NC0020605_Renewal (Application)_20190521

LETTER OF
TY TRANSMITTAL
THE WOOTEN COMPANY
301 West 14th Street.Greenville,NC 27834 DATE JOB NO
May 21, 2019
TO: Mr. Joe Corporon RE: Request for NPDES Permit Renewal
NCDEQ, Division of Water Resources NPDES Permit No. NC 0020605
Water Quality Permitting Town of Tarboro, North Carolina
Surface Water Protection Section - NPDES REC BVED/NODEO/DWR
512 N. Salisbury Street ATTENTION:
9`" Floor—Archdale Building MAY 21 2U19
Raleigh, NC 27604 Water Quality
Permitting Section
WE ARE SENDING: X Attached ❑ Under separate cover via the following items:
❑ Shop Drawings ❑ Prints ❑ Plans ❑ Samples ❑ Specifications
❑ Copy of Letter ❑ Change Order ❑ Other:
DATE I NO. DESCRIPTION
3 5/21/19 NPDES Permit Renewal Application Package
THESE ARE TRANSMITTED as checked below:
❑ For Approval ❑ Reviewed ❑ Revise and resubmit
❑ For your use ❑ Rejected ❑ Submit copies for distribution
❑ As Requested ❑ Corrected ❑ Return corrected print
❑ For Review and comment ❑ Drawings
❑ FOR BIDS DUE [ ] ❑ PRINTS RETURNED AFTER LOAN TO US
REMARKS On behalf of the Town of Tarboro, please find enclosed one (1) original and two
(2) copies of an application package for the renewal of the above-referenced NPDES
Permit. No major modifications have occurred at the facility since issuance of the most
recent permit. If you should have any questions regarding the renewal application, please
contact our office at [phone]. Thank you.
SIGNED: efrr4.�%i?�
William A. Larsen,

Application for Renewal of
NPDES Permit No. NC0020605
Town of Tarboro, North Carolina
RECEIVED/NCDE61/D1MZ
MAY 8 2019
Water Quality
Permitting Section
May 2019
Prepared by:
The Wooten Company
301 West 14th Street
Greenville, North Carolina 27834
[phone]

AL �'J Town of Tarboro
'117nu
500 N Main Street, PO Box 220,Tarboro, NC 27886 (P)252.641.4200 (F)252.641.4286
May 15, 2019
NC DEQ
Division of Water Quality,NPDES Unit
1617 Mail Service Center
Raleigh,NC 27699-1617
Re: NPDES Permit Renewal Application
Permit No.NC0020605
Dear Application Reviewer:
The letter is to confirm that The Wooten Company is the Town of Tarboro's Authorized
Representative in preparing the NPDES Permit Renewal Application.
I certify under penalty of law that this document and all attachments were prepared under
my direction and supervision in accordance with a system designed to assure that
qualified personnel properly gather and evaluated the information submitted. Based on
my inquiry of the person or persons who manage the system or those persons directly
responsible for gathering the information, the information is, to the best and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting
false information, including the possibility of fine and imprisonment for knowing
violations.
If you need additional information, please contact me at(252)641-4250.
Sincerely,
Troy R. Lewis
Town Manager

EPA Form 2A
(inc. Parts A, B, C, D, E & F)

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
FORM Ilinur .
llr-
2A NPDES FORM 2A APPLICATION OVERVIEW
NPDES
APPLICATION OVERVIEW
Form 2A has been developed in a modular format and consists of a "Basic Application Information" packet
and a "Supplemental Application Information" packet. The Basic Application Information packet is divided
into two parts. All applicants must complete Parts A and C. Applicants with a design flow greater than or
equal to 0.1 mgd must also complete Part B. Some applicants must also complete the Supplemental
Application Information packet. The following items explain which parts of Form 2A you must complete.
BASIC APPLICATION INFORMATION:
A. Basic Application Information for all Applicants. All applicants must complete questions A.1 through A.8. A treatment works
that discharges effluent to surface waters of the United States must also answer questions A.9 through A.12.
B. Additional Application Information for Applicants with a Design Flow z 0.1 mgd. All treatment works that have design flows
greater than or equal to 0.1 million gallons per day must complete questions B.1 through B.6.
C. Certification. All applicants must complete Part C(Certification).
SUPPLEMENTAL APPLICATION INFORMATION:
D. Expanded Effluent Testing Data. A treatment works that discharges effluent to surface waters of the United States and meets
one or more of the following criteria must complete Part D(Expanded Effluent Testing Data):
1. Has a design flow rate greater than or equal to 1 mgd,
2. Is required to have a pretreatment program(or has one in place),or
3. Is otherwise required by the permitting authority to provide the information.
E. Toxicity Testing Data. A treatment works that meets one or more of the following criteria must complete Part E(Toxicity Testing
Data):
1. Has a design flow rate greater than or equal to 1 mgd,
2. Is required to have a pretreatment program(or has one in place), or
3. Is otherwise required by the permitting authority to submit results of toxicity testing.
F. Industrial User Discharges and RCRA/CERCLA Wastes. A treatment works that accepts process wastewater from any
significant industrial users(Sills)or receives RCRA or CERCLA wastes must complete Part F (Industrial User Discharges
and RCRA/CERCLA Wastes). Sills are defined as:
1. All industrial users subject to Categorical Pretreatment Standards under 40 Code of Federal Regulations(CFR)403.6 and
40 CFR Chapter I, Subchapter N (see instructions); and
2. Any other industrial user that:
a. Discharges an average of 25,000 gallons per day or more of process wastewater to the treatment works(with certain
exclusions);or
b. Contributes a process wastestream that makes up 5 percent or more of the average dry weather hydraulic or organic
capacity of the treatment plant;or
c. Is designated as an SIU by the control authority.
G. Combined Sewer Systems. A treatment works that has a combined sewer system must complete Part G (Combined Sewer
Systems).
ALL APPLICANTS MUST COMPLETE PART C (CERTIFICATION)
EPA Form 3510-2A(Rev. 1-99). Replaces EPA forms 7550-6&7550-22. Page 1 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
BASIC APPLICATION INFORMATION
PART A. BASIC APPLICATION INFORMATION FOR ALL APPLICANTS:
All treatment works must complete questions A.1 through A.8 of this Basic Application Information Packet.
A.1. Facility Information.
Facility Name Town of Tarboro Wastewater Treatment Plant
Mailing Address Post Office Box 220
Tarboro, North Carolina 27886
Contact Person Trov R.Lewis
Title Town Manager
Telephone Number [phone]
Facility Address Service Road off SR 268/Highway 64 Junction
(not P.O.Box) Tarboro,North Carolina 27886
A.2. Applicant Information. If the applicant is different from the above,provide the following:
Applicant Name Town of Tarboro
Mailing Address Post Office Box 220
Tarboro,North Carolina 27886
Contact Person Trov R.Lewis
Title Town Manager
Telephone Number [phone]
Is the applicant the owner or operator(or both)of the treatment works?
® owner ® operator
Indicate whether correspondence regarding this permit should be directed to the facility or the applicant.
❑ facility ® applicant
A.3. Existing Environmental Permits. Provide the permit number of any existing environmental permits that have been issued to the treatment works
(include state-issued permits).
NPDES NC0020605 PSD N/A
UIC N/A Other WQ0003047
RCRA N/A Other N/A
A.4. Collection System Information. Provide information on municipalities and areas served by the facility. Provide the name and population of each
entity and,if known,provide information on the type of collection system(combined vs.separate)and its ownership(municipal,private,etc.).
Name Population Served Type of Collection System Ownership
Town of Tarboro 11,415 Separate Sanitary Municipal
Town of Princeville 1,025 Separate Sanitary. Municipal
Edgecombe Co.WSD No.5 270 Separate Sanitary Municipal
Total population served 12,710
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 2 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
A.5. Indian Country.
a. Is the treatment works located in Indian Country?
❑ Yes ® No
b. Does the treatment works discharge to a receiving water that is either in Indian Country or that is upstream from(and eventually flows
through)Indian Country?
❑ Yes ® No
A.6. Flow. Indicate the design flow rate of the treatment plant(i.e.,the wastewater flow rate that the plant was built to handle). Also provide the
average daily flow rate and maximum daily flow rate for each of the last three years. Each year's data must be based on a 12-month time period
with the 12`h month of`this year"occurring no more than three months prior to this application submittal.
a. Design flow rate 5.0 mgd
Two Years Ago Last Year This Year
b. Annual average daily flow rate 2.443 1.556 2.258
c. Maximum daily flow rate 10.990 7.071 4.765
A.7. Collection System. Indicate the type(s)of collection system(s)used by the treatment plant. Check all that apply. Also estimate the percent
contribution(by miles)of each.
® Separate sanitary sewer 100
O Combined storm and sanitary sewer N/A
A.8. Discharges and Other Disposal Methods.
a. Does the treatment works discharge effluent to waters of the U.S.? ® Yes 0 No
If yes,list how many of each of the following types of discharge points the treatment works uses:
i. Discharges of treated effluent 1
ii. Discharges of untreated or partially treated effluent 0
iii. Combined sewer overflow points 0
iv. Constructed emergency overflows(prior to the headworks) 0
v. Other N/A N/A
b. Does the treatment works discharge effluent to basins,ponds,or other surface impoundments
that do not have outlets for discharge to waters of the U.S.? 0 Yes ® No
If yes,provide the following for each surface impoundment:
Location: N/A
Annual average daily volume discharge to surface impoundment(s) N/A mgd
Is discharge 0 continuous or 0 intermittent?
c. Does the treatment works land-apply treated wastewater? 0 Yes ® No
If yes,provide the following for each land application site:
Location: N/A
Number of acres: N/A
Annual average daily volume applied to site: N/A mgd
Is land application 0 continuous or ❑ intermittent?
d. Does the treatment works discharge or transport treated or untreated wastewater to another
treatment works? 0 Yes ® No
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 3 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
If yes,describe the mean(s)by which the wastewater from the treatment works is discharged or transported to the other treatment works
(e.g.,tank truck,pipe).
N/A
If transport is by a party other than the applicant,provide:
Transporter Name N/A
Mailing Address N/A
N/A
Contact Person N/A
Title N/A
Telephone Number ( )N/A
For each treatment works that receives this discharge,provide the following:
Name N/A
Mailing Address N/A
N/A
Contact Person N/A
Title N/A
Telephone Number ( )N/A
If known,provide the NPDES permit number of the treatment works that receives this discharge N/A
Provide the average daily flow rate from the treatment works into the receiving facility. N/A mgd
e. Does the treatment works discharge or dispose of its wastewater in a manner not included
in A.8.through A.8.d above(e.g.,underground percolation,well injection): ❑ Yes ® No
If yes,provide the following for each disposal method:
Description of method(including location and size of site(s)if applicable):
N/A
Annual daily volume disposed by this method: N/A
Is disposal through this method ❑ continuous or ❑ intermittent?
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 4 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
WASTEWATER DISCHARGES:
If you answered"Yes"to question A.8.a,complete questions A.9 through A.12 once for each outfall(including bypass points)through
which effluent is discharged. Do not include information on combined sewer overflows in this section. If you answered"No"to question
A.8.a,go to Part B,"Additional Application Information for Applicants with a Design Flow Greater than or Equal to 0.1 mgd."
A.9. Description of Outfall.
a. Outfall number 001
b. Location Town of Tarboro 27886
(City or town,if applicable) (Zip Code)
Edoecombe NC
(County) (State)
35'52'59" 77'32'19"
(Latitude) (Longitude)
c. Distance from shore(if applicable) N/A—cascade aeration into river ft.
d. Depth below surface(if applicable) N/A ft.
e. Average daily flow rate 2.258 mgd
f. Does this outfall have either an intermittent or a periodic discharge? ❑ Yes ® No (go to A.9.g.)
If yes,provide the following information:
Number of times per year discharge occurs: N/A
Average duration of each discharge: N/A
Average flow per discharge: N/A mgd
Months in which discharge occurs: N/A
g. Is outfall equipped with a diffuser? ❑ Yes ® No
A.10. Description of Receiving Waters.
a. Name of receiving water Tar River
b. Name of watershed(if known) Lower Tar
United States Soil Conservation Service 14-digit watershed code(if known): 03020103010020
c. Name of State Management/River Basin(if known):Tar-Pamlico
United States Geological Survey 8-digit hydrologic cataloging unit code(if known): 03020103
d. Critical low flow of receiving stream(if applicable)
acute N/A cfs chronic N/A cfs
e. Total hardness of receiving stream at critical low flow(if applicable): N/A mg/I of CaCO3
EPA Form 3510-2A(Rev. 1-99). Replaces EPA forms 7550-6&7550-22. Page 5 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
A.11. Description of Treatment
a. What levels of treatment are provided? Check all that apply.
El Primary ® Secondary
® Advanced ❑ Other. Describe: N/A
b. Indicate the following removal rates(as applicable):
Design BOD5 removal or Design CBOD5 removal 95+ ok
Design SS removal 85 %
Design P removal 80 %
Design N removal 75 %
Other N/A N/A %
c. What type of disinfection is used for the effluent from this outfall? If disinfection varies by season,please describe:
Chlorine Gas
If disinfection is by chlorination is dechlorination used for this outfall? ® Yes 0 No
Does the treatment plant have post aeration? ® Yes ❑ No
A.12. Effluent Testing Information. All Applicants that discharge to waters of the US must provide effluent testing data for the following
parameters. Provide the indicated effluent testing required by the permitting authority for each outfall through which effluent is
discharged. Do not include information on combined sewer overflows in this section. All information reported must be based on data
collected through analysis conducted using 40 CFR Part 136 methods. In addition,this data must comply with QA/QC requirements of
40 CFR Part 136 and other appropriate QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. At a
minimum,effluent testing data must be based on at least three samples and must be no more than four and one-half years apart.
Outfall number: 001
MAXIMUM DAILY VALUE AVERAGE DAILY VALUE
PARAMETER
Value Units Value Units Number of Samples
pH(Minimum) 6,0 s.u. Pr
pH(Maximum) 7,4 s.u. A ,
Flow Rate 4.765 mgd 2.258 mgd 365
Temperature(Winter) 26.0 C° 15.4 C' 182
Temperature(Summer) Y7.0 C° 23.2 C° 183
For pH please report a minimum and a maximum daily value
MAXIMUM DAILY AVERAGE DAILY DISCHARGE
DISCHARGE ANALYTICAL
POLLUTANT METHOD ML/MDL
Conc. Units Conc. Units Number of
Samples
CONVENTIONAL AND NON CONVENTIONAL COMPOUNDS
BIOCHEMICAL OXYGEN BOD5 15.01 mg/L 3.26 mg/L 365 30
DEMAND(Report one) CBOD5 N/A N/A N/A N/A N/A
FECAL COLIFORM >600 #/100 mL 23.03 #/100 mL 286 200
TOTAL SUSPENDED SOLIDS(TSS) 17.00 mg/L 2.97 mg/L 365 30
END OF PART A.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 6 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
BASIC APPLICATION INFORMATION
PART B. ADDITIONAL APPLICATION INFORMATION FOR APPLICANTS WITH A DESIGN FLOW GREATER THAN OR
EQUAL TO 0.1 MGD(100,000 gallons per day).
All applicants with a design flow rate>_0.1 mgd must answer questions B.1 through B.6. All others go to Part C(Certification).
B.1. Inflow and Infiltration. Estimate the average number of gallons per day that flow into the treatment works from inflow and/or infiltration.
135,000 gpd
Briefly explain any steps underway or planned to minimize inflow and infiltration.
The Town has budgeted$100,000 for sewer line and manhole rehabilitation and replacement.
B.2. Topographic Map. Attach to this application a topographic map of the area extending at least one mile beyond facility property boundaries. This
map must show the outline of the facility and the following information. (You may submit more than one map if one map does not show the entire
area.)
a. The area surrounding the treatment plant,including all unit processes.
b. The major pipes or other structures through which wastewater enters the treatment works and the pipes or other structures through which
treated wastewater is discharged from the treatment plant. Include outfalls from bypass piping,if applicable.
c. Each well where wastewater from the treatment plant is injected underground.
d. Wells,springs,other surface water bodies,and drinking water wells that are: 1)within'/4 mile of the property boundaries of the treatment
works,and 2)listed in public record or otherwise known to the applicant.
e. Any areas where the sewage sludge produced by the treatment works is stored,treated,or disposed.
f. If the treatment works receives waste that is classified as hazardous under the Resource Conservation and Recovery Act(RCRA)by truck,rail,
or special pipe,show on the map where the hazardous waste enters the treatment works and where it is treated,stored,and/or disposed.
B.3. Process Flow Diagram or Schematic. Provide a diagram showing the processes of the treatment plant,including all bypass piping and all
backup power sources or redundancy in the system. Also provide a water balance showing all treatment units,including disinfection(e.g.,
chlorination and dechlorination). The water balance must show daily average flow rates at influent and discharge points and approximate daily flow
rates between treatment units. Include a brief narrative description of the diagram.
B.4. Operation/Maintenance Performed by Contractor(s).
Are any operational or maintenance aspects(related to wastewater treatment and effluent quality)of the treatment works the responsibility of a
contractor? ❑ Yes ® No
If yes,list the name,address,telephone number,and status of each contractor and describe the contractor's responsibilities(attach additional
pages if necessary).
Name: N/A
Mailing Address: N/A
N/A
Telephone Number: ( )N/A
Responsibilities of Contractor: N/A
B.5. Scheduled improvements and Schedules of Implementation. Provide information on any uncompleted implementation schedule or
uncompleted plans for improvements that will affect the wastewater treatment,effluent quality,or design capacity of the treatment works. If the
treatment works has several different implementation schedules or is planning several improvements,submit separate responses to question B.5
for each. (If none,go to question B.6.)
a. List the outfall number(assigned in question A.9)for each outfall that is covered by this implementation schedule.
N/A
b. Indicate whether the planned improvements or implementation schedule are required by local,State,or Federal agencies.
❑ Yes ® No
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 7 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
c. If the answer to B.5.b is"Yes,"briefly describe,including new maximum daily inflow rate(if applicable).
N/A
d. Provide dates imposed by any compliance schedule or any actual dates of completion for the implementation steps listed below,as
applicable. For improvements planned independently of local,State,or Federal agencies,indicate planned or actual completion dates,as
applicable. Indicate dates as accurately as possible.
Schedule Actual Completion
Implementation Stage MM/DD/YYYY MM/DD/YYYY
-Begin Construction N/A N/A
-End Construction N/A N/A
-Begin Discharge N/A N/A
-Attain Operational Level N/A N/A
e. Have appropriate permits/clearances concerning other Federal/State requirements been obtained? ❑ Yes ® No
Describe briefly: N/A
B.6. EFFLUENT TESTING DATA(GREATER THAN 0.1 MGD ONLY).
Applicants that discharge to waters of the US must provide effluent testing data for the following parameters. Provide the indicated
effluent testing required by the permitting authority for each outfall through which effluent is discharged. Do not include information
on combine sewer overflows in this section. All information reported must be based on data collected through analysis conducted
using 40 CFR Part 136 methods. In addition,this data must comply with QA/QC requirements of 40 CFR Part 136 and other appropriate
QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. At a minimum effluent testing data must be
based on at least three pollutant scans and must be no more than four and one-half years old.
Outfall Number: 001
MAXIMUM DAILY AVERAGE DAILY DISCHARGE
DISCHARGE ANALYTICAL
POLLUTANT METHOD ML/MDL
Conc. Units Conc. Units Number of
Samples
CONVENTIONAL AND NON CONVENTIONAL COMPOUNDS
AMMONIA(as N) <5.00 mg/L <5.00 mg/L 249 EPA 353.2 9
CHLORINE(TOTAL 33.00 ug/L <25.00 ug/L 157
RESIDUAL,TRC)
DISSOLVED OXYGEN 15.07 mg/L 8.98 mg/L 365 5
TOTAL KJELDAHL 2.22 mg/L 1.32 mg/L 52 EPA 351.2 0.5
NITROGEN(TKN)
NITRATE PLUS NITRITE 16.63 mg/L 9.86 mg/L 52 EPA 353.2 0.1
NITROGEN
OIL and GREASE N/A N/A N/A N/A N/A EPA 1664A 5
PHOSPHORUS(Total) 1.58 mg/L 0.69 mg/L 52 EPA 365.1 0.1
TOTAL DISSOLVED N/A N/A N/A N/A N/A
SOLIDS(TDS)
OTHER: NITROGEN(Total) 17.85 mg/L 11.20 mg/L 52
END OF PART B.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 8 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
BASIC APPLICATION INFORMATION
PART C. CERTIFICATION
All applicants must complete the Certification Section. Refer to instructions to determine who is an officer for the purposes of this
certification. All applicants must complete all applicable sections of Form 2A,as explained in the Application Overview. Indicate below which
parts of Form 2A you have completed and are submitting. By signing this certification statement,applicants confirm that they have reviewed
Form 2A and have completed all sections that apply to the facility for which this application is submitted.
Indicate which parts of Form 2A you have completed and are submitting:
® Basic Application Information packet Supplemental Application Information packet:
• Part D(Expanded Effluent Testing Data)
® Part E(Toxicity Testing: Biomonitoring Data)
® Part F(Industrial User Discharges and RCRA/CERCLA Wastes)
❑ Part G(Combined Sewer Systems)
ALL APPLICANTS MUST COMPLETE THE FOLLOWING CERTIFICATION.
I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who
manage the system or those persons directly responsible for gathering the information,the information is,to the best of my knowledge and belief,true,
accurate,and complete. I am aware that there are significant penalties for submitting false information,including the possibility of fine and imprisonment
for knowing violations.
Name and official title William A.L rsenP.E.,The Wooten C mpanv
Signature 7i/ t ��"".` J�
Telephone number [phone] Q
Date signed S'i • ZAI ?
Upon request of the permitting authority,you must submit any other information necessary to assure wastewater treatment practices at the treatment
works or identify appropriate permitting requirements.
SEND COMPLETED FORMS TO:
NCDENR/ DWQ
Attn: NPDES Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 9 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
SUPPLEMENTAL APPLICATION INFORMATION
PART D. EXPANDED EFFLUENT TESTING DATA
Refer to the directions on the cover page to determine whether this section applies to the treatment works.
Effluent Testing: 1.0 mgd and Pretreatment Works. If the treatment works has a design flow greater than or equal to 1.0 mgd or it has(or is required
to have)a pretreatment program,or is otherwise required by the permitting authority to provide the data,then provide effluent testing data for the following
pollutants. Provide the indicated effluent testing information and any other information required by the permitting authority for each outfall through which
effluent is discharged. Do not include information on combined sewer overflows in this section. All information reported must be based on data collected
through analyses conducted using 40 CFR Part 136 methods. In addition,these data must comply with QA/QC requirements of 40 CFR Part 136 and
other appropriate QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. Indicate in the blank rows provided below
any data you may have on pollutants not specifically listed in this form. At a minimum,effluent testing data must be based on at least three pollutant
scans and must be no more than four and one-half years old.
Outfall number: 001 (Complete once for each outfall discharging effluent to waters of the United States.)
MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE
POLLUTANT Number ANALYTICAL MLIMDL
Conc. Units Mass Units Conc. Units Mass Units of METHOD
Samples
METALS(TOTAL RECOVERABLE),CYANIDE,PHENOLS,AND HARDNESS.
ANTIMONY ND ug/L ND ug/L 4 EPA 200.7 5
ARSENIC <5.0 ug/L <5.0 ug/L 4 EPA 200.7 5
BERYLLIUM ND ug/L ND ug/L 4 EPA 200.7 1
CADMIUM <1.0 ug/L <1.0 ug/L 4 EPA 200.7 1
CHROMIUM <5.0 ug/L <5.0 ug/L 4 EPA 200.7 5
COPPER 10.0 ug/L 7.50 ug/L 4 EPA 200.7 5
LEAD <5.0 ug/L <5.0 ug/L 4 EPA 200.7 5
MERCURY <1.0 ng/L <1.0 ng/L 4 EPA 1631E 0.5
NICKEL <10 ug/L <10 ug/L 4 EPA 200.7 10
SELENIUM <10 ug/L <10 ug/L 4 EPA 200.7 10
SILVER <5.0 ug/L <5.0 ug/L 4 EPA 200.7 5
THALLIUM ND ug/L ND ug/L 4 EPA 200.7 10
ZINC 60.0 ug/L 34.0 ug/L 4 EPA 200.7 10
CYANIDE <0.005 mg/L <0.005 mg/L 4 SM 4500-CN-E 0.005
TOTAL PHENOLIC 0.075 mg/L 0.049 mg/L 4 EPA 420.4 0.01
COMPOUNDS
HARDNESS(as CaCO3) 34.6 mg/L 31.18 mg/L 4 SM 2340B 0.65
Use this space(or a separate sheet)to provide information on other metals requested by the permit writer
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 10 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
Outfall number: 001 (Complete once for each outfall discharging effluent to waters of the United States.)
MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE
POLLUTANT Number ANALYTICAL ML/MDL
Conc. Units Mass Units Conc. Units Mass Units of METHOD
Samples
VOLATILE ORGANIC COMPOUNDS
ACROLEIN ND ug/L ND ug/L 4 EPA 624 100
ACRYLONITRILE ND ug/L ND uglL 4 EPA 624 100
BENZENE ND ug/L ND ug/L 4 EPA 624 5
BROMOFORM ND ug/L ND ug/L 4 EPA 624 5
CARBON ND ug/L ND uglL 4 EPA 624 5
TETRACHLORIDE
CHLOROBENZENE ND ug/L ND ug/L 4 EPA 624 5
CHLORODIBROMO- ND ug/L ND ug/L 4 EPA 624 5
METHANE
CHLOROETHANE ND ug/L ND ug/L 4 EPA 624 10
2-CHLOROETHYLVINYL ND ug/L ND ug/L 4 EPA 624 10
ETHER
CHLOROFORM ND ug/L ND ug/L 4 EPA 624 5
DICHLOROBROMO- ND ug/L ND ug/L 4 EPA 624 5
METHANE
1,1-DICHLOROETHANE ND ug/L ND ug/L 4 EPA 624 5
1,2-DICHLOROETHANE ND ug/L ND ug/L 4 EPA 624 5
TRANS-I,2-DICHLORO- ND ug/L ND ug/L 4 EPA 624 5
ETHYLENE
1,1-DICHLORO- ND ug/L ND ug/L 4 EPA 624 5
ETHYLENE
1,2-DICHLOROPROPANE ND ug/L ND ug/L 4 EPA 624 5
1,3-DICHLORO- ND ug/L ND ug/L 4 EPA 624 5
PROPYLENE
ETHYLBENZENE ND ug/L ND ug/L 4 EPA 624 5
METHYL BROMIDE ND ug/L ND ug/L 4 EPA 624 5
METHYL CHLORIDE ND ug/L ND ug/L 4 EPA 624 5
METHYLENE CHLORIDE ND ug/L ND ug/L 4 EPA 624 5
1,1,2,2-TETRA- ND ug/L ND ug/L 4 EPA 624 5
CHLOROETHANE
TETRACHLORO- ND ug/L ND ug/L 4 EPA 624 5
ETHYLENE
TOLUENE ND ug/L ND ug/L 4 EPA 624 5
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 11 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NCOO2O6O5 Renewal Tar-Pamlico
Outfall number: 001 (Complete once for each outfall discharging effluent to waters of the United States.)
MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE
POLLUTANT Number ANALYTICAL ML/MDL
Conc. Units Mass Units Conc. Units Mass Units of METHOD
Samples
1,1,1 ND ug/L ND ug/L 4 EPA 624 5
TRICHLOROETHANE
1,1,2 ND ug/L ND ug/L 4 EPA 624 5
TRICHLOROETHANE
TRICHLOROETHYLENE ND ug/L ND ug/L 4 EPA 624 5
VINYL CHLORIDE ND ug/L ND ug/L 4 EPA 624 5
Use this space(or a separate sheet)to provide information on other volatile organic compounds requested by the permit writer
ACID-EXTRACTABLE COMPOUNDS
P-CHLORO-M-CRESOL ND ug/L ND ug/L 4 EPA 624 10
2-CHLOROPHENOL ND ug/L ND ug/L 4 EPA 624 10
2,4-DICHLOROPHENOL ND ug/L ND ug/L 4 EPA 624 10
2,4-DIMETHYLPHENOL ND ug/L ND ug/L 4 EPA 624 10
4,6-DINITRO-O-CRESOL ND ug/L ND ug/L 4 EPA 624 50
2,4-DINITROPHENOL ND ug/L ND ug/L 4 EPA 624 50
2-NITROPHENOL ND ug/L ND ug/L 4 EPA 624 10
4-NITROPHENOL ND ug/L ND ug/L 4 EPA 624 50
PENTACHLOROPHENOL ND ug/L ND ug/L 4 EPA 624 50
PHENOL ND ug/L ND ug/L 4 EPA 624 10
2,4,6- ND ug/L ND ug/L 4 EPA 624 10
TRICHLOROPHENOL
Use this space(or a separate sheet)to provide information on other acid-extractable compounds requested by the permit writer
BASE-NEUTRAL COMPOUNDS
ACENAPHTHENE ND ug/L ND ND 4 EPA 625 6.4
ACENAPHTHYLENE ND ug/L ND ND 4 EPA 625 6.4
ANTHRACENE ND ug/L ND ND 4 EPA 625 6.4
BENZIDINE ND ug/L ND ND 4 EPA 625 6.4
BENZO(A)ANTHRACENE ND ug/L ND ND 4 EPA 625 6.4
BENZO(A)PYRENE ND ug/L ND ND 4 EPA 625 6.4
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 12 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
Outfall number: 001 (Complete once for each outfall discharging effluent to waters of the United States.)
MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE
POLLUTANT Number ANALYTICAL ML/MDL
Conc. Units Mass Units Conc. Units Mass Units of METHOD
Samples
3,4 BENZO- ND ug/L ND ug/L 4 EPA 625 6.4
FLUORANTHENE
BENZO(GHI)PERYLENE ND ug/L ND ug/L 4 EPA 625 6.4
BENZO(K) ND ug/L ND ug/L 4 EPA 625 6.4
FLUORANTHENE
BIS(2-CHLOROETHOXY) ND ug/L ND ug/L 4 EPA 625 12.8
METHANE
BIS(2-CHLOROETHYL)- ND ug/L ND ug/L 4 EPA 625 6.4
ETHER
BIS(2-CHLOROISO- ND ug/L ND ug/L 4 EPA 625 6.4 1
PROPYL)ETHER
BIS(2-ETHYLHEXYL) ND ug/L ND ug/L 4 EPA 625 6.4
PHTHALATE
4-BROMOPHENYL ND ug/L ND ug/L 4 EPA 625 6.4
PHENYL ETHER
BUTYL BENZYL ND ug/L ND ug/L 4 EPA 625 6.4
PHTHALATE
2-CHLORO- ND ug/L ND ug/L 4 EPA 625 6.4
NAPHTHALENE
4-CHLORPHENYL ND ug/L ND ug/L 4 EPA 625 6.4
PHENYL ETHER
CHRYSENE ND ug/L ND ug/L 4 EPA 625 6.4
DI-N-BUTYL PHTHALATE ND ug/L ND ug/L 4 EPA 625 6.4
DI-N-OCTYL PHTHALATE ND ug/L ND ug/L 4 EPA 625 6.4
DIBENZO(A,H) ND ug/L ND ug/L 4 EPA 625 6.4
ANTHRACENE
1,2-DICHLOROBENZENE ND ug/L ND ug/L 4 EPA 625 6.4
1,3-DICHLOROBENZENE ND ug/L ND ug/L 4 EPA 625 6.4
1,4-DICHLOROBENZENE ND ug/L ND ug/L 4 EPA 625 6.4
3,3-DICHLORO- ND ug/L ND ug/L 4 EPA 625 6.4
BENZIDINE
DIETHYL PHTHALATE ND ug/L ND ug/L 4 EPA 625 6.4
DIMETHYL PHTHALATE ND ug/L ND ug/L 4 EPA 625 6.4
2,4-DINITROTOLUENE ND ug/L ND ug/L 4 EPA 625 6.4
2,6-DINITROTOLUENE ND ug/L ND ug/L 4 EPA 625 6.4
1,2-DIPHENYL- ND ug/L ND ug/L 4 EPA 625 6.4
HYDRAZINE
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 13 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
Outfall number: 001 (Complete once for each outfall discharging effluent to waters of the United States.)
MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE
POLLUTANT Number ANALYTICAL ML/MDL
Conc. Units Mass Units Conc. Units Mass Units of METHOD
Samples
FLUORANTHENE ND ug/L ND ug/L 4 EPA 625 6.4
FLUORENE ND ug/L ND ug/L 4 EPA 625 6.4
HEXACHLOROBENZENE ND ug/L ND ug/L 4 EPA 625 6.4
HEXACHLORO- ND ug/L ND ug/L 4 EPA 625 6.4
BUTADIENE
HEXACHLOROCYCLO- ND ug/L ND ug/L 4 EPA 625 12.8
PENTADIENE
HEXACHLOROETHANE ND ug/L ND ug/L 4 EPA 625 6.4
INDENO(1,2,3-CD) ND ug/L ND ug/L 4 EPA 625 6.4
PYRENE
ISOPHORONE ND ug/L ND ug/L 4 EPA 625 12.8
NAPHTHALENE ND ug/L ND ug/L 4 EPA 625 6.4
NITROBENZENE ND ug/L ND ug/L 4 EPA 625 6.4
N-NITROSODI-N- ND ug/L ND ug/L 4 EPA 625 6.4
PROPYLAMINE
N-NITROSODI- ND ug/L ND ug/L 4 EPA 625 6.4
METHYLAMINE
N-NITROSODI- ND ug/L ND ug/L 4 EPA 625 12.8
PHENYLAMINE
PHENANTHRENE ND ug/L ND ug/L 4 EPA 625 6.4
PYRENE ND ug/L ND ug/L 4 EPA 625 6.4
1,2,4- ND ug/L ND ug/L 4 EPA 625 6.4
TRICHLOROBENZENE
Use this space(or a separate sheet)to provide information on other base-neutral compounds requested by the permit writer
Use this space(or a separate sheet)to provide information on other pollutants(e.g.,pesticides)requested by the permit writer
END OF PART D.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 14 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
SUPPLEMENTAL APPLICATION INFORMATION
PART E. TOXICITY TESTING DATA
POTWs meeting one or more of the following criteria must provide the results of whole effluent toxicity tests for acute or chronic toxicity for each of the
facility's discharge points: 1)POTWs with a design flow rate greater than or equal to 1.0 mgd;2)POTWs with a pretreatment program(or those that are
required to have one under 40 CFR Part 403);or 3)POTWs required by the permitting authority to submit data for these parameters.
• At a minimum,these results must include quarterly testing for a 12-month period within the past 1 year using multiple species(minimum of two
species),or the results from four tests performed at least annually in the four and one-half years prior to the application,provided the results
show no appreciable toxicity,and testing for acute and/or chronic toxicity,depending on the range of receiving water dilution. Do not include
information on combined sewer overflows in this section. All information reported must be based on data collected through analysis conducted
using 40 CFR Part 136 methods. In addition,this data must comply with QA/QC requirements of 40 CFR Part 136 and other appropriate QA/QC
requirements for standard methods for analytes not addressed by 40 CFR Part 136.
• In addition,submit the results of any other whole effluent toxicity tests from the past four and one-half years. If a whole effluent toxicity test
conducted during the past four and one-half years revealed toxicity,provide any information on the cause of the toxicity or any results of a
toxicity reduction evaluation,if one was conducted.
• If you have already submitted any of the information requested in Part E,you need not submit it again. Rather,provide the information
requested in question E.4 for previously submitted information. If EPA methods were not used,report the reasons for using alternate methods.
If test summaries are available that contain all of the information requested below,they may be submitted in place of Part E.
If no biomonitoring data is required,do not complete Part E. Refer to the Application Overview for directions on which other sections of the form to
complete.
E.1. Required Tests.
Indicate the number of whole effluent toxicity tests conducted in the past four and one-half years.
®chronic 0 acute
E.2. Individual Test Data. Complete the following chart for each whole effluent toxicity test conducted in the last four and one-half years. Allow one
column per test(where each species constitutes a test). Copy this page if more than three tests are being reported.
Test number: Test number: Test number:
a. Test information.
Test Species&test method number
Age at initiation of test
Outfall number
Dates sample collected
Date test started
Duration
b. Give toxicity test methods followed.
Manual title
Edition number and year of publication
Page number(s)
c. Give the sample collection method(s)used. For multiple grab samples,indicate the number of grab samples used.
24-Hour composite
Grab
d. Indicate where the sample was taken in relation to disinfection. (Check all that apply for each.
Before disinfection
After disinfection
After dechlorination
EPA Form 3510-2A(Rev. 1-99). Replaces EPA forms 7550-6&7550-22. Page 15 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
Test number: Test number: Test number:
e. Describe the point in the treatment process at which the sample was collected.
Sample was collected:
f. For each test,include whether the test was intended to assess chronic toxicity,acute toxicity,or both
Chronic toxicity
Acute toxicity
g. Provide the type of test performed.
Static
Static-renewal
Flow-through
h. Source of dilution water. If laboratory water,specify type;if receiving water,specify source.
Laboratory water
Receiving water
i. Type of dilution water. If salt water,specify"natural"or type of artificial sea salts or brine used.
Fresh water
Salt water
j. Give the percentage effluent used for all concentrations in the test series.
k. Parameters measured during the test. (State whether parameter meets test method specifications)
pH
Salinity
Temperature
Ammonia
Dissolved oxygen
I. Test Results.
Acute:
Percent survival in 100% cyo
effluent
LCso
95%C.I. % % %
Control percent survival % % %
Other(describe)
EPA Form 3510-2A(Rev. 1-99). Replaces EPA forms 7550-6&7550-22. Page 16 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
Chronic:
NOEC ok
IC25
Control percent survival cyo
Other(describe)
m. Quality Control/Quality Assurance.
Is reference toxicant data available?
Was reference toxicant test within
acceptable bounds?
What date was reference toxicant test /
run(MM/DD/YYYY)?
Other(describe)
E.3. Toxicity Reduction Evaluation. Is the treatment works involved in a Toxicity Reduction Evaluation?
❑ Yes ❑ No If yes,describe:
E.4. Summary of Submitted Biomonitoring Test Information. If you have submitted biomonitoring test information,or information regarding the
cause of toxicity,within the past four and one-half years,provide the dates the information was submitted to the permitting authority and a summary
of the results.
Date submitted: / / (MM/DD/YYYY)
Summary of results: (see instructions)
Please see attached summary.
END OF PART E.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE.
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 17 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
SUPPLEMENTAL APPLICATION INFORMATION
PART F.INDUSTRIAL USER DISCHARGES AND RCRA/CERCLA WASTES
All treatment works receiving discharges from significant industrial users or which receive RCRA,CERCLA,or other remedial wastes must
complete part F.
GENERAL INFORMATION:
F.1. Pretreatment program. Does the treatment works have,or is subject to,an approved pretreatment program?
is Yes ❑ No
F.2. Number of Significant Industrial Users(SlUs)and Categorical Industrial Users(ClUs). Provide the number of each of the following types of
industrial users that discharge to the treatment works.
a. Number of non-categorical SlUs. 1
b. Number of ClUs. 3
SIGNIFICANT INDUSTRIAL USER INFORMATION:
Supply the following information for each SIU. If more than one SIU discharges to the treatment works,copy questions F.3 through F.8 and
provide the information requested for each SIU.
F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages
as necessary.
Name: Johnson Controls(originally"Air System Components",see attached name change letter)
Mailing Address: 3301 Main Street
Tarboro,North Carolina 27886
F.4. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge.
Manufacturing of metal grills for air conditioning registers.
F.5. Principal Product(s)and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's
discharge.
Principal product(s): Air Duct Registers
Raw material(s): Sheet Metal,Paint
F.6. Flow Rate.
a. Process wastewater flow rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons per
day(gpd)and whether the discharge is continuous or intermittent.
40,000 gpd (100% continuous or intermittent)
b. Non-process wastewater flow rate. Indicate the average daily volume of non-process wastewater flow discharged into the collection system
in gallons per day(gpd)and whether the discharge is continuous or intermittent.
1,000 gpd (100% continuous or intermittent)
F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following:
a. Local limits El Yes ❑ No
b. Categorical pretreatment standards IS] Yes ❑ No
If subject to categorical pretreatment standards,which category and subcategory?
40 CFR 433,subpart A
EPA Form 3510-2A(Rev. 1-99). Replaces EPA forms 7550-6&7550-22. Page 18 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
F.8. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems(e.g.,
upsets,interference)at the treatment works in the past three years?
❑ Yes ® No If yes,describe each episode.
N/A
RCRA HAZARDOUS WASTE RECEIVED BY TRUCK, RAIL, OR DEDICATED PIPELINE:
F.9. RCRA Waste. Does the treatment works receive or has it in the past three years received RCRA hazardous waste by truck,rail or dedicated pipe?
❑ Yes ® No(go to F.12)
F.10. Waste transport. Method by which RCRA waste is received(check all that apply):
❑ Truck ❑ Rail ❑ Dedicated Pipe
F.11. Waste Description. Give EPA hazardous waste number and amount(volume or mass,specify units).
EPA Hazardous Waste Number Amount Units
N/A N/A N/A
N/A N/A N/A
N/A N/A N/A
CERCLA(SUPERFUND)WASTEWATER, RCRA REMEDIATION/CORRECTIVE ACTION
WASTEWATER,AND OTHER REMEDIAL ACTIVITY WASTEWATER:
F.12. Remediation Waste. Does the treatment work currently(or has it been notified that it will)receive waste from remedial activities?
❑ Yes(complete F.13 through F.15.) ® No
F.13. Waste Origin. Describe the site and type of facility at which the CERCLA/RCRA/or other remedial waste originates(or is excepted to originate in
the next five years).
N/A
F.14. Pollutants. List the hazardous constituents that are received(or are expected to be received). Include data on volume and concentration,if
known. (Attach additional sheets if necessary.)
N/A
F.15. Waste Treatment.
a. Is this waste treated(or will be treated)prior to entering the treatment works?
❑ Yes ❑ No
If yes,describe the treatment(provide information about the removal efficiency):
N/A
b. Is the discharge(or will the discharge be)continuous or intermittent?
❑ Continuous ❑ Intermittent If intermittent,describe discharge schedule.
N/A
END OF PART F.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510-2A(Rev. 1-99). Replaces EPA forms 7550-6&7550-22. Page 19 of 25

/id 1)1i
Johnson
Controls
September 27, 2017
Town of Tarboro, North Carolina
P.O. Box 220
Tarboro, NC 27886
ATTN: Michael Allen
To Whom It May Concern:
Please note the company name change from Air System Components to Johnson Controls effective
immediately. The Plant Manager of the Johnson Controls plant in Tarboro, NC has also changed. Please
update your records to reflect William Kirkpatrick as the current Responsible Official/Authorized Contact
for Johnson Controls in Tarboro, NC.
iicerel
Tara Carr
Environmental Representative
Johnson Controls
3301 N Main Street
Tarboro, NC 27886

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
SUPPLEMENTAL APPLICATION INFORMATION
PART F.INDUSTRIAL USER DISCHARGES AND RCRA/CERCLA WASTES
All treatment works receiving discharges from significant industrial users or which receive RCRA,CERCLA,or other remedial wastes must
complete part F.
GENERAL INFORMATION:
F.1. Pretreatment program. Does the treatment works have,or is subject to,an approved pretreatment program?
® Yes ❑ No
F.2. Number of Significant Industrial Users(Sills)and Categorical Industrial Users(ClUs). Provide the number of each of the following types of
industrial users that discharge to the treatment works.
c. Number of non-categorical SIUs. 1
d. Number of ClUs. 3
SIGNIFICANT INDUSTRIAL USER INFORMATION:
Supply the following information for each SIU. If more than one SIU discharges to the treatment works,copy questions F.3 through F.8 and
provide the information requested for each SIU.
F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages
as necessary.
Name: Sara Lee Frozen Bakery,LLC(originally"The Hillshire Brands Company",see attached name change letters)
Mailing Address: 110 Sara Lee Road
Tarboro,North Carolina 27886
F.4. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge.
Production of consumable basic food and dessert pastries.
F.5. Principal Product(s)and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's
discharge.
Principal product(s): Pound Cake,Muffins,Biscuits,Croissants,Danish,Laver Cakes
Raw material(s): Flour,Eggs,Milk,Sugar,Spices,Stabilizers,Colorings,Flavorings
F.6. Flow Rate.
c. Process wastewater flow rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons per
day(gpd)and whether the discharge is continuous or intermittent.
300,000 gpd ( continuous or 100% intermittent)
d. Non-process wastewater flow rate. Indicate the average daily volume of non-process wastewater flow discharged into the collection system
in gallons per day(gpd)and whether the discharge is continuous or intermittent.
50,000 gpd (100% continuous or intermittent)
F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following:
a. Local limits ® Yes 0 No
b. Categorical pretreatment standards 0 Yes El No
If subject to categorical pretreatment standards,which category and subcategory?
N/A
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 20 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
F.8. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems(e.g.,
upsets,interference)at the treatment works in the past three years?
❑ Yes El No If yes,describe each episode.
N/A
RCRA HAZARDOUS WASTE RECEIVED BY TRUCK, RAIL, OR DEDICATED PIPELINE:
F.9. RCRA Waste. Does the treatment works receive or has it in the past three years received RCRA hazardous waste by truck,rail or dedicated pipe?
❑ Yes ® No(go to F.12)
F.10. Waste transport. Method by which RCRA waste is received(check all that apply):
❑ Truck ❑ Rail ❑ Dedicated Pipe
F.11. Waste Description. Give EPA hazardous waste number and amount(volume or mass,specify units).
EPA Hazardous Waste Number Amount Units
N/A N/A N/A
N/A N/A N/A
N/A N/A N/A
CERCLA(SUPERFUND)WASTEWATER, RCRA REMEDIATION/CORRECTIVE ACTION
WASTEWATER,AND OTHER REMEDIAL ACTIVITY WASTEWATER:
F.12. Remediation Waste. Does the treatment work currently(or has it been notified that it will)receive waste from remedial activities?
0 Yes(complete F.13 through F.15.) El No
F.13. Waste Origin. Describe the site and type of facility at which the CERCLA/RCRA/or other remedial waste originates(or is excepted to originate in
the next five years).
N/A
F.14. Pollutants. List the hazardous constituents that are received(or are expected to be received). Include data on volume and concentration,if
known. (Attach additional sheets if necessary.)
N/A
F.15. Waste Treatment.
c. Is this waste treated(or will be treated)prior to entering the treatment works?
❑ Yes ❑ No
If yes,describe the treatment(provide information about the removal efficiency):
N/A
d. Is the discharge(or will the discharge be)continuous or intermittent?
❑ Continuous 0 Intermittent If intermittent,describe discharge schedule.
N/A
END OF PART F.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 21 of 25

June 29, 2018
Via Certified Mai(
PO Box 220
Tarboro, NC 27886
Attn: Michael Allen
Waste Water Treatment Plant
Re: Change in Name and Ownership for Industrial User Permit, IUP #TOT-001
Dear Mr. Allen:
The purpose of this letter is to inform you of the proposed transaction affecting the identity of the holder
of Industrial User Permit, IUP #TOT-001 (the "Permit"), and to request that the permit be updated to
reflect these changes. The Permit authorizes wastewater discharge from the facility located at 110 Sara
Lee Road,Tarboro, NC 27886 (the"Facility").
The current holder of the permit,The Hillshire Brands Company, will transfer the Facility and the Permit
to KSLB Holdings, LLC as of July 30, 2018. Accordingly, this letter serves as our request for the Waste
Water Treatment Plant's approval, pursuant to Section 20-292(h) of the Tarboro Sewer Use Ordinance,
of the transfer of the Permit to KSLB Holdings, LLC. As required by the referenced Ordinance, this filing
consists of this letter confirming the Change in Ownership and signed by the seller and the buyer.
The Facility's current product is Frozen Baked Goods including but not limited to Pound Cake, Muffins,
Biscuits, Croissants, Sheet cakes, Danish and its current flows are averaging 150,000 GPD.
* * * * * * * * * * *
Please feel free to call Peter Alpert at(617) 951-7906 or [e-mail] if you have any
questions on the application forms or attachments.
69604037_5

On behalf of current permlttee: On behalf of proposed permittee:
The BilishIre Brands Company KSLI Holdings, LLC
By: By: 10100
l�` -0L
17)
Name: Name: Bartlett Harwood IV
Title: Title: Vice President
Date: Date;June 28,2018
cc:
Attachments

On behalf of current permittee: On behalf of proposed permittee:
-The-Hillahire Brands Company i(SLB-Holdings;
By: By:
Name: ohn Tripp Name: Bartlett Harwood IV
Title: Plant Manager Title: Vice President
Date: June 28, 2018 Date:
cc:
Attachments

September 6, 2018
Via Certified Mail
PO Box 220
Tarboro, NC 27886
Attn: Michael Allen
Waste Water Treatment Plant
RE: CHANGE IN NAME FOR INDUSTRIAL USER PERMIT, IUP #TOT-001
Dear Mr. Allen:
The purpose of this letter is to inform you of a name change affecting the identity of the holder of
Industrial User Permit, IUP #TOT-001 (the"Permit"), and to request that the permit be updated to
reflect this change. The Permit authorizes wastewater discharge from the facility located at 110 Sara
Lee Road, Tarboro, NC 27886 (the "Facility").
The current holder of the permit, KSLB Holdings, LLC, has changed its name to Sara Lee Frozen
Bakery, LLC. Pursuant to Section 20-292(h) of the Tarboro Sewer Use Ordinance, there is no change
in the ownership of the Facility associated with this name change. Please update your records to
reflect Sara Lee Frozen Bakery, LLC as the current Permit holder.
The Facility's current product is Frozen Baked Goods including but not limited to Pound Cake, Muffins,
Biscuits, Croissants, Sheet cakes, Danish and its current flows are averaging 150,000 GPD.
Please contact Thomas Fusillo at 609-243-9816 or if you have any questions
regarding this request.
On behalf of the current permittee:
KSLB Holdings, LLC
By:
Name: Bartlett Harwood IV
Title: Vice President
Date: September 6, 2018
Address: KSLB Holdings, LLC
111 Radio Circle
Mt. Kisco, NY 10549

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
SUPPLEMENTAL APPLICATION INFORMATION
PART F.INDUSTRIAL USER DISCHARGES AND RCRA/CERCLA WASTES
All treatment works receiving discharges from significant industrial users or which receive RCRA,CERCLA,or other remedial wastes must
complete part F.
GENERAL INFORMATION:
F.1. Pretreatment program. Does the treatment works have,or is subject to,an approved pretreatment program?
® Yes ❑ No
F.2. Number of Significant Industrial Users(SlUs)and Categorical Industrial Users(CIUs). Provide the number of each of the following types of
industrial users that discharge to the treatment works.
e. Number of non-categorical SIUs. 1
f. Number of ClUs. 3
SIGNIFICANT INDUSTRIAL USER INFORMATION:
Supply the following information for each SIU. If more than one SIU discharges to the treatment works,copy questions F.3 through F.8 and
provide the information requested for each SIU.
F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages
as necessary.
Name: Mayo Knitting Mill,Inc.
Mailing Address: P.O.Box 160
Tarboro,North Carolina 27886
F.4. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge.
Knitting,Dyeing,Finishing,Packaging and Shipping of Hosiery
F.5. Principal Product(s)and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's
discharge.
Principal product(s): Hosiery
Raw material(s): Yams,Dyes,Chemicals
F.6. Flow Rate.
e. Process wastewater flow rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons per
day(gpd)and whether the discharge is continuous or intermittent.
250,000 gpd ( continuous or 100% intermittent)
f. Non-process wastewater flow rate. Indicate the average daily volume of non-process wastewater flow discharged into the collection system
in gallons per day(gpd)and whether the discharge is continuous or intermittent.
1,000 gpd (100% continuous or intermittent)
F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following:
a. Local limits ® Yes ❑ No
b. Categorical pretreatment standards ® Yes ❑ No
If subject to categorical pretreatment standards,which category and subcategory?
40 CFR 410,subpart G
EPA Form 3510-2A(Rev. 1-99). Replaces EPA forms 7550-6&7550-22. Page 22 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
F.8. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems(e.g.,
upsets,interference)at the treatment works in the past three years?
❑ Yes ® No If yes,describe each episode.
N/A
RCRA HAZARDOUS WASTE RECEIVED BY TRUCK, RAIL, OR DEDICATED PIPELINE:
F.9. RCRA Waste. Does the treatment works receive or has it in the past three years received RCRA hazardous waste by truck,rail or dedicated pipe?
❑ Yes ® No(go to F.12)
F.10. Waste transport. Method by which RCRA waste is received(check all that apply):
❑ Truck ❑ Rail ❑ Dedicated Pipe
F.11. Waste Description. Give EPA hazardous waste number and amount(volume or mass,specify units).
EPA Hazardous Waste Number Amount Units
N/A N/A_ N/A
N/A N/A N/A
N/A N/A _ N/A
CERCLA(SUPERFUND)WASTEWATER, RCRA REMEDIATION/CORRECTIVE ACTION
WASTEWATER,AND OTHER REMEDIAL ACTIVITY WASTEWATER:
F.12. Remediation Waste. Does the treatment work currently(or has it been notified that it will)receive waste from remedial activities?
❑ Yes(complete F.13 through F.15.) El No
F.13. Waste Origin. Describe the site and type of facility at which the CERCLA/RCRA/or other remedial waste originates(or is excepted to originate in
the next five years).
N/A
F.14. Pollutants. List the hazardous constituents that are received(or are expected to be received). Include data on volume and concentration,if
known. (Attach additional sheets if necessary.)
N/A
F.15. Waste Treatment.
e. Is this waste treated(or will be treated)prior to entering the treatment works?
❑ Yes ❑ No
If yes,describe the treatment(provide information about the removal efficiency):
N/A
f. Is the discharge(or will the discharge be)continuous or intermittent?
❑ Continuous ❑ Intermittent If intermittent,describe discharge schedule.
N/A
END OF PART F.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 23 of 25

NPDES FORM 2A Additional Information

Topographic Map &
Process Flow Diagram

;\ k.,--` I i 1 'berN--0 ''.c.-14., " 0 .„,.-0- •Flti. :hrs.!•‘. v 0-- v,i . `'''.-P• ' .. -' i I
N Golf ) f, 77/' it , .', - • . .••,•,.‘‘' k -.,•
el
C \ CoLrse I i i' . r• fti --45.`„ -7- s•-- • \ . %,.. tr---' '., •-•• ..• ,*:ti, 'I' . -•*-' , \ '. ..i. ..J .- -
, • ,f .., ...- ...Li: , • 4k .. '.3...-1,-- % 'Ai.j .',..,\. tfill:-.-k.:--
•.,` i . I, S
fl, ..'" kri f n . ''' "ija ni i ; • .•1 Fi .. .....1
. ,.... .... ..., /"..,'..,"/"" 17)..0i-- 111.1 , : -,---....„,... ...i'.`.,.., ,\. \":1.4 1 -‘,.‘ •-: ... • :t .. .-- le.,,.. /.1-'10
N. k '
‘ 8 rt,57.1 . I.0••••;44%‘r.i''. •-• ;. '.)• ,- '' ' t#Cr" - . .t,\•%,.... . •,:t 1,' , ... , ."• .,,-;--.4,,a4 :.1..__ —
---vi . .;1"..-"-. 0(4 '•-- 4 - •- -- --..... -4.. •t 4,', M. \ dodo. _ . • n. .:-.:?..4zi lic,
. t ‘ ', , \ ':,'..,..: '-'.:t-r•---...rj‘mt,-.-ii.....:-F - •
, •r / •\--. /4e.1:4`...` . 1 . '--._
cr,' tric";480., •,
1 r ..._...
I --- •• .:,;1 . i , ....1„..::- ii,r. ...-,.. , . 1 r i::, • ..... ,e„......72..!=r__._,-. ....,....--2....._
.-.., .,•• :..: -1 ..• ...h a - • ... ,. .... , , ..• 7\ P .... ,.. • • _........
.„,. ip. • . . . ,...; c- t 1,,, • j„.. . % . \ 0,, i ..\ ,. ,
1 ,.• . '..; „ 04-
; ../. ..,,.- • x - ... .. .40 1
.:: • ...,. .- „ti ,., • \. 1 . ii
• , ._., ,./ . . .‘..) \ . . v... li. 4,
.:- i . .\ 7". •'` , , 0 ..
'. • - :::. $ '4' i,-4:".. --1.,-..1.i .1. --..-. , • .t . 11r3--- ___._.......T.1?1,11....--:...:
..,• •• 5- . • rt k.. --. ....-. vilitS - . • . ....•
- -1 •••••-•"1- - - ,— - ' ,.,:. • '-,--i----- •••- .--..
4,to 77,1.•' •, . 1 • 0 . .r-N....r.rrizate, .-..g--- __. -.., \ l' :I , . 17,
4,..,1
i t . # t --'•v,. •'t : em .., \ 1 ,... i . :i---. ‘ *- • • 1. I
,..., ., ,;- .... ..
,,•• _44, , d.r.. ▪ - ) ) -, It) :' ,/ .. )
.,- .ei C.,:ri. • ,..
A _Y il!'; ..1 IT A. , i• 41'• lit • • i
......,
iir) •- _ .. . '1; ' II . .., ..• .! .--/,-. .\
..„....i..---..,• . .
,s.:_.--- ___....,...;\ •, ,) . . vi. L..._.
1, ,11 , ' 1 ill .•'.'• / ,/* • .,t r. e. 4.7.4v.441 sr
. •V,
cy ! . ... ..,,, ..., A.;i• •I I! 1 s.
,•- 'IA.-
- • -...,.
C° I •• .... - - .• ,. 1 /' '.. ' ''' ...0(.. 5.1' iii II! 4 -..-.1 r.v. rn . •AO- 1
/ '. . l , ,,,- )"4 ,. 11,
•, -.N.k_ 1 .4101), ...," -1.
• i —i •-:- ...,,z:' - , / ----.---'t---**--* ..".'"r-. ',- -illilk. — . .. . .V. ' ...1.1 i•IdiVj
. .; 1/.\..._, Influenf Lines ' 14 •
-. • .:,....
, f k .
/ / " 111 ‘ ', v ,
1. N. ‘‘, •Illi. 1:10i,\ .
- • '' — - 7 Bmit. ?e.tt .,, ./)/// , / . ., ... ‘ I • ....." •
. ,
.,-0:.' ("?.. :is...:::•\..
. ..,.'eii.). --- "` .',i,? '... ,.;
7 __
.,
1 SeWagli.,II 40ra: , , \
.../....i /.
. . • . , .t.... t ...*
:,...,.. t. , :, • • ,
• ' ,.13 7 6 • sr,-
"
• / ..• --..\ ., •'' )\ i ( 7'''V1 '
Tarboro WWTP . ,i, ,
•• •. Qi•v-`'',..$:•.1 0 . ,... ', Ct.• . .4.4q."..." .....
Discharge .. o •
. . •, I. • i i
. i , ' .11‘. 11 Duffel! 001
• ./ _ ........., •,.., I
' • .. / - .... Jj11) ( , ,..p f. ; ,re., -s-74----.‘j
f.-1 •1 .: it m ..- , , 1 i . ;:, \ ‘— : , /
,,, •,,,,„.,......,...,:,...\-.....).-\,...\,.....„ i
. .x. )e.
-.N'•‘..t.........,. ‘„_, I 1 ‘
.--.. I i . •'', • 1,I6(*) rri
1 , : I
i ! ilia I., . - • • 11 - -... '5,
#1 /25;tif - -- ---), _.- ' ..,--'#...-1 i - . i . : d•I I' t i. Il/ I I
--id -..-4•ft-&-i - ..• ' fr./ "s -"k ....'...r...,...
..—
, - .d•-• ,' i.C...-..- •-•- - -• --. ' :to '' \ ‘,r4 '
, . .
• .
. .
. t'• ..•••- ,
• ; f 1, .
`,A ... ,11). ' -.- • 't- ,—
. . .-- ' • ....Y .--\=*----.......----10 I .
• .1 .-" h ' '
N
1', \
• • •
-.- . I0 ,.....14."; • .-/... .' . I " "'"Nk % 7' :.• 1, I. '''' .
C•' . , ....-- %
., --.-A .• ct , k i
• , ) i ,
'- .•
• • k‘.I. n . • e ... / N •
• / ' (.:, -k ‘
, . - ' Ilk V'?
• ,.. 1 l , I
..77 ‘ . •
; "iti i' 1 %.
1
i r • ..t..: , ,, . .
A
Town of Tarboro WWTP N
NPDES Permit No. NC0020605
Non-Discharge Permit No. WQ0002047
USGS Quads:
Tarboro, NC 1981
0 500' 1000' 2000' Rocky Mount, NC 1985
Scale: f____• ••• J

- t*3'14 -' ' ' . • aNi .„.,,,,,.; sA •
-- , -
. . - 0 fi.. ....-- l'Oirt.., :4-. •• . .._ 'Si C'ta
. , ,
' •PO -,1•,..,.i A _ •,\.t-',.*4,*i Pita rtt
• 4000. ,-, . ^ 4‘ ..___..."`*- _....--, • a
...- -Z„...„-.......\ ..., : •• -•t ' itt .,,,• I' % - tt.04..-S.t
Golf t i a Ni, - .., , - ;47,‘"
..e- ---. _, ...." ...... ..,,--. r, . , o
Course .. ....* ,..--
, ' .0.,*\ 1 wt.:, ;1541! .
.
- .
-1. '.. .•- ' %1i\ - , fN -..„---:"...oP-
........ ... - .4,--
'cjil 1. d 0.'' ..'... . (,, '. '';''S)iip'S!t‘• \74# N. ' 14"-; '
' 8 yr - .j•*#
.0e-, . - -lcre-
' 1 •
1ii
.. N,
,i A%is .'"' ........• _
_- -
-°:, )0/
• / t.ti:JO*, , ,,_-",.,--- i - . CI • ft -1_,—. -..-----
_......_
-...„,, •• al , .& __,..--- J.= ---,, tr,. ..
Z._.$1 • ,,,
Ik‘,>. • : 7./. . • ' Ei.x1,nati ,- -
. ,k, 4„ _V
f
`. :--- .-.„--"1:, ;
• ate i •••••
, • .
.r.'.4•1 \V' ' .0 r .,„ - \
ffr-
_t ,, '.% ---'-----"•-•-__
''':: " '- ••••' ". 11 .
.
gUb•St4ii#Ofc . ‘. " `tliat.
f I/
‘ 1 .
1 ) Lem 1, • i t/ q,„ ..... i . ..,,,
, ‘
„:„„„ , ......__ ., ...„...,___......, 1 .., , , . d„i ,,,,,,,„ ._,
..i. , ,
\ . ,
, I.... , ,.. ..,„
„.........._.__:. , ,61 , •
. ... ... ,,,,...
% - t
1 "k ,.
-___A__•,!. --- -
- ,
• ..-
r— TIN
e1.40.' i
\- /-•:‘, %I --1
„ 4 0 ".. alU.•-Ns.... *4, - ' I'- -;* • 41
3.,
'4+.
I
,0 '‘ • 11:
. N.... „,,,
4 4. -
e fir
t S gerspc
\/
• 1 -; ewa it ‘ .... \\ •
•0 ' ' •clic° 1 ,
•,,.
. i . 0
0 , ,
\,7 .• • et . C
• 1 <
1 ,
1 ,
$ DISCHARGE
OUTFALL 001 1
. 1. WWTP
\t t , •
. . :-; •,I
•
. ._
I 1
)
I / •._ I
Town of Tarboro WWTP
NPDES: NC0020605
A deo)
Non-Discharge: WQ0002047
Feet
re/ma rienewai
0 1,000 2,000
February 2019 TV
[HE WOOTEN COM PAN
iate 02/C6/4,, J - ,.dgecombe ,nty\larborniulltlIntral-acs\arborc_NPUES mxcl

Town of Tarboro Wastewater Treatment Plant
. .
104 .,
•. Headworks Process Flow Diagram
•... •.
..., •••
Primary Clarifiers
1
Anaerobic Digesters eft% '-' eggli fib- . Trickling Filters
, , . ..11,, ,.;1.• -.-1,-.11.,••
. .
II
....0 eirja
. Secondary Clarifiers
... ' - .
-- ,,
II
- IellI4IL‘‘ °111111*
.•..
....,.
Sludge Drying Beds - Cascade
,, Disinfection
•- Aeration
,..,.-
. , i • „,
Activated Sludge ,•••••%;-, .-,-"`;,,r
_ -• „ Aeration Basins
Po
I l' - -Iil --.
,..-
Aerobic Digesters '--,.. --"-
..,'"-...„,..,..„..,c.:
110 .
%It'---
-1 `•-•,, .. '
Aerated Sludge Holding Lagoon

Sludge Management Plan

Sludge Management Plan
Town of Tarboro Wastewater Treatment Plant
NPDES Permit No. NC0020605
Non-Discharge Permit No. WQ0002047
The Town of Tarboro operates a 5.0 mgd modified biological nutrient removal (BNR) plant
which discharges its effluent into the Tar River in the Tar-Pamlico River Basin under NPDES
Permit No. NC0020605. Waste sludge from the primary clarifiers is discharged into two (2)
anaerobic digesters for sludge stabilization while waste activated sludge from the modified BNR
system is pumped to the aerobic sludge digester for stabilization. The anaerobically and
aerobically stabilized sludges are later pumped to the aerated sludge basin for further long term
stabilization and storage prior to disposal by land application. Periodically, supernatant from the
anaerobic digester, aerobic digester, and sludge stabilization/storage basin is withdrawn and
recycled back to the plant headworks for reprocessing. Sludge can also be dewatered using
sludge drying beds prior to disposal by land application.
The stabilized sludge that meets pollutant limits and Class B pathogen reduction and vector
attraction reduction requirements is disposed of in accordance with Non-Discharge Permit No.
WQ0002047. The Class B pathogen reduction requirement is met using Alternative 1 and the
vector attraction reduction requirement is met performing Option 9. Pathogen reduction is
verified through in-house monitoring of fecal coliform bacteria. Sludge is land applied on five
sites (37 fields) totaling 828 acres. The 200 acre Tarboro Farm site is owned by the Town while
the Bourne Farm and Taylor Farm sites are owned by private parties.

Priority Pollutant Analyses

Town of Tarboro
Priority Pollutant Analysis
7/8/2014 4/14/2015 7/19/2016 1/19/2017 10/4/2018
METALS(TOTAL RECOVERABLE),CYANIDE,PHENOLS,AND HARDNESS.
ANTIMONY ug/L
ARSENIC ug/L
BERYLLIUM ug/L
CADMIUM ug/L
CALCIUM ug/L 9300 8500 8460 8910 9500
CHROMIUM ug/L
COPPER ug/L 6.2
LEAD ug/L
MAGNESIUM ug/L 2760 2050 1660 2020 2280
MERCURY ng/L 1.66 0.565 1.17 1.02 2.05
NICKEL ug/L
SELENIUM ug/L
SILVER ug/L
THALLIUM ug/L
ZINC ug/L 15 18 12.9
CYANIDE mg/L 0.024
TOTAL PHENOLIC
COMPOUNDS mg/L 0.075 0.023
HARDNESS(as CaCO3) mg/L 34.60 29.6 28 30.6 33.1
VOLATILE ORGANIC COMPOUNDS
ACROLEIN ug/L
ACRYLONITRILE ug/L
BENZENE ug/L
BROMOFORM ug/L
CARBON TETRACHLORIDE ug/L
CHLOROBENZENE ug/L
CHLORODIBROMO- ug/L
METHANE
CHLOROETHANE ug/L
2-CHLOROETHYLVINYL ug/L
ETHER

CHLOROFORM ug/L
DICHLOROBROMO- ug/L
METHANE
1.1-DICHLOROETHANE ug/L
1,2-DICHLOROETHANE ug/L
TRANS-I,2-DICHLORO- ug/L
ETHYLENE
1,1-DICHLORO-ETHYLENE ug/L
1,2-DICHLOROPROPANE ug/L
1,3-DICHLORO-PROPYLENE ug/L
ETHYLBENZENE ug/L
METHYL BROMIDE ug/L
METHYL CHLORIDE ug/L
METHYLENE CHLORIDE ug/L
1,1,2,2-TETRA-
CHLOROETHANE ug/L
TETRACHLORO-ETHYLENE ug/L
TOLUENE ug/L
1,1,1-TRICHLOROETHANE ug/L
1,1,2-TRICHLOROETHANE ug/L
TRICHLOROETHYLENE ug/L
VINYL CHLORIDE ug/L
ACID-EXTRACTABLE COMPOUNDS
P-CHLORO-M-CRESOL ug/L
2-CHLOROPHENOL ug/L
2.4-DICHLOROPHENOL ug/L
2,4-DIMETHYLPHENOL ug/L
4,6-DINITRO-O-CRESOL ug/L
2,4-DINITROPHENOL ug/L
2-NITROPHENOL ug/L
4-NITROPHENOL ug/L
PENTACHLOROPHENOL ug/L
PHENOL ug/L
2,4,6-TRICHLOROPHENOL ug/L
BASE-NEUTRAL COMPOUNDS
ACENAPHTHENE ug/L

ACENAPHTHYLENE ug/L
ANTHRACENE ug/L
BENZIDINE ug/L
BENZO(A)ANTHRACENE ug/L
BENZO(A)PYRENE ug/L
3,4 BENZO-FLUORANTHENE ug/L
BENZO(GHI)PERYLENE ug/L
BENZO(K)
ug/L
FLUORANTHENE
BIS(2-CHLOROETHOXY) ug/L
METHANE
BIS(2-CHLOROETHYL)- ug/L
ETHER
BIS(2-CHLOROISO-PROPYL) ug/L
ETHER
BIS(2-ETHYLHEXYL) ug/L
PHTHALATE
4-BROMOPHENYL PHENYL ug/L
ETHER
BUTYL BENZYL PHTHALATE ug/L
2-CHLORO-NAPHTHALENE ug/L
4-CHLORPHENYL PHENYL ug/L
ETHER
CHRYSENE ug/L
DI-N-BUTYL PHTHALATE ug/L
DI-N-OCTYL PHTHALATE ug/L
DIBENZO(A,H)ANTHRACENE ug/L
1.2-DICHLOROBENZENE ug/L
1.3-DICHLOROBENZENE ug/L
1,4-DICHLOROBENZENE ug/L
3,3-DICHLORO-BENZIDINE ug/L
DIETHYL PHTHALATE ug/L
DIMETHYL PHTHALATE ug/L
2,4-DINITROTOLUENE ug/L
2,6-DINITROTOLUENE ug/L
1,2-DIPHENYL-HYDRAZINE ug/L
FLUORANTHENE ug/L
FLUORENE ug/L
HEXACHLOROBENZENE ug/L

HEXACHLORO-BUTADIENE ug/L
HEXACHLOROCYCLO- ug/L
PENTADIENE
HEXACHLOROETHANE ug/L 1
INDENO(1,2,3-CD)PYRENE ug/L
ISOPHORONE ug/L
NAPHTHALENE ug/L
NITROBENZENE ug/L
N-NITROSODI-N- ug/L
PROPYLAMINE
N-NITROSODI-METHYLAMINE ug/L
N-NITROSODI-PHENYLAMINE ug/L
PHENANTHRENE ug/L
PYRENE ug/L
1,2,4-TRICHLOROBENZENE ug/L
NITROBENZENE-D5(s) 53% 38% 74% 79% 68%
2-FLUOROBIPHENYL(S) 54% 33% 78% 73% 67%
TERPHENYL-D14(S) 63% 48% 100% 87% 104%
PHENOL-D6(S) 18% 15% 33% 31% 27%
2-FLOROPHENOL(S) 30% 23% 45% 41% 42%
2,4,6 TRIBROMOPHENOL 55% 47% 77% 84% 71%
DIBROMOFLUOROMETHANE
(S)
4-BROMOFLUOROBENZENE
97% 105% 101% 97% 105%
TOLUENE-D8(S) 97% 102% 102% 103% 103%
1,2-DICHLORETHANE-D4(S) 96% 111% 95% 97% 96%
TOTAL DISSOLVED SOLIDS mg/L 260 214 68 225 274
NITROGEN, mg/L 1.4 3.1 0.5 1 1.4
KJELDAHL,TOTAL
NITROGEN,AMMONIA mg/L 0.11 2.1
NITROGEN,TOTAL mg/L 4.4
NITROGEN,NO2 PLUS NO3 mglL 11.8 4.1 3.9 8.3 13
PHOSPHORUS mg/L 1.1 0.053 0.14 0.096 1.2
PHENOL mg/L 0.075 0.023

9l'6£ 917£
6170'0 SLO'0
iZO'0 iZO'0
£'9 86
i0/nIa# 0
0/AIa# 0
i0/nIa# 0
i0/nIa# 0
£6Z'6 90'Z
bS6Z 09LZ
i0/nIa# 0
Z'9 Z'9
i0/AIa# 0
17E68 00S6
0/nIa# 0
i0/AIa# 0
i0/nIa# 0
i0/nIa# 0
a6eaeny xeW

Pace Analytical Services.Inc.
,/11ace Analytical' 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pxaacs.com [phone]
July 24, 2014
Mr. Mike Allen
Town of Tarboro
506 Dowd Street
PO Box 220
Tarboro, NC 27886
RE: Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302
Dear Mr.Allen:
Enclosed are the analytical results for sample(s) received by the laboratory on July 08, 2014. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
Enclosures
Pam,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc. Page 1 of 30

Pace Analytical Servkas,Inc.
ace Analytical 9800 Kincey Ave. SuiteHurneravale,NC zeo787a
MWN.pacoiB com
(704)e75-90e2
CERTIFICATIONS
Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302
Charlotte Certification IDs
9800 Kincey Ave.Ste 100,Huntersville,NC 28078 Florida/NELAP Certification#:E87627
North Carolina Drinking Water Certification#:37706 Kentucky UST Certification#:84
North Carolina Field Services Certification#:5342 West Virginia Certification#:357
North Carolina Wastewater Certification#:12 Virginia/VELAP Certification#:460221
South Carolina Certification#:99006001
Asheville Certification IDs
2225 Riverside Dr.,Asheville,NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAPCertification#:E87648 South Carolina Certification#:99030001
Massachusetts Certification#:M-NC030 West Virginia Certification#:356
North Carolina Drinking Water Certification#:37712 VirginlaNELAP Certification#:460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc. Page 2 of 30

Pace Analytical Services,Inc.
9800 Klncey Ave. Suite 100
,/11.
ace Analytical Huntersvllle,NC28078
www.pacelebs.00m [phone]
SAMPLE ANALYTE COUNT
Project: Tarboro PPA7/7l14
Pace Project No.: 92208302
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92208302001 WASTEWATER EFFLUENT EPA 1664B CLW 1 PASI-C
EPA200.7 JMW 15 PASI-A
EPA1631E SH1 1 PASI-A
EPA625 RES 60 PASI-C
EPA624 GAW 39 PASI-C
SM 2540C WRC 1 PASI-A
EPA 350.1 AES2 1 PASI-A
EPA 351.2 JDA 1 PASI-A
EPA 353.2 DMN 1 PAS1-A
EPA 365.1 JDA 1 PASI-A
EPA 420.4 DMN 1 PASI-A
SM 4500-CN-E JDA 1 PASI-A
92208302002 Field Blank EFFLUENT EPA1631E SH1 1 PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc.. Page 3 of 30

Pace Analytical Services,Inc.
aceAnalytica'r 9800 Kincey Ave. Suite 100
Hunte svllle,NC 28078
WNW peceiat c.ccvn
[phone]
ANALYTICAL RESULTS
Project: Tarboro PPA 7/7/14
Pace Project No : 92208302
Sample: WASTEWATER EFFLUENT Lab ID: 92208302001 Collected: 07/07/14 09:00 Received: 07/08/14 15:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM,Oil and Grease Analytical Method:EPA 16648
Oil and Grease ND mg/L 5.0 1 07/11/14 08:36
200.7 MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA 200.7
Antimony ND ug/L 5.0 1 07/10/14 15:50 07/12/14 00:53 7440-36-0
Arsenic ND ug/L 10.0 1 07/10/14 15:50 07/12/14 00:53 7440-38-2
Beryllium ND ug/L 1.0 1 07/10/14 15:50 07/12/14 00:53 7440-41-7
Cadmium ND ug/L 1.0 1 07/10/14 15:50 07/12/1400:53 7440-43-9
Calcium 9300 ug/L 100 1 07/10/14 15:50 07/12/14 00:53 7440-70-2
Chromium ND ug/L 5.0 1 07/10/14 15:50 07/12/14 00:53 7440-47-3
Copper ND ug/L 5.0 1 07/10/14 15:50 07/12/14 00:53 7440-50-8
Lead ND ug/L 5.0 1 07/10/14 15:50 07/12/14 00:53 7439-92-1
Magnesium 2760 ug/L 100 1 07/10/14 15:50 07/12/14 00:53 7439-95-4
Nickel NO ug/L 5.0 1 07/10/14 15:50 07/12/14 00:53 7440-02-0
Selenium NO ug/L 10.0 1 07/10/14 15:50 07/12/14 00:53 7782-49-2
Silver ND ug/L 5.0 1 07/10/14 15:50 07/12/14 00:53 7440-22-4
Thallium ND ug/L 10.0 1 07/10/14 15:50 07/12/14 00:53 7440-28-0
Hardness,Total(SM 2340B) 34600 ug/L 662 1 07/10/14 15:50 07/12/14 00:53
Zinc 16.0 ug/L 10.0 1 07/10/14 15:50 07/12/14 00:53 7440-66-6
1631E Mercury,Low Level Analytical Method:EPA 1631E Preparation Method:EPA 1631 E
Mercury 1.86 ng/L 0.50 1 07/17/14 15:00 07/18/14 13:08 7439-97-6
825 MSSV Analytical Method:EPA625 Preparation Method:EPA625
Acenaphthene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 83-32-9
Acenaphthylene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 208-96-8
Anthracene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 120-12-7
Benzo(a)anthracene ND ug/L 5.0 1 07/11/14 12:50 07;;15/14 08:33 56-55-3
Benzo(a)pyrene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 50-32-8
Benzo(k)fluoranthene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 205-99-2
Benzo(g,h,l)perylene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 191-24-2
Benzo(k)fluoranthene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 207-08-9
4-Bromophenylphenyl ether ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 101-55-3
Butylbertzylphthalate ND ug/L 5.0 1 07/11/14 12:50 07/15)14 08:33 85-68-7
4-Chioro-3-methylphenol ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 59-50-7
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 07/11/14 12:50 07/15/14 06:33 111-91-1
bis(2-Chloroethyl)ether ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 111-44-4 10
bis(2-Chloroisopropyl)ether ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 108-60-1
2-Chloronaphthalene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 91-58-7
2-Chlorophenol ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 95-57-8 10
4-Chlorophenyiphenyl ether ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 7005-72-3
Chrysene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 218-01-9
Dibenz(a,h)anthracene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 53-70-3
1,2-Dichlorobenzene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 95-50-1 10
1,3-Dichlorobenzene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 541-73-1 10
1,4-Dichlorobenzene ND ug/L 5.0 1 07/11/14 12:50 07/15/1408:33 106-46-7 10
3,3'-Dichlorobenzidine ND ug/L 25.0 1 07/11/14 12:50 07/15/14 08:33 91-94-1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc.. Page 4 of 30

Pace Analytkel Services,Inc.
�/ ]
o 9800 Kincey Ave. Suite 1C0
aceAnalytical Huntersvllle,NC 28078
www.recaies.com [phone]
ANALYTICAL RESULTS
Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302
Sample: WASTEWATER EFFLUENT Lab ID: 92208302001 Collected: 07/07/14 09:00 Received: 07/08/14 15:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
625 MSSV Analytical Method:EPA 625 Preparation Method:EPA 625
2,4-Dichlorophenol ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 120-83-2
Dlethylphthalate ND ug/L 5,0 1 07/11/14 12:50 07/15/1408:33 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 07/11/14 12:50 07/15/14 08:33 105-67-9
Dimethylphthalate ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 131-11-3
DI-n-butylphthalate ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 07/11/14 12:50 07/15/14 08:33 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 07/11/14 12:50 07/15/1408:33 51-28-5
2,4-Dinitrotoluene ND ug/L 5.0 1 07/11/14 12:50 07/15/1408:33 121-14-2
2,6-Dinitrotoluene ND ug/L 5.0 1 07/11/14 12:50 07/15/1408:33 606-20-2
Di-n-octylphthalate ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 117-84-0
1,2-Diphenylhydrazine ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 122-86-7
bis(2-Ethylhexypphthalate ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 117-81-7
Fluoranthene ND ug/L 5.0 1 07/11/14 12:50 07/15/140823 206-44-0
Fluorene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 86-73-7
Hexachlorobonzene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 07/11/14 12:50 07/15/14 08:33 77-47-4
Hexachloroethane ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 67-72-1 10
Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 07/11/14 12:50 07/15114 08:33 193-39-5
Isophorone ND ug/L 10.0 1 07/11/14 12:50 07/15/14 08:33 78-59-1
Naphthalene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 91-20-3
Nitrobenzene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 0833 98-95-3
2-Nitrophenot ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 88-75-5
4-Nitrophenol ND ug/L 50.0 1 07/11/14 12:50 07/15/14 08:33 100-02-7
N-Nftrosodimethylamine ND ug/L 5.0 1 07/11/14 12:50 07/15/14 0833 62-75-9 IO
N-Nitroso-di-n-propylamine ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 621-64-7 10
N-N/trosodiphenyla mine ND ug/L 10.0 1 07/11/14 12:50 07/15/14 08:33 86-30-6
Pentachlorophenol ND ug/L 10.0 1 07/11/14 12:50 07/15/14 08:33 87-86-5
Phenanthrene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 0833 85-01-8
Phenol ND ug/L 5.0 1 07/11/14 12:50 07/15/14 0833 106-95-2 10
Pyrene ND ug/L 5.0 1 07/11/14 12:50 07/15/14 08:33 129-00-0
2.4,6-Trichlorophenol ND ug/L 10.0 1 07/11/14 12:50 07/15/14 08:33 88-06-2
Surrogates
Nitrobenzene-d5(S) 53 % 10-120 1 07/11/14 12:50 07/15/14 08:33 4165-60-0
2-Fluoroblphenyl(S) 54 % 15-120 1 07/11/14 12:50 07/15/14 08:33 321-60-8
Terphenyl-d14(S) 63 % 11-131 1 07/11/14 12:50 07/15/14 08:33 1718-51-0
Phenol-d6(S) 18 % 10-120 1 07/11/14 12:50 07/15/14 08:33 13127-88-3 10
2-Fluorophenol(S) 30 % 10-120 1 07/11/14 12:50 07/15/14 08:33 367-12-4 10
2,4,6-Tribromophenol(S) 55 % 10-137 1 07/11/14 12:50 07/15/14 08:33 118-79-6
824 Volatile Organics Analytical Method:EPA 624
Acroiein ND ug/L 5.0 1 07/16/14 05:51 107-02-8
Acrylonitrile ND ug/L 50.0 1 07/16/14 05:51 107-13-1
Benzene ND ug/L 2.0 1 07/16/1405:51 71-43-2
Bromodichloromethane ND ug/L 2.0 1 07/16/14 05:51 75-27-4
Bromofonn ND ug/L 2.0 1 07/16/1405:51 75-25-2
Bromomethane ND ug/L 2.0 1 07/16/14 05:51 74-83-9
Carbon tetrachloride ND ug/L 2.0 1 07/16/14 05:51 56-23-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07(24/2014 07:59 AM without the wntten consent of Pace Analytical Services,Inc.. Page 5 of 30

Pace Analytical Services,Inc.
ace Analytical* 9800 KinceyAve. Suite 100
Huntersville,NC 28078
wwwpacuebs.carn [phone]
ANALYTICAL RESULTS
Project: Tarboro PPA 7/7/14
Pace Project No. 92208302
Sample: WASTEWATER EFFLUENT Lab ID: 92208302001 Collected: 07/07/14 09:00 Received: 07/08/14 15:30 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua!
624 Volatile Organics Analytical Method:EPA 624
g M
Chlorobenzene ND ug/L 2.0 1 07/16/14 05:51 108-90-7
Chloroethane ND ug/L 2.0 1 07/16/14 05:51 75-00-3
2-Chloroethylvinyl ether ND ug/L 5.0 1 07/16/14 05:51 110-75-8
Chloroform ND ug/L 2.0 1 07/16/14 05:51 67-66-3
Chloromethane ND ug/L 2.0 1 07/16/1405:51 74.87-3
Dibromochloromethane ND ug/L 2.0 1 07/16/14 05:51 124-48-1
1,2-Dichlorobenzene ND ug/L 2.0 1 07/16/14 05:51 95-50-1
1,3-Dichlorobenzene ND ug/L 2.0 1 07/16/1405:51 541-73-1
1,4-Dichlorobonzene ND ug/L 2.0 1 07/16/14 05:51 106-46-7
1,1-Dichloroethane ND ug/L 2.0 1 07/16/1405:51 75-34-3
1,2-Dichioroethano ND ug/L 2.0 1 07/16/1405:51 107-06-2
1,1-Dichloroethene ND ug/L 2.0 1 07/16/14 05:51 75-35-4
trans-1,2-Dichloroethene ND ug/L 2.0 1 07/16/14 05:51 156-60-5
1,2-Dichloropropane ND ug/L 2.0 1 07/16/14 05:51 78-87-5
cis-1,3-Dichloropropene ND ug/L 2.0 1 07/16/1405:51 10061-01-5
trans-1,3-Dichloropropene ND ug/L 2.0 1 07/16/1405:51 10061-02-6
Ethylbenzene ND ug/L 2.0 1 07/16/14 05:51 100-41-4
Hexachlorc-1,3-butadiene ND ug/L 5.0 1 07/16/14 05:51 87-68-3
Methylene Chloride ND ug/L 2.0 1 07/16/14 05:51 75-09-2
Naphthalene ND ug/L 5.0 1 07/16/14 05:51 91-20-3
1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 07/16/1405:51 79-34-5
Tetrachloroethene ND ug/L 2.0 1 07/16/14 05:51 127-18-4
Toluene ND ug/L 2.0 1 07/16/14 05:51 108-88-3
1,2,4-Trlchlorobenzene ND ug/L 2.0 1 07/16/14 05:51 120-82-1
1,1,1-Trichloroethene ND ug/L 2.0 1 07/16/14 05:51 71-55-6
1,1,2-Trichloroethane ND ug/L 2.0 1 07/16/14 05:51 79-00-5
Trichloroothene ND ug/L 2.0 1 07/16/14 05:51 79-01-6
Trichlorofluoromethane ND ug/L 2.0 1 07/16/14 05:51 75-69-4
Vinyl chloride ND ug/L 2.0 1 07/16/14 05:51 75-01-4
Surrogates
4-Bromofluorobenzene(S) 97 % 70-130 1 07/16/14 05:51 460-00-4
Toluene-d8(S) 97 % 70-130 1 07/16/14 05:51 2037-26-5
1,2-Dichloroethane-d4(S) 96 % 70-130 1 07/16/14 05:51 17060-07-0
2640C Total Dissolved Solids Analytical Method:SM 2540C
Total Dissolved Solids 260 mg/L 25.0 1 07/10/14 17:13
360.1 Ammonia Analytical Method:EPA 350.1
Nitrogen,Ammonia 0.11 mg/L 0.10 1 07/11/14 17:20 7664-41-7
361.2 Total Kjeldahl Nitrogen Analytical Method:EPA351.2
Nitrogen,Kjeldahl,Total 1.4 rng/L 0.50 1 07/21/14 10:15 7727-37-9
363.2 Nitrogen,NO2/NO3 pres. Analytical Method:EPA 353.2
Nitrogen,NO2 plus NO3 11.8 mg/L 0.080 4 07/18/14 20:42
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc. Page 6 of 30

Pace Analytical Services,Inc.
aceAnalytical 9800 Klncey Ave. Suite 100
Huntersvllle,NC 28078
s+rw s. [phone]
ANALYTICAL RESULTS
Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302
Sample: WASTEWATER EFFLUENT Lab ID: 92208302001 Collected: 07/07/14 09:00 Received: 07/08/14 15:30 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
366.1 Phosphorus,Total Analytical Method:EPA 385.1
Phosphorus 1.1 mg/L 0.050 1 07/15/141531 7723-14-0
420.4 Phenolics,Total Analytical Method:EPA 420.4
Phenol 0.076 mg/L 0.0050 1 07/22/1420:44 108-95-2 M1
4600CNE Cyanide,Total Analytical Method:SM 4500-CN-E
Cyanide 0.024 mg/L 0.0050 1 07/20/14 11:22 57-12-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc. Page 7 of 30

Pace Analytical Services,Inc.
ace Analytical 9rjoo <inceyAve suite Huntersvllle,NC 2807878
wn.v pace;at s mm (7 04)075-9092
ANALYTICAL RESULTS
Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302
Sample: Field Blank EFFLUENT Lab ID: 92208302002 Collected: 07/07/14 09:00 Received: 07/08/14 15:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method:EPA 1631E Preparation Method:EPA 1631 E
Mercury NO ng/L 0.50 1 07/17/14 15:00 07/18/14 13:15 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc. Page 8 of 30

Pace Analytical Services,Inc.
aceAnalytical• 9800 Klncey Ave. Suite 100
Huntersvllle,NC 28078
. ./11111
! wwwpeceMOa.oan
[phone]
QUALITY CONTROL DATA
Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302
QC Batch: GCSV/18181 Analysis Method: EPA 16848
QC Batch Method: EPA 1664B Analysis Description: 1664 HEM,Oil and Grease
Associated Lab Samples: 92208302001
METHOD BLANK: 1239701 Matrix: Water
Associated Lab Samples: 92208302001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 5.0 07/11/14 08:19
LABORATORY CONTROL SAMPLE: 1239702
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Oil and Grease rng/L 40 37.2 93 78-114
MATRIX SPIKE SAMPLE: 1239703
92208405002 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits QualMers
Oil and Grease mg/L ND 40 37.8 85 78-114
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented Rothe rigid of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc.. Page 9 of 30

Pace Analytical 8.rvlcas,Inc.
e 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
, if°
www.paceleea.cam
I [phone]
I
QUALITY CONTROL DATA
Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302
QC Batch: MERP/6864 Analysis Method: EPA 1631E
QC Batch Method: EPA 1631E Analysis Description: 1631E Mercury,Low Level
Associated Lab Samples: 92208302001,92208302002
METHOD BLANK: 1244537 Matrix: Water
Associated Lab Samples: 92208302001,92208302002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 07/18/14 12:08
METHOD BLANK: 1244538 Matra: Water
Associated Lab Samples: 92208302001,92208302002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 07118/14 13:53
METHOD BLANK: 1244539 Matrix: Water
Associated Lab Samples: 92208302001,92208302002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 07/18/14 15:33
LABORATORY CONTROL SAMPLE: 1244540
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Mercury ng/L 5 4.98 100 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1244541 1244542
MS MSD
92207685002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Mercury ng/L 0.938 25 25 24.7 24.9 95 96 71-125 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1244543 1244544
MS MSD
92208367001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Mercury ng/L 6.07 25 25 27.8 28.1 87 88 71-125 1
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc.. Page 10 of 30

Pace Analytical Services,Inc.
aceAnalytical n 9800 KlnceyAve. Suite 100
Huntersville,NC 2807E
wore,.ecaoCs.com [phone]
QUALITY CONTROL DATA
Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302
QC Batch: MPRP/16418 Analysis Method: EPA 200.7
QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET I
Associated Lab Samples: 92208302001
METHOD BLANK: 1239338 Matrix: Water
Associated Lab Samples: 92208302001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Antimony ug/L ND 5.0 07/11/14 23:52
Arsenic ug/L ND 10.0 07/11/14 23:52
Beryllium ug/L ND 1.0 07/11/14 23:52
Cadmium ug/L ND 1.0 07/11/14 23:52
Calcium ug/L ND 100 07/11/14 23:52
Chromium ug/L ND 5.0 07/11/14 23:52
Copper ug/L ND 5.0 07/11/14 23:52
Hardness,Total(SM 2340B) ug/L ND 662 07/11/14 23:52
Lead ug/L ND 5.0 07/11/14 23:52
Magnesium ug/L ND 100 07/11/14 23:52
Nickel ug/L ND 5.0 07/11/14 23:52
Selenium ug/L ND 10.0 07/11/14 23:52
Silver ug/L ND 5.0 07/11/14 23:52
Thallium ug/L ND 10.0 07/11/14 23:52
Zinc ug/L ND 10.0 07/11/14 23:52
LABORATORY CONTROL SAMPLE: 1239339
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Antimony ug/L 500 460 92 85-115
Arsenic ug/L 500 454 91 85-115
Beryllium ug/L 500 466 93 85-115
Cadmium ug/L 500 469 94 85-115
Calcium ug/L 5000 4760 95 85-115
Chromium ug/L 500 471 94 85-115 '
Copper ug/L 500 456 91 85-115
Hardness,Total(SM 2340B) ug/L 31300
Lead ug/L 500 454 91 85-115
Magnesium ug/L 5000 4720 94 85-115
Nickel ug/L 500 464 93 85-115
Selenium ug/L 500 448 90 85-115 i
Silver ug/L 250 235 94 85-115 '
Thallium ug/L 500 438 88 85-115
Zinc ug/L 500 459 92 85-115
Results presented on this page are In the units indicated by the"units"column except where art alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc. Page 11 of 30

m N1 (n (nz r I () O 00 DD y
m d < m an d m o m m a oo D 7 S - mED- Z w o d o 0 m m
oo .- m ' m 0 a m 2 3 c 3 �. 3 7 n m m 3 m m aa. a, 5 c 3 ? = m m
a 3 3 c y 3 3 3 3 " � 3 3 c c 3 3 3 X o
cn
0 3 0 M 3 3 [D
A m X m A cD
0 m In a m m oz
V n � fA
Cn
Ii
N
K oO '� 73 N ��T 2.• n
a � N W O zo
a U _ N -0 i
X x 2
3 m m D
C C C C C cc CccC C C C C C C C C C C C C C C 0 V
CO
0 CO 0 0 CO CO 0 0 0 CO CO 0 COCO 0 CO rO ra O r3 0 CO 0 Rl CO CO CO CO rC] O
C
a - � r- r= `rr 1— I--- r- r= r= r- r= C -0 r � � rrr . � r--- rr- r= r- r- r= c
r A
m u CD O 5a N no
5 o m o m
-i 73 0 0
14
O O m .c (C�� YOtDB co m tJ
o m ¢ O Z Z Z Z W Z to V N Z m W Z Z Z Z .C—.. 8 W V Z Z CA Co7r A Z o CW+) N E W — Z Z G 8 W
r 0 0 0 0 O r N o r-A r Oo O r N O O O O CD N O O N N 0 0 S O N O rn N O O .. o CD
co
N O N O D
� � � �
O oo ton oo 00 00 00000 ° 00 ^no008 000S0S0 `) m U' D
T o 0 0 0 0 0 00 O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 r'
o b
w o a o a -f
o o Q 0 SENSE
000 0 Do
0 0 0 0 0 0 0 0 000 0 0 0 00 $ 0 00 0 0 z
m 1
D g i x N M N70
� � O
QAy Aa (q� 03 IQ (pJ m M ff(..)) ca 8
2 �c N A W CO N O N O N 1 0 C,) +1 0 CD ^ N W N J 0 0 0) 0 N O CCp V O V N 0 C) L D
0 D
Z 1
d A , 7) —1D
Co co CD -4pC '� co O vc N co N N A A 0 V O A A N A - O
W V (JI p A O N V
CD V A CD A Cl CD 0 IV W O CD O O _ 0p _ 0 _
V CCD N 0 D 0
0 V) 0 CD V A W
c) (/) o
ae
Cp pp c(pp C(pp ttpp .ZI ((DD o .Z1
g28222 IJ OD N N W 0 N N co -+ 0 0 W N O N OV m -A 0 v f 1 N
a
s eK aim
O OD ccpp �(pp CCpp m 0 J ' ppop CCDD .... 0ca 0
A co W A CD W CO (JI N O N A m N 88 V U) W Ej T O CO CD 0 CD n
X
R. V V V V V V V V V V V V V V C * V V J V V J J V V V V V V V r
00000 00 C0� 0 0009 CQ�� 3 8888888
o� 00000� 000� 000� C0t000�9999999 3 23
v
88888 88 O O OO OO O i n O O O O O O O O8) 8 (02
0800 A n co
8 D
c .� xi2 m
s
-13 V C
" -+ O N O � .4 -+ -+ O N " N O O 0 � -4 O " " -4 -4 N � + N O O K O (15 rt X
13
D
r4 O m •
o A A m Z 'c
no
co C7 a
o
N m M
O
0 OD
m O

r
Pace Analytical Services,Inc.
9800 Klncey Ave. Suite 100
aceAnalytical Huntersvllle,NC 28078
,vww.pacMaCs.rom [phone]
QUALITY CONTROL DATA
Project: Tarboro PPA 777/14
Pace Project No.: 92208302
QC Batch: MSV/27575 Analysis Method: EPA 624
QC Batch Method: EPA 624 Analysis Description: 624 MSV
Associated Lab Samples: 92208302001
METHOD BLANK: 1242610 Matrix: Water
Associated Lab Samples: 92208302001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1,1-Trlchloroethane ug/L ND 2.0 07/16/1401:47
1,1,2,2-Tetrachloroethane ug/L ND 2.0 07/16/1401:47
1,1,2-Trichloroethane ug/L ND 2.0 07/16/14 01:47
1,1-Dichloroethane ug/L ND 2.0 07/16/14 01:47
1,1-Dlchloroethene ug/L ND 2.0 07/16/1401:47
1,2,4-Trlchlorobenzene ug/L ND 2.0 07/16/1401:47
1,2-Dichlorobenzene ug/L ND 2.0 07/16/1401:47
1,2-Dichloroethane ug/L ND 2.0 07/16/14 01:47
1,2-Dichloropropane ug/L ND 2.0 07/16/14 01:47
1,3-Dichlorobenzene ug/L ND 2.0 07/16/14 01:47
1,4-Dlchlorobenzene ug/L ND 2.0 07/16/14 01:47
2-Chloroethylvinyt ether ug/L ND 5.0 07/16/14 01:47
Acrolein ug/L ND 5.0 07/16/1401:47
Acrylonitrile ug/L ND 50.0 07/16/14 01:47
Benzene ug/L ND 2.0 07/16/14 01:47
Bromodichloromethane ug/L ND 2.0 07/16/14 01:47
Bromoform ug/L ND 2.0 07/16/14 01:47
Bromomethane ug/L ND 2.0 07/16/1401:47
Carbon tetrachloride ug/L ND 2.0 07/16/14 01:47
Chlorobenzene ug/L ND 2.0 07/16/1401:47
Chloroethane ug/L ND 2.0 07/16/1401:47
Chloroform ug/L ND 2.0 07/16/14 01:47
Chloromethane ug/L ND 2.0 07/16/1401:47
cis-1,3-Dichloropropene ug/L ND 2.0 07/16/1401:47
Dlbromochloromethane ug/L ND 2.0 07/16/14 01:47
Ethylbenzene ug/L ND 2.0 07/16/14 01:47
Hexachloro-1,3-butadiene ug/L ND 5.0 07/16/1401:47
Methylene Chloride ug/L ND 2.0 07/16/14 01:47
Naphthalene ug/L ND 5.0 07/16/14 01:47
Tetrachloroethene ug/L ND 2.0 07/16/1401:47
Toluene ug/L ND 2.0 07/16/1401:47
trans-12-Dichloroethene ug/L ND 2.0 07/16/1401:47
trans-1,3-Dichloropropene ug/L ND 2.0 07/16/1401:47
Trichloroethene uglL ND 2.0 07/16/1401:47
Trlchlorofluoromethane ug/L ND 2.0 07/16/14 01:47
Vinyl chloride ug/L ND 2.0 07/16/14 01:47
1,2-Dichloroethane-d4(S) % 97 70-130 07/16/14 01:47
4-Bromofluorobenzene(S) % 106 70-130 07/16/14 01:47
Toluene-d8(S) % 96 70-130 07/16/14 01:47
Resale presented on this page are In the urine Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full.
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc.. Page 13 of 30

Pace Analytical Services,Inc.
/!?eAnalytical Y 9800 KlnceyAve Suite 100
Huntersville,NC 28078
wxw psceutns.com [phone]
I
QUALITY CONTROL DATA
Project: Tarboro PPA 7/7(14
Pace Project No.: 92208302
LABORATORY CONTROL SAMPLE: 1242611
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,1,1-Trlchloroethane ug/L 20 18.7 93 52-162
1,1,2,2-Tetrachloroethe ne ug/L 20 20.0 100 46-157
1,1,2-Trichloroethene ug/L 20 20.3 102 52-150
1,1-Dichloroethane ug/L 20 17.8 89 59-155
1,1-Dichloroethene ug/L 20 18.1 90 1-234
1,2,4-Trichlorobenzene ug/L 20 23.4 117 70-130
1,2-Dichlorobenzene ug/L 20 20.7 104 18-190
1,2-Dichloroethane ug/L 20 17.1 86 49-155
1,2-Dichloropropane ug/L 20 19.5 98 1-210
1,3-Dichlorobertzene ug/L 20 19.5 97 59-156
1,4-Dichlorobenzene ug/L 20 19.1 96 18-190
2-Chloroethylvinyl ether ug/L 40 25.9 65 1-305
Acroleln ug/L 100 94.7 95 15-152
Acrylonitrile ug/L 100 96.1 96 75-132
Benzene ug/L 20 19.8 99 37-151
Bromodichloromethane ug/L 20 19.7 98 35-155
Bromoform ug/L 20 23.3 117 45-169
Bromomethane ug/L 20 10.1 51 1-242
Carbon tetrachloride ug/L 20 21.1 106 70-140
Chlorobenzene ug/L 20 19.4 97 37-160
Chloroethane ug/L 20 16.4 82 14-230
Chloroform ug/L 20 18.3 92 51-138
Chloromethane ug/L 20 11.7 59 1-273
cls-1,3-Dichloropropene ug/L 20 20.3 102 1-227
Dibromochloromethane ug/L 20 20.9 105 53-149
Ethylbenzene ug/L 20 19.6 98 37-162
Hexachloro-1,3-butadiene ug/L 20 24.2 121 70-130
Methylene Chloride ug/L 20 18.6 93 1-221
Naphthalene ug/L 20 22.1 110 70-130
Tetrachloroethene ug/L 20 21.5 107 64-148
Toluene ug/L 20 19.5 98 47-150
trans-1,2-Dlchloroethene ug/L 20 18.7 94 54-156
trans-1,3-Dichloropropene ug/L 20 20.6 103 17-183
Trichloroethene ug/L 20 21.8 109 71-157
Trlchlorofluorornethene ug/L 20 15.4 77 17-181
Vinyl chloride ug/L 20 16.2 81 1-251
1,2-Drchloroethane-d4(S) % 93 70-130
4-Bromofluorobenzene(S) % 107 70-130
Toluene-d8(S) % 97 70-130
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc.. Page 14 of 30

Pace Analytical Services,Inc.
n 9800KinceyAve. Suite100
- ace Analytical Huntersville,NC 28078
.vvs paca,nts.corn [phone]
QUALITY CONTROL DATA
Project: Tarboro PPA 7r7/14
Pace Project No.: 92208302
QC Batch: OEXT/28783 Analysis Method: EPA625
QC Batch Method: EPA 625 Analysis Description' 625 MSS
Associated Lab Samples: 92208302001
METHOD BLANK: 1240219 Matrix: Water
Associated Lab Samples: 92208302001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,2-Dichlorobenzene ug/L ND 5.0 07/15/1400:53
1,2-Diphenylhydrazine ug/L ND 5.0 07/15/1400:53
1,3-Dichlorobenzene ug/L ND 5.0 07/15/14 00:53
1,4-Dichlorobenzene ug/L ND 5.0 07/15/14 00:53
2,4,6-Trichtorophenol ug/L ND 10.0 07/15/14 00:53
2,4-Dichlorophenol ug/L ND 5.0 07/15/14 00:53
2,4-Dimethylphenol ug/L ND 10.0 07/15/14 00:53
2,4-Dinitrophenol ug/L ND 50.0 07/15/14 00:53
2,4-Dinitrotoluene ug/L ND 5.0 07/15/14 00:53
2,6-Dinitrotoluono ug/L ND 5.0 07/15/14 00:53
2-Chloronaphthalone ug/L ND 5.0 07/15/14 00:53
2-Chlorophenol ug/L ND 5.0 07/15/14 00:53
2-Nitrophenol ug/L ND 5.0 07/15/14 00:53
3,3'-Dichlorobenzidine ug/L ND 25.0 07/15/14 00:53
4,6-Dinitro-2-methylphenol ug/L ND 20.0 07/15/14 00:53
4-Bromophenylphenyl ether ug/L ND 5.0 07/15/14 00:53
4-Chioro-3-methylphenol ug/L ND 5.0 07/15/14 00:53
4-Chloraphenylphenyl ether ug/L ND 5.0 07/15/14 00:53
4-Nitrophenol ug/L ND 50.0 07/15/14 00:53
Acenaphthene ug/L ND 5.0 07/15/1400:53
Acenaphthylene ug/L ND 5.0 07/15/14 00:53
Anthracene ug/L ND 5.0 07/15/14 00:53
Benzo(a)anthracene ug/L ND 5.0 07/15/14 00:53
Benzo(a)pyrene ug/L ND 5.0 07/15/14 00:53
Benzo(b)fluoranthene ug/L ND 5.0 07/15/14 00:53
Benzo(g,h,1)perylene ug/L ND 5.0 07/15/14 00:53
Benzo(k)fluoranthene ug/L ND 5.0 07/15/14 00:53
bis(2-Chloroethoxy)methane ug/L ND 10.0 07/15/14 00:53
bis(2-Chloroethyi)ether ug/L ND 5.0 07/15/14 00:53
bis(2-Chloroisopropy0 ether ug/L ND 5.0 07/15/14 00:53
bis(2-Ethylhexy)phthalate ug/L ND 5.0 07/15/1400:53
Butylbenzylphtha late ug/L ND 5.0 07/15/1400:53
Chrysene ug/L ND 5.0 07/15/14 00:53
Di-n-butylphthalate ug/L ND 5.0 07/15/14 00:53
Di-n-octytphthalate ug/L ND 5.0 07/15/1400:53
Dibenz(a,h)anthracene ug/L ND 5.0 07/15/1400:53
Diethylphthalate ug/L ND 5.0 07/15/14 00:53
Dlmethylphthalate ug/L ND 5.0 07/15/14 00:53
Fluoranthene ug/L ND 5.0 07/15/14 00:53
Fluorone ug/L ND 5.0 07/15/1400:53
Hexachlorobenzene ug/L ND 5.0 07/15/1400:53
Resutte presented on this page are In the units Indicated by the'Units"column except where an alternate unit Is preeented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc. Page 15 of 30

Pace Analytical Services,Inc.
ace Analytical J 9800 Kincey Ave. Suite Huntersville,NC 2807878
www.pacwabs.com [phone]
QUALITY CONTROL DATA
Project Tarboro PPA 7/7/14
Pace Project No.: 92208302
METHOD BLANK: 1240219 Matrix: Water
Associated Lab Samples: 92208302001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Hexachlorocyclopentadiene ug/L ND 10.0 07/15/14 00:53
Hexachloroethane ug/L ND 5.0 07/15/14 00:53
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 07/15/14 00:53
Isophorone ug/L ND 10.0 07/15/14 00:53
N-Nitroso-di-n-propyla mine ug/L ND 5.0 07/15/14 00:53
N-Nitrosodimethylamine ug/L ND 5.0 07/15/14 00:53
N-Nitrosodiphenylamine ug/L ND 10.0 07/15/1400:53
Naphthalene ug/L ND 5.0 07/15/14 00:53
Nitrobenzene ug/L ND 5.0 07/15/1400:53
Pentachlorophenol ug/L ND 10.0 07/15/1400:53
Phenanthrene ug/L ND 5.0 07/15/1400:53
Phenol ug/L ND 5.0 07/15/14 00:53
Pyrene ug/L ND 5.0 07/15/1400:53
2,4,6-Tribromophenol(S) % 70 10-137 07/15/14 00:53
2-Fluorobiphenyl(S) % 79 15-120 07/15/14 00:53
2-Fluorophenol(S) % 45 10-120 07/15/14 00:53
Nitrobenzene-d5(S) % 73 10-120 07/15/14 00:53
Phenol-d6(S) % 28 10-120 07/15/14 00:53
Torphonyl-d14(S) % 89 11-131 07/15/14 00:53
LABORATORY CONTROL SAMPLE: 1240220
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,2-Dichlorobenzene ug/L 50 33.8 68 32-129
1,2-Diphenylhydrazlne ug/L 50 49.0 98 25-150
1,3-Dlchlorobenzene ug/L 50 32.3 65 1-172
1,4-Dichlorobenzene ug/L 50 33.3 67 20-124
2,4,6-Trichlorophenol ug/L 50 45.5 91 37-144
2,4-Dichlorophenol ug/L 50 45.1 90 1-191
2,4-Dimethylphenol ug/L 50 44.7 89 32-119
2,4-Dinitrophenol ug/L 250 254 102 1-181
2,4-Dinitrotoluene ug/L 50 49.7 99 39-139
2,6-Dinitrotoluene ug/L 50 50.7 101 50-158
2-Chloronaphthalene ug/L 50 40.4 81 60-118
2-Chlorophenol ug/L 50 41.6 83 23-134
2-Nitrophenol ug/L 50 46.1 92 29-182
3,3'-Dlchlorobenzidlne ug/L 100 93.3 93 1-262
4,6-Dinitro-2-methylphenol ug/L 100 102 102 1-181 I
4-Bromophenytphenyl ether ug/L 50 47.1 94 53-127
4-Chloro-3-methylphenol ug/L 100 91.6 92 22-147
4-Chbrophenylphenyl ether ug/L 50 47.7 95 25-158
4-Nitrophenol ug/L 250 105 42 1-132
Acenaphthene ug/L 50 45.0 90 47-145
Acenaphthylene ug/L 50 45.0 90 33-145
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc.. Page 16 of 30

i Pace Analytical Services,Inc.
ace Analytical' 9800 Kincey Ave. Suite 100
Hunte sville,NC 28078
;vrow.poco abs.com [phone]
QUALITY CONTROL DATA
Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302 i
LABORATORY CONTROL SAMPLE: 1240220
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Anthracene ug/L 50 46.6 93 1-166
Bonzo(a)anthracene ug/L 50 46.4 93 33-143
Benzo(a)pyrene ug/L 50 46.1 92 17-163
Benzo(b)fluoranthene ug/L 50 44.7 89 24-159
Benzo(g,h,)perylene ug/L 50 44.7 89 1-219
Benzo(k)fluoranthene ug/L 50 45.1 90 11-162
bis(2-Chloroethoxy)methane ug/L 50 45.0 90 33-184
bis(2-chloroethyl)ether ug/L 50 44.4 89 12-158
bis(2-Chloroisopropyl)ether ug/L 50 43.6 87 36-166
bis(2-Ethylhexyf)phthalate ug/L 50 51.4 103 8-158
Butylbenzytphthalate ug/L 50 51.7 103 1-152
Chrysene ug/L 50 46.3 93 17-168
Di-n-butylphthalate ug/L 50 52.9 106 1-118
Di-n-octylphthalate ug/L 50 50.5 101 4-146
Dibenz(a,h)anthracene ug/L 50 46.1 92 1-227
Diethylphthalate ug/L 50 50.4 101 1-114
Dimethylphthalate ug/L 50 49.1 98 1-112
Fluoranthene ug/L 50 48.8 98 26-137
Fluorene ug/L 50 48.3 97 59-121
Hexachlorobenzene ug/L 50 42.7 85 1-152
Hexachlorotyclopentadione ug/L 50 39.2 78 25-150
Hexachloroethane ug/L 50 31.5 63 40-113
Indeno(1,2,3-cd)pyrene ug/L 50 36.5 73 1-171
Isophorone ug/L 50 49.7 99 21-196
N-Nitroso-di-n-propylamine ug/L 50 48.1 96 1-230
N-Nltrosodlmethytamine ug/L 50 28.6 57 25-150
N-Nitrosodiphenylamine ug/L 50 45.7 91 25-150
Naphthalene ug/L 50 39.9 80 21-133
Nitrobenzene ug/L 50 42.6 85 35-180
Pentachtorophenol ug/L 100 101 101 14-176
Phenanthrene ug/L 50 45.1 90 54-120
Phenol ug/L 50 18.4 37 5-112
Pyrene ug/L 50 46.1 92 52-115
2,4,6-Tribromophenol(S) % 89 10-137
2-Fluorobiphenyl(S) % 84 15-120
2-Fluorophenol(S) % 51 10-120
Nitrobenzene-d5(S) % 83 10-120
Phenol-d6(S) e,6 35 10-120
Terphenyl-d14(S) % 92 11-131
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1240221 1240222
MS MSD
92208302001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
1,2-Dichtorobenzene ug/L ND 100 100 31.2 24.1 31 24 32-129 26 IO,M1
Results presented on tills page are In the unite Indicated by the-Unns"column except where an alternate unit Is presented to the light of the result_
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc. Page 17 of 30

Pace Analytical Services,Inc.
(/9
eA 9800 Kincey Ave. Suite 100
Analytical Huntersville,NC 28078
.wv,v prtcma^s u�* [phone]
QUALITY CONTROL DATA
Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1240221 1240222
MS MSD
92208302001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
1,2-Diphenylhydrazine ug/L ND 100 100 64.3 34.1 64 34 25-150 61 10
1,3-Dichlorobenzene ug/L ND 100 100 30.1 24.1 30 24 1-172 22 10
1,4-Dichlorobenzene ug/L ND 100 100 31.3 24.2 31 24 20-124 26 10
2,4,6-Trichlorophenol ug/L ND 100 100 43.3 24.7 43 25 37-144 55 10
2,4-Dichlorophenol ug/L ND 100 100 31.3 25.3 31 25 1-191 21 10
2,4-Dimethylphenol ug/L ND 100 100 32.7 25.5 33 25 32-119 25 10
2,4-Dinitrophenol ug/L ND 500 500 323 132 65 26 1-181 84 10
2,4-Dinitrotoluene ug/L ND 100 100 66.8 30.9 67 31 39-139 73 10
2,6-Dinitrotoluene ug/L ND 100 100 63.9 29.3 64 29 50-158 74 10
2-Chloronaphthalene ug/L ND 100 100 34.3 26.0 34 26 60-118 28 10,M1
2-Chlorophenol ug/L ND 100 100 31.9 25.1 32 25 23-134 24 10
2-Nitrophenol ug/L ND 100 100 32.3 24.3 32 24 29-182 28 10
3,3'-Dichlorobenzidine ug/L ND 200 200 130 59.5 65 30 1-262 75
4,6-Dinitro-2-methylphenol ug/L ND 200 200 138 59.0 69 30 1-181 80 10
4-Bromophenylphenyl ether ug/L ND 100 100 62.4 30.9 62 31 53-127 68 10
4-Chloro-3-methylphenol ug/L ND 200 200 94.5 56.3 47 28 22-147 51 10
4-Chlorophenylphenyl ether ug/L ND 100 100 56.0 30.7 56 31 25-158 58 10
4-Nitrophenol ug/L ND 500 500 202 94.8J 40 19 1-132 10
Acenaphthene ug/L ND 100 100 45.5 29.0 45 29 47-145 44 I0,M1
Acenaphthylene ug/L ND 100 100 44.6 28.2 45 28 33-145 45 10
Anthracene ug/L ND 100 100 64.8 33.0 65 33 1-166 65 10
Benzo(a)anthracene ug/L ND 100 100 87.3 33.1 67 33 33-143 68
Benzo(a)pyrene ug/L ND 100 100 67.5 30.7 67 31 17-163 75
Benzo(b)fluoranthene ug/L ND 100 100 66.6 32.1 67 32 24-159 70
Benzo(g,h,l)perylene ug/L ND 100 100 62.9 29.3 63 29 1-219 73
Benzo(k)fluoranthono ug/L ND 100 100 66.1 31.3 66 31 11-162 71
bis(2-Chloroethoxy)methane ug/L ND 100 100 31.4 25.4 31 25 33-184 21 I0,M1
bis(2-Chbroethyl ether ug/L ND 100 100 34.6 26.9 35 27 12-158 25 10
bis(2-Chloroisopropyl)ether ug/L ND 100 100 32.8 25.7 33 26 36-166 24 10,M1
bis(2-Ethylhexygphthalate ug/L ND 100 100 72.1 31.9 72 32 8-158 77
Butylbenzylphthalate ug/L ND 100 100 72.8 30.9 73 31 1-152 81
Chrysene ug/L ND 100 100 67.9 34.0 68 34 17-168 66
Di-n-butylphthalate ug/L ND 100 100 72.1 32.8 72 33 1-118 75 10
Di-n-octylphthalate ug/L ND 100 100 66.8 27.1 67 27 4-146 84
Dibenz(a,h)anthracene ug/L ND 100 100 64.8 30.2 65 30 1-227 73
Diethylphthatato ug/L ND 100 100 66.9 31.8 67 32 1-114 71 10
Dlmethytphthalate ug/L ND 100 100 64.2 31.2 64 31 1-112 69 10
Fluoranthene ug/L ND 100 100 67.4 33.4 67 33 26-137 67 10
Fluorene ug/L ND 100 100 58.4 31.5 58 32 59-121 60 I0,M1
Hexachlorobenzene ug/L ND 100 100 57.7 28.9 58 29 1-152 66 10
Hexachlorocyclopentadiene ug/L ND 100 100 29.4 21.8 29 22 25-150 30 10
Hexachloroethane ug/L ND 100 100 29.1 24.0 29 24 40-113 19 10,M1
Indeno(1,2.3-cd)pyrene ug/L ND 100 100 51.1 23.5 51 24 1-171 74
Isophorone ug/L ND 100 100 38.2 28.4 38 28 21-196 29 10
N-Nitroso-di-n-propylamine ug/L ND 100 100 34.9 26.1 35 26 1-230 29 10
N-Nitrosodimethylemine ug/L ND 100 100 28.7 22.7 29 23 25-150 23 10
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit le presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc. Page 18 of 30

Pace Analytical Services,Inc.
ace Analytical^ 9800 Kincey Ave. Suite 100
Hunts sville,NC 28078
awe pars:a^score [phone]
QUALITY CONTROL DATA
Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1240221 1240222
MS MSD
92208302001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
N-Nitrosodiphenylamine ug/L ND 100 100 63.7 32.9 64 33 25-150 64 10
Naphthalene ug/L ND 100 100 32.3 24.9 32 25 21-133 26 10
Nitrobenzene ug/L ND 100 100 32.2 25.1 32 25 35-180 25 IO,M1
Pentachlorophenol ug/L ND 200 200 133 58.1 67 29 14-176 79 10
Phenanthrene ug/L ND 100 100 63.2 32.3 63 32 54-120 65 10
Phenol ug/L ND 100 100 20.9 16.0 21 16 5-112 27 10
Pyrene ug/L ND 100 100 67.6 30.8 68 31 52-115 75
2,4,6-Tribromophenol(S) % 60 29 10-137 10
2-Fluorobiphenyl(S) % 33 26 15-120 10
2-Fluorophenol(S) % 23 18 10-120 tO
Nitrobenzene-d5(S) eb 32 24 10-120 tO
Phenol-d6(S) % 17 13 10-120 10
Terphenyl-d14(S) % 67 31 11-131
Results presented on this page are In the unite Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc. Page 19 of 30

Pace Analytical Services,Inc.
aceAnalytical a 9800 Kinney Ave. Suite 100
Huntersvllle,NC 28078
IwrvwpaceteDs oom [phone]
QUALITY CONTROL DATA
Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302
QC Batch: WET/32044 Analysis Method: SM 2540C
QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 92208302001
METHOD BLANK: 1239622 Matrix: N11bter
Associated Lab Samples: 92208302001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L NO 25.0 07/10/14 17:10
LABORATORY CONTROL SAMPLE: 1239623
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Dissolved Solids rng/L 250 256 102 90-110
SAMPLE DUPLICATE: 1239624
92208106001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 52.0 54.0 4
Results presented on this page are In the units Indicated by the"Unite"column except where an aaemate unit Is presented to the right or the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc.. Page 20 of 30

Pace Analytical Services,Inc.
m 9800KinoeyAve. Suite100
aceAnalytical Huntersville,NC 28078
www.pecelebs.com [phone]
QUALITY CONTROL DATA
Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302
QC Batch: WETA/19560 Analysis Method: EPA350.1
QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92208302001
METHOD BLANK: 1240548 Matrix: Water
Associated Lab Samples: 92208302001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Ammonia mg/L ND 0.10 07/11/14 16:51
LABORATORY CONTROL SAMPLE: 1240549
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 4.9 98 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1240550 1240551
MS MSD
92208906002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Dual
Nitrogen,Ammonia mg/L 47.5 5 5 52.1 52.8 92 105 90-110 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1240552 1240553
MS MSD
92208215001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Ree Limits RPD Dual
Nitrogen,Ammonia mg/L ND 5 5 5.1 4.8 101 96 90-110 5
Results presented on thle page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the rseult
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/24/2014 07:59 AM without the wntten consent of Pace Analytical Services,Inc. Page 21 of 30

Pace Analytical Services,Inc.
it, 9800 Kincey Ave. Suite 100
(1aceAnalytical Huntersville,NC 28078
wwwpacekbs.com [phone]
QUALITY CONTROL DATA
Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302
QC Batch: WETA/19619 Analysis Method: EPA 351.2
QC Batch Method: EPA 351.2 Analysis Description: 351.2 TKN
Associated Lab Samples: 92208302001
METHOD BLANK: 1244567 Matrix: Water
Associated Lab Samples: 92208302001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Kjeldahl,Total rng/L ND 0.50 0721/14 10:02
LABORATORY CONTROL SAMPLE: 1244568
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Kjeldahl,Total mg/L 10 10 100 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1244589 1244570
MS MSD
92209368001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Kjeldahl,Total mg/L 3.5 10 10 13.3 13.4 98 99 90-110 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1244571 1244572
MS MSD
92208352013 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Kjeldahl,Total mg/L 34•5 50 50 88.3 88.3 108 108 90-110 0
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right ci the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:0724/2014 07:59 AM without the written consent of Pace Analytical Services,Inc. Page 22 of 30

Pace Analytical Services,Inc.
• 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pecehrila.eom [phone]
QUALITY CONTROL DATA
Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302
QC Batch: WETA/19632 Analysis Method: EPA353.2
QC Batch Method: EPA 353.2 Analysis Description: 353,2 Nitrate+Nitrite,preserved
Associated Lab Samples: 92208302001
METHOD BLANK: 1245559 Matrix: Water
Associated Lab Samples: 92208302001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,NO2 plus NO3 mg/L ND 0.020 07/18/14 20:06
LABORATORY CONTROL SAMPLE: 1245560
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,NO2 plus NO3 mg/L 2.5 2.6 103 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1245561 1245562
MS MSD
92208540005 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,NO2 plus NO3 mg/L 0.77 2.5 2.5 3.2 3.2 98 97 75-125 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1245563 1245564
MS MSD
92208540006 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,NO2 plus NO3 rig/L 0.57 2.5 2.5 2.9 2.9 94 95 75-125 1
Reeulte presented on this page are In the units Indicated by the"Unite"column except where an alternate will Is presented to the right or the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc.. Page 23 of 30

Pace Analytical Services,Inc.
e 9800 Kincey Ave. Suite 100
aceAnalytical Huniersville,NC 28078
-"(< wwwpecelots.eam [phone]
QUALITY CONTROL DATA
Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302
QC Batch: WETA/19578 Analysis Method: EPA 365.1
QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus,Total
Associated Lab Samples: 92208302001
METHOD BLANK: 1241370 Matrix: Water
Associated Lab Samples: 92208302001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 07/15/1415:13
LABORATORY CONTROL SAMPLE: 1241371
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.5 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1241372 1241373
MS MSD
92207515001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rae Limits RPD Qual
Phosphorus mg/L 1.4 2.5 2.5 3.9 3.9 97 100 90-110 2
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1241374 1241375
MS MSD
92208201001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus mg/1- 0.87 2.5 2.5 3.4 3.4 100 100 90-110 0
Results presented on this page are in the unite indicated by the"Units"column except where an alternate unit is presented to the right of the result. 11
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:0724/2014 07:59 AM without the written consent of Pace Analytical Services,Inc.. Page 24 of 30

Pace Analytical Services,Inc,
• 9800 Kincey Ave. Suite 100
ceAnalytical Huntersville,NC 28078
w+ •rs + [phone]
QUALITY CONTROL DATA
Project: Tarboro PPA 7/7114
Pace Project No.: 92208302
QC Batch: WETA/19663 Analysis Method: EPA 420.4
QC Batch Method: EPA 420.4 Analysis Description: 420.4 Phenolics
Associated Lab Samples: 92208302001
METHOD BLANK: 1246862 Matrix: VVater
Associated Lab Samples: 92208302001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phenol mg/L ND 0.0050 07/22/14 20:40
LABORATORY CONTROL SAMPLE: 1246863
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phenol mg/L .05 0.051 102 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1246864 1246865
MS MSD
92208302001 Spike Spike MS MSD MS MSD %Rec '
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phenol mg/L 0.075 .05 .05 0.14 0.14 134 120 90-110 5 M1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1246886 1246867
MS MSD
92208352012 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phenol mg/L 4.3 .05 .05 3.9 3.9 -840 -740 90-110 1 M6
Results presented on this page are In the units Indicated by the"Units"column except where an enemata unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full,
Date:0724/2014 07:59 AM without the written consent of Pace Analytical Services,Inc.. Page 25 of 30

•
Pace Analytical Services,Inc.
`i
CQ�� ticaI• 9800KinceyAve. Suite 100
/JI/'I VG Huntersville,NC 28078
wwwpecelsesoom [phone]
1
QUALITY CONTROL DATA
Project: Tarboro PPA 7/7/14
Pace Project No.: 92206302
QC Batch: WETA/19617 Analysis Method: SM 4500-CN-E
QC Batch Method: SM 4500-CN-E Analysis Description: 4500CNE Cyanide,Total
Associated Lab Samples: 92208302001
METHOD BLANK: 1244514 Matrix: Water
Associated Lab Samples: 92208302001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Cyanide mg/L ND 0.0050 07/20/14 11:00
LABORATORY CONTROL SAMPLE: 1244515
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Cyanide mg/L .1 0.11 114 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1244516 1244517
MS MSD
92208967002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rae %Rec Limits RPD Qua)
Cyanide mg/L 0.0074 .1 .1 0.11 0.11 105 106 75-125 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1244518 1244519
MS MSD
92208236005 Spike Spike MS MSD MS MSD %Roc
Parameter Units Result Conc. Conc. Result Result %Rae %Rae Limits RPD Qual
Cyanide mg/L ND .1 .1 0.022 0.11 20 112 75-125 135 M1,R1
Results presented on this page are In the units indicated by the"Unite"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc.. Page 26 of 30

Pace Analytical Services,Inc.
aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
Nw,v pacn,ets,ccm [phone]
QUALIFIERS
Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to changes in sample preparation,dilution of
the sample aliquot,or moisture content.
ND-Not Detected at or above adjusted reporting limit.
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantltation Limit.
RL-Reporting Limit.
S-Surrogate
1,2-Diphenylhydrazine(8270 listed analyte)decomposes to Azobenzene.
Consistent with EPA guidelines,unfounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether,Styrene,and Vinyl chloride.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
LABORATORIES
PAST-A Pace Analytical Services-Asheville
PAST-C Pace Analytical Services-Charlotte
ANALYTE QUALIFIERS
10 The Internal standard response was outside the laboratory acceptance limits confirmed by reanalysis.The results
reported ere from the most QC compliant analysis.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc. Page 27 of 30

Pace Analytical Services,Inc.
_ ace Analytical* 9800 Kinsey Ave. Suite 100
Huntersville,NC 28078
w4w..pato,ats.,wm
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Tarboro PPA 7/7/14
Pace Project No.: 92208302
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92208302001 WASTEWATER EFFLUENT EPA 1664E GCSV/18181
92208302001 WASTEWATER EFFLUENT EPA200.7 MPRP/16418 EPA200.7 ICP/14833
92208302001 WASTEWATER EFFLUENT EPA 1631E MERP/6864 EPA 1631E MERC/6612
92208302002 Field Blank EFFLUENT EPA1631E MERP/6864 EPA 1631E MERC/6612
92208302001 WASTEWATER EFFLUENT EPA 625 OEXT/28783 EPA 625 MSSV/9391
92208302001 WASTEWATER EFFLUENT EPA 624 MSV/27575
92208302001 WASTEWATER EFFLUENT SM 2540C WET/32044
92208302001 WASTEWATER EFFLUENT EPA350.1 WETA/19560
92208302001 WASTEWATER EFFLUENT EPA351.2 WETA/19619
92208302001 WASTEWATER EFFLUENT EPA 353.2 WETA/19632
92208302001 WASTEWATER EFFLUENT EPA 365.1 WETA/19578
92208302001 WASTEWATER EFFLUENT EPA 420.4 WETA119663
92208302001 WASTEWATER EFFLUENT SM 4500-CN-E WETA119617
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/24/2014 07:59 AM without the written consent of Pace Analytical Services,Inc.. Page 28 of 30

i
CHAIN-OF-CUSTODY!Analytical Request Document co
L�1 I ICaI• The Chtend-Qi x is a LEGAL DOCUMENT.AI reteva t Sacks s rare be afforded aconitey. "Et
ot
apke y Ill/ a to
Section A Section B Section C
ibquised plena Wool:laine Rectured F'no)ect lnfonrotian: o
,/� Wke Inbrrnelion:'n'f (t)/1 G.t' —lc;,L. .e� R°°°"Ta: m;c.ti�,.�ale , n(\e`er Alte+ta`ne ►G11
0.
e 1 Spc1'►f A 1789688
Address:
•_ iL.QSao lAopy TO --- Cznpen Nan pt„I✓l a'(�t1,,CS REGULATORY AGENCY
fl+ ocd A/c. �76 q(o 'f.6• )( 2gO 1C;ey JGre'AlC- 1 WOES r GROUND WATER r DRINKING WATER
EmeP To: ` Rxdius Order t b• fio ariaf L15T RCRA r OTHER
w�1�^ nt{1G•'LrnC.C4••• r5--ACC/e �� ct727$Pets New( Sae London 1
y
57u _4t--471( F a.Z)641_ °ro}zt Name:
/',1� edit Do*DetN►AT: Protect Nub sin Penile* STATE
Requested Analysis Filtered(YIN)
6aabn D _ - _ r
Neev Codas itb.v,nwr..inian erne wpvELfteOF I COLLECTED Pre sometimes >
Daldro Waw Uri
i o r 4R7-r LiWater WT U
WnalotWalet vowi +� a l. c- VTIIaTs
s SSoid SL _ Z
SAMPLE ID
&mown IDs MOST BF tINtOLIE Tissue TS C) a • U apr u�3o
finer or U w p _
W W cl S
t DATE TIME DATE rune +e . . r I z z . Pace Project No/Lab LD-
1 tAiastew er -C la.r cl:G 7-70 Soa Or f d _e
2
4
as ,
4 1 - —
7 '
1 • r
8
f r 1 ,
10 •
r..
11
12 —
ADDTRONAL COMMENTS RELIM IIBNED BY 1 AFFILIATION DATE TEE ACCEPTED BY I AFRLIATION DATE Tlt! ' SAMPLE CONDrTtQI$5
ti
Local Le✓i r" d '.' .
6 1 6-ke— i-7-t..of /I: • 7-101 i 2-0i) ‘.
7-8-r 1530 Q. 4 4 44 .34 6.1 `I t`t `i
SAMPLER NAME AND SIGNATURE o I i\H ILi ifY4t vow parr oftAmPLET2: m l �c
e I Able►� ..j.. -.$ .>e__
-� �g
SIGNATURE a SAMPLER: If n I DATE Shed 7 € $ .g
'kcvbJ NNn.8Y aPa'q trd.I.r.tau.re....noel Pads NET 3a lei°ryseeer Yens end aprOenp so [l los donee n11.SG e✓none,totIntak f I es not peld Belie 70 dale (IIY.'DDrrTI: "7^ 1 m
F-A1L4-020rev.07.I6 7,lsy-2007

Document Name:Sample Condition Upon Document Revised:April 04,2013
aceArlaly/lcal Receipt(SCUR) Pape 1 of 2
/ '^^"^°"^^"•O"' Document No.: Issuing Authorities:
' F-RAL-CS-001-rev.02 Pace Asheville Quality Office
Client Name: TQJ 0D10
Where Received: El Huntersvllie O Asheville 0 Eden i Raleigh
Courier(Circle): Fed Ex UPS USPS Client Commercial de Other
Custody Seal on CoolerfBox Present: 0 yes 2 no Seals intact , yes ❑ no
Packing Material: ❑ Bubble Wrap B Bogs IZ Non, Other
Circle Thermometer Used:IR Gun S :1 072 853B7 e of Ice:420 Blue Nona ❑ Samples on lee,000ttng proves°hes begun
IR Omculk, 537
Temp Correction Factor: Addract 01 Lc . c Date and Inittek of personexamining
Corrected Cooler Temp.: ` C Biological Tissue Is Frozen: Yee No A chec
LI
Temp should be above freezing to a°c Comments:
Chain of Custody Present ' $IJee CJNo ON/A 1. • • - - ,
Chain of Custody Filled Cut: E v.s ONo ON/A 2. • .
Chain of Custody Relinquished: ,eiV•e ONo ON.'A 3.
Sampler Name&Signature on COC: eve* ONo ONA 4.
Samples Arrived within Hold Time: /Yea ONo ON/A S.
Short Hold Time Analyals'(<72hr): D yea No ON/A 8. --
Rush Turn Around Time Requested: Ovea (/No CNA 7.
Sufficient Volume: Yea DNo ON/A 8.
Correct Containers Used: Y.. ONo ON/A 9.
-Pace Containers Used: ( Yes ONo ONA
Containers Intact: yJYet ONo ON/A 10.
Filtered volume irecelved for Dissolved tests Oyes ONo 9'NA 11.
Sample Labels match COC: Yeero ON/A 12: V/i t \SAY' 1 �- ��UOA Wyl
�-Includes date/tlmefD/Ana is Matrix �/ L6L O&M—CAA + hl
Ali containers needing preeerve5on have been checked. N EI , OWA 13.
AU containers needing preservation aro round to be in t(1Y a ONo ON/A
compliance with EPA recommendation.
eO.pt.ortr VOA. co from TOC.0(0,WI-ORO(voter) 41iYee ONo
Samples checked for dechlorination: • 6Ye■ ONo ONA 14.
Headspace in VOA Vials(>6mm): Oyes ONo �wa 15.
Trip Blank Present: Oyes O JJlNo K� /A 16.
Trip Blank Custody Seals Present • DYse ❑No /JwA
Pace Trip Blank Lot#_(if purchased)-_ •
Client Notification/Resolution: Reid Data Required? Y / N
Person Contacted: Date/Time:
Comments!Resolution:
iWO# • 92
+ r rl`.pat?, N r,,,. _ f alct SCURF/SRF oat.; 7/F cf • „JG �' Y
Review:: /f o��r ■■ ' ;;7 '" S 3.' 4ti .
Note: Whenever there is a discrepancy affeling North Carolina compliance �., Nil III I I'p `. 'y$ `-g"1 " "� ,aamp,ee,a copy o`itch form will be sent to the North Carolina DEHNR I �'. r •
Certlfication•Office i.e out of hold,tneorrect preservadtve,out of tamp, 1 9220.030 r'l ar :M ^'r" T ` .t
( hoorrectcontainers) . . ' "I• r' Ii .I' .• 'r.,,r.
Page 30 of 30

Pace Analytical Services,Inc.
® 9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
wpmpooelebs corn
[phone]
May 05, 2015
Mr. Mike Allen
Town of Tarboro
506 Do
wd Street
PO Box 220
Tarboro, NC 27886
RE: Project: Wastewater 4/13
Pace Project No.: 92245377
Dear Mr. Allen:
Enclosed are the analytical results for sample(s) received by the laboratory on April 14, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sinc ly,
L rri ktton
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
/ without the written consent of Pace Analytical Services,Inc.. Page 1 of 24

Pace Analytical Services,Inc.
• 9800 Kincey Ave. Suite 100
7
aceAnalytical Huntersville,NC 28078
wwwrwcebns.cam [phone]
CERTIFICATIONS
Project: Wastewater 4/13
Pace Project No.: 92245377
Charlotte Certification IDs
9800 Kincey Ave.Ste 100,Huntersville,NC 28078 Florida/NELAP Certification#:E87627
North Carolina Drinking Water Certification#:37706 Kentucky UST Certification#:84
North Carolina Field Services Certification#:5342 West Virginia Certification#:357
North Carolina Wastewater Certification#: 12 Virginia/VELAP Certification#:460221
South Carolina Certification#:99006001
Asheville Certification IDs
2225 Riverside Drive,Asheville,NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAP Certification#: E87648 South Carolina Certification#:99030001
Massachusetts Certification#:M-NC030 West Virginia Certification#:356
North Carolina Drinking Water Certification#:37712 VirginiaNELAP Certification#:460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc.. Page 2 of 24

Pace Analytical Services,Inc.
m 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pace;bit own [phone]
SAMPLE ANALYTE COUNT
Project: Wastewater 4/13
Pace Project No.: 92245377
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92245377001 WASTE WATER EFFLUENT EPA 1664B CLW 1 PASI-C
EPA 200.7 JMW 15 PASI-A
EPA 1631E SH1 1 PASI-A
EPA 625 RES 60 PASI-C
EPA 624 GAW 39 PASI-C
SM 2540C JTJ 1 PASI-A
EPA 350.1 SER 1 PASI-A
EPA 351.2 JDA 1 PASI-A
EPA 353.2 SER 1 PASI-A
EPA 365.1 SER 1 PASI-A
EPA 420.4 DMN 1 PASI-A
SM 4500-CN-E AES2 1 PASI-A
92245377002 WASTEWATER EFF LLHG FIELD BLK EPA 1631E SH1 1 PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc.. Page 3 of 24

Pace Analytical Services,Inc.
9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
(1.
www.pece/abscrom [phone]
ANALYTICAL RESULTS
Project: Wastewater 4/13
Pace Project No.: 92245377
Sample: WASTE WATER Lab ID: 92245377001 Collected: 04/13/15 14:30 Received: 04/14/15 15:20 Matrix: Water
EFFLUENT
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM,Oil and Grease Analytical Method:EPA 1664E
Oil and Grease ND mg/L 5.0 1 04/22/15 07:34
200.7 MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA 200.7
Antimony ND ug/L 5.0 1 04/16/15 14:55 04/17/15 19:54 7440-36-0
Arsenic ND ug/L 10.0 1 04/16/15 14:55 04/17/15 19:54 7440-38-2
Beryllium ND ug/L 1.0 1 04/16/15 14:55 04/17/15 19:54 7440-41-7
Cadmium ND ug/L 1.0 1 04/16/15 14:55 04/17/15 19:54 7440-43-9
Calcium 8500 ug/L 100 1 04/16/15 14:55 04/17/15 19:54 7440-70-2
Chromium ND ug/L 5.0 1 04/16/15 14:55 04/17/15 19:54 7440-47-3
Copper ND ug/L 5.0 1 04/16/15 14:55 04/17/15 19:54 7440-50-8
Lead ND ug/L 5.0 1 04/16/15 14:55 04/17/15 19:54 7439-92-1
Magnesium 2050 ug/L 100 1 04/16/15 14:55 04/17/15 19:54 7439-95-4
Nickel ND ug/L 5.0 1 04/16/15 14:55 04/17/15 19:54 7440-02-0
Selenium ND ug/L 10.0 1 04/16/15 14:55 04/17/15 19:54 7782-49-2
Silver ND ug/L 5.0 1 04/16/15 14:55 04/17/15 19:54 7440-22-4
Thallium ND ug/L 10.0 1 04/16/15 14:55 04/17/15 19:54 7440-28-0
Hardness,Total(SM 23408) 29600 ug/L 662 1 04/16/15 14:55 04/17/15 19:54
Zinc ND ug/L 10.0 1 04/16/15 14:55 04/17/15 19:54 7440-66-6
1631E Mercury,Low Level Analytical Method:EPA 1631E Preparation Method: EPA 1631E
Mercury 0.565 ng/L 0.50 1 04/22/15 15:45 04/23/15 13:08 7439-97-6
625 MSSV Analytical Method:EPA 625 Preparation Method:EPA 625
Acenaphthene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 83-32-9
Acenaphthylene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 208-96-8
Anthracene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 120-12-7
Benzo(a)anthracene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 56-55-3
Benzo(a)pyrene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 50-32-8
Benzo(b)fluoranthene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 205-99-2
Benzo(g,h,i)perylene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 191-24-2
Benzo(k)fluoranthene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 207-08-9
4-Bromophenylphenyl ether ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 101-55-3
Butylbenzylphthalate ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 85-68-7
4-Chloro-3-methylphenol ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 59-50-7
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 04/20/15 19:00 04/24/15 11:43 111-91-1
bis(2-Chloroethyl)ether ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 111-44-4
bis(2-Chloroisopropyl)ether ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 108-60-1
2-Chloronaphthalene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 91-58-7
2-Chlorophenol ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 95-57-8
4-Chlorophenylphenyl ether ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 7005-72-3
Chrysene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 218-01-9
Dibenz(a,h)anthracene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 53-70-3
1,2-Dichlorobenzene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 95-50-1
1,3-Dichlorobenzene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 541-73-1
1,4-Dichlorobenzene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 106-46-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 4 of 24

Pace Analytical Services,Inc.
& 9800 Kincey Ave. Suite 100
ceAnalytical Huntersville,NC 28078
www.pacelabs.cam [phone]
ANALYTICAL RESULTS
Project: Wastewater 4/13
Pace Project No.: 92245377
Sample: WASTE WATER Lab ID: 92245377001 Collected: 04/13/15 14:30 Received: 04/14/15 15:20 Matrix: Water
EFFLUENT
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
625 MSSV Analytical Method: EPA 625 Preparation Method:EPA 625
3,3'-Dichlorobenzidine ND ug/L 25.0 1 04/20/15 19:00 04/24/15 11:43 91-94-1
2,4-Dichlorophenol ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 120-83-2
Diethylphthalate ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 04/20/15 19:00 04/24/15 11:43 105-67-9
Dimethylphthalate ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 131-11-3
Di-n-butylphthalate ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 04/20/15 19:00 04/24/15 11:43 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 04/20/15 19:00 04/24/15 11:43 51-28-5
2,4-Dinitrotoluene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 121-14-2
2,6-Dinitrotoluene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 606-20-2
Di-n-octylphthalate ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 117-84-0
1,2-Diphenyihydrazine ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 122-66-7
bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 117-81-7
Fluoranthene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 206-44-0
Fluorene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 86-73-7
Hexachlorobenzene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 04/20/15 19:00 04/24/15 11:43 77-47-4
Hexachloroethane ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 193-39-5
Isophorone ND ug/L 10.0 1 04/20/15 19:00 04/24/15 11:43 78-59-1
Naphthalene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 91-20-3
Nitrobenzene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 98-95-3
2-Nitrophenol ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 88-75-5
4-Nitrophenol ND ug/L 50.0 1 04/20/15 19:00 04/24/15 11:43 100-02-7
N-Nitrosodimethylamine ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1 04/20/15 19:00 04/24/15 11:43 86-30-6
Pentachlorophenol ND ug/L 10.0 1 04/20/15 19:00 04/24/15 11:43 87-86-5
Phenanthrene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 85-01-8
Phenol ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 108-95-2
Pyrene ND ug/L 5.0 1 04/20/15 19:00 04/24/15 11:43 129-00-0
2,4,6-Trichlorophenol ND ug/L 10.0 1 04/20/15 19:00 04/24/15 11:43 88-06-2
Surrogates
Nitrobenzene-d5(S) 38 % 10-120 1 04/20/15 19:00 04/24/15 11:43 4165-60-0 1g
2-Fluorobiphenyl(S) 33 % 15-120 1 04/20/15 19:00 04/24/15 11:43 321-60-8
Terphenyl-d14(S) 48 % 11-131 1 04/20/15 19:00 04/24/15 11:43 1718-51-0
Phenol-d6(S) 15 % 10-120 1 04/20/15 19:00 04/24/15 11:43 13127-88-3
2-Fluorophenol(S) 23 % 10-120 1 04/20/15 19:00 04/24/15 11:43 367-12-4
2,4,6-Tribromophenol(S) 47 % 10-137 1 04/20/15 19:00 04/24/15 11:43 118-79-6
624 Volatile Organics Analytical Method:EPA 624
Acrolein ND ug/L 5.0 1 04/24/15 00:38 107-02-8
Acrylonitrile ND ug/L 50.0 1 04/24/15 00:38 107-13-1
Benzene ND ug/L 2.0 1 04/24/15 00:38 71-43-2
Bromodichloromethane ND ug/L 2.0 1 04/24/15 00:38 75-27-4
Bromoform ND ug/L 2.0 1 04/24/15 00:38 75-25-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 5 of 24

Pace Analytical Services,Inc.
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project: Wastewater 4/13
Pace Project No.: 92245377
Sample: WASTE WATER Lab ID: 92245377001 Collected: 04/13/15 14:30 Received: 04/14/15 15:20 Matrix: Water
EFFLUENT
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
624 Volatile Organics Analytical Method:EPA 624
Bromomethane ND ug/L 2.0 1 04/24/15 00:38 74-83-9
Carbon tetrachloride ND ug/L 2.0 1 04/24/15 00:38 56-23-5
Chlorobenzene ND ug/L 2.0 1 04/24/15 00:38 108-90-7
Chloroethane ND ug/L 2.0 1 04/24/15 00:38 75-00-3
2-Chioroethylvinyl ether ND ug/L 5.0 1 04/24/15 00:38 110-75-8
Chloroform ND ug/L 2.0 1 04/24/15 00:38 67-66-3
Chloromethane ND ug/L 2.0 1 04/24/15 00:38 74-87-3
Dibromochloromethane ND ug/L 2.0 1 04/24/15 00:38 124-48-1
1,2-Dichlorobenzene ND ug/L 2.0 1 04/24/15 00:38 95-50-1
1,3-Dichlorobenzene ND ug/L 2.0 1 04/24/15 00:38 541-73-1
1,4-Dichlorobenzene ND ug/L 2.0 1 04/24/15 00:38 106-46-7
1,1-Dichloroethane ND ug/L 2.0 1 04/24/15 00:38 75-34-3
1,2-Dichloroethane ND ug/L 2.0 1 04/24/15 00:38 107-06-2
1,1-Dichloroethene ND ug/L 2.0 1 04/24/15 00:38 75-35-4
trans-1,2-Dichloroethene ND ug/L 2.0 1 04/24/15 00:38 156-60-5
1,2-Dichloropropane ND ug/L 2.0 1 04/24/15 00:38 78-87-5
cis-1,3-Dichloropropene ND ug/L 2.0 1 04/24/15 00:38 10061-01-5
trans-1,3-Dichloropropene ND ug/L 2.0 1 04/24/15 00:38 10061-02-6
Ethylbenzene ND ug/L 2.0 1 04/24/15 00:38 100-41-4
Hexachloro-1,3-butadiene ND ug/L 5.0 1 04/24/15 00:38 87-68-3 L3
Methylene Chloride ND ug/L 2.0 1 04/24/15 00:38 75-09-2
Naphthalene ND ug/L 5.0 1 04/24/15 00:38 91-20-3 L3
1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 04/24/15 00:38 79-34-5
Tetrachloroethene ND ug/L 2.0 1 04/24/15 00:38 127-18-4
Toluene ND ug/L 2.0 1 04/24/15 00:38 108-88-3
1,2,4-Trichlorobenzene ND ug/L 2.0 1 04/24/15 00:38 120-82-1
1,1,1-Trichioroethane ND ug/L 2.0 1 04/24/15 00:38 71-55-6
1,1,2-Trichloroethane ND ug/L 2.0 1 04/24/15 00:38 79-00-5
Trichloroethene ND ug/L 2.0 1 04/24/15 00:38 79-01-6
Trichlorofluoromethane ND ug/L 2.0 1 04/24/15 00:38 75-69-4
Vinyl chloride ND ug/L 2.0 1 04/24/15 00:38 75-01-4
Surrogates
4-Bromofluorobenzene(S) 105 a/o 70-130 1 04/24/15 00:38 460-00-4
Toluene-d8(S) 102 a/a 70-130 1 04/24/15 00:38 2037-26-5
1,2-Dichloroethane-d4(S) 111 c/a 70-130 1 04/24/15 00:38 17060-07-0
2540C Total Dissolved Solids Analytical Method:SM 2540C
Total Dissolved Solids 214 mg/L 25.0 1 04/17/15 11:14 J(D6)
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen,Ammonia 2.1 mg/L 0.10 1 04/17/15 02:57 7664-41-7
351.2 Total Kjeldahl Nitrogen Analytical Method:EPA 351.2
Nitrogen,Kjeldahl,Total 3.1 mg/L 0.50 1 04/24/15 11:11 7727-37-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 6 of 24

Pace Analytical Services,Inc.
caceAnalyfica/• 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
wwwpacelabs.com [phone]
ANALYTICAL RESULTS
Project: Wastewater 4/13
Pace Project No.: 92245377
Sample: WASTE WATER Lab ID: 92245377001 Collected: 04/13/15 14:30 Received: 04/14/15 15:20 Matrix: Water
EFFLUENT
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
353.2 Nitrogen,NO2/NO3 pres. Analytical Method:EPA 353.2
Nitrogen,NO2 plus NO3 4.1 mg/L 0.020 1 04/21/15 05:46
365.1 Phosphorus,Total Analytical Method:EPA 365.1
Phosphorus 0.053 mg/L 0.050 1 04/23/15 03:33 7723-14-0
420.4 Phenolics,Total Analytical Method:EPA 420.4
Phenol ND mg/L 0.010 1 04/21/15 17:10 108-95-2
4500CNE Cyanide,Total Analytical Method:SM 4500-CN-E
N 0 1 4/23/1 12: 1 7-1 -
Cyanide D mg/L 0 008 0 5 2 5 2 5
Sample: WASTEWATER EFF LLHG Lab ID: 92245377002 Collected: 04/13/15 14:30 Received: 04/14/15 15:20 Matrix: Water
FIELD BLK
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method:EPA 1631E Preparation Method:EPA 1631E
Mercury ND ng/L 0.50 1 04/22/15 15:45 04/23/15 13:16 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 7 of 24

Pace Analytical Services,Inc.
a 9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
www.pecelabs.com [phone]
QUALITY CONTROL DATA
Project: Wastewater 4/13
Pace Project No.: 92245377
QC Batch: GCSV/21028 Analysis Method: EPA 1664E
QC Batch Method: EPA 1664B Analysis Description: 1664 HEM,Oil and Grease
Associated Lab Samples: 92245377001
METHOD BLANK: 1440344 Matrix: Water
Associated Lab Samples: 92245377001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 5.0 04/22/15 07:26
LABORATORY CONTROL SAMPLE: 1440345
Spike LCS LCS % Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L 40 39.9 100 78-114
MATRIX SPIKE SAMPLE: 1440346
92246248001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L ND 40 33.1 80 78-114
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 8 of 24

Pace Analytical Services,Inc.
9800 Kince Ave. Suite 100
aceAnalyfical. Y
Huntersville,NC 28078
• www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Wastewater 4/13
Pace Project No.: 92245377
QC Batch: MERP/7765 Analysis Method: EPA 1631E
QC Batch Method: EPA 1631E Analysis Description: 1631E Mercury,Low Level
Associated Lab Samples: 92245377001,92245377002
METHOD BLANK: 1441495 Matrix: Water
Associated Lab Samples: 92245377001,92245377002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 04/23/15 11:46
METHOD BLANK: 1441496 Matrix: Water
Associated Lab Samples: 92245377001,92245377002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 04/23/15 14:02
METHOD BLANK: 1441497 Matrix: Water
Associated Lab Samples: 92245377001,92245377002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 04/23/15 15:49
LABORATORY CONTROL SAMPLE: 1441498
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Mercury ng/L 5 4.96 99 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1441499 1441500
MS MSD
92245321001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result % Rec %Rec Limits RPD Qual
Mercury ng/L 3.57 25 25 25.1 26.8 86 93 71-125 7
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1441501 1441502
MS MSD
92246343002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Mercury ng/L 9.34 25 25 33.7 33.4 97 96 71-125 1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 9 of 24

Pace Analytical Services,Inc.
a 9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
.vww.pacetebs.com [phone]
QUALITY CONTROL DATA
Project: Wastewater 4/13
Pace Project No.: 92245377
QC Batch: MPRP/18290 Analysis Method: EPA 200.7
QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET
Associated Lab Samples: 92245377001
METHOD BLANK: 1436381 Matrix: Water
Associated Lab Samples: 92245377001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Antimony ug/L ND 5.0 04/17/15 19:30
Arsenic ug/L ND 10.0 04/17/15 19:30
Beryllium ug/L ND 1.0 04/17/15 19:30
Cadmium ug/L ND 1.0 04/17/15 19:30
Calcium ug/L ND 100 04/17/15 19:30
Chromium ug/L ND 5.0 04/17/15 19:30
Copper ug/L ND 5.0 04/17/15 19:30
Hardness,Total(SM 2340B) ug/L ND 662 04/17/15 19:30
Lead ug/L ND 5.0 04/17/15 19:30
Magnesium ug/L ND 100 04/17/15 19:30
Nickel ug/L ND 5.0 04/17/15 19:30
Selenium ug/L ND 10.0 04/17/15 19:30
Silver ug/L ND 5.0 04/17/15 19:30
Thallium ug/L ND 10.0 04/17/15 19:30
Zinc ug/L ND 10.0 04/17/15 19:30
LABORATORY CONTROL SAMPLE: 1436382
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Antimony ug/L 500 498 100 85-115
Arsenic ug/L 500 479 96 85-115
Beryllium ug/L 500 484 97 85-115
Cadmium ug/L 500 485 97 85-115
Calcium ug/L 5000 4790 96 85-115
Chromium ug/L 500 481 96 85-115
Copper ug/L 500 491 98 85-115
Hardness,Total(SM 2340B) ug/L 31900
Lead ug/L 500 486 97 85-115
Magnesium ug/L 5000 4830 97 85-115
Nickel ug/L 500 479 96 85-115
Selenium ug/L 500 480 96 85-115
Silver ug/L 250 241 97 85-115
Thallium ug/L 500 476 95 85-115
Zinc ug/L 500 481 96 85-115
Results presented on this page are In the unite Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 10 of 24

Pace Analytical Services,Inc.
• 9800 Kincey Ave. Suite 100
ace Analytical Huntersviile,NC 28078
www.pacelabscom [phone]
QUALITY CONTROL DATA
Project: Wastewater 4/13
Pace Project No.: 92245377
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1436383 1436384
MS MSD
92245359001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Antimony ug/L ND 500 500 504 501 100 100 70-130 1
Arsenic ug/L ND 500 500 486 484 97 97 70-130 0
Beryllium ug/L ND 500 500 491 483 98 97 70-130 2
Cadmium ug/L ND 500 500 488 484 98 97 70-130 1
Calcium ug/L 10.9 5000 5000 15600 15500 94 92 70-130 1
mg/L
Chromium ug/L ND 500 500 484 477 96 95 70-130 1
Copper ug/L 0.0096 500 500 506 502 99 99 70-130 1
mg/L
Hardness,Total(SM 2340B) ug/L 28.9 60500 59900 1
mg/L
Lead ug/L ND 500 500 490 484 97 96 70-130 1
Magnesium ug/L 0.39 5000 5000 5210 5140 96 95 70-130 1
mg/L
Nickel ug/L ND 500 500 482 476 96 95 70-130 1
Selenium ug/L ND 500 500 483 484 96 97 70-130 0
Silver ug/L ND 250 250 243 241 97 96 70-130 1
Thallium ug/L ND 500 500 479 477 95 95 70-130 0
Zinc ug/L 0.026 500 500 507 503 96 95 70-130 1
mg/L
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1436385 1436386
MS MSD
92245289003 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Antimony ug/L ND 500 500 506 504 101 100 70-130 0
Arsenic ug/L ND 500 500 497 497 99 99 70-130 0
Beryllium ug/L ND 500 500 485 486 97 97 70-130 0
Cadmium ug/L ND 500 500 488 487 98 97 70-130 0
Calcium ug/L 297000 5000 5000 310000 308000 268 222 70-130 1 J(M1)
Chromium ug/L 124 500 500 601 603 95 96 70-130 0
Copper ug/L 5.9 500 500 503 528 100 105 70-130 5
Hardness,Total(SM 2340B) ug/L 748000 801000 795000 1
Lead ug/L ND 500 500 450 448 90 90 70-130 0
Magnesium ug/L 1740 5000 5000 6400 6400 93 93 70-130 0
Nickel ug/L ND 500 500 458 457 91 91 70-130 0
Selenium ug/L ND 500 500 490 487 97 96 70-130 0
Silver ug/L ND 250 250 244 244 97 97 70-130 0
Thallium ug/L ND 500 500 426 430 85 86 70-130 1
Zinc ug/L ND 500 500 464 477 92 94 70-130 3
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Pa a 11 of 24
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. 9

Pace Analytical Services,Inc.
® 9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
wwwpecelebe.corn [phone]
QUALITY CONTROL DATA
Project: Wastewater 4/13
Pace Project No.: 92245377
QC Batch: MSV/31356 Analysis Method: EPA 624
QC Batch Method: EPA 624 Analysis Description: 624 MSV
Associated Lab Samples: 92245377001
METHOD BLANK: 1442449 Matrix: Water
Associated Lab Samples: 92245377001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1,1-Trichloroethane ug/L ND 2.0 04/23/15 20:09
1,1,2,2-Tetrachloroethane ug/L ND 2.0 04/23/15 20:09
1,1,2-Trichloroethane ug/L ND 2.0 04/23/15 20:09
1,1-Dichloroethane ug/L ND 2.0 04/23/15 20:09
1,1-Dichloroethene ug/L ND 2.0 04/23/15 20:09
1,2,4-Trichlorobenzene ug/L ND 2.0 04/23/15 20:09
1,2-Dichlorobenzene ug/L ND 2.0 04/23/15 20:09
1,2-Dichloroethane ug/L ND 2.0 04/23/15 20:09
1,2-Dichloropropane ug/L ND 2.0 04/23/15 20:09
1,3-Dichlorobenzene ug/L ND 2.0 04/23/15 20:09
1,4-Dichlorobenzene ug/L ND 2.0 04/23/15 20:09
2-Chloroethylvinyl ether ug/L ND 5.0 04/23/15 20:09
Acrolein ug/L ND 5.0 04/23/15 20:09
Acrylonitrile ug/L ND 50.0 04/23/15 20:09
Benzene ug/L ND 2.0 04/23/15 20:09
Bromodichloromethane ug/L ND 2.0 04/23/15 20:09
Bromoform ug/L ND 2.0 04/23/15 20:09
Bromomethane ug/L ND 2.0 04/23/15 20:09
Carbon tetrachloride ug/L ND 2.0 04/23/15 20:09
Chlorobenzene ug/L ND 2.0 04/23/15 20:09
Chloroethane ug/L ND 2.0 04/23/15 20:09
Chloroform ug/L ND 2.0 04/23/15 20:09
Chloromethane ug/L ND 2.0 04/23/15 20:09
cis-1,3-Dichloropropene ug/L ND 2.0 04/23/15 20:09
Dibromochloromethane ug/L ND 2.0 04/23/15 20:09
Ethylbenzene ug/L ND 2.0 04/23/15 20:09
Hexachloro-1,3-butadiene ug/L ND 5.0 04/23/15 20:09
Methylene Chloride ug/L ND 2.0 04/23/15 20:09
Naphthalene ug/L ND 5.0 04/23/15 20:09
Tetrachioroethane ug/L ND 2.0 04/23/15 20:09
Toluene ug/L ND 2.0 04/23/15 20:09
trans-1,2-Dichloroethene ug/L ND 2.0 04/23/15 20:09
trans-1,3-Dichloropropene ug/L ND 2.0 04/23/15 20:09
Trichloroethene ug/L ND 2.0 04/23/15 20:09
Trichlorofluoromethane ug/L ND 2.0 04/23/15 20:09
Vinyl chloride ug/L ND 2.0 04/23/15 20:09
1,2-Dichloroethane-d4(S) % 109 70-130 04/23/15 20:09
4-Bromofluorobenzene(S) % 102 70-130 04/23/15 20:09
Toluene-d8(S) % 103 70-130 04/23/15 20:09
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 12 of 24

Pace Analytical Services,Inc.
e 9800 Klncey Ave. Suite 100
ace Analytical Huntersville,NC 28078
www.pacstabs.com [phone]
QUALITY CONTROL DATA
Project: Wastewater 4/13
Pace Project No.: 92245377
LABORATORY CONTROL SAMPLE: 1442450
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,1,1-Trichloroethane ug/L 20 20.8 104 52-162
1,1,2,2-Tetrachloroethane ug/L 20 19.1 95 46-157
1,1,2-Trichloroethane ug/L 20 20.5 103 52-150
1,1-Dichloroethane ug/L 20 21.7 109 59-155
1,1-Dichloroethene ug/L 20 19.7 98 1-234
1,2,4-Trichlorobenzene ug/L 20 25.0 125 70-130
1,2-Dichlorobenzene ug/L 20 20.9 104 18-190
1,2-Dichloroethane ug/L 20 21.2 106 49-155
1,2-Dichloropropane ug/L 20 20.5 102 1-210
1,3-Dichlorobenzene ug/L 20 20.7 103 59-156
1,4-Dichlorobenzene ug/L 20 19.7 98 18-190
2-Chloroethyivinyl ether ug/L 40 43.5 109 1-305
Acrolein ug/L 100 119 119 15-152
Acrylonitrile ug/L 100 111 111 75-132
Benzene ug/L 20 20.3 102 37-151
Bromodichioromethane ug/L 20 18.2 91 35-155
Bromoform ug/L 20 18.2 91 45-169
Bromomethane ug/L 20 34.9 175 1-242
Carbon tetrachloride ug/L 20 21.6 108 70-140
Chlorobenzene ug/L 20 19.4 97 37-160
Chloroethane ug/L 20 22.0 110 14-230
Chloroform ug/L 20 20.1 100 51-138
Chloromethane ug/L 20 22.5 112 1-273
cis-1,3-Dichloropropene ug/L 20 20.9 105 1-227
Dibromochloromethane ug/L 20 16.9 84 53-149
Ethylbenzene ug/L 20 20.3 102 37-162
Hexachloro-1,3-butadiene ug/L 20 28.1 141 70-130 J(LO)
Methylene Chloride ug/L 20 24.3 122 1-221
Naphthalene ug/L 20 27.9 140 70-130 J(LO)
Tetrachloroethene ug/L 20 18.4 92 64-148
Toluene ug/L 20 19.2 96 47-150
trans-1,2-Dichloroethene ug/L 20 22.0 110 54-156
trans-1,3-Dichloropropene ug/L 20 19.5 98 17-183
Trichloroethene ug/L 20 19.8 99 71-157
Trichlorofluoromethane ug/L 20 23.8 119 17-181
Vinyl chloride ug/L 20 22.9 114 1-251
1,2-Dichloroethane-d4(5) % 103 70-130
4-Bromofluorobenzene(S) % 102 70-130
Toluene-d8(S) % 100 70-130
MATRIX SPIKE SAMPLE: 1442452
92246425006 Spike MS MS % Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
1,1,1-Trichooroethane ug/L ND 20 24.6 123 46-171
1,1,2,2-Tetrachloroethane ug/L ND 20 19.6 98 73-159
Results presented on this page are in the units indicated by the"units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 13 of 24

Pace Analytical Services,Inc.
e 9800 KIncey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
wwwpacelabs.com [phone]
QUALITY CONTROL DATA
Project: Wastewater 4/13
Pace Project No.: 92245377
MATRIX SPIKE SAMPLE: 1442452
92246425006 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
1,1,2-Trichloroethane ug/L ND 20 20.9 104 64-152
1,1-Dichloroethane ug/L ND 20 25.2 126 43-172
1,1-Dichloroethene ug/L ND 20 24.0 120 48-189
1,2,4-Trichlorobenzene ug/L ND 20 16.9 84 70-130
1,2-Dichlorobenzene ug/L ND 20 21.6 108 54-154
1,2-Dichloroethane ug/L ND 20 22.5 112 42-171
1,2-Dichloropropane ug/L ND 20 21.7 108 55-157
1,3-Dichlorobenzene ug/L ND 20 22.9 114 57-148
1,4-Dichlorobenzene ug/L ND 20 20.6 103 58-149
2-Chloroethylvinyl ether ug/L ND 40 ND 0 70-130 J(M1)
Acrolein ug/L ND 100 76.1 75 70-130
Acrylonitrile ug/L ND 100 118 118 70-130
Benzene ug/L ND 20 22.4 112 54-163
Bromodichloromethane ug/L ND 20 20.8 104 56-152
Bromoform ug/L ND 20 19.1 95 53-151
Bromomethane ug/L ND 20 18.0 90 10-200
Carbon tetrachloride ug/L ND 20 24.9 125 41-175
Chlorobenzene ug/L ND 20 22.4 112 67-152
Chloroethane ug/L ND 20 26.1 131 23-200
Chloroform ug/L 5.2 20 27.9 114 51-166
Chloromethane ug/L ND 20 25.2 126 40-175
cis-1,3-Dichloropropene ug/L ND 20 20.6 103 38-146
Dibromochloromethane ug/L ND 20 20.2 101 65-144
Ethylbenzene ug/L ND 20 22.6 113 57-152
Hexachloro-1,3-butadiene ug/L ND 20 25.4 127 70-130
Methylene Chloride ug/L ND 20 23.0 115 40-167
Naphthalene ug/L ND 20 18.4 92 70-130
Tetrachloroethene ug/L ND 20 20.8 104 59-155
Toluene ug/L ND 20 21.8 109 47-162
trans-1,2-Dichloroethene ug/L ND 20 24.5 122 47-178
trans-1,3-Dichloropropene ug/L ND 20 20.0 100 39-148
Trichloroethene ug/L ND 20 22.7 114 60-153
Trichlorofluoromethane ug/L ND 20 27.5 138 42-199
Vinyl chloride ug/L ND 20 26.5 133 46-176
1,2-Dichloroethane-d4(S) % 94 70-130
4-Bromofluorobenzene(S) % 95 70-130
Toluene-d8(S) % 99 70-130
SAMPLE DUPLICATE: 1442451
92246425004 Dup
Parameter Units Result Result RPD Qualifiers
1,1,1-Trichloroethane ug/L ND ND
1,1,2,2-Tetrachloroethane ug/L ND ND
1,1,2-Trichloroethane ug/L ND ND
1,1-Dichloroethane ug/L ND ND
Results presented on this page are to the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 14 of 24

Pace Analytical Services,Inc.
® 9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
'Deco/eos.com [phone]
QUALITY CONTROL DATA
Project: Wastewater 4/13
Pace Project No.: 92245377
SAMPLE DUPLICATE: 1442451
92246425004 Dup
Parameter Units Result Result RPD Qualifiers
1,1-Dichloroethene ug/L ND ND
1,2,4-Trichlorobenzene ug/L ND ND
1,2-Dichlorobenzene ug/L ND ND
1,2-Dichloroethane ug/L ND ND
1,2-Dichloropropane ug/L ND ND
1,3-Dichlorobenzene ug/L ND ND
1,4-Dichlorobenzene ug/L ND ND
2-Chloroethylvinyl ether ug/L ND ND
Acrolein ug/L ND ND
Acrylonitrile ug/L ND ND
Benzene ug/L ND ND
Bromodichloromethane ug/L ND ND
Bromoform ug/L ND ND
Bromomethane ug/L ND ND
Carbon tetrachloride ug/L ND ND
Chlorobenzene ug/L ND ND
Chioroethane ug/L ND ND
Chloroform ug/L 5.1 5.2 2
Chloromethane ug/L ND ND
cis-1,3-Dichloropropene ug/L ND ND
Dibromochloromethane ug/L ND ND
Ethylbenzene ug/L ND ND
Hexachloro-1,3-butadiene ug/L ND ND
Methylene Chloride ug/L ND ND
Naphthalene ug/L ND ND
Tetrachloroethene ug/L ND ND
Toluene ug/L ND ND
trans-1,2-Dichloroethene ug/L ND ND
trans-1,3-Dichloropropene ug/L ND ND
Trichioroethene ug/L ND ND
Trichlorofluoromethane ug/L ND ND
Vinyl chloride ug/L ND ND
1,2-Dichloroethane-d4(S) % 114 106 7
4-Bromofluorobenzene(S) % 102 101 1
Toluene-d8(S) % 99 102 3
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 15 of 24

Pace Analytical Services,Inc.
s 9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
wwwpace/Bas.com [phone]
QUALITY CONTROL DATA
Project: Wastewater 4/13
Pace Project No.: 92245377
QC Batch: WET/36903 Analysis Method: SM 2540C
QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 92245377001
METHOD BLANK: 1437166 Matrix: Water
Associated Lab Samples: 92245377001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 04/17/15 11:14
LABORATORY CONTROL SAMPLE: 1437167
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 238 95 90-110
SAMPLE DUPLICATE: 1437168
92245377001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 214 199 7 J(D6)
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 16 of 24

Pace Analytical Services,Inc.
m 9800 Kincey Ave. Suite 100
ace Analytical Nuntersville,NC 28078
r/ wwpecelebe.coin [phone]
QUALITY CONTROL DATA
Project: Wastewater 4/13
Pace Project No.: 92245377
QC Batch: WETA/22585 Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92245377001
METHOD BLANK: 1436025 Matrix: Water
Associated Lab Samples: 92245377001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Ammonia mg/L ND 0.10 04/17/15 02:55
LABORATORY CONTROL SAMPLE: 1436026
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 4.9 97 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1436027 1436028
MS MSD
92245377001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L 2.1 5 5 7.1 7.2 100 102 90-110 2
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1436571 1436572
MS MSD
92245629001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L 20.5 5 5 25.3 25.5 96 100 90-110 1
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 17 of 24

Pace Analytical Services,Inc.
9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
w»wpaceleLa horn [phone]
QUALITY CONTROL DATA
Project: Wastewater 4/13
Pace Project No.: 92245377
QC Batch: WETA/22652 Analysis Method: EPA 351.2
QC Batch Method: EPA 351.2 Analysis Description: 351.2 TKN
Associated Lab Samples: 92245377001
METHOD BLANK: 1440691 Matrix: Water
Associated Lab Samples: 92245377001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Kjeldahl,Total mg/L ND 0.50 04/24/15 11:03
LABORATORY CONTROL SAMPLE: 1440692
Spike LCS LCS %Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen,Kjeldahl,Total mg/L 10 10.1 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1440693 1440694
MS MSD
92245851001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Kjeldahl,Total mg/L 2.0 10 10 12.2 12.3 102 104 90-110 1
Results presented on this page are in the units indicated by the"units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 18 of 24

Pace Analytical Services,Inc.
0 9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
www.pace/abs.oam [phone]
QUALITY CONTROL DATA
Project: Wastewater 4/13
Pace Project No.: 92245377
QC Batch: WETA/22632 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate+Nitrite,preserved
Associated Lab Samples: 92245377001
METHOD BLANK: 1438957 Matrix: Water
Associated Lab Samples: 92245377001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,NO2 plus NO3 mg/L ND 0.020 04/21/15 05:08
LABORATORY CONTROL SAMPLE: 1438958
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,NO2 plus NO3 mg/L 2.5 2.5 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1438959 1438960
MS MSD
92245012012 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,NO2 plus NO3 mg/L ND 2.5 2.5 2.4 2.4 97 97 75-125 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1439085 1439086
MS MSD
92245590003 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,NO2 plus NO3 mg/L 0.070 2.5 2.5 2.5 2.5 96 95 75-125 0
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 19 of 24

Pace Analytical Services,Inc.
® 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pace/abs.con, [phone]
QUALITY CONTROL DATA
Project: Wastewater 4/13
Pace Project No.: 92245377
QC Batch: WETA/22653 Analysis Method: EPA 365.1
QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus,Total
Associated Lab Samples: 92245377001
METHOD BLANK: 1440700 Matrix: Water
Associated Lab Samples: 92245377001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 04/23/15 03:23
LABORATORY CONTROL SAMPLE: 1440701
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.7 108 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1440702 1440703
MS MSD
92245610002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus mg/L 0.14 2.5 2.5 2.7 2.7 104 104 90-110 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1440704 1440705
MS MSD
92245381002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus mg/L 0.50 2.5 2.5 3.0 3.0 100 99 90-110 1
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 20 of 24

Pace Analytical Services,Inc.
e 9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
www.pacelabs.rom [phone]
1
QUALITY CONTROL DATA
Project: Wastewater 4/13
Pace Project No.: 92245377
QC Batch: WETA/22639 Analysis Method: EPA 420.4
QC Batch Method: EPA 420.4 Analysis Description: 420.4 Phenolics
Associated Lab Samples: 92245377001
METHOD BLANK: 1439598 Matrix: Water
Associated Lab Samples: 92245377001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phenol mg/L ND 0.010 04/21/15 16:44
LABORATORY CONTROL SAMPLE: 1439599
Spike LCS LCS % Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phenol mg/L .05 0.048 97 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1439600 1439601
MS MSD
92245411001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phenol mg/L 0.014 .05 .05 0.16 0.16 286 283 90-110 1 J(M1)
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1439602 1439603
MS MSD
92245411002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phenol mg/L 0.017 .05 .05 0.054 0.051 74 68 90-110 6 J(M1)
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 21 of 24

Pace Analytical Services,Inc.
w 9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
1 www.pacelebc.corn [phone]
QUALITY CONTROL DATA
Project: Wastewater 4/13
Pace Project No.: 92245377
QC Batch: WETA/22646 Analysis Method: SM 4500-CN-E
QC Batch Method: SM 4500-CN-E Analysis Description: 4500CNE Cyanide,Total
Associated Lab Samples: 92245377001
METHOD BLANK: 1440419 Matrix: Water
Associated Lab Samples: 92245377001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Cyanide mg/L ND 0.0080 04/23/15 12:09
LABORATORY CONTROL SAMPLE: 1440420
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Cyanide mg/L .1 0.11 110 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1440421 1440422
MS MSD
92245583001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Cyanide mg/L ND .1 .1 0.12 0.11 114 110 75-125 4
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1440423 1440424
MS MSD
92245430002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Cyanide mg/L ND .1 .1 0.10 0.097 97 95 75-125 3
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 22 of 24

Pace Analytical Services,Inc.
• 9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
www pacelabs.com [phone]
QUALIFIERS
Project: Wastewater 4/13
Pace Project No.: 92245377
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitatiori Limit.
RL-Reporting Limit.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether,Styrene,and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services-Asheville
PASI-C Pace Analytical Services-Charlotte
ANALYTE QUALIFIERS
1g Reanalysis conducted in excess of EPA method holding time. Results for this sample confirm original analysis performed
in hold time.
J(D6) Estimated Value.The relative percent difference(RPD)between the sample and sample duplicate exceeded laboratory
control limits.
J(LO) Estimated Value.Analyte recovery in the laboratory control sample(LCS)was outside QC limits.
J(M1) Estimated Value.Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)
recovery.
L3 Analyte recovery in the laboratory control sample(LCS)exceeded QC limits.Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 23 of 24

Pace Analytical Services,Inc.
• 9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
/ www.paceleba.com [phone]
I
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Wastewater 4/13
Pace Project No.: 92245377
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92245377001 WASTE WATER EFFLUENT EPA 1664B GCSV/21028
92245377001 WASTE WATER EFFLUENT EPA 200.7 MPRP/18290 EPA 200.7 ICP/16422
92245377001 WASTE WATER EFFLUENT EPA 1631E MERP/7765 EPA 1631E MERC/7450
92245377002 WASTEWATER EFF LLHG FIELD EPA 1631E MERP/7765 EPA 1631E MERC/7450
BLK
92245377001 WASTE WATER EFFLUENT EPA 625 OEXT/34426 EPA 625 MSSV/10569
92245377001 WASTE WATER EFFLUENT EPA 624 MSV/31356
92245377001 WASTE WATER EFFLUENT SM 2540C WET/36903
92245377001 WASTE WATER EFFLUENT EPA 350.1 WETA/22585
92245377001 WASTE WATER EFFLUENT EPA 351.2 WETA/22652
92245377001 WASTE WATER EFFLUENT EPA 353.2 WETA/22632
92245377001 WASTE WATER EFFLUENT EPA 365.1 WETA/22653
1 92245377001 WASTE WATER EFFLUENT EPA 420.4 WETA/22639
1 92245377001 WASTE WATER EFFLUENT SM 4500-CN-E WETA/22646
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2015 09:25 AM without the written consent of Pace Analytical Services,Inc.. Page 24 of 24

0 CHAIN-OF-CUSTODY/Analytical Request Document
PaeeAnalytieal° The Chain-of-Custody is a LEGAL DOCUMENT.All relevant fields must be completed accurately
www.pacelabs.com
LC6 O'r Page of
Section A Section B Section C
Required Client Information. Required Project Information: Invoice Information: 8 2 3
Company:— �� Report To: Attention: l ! C(.`3
/o,,,.J•t .4- Iory ,-� Ynlc he eel AI/P�1 Y►'1/''haei , // n
Address: 7.L 0.,:,i ,2c Copy To: Company Name /'r
/Lir.•4 bill /4,&,'o REGULATORY AGENCY
Address:
/Q rtvb-J /k/e g7�i{o 1O, /�j6.j . a26 ,q j:,ivc : NPDES GROUND WATER r DRINKING WATER
Smart To: Purchase Order No Pace Quote
/YjGIlt7 c✓ cb„„� Y1C'.C6,7 Reference: 73�(c UST RCRA OTHER
Pione'. F Project Name: ?ace Project
Z)6y/-elecl 212)G,S// 3t:. Manager: Site Location
Requested Due Date/TAT: Project Number: °ace Profile rr STATE:
Requested Analysis Filtered(YIN)
r
Section D Matrix Codes — T Z
RequiredClient Information MATRIX/CODE = 0
0 o COLLECTED Preservatives >
Ddnkirg Water DW . 0 7
Water WT 8 U o ? R .S C k /
Waste Water WW COMPOSITE COMPOSITE
Product P - co START ENDI al START
alrTq 1 5
Soil/Solid SL 0 0 ,y a t- 4.- 4
SAMPLE ID oil of 0 U
(A-Z.0-9/,-) Airpe AR ut H Lu w N c
Z N
to
Sample IDs MUST BE UNIQUE Tissue TS 0 a 2 < m N L
Other OT U Z 2 "y U
u x w O o O °c m
U y 7
Q O Ono L r Q a
W 2 co Q DATE TIME yDATE TIME Q ae D S S I ZZ Z O y ct Pace Project No./Lab I.D.
1 LtJ41�e iskiler �de; / G h 3-1 i.a:,S7,1 1 .
2 C-
3
4
5
6
7
8
9
10
11
12
ADDITIONAL COMMENTS RELINQUISHED Y I AFFILIATION DATE TIME ACCEPTED BY/AFFILIATION DATE TIME SAMPLE CONDITIONS
Cc 0-) Lev,-//Areur;l 1/-/q/-/5 f a�1,L 0:67.,.../47(1--- (2- -7' 4.0444(fic-4,- giegl°tSit -z f� I � S {r
/ 1
SAMPLER NAME AND SIGNATURE `o^ o
ORIGINAL U a
PRINT Name of SAMPLER: I m? o U z Z
t-i'1rc tie/ //A/�,�l�l/e:t a a; ;
SIGNATURE of SAMPLER:2.jy1�. �4LL!/L-L�-r"% _ ((MMIDDIYY)r? DATE a 4•iW —r j� r- U N v m
�/� rn
'Impor By signing this form you are accepting Pace's NET 30 day payment terms and agreeing to late charges of 1 5%per month for .:;es nor paid within 30 days F-ALL-Q-020rev 07,15 )07

Pace Analytical Services,Inc.
• ' aceAnalytical 9800 Kinsey Ave Suite 100
www.paceabs.com Huntersville,NC 28078
[phone]
August 03, 2016
Mr. Mike Allen
Town of Tarboro
506 Dowd Street
PO Box 220
Tarboro, NC 27886
RE: Project: PPA Wastewater 7/19
Pace Project No.: 92305645
Dear Mr.Allen:
Enclosed are the analytical results for sample(s) received by the laboratory on July 19, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN! standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report_
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
lorri.patton©pacelabs.com
Project Manager
Enclosures
P p.
-..�"' REPORT OF LABORATORY ANALYSIS
_///ram..r•
This report shall not be reproduced,except in full,
• without the written consent of Pace Analytical Services,Inc..
_ Page 1 of 32

Pace Analytical Services,Inc.
aceAnalytical ceAnalytical®
9800 Kincey Ave Suite 100
wwwpecelebs.corn
Huntersville,NC 28078
[phone]
CERTIFICATIONS
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
Charlotte Certification IDs
9800 Kincey Ave.Ste 100,Huntersville,NC 28078 South Carolina Certification#:99006001
North Carolina Drinking Water Certification#:37706 Florida/NELAP Certification#:E87627
North Carolina Field Services Certification#:5342 Kentucky UST Certification#:84
North Carolina Wastewater Certification#:12 VirginiaNELAP Certification#:460221
Asheville Certification IDs
2225 Riverside Drive,Asheville,NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
Massachusetts Certification#:M-NC030 VirginiaNELAP Certification#:460222
North Carolina Drinking Water Certification#:37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc.. Page 2 of 32

Pace Analytical Services,Inc.
aceAnalytical 9800 Kinsey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com [phone]
SAMPLE ANALYTE COUNT
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
Analysts
Lab ID Sample ID Method Analysts Reported Laboratory
92305645001 WASTEWATER EFFLUENT EPA 1664B JMS 1 PASI-C
EPA 200.7 JMW 15 PASI-A
EPA 1631E SER 1 PASI-A
EPA 625 BPJ 59 PASI-C
EPA 624 GAW 39 PASI-C
SM 2540C ALC 1 PASI-A
TKN+NO3+NO2 Calculation EWS 1 PASI-A
EPA 350.1 AES2 1 PASI-A
EPA 351.2 BRJ 1 PASI-A
EPA 353.2 DMN 1 PASI-A
EPA 365.1 WRC 1 PASI-A
EPA 420.4 DMN 1 PASI-A
SM 4500-CN-E AES2 1 PASI-A
92305645002 WW EFF LLHG BLK EPA 1631E SER 1 PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc.. Page 3 of 32

Pace Analytical Services,Inc.
7. Kincey Ave Suite 100
aceAnalytical 9800 Huntersville,NC 28078
I wwwpacelabs corn
[phone]
ANALYTICAL RESULTS
Project: PPA
Wastewater 7/19
Pace Project No.: 92305645
Sample: WASTEWATER EFFLUENT Lab ID: 92305645001 Collected: 07/19/16 11:30 Received: 07/19/16 14:40 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM,Oil and Grease Analytical Method:EPA 16648
Oil and Grease ND mg/L 5.0 1 07/26/16 08:34
200.7 MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA 200.7
Antimony ND ug/L 5.0 1 07/22/16 17:55 07/23/16 18:19 7440-36-0
Arsenic ND ug/L 10.0 1 07/22/16 17:55 07/23/16 18:19 7440-38-2
Beryllium ND ug/L 1.0 1 07/22/16 17:55 07/23/16 18:19 7440-41-7
Cadmium ND ug/L 1.0 1 07/22/16 17:55 07/23/16 18:19 7440-43-9
Calcium 8460 ug/L 100 1 07/22/16 17:55 07/23/16 18:19 7440-70-2
Chromium ND ug/L 5.0 1 07/22/16 17:55 07/23/16 18:19 7440-47-3
Copper ND ug/L 5.0 1 07/22/16 17:55 07/23/16 18:19 7440-50-8
Lead ND ug/L 5.0 1 07/22/1617:55 07/23/16 18:19 7439-92-1
Magnesium 1660 ug/L 100 1 07/22/16 17:55 07/23/16 18:19 7439-95-4
Nickel ND ug/L 5.0 1 07/22/16 17:55 07/23/16 18:19 7440-02-0
Selenium ND ug/L 10.0 1 07/22/16 17:55 07/23/16 18:19 7782-49-2
Silver ND ug/L 5.0 1 07/22/1617:55 07/23/16 18:19 7440-22-4
Thallium ND ug/L 10.0 1 07/22/16 17:55 07/23/16 18:19 7440-28-0
Hardness,Total(SM 2340B) 28000 ug/L 662 1 07/22/16 17:55 07/23/16 18:19
Zinc ND ug/L 10.0 1 07/22/16 17:55 07/23/16 18:19 7440-66-6
1631E Mercury,Low Level Analytical Method:EPA 1631E Preparation Method:EPA 1631E
Mercury 1.17 ng/L 0.50 1 07/22/16 02:38 07/22/16 06:26 7439-97-6
625 MSSV Analytical Method:EPA 625 Preparation Method:EPA 625
Acenaphthene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 83-32-9
Acenaphthylene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 208-96-8
Anthracene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 120-12-7
Benzo(a)anthracene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 56-55-3
Benzo(a)pyrene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 50-32-8
Benzo(b)fluoranthene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 205-99-2
Benzo(g,h,i)perylene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 191-24-2
Benzo(k)fluoranthene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 207-08-9
4-Bromophenylphenyl ether ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 101-55-3
Butylbenzylphthalate ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 85-68-7
4-Chloro-3-methylphenol ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 59-50-7
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 07/21/16 14:00 07/22/16 15:17 111-91-1
bis(2-Chloroethyl)ether ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 111-44-4
2-Chloronaphthalene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 91-58-7
2-Chlorophenol ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 95-57-8
4-Chlorophenylphenyl ether ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 7005-72-3
Chrysene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 218-01-9
Dibenz(a,h)anthracene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 53-70-3
1,2-Dichlorobenzene ND ug/L 5.0 1 07/21/16 14:00 07/22N615:17 95-50-1
1,3-Dichlorobenzene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 541-73-1
1,4-Dichlorobenzene ND ug/L 5.0 1 07/21/16 14:00 07/22/1615:17 106-46-7
3,3'-Dichlorobenzidine ND ug/L 25.0 1 07/21/16 14:00 07/22/16 15:17 91-94-1
2,4-Dichlorophenol ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 120-83-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 4 of 32

Pace Analytical Services,Inc.
® 9800 Kincey Ave Suite 100
//7aceAnalytical Huntersville,NC 28078
/ www.pacelabs.rom
I [phone]
ANALYTICAL RESULTS
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
Sample: WASTEWATER EFFLUENT Lab ID: 92305645001 Collected: 07/19/16 11:30 Received: 07/19/16 14:40 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
625 MSSV Analytical Method:EPA 625 Preparation Method:EPA 625
Diethylphthalate ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 07/21/16 14:00 07/22/16 15:17 105-67-9
Dimethylphthalate ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 131-11-3
Di-n-butylphthalate ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 07/21/16 14:00 07/22/16 15:17 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 07/21/16 14:00 07/22/16 15:17 51-28-5
2,4-Dinitrotoluene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 121-14-2
2,6-Dinitrotoluene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 606-20-2
Di-n-octytphthalate ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 117-84-0
1,2-Diphenylhydrazine ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 122-66-7
bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 117-81-7
Fluoranthene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 206-44-0
Fluorene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 86-73-7
Hexachlorobenzene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 118-74-1
Hexachlorocydopentadiene ND ug/L 10.0 1 07/21/16 14:00 07/22/16 15:17 77-47-4
Hexachloroethane ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 193-39-5
Isophorone ND ug/L 10.0 1 07/21/16 14:00 07/22/16 15:17 78-59-1
Naphthalene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 91-20-3
Nitrobenzene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 98-95-3
2-Nitrophenol ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 88-75-5
4-Nitrophenol ND ug/L 50.0 1 07/21/16 14:00 07/22/16 15:17 100-02-7
N-Nitrosodimethylamine ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1 07/21/16 14:00 07/22/16 15:17 86-30-6
Pentachlorophenol ND ug/L 10.0 1 07/21/16 14:00 07/22/16 15:17 87-86-5
Phenanthrene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 85-01-8
Phenol ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17
Pyrene ND ug/L 5.0 1 07/21/16 14:00 07/22/16 15:17 129-00-0
2,4,6-Trichlorophenol ND ug/L 10.0 1 07/21/16 14:00 07/22/16 15:17 88-06-2
Surrogates
Nitrobenzene-d5(S) 74 % 10-120 1 07/21/16 14:00 07/22/16 15:17 4165-60-0
2-Fluorobiphenyl(S) 78 % 15-120 1 07/21/16 14:00 07/22/16 15:17 321-60-8
Terphenyl-d14(S) 100 % 11-131 1 07/21/16 14:00 07/22/16 15:17 1718-51-0
Phenol-d6(S) 33 % 10-120 1 07/21/16 14:00 07/22/16 15:17 13127-88-3
2-Fluorophenol(S) 45 % 10-120 1 07/21/16 14:00 07/22/16 15:17 367-12-4
2,4,6-Tribromophenol(S) 77 % 10-137 1 07/21/16 14:00 07/22/16 15:17 118-79-6
624 Volatile Organics Analytical Method:EPA 624
Acrolein ND ug/L 5.0 1 07/25/16 14:32 107-02-8 J(M1)
Acrylonitrile ND ug/L 50.0 1 07/25/16 14:32 107-13-1
Benzene ND ug/L 2.0 1 07/25/16 14:32 71-43-2
Bromodichloromethane ND ug/L 2.0 1 07/25/16 14:32 75-27-4
Bromoform ND ug/L 2.0 1 07/25/16 14:32 75-25-2
Bromomethane ND ug/L 2.0 1 07/25/16 14:32 74-83-9
Carbon tetrachloride ND ug/L 2.0 1 07/25/16 14:32 56-23-5
Chlorobenzene ND ug/L 2.0 1 07/25/16 14:32 108-90-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Anal
ytical Services,Inc.. Page 5 of 32

Pace Analytical Services,Inc.
a 9800 Kincey Ave Suite 100
aceAnalytical Huntersville,NC 28078
wwwpacelabs.com [phone]
ANALYTICAL RESULTS
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
Sample: WASTEWATER EFFLUENT Lab ID: 92305645001 Collected: 07/19/16 11:30 Received: 07/19/16 14:40 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
624 Volatile Organics Analytical Method:EPA 624
Chioroethane ND ug/L 2.0 1 07/25/16 14:32 75-00-3
2-Chloroethylvinyl ether ND ug/L 5.0 1 07/25/16 14:32 110-75-8 J(M1),c2
Chloroform ND ug/L 2.0 1 07/25/16 14:32 67-66-3
Chloromethane ND ug/L 2.0 1 07/25/16 14:32 74-87-3
Dibromochloromethane ND ug/L 2.0 1 07/25/16 14:32 124-48-1
1,2-Dichlorobenzene ND ug/L 2.0 1 07/25/16 14:32 95-50-1
1,3-Dichlorobenzene ND ug/L 2.0 1 07/25/16 14:32 541-73-1
1,4-Dichiorobenzene ND ug/L 2.0 1 07/25/16 14:32 106-46-7
1,1-Dichioroethane ND ug/L 2.0 1 07/25/16 14:32 75-34-3
1,2-Dichloroethane ND ug/L 2.0 1 07/25/16 14:32 107-06-2
1,1-Dichloroethene ND ug/L 2.0 1 07/25/16 14:32 75-35-4
trans-1,2-Dichloroethene ND ug/L 2.0 1 07/25/16 14:32 156-60-5
1,2-Dichioropropane ND ug/L 2.0 1 07/25/16 14:32 78-87-5
cis-1,3-Dichloropropene ND ug/L 2.0 1 07/25/16 14:32 10061-01-5
trans-1,3-Dichloropropene ND ug/L 2.0 1 07/25/16 14:32 10061-02-6
Ethylbenzene ND ug/L 2.0 1 07/25/16 14:32 100-41-4
Hexachloro-1,3-butadiene ND ug/L 5.0 1 07/25/16 14:32 87-68-3
Methylene Chloride ND ug/L 2.0 1 07/25/16 14:32 75-09-2
Naphthalene ND ug/L 5.0 1 07/25/16 14:32 91-20-3
1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 07/25/16 14:32 79-34-5
Tetrachloroethene ND ug/L 2.0 1 07/25/16 14:32 127-18-4
Toluene ND ug/L 2.0 1 07/25/16 14:32 108-88-3
1,2,4-Trichlorobenzene ND ug/L 2.0 1 07/25/16 14:32 120-82-1
1,1,1-Trichloroethane ND ug/L 2.0 1 07/25/16 14:32 71-55-6
1,1,2-Trichloroethane ND ug/L 2.0 1 07/25/16 14:32 79-00-5
Trichloroethene ND ug/L 2.0 1 07/25/16 14:32 79-01-6
Trichlorofluoromethane ND ug/L 2.0 1 07/25/16 14:32 75-69-4
Vinyl chloride ND ug/L 2.0 1 07/25/16 14:32 75-01-4
Surrogates
4-Bromofluorobenzene(S) 101 % 70-130 1 07/25/16 14:32 460-00-4
Toluene-d8(S) 102 % 70-130 1 07/25/16 14:32 2037-26-5
1,2-Dichloroethane-d4(S) 95 % 70-130 1 07/25/16 14:32 17060-07-0
2540C Total Dissolved Solids Analytical Method:SM 2540C
Total Dissolved Solids 68.0 mg/L 25.0 1 07/21/16 09:33 J(L1)
Total Nitrogen Calculation Analytical Method:TKN+NO3+NO2 Calculation
Total Nitrogen 4.4 mg/L 0.12 1 07/29/16 09:53
350.1 Ammonia Analytical Method:EPA 350.1
Nitrogen,Ammonia ND mg/L 0.10 1 07/26/16 15:01 7664-41-7
351.2 Total Kjeldahl Nitrogen Analytical Method:EPA 351.2
Nitrogen,Kjeldahl,Total 0.50 mg/L 0.50 1 07/27/16 05:27 7727-37-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 6 of 32

Pace Analytical Services,Inc.
aceAnalytical 9800Huntersv Ile,Ave.:::
wwwpacelabs.com
[phone]
ANALYTICAL RESULTS
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
Sample: WASTEWATER EFFLUENT Lab ID: 92305645001 Collected: 07/19/16 11:30 Received: 07/19/16 14:40 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
353.2 Nitrogen,NO2/NO3 pros. Analytical Method:EPA 353.2
Nitrogen,NO2 plus NO3 3.9 mg/L 0.080 4 07/26/16 15:58
365.1 Phosphorus,Total Analytical Method:EPA 365.1
Phosphorus 0.14 mg/L 0.050 1 07/28/16 22:08 7723-14-0
420.4 Phenolics,Total Analytical Method:EPA 420.4
Phenol 0.023 mg/L 0.010 1 07/25/16 14:50
4500CNE Cyanide,Total Analytical Method:SM 4500-CN-E
Cyanide ND mg/L 0.0080 1 07/27/16 18:09 57-12-5
Sample: WW EFF LLHG BLK Lab ID: 92305645002 Collected: 07/19/16 11:30 Received: 07/19/16 14:40 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method:EPA 1631E Preparation Method:EPA 1631E
Mercury ND ng/L 0.50 1 07/22/16 02:38 07/22/16 06:49 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services.Inc.. Page 7 of 32

Pace Analytical Services,Inc.
acer1 /
Al laf l lt//�aI I) 9800 Kincey Ave. Suite 100
xnvw.pace/ebs.com Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
QC Batch: 322537 Analysis Method: EPA 16648
QC Batch Method: EPA 1664E Analysis Description: 1664 HEM,Oil and Grease
Associated Lab Samples: 92305645001
METHOD BLANK: 1786979 Matrix: Water
Associated Lab Samples: 92305645001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 5.0 07/26/16 08:32
LABORATORY CONTROL SAMPLE: 1786980
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L 40 37.0 93 78-114
MATRIX SPIKE SAMPLE: 1786981
92306226001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L ND 40 34.3 86 78-114
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 8 of 32

ac Pace Analytical Services,Inc.
x 9800Hunte sv Ile,NC Suite
28078
eAnalytical
wwwpacelabs.com [phone]
ti
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
QC Batch: 322147 Analysis Method: EPA 1631E
QC Batch Method: EPA 1631E Analysis Description: 1631E Mercury,Low Level
Associated Lab Samples: 92305645001,92305645002
METHOD BLANK: 1785345 Matrix: Water
Associated Lab Samples: 92305645001,92305645002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 07/22/16 03:05
METHOD BLANK: 1785346 Matrix: Water
Associated Lab Samples: 92305645001,92305645002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 07/22/16 05:17
METHOD BLANK: 1785347 Matrix: Water
Associated Lab Samples: 92305645001,92305645002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 07/22/16 07:04
LABORATORY CONTROL SAMPLE: 1785348
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Mercury ng/L 5 4.72 94 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1785349 1785350
MS MSD
92305651001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc- Conc. Result Result %Rec %Rec Limits RPD Qual
Mercury ng/L 0.925 25 25 25.2 25.2 97 97 71-125 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1785351 1785352
MS MSD
92305645001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Mercury ng/L 1.17 25 25 25.7 25.3 98 97 71-125 2
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 9 of 32

Pace Analytical Services,Inc.
s 9800 Kincey Ave Suite 100
aceAnalytical Huntersville,NC 28078
www.pecelabscom
( {704)8759092
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
QC Batch: 322119 Analysis Method: EPA 200.7
QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET
Associated Lab Samples: 92305645001
METHOD BLANK: 1785284 Matrix: Water
Associated Lab Samples: 92305645001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Antimony ug/L ND 5.0 07/23/16 17:02
Arsenic ug/L ND 10.0 07/23/16 17:02
Beryllium ug/L ND 1.0 07/23/16 17:02
Cadmium ug/L ND 1.0 07/23/16 17:02
Calcium ug/L ND 100 07/26/16 10:51
Chromium ug/L ND 5.0 07/23/16 17:02
Copper ug/L ND 5.0 07/23/16 17:02
Hardness,Total(SM 2340B) ug/L ND 662 07/26/16 10:51
Lead ug/L ND 5.0 07/23/16 17:02
Magnesium ug/L ND 100 07/23/16 17:02
Nickel ug/L ND 5.0 07/23/16 17:02
Selenium ug/L ND 10.0 07/23/16 17:02
Silver ug/L ND 5.0 07/23/16 17:02
Thallium ug/L ND 10.0 07/23/16 17:02
Zinc ug/L ND 10.0 07/23/16 17:02
LABORATORY CONTROL SAMPLE: 1785285
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Antimony ug/L 500 517 103 85-115
Arsenic ug/L 500 504 101 85-115
Beryllium ug/L 500 529 106 85-115
Cadmium ug/L 500 521 104 85-115
Calcium ug/L 5000 5540 111 85-115
Chromium ug/L 500 513 103 85-115
Copper ug/L 500 535 107 85-115
Hardness,Total(SM 2340B) ug/L 35100
Lead ug/L 500 510 102 85-115
Magnesium ug/L 5000 5170 103 85-115
Nickel ug/L 500 518 104 85-115
Selenium ug/L 500 517 103 85-115
Silver ug/L 250 256 102 85-115
Thallium ug/L 500 528 106 85-115
Zinc ug/L 500 506 101 85-115
Results presented on this page era In the units Indicated by the"Units"column except where an alternate unit is presented to the right cattle result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 10 of 32

Pace Analytical Services,Inc.
9800 Kincey Ave Suite 100
/111v
aceAnalytical Huntersvitle,NC 28078
( www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1785286 1785287
MS MSD
92305612001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Antimony ug/L ND 500 500 511 512 102 102 70-130 0
Arsenic ug/L ND 500 500 510 508 102 101 70-130 0
Beryllium ug/L ND 500 500 535 536 107 107 70-130 0
Cadmium ug/L ND 500 500 519 520 104 104 70-130 0
Calcium ug/L 880 5000 5000 6110 6150 105 105 70-130 1
Chromium ug/L ND 500 500 512 517 102 103 70-130 1
Copper ug/L ND 500 500 535 533 107 106 70-130 0
Hardness,Total(SM 2340B) ug/L 2200 36200 36500 1
Lead ug/L ND 500 500 494 494 99 99 70-130 0
Magnesium ug/L ND 5000 5000 5070 5140 101 102 70-130 1
Nickel ug/L ND 500 500 507 508 101 102 70-130 0
Selenium ug/L ND 500 500 515 519 103 104 70-130 1
Silver ug/L ND 250 250 254 254 101 102 70-130 0 I
Thallium ug/L ND 500 500 503 493 100 98 70-130 2
Zinc ug/L ND 500 500 501 506 100 101 70-130 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1785288 1785289
MS MSD
92305584001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Antimony ug/L ND 500 500 501 503 100 101 70-130 0
Arsenic ug/L ND 500 500 494 497 99 99 70-130 1
Beryllium ug/L ND 500 500 530 530 106 106 70-130 0
Cadmium ug/L ND 500 500 506 508 101 102 70-130 0
Calcium ug/L 17.3 5000 5000 22200 22500 98 104 70-130 1
mg/L
Chromium ug/L ND 500 500 510 510 102 102 70-130 0
Copper ug/L 0.0027 I 500 500 525 526 105 105 70-130 0
mg/L
Hardness,Total(SM 2340B) ug/L 60.5 93100 94300 1
mg/L
Lead ug/L ND 500 500 481 483 96 97 70-130 0
Magnesium ug/L 4.2 5000 5000 9160 9280 99 102 70-130 1
mg/L
Nickel ug/L ND 500 500 499 500 99 100 70-130 0
Selenium ug/L ND 500 500 499 500 100 100 70-130 0
Silver ug/L ND 250 250 250 250 100 100 70-130 0
Thallium ug/L ND 500 500 492 494 98 99 70-130 0
Zinc ug/L 0.010 500 500 502 503 98 99 70-130 0
mg/L
Results presented on this page are In the units Indicated by the"Units"column except*here an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc. Page 11 of 32

Pace Analytical Services,Inc.
s 9800 Kincey Ave Suite 100
aceAnalytical Hunters ville,NC 28078
www.pacelabs.com
[phone]
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
QC Batch: 322396 Analysis Method: EPA 624
QC Batch Method: EPA 624 Analysis Description: 624 MSV
Associated Lab Samples: 92305645001
METHOD BLANK: 1786421 Matrix: Water
Associated Lab Samples: 92305645001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1,1-Trichloroethane ug/L ND 2.0 07/25/16 11:42
1,1,2,2-Tetrachloroethane ug/L ND 2.0 07/25/16 11:42
1,1,2-Trichloroethane ug/L ND 2.0 07/25/16 11:42
1,1-Dichloroethane ug/L ND 2.0 07/25/16 11:42
1,1-Dichloroethene ug/L ND 2.0 07/25/16 11:42
1,2,4-Trichlorobenzene ug/L ND 2.0 07/25/16 11:42
1,2-Dichlorobenzene ug/L ND 2.0 07/25/16 11:42
1,2-Dichloroethane ug/L ND 2.0 07/25/16 11:42
1,2-Dichloropropane ug/L ND 2.0 07/25/16 11:42
1,3-Dichlorobenzene ug/L ND 2.0 07/25/16 11:42
1,4-Dichlorobenzene ug/L ND 2.0 07/25/16 11:42
2-Chloroethylvinyl ether ug/L ND 5.0 07/25/16 11:42
Acrolein ug/L ND 5.0 07/25/16 11:42
Acrylonitrile ug/L ND 50.0 07/25/16 11:42
Benzene ug/L ND 2.0 07/25/16 11:42
Bromodichloromethane ug/L ND 2.0 07/25/16 11:42
Bromoforrn ug/L ND 2.0 07/25/16 11:42
Bromomethane ug/L ND 2.0 07/25/16 11:42
Carbon tetrachloride ug/L ND 2.0 07/25/16 11:42
Chlorobenzene ug/L ND 2.0 07/25/16 11:42
Chloroethane ug/L ND 2.0 07/25/16 11:42
Chloroform ug/L ND 2.0 07/25/16 11:42
Chloromethane ug/L ND 2.0 07/25/16 11:42
cis-1,3-Dichloropropene ug/L ND 2.0 07/25/16 11:42
Dibromochioromethane ug/L ND 2.0 07/25/16 11:42
Ethylbenzene ug/L ND 2.0 07/25/16 11:42
Hexachloro-1,3-butadiene ug/L ND 5.0 07/25/16 11:42
Methylene Chloride ug/L ND 2.0 07/25/16 11:42
Naphthalene ug/L ND 5.0 07/25/16 11:42
Tetrachloroethene ug/L ND 2.0 07/25/16 11:42
Toluene ug/L ND 2.0 07/25/16 11:42
trans-1,2-Dichloroethene ug/L ND 2.0 07/25/16 11:42
trans-1,3-Dichloropropene ug/L ND 2.0 07/25/16 11:42
Trichloroethene ug/L ND 2.0 07/25/16 11:42
Trichlorofluoromethane ug/L ND 2.0 07/25/16 11:42
Vinyl chloride ug/L ND 2.0 07/25/16 11:42
1,2-Dichloroethane-d4(S) % 93 70-130 07/25/16 11:42
4-Bromofluorobenzene(S) % 99 70-130 07/25/16 11:42
Toluene-d8(S) % 104 70-130 07/25/16 11:42
Results presented on this page are in the units Indicated by the"Units'column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 12 of 32

Pace Analytical Services,Inc.
a 9800 Klncey ,Ave :::ceAnalytical Huntersville,NC 28078
I wwwpacelabs.com [phone]
I
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
LABORATORY CONTROL SAMPLE: 1786422
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,1,1-Trichloroethane ug/L 50 44.3 89 52-162
1,1,2,2-Tetrachloroethane ug/L 50 46.5 93 46-157
1,1,2-Trichloroethane ug/L 50 46.7 93 52-150
1,1-Dichloroethane ug/L 50 43.3 87 59-155
1,1-Dichloroethene ug/L 50 43.2 86 1-234
1,2,4-Trichlorobenzene ug/L 50 50.0 100 70-130
1,2-Dichlorobenzene ug/L 50 47.9 96 18-190
1,2-Dichloroethane ug/L 50 41.5 83 49-155
1,2-Dichloropropane ug/L 50 45.8 92 1-210
1,3-Dichlorobenzene ug/L 50 49.5 99 59-156
1,4-Dichlorobenzene ug/L 50 49.2 98 18-190
2-Chloroethylvinyl ether ug/L 100 101 101 1-305
Acrolein ug/L 250 276 110 15-152
Acrylonitrile ug/L 250 227 91 75-132
Benzene ug/L 50 47.0 94 37-151
Bromodichloromethane ug/L 50 45.0 90 35-155
Bromoform ug/L 50 52.1 104 45-169
Bromomethane ug/L 50 48.9 98 1-242
Carbon tetrachloride ug/L 50 45.9 92 70-140
Chlorobenzene ug/L 50 49.4 99 37-160
Chloroethane ug/L 50 36.4 73 14-230
Chloroform ug/L 50 42.7 85 51-138
Chloromethane ug/L 50 45.5 91 1-273
cis-1,3-Dichloropropene ug/L 50 49.5 99 1-227
Dibromochloromethane ug/L 50 50.3 101 53-149
Ethylbenzene ug/L 50 46.2 92 37-162
Hexachloro-1,3-butadiene ug/L 50 48.5 97 70-130
Methylene Chloride ug/L 50 44.5 89 1-221
Naphthalene ug/L 50 47.9 96 70-130
Tetrachloroethane ug/L 50 47.2 94 64-148
Toluene ug/L 50 46.3 93 47-150
trans-1,2-Dichloroethene ug/L 50 44.8 90 54-156
trans-1,3-Dichloropropene ug/L 50 48.4 97 17-183
Trichloroethene ug/L 50 47.0 94 71-157
Trichlorofluoromethane ug/L 50 39.2 78 17-181
Vinyl chloride ug/L 50 44.6 89 1-251
1,2-Dichloroethane-d4(S) % 88 70-130
4-Bromofluorobenzene(S) % 101 70-130
Toluene-d8(S) % 98 70-130
MATRIX SPIKE SAMPLE: 1786424
92305645001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
1,1,1-Trichloroethane ug/L ND 20 23.5 117 46-171
1,1,2,2-Tetrachloroethane ug/L ND 20 23.0 115 73-159
Results presented on this page ere in the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 13 of 32 1

Pace Analytical Services,Inc.
e 9800 Kinsey Ave Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com [phone]
i
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
MATRIX SPIKE SAMPLE: 1786424
92305645001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
1,1,2-Trichloroethane ug/L ND 20 23.7 119 64-152
1,1-Dichloroethane ug/L ND 20 23.4 117 43-172
1,1-Dichloroethene ug/L ND 20 22.7 114 48-189
1,2,4-Trichlorobenzene ug/L ND 20 24.4 122 70-130
1,2-Dichlorobenzene ug/L ND 20 25.1 125 54-154
1,2-Dichloroethane ug/L ND 20 22.5 112 42-171
1,2-Dichloropropane ug/L ND 20 23.5 118 55-157
1,3-Dichlorobenzene ug/L ND 20 25.8 129 57-148
1,4-Dichlorobenzene ug/L ND 20 25.2 126 58-149
2-Chloroethylvinyl ether ug/L ND 40 ND 0 70-130 J(M 1)
Acrolein ug/L ND 100 141 141 70-130 J(M 1)
Acrylonitrile ug/L ND 100 121 121 70-130
Benzene ug/L ND 20 24.2 121 54-163
Bromodichloromethane ug/L ND 20 22.5 113 56-152
Bromoform ug/L ND 20 24.2 121 53-151
Bromomethane ug/L ND 20 19.6 98 10-200
Carbon tetrachloride ug/L ND 20 21.8 109 41-175
Chlorobenzene ug/L ND 20 25.2 126 67-152
Chloroethane ug/L ND 20 24.2 121 23-200
Chloroform ug/L ND 20 24.6 118 51-166
Chloromethane ug/L ND 20 23.5 117 40-175
as-1,3-Dichloropropene ug/L ND 20 24.2 121 38-146
Dibromochloromethane ug/L ND 20 23.2 116 65-144
Ethylbenzene ug/L ND 20 24.1 120 57-152
Hexachloro-1,3-butadiene ug/L ND 20 24.1 120 70-130
Methylene Chloride ug/L ND 20 26.5 132 40-167
Naphthalene ug/L ND 20 22.9 114 70-130
Tetrachloroethene ug/L ND 20 23.5 118 59-155
Toluene ug/L ND 20 24.3 122 47-162
trans-1,2-Dichloroethene ug/L ND 20 25.4 127 47-178
trans-1,3-Dichloropropene ug/L ND 20 22.9 114 39-148
Trichloroethene ug/L ND 20 24.4 122 60-153
Trichlorofluoromethane ug/L ND 20 20.9 104 42-199
Vinyl chloride ug/L ND 20 23.2 116 46-176
1,2-Dichloroethane-d4(S) % 98 70-130
4-Bromofluorobenzene(S) % 100 70-130
Toluene-d8(S) % 99 70-130
SAMPLE DUPLICATE: 1786423
92305980001 Dup
Parameter Units Result Result RPD Qualifiers
1,1,1-Trichloroethane ug/L ND ND
1,1,2,2-Tetrachloroethane ug/L ND ND
1,1,2-Trichloroethane ug/L ND ND
1,1-Dichloroethane ug/L ND ND
Results presented on this page are In the units Indicated by the"Units"column except where an ultimate unit Is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 14 of 32

Pace Analytical Services,Inc.
ao 9800 Kincey Ave Suite 100
/7aceAnalytical Huntersvive,NC 28078
www pecelabs.corn
r (704)8759092
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
SAMPLE DUPLICATE: 1786423
92305980001 Dup
Parameter Units Result Result RPD Qualifiers
1,1-Dichloroethene ug/L ND ND
1,2,4-Trichlorobenzene ug/L ND ND
1,2-Dichlorobenzene ug/L ND ND
1,2-Dichloroethane ug/L ND ND
1,2-Dichloropropane ug/L ND ND
1,3-Dichlorobenzene ug/L ND ND
1,4-Dichlorobenzene ug/L ND ND
2-Chloroethylvinyl ether ug/L ND ND
Acrolein ug/L ND ND
Acrylonitrile ug/L ND ND
Benzene ug/L ND ND
Bromodichloromethane ug/L ND ND
Bromoform ug/L ND ND
Bromomethane ug/L ND ND
Carbon tetrachloride ug/L ND ND
Chlorobenzene ug/L ND ND
Chloroethane ug/L ND ND
Chloroform ug/L ND ND
Chloromethane ug/L ND ND
cis-1,3-Dichloropropene ug/L ND ND
Dibromochloromethane ug/L ND ND
Ethylbenzene ugh ND ND
Hexachloro-1,3-butadiene ug/L ND ND
Methylene Chloride ug/L ND ND
Naphthalene ug/L ND ND
Tetrachioroethene ug/L ND ND
Toluene ug/L ND ND
trans-1,2-Dichloroethene ug/L ND ND
trans-1,3-Didlloropropene ug/L ND ND
Trichloroethene ug/L ND ND
Trichlorofluoromethane ug/L ND ND
Vinyl chloride ug/L ND ND
1,2-Dichloroethane-d4(S) % 95 96 0
4-Bromofluorobenzene(S) % 99 102 3
Toluene-d8(S) % 105 102 3
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc..
Page 15 of 32

Pace Analytical Services,Inc.
eo 9800 Kincey Ave. Suite 100
ace
Analytical Huntersville,NC 28078
wwwpacelabs cam [phone]
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
QC Batch: 321902 Analysis Method: EPA 625
QC Batch Method: EPA 625 Analysis Description: 625 MSS
Associated Lab Samples: 92305645001
METHOD BLANK: 1783879 Matrix: Water
Associated Lab Samples: 92305645001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,2-Dichlorobenzene ug/L ND 5.0 07/21/16 21:23
1,2-Diphenylhydrazine ug/L ND 5.0 07/21/16 21:23
1,3-Dichiorobenzene ug/L ND 5.0 07/21/16 21:23
1,4-Dichlorobenzene ug/L ND 5.0 07/21/16 21:23
2,4,6-Trichlorophenol ug/L ND 10.0 07/21/16 21:23
2,4-Dichlorophenol ug/L ND 5.0 07/21/16 21:23
2,4-Dimethylphenol ug/L ND 10.0 07/21/16 21:23
I 2,4-Dinitrophenol ug/L ND 50.0 07/21/16 21:23
2,4-Dinitrotoluene ug/L ND 5.0 07/21/16 21:23
2,6-Dinitrotoluene ug/L ND 5.0 07/21/16 21:23
2-Chloronaphthalene ug/L ND 5.0 07/21/16 21:23
2-Chlorophenol ug/L ND 5.0 07/21/16 21:23
2-Nitrophenol ug/L ND 5.0 07/21/16 21:23
3,3'-Dichlorobenzidine ug/L ND 25.0 07/21/16 21:23
4,6-Dinitro-2-methylphenol ug/L ND 20.0 07/21/16 21:23
4-Bromophenylphenyl ether ug/L ND 5.0 07/21/16 21:23
4-Chloro-3-methylphenol ug/L ND 5.0 07/21/16 21:23
4-Chlorophenylphenyl ether ug/L ND 5.0 07/21/16 21:23
4-Nitrophenol ug/L ND 50.0 07/21/16 21:23
Acenaphthene ug/L ND 5.0 07/21/16 21:23
Acenaphthylene ug/L ND 5.0 07/21/16 21:23
Anthracene ug/L ND 5.0 07/21/16 21:23
Benzo(a)anthracene ug/L ND 5.0 07/21/16 21:23
Benzo(a)pyrene ug/L ND 5.0 07/21/16 21:23
Benzo(b)fluoranthene ug/L ND 5.0 07/21/16 21:23
Benzo(g,h,i)perylene ug/L ND 5.0 07/21/16 21:23
Benzo(k)fluoranthene ug/L ND 5.0 07/21/16 21:23
bis(2-Chloroethoxy)methane ug/L ND 10.0 07/21/16 21:23
bis(2-Chloroethyl)ether ug/L ND 5.0 07/21/16 21:23
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 07/21/16 21:23
Butylbenzylphthalate ug/L ND 5.0 07/21/16 21:23
Chrysene ug/L ND 5.0 07/21/16 21:23
Di-n-butylphthalate ug/L ND 5.0 07/21/16 21:23
Di-n-octylphthalate ug/L ND 5.0 07/21/16 21:23
Dibenz(a,h)anthracene ug/L ND 5.0 07/21/16 21:23
Diethylphthalate ug/L ND 5.0 07/21/16 21:23
Dimethylphthalate ug/L ND 5.0 07/21/16 21:23
Fluoranthene ug/L ND 5.0 07/21/16 21:23
Fluorene ug/L ND 5.0 07/21/16 21:23
Hexachlorobenzene ug/L ND 5.0 07/21/16 21:23
Hexachlorocydopentadiene ug/L ND 10.0 07/21/16 21:23
Results presented on thls page are In the units indicated by the"Units"column except where an alternate unit is presented to the rtght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc., Page 16 of 32

Pace Analytical Services,Inc.
aceAnalytical s/1111 9800 Kinsey Ave. Suite 100
Huntersville,NC 28078
wwwpacelabs.com [phone]
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
METHOD BLANK: 1783879 Matrix: Water
Associated Lab Samples: 92305645001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Hexachloroethane ug/L ND 5.0 07/21/16 21:23
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 07/21/1621:23
lsophorone ug/L ND 10.0 07/21/16 21:23
N-Nitroso-di-n-propylamine ug/L ND 5.0 07/21/16 21:23
N-Nitrosodimethylamine ug/L ND 5.0 07/21/16 21:23
N-Nitrosodiphenylamine ug/L ND 10.0 07/21/16 21:23
Naphthalene ug/L ND 5.0 07/21/16 21:23
Nitrobenzene ug/L ND 5.0 07/21/16 21:23
Pentachlorophenol ug/L ND 10.0 07/21/16 21:23
1 Phenanthrene ug/L ND 5.0 07/21/16 21:23
Phenol ug/L ND 5.0 07/21/16 21:23
Pyrene ug/L ND 5.0 07/21/16 21:23
2,4,6-Tribromophenol(S) % 74 10-137 07/21/16 21:23
2-Fluorobiphenyl(S) % 72 15-120 07/21/16 21:23
2-Fluorophenol(S) % 39 10-120 07/21/16 21:23
Nitrobenzene-d5(S) % 79 10-120 07/21/16 21:23
Phenol-d6(S) % 30 10-120 07/21/16 21:23
Terphenyl-d 14(S) % 93 11-131 07/21/16 21:23
LABORATORY CONTROL SAMPLE: 1783880
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,2-Dichlorobenzene ug/L 50 35.7 71 32-129
1,2-Diphenylhydrazine ug/L 50 42.6 85 25-150
1,3-Dichlorobenzene ug/L 50 35.1 70 1-172
1,4-Dichlorobenzene ug/L 50 34.9 70 20-124
2,4,6-Trichlorophenol ug/L 50 47.8 96 37-144
2,4-Dichlorophenol ug/L 50 43.9 88 1-191
2,4-Dimethylphenol ug/L 50 44.9 90 32-119
2,4-Dinitrophenot ug/L 250 186 74 1-181
2,4-Dinitrotoluene ug/L 50 52.2 104 39-139
2,6-Dinitrotoluene ug/L 50 50.2 100 50-158
2-Chloronaphthalene ug/L 50 37.6 75 60-118
2-Chlorophenol ug/L 50 40.8 82 23-134
2-Nitrophenol ug/L 50 48.1 96 29-182
3,3'-Dichlorobenzidine ug/L 100 89.6 90 1-262
4,6-Dinitro-2-methylphenol ug/L 100 113 113 1-181
4-Bromophenyiphenyl ether ug/L 50 44.7 89 53-127
4-Chloro-3-methylphenol ug/L 100 98.0 98 22-147
4-Chlorophenylphenyl ether ug/L 50 48.2 96 25-158
4-Nitrophenol ug/L 250 104 42 1-132
9
Acenaphthene ug/L 50 40.5 81 47-145
P
Acenaphthylene ug/L 50 42.0 84 33-145
Anthracene ug/L 50 41.7 83 1-166
Results presented on this page are In the units Indicated by the"Unit"column except where an alternate unit is presented to the right of the result
1 REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 17 of 32

Pace Analytical Services,Inc.
I c/
Kincey Ave
te
aceAnalytical 9800Hunte sv lle,C128078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: PPA Wastewater 7119
Pace Project No.: 92305645
LABORATORY CONTROL SAMPLE: 1783880
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Benzo(a)anthracene ug/L 50 45.6 91 33-143
Benzo(a)pyrene ug/L 50 43.6 87 17-163
Benzo(b)fluoranthene ug/L 50 43.5 87 24-159
Benzo(g,h,i)perylene ug/L 50 45.9 92 1-219
Benzo(k)fluoranthene ug/L 50 44.1 88 11-162
bis(2-Chloroethoxy)methane ug/L 50 47.4 95 33-184
bis(2-Chloroethyl)ether ug/L 50 47.8 96 12-158
bis(2-Ethylhexyl)phthalate ug/L 50 43.8 88 8-158
Butylbenzylphthalate ug/L 50 43.8 88 1-152
Chrysene ug/L 50 44.5 89 17-168
Di-n-butylphthalate ug/L 50 45.7 91 1-118
Di-n-octylphthalate ug/L 50 41.9 84 4-146
Dibenz(a,h)anthracene ug/L 50 44.8 90 1-227
Diethylphthalate ug/L 50 48.5 97 1-114
Dimethylphthalate ug/L 50 46.9 94 1-112
Fluoranthene ug/L 50 46.8 94 26-137
Fluorene ug/L 50 45.8 92 59-121
Hexachlorobenzene ug/L 50 43.5 87 1-152
Hexachlorocyclopentadiene ug/L 50 32.8 66 25-150
Hexachloroethane ug/L 50 33.9 68 40-113
Indeno(1,2,3-txi)pyrene ug/L 50 44.2 88 1-171
Isophorone ug/L 50 49.7 99 21-196
N-Nitroso-di-n-propylamine ug/L 50 51.1 102 1-230
N-Nitrosodimethylamine ug/L 50 25.8 52 25-150
N-Nitrosodiphenylamine ug/L 50 41.3 83 25-150
Naphthalene ug/L 50 39.4 79 21-133
Nitrobenzene ug/L 50 43.8 88 35-180
Pentachlorophenol ug/L 100 95.9 96 14-176
Phenanthrene ug/L 50 42.8 86 54-120
Phenol ug/L 50 24.0 48 5-112
Pyrene ug/L 50 43.4 87 52-115
2,4,6-Tribromophenol(S) % 95 10-137
2-Fluorobiphenyl(S) % 79 15-120
2-Fluorophenol(S) % 50 10-120
Nitrobenzene-d5(S) % 84 10-120
Phenol-d6(S) % 39 10-120
Terphenyl-d14(S) % 94 11-131
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1783881 1783882
MS MSD
92305495001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
1,2-Dichlorobenzene ug/L ND 100 100 66.4 72.5 66 72 32-129 9
1,2-Diphenyihydrazine ug/L ND 100 100 79.3 85.4 79 85 25-150 7
1,3-Dichlorobenzene ug/L ND 100 100 66.6 70.1 67 70 1-172 5
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 18 of 32

Pace Analytical Services,fnc.
aceAnalytical a 9800 Kinsey Ave. Suite 100
Huntersvllle,NC 28078
wwwpacelabs.com
[phone]
I
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1783881 1783882
MS MSD
92305495001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
1,4-Dichlorobenzene ug/L ND 100 100 65.6 69.2 66 69 20-124 5
2,4,6-Trichlorophenol ug/L ND 100 100 86.1 101 86 101 37-144 16
2,4-Dichiorophenol ug/L ND 100 100 87.4 103 87 103 1-191 17
2,4-Dimethylphenol ug/L ND 100 100 91.5 104 92 104 32-119 13
2,4-Dinitrophenol ug/L ND 500 500 322 391 64 78 1-181 19
2,4-Dinitrotoluene ug/L ND 100 100 97.9 102 98 102 39-139 4
2,6-Dinitrotoluene ug/L ND 100 100 96.2 105 96 105 50-158 9
2-Chloronaphthalene ug/L ND 100 100 71.3 78.6 71 79 60-118 10
2-Chlorophenol ug/L ND 100 100 79.2 92.3 79 92 23-134 15
2-Nitrophenol ug/L ND 100 100 94.2 99.6 94 100 29-182 6
3,3'-Dichlorobenzidine ug/L ND 200 200 186 196 93 98 1-262 5
4,6-Dinitro-2-methylphenol ug/L ND 200 200 199 231 99 116 1-181 15
4-Bromophenylphenyl ether ug/L ND 100 100 85.0 96.9 85 97 53-127 13
4-Chloro-3-methylphenol ug/L ND 200 200 206 235 103 117 22-147 13
4-Chlorophenylphenyl ether ug/L ND 100 100 89.9 98.7 90 99 25-158 9
4-Nitrophenol ug/L ND 500 500 294 311 59 62 1-132 6
Acenaphthene ug/L ND 100 100 75.5 82.5 76 82 47-145 9
Acenaphthylene ug/L ND 100 100 79.0 86.1 79 86 33-145 9
Anthracene ug/L ND 100 100 76.5 82.6 77 83 1-166 8
Benzo(a)anthracene ug/L ND 100 100 84.7 90.8 85 91 33-143 7
Benzo(a)pyrene ug/L ND 100 100 82.5 89.8 83 90 17-163 8
Benzo(b)fluoranthene ug/L ND 100 100 81.8 91.0 82 91 24-159 11
Benzo(g,h,i)perylene ug/L ND 100 100 87.9 92.5 88 92 1-219 5
Benzo(k)fluoranthene ug/L ND 100 100 79.2 88.1 79 88 11-162 11
bis(2-Chloroethoxy)methane ug/L ND 100 100 88.0 94.5 88 95 33-184 7
bis(2-Chloroethyl)ether ug/L ND 100 100 84.2 91.2 84 91 12-158 8
bis(2-Ethylhexyl)ph halate ug/L ND 100 100 78.5 84.5 79 85 8-158 7
Butylbenzylphthalate ug/L ND 100 100 78.7 84.3 79 84 1-152 7
Chrysene ug/L ND 100 100 83.0 88.2 83 88 17-168 6
Di-n-butylphthalate ug/L ND 100 100 84.2 87.6 84 88 1-118 4
Di-n-octylphthatate ug/L ND 100 100 82.3 84.4 82 84 4-146 2
Dibenz(a,h)anthracene ug/L ND 100 100 88.6 91.4 89 91 1-227 3
Diethyiphthalate ug/L ND 100 100 87.8 94.4 88 94 1-114 7
Dimethylphthalate ug/L ND 100 100 84.5 91.9 84 92 1-112 8
Fluoranthene ug/L ND 100 100 88.2 92.1 88 92 26-137 4
Fluorene ug/L ND 100 100 83.5 92.3 84 92 59-121 10
Hexachlorobenzene ug/L ND 100 100 83.0 92.0 83 92 1-152 10
Hexachlorocydopentadiene ug/L ND 100 100 68.8 75.6 69 76 25-150 9
Hexachloroethane ug/L ND 100 100 63.4 65.8 63 66 40-113 4
Indeno(1,2,3-cd)pyrene ug/L ND 100 100 84.7 91.3 85 91 1-171 7
Isophorone ug/L ND 100 100 92.4 99.6 92 100 21-196 7
N-Nitroso-di-n-propylamine ug/L ND 100 100 88.0 99.7 88 100 1-230 12
N-Nitrosodimethylamine ug/L ND 100 100 58.7 62.4 59 62 25-150 6
N-Nitrosodiphenylamine ug/L ND 100 100 77.8 86.1 78 86 25-150 10
Naphthalene ug/L ND 100 100 77.2 82.9 77 83 21-133 7
Nitrobenzene ug/L ND 100 100 84.8 90.7 85 91 35-180 7
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 19 of 32

Pace Analytical Services,Inc.
9800 Klncey Ave. Suite 100
aceAnalytical Hunteraville,NC 28078
wwwpacelebs.com [phone]
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1783881 1783882
MS MSD
92305495001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Pentachlorophenol ug/L ND 200 200 168 200 84 100 14-176 17
Phenanthrene ug/L ND 100 100 78.7 85.3 79 85 54-120 8
Phenol ug/L ND 100 100 65.0 74.0 65 74 5-112 13
Pyrene ug/L ND 100 100 76.4 84.1 76 84 52-115 10
2,4,6-Tribromophenol(S) % 86 99 10-137
2-Fluorobiphenyt(S) % 73 80 15-120
2-Fluorophenol(S) % 59 65 10-120
Nitrobenzene-d5(S) % 79 86 10-120
Phenol-d6(S) % 55 63 10-120
Terphenyl-d14(S) % 84 91 11-131
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 20 of 32

Pace Analytical Services,Inc.
aceAnalytical a 9800 Kincey Ave Suite 100
Huntersvlile,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
QC Batch: 321991 Analysis Method: SM 2540C
QC Batch Method: SM 2540C Analysis Description_ 2540C Total Dissolved Solids
Associated Lab Samples: 92305645001
METHOD BLANK: 1784409 Matrix: Water
Associated Lab Samples: 92305645001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 07/21/16 09:29
LABORATORY CONTROL SAMPLE: 1784410
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 294 118 90-110 J(LO)
SAMPLE DUPLICATE: 1784411
92305360001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 93.0 76.0 20 J(06)
SAMPLE DUPLICATE: 1784412
92305681004 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 239 238 0
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full.
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 21 of 32

Pace Analytical Services,Inc.
aceAnalytical a 9800 Kincey Ave Suite 100
Huntersville,NC 28078
w.wwpacalebs.com [phone]
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
QC Batch: 322557 Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92305645001
METHOD BLANK: 1787044 Matrix: Water
Associated Lab Samples: 92305645001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Ammonia mg/L ND 0.10 07/26/16 14:24
LABORATORY CONTROL SAMPLE: 1787045
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 5.1 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1787046 1787047
MS MSD
92305570001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L 1.1 5 5 6.1 6.1 101 101 90-110 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1787048 1787049
MS MSD
92305642003 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L ND 5 5 5.0 5.0 100 100 90-110 0
Results presented on this page are In the wilts Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 22 of 32

Pace Analytical Services,Inc.
aceAnalytical a 9800 Kinsey Ave Suite 100
Huntersville,NC 2807E
www.pacelabs.com [phone]
r
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
QC Batch: 322337 Analysis Method: EPA 351.2
QC Batch Method: EPA 351.2 Analysis Description: 351.2 TKN
Associated Lab Samples: 92305645001
METHOD BLANK; 1786275 Matrix: Water
Associated Lab Samples: 92305645001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Kjeldahl,Total mg/L ND 0.50 07/27/16 05:07
LABORATORY CONTROL SAMPLE: 1786276
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Kjeldahl,Total mg/L 10 10.4 104 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1786277 1786278
MS MSD
92305500002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Kjeldahl,Total mg/L ND 10 10 9.1 7.8 91 78 90-110 16 J(M1),J(R1)
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1786279 1786280
MS MSD
92305634001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Kjeldahl,Total mg/L 111 10 10 140 127 293 156 90-110 10 M6
Results presented on this page are In the units indicated by the"Units"column except when an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 23 of 32

,
Pace Analytical Services,Inc.
11
aceAnalyticalA
9800 Kinsey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.cvm
[phone]
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
QC Batch: 322585 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate+Nitrite,preserved
Associated Lab Samples: 92305645001
METHOD BLANK: 1787208 Matrix: Water
Associated Lab Samples: 92305645001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,NO2 plus NO3 mg/L ND 0.020 07/26/16 15:34
LABORATORY CONTROL SAMPLE: 1787209
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,NO2 plus NO3 mg/L 2.5 2.3 94 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1787210 1787211
MS MSD
92306020002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,NO2 plus NO3 mg/L 9.7 2.5 2.5 13.3 13.3 145 145 75-125 0 J(M1)
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1787212 1787213
MS MSD
92305595001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,NO2 plus NO3 mg/L 21,5 2.5 2.5 23.2 23.3 69 70 75-125 0 M6
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 24 of 32
I

Pace Analytical Services,Inc.
711111e
aceAnalytical 9800 Kincey Ave Suite 100
Huntersville,NC 28078
wwwpaceIabs.com
[phone]
QUALITY A
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
QC Batch: 322780 Analysis Method: EPA 365.1
QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus,Total
Associated Lab Samples: 92305645001
METHOD BLANK: 1788336 Matrix: Water
Associated Lab Samples: 92305645001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 07/28/16 21:57
LABORATORY CONTROL SAMPLE: 1788337
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.4 98 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1788338 1788339
MS MSD
92304908002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus mg/L 1.9 2.5 2.5 4.3 4.3 97 94 90-110 2
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1788340 1788341
MS MSD
92305645001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus mg/L 0.14 2.5 2.5 2.6 2.5 99 95 90-110 4
Results presented on this page are In the unite indicated by the"Untts"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 25 of 32

Pace Analytical Services,Inc.
® 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
wwwpacelabs.com
[phone]
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
QC Batch: 322397 Analysis Method: EPA 420.4
QC Batch Method: EPA 420.4 Analysis Description: 420.4 Phenolics
Associated Lab Samples: 92305645001
METHOD BLANK: 1786426 Matrix: Water
Associated Lab Samples: 92305645001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phenol mg/L ND 0.010 07/25/16 15:00
LABORATORY CONTROL SAMPLE: 1786427
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phenol mg/L .05 0.052 103 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1786428 1786429
MS MSD
92305236002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qua!
Phenol mg/L 39.5 .05 .05 0.092 0.089 105 99 90-110 3
ug/L
Results presented on this page are In the units indicated by the"Units"column except where an alternate untt is presented to the tight of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 26 of 32

Pace Analytical Services,Inc.
aceAnalytical a 9800 Kinsey Ave. Suite 100
Huntersville,NC 28078
7 wwwpacelabs.corn [phone]
QUALITY CONTROL DATA
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
QC Batch: 322714 Analysis Method: SM 4500-CN-E
QC Batch Method: SM 4500-CN-E Analysis Description: 4500CNE Cyanide,Total
Associated Lab Samples: 92305645001
METHOD BLANK: 1787900 Matrix: Water
Associated Lab Samples: 92305645001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Cyanide mg/L ND 0.0080 07/27/16 18:04
LABORATORY CONTROL SAMPLE: 1787901
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Cyanide mg/L .1 0.11 107 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1787902 1787903
MS MSD
92306181001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Cyanide mg/L ND .1 .1 0.10 0.10 98 101 75-125 3
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1787904 1787905
MS MSD
92306539002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Cyanide mg/L ND .1 .1 0.093 0.098 89 94 75-125 6
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 27 of 32

Pace Analytical Services,Inc.
aceAnalytical a 9800 Kinsey Ave Suite 100
Hunters ville,NC 28078
wwwpacelabs cn n [phone]
QUALIFIERS
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
Rt.-Reporting Limit.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether,Styrene,and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute_
LABORATORIESPAST-A Pace Analytical Services-Asheville
PAST-C Pace Analytical Services-Charlotte
ANALYTE QUALIFIERS
I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.
J(D6) Estimated Value.The relative percent difference(RPD)between the sample and sample duplicate exceeded laboratory
control limits.
J(LO) Estimated Value.Analyte recovery in the laboratory control sample(LCS)was outside QC limits.
J(L1) Estimated Value.Analyte recovery in the laboratory control sample(LCS)was above QC limits. Results for this analyte in
associated samples may be biased high.
J(M1) Estimated Value.Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)
recovery.
J(R1) Estimated Value.RPD value was outside control limits.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
c2 Acid preservation may not be appropriate for the analysis of 2-Chloroethylvinyl ether.
REPORT OF LABORATORY ANALYSIS
This report shalt not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc. Page 28 of 32

Pace Analytical Services,Inc.
'i 9800Hunte sv Ile,NCI28078
aceAnalytical
wwwpacelabs.corn
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: PPA Wastewater 7/19
Pace Project No.: 92305645
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92305645001 WASTEWATER EFFLUENT EPA 1664B 322537
92305645001 WASTEWATER EFFLUENT EPA 200.7 322119 EPA 200.7 322330
92305645001 WASTEWATER EFFLUENT EPA 1631E 322147 EPA 1631E 322150
92305645002 WW EFF LLHG BLK EPA 1631E 322147 EPA 1631E 322150
92305645001 WASTEWATER EFFLUENT EPA 625 321902 EPA 625 322049
92305645001 WASTEWATER EFFLUENT EPA 624 322396
92305645001 WASTEWATER EFFLUENT SM 2540C 321991
92305645001 WASTEWATER EFFLUENT TKN+NO3+NO2 323099
Calculation
92305645001 WASTEWATER EFFLUENT EPA 350.1 322557
92305645001 WASTEWATER EFFLUENT EPA 351.2 322337
92305645001 WASTEWATER EFFLUENT EPA 353.2 322585
92305645001 WASTEWATER EFFLUENT EPA 365.1 322780
92305645001 WASTEWATER EFFLUENT EPA420.4 322397
92305645001 WASTEWATER EFFLUENT SM 4500-CN-E 322714
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:08/03/2016 08:15 AM without the written consent of Pace Analytical Services,Inc.. Page 29 of 32 1

Document Name: Document Revised:May 24,2016
Sample Condition Upon Recelpt(SCUR) _Igo 1 of 2
aeeAnalytical Document No.: Issuing Authority:
• FRAL CS-001-Rev.04 Pace Raleigh Quality Office
o,,..)nf 7 for Internal Use ONLY
Sample Condition Upon Client Name:y ,, WO# : 92305645
Receipt - 1 OCk et b Project A
Courier: ❑fed Ex OURS ❑LISPS ❑Client 111111 III I 11111 JIll III
0 Commercial ElPace ❑Other: 92305645
Custody Seal Present? Dyes ,EjNo Seals Intact? ❑Yes ,No
Date/Initials Person Examining Contents kt v
Packing Material: ❑Bubble Wrap ❑Bubble Bags OICIone DOther:
Thermometer: T1505 Type of Ice: 12(Aet ['Blue ❑None ❑Samples on ice,cooling process has begun
Correction Factor:0.0'C Cooler Temp Corrected('C}: 3 b Biological Tissue Frozen? Dyes ❑No [:A.N/A
Temp should be above freezing to 6'C
USDA Regulated Soil Gal N/A,water sample)
Did samples y rigtnate In a quarantine zone within the United States:CA,NY,or SC(check maps)? Did samples originate from a foreign source(inter Tonally,
Dyes No Including Hawaii and Puerto Rico)?Oyes al No
Comm ents/Discrepancy:
Chain of Custody Present? es ❑No ON/A _1.
Samples Arrived within Hold Time? Yes ONo ON/A 2.
Short Hold Time Analysis(<72 hr.)? Oyes (2!o ON/A 3.
Rush Turn Around Time Requested? Dyes ��jfNo ❑N/A 4.
Sufficient Volume? ,�res ❑No ON/A 5.
Correct Containers Used? Eris ❑No ON/A 6.
-Pace Containers Used? Oho QN/A
Containers Intact? �es ONo ON/A 7.
Samples Field Filtered? ❑Yes ❑No (t/A 8. Note if sediment is visible in the dissolved container
Sample Labels Match C0C? /{5Yes ❑No ON/A 9.
-Includes Date/Time/ID/Analysts Matrix: WC-
All
containers needing acid/base preservation have been r�!� 10.HNC;pia
checked? es ❑NO ❑N/A
All containers needing preservation are found to be in (Yat NO""'
compliance with EPA recommendation? rm04OM
(HNO,,HISO.,HCI<2;NaOH>9 Sulfide,NaOH>12 Cyanide) Yes ❑No ON/A N.oxrw12
Exceptions:VOA,Conform,MC,Oil and Grease,
DRO/8015(water)DOC,LLHg es ❑No ON/A 1iOntryksrova
Samples checked for dechlorination? es ❑No ON/A 11.
Headspace In VOA Vials(>5-6mm)? Ores ❑NoA 12.
Trip Blank Present? Dyes ❑No N/A 13.
Trip Blank Custody Seals Present? ❑Yes ❑No ,TWA
Pace Trip Blank Loth(if purchased): __ _
CLIENT NOTIFICATION/RESOLUTION Field Data Required? Oyes ❑No
Person Contacted: Date/Time:
Comments/Sample
Discrepancy:
Project Manager SCURF Review: 4 Date: //20 1
Project Manager SRF Review: Date: -7 :0 1
Note: Whenever there is a discrepancy affecting North Carolina compliance samples,a copy of this form wit be sent to the North aroil a DEHNR Certification Office(I.e.
Out of hold,Incorrect preservative,out of temp,Incorrect containers)
Page 30 of 32

CHAIN-OF-CUSTODY I Analytical Request Document o
•112e Analytical
...1• The Cnatn-of-CusbCy is a LEGAL DOCUMENT.All relevant fields must be completed acaraloly.
I`V ia!!`fl.Q! M
.� � cn
co
P
,,...164 (ser
Section A Seaton B Section C Pao.: of
o_
Required cram Information: Required Project IAormation
a � Invdce Information.w h a. !4 r�1ert3 Remit To: v✓II CJt 4 e I/Vie e'} -AHaneon: pr//c4a e I Al k l 208 6 4 3 5
Address Copy To:
_r o- 30X . �O C°"°"Y Nd°"`r r�np r0 REGULATORY AGENCY
/e(rmo
✓&c.re),AiC V7si Address �r f NPDES r GROUND WATER r DRINKrNGWATER
Enai To' L Rrerax Order Na. 1Pau ciao
�•�����O /Q ��
rrl4ll[K a�7tjr I._1)F[,�y.. 17-00003 ,:en.c.. .27SY6 E UST I- RCRA r OTHER
x17z-e.ocii-q.ZJ/Flirt-
Project Marro: Part s. Sib Location
25�-G�f/-�('13a iwap�r
Requaata0 Due Deta'TAT: 'Project Number. Pace Pete e: STATE
Requested Analysis Filtered(YIN)
Sec600 0 Melia Codes '^ -r
E.o w.eca0re '+�+ IAATRtz I COEJF g COLLECTED Preservatives >
Nicking Wakr OW = U 2 `�
Wet '
« wr 0 K D 9
Waste Water WW COY►OWE OOYPCSI r U
Product P .4 1 S1AR c•o ur
b1 Z
&AlSoid SL
SAMPLE ID °i1 a 8 u Fi D �- L l7 7f�l� "f S
(A-Z.0-91:) Air°a uy w K z We
r c
Samore IN MUST BE UNIQUE Trssuo TS O a 2 F' o
Q
Ot r OT U V z 2oe o U
B K U m IS 12 i 0
W ' z i n �° Za � %' d - � m G% 2>v5`� S
DATE TIME DATE TIME us a D I=I I Z Z .2 s y fY Pace Project NoJ Lab I.D.
1 /mac!Ile w4 tee' Ell uem-l" 4031116 1/'l�/:36 ee - 'xi ,'
2 .R,at z-
n"7
3
4
5
B
B
i
1C f , . . .
1i
12
I
ADDITIONAL COMMENTS REIJNOUI BY J AFFIUAT10N DATE TYEE ACCEPTED BY?AFFILIATION DATE TIME SAMPLE CONDITIONS
1�c (, .-- 7-is-2 /2td ' i. . ! t r, ., ii LZvy
, C-Dt...)(eve l tr4,-cory - -*.e.4,044,..7.(1.6, Iiiiii) l 11;44771; CA-
ORIGINAL SAMPLER NAME AND SIGNATURE I, C
PRINT wme a SAMPLER: r✓];c_i.1 , RI ✓l s 8� 8 S; s��
� ' Oe f I DATES nW E o o ' - vL
SIGNATUREo1SMIPLER: ! Ia G i o e U-
'enlanent tWte Br sgrurg the term l worm): I7 ~ c ye N
You are xceplog Pace:NE1 JO coy paNrora toms aM opmerq a idle cexpe;at 1.5 a per ream tot am nrdoes not We■m 30 days. F-A1L•0.020rev.07,15-May-2007

��� 17--"a-411 ‘'-%--- . .
Permit No.NC0020605
A: (7) EFFLUENT POLLUTANT SCAN[G.S. 143-215.1(b)]
The Permittee shall perform a total of three (3) Effluent Pollutant Scans for all parameters listed
below. One scan must be performed in each of the following years: 2016, 2017,and 2018. Analytical
methods shall be in accordance with 40 CFR Part 136 and shall be sufficiently sensitive to determine
whether parameters are present in concentrations greater than applicable standards and criteria.
Samples should be collected with one quarterly toxicity test each year, and must represent seasonal
variation[i.e.,do not sample in the same quarter every year]. Unless otherwise indicated,metals shall
be analyzed as"total recoverable."
Ammonia(as N) Trans-1,2-dichloroethylene Bis(2-chloroethyl)ether
Chlorine(total residual,TRC) 1,1{lirhloroethylene Bis(2-rhloroisopropyl)ether
Dissolved oxygen 1,2.dichloropropane Bis(2-ethylbexyl)phthalate
Nitrate/Nitrite 1,3-dichloropropylene 4-bromophenyl phenyl ether
Kjeldahl nitrogen Ethylbenzene Butyl benzyl phthalate
Oil and grease Methyl bromide 2-chloronaphthalene
Phosphorus Methyl chloride 4-chlorophenyl phenyl ether
Total dissolved solids Methylene chloride Chrysene
Hardness 1,1,2,2-tetrachloroethane Di-n-butyl phthalate
Antimony Tetrachloroethylene Di-n-octyl phthalate
Arsenic Toluene Dibenzo(a,h)andaacene
Beryllium 1,1,1-tnrhloroethane 1,2-dichlorobenzene
Cadmium 1,1,2-trichlurocthane 1,3-dichlorobenzene
Chromium Trichloroethylene 1,4-dichlorobenzenc
Copper Virryl chloride 3,3-dichloro benzidine
Lead Acid-Lail-iambic compounds; Diethyl phthalate
Mercury(EPA Method 1631E) P-chloro-m-cresol Dimethyl phthalate
Nickel 2-chlorophenol 2,4-dinitmtoluene
Sp4nium 2,4-dichlorophenol 2,6-dinitrotoluene
Silver 2,4-dimethylphenol 1,2-diphenylhydrazine
Thallium 4,6-dinitrm-o-cresol Fluoranthene
Zinc 2,4-dinitrophenol Fluorene
Cyanide 2-nitrophenol Hexachlorobenzene
Total phenolic compounds 4-nitrophenol Hexachlorobutadirm
Volatileorgaaieepmportndd; Pentachlorophenol Hexachlorocyclo-penta(Ilene
Arrolein Phenol Hexachloroethane 1
Acrylouitnle 2,4,6-trichloropheno! Indeno(1,2,3-cd)pyrene
Benzene Dose-neutral compound&; Isophorone
Bramoform Acenaphthene Naphthalene
Carbon tetrachloride Acenaphthylene Nitrobenzene
Chlorohenzene Anthracene N-nitrosodi-n-ptopylamine
Clilorodibromomethane Benzidine N-nitrosodimethyiamine
Chloroethane Benzo(a)anduacene N-nitrosodiphenylamine
2-rliloroethylvinyl ether Benzo(a)pyrene Phenanthrene
Chloroform 3,4 benzotluoranthene Pyrene
Dichlorobromomcthane Benzu((hi)perylene 1,2,4-tiichluzobenzene
1,1-dichlo roe thane Benzo(k)fluoranthene
1,2-dichloroetbane Bis(2-chloroethoxy)methane
Page 10 of 14
Page 32 of 32

Pace Analytical Services,LLC
e Kincey Ave. Suite 100
aceAnalytical 9800 Huntersville,NC 28078
wwwpacelabs.com [phone]
February 02, 2017
Mr. Mike Allen
Town of Tarboro
506 Dowd Street
PO Box 220
Tarboro, NC 27886
RE: Project: PPA 1/18/17
Pace Project No.: 92326935
Dear Mr.Allen:
Enclosed are the analytical results for sample(s) received by the laboratory on January 19, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
Enclosures
i
,'i � REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
.� •; without the written consent of Pace Analytical Services,LLC. Page 1 of 33

Pace Analytical Services,LLC
//7e 9800 Kincey Ave. Suite 100
Kincey
Huntersville,NC 28078
www.peceiebs.con [phone]
CERTIFICATIONS
Project: PPA 1/18/17
Pace Project No.: 92326935
Charlotte Certification IDS
9800 Kincey Ave.Ste 100,Huntersville,NC 28078 South Carolina Certification#:99006001
North Carolina Drinking Water Certification#:37706 Florida/NELAP Certification#:E87627
North Carolina Field Services Certification#:5342 Kentucky UST Certification#:84
North Carolina Wastewater Certification#: 12 VirginiaNELAP Certification#:460221
Asheville Certification IDS
2225 Riverside Drive,Asheville,NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
Massachusetts Certification#:M-NC030 VirginiaNELAP Certification#:460222
North Carolina Drinking Water Certification#:37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 2 of 33

Pace Analytical Services,LLC
Kincey Ave.
te 100
s 9800Huntersville,NCI28078
aceAnalytical
wwwpacekbs.com [phone]
i r ,
SAMPLE ANALYTE COUNT
Project: PPA 1/18/17
Pace Project No.: 92326935
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92326935001 Wastewater Effluent EPA 1664B JMS 1 PASI-C
EPA200.7 SH1 15 PASI-A
EPA1631E ANB 1 PASI-A
EPA 625 RES 59 PASI-C
EPA 624 GAW 39 PASI-C
SM 2540C MLS 1 PASI-A
EPA 350.1 1993 Rev 2.0 DMN 1 PASI-A
EPA 351.2 BRJ 1 PASI-A
EPA 353.2 WRC 1 PASI-A
EPA 365.1 MDW 1 PASI-A
EPA 420.4 DMN 1 PASI-A
SM 4500-CN-E DMN 1 PASI-A
92326935002 Field Blank Wastewater Eff. EPA 1631E ANB 1 PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services.LLC. Page 3 of 33

Pace Analytical Services,LLC
®• aceAnalytical 9800 Kincey Ave. 00
Huntersville, Suite 178
www.pecelebs.com [phone]
ANALYTICAL RESULTS
C
Project: PPA 1/18/17
Pace Project No.: 92326935
Sample: Wastewater Effluent Lab ID: 92326935001 Collected: 01/18/17 14:00 Received: 01/19/17 13:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM,Oil and Grease Analytical Method:EPA 1664E
Oil and Grease ND mg/L 5.0 1 02/02/17 06:56
200.7 MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA 200.7
Antimony ND ug/L 5.0 1 01/24/17 19:45 01/25/17 12:59 7440-36-0
Arsenic ND ug/L 10.0 1 01/24/17 19:45 01/25/17 12:59 7440-38-2
Beryllium ND ug/L 1.0 1 01/24/17 19:45 01/25/17 12:59 7440-41-7
Cadmium ND ug/L 1.0 1 01/24/17 19:45 01/25/17 12:59 7440-43-9
Calcium 8910 ug/L 100 1 01/24/17 19:45 01/25/17 12:59 7440-70-2
Chromium ND ug/L 5.0 1 01/24/17 19:45 01/25/17 12:59 7440-47-3
Copper ND ug/L 5.0 1 01/24/17 19:45 01/25/17 12:59 7440-50-8
Lead ND ug/L 5.0 1 01/24/17 19:45 01/25/17 12:59 7439-92-1
Magnesium 2020 ug/L 100 1 01/24/17 19:45 01/25/17 12:59 7439-95-4
Nickel ND ug/L 5.0 1 01/24/17 19:45 01/25/17 12:59 7440-02-0
Selenium ND ug/L 10.0 1 01/24/17 19:45 01/25/17 12:59 7782-49-2
Silver ND ug/L 5.0 1 01/24/17 19:45 01/25/17 12:59 7440-22-4
Thallium ND ug/L 10.0 1 01/24/17 19:45 01/25/17 12:59 7440-28-0
Hardness,Total(SM 2340B) 30600 ug/L 662 1 01/24/17 19:45 01/25/17 12:59
Zinc 18.0 ug/L 10.0 1 01/24/17 19:45 01/25/17 12:59 7440-66-6
1631E Mercury,Low Level Analytical Method:EPA 1631E Preparation Method:EPA 1631E
Mercury 1.02 ng/L 0.50 1 01/24/17 14:59 01/26/17 13:33 7439-97-6
625 MSSV Analytical Method:EPA 625 Preparation Method:EPA 625
Acenaphthene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 83-32-9
Acenaphthylene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 208-96-8
Anthracene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 120-12-7
Benzo(a)anthracene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 56-55-3
Benzo(a)pyrene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 50-32-8
Benzo(b)fluoranthene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 205-99-2
Benzo(g,h,i)perylene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 191-24-2
Benzo(k)fluoranthene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 207-08-9
4-Brornophenylphenyl ether ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 101-55-3
Butylbenzylphthalate ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 85-68-7
4-Chloro-3-methylphenol ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 59-50-7
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 01/24/17 08:30 01/25/17 22:38 111-91-1
bis(2-Chloroethyl)ether ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 111-44-4
2-Chloronaphthalene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 91-58-7
2-Chlorophenol ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 95-57-8
4-Chlorophenylphenyl ether ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 7005-72-3
Chrysene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 218-01-9
Dibenz(a,h)anthracene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 53-70-3
1,2-Dichlorobenzene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 95-50-1
1,3-Dichlorobenzene ND ug/L 5.0 1 01/24/1708:30 01/25/1722:38 541-73-1
1,4-Dichlorobenzene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 106-46-7
3,3'-Dichlorobenzidine ND ug/L 25.0 1 01/24/17 08:30 01/25/17 22:38 91-94-1
2,4-Dichlorophenol ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 120-83-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 4 of 33

Pace Analytical Services,LLC
2aceAnalytical® 9800 Klncey Ave. Suite 100
Huntersvllle,NC 28078
www.pacelsbs.cart [phone]
i
ANALYTICAL RESULTS
Project: PPA 1/18/17
Pace Project No.: 92326935
Sample: Wastewater Effluent Lab ID: 92326935001 Collected: 01/18/17 14:00 Received: 01/19/17 13:24 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
625 MSSV Analytical Method:EPA 625 Preparation Method:EPA 625
Diethylphthalate ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 01/24/17 08:30 01/25/17 22:38 105-67-9
Dimethylphthalate ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 131-11-3
Di-n-butylphthalate ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 01/24/17 08:30 01/25/17 22:38 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 01/24/17 08:30 01/25/17 22:38 51-28-5
2,4-Dinitrotoluene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 121-14-2
2,6-Dinitrotoluene ND ug/L 5.0 1 01/24/1708:30 01/25/1722:38 606-20-2
Di-n-octylphthalate ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 117-84-0
1,2-Diphenylhydrazine ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 122-66-7
bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 117-81-7
Fluoranthene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 206-44-0
Fluorene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 86-73-7
Hexachlorobenzene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 01/24/17 08:30 01/25/17 22:38 77-47-4
Hexachloroethane ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 5,0 1 01/24/17 08:30 01/25/17 22:38 193-39-5
Isophorone ND ug/L 10.0 1 01/24/17 08:30 01/25/17 22:38 78-59-1
Naphthalene ND ug/L 5,0 1 01/24/17 08:30 01/25/17 22:38 91-20-3
Nitrobenzene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 98-95-3
2-Nitrophenol ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 88-75-5
4-Nitrophenol ND ug/L 50.0 1 01/24/17 08:30 01/25/17 22:38 100-02-7
N-Nitrosodimethylamine ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1 01/24/17 08:30 01/25/17 22:38 86-30-6
Pentachlorophenol ND ug/L 10.0 1 01/24/17 08:30 01/25/17 22:38 87-86-5
Phenanthrene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 85-01-8
Phenol ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38
Pyrene ND ug/L 5.0 1 01/24/17 08:30 01/25/17 22:38 129-00-0
2,4,6-Trichlorophenol ND ug/L 10.0 1 01/24/17 08:30 01/25/17 22:38 88-06-2
Surrogates
Nitrobenzene-d5(S) 79 % 10-120 1 01/24/17 08:30 01/25/17 22:38 4165-60-0
2-Fluorobiphenyl(S) 73 % 15-120 1 01/24/17 08:30 01/25/17 22:38 321-60-8
Terphenyl-d14(S) 87 % 11-131 1 01/24/17 08:30 01/25/17 22:38 1718-51-0
Phenol-d6(S) 31 % 10-120 1 01/24/17 08:30 01/25/17 22:38 13127-88-3
2-Fluorophenol(S) 41 % 10-120 1 01/24/17 08:30 01/25/17 22:38 367-12-4
2,4,6-Tribromophenol(S) 84 % 10-137 1 01/24/17 08:30 01/25/17 22:38 118-79-6
624 Volatile Organics Analytical Method:EPA 624
Acrolein ND ug/L 5.0 1 01/24/17 19:04 107-02-8
Acrylonitrile ND ug/L 50.0 1 01/24/17 19:04 107-13-1
Benzene ND ug/L 2.0 1 01/24/17 19:04 71-43-2
Bromodichioromethane ND ug/L 2.0 1 01/24/17 19:04 75-27-4
Bromoform ND ug/L 2.0 1 01/24/17 19:04 75-25-2
Bromomethane ND ug/L 2.0 1 01/24/17 19:04 74-83-9
Carbon tetrachloride ND ug/L 2.0 1 01/24/17 19:04 56-23-5
Chlorobenzene ND ug/L 2.0 1 01/24/17 19:04 108-90-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 33

Pace Analytical Services,LLC
s7°, 9800 Klncey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.paceiabs.com [phone]
1
ANALYTICAL RESULTS
Project: PPA 1/18/17
Pace Project No.: 92326935
Sample: Wastewater Effluent Lab ID: 92326935001 Collected: 01/18/17 14:00 Received: 01/19/17 13:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
624 Volatile Organics Analytical Method:EPA 624
Chloroethane ND ug/L 2.0 1 01/24/17 19:04 75-00-3
1 4 11
2-Chloroethylvinyl ether ND ug/L 5.0 1 01/24/17 9.0 0-7 5-8 c2
Chloroform ND ug/L 2.0 1 01/24/17 19:04 67-66-3
Chloromethane ND ug/L 2.0 1 01/24/17 19:04 74-87-3
Dibromochloromethane ND ug/L 2.0 1 01/24/17 19:04 124-48-1
1,2-Dichlorobenzene ND ug/L 2.0 1 01/24/17 19:04 95-50-1
1,3-Dichlorobenzene ND ug/L 2.0 1 01/24/17 19:04 541-73-1
1,4-Dichlorobenzene ND ug/L 2.0 1 01/24/17 19:04 106-46-7
1,1-Dichloroethane ND ug/L 2.0 1 01/24/17 19:04 75-34-3
1,2-Dichloroethane ND ug/L 2.0 1 01/24/17 19:04 107-06-2
1,1-Dichloroethene ND ug/L 2.0 1 01/24/17 19:04 75-35-4
trans-1,2-Dichloroethene ND ug/L 2.0 1 01/24/17 19:04 156-60-5
1,2-Dichloropropane ND ug/L 2.0 1 01/24/17 19:04 78-87-5
cis-1,3-Dichloropropene ND ug/L 2.0 1 01/24/17 19:04 10061-01-5
1 trans-1,3-Dichloropropene ND ug/L 2.0 1 01/24/17 19:04 10061-02-6
Ethylbenzene ND ug/L 2.0 1 01/24/17 19:04 100-41-4
Hexachloro-1,3-butadiene ND ug/L 5.0 1 01/24/17 19:04 87-68-3
Methylene Chloride ND ug/L 2.0 1 01/24/17 19:04 75-09-2
Naphthalene ND ug/L 5.0 1 01/24/17 19:04 91-20-3
1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 01/24/17 19:04 79-34-5
Tetrachloroethene ND ug/L 2.0 1 01/24/17 19:04 127-18-4
Toluene ND ug/L 2.0 1 01/24/17 19:04 108-88-3
1,2,4-Trcchlorobenzene ND ug/L 2.0 1 01/24/17 19:04 120-82-1
1,1,1-Trichioroethane ND ug/L 2.0 1 01/24/17 19:04 71-55-6
1,1,2-Trichloroethane ND ug/L 2.0 1 01/24/17 19:04 79-00-5
Trichloroethene ND ug/L 2.0 1 01/24/17 19:04 79-01-6
Trichlorofluoromethane ND ug/L 2.0 1 01/24/17 19:04 75-69-4
Vinyl chloride ND ug/L 2.0 1 01/24/17 19:04 75-01-4
Surrogates
4-Bromofluorobenzene(S) 97 % 70-130 1 01/24/17 19:04 460-00-4
Toluene-d8(S) 103 % 70-130 1 01/24/17 19:04 2037-26-5
1,2-Dichloroethane-d4(S) 97 % 70-130 1 01/24/17 19:04 17060-07-0
2540C Total Dissolved Solids Analytical Method:SM 2540C
Total Dissolved Solids 225 mg/L 25.0 1 01/23/17 11:42
350.1 Ammonia Analytical Method:EPA 350.1 1993 Rev 2.0
Nitrogen,Ammonia ND mg/L 0.10 1 01/30/17 17:20 7664-41-7
351.2 Total Kjeldahl Nitrogen Analytical Method:EPA 351.2
Nitrogen,Kjeldahl,Total 1.0 mg/L 0.50 1 01/27/17 23:42 7727-37-9
353.2 Nitrogen,NO2/NO3 pres. Analytical Method:EPA 353.2
Nitrogen,NO2 plus NO3 8.3 mg/L 0.10 5 01/25/17 19:23
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 6 of 33

Pace Analytical Services,LLC
e 9800 Kincey Ave. Sulte 100
ac21. eAnalytical Huntersville,NC 28078
www.pacelahacom [phone]
ANALYTICAL RESULTS
Project: PPA 1/18/17
Pace Project No.: 92326935
Sample: Wastewater Effluent Lab ID: 92326935001 Collected: 01/18/17 14:00 Received: 01/19/17 13:24 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
365.1 Phosphorus,Total Analytical Method:EPA 365.1
Phosphorus 0.096 mg/L 0.050 1 01/24/17 19:58 7723-14-0
420.4 Phenolics,Total Analytical Method:EPA 420.4
Phenol ND mg/L 0.010 1 01/26/17 13:56
4500CNE Cyanide,Total Analytical Method:SM 4500-CN-E
Cyanide ND mg/L 0.0080 1 01/31/17 16:45 57-12-5
Sample: Field Blank Wastewater Lab ID: 92326935002 Collected: 01/18/17 14:00 Received: 01/19/17 13:24 Matrix: Water
Eff.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method:EPA 1631E Preparation Method:EPA 1631E
Mercury ND ng/L 0.50 1 01/24/17 14:59 01/26/17 13:41 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 7 of 33

Pace Analytical Services,LLC
® 9800 Kincey Ave. Suite 100
aceAnalytiiJal Huntersvllle,NC 28078
www.pacetabs.com [phone]
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
QC Batch: 346632 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664B Analysis Description: 1664 HEM,Oil and Grease
Associated Lab Samples: 92326935001
METHOD BLANK: 1922909 Matrix: Water
Associated Lab Samples: 92326935001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 5.0 02/02/17 06:55
LABORATORY CONTROL SAMPLE: 1922910
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L 40 38.0 95 78-114
MATRIX SPIKE SAMPLE: 1922911
35291203002 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L 6.4 40 46.2 99 78-114
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 33

Pace Analytical Services,LLC
a 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com
[phone]
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
QC Batch: 345461 Analysis Method: EPA 1631E
QC Batch Method: EPA 1631E Analysis Description: 1631E Mercury,Low Level
Associated Lab Samples: 92326935001,92326935002
METHOD BLANK: 1916657 Matrix: Water
Associated Lab Samples: 92326935001,92326935002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 01/26/17 10:22
METHOD BLANK: 1916658 Matrix: Water
Associated Lab Samples: 92326935001,92326935002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 01/26/17 12:24
METHOD BLANK: 1916659 Matrix: Water
Associated Lab Samples: 92326935001,92326935002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 01/26/17 13:49
LABORATORY CONTROL SAMPLE: 1916660
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Mercury ng/L 5 4.84 97 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1916661 1916662
MS MSD
92327123002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Mercury ng/L 6.63 25 25 31.6 31.6 100 100 71-125 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1916663 1916664
MS MSD
92327182001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Mercury ng/L 6.53 25 25 31.6 31.6 100 100 71-125 0
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 33

Pace Analytical Services,LLC
e
aceAnalytical 9800 Kinsey Ave. Suite 100
Huntersvllle,NC 28078
www.pecelabs.cam [phone]
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
QC Batch: 345331 Analysis Method: EPA 200.7
QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET
Associated Lab Samples: 92326935001
METHOD BLANK: 1916024 Matrix: Water
Associated Lab Samples: 92326935001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1
Antimony ug/L ND 5.0 01/25/17
/17 11:33
Arsenic ug/L ND 10.0 01/25/17 11:33
Beryllium ug/L ND 1.0 01/25/17 11:33
Cadmium ug/L ND 1.0 01/25/17 11:33
Calcium ug/L ND 200 01/25/17 23:04
Chromium ug/L ND 5.0 01/25/17 11:33
Copper ug/L ND 5.0 01/25/17 11:33
Hardness,Total(SM 2340B) ug/L ND 1320 01/25/17 23:04
Lead ug/L ND 5.0 01/25/17 11:33
Magnesium ug/L ND 100 01/25/17 11:33
Nickel ug/L ND 5.0 01/25/17 11:33
Selenium ug/L ND 10.0 01/25/17 11:33
Silver ug/L ND 5.0 01/25/17 11:33
Thallium ug/L ND 10.0 01/25/17 11:33
Zinc ug/L ND 20.0 01/25/17 23:04
LABORATORY CONTROL SAMPLE: 1916025
Spike LCS LCS %Roc
Parameter Units Conc. Result %Rec Limits Qualifiers
Antimony ug/L 500 481 96 85-115
Arsenic ug/L 500 464 93 85-115
Beryllium ug/L 500 459 92 85-115
Cadmium ug/L 500 476 95 85-115
Calcium ug/L 5000 4910 98 85-115
Chromium ug/L 500 460 92 85-115
Copper ug/L 500 477 95 85-115
Hardness,Total(SM 2340B) ug/L 33100 30900 93 85-115
Lead ug/L 500 475 95 85-115
Magnesium ug/L 5000 4530 91 85-115
Nickel ug/L 500 468 94 85-115
Selenium ug/L 500 480 96 85-115
Silver ug/L 250 237 95 85-115
Thallium ug/L 500 473 95 85-115
Zinc ug/L 500 494 99 85-115
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 33

r
Pace Analytical Services,LLC
9800 Klncey Ave. Suite 100
aceARalytical Huntersvllle,NC 28078
www.paceiabs.com
[phone]
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1916026 1916027
MS MSD
92327014001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Antimony ug/L ND 500 500 433 460 77 82 70-130 6
Arsenic ug/L ND 500 500 416 443 83 89 70-130 6
Beryllium ug/L ND 500 500 471 468 94 94 70-130 1
Cadmium ug/L ND 500 500 474 505 94 100 70-130 6
Calcium ug/L 34.6 5000 5000 42600 41700 160 142 70-130 2 M6
mg/L
Chromium ug/L 13.6 500 500 14700 14900 228 258 70-130 1 M6
mg/L
Copper ug/L 1.9 500 500 2560 2610 126 136 70-130 2 M6
mg/L
Hardness,Total(SM 2340B) ug/L 350 33100 33100 407000 409000 175 178 70-130 0
mg/L
Lead ug/L 0.18 500 500 670 682 97 100 70-130 2
mg/L
Magnesium ug/L 63.9 5000 5000 73100 73900 184 200 70-130 1 M6
mg/L
Nickel ug/L 0.25 500 500 725 765 95 103 70-130 5
mg/L
Selenium ug/L ND 500 500 457 492 85 92 70-130 7
Silver ug/L ND 250 250 237 241 93 95 70-130 2
Thallium ug/L ND 500 500 387 398 75 77 70-130 3
Zinc ug/L 16.5 500 500 17800 18400 264 378 70-130 3 M6
mg/L
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1916028 1916029
MS MSD
92327179001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Antimony ug/L ND 500 500 480 467 96 93 70-130 3
Arsenic ug/L ND 500 500 470 460 94 92 70-130 2
Beryllium ug/L ND 500 500 490 477 98 95 70-130 3
Cadmium ug/L ND 500 500 482 468 96 94 70-130 3
Calcium ug/L 41600 5000 5000 47200 45800 111 85 70-130 3
Chromium ug/L ND 500 500 479 452 95 90 70-130 6
Copper ug/L 10.6 500 500 516 494 101 97 70-130 4
Hardness,Total(SM 234013) ug/L 151000 33100 33100 185000 178000 101 81 70-130 4
Lead ug/L ND 500 500 450 439 90 88 70-130 3
Magnesium ug/L 11500 5000 5000 16300 15400 95 78 70-130 5
Nickel ug/L 41.9 500 500 496 481 91 88 70-130 3
Selenium ug/L ND 500 500 482 469 96 94 70-130 3
Silver ug/L ND 250 250 246 236 98 94 70-130 4
Thallium ug/L ND 500 500 450 440 90 88 70-130 2
Zinc ug/L 323 500 500 793 766 94 89 70-130 4
Results presented on this page are In the unite Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 11 of 33
1

Pace Analytical Services,LLC
a 9800 Kincey Ave. Suite 100
aceAnalytical Huntersvllle,NC 28078
1 www.pecelebs.com
[phone]
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
QC Batch: 345466 Analysis Method: EPA 624
QC Batch Method: EPA 624 Analysis Description: 624 MSV
Associated Lab Samples: 92326935001
METHOD BLANK: 1916718 Matrix: Water
Associated Lab Samples: 92326935001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1,1-Trichloroethane ug/L ND 2.0 01/24/17 14:37
1,1,2,2-Tetrachloroethene ug/L ND 2.0 01/24/17 14:37
1,1,2-Trichloroethane ug/L ND 2.0 01/24/17 14:37
1,1-Dichioroethane ug/L ND 2.0 01/24/17 14:37
1,1-Dichloroethene ug/L ND 2.0 01/24/17 14:37
1,2,4-Trichlorobenzene ug/L ND 2.0 01/24/17 14:37
1,2-Dichlorobenzene ug/L ND 2.0 01/24/17 14:37
1,2-Dichioroethane ug/L ND 2.0 01/24/17 14:37
1,2-Dichloropropane ug/L ND 2.0 01/24/17 14:37
1,3-Dichlorobenzene ug/L ND 2.0 01/24/17 14:37
1,4-Dichlorobenzene ug/L ND 2.0 01/24/17 14:37
2-Chioroethylvinyl ether ug/L ND 5.0 01/24/17 14:37
Acrolein ug/L ND 5.0 01/24/17 14:37
Acrylonitrile ug/L ND 50.0 01/24/17 14:37
Benzene ug/L ND 2.0 01/24/17 14:37
Bromodichloromethane ug/L ND 2.0 01/24/17 14:37
Bromoform ug/L ND 2.0 01/24/17 14:37
Bromomethane ug/L ND 2.0 01/24/17 14:37
Carbon tetrachloride ug/L ND 2.0 01/24/17 14:37
Chlorobenzene ug/L ND 2.0 01/24/17 14:37
Chloroethane ug/L ND 2.0 01/24/17 14:37
Chloroform ug/L ND 2.0 01/24/17 14:37
Chloromethane ug/L ND 2.0 01/24/17 14:37
cis-1,3-Dichloropropene ug/L ND 2.0 01/24/17 14:37
Dibromochloromethane ug/L ND 2.0 01/24/17 14:37
Ethylbenzene ug/L ND 2.0 01/24/17 14:37
Hexachloro-1,3-butadiene ug/L ND 5.0 01/24/17 14:37
Methylene Chloride ug/L ND 2.0 01/24/17 14:37
Naphthalene ug/L ND 5.0 01/24/17 14:37
Tetrachloroethene ug/L ND 2.0 01/24/17 14:37
Toluene ug/L ND 2.0 01/24/17 14:37
trans-1,2-Dichloroethene ug/L ND 2.0 01/24/17 14:37
trans-1,3-Dichloropropene ug/L ND 2.0 01/24/17 14:37
Trichloroethene ug/L ND 2.0 01/24/17 14:37
Trichlorofluoromethane ug/L ND 2.0 01/24/17 14:37
Vinyl chloride ug/L ND 2.0 01/24/17 14:37
1,2-Dichloroethane-d4(S) % 90 70-130 01/24/17 14:37
4-Bromofluorobenzene(S) % 94 70-130 01/24/17 14:37
Toluene-d8(S) % 108 70-130 01/24/17 14:37
Results presented on this page are in the units Indicated by the"Units"column except where en alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 12 of 33

Pace Analytical Services,LLC
aceAnalytical a 9800 Kinney Ave. Suite 100
I /eHuntersvllle,NC 28078
wwwpaccelabs.com
[phone]
i
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
LABORATORY CONTROL SAMPLE: 1916719
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,1,1-Trichloroethane ug/L 20 20.7 104 52-162
1,1,2,2-Tetrachloroethane ug/L 20 17.4 87 46-157
1,1,2-Trichloroethane ug/L 20 20.5 102 52-150
1,1-Dichloroethane ug/L 20 19.8 99 59-155
1,1-Dichloroethene ug/L 20 21.8 109 1-234
1,2,4-Trichlorobenzene ug/L 20 19.9 99 70-130
1,2-Dichlorobenzene ug/L 20 18.7 94 18-190
1,2-Dichioroethane ug/L 20 19.3 97 49-155
1,2-Dichloropropane ug/L 20 19.8 99 1-210
1,3-Dichlorobenzene ug/L 20 18.8 94 59-156
1,4-Dichlorobenzene ug/L 20 19.2 96 18-190
2-Chloroethylvinyl ether ug/L 40 37.1 93 1-305
Acrolein ug/L 100 105 105 15-152
Acrylonitrile ug/L 100 99.2 99 75-132
Benzene ug/L 20 20.3 101 37-151
Bromodichloromethane ug/L 20 20.4 102 35-155
Bromoform ug/L 20 18.3 92 45-169
Bromomethane ug/L 20 20.5 103 1-242
Carbon tetrachloride ug/L 20 20.4 102 70-140 1
Chlorobenzene ug/L 20 19.2 96 37-160
Chloroethane ug/L 20 22.2 111 14-230
Chloroform ug/L 20 19.9 99 51-138
Chloromethane ug/L 20 20.8 104 1-273
cis-1,3-Dichloropropene ug/L 20 20.4 102 1-227
Dibromochloromethane ug/L 20 19.3 97 53-149
Ethylbenzene ug/L 20 18.8 94 37-162
Hexachloro-1,3-butadiene ug/L 20 22.1 111 70-130
Methylene Chloride ug/L 20 18.7 93 1-221
Naphthalene ug/L 20 20.3 101 70-130
Tetrachloroethene ug/L 20 18.9 94 64-148
Toluene ug/L 20 19.2 96 47-150
trans-1,2-Dichloroethene ug/L 20 20.4 102 54-156
trans-1,3-Dichloropropene ug/L 20 19.3 96 17-183
Trichloroethene ug/L 20 19.8 99 71-157
Trichlorofluoromethane ug/L 20 21.6 108 17-181
Vinyl chloride ug/L 20 16.8 84 1-251
1,2-Dichloroethane-d4(S) % 98 70-130
4-Bromofluorobenzene(S) % 97 70-130
Toluene-d8(S) % 99 70-130
MATRIX SPIKE SAMPLE: 1916721
92327279001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
1,1,1-Trichloroethane ug/L ND 20 24.3 121 46-171
1,1,2,2-Tetrachloroethane ug/L ND 20 20.6 103 73-159
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 13 of 33

Pace Analytical Services,LLC
s
211(ace 9800Huntersv lle,C'28078
• Analytical Kincey Ave.
ww .pecelabs.com
[phone]
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
MATRIX SPIKE SAMPLE: 1916721
92327279001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
1,1,2-Trichloroethane ug/L ND 20 23.6 118 64-152
1,1-Dichloroethane ug/L ND 20 23.2 116 43-172
1,1-Dichloroethene ug/L ND 20 25.5 128 48-189
1,2,4-Trichlorobenzene ug/L ND 20 21.2 106 70-130
1,2-Dichlorobenzene ug/L ND 20 21.0 105 54-154
1,2-Dichloroethane ug/L ND 20 22.4 111 42-171
1,2-Dichloropropane ug/L ND 20 23.3 117 55-157
1,3-Dichlorobenzene ug/L ND 20 20.5 102 57-148
1,4-Dichlorobenzene ug/L ND 20 20.3 102 58-149
2-Chloroethylvinyl ether ug/L ND 40 ND 0 70-130 J(M1),c2
Acrolein ug/L ND 100 106 106 70-130
Acrylonitrile ug/L ND 100 115 115 70-130
Benzene ug/L ND 20 23.8 119 54-163
Bromodichloromethane ug/L ND 20 22.5 113 56-152
Bromoform ug/L ND 20 20.3 101 53-151
Bromomethane ug/L ND 20 16.2 81 10-200
Carbon tetrachloride ug/L ND 20 23.3 116 41-175
Chlorobenzene ug/L ND 20 22.2 111 67-152
Chloroethane ug/L ND 20 24.4 122 23-200
Chloroform ug/L ND 20 22.4 112 51-166
Chloromethane ug/L ND 20 20.8 104 40-175
cis-1,3-Dichloropropene ug/L ND 20 22.0 110 38-146
Dibromochloromethane ug/L ND 20 21.5 108 65-144
Ethylbenzene ug/L ND 20 22.3 111 57-152
Hexachloro-1,3-butadiene ug/L ND 20 16.9 84 70-130
Methylene Chloride ug/L ND 20 20.1 92 40-167
Naphthalene ug/L ND 20 20.0 100 70-130
Tetrachloroethene ug/L ND 20 21.6 108 59-155
Toluene ug/L ND 20 23.0 115 47-162
trans-1,2-Dichloroethene ug/L ND 20 25.2 126 47-178
trans-1,3-Dichloropropene ug/L ND 20 21.8 109 39-148
Trichloroethene ug/L ND 20 24.1 120 60-153
Trichlorofluoromethane ug/L ND 20 25.5 128 42-199
Vinyl chloride ug/L ND 20 19.4 97 46-176
1,2-Dichloroethane-d4(S) e/u 104 70-130
4-Bromofluorobenzene(S) % 101 70-130
Toluene-d8(S) % 99 70-130
SAMPLE DUPLICATE: 1916720
92327264001 Dup
Parameter Units Result Result RPD Qualifiers
1,1,1-Trichloroethane ug/L ND ND
1,1,2,2-Tetrachloroethane ug/L ND ND
1,1,2-Trichloroethane ug/L ND ND
1,1-Dichloroethane ug/L ND ND
Results presented on this page are In the unite Indicated by the"Unite"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 14 of 33

Pace Analytical Services,LLC
/1.2ceAnalytical a 9800 Klncey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com
[phone]
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
SAMPLE DUPLICATE: 1916720
92327264001 Dup
Parameter Units Result Result RPD Qualifiers
1,1-Dichloroethene ug/L ND ND
1,2,4-Trichlorobenzene ug/L ND ND
1,2-Dichlorobenzene ug/L ND ND
1,2-Dichloroethane ug/L ND ND
1,2-Dichloropropane ug/L ND ND
1,3-Dichlorobenzene ug/L ND ND
1,4-Dichlorobenzene ug/L ND ND
2-Chloroethylvinyl ether ug/L ND ND
Acrolein ug/L ND ND
Acrylonitrile ug/L ND ND
Benzene ug/L ND ND
Bromodichloromethane ug/L ND ND
Bromoform ug/L ND ND
Bromomethane ug/L ND ND
Carbon tetrachloride ug/L ND ND
Chlorobenzene ug/L ND ND
Chloroethane ug/L ND ND
Chloroform ug/L ND ND
Chloromethane ug/L ND ND
cis-1,3-Dichloropropene ug/L ND ND
Dibromochloromethane ug/L ND ND
Ethylbenzene ug/L ND ND
Hexachloro-1,3-butadiene ug/L ND ND
Methylene Chloride ug/L ND ND
Naphthalene ug/L ND ND
Tetrachloroethene ug/L ND ND
Toluene ug/L ND ND
trans-1,2-Dichloroethene ug/L ND ND
trans-1,3-Dichloropropene ug/L ND ND
Trichloroethene ug/L ND ND
Trichlorofluoromethane ug/L ND ND
Vinyl chloride ug/L ND ND
1,2-Dichloroethane-d4(S) % 92 92 0
4-Bromofluorobenzene(S) % 95 98 2
Toluene-d8(S) % 110 110 0
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 15 of 33

Pace Analytical Services,LLC
a
•
aceAnalytical 9800 Klncey Aye, Suite 100
Huntersville,NC 28078
www.pecNeOs.corn [phone]
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
QC Batch: 345381 Analysis Method: EPA 625
QC Batch Method: EPA 625 Analysis Description: 625 MSS
Associated Lab Samples: 92326935001
METHOD BLANK: 1916140 Matrix: Water
Associated Lab Samples: 92326935001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,2-Dichlorobenzene ug/L ND 5.0 01/25/17 10:26
1,2-Diphenylhydrazine ug/L ND 5.0 01/25/17 10:26
1,3-Dichlorobenzene ug/L ND 5.0 01/25/17 10:26
1,4-Dichlorobenzene ug/L ND 5.0 01/25/17 10:26
2,4,6-Trichlorophenol ug/L ND 10.0 01/25/17 10:26
2,4-Dichlorophenol ug/L ND 5.0 01/25/17 10:26
2,4-Dimethylphenol ug/L ND 10.0 01/25/17 10:26
2,4-Dinitrophenol ug/L ND 50.0 01/25/17 10:26
2,4-Dinitrotoluene ug/L ND 5.0 01/25/17 10:26
2,6-Dinitrotoluene ug/L ND 5.0 01/25/17 10:26
2-Chloronaphthalene ug/L ND 5.0 01/25/17 10:26
2-Chlorophenol ug/L ND 5.0 01/25/17 10:26
2-Nitrophenol ug/L ND 5.0 01/25/17 10:26
3,3'-Dichlorobenzidine ug/L ND 25.0 01/25/17 10:26
4,6-Dinitro-2-methylphenol ug/L ND 20.0 01/25/17 10:26
4-Bromophenylphenyl ether ug/L ND 5.0 01/25/17 10:26
4-Chloro-3-methylphenol ug/L ND 5.0 01/25/17 10:26
4-Chlorophenylphenyl ether ug/L ND 5.0 01/25/17 10:26
4-Nitrophenol ug/L ND 50.0 01/25/17 10:26
Acenaphthene ug/L ND 5.0 01/25/17 10:26
Acenaphthylene ug/L ND 5.0 01/25/17 10:26
Anthracene ug/L ND 5.0 01/25/17 10:26
Benzo(a)anthracene ug/L ND 5.0 01/25/17 10:26
Benzo(a)pyrene ug/L ND 5.0 01/25/17 10:26
Benzo(b)fluoranthene ug/L ND 5.0 01/25/17 10:26
Benzo(g,h,i)perylene ug/L ND 5.0 01/25/17 10:26
Benzo(k)fluoranthene ug/L ND 5.0 01/25/17 10:26 1
bis(2-Chloroethoxy)methane ug/L ND 10.0 01/25/17 10:26
bis(2-Chloroethyl)ether ug/L ND 5.0 01/25/17 10:26
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 01/25/17 10:26
Butylbenzylphthalate ug/L ND 5.0 01/25/17 10:26
Chrysene ug/L ND 5.0 01/25/17 10:26
Di-n-butylphthalate ug/L ND 5.0 01/25/17 10:26
Di-n-octylphthalate ug/L ND 5.0 01/25/17 10:26
Dibenz(a,h)anthracene ug/L ND 5.0 01/25/17 10:26
Diethylphthalate ug/L ND 5.0 01/25/17 10:26
Dimethylphthalate ug/L ND 5.0 01/25/17 10:26
Fluoranthene ug/L ND 5.0 01/25/17 10:26
Fluorene ug/L ND 5.0 01/25/17 10:26
Hexachlorobenzene ug/L ND 5.0 01/25/17 10:26
Hexachlorocyciopentadiene ug/L ND 10.0 01/25/17 10:26
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 16 of 33

Pace Analytical Services,LLC
aceAnalytical•
® 9800 Kincey Ave. Suite 100
Huntersville.NC 28078
www.pecslabs.com
1 [phone]
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
METHOD BLANK: 1916140 Matrix: Water
Associated Lab Samples: 92326935001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Hexachloroethane ug/L ND 5.0 01/25/17 10:26
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 01/25/17 10:26
Isophorone ug/L ND 10.0 01/25/17 10:26
N-Nitroso-di-n-propylamine ug/L ND 5.0 01/25/17 10:26
N-Nitrosodimethylamine ug/L ND 5.0 01/25/17 10:26
N-Nitrosodiphenylamine ug/L ND 10.0 01/25/17 10:26
Naphthalene ug/L ND 5.0 01/25/17 10:26
Nitrobenzene ug/L ND 5.0 01/25/17 10:26
Pentachlorophenol ug/L ND 10.0 01/25/17 10:26
Phenanthrene ug/L ND 5.0 01/25/17 10:26
Phenol ug/L ND 5.0 01/25/17 10:26
Pyrene ug/L ND 5.0 01/25/17 10:26
2,4,6-Tribromophenol(S) % 82 10-137 01/25/17 10:26
2-Fluorobiphenyl(S) % 79 15-120 01/25/17 10:26
2-Fluorophenol(S) % 37 10-120 01/25/17 10:26
Nitrobenzene-d5(S) % 78 10-120 01/25/17 10:26
Phenol-d6(S) % 28 10-120 01/25/17 10:26
Terphenyl-d14(S) % 100 11-131 01/25/17 10:26
LABORATORY CONTROL SAMPLE: 1916141
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,2-Dichlorobenzene ug/L 50 28.7 57 32-129
1,2-Diphenylhydrazine ug/L 50 41.1 82 25-150
1,3-Dichlorobenzene ug/L 50 28.0 56 1-172
1,4-Dichlorobenzene ug/L 50 26.8 54 20-124
1 2,4,6-Trichlorophenol ug/L 50 47.8 95 37-144
2,4-Dichlorophenol ug/L 50 42.2 84 1-191
2,4-Dimethylphenol ug/L 50 43.0 86 32-119
2,4-Dinitrophenal ug/L 250 170 68 1-181
2,4-Dinitrotoluene ug/L 50 40.9 82 39-139
2,6-Dlnitrotoluene ug/L 50 40.0 80 50-158
2-Chloronaphthalene ug/L 50 39.1 78 60-118
2-Chlorophenol ug/L 50 34.5 69 23-134
2-Nitrophenol ug/L 50 40.7 81 29-182
3,3'-Dichlorobenzidine ug/L 100 77.5 78 1-262
4,6-Dinitro-2-methylphenol ug/L 100 88.1 88 1-181
4-Bromophenylphenyl ether ug/L 50 41.4 83 53-127
4-Chloro-3-methylphenol ug/L 100 86.6 87 22-147
4-Chlorophenylphenyl ether ug/L 50 41.1 82 25-158
4-Nitrophenol ug/L 250 100 40 1-132
Acenaphthene ug/L 50 39.5 79 47-145
Acenaphthylene ug/L 50 42.1 84 33-145
Anthracene ug/L 50 38.5 77 1-166
Results presented on this page are In the units indicated by the'Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 17 of 33
i

Pace Analytical Services,LLC
/�� t+ 9800 Kincey Ave. Suite 100
>4
aceAlr ialytical Huntersville,NC 28078
i www.pacalaba.com [phone]
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
LABORATORY CONTROL SAMPLE: 1916141
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Benzo(a)anthracene ug/L 50 42.0 84 33-143
Benzo(a)pyrene ug/L 50 44.8 90 17-163
Benzo(b)fluoranthene ug/L 50 43.8 88 24-159
Benzo(g,h,i)perylene ug/L 50 43.3 87 1-219
Benzo(k)fluoranthene ug/L 50 46.2 92 11-162
bis(2-Chloroethoxy)methane ug/L 50 37.7 75 33-184
bis(2-Chloroethyl)ether ug/L 50 33.7 67 12-158
bis(2-Ethylhexyl)phthalate ug/L 50 45.9 92 8-158
Butylbenzylphthalate ug/L 50 45.0 90 1-152
Chrysene ug/L 50 41.3 83 17-168
Di-n-butylphthalate ug/L 50 45.5 91 1-118
Di-n-octylphthalate ug/L 50 45.2 90 4-146
Dibenz(a,h)anthracene ug/L 50 45.7 91 1-227
Diethylphthalate ug/L 50 46.4 93 1-114
Dimethylphthalate ug/L 50 42.0 84 1-112
Fluoranthene ug/L 50 43.9 88 26-137
Fluorene ug/L 50 41.6 83 59-121
Hexachlorobenzene ug/L 50 43.5 87 1-152
Hexachlorocyclopentadiene ug/L 50 43.2 86 25-150
Hexachloroethane ug/L 50 27.7 55 40-113
Indeno(1,2,3-cd)pyrene ug/L 50 46.2 92 1-171
Isophorone ug/L 50 40.7 81 21-196
N-Nitroso-di-n-propylamine ug/L 50 37.8 76 1-230
N-Nitrosodimethylamine ug/L 50 25.8 52 25-150
N-Nitrosodiphenylamine ug/L 50 40.1 80 25-150
Naphthalene ug/L 50 35.3 71 21-133
Nitrobenzene ug/L 50 42.9 86 35-180
Pentachlorophenol ug/L 100 107 107 14-176
Phenanthrene ug/L 50 38.4 77 54-120
Phenol ug/L 50 16.9 34 5-112
Pyrene ug/L 50 41.8 84 52-115
2,4,6-Tribromophenol(S) % 92 10-137
2-Fluorobiphenyl(S) % 83 15-120
2-Fluorophenol(S) % 41 10-120
Nitrobenzene-d5(S) % 85 10-120
Phenol-d6(S) % 30 10-120
Terphenyl-d14(S) % 85 11-131
MATRIX SPIKE SAMPLE: 1916142
92326918001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
1,2-Dichlorobenzene ug/L ND 50 27.4 55 32-129
1,2-Diphenylhydrazine ug/L ND 50 40.5 81 25-150
1,3-Dichlorobenzene ug/L ND 50 27.8 56 1-172
1,4-Dichlorobenzene ug/L ND 50 26.2 52 20-124
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 18 of 33

Pace Analytical Services,LLC
s 9800 Kincey Ave. Suite 100
aceAnaiytical Huntersvllle.NC 28078
waWpacelabs.corn [phone]
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
MATRIX SPIKE SAMPLE: 1916142
' 92326918001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
2,4,6-Trichlorophenol ug/L ND 50 47.0 94 37-144
2,4-Dichlorophenol ug/L ND 50 42.1 84 1-191
2,4-Dimethyiphenol ug/L ND 50 43,2 86 32-119
2,4-Dinitrophenol ug/L ND 250 137 55 1-181
2,4-Dinitrotoluene ug/L ND 50 42.4 85 39-139
2,6-Dinitrotoluene ug/L ND 50 40.2 80 50-158
2-Chloronaphthalene ug/L ND 50 39.3 79 60-118
2-Chlorophenol ug/L ND 50 31.6 63 23-134
2-Nitrophenoi ug/L ND 50 39.5 79 29-182
3,3'-Dichlorobenzidine ug/L ND 100 75.1 75 1-262
4,6-Dinitro-2-methylphenol ug/L ND 100 83.9 84 1-181
4-Bromophenytphenyl ether ug/L ND 50 40.4 81 53-127
4-Chloro-3-methylphenol ug/L ND 100 91.3 91 22-147
4-Chlorophenylphenyl ether ug/L ND 50 42.3 85 25-158
4-Nitrophenol ug/L ND 250 97.2 39 1-132
Acenaphthene ug/L ND 50 39.0 78 47-145
Acenaphthylene ug/L ND 50 42.7 85 33-145
Anthracene ug/L ND 50 37.5 75 1-166
Benzo(a)anthracene ug/L ND 50 40.6 81 33-143
Benzo(a)pyrene ug/L ND 50 41.5 83 17-163
Benzo(b)fluoranthene ug/L ND 50 41.7 83 24-159
Benzo(g,h,i)perylene ug/L ND 50 43.2 86 1-219
Benzo(k)fluoranthene ug/L ND 50 44.2 88 11-162
bis(2-Chloroethoxy)methane ug/L ND 50 37.4 75 33-184
bis(2-Chloroethyl)ether ug/L ND 50 30.9 62 12-158
bis(2-Ethylhexyl)phthalate ug/L ND 50 44.5 89 8-158
Butylbenzylphthalate ug/L ND 50 43.1 86 1-152
Chrysene ug/L ND 50 39.2 78 17-168
Di-n-butylphthalate ug/L ND 50 46.3 93 1-118
Di-n-octylphthalate ug/L ND 50 43.4 87 4-146
Dibenz(a,h)anthracene ug/L ND 50 44.0 88 1-227
Diethylphthalate ug/L ND 50 48.7 97 1-114
Dimethylphthalate ug/L ND 50 43.7 87 1-112
Fluoranthene ug/L ND 50 44.8 90 26-137
Fluorene ug/L ND 50 44.1 88 59-121
Hexachlorobenzene ug/L ND 50 42.7 85 1-152
Hexachlorocydopentadiene ug/L ND 50 37.8 76 25-150
Hexachloroethane ug/L ND 50 27.2 54 40-113
Indeno(1,2,3-cd)pyrene ug/L ND 50 44.5 89 1-171
Isophorone ug/L ND 50 42.1 84 21-196
N-Nitroso-di-n-propylamine ug/L ND 50 36.3 73 1-230
N-Nitrosodimethylamine ug/L ND 50 21.3 43 25-150
N-Nitrosodiphenylamine ug/L ND 50 39.1 78 25-150
Naphthalene ug/L ND 50 37.5 75 21-133
Nitrobenzene ug/L ND 50 41.7 83 35-180 1
Pentachlorophenol ug/L ND 100 93.4 93 14-176
Phenanthrene ug/L ND 50 38.7 77 54-120
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 19 of 33

Pace Analytical Services,LLC
a
• ace Analytical 9800 KinceyAve. Suite 100
Huntersville,NC 28078
wwrv.pacelabs.cam [phone]
r
I
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
MATRIX SPIKE SAMPLE: 1916142
92326918001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Phenol ug/L ND 50 14.4 29 5-112
Pyrene ug/L ND 50 39.7 79 52-115
2,4,6-Tribromophenol(S) % 91 10-137
2-Fluorobiphenyl(S) % 81 15-120
2-Fluorophenol(S) % 34 10-120
Nitrobenzene-d5(S) % 83 10-120
Phenol-d6(S) % 25 10-120
Terphenyl-d14(S) % 81 11-131
SAMPLE DUPLICATE: 1916143
92326935001 Dup
Parameter Units Result Result RPD Qualifiers
1,2-Dichlorobenzene ug/L ND ND
1,2-Diphenylhydrazine ug/L ND ND
1,3-Dichlorobenzene ug/L ND ND
1,4-Dichlorobenzene ug/L ND ND
2,4,6-Trichlorophenol ug/L ND ND
2,4-Dichlorophenol ug/L ND ND
2,4-Dimethylphenol ug/L ND ND
2,4-Dinitrophenol ug/L ND ND
2,4-Dlnitrotoluene ug/L ND ND
2,6-Dinitrotoluene ug/L ND ND
2-Chloronaphthalene ug/L ND ND
2-Chlorophenol ug/L ND ND
2-Nitrophenol ug/L ND ND
3,3'-Dichlorobenzidine uglL ND ND
4,6-Dinitro-2-methylphenol ug/L ND ND
4-Bromophenylphenyl ether ug/L ND ND
4-Chloro-3-methylphenol ug/L ND ND
4-Chlorophenylphenyl ether ug/L ND ND
4-Nitrophenol ug/L ND ND
Acenaphthene ug/L ND ND
Acenaphthylene ug/L ND ND
Anthracene ug/L ND ND
Benzo(a)anthracene ug/L ND ND
Benzo(a)pyrene ug/L ND ND
Benzo(b)fluoranthene ug/L ND ND
1 Benzo(g,h,i)perylene ug/L ND ND
Benzo(k)fluoranthene ug/L ND ND
bis(2-Chloroethoxy)methane ug/L ND ND
bis(2-Chloroethyl)ether ug/L ND ND
bis(2-Ethylhexyl)phthalate ug/L ND ND
Butylbenzylphthalate ug/L ND ND
Chrysene ug/L ND ND
Di-n-butylphthalate ug/L NO ND
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 20 of 33

Pace Analytical Services,LLC
e 9800 Kincey Ave. Suite 100
aceAnalylical Huntersville,NC 28078
www.pacelabs.com
[phone]
1
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
SAMPLE DUPLICATE: 1916143
92326935001 Dup
Parameter Units Result Result RPD Qualifiers
Di-n-octylphthalate ug/L ND ND
Dibenz(a,h)anthracene ug/L ND ND
Diethylphthalate ug/L ND ND
Dimethylphthalate ug/L ND ND
Fluoranthene ug/L ND ND
Fluorene ug/L ND ND
Hexachlorobenzene ug/L ND ND
Hexachlorocyclopentadiene ug/L ND ND
Hexachioroethane ug/L ND ND
Indeno(1,2,3-cd)pyrene ug/L ND ND
Isophorone ug/L ND ND
N-Nitroso-di-n-propylamine ug/L ND ND
N-Nitrosodimethylamine ug/L ND ND
N-Nitrosodiphenylamine ug/L ND ND
Naphthalene ug/L ND ND
Nitrobenzene ug/L ND ND
Pentachlorophenol ug/L ND ND
Phenanthrene ug/L ND ND 1
Phenol ug/L ND ND
Pyrene ug/L ND ND
2,4,6-Tribromophenol(S) % 84 78 7
2-Fluorobiphenyl(S) % 73 69 7
2-Fluorophenol(S) % 41 36 14
Nitrobenzene-d5(S) % 79 70 12
Phenol-d6(S) % 31 25 19
Terphenyl-d14(S) % 87 84 4
Results presented on this page are In the units Indicated by the"Units"column except Where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 21 of 33

Pace Analytical Services,LLC
e 9800 Klncey Ave. Suite 100
aceAnalyticai Huntersville,NC 28078
www.pecelebs.com [phone]
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
QC Batch: 345214 Analysis Method: SM 2540C
QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 92326935001
METHOD BLANK: 1915424 Matrix: Water
Associated Lab Samples: 92326935001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 01/23/17 11:40
LABORATORY CONTROL SAMPLE: 1915425
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 226 90 90-110
SAMPLE DUPLICATE: 1915426
92326728001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 518 542 5
SAMPLE DUPLICATE: 1915427
92326728017 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 179 173 3
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 22 of 33

Pace Analytical Services,LLC
® 9800 Klncey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
r www.pecefebs.com [phone]
I
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
QC Batch: 346115 Analysis Method: EPA 350.1 1993 Rev 2.0
QC Batch Method: EPA 350.1 1993 Rev 2.0 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92326935001
METHOD BLANK: 1920037 Matrix: Water
Associated Lab Samples: 92326935001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Ammonia mg/L ND 0.10 01/30/17 16:49
LABORATORY CONTROL SAMPLE: 1920038
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 5.0 100 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1920039 1920040
MS MSD
92327553001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L ND 5 5 5.0 5.0 99 99 90-110 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1920041 1920042
MS MSD
92327579001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L 3.6 5 5 8.2 8.3 93 94 90-110 0
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 23 of 33

•
Pace Analytical Services,LLC
• aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
wwwpecelebe.com
[phone]
QUALITY CONTROL DATA
' Project: PPA 1/18/17
Pace Project No.: 92326935
QC Batch: 345526 Analysis Method: EPA 351.2
QC Batch Method: EPA 351.2 Analysis Description: 351.2 TKN
Associated Lab Samples: 92326935001
METHOD BLANK: 1916972 Matrix: Water
Associated Lab Samples: 92326935001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Kjeldahl,Total mg/L ND 0.50 01/27/17 23:24
LABORATORY CONTROL SAMPLE: 1916973
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers 1
' Nitrogen,Kjeldahl,Total mg/L 10 10.1 101 90-110
i
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1916974 1916975
MS MSD
92327290001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual 1
Nitrogen,Kjeldahl,Total mg/L 2.6 10 10 11.4 11.5 88 89 90-.110 1 J(M1)
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1916976 1916977
MS MSD
92327364002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Kjeldahl,Total mg/L 0.52 10 10 9.6 9.6 91 91 90-110 1
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 24 of 33

Pace Analytical Services,LLC
a 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
wwwpecelabs.mm
[phone]
I
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
QC Batch: 345653 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate+Nitrite,preserved
Associated Lab Samples: 92326935001
METHOD BLANK: 1917632 Matrix: Water
Associated Lab Samples: 92326935001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,NO2 plus NO3 mg/L ND 0.020 01/25/17 19:12
LABORATORY CONTROL SAMPLE: 1917633
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,NO2 plus NO3 mg/L 2.5 2.7 107 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1917634 1917635
MS MSD
92327041008 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,NO2 plus NO3 mg/L 0.31 2.5 2.5 2.7 2.7 95 95 75-125 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1917636 1917637
MS MSD
92327166011 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,NO2 plus NO3 mg/L 0.37 2.5 2.5 2.8 2.8 97 98 75-125 0
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 25 of 33

Pace Analytical Services,LLC
a 9800 KlnceyAve. Suite 100
aceAnalytical Huntersville,NC 28078
wwwpacelabs.com
[phone]
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
QC Batch: 345317 Analysis Method: EPA 365.1
QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus,Total
Associated Lab Samples: 92326935001
METHOD BLANK: 1915944 Matrix: Water
Associated Lab Samples: 92326935001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 01/24/17 19:47
LABORATORY CONTROL SAMPLE: 1915945
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.6 106 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1915946 1915947
MS MSD
92327169001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus mg/L 28.0 2.5 2.5 29.6 29.3 61 53 90-110 1 M6
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1915948 1915949
MS MSD
92327171001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus mg/L 11.6 2.5 2.5 16.1 15.5 180 155 90-110 4 J(M1)
Results presented an this page are in the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 26 of 33

Pace Analytical Services,LLC
® 9800 Kincey Ave. Suite 100
aceAnalyticai Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
QC Batch: 345588 Analysis Method: EPA 420.4
QC Batch Method: EPA 420.4 Analysis Description: 420.4 Phenolics
Associated Lab Samples: 92326935001
METHOD BLANK: 1917236 Matrix: Water
Associated Lab Samples: 92326935001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phenol mg/L ND 0.010 01/26/17 13:27
LABORATORY CONTROL SAMPLE: 1917237
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phenol mg/L .05 0.050 100 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1917238 1917239
MS MSD
92326706002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phenol mg/L 0.043 .05 .05 0.18 0.098 273 110 90-110 59 J(M1),J(R1)
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1917240 1917241
MS MSD
92327047001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phenol mg/L 0.025 .05 .05 0.070 0.067 90 84 90-110 4 J(M1)
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 27 of 33

Pace Analytical Services,LLC
a/6 9600 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www pacelebs.com
[phone]
i
QUALITY CONTROL DATA
Project: PPA 1/18/17
Pace Project No.: 92326935
QC Batch: 346220 Analysis Method: SM 4500-CN-E
QC Batch Method: SM 4500-CN-E Analysis Description: 4500CNE Cyanide,Total
Associated Lab Samples: 92326935001
METHOD BLANK: 1920738 Matrix: Water
Associated Lab Samples: 92326935001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Cyanide mg/L ND 0.0080 01/31/17 16:33
LABORATORY CONTROL SAMPLE: 1920739
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Cyanide mg/L .1 0.088 88 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1920740 1920741
MS MSD
92327429001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Cyanide mg/L ND .1 .1 0.093 0.089 91 88 75-125 4
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1920742 1920743
MS MSD
92326811002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Cyanide mg/L ND ,1 .'I 0.10 0.10 101 102 73-125 1
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 28 of 33

Pace Analytical Services,LLC
/4te 100
aceAnalytical 9800 Kincey Ave.Hunteraville,NCf28078
wwwpacelabs.corn [phone]
QUALIFIERS
Project: PPA 1/18/17
Pace Project No.: 92326935
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 Is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services-Asheville
PASI-C Pace Analytical Services-Charlotte
ANALYTE QUALIFIERS
The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.
J(M1) Estimated Value.Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)
recovery.
J(R1) Estimated Value.RPD value was outside control limits.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
c2 Acid preservation may not be appropriate for the analysis of 2-Chloroethylvinyl ether.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 29 of 33

Pace Analytical Services,LLC
9800 KinceyAve. Suite 100
.,?
aceAnalytical Huntersville,NC 28078
www.pacelobs.zom [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: PPA 1/18/17
Pace Project No: 92326935
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92326935001 Wastewater Effluent EPA 1664B 346632
92326935001 Wastewater Effluent EPA 200.7 345331 EPA 200.7 345518
92326935001 Wastewater Effluent EPA 1631E 345461 EPA 1631E 345462
92326935002 Field Blank Wastewater Eff. EPA 1631E 345461 EPA 1631E 345462
92326935001 Wastewater Effluent EPA 625 345381 EPA 625 345564
92326935001 Wastewater Effluent EPA 624 345466
92326935001 Wastewater Effluent SM 2540C 345214
92326935001 Wastewater Effluent EPA 350.1 1993 Rev 2.0 346115
92326935001 Wastewater Effluent EPA 351.2 345526
92326935001 Wastewater Effluent EPA 353.2 345653
92326935001 Wastewater Effluent EPA 365.1 345317
92326935001 Wastewater Effluent EPA 420.4 345588
92326935001 Wastewater Effluent SM 4500-CN-E 346220
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:02/02/2017 03:52 PM without the written consent of Pace Analytical Services,LLC. Page 30 of 33

/f ur+c/via/ytIUQi .wqurrron U.o e • s » •a •>�i;•..
i . _�.i Pa e1of2 kt.-
•
/ focutnentN.,(;j,! i• •. k Issuing Authority: . ',4.
F-CAR-CS-0B3;R i4'.-: . .: . Pace Quality Office__
Laboratory receiving samples:
t
Asheville❑ Eden Greenwood }:�' .
ood 0 Huntel3vlge l� s• : .b .Adectoulcsultie •z_
•',Samip•gliBR)i'itlnr}•1 r. ITT^r- —.
. •�«,:. Y'-��:�_ �:� WO## 92326935 -
•
Coarser: Fed�
❑Commercial UPS . USPS ❑ta lent
Other:
I
�92326935 1�11 III
Il 11 III II III
N .
�,�atodySea'Present? ❑Yes �o seals Intact? C3Yes No ,Q
�.• Date/InittaLs Person£�arntning contertu��7—4 t�
PeddMgMaterial: ❑Bubble Wrap Lid-Bubble Bags ' ,. • I�
7herrnometer: s. ❑None �pt}ar.
,c.i. .
IRGun ID: .zS•3¢'Q.,2_ •TypOofkw • et OBJuo None Demotes on ice,coolingprocesshashegiip•,.••.
Correction Iractars�fd•S' COOter.Temp Corrected•(•C); '.Z
Temp should be.above freezl g to b•C 9iologigl Thule Fro><6n? Dyes . (]No Qhtl '
USDA Regulated Soli(water sample)
Rldsampies'or - -fn a quarantine zone within the United Staiea;Gi,NY,orSC.(dredc maps)? Old samplesodglnpte'froryta foreleg source antematio• 'I es G a • . • Ncludh8 FLaViali and Puerto Rico)?a Yes jr,' '.'' •.,z•t-•i
CoininorKe(DipTePlncyl •
Chain of Custody Present? • O -
• _� <i,
t�r4s- No A •1 • • r'.. ,:11
$imples"Ardved'withln Nold•Time? P ei'• v III No s N A �f, ..•##.!
ShortHotdTitneMe(yst (flhr.)? i! �::.:• i
ttushiuin Areend Twit Re�aested?
Sufficteiit Volumes 4 q
E:1Na' 'QWA. s 1
CAft'.t.contalners Used? No DOA 6:
dace Containers Used? • • , >r:
as QNo QN/A
Contain
` ers Intact? .r-FNo, •ON/A 'Ti ' ' 1
SaM las Field Filtered? trS . �-^ z
-( Yas .•i4No . Eff & NonIf samentIs vislblo In the dissolved container
.S it`Ple Cabals Match CQC? Ejfea (JNo ••QN/A 9• • •
''-likludesbatefFTmeilDfMalysls Matrix. " • • •�`
•it Space iri VOA Vlals(2S•6rpro)? , , Yes'' Jo' NIA Kt •
L
•
'i.. Present? CrYes QNo ( N/A 1L •
•Trip FllankkCustody Seals Present?. ...II aka • QNq ON/A _ e
• ' CLIENT NOTIFICATION/RPSCLUTION" • Feld Data Required? Dyes ,QNo . • ••:::',--1
•
•
• Person corftacted: - • bate/nine: •Comments/sample • i
,
i
i
' i
1
•
• •prolect Man eget SCURF Review: Date• I/l !l�7
I
• •ProIect:Mllanager SRF AevieVr: Date: f 1�9 111 •
. .
IAft�ttiiever•therelsildlscepaecYsslTestleoNdith orpq�.cDmplleet4.samples,acopyofthlsformuhyes�ttothettorth Rle
• „oh
•'.'_y„ye�.;."�hOQ(t�j..;_pt �%7':'� '�t�`''�=��• + '. .• ° DF1iNR OertltFation't7ff1°e(La •" •Y' •
�•o}!•, '�e-.�°4�y, ►•.W�e.n MrMI.:^J'6'ifit.M^\.. " jr"':.•erFQit.�f:.•:,i'..,.• .
.:i:•.a!'e`...e: kttti•M:V4..,VsKi riaAy:,.}. ..,. t..,.».eSS31LiL.!.i<4%,tti,yMt'.r•vr.• ,'J,........ - • Bi'I.Ot3

•
. .
•
' .
—
. .
•
•
• . ; ::: _ ...i at tn 4, 144 ta Ir...
:.,c,•:• :,- -.•::,
a < g
t:11,...cl•-. .,.. '
?"."Fr..ti;i•• .• , ': 5 .
BP411.1-1.25 Mastic UnpreseNed(N/A)(CI-) $ 44 9.• tb,
... .A„ :-.1.,i' :*:: • . • : .
- 5 ,
B1130-250 rra.Mak tlaprierweci(WA) 0 IX z
...
0.
.;4"'<'is•-‘::*.:
.•
0 as 01
• - .
--.•,'4E):.;.-i• • • ' . .
•
=• ;;-
.., . .
: -BP2U-800 mt Plastk Unpreserved(N/A) 0
a's Ct•
j • .,
•
-
. -
•
• •• . ..
-
. . ,_
BP10-1.liter Plastic Linpreserved(NfA)• - = =
-• , . . .
, -
'
-
/7') - 7/....- .V ' V 11.195,7_50 mL Plastic ii1S64(pH-c 2)KS-)
V * 5 *
' -s4:--• :
ce ,
•i, : •••0. --.. .1: — . .
.
i; 1,:17'),C..i' • • .
/Z. .
' 4.,....,.... -• 250 mi.plastic Krim(pH A 2.)
— n x
el .
. .
ED "Zr.
... '...;;V%-:.'''. - . ' •
A . BP3Z-250 mL Pla.sticZN Acetate&NaOH(>9) xi .12
ni =
"..1 .1' ::.-.4: •.:i •• . _ .
. _ est •4, • . = .
= tp
-*-"P" . ' • . ' \10030.250 mi_Plastic NaOH(pH>12)(CI-)
,Y• .: • .• 4 • .
' ._
, • lisr R 3
CL
'.f.i. • i ..• .0 .
•
•
-..,
Vit614.1-Wi6e-rnautiect Glassier LInpreserved
:: :"‘.• -, •* ' " • . -
- . ' 2 10; . • '
: 1:i -*.: '. • • . . . '
- g• . r--) ":AG0.t)-1.reerAmbeelJapteserved(N/A)(Ct-) 1 ra ifiL1
-,s
• •
.' : ---- . ,
11
• -I
CT
: .'t:0, •4•;- : - •- i .
HO H<2),,f,"//:////-/7//e71,VAGIN-lliterAmber (P I •-•
;• i•-• `',..-...'I. •
0 r
• .
-a 2 •
•AG3U-2.50 ml.Punber linpreserved(WA)(CU)
i ' ..". -*-• .
" .
. 1 . . .
• g °
• 0. Co .
-• " .
. • - ' AG1S-1 liter Amber H2504(pH<2) .
AG3S-150 mi.Amber H2SO4(pH 2,) •
• 1A2 ,
Z t
•
i ... • '
SI-7
21;
i '13 ' .- . Y' '. • AS3AMESSA)-250 mL Amber N144(1(N/A)(C14 • - t<t..
.a • .. .
. ,
i i," '• • '
•
. 1 • . 00 DG9H-40 mi..VOA HO(WA) • '1•:-•".. -4.'1
•
- .
•
g 3 •
. • & . CM.
' •
r 3 r.
• 'Vi391,>40.mLVOA Unp(N/A)
.g. 1-
. ILI 3 =
. • .1
- 6'
• al . - ,
,
•
PP-40 mL VOA PCNI(N/A) z r- itt
f.'... •••••
0 as . .
•• -u
,VOA1C(a vials per iilt)L503.5 kit(N/A)
• - = ,,,,,, •
• •
(1)
. .
• . ..
• U/a/C(a vials per lat)-VPH/Gas ith(WA) kl CO -a,
•
1
- . --. 2
2 - - . •• • I SPST-3.25 mL Sterile Plastic(WA-tab) 0 N ta,
•
H. . • .
-1
.
cr
• . .
• .
SP2T-2.50 mi.Sterile Mastic(NIA.-lab) 0 0 64 -
•
—1 C psti j 0
0 • 3.
: • • .-
cp CI)
'• .
CO
t
. ,.. ...,....• • V- CO
. .
,
. ... ,• m
• • .
VOnt-,20 MLSaatItletlon viers OVA) • - (A) \
. -
• .
- , - 4
- .
2 tin 1
1 :. .i i `1--;• .., . .
, .
:-... .•:
- GN
.. • .
i 1:!....'",: , • .
-7- LL •11) k i-- • .
i,,:,..., : . . . .
, .
.
/,._.•
- •-..,-.7: .... • . • .
.._
• ..-- • . . _
._.
. . .
•
P r!..-•_4•,,, •. • .. . . -. . -•- . . .. • ....*--,.,
•......•
•:• . . ,•
, .•
• • . • .....1• •... • . .. . - -
i-s•••• -_,•,-*.*..: ' • -• . _ . .., .t...
. - • 1 ' •
. •. '. : ..
: -

CHAIN-OF-CUSTODY I Analytical Request Document
C7��{,,,,r�/�(�/� The Chain-al-C stady is a LEGAL DOC:UMEN'T.At relevant fluids rra t on wrnplereo acxur�l-ly.
a*rpcalapc.am ,/J/„rj (�-/•l `c
LL , _ 1 co
Section A Section B Section C Paye: d
Requited cb a►at:ration Regiued Praiea Inforrnatrat Invoice Infmrratm \ d,
Coma,y To 2069939/Q. iGr�.la-Q michaeI /4/; 'M;Cha'/B//tK
A edz d. D J O Copy To. Con Gsny----au REGULATORY AGENCY
� LPG! p� •? �K p�T rho r4
Q��DrG�NC �7Ya � e). �J c x Z� kf l+Ord tvC r NI'DeS E GROUND WATER r DRINKING WATER
Ema,T Ma IIe,46340wo..,tc,co,,.P" 'Order Na. vac.Oonc
a.r..a,. 7 FIG i UST r RCRA r OTHER
1 2?4i//../2S1[z'�t)bsf�- 3a P N. Pe Menage,Pm- —.
Sae Location
Racuestad Duo DatorAT: Profed NURCeE -a:a F1dUa r STATE
Rsqusstid Analysis Fltterad(YIN)
-.4
S.cll n D
Yab1c Cadal a =
R .ecr v imom r ___nc r __ 2 COLLECTED P as<rvatwes >
Ddnickg W,abx DW ! 0 - - A -_
Water WT
Waste weer MN s m ca s rE w j Q (�
Product P z � START E":1151 - 1 z
ci a
O ►
SAMPLE ID ,p w a m �; PO L L t1 1 A l�(T 5 Co 3,2(135
Moe AR
Sample FOs MOST BE UNIQUE Tissue TSY.f, 0 C ` Fes- c • 0
Cer OT U I- P 2 M —
" x uJ 9 Ov ram, O cc ?,
LL = rn L m G
W a 4� O L Q m
- 2 w_ OATE TIME DATE TIME .. x 3 S I I z m M O ,r Cr Paces Protect NoJ Lab LD.
I [,Ja *- lut.cf ttx,J G aiCe_2°° :1'4 r- J
C�
i
2
3
s
7 -
It
9
_ . _ .
ADMTTONA/COMMENTS •a� . ilUAT1ott TI
ay/Ar BATE T1ttE ACCEPTED BYE AFRUAON DATE TIME SAMPLE CONDITIONS
Low ✓e / i *_ _1/ /-/�i7 fo:35 g' I-I§•I Iv'.3C
I N At ' J-M' 11 13:& -- . _/fe 1-r9-I? I3z 2. 2 V /V V
r /
ORIGINAL SAW'LER NAME AND SW:MMATURE t -
/ o-- 9
PRINT Name at SAMPLER i �j e I RI(e'v B ' 7;V z w
SIGNATURE of SAMPLER• DATE Signed ` U U$ E
l ow-carry I- /g-I17 _
-InTacam nom ey vsnng arm ram ro ,e ecceda,y Paces NET 30 6ry poymeN terms and ag,wrg b Lan d ry.n al 15:ar man Ior .y . .cy o.ad ertr 30 clay,. F-ALL-O-020rev.07-15-May-2007

Pace Analytical Services,LLC
! 9800 Kincey Ave. Suite 100
aceAnalytical 1 Huntersville,NC 28078
.mw.pacelats.cwn (+r I; [phone]
.I
October 18, 2018
Mr. Mike Allen
Town of Tarboro
506 Dowd Street
PO Box 220
Tarboro, NC 27886
RE: Project: Annual PPA 10/2/18
Pace Project No.: 92402195
Dear Mr.Allen:
Enclosed are the analytical results for sample(s) received by the laboratory on October 04, 2018.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Chris Derouen
[e-mail]
[phone]
Project Manager
Enclosures
orPC
_., REPORT OF LABORATORY ANALYSIS
. _
I I This report shall not be reproduced,except in full,
7e9.8A19/'
without the written consent of Pace Analytical Services.LLC. Page 1 of 29
fral e_0\ 11(0 I - 1015-d4()-DD07-gt�'i5-2`52.0

Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
wwwpacolass.com [phone]
CERTIFICATIONS
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
Charlotte Certification IDs
9800 Kincey Ave.Ste 100,Huntersville,NC 28078 South Carolina Certification#:99006001
Louisiana/NELAP Certification#LA170028 Florida/NELAP Certification#:E87627
North Carolina Drinking Water Certification#:37706 Kentucky UST Certification#:84
North Carolina Field Services Certification#:5342 VirginiaNELAP Certification#:460221
North Carolina Wastewater Certification#: 12
Asheville Certification IDs
2225 Riverside Drive,Asheville,NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
Massachusetts Certification#:M-NC030 VirginiaNELAP Certification#:460222
North Carolina Drinking Water Certification#:37712 • - _
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 2 of 29

Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersvllle,NC 28078
rnrw pacelats.con [phone]
SAMPLE ANALYTE COUNT
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92402195001 Wastewater Effluent EPA 1664B JMS 1 PASI-C
EPA 200.7 Rev 4.4 1994 DS 15 PASI-A
EPA 1631E RDT 1 PASI-A
EPA 625.1 PKS 59 PASI-C
EPA 624.1 GAW 39 PASI-C
SM 2540C-2011 CEH 1 PASI-A
EPA 350.1 Rev 2.0 1993 NAL 1 PASI-A
EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 353.2 Rev 2.0 1993 CJH1 1 PASI-A
EPA 365.1 Rev 2.0 1993 NAL 1 PASI-A
EPA 420.4 Rev 1.0 1993 DMN 1 PASI-A
SM 4500-CN-E-2011 KDF1 1 PASI-A
92402195002 Field Blank Effluent EPA 1631E RDT 1 PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 3 of 29

Pace Analytical Services,LLC
x 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
wwwpace/am corn [phone]
ANALYTICAL RESULTS
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
Sample: Wastewater Effluent Lab ID: 92402195001 Collected: 10/02/18 09:30 Received: 10/04/18 14:15 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM,Oil and Grease Analytical Method:EPA 1664B
Oil and Grease ND mg/L 4.8 1 10/18/18 02:41
200.7 MET ICP Analytical Method:EPA 200.7 Rev 4.4 1994 Preparation Method:EPA 200.7 Rev 4.4 1994
Antimony ND ug/L 5.0 1 10/08/18 15:28 10/09/18 17:45 7440-36-0
Arsenic ND ug/L 10.0 1 10/08/18 15:28 10/09/18 17:45 7440-38-2
Beryllium ND ug/L 1.0 1 10/08/18 15:28 10/09/18 17:45 7440-41-7
Cadmium ND ug/L 1.0 1 10/08/18 15:28 10/09/18 17:45 7440-43-9
Calcium 9500 ug/L 100 1 10/08/18 15:28 10/09/18 17:45 7440-70-2
Chromium ND ug/L 5.0 1 10/08/18 15:28 10/09/18 17:45 7440-47-3
Copper 6.2 ug/L 5.0 1 10/08/18 15:28 10/09/18 17:45 7440-50-8
Lead ND ug/L 5.0 1 10/08/18 15:28 10/09/18 17:45 7439-92-1
Magnesium 2280 ug/L 100 1 10/08/18 15:28 10/09/18 17:45 7439-95-4
Nickel ND ug/L 5.0 1 10/08/18 15:28 10/09/18 17:45 7440-02-0
Selenium ND ug/L 10.0 1 10/08/18 15:28 10/09/18 17:45 7782-49-2
Silver ND ug/L 5.0 1 10/08/18 15:28 10/09/18 17:45 7440-22-4
Thallium ND ug/L 10.0 1 10/08/18 15:28 10/09/18 17:45 7440-28-0
Hardness,Total(SM 2340B) 33100 ug/L 662 1 10/08/18 15:28 10/09/18 17:45
Zinc 12.9 ug/L 10.0 1 10/08/18 15:28 10/09/18 17:45 7440-66-6
1631E Mercury,Low Level Analytical Method:EPA 1631E Preparation Method:EPA 1631E
Mercury 2.05 ng/L 0.50 1 10/08/18 14:00 10/10/18 13:56 7439-97-6
625 MSSV Analytical Method:EPA 625.1 Preparation Method:EPA 625.1
Acenaphthene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 83-32-9 Q
Acenaphthylene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 208-96-8 Q
Anthracene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 120-12-7 Q
Benzo(a)anthracene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 56-55-3 Q
Benzo(a)pyrene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 50-32-8 Q
Benzo(b)fluoranthene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 205-99-2 Q
Benzo(g,h,i)perylene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 191-24-2 Q
Benzo(k)fluoranthene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 207-08-9 Q
4-Bromophenyiphenyl ether ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 101-55-3 Q
Butylbenzylphthalate ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 85-68-7 Q
4-Chloro-3-methylphenol ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 59-50-7 Q
bis(2-Chloroethoxy)methane ND ug/L 9.6 1 10/10/18 08:25 10/12/18 12:53 111-91-1 Q
bis(2-Chloroethyl)ether ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 111-44-4 Q
2-Chloronaphthalene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 91-58-7 Q
2-Chlorophenol ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 95-57-8 Q
4-Chlorophenylphenyl ether ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 7005-72-3 Q
Chrysene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 218-01-9 Q
Dibenz(a,h)anthracene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 53-70-3 0
1,2-Dichlorobenzene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 95-50-1 Q
1,3-Dichlorobenzene ND ug/L 4.8 1 10/10/1808:25 10/12/18 12:53 541-73-1 Q
1,4-Dichlorobenzene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 106-46-7 Q
3,3'-Dichlorobenzidine ND ug/L 24.0 1 10/10/18 08:25 10/12/18 12:53 91-94-1 Q
2,4-Dichlorophenol ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 120-83-2 Q
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 4 of 29

Pace Analytical Services,LLC
Q n e 9800 Kincey Ave. Suite 100
• . ac A ralytical( Huntersville,NC 28078
Alm uacelabs.mrn [phone]
ANALYTICAL RESULTS
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
Sample: Wastewater Effluent Lab ID: 92402195001 Collected: 10/02/18 09:30 Received: 10/04/18 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
625 MSSV Analytical Method:EPA 625.1 Preparation Method:EPA 625.1
Diethylphthalate ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 84-66-2 Q
• 2,4-Dimethyiphenol ND ug/L 9.6 1 10/10/18 08:25 10/12/18 12:53 105-67-9 Q
Dimethylphthalate ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 131-11-3 Q
! Di-n-butylphthalate ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 84-74-2 Q
j 4,6-Dinitro-2-methylphenol ND ug/L 19.2 1 10/10/18 08:25 10/12/18 12:53 534-52-1 Q
2,4-Dinitrophenol ND ug/L 48.1 1 10/10/18 08:25 10/12/18 12:53 51-28-5 Q
2,4-Dinitrotoluene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 121-14-2 Q
2,6-Dinitrotoluene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 606-20-2 Q
Di-n-octylphthalate ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 117-84-0 Q
12-Diphenylhydrazine ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 122-66-7 Q
bis(2-Ethylhexyl)phthalate ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 117-81-7 Q
Fluoranthene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 206-44-0 Q
Fluorene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 86-73-7 Q
Hexachlorobenzene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 118-74-1 Q
Hexachlorocyclopentadiene ND ug/L 9.6 1 10/10/18 08:25 10/12/18 12:53 77-47-4 Q
Hexachloroethane ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 67-72-1 Q
Indeno(1,2,3-cd)pyrene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 193-39-5 Q
Isophorone ND ug/L 9.6 1 10/10/18 08:25 10/12/18 12:53 78-59-1 Q
Naphthalene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 91-20-3 Q
i Nitrobenzene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 98-95-3 Q
2-Nitrophenol ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 88-75-5 Q
4-Nitrophenol ND ug/L 48.1 1 10/10/18 08:25 10/12/18 12:53 100-02-7 Q
N-Nitrosodimethylamine ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 62-75-9 Q
N-Nitroso-di-n-propylamine ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 621-64-7 Q
! N-Nitrosodiphenylamine ND ug/L 9.6 1 10/10/18 08:25 10/12/18 12:53 86-30-6 Q
Pentachlorophenol ND ug/L 9.6 1 10/10/18 08:25 10/12/18 12:53 87-86-5 Q
Phenanthrene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 85-01-8 Q
Phenol ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 108-95-2 Q
Pyrene ND ug/L 4.8 1 10/10/18 08:25 10/12/18 12:53 129-00-0 Q
2,4,6-Trichlorophenol ND ug/L 9.6 1 10/10/18 08:25 10/12/18 12:53 88-06-2 Q
Surrogates
Nitrobenzene-d5(S) 68 % 10-120 1 10/10/18 08:25 10/12/18 12:53 4165-60-0
2-Fluorobiphenyl(S) 67 % 15-120 1 10/10/18 08:25 10/12/18 12:53 321-60-8
Terphenyl-d14(S) 104 % 11-131 1 10/10/18 08:25 10/12/18 12:53 1718-51-0
Phenol-d6(S) 27 % 10-120 1 10/10/18 08:25 10/12/18 12:53 13127-88-3
2-Fluorophenol(S) 42 % 10-120 1 10/10/18 08:25 10/12/18 12:53 367-12-4
2,4,6-Tribromophenol(S) 71 % 10-137 1 10/10/18 08:25 10/12/18 12:53 118-79-6
t524 Volatile Organics Analytical Method:+PA 624.1
Acrolein ND ug/L 5.0 1 10/08/18 18:57 107-02-8
Acrylonitrile ND ug/L 50.0 1 10/08/18 18:57 107-13-1
Benzene ND ug/L 2.0 1 10/08/18 18:57 71-43-2
Bromodichloromethane ND ug/L 2.0 1 10/08/18 18:57 75-27-4
Bromoform ND ug/L 2.0 1 10/08/18 18:57 75-25-2
Bromomethane ND ug/L 2.0 1 10/08/18 18:57 74-83-9
Carbon tetrachloride ND ug/L 2.0 1 10/08/18 18:57 56-23-5
Chlorobenzene ND ug/L 2.0 1 10/08/18 18:57 108-90-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 29

"(7)
Pace Analytical Services,LLC
a 9800 Kincey Ave. Suite 100
Ace Huntersville,NC 28078
www.pace1ans.com [phone]
ANALYTICAL RESULTS
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
Sample: Wastewater Effluent Lab ID: 92402195001 Collected: 10/02/18 09:30 Received: 10/04/18 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
624 Volatile Organics Analytical Method:EPA 624.1
Chloroethane ND ug/L 2.0 1 10/08/18 18:57 75-00-3
2-Chloroethylvinyl ether ND ug/L 5.0 1 10/08/18 18:57 110-75-8 c2
Chloroform ND ug/L 2.0 1 10/08/18 18:57 67-66-3
Chloromethane ND ug/L 2.0 1 10/08/18 18:57 74-87-3
Dibromochloromethane ND ug/L 2.0 1 10/08/18 18:57 124-48-1
1,2-Dichlorobenzene ND ug/L 2.0 1 10/08/18 18:57 95-50-1
1,3-Dichlorobenzene ND ug/L 2.0 1 10/08/18 18:57 541-73-1
1,4-Dichlorobenzene ND ug/L 2.0 1 10/08/18 18:57 106-46-7
1,1-Dichloroethane ND ug/L 2.0 1 10/08/18 18:57 75-34-3
1,2-Dichloroethane ND ug/L 2.0 1 10/08/18 18:57 107-06-2
1,1-Dichloroethene ND ug/L 2.0 1 10/08/18 18:57 75-35-4
trans-1,2-Dichloroethene ND ug/L 2.0 1 10/08/18 18:57 156-60-5
1.2-Dichloropropane ND ug/L 2.0 1 10/08/18 18:57 78-87-5
cis-1,3-Dichloropropene ND ug/L 2.0 1 10/08/18 18:57 10061-01-5
trans-1,3-Dichloropropene ND ug/L 2.0 1 10/08/18 18:57 10061-02-6
Ethylbenzene ND ug/L 2.0 1 10/08/18 18:57 100-41-4
Hexachloro-1,3-butadiene ND ug/L 5.0 1 10/08/18 18:57 87-68-3
Methylene Chloride ND ug/L 2.0 1 10/08/18 18:57 75-09-2
Naphthalene ND ug/L 5.0 1 10/08/18 18:57 91-20-3
1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 10/08/18 18:57 79-34-5
Tetrachloroethene ND ug/L 2.0 1 10/08/18 18:57 127-18-4
Toluene ND ug/L 2.0 1 10/08/18 18:57 108-88-3
1,2,4-Trichlorobenzene ND ug/L 2.0 1 10/08/18 18:57 120-82-1
1,1,1-Trichloroethane ND ug/L 2.0 1 10/08/18 18:57 71-55-6
1,1,2-Trichloroethane ND ug/L 2.0 1 10/08/18 18:57 79-00-5
Trichloroethene ND ug/L 2.0 1 10/08/18 18:57 79-01-6
Trichlorofluoromethane ND ug/L 2.0 1 10/08/18 18:57 75-69-4
Vinyl chloride ND ug/L 2.0 1 10/08/18 18:57 75-01-4
Surrogates
4-Bromofluorobenzene(S) 105 % 70-130 1 10/08/18 18:57 460-00-4
Toluene-d8(S) 103 % 70-130 1 10/08/18 18:57 2037-26-5
1,2-Dichloroethane-d4(S) 96 % 70-130 1 10/08/18 18:57 17060-07-0
2540C Total Dissolved Solids Analytical Method:SM 2540C-2011
Total Dissolved Solids 274 mg/L 25.0 1 10/08/18 23:54
350.1 Ammonia Analytical Method:EPA 350.1 Rev 2.0 1993
Nitrogen,Ammonia ND mg/L 0.10 1 10/10/18 18:57 7664-41-7
351.2 Total Kjeldahl Nitrogen Analytical Method:EPA 351.2 Rev 2.0 1993 Preparation Method:EPA 351.2 Rev 2.0 1993
Nitrogen,Kjeldahl,Total 1.4 mgiL 0.50 1 10/08/18 18:45 10/09/18 01:45 7727-37-9
353.2 Nitrogen,NO2/NO3 pres. Analytical Method:EPA 353.2 Rev 2.0 1993
Nitrogen,NO2 plus NO3 13.0 mg/L 0.10 5 10/13/18 12:16
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 6 of 29

Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
wwwpacelabs.orn [phone]
ANALYTICAL RESULTS
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
Sample: Wastewater Effluent Lab ID: 92402195001 Collected: 10/02/18 09:30 Received: 10/04/18 14:15 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
365.1 Phosphorus,Total Analytical Method:EPA 365.1 Rev 2.0 1993 Preparation Method:EPA 365.1 Rev 2.0 1993
Phosphorus 1.2 mg/L 0.050 1 10/08/18 12:16 10/08/18 16:14 7723-14-0
420.4 Phenolics,Total Analytical Method:EPA420.4 Rev 1.0 1993 Preparation Method: EPA420.4 Rev 1.0 1993
Phenol ND mg/L 0.010 1 10/10/18 11:21 10/11/18 13:50 108-95-2 BC
4500CNE Cyanide,Total Analytical Method:SM 4500-CN-E-2011 Preparation Method:SM 4500-CN-E-2011
Cyanide ND mg/L 0.0080 1 10/11/18 15:00 10/12/18 13:23 57-12-5
Sample: Field Blank Effluent Lab ID: 92402195002 Collected: 10/02/18 09:30 Received: 10/04/18 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method:EPA 1631E Preparation Method:EPA 1631E
Mercury ND ng/L 0.50 1 10/08/18 14:00 10/10/18 12:01 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 7 of 29

Pace Analytical Services,LLC
a 9800 Kincey Ave, Suite 100
ace Analytical Huntersville,NC 28078
mvwpacelabsoom
[phone]
QUALITY CONTROL DATA
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
QC Batch: 436876 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664B Analysis Description: 1664 HEM,Oil and Grease
Associated Lab Samples: 92402195001
METHOD BLANK. 2403341 Matrix: Water
Associated Lab Samples: 92402195001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 4.8 10/18/18 02:31
LABORATORY CONTROL SAMPLE 2403342
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L 38.5 33.8 88 78-114
MATRIX SPIKE SAMPLE: 2403343
92403081004 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L ND 38.5 37.6 98 78-114
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 29

Pace Analytical Services,LLC
® 9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
wwwpaceiabsccvn [phone]
QUALITY CONTROL DATA
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
QC Batch: 434997 Analysis Method: EPA 1631E
QC Batch Method: EPA 1631E Analysis Description: 1631E Mercury,Low Level
Associated Lab Samples: 92402195001,92402195002
METHOD BLANK: 2394783 Matrix: Water
Associated Lab Samples: 92402195001,92402195002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 10/10/18 10:37
METHOD BLANK: 23947 4 Matrix: Water
8
Associated Lab Samples: 92402195001,92402195002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 10/10/18 12:09
METHOD BLANK: 2394785 Matrix: Water
Associated Lab Samples: 92402195001,92402195002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 10/10/18 14:03
LABORATORY CONTROL SAMPLE: 2394786
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Mercury ng/L 5 5.00 100 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2394787 2394788
MS MSD
92402386001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Mercury ng/L 1.52 25 25 26.3 27.3 99 103 71-125 4
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2394789 2394790
MS MSD
92402336005 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Mercury ng/L 1.75 25 25 27.2 27.5 102 103 71-125 1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not on reproduced,except in full, '
Date:10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 29

Pace Analytical Services,LLC
e 9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
www.pacelabs.cam [phone]
QUALITY CONTROL DATA
Project: Annual PPA 10/2J18
Pace Project No.: 92402195
QC Batch: 434971 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Associated Lab Samples: 92402195001
METHOD BLANK: 2394674 Matrix: Water
Associated Lab Samples: 92402195001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Antimony ug/L ND 5.0 10/09/18 16:40
Arsenic ug/L ND 10.0 10/09/18 16:40
Beryllium ug/L ND 1.0 10/09/18 16:40
Cadmium ug/L ND 1.0 10/09/18 16:40
Calcium ug/L ND 100 10/09/18 16:40
Chromium ug/L ND 5.0 10/09/18 16:40
Copper ug/L ND 5.0 10/09/18 16:40
Hardness,Total(SM 2340B) ug/L ND 662 10/09/18 16:40
Lead ug/L ND 5.0 10/09/18 16:40
Magnesium ug/L ND 100 10/09/18 16:40
Nickel ug/L ND 5.0 10/09/18 16:40
Selenium ug/L ND 10.0 10/09/18 16:40
Silver ug/L ND 5.0 10/09/18 16:40
Thallium ug/L ND 10.0 10/09/18 16:40
Zinc ug/L ND 10.0 10/09/18 16:40
LABORATORY CONTROL SAMPLE: 2394675
Spike LCS LCS %Rec
Parameter Units Conc. Result °Ae Rec Limits Qualifiers
Antimony ug/L 500 476 95 85-115
Arsenic ug/L 500 472 94 85-115
Beryllium ug/L 500 483 97 85-115
Cadmium ug/L 500 471 94 85-115
Calcium ug/L 5000 4820 96 85-115
Chromium ug/L 500 477 95 85-115
Copper ug/L 500 479 96 85-115
Hardness,Total(SM 23408) ug/L 31600
Lead ug/L 500 464 93 85-115
Magnesium ug/L 5000 4750 95 85-115
Nickel ug/L 500 467 93 85-115 I
Selenium ug/L 500 472 94 85-115
Silver ug/L 250 241 96 85-115
Thallium ug/L 500 463 93 85-115
Zinc ug/L 500 468 94 85-115
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 10/18/2018 04.49 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 29

Pace Analytical Services,LLC
s 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www pacoiaes.own [phone]
QUALITY CONTROL DATA
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2394678 2394679
MS MSD
92402240001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Antimony ug/L ND 500 500 479 478 95 95 70-130 0
Arsenic ug/L ND 500 500 483 487 96 97 70-130 1
Beryllium ug/L ND 500 500 558 556 112 111 70-130 0
Cadmium ug/L ND 500 500 510 509 102 102 70-130 0
Calcium ug/L 19.3 5000 5000 24900 25000 112 112 70-130 0
mg/L
Chromium ug/L 0.0078 500 500 505 505 100 99 70-130 0
mg/L
Copper ug/L 0.028 500 500 559 558 106 106 70-130 0
mg/L
Hardness,Total(SM 2340B) ug/L 69.3 104000 103000 0
mg/L
Lead ug/L ND 500 500 463 463 92 92 70-130 0
Magnesium ug/L 5.1 5000 5000 10000 9980 99 97 70-130 1
mg/L
Nickel ug/L 0.010 500 500 492 492 96 96 70-130 0
mg/L
Selenium ug/L ND 500 500 525 525 105 105 70-130 0
Silver ug/L ND 250 250 256 256 102 102 70-130 0
Thallium ug/L ND 500 500 173 165 35 33 70-130 5 J(M1)
Zinc ug/L 0.15 500 500 608 608 91 91 70-130 0
mg/L
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2394831 2394832
MS MSD
92401609001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Antimony ug/L ND 500 500 510 512 102 102 70-130 1
Arsenic ug/L ND 500 500 502 503 100 101 70-130 0
Beryllium ug/L ND 500 500 512 512 102 102 70-130 0
Cadmium ug/L ND 500 500 506 507 101 101 70-130 0
Calcium ug/L 1.4 5000 5000 6580 6560 103 103 70-130 0
mg/L
Chromium ug/L ND 500 500 503 504 100 101 70-130 0
Copper ug/L 0.058 500 500 564 567 101 102 70-130 1
mg/L
Hardness,Total(SM 2340B) ug/L 5310 39100 39000 0
Lead ug/L ND 500 500 494 496 98 99 70-130 0
Magnesium ug/L 0.42 5000 5000 5500 5480 102 101 70-130 0
mg/L
Nickel ug/L 0.014 500 500 509 511 99 99 70-130 0
mg/L
Selenium ug/L ND 500 500 519 519 104 104 70-130 0
Silver ug/L ND 250 250 258 258 103 103 70-130 0
Thallium ug/L ND 500 500 489 490 97 97 70-130 0
Zinc ug/L 0.24 500 500 738 732 101 99 70-130 1
mg/L
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 11 of 29

Paco Analytical Services,LLC
s 9800 Kincey Ave. Suite 100
• aceAnalytical Huntersville,NC 28078
wwwpacelahs.com [phone]
QUALITY CONTROL DATA
Project: Annual PPA 10/2/18 I
Pace Project No.: 92402195
QC Batch: 434841 Analysis Method: EPA 624.1
QC Batch Method: EPA 624.1 Analysis Description: 624 MSV
Associated Lab Samples: 92402195001
METHOD BLANK: 2394297 Matrix: Water
Associated Lab Samples: 92402195001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1,1-Trichloroethane ug/L ND 2.0 10/08/18 13:22
1,1,2,2-Tetrachloroethane ug/L ND 2.0 10/08/18 13:22
1,1,2-Trichloroethane ug/L ND 2.0 10/08/18 13:22
1,1-Dichloroethane ug/L ND 2.0 10/08/18 13:22
1,1-Dichloroethene ug/L ND 2.0 10/08/18 13:22
1,2,4-Trichlorobenzene ug/L ND 2.0 10/08/18 13:22
1,2-Dichlorobenzene ug/L ND 2.0 10/08/18 13:22
1,2-Dichloroethane ug/L ND 2.0 10/08/18 13:22
1,2-Dichloropropane ug/L ND 2.0 10/08/18 13:22
1,3-Dichlorobenzene ug/L ND 2.0 10/08/18 13:22
1.4-Dichlorobenzene ug/L ND 2.0 10/08/18 13:22
2-Chloroethylvinyl ether ug/L ND 5.0 10/08/18 13:22
Acrolein ug/L ND 5.0 10/08/18 13:22
Acrylonitrile ug/L ND 50.0 10/08/18 13:22
Benzene ug/L ND 2.0 10/08/18 13:22
Bromodichloromethane ug/L ND 2.0 10/08/18 13:22
Bromoform ug/L ND 2.0 10/08/18 13:22
Bromomethane ug/L ND 2.0 10/08/18 13:22
Carbon tetrachloride ug/L ND 2.0 10/08/18 13:22
Chlorobenzene ug/L ND 2.0 10/08/18 13:22
Chloroelhane ug/L ND 2.0 10/08/18 13:22
Chloroform ug/L ND 2.0 10/08/18 13:22
Chloromethane ug/L ND 2.0 10/08/18 13:22
cis-1,3-Dichloropropene ug/L ND 2.0 10/08/18 13:22
Dibromochloromethane ug/L ND 2.0 10/08/18 13:22
Ethylbenzene ug/L ND 2.0 10/08/18 13:22
Hexachloro-1,3-butadiene ug/L ND 5.0 10/08/18 13:22
Methylene Chloride ug/L ND 2.0 10/08/18 13:22
Naphthalene ug/L ND 5.0 10/08/18 13:22
Tetrachloroethene ug/L ND 2.0 10/08/18 13:22
Toluene ug/L ND 2.0 10/08/18 13:22
trans-1,2-Dichloroethene ug/L ND 2.0 10/08/18 13:22
trans-1,3-Dichloropropene ug/L NO 2.0 10/08/18 13:22
Trichloroethene ug/L ND 2.0 10/08/18 13:22
Trichlorofluoromethane ug/L ND 2.0 10/08/18 13:22
Vinyl chloride ug/L ND 2.0 10/08/18 13:22
1,2-Dichloroethane-d4(S) % 88 70-130 10/08/18 13:22
4-Bromofluorobenzene(S) % 105 70-130 10/08/18 13:22
Toluene-d8(S) % 107 70-130 10/08/18 13:22
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 12 of 29

Pace Analytical Services,LLC
e 9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
'n`wwpaced elm.com [phone]
QUALITY CONTROL DATA
1
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
LABORATORY CONTROL SAMPLE: 2394298
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,1,1-Trichloroethane ug/L 20 19.1 95 70-130
1,1,2,2-Tetrachloroethane ug/L 20 17.4 87 60-140
1,1,2-Trichloroethane ug/L 20 18.0 90 70-130
1,1-Dichloroethane ug/L 20 18.0 90 70-130
1,1-Dichloroethene ug/L 20 18.8 94 50-150
1,2,4-Trichlorobenzene ug/L 20 18.2 91 70-130
1,2-Dichlorobenzene ug/L 20 18.3 91 65-135
1,2-Dichloroethane ug!L 20 17.6 88 49-155
' 1,2-Dichloropropane ug/L 20 19.5 98 35-165
1,3-Dichlorobenzene ug/L 20 18.2 91 70-130
1,4-Dichlorobenzene ug/L 20 18.4 92 65-135
2-Chloroethylvinyl ether ug/L 40 36.4 91 1-225
Acrolein ug/L 100 84.3 84 60-140
Acrylonitrile ug/L 100 76.8 77 60-140
Benzene ug/L 20 19.5 98 65-135
Bromodichloromethane ug/L 20 17.9 89 65-135
Bromoform ug/L 20 15.6 78 70-130
Bromomethane ug/L 20 12.2 61 15-185
Carbon tetrachloride ug/L 20 19.0 95 70-130
Chlorobenzene ug/L 20 18.8 94 65-135
Chloroethane ug/L 20 14.6 73 40-160
Chloroform ug/L 20 17.1 86 70-135
Chloromethane ug/L 20 15.8 79 1-205
cis-1,3-Dichloropropene ug/L 20 19.1 96 25-175
Dibromochloromethane ug/L 20 18.0 90 70-135
Ethylbenzene ug/L 20 18.2 91 60-140
Hexachloro-1,3-butadiene ug/L 20 19.3 97 70-130
Methylene Chloride ug/L 20 13.7 68 60-140
Naphthalene ug/L 20 17.4 87 70-130
Tetrachloroethene ug/L 20 19.2 96 70-130
Toluene ug/L 20 18.2 91 70-130
trans-1,2-Dichloroethene ug/L 20 19.0 95 70-130
trans-1,3-Dichloropropene ug/L 20 18.6 93 50-150
Trichloroethene ug/L 20 20.0 100 65-135
Trichlorofluoromethane ug/L 20 19.0 95 50-150
Vinyl chloride ug/L 20 19.9 99 5-195
1,2-Dichloroethane-d4(S) % 98 70-130
4-Bromofluorobenzene(S) % 100 70-130
Toluene-d8(S) % 98 70-130
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2394299 2394300
MS MSD
92402366003 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
1,1,1-Trichloroethane ug/L ND 20 20 21.5 23.7 107 118 52-162 10
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced.except in full,
Date: 10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 13 of 29

Pace Analytical Services,LLC
s 9800 Kincey Ave. Suite 100
aceAnalyfical Huntersville,NC 28078
www.paceteas.com [phone]
QUALITY CONTROL DATA
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2394299 2394300
MS MSD
92402366003 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
1,1,2,2-Tetrachloroethane ug/L ND 20 20 17.5 18.7 87 94 46-157 7
1,1,2-Trichloroethane ug/L ND 20 20 19.5 21.3 97 106 52-150 9
1,1-Dichloroethane ug/L ND 20 20 20.5 21.8 102 109 59-155 6
1,1-Dichloroethene ug/L ND 20 20 22.3 23.6 112 118 1-234 6
1,2,4-Trichlorobenzene ug/L ND 20 20 12.6 14.5 63 73 70-130 14 J(M1)
1,2-Dichlorobenzene ug/L ND 20 20 16.4 17.8 82 89 18-190 8
1,2-Dichloroethane ug/L ND 20 20 19.9 21.7 100 108 49-155 9
1,2-Dichloropropane ug/L ND 20 20 21.3 22.5 107 112 1-210 5
1,3-Dichlorobenzene ug/L ND 20 20 16.2 17.9 81 89 59-156 10
1,4-Dichlorobenzene ug/L ND 20 20 16.5 18.4 83 92 18-190 11
2-Chloroethylvinyl ether ug/L ND 40 40 ND ND 0 0 1-305 J(M1)
Acrolein ug/L ND 100 100 92.3 96.5 92 97 40-160 5
Acrylonitrile ug/L ND 100 100 103 102 103 102 40-160 1
Benzene ug/L ND 20 20 21.2 22.7 106 114 37-151 7
Bromodichloromethane ug/L ND 20 20 19.4 21.3 97 106 35-155 9
Bromoform ug/L ND 20 20 14.5 15.0 73 75 45-169 3
Bromomethane ug/L ND 20 20 8.4 9.7 42 48 1-242 14
Carbon tetrachloride ug/L ND 20 20 20.9 22.6 105 113 70-140 8
Chlorobenzene ug/L ND 20 20 18.9 20.5 95 103 37-160 8
Chloroethane ug/L ND 20 20 18.7 19.6 94 98 14-230 5
Chloroform ug/L ND 20 20 18.9 19.5 92 95 51-138 3
Chloromethane ug/L ND 20 20 16.3 17.9 81 88 1-273 9
cis-1,3-Dichloropropene ug/L ND 20 20 20.5 22.5 103 113 1-227 9
Dibromochloromethane ug/L ND 20 20 17.6 19.4 88 97 53-149 10
Ethylbenzene ug/L ND 20 20 17.9 192 90 96 37-162 7
Hexachloro-1,3-butadiene ug/L ND 20 20 9.9 10.9 50 54 70-130 9 J(M1)
Methylene Chloride ug/L ND 20 20 16.8 17.4 84 87 1-221 4
Naphthalene ug/L ND 20 20 13.2 15.0 66 75 70-130 12 J(M1)
Tetrachloroethene ug/L ND 20 20 18.3 19.8 91 99 64-148 8
Toluene ug/L ND 20 20 19.9 21.4 99 107 47-150 7
trans-1,2-Dichloroethene ug/L ND 20 20 21.9 23.2 109 116 54-156 6
trans-1,3-Dichloropropene ug/L ND 20 20 19.6 20.8 98 104 17-183 6 i
Trichloroethene ug/L ND 20 20 21.9 23.5 109 117 70-157 7
Trichloroiluoromethane ug/L ND 20 20 22.5 24.1 112 121 17-181 7
Vinyl chloride ug/L ND 20 20 24.3 25.5 121 128 1-251 5
1,2-Dichloroethane-d4(S) % 104 101 70-130
4-Bromofluorobenzene(S) % 102 97 70-130
Toluene-d8(S) % 101 102 70-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 14 of 29

Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
aceAnalytical Huntersvllle,NC 28078
WWW pacela bs.corn [phone]
QUALITY CONTROL DATA
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
QC Batch: 435351 Analysis Method: EPA 625.1
QC Batch Method: EPA 625.1 Analysis Description: 625 MSS
Associated Lab Samples: 92402195001
METHOD BLANK: 2396302 Matrix: Water
Associated Lab Samples: 92402195001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,2-Dichlorobenzene ug/L ND 5.0 10/11/18 20:43
1,2-Diphenylhydrazine ug/L ND 5.0 10/11/18 20:43
1,3-Dichlorobenzene ug/L ND 5.0 10/11/18 20:43
1,4-Dichlorobenzene ug/L ND 5.0 10/11/18 20:43
2,4,6-Trichlorophenol ug/L ND 10.0 10/11/18 20:43
2,4-Dichlorophenol ug/L ND 5.0 10/11/18 20:43
2,4-Dimethylphenol ug/L ND 10.0 10/11/18 20:43
2.4-Dinitrophenol ug/L ND 50.0 10/11/18 20:43
2,4-Dinitrotoluene ug/L ND 5.0 10/11/18 20:43
2,6-Dinitrotoluene ug/L ND 5.0 10/11/18 20:43
2-Chloronaphthalene ug/L ND 5.0 10/11/18 20:43
2-Chlorophenol ug/L ND 5.0 10/11/18 20:43
2-Nitrophenol ug/L ND 5.0 10/11/18 20:43
3,3'-Dichlorobenzidine ug/L ND 25.0 10/11/18 20:43
4,6-Dinitro-2-methylphenol ug/L ND 20.0 10/11/18 20:43
4-Bromophenylphenyl ether ug/L ND 5.0 10/11/18 20:43
4-Chloro-3-methylphenol ug/L ND 5.0 10/11/18 20:43
4-Chlorophenylphenyl ether ug/L ND 5.0 10/11/18 20:43
4-Nitrophenol ug/L ND 50.0 10/11/18 20:43
Acenaphthene ug/L ND 5.0 10/11/18 20:43
Acenaphthylene ug/L ND 5.0 10/11/18 20:43
Anthracene ug/L ND 5.0 10/11/18 20:43
Benzo(a)anthracene ug/L ND 5.0 10/11/18 20:43
Benzo(a)pyrene ug/L ND 5.0 10/11/18 20:43
8enzo(b)fluoranthene ug/L ND 5.0 10/11/18 20:43
Benzo(g,h,i)perylene ug/L ND 5.0 10/11/18 20:43
Benzo(k)fluoranthene ug/L ND 5.0 10/11/18 20:43
bis(2-Chloroethoxy)methane ug/L ND 10.0 10/11/18 20:43
bis(2-Chloroethyl)ether ug/L ND 5.0 10/11/18 20:43
bis(2-Ethylhexyl)phlhalate ug/L ND 5.0 10/11/18 20:43
Butylbenzylphthalate ug/L ND 5.0 10/11/18 20:43
Chrysene ug/L ND 5.0 10/11/18 20:43
Di-n-butylphthalate ug/L ND 5.0 10/11/18 20:43
Di-n-octylphthalate ug/L ND 5.0 10/11/18 20:43
Dibenz(a,h)anthracene ug/L ND 5.0 10/11/18 20:43
Diethylphthalate ug/L ND 5.0 10/11/18 20:43
Dimethylphthalate ug/L ND 5.0 10/11/18 20:43
Fluoranthene ug/L ND 5.0 10/11/18 20:43
Fluorene ug/L NO 5.0 10/11/18 20:43
Hexachlorobenzene ug/L ND 5.0 10/11/18 20:43
Hexachlorocyclopentadiene ug/L ND 10.0 10/11/18 20:43
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full.
Date. 10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 15 of 29

Pace Analytical Services.LLC
A 9800 Kincey Ave. Suite 100
/')
eAnalytical Huntersville,NC 28078
www.pecelaescom [phone]
QUALITY CONTROL DATA
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
METHOD BLANK: 2396302 Matrix: Water
1 Associated Lab Samples: 92402195001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Hexachloroethane ug/L ND 5.0 10/11/18 20:43
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 10/11/18 20:43
Isophorone ug/L ND 10.0 10/11/18 20:43
N-Nitroso-di-n-propylamine ug/L ND 5.0 10/11/18 20:43
N-Nitrosodimethylamine ug/L ND 5.0 10/11/18 20:43
N-Nitrosodiphenylamine ug/L ND 10.0 10/11/18 20:43
Naphthalene ug/L ND 5.0 10/11/18 20:43
Nitrobenzene ug/L ND 5.0 10/11/18 20:43
Pentachlorophenol ug/L ND 10.0 10/11/18 20:43
Phenanthrene ug/L ND 5.0 10/11/18 20:43
Phenol ug/L ND 5.0 10/11/18 20:43
Pyrene ug/L ND 5.0 10/11/1820:43
2,4,6-Tribromophenol(S) '/0 83 10-137 10/11/18 20:43
2-Fluorobiphenyl(S) % 84 15-120 10/11/18 20:43
2-Fluorophenol(S) % 50 10-120 10/11/18 20:43
Nitrobenzene-d5(S) % 80 10-120 10/11/18 20:43
Phenol-d6(S) % 31 10-120 10/11/18 20:43
Terphenyl-d14(S) % 104 11-131 10/11/18 20:43
LABORATORY CONTROL SAMPLE&LCSD: 2396303 2396304
Spike LCS LCSD LCS LCSD %Rec Max
Parameter Units Conc. Result Result %Rec %Rec Limits RPD RPD Qualifiers
1,2-Dichlorobenzene ug/L 50 40.9 36.2 82 72 32-129 12 30
1,2-Diphenyihydrazine ug/L 50 47.4 44.9 95 90 25-150 5 30
1,3-Dichlorobenzene ug/L 50 37.0 37.1 74 74 1-172 0 30
1,4-Dichlorobenzene ug/L 50 39.8 35.7 80 71 20-124 11 30
2,4,6-Trichlorophenol ug/L 50 46.7 42.9 93 86 37-144 8 58
2,4-Dichlorophenol ug/L 50 43.0 41.6 86 83 39-135 3 50
2.4-Dimethylphenol ug/L 50 48.2 45.1 96 90 32-120 7 58
2.4-Dinitrophenol ug/L 250 230 183 92 73 1-191 22 132
2,4-Dinitrotoluene ug/L 50 46.5 43.3 93 87 39-139 7 42
2.6-Dinitrotoluene ug/L 50 44.9 44.3 90 89 50-158 1 48
2-Chloronaphthalene ug/L 50 44.9 43.2 90 86 60-120 4 24
2-Chlorophenol ug/L 50 43.3 36.5 87 73 23-134 17 61
2-Nitrophenol ug/L 50 41.7 41.1 83 82 29-181 1 55
3,3'-Dichlorobenzidine ug/L 100 90.0 79.9 90 80 1-262 12 108
4,6-Dinitro-2-methylphenol ug/L 100 99.9 85.8 100 86 1-181 15 30
4-Bromophenylphenyl ether ug/L 50 46.1 44.4 92 89 53-127 4 43
4-Chloro-3-methylphenol ug/L 100 81.7 76.5 82 76 22-147 7 73
4-Chlorophenylphenyl ether ug/L 50 47.7 43.9 95 88 25-158 8 61
4-Nitrophenol ug/L 250 103 89.1 41 36 1-132 15 131
Acenaphthene ug/L 50 47.6 45.7 95 91 47-145 4 48
Acenaphthylene ug/L 50 47.0 44.1 94 88 33-145 6 74
Anthracene ug/L 50 47.7 46.6 95 93 27-133 2 66
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full.
Date: 10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 16 of 29

Pace Analytical Services,LLC
a; 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
vnrwpacnraDscom [phone]
QUALITY CONTROL DATA
' Project: Annual PPA 10/2/18
Pace Project No.: 92402195
LABORATORY CONTROL SAMPLE&LCSD: 2396303 2396304
Spike LCS LCSD LCS LCSD %Rec Max
Parameter Units Conc. Result Result %Rec %Rec Limits RPD RPD Qualifiers
Benzo(a)anthracene ug/L 50 47.3 44.7 95 89 33-143 6 53
Benzo(a)pyrene ug/L 50 48.5 45.1 97 90 17-163 7 72
Benzo(b)fluoranthene ug/L 50 48.4 43.9 97 88 24-159 10 71
' Benzo(g,h,i)perylene ug/L 50 48.6 48.7 97 97 1-219 0 97
Benzo(k)fluoranthene ug/L 50 50.3 46.9 101 94 11-162 7 63
bis(2-Chloroethoxy)methane ug/L 50 46.9 44.1 94 88 33-184 6 54
bis(2-Chloroethyl)ether ug/L 50 45.7 41.3 91 83 12-158 10 108
bis(2-Ethylhexyl)phthalate ug/L 50 43.9 40.7 88 81 8-158 7 82
Butylberzylphthalate ug/L 50 43.7 41.6 87 83 1-152 5 60
Chrysene ug/L 50 47.9 46.8 96 94 17-168 2 87
Di-n-butylphthalate ug/L 50 42.4 38.8 85 78 1-120 9 47
Di-n-octylphthalate ug/L 50 44.9 41.8 90 84 4-146 7 69
Dibenz(a,h)anthracene ug/L 50 45.4 45.1 91 90 1-227 1 126
Diethylphthalate ug/L 50 41.7 38.5 83 77 1-120 8 100
Dimethylphthalate ug/L 50 40.9 38.6 82 77 1-120 6 183
Fluoranthene ug/L 50 48.1 43.6 96 87 26-137 10 66
Fluorene ug/L 50 46.6 42.9 93 86 59-121 8 38
Hexachlorobenzene ug/L 50 45.4 43.3 91 87 1-152 5 55
Hexachlorocyclopentadiene ug/L 50 46.2 41.2 92 82 25-150 11 30
Hexachloroethane ug/L 50 38.0 35.9 76 72 40-120 6 52
Indeno(1,2,3-cd)pyrene ug/L 50 47.5 45.5 95 91 1-171 4 99
Isophorone ug/L 50 39.1 35.2 78 70 21-196 10 93
N-Nitroso-di-n-propylamine ug/L 50 44.5 37.5 89 75 1-230 17 87
N-Nitrosodimethylamine ug/L 50 33.8 31.3 68 63 25-150 8 30
N-Nitrosodiphenylamine ug/L 50 44.9 42.4 90 85 25-150 6 30
Naphthalene ug/L 50 43.3 40.9 87 82 21-133 6 65
Nitrobenzene ug/L 50 45.0 42.3 90 85 35-180 6 62
Pentachlorophenol ug/L 100 77.9 60.4 78 60 14-176 25 86
Phenanthrene ug/L 50 47.5 45.5 95 91 54-120 4 39
Phenol ug/L 50 18.6 16.1 37 32 5-120 14 64
Pyrene ug/L 50 48.4 48.7 97 97 52-120 0 49
2,4,6-Tribromophenol(S) % 93 87 10-137
2-Fluorobiphenyl(S) % 89 84 15-120
1 2-Fluorophenol(S) % 60 51 10-120
Nitrobenzene-d5(S) % 86 79 10-120
Phenol-d6(S) % 37 32 10-120
Terphenyl-d14(S) % 100 100 11-131
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit is presented to the tight of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 17 of 29

Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
./ ace Analytical Huntersville,NC 28078
mewpacelabs.com [phone]
QUALITY CONTROL DATA
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
QC Batch: 435084 Analysis Method: SM 2540C-2011
QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 92402195001
METHOD BLANK: 2395173 Matrix: Water
Associated Lab Samples: 92402195001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 10/08/18 23:54
LABORATORY CONTROL SAMPLE: 2395174
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 254 101 90-110
SAMPLE DUPLICATE: 2395175
92402195001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 274 268 2
SAMPLE DUPLICATE: 2395176
92402028009 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 1000 1030 3
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full.
Date: 10/18/2018 04:49 PM without the written consent of Pace Analytical Services.LLC. Page 18 of 29

Pace Analytical Services,LLC
Analytical® 9800 Kincey Ave. Suite 100
,2e Huntersville,NC 28078
wnxpacelahs.coin [phone]
QUALITY CONTROL DATA
Project: Annual PPA 10/2/18
Pace Project No.. 92402195
QC Batch: 435392 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92402195001
METHOD BLANK: 2396421 Matrix: Water
Associated Lab Samples: 92402195001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Ammonia mg/L ND 0.10 10/10/18 18:33
LABORATORY CONTROL SAMPLE: 2396422
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 4.8 96 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2396423 2396424
MS MSD
92402154001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L 6.1 5 5 112 11.3 102 104 90-110 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2396425 2396426
MS MSD
92402194003 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L ND 5 5 5.1 5.2 102 103 90-110 1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 19 of 29

Pace Analytical Services,LLC
e 9800 Kincey Ave. Suite 100
ace Analytical Huntersville,NC 28078
www.pace/ah&can [phone]
QUALITY CONTROL DATA
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
QC Batch: 435071 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351 2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Associated Lab Samples: 92402195001
METHOD BLANK: 2395141 Matrix: Water
Associated Lab Samples: 92402195001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Kjeldahl,Total mg/L ND 0.50 10/09/18 01:44
LABORATORY CONTROL SAMPLE 2395142
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Kjeldahl,Total mg/L 10 10.6 106 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2395143 2395144
MS MSD
92401310001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Kjeldahl,Total mg/L 389 10 10 416 433 274 439 90-110 4 M6
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2395145 2395146
MS MSD
92402210001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Kjeldahl,Total mg/L 25.8 10 10 32.4 33.8 67 80 90-110 4 J(M1)
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 20 of 29

Pace Analytical Services,LLC
e
aceAnalytical 9800 KineyAve. Suite 100
Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
QC Batch: 436107 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate+Nitrite,preserved
Associated Lab Samples: 92402195001
METHOD BLANK: 2399759 Matrix: Water
Associated Lab Samples: 92402195001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,NO2 plus NO3 mg/L ND 0.020 10/13/18 11:15
LABORATORY CONTROL SAMPLE: 2399760
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen.NO2 plus NO3 mg/L 2.5 2.7 109 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2399761 2399762
MS MSD
92402778002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen.NO2 plus NO3 mg/L ND 2.5 2.5 2.5 2.5 100 100 75-125 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2399763 2399764
MS MSD
92402236002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,NO2 plus NO3 mg/L 0.75 2.5 2.5 2.5 2.4 68 66 75-125 2 J(M1)
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
•
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 21 of 29

Pace Analytical Services,LLC
x 9800 Kincey Ave. Suite 100
i aceAnalytical Huntersville,NC 28078
www.pacerens.com [phone]
QUALITY-CONTROL DATA
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
QC Batch: 434935 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus,Total
Associated Lab Samples: 92402195001
METHOD BLANK: 2394521
Matrix: Water
Associated Lab Samples: 92402195001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 10/08/18 15:34
LABORATORY CONTROL SAMPLE: 2394522
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.6 105 90-110 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2394523 2394524
MS MSD
92402094002 Spike Spike MS MSD MS MSD °A)Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus mg/L 0.43 2.5 2.5 3.0 3.1 101 106 90-110 4
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2394525 2394526
MS MSD
92402410001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus mg/L 4.1 2.5 2.5 7.0 7.2 115 123 90-110 3 J(M1)
•
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 22 of 29

Pace Analytical Services,LLC
e 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville,NC 28078
www.pacetaos.con [phone]
QUALITY CONTROL DATA
Project: Annual PPA 10/2/18 1
Pace Project No.: 92402195
QC Batch: 435345 Analysis Method: EPA 420.4 Rev 1.0 1993
QC Batch Method: EPA 420.4 Rev 1.0 1993 Analysis Description: 420.4 Phenolics
Associated Lab Samples: 92402195001
1
METHOD BLANK: 2396283 Matrix: Water
• Associated Lab Samples: 92402195001
Blank Reporting _
Parameter Units Result Limit Analyzed Qualifiers
Phenol mg/L ND 0.010 10/11/18 13:35 BC
I
LABORATORY CONTROL SAMPLE: 2396284
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phenol mg/L .05 0.050 100 90-110 BC
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2396285 2396286
MS MSD
92401994001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phenol mg/L ND .05 .05 0.057 0.058 97 100 90-110 2 BC
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2396287 2396288
MS MSD
92402014001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phenol mglL 0.054 .05 .05 0.099 0.10 90 99 90-110 4 BC
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 23 of 29

Pace Analytical Services,LLC
A
ace Analytical 9800 Kincey Ave. Suite 100
' Huntersville,NC 28078
mry pacelabs.Cam [phone]
QUALITY CONTROL DATA
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
QC Batch: 435691 Analysis Method: SM 4500-CN-E-2011
QC Batch Method, SM 4500-t N-E-2011 Analysis Description: 4500CNE Cyanide,Total
Associated Lab Samples: 92402195001
METHOD BLANK: 2397735 Matrix: Water
Associated Lab Samples: 92402195001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Cyanide mg/L ND 0.0080 10/12/18 12:56
LABORATORY CONTROL SAMPLE: 2397736
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Cyanide mg/L .1 0.10 103 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2397737 2397738
MS MSD
92402393002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Cyanide mg/L ND .1 1 0.074 0.086 68 80 80-120 14 J(M1),J(R1)
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2397739 2397740
MS MSD
92402411002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Cyanide mg/L 0.0052 I .1 .1 0.096 0.097 91 92 80-120 1
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 24 of 29

Pace Analytical Services,LLC
e
aceAnalytical 9800 Kinsey Ave. Suite 100
' Huntersville.NC 28078
Wvw.pacetabs.corn [phone]
QUALIFIERS
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous To Count
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services-Asheville
PASI-C Pace Analytical Services-Charlotte
ANALYTE QUALIFIERS
The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.
BC The same analyte was detected in an associated blank at a concentration above 1/2 the reporting limit but below the
laboratory reporting limit.
J(M1) Estimated Value.Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)
recovery.
J(R1) Estimated Value.RPD value was outside control limits.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
Q Sample held beyond the accepted holding time.
c2 Acid preservation may not be appropriate for the analysis of 2-Chloroethylvinyl ether.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 25 of 29

KIn/ Pace Analytical Services,LLC
9800 Kincey Ave. Suite 100
ace Analytical x Huntersville,NC 28078
,rww,f cA'ans.ecru [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Annual PPA 10/2/18
Pace Project No.: 92402195
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92402195001 Wastewater Effluent EPA 16648 436876
92402195001 Wastewater Effluent EPA 200.7 Rev 4.4 1994 434971 EPA 200.7 Rev 4.4 1994 435065
92402195001 Wastewater Effluent EPA 1631E 434997 EPA 1631E 435217
92402195002 Field Blank Effluent EPA 1631E 434997 EPA 1631E 435217
92402195001 Wastewater Effluent EPA 625.1 435351 EPA 625.1 435694
92402195001 Wastewater Effluent EPA 624.1 434841
92402195001 Wastewater Effluent SM 2540C-2011 435084
92402195001 Wastewater Effluent EPA 350.1 Rev 2.0 1993 435392
92402195001 Wastewater Effluent EPA 351.2 Rev 2.0 1993 435071 EPA 351.2 Rev 2.0 1993 435087
92402195001 Wastewater Effluent EPA 353.2 Rev 2.0 1993 436107
92402195001 Wastewater Effluent EPA 365.1 Rev 2.0 1993 434935 EPA 365.1 Rev 2.0 1993 434994
92402195001 Wastewater Effluent EPA 420.4 Rev 1.0 1993 435345 EPA 420.4 Rev 1.0 1993 435739
92402195001 Wastewater Effluent SM 4500-CN-E-2011 435691 SM 4500-CN-E-2011 435940
REPORT OF LABORATORY ANALYSIS
This report shaft no:be reproduced,except in full,
Date: 10/18/2018 04:49 PM without the written consent of Pace Analytical Services,LLC. Page 26 of 29

Document Name: Document Revised:February 7,2018
ac6Ana/yticai Sample Conditton Upon Rtrcelpt(SCUR) Page 1 of 2
Document No.: Issuing Authority: I
F•CAR•CS•033-Rev.06 Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville❑ Eden[] Greenwood
❑ Huntersvtlle❑ Raleigh Mechanicsville[]
sa"mple'cgndition;°.=; Client
6pon.Receint WO# : 92402195
Project
Courier: . ec- --(;_(Fed Ex _..._ .UP5 — ['LISPS ......._ . °Clteht 111111 111111111 1111 I/I
❑Commercial (pace ['Other:
Custody Seal Present? 'Dyes h� 92402195
60a1�_Seals Intact? Oyes ANo
°ate/Initials Person Examining Contents: ___
Packing Material: OBubble Wra (r17r• /J
P bble Bags one `'���
Thermo / ❑ Other Biological Tissue Frozen?
IR Gun ID: d°? Type of Ice: ❑Blue �N
of 0Yes ONo RN/A
7�� — ane '"
Cooler Temp('C):---c� Correction Fact :Ad Subtract(.C) (^).
Cooler Temp Corrected('C):�� Temp houtd be above freezing to 6'C
,�,/ �mpies out of temp criteria.Samples on Ice,cooling process
USDA Regulated Soil (IAJ/ie/A,water sample) hasDeBun
Did samples=tire quarantine zone within the United States:CA,NY,or SC(check maps)? Did samples originate from a foreign source(Internationally,
■Yes
Including Hawaii and Puerto Rico)?Dyes
Comments/011cre•cowChain of Custod Present? i
C es ■No QN/A 1.
.iiiiG " ■ ■ 2.
Rush Turn Around Time Requested?
Yes la jtErM
Sufficient Volume?
G es •No ✓♦N/A
Correct Containers Used?
-Pace Containers Used? LilY- ❑No DI/A
C es NINo ■N/A
Containers Intact? I
glYes ❑N ON/A 7,
Dissolved analysis:Samples Field Filtered? gl Sample Labels Match CDC? Yes ■No G'IA g,
•es Duo ON/A 9.
-Includes Date/Time/ID/Analysis Matrix: 'If
Headspace in VOA Vials('S-6mm)?
Trip Blank Present? Yes I No �N/a 10.
Des II No ( N/A 1L
Trip Blank Custody Seals Present?
[]Yes dine ❑ruM
COMMENTS/SAMPLE DISCREPANCY
Field Dab Required? QYes QNo
(r
at IFICATION/AESOLUTION 0 S t containers:
Person contacted: i
Date/Time:
Project Manager SCURF Review:
Date: U El"
Project Manager SRF Review:
-, Date: 'G �t f
Page 27 of 29

I.
--____---._
pa •-• o . CO v Cl •.n y ,..0
3
o T Hama
G ni
i In In C M
g o •—� BP4U-125 ml Plastic Unpreserved(N/A)(Cl-) m 3 i
,0 - A
cO St
nP3U-250 mL Plastic Unpreserved(N/A) O r 27 m„ 4 x-
`I �— 03 3 3
7,1 n a a 0 N
N ° ~ BP2U-50D mL Plastic Unpreserved(N/A) pt 0 ix
n •" ° O
8P1U-1 liter Plastic Unpreserved(N/A) ••-•• at S
a ? Ir- Cka
1 O 3 ,O^. a_ai
BP45-125 mL Plastic H2SO4(pH e 2)(C(.) I�
lb 0
a
cy
3 47
'ArAdd���� BP3N-250 mL plastic HNO3(pH<2) o 14.7 o d a
°O = BP4Z-]25 mt Plastic ZN Acetate&NaOH(>9)
Z CIVA 7 Q. ^� -w
2 ' "'� BD4C•115 mL Plastic NaOH (pH>12)(CI-) N n S
n = tr m
a 1"Q��(t'G�•V�Ide-mouthed Glass jar Unpreserved ro 0 j a
r7 u Q i3/
Q
a 3 o C AG1U-1 liter Amber Unpreserved(N/A)(CH
.Q o G y`
o N / 0 2 0 rD n�i
m /! /� ' 3
�� AG1H•1 liter Amber HO(pH<2) N f a n 3
o
T. ro O a
3 G3U-250 mL Amber U i m r(b =' T o 3 z r► Unpreserved(N/A)(CI J
3 a. r
M ° C O y T D f7 ^ O
AG15-1 liter Amber H2SO4(pH<2) o 0 r�° 3
n pZ7...gg
M AG3S-250 mL Amber H2504(pH<2) u' W 7.
2. m w Z
a m >o Z d
j. y AG3A(063A)-250 mL Amber NH4U(N/A)(0-) S O3
M m 0
° DG9H-40 ML VGA HO (N/A) w
_i s
3
f t2 p in
a VG9T-40 ml VOA Na252O9(N/A) rti C
g n a
a `� 1
VG9O 40 mi.VOA Unp(N/A)
°: O
FirDG9P-40 ml VGA H3PO4(N/A) r 3
o o
Ln
n H
rn O o
o VOA((6 vials per kit)5035 kit IN/A)
-� 0 `. ,' ' v c
z 3 �. ?di 3
to
V/GK(3 vials per kit)•VPH/Gas kit(N/A) CO •
,��i^/•
o N
oa SPST-125 ml5ter(le Plastic(N/A-lab) al A' S p3y
_ . �+ D `° 4
a A o
s J �� SP2T-250 mL Sterile Plastic (N/A-lab) O 0 e s
al
m /J // J GG�/ /e ° W o
/ I / p o
/ / BP3A-250 mL Plastic(NH2)2504(9.3-9.7) `.,,, �"
9) o
AGOU-].00 mL Amber Unpreserved vials(N/A) to
~
0
s VSGlf20mLScintlllatlonvials (N/A) C
IT
iv
laDG9U-40 mLAmber Unpreserved vials(N/A) co
\CD
I-.
00
to
ND
Co
O_
(
Na
ID

r' ;��fa:rA ,� 'or/:k ' e1 ini•7.��'w n ' i ITEM R t3 a
z
1• c, n
'r1 f $ Cn m O ' id
f: ( r
rn _
r i R
c
1.2
SS dddS
v yro A g'
0 6 m
R z a'
��' MATRU(COD'e (ue+•e:IC codes mlenJ a
......©SAAPLETYPE (G=GRA9 C- CIdP) o a
il i3_XI 131:14
g p
o.cs Leh co -o. _
z w
N'�i? o R., •
.0 , xi
o Z
,V CC �7 , r
3'!sr f Sy i' m
71
A .--I. � 2, SA/4PLETEMP AT COLLECTION u.! 1ft
. 30f CGHTAINE.35 i
unpraeervad n fi CD
'�
+L7. HCI ( V'A3 ., p S'
O D
`` NaOH 2. ss X r 7 7
`7 .` W. • IT X
• e, Øj 'Th825nDC �, ^.p
y K,R• �.......- OII erd Groesa.y 1654 HE-h� �' CD
rn 5. v } ' ...�■�..�ammo'' , Z f, N 0
i,f :� MITTP S� {1 3 0
n `I a 0
h• 111111111111 CYande c
( r G- ;, ,III in
III� S' ,5r
1uuIuIIpHI __ I
:, i
y ,c rs3 , a tG,
T E7..P in C • `g. •.
t RenldualCh'c or ) •'Y. .
,f',j7;1 M o, o.
ReCo)fod oo i qi''. �}� R- •
tco
^uslooy k In
,--.. {� yY:ii U 2
Seaiad ,y `l' r' 'mo- #ki�?••��/'• O
P,c1 o, t. rr'`:r.J s
Page 29 of 29

Toxicity Testing
Ceriodaphnia dubia
Pimephales Promelas

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NC0020605 Renewal Tar-Pamlico
Part E.4 Toxicity Testing Data
Summary of Submitted Biomonitoring Test Information
Organism: Ceriodaphnia Dubia
Date Pipe Collection Testing
Submitted Number Date Date Method Summary
01/30/14 001 01/20/14 01/22/14 Chronic Pass/Fail PASS
04/24/14 001 04/14/14 04/16/14 Chronic Pass/Fail PASS
07/17/14 001 07/07/14 07/09/14 Chronic Pass/Fail PASS
10/23/14 001 10/13/14 10/15/14 Chronic Pass/Fail PASS
02/05/15 001 01/26/15 01/28/15 Chronic Pass/Fail PASS
04/20/15 001 04/06/15 04/08/15 Chronic Pass/Fail PASS
07/21/15 001 07/06/15 07/08/15 Chronic Pass/Fail PASS
10/28/15 001 10/12/15 10/14/15 Chronic Pass/Fail PASS
01/15/16 001 01/04/16 01/06/16 Chronic Pass/Fail PASS
04/14/16 001 04/04/16 04/06/16 Chronic Pass/Fail PASS
07/28/16 001 07/18/16 07/20/16 Chronic Pass/Fail PASS
11/02/16 001 10/24/16 10/26/16 Chronic Pass/Fail PASS
01/26/17 001 01/16/17 01/18/17 Chronic Pass/Fail PASS
04/20/17 001 04/10/17 04/12/17 Chronic Pass/Fail PASS
06/28/17 001 04/18/17 04/20/17 Chronic Pass/Fail PASS
07/20/17 001 07/10/17 07/12/17 Chronic Pass/Fail PASS
10/13/17 001 10/02/17 10/04/17 Chronic Pass/Fail PASS
01/23/18 001 01/08/18 01/10/18 Chronic Pass/Fail PASS
05/01/18 001 04/16/18 04/18/18 Chronic Pass/Fail PASS
07/20/18 001 07/09/18 07/11/18 Chronic Pass/Fail PASS
10/11/18 001 10/01/18 10/03/18 Chronic Pass/Fail PASS
Organism: Pimephales Promelas(Fathead Minnow Fish)
Date Pipe Collection Testing
Submitted Number Date Date Method Summary
09/11/15 001 08/31/15 09/02/15 Chronic Multi-Conc. ChV> 15.84%
09/24/15 001 09/16/15 09/18/15 Chronic Multi-Conc. ChV> 15.84%
10/09/15 001 09/28/15 09/30/15 Chronic Multi-Conc. ChV> 15.84%
10/23/15 001 10/12/15 10/14/15 Chronic Multi-Conc. ChV> 15.84%
08/04/16 001 07/17/16 07/19/16 Chronic Multi-Conc. ChV>32%
02/06/17 001 01/15/17 01/17/17 Chronic Multi-Conc. ChV>32.00%
05/24/18 001 04/15/18 04/17/18 Chronic Multi-Conc. ChV>32.00%