950002_ENFORCEMENT_20171231

■ Complete Items 1j, 2, and 3. Also complete A. Si urea
Item 4 if Restricted Delivery is desired. // / ❑ Agent
■ Print your name and address on the reverse ❑ Addressee
so that we can return the card to you. .Recel a by (�nt } D ate of Delivery
N Attach this card to the back of the.mallplece,
or on the front if space permits.
D. Is delivery ed �1? ❑ Yes
=1. Article Addressed to: if YES, enter d iv address belo ❑ No
Mr. Johnny Brown" N {mil 0
Mack Browlt Incorporated ��
PO Box 488
Boone, NC 28607 3. 5e ceType
fCertiged Mall ❑ress Mail
❑ Registered Return Receipt far Merchandise
❑ Insured Mall 11 C.Q.D.
4. Restricted Delivery? (Extra Fee) ❑ Yes
2 ArticleNumtx il!t SS 7004 i 25101 0002 2066i Ii961,3
(I!msferJr rn s s z+
PS Form 3811. February 2004 Domestle. Return Receipt tnssssa¢�t-isao

UNITED STATES POSTAL SERVI
F}
`' P M
r r. "% -
6
21 Frii
• Sender, Please p "
N /M�
NC i)i NIV
AQUIFER PROTECTION DWISION
585 WAUCIITOWN STREET
WINS"f ON-SALEM, NC 27107-2241
_J t
IFE'i�Illl�kllfll�lllil}llfll!'li�f�llili}'fl}�IITIlIIi!!IIlII *•

Brown Notice of Violation
• 16
Subject: Brown Notice of Violation
From: Melissa Rosebrock <[e-mail]>
Date: Tue, 21 Mar 2006 14:42:24 -0500
To: Derek Goddard <[e-mail]>
Derek,
I wanted to follow --up on our recent phone conversation regarding the complaint and
subsequent NOV at the Brown property on Wade Moretz Road.
We received Johnny Brown's response to the NOV on March 2, 2006.
His response letter appeared to address the concerns outlined in our NOV. It is our
understanding that cattle have now been removed and that denuded areas near the
creek are to be re -vegetated no later than April 30, 2006. If cattle are returned
to this area, Mr. Brown stated stated that BMPs would be implemented per SWCD
recommendations to maintain a vegetative cover, move feeding areas behind chicken
houses, and maintain a cattle stocking rate of no greater than one head per acre.
This office believes that the above -stated guidelines and conditions should
alleviate the water quality concerns/violations described in the NOV. This office
also wishes to express appreciation to both Mr. Brown and your office for
addressing the water quality problems so quickly. Should you have further questions
and need clarification please contact me anytime.
Sincerely,
Melissa Rosebrock
Melissa Rosebrock
NC DENR Winston-Salem Regional Office
Division of Water Quality, Aquifer Protection Section
585 Waughtown Street
Winston-Salem, NC 27107
Voice: [phone]
FAX. [phone]
Melissa Rosebrock<Melissa.Rosebrock(a-),NCmail.net>
wSRO
NC DENR
1 of 1 3/21/2006 2:42 PM

•
r-I
LJ
Ms. Sherri Knight
DENR-DWQ
585 Waughtown Street
Winston-Salem, NC 27107
Johnny Brown
Mack Brown Inc.,
P.O. Box 488
Boone, NC 28607
Ms. Knight,
4.0, Dept, of !.—I
21006
After extensive consideration please accept this letter as a Plan of Action to correct the
Violation letter dated 2/15/2006. With the Cooperation of the Watauga SWCD the
following actions and corresponding timeframe will be carried out.
➢ All cattle will be moved from the site and Sold via Video Auction before 3/17/06
➢ All denuded areas will be re -vegetated per Watauga SWCD Specifications After
April 1 but no later than April 30t`.
If we chose to move cattle back on to this property we will implement the following
Best management practices per SWCD recommendations:
➢ Maintain Vegetative cover
➢ Move hay feeding areas behind the abandoned chicken house
➢ Reduce stocking rate to no greater than 1 head per acre.
7Th Yo ,
ALZ��
Johnny Brown

RE: Brown complaint
•
Subject: RE: Brown complaint
From: "Goddard, Derek - Boone, NC" <[e-mail]>
Date: Wed, 22 Feb 2006 14:59:47 -0600
To: <[e-mail]>
Your response helps alot. I have no problem with working with Mr. Brown i just wanted to clarifiy the
letter.
Here is the approach that i would like to take. I am going to draft a plan to establish a vegetative cover,
reduce the number of animals, move the feeding area, and limit the access to the stream. This will
accompany any letter Mr. Brown sends along with a letter from the SWCD This would be a "try and see
method"
Do you think it would work?
Thanks
Derek
From: Melissa Rosebrock[mailto:[e-mail]]
Sent: Wednesday, February 22, 2006 2.38 PM
To: Goddard, Derek - Boone, NC
Subject: Re: Brown complaint
Mr. Brown is required to respond to our office stating what he intends to do to correct the violations.
If he doesn't respond at all, then we will probably start collecting fecal samples and go for a civil
penalty assessment (fine). We can't tell him exactly what/how to do it .... only that what he/and you
decide to do should alleviate the potential for run-off of soil and animal waste. We urge him to work
with your office regarding what you would suggest to eliminate run-off. As you previously mentioned,
that might include fencing the animals out and providing a heavy use/feeding/drinker, etc. or in might
include moving them to another location that would not cause a WQ concern (we would probably
request directions/map as to where they were being moved). As I see it, he at least needs to get some
permanent vegetation on both sides of the creek ASAP to begin controlling the run-off of sediment
and waste. You/he/we may find that he needs to do more to actually control the turbidity, solids, and
fecal coliform water quality standard problems (we can issue fines on those) that are impacted by the
operation as it is currently (or the last time I saw it). As it gets warmer, I usually see the DO go down
in situations like this. He would then have the potential for a DO violation and fine as well.
We don't require you all to assist him .... but we urge Mr. Brown to seek your assistance in coming up
with a plan or solution that he/you believe will work. We are ok with allowing flexibility to try
something first, then try something else if that doesn't work. We just want the operation to have no
impact on the WQ of the stream in the future. We would much rather him spend his/your time and
money fixing the problem than us pursuing a fine. We are required, however, in the letter to warn him
of the potential for fines.
Hope that helps....??? Let me know and we can talk some more. It's tough (for me) to convey
thoughts through email! Thanks again for your assistance.
Melissa Rosebrock
1 of 2 2/27/2006 9:04 AM

RE: Brown complaint
NC DENR Winston-Salem Regional Office
Division of Water Quality, Water Quality Section
585 Waughtown Street
Winston-Salem, NC 27107
Voice: [phone] ext 383
FAX: [phone]
On 2/22/2006 2:13 PM, Goddard, Derek - Boone, NC wrote:
Hey, hope all is well.
I got the letter and I am throughly confused. What is required of Mr.
Brown?
I read the letter as nothing other than establish a vegetative buffer?
Our SWCD j
Board has serious concerns about other farms in the county and the
implications of the NOV on Q'ur amount of funding and image.
Thanks
Derek
-----Original Message -----
From: Melissa Rosebrock[mailto:Melissa.Rosebrock@ncmail..net]
Sent: Wednesday, February 22, 2006 2:09 PM
To: Goddard, Derek - Boone, NC
Subject: Brown complaint
Hey Derek,
I didn't want you to think I was ignoring you ... they are putting in a
new -phone system today so our phones are out today and possibly
tomorrow. I can try calling you tomorrow or we can email??
2 of 2 2/27/2006 9:04 AM

o�0� wAr69�G
UJ r
o �
February 15, 2006
CERTIFIED MAIL 7004 2510 0002 2066 9613
RETURN RECEIPT REQUESTED
CMr. Johnny Brown - ,
Mack Brown'incoiporated
PO Box 488
Boone, NC 28607
SUBJECT: Notice of Violation - Complaint Investigation
_Watauga County
Dear Mr. Brown,
. Michael F. Easley, Governor
' William G. Ross Jr., Secretary
North Carolina Department of Environment and Natural Resources
Alan W. Klitn k, P.E. Dimctpr
Division of Water Quality
As you know, Division of Water Quality (DWQ) staff from the Winston-Salem Regional Office visited
your cattle operation located along Wade Moretz Road on January 4; 2006 in response to a complaint alleging
sediment and animal waste run-off from the cattle lot into surface waters. This letter is to summarize the water
quality violations and concerns noted during our investigation.
DWQ staff observed evidence of accumulated sediment and organic matter in the section of an unnamed
tributary (UT) to Meadow Creek (class C+ waters of the State) that flows through the cattle lot. Staff also
observed that the cattle have uncontrolled access to waters of the State and that the buffer area along the
waterway is also void of vegetation due to excessive cattle traffic. Sediment and waste was documented to have
washed into the UT and its presence has impacted at least 800 linear feet of stream. The presence of settleable
solids in amounts that make the water unsafe or unsuitable for aquatic life and wildlife or impairs the water for
any designated use is a violation of NC Administrative Code .0211(3)(c).
NC Administrative Code 2B .0211 states that this section of the UT to Meadow Creek "must be suitable
for aquatic life propagation and maintenance of biological integrity, wildlife, secondary recreation, and
agriculture; sources of water pollution which preclude any of these uses on either a short-term or long-term
basis shall be considered to be violating a water quality standard." You are hereby notified that the preclusion
of best usage in the UT to Meadow Creek, which includes aquatic life propagation, biological integrity,
wildlife, and secondary recreation, represents a water quality standard violation. NC Administrative Code
2B'.0225 also states that the impacted section of Meadow Creek is subject to a special management strategy in
order to protect downstream waters classified as Outstanding Resource Waters (ORW). Such downstream
waters are of exceptional state or national recreational or ecological significance and are to have exceptional
water quality.
Stream samples were also obtained and analyzed for dissolved oxygen (DO), pH, specific conductance,
nutrient levels, biochemical oxygen demand (BOD), turbidity, and fecal coliform. As the results below indicate,
there were no violations of the State's water quality standard for DO, pH, fecal coliform, or turbidity (there is
no water quality standard for specific conductance, nutrients, or BOD). While there were no analytical
violations on the date of our complaint investigation, there is certainly the potential for these types of violations
during rain events and as conditions deteriorate: N°i" caroling
)r0&C r�
Division of Water Quality I Aquifer Protection Section Customer Service
585 Waughtown Street, Winston-Salem NC 27107 1-877-623-6748
Phone: [phone] Fax: [phone] Internet: hop:/inCNNaterqualit.•.or,

J. Brown - NOV
February 45, 2006
Page 2
Upstream_ of Cattle Lot
'Fecal coliform = 200 col/100 mL
Z DO = 10.02 mg/L
3 pH = 6.05
4Turbidity 3.2 NTU
NH3 = .02 mg/L
TKN= 0.20 mg/L
NO2+NO3= 2.8 mg/L
Total P = 0.04 mg/L
Specific conductance = 54.5 µs
BOD = 2.0 mg/L
in -Stream Prior to Culvert
Fecal coliform = 3900 col/100 mL
DO = 9.45 mg/L
PH = 5.99
Turbidity = 13 NTU
NH3 = 0.05 mg/L
TKN = 0.35 mg/L
NO2+NO3 = 2.9 mg/L
Total P = 0.12 mg/L
Specific conductance = 59.7 µs
BOD = 2.0 mg/L
Downstream of Cattle Lot
Fecal coliform = 3400 cot/ 100 mL
DO = 6.96 mg/L
PH = 6.26
Turbidity = 8.5 NTU
NH3 = 0.04 mg/L.
TKN = 0.35mg/L,
NO2+NO3 = 2.8 mg/L
Total P = 0.10 mg/L
Speck conductance = 61.7 µs
BOD = 2.0 mg/L
'The NC water quality standard for fecal coliform is 200 colonies / 100 ml (maximum, geometric mean of five consecutive
samples in 30 days).
2 The NC water quality standard for dissolved oxygen in this stream is 4.0 mg/L (minimum, instantaneous) and not less than a
daily average of 5.0 mg/L.
3 The NC water quality standard for pH is 6.0 - 9.0 units.
a The NC water quality standard for turbidity in this stream is 50 NTU (maximum).
A reminder, that the unpermitted discharge of animal waste into waters of the State is a violation of
North Carolina General Statute (NCGS)143-215.1. At minimum, vegetation should be established in the
buffer area along the UT to prevent further run-off, as soon as soil and climate conditions allow. In addition, we
strongly urge your continued cooperation with the Watauga County SWCD/NRCS regarding technical and/or
financial assistance. They may be contacted by phone at [phone].
The enforcement remedies available to the Division for the above mentioned violations include civil
penalties of up to $25,000.00 per day, per violation. A written response is expected within ten (10) days of
receipt of this Notice, indicating the actions you are taking to correct the noted violations. Your response should
include statements and specific descriptions of how and when the water quality concerns are to be/have been
addressed. Please direct your response to my attention at the address listed on this letterhead.
If you have questions regarding this Notice, please contact Melissa Rosebrock or me at [phone].
Sincerely,
Sherri V. Knight
Regional Aquifer Protection Supervisor
cc: DWQ-AP Section -Animal Feeding Operations Unit
Derek Goddard - Watauga County Soil and Water Conservation District
Central Files
,WSRO AP Facility Files

NC Division of Water Ouality Laboratory Section Resul
►t ENR
Loc. Descr.: DOWNSTREAM OF BROWN FARM
FEB 0 2006
Location ID: BROWNFARM3
County; WATAUGA Sample ID: AB00118 Winston Salem
PO Number # 6WO061 FReglonaOttice
River Basin
VisitiD
Report To WSROSP
Region: WSRO
Date Received:
01/0512006
Collector: M ROSEBROCK
Time Received:
10:00
Sample Matrix: SURFACEWATER
Recv'd By:
CGR
Loc. Type: RIVER/STREAM
Date Reported:
01/27/2006
Sample Depth
Collect Date: 01104/2006
Collect Time:: 12:25
nalyte Name
PQL Result Qualifier Units
Approved By
LAB
Sample temperature at receipt by lab
1.0 °C
JGOODWIN
mic
BOD, 5-Day in liquid 2.0 2 UG5G6 mg1L CGREEN
Turbidity 1 8.5 NTU CGREEN
NUT
NH3 as N in liquid
0.02
0.04
mg/L as N
CGREEN
NO2+NO3 as N in liquid
0.02
2.8
mg1L as N
CGREEN
Phosphorus_totai as P in liquid
0.02
0.10
mg/L as P
CGREEN
Total Kjeldahl N as N in liquid
0.2
0.35
mg1L as N
CGREEN
i13oloi
Laboratory Section>> 1623 Mall Service Center, Raleigh, NC 27699-1623 [phone]

COUNTY WATAUGA
RIVER BASIN
RHPORTTO WSRO Regional Office
Other
COLLECTOR(S) : M ROSEBROCK
DIVISION OF WATER QUALITY
Cbemhtry Laboratory Report! Water Quality
PRIORITY
X� AMBIENT QA
COMPLIANCE CHAIN OF CUSTODY
❑ EMERGENCY VISIT ID
0
W❑ SAMPLE TYPE
X❑ STREAM
EFFLUENT
LAKE
INFLUENT
ESTUARY
3
a
IabNmnber :
6WO061
Date Received:
1/512006
Time Received:
10:OO AM
Received By
DS
JSW
Date Rqx tcd :
112WOOO
Eatimated ROD Range: Station Location: DOWNSTREAM OF BROWN FARM
Seed: Cbloriaated: Remarks: ANIMAL WASTE RUNOFF FROM LOT (CATTLE)
Smi Date Begin (yylmmldd) Date End (yylmmldd) Time Begin Time End Deptb - DM, DD, DBM Value Type - A, H, L Compoaile-T, S, Seto Typc
20060104 1 1 1225
X
BOD 310 2U G5 G0 m
COD High 340 m
COD Low 335 m
Coliform: MF Fecal 31616 1100m1
Coliform: MT Total 31504 llOOtnl
CDlifarm: tube Fecal 31615 11 OOmI
Coliform: Fecal Strep 31673 1100ml
Residue: Total "0 m
Volatile 505 m
Fixed 510 MfZL
Residue- Suspended 530 m
Volatile 535
Fixed 540 m
H 403 units
Acidity to PH 4,5 436
Acidity to H 9 3 435
A[kalini to H 9.3 415 TVL
Alkalies to H 4.5 410 m
690 m
X
76 8.5 NTU
CaGform Total Tube "1100 MIS
COMMENTS :
Chloride 940 m
Chi a: Tri 32217 u
Chi a: Corr 32209
Pbea . a 32213 USIL
Cntor. True 80 C.U.
Color H 83 PH. Cu.
Color: PH 7.6 82 c.m
Cyanide 720 m
Fluoride 951 m
Fommkkbyde 71980
Grease and Oils 556
lkardnas Total 900 mgfL
S ific Cond. 95 umhosken
MBAS 38260 m
Phenols 32730 uWL
Sulfas 945
Sulfide 745 m
Damn
Tannin & Lignin -
Hexavalem Chrotnium
Bicarbonate m
Carbonate m
Total Dissolved Solids m
X
NH3 as N 610
0.04
mgfL
X
TKN an N 625
0.35
m
X
NO2 Plus NO3 as N 630
2.B
m
X
P: Total as P 665
0.10
m
PO4 as P M07
P: Dissolved as P 666
K-Potassium
Cd- Cadmium 1027
Cr-Chmmium:Total 1034
u
Cu 1042
Ni-Nickel 1067
twL
Pb-Lead 1051
Zn- Zinc 1092
V-Vanadium'WL
- Silva 1077
Al- Alumiamn 1105
Be. Beryllium 1012UWL
Ca- Calcium 916
mgfL
Co- Cobalt I037
ugIL
Fc- Iron I045
Mo-Mo um
Sb-An"
Sn-Tot
uzga
TI-Thallium
u
Ti-Titanitnn
UyL
H -1631
Ll-Lithium 1 L32
Ma- Magnesi= 927 mgfL
M.-M.M. 1055 u
Na- Sodium 929 m
Arsenic:ToW 1002
Se- Selenium 1147 uFfl-
HR-M 71900
Ba-Barium u
Orpopchloiipe Pesticides
orgiulophosphorm Pesrleideg
Add Herbicides
Baw Neutral&Acid Extractable Organics
TPH Diesel Range
PTp-ble Organics (VOA bottle 'd)
TPH Gasoline Pimp
TPWBTEX Gasoline Range
a
5

DIVISION OF ENVIRONMENTAL MANAGEMENT WATER (�i111L "Y F LAB FORM (Dh11)
COUNTY vet 1�l LV PRIORITY 5/VLE TYPE
RIVER BASIN � j
3EPORT TO: ARO FRO MRO RRO WaRO WiRO lYSRO S ` %NMBIENTXF
A STREAM CJ EFFLUENT
%T BM
71her COMPLIANCEHAIN LAKE INFLUENT
CUSTODY
Shipped by: Bus Doris Staff. Other ❑ EMERGENCY ESTUARY
'OLLECTORI,S):M. e— t c) //ll �r� l
Estimated BOD Range: 0-5/5-25 25 65 G-130 or 100 plus STATION LOCATION- � V� r ,^ , d, rf ,0- Qni
Seed: Yes ❑ No rq Chlorinated,• Yes El No REMARKS: Af)IMArallJ0.St-e- v--u n n
Lab Number:
V (�
Date Received-)
Rec'd by(�
From: Bu -Courier- and Del
DATA ENTRY BY:
CK:
DATE REPORTED:
Station # Date Begin (yy/mm/dd Time Begin Date End Time End Depth DM DB DBM Value Type Composite Sample T
O dl V� t2a`� b{, {?` b`{ lad A H L T S B C_ GGNxx
GODS 310 mg/1
GOD High 340 mg/l
3
COD Low 335 mg/1
4
Conform: MF Fecal 31616 /100m1
5
'
Conform: MF Total 31504 /100m1
6
Coliform: Tube Fecal 31615 /104ml
7
Coliform: Fecal Strep 31673 /100ml
81
Residue: Total 500 mg/l
11
Residue: Suspended 530 Mgt]
12
Volatile 535 m9/I
13
Fixed 540 mg/I
14
pH 403 units
15
Acidity to pH 4-5 436 mg/I
Acidity to pH 8.3 435 mg/1
17
Alkalinity to pH 8.3 415 mg/1
18
Alkalinity to pH 4.5 410 mg/I
19
TOC 680 mg/i
20
Turbidity 76 NTU
Chloride 940 mg/l
Chi a: TO 32217 ug/i
Chi a: Corr 32209 ug/1
Pheophytin a 32213 ug/1
Color: True 80 Pt -Co
Color:(pH j 83 ADMi
Color: pil 7.6 82 AUMI
Cyanide 720 mg/I
Fluoride 951 mg/i
Formaldehyde 71880 rng/I
Grease and Oils 556 mg/I
Hardness Total900 mg/1
Specific Cond. 95 uMhos/cm2
-mBAS 36260 mg/I
Phenols 32730 ug/1
Sulfate 945 ing/t
Sulfide 745 mg/1
NH3 as N 610 mg/1
TKN as N 625 mg/l
02 plus NO3 as N 630 mg/1
Total as P 665 mg/1
PO4 as P 70507 mgA
P: Dissolved as P 666 mg/l
Cd-Cadmlum 1027 ugA
Cr-Chromium-Total1034 ugA
Cu-Copper 1042 u9/1
NI -Nickel 1067 ug/l
Pb-Lead 1051 ug/I
Zn-Zinc 1092 ug/l
Ag-Silver 1077 ug/1
AI -Aluminum 1105 ug/1
Be -Beryllium 1012 ug/l
Ca-Calclum 916 mg/l
Co -Cobalt 1037 ug/1
Fe -Iron 1045 ug/I
Li -Lithium 1132 ug/I
Mg -Magnesium 927 mg/i
Mn-Manganese 1055 ug/1
Na-Sodium 929 mg/I
Arsenic -Total 1002 ug/I
Se -Selenium 1147 ug/1
fig -Mercury 71900 ug/I
Organochiarine Pesticides
Organophosphorus Pesticides
Acid Herbicides
Base/ Neutral Extractable Organics
Acid Extractable Organics
Purgeable Organics (VOA bottle reg'd)
Phytoplankton
Sampling Point X
Conductance at 25 C
� �
aler Temperature
D.O. mg/i
/_
(D - ` tp
pill
(,.(j n(
Alkalinity
1A18.3 pll CS
Acidity
pit 4.5 pll 8.3
Air Temperature (c)
O
-
lQ .�
� 0 `
tD
[
2
94
10
TX)
400
82244 1 431
82243 82242
20
Salinity %
Preclpilion On/day)
Cloud Cover %
Whtd Direction (Deg)
Stream Row Severity
Turbidity Severity
Wind Velocity M/H
can Stream Depth It.
Scram Width it.
J
480
145
132
136
11351
1350
135
64 b
4
DMI/Revised 10/86

Report to: WSRO
Lab Number:
Station Location:
6WO061
DOWNSTREAM
OF BROWN
FARM
Sample Type: STREAM
Date collected: 01/04/06
Affected Parameter(s): BOD
C DENR/DWQ Laboratory
ample Anomaly Report (SAR)
Sample ID:
County: WATAUGA
•
Region:
Priority: CHAIN OF Collector:
CUSTODY
Date received: 01/05/06 Date analyzed:
Analytical Area (check one):
❑ WCH [-]METALS
❑NUT ®MICRO
The following anomalies occurred (check all that apply):
❑Samples
[]improper container used
❑VOA vials with headspace
❑Sulfide samples with headspace
[]Samples not received, but listed on fieldsheet
❑Samples received, but not listed on fieldsheet
❑Mislabeled as to tests, preservatives, etc.
❑Holding time expired
❑Prior to receipt in lab
❑After receipt in lab
❑Insufficient quantity for analysis
[]Sample exhibits gross non -homogeneity
[]Sample not chemically preserved properly
❑pH out of range (record pH):
❑Improper chemical
❑Residual chlorine present in sample
❑Color interference
❑Heavy emulsion formed during extraction
❑Sample bottle broken in lab - no reportable results
❑Other (specify):
WINSTON-SALEM
M. ROSEBROCK
01/05/06
❑VOA ❑SVO
❑PEST
®Quality Control
[:]Instrument failure — no reportable results
❑Analyst error — no reportable results
❑Surrogates
❑None added
❑Recovery outside acceptance limits
[]Spike recovery
[]None added
❑Recovery outside acceptance limits
❑Failed to meet criteria for precision
❑Internal standards
❑Blank contamination
®QC data reported outside of controls (e.g., QCS, LCS)
❑Incorrect procedure used
El SOP intentionally modified with QA and Branch Head
approval
❑Invalid instrument calibration
❑Elevated detection limits due to:
❑Insufficient sample volume
Comments: One GGA standard and the seed correction factor were outside of limits. GGA standards were 132 and 180.5 mg/L
(198 t 30.5 mg/L) and seed correction was 1.2 (0.60-1.0).
Corrective Action:
USamples were rejected by DWQ Lab. Authorized by: Date:
❑Accepted and analyzed after notifying the collector or contact person and determining that another sample could not be secured.
❑Sample(s) on hold until:
®Sample reported with qualification. Data qualification code used: G5, G6
[JOther (explain):
Notification Required? ❑ Yes ❑ No
Person Contacted: Date:
Form completed by: _Peth_Mitchell] VMV4{tAC VA) Date: 1/10/06
Lead Chemis i (initial):
❑OCIfE e • (initial):
❑PEST ❑SVOA_
[]METALS ❑ VOA
Branch Head Review (initial):
QA/QC Review (initial): Logged into database by (initial):

RECEn—
NC Division of Water 1jality
Laboratory Section Resu
N.C. Dept___
Loc. Descr.: END OF LOT -BROWN FARM
I �
Location ID: BROWNFARM2
Sample ID:
Winsto-
ABt�I�na' �••---
County: WATAUGA
PO Number #
6W0060
River Basin
VISitID
Report To WSROSP
Region: WSRO
Date Received:
0110512006
Collector: M ROSEBROCK
Time Received:
10:00
S m le M t i SURFACEWATER
a p a r x.
Loc. Type: RIVER/STREAM Reov'd By: CGR
Date Reported: 01/27/2006
Sample Depth
Collect Date: 0110412006
Collect Time:: 12:00
na yte Name POL Result Qualifier Units Approved By
LAB
Sample temperature at receipt by lab 1.0 °C JGOODWIN
MIC
BOD, 5-Day in liquid 2.0 2 UG5G6 mg/L CGREEN
Turbidity 1 13 NTU CGREEN
NUT
NH3 as N in liquid
0.02
0.05
mg/L as N
CGREEN
NO2+NO3 as N in liquid
0.02
2.13
mg/L as N
CGREEN
Phosphorus —total as P in liquid
0.02
0.12
mg/L as P
CGREEN
Total Kjeldahl N as N in liquid
0.2
0.35
mg/L as N
CGREEN
Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699.1623 [phone]

COUNTY WATAUGA
RIVER BASIN
REPORTTO WSRO Regional Office
Other :
COLLECTOR(S) : M ROSEBROCK
Estimated BOD Range.
Seed: Chlorinated:
Station 0 ` Date Begin (yylmmldd)
}C
HOD 310 2U G5 G6 mgfL
COD High 340 m
COD Low 335 m
Coliform: MF Feral 31616 1100m1
Colifotm: MF Total 31504 1100m1
Colifonn: tube Fecal 31615 1100ml
Coliform: Fecal Sttrp 31673 1100m]
Residue. Total 500 m
Volatile 508 m
Fixed 510 mgti..
Residue: Suspended 530 mg1L
Volatile 5l5 in
Flxcd 540 mg1L
H 403 units
Acidity to PH 4.5 436 m
Acidity to pH 8.3 435 m
Alkalinity to H 8-3 415 mg1L
Alkalinity to pH 4.5 410
TOC 680 g1L.
X
' icy 76 13 NTU
alarm Total Tube "1100 ml
COMMENTS:
DIVISION OF WATER QUALITY
Chemistry Laboratory Report I Water Quality
$AMPLE IDT
PRIORITY
AMBIENT
QA
X❑ STREAM
EFFLUENT
COMPLIANCE
CHAIN OF CUSTODY
❑ LAKE
❑ INFLUENT
EMERGENCY
VISIT ID
ESTUARY
2
Station location_ END OF LOT - BROWN FARM
Remarks: ANIMAL WASTE RUNOFF FROM LOT (CATTLE)
Date End (yylm% Jdd)
Time Begin
Time End I
Depth - DM, DB, DBM
Value Type - A, 11, L
Chloride 940
Chi a: Tri 32217 u91L
Chl a: Can 32209 ugfL
Pheophytin a 32213 uILL
Color- True 80 c.u.
Color_ (H ) 83 H— c.u.
Color: pH 7.6 82 c.u.
Cyanide 720 m
Fluoride 951 m
Formaideh 71880 m
Grease and Oils 556 m
Hardness Total 9W
Specific Card. 95 tmthos1cm
MBAS 3826D m
Pbenols 32730
Sulfate 945 m
Sulfide 745 cavil
Boron
Tannin R Lignin uSIL
Hexavalem Chromium
Bicarbonate m
Carbtmalc m
Total Dissolved Solids m
•
NH3 asN 610
005
X
TKN an N 625
0.36
mg1L
X
NO2 plus NO3 as N 630
2.8
mg1L
X
P: Total as P 665
0.12
m
PO4 as P 70507
mg1L
P: Dissolved as P 666
m
K-Potassium
mgfL
Cd-Cadmium 1027
Cr-Chrom ium:Total 1034
Cu- Cpm 1042
Ni-Nickel 1067
u
Pb- Lead 1051
2n-T.-nc 1092
u
V-Vanadium
u
A -Silver 1077
u
Al- Aluminum 1105
uSfL
Be- Beryllium 1012
Ca- Calcium 916
mg1L
Co -Cobalt 1037
ugfL
Fe- Iron 1045
UFJL
Mo-Mol bdemmi
U IL
Si-Anlimony
ugfL
Sn-Trn
u
Tl-Tballiwn
Ti Tiunium
WL
H -1631
Dra
Lab Number
6WO060
Date Received :
11511006
Time Received :
10:00 AM
Received By
DS
DataAll�d
Dale Reported :
1252006
Composite-T, S, q Sample Type
fI
Li -Lithium 1132
Mg- Magnesium 927 mgfL
Mn-Manganese 1055 uSIL
Na. Sodium 929 mg1L
Arse :Total1002 ug/L
Sc- Selenium 1147 ug1L
Fig- Met,cury 719M ueL
Ba-Barium u91L
Organoc:hlorinc Pesticides
Pesticides
Acid Herbicides
BasclNeusral$Acid Extractable OWiucs
TPH Diesel Rangc
Pur bk ics(VOA bonie 'd)
TPH Gasoline RanV
TPHIBTEX Gasoline Range
Phroplakt.
P

DIVISION OF ENVIRONMENTAL MANAGEMENT
WATER QUALIT
1- FO I (DM1)
COUNTY Ai -
PRIORITY
❑AMBIENT ❑ t1A
SAMPLE TYPE
STREAM
❑ EFFLUENT
RIVER BASIN Q.
REPORT TO: AHO FRO MRO RHO WaRO WIRO TS
WSR
AT HM
Other
INCOMPLIANCE CHAIN
OF CUSTODY
❑ LAKE
❑ESTUARY
❑ INFLUENT
❑ EMERGENCY
Shipped by: Bus Dueler Staff, Other
C_OLLECTOR(S). _M
Estimated SOD Range- 0 5-25/)5-65/40-130 or 100 plus
Seed: Yes ❑ No) Chlorinated: Yes ❑ Nov
Station # Date Begin (yy/mm/�+dd))t Time Begin Date End
0 ljT/J1 0\ `y1 - ]L=1 •^bb 1 C) I 1
1
BOD5 310 mg/I
COD High 340 mg/1
3
COD Low 335 mg/f
4
Coliform: MF Fecal 31616 /100ml
5
Coliform: MF Total 31504 /100ml
6
Coliform: Tube Fecal 31615 /loom]
COIR4rm: Fecal Steep 31673 /100m1
8
Residue: Total 500 mg/I
9
Volatile 505 mg/1
to
Fixed 510 mg/1
11
Residue: Suspended 530 mg/1
12
Volatile 535 mg/I
13
Fixed 540 mg/1
14
PH 403 units
15
Acidity to pH 4.5 436 n1g/1
Acidity to pH 8.3 435 mg/I
TT
Alkalinity to pH 8.3 415 ' mg/1
18
Alkalinity to pH 4.5 410 mg/I
19
TOC 690 mg/1
20
Turbidity 76 NTU
1-1_ah II.. 41N1 v YI_JL JT►�-I
Lab Number:
Date Received: ✓ Tlme:
Rec'd b From: Busourler land Del
DATA ENTRY BY: CH..
DATE REPORTED: j
Time End Depth DM DB DBM Value Type Composite Sample T}�
a4 1, A H. L T S B . C (G' I GNXX
Chloride 940 mg/1
Chi a: TH 32217 ug/1
Chi a: Corr 32209 ug/1
Pheophytin a 32213 ug/1
Color: True 80 Pt -Co
Color:(pH ) 83 ADMI
Color: pil 7.6 82 ADMI
Cyanide 720 mg/I
Fluoride 951 mg/I
Formaldehyde 71880 Ing/I
Grease and Oils 556 mg/i
Hardness Total900 mg/I
Specific Cond. 95 uMhos/cm2
MBAS 38260� mg/i
Phenols 32730 ug/1
Sulfate 945 mgA
Sulfide 745 mg/1
H3 as N 610 mg/1
KN as N 625 mg/I
NO2 plus NO3 as N 630 mg/1
Total as P 665 mg/1
PO4 as P 70507 mgA
P: Dissolved as P 666 mg/1
CdCadmlum 1027 ugA
Cr-Chromium:Total1034 ug/1
CuCupper 1042 ug/I
Ni-Nickel 1067 ug/i
Pb-Lead 1051 ug/I
Zn-Zinc 1092 ug/I
Ag-Stiver 1077 ug/I
Al -Aluminum 1105 ug/I
Be -Beryllium 1012 ug/I
Ca -Calcium 916 mg/I
Co -Cobalt 1037 ug/I
Fe -Iron 1045 ug/l
LI-Llthlum 1132 ug/1
Mg -Magnesium 927 mg/1
Mn-Manganese 1055 ug/1
Na-Sodlum 929 mg/1
Arsenic:Total 1002 ug/1
Se -Selenium 1147 ug/1
fig -Mercury 71900 ug/I
Organochlorine Pesticides
Organophosphorus Pesticides
Acid Herbicides
Base/ Neutral Extractable Organics
Acid Extractable Organics
Purgeable Organics (VOA bottle reg'd)
Phytoplankton
Sampling Point %
Conductance at 25 C
ater Temperature
D.O. mg/1
pit
Alkalinity
Acidity
Air Temperature (C)
,
PH8-3PH4.5
PH4.5p11 8.3
} O - C)2
Ii
94
o
300 •
400 •
82244 431
82243 82242
20
Salinity %
Precipilton (In/day)
Cloud Cover %
Wind Direction (Deg)
Stream flow Severity
Turbidity Severity
Wind,,VVelocity M/H
can Stream Depth ft.
Stream Width I L
480
45
32
36
1351
1350
35
64
4

Report to: WSRO
Lab Number:
Station Location:
sample Type:
6WO060
END OF LOT -
BROWN FARM
STREAM
Date collected: 01/04/06
Affected Parameter(s)
BOD
&C DENR/DWQ Laboratory
ample Anomaly Report (SAR)
Sample ID:
County: WATAUGA
Region:
Priority: CHAIN OF Collector:
CUSTODY
Date received: 01/05/06 Date analyzed:
Analytical Area (check one):
❑ WCH ❑METALS
❑NUT ®MICRO
The following anomalies occurred (check all that apply):
❑Samples
❑Improper container used
❑VOA vials with headspace
❑Sulfide samples with headspace
❑Samples not received, but listed on fieldsheet
❑Samples received, but not listed on fieldsheet
❑Mislabeled as to tests, preservatives, etc.
❑Holding time expired
❑Prior to receipt in lab
❑After receipt in lab
❑Insufficient quantity for analysis
❑Sample exhibits gross non -homogeneity
❑Sample not chemically preserved properly
❑pH out of range (record pH):
[Improper chemical
❑Residual chlorine present in sample
❑Color interference -
❑Heavy emulsion formed during extraction
❑Sample bottle broken in lab - no reportable results
❑Other (specify):
WINSTON-SALEM
M. ROSEBROCK
01/05/06
❑VOA ❑SVO
❑PEST
®Quality Control
❑instrument failure — no reportable results
❑Analyst error — no reportable results
❑ Surrogates
❑None added
❑Recovery outside acceptance limits
[]Spike. recovery
❑None added
❑Recovery outside acceptance limits
❑Failed to meet criteria for precision
❑Internal standards
❑Blank contamination
®QC data reported outside of controls (e.g., QCS, LCS)
❑Incorrect procedure used
❑SOP intentionally modified with QA and Branch Head
approval
❑Invalid instrument calibration
❑Elevated detection limits due to:
❑Insufficient sample volume
Comments: One GGA standard and the seed correction factor were outside of limits. GGA standards were 132 and 180.5 mg/L
(198 f 30.5 mg/L) and seed correction was 1.2 (0.60-1.0).
"Samples were rejected by DWQ Lab. Authorized by: - Date:
[]Accepted and analyzed after notifying the collector or contact person and determining that another sample could not be secured.
❑Sample(s) on hold until:
®Sample reported with qualification. Data qualification code used: G5, G6
❑Other (explain):
Notification Required? ❑ Yes ❑ No
Person Contacted: Date: ,
Form completed by:
Lead Chemist Review (in
❑BIOCHEM(' ❑PEST
[]METALS ❑VOA
Branch Head Review (initia
QA/QC Review (initi
Date: 1 / 10/06
❑SVGA _
Logged into database by (initial):

Name of Stream
Description
Curr. Class
Date Prop. Class
Basin
Stream Index #
Howard Creek
From the Appalachian
C;Tr,HQW
08/01/90
New
10-1-9-(6)
State University Raw
Water Supply Intake Dam
to South Fork New River
Norris Branch,
From source to the
WS-II;Tr,H
08/03/92
New
10-1-9-7-(1)
including the raw
Appalachian State
QW,CA
water holding
University Raw Water
reservoir below
Holding Reservoir Dam
normal
reservoir
elevation
Norris Branch
From the Appalachian
C;Tr:+
02/01/93
New
10-1-9-7-(2)
State University Raw
Water Holding Reservoir
Dam to Howard Creek
Meat Camp Creek
From source to South
C;Tr:+
02/01/93
New
10-1-10
Fork New River
Little Creek
From source to Meat
C;Tr:+
02/01/93
New
10-1-10-1
Camp Creek
Norris Fork
From source to Meat
C;Tr:+
02/01/93
New
10-1-10-2
Camp Creek
Cobb Creek
From source to Meat
C;Tr:+
02/01/93
New
10-1-10-3
Camp Creek
Rittle Fork
From source to Meat
C;Tr:+
02/01/93
New
10-1-10-4
(Rittle Creek)
Camp Creek
Pine Run
From source to South
C;Tr:+
02/01/93
New
10-1-11
Fork New River
Thaxon Creek
From south to South
C:+
02/O1/93
New
10-1-12
(Tharton Creek)
Fork New River
Laxon Creek
From source to South
C.+
02/01/93
New
10-1-13
Fork New River
Pine Branch
From source to Laxon
C.+
02/01/93
New
10-1-13-1
Creek
Grassy Creek
From source to South
C:+
02/01/93
New
10-1-14
Fork New River
South Fork New
From Elk Creek to a
C;HQW
08/01/90
New
10-1-(14.5)
River
point 0.4 mile upstream
of Couches Creek
Elk Creek
From source to South
C;Tr:+
02/01/93
New
10-1-15
Fork New River
Pine Orchard
From source to Elk
C;Tr:+
02/01/93
New
10-1-15-1
Creek
Creek
`Meadow Creek
From source to South
C:+
02/01/93
New
10-1-17
Fork New River
Cranberry Creek
From source to South
C:+
02/01/93
New
10-1-19
Fork New River
Gap Creek
From source to South
C;Tr:+
OB/01/98
New
10-1-23
Fork New River
Page 5 of II

0 •
NC DENR - DIVISON OF WATER QUALITY
2B .0300
.0307 NEW RIVER BASIN
Classification
Name of Stream
Description
Class
Date
Index No.
Little River (North Carolina
From N.C. Hwy. 18 Bridge
C;HQW
08/01/90
10-9-(11.5)
Portion)
to North Carolina -Virginia
State Line
Crab Creek
From source to Little River
C;Tr
05/15/63
10-9-12
West Fork Chestnut Creek
From source to North
C
O5/15/63
10-10-1
Carolina -Virginia State Line
(Tributary to Chestnut
Creek)
+ This symbol identifies waters that are subject to a special management strategy specified in 15A NCAC 2B
�0225 the Outstanding Resource Waters (ORW) rule,, -in order to protect downstream waters designated as
ORW.
Note: "CA" means Critical area.
11

15A NCAC 025.0225OUTSTANDING RESOURCE WATERS
(a) General In addition to the existing classifications, the Commission may classify unique and special surface waters of the
state as outstanding resource waters (ORW) upon finding that such waters are of exceptional state or national recreational or
ecological significance and that the waters have exceptional water quality while meeting the following, conditions:
(1) that the water quality is rated as excellent based on physical, chemical or biological information;
(2) the characteristics which make these waters unique and special may not be protected by the assigned
narrative and numerical water quality standards.
(b) Outstanding Resource Values. In order to be classified as ORW, a water body must exhibit one or more of the following
values or uses to demonstrate it is of exceptional state or national recreational or ecological significance:
(1) there are outstanding fish (or commercially important aquatic species) habitat and fisheries;
(2) there is an unusually high level of water -based recreation or the potential for such recreation;
(3) the waters have already received some special designation such as a North Carolina or National Wild and
Scenic River, Native or Special Native Trout Waters, National Wildlife Refuge, etc, which do not provide
any water quality protection;
(4) the waters represent an important component of a state or national park or forest; or
(5) the waters are of special ecological or scientific significance such as habitat for rare or endangered species
or as areas for research and education.
(c) Quality Standards for ORW
(1) Freshwater: Water quality conditions shall be maintained to protect the outstanding resource values of
waters classified ORW. Management strategies to protect resource values shall be developed on a site
specific basis during the proceedings to classify waters as ORW. No new discharges or expansions of
existing discharges shall be permitted, and stormwater controls for all new development activities requiring
an Erosion and Sedimentation Control Plan in accordance with rules established by the NC Sedimentation
Control Commission or an appropriate local erosion and sedimentation control program shall be required to
follow the stormwater provisions as specified in 15A NCAC 02H .1000. Specific stormwater requirements
for ORW areas are described in 15A NCAC 02H .1007.
(2) Saltwater: Water quality conditions shall be maintained to protect the outstanding resource values of waters
classified ORW. Management strategies to protect resource values shall be developed on a site -specific
basis during the proceedings to classify waters as ORW. New development shall comply with the
stormwater provisions as specified in 15A NCAC 02H .1000. Specific stormwater management
requirements for saltwater ORWs are described in 15A NCAC 02H .1007. New non -discharge permits shall
meet reduced loading rates and increased buffer zones, to be determined on a case -by -case basis. No dredge
or fill activities shall be allowed if those activities would result in a reduction of the beds of submerged
aquatic vegetation or a reduction of shellfish producing habitat as defined in 15A NCAC 031
.0101(b)(20)(A) and (B), except for maintenance dredging, such as that required to maintain access to
existing channels and facilities located within the designated areas or maintenance dredging for activities
such as agriculture. A public hearing is mandatory for any proposed permits to discharge to waters
classified as ORW.
Additional actions to protect resource values shall be considered on a site specific basis during the proceedings to classify
waters as ORW and shall be specified in Paragraph (e) of this Rule. These actions may include anything within the powers of
the Commission. The Commission shall also consider local actions which have been taken to protect a water body in
determining the appropriate state protection options. Descriptions of boundaries of waters classified as ORW are included in
Paragraph (e) of this Rule and in the Schedule of Classifications (15A NCAC 02B .0302 through 02B .0317) as specified for
the appropriate river basin and shall also be described on maps maintained by the Division of Water Quality.
(d) Petition Process. Any person may petition the Commission to classify a surface water of the state as an ORW. The
petition shall identify the exceptional resource value to be protected, address how the water body meets the general criteria in
Paragraph (a) of this Rule, and the suggested actions to protect the resource values. The Commission may request additional
supporting information from the petitioner. The Commission or its designee shall initiate public proceedings to classify waters
as ORW or shall inform the petitioner that the waters do not meet the criteria for ORW with an explanation of the basis for this
decision. The petition shall be sent to:
Director
DENR/Division of Water Quality
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
NORTH CAROLINA ADMINISTRATIVE CODE Elf August 1, 2004 Page 43

0 •
15A NCAC 02B .0211 FRESH SURFACE WATER QUALITY STANDARDS FOR CLASS C WATERS
General. The water quality standards for all fresh surface waters are the basic standards applicable to Class C waters. See
Rule .0208 of this Section for standards for toxic substances and temperature. Additional and more stringent standards
applicable to other specific freshwater classifications are specified in Rules .0212, .0214, .0215, .0216, .0217, .0218, .0219,
.0223, .0224 and .0225 of this Section.
(1) 'Best Usage of Waters. Aquatic life propagation and maintenance of biological integrity (including fishing,
and fish), wildlife, secondary recreation, agriculture and any other usage except for primary recreation or as
a source of water supply for drinking, culinary or food processing purposes;
(2) Conditions Related to Best Usage. The waters shall be suitable for aquatic life propagation and maintenance
of biological integrity, wildlife, secondary recreation, and agriculture; sources of water pollution which
preclude any of these uses on either a short-term or long-term basis shall be considered to be violating a
water quality standard;
(3) Quality standards applicable to all fresh surface waters:
(a) Chlorophyll a (corrected): not greater than 40 ue for lakes, reservoirs, and other waters subject to
growths of macroscopic or microscopic vegetation not designated as trout waters, and not greater
than 15 ug/l for lakes, reservoirs, and other waters subject to growths of macroscopic or
microscopic vegetation designated as trout waters (not applicable to lakes and reservoirs less than
10 acres in surface area); the Commission or its designee may prohibit or limit any discharge of
waste into surface waters if, in the opinion of the Director, the surface waters experience or the
discharge would result in growths of microscopic or macroscopic vegetation such that the
standards established pursuant to this Rule would be violated or the intended best usage of the
waters would be impaired;
(b) Dissolved oxygen: not less than 6.0 mg/l for trout waters; for non -trout waters, not less than a daily
average of 5.0 mg/l with a minimum instantaneous value of not less than 4.0 mg/l; swamp waters,
lake coves or backwaters, and lake bottom waters may have lower values if caused by natural
conditions;
(c) Floating solids; settleable solids; sludge deposits: only such amounts attributable to sewage,
industrial wastes or other wastes as shall not make the water unsafe or unsuitable for aquatic life
and wildlife or impair the waters for any designated uses;
(d) Gases, total dissolved: not greater than 110 percent of saturation;
(e) Organisms ofthecoliformgroup: fecal coliformsshall not exceed ageometricmeanof200/100ml
(MF count) based upon at least five consecutive samples examined during any 30 day period, nor
exceed 400/100ml in more than 20 percent of the samples examined during such period; violations
ofthe fecal coliform standard are expected during rainfall events and, in some cases, this violation
is expected to be caused by uncontrollable nonpoint source pollution; all coliform concentrations
are to be analyzed using the membrane filter technique unless high turbidity or other adverse
conditions necessitate the tube dilution method; in case of controversy over results, the MPN
5-tube dilution technique shall be used as the reference method;
(f) Oils; deleterious substances; colored or other wastes: only such amounts as shall not render the
waters injurious to public health, secondary recreation or to aquatic life and wildlife or adversely
affect the palatability of fish, aesthetic quality or impair the waters for any designated uses; for the
purpose of implementing this Rule, oils, deleterious substances, colored or other wastes shall
include but not be limited to substances that cause a film or sheen upon or discoloration of the
surface of the water or adjoining shorelines pursuant to 40 CPR 110.4(a)-(b) which are hereby
incorporated by reference including any subsequent amendments and additions. This material is
available for inspection at the Department of Environment and Natural Resources, Division of
Water Quality, 512 North Salisbury Street, Raleigh, North Carolina. Copies may be obtained from
the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C.
20402-9325 at a cost of thirteen dollars ($13.00).
(g) pH: shall be,normal for the waters in the area, which generally shall range between 6.0 and 9.0
except that swamp waters may have a pH as low as 4.3 if it is the result of natural conditions;
(h) Phenolic compounds: only such levels as shall not result in fish -flesh tainting or impairment of
other best usage;
(i) Radioactive substances:
NORTH CAROLINAADMINISTRATIVE _CODE _cif. August 1, 2004 Paee 21

u)
(k)
(1)
0) Combined radium-226 and radium-228: the maximum average annual activity level
(based on at least four samples collected quarterly) for combined radium-226 and
radium-228 shall not exceed five picoCuries per liter;
(ii) Alpha Emitters: the average annual gross alpha particle activity (including radium-226,
but excluding radon and uranium) shall not exceed 15 picoCuries per liter;
(iii) Beta Emitters: the maximum average annual activity level (based on at least four samples,
collected quarterly) for strontium-90 shall not exceed eight picoCuries per liter; nor shall
the average annual gross beta particle activity (excluding potassium-40 and other
naturally occurring radio -nuclides) exceed 50 picoCuries per liter; nor shall the maximum
average annual activity level for tritium exceed 20,000 picoCuries per liter;
Temperature: not to exceed 2.8 degrees C (5.04 degrees F) above the natural water temperature,
and in no case to exceed 29 degrees C (84.2 degrees F) for mountain and upper piedmont waters
and 32 degrees C (89.6 degrees F) for lower piedmont and coastal plain waters. The temperature
for trout waters shall not be increased by more than 0.5 degrees C (0.9 degrees F) due to the
discharge of heated liquids, but in no case to exceed 20 degrees C (68 degrees F);
Turbidity: the turbidity in the receiving water shall not exceed 50 Nephelometric Turbidity Units
(NTU) in streams not designated as trout waters and 10 NTU in streams, lakes or reservoirs
designated as trout waters; for lakes and reservoirs not designated as trout waters, the turbidity
shall not exceed 25 NTU; if turbidity exceeds these levels due to natural background conditions,
the existing turbidity level cannot be increased. Compliance with this turbidity standard can be
met when land management activities employ Best Management Practices (BMPs) [as defined by
Rule .0202 of this Section] recommended by the Designated Nonpoint Source Agency [as defined
by Rule .0202 ofthis Section]. BMPs must be in full compliance with all specifications governing
the proper design, installation, operation and maintenance of such BMPs;
Toxic substances: numerical water quality standards (maximum permissible levels) for the
protection of human health applicable to all fresh surface waters are in Rule .0208 of this Section;
numerical water quality standards (maximum permissible levels) to protectaquatic life applicable
to all fresh surface waters:
0) Arsenic: 50 ug/l;
(ii) Beryllium: 6.5 ug/l;
(iii) Cadmium: 0.4 ug/l for trout waters and 2.0 ug/l for non -trout waters; attainment of these
water quality standards in surface waters shall be based on measurement of total
recoverable metals concentrations unless appropriate studies have been conducted to
translate total recoverable metals to a toxic form. Studies used to determine the toxic
form or translators must be designed according to the "Water Quality Standards
Handbook Second Edition" published by the Environmental Protection Agency (EPA
823-B-94-005a) or "The Metals Translator:. Guidance For Calculating a Total
Recoverable Permit Limit From a Dissolved Criterion" published by the Environmental
Protection Agency (EPA 823-B-96-007) which are hereby incorporated by reference
including any subsequent amendments. The Director shall consider conformance to EPA
guidance as well as the presence of environmental conditions that limit the applicability
of translators in approving the use of metal translators.
(iv) Chlorine, total residual: 17 ug/l;
(v) Chromium, total recoverable: 50 ug/l;
(vi) Cyanide: 5.0 ug/l; unless site -specific criteria are developed based upon the aquatic life
at the site utilizing The Recalculation Procedure in Appendix B of Appendix L in the
Environmental Protection Agency's Water Quality Standards Handbook hereby
incorporated by reference including any subsequent amendments;
(vii) Fluorides: L8 mg/l;
(viii) Lead, total recoverable: 25 ug/1; collection of data on sources, transport and fate of lead
shall be required as part of the toxicity reduction evaluation for dischargers that are out of
compliance with whole effluent toxicity testing requirements and the concentration of
lead in the effluent is concomitantly determined to exceed an instream level of 3.1 ug/l
from the discharge;
(ix) Mercury: 0.012 ug/l;
NORTH CAROLINA ADMINISTRATIVE CODE Eft: August 1, 2004 Page 22

0 0
(x) Nickel: 88 ug/l; attainment of these water quality standards in surface waters shall be
based on measurement of total recoverable metals concentrations unless appropriate
studies have been conducted to translate total recoverable metals to a toxic form. Studies
used to determine the toxic form or translators must be designed according to the "Water
Quality Standards Handbook Second Edition" published by the Environmental Protection
Agency (EPA 823-B-94-005a) or "The Metals Translator: Guidance For Calculating a
Total Recoverable Permit Limit From a Dissolved Criterion" published by the
Environmental Protection Agency (EPA 823-B-96-007) which are hereby incorporated
by reference including any subsequent amendments. The Director shall consider
conformance to EPA guidance as well as the presence of environmental conditions that
limit the applicability of translators in approving the use of metal translators.
(xi) Pesticides:
(A) Aldrin: 0.002 ug/l;
(B) Chlordane: 0.004 ug/l;
(C) DDT: 0.001 ug/l;
(D) Demeton: 0.1 ug/l;
(E) Dieldrin: 0.002 ug/l;
(F) Endosulfan: 0.05 ug/l;
(G) Endrin: 0.002 ug/l;
(H) Guthion: 0.01 ug/l;
(I) Heptachlor: 0.004 ug/I;
(J) Lindane: 0.01 ug/1;
(K) Methoxychlor: 0.03 ug/l;
(L) Mirex: 0.001 ug/l;
(M) Parathion: 0.013 ug/l;
(N) Toxaphene: 0.0002 ug/l;
(xii) Polychlorinated biphenyls: 0.001 ug/l;
(xiii) Selenium: 5 ug/l;
(xiv) Toluene. I 1 ug/1 or 0.36 ug/1 in trout waters;
(xv) Trialkyltin compounds: 0.008 ug/i expressed as tributyltin;
(4) Action Levels for Toxic Substances: if the Action Levels for any of the substances listed in this
Subparagraph (which are generally not bioaccumulative and have variable toxicity to aquatic life because of
chemical form, solubility, stream characteristics or associated waste characteristics) are determined by the
waste load allocation to be exceeded in a receiving water by a discharge under the specified low flow
criterion for toxic substances (Rule .0206 in this Section), the discharger shall monitor the chemical or
biological effects of the discharge; efforts shall be made by all dischargers to reduce or eliminate these
substances from their effluents. Those substances for which Action Levels are listed in this Subparagraph
shall be limited as appropriate in the NPDES permit based on the Action Levels listed in this Subparagraph
if sufficient information (to be determined for metals by measurements of that portion of the dissolved
instream concentration of the Action Level parameter attributable to a specific NPDES permitted discharge)
exists to indicate that any of those substances may be a causative factor resulting in toxicity of the effluent.
NPDES permit limits may be based on translation of the toxic form to total recoverable metals. Studies
used to determine the toxic form or translators must be designed according to "Water Quality Standards
Handbook Second Edition" published by the Environmental Protection Agency (EPA 823-B-94-005a) or
"The Metals Translator: Guidance For Calculating a Total Recoverable Permit Limit From a Dissolved
Criterion" published by the Environmental Protection Agency (EPA 823-B-96-007) which are hereby
incorporated by reference including any subsequent amendments. The Director shall consider conformance
to EPA guidance as well as the presence of environmental conditions that limit the applicability of
translators in approving the use of metal translators.
(a) Copper: 7 ug/l;
(b) Iron: 1.0 mg/l;
(c) Silver: 0.06 ug/l;
(d) Zinc: 50 ug/l;
(e) Chloride: 230 mg/l;
NORTH CAROLINA ADMINISTRATIVE CODE Eff August 12004 Pa a 23

M
For purposes other than consideration ofNPDES permitting of point source discharges as described in this Subparagraph, the
Action Levels in this Rule, as measured by an appropriate analytical technique, per 15A NCAC 02B .0103(a), shall be
considered as numerical ambient water quality standards.
History Note: Authority G.S. 143-214.1; 143-215.3(a)(1);
Eff. February 1, 1976;
Amended Efj. April 1, 2003; August 1, 2000; October 1, 1995; August 1, 1995; April 1, 1994; February 1,
1993.
15A NCAC 02B .0212 FRESH SURFACE WATER QUALITY STANDARDS FOR CLASS WS-I WATERS
The following water quality standards apply to surface waters within water supply watersheds that are classified W S-I. Water
quality standards applicable to Class C waters as described in Rule .0211 of this Section also apply to Class WS-1 waters.
(1) The best usage of WS-1 waters are as follows: a source of water supply for drinking, culinary, or
food -processing purposes for those users desiring maximum protection of their water supplies, waters
located on land in public ownership, and any best usage specified for Class C waters.
(2) The conditions related to the best usage are as follows: waters of this class are protected water supplies
within essentially natural and undeveloped watersheds in public ownership with no permitted point source
dischargers except those specified in Rule .0104 of this Subchapter; waters within this class must be
relatively unimpacted by nonpoint sources of pollution; land use management programs are required to
protect waters from nonpoint source pollution; the waters, following treatment required by the Division of
Environmental Health, shall meet the Maximum Contaminant Level concentrations considered safe for
drinking, culinary, and food -processing purposes which are specified in the national drinking water
regulations and in the North Carolina Rules Governing Public Water Supplies, 15A NCAC 18C .1500;
sources of water pollution which preclude any of these uses on either a short-term or long-term basis shall be
considered to be violating a water quality standard. The Class WS-1 classification may be used to protect
portions of Class WS-11, WS-1I1 and WS-1V water supplies. For reclassifications occurring after the July 1,
1992 statewide reclassification, the more protective classification requested by local governments shall be
considered by the Commission when all local governments having jurisdiction in the affected area(s) have
adopted a resolution and the appropriate ordinances to protect the watershed or the Commission acts to
protect a watershed when one or more local governments has failed to adopt necessary protection measures.
(3) Quality standards applicable to Class WS-1 Waters are as follows:
(a) MBAS (Methylene -Blue Active Substances): not greater than 0.5 mg/l to protect the aesthetic
qualities of water supplies and to prevent foaming;
(b) Nonpoint Source Pollution: none that would adversely impact the waters for use as a water supply
or any other designated use;
(c) Organisms of coliform group: total coliforms not to exceed 501100 ml (MF count) as a monthly
geometric mean value in watersheds serving as unfiltered water supplies;
(d) Phenolic compounds: not greater than 1.0 ug/l (phenols) to protect water supplies from taste and
odor problems from chlorinated phenols;
(e) Sewage, industrial wastes: none except those specified in Subparagraph (2) of this Paragraph or
Rule .0104 of this Subchapter;
(f) Solids, total dissolved: not greater than 500 me;
(g) Total hardness: not greater than 100 mg/l as calcium carbonate;
(h) Toxic and other deleterious substances:
(i) Water quality standards (maximum permissible concentrations) to protect human health
through water consumption and fish tissue consumption for non -carcinogens in Class
WS-1 waters:
(A) Barium: 1.0 mg/l;
(B) Chloride: 250 mg/l;
(C) Manganese: 200 ue;
(D) Nickel: 25 ug/l;
(E) Nitrate nitrogen: 10.0 mg/1;
(F) 2,4-D: 100 ug/l;
(G) 2,4;5-TP (Silvex): 10 ug/1;
(H) Sulfates: 250 mg/l;
NORTH CAROLINA ADMINISTRATIVE CODE E'ff. August]. 2004 Page 24

Report to: • 1') s R-o WATER QUALITY SECTION Page—Lof
CHAIN OF CUSTODY (COC) RECORD
kENTRAL
NC DENR/DWQ LABORATORY (check one): I I ARO I I WaRO
For Investigation of: 13 row to FQrvy�
Sample collector (print narne) `
and DM-1 forms completed by: i R-c)6 e 1� r-O (—V_- Sample collector's signature: L
Field storage condition4and location (when appl'Cable):
LoC V
Lab Use Only
LAB NO.
STATION NO.
STATION LOCATION
DATE
SAMPLED
TIME
SAMPLED
NUMBER
OF
CONTAINERS
I
5Tpd,3
+} wo
r., 113 o
3
lot
3
1' ui ` by (si n cure):
jL
Date
Time
Received by (signature):
Date
Time
elinq ash by (signatur ):
Date
Time
Received by (signature):
Date
Time
Relinquished by (signature):
Date
Time
Received by (signature):
Date
Time
Method of Shi ment circle one): Couri Hand -delivered Federal Ex ress UPS
Other:
5e C, V 4' { [i Scaled b Broken by:
Security Type and onditi ns:) I
INTRALARORATCIRV _ A1N nP CI18TC11)Y _ 1,nh 11rP f)n1v
LAB NUMBERS
FROM THROUGH
NUMBER
BOTTLES
ANALYSES
REQUESTED
RELINQUISHED
BY-
PLECEIVED
BY:
DATE
TIME
QAIForms\Sample Rcceiving\COC form WQ 4110/01dbs
Lk

M.ER CALIBRATION SHEET•
UNIT
D.O. METER
Meter Number.
SAN
DATE aoo(o TIME O S
SCT METER
Meter Number
NAME
Meter Mfg. by
Membrane Last Replaced Probe Last Replaced Meter Number
Batteries Last Replaced Batteries Last Replaced Probe Last Replaced
Red Line
Zero
Air
Red Line
Zero �.
Initial Callbratio'n initial Calibration
Temperature_
D.O. from Table
Barometric Pressure or Alt. Factor i
factor X D.O. from Table Calib. D.O.
... y�- - x ��Za �4
Meter Reading I
Meter Corrected to
Winkler
Winkler #1 ValXto
Winkler #2 Valu
Meter Reading
Meter Corrects
Standard 01 (147 umhos.)
Temperature _ o/- 12 1
Std. after Temp. Correction
Meter Reading I q
K Value a Std after Temp. Correction
Me er Reading
Value = {
{
K Value
Standard 12 (718 umhoe.)
Temperature - 2.{ . 1
Std, after Temp. Correction
Meter Reading
Batteries Last Replaced
Buffer Sol. Last Replaced F7 O
4
lnitia! Calibration
Buffer f1 {6.86 o oo)
Temperature 2 �. I �^
Buffer after Temp. Correction
Meter Reading _ —7 . d I
Meter Corrected to —? . C) 0
Buffer f2 2 r 9.11'8.1
Temperature
Buffer after Temp. Correction
Meter Reading 3
Meter Corrected to • ob
Final Calibration Finai Caltration Finai Calibratio h
Air Standard Value Buffer Value
Temperature a, - Temperature Temperature
D.O. from Table g . $(a
Barometric Pressure or Alt. Factor
factor X D.O. from Table /- s Calib, D.O.
•"1� x al
`�.`d� a Uas
Meter Reading . :3 m d. 5
Meter Corrected to
Winkler #t lue _
Winkler #2 Value
Meter Reading
Meter Corrected to
Std, after Temp. Correction
LAMeter Reading 1
Buffer after Temp. Correction --~-
Meter Reading
Meter Corrected to
COMMENTS: _ _

Report to
•
WATER QUALITY SECTION
CHAIN OF CUSTODY (COC) RECORD
NC DENR/DWQ LABORATORY (check one): kENTRAL I I ARO I I WaRO
S PLC
iR�c�rvel�
�l• Rapt. of ENR
JAM M�L of
i:;•1bton.5alem
Reglonaf office
For investigation of: 'j�, f 0 W >n Fo,v-vvl
��VV
�
Sample collector (print name)
and DM-1 Forms completed by:
� ii-?.� Cj ��_ti� C_i _ Sample collector's signature:
Field storage condition and location (when applicable):
Lab Use Only
LAB NO.
STATION NO.
STATION LOCATION
DATE
SAMPLED
TIME
SAMPLED
NUMBER
OF
CONTAINERS
&Umon
S zoo
1130
3
D
2
(�ha 0Lot
;zot
3
1' qui
by,(si n lure):
]
Date
Time
Receiv b na
t
Tim
elinq is 'by (signatu ):
Date
Time
Received by (signature):
Date
Time
Relinquished by (signature):
Date
Time
Received by (signature):
Date
Time
M thod of Shipment circle one):
Couri Hand -delivered Federal Ex res UPS Other:
, 7 ' �
Security T e andonditi ns:
Sealed b
Brien
INTRAI.AACIRATC)RV C AIN OF CUSTODY- i.ah llse Only
NUMBERS
FROM THROUGH
IWM!=
ANALYSES
REQUESTED
RELINQUISHEDAB
,IY
BY:
MEMO
QA\Fortns\Sample Receiving\COC farm WQ
01101dbs
`-k—
J

TRITEST
6300 Ramada Drive, Suite C2 Chain Of Custody Tritest W.O_#
m,
Clemons, NC 27012
Ph: [phone] Fax: [phone]
Report Results To: Bill To:
Company: IJ e- Dt� K)(-DE N g
Address: 515 Work-4VAoWh S+.
�Sl, \-\ -Nary "1-1 lerrn , N (--
Attn: P ,. � �. r OL*- , 1 f01
Phone: 11 `q
e .l r a •
Sampled by (signature):
Project Reference: -b cif W ri
Project Number:
Purchase Order #:
9 Standard Report Delivery
❑ Rush Report Delivery (w! sumharge)
"Fish proMm am object b prior oppuad by ft Iv6or+luY
Requested Due Date:
Sample Description
C R a
Gm
Start Date
start rune
End Date
End Time
Matrix
rim
Analyses Requested
TritasF
UQSk`eaVY)
I y Foro
U3o
Cr
113o
e a� C4�+ tcz .
O
y vio
o�
flow+n� rea
G
Im
a a s
R Fa
ti a a s
S
.t C_
w
I
L
9gnaReceived
r #
q
try (signanrel '
Dace
Tune
Receipt Conditions (Lab Use Only)
❑ 4±2-C 0 Temp: -- 'C
Res. Chlorine)<Absent ❑ Present)(Na
Acid preserv. <2? ❑ Yes KNo ❑ Na
Base preserv. >1 2? El Yes VNo ❑Na
Relin4uistred by (signature)
Received by (signatura)'
Data
Aetinq—hed by (signature)
Received try (signature)
Date
Tens

•
TRITEST
January 12, 2006
CLIENT NAME
CLIENT NUMBER
SAMPLE NUMBER
COLLECTED DATE
RECEIVED DATE
DESCRIPTION
TEST UNITS
FECAL COLIFORM #/100ML
CERTIFICATION #
CERTIFIED BY:
CERTIFICATE OF ANALYSIS
DENR / DWQ
800132
263351
263352
263353
1/4/06
114/06
114/06
114/06
114/06
1 /4106
us
END OF
DS
LOT
RESULTS RESULTS RESULTS
200
NC 103
NC 37733
3900 3400
•
TEL: [phone] FAX: [phone] WEB: www.tritestinc.com
6300 Ramada Drive, Suite C2, Clemmons, North Carolina 27012

TRiT€STD' ,
6300 Ramada Drive,- site C2
Clemmons, NC 27012
Ph: [phone] Fax: [phone]
Report Results To:
Chain of %: ustod
y
Bill To:
Company: N G - +g 0 N RL - r-1)w�.- -
Address: ` W aL%-xA- "fin ;,v n St .
W*, V-% s*ors f O- t� �-
Attn: Ifs` : O C.-V -:�- `!
Phone-1 "I Fax -
Sampled by (signature):
r� w� Tritest W.O.if
Project Reference:
Project Number:
Purchase Order M
XStandard Report Delivery
❑ Rush Report Delivery (w/ surcharge)
Rob pro M w sfted a prior M to labMOMy
Requested Due Date:
Sarrg)Ie Description
G.b
^
Start Date
Start Time
End Date
End Time
Matrix
oO
Analyses Requested
T
17 471,
{ ! 3 o
GCS
113c�
�'-C- Lotc.• iE-- oc,7
I�b
�ewn �r
i
a a s
R (signature)
41"L[
Received by (signature)
Date
j
OLD
Time
Receipt ConditiCns (Lab Use Only)
❑ 4±2°C ❑Temp: !� °C
Res. Chlorine)<Absent ❑ PresentKNa
Acid preserv. <2? ❑ Yes 14No ❑ Na
Base preserv. > 12? 13 Yes N/No ❑ Wa
Fla.pr shed by (Au.)
Received by (signw..)
Date
TWA
Rely q-4W by (signature)
Received by (signature)
Date
Tens

0
FAX
NORTH CAROLINA DEPARTMENT OF
ENVIRONMENTAL AND NATURAL RESOURCES
585 WAUGHTOWN STREET
WINSTON-SALEM, NC 27107
TELEPHONE : [phone]
DATE:
TO: ex-e- �L-
FAX
iq o�o
L�
3
OF PAGES (INCLUDING THIS PAGE)
FROM: I' l e 6 S 5 A-
NOTE: 4esr � auJ

SENDING CONFIRMATION
DATE JAN-19-2006 THU 17:05
NAME NC DENR
TEL [phone]
PHONE
: 918282643067
PAGES
: 3/3
START TIME
: JAN-19 17:04
ELAPSED TIME
: 00'49"
MODE
: ECM
RESULTS
: OK
FIRST PAGE OF RECENT DOCUMENT TRANSMITTED...
FAX
NORTH cAR01.1 N A 1)ErA1iTmN-r oM
Lh-VMONMXN7ALAND \ATL'3tAL REutiOliRas
5H5 WAUGUTOW N STREET
WINSTON-SALF.M, NC .27197
TELEPHONE : ;=6.711-46DD
GA\ NUMBER: 336-771-402
TO:1�—
VAX 0
- 3 -----B OF PAGES ILNCLUDTNC TTUS PAGh)
N UTH:
I(L.:,,f�n.C.�� 1 �I ��.i f' JI.�e.r..t,,�c.J P.{�+.�� ••-'�1fi��--�
!i
;��QQVui�'.24.' -.� 7°-�.�.� (,�rC (ies,-/,�.y J!'�i_r}P.-;�• �.�inp� Hof- fi.d-r._..J
'—'7�tJ-'1%%t�F;,A, � i.l-i,J �_•C!i�-�J. W-' i�.-Y�L�'r )
1 �n
/tc!� O.n._J A-�,'.}(i�•W r/J �? �.� !) ���Q 1 7.•-�-
.---1���•ltil-(✓'/1li

RECEIVED
NC Division of Water QLjalit Laboratory Section Resu,& N.C. Dept. of ENR
Loc. Descr.:
UPSTREAM OF BROWN FARM
JAN 3 .I mow,
Location ID:
BROWNFARMI
n
llemCoune
Sample ID:
ABpQinst
O
WATAUGA
PO Number #
6W0059
River B.
River Basin
VisitID
Report To
WSROSP
Region:
WSRO
Date Received:
01105/20D6
Collector:
M ROSEBROCK
Time Received:
10:00
Sample Matrix:
SURFACEWATER
Recv'd By:
CGR
Loc. Type:
RIVERISTREAM
Date Reported:
0112712006
Sample Depth
Collect Date:
01104/2006
Collect Time::
11:30
nalyte Name
PQL Result
Qualifier Units
Approved By
LAB
Sample temperature at receipt by lab 1.0
°C
JGOODWIN
mic
BOD, 5-Day in liquid'
2.0
2
UG5G6 mg1L
CGREEN
Turbidity
1
3.2
NTU
CGREEN
NUT
NH3 as N in liquid
0.02
0.02
U mglL as N
CGREEN
NO2+NO3 as N in liquid
0.02
2.8
mglL as N
CGREEN
Phosphorus total as P in liquid
0.02
0.04
mg1L as P
CGREEN
Total Kjeldahl N as N in liquid
0.2
0.20
mg1L as N
CGREEN
k
Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]

t
COUNTY WATAUGA
R,VER BASIN:
REPORTTO WSRO Rcgioml Office
Other
COLLECTOR(S) : M ROSEBROCK
Estimated BOD Range:
Seed: Chlorinated:
katian N I Date Begin (yylmmldd)
X
BOD 310 21.1 G5 Ge mLJL
COD High 340 mg/L
COD Low 335 mgfL
Colifonm: MF Fecal 31616 11OOml
Coliform: MF Total 31504 1100031
Colifum- tube Feel 31615 f 1 OOml
Coliform: Fecal St 31673 /10(kni
Residue: Total 500 m9fL
Volatile 505 mg/L
Fixed 510 m
Residue: Suspended 530 m
Volatile 535 m
Fixed $40 mg/L
H 403 n as
Acidity to pH 43 436 mg/L
Acidi to H 9.3 435 mgfL
Alkaliniry to PH 8.3 415 mglL
Alkalniry m PH 4.5 410 m
TOC 6811 MCI
X
idity 76 3.2 NTU
iform Total Tube "/100 ml
COMMENTS:
DIVISION OF WATER QUALITY
Chemistry Laboratory Report I Water Quality
SAMPLE TYPE
PRIORITY
AMBIENT Qw X❑ STREWN EFFLUENT
COMPLIANCE CHAIN OF CUSTODY LAKE INFLUENT
EMERGENCY VISIT 113
ESTUARY
1
Station Location: UPSTREAM OF BROWN FARM
Remarks:
End (yylmm/dd) Time Begin I Time End I Depth - DM. DB. UBM
Cblaride 940 mglL
Chi a: Tri 32217 U911-
Chi a: Corr 32209 ug/L-
Pbmpbytin a 32213 u
Cover: Tmse 90 e.0
Color. (H ) 83 pH. c.0
Color. pH 7.6 82 C.U.
Cyanide 720 m
Fluoride 951 mVL
Fomuddeh 71880 mglL
Grease and Oils 556 m '
Hardiness Toul900 mgfL
S iftc Cond. 95 tanhoslcrm
MBAS 38260 mg1L.
Pha ots 32730
Sulfate 945 mSfL
Sulfide 745 mLll-
113arton
Tannin & Li is ug/L
Hexavalem Chromium ugJL
Bicarbonate mgtL
Carbonut mgfL
Total Dissolved Solids mg1L
Lab Nmmba 6WO059
Date Received : 115/2006
Time Received - 10:00 AM
Received By D
qcI0:
eased
Date Repotted : 1f25=06
Value Type - A. H. L I Composite-T. S. ll Sample Type
%
NH3 as N 610
0.02U
X
TKN an N 625
0.20
m
X
NO2 plus NO3 as N 630
2.8
m
X
P: Total as P 665
0.04
m
PO4 as P 70507
mgA-
P: Dissolved as P 666
malL
K-Potassium
mglL
Cd-Cadmium 1027
u
Cr-Chromium:Tatal 1034
Cu- Copp, 1042
U911-
Ni-Nickel 1067
UBIL
Pb- Lcad 1051
UFL
Zn- Zinc 1092
ugfL
V-Vanadium
UWL
A - Silver 1077
ta91L
A]- Aluminum 1 105
ug/L
Be- Beryllium 1012
uglL
Ca- Calcium 916
mg/L
Co- Cobalt 1037
Fe- Iron 1045
ua
Mn-Mot hdenum
uSIL
Sb-Amimony
ug/L
Sn-Tin
T]-Thallium
ua
Ti-Titanium
ugll.
H -1631
Li-liduum 1132 WL
Mg- Magnesium 927 mgtL
Mn-Manionest 1055 u
Na- Sodium 929 mpjL.
Amcnic:Total I002
Se- Selenium 1147
H - Memury 7t900 ug/L
Ba-Barium ugfL
Orgprwc,lmne Pesticides
Pesticides
Acid Herbicides
BmefNcuua &Acid Extractable Organics
TPH Diesel Ranp
Purpgbje Organics (VOA bottle 'd)
TPH Gasoline Range
TPH/8TE7C Gasoline
Phymplanklon

DIVISION OF ENVIRONMENTAL MANAGEMENT WATER QUALITY EL FORM (DM1)
C
COUNfY PRIORITY PLC TYPE
,MVER BASIN - Q.
IEPORT TO: ARO FRO MnO RHO WaRO WIR WSRO TS DAMBIENT QA STREAM ❑ EFFLUENT
B !T M1:1VT COMPLIANCE CHAIN LAKE INFLUENT
OF CUSTODY
ihipped by: Bus ou�rle }Staff, Other ❑EMERGENCY ❑ESTUARY
rnr r.an uso. urvr_r
Lab Number:
Date RecelvedA--5,6,6
Tim
Rec'd b From: Bu ourie sand Del
DATA ENTRY BY: CK:
DATE REPORTED:
,OLLECTORISI: in IZOI)e—lQ 1'c CIL
STATION LOCATION: r0>-i
Estimated BOD Range: 0-5 -25 5-65/40-130 or 100 plus
Seed: Yes ❑ No�( Chlorinated: Yes ❑ No V REMARKS:
Staifan] Date Begin (yy/mm/dd) Time Begin I Date End Time End Depth DM DB DBM Value Type
to o f Loy{ 11 =3 o 010 OL 6q1 113 d 1
A H �L
1
BODS 310 mg/l
COD High 340 mg/t
3
COD Low 335 mg/1
4
Collform: MF Fecal 31616 /100ml
5
Collform: MF Total 31504 /10om1
6
Collform: Tube Fecal 31615 /loom]
7
CnlllOrm: Fecal Strep 31673 /loom]
S
Residue: Total 500 mg/1
9
Volatile 505 mg/1
10
Fixed 510 mg/I
11
Residue: Suspended 530 mg/I
12
Volatile 535 mg/l
131
Fixed 540 mg/l
14
pH 403 units
15
Acidity to pH 4.5 436 mg/1
Acidity to pH 8.3 435 mg/I
1
Alkalinity to pH 8.3 415 mg/I
18
Alkalinity to pH 4.5 410 mg/]
19
TOC 680 mg/I
20
Turbidity 76 NTU
Chloride 940 mg/I
Chi a: Tri 32217 ug/I
Chl a: Corr 32209 ug/l
Pheophytin a 32213 ug/I
Color: True 80 Pt -CO
Color:(p1f ) 83 ADMI
Color: p11 7.6 82 ADMI
Cyanide 720 mg/l
Fluoride 951 mg/1
FOrmaldehyde 71880 mg/I
Grease and Oils 556 mg/l
Hardness total900 mg/I
Specific Cond. 95 2 uMltos/cm
MBAS 38260— mg/1
Phenols 32730 ug/1
Sulfate 945 m9A
Sulfide 745 mg/1
NH3 as N 610 mg/l
TKN as N 625 mg/1
NO2 plus NO3 as N 630 mg/I
P. Total as P 665 mg/I
PO4 as P 70507 mg/1
P: Dissolved as P 666 mg/I
Cd-Cadmium 1027 USA
CrChramlum:Total1034 ugA
Cu-copper 1042 ug/1
Ni-Nickel 1067 u9/1
Pb-Lead 1051 ug/I
Zn-Zinc 1092 ug/1
Ag-Silver 1077 ug/I
AI -Aluminum 1105 ug/1
Be -Beryllium 1012 ug/I
Ca -Calcium 916 mg/1
Co -Cobalt 1037 ug/l
Fe -Iron 1045 ug/1
Composite Sample T
T S B C! G 1 GNXX
LI-Lithium 1132 �./ ug/l
Mg -Magnesium 927 mg/I
Mn-Manganese 1055 ug/1
Na-Sodium 929 mg/1
Arsenlc:Total 1002 ug/I
Se -Selenium 1147 ug/1
Hg-Mercury 71900 ug/I
Organochlorine Pesticides
Organophog6orus Pesticides
Acid Herbicides
HBase/ Neutral Extractable Organics
Acid Extractable Organics
Purgeable Organics {VOA bottle reg'd)
Phytoplankton
Sampling Point %
Conductance at 25 C
ater Temperature (
D.O. mgA
pll
Alkalinity
Acidity
Air Temperature (C)
S5
A
lb. oZ
0
M3 p i8114.5
pit 4.5 pit 8.3
0.0
2
94
10
300 -
400 •
82244 431
B2243 IBZ242
20
Salinity `5
Preclpitlan On/day)
Cloud Cover %
Wind Direction (leg)
Stream FLOW Severity
Turbidity Severity
Wind Velocity M/H
vlean Stream Depth It.
Stream Width ft.
480
45
32
136
11351
1350
135
64
14
O L

C DENR/DWQ Laboratory
Report to: WSRO ample Anomaly Report (SAR)
Lab Number: 6WO059 Sample ID:
Station Location: UPSTREAM OF County. WATAUGA
BROWN FARM
,sample Type: STREAM
Date collected: • 01/04/06 '
Affected Parameter(s): BOD
Priority: CHAIN OF
CUSTODY
0
Region: WINSTON-SALEM
Collector: M. ROSEBROCK
Date received: 01/05/06 Date analyzed:
Analytical Area (check one):
❑ WCH [—]METALS
❑NUT ®MICRO
The following anomalies occurred (check all that apply):
❑Samples
❑Improper container used
❑VOA vials with headspace
❑Sulfide samples with headspace
❑Samples not received, but listed on fieldsheet
[]Samples received, but not listed on fieldsheet
❑Mislabeled as to tests, preservatives, etc.
[]Holding'time expired
[]Prior to receipt in lab
[]After receipt in lab
❑Insufficient quantity for analysis
El Sample exhibits gross non -homogeneity
❑Sample not chemically preserved property
❑pH out of range (record pH):
❑Improper chemical
❑Residual chlorine present in sample
❑Color interference
❑Heavy emulsion formed during extraction
❑Sample bottle broken in lab - no reportable results
❑Other (specify):
01/05/06
[_]VOA ❑SVO
❑PEST
®Quality Control
❑Instrument failure — no reportable results
❑Analyst error — no reportable results
❑ Surrogates
❑None added
❑Recovery outside acceptance Iimits
[]Spike recovery
[]None added
❑Recovery outside acceptance limits
❑Failed to meet criteria for precision
❑Internal standards '
[]Blank contamination
®QC data reported outside of controls (e.g., QCS, LCS)
❑lncorrect procedure used
❑SOP intentionally modified with QA and Branch Head
approval
❑Invalid instrument calibration
❑Elevated detection limits due to:
❑Insufficient sample volume
Comments: One GGA standard and the seed correction factor were outside of limits. GGA standards were 132 and 180.5 mg/L
(198 ± 30.5 mg/L) and seed correction was 1.2 (0.60-1.0).
Corrective Action:
❑Samples were rejected by DWQ Lab. Authorized by: Date:
❑Accepted and analyzed after notifying the collector or contact person and determining that another sample could not be secured.
❑Sample(s) on hold until:
®Sample reported with qualification. Data qualification code used: G5, G6
❑Other (explain):
Notification Required? ❑ Yes' ❑ No
Person Contacted: Date:
Form completed by:
Lead Chemist Review fir
A l0CHE -, [:]PEST
❑METALS ❑ VOA
Branch Head Review (initial
QA/QC Review (initial ,
Date: 1 / 10/06
❑SVGA _
Logged into database by (initial):

search
http:/Ibim .enr.state.nc.us:7001/maintainIncident2.do
.
W Delete
Incident Detailsl Incident DetailsZ Agencies Material Categories
Events Related Incidents Action History
* Incident Type: Complatnt, j j ?,
Incident Number pt]60QIN
* ...............
Category: 1 Animal
* Started Date/Time : 121191200s F4.00 pm
County: •'h+atauga ice:
FarmN:l Q• Z
Decimal DD:MM:SS
Latitude: Position Accuracy:[Selectvalue-
Longitude; Position Method: ---Select Value---
Position Datum: ---Select Value---
Reporting Person : r Anonymous
First Name jPeter
Address :1wsro
Middle Name :
85 Weughtown St
Last Name jPozzo
City : inston-Salem
State/Zip : NC 7107
Phone : [phone] F__
Cell/Pager : r
" Location of the Incident : Fd. Moretz Road
Address: 1106 wade Moretz Rd
City/StatelZip: IDeep Gap NC 128618
Cause/Observation of the incident :
Staff of APS observed potential impact to surface
water due to cattle access and traffic in creek.
Action Taken
M. Rosebrock notified staff (Derek Goddard) of
Watauga SWCD/NRCS of complaint. Derek investigated
site in question and reported back to APS animal
inspectoron his observations.
Surface Water Impacted : t' Yes C; No r Unknown
Waterbody :I Meadow Creek - 10-1-17
Waterbody (Other) m.;1r� „.. �r` ,:3�. '.!1,6-1€aE;a;AJ
Report Received By:.Ro--.........................-....._-..........._....•....-_
sebrock, Melissa
Phone : (336)7.7r1;4600
Date/Time : 12/1912005 4:00 pm
Referred Via : [---Select Value--- J
Directions :
Hwy 421 north. Right onto Brownwood Road. Left
onto wade Moretz Road. Cattle lot is on right.
Comments/Findings
APS staff visited site on 1/4/2006 and observed
approx. 800 ft. of impact in the'creek. Stream
samples were obtained for analysis.
Water Supply Wells within I500ft : r Yes r No 0 Unknown
Groundwater Impacted : r Yes r No re Unknown
'I'%;Flnlsh'3' 13'Cancel(.a'
Conveyance :' Unnamed tributaryL;I
RO Contact : Rosebrock, Melissa ,
Phone : (336)771,atzQt7J , � _$3,t 14,1j
Date/Time: 12/1912005 :00 PM
_.
Referred Via : ` Select Value---
I of 1 1 i 10/2006 3:08 PM

search
http;//bienr.state.ne.us: 7001/maintain Incident l.do
Incident Detallsi Incident Details2 Agencies Material Categories Events Related Incidents Action History
Incident Type : Complaint Incident Number : 200600102
Doterrime : 12/19/2005 04:00 pm
County : Watauga City: Deep Gap
Responsible Party :
Incident Owner : - -.' , : i "�" .-77 ! Find Droner Clear
Permit Find Permit 191syl
Facility.,.;if�a;.dlail.6„1'>r�;°r.16:J;( Find Facility lClearl
First Name : a ;w,.;j�.,i.;:is;;,"mod Address : IMack erownlncJ;;„•;a ; ;;�;.%;i s�'
Middle Name : Po a• �e8 t 1,dLi 1
Lust Name : 9,7-i::7,i Li City:
Company Name :jMac Drawn lac iy ;_ I Statealp : tlC,;,fy'I 86b7 ;;amm7 J
Phone : a2aJ291-01151d ;•y,;�j;,;;j CelllPager : :',d,•w;;;,;j
(Clear Responsible Pnrtyj
Onsite Contact
First Name:
Middle Name : r
Last Name
Contact Agency
Phone • a28)2w-0u5)?_„
CelllPager 7777U
Fish Kill : C Yes f) No R Unknown
Containment: f. Yes f No F Unknown
Report Entered By : Ro•.brork Menas. w?-
Phone: saelnusao� _tsss�j
Date/Time: tncrsooa9?a:al sslvi"::al.
Estimated Fish Kill : _ .;'�€I:a.. 1
Cleanup complete: r Yes (,- No a Unknown
Storage tank ; r. AST r. UST
Written Report Requested • 7-.:1::-..;!,_i Well Contractor33lCjjerttf: s7i; t7.
• f6 HI l i d3i t i ! t1 1_ f1 1 11' �i l i�'I Ji i34
Information Requested
�E14 yy
Closed Date:
?Flnl.t�� r'canui`
1 of 1 1 / 10/2006 3:13 PM

Driving ]Directions from 585 Waughtown St, Winston Salem, NC to ... http://www.mapquest.cdirections/main.adp?do=prt&mo=ma&2s..
I of 4
�.,jm j-*-
Start: 585 Waughtown St
Winston Salem, NC
27107-2275, US
End: [100-699] Wade Moretz Rd
Deep Gap, NC 28618, US
Directions
Distance
Total Est. Time: 1 hour, 32 minutes Total Est. Distance: 81.06
miles
1: Start out going SOUTHEAST on WAUGHTOWN ST
<0.1 miles
toward OLD LEXINGTON RD.
A\
2: Turn RIGHT onto OLD LEXINGTON RD.
<0.1 miles
2
3: Turn RIGHT onto E SPRAGUE ST.
0.1 miles
g2
4: Merge onto US-52 S / NC-8 S [JOHN M GOLD
0.2 miles
FWY via the ramp on the LEFT toward US-311 S.
5: Merge onto I-40 W via EXIT 107B toward
5.1 miles
STATESVILLE.
azt
6: Merge onto US-421 N via EXIT 188 toward
45.7 miles
YADKINVILLE / WILKESBORO.
ORT
7: US-421 N becomes US-421 BYP N.
4.6 miles
4$t
DYP.
aZt
8: US-421 BYP N becomes US-421 N.
22.7 miles
l
9: Turn RIGHT onto BROWNWOOD RD.
2.0 miles
NV
"1,
10: Turn LEFT onto WADE MORETZ RD.
0.3 miles
=11: End at [100-699] Wade Moiretz Rd
Va mIle- doWV) an ri�hf
r) ear
l 1 / 14/2005 12:41 PM

Driving Directions from 585 Waughtown St, :ton Salem, NC to ... http://www.mapquest.com/directions/main.adp?do=prt&mo=ma&2s..
Directions Distance
Total Est. Time: 1 hour, 32 minutes Total Est. Distance: 81.06
miles
2 of 4 11/14/2005 12:41 PM

.Driving Directions from 585 Waughtown St, Winston Salem, NC to ... http://www.mapquest.com/directions/main.adp?do=prt&mo=ma&2s..
pt�srpah r
lie
i1
E}P±%hlRt irp!•i,.. i� t°"�,j . '\ `il-i-I: �0� } �� it
Q owcll RAM P' o
doodfawnj : ta>tville W 'dlaaf
"' 12 Mo atita"'i: o i
i
C va
Newlan
ka outm 42
Sta rt:
585 Waughtown St
Winston Salem, NC 27107-2275, US
30Q
_.+
VCO
These directions are Informational only. No representation is made or warranty glen as to their content, road conditions or route L
expeditiousness. User assumes all risk of use. MapQuest and Its suppliers assume no responsibility for any loss or delay resulting fi
use.
4 of 11/14/2005 12:41 PM

MapQuest: Maps
E
http://�vww.mapquest.com/maps/print.adp?mapdata=Qg5DZUIxQC
[100-699] Wade Moretz Rd
Deep Gap INC
28618 US
Notes:
Get -Our
F e
BEST:I'RATF`
y
IofI
11/14/2005 12:43 PM

77
,sty P •
.ram\1
0a'
4
r
I,
.t N k
E � y 5 � t�'� � mot• �! �� .
. �. i I . �, '1,�'k[�'9 x`
NL f
I N-11 �i .
' - a� � � 9 y .y�„ 4'syxaLL. ', 1 . !�� ;,.. F .e � A'• i 1' yj�.a���9 1, ��� '
*'i • f ,�,;, � �;� � � � ; per �.- d � i i� � ,�� Fill „�.I l �k, {�
a
u' p
pia t4'f g `L F °� y
a

V lON -
Far Lab Use ONLY
INNIS"
OF LNVIRONhiENIAL MANAGL•MENC WATER QIJALIIY 1•11-LD-LAB FORM (1)M1}
COUNTY PRIORITY SAMPLE TYPE
RIVER BASIN NeV U
REPORT TO: ARO FRO MRO RHO WORD W1R WSRq TS ❑AFinIENT QA STREAM ❑ EFFLUENT
AT BM
Other ❑COMPLIANCE CHAIN LAKE ❑ INFLUENT
OF CUSTODY
Shipped by: BusC-1—DI-11
Staff, Other ❑EMERGENCY ❑ESTUAItY
Lab Number:
Date Received: Time:
Rec'd by: From: Bus -Courier -Hand Del
DATA ENTRY BY: CK:
DATE REPORTED:
COLLECTO_R(S):^M KnS'e'blf'OC_iL
Estimated BOD Range. 0-5 -25 5-65/40-130 or 100 plus STATION LOCATION:_
Seed: Yea ❑ No�( Chlorinated: Yes ❑ No V REMARKS:
Station ?7! date Begin (yy/mm/ddl Time Begin Date End Time EnJ Depth DM DB DBM Value Type Composite Sample T
O(a . b1 .0y y,3O 010..& Aq 1113 0 A H L T S R .C'((,')GNXX
1
BOD5 310 mg/l
2
COD High 340 mg/I
3
COD Lour 335 mg/I
4
Collform: MF Fecal 31616 /100ml
5
Collform: MF Total 31504 /100m1
6
Collform: Tube Fecal 31615 /100ml
7
COIIIGTM: Fecal Slrep 31673 /100ml
8
Residue: Total 500 mg/I
9
Volatile 505 mg/l
10
Fixed 510 mg/l
11
Residue. Suspended 530 mg/I
12
Volatile 535 mg/I
13
Fixed 540 mg/1
14
PH 403 units
15
I Acidity to pH 4.5 436 m9A
16
Acidity to pH 8_3 435 mg/I
17
Alkalinity to pH 8.3 415 mg/I
18
Alkalinity to pH 4.S 410 mg/l
19
TOC 680 mg/1
20
Turbidity 76 NTU
Chloride 940 mg/i
Chl a: Tri 32217 ug/I
Chl a: Corr 32209 ug/I
Pheophytln a 32213 u9/1
Color: True 80 Pt -Co
Color.(pll 1 83 AI)MI
Color. pit 7.6 82 ADMI
Cyanide 720 tug/I
Fluoride 951 nrgll
Formaldehyde 71880 tng/l
Grease and Oils 556 nrg/I
Ilardness Total900 mg/I
Specific Cond. 95 011hus/cm2
MRAS 38260 ntg/1
Phenols 32730 ug/I
Sulfate 945 mqA
Sulfide 745 mg/I
NIi3 as N 610 mg/1
TKN as N 625- mg/l
NO2 plus NO3 as N 630 mg/I
P: Total asp 665 mg/I
PO4 as 1' 70507 mgA
P: Dissolved as P 666 mg/I
Cd-Cadmium 1027 ug/l
Cr-01rotnioin:Tola11034 ugA
Cu-copper 1042 ugll
NI -Nickel 1067 ug/l
Pb-Lead 1051 ug/I
Zn-Zinc 1092 ug/I
Ag-Sliver 1077 ug/1
AFAlutnlnum 1105 ug/I
Be -Beryllium 1012 ug/E
Ca -Calcium 916 mg/i
Co -Cobalt 1037 ug/I
Fe -Iron 1045 ug/1
LI-Lithlum 1132
ug/l
Mg -Magnesium 927
mg/(
Mn-Manganese 1055
ug/I
Na-Sodium 929
mg/I
Arsenic:Total 1002
ug/I
Se-Seienlum 1I47
ug/I
Ifg-blercury 71900
ug/1
Organochlorine Pesticides
Organoplurlfl`orus Pesticides
I I Acid 1 lerbicides I
IBase/ Neutral Extractable Organics I
Acid Extractable Organics
rgeable Organics (VOA bottle reg'd)
I Plrytoplanklon I
Sampling Point S i
Conductance at 25 C
Natef Temperature
D.O. usg/1
pl l
Alkalinity
Acidity
Air Teenlrerature (C)
S.Sr.
510
lodz
C�1418.3
1E14.5
1,114.5 p118.3
in. 0
94
202
Salinity
Precipltion 0n/day)
Cloud Cover R
Wind Direction (Deg)
Stream Flow Severity
Turbidity Severity
Wind VelocilyM/11 lean Stream Depdr It.
Stream Width It.
_J o
480
45
32
36
1351
1350
35 64
4
DMI/Revised 10/86

DIVISION Or ENVIRONMENTAL MANAGEMENT WATER QUALITY 1-11-LD-LAB FORM11 (I)M1)
COUNTY Q PRIORITY
RIVER BASIN
REPORT TO: ARO FRO MRO RRO WaRO WI RO WSR TS ❑AMBIENT ❑ QA
AT BM
Other - ❑COMPLIANCE CIIAIN
OF CUSTODY
Shipped by: Bus Warier Staff, Other
❑EMERGENCY
COLLECTOR(S):_ rn� C) S Q 1p r-o C LLB _
Estimated DOD Range: 0- 5-65/40-130 or 100 plus STATION LOCATION;
5-25/
Seed: Yea ❑ No)9 Chlorinated: Yes ❑ No V REMARKS: h
Station # Date Begin (yy/mm/dd) Time Regin Date End
10(0 O O 4Zb0 fo b
1 BODS 310 mg/1
2
COD High 340 mg/I
3
COD Low 335 mg/1
4
Collform: MF Fecal 31616 /IOOml
5
Coliform: MF Total 31504 ./100ml
6
Coliform: Tube Fecal 31615 /IODml
7
Collform: Fecal Strap 31673 /1DOml
8
Residue: Total 500 moll
9
Volatile 505 mg/I
10
Fixed 510 mall
11
Residue: Suspended 530 moll
12
Volatile 535 moll
13
Fixed 540 mg/I
;4
pH 403 units
15
Acidity to pH 4.5 436 mg/I
16
Acidity to pH 8.3 435 mg/I
17
Alkalinity to pH 8.3 415 mg/I
18
Alkalinity to pH 4.5 410 moll
19
TOC 680 mg/1
YQ
Turbidity 76 NTU
SAMPLE TYPE_
Ci-STREAM
❑ LAKE
ESTUARY
��j
❑
EFFLUENT
❑
INFLUENT
1=nr Lnh 11— f1Nr V
Lab Number. -
Date Recelved: Time:
Rec'd by: From: Bus•Cnurler•lland Del
DATA ENTRY BY: CK;
DATE REPORTED:
Time EnJ Depth DM DB DBM Value Type Composite Sample T
a A H L T S B C G GNXX
Chloride 940 mg/I
Chi a: Tri 32217 ug/1
Chi a: Corr 32209 ug/I
Pheophylln a 32213 ug/I
Color. True 80 Pt Ca
Color:(pll ) 83 ADMI
Color: pll 7.6 82 ADMI
Cyanide 720 mg/I
1 mg/I
hyde 71880 mg/]d
Dlls 556 mg/I
Tota1900 mg/1
F
ond. 95 2
_26D ntg/1
2730 will
Sulfate 945 mg/1
Sulfide 745 mg/1
'NH3 as N 610 mg/1
KN as N 625 mg/1
NO2 plus NO3 as N 630 m9/[
: Total as P 665 mg/I
PO4 as P 70507 moll
P: Dissolved as P 666 moll
Cd-Cadmium 1027 ugA
Cr-Chromium:TOtal1034 u9A
Cu-Copper 1042 ug/1
NI -Nickel 1067 USA
Pb-Lead 1051 ug/I
Zn-Zinc 1092 ug/I
Ag-Sliver 1077 uo/I
AI -Aluminum 1105 u9/1
U;ii I' 12 ug/1
Ca -Calcium 916 moll
Co-Cubalt 1037 ug/l
Fe -Iron 1045 ug/1
LI-Lithlum 1132 ugA
Mg -Magnesium 927 mg/
Mu -Manganese 1055 ug/l
Na-Sodium 929 mg/I
Arsenic:Total 1002 ug/1
Se-Selenlum 1147 ug/l
Jig -Mercury 71900 ug/I
Organochlorine Pesticides
Organop oGomrus Pesticides
Add 1 Ierbicides
Base/ Neutral Extractable Organics
Acid Extractable Organics
Purgeable Organics (VOA bottle reg'd)
Phytoplank ton
Sampling Paint X
Conductance at 25 C
Water Temperature
U.O. moll
Idl^—
Alkalinity
Acidity
Air Temperature (C)
S 9
1
ICI{ 8.3 pll 4.5
pli 4.5 pll 8.3
O
2
94
0
300 1•
400 1•
82244 431
82243 82242
20
Salinity X
Precipition an/day)
Cloud Cover %
Whid Direction Weg)
Stream Flow Severity
Turbidity Severity
WindM/li
Sean Stream Depth it.
Stream Width ft.
S—
,,VVelocity
V —3
0 (-10
�� O
480
45
32
36
1351
1350
35
64
4
�J
J
10/86

D1V[S(ON`_OtF ENVIRONMENTAL MANAGEMENT WATT R Q11ALITY 111--l-I-LAB FORM (DIA0
V
COUNTY o v&� 1 PRIORITY SAMPLE-.TYPF-
RIVER BASIN e.
REPORT TO: ARO FRO MRO ARO WaRO WIRO WSRO S �MBIENT QA STREAM ❑ EFFLUENT
Other
er ❑COMPLIANCE RAIN ❑ LAKE ❑ INFLUENT
Other
F CUSTODY
Shipped by; Busourie _ Staff. Other ❑ EMERGENCY ❑ ESTUARY
COLLECTOR(S): MP--OSe-biOL--- r+
Estimated BOO Range: 0-5/5-25 25-65 0 L30 or 100 plus STATION LOCATION: P o, .O �2 O
Seed: Yes 1-1 No Chlorinated: Yes El No REMARKS: AnS {��� 0.S�e yR) (} ��
Station # Dale Begin (yy/mm/dd Time Begin Date End Time End Depth DM DB DBM ji
b(p of o� tizas 06 0E 0q ►al
1
X
BOD5 310 m9/1
2
COD High 340 mg/I
3
COD Low 335 mg/1
4
Coliform: MF Fecal 31616 /100MI
5
Coliform: MF Total 31504 /100ml
6
Coliform: Tube Fecal 31615 /100ml
7
Coliform: Fecal Strap 31673 /100ml
8
Residue: Total 500 mg/I
9
Volatile 505 mg/I
to
Fixed 510 mg/1
11
Residue: Suspended 530 mg/I
12
Volatile 535 mg/I
13
Fixed 540 mg/I
14
pH 403 units
15
Acidity to pH 4.5 436 mg/1
16
Acidity to pH 8.3 435 mg/I
17
Alkalinity to pH 8.3 415 mg/I
18
Alkalinity to pH 4.5 410 mg/1
19
TOC 680 mg/I
Turbidity 76 NTU
Chloride 940 mg/1
Chi a: Tri 32217 ug/I
Chi a: Cott 32209 ug/I
Plreophytln a 32213 ug/I
Color: True 80 Pt -Co
Color:(pll } 83 ADMI
Color: pil 7.6 82 ADMI
Cyanide 720 mg/1
Fluorkle 951 mg/I
Formaldehyde 7t880 mg/I
Grease and Oils 556 mg/1
Ilardness Total900 mg/I
Specific Cond. 95 UNIhos/cm2
MBAS 38260T Ing/I
Phenols 32710 u0/I
Sulfate 945 mgA
Sulfide 745 mg/I
t,or Lab HA.. ON1 V
Lab Number: _
Date Received: Time:
Rec'd by: From. Bus-Courier-liand Del
DATA ENTRY BY: CK:
DATE REPORTED:
re t ype
A H L
NiM as N 610 mg/I
KN as N 625- mg/I
02 plus NO3 as N 630 mgA
Total as P 665 mg/1
PO4 as P 70507 mgA
P. Dissolved as P 666 mg/I
CdCadmlum 1027 ugA
CrChromlum:Toast 1034 ug/1
Cu-Copper 1042 ug/I
Nl-Nickel 1067 ug/I
Pb-Lead 1051 ug/I
Zn-Zinc I092 ug/I
Au -Sliver 1077 ug/1
AI -Aluminum 1105 ug/l
Be -Beryllium 1012 ug/I
Ca -Calcium 916 tngA
Co -Cobalt 1037 ug/I
Fe -iron 1045 ug/I
t=ompostie
T S B
aampte 7
C GNXX -
LI-Lithium 1132 ug/I
Mg -magnesium 927 mg/
Mn-Manganese 1055 ug/I
Na-Sodium 929 mg/1
Arsenic:Total 1002 ug/1
Se -Selenium 1I47 ug/I
Hg-Mercury, 71900 ug/I
Organochlorine Pesticides
Organophosphorus Pesticides
f 1 Add Herbicides
l Base/ Neutral Extractable Organics
Acid Extractable Organics
1 1 Purgeable Organics (VOA bottle reg'd)-
i . [phytoplanklon f
Sampling Point x
Conductance at 25 C
Nater Temperature (CI
Q.O. m9A
6hl1
JAI � ��
� Alkalinity
8.3 141 4.5
Acidity
pll 4.5 p11 8.3
Air Temperature (C)
� ] -7
U 1
,
I D .O
2
94
10
301)
400
82244 431
82243 182242
20
Salinity %
Precipition (In/day)
Cloud Cover
Whid Direction (Deg)
Stream now Severity
Turbidity Severity
Wind Velocity M/H
Sean Stream Depth ft-
Stream Width It.
S�
O V 3
5 4 O
480
45
32
36
1351
1350
35
54 a
4
DM1/Revised 10/96