
10/19/16 10.24
10/19/16 16;03 1031-07-8
Endrin
NO
ug1L
0 050
1
10119/16 1024
10/19116 18;03 72-20-8
Enddn aldehyde
NO
U91L
0.050
1
1011911610,24
10/19116 18:03 7421.93-4
Heptachlor
NO
u98.
0 050
1
101191181024
1011911618:03 76-44-8 L3
Heptachlor epoxide
NO
ug1L
0.050
1
1011911810 24
1011911618:03 1024-57-3
PCB-1016 (Arodor 1016)
NO
u91L
0.60
1
101191161024
1011911618:03 12674-11-2
PCB-1221(Anx:Ior 1221)
NO
ug1L
0.50
1
10/19110 10.24
1011911618:03 11104.28.2
PCB-1232 (Arocitw 1232)
NO
u911-
0,50
1
10119116 10.24
1011911618:03 11141.1&5
PCB-1242 (Aroctor 1242)
NO
tr11111-
0.50
1
10119116 1024
1011911618:03 53469-21-9
PCB-1248 (Arockw 1248)
NO
t1911-
0.50
1
10119116 1024
1011911618:03 12672 2M
PCB-1254 (Aroclor 1254)
NO
t1911-
0.50
1
10119116 10:24
1011911618:03 11097-69.1
PCB-1260 (Arocter 1260)
NO
ug1L
0,50
1
10119116 10:24
10119f18 18:03 11098-62-5
Taxaphene
NO
ug1L
0,50
1
10/1911610:24
1011911618:03 8001-35-2
Surrogates
Telrachk=-nrxylene IS)
65
%
20.110
1
10J19116 10:24
1011911610 03 877.09-6
Decachlarobiphanyl (S)
24
%
20-138
1
10119116 10:24
10119116 18.03 2051-24-3
625 MSSV
Analytical Method. EPA 525 Preparation Method EPA
625
Acensphlhene
NO
t9t
5.0
1
1011811611-00
10/1911612-38 83.32.9
Acemphthylene
NO
ugfL
50
1
1011811511-00
101191181238 20&96.8
Anthracene
ND
U91L
50
1
10118116 11:00
1011911612:38 120-12-7
Bertzidine
ND
ug1L
50.0
1
1011811611:00
1011911612:38 92-87.5 L2
Benzo(e)anthracene
NO
ug1L
5.0
1
1011811611:00
1011911612:38 56-SS-3
Senzo(a)pyrene
ND
1t911.
50
1
10f1Oil 611:00
10119f1612,38 50.32-8
Benzo(b)lluoranthene
ND
tt911.
S.0
1
1011811611:00
1011WIS 12:38 205.99-2
Benzo(9,h.9perylene
ND
U91L
5.0
1
1011WIG 11:00
10119f1612:38 191.24-2
Benzo(k)0ttoranthene
NO
ug1L
6.0
1
1011811611:00
1011911612:38 207-08-9
4-Bmmophenylphanyl ether
NO
ugfL
6,0
1
10118/16 11:00
1011911612:38 101-55-3
Bldylbertzylphthalate
NO
U91L
5.0
1
1011811511:00
1011911612:38 85-a8-7
4-Chloro-3-methylphenol
NO
ugfL
5.0
1
1011811511.00
101191161238 59.50.7
bis(2-Chlomethoxy)melhane
NO
ug1L
10.0
1
101181151140
1011911612:38 111-91-1
bis(2-Chtomathyl) ether
NO
ugfL
6.0
1
10f18116 11.00
1011911612:38 111-44-4
2-Chloronaphthalene
NO
ugfL
5.0
1
1011811611:00
1011911612:38 91-58-7
2-Chlorophenol
NO
u91L
5.0
1
10llWlG 11:00
10119116 12:38 95.57-8
4-Chlompherrytphenyl ether
ND
U91L
5.0
1
1011811511:00
10/19116 12:38 7005.72-3
REPORT OF LABORATORY ANALYSIS
This report AM not be reproduced, except in
full,
Date 10/20/2016 08 58 AM
without the written consent of ParaMolylicel Services, LLC
Page 13 of 34

aceAna"cal e
wwt mm
ANALYTICAL RESULTS
Projed: J16100443
Pace Project No.: 92316307
Pace Analytical Senfkes, LLC
1 '&4"Blrt a SUM 100
HunMig NC 28078
[phone]
Sample: 2016033541 Lab )D: 92316307002 Collected; 1011711815:37 Recelved: 10118116 09:19 Matrix: waler
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
625 MSSV Analytical Me0t0d EPA825 Preparation Melhod EPA 525
C"sene
NO
ug1L
5.0
1
1011811611:00
1011911612:38 218.01-9
Dibenz(a.h)anthracene
NO
uglL
6.0
1
1011811611:00
1011011612:38 53-70-3
3.7-Dichlorobenzidlne
NO
ug1L
25.0
1
1011811611:00
1011911612:38 91.94.1
2.4-DiWomphenat
NO
ug1L
5.0
1
1011811611:00
1011911612:38 12"3.2
Dlelhylphthalate
NO
ug1L
5.0
1
1011811611:00
10119/16IZ38 84-W2
2,4-Dimethylphenol
NO
ug1L
10.0
1
1011811611:00
10119/1612:38 105.67-9
Dlmethylphlhalale
NO
ug1L
5.0
1
10f1811E 11:00
10119/16 12:38 131-11-3
Dl-n-bulylphthalate
NO
ug1L
5.0
1
10118116 11:00
1011911612:36 64 74-2
4.6-Dinitro-2-methylphenol
NO
ug1L
20.0
1
1011811611:00
1011911612:38 534-52-1
2.4-Dinitrophenol
ND
ug1L
50.0
1
10/18116 WOO
1011W1612:38 51-28-5
2.4-Dinitrotoluene
NO
ug1L
5.0
1
1011811611:00
1011911612:38 121.14.2
2.6-Dinitrotoluene
NO
ug1L
5.0
1
10118111611:00
1011911512:38 606.20.2
Di-n-octylphlhalele
ND
uglL
5.0
1
1011811611M
1011911612.38 117-111"
1.2-Diphenythydrazine
ND
ugfl-
5.0
1
1011811611:00
1011911612:38 122-66-7
bls(2-Elhylhexyl)phihalale
ND
ug1L
5.0
1
1011SMS 11:00
1011911812,38 117-81-7
Ftuoranlhene
ND
ug1L
5.0
1
1011811611:00
1011911612:38 206.44-0
Fluorene
ND
u911-
5.0
1
1011811611:00
1011911612:38 86.73.7
Hexachloro-1,3-butadiene
ND
ug1L
5.0
1
1011811611:00
10119/1512:38 87.88.3
Hexachlorobenzene
ND
ug1L
5.0
1
1011811611:00
10119116 12:35 118-74-1
Hexa&4orocyrlopentadiene
ND
u91L
10.0
1
1011811611:00
1011911612:38 77.474
Hexactdomelhane
ND
ug1L
5.0
1
1011811611;00
1011911612,38 57-724
Indeno(1,2,3-cd)pyrene
ND
u91L
5.0
1
1011611611;00
1011911612,38 193-39.5
Isophomne
ND
u91L
10.0
1
1011811511;00
11011911612:38 78.59-1
384-Melhyiphend(mdp Cresol)
NO
u91L
10.0
1
10M8118 11:00
10/19116 12:38
Naphthalene
ND
u911-
5.0
1
1011811511:00
10/1911612,38 91-20-3
Nitrobenzene
ND
ug1L
5.0
1
1011811611:00
1011911812.38 98-96-3
2-Nllrophend
ND
ug1L
5.0
1
1011811611,00
1011913612:38 W75-5
4-Nllropherd
ND
u91L
50.0
1
1011811611:00
1011911612:38 100-02-7
N-Nilrosodkaethylamine
ND
ug1L
5.0
1
t0118116 MOD
10119118 12:38 62-75-9
N-N 10=9-dl-n-propylamine
ND
ug1L
5.0
1
10118116 MOD
10119118 12:38 621.64-7
N-Nitrosodiphenylandne
NO
u911-
10.0
1
MUM 11:00
10119116 12:38 86.30.E
ZT-Oxyhts(i-ddoropropane)
NO
u911-
5.0
1
1011811811:00
1011911612:36 10MG-1
Pentachlorophenol
ND
u91L
10.0
1
i011811611:00
1011911612.36 87.8E-5
Phenanthmne
NO
ug1L
5.0
1
1011811611-00
10119f1612,38 85.01-6
Phenol
NO
ug1L
5.0
1
10M&16 11-00
10119/16 12.38
Pyrene
ND
u911-
5.0
1
10/18116 11-00
10110/16 12 38 129430.0
2.4.6-Tdchinrophenol
NO
ug1L
10.0
1
1011811611:00
1011911612.36 88.0E-2
surrogates
NNrabenzene-0 (S)
76
%
10-120
1
10118116 1100
10119116 12:38 4165-60-0
2-Fhrombiphenyl (S)
61
°%
15-120
1
1011811511:00
10/19116 12:38 321.60-B
Terphenyl-d14 (S)
81
%
11-131
1
10118ME 11:00
10/19116 12:38 1718-51-0
Phenol -de (S)
25
%
10.120
1
1011811611:00
1011911612:38 13127-88-3
2-Fluorophenol (S)
37
%
10-120
1
1011811611:00
10/19116 12:38 357-12-4
2.4.6•Tdbromaphend (S)
74
%
10-137
1
14118/16 11:00
1011911E 12:38 118-7M
624 Volatile Organics
Analytical Method- EPA 624
Acrolein
NO
1U9fL
5.0
1
10/18116 20:29 107-02-8
REPORT OF LABORATORY ANALYSIS
This faMn shall not be reproduced, essept In tuff.
Date 1012012D16 08 58 AM without the wrW*n coned of Pace Analytkal services. LLC Page 14 of 34

aceAnali ircal"
wwwtpsoersAtcom
ANALYTICAL RESULTS
Project: J161011a43
Pace Analytical 3ervloes, LLC
196"Waa Sutie,og
Hwteravi:e_ NC 2W?ff
Q04Da75.9092
Pace Project No.: 92316307
Sample: 2016033541 Lab lD: 92316307002 Collected: 101171161537 Received 10/18/16 09-19 Matrix Water
Paramelem Results units Report Umk DF Prepared Analyzed CAS No Dual
624 Volatile Organics Analytical Method: EPA624
Acrylonkrk
NO
u911.
500
1
10/18/16 20:29 107-13-1
Benzene
NO
u911L
2.0
1
10118/18 20:29 71-43-2
Bromodichloromethene
NO
u911.
2.0
1
10/15115 2029 75-27-4
Bromoform
NO
u911.
2.0
1
1DII8116 2029 75.26.2
Bromomethane
NO
u911.
2.0
1
10/18116 20:29 74.83.9
Carbon tetrachloride
NO
u91L
2.0
1
1011WIS 20:29 56-23.5
Chlorobenzene
NO
u91L
2.0
1
10118116 20:29 108-90.7
Chloroethene
NO
u91L
2.0
1
10118116 20,29 75.00.3
2-0domethylvinyl ether
NO
u911-
5.0
1
10118116 2029 110-75-8 c2
Chloroform
NO
u911.
2.0
1
10118115 20-29 67-M-3
Chloromethane
NO
u911.
2.0
1
10118116 20:29 74-87-3
Didromochioromethane
NO
u911
2.0
1
10118115 20-29 124-48-1
1,2-01ctdombenzene
ND
u91L
2,0
1
10118116 20:29 95-5D-1
1,3-Dichlorobenzene
ND
u9fl-
2.0
1
10118/16 20:29 541 73-1
IIA-Dlchlorobenzene
NO
u911-
2.0
1
10 IMS 20:29 106-46.7
1,1-Dlchloroethane
NO
u91L
2.0
1
10118116 20.29 75-34-3
1,2-Dlchloroelhane
NO
ugn-
2.0
1
10118/16 20:29 107406.2
1,1-DiWOroethene
NO
u91L
2.0
1
101UM 20:29 75-35.4
trans-11,2-OkMoroethene
NO
ug1L
2.0
1
10M8116 20:29 156.80-5
1,2-Dlchloropropone
NO
u91L
2.0
1
10118/16 20:29 78-67-5
cis-1,3-DiCdompropene
NO
u91L
2,0
1
10/18/16 20:29 10051.01.5
trans-1,3-Dichkwopropane
NO
ug1L
20
1
10/13/16 20.29 10051.02.6
Ethylbenzene
NO
ug1L
2.0
1
1W1811820.29 100.41.4
Methylene Chloride
NO
ullk
20
1
10/18116 20.29 75-09-2
1,1,2,2-Tetrachloroethane
NO
ug1L
2.0
1
1011811620,29 79-34-5
Talrachlomethene
NO
ug1L
2.0
1
10/18116 20.29 127-18.4
Toluene
NO
u9n-
2.0
1
10/18116 20-29 108-8&3
12,4-TrichloroWnzene
NO
u91L
20
1
10/18116 20 29 1213-82-1
1,1,1•Trichloroethane
NO
ug1L
2 0
1
10/18116 20:29 71.55.6
1,1,2-Trlchbroethane
NO
u911-
2.0
1
10/18118 20:29 79-00-5
Tdchloroethene
NO
u91L
2.0
1
101181162029 79.01.E
Trichiaronuoromelhane
NO
u911.
2 0
1
10118116 20:29 75.6S4
%Aryl chloride
NO
u91L
2.0
1
10118116 20,29 7MI-4
Surrogates
4-Bromotluambenzene (S)
91
%
70-130
1
10118116 20,29 460-004
Toluene-d8 (S)
108
%
70-130
1
1011811E 2029 2037.26.5
1,2-Dlchlomelhane-d4 (S)
95
%
70-130
1
10118116 20:29 17060.07-0
45MCNE Cyanide, Total
Analytical Method: SM 4500-CN-E
Cyanide
NO
mgfL
0.0080
1
1011911612:00 57-12.5
REPORT OF LABORATORY ANALYSIS
This report sW riot be reproduced, except In lug,
Date: I W2012018 08 58 AM without the written consent of PacaAnslylical Services, LLC Page 15 of 34

Duke Energy Progress, Inc.
Attachment
CT Site Area
H. F. Lee Energy Complex
NPDES Permit Number NCO03417
0 0.2 0.4 0.6 0.e 1. at
USES Northwest Goldsboro (NC) Quadrangle
10/2512016