WQ0000838_2014 Residual Annual Report - Volume I of III_20150302

GRA NVILLE FARMS, INC.
2014 ANNUAL LAND APPLICATION OF
RESIDUAL BIO-SOLIDS REPORT
CLASS B PROGRAM
VOLUME I OF III
Certification
Source & Field Summaries
Source Analytical
Submitted by:
Soil Plus
208 Williams Street
Greenville, North Carolina 27858
February 19, 2015

February 18, 2015
NCDENR-DWQ
Information.Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Re: 2014 LAND APPLICATION ANNUAL REPORT
Granville farms, Inc. "Class B" Program
NC Permit No.: WQ0000838
Soil Plus Project No. 200705.A10
Information Processing Unit:
Soil Plus, LLC (Soil Plus) is submitting all monitoring and reporting requirements as
specified in the above referenced permit for Granville Farms, Inc. Soil Plus compiled this
report using data gathered during the compliance year. This data includes (1) certification
form, (2) residual sampling, (3) field loading calculations, (4) pathogen and vector attraction
reduction documentation; (5) standard soil fertility nutrient analysis. Due to the size of the
permit there are three volumes that are included with this submission. The first volume
includes Certification/Summaries, Loading Calculations & Analytical Data (Nutrient, 503
Metals, TCLP), the second volume includes Field Loading Summary, and the third volume
includes Pathogen & Vector data and 2014 Soil Samples.
Granville Farms, Inc. conducted application events on permitted fields in Franklin,
Granville, Halifax, Johnston, Nash, Vance, Wake, & Warren Counties during 2014. A total
of 1,942.29 Dry Tons or 22,192,085 gallons of permitted residual bio-solids were land
applied to permitted fields.
If there is any further information required or questions regarding this annual report please
do not hesitate to contact me or the Granville Farms, Inc. (919-690-8000) for further
assistance.
Respectfully,
C. Scott Carpenter, L.S.S.
North Carolina Nutrient Management Planner
208 Williams st. Andy Smith, Granville Farms
Greenville, NC 27858 Jason Smith, Granville Farms
t [phone]
f [phone]
www.soilplus.net

i Granville Farms, Inc. 2014 Land Application of Residual Biosolids Annual Report
Volume I of III Table of Contents — Permit Certification and Source Analytical
APPENDIX
CONTENT
1
Annual Certification Form
Source Summary Report
Field Loading Summary
2
Amherst WWTP RSSF
Field Loading Calculations
Analytical
3
Barclay Downs WWTP RSSF
Field Loading Calculations
Analytical
4
Briarwood Farms WWTP RSSF
Field Loading Calculations
Anal 'cal
5
Carolina Meadows WWTP RSSF
Field Loading Calculations
Analytical
6
Cole Park Plaza RSSF
Field Loading Calculations
Analytical
7
Colvard Farms RSSF
Field Loading Calculations
Analytical
8
Crooked Creek WWTP RSSF
Field Loading Calculations
Analytical
9
Cross Creek Mobile Estates RSSF
Field Loading Calculations
Analytical
10
Deerchase WWTP RSSF
Field Loading Calculations
Analytical
11
Enfield WTP RSSF
Field Loading Calculations
Analytical
12
Enfield WWTP RSSF
Field Loading Calculations
Anal tical
13
Fearrington Utility WWTP RSSF
Field Loading Calculations
Analytical
14
Franklin County WWTP RSSF
Field Loading Calculations
Analytical
15
Goveno?s Club WWTP RSSF
Field Loading Calculations
- Anal tical
16
Hawthorne Subdivision WWTP RSSF
Field Loading Calculations
Analytical
17
Henderson WRF RSSF
Field Loading Calculations
Analytical
18
Johnston County WWTP RSSF
Field Loading Calculations
Analytical
19
Kenly WWTP RSSF
Field Loading Calculations
Anal 'cal
20
Kerr Lake Regional WTP RSSF
Field Loading Calculations
Anal tical
21
Kings Grant Subdivision RSSF
Field Loading Calculations
Analytical
APPENDIX
CONTENT
22
Kittrell Job Corp RSSF
Field Loading Calculations
Analytical
23
Knightdale MHP RSSF
Field Loading Calculations
Analytical
24
Little Creek WWTP RSSF
Field Loading Calculations
Analytical
25
Mallard Crossing WWTP RSSF
Field Loading Calculations
Analytical
26
Nature Trails WWTP RSSF
Field Loading Calculations
Analytical
27
Neuse Colony WWTP RSSF
Field Loading Calculations
Analytical
28
Neuse River Village RSSF
Field Loading Calculations
Analytical
29
Neuse River WWTP RSSF
Field Loading Calculations
Analytical
30
Pope Industrial RSSF
Field Loading Calculations
Analytical
31
SGWASA WTP RSSF
Field Loading Calculations
Analytical
32
SGWASA WWTP RSSF
Field Loading Calculations
Analytical
33
Shearon Harris NPP RSSF
Field Loading Calculations
Analytical
34
Sunset WTP RSSF
Field Loading Calculations
Analytical
35
Tar River Regional WWTP RSSF
Field Loading Calculations
Analytical
36
Tar River WTP RSSF
Field Loading Calculations
Analytical
37
Town of Louisburg RSSF
Field Loading Calculations
Analytical
38
Town of Warrenton WWTP RSSF
Field Loading Calculations.
Analytical
39
Tradewinds WWTP RSSF
Field Loading Calculations
Analytical
40
Whippoorwill WWTP RSSF
Field Loading Calculations
Analytical
41
Wildwood Green WWTP RSSF
Field Loading Calculations
Analytical
42
Willowbrook WWTP RSSF
Field Loading Calculations
Analytical

ANNUAL LAND APPLICATION CERTIFICATION FORM
PermitNumber FacilityName Land Application Operator County Phone Number
WQ0000838 Granville Farms, Inc. Class B Granville Farms, Inc. Granville [phone]
Year: 2014
Land application of residuals as allowed by the permit occurred during the past calendar year? If No, skip Part A, and Part Yes No
B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the ❑� ❑�
residuals were handled.
Part A - Residuals Application Summary:
Total number of application fields in the permit: 185
Total number of fields utilized for land application during the year: 71
Total amount of dry tons applied during the year for all application sites: 1942.29
Total number of acres utilizes for land application during the year: 1274.34
Part B - Annual Compiance Statement:
Facility was compliant during calendar year with all conditions of the land application permit? Yes No
Including but not limited to items 1-13 below) issued by the Division of Water Quality ❑d ❑[7
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6
3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory
results are attached
4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached
5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of
certified laboratory results are attached
6.The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T
7. All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated
facilities).
8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated
facilities).
9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was
received from the Division of Water Quality
10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to
include appropriate actions and remediations.
11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit.
12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13. All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and
complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations."
Bryan A. Smith, President 4—a,~-r
�✓ 2-19-2015
Permittee Name and Title (type or print):
Signature of Preparer* Date
(if different from Permittee)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26)
t_
Thursday, February 19, 2015
Signature of Permittee
Signature of Land Applier Date
(if different from Permittee)

L.
Source Summary
L_
WWTP Volume Applied Dry Tons
Amherst WWTP
53,400
4.34 -
Barclay Downs WWTP
17,800
0.37
Beachwood WWTP
35,600
1.19-
Briarwood Farms WWTP
71,200
4.16
Carolina Meadows WWTP
236,500
28.60 _
Cole Park Plaza
40,050
1.00
Colvard Farms
40,050
2.51,
Crooked Creek WWTP
129,050
15.07
Cross Creek Mobile Estates
75,650
1.89
Deerchase WWTP
66,750
1.84—
Enfield n;Q
56,000
4.41E
Enfield WWTP
210,000
24.87-
Fearrington Utility WWTP
216,000
32.25--
Franklin County WWTP
686,000
30.32--
Govenor's Club WWTP
231,400
9.65--
Hawthorne Subdivision WW17P
311,500
28.58'
Henderson WRIT
3,325,000
293.51-
Johnston County WWTP
234,000
33.18_
Kenly Regional WWTP
903,000
53.09-
Kerr Lake Regional T
3,430,000
141.60s
Kings Grant Subdivision
26,700
1.89,
Kittrell Job Corp
21,000
2.29—
Knightdale Mobile Home Park
97,900
6.25_
Little Creek WWTP
1,051,168
106.52_
Mallard Crossing WWTP
124,600
9.35-
Nature Trails MHP WWTP
178,000
10.39-
Neuse Colony WWTP
902,850
22.59 -
Neuse River Village
84,550
2.82-
Neuse River WWTP
89,367
12.04-
Pope Industrial Park
13,350
0.17--
SGWASA WTP
1,274,000
175.32-
5..w�p
Friday, February 20, 2015 Page 1 of 2

WWTP Volume Applied Dry Tons
SGWASA WWTP
3,073,000
339.20 —
Shearon Harris NPP
231,400
0.87-
i
Sunset
280,000
51.04-
Tar River Regional WWTP
1,605,500
176.01--
Tar River �
623,000
124.12-
Town of Louisburg
931,000
94.73-
Town of Warrenton WWTP
882,000
80.91_
Tradewinds WWTP
111,250
1.86-
Whippoorwill Valley WWTP
40,050
1.05
Wildwood Green WWTP
111,250
7.42_
Willowbrook WWTP
71,200
3.03,
Grand Total
22,192,085
1,942.29
Friday, February 20, 2015 Page 2 of 2

YEAR TO DATE FIELD LOADING SUMMARY
CROPS USED AND VOLUME APPLIED
PERMITTED CROPS AND LOADING RATES
Acres Volume
Crop 1 PAN Crop 2 PAN
Total P
Crop 1
PAN 1 Crop 2 PAN 2
Field Used Applied
Total DT lbs/Ac. lbs/Ac.
lbs/Ac.
Crop 1 Name PAN
Used Crop 2 Name PAN Used
Site# 1677
1 8.55 385,000
35.56 199.07
181.95
Fescue Pasture 250
79.6%
2 44.26 588,000
50.36 58.96
48.94
Fescue Pasture 250
23.6%
Site# 2009
Site# 375
2 56.47
1,560,000
109.05
3 19.59
434,000
28.29
4 17.44
332,000
24.07
1 12.85
259,000
19.34
2 16.32
287,000
21.87
3 7.02
374,000
31.07
66.88
84.12
Fescue Pasture
250
26.8%
109.47
68.21
Fescue Pasture
250
43.8%
57.75
60.46
Fescue Pasture
250
23.1%
39.43
73.97
Fescue Pasture
250
15.8%
25.44
74.95
Fescue Pasture
250
10.2%
118.09
200.41
Fescue Pasture
250
47.2%
February 18, 2015 Page 1 of 8

YEAR TO DATE FIELD LOADING SUMMARY
CROPS USED AND VOLUME APPLIED PERMITTED CROPS AND LOADING RATES
Acres Volume Crop 1 PAN Crop 2 PAN Total P Crop 1 PAN 1 Crop 2 PAN 2
Field Used Applied Total DT lbs/Ac. lbs/Ac. lbs/Ac. Crop 1 Name PAN Used Crop 2 Name PAN Used
4 32.24 766,000 80.27 47.33 103.26 Fescue Pasture 250 18.9%
Site# 4801-CH
4
41.66
58,856
8.27
10.57
16.82
Fescue Pasture
250
4.2%
Site# 4801 JH
1
10.07
112,000
7.27
31.60
54.28
Fescue Pasture
250
12.6%
2
6.51
189,000
20.07
43.13
110.43
Fescue Pasture
250
17.3%
3
11.66
315,000
32.82
47.93
118.50
Fescue Pasture
250
19.2%
4
2.76
62,000
6.21
33.19
43.41
Fescue Pasture
250
13.3%
5
18.81
420,000
33.88
61.41
96.58
Fescue Pasture
250
24.6%
6
11.53
357,000
35.99
58.33
136.79
Fescue Pasture
250
23.3%
7
6.88
180,000
19.70
47.60
65.72
Fescue Pasture
250
19.0%
8
15.87
378,000
29.85
60.22
145.45
Fescue Pasture
250
24.1%
February 18, 2015 Page,2 of 8

- - ----
---
r ----, - -- -
--
r -- ---- -- f --- r--^ r---
f - -'i
YEAR TO DATE FIELD
LOADING SUMMARY
CROPS USED AND VOLUME APPLIED
PERMITTED CROPS AND LOADING
RATES
Acres
Volume Crop 1 PAN Crop 2 PAN
Total P
Crop 1 PAN 1
Crop 2 PAN 2
Field
Used
Applied Total DT lbs/Ac. lbs/Ac.
lbs/Ac.
Crop 1 Name PAN Used Crop 2 Name
PAN Used
Site# 4801-WP
1
21.76
950,650 84.70 99.30
187.75
Fescue Pasture 250 39.7%
2
37.48
724,050 58.58 55.45
82.19
Fescue Pasture 250 22.2%
3
8.76
116,400 8.81 40.10
109.85
Fescue Pasture 250 16.0%
4
30.18
774,300 73.66 67.02
125.61
Fescue Pasture 250 26.8%
Site# 7823
8A 28.84 1,243,500 56.87 38.12 23.28 81.45 Common 220 17.3% .Annual Ryegrass - 50 46.6%
Bermudagrass Pasture
8B 29.28 1,368,150 68.87 43.97 28.64 58.17 Common 220 20.0% Annual Ryegrass - 50 57.3%
Bermudagrass Pasture
Site# 8015-01
1 10.37 286,000 31.12 183.76 202.23 Fescue Pasture 250 73.5%
2 36.47 245,500 48.11 21AO 21.71 Fescue Pasture 250 8.6%
3 20.53 292,500 44.70 85A5 74.57 Fescue Pasture 250 34.2%
Site# 8015-02
February 18, 2015 Page 3 of 8

YEAR TO DATE FIELD LOADING SUMMARY
CROPS USED
AND VOLUME APPLIED
PERMITTED CROPS AND LOADING RATES
Acres
Volume
Crop 1 PAN Crop 2 PAN
Total P
Crop 1
PAN 1 Crop 2 PAN 2
Field
Used
Applied
Total DT
lbs/Ac. lbs/Ac.
lbs/Ac.
Crop 1 Name
PAN
Used Crop 2 Name PAN Used
1
21.45
737,796
73.38
119.78
166.67
Fescue Pasture
250
47.9%
2
19.61
161,000
25.10
34.09
30.51
Fescue Pasture
250
13.6%
3
7.13
158,000
20.23
117.86
120.56
Fescue Pasture
250
47.1%
4
12.03
216,500
26.67
98.76
104.92
Fescue Pasture
250
39.5%
6
7.81
110,500
12.16
84.12
97.35
Fescue Pasture
250
33.6%
7
28.48
599,000
51.96
47.85
57.29
Fescue Pasture
250
19.1%
8
12.02
288,000
33A6
98.65
147.27
Fescue Pasture
250
39.5%
Site# GF
11
60.8
1,312,000
108.95
72.03
69.08
Fescue Pasture
250
28.8%
12
7.4
42,000
4.92
31.90
30.72
Fescue Pasture
250
12.8%
3
32.4
56,000
7.24
5.83
16.67
Fescue Pasture
250
2.3%
February 18, 2015 Page 4 of 8

YEAR TO DATE FIELD
LOADING SUMMARY
CROPS USED AND VOLUME APPLIED
PERMITTED CROPS AND LOADING RATES
Acres
Volume
Crop 1 PAN Crop 2 PAN
Total P
Crop 1 PAN 1 Crop 2 PAN 2
Field
Used
Applied
Total DT lbs/Ac. lbs/Ac.
lbs/Ac.
Crop 1 Name PAN Used Crop 2 Name PAN Used
4
43.2
14,000
1.81 1.09
3.13
Fescue Pasture 250 0.4%
6
80
294,000
24.36 13.91
15.44
Fescue Pasture 250 5.6%
7
20.5
266,000
26.06 54.48
75.85
Fescue Pasture 250 21.8%
8
25.1
265,000
19.09 41.51
38.35
Fescue Pasture 250 16.6%
9
51.3
864,000
63.14 50.83
52.41
Fescue Pasture 250 20.3%
Site# JC
6 15.64 39,000 5.53 15.76 25.95 Fescue Pasture 250 6.3%
Site# JL
1 5.37 25,926 2.63 16.50 36.50 Wheat, Grain 100 16.5%
2 6.28 77,778 7.88 42.32 93.62 Wheat, Grain 100 42.3%
3 5.43 58,334 5.91 36.71 81.21 Wheat, Grain 100 36.7%
Site# JM
February 18, 2015 Page 5 of 8

YEAR TO DATE FIELD LOADING SUMMARY
CROPS USED AND VOLUME APPLIED
PERMITTED CROPS AND LOADING RATES
Acres
Volume
Crop 1 PAN Crop 2 PAN
Total P
Crop 1
PAN 1 Crop 2 PAN 2
Field
Used
Applied
Total DT
lbs/Ac. lbs/Ac.
lbs/Ac.
Crop 1 Name
PAN
Used Crop 2 Name PAN Used
2
13.3
441,000
42.40
143.89
139.03
Fescue Pasture
250
57.6%
3
8
105,000
11.73
79.50
74.83
Fescue Pasture
250
31.8%
4
1.3
28,000
2.80
97.67
100.69
Fescue Pasture
250
39.1%
5
10.1
231,000
24.45
113.80
110.38
Fescue Pasture
250
45.5%
6
8.8
133,000
10.56
52.56
51.32
Fescue Pasture
250
21.0%
7
5.2
77,000
6.56
52.84
57.14
Fescue Pasture
250
21.1%
8
1.8
70,000
7.72
201.68
199.00
Fescue Pasture
250
80.7%
9
24.68
427,000
36.18
69.89
58.71
Fescue Pasture
250
28.0%
Site# JTs
6 8.71 104,000 14.75
7 10.59 291,408 34.98
Site# MP
February 18, 2015
75.48 124.26 Oats (Hay/Pasture) 100 75.5% Sorghum
(Hay/Pasture)
72.84 2.64 114.63 Oats (Hay/Pasture) 100 72.8% Sorghum
(Hay/Pasture)
Page 6of8
50
50 5.3%

YEAR TO DATE FIELD
LADING SUMMARY
CROPS USED AND VOLUME APPLIED
PERMITTED CROPS AND LOADING RATES
Acres
Volume
Crop 1 PAN Crop 2 PAN
Total P
Crop 1
PAN 1
Crop 2 PAN 2
Field
Used
Applied
Total DT
lbs/Ac. lbs/Ac.
lbs/Ac.
Crop 1 Name
PAN
Used
Crop 2 Name
PAN Used
1
0.87
19,771
2.00
77.65
171.79
Common
220
35.3%
Annual Ryegrass -
50
Bermudagrass Hay
Hay
10
2.57
39,541
4.01
52.57
116.30
Common
220
23.9%
Annual Ryegrass -
50
Bermudagrass Hay
Hay
2
1.69
52,721
5.34
106.59
235.82
Common
220
48.5%
Annual Ryegrass -
50
Bermudagrass Hay
Hay
3
9.16
177,934
18.03
66.37
146.84
Common
220
30.2%
Annual Ryegrass -
50
Bermudagrass Hay
Hay
4
0.48
13,180
1.34
93.82
207.57
Common
220
42.6%
Annual Ryegrass -
50
Bermudagrass Hay
Hay
5
2.21
32,951
3.34
50.95
112.71
Common
220
23.2%
Annual Ryegrass -
50
Bermudagrass Hay
Hay
6
1.98
46,131
4.67
79.61
176.12
Common
220
36.2%
Annual Ryegrass -
50
Bermudagrass Hay
Hay
7
1.17
19,771
2.00
57.74
127.74
Common
220
26.2%
Annual Ryegrass -
50
Bermudagrass Hay
Hay
8
6.88
138,394
14.02
68.73
152.06
Common
220
31.2%
Annual Ryegrass -
50
Bermudagrass Hay
Hay
9
6.04
112,033
1135
63.38
140.21
Common
220
28.8%
Annual Ryegrass -
50
Bermudagrass Hay
Hay
Site# RE
February 18, 2015 Page 7 of 8

Site# SE
YEAR TO DATE FIELD
LOADING .SUMMARY
CROPS USED AND VOLUME APPLIED
PERMITTED CROPS AND LOADING RATES
Acres
Volume
Crop 1 PAN Crop 2 PAN
Total P
Crop 1
PAN 1 Crop 2 PAN 2
Field
Used
Applied
Total DT lbs/Ac. lbs/Ac.
lbs/Ac.
Crop 1 Name
PAN
Used Crop 2 Name PAN Used
3
46.6
340,000
21.85 14.56
18.56
Fescue Pasture
250
5.8%
2
31.92
259,000
17.18 19.01
24.94
Fescue Pasture
250
7.6%
4
20.12
105,011
16.98 27.28
32.93
Fescue Pasture
250
10.9%
6
6.2
119,500
. 15.02 68.06
97.17
Fescue Pasture
250
27.2%
7
17.26
166,000
23.16 58.41
50.66
Fescue Pasture
250
23.4%
Total 22,192,085 1,942.29
February 18, 2015 Page 8 of 8

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO061638
Laboratory 1 Environment
1, Inc.
Laboratory 2
Sample or CompositeDate 12/2/2014
Parameter (mg/Rg) Class A Clas B
Aluminum
N/A
N/A
4,563
Ammonia Nitrogen
N/A
N/A
3,849
Arsenic
41
75
2.5
Cadmium
39
85
1
Calcium
N/A
N/A
13,992
Copper
1,500
4,300
1064
Lead
300
840
10
Magnesium
N/A
N/A
2,951
Mercury
17
57
0.2
Molybdenum
N/A
75
5
Nickel
420
420
8
Nitrate -Nitrite Nitrogen
N/A
N/A
4
Percent Solids
N/A '
N/A
1.95
pH (no units)
N/A
N/A
6.50
Phosphorus
N/A
N/A
8,547
Potassium
N/A
N/A
2,943
PAN (Inj./Inc.)
N/A
N/A
3,923
PAN (Surface)
N/A
N/A
1,998
Selenium
100
100
5
Sodium
N/A
N/A
17,644
SAR
N/A
N/A
4.93
TRN
N/A
N/A
4,081
Zinc
2,800
7,500
2037
Source Name Amherst WWTP
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

yrR
Facility Amherst VvW'IP
Sampling Date 12/2/2014
% Solids 1.95
Mineralization Rate 0.30
Gallons per DT 12,297.85
pH 6.5
FIELD LOADING ESTIMATES
Sodium Absorpotion 4.93 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 4,081 lbs./1,000 gal 0.66
Ammonia Nitrogen (mg/Kg) 3,849.00 lbs./1,000 gal 0.63
Nitrate -Nitrite (mg/Kg) 3.93 lbs./1,000 gal 0.00
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 1,998 lbs./1,000 gal 0.32
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 3,923 lbs./1,000 gal 0.64
Volatization Rate= 0.5 Surface Application
1.0 Injection /Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1st Year
2nd Year
3rd Year
4th Year
5th Year
Potassium lbs./1,000 gal 0.48
Phosphorus lbs./1,000 gal 1.39
Calcium lbs./1,000 gal 2.28
Magnesium lbs./1,000 gal 0.48
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
2.50
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
1064.00
Copper lbs./1,000 gal
0.17
Lead (mg/Kg)
10.00
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.20
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
8.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
2037.00
Zinc lbs./1,000 gal
0.33
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg)
(lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
4,081
1,998
4.00
2,083
4,081
3,923 7.85
158
2,083
312
0.62
1,771
158
24 0.05
135
1,771
133
0.27
1,638
135
10 0.02
125
1,638
61
0.12
1,576
125
5 0.01
120
1,576
30
0.06
1,547
120
2 0.00
118
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 2,534 5.07
Total 3,963 7.93

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J
ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO040606
Laboratory 1 Environmental
Conservation
Laboratory 2
Sample or CompositeDate 10/29/2014
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
11,400
Ammonia Nitrogen
N/A
N/A
69
Arsenic
41
75
OVER
Cadmium
39
85
1.85
Calcium
N/A
N/A
43,100
Copper
1,500
4,300
570
Lead
300
840
OVER
Magnesium
N/A
N/A
27,600
Mercury
17
57
1.33
Molybdenum
N/A
75
29.4
Nickel
420
420
113
Nitrate -Nitrite Nitrogen
N/A
N/A
5,400
Percent Solids
N/A
N/A
0.50
PH (no units)
N/A
N/A
6.40
Phosphorus
N/A
N/A
1,900
Potassium
N/A
N/A
30,600
PAN (Inj./Inc.)
N/A
N/A
21,048
PAN (Surface)
N/A
N/A
21,014
Selenium
100
100
19.3
Sodium
N/A
N/A
7,160
SAR
N/A
N/A
0.47
TKN
N/A
N/A
52,000
Zinc
2,800
7,500
1050
Source Name Barclay Downs W WTP
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
/-:I. 02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

€
A GNUN
-- FIELD LOADING ESTIMATES
- Facility Barclay Downs WWIP
Sampling Date 10/29/2014
-- % Solids 0.5
Mineralization Rate 0.3
Gallons per DT 47,961.63
PH 6.4
Sodium Absorpotion 0.47 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not
Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 52,000 lbs./1,000 gal 2.17
Potassium lbs./1,000 gal
1.28
Ammonia Nitrogen (mg/Kg) 69.00 lbs./1,000 gal 0.00
Phosphorus lbs./1,000 gal
0.08
Nitrate -Nitrite (mg/Kg) 5,400.00 lbs./1,000 gal 0.23
Calcium lbs./1,000 gal
1.80
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
1.15
PAN (mg/Kg) 21,014 lbs./1,000 gal 0.88
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 21,048 lbs./1,000 gal 0.88
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
j 1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Limits (mg/Kg)
41
39
1,500
300
17
r` 1st Year
I
2nd Year
3rd Year
4th Year
5th Year
Class B Ceiling
Limits (mg/Kg)
75
85
4,300
840
57
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
123.00
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
1.85
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
570.00
Copper lbs./1,000 gal
0.02
Lead (mg/Kg)
1120.00
Lead lbs./1,000 gal
0.05
Mercury (mg/Kg)
1.33
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
113.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
19.30
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
1050.00
Zinc lbs./1,000 gal
0.04
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TEN
(mg/kg)
(lbs/DT)
(mgXg)
TEN
(mg/kg) (lbs/DT)
(mg/Kg)
52,000
21,014
42.03
30,986
52,000
21,048 42.10
30,952
30,986
4,648
9.30
26,338
30,952
4,643 9.29
26,309
26,338
1,975
3.95
24,363
26,309
1,973 3.95
24,336
24,363
914
1.83
23,449
24,336
913 1.83
23,423
23,449
440
0.88
23,010
23,423
439 0.88
22,984
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 28,990 57.98
Total 29,016 58.03

www.encolabs.com
SAMPLE DETECTION SUMMARY
Client ID: Barclay Sludge
Lab ID:
C413798-01
Analvte
Results
Has
MU
P46
Units
Method Note
% Solids
0.5
0.1
0.1
% by Weight
% Solids
i Ammonia as N
69
D
17
38
mg/kg dry
EPA 350.1
`j Arsenic - Total
123
19.3
96.5
mg/kg dry
EPA 6010C
Calcium - Total
43100
B
1080
4820
mg/kg dry
EPA 6010C QB-01
— Copper - Total
570
36.7
96.5
mg/kg dry
EPA 6010C
Lead - Total
1120
23.2
96.5
mg/kg dry
EPA 6010C
Magnesium - Total
27600
B
125
4820
mg/kg dry
EPA 6010C QB-01
Molybdenum - Total
29.4
1
19.3
96.5
mg/kg dry
EPA 6010C
Nickel- Total
113
1
69.5
482
mg/kg dry
EPA 6010C
III
Nitrate/Nitrite as N
5400
D
770
1900
mg/kg dry
EPA 353.2
— pH
6.4
1.0
1.0
pH Units
EPA 9045D
Potassium - Total
30600
772
4820
mg/kg dry
EPA 6010C
Sodium - Total
7160
1160
4820
mg/kg dry
EPA 6010C
Total Solids
0.52
0.0010
0.0010
% by Weight
SM 2540G1997
Zinc - Total
1050
212
482
mg/kg dry
EPA 6010C
Client ID: Barclav Slud a
Lab ID:
C413798-OIREI
Analvte
Results
rha
l&
M
Units
Jwetbod Notes
Aluminum - Total
11400
405
1930
mg/kg dry
EPA 6010C
Phosphorus
1900
D
35
96
mg/kg dry
EPA 365.4
_ Total Kjeldahl Nitrogen
5200
D
170
180
mg/kg dry
EPA 351.2
I
L
r,
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 11

www.encolabs.com
ANALYTICAL RESULTS
Description: Barclay Sludge Lab Sample ID:C413798-01 Received: 10/29/14 13:12
Matrix: Sludge Sampled:10/29/14 10:45 Work Order: C413798
Project: Barclay -Annual Sludge Analysis Sampled By: Andy Stevens % Solids: 0.52
Metals by EPA 6000/7000 Series Methods
^ - &NCO Cary certified ana/yte [NC 591]
Analyse [CAS Numberl Results
Fim
Units
2E
MDL
PQ6
Batch
Method
Analyzed
]iX Notes
Aluminum [7429-90-5]A
11400
mg/kg dry
1
405
1930
4K13030
EPA 6010C
11/14/14 13:46
JDH
Arsenic[7440-38-2]A
123
mg/kg dry
1
19.3
96.5
4KO5014
EPA 6010C
11/07/14 13:04
JDH
Cadmium [7440-43-9]A
< 1.85
mg/kg dry
1
1.85
9.65
4KO5014
EPA 6010C
11/07/14 13:04
JDH
Calcium [7440-70-2]A
43100
B
mg/kg dry
1
1080
4820
4KO5014
EPA 6010C
11/07/14 13:04
JDH QB-01
Copper [7440-50-8]A
570
mg/kg dry
1
36.7
96.5
4KO5014
EPA 6010C
11/07/14 13:04
JDH
Lead [7439-92-1]A
1120
mg/kg dry
1
23.2
96.5
4KO5014
EPA 6010C
11/07/14 13:04
JDH
Magnesium [7439-95-4]A
27600
B
mg/kg dry
1
125
4820
4KO5014
EPA 6010C
11/07/14 13:04
JDH QB-01
Mercury[7439-97-6]A
< 3.33
mg/kg dry
1
1.33
4.63
4KO4012
EPA 7471E
11/04/14 17:50
T11)
Molybdenum [7439-98-7]A
29.4
J
mg/kg dry
1
19.3
96.5
4KO5014
EPA 6010C
11/07/14 13:04
JDH
Nickel[7440-02-O]A
113
J
mg/kg dry
1
69.5
482
4KO5014
EPA 6010C
11/07/14 13:04
JDH
Potassium [7440-09-7]A
30600
mg/kg dry
1
772
4820
4KO5014
EPA 6010C
11/07/14 13:04
JDH
Selenium [7782-49-2]A
< 19.3
mg/kg dry
1
19.3
96.5
4KO5014
EPA 6010C
11/07/14 13:04
JDH
Sodium [7440-23-5]A
7160
mg/kg dry
1
1160
4820
4KO5014
EPA 6010C
11/07/14 13:04
JDH
Zinc[7440-66-6]A
1050
mg/kg dry
1
212
482
4KO5014
EPA 6010C
11/07/14 13:04
JDH
Classical Chemistry Parameters
Analyte rCAS Numberl
Results
Elm
Units
DF
MU
EU
Batch
Method
Analyzed
Notes
% Solids
0.5
% by Weight
1
0.1
0.1
4KO3019
% Solids
10/31/14 16:01
MMR
Ammonia as N [7664-41-7]
69
D
mg/kg dry
2
17
38
4329005
EPA 350.1
10/30/14 09:54
SHA
Nitrate/Nitrite as N
5400
D
mg/kg dry
97.5
770
1900
4KO4005
EPA 353.2
11/04/14 13:14
SHA
pH
6.4
pH Units
1
1.0
1.0
4130037
EPA 9045D
10/30/14 15:50
MMR
Phosphorus[7723-14-0]
1900
D
mg/kg dry
5
35
96
4131009
EPA 365.4
11/03/14 14:56
clv
Total Kjeldahl Nitrogen
5200
D
mg/kg dry
2
170
180
4131008
EPA 351.2
11/03/14 14:36
clv
Total Solids
0.52
% by Weight
1
0.0010
0.0010
4331024
SM 254OG-1997
10/31/14 16:01
MMR
I FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 11

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO060577 Source Name Beachwood WWI'P
Laboratory 1 Environmental
Conservation
Laboratory 2
Sample or CompositeDate 12/2/2014
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
7,720
Ammonia Nitrogen
N/A
N/A
74
Arsenic
41
75
12.9
Cadmium
39
85
1.4
Calcium
N/A
N/A
14,800
Copper
1,500
4,300
140
Lead
300
840
15.4
Magnesium
N/A
N/A
3,250
Mercury
17
57
8.56
Molybdenum
N/A
75
12.9
Nickel
420
420
46.3
Nitrate -Nitrite Nitrogen
N/A
N/A
3,800
Percent Solids
N/A
N/A
0.80
pH (no units)
N/A
N/A
6.20
Phosphorus
N/A
N/A
4,200
Potassium
N/A
N/A
5,240
PAN (Inj./Inc.)
N/A
N/A
19,452
PAN (Surface)
N/A
N/A
19,415
Selenium
100
100
12.9
Sodium
N/A
N/A
13,900
SAR
N/A
N/A
2.40
TKN
N/A
N/A
52,000
Zinc
2,800
7,500
829
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
14-�- 02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

P,�
FIELD LOADING ESTIMATES
Facility Beachwood VAVFP
Sampling Date 12/2/2014
% Solids 0.8
Mineralization Rate 0.3
Gallons per DT 29,976.02
PH 6.2
Sodium Absorpotion 2.40 <5.0 Safe 5.0 -10.0 Careful'Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 52,000 lbs./1,000 gal 3.47
Ammonia Nitrogen (mg/Kg) 74.00 lbs./1,000 gal 0.00
�-
Nitrate-Nitrite (mg/Kg) 3,800.00 lbs./1,000 gal 0.25
1 PLANT AVAILABLE NITROGEN SURFACE APPLIED
_� PAN (mg/Kg) 19,415 lbs./1,000 gal 1.30
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 19,452 lbs./1,000 gal 1.30
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
( i
4th Year
5th Year
HEAVY METAL CONCENTRATION
Potassium lbs./1,000 gal 0.35
Phosphorus lbs./1,000 gal 0.28
Calcium lbs./1,000 gal 0.99
Magnesium lbs./1,000 gal 0.22
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
12.90
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.40
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
140.00
Copper lbs./1,000 gal
0.01
Lead (mg/Kg)
15.40
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
8.56
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
46.30
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
12.90
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
829.00
Zinc lbs./1,000 gal
0.06
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
132,548
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
52,000
19,415 38.83
.32,585
52,000
19,452 38.90
32,548
32,585
4,888 9.78
27,697
4,882 9.76
27,666
27,697
2,077 4.15
25,620,
27,666
2,075 4.15
25,591
25,620
961 1.92
24,659
25,591
960 1.92
24,631
24,659
462 0.92
24,197
24,631
462 0.92
24,170
Equations
1st Yr. PAN (mg/Kg)=(VM x (TICN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 27,803 55.61
Total 27,830 55.66

www.encolabs.aom
SAMPLE DETECTION SUMMARY
Client ID: Beachwood Sludge
Lab ID:
C413799-01
— Analyte
Results
EIa4
MPS,
P4.L
Units
Method
Notes
- -- % Solids
0.8
0.1
0.1
% by Weight
% Solids
Aluminum - Total
7720
270
1290
mg/kg dry
EPA 6010C
Ammonia as N
74
D
28
63
mg/kg dry
EPA 350.1
Cadmium - Total
1.40
1
1.23
6.43
mg/kg dry
EPA 6010C
Calcium - Total
14600
B
720
3220
mg/kg dry
EPA 6010C
QB-01
Copper - Total
140
24.4
64.3
mg/kg dry
EPA 6010C
Magnesium - Total
3250
B
83.6
3220
mg/kg dry
EPA 6010C
QB-01
Mercury - Total
8.56
0.888
3.09
mg/kg dry
EPA 7471E
Nitrate/Nitrite as N
3800
BD
500
1200
mg/kg dry
EPA 353.2
QB-01
pH
6.2
1.0
1.0
pH Units
EPA 9045D
--- Phosphorus
4200
D
95
380
mg/kg dry
EPA 365.4
Potassium - Total
5240
515
3220
mg/kg dry
EPA 6010C
Sodium - Total
13900
772
3220
mg/kg dry
EPA 6010C
Total Solids
0.78
0.0010
0.0010
% by Weight
SM 2540G-1997
—j Zinc - Total
829
142
322
mg/kgmg/kg dry
EPA 6010C
Client ID: Beachwood Slud a
Lab ID:
C413799-01REi
Analyt€
Results
Flag
Mom,
E"
Units
Method
Notes
Total Kjeldahl Nitrogen
52000
D
1600
3000
mg/kg dry
EPA 351.2
�. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 11
_I

ce-NLOO)
www.encolabs.com
ANALYTICAL RESULTS
Description: Beachwood Sludge Lab Sample ID:C413799-01 Received: 12/02/14 13:10
Matrix: Sludge Sampled: 12/02/14 09:00 Work Order: C413799
Project: Beachwood -Annual Sludge Analysis Sampled By: Ray Dixon % Solids: 0.78
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary ceitified analyte [NC 5911
Analvte rCAS Numberl
Results
fift
Units
P-E
MU
PQ.L
Batch
Method
Analyzed
!}y( Notes
Aluminum [7429-90-5]A
7720
mg/kg dry
1
270
1290
41-10026
EPA 6010C
12/12/14 11:07
JDH
Arsenic[7440-38-2]A
< 12.9
mg/kg dry
1
12.9
64.3
41-10026
EPA 6010C
12/12/14 11:07
JDH
Cadmium [7440-43-9]A
1.40
J
mg/kg dry
1
1.23
6.43
4LI0026
EPA 6010C
12/12/14 11:07
JDH
Calcium [7440-70-2]A
14800
B
mg/kg dry
1
720
3220
4L10026
EPA 6010C
12/12/14 11:07
JDH QB-01
Copper[7440-50-B]A
140
mg/kg dry
1
24.4
64.3
4L10026
EPA 6010C
12/12/14 11:07
JDH
Lead [7439-92-1]A
< 15.4
mg/kg dry
1
15.4
64.3
41-10026
EPA 6010C
12/12/14 11:07
JDH
Magnesium [7439-95-4]A
3250
B
mg/kg dry
1
83.6
3220
41-10026
EPA 6010C
12/12/14 11:07
JDH QB-01
Mercury [7439-97-6]A
8.56
mg/kg dry
1
0.888
3.09
41-11033
EPA 7471B
12/12/14 14:44
T1D
Molybdenum [7439-98-7]A
< 12.9
mg/kg dry
1
12.9
64.3
41-10026
EPA 6010C
12/12/14 11:07
JDH
Nickel[7440-02-0]A
< 46.3
mg/kg dry
1
46.3
322
4L10026
EPA 6010C
12/12/14 11:07
JDH
Potassium [7440-09-7]A
5240
mg/kg dry
1
515
3220
41-10026
EPA 6010C
12/12/14 11:07
JDH
Selenium [7782-49-2]A
< 12.9
mg/kg dry
1
12.9
64.3
41-10026
EPA 6010C
12/12/14 11:07
JDH
Sodium [7440-23-5]A
13900
mg/kg dry
1
772
3220
41-10026
EPA 6010C
12/12/14 11:07
JDH
Zinc [7440-66-6]A
829
mg/kg dry
1
142
322
4L10026
EPA 6010C
12/12/14 11:07
JDH
Classical Chemistry Parameters
Analyte rCAS Numberl
Results
flag
Units
PIE
MK
M
Batch
Method
Analyzed
Notes
% Solids
0.8
% by
1
0.1
0.1
4LO3035
% Solids
12/03/14 15:33
MMR
Weight
Ammonia as N [7664-41-7]
74
D
mg/kg dry
5
28
63
4L08028
EPA 350.1
12/09/14 10:01
SHA
Nitrate/Nitrite as N -
3800
BD
mg/kg dry
97.5
S00
1200
4LO4004
EPA 353.2
12/04/14 16:31
AJB QB-01
pH
6.2
pH Units
1
1.0
1.0
4LO2040
EPA 9045D
12/02/14 15:50
MMR
Phosphorus[7723-14-0]
4200
D
mg/kg dry
30.2
95
380
41-11005
EPA 365.4
12/15/14 15:03
AJB
Total Kjeldahl Nitrogen
52000
D
mg/kg dry
50
1600
3000
4L11006
EPA 351.2
12/15/14 16:05
AJB
Total Solids
0.78
% by
1
0.0010
0.0010
4LO3034
SM 254OG-1997
12/03/14 15:33
MMR
Weight
FINAL
This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 11

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO062740
Laboratory 1 Environmental
Conservation
Laboratory 2
Sample or CompositeDate 12/23/2014
Parameter (mg/Eg) Class A Clas B
Aluminum
N/A
N/A
7,590
Ammonia Nitrogen
N/A
N/A
190
Arsenic
41
75
7.01
Cadmium
39
85
1.65
Calcium
N/A
N/A
19,600
Copper
1,500
4,300
159
Lead
300
840
8.42
Magnesium
N/A
N/A
4,130
Mercury
17
57
0.415
Molybdenum
N/A
75
8.44
Nickel
420
420
25.2
Nitrate -Nitrite Nitrogen
N/A
N/A
270.00
Percent Solids
N/A
N/A
1.40
PH (no units)
N/A
N/A
6.90
Phosphorus
N/A
N/A
18,000
Potassium
N/A
N/A
5,650
PAN (Inj./Inc.)
N/A
N/A
1,963
PAN (Surface)
N/A
N/A
1,868
Selenium
100
100
16.7
Sodium
N/A
N/A
12,000
SAR
N/A
N/A
2.40
TEN
N/A
N/A
5,200
Zinc
2,800
7,500
929
Source Name Briarwood Farms WWTP
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations.
0 -c-a- 02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

FIELD LOADING ESTIMATES
Facility Briarwood Farms WWTP
Sampling Date 12/23/2014
r % Solids 1.4
Mineralization Rate 0.3
Gallons per DT 17,129.15
PH 6.9
Sodium Absorpotion 2.40 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land .Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 5,200 lbs./1,000 gal 0.61
Potassium lbs./1,000 gal
0.66
Ammonia Nitrogen (mg/Kg) 190.00 lbs./1,000 gal 0.02
Phosphorus lbs./1,000 gal
2.10
Nitrate -Nitrite (mg/Kg) 270.00 lbs./1,000 gal 0.03
Calcium lbs./1,000 gal
2.29
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.48
PAN (mg/Kg) 1,868 lbs./1,000 gal 0.22
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 1,963 lbs./1,000 gal 0.23
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
1 St Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
7.01
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.65
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
159.00
Copper lbs./1,000 gal
0.02
Lead (mg/Kg)
8.42
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.42
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
25.20
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
16.70
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
929.00
Zinc lbs./1,000 gal
0.11
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TEN
(mg/kg) (lbs/DT)
(mg/Kg)
TRN
(mg/kg) (lbs/DT)
(mg/Kg)
5,200
1,868
3.74
3,332
5,200
1,963 3.93
3,237
3,332
500
1.00
2,832
3,237
486 0.97
2,751
2,832
212
0.42
2,620
2,751
206 0.41
2,545
2,620
98
0.20
2,522
2,545
95 0.19
2,450
2,522
47
0.09
2,474
2,450
46 0.09
2,404
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 2,726 5.45
Total 2,796 5.59

www.encolabs.com
SAMPLE DETECTION SUMMARY
Client ID: Briarwood Sludge
Lab ID:
C413800-01
Awe
Results
Elm
N
Units
Method
Notes
% Solids
1.4
0.1
0.1
% by Weight
% Solids
Aluminum - Total
7590
147
701
mg/kg dry
EPA 6010C
Cadmium -Total
1.65
0
0.673
3.51
mg/kg dry
EPA 6010C
Calcium - Total
19600
B
393
1750
mg/kg dry
EPA 6010C
QB-01
Copper - Total
159
13.3
35.1
mg/kg dry
EPA 6010C
Magnesium - Total
4130
B
45.6
1750
mg/kg dry
EPA 6010C
QB-01
Molybdenum - Total
8.44
3
7.01
35.1
mg/kg dry
EPA 6010C
pH
6.9
1.0
1.0
pH Units
EPA 90451)
Phosphorus
18000
D
980
2700
mg/kg dry
EPA 365.4
Potassium - Total
5650
281
1750
mg/kg dry
EPA 6010C
Selenium - Total
16.7
J
7.01
35.1
mg/kg dry
EPA 6010C
Sodium - Total
12000
421
1750
mg/kg dry
EPA 6010C
Total Kjeldahl Nitrogen
52000
D
2900
3200
mg/kg dry
EPA 351.2
Total Solids
1.4
0.0010
0.0010
% by Weight
SM 2540G-1997
Zinc - Total
929
77.2
175
mg/kgmg/kg dry
EPA 6010C
Client ID: Briarwood Sludge
Lab ID:
C413800-01RE3
Analvte
Results
Elan
M L
EU
Units
Method
NQM
Ammonia as N
190
D
15
34
mg/kg dry
EPA 350.1
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 11

F-
www.encolabs.com
ANALYTICAL RESULTS
Description: Briarwood Sludge Lab Sample ID:C413800-01 Received: 12/23/14 11:00
Matrix: Sludge Sampled:12/23/14 10:26 Work Order: C413800
Project: Briarwood-Annual Sludge Analysis Sampled By: Eric Riggins % Solids: 1.43
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Elag
Units
DF
MU
M
Batch
Method
Analyzed
j}y Notes
Aluminum [7429-90-5]A
7590
mg/kg dry
1
147
701
4L29017
EPA 6010C
01/02/15 13:01
JDH
Arsenic[7440-38-2]^
< 7.01
mg/kg dry
1
7.01
35.1
41-29017
EPA 6010C
01/02/15 13:01
JDH
Cadmium [7440-43-9]A
1.65
J
mg/kg dry
1
0.673
3.51
41-29017
EPA 6010C
01/02/15 13:01
JDH
Calcium [7440-70-2]A
19600
B
mg/kg dry
1
393
1750
41-29017
EPA 6010C
01/02/15 13:01
JDH QB-01
Copper [7440-50-8]A
159
mg/kg dry
1
13.3
35.1
41-29017
EPA 6010C
01/02/15 13:01
JDH
Lead [7439-92-1]A
< 8.42
mg/kg dry
1
8.42
35.1
4L29017
EPA 6010C
01/02/15 13:01
JDH
Magnesium [7439-95-4]A
4130
B
mg/kg dry
1
45.6
1750
41-29017
EPA 6010C
01/02/15 13:01
JDH QB-01
Mercury[7439-97-6]A
< 0.415
mg/kg dry
1
0.415
1.44
41-24027
EPA 7471B
12/30/14 13:12
T1D
Molybdenum [7439-98-7]A
8.44
J
mg/kg dry
1
7.01
35.1
41-29017
EPA 6010C
01/02/15 13:01
JDH
Nickel[7440-02-0]A
< 25.2
mg/kg dry
1
25.2
175
4L29017
EPA 6010C
01/02/15 13:01
JDH
Potassium [7440-09-7]A
5650
mg/kg dry
1
281
1750
41-29017
EPA 6010C
01/02/15 13:01
JDH
Selenium [7782-49-2]A
16.7
J
mg/kg dry
1
7.01
35.1
41.29017
EPA 6010C
01/02/15 13:01
JDH
Sodium [7440-23-5]A
12000
mg/kg dry
1
421
1750
4L29017
EPA 6010C
01/02/15 13:01
JDH
Zinc [7440-66-6]A
929
mg/kg dry
1
77.2
175
41-29017
EPA 6010C
01/02/15 13:01
JDH
Classical Chemistry Parameters
Analyte rCAS Numberl
Results
Pl6g
Units
lE
MU
E"
Batch
Method
Analyzed
gy Notes
Solids
1.4
% by
1
0.1
0.1
4L24021
% Solids
12/24/14 11:05
MMR
Weight
Ammonia as N [7664-41-7]
190
D
mg/kg dry
5
15
34
4L31003
EPA 350.1
12/31/14 12:04
SHA
Nitrate/Nitrite as N.
< 270
D
mg/kg dry
97.5
270
660
41-30004
EPA 353.2
12/30/14 10:46
SHA R-01
PH
6.9
pH Units
1
1.0
1.0
4L24007
EPA 9045D
12/24/14 08:35
A]B
Phosphorus [7723-14-0]
18000
D
mg/kg dry
400
980
2700
SA02004
EPA 365.4
01/05/15 10:53
SHA
Total Kjeldahl Nitrogen
52000
D
mg/kg dry
100
2900
3200
SA02003
EPA 351.2
01/05/15 09:39
SHA
Total Solids
1.4
% by
1
0.0010
0.0010
41-24020
SM 254OG-1997
12/24/14 11:05
MMR
Weight
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 11
I_

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO056413
Laboratory 1 Environmental
Conservation
Laboratory 2
Sample or CompositeDate 12/19/2014
Parameter (mg/Yg) Class A Clas B
Aluminum
N/A
N/A
61800
Ammonia Nitrogen
N/A
N/A
1,600
Arsenic
41
75
3.5
Cadmium
39
85
0.992
Calcium
N/A
N/A
12,900
Copper
1,500
4,300
339
Lead
300
840
5.14
Magnesium
N/A
N/A
2,300
Mercury
17
57
0.181
Molybdenum
N/A
75
4.42
Nickel
420
420
24.6
Nitrate -Nitrite Nitrogen
N/A .
N/A
240.00
Percent Solids
N/A
N/A
2.90
PH (no units)
N/A
N/A
7.10
Phosphorus
N/A
N/A
29,000
Potassium
N/A
N/A
3,100
PAN (Inj./Inc.)
N/A
N/A
.15,460
PAN (Surface)
N/A
N/A
14,660
Selenium
100
100
5.68
Sodium
N/A
N/A
3,670
SAR
N/A
N/A
1.33
TKN
N/A
N/A
47,000
Zinc
2,800
7,500
980
Source Name Carolina Meadows WWTP
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
1d - c-It- 02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26

FIELD LOADING ESTIMATES
! Facility Carolina Meadows V/WTP
Sampling Date 12/19/2014
f % Solids 2.9
IL Mineralization Rate 0.3
Gallons per DT 8,269.25
C., pH 7.1
Sodium Absorpotion 1.33 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 47,000 lbs./1,000 gal 11.37
Ammonia Nitrogen (mg/Kg) 1,600.00 lbs./1,000 gal 0.39
L- Nitrate -Nitrite (mg/Kg) 240.00 lbs./1,000 gal 0.06
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 14,660 lbs./1,000 gal 3.55
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 15,460 lbs./1,000 gal 3.74
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
Potassium lbs./1,000 gal 0.75
Phosphorus lbs./1,000 gal 7.01
Calcium lbs./1,000 gal 3.12
Magnesium lbs./1,000 gal 0.56
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
3.50
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.99
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
339.00
Copper lbs./1,000 gal
0.08
Lead (mg/Kg)
5.14
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.18
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
24.60
Nickel lbs./1,000 gal
0.01
Selenium (mg/Kg)
5.68
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
980.00
Zinc lbs./1,000 gal
0.24
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TEN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
47,000
14,660 29.32
32,340
47,000
15,460 30.92
31,540
32,340
4,851 9.70
27,489
31,540
4,731 9.46
26,809
27,489
2,062 4.12
25,427
26,809
2,011 4.02
24,798
25,427
954 1.91
24,474
24,798
930 1.86
23,868
24,474
459 0.92
24,015
23,868
448 0.90
23,421
Equations
1st Yr. PAN (mg/Kg)=(IvlR x (TKN-NI-I3))+(VR x NI-I3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 22,985 45.97
Total 23,579 47.16

www.encolabs.com
SAMPLE DETECTION SUMMARY
LClient
ID: Carolina Meadows Sludge
Lab ID:
C413801-01
Analvte
Results
Fing
MPS
EQL
Units
Method
Notes
% Solids
2.9
0.1
0.1
% by Weight
% Solids
Aluminum - Total
6800
73.5
350
mg/kg dry
EPA 6010C
Ammonia as N
1600
D
140
310
mg/kg dry
EPA 350.1
Cadmium - Total
0.992
3
0.336
1.75
mg/kg dry
EPA 6010C
Calcium -Total
12900
B
196
875
mg/kg dry
EPA 6010C
QB-01
Copper - Total
339
6.65
17.5
mg/kg dry
EPA 6010C
Lead - Total
5.14
3
4.20
17.5
mg/kg dry
EPA 6010C
Magnesium - Total
2300
B
22.7
875
mg/kg dry
EPA 6010C
QB-01
Molybdenum -Total
4.42
3
3.50
17.5
mg/kg dry
EPA 6010C
Nickel- Total
24.6
3
12.6
87.5
mg/kg dry
EPA 6010C
Nitrate/Nitrite as N
240
3D
140
330
mg/kg dry
EPA 353.2
R-01
pH
7.1
1.0
1.0
pH Units
EPA 9045D
Potassium - Total
3100
140
875
mg/kg dry
EPA 6010C
Selenium - Total
5.68
3
3.50
17.5
mg/kg dry
EPA 6010C
Sodium - Total
3670
210
875
mg/kg dry
EPA 6010C
Total Kjeldahl Nitrogen
47000
D
1500
1600
mg/kg dry
EPA 351.2
Total Solids
2.9
0.0010
0.0010
% by Weight
SM 254OG-1997
Zinc - Total
980
38.5
87.5
mg/kg dry
EPA 6010C
Client ID: Carolina Meadows Sludge
Lab ID:
C413801-01RE1
AoalM
Results
flag
MP-L
P_Q.L
Units
Method
Notes
Phosphorus
29000
D
500
1400
mg/kg dry
EPA 365.4
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 11

c4a
www.encolabs.com
ANALYTICAL RESULTS
Description: Carolina Meadows Sludge Lab Sample ID: C413801-01 Received: 12/19/14 12:20
Matrix: Sludge Sampled:12/19/14 10:20 Work Order: C413801
Project: Carolina Meadows -Annual Sludge Sampled By: Eric Wiggins % Solids: 2.86
(Metals
by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analvte rCAS Numberl
Results
lag
UnitS
PE
MDL
POL
Batch
Method
Analyzed
!3]C Notes
Aluminum [7429-90-5]^
6800
mg/kg dry
1
73.5
350
41-29017
EPA 6010C
01/02/15 13:27
JDH
Arsenic [7440-38-2]^
< 3.50
mg/kg dry
1
3.50
17.5
41-29017
EPA 6010C
01/02/15 13:27
JDH
Cadmium [7440-43-9]^
0.992
J
mg/kg dry
1
0.336
1.75
41-29017
EPA 6010C
01/02/15 13:27
JDH
Calcium [7440-70-2]^
12900
B
mg/kg dry
1
196
875
41-29017
EPA 6010C
01/02/15 13:27
JDH QB-01
Copper[7440-50-8]^
339
mg/kg dry
1
6.65
17.5
41-29017
EPA 6010C
01/02/15 13:27
JDH
Lead [7439-92-1]^
it
5.14
J
mg/kg dry
1
4.20
17.5
4129017
EPA 6010C
01/02/15 13:27
JDH
Magnesium [7439-95-4]^
2300
B
mg/kg dry
1
22.7
875
41-29017
EPA 6010C
01/02/15 13:27
JDH. QB-01
Mercury [7439-97-6]^
< 0.181
mg/kg dry
1
0.181
0.630
41-24027
EPA 7471B
12/30/14 13:14
T1D
Molybdenum [7439-98-7]^
4.42
J
mg/kg dry
1
3.50
17.5
41-29017
EPA 6010C
01/02/15 13:27
JDH
Nickel[7440-02-0]^
24.6
J
mg/kg dry
1
12.6
87.5
41-29017
EPA 6010C
01/02/15 13:27
JDH
. , Potassium [7440-09-7]^
3100
mg/kg dry
1
140
875
41-29017
EPA 6010C
01/02/15 13:27
JDH
Selenium [7782-49-2]^
5.68
J
mg/kg dry
1
3.50
17.5
41-29017
EPA 6010C
01/02/15 13:27
JDH
Sodium [7440-23-5]^
3670
mg/kg dry
1
210
875
41-29017
EPA 6010C
01/02/15 13:27
JDH
Zinc [7440-66-6]^
980
mg/kg dry
1
38.5
87.5
41-29017
EPA 6010C
01/02/15 13:27
JDH
Classical Chemistry Parameters
Analyte rCAS Numberl
Results
f]Bg
Units
RE
IAL
M
Batch
Method
Analyzed
Notes
% Solids
2.9
% by
1
0.1
0.1
41-22037
% Solids
12/22/14 16:08
MMR
Weight
Ammonia as N [766441-7]
1600
D
mg/kg dry
90
140
310
41-31003
EPA 350.1
12/31/14 10:51
SHA
Nitrate/Nitrite as N
240
JD
mg/kg dry
97.5
140
330
41-23015
EPA 353.2
12/23/14 13:24
SHA R-01
PH
7.1
pH Units
1
1.0
1.0
41-24007
EPA 9045D
12/24/14 08:35
AJB
Phosphorus[7723-14-0]
29000
D
mg/kg dry
400
500
1400
SA02004
EPA 365.4
01/05/15 12:04
SHA
Total Kjeldahl Nitrogen
47000
D
mg/kg dry
100
1500
1600
5A02003
EPA 351.2
01/05/15 09:41
SHA
Total Solids
2.9
% by
1
0.0010
0.0010
41-22036
SM 254OG-1997
12/22/14 16:08
MMR
Weight
r
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of l l

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO051314
Laboratory 1 Environmental
Conservation
Laboratory 2
Sample or CompositeDate 11/4/2014
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
3,380
Ammonia Nitrogen
N/A
N/A
220
Arsenic
41
75
16.2
Cadmium
39
85
1.55
Calcium
N/A
N/A
19,900
Copper
1,500
4,300
260
Lead
300
840
20.8
Magnesium
N/A
N/A
4,100
Mercury
17
57
0.836
Molybdenum
N/A
75
16.2
Nickel
420
420
58.2
Nitrate -Nitrite Nitrogen
N/A
N/A
7,400
Percent Solids
N/A
N/A
0.60
PH (no units)
N/A
N/A
7.40
Phosphorus
N/A
N/A
29,000
Potassium
N/A
N/A
5,170
PAN (Inj./Inc.)
N/A
N/A
27,354
PAN (Surface)
N/A
N/A
27,244
Selenium
100
100
20.5
Sodium
N/A
N/A
38,400
SAR
N/A
N/A
5.00
TKN
N/A
N/A
66,000
Zinc
2,800
7,500
382
Source Name Cole Park Plaza
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations.
ldr-r� 02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

l
AGMA
Facility Cole Park Plaza
Sampling Date 11/4/2014
% Solids 0.6
Mineralization Rate 0.3
Gallons per DT 39,968.03
pH 7.4
J
FIELD LOADING ESTIMATES
Sodium Absorpotion 5.00 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 66,000 lbs./1,000 gal 3.30
Ammonia Nitrogen (mg/Kg) 220.00 lbs./1,000 gal 0.01
Nitrate -Nitrite (mg/Kg) 7,400.00 lbs./1,000 gal 0.37
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 27,244 lbs./1,000 gal 1.36
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 27,354 lbs./1,000 gal 1.37
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1st Year
[` 2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
Potassium lbs./1,000 gal 0.26
Phosphorus lbs./1,000 gal 1.45
Calcium lbs./1,000 gal 1.00
Magnesium lbs./1,000 gal 0.21
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
16.20
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.55
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
260.00
Copper lbs./1,000 gal
0.01
Lead (mg/Kg)
20.80
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.84
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
58.20
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
20.50
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
382.00
Zinc lbs./1,000 gal
0.02
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation. Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TEN
(mg/kg) (lbs/DT)
(m g/Kg)
TEN
(mg/kg) (lbs/DT)
(mg/Yg)
66,000
27,244 54.49
38,756
66,000
27,354 54.71
38,646
38,756
5,813 11.63
32,943
38,646
5,797 11.59
32,849
32,943
2,471 4.94
30,472
32,849
2,464 4.93
30,385
30,472
1,143 2.29
29,329
30,385
1,139 2.28
29,246
29,329
550 1.10
28,779
29,246
548 1.10
28,698
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 37,221 74.44
Total 37,302 74.6U

L1
I
C
www.encola6s.com
SAMPLE DETECTION SUMMARY
Client ID: Cole Park Sludge
Lab ID:
C413803-01
Analvte
Results
Flan
LLDL
P2t
Units
Method
Notes
% Solids
0.6
0.1
0.1
% by Weight
% Solids
Aluminum - Total
3380
339
1620
mg/kg dry
EPA 6010C
Calcium - Total
19900
B
905
4040
mg/kg dry
EPA 6010C
QB-01
Copper- Total
260
30.7
80.8
mg/kg dry
EPA.6010C
Lead - Total
20.8
J
19.4
80.8
mg/kg dry
EPA 6010C
Magnesium - Total
4100
B
105
4040
mg/kg dry
EPA 6010C
3-01
Nitrate/Nitrite as N
7400
D
640
1600
mg/kg dry
EPA 353.2
pH
7.4
1.0
1.0
pH Units
EPA 9045D
Phosphorus
29000
D
1300
5100
mg/kg dry
EPA 365.4
Potassium - Total
5170
646
4040
mg/kg dry
EPA 6010C
Selenium - Total
20.5
JB
16.2
80.8
mg/kg dry
EPA 6010C
3-01
Sodium - Total
38400
969
4040
mg/kg dry
EPA 6010C
Total Kjeldahl Nitrogen
66000,
D
4200
7700
mg/kg dry
EPA 351.2
Total Solids
0.62
0.0010
0.0010
% by Weight
SM 2540G-1997
Zinc - Total
382
J
178
404
mg/kg d
EPA 6010C
Client ID: Cole Park Sludge
Lab ID:
C413803-01RE1
Analvte
Results
fins
MDL
E46
Units
Method
Notes
Ammonia as N
220
D
14
32
mg/kg dry
EPA 350.1
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 10

www.encolabs.com
ANALYTICAL RESULTS
Description: Cole Park Sludge Lab Sample ID: C413803-01 Received: 11/04/14 11:15
Matrix: Sludge Sampled:11/04/14 09:45 Work Order: C413803
_ Project: Cole ParkPlaza-Annual Sludge Analysis Sampled By: Bruce Butler % Solids: 0.62
(Metals
by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte f CAS Numberl Results
Eft
Units
RE
MDL
EM
Batch
Method
Analyzed
Notes
Aluminum [7429-90-5]^
3380
mg/kg dry
1
339
1620
4KO5014
EPA 6010C
11/07/14 13:06
JDH
Arsenic[7440-38-2]^
< 16.2
mg/kg dry
1
16.2
80.8
4KO5014
EPA 6010C
11/07/14 13:06
JDH
�4 Cadmium [7440-43-9]^
< 1.55
mg/kg dry
1
1.55
8.08
4KO5014
EPA 6010C
11/07/14 13:06
JDH
Calcium [7440-70-2]A
L
19900
B
mg/kg dry
1
905
4040
4KO5014
EPA 6010C
11/07/14 13:06
JDH QB-01
Copper[7440-50-8]A
260
mg/kg dry
1
30.7
80.8
4KO5014
EPA 6010C
11/07/14 13:06
JDH
Lead [7439-92-1]A
20.8
J
mg/kg dry
1
19.4
80.8
4KO5014
EPA 6010C
11/07/14 13:06
JDH
Magnesium [7439-95-4]A
4100
B
mg/kg dry
1
105
4040
4KO5014
EPA 6010C
11/07/14 13:06
JDH 3-01
y Mercury [7439-97-6]^
< 0.836
mg/kg dry
1
0.836
2.91
4K10027
EPA 7471E
11/11/14 13:56
TO
Molybdenum [7439-98-7]^
< 16.2
mg/kg dry
1
16.2
80.8
4KO5014
EPA 6010C
11/07/14 13:06
JDH
Nickel[7440-02-0]^
< 58.2
mg/kg dry
1
58.2
404
4KO5014
EPA 6010C
11/07/14 13:06
JDH
Potassium [7440-09-7]A
5170
mg/kg dry
1
646
4040
4KO5014
EPA 6010C
11/07/14 13:06
JDH
Selenium [7782-49-2]A
20.5
JB
mg/kg dry
1
16.2
80.8
4KO5014
EPA 6010C
11/07/14 13:06
JDH 3-01
Sodium [7440-23-5]A
38400
mg/kg dry
1
969
4040
4KO5014
EPA 6010C
11/07/14 13:06
JDH
Zinc [7440-66-6]A
382
J
mg/kg dry
1
178
404
4KO5014
EPA 6010C
11/07/14 13:06
JDH
Classical Chemistry Parameters
AnalM rCAS Numberl
i
Results
E[ag
Units
2E
MDL
M
Batch
Method
Analyzed
Notes
% Solids
0.6
% by Weight
1
0.1
0.1
4KO6028
% Solids
11/06/1413:21
MMR
Ammonia as N [7664-41-7]
220
D
mg/kg dry
2
14
32
4KO7019
EPA 350.1
11/07/14 16:19
SHA
Nitrate/Nitrite as N
7400
D
mg/kg dry
97.5
640
1600
4K11002
EPA 353.2
11/11/14 12:21
SHA
PH
7.4
pH Units
1
1.0
1.0
4KO6024
EPA 9045D
11/06/14 14:44
MMR
Phosphorus[7723-14-0]
29000
D
mg/kg dry
320
1300
5100
4K12014
EPA 365.4
11/17/14 13:10
SHA
Total Kjeldahl Nitrogen
66000
D
mg/kg dry
100
4200
7700
4K12008
EPA 351.2
11/17/14 10:33
SHA
Total Solids
0.62
% by Weight
1
0.0010
0.0010
4KO6026
SM 254OG-1997
11/06/14 13:21
MMR
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 10

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NOT ON PERMIT
Laboratory 1 Environmental
Conservation
Laboratory 2
Sample or CompositeDate 1/30/2015
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
7840
Ammonia Nitrogen
N/A
N/A
71
Arsenic
41
75
6.83
Cadmium
39
85
0.799
Calcium
N/A
N/A
29,600
Copper
1,500
4,300
601
Lead
300
840
24.4
Magnesium
N/A
N/A
2,730
Mercury
17
57
0.472
Molybdenum
N/A
75
8.68
Nickel
420
420
24.6
Nitrate -Nitrite Nitrogen
N/A
N/A
3,900.00
Percent Solids
N/A
N/A
1.50
PH (no units)
N/A
N/A
6.90
Phosphorus
N/A
N/A
17,000
Potassium
N/A
N/A
3,370
PAN (Inj./Inc.)
N/A
N/A
24,350
PAN (Surface)
N/A
N/A
24,314
Selenium
100
100
6.83
Sodium
N/A
N/A
13,000
SAR
N/A
N/A
2.37
TKN
N/A
N/A
68,000
Zinc
2,800
7,500
1970
Source Name Colvard Farms
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
/4-C.-- 2-19-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

FIELD LOADING ESTIMATES
Facility Colvard Farms
-' Sampling Date 1/30/2015
% Solids 1.5
I_r Mineralization Rate 0.30
Gallons per DT 15,987,21
PH 6.9
Sodium Absorpotion 2.37 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 68,000 lbs./1,000 gal 8.51
Ammonia Nitrogen (mg/Kg) 71.00 lbs./1,000 gal 0.01
Nitrate -Nitrite (mg/Kg) 3,900.00 lbs./1,000 gal 0.49
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 24,314 lbs./1,000 gal 3.04
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 24,350 lbs./1,000 gal 3.05
Volatization Rate= 0.5 Surface Application
1.0 Injection /Incorporation
EPA METAL LIMITS
P
(-i 1st Year
2nd Year
3rd Year
I.
4th Year
5th Year
Potassium lbs./1,000 gal 0.42
Phosphorus lbs./1,000 gal 2.13
Calcium lbs./1,000 gal 3.70
Magnesium lbs./1,000 gal 0.34
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
6.83
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.80
Cadmium lbs./1,000 gal
• 0.00
Copper (mg/Kg)
601.00
Copper lbs./1,000 gal
0.08
Lead (mg/Kg)
24.40
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.47
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
24.60
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
6.83
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
1970.00
Zinc lbs./1,000 gal
0.25
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TEN
(mg/kg) (lbs/DT)
(mg/]Kg)
TEN
(mg/kg) (lbs/DT)
(mg/Eg)
68,000
24,314 48.63
43,686
68,000
24,350 48.70
43,650
43,686
6,553 13.11
37,133
43,650
6,548 13.10
37,103
37,133
2,785 5.57
34,348
37,103
2,783 5.57
34,320
34,348
1,288 2.58
33,060
34,320
1,287 2.57
33,033
33,060
620 1.24
32,440
33,033
619 1.24
32,414
Equations
1st Yr. PAN (mg/Kg)=(MIt x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 35,560 71.12
Total 35,586 71.17

_J
www.encolabs.com
SAMPLE DETECTION SUMMARY
Client ID: Colvard Farms Sludge
Lab ID: C413804-01
Analvte
Results
Flan
MPs
M
Units
Method Notes
% Solids
1.5
0.1
0.1
% by Weight
% Solids
Aluminum - Total
2840
144
683
mg/kg dry
EPA 6010C
Cadmium - Total
0.799
J
0.656
3.42
mg/kg dry
EPA 6010C
Calcium - Total
29600
B
383
1710
mg/kg dry
EPA 6010C QB-01
Copper - Total
601
13.0
34.2
mg/kg dry
EPA 6010C
Lead - Total
24.4
J
8.20
34.2
mg/kg dry
EPA 6010C
Magnesium - Total
2730
B
44.4
1710
mg/kg dry
EPA 6010C QB-01
Molybdenum - Total
8.68
1
6.83
34.2
mg/kg dry
EPA 6010C
Nitrate/Nitrite as N
3900
D
270
660
mg/kg dry
EPA 353.2
pH
6.9
1.0
1.0
pH Units
EPA 9045D
Phosphorus
17000
D
680
2700
mg/kg dry
EPA 365.4
Potassium - Total
3370
273
1710
mg/kg dry
EPA 6010C
Sodium - Total
13000
410
1710
mg/kg dry
EPA 6010C
Total Solids
1.5
0.0010
0.0010
% by Weight
SM 2540G-1997
Zinc - Total
1970
75.2
171
mg/kg dry
EPA 6010C
Analvte Results Flat MDL POL Units Method Notes
Ammonia as N 71 3.1 6.8 mg/kg dry EPA 350.1
Total Kjeldahl Nitrogen 68000 D 1800 3300 mg/kg dry EPA 351.2
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 11

L"!
.NCO
www.encolabs.com
ANALYTICAL RESULTS
Description: Colvard Farms Sludge Lab Sample ID:C413804-01 Received: 01/30/15 11:45
Matrix: Sludge . Sampled:01/30/15 11:05 Work Order: C413804
Project: Colvard Farms -Annual Sludge Analysis Sampled By: Eric Riggins % Solids: 1.46
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary ceitified analyte [NC 5911
Analyte rCAS Numberl
Results
p&q
Units
2E
MU
M
Batch
Method
Analyzed
@y Notes
Aluminum [7429-90-5]^
2840
mg/kg dry
1
144
683
SB04030
EPA 6010C
02/05/15 12:26
JDH
Arsenic [7440-38-2]A
< 6.83
mg/kg dry
1
6.83
34.2
5B04030
EPA 6010C
02/05/15 12:26
JDH
Cadmium [7440-43-9]^
0.799
J
mg/kg dry
1
0.656
3.42
SB04030
EPA 6010C
02/05/15 12:26
JDH
Calcium [7440-70-2]^
29600
B
mg/kg dry
1
383
1710
SB04030
EPA 6010C
02/05/15 12:26
JDH QB-01
Copper [7440-50-8]^
601
mg/kg dry
1
13.0
34.2
BB04030
EPA 6010C
02/05/15 12:26
JDH
Lead [7439-92-1]^
24.4
J
mg/kg dry
1
8.20
34.2
5BO4030
EPA 6010C
02/05/15 12:26
JDH
Magnesium [7439-95-4]^
2730
B
mg/kg dry
1
44.4
1710
5BO4030
EPA 6010C
02/05/15 12:26
JDH QB-01
Mercury'[7439-97-6]A
< 0.472
mg/kg dry
1
0.472
1.64
SB11024
EPA 7471B
02/13/15 13:48
T11)
Molybdenum [7439-98-7]^
8.68
J
mg/kg dry
1
6.83
34.2
5B04030
EPA 6010C
02/05/15 12:26
JDH
Nickel[7440-02-0]A
< 24.6
mg/kg dry
1
24.6
171
SB04030
EPA 6010C
02/05/15 12:26
JDH
Potassium [7440-09-7]^
3370
mg/kg dry
1
.273
1710
SB04030
EPA 6010C
02/05/15 12:26
JDH
Selenium [7782-49-2]^
< 6.83
mg/kg dry
1
6.83
34.2
5BO4030
EPA 6010C
02/05/15 12:26
JDH
Sodium [7440-23-5]^
13000
mg/kg dry
1
410
1710
SB04030
EPA 6010C
02/05/15 12:26
JDH
Zinc[7440-66-6]^
1970
mg/kg dry
1
75.2
171
SB04030
EPA 6010C
02/05/15 12:26
JDH
Classical Chemistry Parameters
Analvte rCAS Numberl
Results
FiM
Units
AE
MU
EM
Batch
Method
wed
By Notes
% Solids
1.5
% by
1
0.1
0.1
5BOS034
% Solids
02/05/15 15:06
MMR
Weight
Ammonia as N [7664-41-7]
71
mg/kg dry
1
3.1
6.8
5BO4011
EPA 350.1
02/04/15 15:26
SHA
Nitrate/Nitrite as N
3900
D
mg/kg dry
97.5
270
660
SBOS003
EPA 353.2
02/05/15 11:49
SHA
pH
6.9
pH Units
1
1.0
1.0
5B04019
EPA 9045D
02/04/15 11:06
MKS
Phosphorus[7723-14-0]
17000
D
mg/kg dry
400
680
2700
5B06028
EPA 365.4
02/09/15 11:34
SHA
Total Kjeldahl Nitrogen
68000
D
mg/kg dry
100
1800
3300
SB06029
EPA 351.2
02/09/15 12:52
SHA
Total Solids
1.5
% by
1
0.0010
0.0010
5BO5033
SM 254OG-1997
02/05/15 15:06
MMR
Weight
r- -
I FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 11

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO062715
Laboratory 1 Environmental
Conservation
Laboratory 2
Sample or CompositeDate 12/2/2014
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
2,370
Ammonia Nitrogen
N/A
N/A
91
Arsenic
41
75
3.63
Cadmium
39
85
0.348
Calcium
N/A
N/A
18,800
Copper
1,500
4,300
227
Lead
300
840
7.88
Magnesium
N/A
N/A
2,740
Mercury
17
57
0.25
Molybdenum
N/A
75
3.63
Nickel
420
420
18.4
Nitrate -Nitrite Nitrogen
N/A
N/A
520
Percent Solids
N/A
N/A
2.80
PH (no units)
N/A
N/A
7.00
Phosphorus
N/A
N/A
170
Potassium
N/A
N/A
2,100
PAN (Inj./Inc.)
N/A
N/A
974
PAN (Surface)
N/A
N/A
928
Selenium
100
100
3.63
Sodium
N/A
N/A
6,820
SAR
N/A
N/A
2.05
TKN
N/A
N/A
1,300
Zinc
2,800
7,500
1220
Source Name Crooked Creek WWTP
`°I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
OU
02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

FIELD LOADING ESTIMATES
Facility Crooked Creek VA=
Sampling Date 12/2/2014
% Solids 2.8
Mineralization Rate 0.3
Gallons per DT 8,564.58
PH 7
Sodium Absorpotion 2.05 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land ripply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 1,300 lbs./1,000 gal 0.30
Potassium lbs./1,000 gal
0.49
Ammonia Nitrogen (mg/Kg) 91.00 lbs./1,000 gal 0.02
Phosphorus lbs./1,000 gal
0.04
Nitrate -Nitrite (mg/Kg) 520.00 lbs./1,000 gal 0.12
Calcium lbs./1,000 gal
4.39
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.64
PAN (mg/Kg) 928 lbs./1,000 gal 0.22
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 974 lbs./1,000 gal 0.23
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
- 1st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
3.63
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.35
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
227.00
Copper lbs./1,000 gal
0.05
Lead (mg/Kg)
7.88
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.25
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
18.40
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
3.63
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
1220.00
Zinc lbs./1,000 gal
0.28
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
TEN
PAN PAN
Nitrogen
TEN
PAN PAN
Nitrogen
(mg/kg) (lbs/DT)
(mg/Eg)
(mg/kg) (lbs/DT)
(mg/Eg)
1,300
928 1.86
372
1,300
974 1.95
326
372
56 0.11
316
326
49 0.10
277
316
24 0.05
292
277
21 0.04
257
292
11 0.02
281
257
10 0.02
247
281
5 0.01
276
247
5 0.01
242
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
"lotal 1,U24 2.05
Total 1,058 2.12

L— JL- J
www.encolabs.com
SAMPLE DETECTION SUMMARY
Client ID: Crooked Creek Sludge
Lab ID:
C413805-01
Analyte
Results
EI94
MPS
M
Units
Method Notes
% Solids
2.8
0.1
0.1
% by Weight
% Solids
Aluminum - Total
2370
76.2
363
mg/kg dry
EPA 6010C
— Calcium - Total
18800
B
203
907
mg/kg dry
EPA 6010C QB-01
Copper - Total
227
6.90
18.1
mg/kg dry
EPA 6010C
- -- Lead - Total
7.88
1
4.36
18.1
mg/kg dry
EPA 6010C
Magnesium - Total
2740
B
23.6
907
mg/kg dry
EPA 6010C QB-01
Nickel- Total
18.4
1
13.1
90.7
mg/kg dry
EPA 6010C
Nitrate/Nitrite as N
520
BD
140
340
mg/kg dry
EPA 353.2 QB-01
pH
7.0
1.0
1.0
pH Units
EPA 9045D
Phosphorus
170
D
26
100
mg/kg dry
EPA 365.4
_ Potassium - Total
2100
145
907
mg/kg dry
EPA 6010C
Sodium - Total
6820
218
907
mg/kg dry
EPA 6010C
Total Kjeldahl Nitrogen
1300
D
90
170
mg/kg dry
EPA 351.2
Total Solids
2.8
0.0010
0.0010
% by Weight
SM 2540G-1997
- Zinc - Total
1220
39.9
90.7
mgft dry
EPA 6010C
Client ID: Crooked Creek Slud a
J
Lab ID:
C413805-01RE1
Analvte
Results
BM
MP&
P_4.6
Units
Method Notes
Ammonia as N
91
D
7.7
17
mg/kg dry
EPA 350.1
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 11

Sa6 "
www.encolabs.com
ANALYTICAL RESULTS
Description: Crooked Creek Sludge
Lab Sample ID:C413805-01
Received: 12/02/14 11:00
Matrix: Sludge
Sampled: 12/02/14 08:30
Work Order: C413805
Project: Crooked Creek -Annual Sludge Analysis
Sampled By: Shelby Cheek
% Solids: 2.76
Metals by EPA 6000 7000 Series Methods
C; A - ENCO Cary ceitified analyte (NC 5911
Ana yte rCAS Numberl
Results
Flag
Units
PE
MAL
EQL
Batch
Method
Analyzed
Notes
Aluminum [7429-90-5]A
2370
mg/kg dry
1
76.2
363
4L10026
EPA 6010C
12/12/14 11:43
JDH
Arsenic [7440-38-2]A
< 3.63
mg/kg dry
1
3.63
18.1
41-10026
EPA 6010C
12/12/14 11:43
JDH
Cadmium [7440-43-9]A
< 0.348
mg/kg dry
1
0.348
1.81
4L10026
EPA 6010C
12/12/14 11:43
JDH
' Calcium [7440-70-2]A
18800
B
mg/kg dry
1
203
907
41-10026
EPA 6010C
12/12/14 11:43
JDH QB-01
l Copper[7440-50-8]A
227
mg/kg dry
1
6.90
18.1
41-10026
EPA 6010C
12/12/14 11:43
JDH
Lead [7439-92-1]A
7.88
J
mg/kg dry
1
4.36
18.1
41-10026
EPA 6010C
12/12/14 11:43
JDH
Magnesium [7439-95-4]A
2740
B
mg/kg dry
1
23.6
907
4L10026
EPA 6010C
12/12/14 11:43
JDH QB-01
Mercury [7439-97-6]A
< 0.250
mg/kg dry
1
0.250
0.871
4L11033
EPA 7471B
12/12/14 15:10
TiD
Molybdenum [7439-98-7]A
< 3.63
mg/kg dry
1
3.63
18.1
4L10026
EPA 6010C
12/12/14 11:43
JDH
Nickel [7440-02-O]A
18.4
J
mg/kg dry
1
13.1
90.7
41-10026
EPA 6010C
12/12/14 11:43
JDH
Potassium [7440-09-7]A
2100
mg/kg dry
1
145
907
4L10026
EPA 6010C
12/12/14 11:43
JDH
l Selenium [7782-49-2]A
< 3.63
mg/kg dry
1
3.63
18.1
4L10026
EPA 6010C
12/12/14 11:43
JDH
Sodium [7440-23-5]A
6820
mg/kg dry
1
218
907
41-10026
EPA 6010C
12/12/14 11:43
JDH
Zinc[7440-66-6]A
1220
mg/kg dry
1
39.9
90.7
41-10026
EPA 6010C
12/12/14 11:43
JDH
Classical Chemistry Parameters
Analyte [CAS Numberl
Results
Flag
Units
RE
W1
M
Batch
Method
Analyzed
By Dotes
Solids
2.8
% by
1
0.1
0.1
4LO2026
% Solids
12/02/14 12:17
MMR
Weight
Ammonia as N [7664-41-7]
91
D
mg/kg dry
5
7.7
17
4LO8028
EPA 350.1
12/09/14 13:54
SHA
Nitrate/Nitrite as N
520
BD
mg/kg dry
97.5
140
340
4LO4004
EPA 353.2
12/04/14 16:32
AIB QB-01
pH
7.0
pH Units
1
1.0
1.0
4LO2040
EPA 9045D
12/02/14 15:50
MMR
Phosphorus [7723-14-0]
170
D
mg/kg dry
30.2
26
100
4L11005
EPA 365.4
12/15/14 15:04
AJB
Total Kjeldahl Nitrogen
1300
D
mg/kg dry
10
90
170
41-11006
EPA 351.2
12/15/14 13:05
AJB
Total Solids
2.8
% by
1
0.0010
0.0010
4LO2025
SM 254OG-1997 12/02/14 12:17
MMR
Weight
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 11

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NC0056391
Laboratory 1 Environmental
Conservation
Laboratory 2
Sample or CompositeDate 11/5/2014
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
6,220
Ammonia Nitrogen
N/A
N/A
82
Arsenic
41
75
16.8
Cadmium
39
85
1.61 '
Calcium
N/A
N/A
29,600
Copper
1,500
4,300
185
Lead
300
840
20.2
Magnesium
N/A
N/A
3,220
Mercury
17
57
1.16
Molybdenum
N/A
75
16.8
Nickel
420
420
60.5
Nitrate -Nitrite Nitrogen
N/A
N/A
4,300
Percent Solids
N/A
N/A
0.60
pH (no units)
N/A
N/A
7.10
Phosphorus
N/A
N/A
23,000
Potassium
N/A
N/A
6,280
PAN (Inj./Inc.)
N/A
N/A
31,957
PAN (Surface)
N/A
N/A
31,916
Selenium
100
100
16.8
Sodium
N/A
N/A
23,300
SAR
N/A
N/A
2.65
TKN
N/A
N/A
92,000
Zinc
2,800
7,500
927
Source Name Cross Creek Mobile Estates
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations"
/'""C.Lt- 02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

tt AGMAN
Facility Cross Creek Mobile Estates
Sampling Date 11/5/2014
% Solids 0.6
Mineralization Rate 0.30
Gallons per DT 39,968.03
PH 7.1
FIELD LOADING ESTIMATES
Sodium Absorpotion 2.65 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land ripply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 92,000 lbs./1,000 gal 4.60
Ammonia Nitrogen (mg/Kg) 82.00 lbs./1,000 gal 0.00
Nitrate -Nitrite (mg/Kg) 4,300.00 lbs./1,000 gal 0.22
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 31,916 lbs./1,000 gal 1.60
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 31,957 lbs./1,000 gal 1.60
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
i
5th Year
HEAVY METAL CONCENTRATION
Potassium lbs./1,000 gal 0.31
Phosphorus lbs./1,000 gal 1.15
Calcium lbs./1,000 gal 1.48
Magnesium lbs./1,000 gal 0.16
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
16.80
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.61
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
185.00
Copper lbs./1,000 gal
0.01
Lead (mg/Kg)
20.20
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
1.16
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
60.50
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
16.80
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
927.00
Zinc lbs./1,000 gal
0.05
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Yg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
92,000
31,916
63.83
60,084
92,000
31,957 63.91
60,043
60,084
9,013
18.03
51,071
60,043
9,006 18.01
51,036
51,071
3,830
7.66
47,241
51,036
3,828 7.66
47,208
47,241
1,772
3.54
45,469
47,208
1,770 3.54
45,438
45,469
853
1.71
44,617
45,438
- 852 1.70
44,586
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg) 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/I6)
Total 47,383 94.77 Total 47,414 94.83

www.encolabs.com
SAMPLE DETECTION SUMMARY
Client ID: Cross Creek Sludge
Lab ID:
C413806-01
Analvte
Results
E183
Nu
POL
mom
Method Notes
% Solids
0.6
0.1
0.1
% by Weight
% Solids
I
Aluminum - Total
6220
353
1680
mg/kg dry
EPA 6010C
Cadmium - Total
1.61
]
1.61
8.40
mg/kg dry
EPA 6010C
Calcium - Total
29600
B
941
4200
mg/kg dry
EPA 6010C QB-01
Copper - Total
185
31.9
84.0
mg/kg dry
EPA 6010C
Magnesium - Total
3220
JB
109
4200
mg/kg dry
EPA 6010C QB-01
Nitrate/Nitrite as N
4300
D
660
1600
mg/kg dry
EPA 353.2 .
pH
7.1
1.0
1.0
pH Units
EPA 9045D
Phosphorus
23000
D
1300
5300
mg/kg dry
EPA 365.4
Potassium - Total
6280
672
4200
mg/kg dry
EPA 6010C
-
Sodium - Total
23300
1010
4200
mg/kg dry
EPA 6010C
Total Kjeldahl Nitrogen
92000
D
4300
8000
mg/kg dry
EPA 351.2
Total Solids
0.60
0.0010
0.0010
% by Weight
SM 254OG-1997
Zinc - Total
927
185
420
mg/kg dry
EPA 6010C
Client ID: Cross Creek Sludge
Lab ID:
C413806-01RE1
Analvte
Results
Elan
MPPL
E"
Units
Method Notes
Ammonia as N
82
7.5
17
mg/kg dry
EPA 350.1
F1
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 11

www.encolabs.com
ANALYTICAL RESULTS
Description: Cross Creek Sludge Lab Sample ID:C413806-01 Received: 11/05/14 14:45
Matrix: Sludge Sampled:11/05/14 11:00 Work Order: C413806
Project: Cross Creek -Annual Sludge Analysis Sampled By: Van Gurley % Solids: 0.60
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl Results
FFI g
Units
AE
MDL
EQL
Batch
Method
Analyzed
Notes
Aluminum [7429-90-5]^
6220
mg/kg dry
1
353
1680
4K13030
EPA 6010C
11/14/14 14:09
JDH
Arsenic [7440-38-2]^
< 16.8
mg/kg dry
1
16.8
84.0
41<13030
EPA 6010C
11/14/14 14:09
JDH
Cadmium [7440-43-9]^
1.61
J
mg/kg dry
1
1.61
8.40
4K13030
EPA 6010C
11/14/14 14:09
JDH
Calcium [7440-70-2]^
29600
B
mg/kg dry
1
941
4200
4K13030
EPA 6010C
11/14/14 14:09
JDH QB-01
Copper[7440-50-8]^
185
mg/kg dry
1
31.9
84.0
41<13030
EPA 6010C
11/14/14 14:09
JDH
Lead [7439-92-1]A
< 20.2
mg/kg dry
1
20.2
84.0
41<13030
EPA 6010C
11/14/14 14:09
JDH
Magnesium [7439-95-4]^
3220
JB
mg/kg dry
1
109
4200
4K13030
EPA 6010C
11/14/14 14:09
JDH QB-01
Mercury [7439-97-6]^
< 1.16
mg/kg dry
1
1.16
4.03
4K10027
EPA 7471B
11/11/14 13:58
T1D
Molybdenum [7439-98.7]^
< 16.8
mg/kg dry
1
16.8
84.0
4K13030
EPA 6010C
11/14/14 14:09
JDH
Nickel[7440-02-0]^
< 60.5
mg/kg dry
1
60.5
420
4K13030
EPA 6010C
11/14/14 14:09
JDH
Potassium [7440-09-7]^
6280
mg/kg dry
1
672
4200
4K13030
EPA 6010C
11/14/14 14:09
JDH
Selenium L7782-49-2]^
< 16.8
mg/kg dry
1
16.8
84.0
4K13030
EPA 6010C
11/14/14 14:09
JDH
Sodium [7440-23-5]^
23300
mg/kg dry
1
1010
4200
41<13030
EPA 6010C
11/14/14 14:09
JDH
Zinc [7440-66-6]^
927
mg/kg dry
1
185
420
4K13030
EPA 6010C
11/14/14 14:09
JDH
Classical Chemistry Parameters
Analyte rCAS Numberl
Results
fag
Units
RE
MDL
E"
Batch
Method
Analyzed
ft Notes
! % Solids
0.6
% by Weight
1
0.1
0.1
4KO6028
% Solids
11/06/14 13:21
MMR
Ammonia as N [7664-41-7]
82
mg/kg dry
1
7.5
17
41<12005
EPA 350.1
11/12/14 14:58
SHA
-, Nitrate/Nitrite as N
4300
D
mg/kg dry
97.5
660
1600
4K11002
EPA 353.2
11/11/14 12:23
SHA
pH
7.1
pH Units
1
1.0
1.0
4KO6024
EPA 9045D
11/06/14 14:44
MMR
Phosphorus[7723-14-0]
23000
D
mg/kg dry
320
1300
5300
4K12014
EPA 365.4
11/17/14 13:12
SHA
Total Kjeldahl Nitrogen
92000
D
mg/kg dry
100
4300
8000
4K12008
EPA 351.2
11/17/14 10:35
SHA
Total Solids
0.60
% by Weight
1
0.0010
0.0010
4KO6026
SM 254OG-1997
11/06/14 13:21
MMR
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 11

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Grtmille [-'arms, Inc. Class B Source Permit No. NCO063746
Laboratory 1 I-:1nitnnmcnt
1, Inc.
Laboratory 2 — ---
Sample or CompositeDate
Parameter (mg/Kg) Class A Clas B
Aluminum
Ammonia Nitrogen
----- Arsenic
- -- -' Cadmium
Calcium
Copper
N/A
N/A
N/A
-- 75
-- 85 -
J,R9R
N/A
41
- 39 -
N/A
1,500
-- 23 -
- 0.7 -
N/A
4,300
15,245
1]OG
------ Lead
300
N/A
17
N/A
---420
840
N/A
--- u - -
3,477
- ---0 33 --- -
- --Magnesium
Molybdenu
57
75
420
G
12
--- — — Nickel
Nitrate-Nitritc Nitrogen
N/A
N/A
— 4
PcrccntSolids
--- -- PH (no units)
---- Phosphorus
- Potassium
N/A
- - N/A
N/A
N/A
N/A
N/A
N/A
aGG
-- [ 70
394 --
N/A
_ R;184
PAN047[nL)
[;i/A
-N/A
---3.416 -
PAN (Surface)
N/A
N/A
2,1R3
Selenium
Sodium
— -- SAR'
-
t00
N/A
100
N/A
- —3 —
11052
N/A
- N/A
LiO--
-
THN
N/A
- N/A
7,50
-- 5.620 -
---940
--- Zinc
2,900
Source Name Deerehase %KIXXrl'P
"I certify, under penalty of law, drat this document was prepared under my direction or supervision in accordance with a system designed to
assure drat qualified personnel properly gathered and evaluated the information submitted. [ am aware drat thee-'- arc significant penalties for
submitting Else information, including the possibility of fins and imprisonment for kknnowing violations."
J -2 ( rlm'11r,
Signature of Preparcr * Date
*Pmparer is defined in 40 CPR Pact 503.9(r) and ISA NCAC 2T .1102 (26) /�

i
" AGMAN
FIELD LOADING ESTIMATES
Facility Deerchase VAVI'P
Sampling Date 4/24/2014
% Solids 0.66
i
�v Mineralization Rate 0.3
Gallons per DT 36,334.57
pH 6.7
Sodium Absorpotion 1.70 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 5,620 lbs./1,000 gal 0.31
Potassium lbs./1,000 gal
0.49
Ammonia Nitrogen (mg/Kg) 2,466.00 lbs./1,000 gal 0.14
Phosphorus lbs./1,000 gal
0.02
i
Nitrate -Nitrite (mg/Kg) 3.93 lbs./1,000 gal 0.00
Calcium lbs./1,000 gal
0.84
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.19
i
PAN (mg/Kg) 2,183 lbs./1,000 gal 0.12
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED.
Sulfur lbs./1,000 gal
PAN (mg/Kg) 3,416 lbs./1,000 gal 0.19
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
1st Yea:
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
2.50
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.70
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
1306.00
Copper lbs./1,000 gal
0.07
Lead (mg/Kg)
11.00
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.33
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
12.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
940.00
Zinc lbs./1,000 gal
0.05
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TEN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Yg)
5,620
2,183
4.37
3,437
5,620
3,416 6.83
2,204
3,437
516
1.03
2,921
2,204
331 0.66
1,873
2,921
219
0.44
2,702
1,873
140 0.28
1,733
2,702
101
0.20
2,601
1,733
65 0.13
1,668
2,601
49
0.10
2,552
1,668
31 0.06
1,637
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 3,068 6.14
Total 3,983 7.97

environment 1, Incorporated
7„'t14�AKMONT C3RIV,E : _ PHA
DEERCHASE (CLARKE)
C/O CLARKE UTILITIES LLC
223 HWY. 70 EAST
EAST POINTE 1.20 B
GARNER ,NC 27529-4062
Sludge
Analysis
Method
PARAMETERS
Sample
Date Analyst
Code
PH (not to be used for reporting)
6.7
04/24/14 TRB
4500IM-00
Aluminum, (dry wt. basis), mg/kg
3898
OSIO6114 LFJ
EPA200.7
Arsenic (dry wt. basis), mg/kg,
<2.5
05/07/14 MEL
3113B-04
Calcium (dry wt. basis), mg/kg
15245
05/06/14 LFJ
EPA200.7
Cadmium (dry wt. basis), mg/kg
0.7
05/15/14 MEL
311313-04
Copper (dry wt. basis), mg/kg
1306
05106114 LF.1
EPA200.7
Chromium, T.(dry wt. basis),mg/kg
8
05/06/14 LFJ
EPA200.7
Lead (dry weight basis), mg/kg
11
05/06/14 MEL
311313®04
Magnesium (dry wt. basis), mg/kg
3477
05/06/14 LFJ
EPA200.7
Mercury (dry wt. basis), mg/kg
0.33
05/08/14 MTM
245.1 R3.94
Nickel (dry wt. basis), mg/kg
12
05/06/14 LFJ
''EPA200.7
Potassium (dry wt. basis), mg/kg
8994
05/06/14 LFJ
EPA200.7
Selenium (dry wt. basis), mg/kg
<5.0
05/14/14 NOEL
3113Bd04
Sodium (dry wt. basis), mg/kg
11052
05/06114 MTM
3111B.99
Zinc (dry wt. basis), mg/kg
940
05/07/14 MTM
3111B-99
Total Solids, %
0.66
04/25/14 CMC
2540G-97
TIN (dry wt.), mg/kg
5620
05/05/14 ANO
351.2 R2.93
Ammonia Nitrogen (dry-wt.),mg/kg
2466
04/29/14 ALB
350.1 R2-93
Phosphorus, T. (dry wt.), mg/kg
394
05/01114 ALB
365.4 -74
Nitrate -Nitrite (dry wt.), mg/kg
<3.93
04/30/14 ANO
353.2 R2-93
Plant Available Nitrogen, mg/kg
2179
05/14/14 SEJ
Molybdenum (dry wt. basis), mg/kg
6
05/06114 LFJ
EPA200.7
ID#: 432 A
DATE COLLECTED: 04/24/1.4
DATE REPORTED t 0 5 / 1. 9 / 1.4
e 04
REVIEWED BSC s _. �V� -

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Pemut No. WQ0000838 Facility Name Granville rarms, Inc. Class B Source Peunit No. 0442-025
Laboratotyl MLFastem
1. Laln, Inc
laboratory 2
Sample or CompositeDate 6/16/20t4
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
119,g03
Ammonia Nitrogen
N/A
N/A
1,590
Arsenic
41
! 75
10
Cadmium
39
85
2
Calcium
N/A
N/A
1,990
Copper
1,500
4,300
23
Lead
300
840
12
Magnesium
N/A
N/A
936
Mercury
17
57
0.{
Molybdenum
N/A
75
5
Nickel
420
420
20
Nitrate -Nitrite Nitrogen
N/A
, N/A
48
Percent Solids
N/A
N/A
I.69
PH (no units)
N/A
N/A
6.39
Phosphorus
. N/A
N/A
2,520
Potassium
N/A
N/A
758
PAN (Inj./Ina)
N/A
N/A
3,966
PAN (Surface)
N/A
N/A
3,17t
Selenitun
100
100
5
Sodium
N/A
N/A
396
SAR-
N/A
N/A
05
TKN
N/A
N/A
7.410
Zinc
2,800
7,500
98
Source Name Enfield Wl'P
"i certify, under penalty of law; that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnelproperly gathered and evaluated the informafion submitted [ am aware that there ark sigrrdieaattpenalties for
submitting false information, including the possibility offines and imprisonment for knowing violations:'
' J
inS OfPwpaser r' Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC ZT .M2 (26)

FIELD LOADING ESTIMATES
Facility Enfield WI'P
Sampling Date 6/16/2014
% Solids 1.89
Mineralization Rate 0.40
Gallons per DT 12,688.26
pH 6.39
Sodium Absorpotion 0.25 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 7,410 lbs./1,000 gal 1.17
Potassium lbs./1,000 gal
0.12
Ammonia Nitrogen (mg/Kg) 1,590.00 lbs./11-000 gal 0.25
Phosphorus lbs./1,000 gal
0.40
Nitrate -Nitrite (mg/Kg) 47.60 lbs./1,000 gal 0.01
Calcium lbs./1,000 gal
0.31
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.15
PAN (mg/Kg) 3,171 lbs./1,000 gal 0.50
Manganese lbs./1,000 gal
0.60
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
0.77'
PAN (mg/Kg) 3,966 lbs./1,000 gal 0.63
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Limits (mg/Kg)
41
1st Year
2nd Year
3rd Year
4th Year
5th Year
Class B Ceiling
Limits (mg/Kg)
75
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
10.00
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
2.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
23.00
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
12.00
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.40
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
20.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
88.00
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
, Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TEN
(mg/kg) (lbs/DT)
(mg/Kg)
7,410
3,171 6.34
4,239
7,410
3,966 7.93
3,444
4,239
848 1.70
3,392
3,444
689 1.38
2,756
3,392
339 0.68
3,052
2,756
276 0.55
2,480
3,052
153 0.31
2,900
2,480
124 0.25
2,356
2,900
72 0.14
2,827
2,356
59 0.12
2,297
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 4,583 9.17
Total 5,113 10.23

Page: 1,of 2
Report Number: 14-168-0205
Account Number: 04596
Submitted By: SCOTT CARPENTER
Send To: SOIL PLUS, LLC
SCOTT CARPENTER
P.O. BOX 1396
OXFORD, NC 27565
Lab Number: 55972
Sample Id : EWTP 061614
�L A &L Eastern Laboratories, Inc.
7621 Whitepine Road Richmond, Virginia 23237 [phone] Fax [phone]
WWW.aleastem.com
Project: ENFIELD WTP
NC CERT#257
REPORT OF ANALYSIS Date Sampled: 6/16/2014 10:30:00
Date Received: 06/17/2014 00:00
Date Reported: 06/20/2014
Total Solids *
1.89
18900
100.0
MW
06/18/2014 07:39
SM-2540G
Moisture "
98.11
100.0
MW
06/18/2014 07:39
SM-254OG
Total Kjeldahl Nitrogen
0.74
7410
10.0
JM
06/18/2014 07:59
SM-4500-NH3C-TKN
Total Phosphorus
0.25
2520
100
KM
06/18/2014 13:27
SW 6010C
Total Potassium
0.08
758
100
KM
06/18/2014 13:27
SW 6010C
Total Sulfur
0.49
4910
100
KM
06/18/2014 13:27
SW 6010C
Total Calcium
0.20
1990
100
KM
06/18/2014 13:27
SW 6010C
Total Magnesium
0.09
936
100
KM
06/18/2014 13:27
SW 6010C
Total Sodium
0.04
396
100
KM
06/18/2014 13:27
SW 6010C
Total Iron
52600
100
KM
06/18/2014 13:27
SW 6010C
Total Aluminum
119000
100
KM
06/18/2014 13:27
SW 6010C
Total Manganese
3820
5
KM
06/18/2014 13:27
SW 6010C
Total Copper
23
5
KM
06/18/2014 13:27
SW 6010C
Total Zinc
88
5
KM
06/18/2014 13:27
SW 6010C
Ammonia Nitrogen
0.16
1590
10.0
JM
06/18/2014 07:59
SM-4500-NI3C
Organic N
0.58
5820
10.0
06/18/2014 07:59
CALCULATION
Nitrate+Nitrite-N
47.6
2.00
JM
06/18/2014 08:00
SM-450ONO3F
Total Cadmium
<2.0
2.0
KM
06/18/2014 13:27
SW 6010C
All values are on a dry weight
basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
9&U-(*A
Our reports and letters are for the exclusive and confidential use of our clients and may not be reproduced
in whole or partnor may
any reference be made
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
Debbie Holt

Page: 2;of 2
Report Number: 14-168-0205
Account Number: 04596
Submitted By: SCOTT CARPENTER
Send To: SOIL PLUS, LLC
SCOTT CARPENTER
P.O. BOX 1396
OXFORD, NC 27565
Lab Number: 55972
Sample Id : EWTP 061614
� L A&L Eastern Laboratories, Inc.
7621 Whitepine Road Richmond, V[rginia 23237 [phone] Nx [phone]
www.aleastemcom
Project: ENFIELD WTP
NC CERT#257
REPORT OF ANALYSIS Date Sampled: 6/16/2014 10:30:00
Date Received: 06/17/2014 00:00
Date Reported: 06/20/2014
Total Chromium
84
5
KM
06/18/2014 13:27
SW 6010C
Total Nickel
20
5
KM
06/18/2014 13:27
SW 6010C
Total Lead
12
5
KM
06/18/2014 13:27
SW 6010C
Total Arsenic
10.0
3.0
KM
06/18/2014 13:27
SW 6010C
Total Mercury
<0.4
0.4
KM
06/19/2014 00:00
SW-7471 B
Total Selenium
<5.0
5.0
KM
06/18/2014 13:27
SW 6010C
pH (Standard Units) * 6.39
2.00
JM
06/18/2014 07:59
SW-9045D
Total Molybdenum
<5
5
KM
06/18/2014 13:27
SW 6010C
Soluble Phosphorus 0.05
500
100
JM
06/18/2014 09:45
SOLUBLE P IN MANURE
Comments:
WATER SOLUBLE P, SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES.
QUALIFIER: THE LRB WAS OUT OF LIMITS FOR "Na". THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Fe", "P", AND "S". ALL OTHER QC DATA IS
ACCEPTABLE.
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
Debbie Holt

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
W'Q Pen -nit No. WQ0000838 l:aaliEy!`fame Gr tiville Farms, Inc. Class B tiourcc PemucNo. Ni C.00254112
Laboratory! AW.Gascern
[Al'. Inc-
Laboratoty 2
Sample or CompositcDate
6/ 16 /20 14
Parameter (mg/Ps)
Class A
Clas B
Aluminum
N/A
N/A
33,4110
Ammonia. Nitrogen:
N/A
N/A
I Sun
Arsenic
41
75
6
Cadmium
39
85
2
Calcium
N/A
N/A
Ip,6(*
Copper!
1,500
4,300
253
Lead!
300
840
65
Magnesium;
N/A
N/A
H8o
Mercury
17
57
1-5
-Molybdenum,
NIA
-75
5
- - Nickel
420
42-0
36
Nitcate-Nimte Nkrogerl�
N/A
N/A -
-_- 11
Percent Solids'
N/A
N/A
2.94
PH (no units)
N/A
N/A
6.14
Phosphorus!
i
N/A
N/A
24,tUxt
Porassiuml
N/A
N/A
5 2twt
PAN((nj./Inc-)
N/A
N/A
Iro,,,,
PAN (Surface)�
c
N/A
N/A
i4,516
Selenium
100
100
5
Sodium
---��
N/A
N/A
SAW
N/A
N/A
6-59
TEN.
N/A
N/A
V 45JI41
Zfac .
2,800
7,5110
tiourcc Name Etitield WWII)
"L ccrtifg, under penal", of late, that this document wAs prepared under my direaion or supervision in accordance tcith a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted- I am zware that there are significant penalties for
submitting false information, i tiding the passibility of Fmes and imprisonment for knowing violations_"
Signature of Pre ace Date

i
AGIVIAN
FIELD LOADING ESTIMATES
Facility Enfield WW'I'P
�i
-' Sampling Date 6/16/2014
Solids 2.84
I
Mineralization Rate 0.3
Gallons per DT 8,443.95
pH 6.14
Sodium Absorpotion 0.59 <5.0 Safe 5.0
-10.0 Careful Management >15.0 Do Not
Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 45,100
lbs./1,000 gal 10.68
Potassium lbs./1,000 gal
1.23-
Ammonia Nitrogen (mg/Kg) 4,580.00
lbs./1,000 gal 1.08
Phosphorus lbs./1,000 gal
5.87
Nitrate -Nitrite (mg/Kg) 70.42
lbs./1,000 gal 0.02
Calcium lbs./1,000 gal
2.51
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.92
PAN (mg/Kg) 14,516
lbs./1,000 gal 3.44
Manganese lbs./1,000 gal
0.08
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
1.64
PAN (mg/Kg) 16,806
lbs./1,000 gal 3.98
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
F,
L'
r
I
I
1 St Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
6.00
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
2.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
253.00
Copper lbs./1,000 gal
0.06
Lead (mg/Kg)
65.00
Lead lbs./1,000 gal
0.02
Mercury (mg/Kg)
1.50
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
36.00
Nickel lbs./1,000 gal
0.01
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
944.00
Zinc lbs./1,000 gal
0.22
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN
PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
45,100
14,516
29.03
30,584
45,100
16,806
33.61
28,294
30,584
4,588
9.18
25,996
28,294
4,244
8.49
24,050
25,996
1,950
3.90
24,046
24,050
1,804
3.61
22,246
24,046
902
1.80
23,145
22,246
834
1.67
21,412
23,145
434
0.87
22,711
21,412
401
0.80
21,010
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 22,389 44.78
Total 24,090 48.18

Page: 1 of 2
Report Number: 14-168-0204
Account Number: 04596
Submitted By: SCOTT CARPENTER
Send To: SOIL PLUS, LLC
SCOTT CARPENTER
P.O. BOX 1396
OXFORD, NC 27565
Lab Number: 55971
Sample Id : EWWTP 061614
�L A&L Eastern Laboratories, Inc.
7621 Whitepine Road Richmond, Virginia23237 [phone] Fax[phone]
wwwaleastem.com
Project: ENFIELD WWTP
NC CERT#257
REPORT OF ANALYSIS Date Sampled: 6/16/2014 11:30:00
Date Received: 06/17/2014 00:00
Date Reported: 06/20/2014
Total Solids *
2.84
28400
100.0
MW
06/18/2014 07:39
SM-2540G
Moisture `
97.16
100.0
MW
06/18/2014 07:39
SM-2540G
Total Kjeldahl Nitrogen
4.51
45100
10.0
JM
06/18/2014 07:59
SM-4500-NH3C-TKN
Total Phosphorus
2.48
24800
100
KM
06/18/2014 13:27
SW 6010C
Total Potassium
0.52
•5200
100
KM
06/18/2014 13:27
SW 6010C
Total Sulfur
0.69
6910
100
KM
06/18/2014 13:27
SW 6010C
Total Calcium
1.06
10600
100
KM
06/18/2014 13:27
SW 6010C
Total Magnesium
0.39
3880
100
KM
06/18/2014 13:27
SW 6010C
Total Sodium
0.17
1650
100
KM
06/18/2014 13:27
SW 6010C
Total Iron
16300
100
KM
06/18/2014 13:27
SW 6010C
Total Aluminum
33400
100
KM
06/18/2014 13:27
SW 6010C
Total Manganese
339
5
KM
06/18/2014 13:27
SW 6010C
Total Copper
253
5
KM
06/18/2014 13:27
SW 6010C
Total Zinc
944
5
KM
06/18/2014 13:27
SW 6010C
Ammonia Nitrogen
0.46
.4580
10.0
JM
06/18/2014 07:59
SM-4500-NH3C
Organic N
4.05
40520
10.0
06/18/2014 07:59
CALCULATION
Nitrate+Nitrite-N
<2.00
2.00
JM
06/18/2014 08:00
SM-450ONO3F
Total Cadmium
2.0
2.0
KM
06/18/2014 13:27
SW 6010C
All values are on a dry weight
basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced
in whole or part, nor may
any reference be made
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior
written authorization.
Debbie Holt

Page: 2 of 2
Report Number: 14-168-0204
Account Number: 04596
Submitted By: SCOTT CARPENTER
Send To: SOIL PLUS, LLC
SCOTT CARPENTER
P.O. BOX 1396
OXFORD, NC 27565
Lab Number: 55971
Sample Id : EWWTP 061614
A&L Eastern Laboratories, Inc.
7621 Whitepme Road Richmond, Virginia 23237 (8041743-9401 Fax[phone]
-w
uvwmleastem.com
Project: ENFIELD WWTP
NC CERT#257
REPORT OF ANALYSIS Date Sampled: 6/16/2014 11:30:00
Date Received: 06/17/2014 00:00
Date Reported: 06/20/2014
Total Chromium
70
5
KM
06/18/2014 13:27
SW 6010C
Total Nickel
36
5
KM
06/18/2014 13:27
SW 6010C
Total Lead
65
5
KM
06/18/2014 13:27
SW 6010C
Total Arsenic
6.0
3.0
KM
06/18/2014 13:27
SW 6010C
Total Mercury
1.5
0.4
KM
06/19/2014 00:00
SW-7471 B
Total Selenium
<5.0
5.0
KM
06/18/2014 13:27
SW 6010C
pH (Standard Units) " 6.14
2.00
JM
06/18/2014 07:59
SW-9045D
Total Molybdenum
<5
5
KM
06/18/2014 13:27
SW 6010C
Soluble Phosphorus 0.25
2500
100
JM
06/18/2014 09:45
SOLUBLE P IN MANURE
Comments:
WATER SOLUBLE P, SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE
PURPOSES.
QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Fe",
"P", AND
"S". ALL OTHER QC DATA IS ACCEPTABLE.
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
Debbie Holt

3
Microbac Laboratories, Inc. - Wilson Division
3809 Airport Drive NW
Wilson, NC 27896
Tel: [phone]
CERTIFICATE OF ANALYSIS Report Date: 2014/06/26
SIDN Client Marks
AA51407
Enfield WWTP EWWTP 061614
AA51407
Enfield WWTP EWWTP 061614
AA51407
Enfield WWTP EWWTP 061614
AA51407
Enfield WWTP EWWTP 061614
AA51407
Enfield WWTP EWWTP 061614
Comments:
Quote: 23-20140328-14
Work Order: 2014-06-16-016
Matrix: Sludge
Collection Date: 2014/06/16
Sample Submission Date: 2014/06/16
Analvsis Name Method
Flash Point - LiquidsSubcontracted
pH (Corrosivity) Subcontracted
Reactive Cyanide Subcontracted
Reactive Sulfide Subcontracted
TCLP Full Metals V(Subcontracted
Approved by:
Kim Hesse
Result Unit
*See Attached
*See Attached
*See Attached
*See Attached
*See Attached
For any feedback concerning our services, please contact James Nokes, Senior Vice President, at [e-mail]
or Trevor Boyce at [e-mail]
Environmental • Agrochemical • Food • Pharmaceuticals Page 1 of 1

Laboratory Report Number: L14061144
Kim Hesse
Microbac Laboratories
3809 Airport Drive
Wilson, NC 27896
1J, Please find enclosed the analytical results for the samples you submitted to Microbac
Laboratories. Review and compilation of your report was completed by Microbac's Ohio
Valley Division (OVD). If you have any questions, comments, or require further assistance
regarding this report, please contact your service representative listed below.
Laboratory Contact:
Emily Yoak — Client Services Specialist
[phone]
[e-mail]
I certify that all test results meet all of the requirements of the accrediting authority listed below. All results for soil
samples are reported on a 'dry -weight' basis unless specified otherwise. Analytical results for water and wastes are
reported on a 'as received' basis unless specified otherwise. A statement of uncertainty for each analysis is
IJ available upon request. This laboratory report shall not be reproduced, except in full, without the written approval of
Microbac Laboratories. The reported results are related only to the samples analyzed as received.
LJThis report was certified on June 26 2014
F-1
David Vandenberg — Managing Director
State of Origin: IL
Accrediting Authority: Environmental Protection Agency ID:00152
QAPP: Microbac OVD
Microbac Laboratories * Ohio Valley Division
158 Starlite Drive, Marietta, OH 45750 * T. [phone] F: [phone] * www.microbac.com
Page 1
L14061144 / Revision: 0 / 31 total pages Generated: 06/26/2014 13:24

F
L -
sort #: L14061144
ject #: 2941.016
Marne: Wilson NC
intact: Emily Yoak
Record of Sample Receipt and Inspection
U—o'M7 irndfitslb�ir:�—Cre z
ancies
This is the record of the shipment conditions and the inspection records for the samples received and reported as a sample delivery
group (SDG). All of the samples were inspected and observed to conform to our receipt policies, except as noted below.
The following discrepancies were noted:
Discrepancy
The temperature was out of the acceptable range for the following
samples
No ice present CJR
EWWTP/ AA51407: 2 of 5 1000-g containers received broken. CLS
Resolution
Please proceed.-eny
Please proceed.
Spoke to Kim from Wilson Division per the client please proceed with
remaining volume.-eny
Cooler #
Temperature Temperature CDC # Airbill #
Temp Required?
Gun
0019597
1 20.0 1Z 20 5015 031 03 167 6 4
x
li t
7
#
Question
Result
1
Were shipping coolers sealed?
Yes
2
Were custody seals intact?
Yes
Ll 3
Were cooler temperatures in range of 0-6?
No
4 F
Was ice present?
No
5
Were COC's received/information complete/signed and dated?
Yes
6
Were sample containers intact and match COC?
No
7
Were sample labels intact and match COC?
Yes
8
Were the correct containers and volumes received?
Yes
9
Were samples received within EPA hold times?
Yes
10
Were correct preservatives used? (water only)
NA
11
Were pH ranges acceptable? (vba!s excluded)
NA
12
Were VOA samples free of headspace (less than 6mm)?
NA
Microbac Laboratories e Ohio Valley Division
158 Starlite Drive, Marietta, OH 45750 e T. [phone] F: [phone]
www.microbac.com
Page 2
L14061144 / Revision: 0 / 31 total pages
Generated: 06/26/2014 13:24

sport #: L14061144
)ject #: 2941.016
Name: Wilson NC
ontact: Emily Yoak
Client ID Laboratory ID Date Collected { Date Received
EWWTP L14061144-01
EW WTP L14061144-02
O6/16/2014 13:00 { 06/18/2014 09:44
06/16/201413:00 06/18/2014 09:44
Microbac Laboratories • Ohio Valley Division
158 Starlite Drive, Marietta, OH 45750 • T. [phone] R [phone]
www.microbac.com
l
Page 3
L14061144 / Revision: 0 / 31 total pages
Generated: 06/26/2014 13:24

u5
Microbac Laboratories
Case Narrative
Login Number: L14061144
Department: Volatiles
Analyst: Franci Bolden
METHOD
Preparation SW-846 5030C/5035A
Analysis SW-846 8260B
HOLDING TIMES
Sample Preparation: All holding times were met.
Sample Analysis: All holding times were met.
PREPARATION
Sample preparation proceeded normally.
CALIBRATION
Initial Calibration: For all compounds that yielded a %RSD greater than 15%, linear or higher order equations were
applied. All acceptance criteria were met.
Alternate Source Standards: All acceptance criteria were met.
Continuing Calibration and Tune: All acceptance criteria were met.
BATCH QAIQC
Method Blank: All acceptance criteria were met.
Laboratory Control Sample: All acceptance criteria were met.
1_
Matrix Spikes: The MS/MSD results were not associated with this sample delivery group (SDG), due to insufficient
volume of sample. The laboratory included an LCS and LCS duplicate in the preparation batch in lieu of the NELAC
prescribed MS/MSD. Microbac Laboratories recommends site specific MS/MSD samples to avoid possible data
qualifications.
1 Page 1 of 2 Generated at Jun 25, 2014 13:37
L
Page 4
L14061144 / Revision: 0 / 31 total pages Generated: 06/26/2014 13:24

SAMPLES
Internal Standards: All acceptance criteria were met.
Surrogates: All acceptance criteria were met.
Other: Samples 02, were run at a dilution.
Manual Integration Reason Codes
Reason #1: Data System Fails to Select Correct Peak. In some cases the chromatography system selects and
integrates the 'wrong peak'. In this case the analyst must correct the selection and force the system to integrate the proper
peak. Other times the system may miss the peak completely.
Reason #2: Data System Splits the Peak Incorrectly or Integrates a False Peak as a Rider Peak. This phenomena is
common at low concentrations where the signal:noise ratio is low. A single compound (peak) is incorrectly split into
multiple peaks or integrated as a main peak with one or more rider peaks resulting in low area
counts for the target compound.
Reason #3: Improperly Integrated Isomers and/or coeluting compounds. This system often fails to distinguish
coeluting compounds and or isomers. The integration areas and concentrations are wrong, and they must be corrected by
manual integration. Prime examples are benzo(k)fluoranthene and benzo(b)fluoranthene which are often unresolved and
integrated improperly when both are present at low concentrations in standards or samples.
Reason #4: System Establishes Incorrect Baseline. There are numerous situations in chromatography where the
system establishes the baseline incorrectly. Some baseline errors will be obvious to the analyst and should be corrected
via manual procedures.
Reason #5: Miscellaneous. Other situations involving integration errors may require in-depth review and technical
judgment. These cases should be brought to the attention of the laboratory management. If the form of manual integration
is not clearly covered by these four cases, then review and approval by the Managing Director or the QAO will be
required.
certify that this data package is in compliance with the terms and conditions agreed to by the client and Microbac
Laboratories Inc., both technically and for completeness, except for the conditions noted above. Release of the data
contained in this hard copy data package has been authorized by the Laboratory Manager or designated person, as
verified by the following signature.
Narrative ID: 85361
Approved By: Michael Albertson
Page 2 of 2 Generated at Jun 25, 201413:37
Page 5
r-
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Generated: 06/26/2014 13:24

a
Microbac Laboratories
Case Narrative
Login Number: L14061144
Department: Semivolatiles
Analyst: Cassie A. Augenstein
METHOD
Preparation 3510C/1311
Analysis SW-846 8270C
HOLDING TIMES
Sample Preparation: All holding times were met.
Sample Analysis: All holding times were met.
PREPARATION
Sample preparation proceeded normally.
CALIBRATION
Initial Calibration: For all compounds that yielded a %RSD greater than 15%, linear or higher order equations were
applied. All acceptance criteria were met.
Alternate Source Standards: The percent difference was out of range for the following analyte:
H exachlorocyclopentadiene.
Continuing Calibration and Tune: All acceptance criteria were met.
BATCH QA/QC
Method Blank: All acceptance criteria were met.
Laboratory Control Sample:
Sample #
Analyte
Date
Result
Lower
Upper
Type
WG481469-02
Pyridine
2014-06-2413:41:00
6.00
10
100
Recovery
WG481469-03
Pyridine
2014-06-2414:13:00
157
30
RPD
Page 1 of 2 Generated at Jun 25, 201415:16
Page 6
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Generated: 06/26/2014 13:24

Matrix Spikes: The client did not specify an MS/MSD for this sample delivery group. The laboratory selected sample 02
- for MS analysis and all acceptance criteria were met.
SAMPLES
Samples: All acceptance criteria were met.
Internal Standards: All acceptance criteria were met.
Surrogates: All acceptance criteria were met.
Manual Integration Reason Codes
Reason #1: Data System Fails to Select Correct Peak In some cases the chromatography system selects and
integrates the 'wrong peak'. In this case the analyst must correct the selection and force the system to integrate the proper
peak. Other times the system may miss the peakcompletely.
i
Reason #2: Data System Splits the Peak Incorrectly or Integrates a False Peak as a Rider Peak This phenomena is
common at low concentrations where the signal:noise ratio is low. A single compound (peak) is incorrectly split into
multiple peaks or integrated as a main peak with one or more rider peaks resulting in low areacounts for the target
compound.
Reason #3: Improperly Integrated Isomers and/or coeluting compounds. This system often fails to distinguish
coeluting compounds and or isomers. The integration areas and concentrations are wrong, and they must be corrected by
manual integration. -Prime examples are benzo(k)fluoranthene andbenzo(b)fluoranthene which are often unresolved and
integrated improperly when both are present at low concentrations in standards or samples.
Reason #4: System Establishes Incorrect Baseline There are numerous situations in chromatography where the
system establishes the baseline incorrectly. Some baseline errors will be obvious to the analyst and should be corrected
via manual procedures.
Reason #5: Miscellaneous Other situations involving integration errors may require in-depth review and technical
judgment. These cases should be brought to the attention of the laboratory management. If the form of manual integration
is not clearly covered by these four cases, then review and approval by the Managing Director or the QAO will be
required.
I certify that this data package is in compliance with the terms and conditions agreed to by the client and Microbac
Laboratories Inc., both technically and for completeness, except for the conditions noted above. Release of the data
contained in this hard copy data package has been authorized by the Laboratory Manager or designated person, as
verified by the following signature.
Narrative ID: 85384
Approved By: Eric Lawson
Page 2 of 2 Generated at Jun 25, 2014 15:16
Page 7
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M
Microbac Laboratories
Case Narrative
Login Number: L14061144
Department: General Chromatography
Analyst: Eric Lawson
METHOD
Analysis SW-846 8081
HOLDING TIMES
Sample Preparation: All holding times were met.
Sample Analysis: All holding times were met.
PREPARATION
Sample preparation proceeded normally.
CALIBRATION
Initial Calibration: For all compounds that yielded a %RSD greater than 20%, linear or higher order equations were
applied. All acceptance criteria were met.
Alternate Source Standards: All acceptance criteria were met.
Continuing Calibration and Tune: All acceptance criteria were met.
BATCH QAIQC
Method Blank: All acceptance criteria were met.
Laboratory Control Sample: All acceptance criteria were met.
Matrix Spikes: There were no MS/MSD results associated with this sample delivery group, due to insufficient volume of
sample. The laboratory included an LCS and LCS duplicate in the preparation batch in lieu of the NELAC prescribed
MS/MSD. Microbac recommends site specific MS/MSD samples to avoid possible data qualification.
SAMPLES
Page 1 of 2 Generated at Jun 25, 2014 13:34
Page 8
L14061144 / Revision: 0 / 31 total pages ' Generated: 06/26/2014 13:24

P-11
Samples: All acceptance criteria were met.
LSurrogates: All acceptance criteria were met.
Manual Integration Reason Codes
Reason #1: Data System Fails to Select Correct Peak In some cases the chromatography system selects and
integrates the 'wrong peak'. In this case the analyst must correct the selection and force the system to integrate the proper
peak. Other times the system may miss the peakcompletely.
Reason #2: Data System Splits the Peak Incorrectly or Integrates a False Peak as a Rider Peak This phenomena is
common at low concentrations where the signal:noise ratio is low. A single compound (peak) is incorrectly split into
multiple peaks or integrated as a main peak with one or more rider peaks resulting in low areacounts for the target
Elcompound.
Reason #3: Improperly Integrated Isomers and/or coeluting compounds. This system often fails to distinguish
coeluting compounds and or isomers. The integration areas and concentrations are wrong, and they must be corrected by
M manual integration. Prime examples are benzo(k)fluoranthene andbenzo(b)fluoranthene which are often unresolved and
integrated improperly when both are present at low concentrations in standards or samples.
Reason #4: System Establishes Incorrect Baseline There are numerous situations in chromatography where the
system establishes the baseline incorrectly. Some baseline errors will be obvious to the analyst and should be corrected
via manual procedures.
Reason #5: Miscellaneous Other situations involving integration errors may require in-depth review and technical
judgment. These cases should be brought to the attention of the laboratory management. If the form of manual integration
is not clearly covered by these four cases, then review and approval by the Laboratory Director or the QA/QC Supervisor
will be required.
I certify that this data package is in compliance with the terms and conditions agreed to by the client and Microbac
Laboratories Inc., both technically and for completeness, except for the conditions noted above. Release of the data
contained in this hard copy data package has been authorized by the Laboratory Manager or designated person, as
verified by the following signature.
Narrative ID: 85360
Approved By: Cassie A. Augenstein
Page 2 of 2 Generated at Jun 25, 2014 13:34
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L14061144 / Revision: 0 / 31 total pages
Generated: 06/26/2014 13:24

1
i
Microbac Laboratories
Case Narrative
Login Number: L14061144
Department:. Conventionals
Analyst: April Greene
1` METHOD
( Analysis SW846 9040C,9045D/EPA 150.1/SM4500-H B (pH)
HOLDING TIMES
0
Sample Analysis: All holding times were met.
i
-� PREPARATION
Sample preparation proceeded normally.
BATCH QAIQC
Method Blank: All acceptance criteria were met.
Laboratory Control Sample: All acceptance criteria were met.
Matrix Spikes: All acceptance criteria were met.
Duplicates: All acceptance criteria were met.
SAMPLES
Samples: All acceptance criteria were met.
I certify that this data package is in compliance with the terms and conditions agreed to by the client and Microbac
Laboratories Inc., both technically and for completeness, except for the conditions noted above. Release of the data
contained in this hard copy data package has been authorized by the Laboratory Manager or designated person, as
verified by the following signature.
Narrative ID: 85394
Approved By: Deanna Hesson
Page 1 of 1 Generated at Jun 26, 2014 08:42
Page 10
L14061144 / Revision: 0 / 31 total pages Generated: 06/26/2014 13:24

Microbac Laboratories
Case Narrative
Login Number: L14061144
Department: General Chromatography
Analyst: Eric Lawson
f
METHOD
Analysis SW-846 8151A
HOLDING TIMES
Sample Preparation: All holding times were met.
Sample Analysis: All holding times were met.
PREPARATION
Sample preparation proceeded normally.
CALIBRATION
Initial Calibration: For all compounds that yielded a %RSD greater than 20%, linear or higher order equations were
applied. All acceptance criteria were met.
Alternate Source Standards: All acceptance criteria were met.
Continuing Calibration and Tune: All acceptance criteria were met.
BATCH QAIQC
Method Blank: All acceptance criteria were met.
' Laboratory Control_ Sample: All acceptance criteria were met.
Matrix Spikes: There were no MS/MSD results associated with this sample delivery group, due to insufficient volume of
sample. The laboratory included an LCS and LCS duplicate in the preparation batch in lieu of the NELAC prescribed
! MS/MSD. Microbac recommends site specific MS/MSD samples to avoid possible data qualification.
SAMPLES
I Page 1 of 2 Generated at Jun 25, 2014 10:04
Page 11
L14061144 / Revision: 0 / 31 total pages Generated: 06/26/2014 13:24

C
C
Samples: All acceptance criteria were met.
Surrogates: All acceptance criteria were met.
Manual Integration Reason Codes
Reason #1: Data System Fails to Select Correct Peak In some cases the chromatography system selects and
integrates the 'wrong peak'. In this case the analyst must correct the selection and force the system to integrate the proper
peak. Other times the system may miss the peakcompletely.
Reason #2: Data System Splits the Peak Incorrectly or Integrates a False Peak as a Rider Peak This phenomena is.
common at low concentrations where the signal:noise ratio is low. A single compound (peak) is incorrectly split into
multiple peaks or integrated as a main peak with one or more rider peaks resulting in low areacounts for the target
compound.
Reason #3: Improperly Integrated Isomers and/or coeluting compounds. This system often fails to distinguish
coeluting compounds and or isomers. The integration areas and concentrations are wrong, and they must be corrected by
manual integration. Prime examples are benzo(k)fluoranthene andbenzo(b)fluoranthene which are often unresolved and
integrated improperly when both are present at low concentrations in standards or samples.
Reason #4: System Establishes Incorrect Baseline There are numerous situations in chromatography where the
system establishes the baseline incorrectly. Some baseline errors will be obvious to the analyst and should be corrected
via manual procedures.
Reason #5: Miscellaneous Other situations involving integration errors may require in-depth review and technical
judgment. These cases should be brought to the attention of the laboratory management. If the form of manual integration
is not clearly covered by these four cases, then review and approval by the Laboratory Director or the QA/QC Supervisor
will be required.
I certify that this data package is in compliance with the terms and conditions agreed to by the client and Microbac
Laboratories Inc., both technically and for completeness, except for the conditions noted above. Release of the data
contained in this hard copy data package has been authorized by the Laboratory Manager or designated person, .as
verified by the following signature.
Narrative ID: 85353
Approved By: Cassie A. Augenstein
Page 2 of 2 Generated at Jun 25, 201410:04
L14061144 / Revision: 0 / 31 total pages
Page 12
Generated: 06/26/2014 13:24

a
w
Login Number: L14061144
Department: Metals
Analyst: Brendan Torrence
METHOD
Preparation: SW-846 3015
Analysis: SW-846 6010
HOLDING TIMES
Sample Preparation. All holding times were met.
Sample Analysis: All holding times were met.
PREPARATION
Sample preparation proceeded normally.
CALIBRATION
Initial Calibration: All acceptance criteria were met.
Alternate Source Standards: All acceptance criteria were met.
Interference Check Standards: All acceptance criteria were met.
Continuing Calibration Verification: All acceptance criteria were met.
Continuing Calibration Blank: All acceptance criteria were met.
BATCH QA/QC
Method Blank: All acceptance criteria were met.
Laboratory Control Sample: All acceptance criteria were met.
Serial Dilution/Post Digestion Spikes: WG481442 - All acceptance criteria were met.
Page 1 of 2
Microbac Laboratories
Case Narrative
Generated at Jun 25, 2014 10:55
Page 13
, L14061144 / Revision: 0 / 31 total pages Generated: 06/26/2014 13:24

Matrix Spikes: All acceptance criteria were met.
SAMPLES
Samples: All acceptance criteria were met.
Narrative ID: 85307
Approved By: Sheri Pfalzgraf
clrw�c.,`� Go-6 .
Page 2 of 2 Generated at Jun 25, 2014 10:55
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L14061144 / Revision: 0 / 31 total pages Generated: 06/26/2014 13:24

n
Microbac Laboratories
Case Narrative
Login Number: L14061144
Department: Conventionals
Analyst: Dorothy Payne
METHOD
Analysis SW846 9014/9010C/SM4500-CN-C,E-20th (Cyanide)
HOLDING TIMES
Sample Analysis: All holding times were met.
PREPARATION
Sample preparation proceeded normally.
BATCH QA/QC
Method Blank: All acceptance criteria were met.
Laboratory Control Sample: All acceptance criteria were met.
Matrix Spikes: All acceptance criteria were met.
Duplicates: All acceptance criteria were met.
SAMPLES
Samples: All acceptance criteria were met.
I certify that this data package is in compliance with the terms and conditions agreed to by the client and Microbac
Laboratories Inc., both technically and for completeness, except for the conditions noted above. Release of the data
contained in this hard copy data package has been authorized by the Laboratory Manager or designated person, as
verified by the following signature.
Narrative ID: 85395
Approved By: Deanna Hesson
�.�24?.rn4 ��.dOex1-L
Page 1 of 1 Generated at Jun 26, 2014 08:42
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L14061144 / Revision: 0 / 31 total pages Generated: 06/26/2014 13:24

LJ
2
Microbac Laboratories
Case Narrative
Login Number: L14061144
Y- Department: Conventionals
Analyst: Roy Halstead
METHOD
Analysis SW-846 1010 (Flashpoint)
Analysis Method 1010 is applicable only to liquid samples as specified in 40 CFR Part 261.21(a) (1). Section 261.21
does not define ignitability criteria, or test methods, for solid matrices. Any flashpoint data reported in this report for
samples other than liquids should be considered of screening value only.
HOLDING TIMES
Sample Analysis: All holding times were met.
PREPARATION
Sample preparation proceeded normally.
BATCH QA/QC
Method Blank: All acceptance criteria were met.
Laboratory Control Sample: All acceptance criteria were met.
Duplicates: All acceptance criteria were met.
SAMPLES
Samples: All acceptance criteria were met.
I certify that this data package is in compliance with the terms and conditions agreed to by the client and Microbac
Laboratories Inc., both technically and for completeness, except for the conditions noted above. Release of the data
contained in this hard copy data package has been authorized by the Laboratory Manager or designated person, as
verified by the following signature.
Narrative ID: 85396
Approved By: Deanna Hesson
Page 1 of 2 Generated at Jun 26, 2014 08:43
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L14061144 / Revision: 0 / 31 total pages Generated: 06/26/2014 13:24

�jl�irv+a ��2:2om'yL
Page 2 of 2 Generated at Jun 26, 2014 08:43
Page 17
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Lab Report #: L14061144
Lab Project #: 2941.016
Project Name: Wilson NC
Lab Contact: Emily Yoak
certiticate of Analysis
Sample #: L14061144-01
PrePrep Method: N/A
Instrument: BURET
I Client ID: EWWTP
Prep Method: SW7.34
Prep Date: N/A
Matrix: LigWaste
Analytical Method: SW7.34
Cal Date:
Workgroup #: WG481583
Analyst: EPT
Run Date: 06/24/201414:45
Collect Date: 06/16/2014 13:00
Dilution: 1
File ID: ET.1406241445-04
Sample Tag:
Units: mg/kg
Analyte
CAS #
Result
Qual
RL
MDL
Reactivity, Sulfide
18496-25-8
U
100
100
U Not detected at or above adjusted sample detection limit
Sample #:
L14061144-01
PrePrep Method: N/A
Instrument: ORION=4STAR
Client ID:
EWWTP
Prep Method: 9040C
Prep Date: N/A
Matrix:
LigWaste
Analytical Method: 9040C
Cal Date:
Workgroup #:.
WG481172
Analyst: AD6
Run Date: 06/20/2014 08:01
Collect Date:
06/16/2014 13:00
Dilution: 1
File ID: OS14062315084601
Sample Tag:
Units: UNITS,
Analyte
CAS #
Result
Qual
RL
MDL
Corrosivity pH
10-29-7
5.92
0.000
0.000
Temperature At Determination (C)
16.3
U
0.000
0.000
U Not detected at or above adjusted sample detection limit
I Sample #:
,1-14061144-01
PrePrep Method: N/A
Instrument: UV-120-1V
Client ID:
EWWTP
Prep Method: 9014-9010C
Prep Date: N/A
Matrix:
LigWaste
Analytical Method: 9014-9010C
Cal Date: 05/22/201415:00
Workgroup #:
WG481560
Analyst: DLP
Run Date: 06/24/201415:30 '
Collect Date:
06/16/2014 13:00
Dilution: 1
File ID: 1V.1406241530-04
Sample Tag:
Units: mg/L
Analyte
CAS #
Result
Qual
RL
MDL
Cyanide
57-12-5
0.0227
0.0100
0.00500
Sample #: L14061144-01
PrePrep Method: N/A
Instrument: PRECISION
Client ID: EWWTP
Prep Method: 1010
Prep Date: N/A
Matrix: LigWaste
Analytical Method: 1010
Cal Date:
Workgroup #: WG481363
Analyst: RAH
Run Date: 016/23/2014 09:00
Collect Date: 06/16/2014 13:00
Dilution: 1
'Pile ID: PR14062314500861
Sample Tag:
Units: Degrees C
Page 1 of 2 Generated at Jun 26, 2014 13:21
Page 18
L14061144 / Revision: 0 / 31 total pages
Generated: 06/26/2014 13: 24

Lab Report #: L14061144
Lab Project #: 2941.016
Project Name: Wilson NC
Lab Contact: Emily Yoak
rprtifiratp of Annlvcic
Analyte
CAS #
Result
Qiut
RL
MDL
Ignitability
68.0
>
0.000
0.000
> Result is greater than the associated numerical value.
`Sample #: L14061144=01-.
PrePrep Method: N/A'-
Instrument..Uy-120=1V
Client ID! �EWVVTP - _
- Prep Met hid:,'SW7.33.
Prep"Date¢;�N/A', '
-Matrix`'LigWaste
_ Analytical Method: "SW7:-93a
�. Cal Date -66/16/2014'11:00
Workgroup'# WG481625
_ _Analyst:" DLO
RunlDaie 06124/20141230�=
Collect Date 06/16/2014 13:00;
Dilution: 1
File ID 1V 1406241230 03
sample Ta _
p g
al-i _ _.: —
Urnts: m /k
- g g
j
Analyte
CAS #
Result
Qual
RL
MDL
Reactivity, Cyanide
57-12-5
U
10.0
10.0
U Not detected at or above adjusted sample detection limit
Page 2 of 2 Generated at Jun 26, 2014 13:21
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L14061144 / Revision: 0 / 31 total pages Generated: 06/26/2014 13:24

Lab Report #: L14061144
Lab Project #: 2941.016
Project Name: Wilson NC
Lab Contact: Emily Yoak
uertlticate OT Analysis
Sample #: L14061144-02
PrePrep Method:
Instrument: HPMS11
Client ID: EWWTP
Prep Method: 5030B/503OC/5035A
Prep Date: N/A
Matrix: TCLP Leach
Analytical Method: 8260E
Cal Date: 05/28/201422:32
Workgroup #: WG481419
Analyst: FJB
Run Date: 06/24/2014 02:37
Collect Date: 06/16/2014 13:00
Dilution: 10
File ID: 11M02060
Sample Tag: DL01
Units: ug/L
Analyte
Result
Qual
RL
MDL
EPA HW#
Reg. Limit
Benzene
U
50.0
1.25
D018
500
Carbon tetrachloride
U
50.0
2.50
D019
500
Chlorobenzene
U
50.0
1.25
D021
100000
Chloroform
U
50.0
1.25
D022
6000
1,2-Dichloroethane
U
50.0
2.50
D028
500
1,1-Dichloroethene
U
50.0
5.00
D029
700
Methyl Ethyl Ketone
U
100
25.0
D035
200000
Tetrachloroethene
U
50.0
2.50
D039
700
Trichloroethene
U
50.0
2.50
D040
500
Vinyl chloride
U
100
2.50
D043
200
Surrogate
Recovery
Lower Limit
Upper Limit
Q
Dibromofluoromethane
93.2
86
118
1,2-Dichloroethane-d4
83.6
80
120
Toluene-d8
98.7
88
110
4-Bromofluorobenzene
96.7
86
115
U Not detected at or above adjusted sample detection limit
Sample #: L14061144-02
PrePrep Method:
Instrument: HPMS12
j Client ID: EWWTP
Prep Method: 3510C
Prep Date: 06/23/201414:00
1 Matrix: TCLP Leach
Analytical Method: 8270C
Cal Date: 06/19/201412:39
j( Workgroup #: WG481549
Analyst: CAA
Run Date: 06/24/201415:17
Collect Date: 06/16/2014 13:00
Dilution: 1
File ID: 12N149472
Sample Tag: 01
Units: ug/L
Analyte
Result
Qual
RL
MDL
EPA HW#
Reg. Limit
o-Cresol
U
50.0
25.0
D023
200000
m-,p-Cresol
U
50.0
25.0
D025
200000
1,4-Dichlorobenzene
U
50.0
25.6
D027
7500
2,4-Dinitrotoluene
U
50.0
25.0
D030
130
Hexachlorobenzene
U
50.0
25.0
D032
130
Hexachlorobutadiene
U
50.0
25.0
D033
500
Hexachloroethane
U
50.0
25.0
D034
3000
Page 1 of 4 Generated at Jun 26, 2014 13:21
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Lab Report #: L14061144
Lab Project #: 2941.016
Project Name: Wilson NC
Lab Contact: Emily Yoak
C.prtifiratp of Analvcic
Analyte
Result
Qual
RL
MDL
EPA HW#
Reg. Limit
Nitrobenzene
U
50.0
25.0
D036
2000
Pentachlorophenol
U
250
125
D037
100000
Pyridine
U
250
125
D038
5000
2,4,5-Trichlorophenol
U
50.0
25.0
D041
400000
2,4,6-Trichlorophenol
U
50.0
25.0
D042
2000
Surrogate
Recovery
Lower Limit
Upper Limit
Q
2-Fluorophenol
41.7
21
100
Phenol-d5
27.6
10
94
Nitrobenzene-d5
72.2
35
114
2-Fluorobiphenyl
70.5
43
116
2,4,6-Tribromophenol
90.4
10
123
p-Terphenyl-d14
83.6
33
141
U Not detected at or above adjusted sample detection limit
Sample #: L14061144-02
PrePrep Method:
Inst HP15
Client ID: EWWTP
Pre Method: 3510C
p
Prrumete
ep' Date-06/23/201411:00
Matrix: TCLP Leach
Analytical Method' 8081A'
Cal Date --- 06/24/2014 20:08
Workgroup M. WG481565
Analyst: ECL_
Run Date:: 06/24/2014 22:27
Collect Date: 06/16/2014 13:00
Dilution: 1 .
"File ID: 15G44802:R
Sample Tag: 01
Units: ug/L
Analyte
Result
Qua[
RL
MDL
EPA HW#
Reg. Limit
Endrin
U
0.500
0.100
D012
20
Lindane
U
0.500
0.100
D013
400
Methoxychlor
U
0.500
0.100
D014
10000
Toxaphene
U
10.0
3.00
D015
500
Chlordane
U
10.0
3.00
D020
30
Heptachlor
U
0.500
0.100
D031
8
Heptachlor Epoxide
U
0.500
0.100
D031
8
alpha Chlordane
U
0.500
0.100
gamma Chlordane
U
0.500
0.100
Surrogate
Recovery
Lower Limit
Upper Limit
Q
2,4,5,6-Tetrachloro-m-xylene
60.0
20
180
Decachlorobiphenyl
60.9
25
140
U Not detected at or above adjusted sample detection limit
Page 2 of 4 Generated at Jun 26, 2014 13:21
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L14061144 / Revision: 0 / 31 total pages Generated: 06/26/2014 13:24

Lab Report #: L14061144
Lab Project #: 2941.016
Project Name: Wilson NC
Lab Contact: Emily Yoak
Certlticate of Analyses
Sample #: L14061144-02
PrePrep Method:
Instrument: HP17
Client ID: EWWTP
Prep Method: METHOD
Prep Date: 06/23/2014 09:31
Matrix: TCLP Leach
Analytical Method: 8151A
Cal Date: 06/13/2014 18:10
Workgroup#: WG481567
Analyst: ECL
Run Date: 06124/201417:07
Collect Date: 06/16/2014 13:00
Dilution: 1
Pile ID: 17617288.F
Sample Tag: 01
Units: ug/L
Analyte
Result
Qual
RL
MDL
EPA HW#
Reg. Limit
2,4-D
U
20.0
5.00
D016
10000
2,4,5-TP (Silvex)
U
2.00
0.500
D017
1000
Surrogate
Recovery
Lower Limit
Upper Limit
Q
2,4-Dichlorophenylacetic acid
73.3
20
144
U Not detected at or above adjusted sample detection limit
Sample #: L14061144-02
PrePrep Method:
Instrument: ICP-THERMO2
Client ID: EWWTP
Prep Method: 3015
Prep Date: 06/23/2014 08:20
Matrix: TCLP Leach
Analytical Method: 6010B
Cal Date: 06/23/2014 13:33
Workgroup #: WG481442
Analyst: BKT
Run Date: 06/23/2014 16:02
Collect Date: 06/16/2014 13:00
Dilution: 1
File ID: T2.062314.160208
Sample Tag: 01
_ Units: mg/L
Analyte
Result
Qua[
RL
MDL
EPA HW#
Reg. Limit
Arsenic, TCLP
U
1.00
0.500
D004
5
Barium, TCLP
U
0.100
0.0500
D005
100
Cadmium, TCLP
U
0.100
0.0500
D006
1
Chromium, TCLP
U
0.200
0.100
D007
5
Lead, TCLP
U
1.00
0.500
D008
5
Selenium, TCLP
U
0.800
0.400
D010
1
Silver, TCLP
U
0.100
0.0500
D011
5
U Not detected at or above adjusted sample detection limit
Sample #: L14061144-02
PrePrep Method:
Instrument: CVAA1
Client ID: EWWTP
Prep Method: 7470A
Prep Date: 06/23/2014 09:47 ,
Matrix: TCLP Leach
Analytical Method: 7470A
Cal Date: 06/231201415:28
Workgroup #: WG481471
Analyst: JJS
Run Date: 06/23/2014 16:16
Collect Date: 06/16/2014 13:00
Dilution: 1
File ID: M1.062314161634
Sample Tag: 01
Units: mg/L
Analyte
Result
Qual
RL
MDL
EPA HW#
Reg. Limit
Mercury
U
0.00200
0.00100
D009
0.2
U Not detected at or above adjusted sample detection limit
Page 3 of 4 Generated at Jun 26, 2014 13:21
Page 22
L14061144 / Revision: 0 / 31 total pages
Generated: 06/26/2014 13:24

Lab Report #: L14061144
Lab Project #: 2941.016
Project Name: Wilson NC
Lab Contact: Emily Yoak
Certificate of Analysis
r
Page 4 of 4 Generated at Jun 26, 2014 13:21
Page 23
I
L14061144 / Revision: 0 / 31 total pages
Generated: 06/26/2014 13:24

IF
L..
L
Microbac Laboratories Inc.
Ohio Valley Division Analyst List
June 26, 2014
001
- BIO-CHEM TESTING WVDEP 220
002 -
REIC Consultants, Inc.
003
- Sturm Environmental
004 -
MICROBAC PITTSBURGH
005
- ES LABORATORIES
006 -
ALCOSAN LABORATORIES
007
- ALS LABORATORIES
008 -
BENCHMARK LABORATORIES
010
- MICROBAC CHICAGOLAND
ADC -
ANTHONY D. CANTER
ADG
- APRIL D. GREENE
ALS -
ADRIANE L. STEED
AWE
- ANDREW W. ESSIG
AZH -
AFTER HOURS
BAF
- BRICE A. FENTON
BJO -
BRIAN J. OGDEN
BKT
- BRENDAN TORRENCE
BLG -
BRENDA L. GREENWALT
BRG
- BRENDA R. GREGORY
CAA -
CASSIE A. AUGENSTEIN
CAF
- CHERYL A. FLOWERS
CEB -
CHAD E. BARNES
CJR
- COURTNEY J. REXROAD
CLC -
CHRYS L. CRAWFORD
CLS
- CARA L. STRICKLER
CLW -
CHARISSA L. WINTERS
CPD
- CHAD P. DAVIS
CSH -
CHRIS S. HILL
DAK
- DEAN A. K
DCM -
DAVID C. MERCKLE
DEV
- DAVID E. VANDENBERG
DIH -
DEANNA I. HESSON
DLB
- DAVID L. BUMGARNER
DLP -
DOROTHY L. PAYNE
DSM
- DAVID S. MOSSOR
ECL
- ERIC C. LAWSON
ENY
- EMILY N. YOAK
EPT -
ETHAN P. TIDD
ERP.
- ERIN R. PORTER
FJB
- FRANCES J. BOLDEN
JBK
- JEREMY B. KINNEY
JDH
- JUSTIN D. HESSON
JDS
- JARED D. SMITH
JJS
- JOHN J. ST MARIE
JLL
- JOHN L. LENT
JMW
- JEANA M. WHITE
JTP
- JOSHUA T. PEMBERTON
JWR
- JOHN W. RICHARDS
JWS
- JACK W. SHEAVES
JYH
- JI Y. HU
KAJ
- KELLIE A. JOHNSON
KDW
- KATHRYN D. WELCH
KEB
- KATIE E. BARNES
KHR
- KIM H. RHODES
KRA
- KATHY R. ALBERTSON
KRB
- KAELY R. BECKER
KRP
- KATHY R. PARSONS
LEC
- LAURA E. CARPENTER
LKN
- LINDA K. NEDEFF
LLS -
LARRY L. STEPHENS
LSB
- LESLIE S. BUCINA
MBK -
MORGAN B. KNOWLTON
MDA
- MIKE D. ALBERTSON
MDC -
MIKE D. COCHRAN
MES
- MARY E. SCHILLING
MLB -
MEGAN L. BACHE
MMB
- MAREN M. BEERY
MRT -
MICHELLE R. TAYLOR
MSW
- MATT S. WILSON
PDM -
PIERCE D. MORRIS
PIT
- MICROBAC WARRENDALE
PSW -
PEGGY S. WEBB
QX -
QIN XU
RAH -
ROY A. HALSTEAD
REK
- BOB E. KYER
RLB -
BOB BUCHANAN
RM -
RAYMOND MALEKE
RNP -
RICK N. PETTY
RS -
ROSEMARY SCOTT
SAV -
SARAH A. VANDENBERG
SDC
- SHALYN D. CONLEY
SEP -
SUZANNE J. PAUGH
SLM
- STEPHANIE L. MOSSBURG
SLP -
SHERI L. PFALZGRAF
TLC
- TYLER L. CORDELL
TMB -
TIFFANY M. BAILEY
TMM
- TAMMY M. MORRIS
TPA -
TYLER P. AMRINE
VC -
VICKI COLLIER
WJB -
WILL J. BEASLEY
WRR
- WESLEY R. RICHARDS
WTD -
WADE T. DELONG
XXX
- UNAVAILABLE OR SUBCONTRACT
WVDEP 060
L14061144 / Revision: 0 / 31 total pages
Page 24
Generated: 06/26/2014 13: 24

Microbac Laboratories Inc.
List of Valid Qualifiers
June 26, 2014
Qualkey: STD_ND=U
Qualifier Description
Surrogate or spike compound out of range
+ Correlation coefficient for the MSA is less than 0.995
< Result is less than the associated numerical value.
> Result is greater than the associated numerical value.
A See the report narrative
B Analyte present in method blank
131 Target analyte detected in method blank at or above the method reporting limit
B3 Target analyte detected in calibration blank at or above the method reporting limit
C Confirmed by GC/MS
CG Confluent growth
DL Surrogate or spike compound was diluted out
E Estimated concentration due to sample matrix interference
EDL Elevated sample reporting limits, presence of non -target analytes
EMPC Estimated Maximum Possible Concentration
F, S Estimated result below quantitation limit; method of standard additions(MSA)
FL Free Liquid
H1 Sample analysis performed past holding time.
I Semiquantitative result (out of instrument calibration range)
J The analyte was positively identified, but the quantitation was below the RL
J,B Analyte detected in both the method blank and sample above the MDL.
J,H1 The analyte was positively identified, but the quantitation was below the RL. Sample analysis performed past holding time
J,P
Estimate; columns don't agree to within 40%
-- J,S
Estimated concentration; analyzed by method of standard addition (MSA)
L
Sample reporting limits elevated due to matrix interference
L1
The associated blank spike (LCS) recovery was above the laboratory acceptance limits:
L2
The associated blank spike (LCS) recovery was below the laboratory acceptance limits.
M
Matrix effect; the concentration is an estimate due to matrix effect.
N
Tentatively identified compound(TIC)
NA
Not applicable
ND, L
Not detected; sample reporting limit (RL) elevated due to.interference
ND, S
Not detected; analyzed by method of standard addition (MSA)
NF
Not found by library search
NFL
No free liquid
NI
Non -ignitable
NR
Analyte is not required to be analyzed
NS
Not spiked
P
Concentrations >40% difference between the two GC columns
Q
One or more quality control criteria failed. See narrative.
QNS
Quantity of sample not sufficient to perform analysis
RA
Reanalysis confirms reported results
RE
Reanalysis confirms sample matrix interference
S
Analyzed by method of standard addition (MSA)
SMI
Sample matrix interference on surrogate
SP
Reported results are for spike compounds only
TIC
Library Search Compound
TNTC
Too numerous to count
U
Not detected at or above adjusted sample detection limit
- U,H1
Not detected; sample analysis performed past holding time.
UJ
Undetected; the MDL and RL are estimated due to quality control discrepancies.
W
Post -digestion spike for furnace AA out of control limits
X
Exceeds regulatory limit
X, S
Exceeds regulatory limit; method of standard additions (MSA)
Z
Cannot be resolved from isomer - see below
Page 25
L14061144 / Revision: 0 / 31 total pages Generated: 06/26/2014 13:24

�VMiCROBAC"'
Submission Form
11 RRAD rl r_1 D CIICn 410%ar
Wilson Division ..
3809 Airport Drive, Wilson, NC 27896
Phone: [phone]
Fax: [phone]
www.microbac.com
Submitted By (include company name, address, contact name, phone numb r & email
address): Check here If you want confirmation that your samples were received.
El
Date Submitted:
Quote No.:
Payment InfoJPO No.:
of
Report To (include company name, address, contact name, phone number & email address):
Same as above ❑
1k;m rAV-1'5sif— .
Wd Report By: )� inLb S � ia�s$ ��mt-ob ba,- e em
Email/PDF
❑ Fax
(email addresses)
(fax
umber) ❑ Mail
❑ Report cc:
❑ Other
Invoice To (include company name, address, contact name, phone number & email ad
ress): Same as above ❑
�6o
Turn -around -time:
Raw Data Required:" UY 0
N
Controlled
Substance: Y N
�
`"Additional charges apply
DE4
egistration No.:
0 Standard (10-15 workdays)
El Rush workdays)*
Sample Storage &Handlin
pgg
Hazardous
❑ Not
Information:
Hazardous
❑ Emergency Rush (1-2 work days)"
❑ A bient
Refrigerator °C to 8 °C)
❑ Hazardous
— M bS Required
'must have prior approval from Microbac VJNC,
(2
❑ Freezer (-10°C to -26 °C)
Suitab
specia
a for dispo al in a landfill w/o treatment or
packagin
Please refer to quote for surcharge information.
❑ Freezer (-80°C)
❑ Y ❑ N
SIDN &
Sample Type/
Customer
Analysis
& Method
Reporting
Sample
WO
Material Name
Sample ID
R
quested
Criteria
Collection
(internal "
use only)
(This info. will be on the CoA/report)
(LOD, specs,
etc. If left blank
Time &
results will be
Date
reported as
(optional):
found)
r' YV
�} s% �} (�
ro(-re,,-
P
OL
COr
, ire �y
Micro
ac OVD
06/18/2
14 09:44
Additional Comments:
' Received:
By: CO
RTNEY REXR
R0 221000055915
If data is to be used for regulatory compliance please indicate which regulatory agency.
Submission of this order form constitutes a binding contract for the
requested
analysis.
I
Page 26
L14061144 / Revision: 0 / 31 total pages Generated: 06/26/2014 13:24

Microbac Laboratories Inc.
Internal Chain of Custody Report
Login: L14061144
Account: 2941
Project: 2941.016
Samples: 2
Due Date: 25-JUN-2014
Samplenum Container ID Products
L14061144-01 390156
Bottle: 1
Seq.
I Purpose
I From
I To
I Date/Time -JAcceptIRelinquishi
pH
1
LOGIN
COOLER
W1
19-JUN-2014 15:10
CJR
2
ANALYZ
W1
WET
20-JUN-2014 07:52
ADG
BJO
3
ANALYZ
W1
EXT
23-JUN-2014 08:17
RAH
CLS
Comments:Products cancelled..
4 ALYZ WET I A2 24-JUN-2014 11:28 CLS I EPT
Comments:Products cancelled.
Samplenum Container ID Products
L14061144-01 390157
Bottle: 1
Seq.
I Purpose
From
I To
I Date/Time
JAcceptlRelinquishl
pH
1
GIN
COOLE
W1
19-JUN-2014 15:10
CJR
2
PALYZ
I W1
I TCL
20-JUN-2014 07:45
1 BRG
I BJO
Samp 1enum Container ID Products
L14061144-01 390158
Bottle: 1
Seq.
I Purpose
I From
I To
I Date/Time
Accept
Relinquish
pH
1
OGIN
COOLE
W1
19-JUN-2014 15:10
CJR
2
MALYZ
I Wl
I TCL
20-JUN-2014 07:45
1 BRG
I BJO
Samplenum Container ID Products
L14061144-01 391107 CN COR-PH FLASH REACTC REACTS
Bottle: 1
Seq.
Purpose
From
I To
Date/Time
IAccept
Relinquish
pH
1
OGIN
COOLE
W1
20-JUN-2014 15:14
BRG
Samplenum Container ID Products
L14061144-02 391108
Bottle: 1
Seq.
I Purpose
From
I To
I Date/Time
Accept
Relinquish
pH
1
OGIN
COOLE
TCL
20-JUN-2014 15:14
BRG
2
ISTORE
TCL
I A2
23-JUN-2014 14:24
CLS
ERG
Al - Sample Archive (COLD)
A2 - Sample Archive (AMBIENT)
Fl - Volatiles Freezer in Login
Vl - Volatiles Refrigerator in Login
Wl - Walkin Cooler in Login
Page 27
L14061144 / Revision: 0 / 31 total pages Generated: 06/26/2014 13:24

Microbac Laboratories Inc.
Internal Chain of Custody Report
Login: L14061144
Account: 2941
Project: 2941.016
Samples: 2 _
Due Date: 25-JUN-2014
Sampleiium Container ID Products
L14061144-02 391109 8081-TC 8151-TC 826-TC 827-TC TC-EX TC-ZHE
Bottle: 1
Seq.
I Purpose
From
To
I Date/Time
AcceptlRelinquishl
pH
1
OGIN
COOLE
TCL
20-JUN-2014 15:14
1 BRG
2
STORE
I TCL
I A2
23-JUN-2014 14:24
1 CLS
I BRG
Al. - Sample Archive (COLD)
A2 - Sample Archive (AMBIENT)
F1 - Volatiles Freezer in Login
V1 - Volatiles Refrigerator in Login
W1 - Walkin Cooler in Login
Page 28
L14061144 / Revision: 0 / 31 total pages Generated: 06/26/2014 13:24

NELAP Addendum -May 22, 2014
Non-NELAP LIMS Product and Description
The following is a list of those tests that are not included in the Microbac — OVL NELAP Scope of
Accreditation:
Heat of Combustion (BTU)
Total Halide by Bomb Combustion (TX)
Particle Sizing - 200 Mesh (PS200)
Specific Gravity/Density (SPGRAV)
Total Residual Chlorine (CL-TRL)
Total Volatile Solids (all forms) (TVS)
Total Coliform Bacteria (all methods)
Fecal Coliform Bacteria (all methods)
Sulfite (S03)
Thiodiglycol (TDG-LCMS)
Acetate (HPLC-UV)
Formate (HPLC-UV)
Acetaldehyde (HPLC-UV)
Propionaldehyde (HPLC-UV)
Fluoroborate (ISE)
SOLID AND HAZARDOUS CHEMICALS
Nitrogen, Ammonia by Method 350.1
Chromium, Hexavalent, Leachable by SM3500 Cr-B 2009
( Phenolics, Total by Method 420.1
i
NELAP Accreditation by Laboratory SOP
NONPOTABLE WATER
OVL HPLCO2/HPLC-UV
Nitroglycerin
Acetic acid
Butyric acid
Lactic acid
Propionic acid
Pyruv'ic acid
OVL MSS01/GC-MS
1,4-Phenylenediamine
1-Methylnaphthalene
1,4-Dioxane
Atrazine
Benzaldehyde
Biphenyl
Caprolactam
Page 29
L14061144 / Revision: 0 / 31 total pages Generated: 06/26/2014 13:24

Hexamethylphosphoramide (HMPA)
Pentachlorobenzene
Pentachloroethane
f NELAP Accreditation by Laboratory SOP
NONPOTABLE WATER
OVL MSV01/GC-MS
1, 1, 2-Trichloro-1,2,2-trifluoroethane
1,3-Butadiene
Cyclohexane
Cyclohexanone
Dimethyl disulfide
Dimethylsulfide
Ethyl-t-butylether (ETBE)
Isoprene
Methylacetate
Methylcyclohexane
T-amylmethylether (TAME)
Tetrahydrofuran (THF)
OVL RSKOI/GC-FID
Isobutane
n-Butane
Propane
Propylene
Propyne
OVL HPLC07/HPLC-MS-MS
Hexamethylphosphoramide (XMPA-LCMS)
SOLID AND HAZARDOUS CHEMICALS
OVL MSS01/GC-MS
1-Methyinaphthalene
Benzaldehyde
Biphenyl
Caprolactam
Pentachloroethane
NELAP Accreditation by Laboratory SOP
Page 30
L14061144 / Revision: 0 131 total pages Generated: 06/26/2014 13:24

SOLID AND HAZARDOUS CHEMICALS
OVL MSV01/GC-MS
1.3-Butadiene
Cyclohexane
Cyclohexanone
Dimethyl disulfide
Dimethylsulfide
Ethyl-t-butylether (ETBE)
Isoprene
Methylacetate
Methylcyclohexane
n-Hexane
T-amylmethylether (TAME)
Page 31
L14061144 / Revision: 0 / 31 total pages Generated: 06/26/2014 13:24

ANNUAL. RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000839 Facility Name Granville Farms, Inc. Class S Source Permit No. NCO043559
LaboratoryI A&LEastem
Labs, Inc.
Laboratory 2
Sample or CompositeDate
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
57,200
AmmoniaNitr+ogen
N/A
N/A
5,590
Arsenic
41
75
3
Cadmium
39
85
2
Calcium
N/A
N/A
17s000
Copper
1,500
4,300
147
Lead
300
840
5
Magnesium
N/A
N/A
2,470
M ercury
17
57
0.4
Molybdenum
N/A
75
5
Nickel
420
420
8
Nitrate -Nitrite Nitrogen
N/A
N/A
56
Percent Solids
N/A
N/A
3.58
pH (no units)
N/A
N/A
11.60
Phosphorus
N/A
N/A
22;600-
Potassium
N/A
N/A
1,110
PAN (Ini./Inc.)
N/A
N/A
13,359
PAN (Surface)
N/A
N/A
10,564
Selenium
100
100
5
Sodium
N/A
N/A
2,360
SAR
N/A
N/A
0.29
TrKN
N/A
N/A
31,300
Zinc
2,800
7,500
452
Source Name Feardngton Utility WW TP
"I certify- under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified persounel pro edy gathered and evaluated the infomtation submitted. I am aware that there are significant penalties for
submi ' false information, in ing the possibility of fines and imprisonment for knowi n violati
ons"7"
A Ts
afore of Fteparer Date
sPtepater is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1162 (26)

Facility Fearrington Utility VIW FP
IT Sampling Date 9/18/2014
% Solids 3.58
I
Mineralization Rate 0.3
Gallons per DT 6,698.55
PH 11.6
1
i
i
i
J
FIELD LOADING ESTIMATES
Sodium Absorpotion 0.29 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 31,300 lbs./1,000 gal 9.35
Ammonia Nitrogen (mg/Kg) 5,590.00 lbs./1,000 gal 1.67
Nitrate -Nitrite (mg/Kg) 55.87 lbs./1,000 gal 0.02
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 10,564 lbs./1,000 gal 3.15
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 13,359 lbs./1,000 gal 3.99
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
.420
100
100
2,800
7,500
1 St Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
Potassium lbs./1,000 gal
0.33
Phosphorus lbs./1,000 gal
6.75
Calcium lbs./1,000 gal
52.25
Magnesium lbs./1,000 gal
0.74
Manganese lbs./1,000 gal
0.10
Sulfur lbs./1,000 gal
1.56
Molybdenum lbs./1,000 gal
0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
3.00
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
2.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
147.00
Copper lbs./1,000 gal
0.04
Lead (mg/Kg)
5.00
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.40
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
.8.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
452.00
Zinc lbs./1,000 gal
0.13
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
TKN
PAN PAN
Nitrogen
TKN
PAN PAN
Nitrogen
(mg/kg) (lbs/DT)
(mg/Kg)
(mg/kg) (lbs/DT)
(mg/Y-g)
31,300
10,564 21.13
20,736
31,300
13,359 26.72
17,941
20,736
3,110 6.22
17,626
17,941
2,691 5.38
15,250
17,626
1,322 2.64
16,304
15,250
1,144 2.29
14,106
16,304
611 1.22
15,692
14,106
529 1.06
13,577
15,692
294 0.59
15,398
13,577
255 0.51
13,323
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)'
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
lotai 15,902 31.80
Total 17,977 35.95

Page: 1 of 2
Report Number: 14-262-0207
Account Number: 04596
Submitted By: SCOTT CARPENTER
Send To: SOIL PLUS, LLC
SCOTT CARPENTER
P.O. BOX 1396
OXFORD, NC 27565
�L A&L Eastern Laboratories, Inc.
7621 Whitepine Road Richmond, Virginia 23237 IBM) 743-9401 Fax [phone]
ue m.aleastern.cotn
Project: 200705.A17- FERRINGTON VILLAGE CLASS B
NC CERT # 257
REPORT OF ANALYSIS
Date Sampled: 9/18/2014 11:00:00
Lab Number: 57670
Date Received: 09/19/2014 00:00
Sample Id : FV 091814
Date Reported: 09/24/2014
RESULT
RESULT
QUANTITATION
METHOD
Total Solids *
3.58
35800
100.0
RD
09/19/2014 14:39
SM-254OG
Moisture *
96.42
100.0
RD
09/19/2014 14:39
SM-2540G
Total Kjeldahl Nitrogen
3.13
31300
10.0
JM
09/22/2014 08:24
SM-4500-NH3C-TKN
Total Phosphorus
2.26
22600
100
KM
09/22/2014 13:29
SW 6010C
Total Potassium
0.11
1110
100
KM
09/22/2014 13:29
SW 6010C
Total Sulfur
0.52
5210
100
KM
09/22/2014 13:29
SW 6010C
Total Calcium
17.50
175000
100
KM
09/22/2014 13:29
SW 6010C
Total Magnesium
0.25
2470
100
KM
09/22/2014 13:29
SW 6010C
Total Sodium
0.24
2360
100
KM
09/22/2014 13:29
SW 6010C
Total Iron
5260
100
KM
09/22/2014 13:29
SW 6010C
Total Aluminum
57200
100
KM
09/22/2014 13:29
SW 6010C
Total Manganese
322
5
KM
09/22/2014 13:29
SW 6010C
Total Copper
147
5
KM
09/22/2014 13:29'
SW 6010C
Total Zinc
452
5
KM
09/22/2014 13:29
SW 6010C
Ammonia Nitrogen
0.56
5590
10.0
JM
09/22/2014 08:24
SM-4500-NH3C
Organic N
2.57
25710
10.0
09/22/2014 08:24
CALCULATION
Nitrate+Nitrite-N
<2.00
2.00
JM
09/22/2014 09:00
SM-450ONO3F
Total Cadmium
<2,0
2.0
KM
09/22/2014 13:29
SW 6010C
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made A&M-(*A
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
Debbie Holt

Page: 2 of 2
Report Number: 14-262-0207
Account Number: 04596
Submitted By: SCOTT CARPENTER
Send To: SOIL PLUS, LLC
SCOTT CARPENTER
P.O. BOX 1396
OXFORD, NC 27565
�L A&L Eastern Laboratories, Inc.
7621 Whitepme Road Richmond, Virginia 23237 [phone] Fax [phone]
www.aleadern.com
Project: 200705.A17- FERRINGTON VILLAGE CLASS B
NC CERT # 257
REPORT OF ANALYSIS Date Sampled: 9/18/2014 11:00:00
Lab Number: 57670 Date Received: 09/19/2014 00:00
Sample Id : FV 091814 Date Reported: 09/24/2014
Total Chromium
16
5
KM
09/22/2014 13:29
SW 6010C
Total Nickel
8
5
KM
09/22/2014 13:29
SW 6010C
Total Lead
5
5
KM
09/22/2014 13:29
SW 6010C
Total Arsenic
<3.0
3.0
KM
09/22/2014 13:29
SW 6010C
Total Mercury
<0.4
0.4
KM
09/22/2014 10:10
SW-7471 B
Total Selenium
<5.0
5.0
KM
09/22/2014 13:29
SW 6010C
pH (Standard Units) * 11.60
2.00
JM
09/22/2014 08:24
SW-9045D
Total Molybdenum
<5
5
KM
09/22/2014 13:29
SW 6010C
Soluble Phosphorus 0.02
200
100
MW
09/22/2014 10:05
SOLUBLE P IN MANURE
Comments:
SULFUR, SOLUBLE PHOSPHORUS AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES.
QUALIFIER: THE MS, MSD WAS OUT OF LIMITS for "Al".
ALL OTHER QC DATA IS ACCEPTABLE. -
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
Debbie Holt

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Fawns, Inc. Class B Source Permit No. NCO069311 Source Name Franklin County W WTP
Laboratory i Medwl), Inc.
Laboratory 2
Sample of CompositeDate 8/8/2014
I
Parameter (mg/rg) Class A Cias B
Aluminum
N/A
N/A
29,800
Ammonia Nitrogen
N/A
N/A
5,868
Arsenic
41
75
0.943
Cadmium
39
85
0,566
Calcium
N/A
N/A
14,300
Copper
1,500
4,300
132
Lead
300
840
It
Magnesium
N/A
N/A
3,360
Mercury
17
57
0.292
Molybdenum
N/A
75
0.943
Nickel
420
420
11.2
Nittwe-MWte Mttagen
N/A
N/A
102
Percent Solids
N/A
N/A
1.06
pH (no units)
N/A
N/A
7.00
Phosphorus
N/A
N/A
22; 60
Potassium
N/A
N/A
25,900
PAN (En;./Inc.)
N/A
N/A
14,560
PAN (Sutface)
N/A
N/A
11,626
Selenium
100
100
0.943
Sodium
N/A
N/A.
21200
SAR
N/A
NIA,
429
TEN
N/A
N/A
34590
Zinc
2,800
7,W0
319
uI certify, under penalty of law, that. this document was prepared under my direction or superdsiortin accordan= with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there ate significant penalties for
submitting false information. including the possibility offines and imprisonment for knowing violations."
Signature ofP,.pare><* Date
*Pwparer is de£med in 40 CPR Part 503.9(r) and BA NCAC 2T 1102 (ZW)

FIELD LOADING ESTIMATES
Facility Franklin County WW I'P
Sampling Date 8/8/2014
% Solids 1.06
Mineralization .Rate 0.30
Gallons per DT 22,623.41
pH 7
Sodium Absorpotion 4.25 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land ripply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 34,500 lbs./1,000 gal 3.05
Ammonia Nitrogen (mg/Kg) 5,867.92 lbs./1,000 gal 0.52
Nitrate -Nitrite (mg/Kg) 102.00 lbs./1,000 gal 0.01
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 11,626 lbs./1,000 gal 1.03
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 14,560 lbs./1,000 gal 1.29
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1st Yeac
2nd Year
3rd Yea:
4th Year
5th Year
HEAVY METAL CONCENTRATION
Potassium lbs./1,000 gal . 2.29
Phosphorus lbs./1,000 gal 1.97
Calcium lbs./1,000 gal 1.26
Magnesium lbs./1,000 gal 0.30
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00 .
HEAVY METAL LOADING
Arsenic (mg/Kg)
0.94
Cadmium (mg/Kg)
0.57
Copper (mg/Kg)
132.00
Lead (mg/Kg)
11.00
Mercury (mg/Kg)
0.29
Nickel (mg/Kg)
11.20
Selenium (mg/Kg)
0.94
Zinc (mg/Kg)
318.00
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
TEN
PAN PAN
Nitrogen
TIEN
PAN PAN
Nitrogen
(mg/kg) (Ibs/DT)
(mg/Kg)
(mg/kg) (Ibs/DT)
(mg/Kg)
34,500
11,626 23.25
22,874
34,500
14,560 29.12
19,940
22,874
3,431 6.86
19,443
19,940
2,991 5.98
16,949
19,443
1,458 2.92
17,985
16,949
1,271 2.54
15,678
17,985
674 1.35
17,311
15,678
588 1.18
15,090
17,311
325 0.65
16,986
15,090
283 0.57
14,807
Arsenic lbs./1,000 gal
0.00
Cadmium lbs./1,000 gal
0.00
Copper lbs./1,000 gal
0.01
Lead lbs./1,000 gal
0.00
Mercury lbs./1,000 gal
0.00
Nickel lbs./1,000 gal
0.00
Selenium lbs./1,000 gal
0.00
Zinc lbs./1,000 gal
0.03
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x NR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
l oaai 11,514 35.113
Total 19,693 39.39

1211812014 12:21 Franklin Co. Public
fAY)19195566709 P.0041006
. Meriteck Inc.
EnvlronmentaI Laboratory
Laboratory CertifIcation No.165
Contact: Wrenne Kapornyai
Client. Franklin Co Public Utilities
Page 1
Report Date: 8/8/2014
NPDSS*; NCO069311
1630 CIS Hwy 1 U
Youngsville NC 27596 Date 2014 Sample Rcvd: 7 24
p I l
Meritech Work Order # 07241440 Sample: Sludge Digester Grab 7/24/14
% Total Solids
1..06 %
7/24/14
0-100 %
SM 2640B
% Dry Weight
1.08 %
7/25/14
- %
SM 2540D
Chloride
34,500 mg/kg
7/29114
10.0 rn&ft
SM 4500 Cl C
TKN
53,700 mg/kg
8/6/14
20 mg/kg
SPA 351.1
Nitrate, total
< 102 mg/kg
7/25/14
102 mg/kg
EPA 35&.2
Nitrite, total
< 102 mg/kg
7/25/14
102 mg/kg
8PA 353.2
Nitrogen, total
53,700 mg/kg
8/7/14
20 mg/kg
EPA 353.2
Sulfate
9,770 mg/kg
7/30/14
500 mg/kg
SW 846 9038
Aluminum, total
29,800 mg/kg
7/29/14
2.$0 mg/kg
EPA 200.7
Arsenic, total
< 0.943 mg/kg
7/29/14
0.943 mg/kg
SPA 200.7
Cadmium, total
0.566 mg/kg
7129/14
0.002 mg/kg
SPA 200.7
Calcium, total
14,300 mg/kg
7/29/14
10.0 mg/kg
EPA 200.7
Copper, total
132 mg/kg
7/29/14
0.002 mg/kg
EPA 200.7
Iron, total
9,62D mg/kg
7/29/14
1.25 mg/kS
EPA 200.7
Lead, total
11.D mg/kg
7129/14
0.010 mg/kg
EPA 200.7
Magnesium, total
3,36D mg/kg
7/29/14
0.005 mg/kg
EPA 200.7
Mercury, total
0.292 mg/kg
7/28/14
0.0002 mg/kg
EPA 245.1
Molybdenum, total
0,943 mg/kg
7/29/14
0.005 mg/kg
SPA 200.7
Nickel, total
11..2 mg/kg
7/29/14
0.010 mg/kg
SPA 200.7
Phosphorus, total
22,300 mg/kg
7/29/14
0.020 mg/kg
EPA 200.7
Potassium, total
25,900 mg/kg
7/29/14
1.00 mg/kg
EPA 200.7
Selenium, total
< 0.943 mg/kg
7/29/14
0.943 zing/kg
EPA 200.7
Sodium, total
21,200 mg/kg
7/29/14
0.100 mg/kg
EPA 200.7
Zinc, total
318 rmg/kg
7/29/14
0.010 mg/kg
EPA 200.7
Merltech Work Order # 07241441 Sample; Sludge Digester Grab 7/24/14
% Solids 1.43 % 7/24/14 0.2 % SM 2540B
Fecal Coliform (Sludge) 1,260 col/g dry wt 7/24/14 130 col/g dry wt SM 9222D
642 Tarneo Road, Reidsville, North Carolina 27320
tel.[phone] fac.[phone]

1211812014 12:20 Franklin Co. Public
OWj19195566709 P.0011006
" Merltech, Inc.
Environmental Laboratory
Laboratory Certification No.1,65
4 AL.
Contact: Wrenne Kapornyal r Report Date: 8/8/2014
Client: Franklin Co Public Utilities
1630 US Hwy 1
Youngsville NC 27596 Date Sample Rcvd: 7/24/14
Meritech Work Order #
07241440 A Sample: Sludge Digester
Collection Date: 7/24/14
13 11 -
TCLP Metals
Arsenic
Barium
Cadmium
c 0.1.00 mg/L
0.172 mg/L
0.020 mg/L
7/30/14
7130/14
7/30/14
0.100
0.050
0.020
510
100.0
110
EPA 200.7
EPA, 200.7
EPA 200,7
Chromium
a 0.050 mg/L
7/30/14
0.050
5.0
EPA 200.7
Lead
Mercury
< 0.100 mg/L
< 0,02 mg/L
7/30114
8/4/14
0.100
0.02
5.0
0.2
EPA 200.7
EPA 245.1
Selenium
c 0,100 rag/L
7/30/14
0.100
1.0
EPA 200.7
Silver
< 0.050 mg/L
7/30/14
0.050
5.0
EPA 200.7
unyanics
J
D"i
Parametsr
Volatiles 8260
Semi Vol. 8270
t ;
Attached
Attached
rg�1 s[s
7/29/14
7/30/14
Method
$260
9270
Other Tests
Eararnet�r
�,g
nal
Renortioe.Limlt
Notbod
Cyanide, total
{ 0.050 mg/kg
7/30/14 0.050 mg/kg EPA 335.4
Ignitability
> 140 OF
7/30/14 - - EPA 1030
PH
7.0 S.U.
7/28/14 1.0 -14.0 S.U. SM 4500 HB
Sulfide. total
K 94.3 mg/leg
7/28/14 94.3 mg/k9 SM 4500 Sri
642 Tameo Road, Reidsville, North Carolina 27320
teL(336)34x-4748 fax.(336)342-IS22

1211812014 12:20 Franklin Co. Public O:AX)19195566709
P.0021006
Meritech, Inc.
-, Environmental Labo ratary
Laboratory Certification No.165
Contact: Wrenne Kapornyai Report hate:
8/8/2014
Client; 1~ran1din Co Public Utilities
1630 US Hwy 1
Youngsville NC 27596 Data Sample Rcvd:
7/24/14
Meritech Work Order # 07241440A Sample: Sludge Digester Collection Date-.
7/24/14
1311- TCLP Pesticides & Herbicides
-' Analyst: Summit Analysis Date:
8/6/14
,Porarmeter Refinka 121t. Lim, MgJAMit IDIIUIID13
Fpetor
Heptachlor Epoxide < 0.002 mg/L 0.002 0.008 1
Endrin < 0.002 mg/L 0.002 0.02 1
Chlordane c 0.01 mg/L 0.01 0.03 1
Gamma • BHC < 0.002 mg/L 0.002 0.4 1
Toxaphene a 0.1 mg/L 0.1 0.5 1
Methoxychlor a 0.002 mg/L 0.002 10.0 1
Heptachlor < 0.002 mg/L 0.002 0.008 1
l`ie��icides - SW-$46.815,�,g
Analyst: Summit Analysis Date:
E!armwe
2,4-D
Reaft
a 5 mg/L
Det, LIM
5
bai Lim
10.0
Mugon 1Ra.M.._
1
2.4,5-TP (Silvex)
��Rhl�lill}I
c 0.5 mg/L
1 " - -
0.5
1.0
i1�41YYll
X
I hereby certify that I have reviewed and approve threw data.
Laboratory Representative
642 TaMco Road, Reidsville, North Carolina 27320
tol.[phone] f4X.(S36)3424522

1211812014 12:20 Franklin Co. Public fAK}19195566709 P.0031006
.,..w.l..,...-.w.r....r•...-un...w,..nrowrrnmrr..rw.«.,. w...wwYw.a»+a..w•....x.wnw....,w..0 ..r...mw...
V
MERITECH, I NC,
Environmental Laboratories
A aiviWon of Water Technology and Controls, Inc.
CHOW
: Franklin CO. Public Utilities
Project: TCLP
Client Sample ID: Sludge Digester
Sample Collection; 07/24114
Meritech Sample 1D: O7241440
1311 - MI-P Organics
UO stiias: SW4146 WO
Analysis: 07/29/14 Date Extracted: 07/28/14
Analyst: VWV
ra r $t;�ult � 11�i-�S11�JL�S>i�
Benzene < 0.0100 mp/L 0.0100 0.50 10
CBrbgn Tetrachloride < 0.0100 ma/L 0.0100 0.30 10
chlorobenme < 0.0100 mg/L 0.0100 100 10
- - Chloroform < 0.0100 MA 0.0100 6.0 10
1,2-Dichloroethane a 0.0100 nqx 0.0100 0.50 10
]I J-Dichlorocthene < 0.0100 Mg/L 0.0100 0,70 10
McThyl Ethyl K,ewne < 0.100 nwt 01100 200 10
Tetmchloroethylene < 0.0100 M81 0.0100 0.70 10
Triohknethene < 0.0100 MA0.0100 0.50 10
{ Vinyl Chloride <0.0200 MIX 0,020 0.20 10
i-V
Extraotlon: 07/28/14
4 Analysis; 07/30/14 Analyst: PM
L�
k�arum,eter Result Units Dot, limit Pa. Limit Dilufion_P'acYor_
1,4-Dichloroban=ne <0.100 mg/L 0.100 7.5 10
Hexaohlamben=ne <0,100 nWL 0.100 0.13 10
Hexachloro,1,3-butadiene <0.100 mg/L 0.100 0.5 10
Mexachlomothane -0.100 mg/L 0.100 3.00 to
o-cresol 40.100 rog/Ir 0.100 200 10
m&p-cresol <0.200 mg/L 0.200 200 10
ToW mesols <0.300 mg/t, 0.300 200 10
Nitroben=e 40.I00 rng/L 0.100 2.00 10
Pantaohlorophenol <0.500 mVL Moo 100 •10
Pyridine <0.100 m$/L 0.100 5.0 10
2AS-Trlchlorophonol 4.100 mg/L 0.100 400 10
1 2,4.6-Trichlorophenol <0.100 mg/L 0.100 2.00 10
2,4-Din1t vtoluene <0.100 mg/L 0.100 0.13 10
I hereby eer1 J& that I have reviewed and approve these data. ([�
Loboratary Baprsesentwbt
642 'Tamco Road * R®ldsvllle, NC 27320
(336)1 342-4748 Ph * (338) 342.1a22 FaX
�,

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. WQ00000088
Laboratory 1 Environmental
Conservation
Laboratory 2
Sample or CompositeDate 11/6/2014
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
5,200
Ammonia Nitrogen
N/A
N/A
3,500
Arsenic
41
75
9.78
Cadmium
39
85
1.57
Calcium
N/A
N/A
14,900
Copper
1,500
4,300
287
Lead
300
840
12.6
Magnesium
N/A
N/A
5,220
Mercury
17
57
0.675
Molybdenum
N/A
75
13.8
Nickel
420
420
35.2
Nitrate -Nitrite Nitrogen
N/A
N/A
390
Percent Solids
N/A
N/A
1.00
PH (no units)
N/A
N/A
6.80
Phosphorus
N/A
N/A
24,000
Potassium
N/A
N/A
7,000
PAN (Inj./Inc.)
N/A
N/A
26,240
PAN (Surface)
N/A
N/A
24,490
Selenium
100
100
9.78
Sodium
N/A
N/A
12,800
SAR
N/A
N/A
2.29
TKN
N/A
N/A
78,000
Zinc
2,800
7,500
1320
Source Name Govenor's Club WW PP
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
0902-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

FIELD LOADING ESTIMATES
Facility Govenor's Club WWTP
Sampling Date 11/6/2014
% Solids 1
Mineralization Rate 0.3
Gallons per DT 23,980.82
PH 6.8
Sodium Absorpotion 2.29 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 78,000 lbs./.1,000 gal 6.51
Potassium lbs./1,000 gal
0.58
Ammonia Nitrogen (mg/Kg) 3,500.00 lbs./1,000 gal 0.29
Phosphorus lbs./1,000 gal
2.00
Nitrate -Nitrite (mg/Kg) 390.00 lbs./1,000 gal 0.03
Calcium lbs./1,000 gal
1.24
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.44
PAN (mg/Kg) 24,490 lbs./1,000 gal 2.04
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 26,240 lbs./1,000 gal 2.19
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1st Year
2nd Year
3rd Year
4th Year
5th Year
F�
LJ
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
9.78
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.57
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
287.00
Copper lbs./11000 gal
0.02
Lead (mg/Kg)
12.60
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.68
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
35.20
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
9.78
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
1320.00
Zinc lbs./1,000 gal
0.11
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TEN
(mg/kg) (lbs/DT)
(mg/Eg)
TKN
(mg/kg) (lbs/DT)
(mg/Eg)
78,000
. 24,490 48.98
53,510
78,000
26,240 52.48
51,760
53,510
8,027 16.05
45,484
51,760
7,764 15.53
43,996
45,484
3,411 6.82
42,072
43,996
3,300 6.60
40,696
42,072
1,578 3.16
40,495
40,696
1,526 3.05
39,170
40,495
759 1.52
39,735
39,170
734 1.47
38,436
Equations
1st Yr. PAN (mg/Kg)=(MR x (1'KN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 38,265 76.53
Total 39,564 79.13

CI
www.encolabs.com
SAMPLE DETECTION SUMMARY
Client ID: Governors ClubSludge
Lab ID: C4i3807-01
Anallft
Results
Flass
MPS
M
Units
Method Notes
% Solids
1.0
0.1
0.1
% by Weight
% Solids
Aluminum - Total
5200
205
978
mg/kg dry
EPA 6010C
Ammonia as N
3500
D
87
190
mg/kg dry
EPA 350.1
Cadmium - Total
1.57
1
0.939
4.89
mg/kg dry
EPA 6010C ,
Calcium - Total
14900
B
548
2440
mg/kg dry
EPA 6010C QB-01
Copper - Total
287
18.6
48.9
mg/kg dry
EPA 6010C
Lead -Total
12.6
3
11.7
48.9
mg/kg dry
EPA 6010C
Magnesium - Total
5220
B
63'.6
2440
mg/kg dry
EPA 6010C QB-01
Molybdenum - Total
13.8
1
9.78
48.9
mg/kg dry
EPA 6010C
pH
6.8
1.0
1.0
pH Units
- EPA 9045D
Phosphorus
24000
D
300
1200
mg/kg dry
EPA 365.4
Potassium - Total
7000
391
2440
mg/kg dry
EPA 6010C
Sodium - Total
12800
587
2440
mg/kg dry
EPA 6010C
Total Kjeldahl Nitrogen
78000
D
1300
2300
mg/kg dry
EPA 351.2
Total Solids
1.0
0.0010
0.0010
% by Weight
SM 254OG-1997
Zinc - Total
1320
108
244
. mg/kg dry
EPA 6010C
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 11

www.encolabs.com
ANALYTICAL RESULTS
Description: Governors Club Sludge Lab Sample ID:C413807-01 Received: 11/06/14 12:30
Matrix: Sludge Sampled:11/06/14 12:00 Work Order: C413807
Project: Governors Club -Annual Sludge Analysis Sampled By:Aaron Chambers % Solids: 1.02
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analvte [CAS Numberl
Results
Fig
gaftg
PF
MDL
4
Batch
Method
Analysed
y Notes
Aluminum [7429-90-5]^
5200
mg/kg dry
1
205
978
41<13030
EPA 6010C
11/14/14 14:11
JDH
Arsenic[7440-38-2]^
< 9.78
mg/kg dry
1
9.78
48.9
41<13030
EPA 6010C
11/14/14 14:11
JDH
Cadmium [7440-43-9]^
1.57
J
mg/kg dry
1
0.939
4.89
4K13030
EPA 6010C
11/14/14 14:11
JDH
Calcium [7440-70-2]^
14900
B
mg/kg dry
1
548
2440
4K13030
EPA 6010C
11/14/14 14:11
JDH QB-01
Copper[7440-50-8]^
287
mg/kg dry
1
18.6
48.9
4K13030
EPA 6010C
11/14/14 14:11
JDH
Lead [7439-92-1]^
12.6
J
mg/kg dry
1
11.7
48.9
41<13030
EPA 6010C
11/14/14 14:11
JDH
Magnesium [7439-95-4]^
5220
B
mg/kg dry
1
63.6
2440
41<13030
EPA 6010C
11/14/14 14:11
JDH QB-01
Mercury[7439-97-6]^
< 0.675
mg/kg dry
1
0.675
2.35
4K10027
EPA 7471B
11/11/14 14:00
T113
Molybdenum [7439-98-7]^
13.8
J
mg/kg dry
1
9.78
48.9
4K13030
EPA 6010C
11/14/14 14:11
JDH
NickelL7440-02-0]^
< 35.2
mg/kg dry
1
35.2
244
4K13030
EPA 6010C
11/14/14 14:11
JDH
Potassium [7440-09-7]^
7000
mg/kg dry
1
391
2440
4K13030
EPA 6010C
11/14/14 14:11
JDH
Selenium [7782-49-2]^
< 9.78
mg/kg dry
1
9.78
48.9
41<13030
EPA 6010C
11/14/14 14:11
JDH
Sodium [7440-23-5]^
12800
mg/kg dry
1
587
2440
41<13030
EPA 6010C
11/14/14 14:11
JDH
Zinc [7440-66-6]^
1320
mg/kg dry
1
108
244
41<13030
EPA 6010C
11/14/14 14:11
JDH
Classical Chemistry Parameters
Analyte rCAS Numberl
Results
Elm
Units
DIE
MDL
pgl
Batch
Method
Analyzed
]t Notes
Solids
1.0
% by Weight
1
0.1
0.1
4KO7048
% Solids
11/07/14 16:17
MMR
Ammonia as N [7664-41-7]
3500
D
mg/kg dry
20
87
190
41<12005
EPA 350.1
11/12/14 11:33
SHA
Nitrate/Nitrite as N
< 390
D
mg/kg dry
97.5
390
940
4K11002
EPA 353.2
11/11/14 12:25
SHA R-01
pH
6.8
pH Units
1
1.0
1.0
4KO7044
EPA 9045D
11/07/14 15:44
MMR
Phosphorus [7723-14-0]
24000
D
mg/kg dry
123.1
300
1200
4K12014
EPA 365.4
11/17/14 13:14
SHA
Total Kjeldahl Nitrogen
78000
D
mg/kg dry
50
1300
2300
4K12008
EPA 351.2
11/17/14 10:42
SHA
Total Solids
1.0
% by Weight
1
0.0010
0.0010
4KO7047
SM 254OG-1997
11/07/14 16:17
MMR
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 11

1 ( 1
ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NC0049662
Laboratory 1 Environmental
Conservation
Laboratory 2
Sample or CompositeDate 11/12/2014
Parameter (mg/Kg) Class A Clas B
Aluminum N/A N/A 2 260
Ammonia Nitrogen
N/A
N/A
290
Arsenic
41
75
4.47
Cadmium
39
85
0.429
Calcium
N/A
N/A
26,600
Copper
1,500
4,300
296
Lead
300
840
5.36
Magnesium
N/A
N/A
2,780
Mercury
17
57
0.308
Molybdenum
N/A
75
4.47
Nickel
420
420
35
Nitrate -Nitrite Nitrogen
N/A
N/A
540
Percent Solids
N/A
N/A
2.20
pH (no units)
N/A
N/A
7.10
Phosphorus
N/A
N/A
82,000
Potassium
N/A
N/A
2,470
PAN (Inj./Inc.)
N/A
N/A
16,643
PAN (Surface)
N/A
N/A
16,498
Selenium
100
100
13.9
Sodium
N/A
N/A
7,500
SAR
N/A
N/A
1.73
TKN
N/A
N/A
53,000
Zinc
2,800
7,500
860
i
Source Name Hawthorne Subdivision WWTP
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
/� 02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

AGMAN
FIELD LOADING ESTIMATES
Facility Hawthorne Subdivision VAVI'P
Sampling Date 11/12/2014
% Solids 2.2
Mineralization Rate 0.3
Gallons per DT 10,900.37
pH 7.1
Sodium Absorpotion 1.73 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land ripply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 53,000 lbs./1,000 gal 9.72
Potassium lbs./1,000 gal
0.45
Ammonia Nitrogen (mg/Kg) 290.00 lbs./1,000 gal 0.05
Phosphorus-lbs./1,000 gal
15.05
Nitrate -Nitrite (mg/Kg) 540.00 lbs./1,000 gal 0.10
Calcium lbs./1,000 gal
4.88
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.51
PAN (mg/Kg) 16,498 lbs./1,000 gal 3.03
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 16,643 lbs./1,000 gal 3.05
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
4.47
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.43
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
296.00
Copper lbs./1,000 gal
0.05
Lead (mg/Kg)
5.36
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.31
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
35.00
Nickel•lbs./1,000 gal
0.01
Selenium (mg/Kg)
13.90
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
860.00
Zinc lbs./1,000 gal
0.16
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
53,000
16,498
33.00
36,502
53,000
16,643 33.29
36,357
36,502
5'475
10.95
31,027
36,357
5,454 10.91
30,903
31,027
2,327
4.65
28,700
30,903
2,318 4.64
28,586
28,700
1,076
2.15
27,623
28,586
1,072 2.14
27,514
27,623
518
1.04
27,106
27,514
516 1.03
26,998
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 25,894 51.79
Total 26,002 52.00

Esc
www.encolabs.com
SAMPLE DETECTION SUMMARY
Analvte
a2sults
E>acl
JMDDL
P2
ywlik
Method Mote
% Solids
2.2
0.1
0.1
% by Weight
% Solids
Aluminum - Total
2260
93.9
447
mg/kg dry
EPA 6010C
Ammonia as N
290
D
20
44
mg/kg dry
EPA 350.1
Calcium -Total
26600
B
250
1120
mg/kg dry
EPA 6010C QB-01
Copper - Total
296
8.49
22.4
mg/kg dry
EPA 6010C
Magnesium - Total
2780
B
29.1
1120
mg/kg dry
EPA 6010C QB-01
Nickel- Total
35.0
1
16.1
112
mg/kg dry
EPA 6010C
Nitrate/Nitrite as N
540
D
170
430
mg/kg dry
EPA 353.2
pH
7.1
1.0
1.0
pH Units
EPA 9045D
Phosphorus
82000
D
870
3500
mg/kg dry
EPA 365.4
Potassium - Total
2470
179
1120
mg/kg dry
EPA 6010C
Selenium - Total
13.9
J
4.47
22.4
mg/kg dry
EPA 6010C
Sodium - Total
7500
268
1120
mg/kg dry
EPA 6010C
Total Kjeldahl Nitrogen
53000
D
910
1700
mg/kg dry
EPA 351.2
Total Solids
2.2
0.0010
0.0010
% by Weight
SM 2540G-1997
Zinc - Total
860
49.2
112
mg/kg dry
EPA 6010C
�I
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 11

www.encolabs.com
ANALYTICAL RESULTS
Description: Hawthorne Sludge
Lab Sample ID: C413809-01
Received: 11/12/14 13:00
Matrix: Sludge
Sampled:11/12/14 10:55
Work Order: C413809
Project: Hawthorne -Annual Sludge Analysis
Sampled By: Ray Dixon
% Solids:
2.24
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary ceitified anaiyte [NC 5911
Analyte rCAS Numberl
Results
Flag
Units
PF
MQL
M
Batch
Method
Ana[yed
Notes
Aluminum [7429-90-5]A
2260
mg/kg dry
1
93.9
447
41<13030
EPA 6010C
11/14/14 14:14
JDH
Arsenic [7440-38-2]A
< 4.47
mg/kg dry
1
4.47
22.4
4K13030
EPA 6010C
11/14/14 14:14
JDH
Cadmium L7440-43-9]A
< 0.429
mg/kg dry
1
0.429
2.24
4K13030
EPA 6010C
11/14/14 14:14
JDH
{+
Calcium [7440-70-2]A
26600
B
mg/kg dry
1
250
1120
41(13030
EPA 6010C
11/14/14 14:14
JDH QB-01
Copper[7440-50-8]A
296
mg/kg dry
1
8.49
22.4
41<13030
EPA 6010C
11/14/14 14:14
JDH
Lead [7439-92-1]A •
< 5.36
mg/kg dry
1
5.36
22.4
41<13030
EPA 6010C
11/14/14 14:14
JDH
Magnesium [7439-95-4]A
2780
B
mg/kg dry
1
29.1
1120
4K13030
EPA 6010C
11/14/14 14:14
JDH QB-01
Mercury[7439-97-6]A
< 0.308
mg/kg dry
1
0.308
1.07
4LO1012
EPA 7471B
12/02/14 12:59
T1D
Molybdenum [7439-98-7]A
< 4.47
mg/kg dry
1
4.47
22.4
41<13030
EPA 6010C
11/14/14 14:14
JDH
Nickel[7440-02-O]A
35.0
J
mg/kg dry
1
16.1
112
4K13030
EPA 6010C
11/14/14 14:14
JDH
Potassium [7440-09-7]A
2470
mg/kg dry
1
179
1120
4K13030
EPA 6010C
11/14/14 14:14
JDH
Selenium [7782-49-2]A
13.9
J
mg/kg dry
1
4.47
22.4
41<13030
EPA 6010C
11/14/14 14:14
JDH
Sodium [7440-23-5]A
7500
mg/kg dry
1
268
1120
41<13030
EPA 6010C
11/14/14 14:14
JDH
Zinc [7440-66-6]A
860
mg/kg dry
1
49.2
112
4K13030
EPA 6010C
11/14/14 14:14
JDH
Classical Chemistry Parameters
Analvte rCAS Numberl
Results
Eft
Units
AE
MDL
PM
Batch
Method
Analyzed
By Notes
Solids
2.2
% by
1
0.1
0.1
4K13021
% Solids
11/13/14 13:17
MMR
Weight
Ammonia as N [7664-41-7]
290
D
mg/kg dry
10
20
44
41<18005
EPA 350.1
11/18/14 13:27
SHA
Nitrate/Nitrite as N
540
D
mg/kg dry
97.5
170
430
41<19013
EPA 3512
11/19/14 12:32
AIB
pH
7.1
pH Units
1
1.0
1.0
41<13024
EPA 9045D
11/13/14 13:35
MMR
Phosphorus[7723-14-0]
82000
D
mg/kg dry
400
870
3500
41(14012
EPA 365.4
11/17/14 17:37
SHA
Total Kjeldahl Nitrogen
53000
D
mg/kg dry
80
910
1700
4K14011
EPA 351.2
11/17/14 16:21
SHA
Total Solids
2.2
% by
1
0.0010
0.0010
41<13020
SM 254OG-1997
11/13/14 13:17
MMR
Weight
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 11

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Perrnit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO020559 Source Name Henderson WRF
Laboratory 1
Laboratory 2
Sample or CompositeDate
Parameter (mg/Kg) Class A Clas B
I A&L Eastern
Labs, Inc.
A&L lrastern
Labs, Inc.
A&L Eistem
Labs, Inc
A&L Fasten
I Labs, Inc.
1/8/ 14
^+/9/2U1+
7/9/Z01+
t0/B/?A]4
Aluminumi N/A
N/A
16,100
u,laa
14400
3,700
Ammonia Nitrogen, N/A
Arsenics 41
Cadmium 39
N/A
—75
85
�+
2
47,500
5
2
9,300
5
527,000
4
2
2
Calcium- N/A
N/A
27,600
27,900
9,400
42,400
Copper; %500
- — --- Lead - 300
4,300
840
339
^ 43 —
352
— 44 —
400
---
84
52
- it _
Maguesium N/A
N/A
3,030
2,830
2,780
4,3W
Mercuryj I7
57
0-+
0.6
0.9
05
Molybdenum N/A
75
11
12
9
5
Nickel: 420
Numte-Niaite Nitmgen 1 N/A
420
N/A
29
9
— 70
9
55+
1t
1,333
Percent Solids; N/A
N/A
3.36
2.42
3.72
0.15
PH (no unite) N/A
- - - Phosphorus N/A
Potassium N/A
N/A
N/A
N/A
836
28,3t o
3,67ti
8.36
-- 26,9t1) -
3,700
&15
25,9£l0
2,660
&39
1--106
13=0
PAN (Ini./Inc.)i N/A
PAN (Surlace)� N/A
N/A
N/A
_
60,350
36,6(0
40,934
26,184
536,133
7F2,633- _
Scleniuml 100
Sodium: N/A
SAIL N/A
Lao
N/A
N/A
5
2,210
0.62
5
2n170
0S1
5
5
1,7W
74.9
9,11a
f] 4 F
TEX N/A
N/A
6+,9 )
9%laa
65,906D
Sawa
Zinc' V410
7,500
786
748
734
216
_1 Cerny; utmer penury oa 13c , Mat ttds doeument vw prepared under my direction or supervision is accordance with a system designed to
assure that qualified personnel, properly gathered and evaluated the information submitted. I am aware that there arm significant penalties for
�faise information, including the passibility oftines and amp&onmentfor kooVvingviolations.1°
Signature of Preparer k Date
Vreparer is defined is 40 CFR Part 503.9(r) and 15A NCAC 2T _1102 (26)

FIELD LOADING ESTIMATES
Facility Henderson WRIT
Sampling Date 1 /8/2014
% Solids 3.36
Mineralization Rate 0.30
Gallons per DT 7,137.15
PH 8.36
Sodium Absorpotion 0.62 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land .Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 64,900 lbs./1,000 gal 18.19
Ammonia Nitrogen (mg/Kg) lbs./1,000 gal
Nitrate -Nitrite (mg/Kg) lbs./1,000 gal
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) lbs./1,000 gal
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
Potassium lbs./1,000 gal 1.03
Phosphorus lbs./1,000 gal 7.93
Calcium lbs./1,000 gal 7.73
Magnesium lbs./1,000 gal 0.85
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
4.00
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
2.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
359.00
Copper lbs./1,000 gal
0.10
Lead (mg/Kg)
43.00
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.40
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
29.00
Nickel lbs./1,000 gal
0.01
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
786.00
Zinc lbs./1,000 gal
0.22
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN Nitrogen
TEN
PAN PAN Nitrogen
TEN
(mg/kg) (lbs/DT) (mg/Eg)
(mg/kg) (lbs/DT) (mg/Kg)
64,900
64,900
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total
Total

, 1 -- i--1 C:::�] F-,
Page: i of 2
Report Number: 14-009-0209
Account Number: 46116
Submitted By: DARREL JOHNSON
Send To: CITY OF HENDERSON
POB 1434
HENDERSON , NC 27536
99 A&L Eastern Laboratories, Inc.
762' W t 0W'tQW R1Cft 4 VW1ftnW (ti ITOOM FtxPM 2rt-M
Project: SHT FIRST QTR AEROBIC DIG 2014
NC CERT#257
REPORT OF ANALYSIS Date Sampled: 1181201410'-05:00
Lab Number: 97402 Date Received: 01/09/2014 00:00
Samplea Idd :SHT Date Reported: 01/14/2n14
O"MUv
1UU.0
JM
01IM01414:30
SM-254OG
Moisture "
96.64
100.0
JM
01/09201414:30
SM-254OG
Total Kjeldahl Nitrogen
6.49
649M
10.0
JM
01/1012014 08:15
SM-4500-NH3C-TKN
Total Phosphorus
2.83
28300
100
KM
0111OM1414:19
SW 6010C
Total Potassium
0.37
3670
100
KM
01110201414:19
SW 6010C
Total Calcium
Z76
27600
100
KM
01/10201414:19
SW 6010C
Total Magnesium
0.30
3030
100
KM
01/10201414.19
SW 6010C
Total Sodium
0.22
2210
100
KM
01/10201414:19
SW 6010C
Total Aluminum
16100
100
KM
01110201414.19
SW 6010C
Total Copper
359
5
KM
01/10201414:19
SW 6010C
Total Zinc
786
5
KM
01110201414:19
SW 6010C
Total Cadmium
2.0
2.0
KM
01110201414:19
SW 6010C
Total Chromium
61
5
KM
01110201414.19
SW 6010C
Total Nickel
29
5
KM
0111=1414:19
SW 6010C
Total Lead
43
5
KM
011109201414.19
SW 6010C
Total Arsenic
4.0
3.0
KIWI
0111020141*19
SW 6010C
Total Mercury
<0.4
0.4
KU
01/102014 09.00
SW 74718
Total Selenium
<5.0
5.0
ICI
01110201414.19
SW 6016C
AN values are on a dry weight basis except as noted by asterisk Detection limit on all N series
is on a wet basis.
Offrepads aMfiMmambr*9ex
aW me drew
&&
tbL
Lb Me
a9d8WynWfr9AWRXftWd1fi¢aP
°sarmrtwr yaag/
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wak U're a wft CM9 o in any , no= Grm PV&ft
o �
Debbie
Hoe

Page: 2 of 2
Report Number: 14-009-0209
Account Number: 46116
Submitted By: DARREL JOHNSON
Send To: CITY OF HENDERSON
POB 1434
HENDERSON . NC 27536
Lab Number: 97402
Sample Id: SHT
A&L Eastern► Laborato►ies, Inc.
M21 a Rood ftim" Vftft =7 (804) 74SMI Fax (80Q 2J-m
wwr MA0m
Project: SHT FIRST QTR AEROBIC DIG 2014
NC CERT#257
REPORT OF ANALYSIS
pH (Standard Units)8.36
2.00
Total Volatile Solids 56.24 562400 100.0
Total Molybdenum 11 5
Chloride 3820 200
,omments:
SULFUR AND CHLORIDE NOT FOR COMPLIANCE PURPOSES.
FULL TCLP, ICR AND AG TO FOLLOW
QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR 'Ni . ALL OTHER QC DATA IS ACCEPTABLE.
Date Sampled: 1181201410:05:00
Date Received: 01/09/2014 00:00
Date Reported: 01/14/2014
JM 01/10/2014 08:15 SW 9045D
JM 01/09/201414-30 SM-254OG
KM 01/10)201414:19 SW 6010C
JM 01/1012014 0925 SM-4500C1-D
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N serves is an a met basis.
3acvr Putt and IBM= am forMeembsiveaWconraftIM use a®aff effelft enm aWbe legmmdua+IDtie whale � rnacro[a�/aeaP/aefe�otxe �m�
to MOO fOteeesatlrs ertleeoartpanya+arq .Remm mrofleesF 2nwU0=zenfteotiYnauB mQgm6orm w auMaj&uffam
Debbie Holt

FIELD LOADING ESTIMATES
Facility Henderson WRIT
Sampling Date 4/9/2014
% Solids 2.42
Mineralization Rate 0.30
Gallons per DT 9,909.43
pH 8.36
Sodium Absorpotion 0.51 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 90,100 lbs./1,000 gal 18.18
Ammonia Nitrogen (mg/Kg) 47,500.00 lbs./1,000 gal 9.59
Nitrate -Nitrite (mg/Kg) 70.20 lbs./1,000 gal 0.01
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 36,600 lbs./1,000 gal 7.39
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 60,350 lbs./1,000 gal 12.18
Volatization Rate= 0.5 Surface Application
1.0 Injection /Incorporation
EPA METAL LIMITS
Potassium lbs./1,000 gal
0.75
Phosphorus lbs./1,000 gal
5.43
Calcium lbs./1,000 gal
5.63
Magnesium lbs./1,000 gal
0.57
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal
0.00
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
HEAVY METAL CONCENTRATION
HEAVY METAL LOADING
41
75
Arsenic (mg/Kg)
5.00
Arsenic lbs./1,000 gal
0.00
39
85
Cadmium (mg/Kg)
2.00
Cadmium lbs./1,000 gal
0.00
1,500
4,300
Copper (mg/Kg)
352.00
Copper lbs./1,000 gal
0.07
300
840
Lead (mg/Kg)
44.00
Lead lbs./1,000 gal
0.01
17
57
Mercury (mg/Kg)
0.60
Mercury lbs./1,000 gal
0.00
420
420
Nickel (mg/Kg)
28.00
Nickel lbs./1,000 gal
0.01
100
100
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
2,800
7,500
Zinc (mg/Kg)
748.00
Zinc lbs./1,000 gal
0.15
RESIDUAL NITROGEN CALCULATION .
1 st Yeas
2nd Year
3rd Yeas
4th Year
5th Year
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
TEN
PAN PAN
Nitrogen
TEN
PAN PAN
Nitrogen
(mg/kg) (lbs/DT)
(mg/Kg)
(mg/kg) (lbs/DT)
(mg/Eg)
90,100
36,600 73.20
53,500
90,100
60,350 120.70
29,750
53,500
8,025 16.05
45,475
29,750
4,462 8.92
25,287
45,475
3,411 6.82
42,064
25,287
1,897 3.79
23,391
42,064
1,577 3.15
40,487
23,391
877 1.75
22,514
40,487
759 1.52
39,728
22,514
422 0.84
22,091
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-- 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 50,372 100.74
Total 68,009 136.02

Page: 1 of 2
Report Number: 14-100-0202
Account Number: 46116
Submitted By: DARREL JOHNSON
Send To: CITY OF HENDERSON
POB 1434
HENDERSON , NC 27536
A&L Eastem Laboratories, Inc.
7W Wbft a Road RMmottd, VttgM 2MI (M) 74"M Fax IBM 2 14M
wwxcalastetecom
Project: 2ND QTR 2014 AEROBIC DIGESTER
NC CERT#257
Lab Number: 98908
REPORT OF ANALYSIS Date Sampled: 4191201411:45:00
Sample Id: SHT
Date Received: 04/102014 00:00
Date Renarlad- M11512Md
-ruu.0
JM
041101201415:00
Moisture •
97.58
100.0
JM
04110/201415.00
Total Kjeldahl Nitrogen
9.01
90100
10.0
JM
04/112014 08:44
Total Phosphorus
2.69
26900
100
KM
04/11201415:19
Total Potassium
0.37
3700
100
KM
04111201415:19
Total Calcium
2.79
27900
100
KM
04/111201415:19
Total Magnesium
0.28
2830
100
KM
041111201415:19
Total Sodium
0.22
2170
100
KM
04111/201415:19
Total Aluminum
15100
100
KM
041111201415:19
Total Copper
352
5
KM
041111201415:19
Total Zinc
748
5
KM
04111201415:19
Ammonia Nitrogen
4.75
47500
10.0
JM
04/112014 08:44
Organic N
4.26
42600
10.0
04/112014 08:44
Nitrate+Nihite-N
702
2.00
.ERA
04/112014 08:55
Total Cadmium
2.0
2.0
KM
0411120141&19
Total Chromium
56
5
KM
04111201415:19
Total Nickel
28
5
KM
04111201415:19
Total Lead
44
5
KM
04111201415:19
All values are on a dry weight
basis except as noted by asterisk. Detection limit on a!I N series
is on a wet bas-
SM-254OG
SM-254OG
SM-4500-NH3G-TKN
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SM-4500-NH3C
CALCULATION
SM-450ONO3F
SW 6010C
SW 6010C
SW 6010C
SW 6010C
aegzm¢saW re6tevs are for Me exdu&W aid caaffifei-A6kt
thae ease G1Wr amdMY1Wte IePudred in wimb orpot awmWaWrefewaaw be as
a:b ALL
tm UP-' ccnA Me fimft, Or00 cWWWyin aW . nexus jefeaW. Cr affw pffhL-annaIMMM&WWWd oftmu &wpnw mean
auummam
Debbie Halt

Page: 2 Of 2
Report Number: 14-100-0202
Account Number: 46116
Submitted By: DARREL JOHNSON
Send To: CITY OF HENDERSON
POB 1434
HENDERSON . NC 27536
A&L Eastem Laboratories, Inc.
RZ Whi0 kw Road 1 t1"1A %%8hde nW (0743-MM FaW4I2714W
rawwdeutemaarn
Project: 2ND QTR-2014 AEROBIC DIGESTER
NC CERT#257
Lab Number: 98908
REPORT OF ANALYSIS Date Sampled: V91201411.45:00
Sample Id: SHT Date Received: OM1012014 00.00
Date Rennrted- nd11FP9n1d
U.0
d.0
Total Mercury
0.6
0.4
Total Selenium
<5.0
5.0
pH (Standard Units) ¢ 8.36
2.00
Total Volaatile Solids 56.39
563900
100.0
Total Molybdenum
12
5
Chloride
3690
200
Total Barium
298
5
Comments:
CHLORIDE AND SULFUR NOT FOR COMPLIANCE PURPOSES.
AG TO FOLLOW
QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR'P'.
ALL OTHER QC DATA IS ACCEPTABLE.
KM
041111201415:19
SW 6010C
KM
04/112014 09:00
SW-7471 B
KM
04111201415:19
SW 6010C
JM
04/112014 08:55
SW-9045D
JM
04/10201415:00
SAIL-254OG
KM
04/11201415:19
SW 6010C
JM
04/112014 09-30
SM-4500CI-D
KM
041111201415:19
SW 6010C
All values are on a dry weight basis except as noted by asterisL Detection limit on aU N series is on a wet basis.
OcraePcrra and Ctrs are krMe exc&mw dc=ffdwjdaw cicffcffenft aard mWaad b_- mo =v Mb c Pwt nw=YaVn&rerwe he made
b eye ww, We rescue erffie murcWer y o mWadmiWn awws aebase, ct a �
Debbie Hsit

^ wo
a
14
Facility Henderson WRF
Sampling Date 7/9/2014
Solids 3.72
FIELD LOADING ESTIMATES
Mineralization Rate 0.30
Gallons per DT 6,446.46
pH 8.15
Sodium Absorpotion 0.49 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 65,900 lbs./1,000 gal 20.45
Ammonia Nitrogen (mg/Kg) 29,300.00 lbs./1,000 gal 9.09
Nitrate -Nitrite (mg/Kg) 554.00 lbs./1,000 gal 0.17
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 26,184 lbs./1,000 gal 8.12
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 40,834 lbs./1,000 gal 12.67
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
Potassium lbs./1,000 gal 0.81
Phosphorus lbs./1,000 gal 8.04
Calcium lbs./1,000 gal 9.12
Magnesium lbs./1,000 gal 0.86
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
5.00
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
2.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
400.00
Copper lbs./1,000 gal
0.12
Lead (mg/Kg)
52.00
Lead lbs./1,000 gal
0.02
Mercury (mg/Kg)
0.80
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
29.00
Nickel lbs./1,000 gal
0.01
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
799.00
Zinc lbs./1,000 gal
0.25
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN
PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
65,900
26,184
52.37
39,716
65,900
40,834
81.67
25,066
39,716
5,957
11.91
33,759
25,066
3,760
7.52
21,306
33,759
2,532
5.06
31,227
21,306
1,598
3.20
19,708
31,227
1,171
2.34
30,056
19,708
739
1.48
18,969
30,056
564
1.13
29,492
18,969
356
0.71
18,613
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN.x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 36,408 72.82
Total 47,287 94.57

— --- �—; F_7 7-1)
Page: 1 of 2
Report Number: 14-191-0205 A&L Eastem Laboratories Inc.
Account Number. 46116
@90
782tW1�rP►rtoRwd Ri�ar4Yi�iaT�dr �7�-etm Fmc�a7t�t4e
Submitted By: DARREL JOHNSON
anvtrabntrrecaor
Send To: CITY OF HENDERSON Project: 3RD QUARTER AEROBIC DIGESTER
POB 1434 NC CERT # 257
HENDERSON , NC 27536
REPORT OF ANALYSIS Date Sampled: 7/9/2014 08:30:00
Lab Number: 56415 Date Received: 07/10/2014 00:00
Sample Id: SHT Date Reported: 07/17/2014
• ��-•--�••��
on vret
o.rz
aizuu
1uu.0
JM
07/10/201415:40
Moisture •
96.28
100.0
JM
07110/201415.40
Total Kjeldahl Nitrogen
6.59
659W
10.0
JM
07/11/2014 09:15
Total Phosphorus
2.59
25900
100
KM
07/11/201413.35
Total Potassium
0.26
2600
100
KM
07111120141325
Total Calcium
2.94
29400
100
KM
07111/201413:35
Total Magnesium
028
2780
100
KM
07/11/201413:35
Total Sodium
0.17
1700
100
KM
07/11/201413:35
Total Aluminum
14400
100
KM
07/111201413:35
Total Copper
400
5
KM
071111201413:35
Total Zinc
799
5
KM
07111/201413:35
Ammonia Nitrogen
2.93
29300
10.0
JM
07/11/2014 09:15
Organic N
3.66
36600
10.0
07/11/2014 09.15
Wdrate+Nitd"
554
2-00
JM
07/11/2014 09:15
Total Cadmium
2.0
2.0
KM
07/11/201413:35
Total Chromium
52
5
KM
071111201413-35
Tom Nickel
29
5
KM
07/111201413:35
Total Lead
52
5
KM
071111201413:35
All values are an a dry weight basis
except as noted by asterisk Detection Wt an a®. N series is
basis
a
>��W�+rsanBA�easarat�rPogexd�ereaec� as��b�ea'i�,a�ereay.Aoate®.�p.c�narpe�r�aem�a�geaet�aeaanetemra� "
�rbsar�lheresu�,��syyv�sveeay emwvse aca �.
SM-254OG
SM-254OG
SM-4500-NH3C-TKN
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SM-4500-NH3C
CALCULATION
SM-450ONO3F
SW 6010C
SW 6010C
SW 6010C
SW 6010C

Page: 2 of 2
Report Number. 14-191-0205
Account Number: 46116
Submitted By. DARREL JOHNSON
Send To: CITY OF HENDERSON
POB 1434
HENDERSON . NC 27536
A&L Eastem Laboratories Inc.
7b21WhftapimRotN! RkhaWnd,VhpNlh�Yd7 (60�7438Q01 r2x(&04i271.8448
Project: 3RD QUARTER AEROBIC DIGESTER
NC CERT # 257
Lab Number: 56415
REPORT OF ANALYSIS Date Sampled: 7/9/2014 08:30:00
Sample Id : SHT
Date Received: 07/10/2014 00:00
-
Dafa Ran~## .A- n7/17"n1 d
.i.v
Total Mercury 0.8
3.V
0.4
Total Selenium L5.0
5.0
pH (Standard Units) * 8.15
2.00
Total Volatile Solids 57.24 572400
100.0
Total Molybdenum 9
5
Chloride 6970
200
Total Barium 334
5
Zmments:
HLORIDE AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES.
LVER TO FOLLOW
UALIFIER: THE MSD WAS OUT OF LIMITS FOR'Ar AND W. ALL OTHER QC DATA IS ACCEPTABLE.
KM
07/11/201413:35
SW 6010C
KM
07/1112014 09:00
SW 7471E
KM
071111201413:35
SW 6010C
JM
07/1112014 09:15
SW-9045D
JM
07/10/201415,40
SM-254OG
KM
07/11/201413:35
SW 6010C
JM
07/141201410:05
SM-4500CI-D
KM
07/11/201413:35
SW 6010C
All values are on a dry weight basis except as noted by asl eridL Dekaon limit on all N series is on a wet basis.
ao s aid krteasae Abclfae exsl5ueua and oordiderWal usa aiaaardA , a,doW ad he rwrm +dire wranPe arm awrmayaaeYreiaeace he erg
ftwaA6E emuft or as o�p sar e,
LJ -U

FIELD LOADING ESTIMATES
Facility Henderson WRF
Sampling Date 10/8/2014
% Solids 0.15
Mineralization Rate 0.30
Gallons per DT 159,872.10
PH 8.39
Sodium Absorpotion 0.44 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 553,000 lbs./1,000 gal 6.92
Potassium lbs./1,000 gal
0.17
Ammonia Nitrogen (mg/Kg) 527,000.00 lbs./11000 gal 6.59
Phosphorus lbs./1,000 gal
0.15
Nitrate -Nitrite (mg/Kg) 1,333.00 lbs./1,000 gal 0.02
Calcium lbs./1,000 gal
0.53
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.05
PAN (mg/Kg) 272,633 lbs./1,000 gal 3.41
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 536,133 lbs./1,000 gal 6.71
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection / Incorporation
EPA METAL LIMITS
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
4.00
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
2.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
84.00
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
11.00
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.50
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
11.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
210.00
Zinc lbs./1,000 gal
0.00
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN
PAN
Nitrogen
TffiV
(mg/kg) (lbs/DT)
(mg/Kg)
Tl�i
(mg/kg) (lbs/DT)
(mg/Kg)
553,000
272,633
545.27
280,367
553,000
536,133
1,072.27
16,867
280,367
42,055
84.11
238,312
16,867
2,530
5.06
14,337
238,312
17,873
35.75
220,439
14,337
1,075
2.15
13,262
220,439
8,266
16.53
212,172
13,262
497
0.99
12,764
212,172
3,978
7.96
208,194
12,764
239
0.48
12,525
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 344,806 689.61
Total '540,475 1,080.95

r Page: 1 of 2
Report Number: 14-283-0201
Account Number: 46116
Submitted By: DARREL JOHNSON
Send To: CITY OF HENDERSON
POB 1434 '
HENDERSON , NC 27536
A&L Eastern Laboratories, Inc.
7621 Whitepine Road Richmond, Virginia 2323T [phone] Fax [phone]
Project: 4TH QTR AEROBIC DIGESTER
NC CERT#257
PORT OF ANALYSIS Date Sampled: 10/8/2014 17:10:00
Lab Number: 58045 Date Received: 10/10/2014 00:00
Sample Id: SHT/4TH QTR AERO DIG Date Reported: 10/23/2014
Arai vuuua
u.15
15uu
100.0
JM
10/22/201414:30
Moisture''
99.85
100.0
JM
10/22/201414:30
Total Kjeldahl Nitrogen
55.30
553000
10.0
JM
10113/2014 07:54
Total Phosphorus
1.21
12100
100
KM
10/17/2014 11:35
Total Potassium
1.32
13200
100
KM
10/17/2014 11:35
Total Calcium
4.24
42400
100
KM
10/17/201411:35
Total Magnesium
0.43
4300
100
KM
10M 7/2014 11:35
Total Sodium
0.91
9110
100
KM
10117/201411:35
Total Aluminum
3700
100
KM
101171201411:35
Total Copper
84
5
KM
10117/201411:35
Total Zinc
210
5
KM
10117/201411:35
Ammonia Nitrogen
52.70
527000
10.0
JM
10/13/2014 07:54
Organic N
2.60
26000
10.0
10/13/2014 07:54
Nitrate+Nitrite-N
<2.00
2.00
JM
10/13/2014 07:55
Total Cadmium
<2.0
2.0
KM
10117/201411:35
Total Chromium
8
5
[W
10117/201411:35
Total Nickel
11
5
KM
10117/2G1411:35,
Total Lead
11
5
KM
10/17/201411:35
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Qurmperft and lefters are forthe excfusive and conMenfiaf use of awcGeafs and may not be repmduced in whole or part normay anyreremace be made
to the work the resuffs orfhe company in any adverflsing; crews release or ofber public anamincements wifheut obtaining our priorwaffen aufhal&WOn.
Debbie Hoff
SM-254OG
SM-2540G
SM-4500-NH3C TKN
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SM-4500-NH3C
CALCULATION
SM-4500NO3F
SW 6010C
SW 6010C
SW 6010C
SW 6010C

h --D . 17-
- 1 - - --, ql (-- -1 l f—f --1
Page: 2 of 2
Report Number: 14-283-0201
Account Number: 46116
Submitted By: DARREL JOHNSON
Send To: CITY OF HENDERSON
POB 1434
HENDERSON , NC 27536
A&L Eastern Laboratories, Inc.
7621 Whftepine Road Richmond, Virginia 23237 (804) 74W01 Fax [phone]M
wlui#►akastem.eom:
Project: 4TH QTR AEROBIC DIGESTER
NG CERT#257
REPORT OF ANALYSIS Date Sampled: 1018/201417:10:00
Lab Number: 58045 Date Received: 10/10/2014 00:00
Sample Id : SHT/4TH QTR AERO DIG Date Reported: 10/23/2014 ,
4•u
3.0
KM
10/171201411:35
SW 6010C
Total Mercury
0.5
0.4
KM
10/13/2014 09:00
SW-7471 B
Total Selenium
<5.0
5.0
KM
10/171201411:35
SW 6010C
pH (Standard Units) * 8.39
2-00
.IM
10113/2014 07:54
SW 9045D
Total Volatile Solids 65.26
652600
100.0
JM
101101201414.35
SM-254OG
Total Molybdenum
<5
5
KM
10117/201411:35
SW 6010C
Chloride
67600
200
JM
1011312014 09:00
SM-4500CI-D
Total Barium
74
5
KM
10/171201411:35
SW 6010C
Comments:
CHLORIDE AND.ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES.
AG TO FOLLOW
QUALIFIER: THE LRB WAS OUT OF LIMITS FOR "Mn". THE MATRIX SPIKE WAS OUT OF LIMITS FOR "AI", "Ba", "Ce%
AND "P". ALL OTHER QG DATA IS
ACCEPTABLE.
All values are an a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Ourrepods and rett m ate rorthe exetusve andconWentiatuse cfamcffentr, andmayaot be reprodkmedua whole orpeft norm ay any reference be made
to the work the aesrdts, orthe eoantranyua anyadverftbg, amsrnlease, oroffwpubGc annouarc&nerzft vafflmutabtakariag oarptfdrwfiWw auth0r&3g0a_
Debbie Holt

aceAr�alytical
- wvw.pQepl9tu.aom
January 24, 2014
Pace Analytical Services, Inc.
205 East Meadow Road - Sub A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr,
Asheville, NO 28804
[phone]
Pace Analytical Services, Inc,
8800 KlncoyAva. Sub 1o0
Hunteravllle, NO 28078
[phone]
11111111lN�tlptlYOW�NkIls� ;CITY OF HENDERSON %e,:
Ms. Trisha Stoss CITY OF HENDERSON 4611e
A&L Eastern Laboratories POB 1434
7621 Whitepine Rd HENDERSON NC 27536
D
Richmond, VA 23237
RE: Project: 14-009-0201 St QUar{,e4-
Pace Project No.: 92185947 UZ76 , C 5LS CC'.0
Dear Ms. Stoss:
Enclosed are the analytical results for sample(s) received by the laboratory on January 10, 2014.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where appiloable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location Indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely, '
qz�nywaA�
Erin Waters
[e-mail]
Project Manager
Enclosures
cc: Ms. Jerri Dawson, A&L Eastem Laboratories
Ms. Kathy Scott, A&L Eastern Laboratories
REPORT OF LABORATORY ANALYSIS
This report shall not bo roproducad, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 22

Paco Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Dervices, Inc,
aceAIalytic81
0 205 East Meadow Road - Suite A 2226 Rivorsido Dr. 0800 IGneay Ave. Suits 100
Eden, NO 27288 Asheville, NO 28804 Wuntersvllle, NO 28078
r vµecalaba•com [phone] [phone] [phone]
f
CERTiFICATIONS
Project: 14-009-0201
Pace Project No.: 92185947
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Arizona Certification M AZ0735
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification M E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification M 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification M 90050
Louisiana Certification M FL NELAC Reciprocity
Louisiana Environmental Cerdficate #: 05007
Maine Certification #: FLO1264
Maryland Certification: 0346
Massachusetts Certification* M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Montano Certification #: Cart 0074
Nebraska Certification: NE-OS-28-14
Nevada Cortification: FL NELAC Reciprocity
New Hampshire Certification #: 2968
New Jersey Certification #: FL766
New York Certification #: 11608
North Carolina Environmental Certificate M 667
North Carolina Certification M 12710
Pennsylvania Cortifioatlon M 68.00647
Puerto Rico Certification #: FLO1264
South Carolina Certifleation: 096042001
Tennessee Certification* TN02074
Texas Certification: FL NELAC Reciproci US Virgin Islands Certification: FL NELA Reciprocity
Virginia Environmental Certification #: 480166
Washington Certification #: C956
West Virginia Certfication * 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Kansas Certification IDs
9608 Loiret Boulevard, Lenexa, KS 66219
Louisiana Certification #: 03066
WY STIR Certification #: 2466.01
Nevado Cerlificetion #: KS000212008A
Arkansas Certification M 13-012-0
Oklahoma Cortiflcation A 0206/0936
Illinois Certification M 003097
Texas Certification 0: T104704407.13.4
Iowa Certification * 118
Utah Certification M K8000212013-3
Kansas/NELAP Certification #: E-10116
Illinois Certification #: 003097
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Flodda/NELAP Certification #: E87627
j North Carolina Drinking Water Certification M 37706
Kentucky UST Cartifleation P. 84
North Carolina Field Services Certification M 5342
West Virginia Certification P 357
-_' North Carolina Wastewater Certification #: 12
VlrginieiVELAP Certificatlen #: 400221
South Carolina Certification #: 99006001
Asheville Certification We
2226 Riverside Dr., Asheville, NC 28804 North Carolina Wastewater Certification #: 40
Florida/NELAP Certification #: E87648 South Carolina Certification #: 90030001
Massachusetts Certification #: M-NC030 West Virginia Certification #: 356
North Carolina Drinking Water Certification M 37712 Virginle/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be roproduced, except In full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 22

i
aceAnalytical
7 wnvpmxteba.ewn
Pace Analytical Service$, Inc.
206 East Meadow Read - Suite A
Eden, NO 27288
[phone]
Pace Ana"cai Services, Inc.
2226 Riverside Dr.
Asheville, NO 28604
[phone]
SAMPLE ANALYTE COUNT
Pace Analytical Services, Inc,
6800 i9ne sy Ave. Suite 100
Hunteraville, NO 28078
[phone]
Project:
Pace Project No.:
14-009-0201
92185947
D
Analyfast
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
4
92186947001
97392
EPA 8081
RES
8
PASI-C
EPAS151
LJM
3
PASI-0
EPA0010
JMW
1
PASI-A
EPA 6010
JMW
7
PASI-A
EPA 7470
MTS
1
PASI-A
EPA 8270
Bpi
18
PASI-C
EPA 8260
CAM
14
PASI-C
EPA 1010
DAB
1
PASI-A
SW-846 7.3.4.2
AJM
1
PASI-K
(
EPA 9046
AES2
1
PASI-A
SV%L846 7.3.3.2
AJM
1
PASI-K
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 22

Pace Analytical Services, Inc.
Pace Analytical &ervicos, Inc.
Pace Analytical Services, Ina,
OW ,_' Q6✓ir A �_r �^,�®
1✓iGf' r 6iGt
206 East Meadow Road - SuiteA
Eden, NO 27288
2226 Rivor®Ide Dr.
Asheville, NO 28804
g900 WnceyAve, 3ulte 100
Hunteravilla, NO 20078
' WW'pe=§bs.c0m
I
[phone]
[phone]
[phone]
ANALYTICAL RESULTS
Project: 14-009-0201
Pace Project No.: 92185947
Sample: 97392 Lab ID: 92185947001 Collected: 01/08/14 10:05 Received: 01/10/1410:00 Matrix: Solid
Results reported on a "wet weigh!"basis
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
8081 GCS Pesticides, TCLP Analytical Method: EPA 8081 Preparation Method: EPA 3510
gamma-BHC (Lindane)
Chlordane (Technical)
Endrin
Heptachlor epoxide
Methoxychlor
Toxaphene
sun-ogates
Decachlorobiphenyi (S)
Tetrachloro-m-xylene IS)
8151 Chlorinate Herbicide TCLP
2,4-D
2,4,5-TP (Siivex)
Surrogates
2,4-DCAA IS)
6010 MET ICP
Silver
Leachate Method/Date: EPA 1311; 01/18/14 14:00
NO ug/L
0.60
1
01/21/1410:40 01/2311413:28
68-69.0
NO ug/L
3.0
1
01/21/1410:40 01/23/1413:20
57.74.9
NO ug/L
0.60
1
01/21/14 10:40 01/23/14 13:26
72.20.8
ND ug/L
0.60
1
01/21/1410:40 01/23/1413:28
1024.57.3
NO ug/L
1000
1
01/21/1410:40 01/2311413:28
72-43-5
NO ug/L
3.0
1
01/21/1410:40 01/2311413:28
8001-36-2
43 %
10.138
1
01/21/1410:40 0112311413:28
2051-24.3
49 %
10-110
1
01/21/1410:40 01/23/1413:28
877-00-8
Analytical Method: EPA 8151
Preparation Method: EPA 3010
NO mg/L
0.010
1
01/16/14 08:00 01/18114 22:31
04.76-7
ND mg/L
0.010
1
01/16/14 08:00 01/18/14 22:31
93-72-1
88 %
70-130
1
01116/14 08:00 01/1 all 22:31
19719.28.9
Analytical Method: EPA 6010 Preparation Method: EPA 3050
NO mg/kg 0,37 1 01/11/141DA6 01/13/1416.42 7440.22.4
6010 MET ICP, TCLP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Leachate Method/Date: EPA 1311; 01/13/14 10:49
Arsenic
NO mg/L 0,060 1 01/14/14 11:10
01/14/14 23:00 7440.38.2
Barium
0.26 mg/L 0.26 1 01114/1411:10
01/14/14 23:00 7440-311.3
Cadmium
NO mg/L 0.0060 1 01/14/14 11:10
01/14/14 23:09 7440-43-9
Chromium
NO mg/L 0.026 1 01/1411411:10
01/14/14 23:09 7440.47-3
Lead
NO mg/L 0,026 1 01/14/14 11:10
01/14/14 23:09 743942-1
Selenium
NO mg/L 0.10 1 01/14/14 11:10
01/14/14 23:09 7782-49-2
Sliver
NO mg/L 0.025 1 01/14/14 11:10
01/14/14 23:09 7440.22-4
7470 Mercury, TCLP
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Leachate Method/Date: EPA 1311; 01/13/1410:40
Mercury
NO ug/L 0.20 1 01/14/1411:46
01/16/1415:60 7430.97-6
8270 MSSV TCLP Sep Funnel
Analytical Method: EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date: EPA 131l; 01/16/14 14:00
1,4-Dichlorobenzene
ND ug/L 60.0 1 01/21/14 09:40
01/22/1415:08 106-46.7
2,4-Dinitrotoluene
ND ug/L 50.0 1 01/21/14 09:40
01/22/1416:09 121.14-2
Hexachloro-1,3-butadiene
ND ug/L 60.0 1 01/21/14 00:40
01/22/1416:08 87.68-3
Hexachlorobenzene
ND ug/L 50.0 1 01/21/14 09:40
01122/1416:09 118.14-1
Hexachloroethane
NO ug/L 60.0 1 01/21/14 09:40
01/22/1416:09 67.72-1
2-Methyiphenol(o-Cresol)
75.7 ug/L 60.0 1 01/21/14 00:40
01/22/1416:00 9648-7
3&4-Methylphenol(m&p Cresol)
ND ug/L 60.0 1 01/21/14 09:40
01/22/1415:09
Nitrobenzene
ND ug/L 50.0 1 01/21/14 09:40
01/22/1416:09 98.9&3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
Date: 01/24/2014 03:21 PM
without the written consent of Pace Analytical Services, Inc,.
Page 4 of 22

aceAnalytb?l
nww.pecelabs.com
Project: 14-009-0201
Pace Project No.: 92185947
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Paco Analytical Services, Inc.
0800 KlncoyAve. Suite 100
Hunteravlllo, NC 28078
[phone]
Sample: 97392 Lab ID: 92186947001
Results reported on a "wet -weight" basis
Parameters Results Units
Collected: 01/08/14 10:05
Report Limit OF
Received: 01/10/1410:00 Matrix: Solid
Prepared Analyzed CAS No. Qual
8270 MSSV TCLP Sep Funnel
Analytical Method: EPA $270 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 01/16/14 14:00
Pentachlorophenol
NO ug/L
100 1
01/21114 09:40
01/22/14 15:09
87-86.5
Pyridine
ND ug/L
50.0 1
01/21/14 09:40
01/22114 16:09
110-88-1
2,4,5-Tdchlorophenol
NO ug/L
50.0 1
01/21/14 09:40
01/22114 16:09
95.95-4
2,4,6-Trichlorophenol
NO ug/L
60.0 1
01/21/14 09:40
01122/14 16:09
88-06-2
Surrogates
Nitrobenzene-d5 (S)
51 %
12-102
1
01/21/14 09:40 01/22/14 16:09 4166-60.0
2-Fluorobiphenyl (8)
53 %
13.107
1
01/21/14 09:40 01/2211416:09
321.80.8
Terphenyl-d14 (8)
52 %
21-132
1
01/21/14 09:40 01/22/14 16:09
1718.31-0
Phenol-d6 (S)
30 %
10-110
1
01/21/14 09:40 0112211416:09
13127.88-3
2-Fluorophenol (S)
34 %
10-110
1
01/21/14 09:40 01/2211416:09
367.12-4
2,4,6-Tribromophenol (S)
75 %
27-108
1
01/21/14 09:40 01/22/14 16:09
118-79.8
8260 MSV TCLP
Analytical Method: EPA 8260
Benzene
NO ug/l.
5.0
1
01/16/1412:63
71.43-2
2-Butanone (MEK)
NO ug/L
10.0
1
01/16/1412:63
78-93.3
Carbon tetrachloride
NO ug/L
6.0
1
01/16/1412:63
66.23-6
Chlorobenzene
NO ug/L
6.0
1
0111611412:63
108-90-7
Chloroform
NO ug/L
6.0
1
01116/1412:63
07.66.3
1,4-Dichlorobenzene
ND ug/L
6.0
1
01/1611412:63
106-48.7
1,2-Dichloroethane
NO ug/L
5.0
1
01/18/1412:63
107.06.2
1,1-Dichloroethene
NO ug/L
5.0
1
01/16/1412:53
76.364
Tetrachloroethene
NO ug/L
6.0
1
01/16/1412:63
127-18-4
Trichlorcethene
NO ug/L
5.0
1
01/15/14 12:63
7941.6
Vinyl chloride
ND ug/L
6.0
1
01/16/1412:63
76-01-4
Surrogates
1,2-Dichloroethane-d4 (S)
110 %
70-130
1
01/16/1412:63
17060-07-0
Toluene-d8 (S)
98 %
67-135
1
01/15/1412:63
2037.2"
4-Bromofluorobenzene (S)
98 %
70-130
1
01/16/14 12:83
480.00-4
1010 Flashpoint,Closed Cup
Analytical Method: EPA 1010
Flashpoint
>200 deg F
70.0
1
01/13/14 00:00
Reactive Sulfide
Analytical Method: SW-846 7.3.4.2
Sulfide, Reactive
ND mg/kg
100
1
0111511414:00
9046 pH Soli
Analytical Method: EPA 9046
pH at 25 Degrees C
7.8 Std. Units
0.10
1
01/21/14 16:46
733C S Reactive Cyanide
Analytical Method: SW-B46 7.3.3.2
Cyanide, Reactive
NO mg/kg
0.060
1
01/15/14 12:38
Date: 01/24/2014 03:21 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Paco Analytical Services, Inc..
Page 6 of 22

i
Pace Analytical Services, Inc, Pace Analytical Services, Inc. Pace Analytieai Services, ine,
{ 5-alcewwwpmehbszw 205 East MeadoEden, NC 27288 Asheville,NC 28804 g80Aunoravlla, NC 28078 3
(.36)623-8921 [phone] (704)87&0082
QUALITY CONTROL DATA
Project: 14-009-0201
Pace Project No.: 92185947
QC Batch: MERP/6045
Analysis Method:
EPA 7470
QC Batch Method: EPA 7470
Analysis Description:
7470 Mercury TCLP
Associated Lab Samples: 92185947001
METHOD BLANK: 1120477
Matrix: Water
Associated Lab Samples: 92185947001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ug/L
ND 0.20 01115/1416:49
LABORATORY CONTROL SAMPLE: 1120478
Spike LCS
LCS % Roe
Parameter Units
Conc. Result
% Roe Limits Quallflor9
Mercury ug/L
2.5 2.4
95 80-120
i MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1120479 1120480
MS MSD
92186027001 Spike Spike MS MSD MS MSD % Roe
Parameter Units Result Conc. Conc. Result Result % Roe % Rec Limits RPD Qual
Mercury ug/L ND 2.6 2.5 2.2 2.0 86 80 76-125 7
i
Date: 01/24/2014 03:21 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc..
Page 0 of 22

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Pace Analytical Servieoa, Inc.
r � +® 205 East Meadow Road - Suite A 2226 Riverside Dr.
54aceJ d
9800 Kincey Ave, Suite 100
Eden, NO 27288 Asheville, NO 28804
Huntorsville, NO 28078
wvw.pacefabs.com
[phone] [phone]
[phone]
QUALITY CONTROL DATA
Project: 14-009-0201
Pace Project No.: 92185947
QC Batch: MPRP/15030
Analysis Method: EPA 6010
QC Batch Method: EPA 3050
Analysis Descriptlon: 6010 MET
Associated Lab Samples: 92186847001
I_
METHOD BLANK: 1119778
Matrix: Solid
Associated Lab Samples: 92185947001
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Silver mg/kg
ND 0.50 01/13/14 16:18
I,-
l_ LABORATORY CONTROL SAMPLE: 1119779
Spike LCS LCS % Ree
Parameter Units
Cone. Result % Roe Limits Qualifiers
Silver mg/kg
25 26.5 106 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1119780 1119781
MS MSD
92186874003
Spike Spike MS MSD MS MSD
% Roo
Parameter Units Result
Cone. Cone. Result Result % Rec % Roc
Limita RPD Qual
j Silver mg/kg ND
I
it
i
27.9 26.8 27.9 26.0 100 101
76�126 7
REPORT OF LABORATORY ANALYSIS
This report shall not bo reproduced, except In full,
Date: 01/24/2014 03:21 PM without the written consent of Paco Analytical Services, Inc.,
Page 7 of 22

aceAnaljdcal
WMPar labs.com
Project: 14-009-0201
Pace Project No.: 92185947
Pace Analytical Services, Inc.
206 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2226 Riverside Dr.
Asheville, NO 28804
[phone]
QUALITY CONTROL DATA
QC Batch: MPRP/15040 Analysis Method: EPA6010
QC Batch Method: EPA 3010 Analysis Description: 8010 MET TCLP
Associated Lab Samples: 92185947001
METHOD BLANK: 1120484 Matrix: Water
Associated Lab Samples: 92185947001
Parameter
Units
Blank
Result
Arsenic
mg/L
NO
Barium
mg/L
NO
Cadmium
mg/L
NO
Chromium
mg/L
ND
Lead
mg/L
NO
Selenium
mg/L
NO
Silver
mg/L
NO
LABORATORY CONTROL SAMPLE: 1120485
Parameter
Units
Arsenic
mg/L
Barium
mg/L
Cadmium
mg/L
Chromium
mg/L
Lead
mg/L
Selenium
mg/L
Silver
mg/L
Reporting
Limit Analyzed Quallfiers
0.050
01/14/14 22:64
0.26
01/14/14 22:64
0,0060
01/14/14 22:64
0.026
01/14/14 22:64
0,026
01/14/14 22:64
0.10
01/14/14 22:64
0,026
01/14/14 22:64
Spike
LCS
LOS
Cone,
Result
% Roe
2.5
2.5
100
2.5
2.2
87
2.5
2.3
91
2.5
2.3
90
2.5
2.1
85
2.5
2.6
100
1.2
1.2
94
Paco Analytical Services, Inc,
9800 KlnoeyAve. Suite 100
Huntersville, NO 28078
[phone]
% Rec
Umlta Qualifiers
80-120
80-120
80-120
80-120
M120
80-120
SD-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1120486
1120487
MS
MSD
92188027001
Spike
Spike
MS.
MSD
MS
MSD
% Roe
Parameter
Units
Result
Cone,
Cone.
Result
Result
% Roo
% Rec
Limits
RPD Qual
Arsenic
mg/L
NO
2.6
2.6
2.4
! 2.5
95
98
76-926
3
Barium
mg/L
0.74
2.5
2.6
2.7
2.8
78
84
76-125
6
Cadmium
mg/L
NO
2.6
2.5
2.2
2.3
87
92
76-126
6
Chromium
mg/L
NO
2.5
2.6
2.2
2.3
Be
91
78-126
6
Lead
mg/L
NO
2.6
2.6
2.1
2.2
82
88
7V26
6
Selenium
mg/L
NO
2.5
2.6
2.3
2.4
91
98
75-126
7
Silver
mg/L
NO
1.2
1.2
1.1
1.2
89
93
76-125
4
Date: 01/24/2014 03:21 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written conaont of Pace Analytical SarAcoa, Inc„
Page 8 of 22

Pace Analytical Services, Inc, Pace Analytical Services, Inc.
ac�Analytical ® 206 East Meadow Road - Suite A 2226 Riverside OF.
Eden, NC 27288 Ashevlllo, NC 28804
wtvwpaCgbba.com [phone] [phone]
r
I
QUALM CONTROL DATA
Project: 14-009-0201
Pace Project No.: 92185947
QC Batch: MSV/25505 Analysis Method: EPA 8260
QC Batch Method: EPA 8260 Analysis Description: 8260 MSV TCLP
Associated Lab Samples: 92185947001
METHOD BLANK: 1121399 Matrix: Water
Associated Lab Samples: 92185947001
Parameter
Units
Blank
Result
Reporting
Limit
Analyzed Quallflere
1,1-Dichloroethene
ug/L
NO
6.0
01/16/1412:22
1,2-Dichloroethene
ug/L
NO
5.0
01/16/1412:22
1,4-Dichlorobenzene
ug/L
NO
5.0
01/16/1412:22
2-Butanone (MEK)
ug/L
NO
10.0
01/15/14 12:22
Benzene
ug/L
NO
6.0
0111611412:22
Carbon tetrachloride
ug/L
ND
6.0
01/16/14 12:22
Chlorobenzene
ug/L
NO
6.0
01115/1412:22
Chloroform
ug/L
NO
5.0
01/15/1412:22
Tetrachloroethene
ug/L
NO
6.0
01116/1412:22
Trichloroethene
ug/L
ND
6.0
01/16/1412:22
Vinyl chloride
ug/L
NO
5.0
01116/1412:22
1,2-Dichloroethene-d4 (S)
%
111
70-130
01/1611412:22
4-Bromofluorobenzene (S)
%
99
70-130
01/16/14 12:22
Toluene-d8 (S)
%
98
67-135
01/16/1412:22
LABORATORY CONTROL SAMPLE: 1121400
Paco Analytical Services, Inc,
0000 KlnceyAve. suite 100
Wuntorsvlllo, NC 20070
[phone]
Parameter
Units
Spike
Cone.
LCS
Result
LCS
% Rae
% Rae
Limits QuaOflera
1,1-Dichloroethene
ug/L
60
47.4
95
70-141
1,2-Dichloroethene
ug/L
60
60,7
101
70-130
1,4-Dichlorobenzene
ug/L
60
45.9
92
70-141
2-Butanone (MEK)
ug/L
100
90.4
90
63-160
Benzene
ug/L
60
46.2
92
70.132
Carbon tetrachloride
ug/L
60
46,2
92
70-160
Chlorobenzene
ug/L
60
45.6
91
70-134
Chloroform
ug/L
60
47.0
94
70-130
Tetrachloroethene
ug/L
50
42.6
86
70-137
Trichloroethene
ug/L
50
42.9
86
70.131
Vinyl chloride
ug/L
50
44.0
90
66-144
1,2-Dichloroethane-d4 (S)
%
100
70-130
4-Bromofluorobenzene (S)
%
97
70-130
Toluene-d8 (S)
%
99
67-136
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1121401
1121402
MS
MSD
92186089001 Spike
Spike
MS
MSD
MS
MSD
% Roo
Parameter Units
Result Cone.
Cone.
Result
Result
% Roo
% Roo
Llmite
RPD Qual
1,1-Dichloroethene ug/L
NO 50
60
67.1
56.1
114
112
70.160
2
Benzene ug/L
NO 50
60
66.4
63.9
111
108
70-160
3
Chlorobenzene ug/L
NO 60
50
64.8
62.9
110
100
70-160
4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproducad, except in full,
Date: 01/24/2014 03:21 PM without the written consent of Paco Analytical Services, Inc,. Page 9 of 22

,
i aceAnalgical
wvw'Mm/abs com
L
Project: 14-009-0201
f _ Pace Project No.: 92185947
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NO 27288
[phone]
Pace Anslyticai Services, Inc.
2225 Riverside Dr.
Asheville, NO 28864
[phone]
QUALITY CONTROL DATA
Paco Analytical Services, Inc.
9600 Klncey Ave. Suite 100
Muntersvllle, NC28078
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1121401
1121402
MS
MSD
92186089001 Spike
Spike MS
MSD MS
MSD
% Rae
Parameter
Units Result Cone.
Cone, Result
Result % Rec
% Roc
Limits RPD Qual
Trichlorcethene
ug/L ND 50
50 64.9
54.1 110
108
70-160 2
1,2-Dichloroethane-d4 (S)
%
110
109
70-130
4-Bromofluorobenzene (S)
%
98
98
70.13D
Toluene-d8 (S)
%
99
97
97-136
I'
In
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/24/2014 03:21 PM without the written consentof PeceAnalytial Services, Inc..
r-,
Page 10 of 22

aceAnalytical
mvwpet�abs.00m
1
I
Project: 14-009.0201
Pace Project No.: 92185947
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NO 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Or,
Asheville, NO 28804
[phone]
QUALITY CONTROL DATA
QC Batch: OEXT/25609 Analysis Method: EPA 8081
QC Batch Method: EPA 3510 Analysis Description: 8081 GCS TCLP Pesticides
Associated Lab Samples: 92186947001
METHOD BLANK: 1124601 Matrix: Water
Associated Lab Samples: 92185947001
Parameter
Units
Blank
Result
Reporting
Limit
Analyzed Qualifiers
Chlordane (Technical)
ug/L
NO
3.0
01/21/14 23:53
Endrin
ug/L
NO
0.50
01/21/14 23:63
gamma-BHC (Lindane)
ug/L
NO
0.50
01/21/14 23:53
Heptachlor epoxide
ug/L
NO
0.50
01/21/14 23:53
Methoxychlor
ug/L
NO
1000
01/21/14 23:53
Toxaphene
ug/L
NO
3.0
01/21/14 23:53
Decachlorobiphenyl (S)
%
94
10-138
01/21/14 23:63
Tetrachloro-m-xylene (S)
%
63
10-110
01/21/14 23:63
LABORATORY CONTROL SAMPLE: 1124502
Paco Analytical 3ervicaa, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NO 28078
[phone]
Parameter
Units
Spike
Cone.
LCS
Result
LCS
% Roo
% Roe
Limits Qualifiers
Endrin
ug/L
1.2
1.2
94
20-134 _
gamma-BHC (Lindane)
ug/L
1.2
1.0
85
20.118
Heptachlor epoxide
ugll-
1.2
1.1
91
22-133
Methoxychlor
ug/L
3.7
NO
98
44-160
Decachlorobiphenyl (S)
%
97
10-138
Tetrachloro-m-xylene (S)
%
88
10-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1124603
1124504
MS
MSD
92186953001
Spike
Spike
MS
MSD
MS
MSD
% Roe
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Roo
% Roo
Limits
RPD Quel
Endrin
ug/L
NO
1.2
1.2
0.97
0.99
78
80
21.133
2
gamma-BHC (Lindane)
ug/L
NO
1.2
1.2
0.85
0.90
69
73
24-110
6
Heptachlor epoxide
ug/L
NO
1.2
1.2
1.0
0.97
84
78
60-180
7
Methoxychlor
ug/L
ND
3.7
3,7
NO
NO
82
80
50-160
Decachlorobiphenyt (S)
%
78
80
10-130
Tetrachloro-m-xylene (S)
%
68
88
10-110
Date: 01/24/2014 03:21 PM
REPORT OF LABORATORY ANALYSIS
This report shell not be reproduced, except In full,
without the writton consent of Pace Analytical Services, inc..
Page 11 of 22

riW/•PbS.WTn
1
I
Project: 14-009-0201
Pace Project No.: 92185947
Pace Analytical Services, Inc.
206 East Meadow Road- Suite A
Eden, NO 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NO 28804
[phone]
QUALITY CONTROL DATA
QC Batch: OEXT/15732 Analysis Method: EPA 8161
QC Batch Method: EPA 3510 Analysis Description: 8161 GCS Herbloides TCLP
Associated Lab Samples: 92185947001
METHOD BLANK: 807605 Matrix: Water
Associated Lab Samples: 92186947001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
2,4,5-TP (Slivex) mg/L ND 0.010 01/18/14 20:00
2,4-0 mg/L ND 0.010 01/18/14 20:00
2,4-DCAA (S) % 92 70-130 01/18/14 20:00
Pace Analytical Bervices, Inc.
9800 KinceyAve, Suite 100.
Huntersvlllo, NO 28078
[phone]
LABORATORY CONTROL SAMPLE:
807606
Spike
LCS LCS % Roe
Parameter
Units
Cone.
Result % Rae Limits Qualifiers
2,4,5-TP (Siivex)
mg/L
.012
0.013 106 47-146
2,4-D
mg/L
.06
0.061 101 50-130
2,4-DCAA (S)
%
89 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
808057
808068
MS
MSD
92186027001
Spike
Spike
MS
MSD
MS
MSD
% Rea
Parameter Units
Result
Cone.
Cone.
Result
Result
% Rea
% Rea
Limits RP® Qual
2,4,5-TP (Slivex) mg/L
ND
.012
.012
0.013
0.012
106
104
47.148 2
2,4-D mg/L
ND
.06
.08
0.063
0.082
106
103
60-130 2
2,4-DCAA (S) %
94
93
70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/24/2014 03:21 PM without the written consent of Pace Analytical Services, Inc,,
Page 12 of 22

aceAnaly�ical
wwwpewbbs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NO 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NO 28804
[phone]
QUALITY CONTROL DATA
Project: 14-009-0201
Pace Project No.: 92185947
QC Batch: OEXT/25604 Analysis Method: EPA 8270
QC Batch Method: EPA 3510 Analysis Description: 8270 TCLP MSSV
- Associated Lab Samples: 92185947001
I_ METHOD BLANK: 1124406
Associated Lab Samples: 92185947001
Parameter Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed Qualifiers
.1
1,4-Dichlorobenzene
ug/L
NO
60.0
01/2211414:42
2,4,6-Tdchlorophenol
ug/L
NO
60,0
01/22/1414:42
2,4,6-Tdchlorophenol
ug/L
ND
60.0
01/2211414:42
2,4-Dinitrotoluene
ug/L
NO
60.0
01/2211414:42
2-Methylphenol(o-Cresol)
ug/L
NO
60,0
01/22/1414:42
3&4-Methylphenol(m&p Cresol)
ug/L
ND
60.0
01/22/14 14:42
Hexachloro-1,3-butadiene
ug/L
NO
60,0
01/22/1414:42
Hexachlorobenzene
ug/L
NO
60.0
01/2211414:42
Hexachloroethane
ug/L
ND
60.0
01/2211414:42
- Nitrobenzene
ug/L
NO
60.0
01/22/1414:42
Pentachlorophenol
ug/L
ND
100
01/22/1414:42
Pyridine
ug/L
ND
60.0
01/22/1414:42
2,4,6-Tribromophenol (S)
%
74
27-108
01/22/1414:42
2-Fluorobiphenyl IS)
%
86
13-107
01/2211414:42
2-Fluorophenol (S)
%
44
10-110
01/22/1414:42
_ Nitrobenzene-d5 (S)
%
80
12-102
01/22/1414:42
Phenol-d6 (S)
%
30
10-110
0112211414:42
Terphenyl-d14 (S)
%
99
21-132
01122/1414:42
r
LABORATORY CONTROL SAMPLE:
Parameter
1124407
Units
Spike
Conc.
1,4-Dichlorobenzene
ug/L
600
2,4,6-Tdchlorophenol
ug/L
500
2,4,6-Tdchlorophenol
ug/L
500
24-Din1trotoluene
ug/L
600
2-Methylphenol(o-Cresol)
ug/L
600
3&4-Methylphenol(m&p Cresol)
ug/L
600
Hexachloro-1,3-butadiene
ug/L
600
Hexachlorobenzene
ug/L
600
Hexachloroethane
ug/L
500
Nitrobenzene
ug/L
600
Pentachlorophenol
ug/L
1000
Pyridine
ug/L
600
2,4,6-Tribromophenol (S)
°%
2-Fluorobiphenyl (S)
°%
2-Fluorophenol(S)
%
Nitrobenzene-d5 (S)
%
Phenof-d6 (S)
%
Terphenyl-04 (S)
°%
Date: 01/24/2014 03:21 PM
LCS
Result
LCS
% Rec
°% Reo
Limits
312
82
10-110
409
82
39.108
331
66
40-104
616
103
42-109
400
80
31-110
385
77
30.110
293
69
10-110
403
81
39-121
299
60
10-110
414
83
32-101
289
29
18-108
216
43
10-110
84
27-108
78
13-107
43
10-110
77
12.102
38
10-110
92
21-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Paco Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 KneeyAvo. Suite 100
Huntersville, NO20078
(704)876.90e2
Qualifiers
Page 13 of 22

aceAnalyt�cal�
tvwwpecslsbs.eom
Pace Analytical Services, Inc.
206 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2226 Riverside Dr.
Asheville, NO 28804
[phone]
QUALITY CONTROL DATA
Paw Analytical Services, Inc,
®®00 KlnceyAve. Suke 100
Hunterevillo, NO 28078
[phone]
Project: 14-009-0201
Pace Project No.: 92185947
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1124408
1124409
MS
MSD
92186447001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone,
Result
Result
% Rae
% Roo
Limits
RPD Qual
1,4-Dichlorobenzene
ug/L
ND
500
500
214
242
43
46
30-150
13
2,4,5-Trichlorophenol
ug/L
NO
500
500
326
358
66
72
30.150
0
2,4,6-Trichlorophenol
ug/L
NO
500
800
258
302
52
60
30-160
16
2,4-Dinitrotoluene
ug/L
NO
60D
500
445
409•
89
82
30.160
9
2-Methylphenol(o-Cresol)
ug/L
ND
Soo
Soo
242
311
48
62
30-160
26
3&4-Methylphenol(m&p
ug/L
128
500
500
322
421
39
69
30.150
27
i Cresol)
Hexachloro-1,3-butadiene
ug/L
NO
500
600
193
229
39
46
30.160
17
Hexachlorobenzene
ug/L
NO
500
600
319
308
64
62
30-160
4
Hexachloroethane
ug/L
ND
600
500
199
229
40
46
30.160
14
Nitrobenzene
ug/L
ND
Soo
600
259
307
52
61
30-160
17
Pentachlorophenol
ug/L
NO
1000
1000
621
688
62
69
30-160
6
Pyridine
ug/L
NO
600
Soo
156
167
31
33
30-160
7
2,4,6-Tribromophenol (S)
%
81
79
27-108
2-Fluorobiphenyl (S)
%
60
61
13.107
2-Fluorophenol(S)
%
34
42
10-110
Nitrobenzene-d5(S)
%
50
60
12-102
Phenol-d6 (S)
%
27
38
10-110
Terphenyl-d14 (S)
%
80
73
21-132
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
Parameter
1,4-Dichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dinitrotoluene
2-Methylphenol(o-Cresol)
3&4-Methylphenol(m&p
Cresol)
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachloroethane
Nitrobenzene
Pentachlorophenol
Pyridine
2,4,6-Tdbromophenol (S)
2-Fluorobiphenyl (S)
2-Fluorophenol(S)
Nitrobenzene45 (S)
Phenol-d6 (S)
Terphenyl-d14 (S)
Date: 01/24/2014 03:21 PM
1125390
MS
92186813001 Spike
Units Result Cone.
ug/L
NO
600
ug/L
NO
600
ug/L
NO
600
ug/L
NO
500
ug/L
ND
500
ug/L
NO
500
1126391
MSD
Spike MS
Cone. Result
600 328
600 464
6D0 400
600 . 608
600 412
600 393
MSD
MS
MSD
% Roo
Result
% Roe
% Roo
Llmfle
RRfO Qual
294
66
6®
060
—11 --
423
93
86
30.150
9
366
80
71
30-160
12
404
102
99
30-160
3
410
82
82
30-150
1
396
79
79
30-160
1
ug/L
NO
600
600
327
273
65
56
30-160
ug/L
ND
500
600
389
360
78
72
30.160
ug/L
NO
500
600
316
280
63
66
30-180
ug/L
NO
600
500
413
374
83
76
30.160
ug/L
ND
1000
1000
660
648
66
6B
30-160
ug/L
NO
600
600
199
72.3
40
14
30-160
%
92
86
27.108
%
80
73
13.107
%
65
63
10-110
%
78
71
12.102
%
52
62
10-110
%
73
72
21-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
18
8
12
10
2
94 M1
Page 14 of 22

at�eAnalylrcal
wyw.pacdeba.o�rn
J
l
Project: 14-009-0201
Pace Project No.: 92185947
Paco Analytical Services, Inc.
206 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2226 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
QC Batch: WET/29053 Analysis Method: EPA 1010
QC Batch Method: EPA 1010 Analysis Description: 1010 Flash Point, Closed Cup
Associated Lab Samples: 92186947001
SAMPLE DUPLICATE: 1120247
92186947001 Dup
Parameter Units Result Result RPD Qualltiers
Flashpoint deg F >200 >200
Date: 01/24/2014 03:21 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Paco Analytical Services, Inc,.
Paco Analytical Services, Inc.
0800 KlnceyAve, Suite 100
Nunteravillc, NC 28070
[phone]
Page 16 of 22

aceAnalytical
/ aww.Paeelebs.com
I
Project: 14-009-0201
Pace Project No.: 92185947
Pace Analytical Services, Inc,
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Paco Ana"cal Services, Ina,
2226 Riverside Dr,
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
QC Batch: WET/45615 Analysis Method: SW 846 7.3.4.2
QC Batch Method: SW 846 7.3.4.2 Analysis Description: Reactive Sulfide
Associated Lab Samples: 92185947001
METHOD BLANK: 1317348 Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide, Reactive mg/kg ND 100 01/16/1414:00
LABORATORY CONTROL SAMPLE: 1317349
Parameter Units
Sulfide, Reactive mg/kg
Paco Analytical Services, Inc,
9800 K(nceyAve. Suft© 100
Hunteraville, NC 28078
[phone]
Spike LCS LCS % Roe
Cone. Result % Roo Limits Qualifiers
200 188 94 77-110
MATRIX SPIKE SAMPLE: 1317350
10254068001 Spike MS MS % Roo
Parameter Units Result Cone. Result % Rec Limits Qualifiers
Sulfide, Reactive mg/kg ND 500 420 84 87-118
SAMPLE DUPLICATE: 1317351
10264061001 Dup
Parameter Units Result Result RPD Qualifiers
Sulfide, Reactive mg/kg ND ND
Date: 01/24/2014 03:21 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of pace Analytical Services, Inc..
Page 10 of 22

i
I
aceAnaljdcal
r� Wwwparafabs.mm
d
Project: 14-009-0201
Pace Project No.: 92185947
Pace Analyteal Services, Inc.
206 East Meadow Road - Suite A
Eden, NO 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NO 28804
[phone]
QUALITY CONTROL DATA
QC Batch: WET/29172 Analysis Method: EPA 9045
QC Batch Method: EPA 9046 Analysis Description: 9046 pH
Associated Lab Samples: 92185947001
SAMPLE DUPLICATE: 1124568
92185947001 Dup
Parameter Units Result Result RPD Qualifiers
pH at 25 Degrees C Std. Units 7.8 7.8 0
Date: 01/24/2014 03:21 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc,.
Paco Analytical Services, Inc.
0800 Kincey Ave. Suite 100
Hunteravill®, NO 28078
[phone]
Page 17 of 22

Pace Analytical Services, Inc. Pace Analytical Services, Inc. Paco Analytical Services, Inc.
�^� I ; l m
!cG
206 East Meadow Road - Suite A 2228 Riverside Dr. 9800 Kincey Ave, Suite 100
Eden, NC 27288 Asheville, NC 28804 Huntersvilla, NC 28078
tiwovpaesfaba.eom
r
[phone] [phone] [phone]
QUALITY CONTROL DATA
Project: 14-009-0201
- Pace Project No.: 92185947
QC Batch: WETA/27820
Analysis Method: SW-846 7.3.3.2
QC Batch Method: SW-846 7.3.3.2
Analysis Description: 733C Reaetive Cyanide
Associated Lab Samples: 92185947001
METHOD BLANK: 1317362
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units Result Limit Analyzed Qualifiers
Cyanide, Reactive
mg/kg ND 0.060 01/16/14 12:34
LABORATORY CONTROL SAMPLE:
1317363
Spike LCS LCS % Roe
Parameter
Units Cone. Result % Roe Limits Qualifiers
Cyanide, Reactive
mg/kg .5 0.62 103 71-123
MATRIX SPIKE SAMPLE:
1317364
10264253001
Spike MS MS % Ree
Parameter
Units
Result
Cone. Result % Rao Limits Quellflem
Cyanide, Reactive
mg/kg
0.050 U
.5 0.51 102 57.132
SAMPLE DUPLICATE: 1317365
92186947001
Dup
Parameter
Units
Result
Result RPD Qualifiers
Cyanide, Reactive
mg/kg
ND
ND
Date: 01/24/2014 03:21 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc..
Page 18 of 22

Paco Analytical Services, Inc.
Paco Analytical Services, Inc.
Pace Analytical Sorvicos, Inc.
�^a A,_�l„{�^�t®
uiGk7 j}/L 1.+i[
206 Fast Meadow Road - Suite A
Eden, NO 27288
2226 Riverside Dr,
Asheville, NO 28804
8000 KlnceyAve. Suite 100
WuntorsvIlle, NO 28078
wyrwpacelsbs,com
I
[phone]
[phone]
[phone]
j
QUALIFIERS
Project: 14-009-0201
Pace Project No.: 92185947
L_ DEFINITIONS
OF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Dlphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nhrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270, The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes,
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
f PASI-C Pace Analytical Services - Charlotte
PASI-K Paoe Analytical Services - Kansas City
PASI-0 Pace Analytical Services - Ormond Beeoh
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/24/2014 03:21 PM without the written consent of Pace Analytical Services, Inc,.
Page 19 of 22

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
` aCeAR�i�trrCai� 206 East Meadow Road - Suite A 2226 Riverside Dr,
1+G c Eden, NO 27288 Asheville, NO 28804
www.pecelsbs.swn [phone] [phone]
r
i
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: 14-009-0201
Pace Project No.: 92186947
Pace Analytical Services, Inc,
0800 KlnceyAve. Sulto 100
Huntersvllla, NO 28078
[phone]
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92185947001
97392
EPA 3510
OEXT/25609
EPA 8081
OCSV/16492
92185947001
97392
EPA 3610
OEXT/15732
EPA 8161
GCSW10404
92185947001
97392
EPA 3060
MPRP/16030
EPA 6010
ICP/13642
92186947001
97392
EPA3010
MPRP/15040
EPA6010
ICP/13666
92186947001
97392
EPA 7470
MERP/6045
EPA 7470
MERC/6839
92186947001
97392
EPA 3510
OEXT/26004
EPA 8270
MSSV/8070
92186947001
97392
EPA 8260
MSV/26606
92186947001
97392
EPA1010
VVET/29063
92186947001
97392
SW 846 7.3.4.2
WET/46615
92186947001
97392
EPA 9045
WET/29172
92185947001
97392
SW 846 7.3.3.2
WETA/27620
Date: 01/24/2014 03:21 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc..
Page 20 of 22

s I aceAnal;�irnl
LJUW111611L IV01110. LJVV4111V11L 1 -V o-w—, r.. s.-., ... v. ..I ­ ..
Condition Upon Receipt SCUR Page 1 of 2
Document Number: Issuing Authority:
F-CHR-CS-03-rev.13 Pace Huntersville Quality Office
Client Name:__ f L-
'ourier: ❑ Fed Ex0UPS❑ USPS❑ Client❑ Commercial® Pace Other
optional
Custody Seat on Cooler/Box Present: ❑ yes �] no Seals Intact: ❑ yes
I
❑
no
Proj. Due Date:
Prof; Name:
Packing Material: ❑ Bubble Wrap Bubble Bags ❑ NonjLfl Other
Thermometer Used: IR Gun T1102 T1301 Type of Ice: Wet Blue Non®
Samples on Ica, cooling process has bosun
Temp Correction Factor T1102: o Correction T1301: No Correction
Corrected Cooler Temp.: •C Biological Tissue is Frozen: Yee N/A
Date contents iUel p r/t a �%/ Ininp
in
Temp should be above freezing to 610 Comments:
Chain of Custody Present: Yes ❑No ON/All.
Chain of Custodv Filled Out: Qlyes ❑No ❑NIA
2.
Sampler Name & Signature on COC:
Yes ❑No
❑NIA
4.
Samples Arrived within Hold Time:
Yes ❑No
❑NIA
5.
Short Hold Time Analysis <72h :
❑Yes 4N6
❑N/A
6.
Rush Turn Around Time Requested:
Oyes No
❑NIA
7,
Sufficient Volume:
Yea ONo
❑N/A
$,
Correct Containers Used:
l Yes ❑No
❑NIA
9.
-Pace Containers Used:
❑Yes JbNo
❑wA
Containers Intact
YlYes ❑No
OWA
10.
=lftered volume received for Dissolved tests
❑Yes ❑No
76A
11.
Sample Labels match COC:
Kyles ❑No
❑N►A
12.
-Includes date/time/ID/Mal sis Matrix:
a<
All containers needing preservation have been checked.
Oyes ❑No
NIA
13.
All containers needing preservation are found to be in
❑Yes ❑No
N/A
compliance with EPA recommendation.
exceptions: VOA, od(form, TOO, O&G, WI-DRO (avatar
❑Yes qNo
Sam lea checked for dechlorination:
❑yes 8NO
jbNZA
14.
Heads ace in VOA Vials >Gmm :
OYes ONo
OEA
15.
Trip Blank Present:
Dyes ❑No
WA.
16,
Trip Blank Custody Seals Present
❑Yes ❑No
Client Notification/ Resolution: Field Date Required? Y I N
Person Contacted: Date/rime:
Comments/ Resolution:
SCURF Review: Date: full*
SRF Review: Data: D I
Note: Whenever there is a discrepancy affecting North Carolina compliance
samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office ( Le out of hold, Incorrect preservative, out of temp,
incorrect containers)
Place label here _
8�ti -
Page 21 of 22

cc
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A & L Eastern Laboratories , Inc.
1621 WgitepineRoad, Richmond, VA=37-Td: N4-743.9401-ftm BW271-641*Zmefl: ofltce®id-labs-wa era.eom
�'1►=' �' t•1�:
Cwtract Lab:
Address:•
P.bpae:
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F
_iicrtPiiiQn
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Fax:
Kathy soon
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ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. XVQ0000838 Facility Name Granville Farms, Inc Class B Source Permit No. NCO025576
Labottory 1 A&I.Esacm
Labs, lne.
Laboratory 2
Sample or CompositeDate 5/27/2014
Parameter (mg/7g) Class A Clas B
Aluminum
N/A
N/A
24,000
`3,820
Ammonia Nitrogen
N/A I
N/A
Arsenic
41
75
5
Cadmium
39
65
2
C.I.W.
N/A
N/A
20,400
---- - — Copper
1,500
i
4,3W
337
Lead
390
840
19
Magnesium
N/A
N/A
�.
i
Rletcuty
17
i
04
Mo1y
N/A
75
9
NIc,3
420
420
26
Natrace-NledusNiacugem
N/A
N/A
9,%o
Percent SoUd�
ce
N/A
N/A
3.40
pH(no -d-)
N/A
N/A
4.65
Phosphorus
N/A
N/A
36.700
Potassium
N/A
N/A
17,2W
PAN (Its)./Inc-)
N/A
N/A,
24,w4
PAN (Sutffucc)
N/A
N/A
22 294
sclenivaa
10d1
too
S
sesditttn
N/A
W/A
49.6m
SARI N/A
N/A
14.22.
—:iQ100
TEN: N/A
N/A
—
zinc 2,800
972
Source Nance Johnston County WWII'
"1 certify, ander penalty off law, that this d a onatient was pmqmmd wad'ee my d'tecdota cc supervidan in accordance with a system d-igned ran
assure that qu:tllicd pasacmd prepetiy gwb=M sacra evahzzted t&e mf mmatden scha duel. I area =waze that them: ate s i�t Ew
sutsmittfesg tiorna Wadies the poasTmsPity ruff i s erred hoptilsommeast fear lmawicb vsolad a= '
si, taaco txf L➢t zwr a >lgle
sFa:pua:a't®dcihced Ira 40 CItEC ['act 5033'(t) artd H$AdL'CAC 2'iC .flL02 QB n�

s� AGN UN
Facility Johnston County WWTP
Sampling Date 5/27/2014
%Solids 3.4
Mineralization Rate 0.30
Gallons per DT 7,053.18
pH 4.65
FIELD LOADING ESTIMATES
Sodium Absorpotion 14.22 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land ripply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 40,900 lbs./1,000 gal 11.60
Ammonia Nitrogen (mg/Kg) 3,820.00 lbs./1,000 gal 1.08
Nitrate -Nitrite (mg/Kg) 9,260.00 lbs./1,000 gal 2.63
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 22,294 lbs./1,000 gal 6.32
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 24,204 lbs./1,000 gal 6.86
Volatization Rate= 0.5 Surface Application
1.0 Inj ection /Incorporation
EPA METAL LIMITS
1stYear
2nd Year
3rd Year
i
4th Year
l
5th Year
Potassium lbs./1,000 gal
4.88
Phosphorus lbs./1,000 gal
10.41
Calcium lbs./1,000 gal
5.78
Magnesium lbs./1,000 gal
1.85
Manganese lbs./1,000 gal
0.48
Sulfur lbs./1,000 gal
4.05
Molybdenum lbs./1,000 gal
0.00
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
5.00
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
2.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
337.00
Copper lbs./1,000 gal
0.10
Lead (mg/Kg)
19.00
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.40
Mercury lbs./1,000 gal
0.00 -
Nickel (mg/Kg)
26.00
Nickel lbs./1,000 gal
0.01
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
972.00
Zinc lbs./1,000 gal
0.28
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TEN
(mg/kg) (lbs/DT)
(mg/y-g)
TKN
(mg/kg) (lbs/DT)
(mg/Yg)
40,900
22,294
44.59
18,606
40,900
24,204 48.41
16,696
18,606
2,791
5.58
15,815
16,696
2,504 5.01
14,192
15,815
1,186
2.37
14,629
14,192
1,064 2.13
13,127
14,629
549
1.10
14,080
13,127
492 0.98
12,635
14,080
264
0.53
13,816
12,635
237 0.47
12,398
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NI3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yt PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 27,084 54.17
1'otat 28,502 57.00

Page: i of 2
Report Number: 14-148-0205
Account Number: 04596
Submitted By: SCOTT CARPENTER
Send To: SOIL PLUS, LLC
SCOTT CARPENTER
P.O. BOX 1396
OXFORD, NC 27565
Lab Number: 55598
Sample Id : JC052714
A&L Eastern Laboratories, Inc.
7621 Whitepine Road Richmond, Virginia 23237 (B04) 743-9401 Fax [phone]
wwwaleastem.com
Project: 201404.A10-JOHNSTON COUNTY WWTP
NC CERT#257
REPORT OF ANALYSIS Date Sampled: 5/27/2014 13:30:00
Date Received: 05/28/2014 00:00
Date Reported: 06/04/2014
Total Solids *
3.40
34000
100.0
JM
05/28/2014 13:34
SM-2540G
Moisture *
96.60
100.0
JM
05/28/2014 13:34
SM-2540G
Total Kjeldahl Nitrogen
4.09
40900
10.0
JM
05/29/2014 08:30
SM-4500-NH3C-TKN
Total Phosphorus
3.67
36700
100
KM
06/03/2014 13:46
SW 6010C
Total Potassium
1.72
17200
100
KM
06/03/2014 13:46
SW 6010C
Total Sulfur
1.43
14300
100
KM
06/03/2014 13:46
SW 6010C
Total Calcium
2.04
20400
100
KM
06/03/2014 13:46
SW 6010C
Total Magnesium
0.65
6540
100
KM
06/03/2014 13:46
SW 6010C
Total Sodium
4.96
49600
100
KM
06/03/2014 13:46,
SW 6010C
Total Iron
25300
100
KM
06/03/2014 13:46
SW 6010C
Total Aluminum
24000
100
KM
06/03/2014 13:46
SW 6010C
Total Manganese
1680
5
KM
06/03/2014 13:46
SW 6010C
Total Copper
337
5
KM
06/03/2014 13:46
SW 6010C
Total Zinc
972
5
KM
06/03/2014 13:46
SW 6010C
Ammonia Nitrogen
0.38
3820
10.0
JM
05/29/2014 08:30
SM-4500-NH3C
Organic N
3.71
37080
10.0
05/29/2014 08:30
CALCULATION
Nitrate+Nitrite-N
9260
2.00
JM
05/29/2014 08:30
SM-450ONO3F
Total Cadmium
<2.0
2.0
KM
06/03/2014 13:46
SW 6010C
All values are on a dry weight
basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced
in whole or part, nor may
any reference be made
to the work, the results, or the company in any advertising, news release, or other
public announcements without obtaining our prior written authorization.
Debbie Holt

Page: 2 of 2
Report Number: 14-148-0205
Account Number: 04596
Submitted By: SCOTT CARPENTER
Send To: SOIL PLUS, LLC
SCOTT CARPENTER
P.O. BOX 1396
OXFORD, NC 27565
Lab Number: 55598
Sample Id : JC052714
�L A&L Eastern Laboratories, Inc.
7621 Whitepine Road Richmond, Virginia 23237 [phone] Fax [phone]
w wwaleastenwom
Project : 201404.A10-JOHNSTON COUNTY WWTP
NC CERT#257
REPORT OF ANALYSIS Date Sampled: 5/27/2014 13:30:00
Date Received: 05/28/2014 00:00
Date Reported: 06/04/2014
Total Chromium
41
5
KM
06/03/2014 13:46
SW 6010C
Total Nickel
26
5
KM
06/03/2014 13:46
SW 6010C
Total Lead
19
5
KM
06/03/2014 13:46
SW 6010C
Total Arsenic
5.0
3.0
KM
06/03/2014 13:46
SW 6010C
Total Mercury
<0.4
0.4
KM
05/29/2014 09:00
SW-7471 B
Total Selenium
<5.0
5.0
KM
06/03/2014 13:46
SW 6010C
pH (Standard Units) * 4.65
2.00
JM
05/29/2014 08:30
SW-9045D
Total Molybdenum
9
5
KM
06/03/2014 13:46
SW 6010C
Soluble Phosphorus 0.63
6300
100
JM
05/29/2014 11:10
SOLUBLE PIN MANURE
Comments:
WATER SOLUBLE P, SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES,
QUALIFIER: THE LRB WAS OUT OF LIMITS FOR "Mo". THE MATRIX SPIKE WAS OUT OF LIMITS FOR "AL" AND
"As". ALL OTHER QC DATA IS
ACCEPTABLE.
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
Debbie Holt

tad ' ��= •.
Analytical Results Date: Tuesday, June 24, 2014
Client: Microbac Southern Testing Division
Client Project: AA50017 & AA50018
Client Sample ID: AA50018 Johnston Co WWTP Work Order/ID: 14E1534-02
Sample Description: Sampled: 05/27/2014 10:00
Matrix: Aqueous Received: 05/30/2014 9:15
Analyses Certs AT Result RL Qual Units DF Analyzed
Method:131118081A Analyst:als
TCLP Pesticides Prep Method: SW-846 1311/SW846 351.0 Prep Date/Time:06/12/2014 07:22
Method: 131118270C Analyst: BRR
CLP Semivolatile Organic Compounds
1,4-Dichlorobenzene
2,4,5-Trichloro henol
2,4,6-Trichloro henol
2,4-Dinitrotoluene
cgk
cgk
cgk
cgk
A
A
A
A
Prep Method:SW-846 1311/SW846 3510
ND 0.050
ND 0.050
ND 0.050
ND 0.050
mg/L
mg/L
mg/L
mg/L
Prep Date/Time:06/11/2014 14:14
1 06/13/2014 15:03
1 06/13/2014 15:03
1 06/13/20 44 15:03
1 06/13/2014 15:03
2-Methylphenol
cgk
A
ND
0.050
mg/L
1
06/13/2014 15:03
3/4-Meth I henol
cgk
A
NDl
0.050
mg/L
1
06/13/2014 15:03
Hexachlorobenzene
cgk
A
ND
0.050
mg/L
1
06/13/2014 15:03
Hexachlorobutadiene
cgk
ND
0.050
mg/L
1
06/13/2014 15:03
Hexachloroethane
cgk
_A
A
ND
0.0501
mg/L
1
06/13/2014 15:03
Nitrobenzene
cgk
A
ND
0.050
mg/L
1
06/13/2014 15:03
Pentachlorophenol
cgk
A
ND
0.25
mg/L
1
06/13/2014 15:03
Pyridine
cgk
A
ND
0.050
mg/L
1
06/13/2014 15:03
Total Cresol
cgk
M
ND
0.050
mg/L
1
06/13/2014 15:03
Surr:2,4,6-Tribromophenol
S
88.3
47.8-138
%REC
1
06/13/2014 15:03
Surr.2-F/uorobi hen l
S
57.5
10-110
%REC
1
06/13/2014 15:03
Sum 2 F/uorophenol
S
67.1
10-110
%REC
1
06/13/2014 15:03
Surr. Nitrobenzene-d5
S
63.4
10-110
%REC
1
06/13/2014 15:03
Surr. Phenol-d5
S
61.7
43.7-126
%REC
1
06/13/2014 15:03
Surr.Teruel-04
P S
R 97.1
1
33.7-136
%REC
1
06/13/2014 15:03
Method: 131118260B Analyst: jln
TCLP VOA Zero Head Extraction Prep Method: SW-846 1311/8260_TCLP_PREP Prep Date/Tme:06/08/201417:09
Microbac Laboratories, Inc.
250 West 841h Drive I Merrillville, IN 46410 1800.536.8379 p 1219.769.8378 p 1219.769.1664 f I www.microbac.com
Page 5 of 10

Analytical Results Date: Tuesday, June 24, 2014
Client: Microbac Southern Testing Division
1 Client Project: AA50017 & AA50018
Client Sample ID: AA50018 Johnston Co WWTP Work Order/ID: 14E1534-02
I- Sample Description: Sampled: 05/27/2014 10:00
Matrix: Aqueous Received: 05/30/2014 9:15
Analyses Certs AT Result RL Qual Units DF Analyzed
j Method: 131118260B Analyst: jln
TCLP VOA Zero Head Extraction Prep Method: SW-846 1311/8260_TCLP _PREP Prep Date/Time:06108/2014 17:09
Method: 131117470A Analyst:AG
TCLP Mercury by CVAA Prep Method: SW-846 1311/SW-846 7470 Prep Date/Time:06/09/2014 08:42
Mercury � cgk A ND 0.0010 mg/L 1 06/09/2014 13:02
Method: SW8151A Analyst:ECL
Herbicides - TCLP Prep Date/Time:06/11/2014 15:30
Method:1311/6010B
Analyst:AG
TCLP Metals by ICP _
Prep Method: SW-846 131VSW846 3005A
_
Prep Date/Time:06/06/2014 09:25
Arsenic
cgkn
A ND
0.EF�'
g/L
1 06/06/2014 16:02
Barium _
cgk
A ND
g/L
1 06/06/2014 16:02
Cadmium~
cgkn
A ND
0.00200
mg/L
1 06/06/2014 16:02
Chromium
cgkn
A n 0.00380
0.00300
mg/L
1 06/06/2014 16:02
Lead
cgkn
A 0.0120
0.00750
mg/L
1 06/06/2014 16:02
Selenium
cgkn
A ` ND1
0.0300
mg/L
C 1 06/06/2011 16:02
Silver
cgkn
A s ND I
0.0100
mg/L
1 06/06/2014 16:02
Method: SW-846 1010
Analyst:EB
Ignitability (Closed Cup)
Prep Date/Time:06/05/201413:12
I nitabilit
cgk
A > 170
30
°F
1 06/05/2014 13:12
Method: SW-846 9045C
Analyst:EB
pH
Prep Date/Time:06/03/2014 14:45
H
cgk
A 4.23
2.00
pH Units
1 O6/03/2014 14:45
Method: Chapter 7/9014
Analyst:AGRIE
Reactive Cyanide
Prep Method:Aqueous Reactive CN Distillation
Prep Date/Time:06/03/2014 08:30
Reactive C snide
cg
A ND
2.0
mg/L
1 06/04/2014 11:51
Method: Chapter 719034
Analyst:EB
Reactive Sulfide
Prep Method:Aqueous Reactive
Sulfide Distillation
Prep Date/Time:06/03/2014 08:30
Reactive Sulfide
cg
A ND
2.0
mg/L
1 06/03/2014 8:30
Microbac Laboratories, Inc.
250 West 84th Drive I Merrillville, IN 46410 1 800.536.8379 p 1219.769.8378 p 1219.769.1664 f I www.microbac.com
Page 6 of 10

FLAGS. FOOTNOTES AND ABBREVIATIONS (as needed)
B = Detected in the associated method Blank at a concentration above the routine RL
b- = Detected in the associated method Blank at a concentration greater than 2.2 times the MDL
b' = Detected in the associated method Blank at a concentration greater than half the RL
CFU = Colony forming units
D = Dilution performed on sample
DF = Dilution Factor
g = Gram
E = Value above quantitation range
H = Analyte was prepared and/or analyzed outside of the analytical method holding time
I = Matrix Interference
J = Analyte concentration detected between RL and MDL (Metals / Organics)
LOD = Limit of Detection
m3 = Meters cubed
MDL = Method Detection Limit
mg/Kg = Milligrams per Kilogram (ppm)
mg/L = Milligrams per Liter (ppm)
NA = Not Analyzed
ND = Not Detected at the Reporting Limit (or the Method Detection Limit, if used)
NR = Not Recovered
R = RPD outside accepted recovery limits
RL = Reporting Limit
S = Spike recovery outside recovery limits
Surr = Surrogate
U = Undetected
> = Greater than
<= Less than
= Percent
ANALYTE TYPES: (AT)
A,B = Target Analyte
I = Internal Standard
M = Summation Analyte
S = Surrogate
T = Tentatively Identified Compound (TIC, concentration estimated)
QC SAMPLE IDENTIFICATIONS
BLK = Method Blank ICSA= Interference Check Standard "A"
DUP = Method Duplicate ICSAB = Interference Check Standard "AB"
BS = Method Blank Spike BSD = Method Blank Spike Duplicate
MS = Matrix Spike MSD = Matrix Spike Duplicate
ICB = Initial Calibration Blank ICV = Initial Calibration Verification
CCB = Continuing Calibration Blank CCV = Continuing Calibration Verification
CRL = Client Required Reporting Limit OPR = Ongoing Precision and Recovery Standard
PDS = Post Digestion Spike SD = Serial Dilution
QCS = Quality Control Standard
CERTIFICATIONS (Certs)
Below is a list of certifications maintained by the Microbac Merrillville Laboratory. All data included in this report has been reviewed for and
meets all project specific and quality control requirements of the applicable accreditation, unless otherwise noted. Complete lists of individual
analytes pursuant to each certification below are available upon request.
a The American Association for Laboratory Accreditation [A2LA] for Biological Testing, ISO/IEC 17025 (Certificate# 3045.01)
b The American Association for Laboratory Accreditation [A2LA] for Environmental Department of Defense Testing, ISO/IEC 17025
(Certificate# 3045.02)
c Illinois EPA for the analysis wastewater and solid waste in accordance with the requirements of the National Environmental Laboratory
Accreditation Program [NELAP] (accreditation #200064)
d Illinois Department of Public Health for the microbiological analysis of drinking water (registry #1755266)
- Indiana DEM approved support laboratory for solid waste and wastewater analyses
e Indiana SDH for the chemical analysis of drinking water (lab #C45-03)
f Indiana SDH for the microbiological analysis of drinking water (lab #M-45-8)
g Kansas Department of Health and Environment for the analysis of drinking water, wastewater, and solid hazardous waste in accordance
with the requirements of the National Environmental Laboratory Accreditation Program [NELAP] (Certificate No. E-10397)
h Kentucky EPPC for the analysis of samples applicable to the Underground Storage Tank program (lab #75)
r New York SDOH in accordance with the requirements of the National Environmental Laboratory Accreditation Program [NELAP]
(Lab#12006;accreditation #49179)
i i New York SDOH in accordance with the requirements of the National Environmental Laboratory Accreditation Program [NELAP]
(Lab# 12006; accreditation #49386)
k North Carolina DENR for the environmental analysis for NPDES effluent, surface water, groundwater, and pretreatment
regulations(certificate #597)
Pennsylvania Department of Environmental Protection [NELAP] (Lab# 68-04863)
m Washington State Department of Ecology in accordance to Ch. 173-50 WAC (lab #C992)
n Wisconsin DNR for the chemical analysis of wastewater and solid waste (lab #998036710)
Microbac Laboratories, Inc.
250 West 84th Drive I Merrillville, IN 46410 1 800.536.8379 p 1219.769.8378 p 1219.769.1664 f www.microbac.com
Page 7 of 10

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
XVQ Permit No. WQ0000838 Facility Name Granville harms, Inc. Class B Source Permit No. NCO064891
Laboratory 11 A&L Eastern
Labs, Inc
Laboratory 21
Sample or CompositeDate 7/2/2014
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
17,800
Ammonia Nitrogen
N/A
N/A
19,100
Arsenic
41
75
7
Cadmium
39
85
16
Calcium
N/A
N/A
' 14.4o0
Copped
1,500
4,300
585
Lead
360
940
55
Magnesium
N/A
N/A
i
6,170
Mercury1
17
57
0.8
Molybdenum'
N/A
75
to
Nickel
420
420
34
Nitrate-Nitdte Nhwgen
N/A
N/A
57
Percent Solids
N/A
N/A
t.41
PH (no units)
N/A
NIA
7.75
Phosphomsi
N/A
N/A
` 29.100
Potassiumi
N/A
N/A
6,690
PAN &J./IInai4
N/A
N/A
31,097
PAN (Surface)
N/A
N/A
21,547
Selenium
100
160
5
Sodium
N/A
N/A
6,080
SAR
N/A
N/A
1 J
THN
N/A
N/A
58,900
Zinc
2,800
7,500
21m0
Source Name Kenly Regional %"VI"P
"II certify, under pena9ey of law, that alms document was prepared under my direction or sup=vkion in accomdamce with a system designed to
assure that qualified personnel properly i adwced and cvadmeed the information submitted. I am aware &hat there are sign ,=nt penalties for
submitting Edw information, inclmding the possibility oF Times and imprisonment for lm ing violateons f°
J)a� a, —/ t-
Signature ofprepater * Date
' Prepa= is defined in 40 CFR Pare 503.9(r) and M NCAC 2T .110:: 0

AGMAN
-
FIELD LOADING ESTIMATES
Facility Kenly Regional WWI?
Sampling Date 7/2/2014
Solids 1.41
i
Mineralization Rate 0.30
Gallons per DT 17,007.67
pH 7.75
Sodium Absorpotion 1.26 <5.0 Safe 5.0
-10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
- TKN (mg/Kg) 58,900
lbs./1,000 gal 6.93
Potassium lbs./1,000 gal
0.79
Ammonia Nitrogen (mg/Kg) 19,100.00
lbs./1,000 gal 2.25
Phosphorus lbs./1,000 gal
3.42
Nitrate -Nitrite (mg/Kg) 56.70
lbs./1,000 gal 0.01
Calcium lbs./1,000 gal
1.69
PLANT AVAILABLE NITROGEN
SURFACE APPLIED
Magnesium lbs./1,000 gal
0.73
PAN (mg/Kg) 21,547
lbs./1,000 gal 2.53
Manganese lbs./1,000 gal
0.05
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
0.98
PAN (mg/Kg) 31,097
lbs./1,000 gal 3.66
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Inj ection / Incorporatio n
EPA METAL LIMITS
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
7.00
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
16.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
585.00
Copper lbs./1,000 gal
0.07
Lead (mg/Kg)
55.00
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.80
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
34.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
2100.00
Zinc lbs./1,000 gal
0.25
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TEN
(mg/kg) (lbs/DT)
(mg/Kg)
58,900
21,547 43.09
37,353
58,900
31,097 62.19
27,803
37,353
5,603 11.21
31,750
27,803
4,170 8.34
23,633
31,750
2,381 4.76
29,369
23,633
1,772 3.54
21,860
29,369
1,101 2.20
28,268
21,860
820 1.64
21,041
28,268
530 1.06
27,738
21,041
395 0.79
20,646
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 31,162 62.32
Total 38,254 76.51

Page: 1 of 2
Report Number: 14-184-0204
Account Number: 04596
Submitted By: SCOTT CARPENTER
Send To: SOIL PLUS, LLC
SCOTT CARPENTER
P.O. BOX 1396
OXFORD, NC 27565
Lab Number: 56285
Sample Id : TK 072014
�L A&L Eastern Laboratories, Inc.
7621 Whitepine Road Richmond, Virginia 23237 [phone] Fax (804)27i-6446
Www.aleastem.com
Project: TOWN OF KENLY
NC CERT#257
REPORT OF ANALYSIS Date Sampled: 7/2/2014 15:00:00
Date Received: 07/03/2014 00:00
Date Reported: 07/10/2014
Total Solids "
1.41
14100
100.0
JM
07/03/2014 12:35
SM-2540G
Moisture *
98.59
100.0
JM
07/03/2014 12:35
SM-2540G
Total Kjeldahl Nitrogen
5.89
58900
10.0
JM
07/07/2014 08:19
SM-4500-NH3C-TKN
Total Phosphorus
2.91
29100
100
KM
07/08/2014 10:35
SW 6010C
Total Potassium
0.67
6690
100
KM
07/08/2014 10:35
SW 6010C
Total Sulfur
0.84
8360
100
KM
07/08/2014 10:35
SW 6010C
Total Calcium
1.44
14400
100
KM
07/08/2014 10:35
SW 6010C
Total Magnesium
0.62
6170
100
KM
07/08/2014 10:35
SW 6010C
Total Sodium
0.61
6080
100
KM
07/08/2014 10:35
SW 6010C
Total Iron
45900
100
KM
07/08/2014 10:35
SW 6010C
Total Aluminum
17800
100
KM
07/08/2014 10:35
SW 6010C
Total Manganese
412
5
KM
07/08/2014 10:35
SW 6010C
Total Copper
585
5
KM
07/08/2014 10:35
SW 6010C
Total Zinc
2100
5
KM
07/08/2014 10:35
SW 6010C
Ammonia Nitrogen
1.91
19100
10.0
JM
07/07/2014 08:19
SM-4500-NH3C
Organic N
3.98
39800
10.0
07/07/2014 08:19
CALCULATION
Nitrate+Nitrite-N
56.7
2.00
JM
07/07/2014 08:20
SM-450ONO3F
Total Cadmium
16.0
2.0
KM
07/08/2014 10:35
SW 6010C
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made A&U-(�YA
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
Debbie Holt

Page: 2 of 2
Report Number: 14-184-0204
Account Number: 04596
Submitted By: SCOTT CARPENTER
Send To: SOIL PLUS, LLC
SCOTT CARPENTER
P.O. BOX 1396
OXFORD, NC 27565
Lab Number: 56285
Sample Id : TK 072014
�L A&L Eastern Laboratories, Inc.
7621 Whitepine Road Richmond, Virginia 23237 [phone] Fax [phone]
www.aleastern.com
Project: TOWN OF KENLY
NC CERT#257
REPORT OF ANALYSIS
Total Chromium
77
5
KM
Total Nickel
34
5
KM
Total Lead
55
5
KM
Total Arsenic
7.0
3.0
KM
Total Mercury
0.8
0.4
KM
Total Selenium
<5.0
5.0
KM
pH (Standard Units) *
7.75
2.00
JM
Total Molybdenum
10
5
KM
Soluble Phosphorus
<0.01 <100
100
MW
Comments:
WATER SOLUBLE P, SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE
PURPOSES.
QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Al" AND "S".
ALL OTHER QC DATA IS
ACCEPTABLE.
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis
Date Sampled: 7/2/2014 15:00:00
Date Received: 07/03/2014 00:00
Date Reported: 07/10/2014
07/08/2014
10:35
SW 6010C
07/08/2014
10:35
SW 6010C
07/08/2014
10:35
SW 6010C
07/08/2014
10:35
SW 6010C
07/08/2014
09:00
SW-7471 B
07/08/2014
10:35
SW 6010C
07/07/2014
08:44
SW-9045D
07/08/2014
10:35
SW 6010C
07/07/2014
09:04
SOLUBLE P IN MANURE
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
Debbie Holt

CERTIFICATE OF ANALYSIS
Report To
SCOTT CARPENTER
SOIL PLUS
208 WILLIAMS ST
GREENVILLE NC 27858
USA
Microbac Laboratories, Inc. - Wilson Division
3809 Airport Drive NW
Wilson, NC 27896
Tel: [phone]
Report Date: 2014/07/17
Quote: 23-20140328-14
Work Order: 2014-07-02-018
Matrix: WW
Collection Date: 2014/07/02
Sample Submission Date: 2014/07/02
SIDN Client Marks Analvsis Name Method
AA52816
Town of Kenly TK070214
Flash Point - LiquidsSubcontracted
AA52816
Town of Kenly TK070214
pH (Corrosivity) Subcontracted
AA52816
Town of Kenly TK070214
Reactive Cyanide Subcontracted
AA52816
Town of Kenly TK070214
Reactive Sulfide Subcontracted
AA52816
Town of Kenly TK070214
TCLP Full Metals V(Subcontracted
Comments:
Approved by:
Kim Hesse
Result Unit
*See Attached
*See Attached
*See Attached
*See Attached
*See Attached
For any feedback concerning our services, please contact James Nokes, Senior Vice President, at [e-mail]
or Trevor Boyce at [e-mail]
Environmental • Agrochemical • Food • Pharmaceuticals Page 1 of 1

Lab Report #: L14070270
Lab Project#: 2941.016
Project Name: Wilson NC
Lab Contact: Emily Yoak
certlticate otAnai sls
Sample #
L14070270-01
t PrePrep Method: "N/A `
Instrument F_. BURET.. ,.
Chent ID:
AA52816
Prep Method: SW7.34
Prep Date N/A
- Matrix
LigWaste _
Analytical Method: SW7:34
CaGDate
1Norkgroup�#
WG48$350 , ';
=-Analyst¢ EFT
Run Date 07/09/201410 00
Collect,Dat6:
07102/2014-15:00
Dilution:-1
-File ID ET1407091000 08E xi
Sample Tag
Urnts mglkg. µ
Analyte
CAS #
Result
Qua[
RL
MDL
Reactivity, Sulfide
18496-25-8
U
100
100
U Not detected at or above adjusted sample detection limit
Analyte
CAS #
Result
Qua[
RL
MDL
Corrosivity pH
10-29-7
7.39
0.000
0.000
Temperature At Determination (C)
17.4
0.000
0.000
Sample:#: L14070270-b1`.PrePrep
Method: N/A
�,. Instrument '11Y120 1V
-,,Client ID: AA52816
Prep Method: 9014=9010C ,"
Prep Date: -N
s Matrix LlgWaste
"Analytical Method: 4014-90106 =
"s
Cal Date 05/22/2614 15 00 "
VUorkgroup #. ,WG483523 ,.
Analyst:, DLP °
Run Date T07/10/20341015
Collect Date 07/02/2014 15:00
Dilution: 1
File ID 1V 1407101015 04 ,-,
Sample .Tag
Units: mg/L
;
Analyte
CAS #
Result
Qua[
RL
MDL
Cyanide
57-12-5
U
0.0100
0.00500
U Not detected at or above adjusted sample detection limit
Page 1 of 2 Generated at Jul 16, 2014 11:11
Page 22
L14070270 / Revision: 0 / 35 total pages
Generated: 07/16/2014 11:15

Lab Report #: L14070270
'Lab Project #: 2941.016
Project Name: Wilson NC
Lab Contact: Emily Yoak
C:artifirnta of AnalvsiG
Analyte
CAS #
Result
Qual
RL
MDL
Ignitability
62.0
>
0.000
0.000
> Result is greater than the associated numerical value.
Sample #: L14070270-01
PrePrep Method: WA
Instrument:' UV-120-1V
Client ID:. AA52816
Prep Method: SW7.33...
.. Prep Date: N/A ;
Matrix: LigWaste
Analytical Method: SW7.33
Cal Date: 06/16/2014 11:00,
Workgroup #: WG483328
Analyst: DLP
Run Date: 07/0 9/2014 15:00-
Collect Date:"07/02/2014 15:00
Dilution: 1
File ID: 1V.1407091500=07 ;
Sample Tag.
Units: mg/kg
Analyte
CAS #
Result
Qual
RL
MDL
Reactivity, Cyanide
57-12-5
U
49.9
49.9
U Not detected at or above adjusted sample detection limit
Page 2 of 2 Generated at Jul 16. 2014 11:11
Page 23
L14070270 / Revision: 0 / 35 total pages Generated: 07/16/2014 11:15

Lab Report #:
L14070270
Lab Project #:
2941.016
Project Name:
Wilson NC
Lab Contact:
Emily Yoak
certlticate of Analysis
Sample#: L14070270-01
PrePrep,Method:,
Instrument: HPMS8 ,
Client'ID: AA52816
Prep Method:, 5030B/5030C15035A
Prep Date: N/A-,
_Matrix: TCLP Leach
Analytical Method: 8260B
Cal Date: 06/24/2014 17:18 -
Workgroup #: WG483538
Analyst: TMB
Run Date:. 07/10/2014,12:25 -'
Collect Date: 07/02/2014 15:00
� Dilution: 10
_ File ID: 8M398585
Sample Tag: DL01 -
Units: ug/L -
Analyte
Result
Qual
RL
MDL
EPA HW#
Reg. Limit
Benzene
U
50.0
1.25
D018
500
Carbon tetrachloride
U
50.0
2.50
D019
500
Chlorobenzene
U
50.0
1.25
D021
100000
Chloroform
U
50.0
1.25
D022
6000
1,2-Dichloroethane
U
50.0
2.50
D028
500
1,1-Dichloroethene
U
50.0
5.00
D029
700
Methyl Ethyl Ketone
U
100
25.0
D035
200000
Tetrachloroethene
U
50.0
2.50
D039
700
Trichloroethene
U
50.0
2.50
D040
500
Vinyl chloride
U
100
2.50
D043
200
Surrogate
Recovery
Lower Limit
Upper Limit
Q
Dibromofluoromethane
117
86
118
1,2-Dichloroethane-d4
119
80
120
Toluene-d8
107
88
110
4-Bromofluorobenzene
104
86
115
U Not detected at or above adjusted sample detection limit
Sample#: L14070270-01•PrePrep,Method:
-n
Instrument- HPM812-'._
Client ID: -AA52816
Prep Method: 3510C
Prepbate: ,07/08/201413:30 _
Matrix: TCLP Leach
Analytical Method: 827UC
Cal Date: ' 06/19/2014 1229
Workgroup #: WG483324
Analyst: CAA
Run Date:, 07/09/201413.03' '
Collect Date:,07/0212014 15:00.
Dilution:.1`• - .-
File ID: 12M49651
Sample Tag01
Units: -ug/L
Analyte
Result
Qua[
RL
MDL
EPA HW#
Reg. Limit
o-Cresol
U
50.0
25.0
D023
200000
m-,p-Cresol
U
50.0
25.0
D025
200000
1,4-Dichlorobenzene
U
50.0
25.0
D027
7500
2,4-Dinitrotoluene
U
50.0
25.0
D030
130
Hexachlorobenzene
U
50.0
25.0
D032
130
Hexachlorobutadiene
U
50.0
25.0
D033
500
Hexachloroethane
U
50.0
25.0
D034
3000
Page 1 of 4 Generated at Jul 16, 2014 11:11
Page 24
L14070270 / Revision: 0 / 35 total pages Generated: 07/16/2014 11:15

Lab Report #: L14070270
Lab Project #: 2941.016
Project Name: Wilson NC
Lab Contact: Emily Yoak
17'.Prtifirnfn of AnalvciS
Analyte
Result
Qual
RL
MDL
EPA HW#
Reg. Limit
Nitrobenzene
U
50.0
25.0
D036
2000
Pentachlorophenol
U
250
125
D037
100000
Pyridine
U
250
125
D038
5000
2,4,5-Trichlorophenol
U
50.0
25.0
D041
400000
2,4,6-Trichlor6phenol
U
50.0
25.0
D042
2000
Surrogate
Recovery
Lower Limit
Upper Limit
Q
2-Fluorophenol
44.4
21
100
Phenol-d5
29.5
10
94
Nitrobenzene-d5
79.1
35
114
2-Fluorobiphenyl
75.5
43
116
2,4,6-Tribromophenol
95.0
10
123
p-Terphenyl-d14
98.0
33
141
U Not detected at or above adjusted sample detection limit
Sample #: L14070270-01
PrePrep Method:
Instrument: HP15
Client ID: AA52816
Prep Method: 3510C
Prep Date: .07/08/2014 08 50.-
Matrix: TCLP Leach
Analytical Method: 8081A ,
Gal Date _' 07/10/201-4 2134
Workgroup #: WG483355
Analyst: ECL
Run,Date 07/14/m416 46 '
Collect Date: 07/02/2014,15:00
Dilution: 1
File ID ,15G45253.R
Sam le Ta 01
.p 9
Units: u /L
g
Analyte
Result
Qual
RL
MDL
EPA HW#
Reg. Limit
Endrin
U
0.500
0.100
D012
20
Lindane
U
0.500
0.100
D013
400
Methoxychlor
U
0.500
0.100
D014
10000
Toxaphene
U
10.0
3.00
D015
500
Chlordane
U
10.0
3.00
D020
30
Heptachlor
U
0.500
0.100
D031
8
Heptachlor Epoxide
U
0.500
0.100
D031
8
alpha Chlordane
U
0.500
0.100
gamma Chlordane
U
0.500
0.100
Surrogate
Recovery
Lower Limit
Upper Limit
Q
2,4,5,6-Tetrachloro-m-xylene
75.3
20
180
Decachlorobiphenyl
76.2
25
140
U Not detected at or above adjusted sample detection limit
Page 2 of 4 Generated at Jul 16, 2014 11:12
Page 25
L14070270 / Revision: 0 / 35 total pages Generated: 07/16/2014 11:15

Lab Report #: L14070270
Lab Project #: 2941.016
Project Name: Wilson NC
Lab Contact: Emily Yoak
certiticateot Anaiysls
Sample #: L14070270-01
PrePrep Method:
Instrument: I HP17
Client ID: AA52816
Prep Method: METHOD
Prep Date: 07/08/2014 15:45
Matrix: TCLP Leach
Analytical Method: 8151A
Cal Date: 07/11/2014 17:34
Workgroup #: WG483601
Analyst: ECL
Run Date: 07/11/2014 23:40
Collect Date: 07/02/2014 15:00
Dilution: 1
File ID: 17G17468.F
Sample Tag: 01
Units: ug/L
Analyte
Result
Qual
RL
MDL
EPA HW#
Reg. Limit
2,4-D
U
20.0
5.00
D016
10000
2,4,5-TP (Silvex)
U
2.00
0.500
D017
1000
Surrogate
Recovery
Lower Limit
Upper Limit
Q
2,4-Dichlorophenylacetic acid
52.0
20
144
U Not detected at or above adjusted sample detection limit
Sample #: L14070270-01
PrePrep Method:
Instrument: ICP-THERMO2
Client ID: AA52816
Prep Method: 3015
Prep Dater 07/08/2014 08:57
Matrix: TCLP Leach
Analytical Method: 6010B
Cal Date: 07/08/2014 09:50
Workgroup #: WG483191
Analyst: BKT
Run Date: 07108/201412:16
Collect Date: 07/02/2014 15:00
Dilution: 1
File ID: T2.070814.121606
Sample Tag: 01
Units: mg/L
Analyte
Result
Qual
RL
MDL
EPA HW#
Reg. Limit
Arsenic, TCLP
U
1.00
0.500
D004
5
Barium, TCLP
U
0.100
0.0500
D005
100
Cadmium, TCLP
U
0.100
0.0500
D006
1
Chromium, TCLP
U
0.200
0.100
D007
5
Lead, TCLP
U
1.00
0.500
D008
5
Selenium, TCLP
U
0.800
0.400
D010
1
Silver, TCLP
U
0.100
0.0500
D011
5
U Not detected at or above adjusted sample detection limit
Sample #. L14070270-01
PrePrep Method:
Instrument. CVAA1
Client ID: AA52816
Prep Method: 7470A
Prep Date: 07/08/2014 09:15
Matrix: TCLP Leach
Analytical Method: 7470A
Cal Date: 07108/201414:19
Workgroup #: WG483236
Analyst: JJS
Run Date: 07/08/201415:26
Collect Date: 07/02/2014 15:00
Dilution: 1
File ID: M7.070814.152626
Sample Tag: 01
Units: mg/L
Analyte
Result
Qual
RL
MDL
EPA HW#
Reg. Limit
Mercury
U
0.00800
0.00400
D009
0.2
U Not detected at or above adjusted sample detection limit
Page 3 of 4 Generated at Jul 16, 2014 U:12
Page 26
L14070270 / Revision: 0 / 35 total pages Generated: 07/16/2014 11:15

Lab Report #: L14070270
Lab Project #: 2941.016
Project Name: Wilson NC
Lab Contact: Emily Yoak
Certificate of Analysis
Page 4 of 4
Generated at Jul 16, 2014 11:12
Page 27
L14070270 / Revision: 0 / 35 total pages Generated: 07/16/2014 11:15

-- F-
ANNUAL RESIDUAL SAMPLING SUMMARY FORM
%X'Q Permit No. WQ0000838 Facility Name Granville farms, Inc. Class 11 Source Permit No. 02-91-010
Laboratory 1
A&I. F.astem
Iabs, Inc
Laboratory 2
_
Sample or CompositeDate
7,2.'3114
Parameter (mg/Yg) Class A Clas B
Alumimrm^ N/A
N/A
162,0t41
Ammonia Nitrogen N/A
N/A
y tr7t1
Arsenic 41
75
1;
Cadmium 39
85
_
Calcium N/A
N/A
4,300
249a
42
Copper 1,500
Lead 300
840
6
Magnesium N/A
N/A
I,(K10
Mercury 17
57
R-1
hfol0denum N/A
75
9
Nickel 420
420
8
Nitrite -Nitrite Nitrogen N/A
N/A
51
Pcrceit lid, N/A
N/A
tk99
pH (no units) N/A
N/A
7.11
Phosphorus N/A
N/A
1;F10
Potassium N/A
N/A
767
PAN (Lnj,/Inc.) N/A
N/A
N/A
100
11,985
7,440
io
PAN (Surface) N/A
Selenium loo j
Sodium N/A
N/A
640
SAR N/A
N/A
N/A
7,500
rk27
16_11af
TKN N/A
'Line 2,800
jCY
Source Name Kerr ! ikc llel,Rotial WIT
"Y eemty, under penalty of Last; that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qua&fied personnel property gathered and evaluated the information submitted. 1 am aware that there are significant penalties for
submitting f1d ' Wormation, includinyt�'th�e possibWty of fines and imprisonment for knowing violations."
]tgIrarUFe or Date
Vreparer is defined i t�4�PR" ant 503.9(r) and 15A NCAC ZT .1102 M

FIELD LOADING ESTIMATES
Facility Kerr Lake Regional WTP
Sampling Date 7/2/2014
% Solids 0.99
Mineralization Rate 0.4
Gallons per DT 24,223.05
pH 7.23
Sodium Absorpotion 0.27 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 16,200 lbs./1,000 gal 1.34
Potassium lbs./1,000 gal
0.06
Ammonia Nitrogen (mg/Kg) 9,090.00 lbs./1,000 gal 0.75
Phosphorus lbs./1,000 gal
0.16
Nitrate -Nitrite (mg/Kg) 50.50 lbs./1,000 gal 0.00
Calcium lbs./1,000 gal
0.21
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.08
PAN (mg/Kg) 7,440 lbs./1,000 gal 0.61
Manganese lbs./1,000 gal
1.35
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
0.61
PAN (mg/Kg) 11,985 lbs./1,000 gal 0.99
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling Class B Ceiling
Limits (mg/Kg) Limits (mg/Kg)
41 75
39 85
1,500 4,300
300 840
17 57
420 420
100 100
2,800 7,500
1st Yea:
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
13.00
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
2.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
42.00
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
6.00
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.40
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
8.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
10.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
50.00
Zinc lbs./1,000 gal
0.00
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
16,200
7,440 14.88
8,761
16,200
11,985 23.97
4,216
8,761
1,752 3.50
7,008
4,216
843 1.69
3,372
7,008
701 1.40
6,308
3,372
337 0.67
3,035
6,308
315 0.63
5,992
3,035
152 0.30
2,883
5,992
150 0.30
5,842
2,883
72 0.14
2,811
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)- 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 10,358 20.72
Total 13,389 26.78

Page: 1 of 2
Report Number: 14-184-0203
Account Number: 04596
Submitted By: SCOTT CARPENTER
Send To: SOIL PLUS, LLC
SCOTT CARPENTER
P.O. BOX 1396
OXFORD, NC 27565
Lab Number: 56284
Sample Id : KL 072014
� L A&L Eastern Laboratories, Inc.
7621 Whitepine Road Richmond, Virginia 23237 [phone] Fax [phone]
www.aleastem.com
Project: KERR LAKE
NC CERT#257
REPORT OF ANALYSIS Date Sampled: 7/2/2014 13:00:00
Date Received: 07/03/2014 00:00
Date Reported: 07/11/2014
Total Solids "
0.99
9900
100.0
JM
07/03/2014 12:35
SM-2540G
Moisture *
99.01
100.0
JM
07/03/2014 12:35
SM-2540G
Total Kjeldahl Nitrogen
1.62
16200
10.0
JM
07/07/2014 08:19
SM-4500-NH3C-TKN
Total Phosphorus
0.20
1990
100
KM
07/08/2014 10:35
SW 6010C
Total Potassium
0.08
767
100
KM
07/08/2014 10:35
SW 6010C
Total Sulfur
0.73
7340
100
KM
07/08/2014 10:35
SW 6010C
Total Calcium
0.25
2490
100
KM
07/08/2014 10:35
SW 6010C
Total Magnesium
0.10
1000
100
KM
07/08/2014 10:35
SW 6010C
Total Sodium
0.06
640
100
KM
07/08/2014 10:35
SW 6010C
Total Iron
30700
100
KM
07/08/2014 10:35
SW 6010C
Total Aluminum
162000
100
KM
07/08/2014 10:35
SW 6010C
Total Manganese
16400
5
KM
07/08/2014 10:35
SW 6010C
Total Copper
42
5
KM
07/08/2014 10:35
SW 6010C
Total Zinc
50
5
KM
07/08/2014 10:35
SW 6010C
Ammonia Nitrogen
0.91
9090
10.0
JM
07/09/2014 08:00
SM-4500-NI3C
Organic N
0.71
7110
0.001
JM
07/11/2014 10:35
CALCULATION
Nitrate+Nitrite-N
50.5
2.00
JM
07/07/2014 08:20
SM-450ONO3F
Total Cadmium
<2.0
2.0
KM
07/08/2014 10:35
SW 6010C
All values are on a dry weight
basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
A&AVA
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced
in whole or part, nor may
any reference be made
to the work, the results, or the company in any advertising, news release, or other
public announcements without obtaining our prior written authorization.
Debbie Holt

Page: 2 of 2
Report Number: 14-184-0203
Account Number: 04596
Submitted By: SCOTT CARPENTER
Send To: SOIL PLUS, LLC
SCOTT CARPENTER
P.O. BOX 1396
OXFORD, NC 27565
Lab Number: 56284
Sample Id : KL 072014
�L A &L Eastern Laboratories, Inc.
7621 Whitepine Road Richmond, Virginia 23237 [phone] Fax [phone]
wwwaleastem.com
Project: KERR LAKE
NC CERT#257
REPORT OF ANALYSIS
Total Chromium
120
5
KM
Total Nickel
8
5
KM
Total Lead
6
5
KM
Total Arsenic
13.0
3.0
KM
Total Mercury
<0.4
0.4
KM
Total Selenium
10.0
5.0
KM
pH (Standard Units) *
7.23
2.00
JM
Total Molybdenum
9
5
KM
Soluble Phosphorus
<0.01 <100
100
MW
Comments:
WATER SOLUBLE P, SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES.
QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "AI" AND "S".
ALL OTHER QC DATA IS ACCEPTABLE.
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis
Date Sampled: 7/2/2014 13:00:00
Date Received: 07/03/2014 00:00
Date Reported: 07/11/2014
07/08/2014 10:35
SW 6010C
07/08/2014 10:35
SW 6010C
07/08/2014 10:35
SW 6010C
07/08/2014 10:35
SW 6010C
07/08/2014 09:00
SW-7471 B
07/08/2014 10:35
SW 6010C
07/07/2014 08:44
SW-9045D
07/08/2014 10:35
SW 6010C
07/07/2014 09:04
SOLUBLE P IN MANURE
Ourreports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
Debbie Holt

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO062219
Laboratory 1 Environment
1, Inc.
Laboratory 2
Sample or CompositeDate 2/28/2014
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
5,370
Ammonia Nitrogen
N/A
N/A
2,351
Arsenic
41
75
2.5
Cadmium
39
85
0.7
Calcium
N/A
N/A
11,790
Copper
1,500
4,300
351
Lead
300
840
12
Magnesium
N/A
N/A
2,369
Mercury
17
57
0.21
Molybdenum
N/A
75
6
Nickel
420
420
5
Nitrate -Nitrite Nitrogen
N/A
N/A
4
Percent Solids
N/A
N/A
1.70
PH (no units)
N/A
N/A
6.40
Phosphorus
N/A
N/A
5,124
Potassium
N/A
N/A
4,250
PAN (Inj./Inc.)
N/A
N/A
2,512
PAN (Surface)
N/A
N/A
1,337
Selenium
100
100
5
Sodium
N/A
N/A
8,325
SAR
N/A
N/A
2.38
TKN
N/A
N/A
2,876
Zinc
2,800
7,500
424
Source Name Kings Grant Subdivision
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations"
/4-CIL 02-14-2015
Signature of Preparer *' Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

AGMAN
e FIELD LOADING ESTIMATES
-
Facility Kings Grant Subdivision
Sampling Date 2/28/2014
% Solids 1.7
Mineralization Rate 0.3
Gallons per DT 14,106.36
pH 6.4
Sodium Absorpotion 2.38 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 2,876 lbs./1,000 gal 0.41
Potassium lbs./1,000 gal
0.60
Ammonia Nitrogen (mg/Kg) 2,351.00 lbs./1,000 gal 0.33
Phosphorus lbs./1,000 gal
0.73
Nitrate -Nitrite (mg/Kg) 3.86 lbs./1,000 gal 0.00
Calcium lbs./1,000 gal
1.67
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.34
PAN (mg/Kg) 1,337 lbs./1,000 gal 0.19
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 2,512 lbs./1,000 gal 0.36
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
C
1.0 Injection/Incorporation
`
EPA METAL LIMITS
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
2.50
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.70
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
351.00
Copper lbs./1,000 gal
0.05
Lead (mg/Kg)
12.00
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.21
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
5.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
424.00
Zinc lbs./1,000 gal
Q.06
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
TKN
PAN
PAN
Nitrogen
TKN
PAN PAN
Nitrogen
(mg/kg) (lbs/DT)
(mg/Kg)
(mg/kg) (lbs/DT)
(mg/Kg)
2,876
1,337
2.67
1,539
2,876
2,512 5.02
364
1,539
231
0.46
1,308
364
55 0.11
309
1,308
98
0.20
1,210
309
23 0.05
286
1,210
45
0.09
1,165
286
11 0.02
275
1,165
22
0.04
1,143
275
5 0.01
270
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
"Total 1;/33 3.47
Total 2,606 5.21

EINWO'TOME 0 % HEmppTOW
Raetewati®�
PO. BOXR7085, 114 OAKMONT DRIVE„ PHONE [phone] y
GREENVILLE, N.C. 27835-7085 FAX [phone]
ID#: 622 A
KINGS GRANT (CwS)
CAROLINA WATER SERVICE OF NC
315B HWY. 70 EAST DATE COLLECTED: 02/28/1.4
GARNER ,NC 27529 DATE REPORTED : 04/0'2/14
REVIEWED BY: 'A-4 `
Sludge
Analysis
Method
PARAMETERS
Sample
Date Analyst
Code
PH, Units
6.4
03/04/14 TRB
4500T-IB-00
Aluminum, (dry wt. basis), mg/kg
5370
03/05/14 LFJ
EPA200.7
Arsenic (dry wt. basis), mg/kg
<2.5
03/18/14 MEL
3113B-04
Calcium (dry wt. basis), mg/kg
11790
03/05/14 LFJ
EPA200.7
Cadmium (dry wt. basis), mg/kg
0.7
03/26/14 MEL
311313-04
Copper (dry wt. basis), mg/kg
351
03/05/14 LFJ
EPA200.7
Chromium, T.(dry wt. basis),mg/kg
8
03/05/14 LFJ
EPA200.7
Lead (dry weight basis), mg/kg,
12
03/31/14 1%fEL
311313-04
Magnesium (dry wt. basis), mg/kg
2369
03/05/14 LFJ
EPA200.7
Mercury (dry wt. basis), mg/kg
0.21
03/10/14 ADD
245.1 R3-94
Nickel (dry wt. basis), mg/kg
<5.0
03/07/14 LFJ
EPA200.7
Potassium (dry wt. basis), mg/kg
4250
03/05/14 LFJ
EPA200.7
Selenium (dry wt. basis), mg/kg
<5.0
03/25/14 MEL
3113E-04
Sodium (dry wt. basis), mg/kg
8325
03/19/14 11M1%1
3111B-99
Zinc (dry wt. basis), mg/kg
424
03/10/14 ADD
3111E-99
Total Solids, %
1.7
03/03/14 MDD
254OG-97
TKN (dry wt.), mg/kg
2876
03/13/14 ANO
351.2 R2-93
Ammonia Nitrogen (dry wt.),rng/kg
2351
03/06/14 ANO
350.1 R2-93
Phosphorus, T. (dry wt.), mg/kg
5124
03/06/14 ALB
365.4 -74
Nitrate -Nitrite (dry wt.), mg/kg
<3.86
03/05/14 ANO
353.2 112-93
Plant Available Nitrogen, mg/kg
1333
03/14/14 SEJ
Molybdenum (dry wt. basis), mg/kg
6
03/05/14 LFJ
EPA200.7

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
XVQ Pemit No. WQOOD0838 FacdityName GranviEc Farms, Im Class i3 Source Pcnei[No_ vC002'9131 Source 21 me K drell Job Corp
Labarapoty 1 R&L Eucem
_ I.abr, 9nc
Laboratory
SampleorCompositeMte 12/1712014
Parameter (mg/Kg) Gass A Chw B
Akrxn; um. N/A N/A um
Amruonia Nitrogen N/A N/A 5.360
Arsem 41 75 3
! Cadmium 34 85 2
Caicinm N/A N/A ii7,rKxl
_ Copper 4500 4,3W t,"
---
---
i - • —
--
Magnesium
i.
N/A
-
N/A
3.130
Macuwq'- 17
57
0.4
Molybdeamn MIA 7S
5
Nickel
420
- 420 . 9
Vitraw-Nirrire Nivagen
N/A
N/A
126A10
PeeueetSolids' N/A
N/A
7-61
gR (no units)
N/A N/A
, 11.55
Phosphorus
N/A
N/A
1001)
Potassium
NIA
NIA I
?,210
j PAN (lnl./Ins) N/A
N/A
21AI S
PAN (Surface)
N/A ` N/A 19.139
Selenium
100
100
5
Sodium
N/A
NIA
vM
SAR N/A
N/A
p.29
. --_ TYAt ATl•
AT1l
.A9fYf
Zinc 1 200 i 7,50D I 367 1
"I certik under penahyadlawi that this doerunentwas prepared under my directimo or supervision in acemlance with a system designed to,
assure 9 d peeaomnel properly gathered and evaluated the informatimm oubmittcd. Ian aware that trove are significant penalties for
stebm se " including the possibility coin. and imprisonment forknowingvielatioas s
Signature of Preparcr's gape
Wilteparer is defined in 40 CFR Part 5039(r) and 15A NCAC 2T M02 (26)

Page: 1 of 2
Report Number: 15-012-9207
Account Number: 04596
Send To: SOIL PLUS, LLC
SCOTT CARPENTER
P.O. BOX 1396
OXFORD, NC 27565
Lab Number: 59600
Sample Id: KITTRELL
AFL A&L Eastern Laboratories, Inc.
7621 Whitepine Road Richmond, Virginia 23237 [phone] Fax (804) 271-W6
wr maleastern.com
Project: 200705.A11-KITTRELL JOB CORP WWTP
NC CERT#257
REPORT OF ANALYSIS Date Sampled: 12/17/2014 11:35:00
Date Received: 01/12/2015 00:00
Date Reported: 02/18/2015
Total Solids *
2.61
26100
100.0
CZ
01/13/2015 11:01
SM-2540G
Moisture *
97.39
100.0
CZ
01/13/2015 11:01
SM-2540G
Total Kjeldahl Nitrogen
5.98
59800
10.0
JM
01/14/2015 08:50
SM-4500-NH3C-TKN
Total Phosphorus
1.68
16800
100
KM
01/13/2015 12:47
SW 6010C
Total Potassium
0.22
2210
100
KM
01/13/2015 12:47
SW 6010C
Total Sulfur
0.87
8710
100
KM
01/13/2015 12:47
SW 6010C
Total Calcium
11.70
117000
100
KM
01/13/2015 12:47
SW 6010C
Total Magnesium
0.31
3130
100
KM
01/13/2015 12:47
SW 6010C
Total Sodium
0.23
2260
100
KM
01/13/2015 12:47
SW 6010C
Total Iron
11400
100
KM
01/13/2015 12:47
SW 6010C
Total Aluminum
8300
100
KM
01/13/2015 12:47
SW 6010C
Total Manganese
73
5
KM
01/13/2015 12:47
SW 6010C
Total Copper
144
5
KM
01/13/2015 12:47
SW 6010C
Total Zinc
367
5
KM
01/13/2015 12:47
SW 6010C
Ammonia Nitrogen
0.54
5360
10.0
JM
01/13/2015 09:29
SM-4500-NH3C
Organic N
5.44
54440
10.0
01/13/2015 09:29
CALCULATION
Nitrate+Nitrite-N
126
2.00
JM
01/14/2015 08:50
SM-450ONO3F
Total Cadmium
<2.0
2.0
KM
01/13/2015 12:47
SW 6010C
All values are on a dry weight basis except as noted
by asterisk. Detection
limit on all N series
is on a wet basis.
•(`��
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in
whole or part, nor may any reference be made
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
Debbie Holt

Page: 2 of 2
Report Number: 15-012-9207 � � A&L Eastern Laboratories, Inc.
Account Number: 04596 7621 Whitepine Road Richmond, Virginia23237 [phone] Fax [phone]
mvw.aleastem.com
Send To: SOIL PLUS, LLC
SCOTT CARPENTER
P.O. BOX 1396
OXFORD, NC 27565
Lab Number: 59600
Sample Id: KITTRELL
Project: 200705.A11-KITTRELL JOB CORP WWTP
NC CERT#257
REPORT OF ANALYSIS Date Sampled: 12/17/2014 11:35:00
Date Received: 01/12/2015 00:00
Date Reported: 02/18/2015
Total Chromium
24
5
KM
01/13/2015 12:47
SW 6010C
Total Nickel
9
5
KM
01/13/2015 12:47
SW 601OC
Total Lead
15
5
KM
01/13/2015 12:47
SW 601OC
Total Arsenic
<3.0
3.0
KM
01/13/2015 12:47
SW 601 OC
Total Mercury
<0.4
0.4
KM
01/14/201509:00
SW-7471B
Total Selenium
<5.0
5.0
KM
01/13/2015 12:47
SW 601OC
pH (Standard Units) 11.55
2.00
JM
01/13/2015 09:29
SW-9045D
Total Molybdenum
<5
5
KM
01/13/2015 12:47
SW 601OC
Soluble Phosphorus 0.03
300
100
JM
01/14/2015 08:15
SOLUBLE P IN MANURE
Comments:
WATER SOLUBLE P, SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES.
QUALIFIER: THE LRB WAS OUT OF LIMITS FOR "Mn".
THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Fe" AND "S".
THE MSD WAS OUT OF LIMITS FOR
"Se". ALL OTHER QC DATA IS ACCEPTABLE.
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
Debbie Holt

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO040266 Source Name Knightdale Mobile Home Park
Laboratory 1 Pace Analytical
Laboratory 2
Sample or CompositeDate 10/16/2014
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
6,326
Ammonia Nitrogen
N/A
N/A
1,630
Arsenic
41
75
1.01
Cadmium
39
85
0.065
Calcium
N/A
N/A
116,340
Copper
1,500
4,300
123.53
Lead
300
840
6.67
Magnesium
N/A
N/A
2,739
Mercury
17
57
0.131
Molybdenum
N/A
75
7.45
Nickel
420
420
7.12
Nitrate -Nitrite Nitrogen
N/A
N/A
575
Percent Solids
N/A
N/A
1.53
pH (no units)
N/A
N/A
7.75
Phosphorus
N/A
N/A
4,046
Potassium
N/A
N/A
2,288
PAN (Inj./Inc.)
N/A
N/A
9,481
PAN (Surface)
N/A
N/A
8,666
Selenium
100
100
1.76
Sodium
N/A
N/A
5,699
SAR
N/A
N/A
0.56
TKN
N/A
N/A
25,882
Zinc
2,800
7,500
454.9
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
lx02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

F
L
F�
U
FIELD LOADING ESTIMATES
Facility Knightdale Mobile Home Park
Sampling Date 10/16/2014
% Solids 1.53
Mineralization Rate 0.3
Gallons per DT 15,673.74
PH 7.75
Sodium Absorpotion 0.56 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land .Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 25,882 lbs./1,000 gal 3.30
Potassium lbs./1,000 gal
0.29
.Ammonia Nitrogen (mg/Kg) 1,630.00 lbs./1,000 gal 0.21
Phosphorus lbs./1,000 gal
0.52
Nitrate -Nitrite (mg/Kg) 575.16 lbs./1,000 gal 0.07
Calcium lbs./1,000 gal
14.85
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.35
PAN (mg/Kg) 8,666 lbs./1,000 gal 1.11
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
0.22
PAN (mg/Kg) 9,481 lbs./1,000 gal 1.21
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Limits (mg/Kg)
41
1st Year
2nd Year
3rd Year
4th Year
5th Year
Class B Ceiling
Limits (mg/Kg)
75
85
4,300
840
57
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
1.01
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.07
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
123.53
Copper lbs./1,000 gal
0.02
Lead (mg/Kg)
6.67
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.13
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
7.12
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
1.76
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
454.90
Zinc lbs./1,000 gal
0.06
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
T
(mg/kg) (lbs/DT)
(mg/Kg)
25,882
8,666 17.33
17,216
25,882
9,481 18.96
16,401
17,216
2,582 5.16
14,634
16,401
2,460 4.92
13;941
14,634
1,098 2.20
13,536
13,941
1,046 2.09
12,895
13,536
- 508 1.02
13,029
12,895
484 0.97
12,412
13,029
244 0.49
12,784
12,412
233 . 0.47
12,179
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
fatal 13,098 26.20 ,
Total 13,703 27.41

FROM : HARVE`t' AND BETTY MURPHREY FAX NO. : 919-366--1814 Jars. 09 2015 01:12PM P1
PAW MoWtAl s o v ice Me,
rtareia „ NC 2740
� IRY+tC�E%9A.-04�t (819)�9Sd
I
ANALYTICAL L RESULTS
i
Praie= KNIGHTDALE
L_ Pace Prajed Ko,: S=1814
Sample: 1ft1ta1.1rbaks@. 6GE Lo�)10: 92221814001 Collected: 1011611410:25 Received: 10116/1415:25 Matrix 1Nater
Prlrameler
RMits Units
Repon Limit
DF
Prepared Axlalyaed
C.RS No. QUM
6010 MET 1CP
Analytical Method: EPA 6010 Pmparaticm Me ttad. EPA 3010
Aluminum
08800 urjlL
100
1
10=11415.15 10121/1401:11
742 fifl-6
Arsers;c
16.4 ug/L
10.0
1
10120114.16:45 10/2411d01:11
7+44MB-2
Cadmium
NO ug/L
1.0
1
.1012011415.16 1012111401:11
7440-43.9
Caldum
1780000 ug/L
10000
100
1012011416y.15 1W111414:08
74440--70-2
Chromium
110 ug/L
6.0
1
1012011416:16 10121/14 01:11
1440.47.3
Copper
100 ug/L
5.0
1
1020/1415:15 10/21/14 01;11'
7440=50-t
Le> d
102 ug/L
5.0
1
10/20/141M15 1®/71/14 01A1
7439- 1
Magnesium
41000 414
100
1
10/20/1415:16 101114 ft'll
746"6-4
Molybdenum
114 ug/L
6.0
1
10120 A 15:15 10/21/14 04:11
7+5SO-06-11
Nickel
10 ug1L
6.0
1
1012011416:1$ 10121M40111
76dd04"
PalaStiam
36000 ug/L
6000
1
10/2M415:15 IM1114,01,11
744049-7
Selenium
2.6.0 ug/L
10.0
1
10/2011415:15 10/2111401:11
7782.49-7
Sodium
87200 U911.
5600
1
10MI1415:15 10/21/i413.41
7440 5
Zinc
99M ug/L
10.0
1
1012011415:15 10121/14 01:11
76.6
7470 Merouey
Analytical Method; EPA 7470 Propontgion Nialrrad: EPA 7470
Mermary
10 ug/i.
0.20
1
1011i1/14 44:10 10/23M415:63
74S"M
2mia TOW wide
AnaloC*l It Minor: GM 26410 i
'total Solids
ism mg/L.
833
1
10120/1418:59
Total Witrvgen Calualafio i
Analytical Method:-'ttN+NO3+NO2 Calculation
Total Nitrogen
40S rng1L
0.12
1
11104/1415:03
300.010 Aniaw 23 Dap
Analytical Method: EPA 300.0
Sulfate
2C.i mg/L
2.0
1
101WI401:05
1008-111-5
351,2 Tatai i itltthl hi&Cgon
Analytical Method: EPA 351.2
Nitrogen, Kjeldahi, Tonal
398 m81L
10.0
20
1012111410,52
7727-97-9 M1
353:2 ffltrrugan, "021Ti 03 Pais.
1Analyl;'cal Method: EPA 3632
Nitrogen,, N'02 plus NO3
&S mg/L
0.20
10
1012811417:35
365.1 Phosphor"% Total
Anaiydeal Meth oti: EPA ; 66.1
Phosphorus
61.0, rtmgtL
1.2
25
10/26/1415•.40
7723.1"
4600 Chlorides
AnVilyt eel RYeihod: tM 450ii-Cl-E
Chloride
61.1 mg/L
10.0
10
10128/14 05:04
tr"ra87-M-6
REPORT OF LASOPATORY ANALYSIS
Yhls report "R rvot tm mpro iuerd, oxoapt in full,
Oate: i 11b412014 03:05 PM w;VW ma+earitten omwnt of PMe AUwwaMk;51 Servioos, Irx..
Pogo 4 *117

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Claims B Source Permit No. NCO079316
Laboratory I A&LEastern
Jabs, Inc.
Laboratory 2
Sample orCompositeDate 2/10/2014
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
47,700
Ammonia Nitrogen
N/A
N/A
4,530
Arsenic
41
75
4
Cadmium
39
85
Calcium
N/A
N/A
18,700
Copper
1,500
4,300
368
Lead
300
840
22
Magnesium
N/A
N/A
3,6W
Mercury
17
57
1.4
Molybdenum
N/A
75
6
Nickel
420
420
_ 17
Nitrate-Ntrite Nitrogen
N/A
N/A
144.00
Percent Solids
N/A
N/A
2.43
PH (no units)
N/A
DWA
6.85
Phosphorus
Potassium
N/A
N/A
N/A
N/A
37MO
4,640
PAN (N./Inc.)N/A
7-7
N/A
19,125
PAN (Surface)
N/A
N/A
16,860
Selenium
100
100
5
Sodium
N/A
N/A
3,840
SAR
N/A
N/A
1.05
TIIN
N/A
N/A
52,700
Zinc
2,800
7,500
539
Source Name Little Creek W WTP
. cnmry, under penalty of taw, that this docurnentwas prepared under my direction or supervision in accordance with a system designed to
assure that qualified onnel property g ered and evahtated the information submitted. I am aware that there are significant penalties for
submitting false in tion, i d' possibility of fines wd imprisonment for knowing violations."
Signature of Preparer *
Date
*Preparer is defined in 40 CFR Part 503.9(t) and 15A NCAC 2T .1102 (26)

�i
�-=
_6 GMAN
i �
W,a FIELD LOADING ESTIMATES
Facility Little Creek VAWP
Sampling Date 2/10/2014
% Solids 2.43
DiMineralization
Rate 0.30
Gallons per DT 9,868.65
pH 6.85
I
Sodium Absorpotion 1.05 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
I
NITROGEN APPLICATION
NUTRIENT APPLICATION
IY
TKN (mg/Kg) 52,700 lbs./1,000 gal 10.68
Potassium lbs./1,000 gal
0.94
Ammonia Nitrogen (mg/Kg) 4,530.00 lbs./1,000 gal 0.92
Phosphorus lbs./1,000 gal
7.56
Nitrate -Nitrite (mg/Kg) 144.00 lbs./1,000 gal 0.03
Calcium lbs./1,000 gal
3.79
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.73
PAN (mg/Kg) 16,860 lbs./1,000 gal 3.42
Manganese lbs./1,000 gal
0.09
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
1.44
PAN (mg/Kg) 19,125 lbs./1,000 gal 3.88
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
D
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Limits (mg/Kg)
41
Class B Ceiling
Limits (mg/Kg)
75
.HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
4.00
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
2.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
368.00
Copper lbs./1,000 gal
0.07
Lead (mg/Kg)
22.00
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
1.40
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
17.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
538.00
Zinc lbs./1,000 gal
0.11
RESIDUAL NITROGEN CALCULATION
1i
F1
1st Year
2nd Year
3rd Year
r-•
4th Year
5th Year
A
L
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TEN(mg/kg)
(lbs/DT)
(mg/Kg)
52,700
16,860 33.72
35,840
52,700
19,125 38.25
33,575
351840
5,376 10.7.5
30,464
33,575
5,036 10.07
28,539
30,464
. 2,285 4.57
28,179
28,539
2,140 4.28
26,398
28,179
1,057 2.11
27,122
26,398
990 1.98
25,408
27,122
509 1.02
26,614
25,408
476 0.95
24,932
Total 26,086 52.17
Total 27,768 55.54
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)

r-7
Page: 1 of 2
Report Number. 14-042-0201
Account Number: 45861
Submitted By: BRIAN GAY
Send To: CITY OF RALEIGH/LITTLE CREEK
BRIAN C GAY
1419 HWY 39
ZEBULON , NC 27597
Lab Number: 97858
Sample Id : SLG-21014
t
� L A&L Easters Laboratories, Inc.
7621 Whitepine Road Richmond, Virginia 23237 (604) 7439401 Fax [phone]
unvwoleastem com
r
Project: LCWWTP - SLUDGE 2-10-14
NC CERT#257
REPORT OFANALYSIS
Total Solids `
2.43
24300
100.0 - J
Moisture .
97.57
100.0 J
Total Keldahl Nitrogen
5.27
52700
10.0 J
Total Phosphorus
3.73
37300
100 K
Total Potassium
• 0.46
4640
100 K
Total Sulfur
0.71
7120
100 K
Total Calcium
1.87
18700
100 K
Total Magnesium
0.36
3600
100 K
Total Sodium
0.38
3840
100 K
Total Iron
16400
100 K
Total Aluminum
47700
100 K
Total Manganese
441
5 K
Total Copper
368
5 K
Total Zinc
538
5 K
Ammonia Nitrogen
0.45
4530
10.0 J
Organic N
4.82
48170
0.001 Ji
Nitrate+Nitrite-N
144
2.00 JI
Total Cadmium
<2.0
2.0 K
All values are on a dry weight
basis except as noted by asterisk. Detection Emit on all N series is on a
Date Sampled: 2/10/2014 10:30:00
Date Received: 02/11/2014 00:00
Date Reported: 02/14/2014
02111/201415:20
SM-254OG
02/11/201415:20
SM-2540G
02/12/2014 08:19
SM-4500-NH3C-TKN
02/1212014 11:36
SW 6010C
02/12/201411:36
SW 6010C
02112/201411:36
SW 6010C
02/12/2614 11:36
SW 6010C
02/12/201411:36
SW 6010C
02112/201411:36
SW 6010C
021121201411:36
SW 6010C
021121201411:36
SW 6010C
02/121201411:36
SW 6010C
02112/201411:36
SW 6010C
02/12/2014 11:36
SW 6010C
02/12/2014 08:19
SM-4500-NI3C
02114/201413:12
CALCULATION
02/12/2014 08:20
SM-450ONO3F
02/12/2014 11:36
SW 6010C
basis.
OW a3Nn, is aaacd ,eiers are to: lfae a3xciaessvas anti axaaatia°anfiat rrss of enr clieaats, areal aasay rae2 be refarudimed in node or part, nor may any retrreracaa be 1,06ae
to the i:•airf; flan awaits. or Ilse crnaa;eatay in any arFaaadis�arg. news reka e. ®r�iJaerFaae�tnc aaaiaoseaaceyaReaars ur7fnced o9�taieamay am farior tisteTtsar ataUxuizatic�re.
Debbie Holt

Page: 2 of 2
Report Number: 14-042-0201
Account Number: 45861
Submitted By: BRIAN GAY
Send To: CITY OF RALEIGH/LITTLE CREEK
BRIAN C GAY
1419 HWY 39
ZEBULON , NC 27597
�L A&L Eastern Laboratories, Inc.
7621 W6itepine Road R(d•oond, VirgiNa 23237 (604) T43-9401 Fax PM) 271-6446
d
wwwjleastem.eom
Project: LCWWTP - SLUDGE 2-10-14
NC CERT#257
REPORT OF ANALYSIS
Date Sampled: 2/10/201410:30:00
Lab Number: 97858
Date Received: 02/11/2014 00:00
Sample Id : SLG-2 10 14
Date Reported: 02/14/2014
PARAMETER RESULT
RESULT allANTITATION
DATE/TIMEMETHOD
Total Chromium
42
5
KM.
02/12/2014 11:36
SW 6010C
Total Nickel
17
5
KM
02/12/2014 11:36
SW 6010C
Total Lead
22
5
KM
02/12/2014 11:36
SW 6010C
Total Arsenic
4.0
3.0
KM
02/12/2014 11:36
SW 6010C
Total Mercury
1A
0.4
KM
02/12/2014 09:00
SW-7471B
Total Selenium
<5.0
5.0
KM
02/12/2014 11:36
SW 6010C
pH (Standard Units) " 6.85
2.00
JM
02/12/2014 08:19
SW-9045D
Total Molybdenum
6
5
KM
02/12/2014 11:36
SW 6010C
Chloride
2360
200
JM
02/12/2014 09:50
SM-4500CI-D
Total Beryllium
<5
5
KM
02/121201411:36
SW 6010C
Comments:
CHLORIDE, SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES.
QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "AI".
ALL OTHER QC DATA IS ACCEPTABLE.
All values are on a dry weight basis except as noted by asterisk. Deteclion bra on am N series is on a wet basis -
()Ur 14aP0IiS a f I d ietiez s are !or III 6X AJsFmfl atmi c=Aidp OkV aas-& ®d aaar esaesats, aced may f" be top, axdatw]f4 no 7,.fz de orpa4'W via aaay rarAsreme IM anal
"o Osea 114W4, Nate IeavAs, or life e:axrVsaary in any adveyfisim, nows rc'Gmm. oroilaer¢rUW aasawrN=ef rd3 a ffWad chtak;kv curer ffiar muse" aselfa�iaa6daxa.
Debbie Holt

��Of
ceAnalylical
w.vw.pacela6acam
i
February 26, 2014
Mr. Brian Gay
City of Raleigh -Little Creek WWTP
1419 Highway 39
Zebulon, NC 27597
RE: Project: TCLP SLUDGE
Pace Project No.: 92189434
Pace Analytical Servlcea, Inc.
9800I(lnceyAve, Suite 100
Hunterevllle, NC 28078
[phone]
Dear Mr. Gay:
Enclosed are the analytical results for sample(s) received by the laboratory on February 11, 2014.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
qt�nmwa;&�,O;
Erin Waters
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 20

i
Paco Analytical services, Ina
aceAnalXlcal fl 9800 Kinc®yAv®, Suite 100
Huntersville, NC 28079
w�rnpacelabs.eom (704)975.90e2
� 1
I
CERTIFICATIONS
Project: TCLP SLUDGE
iPace Project No.: 92189434
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification M 41320
Mississippi Certiflcatlon: FL NELAC Reciprocity
Arizona Certification M AZ0735
Montana Certification #: Cart 0074
Nebraska Certification: NE-OS-28-14
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Nevada Certificatlon: FL NELAC Reciprocity
Delaware Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New Jerseyy Certification #: FL765
Florida Certification #: E83079
Georgia Certification #: 956
New York Certiflcatlon M 11608
North Carolina Environmental Certiflcate #: 067
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
North Carolina Certification M 12710
Pennsylvania Certification #: 68.00547
Illinois Certification M 200068
Indiana Certification: FL NELAC Reciprocity
Puerto Rico Certification M FLO1264
South Carolina Certification: #96042001
Kansas Certification #: E-10383
Kentucky Certification M 90050
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate M 05007
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification M 460106
Maine Certification #: FLO1264
Maryland Certification: #346
Washington Certification #: 0955
West Virginia Certification #: 9962C
Massachusetts Certification M M-FL1264
Michigan Certification #: 9911
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Kansas Certification IDs
9608 Loiret Boulevard, Lenexa, KS 66219
Louisiana Certification #: 03065
WY STR Certification #: 2456.01
Arkansas Certification M 13-012-0
Nevada Certification #: KS000212008A
Illinois Certification M 003097
Oklahoma Certification #: 9205/9935
Texas Certification M T104704407-13.4
Iowa Certification* 118
Kansas/NELAP Certification #: E-10116 L�c
Utah Certification #: KS000212013-3
Illinois Certification M 003097
Charlotte Certification IDs
_
9800 Kincey Ave. Ste 100, Huntersvllle, NC 28078
Florlda/NELAP Cartiflcatlon #: E87627
North Carolina Drinking Water Certification M 37706
Kentucky UST Certiflcatlon M 84
North Carolina Field Services Certiflcatlon #: 5342
West Virginia Certification #: 357
North Carolina Wastewater Certification #: 12
South Carolina Certification M 99006001
VirginlaNELAP Certiflcation #: 460221
Asheville Certification IDs
2225 Riverside Dr., Asheville, NO 28804 North Carolina Wastewater Certification #: 40
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
Massachusetts Certification #: M-NCO30 West Virginia Certification #: 356
North Carolina Drinking Water Certification #: 37712 VlrginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical services, Inc..
Page 2 of 20

Z�aceAnalXical
vvwwpacelabs'com
SAMPLE ANALYTE COUNT
Project: TCLP SLUDGE
Pace Project No.: 92189434
Paco Analytical Services, Inc,
9800 Klncey Ave, Suite 100
Huntorsville, NC 28078
[phone]
Lab ID Sample ID MethodAnalysts
Analytes
Reported
Laboratory
92189434001 TCLP Sludge EPA8081
NU1
8
PASI-C
EPA 8151
LJM
3
PASI.O
EPA6010
SHI
7
PASI-A
EPA 7470
MTS
1
PASI-A
EPA 8270
Bpi
18
PASI-C
EPA 8260
MCK
14
PASI-C
EPA 1010
JTJ
1
PASI-A
SW 846 7.3.4.2
NDL
1
PASI-K
EPA 9045
MDW
1
PASI-A
SW 846 7.3.3.2
NDL
1
PASI-K
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, inc..
Page 3 of 20

YacceiAnalyftal
/ wwx:pacelabs.com
i
r
ANALYTICAL RESULTS
I -
Project: TCLP SLUDGE
Pace Project No.: 92189434
Pace Analytical Services, Inc.
0800 Kincey Ave, Suite 100
Huntersville, N0 26070
[phone]
-zampie: rtrt-r Stuage Lab ID: 92189434001 Collected: 02/10/14 14:15 Received: 02/11/14 16:34 Matrix; Solid
Results reported on a "wet weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qua]
8081 GCS Pesticides, TCLP Analytical Method: EPA8081 Preparation Method- PPA'Aln
gamma-BHC (Lindane)
Chlordane (Technical)
Endrin
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogates
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)
8151 Chlorinate Herbicide TCLP
2,4-D
2,4,5-TP (Silvex)
Surrogates
2,4-DCAA (S)
6010 MET ICP, TCLP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7470 Mercury, TCLP
Mercury
8270 MSSV TCLP Sep Funnel
1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachloro-1,3-butadiene
Hexachioro benzene
Hexachloroethane
2-M ethylphen ol(o-Cresol)
3&4-Methylphenol(m&p Cresoi)
Nitrobenzene
Pentachlorophenol
Pyridine
2,4,5-Tdchlorophenol
Date; 02/26/2014 05:06 PM
Leachate Method/Date: EPA 1311: 02/17114 14:45
NO ug/L
0.50
1
02M8/1411:15
02119/1409:31
58-89.9
NO ug/L
3.0
1
02/18/14 11:15
02/19/14 09:31
57.74.9
NO ug/L
0.50
1
02/1811411:15
02/19/14 09:31
72-20.8
NO ug/L
0.50
1
02118/1411:15
02/19/14 09:31
1024.67-3
NO ug/L
1000
1
02/18/14 11:15
02/19/14 09:31
72.43.5
NO ug/L
3.0
1
02/18/14 11:15
02/19/14 09:31
$001.35-2
60 %
10-138
1
02/18/1411:16
02/19/14 09:31
2051.24-3
48 %
10-110
1
02118/1411:18
02/19/14 09:31
877-09.8
Analytical Method: EPA S151 Preparation Method: EPA 3510
NO mg/L
0.010 1
NO mg/L
0.010 1
94 %
70.130 1
02/20/14 08:00 02/20/14 19:17 94-76-7
02/20/14 08:00 02/20/14 19:17 93-72.1
02/20/14 08:00 02/20/14 19:17 19719.28-9
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Leachate Method/Date: EPA 1311; 02/14/14 17:30
NO mg/L
0.050 1
0211711415:30 02/18/14 14:30
7440.38.2
NO mg1L
0.25 1
02117/1415:30 02/18/14 14:30
7440.39.3
NO mg/L
0.0050 1
02/17/1416:30 02/18/14 14:30
7440-43-9
NO mg/L
0,025 1
02/17/1415:30 02/18/14 14:30
7440-47-3
NO mg/L
0.026 1
02/17/14 15;30 02/1811414:30
7439-92-1
NO mg/L
0.10 1
02/17/14 15:30 02/18/14 14:30
7782-49.2
NO mg/L
0.025 1
02/17/14 15:30 02/18114 14:30
7440-22-4
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Leachate Method/Date: EPA 1311; 02/14/14 17:30
NO ug/L
0.20 1
02117/14 15:20 02/17/14 19:14
7439-07-6
Analytical Method: EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date: EPA
1311: 02/17/14 14:46
NO ug/L
50.0 1
02/18/14 10:00 02/19/14 13:32
108-46-7
NO ug/L
50.0 1
02/18/14 10:00 02/19/14 13:32
121-14-2
ND ug/L
60.0 1
02/18/14 10:00 02/19/14 13:32
87.68-3
NO ug/L
50.0 1
02/18/14 10:00 02/19/14 13:32
118.74-1
NO ug/L
50.0 1
02118/1410:00 02/19/14 13:32
67.72-1
NO ug/L
50.0 1
02/18/14 10:00 02/19/14 13:32
96 48-7
NO ug/L
50.0 1
02/18/14 10:00 02/19/14 13:32
NO ug/L
50.0 1
02/18/14 10:00 02/19/14 13:32
96-96.3
ND ug/L
100 1
02/18/14 10:00 02/19/14 13:32
87-88.5
NO ug/L
50,0 1
02/18/14 10:00 02/19/14 13:32
110-86.1
NO ug/L
50.0 1
02/18/14 10:00 02/19/14 13:32
05.95-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.,
Page 4 of 20

Af 'yt{ca' 0
-` r9 Vp
wJrvpacacela6scom
j
L --
Project: TCLP SLUDGE
Pace Project No.: 92189434
ANALYTICAL RESULTS
Pace Analytical Service@, Inc.
9800 Kincey Ave. Suite 100
Hunteraville, NO 28078
[phone]
Sample: TCLP Sludge
Lab ID: 92189434001 Collected: 02/10114 14:15
Received: 02/11/14 15:34 Matrix: Solid
Results reported on a "wet -weight" basis
Parameters
Results Units Report
Limit
DF
Prepared Analyzed
CAS No. 6ual
l
— _ 8270 MSSV TCLP Sep Funnel
Analytical Method: EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 02/17/14 14:45
2,4,6-Tdchlorophenol
ND ug/L
50.0
1
02/18/1410:00 02/19/14 13:32
88-06-2
Surrogates
Nitrobenzene-d5 (S)
46 %
12-102
1
02/1811410:00 02/19/14'13:32
4186.60.0
2-Fluorobiphenyl (8)
45 %
13.107
1
02118/1410:00 02/19/14 13:32
321-60-8
Terphenyl-d14 (S)
54 %
21-132
1
02(1S/1410:00 02/19/14 13:32
1716.51.0
Phenol-d6 (S)
26 %
10-110
1
02/18/14 10:00 02/19/14 13:32
13127.88-3
2-Fluorophenol(S)
33 %
10-110
1
02/18/14 10:00 02/19/14 13:32
367-12.4
2,4,8-Tribromophenoi (S)
53 %
27-108
1
02/18/1410:00 02/1911413:32
118-79-6
8260 MSV TCLP
Analytical Method: EPA 8260
Benzene
ND ug/L
5.0
1
02/20/14 12:13
71-43-2
f 2-Butanone (MEK)
49.2 ug/L
10.0
1
02/20/14 12:13
78-93.3
Carbon tetrachloride
ND ug/L
5.0
1
02/20/14 12:13
58-23.5
' Chlorobenzene
ND ug/L
5.0
1
02/20/14 12:13
108-90.7
Chloroform
ND ug/L
5.0
1
02/20/14 12:13
67-68.3
1,4-Dichlorobenzene
ND ug/L
5.0
1
02/2011412:13
10&48-7
1,2-Dichloroethane
ND ug/L
510
1
02/20/14 12:13
107-06.2
1,1-Dichloroethene
ND ug/L
5.0
1
0212011412:13
76-35.4
Tetrachloroethene
ND ug/L
5.0
1
02/20/14 12:13
.
127-18.4
Trichloroethene
ND ug/L
510
1
02/20/14 12:13
79-01.6
Vinyl chloride
Surrogates
ND ug/L
5.0
1
02/20/14 12:13
76.01.4
1,2-Dichloroethane-d4 (S)
_
92 %
70-130
1
02/20/14 12:13
17000-07-0
I Toluene-d8 (S)
97 %
67-135
1
02/20/14 12:13
2037-26.5
4-Bromofluorobenzene (S)
I
101
70.130
1
02/20/14 12:13
480-00-4
1010 Flash point, Closed Cup
Analytical Method: EPA 1010
Fiashpoint
>200 deg F
70.0
1
02125/14 01:36
Reactive Sulfide
Analytical Method: SW 846 7.3.4.2
Sulfide, Reactive
ND mglkg
100
1
02/21/14 16:00
9045 pH Soil
Analytical Method: EPA9045
pH at 25 Degrees C
6.8 Std. Units
0.10
1
02/12/14 10:45
733C S Reactive Cyanide
Analytical Method: SW-846 7.3.3.2
Cyanide, Reactive
ND mg/kg
0.050
1
02/20/14 16:28
Date: 02/26/2014 05:06 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 20

r
t
lace Analytical Services, Inc.
� ce An j4ical
t�
9800 Kincey Ave, Suite 100
— /f
tiwnipacola6s.com
I i � ela
Huntsrsviile, NC 26078
-
[phone]
QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No,: 92189434
L_. QC Batch: MERP/6180
Analysis Method: EPA 7470
QC Batch Method: EPA 7470
Analysis Description: 7470 Mercury TCLP
Associated Lab Samples: 92189434001
METHOD BLANK: 1138786
Matrix: Water
Associated Lab Samples: 92189434001
Blank Reporting
' Parameter Units
L-
Result Limit Analyzed Qualifers
Mercury ug/L
NO 0.20 02/17/1417:40
LABORATORY CONTROL SAMPLE: 1138787
Spike LCS LCS % Rec
f Parameter Units
Cone. Result % Rec Limits Qualifiers
Mercury ug/L
2.5 2.3 91 80-120
I MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1138788 1138789
MS MSD
92188842006 Spike Spike MS MSD MS MSD % Roo
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual _
Mercury ug/L NO 2,5 2,5 1.9 1.9 76 76 75-125 1
Date: 02/26/2014 05:06 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc -
Page 6 of 20

Pace Analytical Services, Inc.
1-58'CeAnalXical-
9800 Klncey Ave. Suite 100
rm
wwk:pacelabs.com
Huntersville, NC 26078
L'
[phone]
L
QUALITY CONTROL DATA
Project: TCLP SLUDGE
i
Pace Project No.: 92189434
-
QC Batch: MPRP/15245
Analysis Method: EPA 6010
QC Batch Method: EPA3010
Analysis Description: -6010 METTCLP
Associated Lab Samples: 92189434001
"
METHOD BLANK: 1138782
Matrix; Water
Associated Lab Samples: 92189434001
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Arsenic
mg/L
ND 0.050 02/18/1413:29
Barium
mg/L
NO 0.26 02118/1413:29
Cadmium
mg/L
NO 0.0050 02118/1413:29
Chromium
mg/L
NO 0,025 02/18/1413:29
Lead
mg/L
ND 0.025 02/18/1413:29
Selenium
mg/L
NO 0.10 02/18/1413:29
Silver
mg/L
ND 0,025 02118/1413:29
LABORATORY CONTROL SAMPLE: 1138783
r Arsenic
Barium
L Cadmium
Chromium
Lead
Selenium
Silver
Parameter Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Spike
LCS
Cone.
Result
2.5
2.5
2.5
2.4
2.5
2.4
2.5
2.4
2.5
2.3
2.5
2.6
1.2
1.2
LCS
% Rec
% Rec
Limits Qualifiers
101
80-120
94
80-120
95
80.120
97
80-120
91
80-120
105
80-120
100
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1138784
1138785
MS
MSD
92188842006
Spike .
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rao
Limits
RPD Qual
Arsenic
mg/L
NO
2.5
2.5
2.7
2.7
107
107
75-125
0
Barium
mg/L
0.64
2.5
2.5
3.0
3.0
94
95
75-125
1
Cadmium
mg/L
ND
2.5
2.5
2A
2.4
98
97
76-125
1
Chromium
mg/L
NO
2.5
2.5
2.5
2.5
99
100
76-125
1
Lead
mg/L
NO
2.5
2.5
2.4
2.4
96
95
75-125
1
Selenium
mg/L
ND
Is
2.5
2.6
2.7
105
109
75-126
4
Silver
mg&
NO
1.2
1.2
1.3
1.3
104
105
75.125
1
Date: 02/26/2014 05:06 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 7 of 20

1--'-Ac6Ana1Xica1"
/ wmpacelabstcm
i
QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92189434
QC Batch: MSV/25839 Analysis Method: EPA 8260
QC Batch Method: EPA 8260 Analysis Description: 8260 MSV TCLP
Associated Lab Samples: 92189434001
METHOD BLANK: 1140664 Matrix: Water
Associated Lab Samples: 92189434001
Parameter
1,1-Dichloreethene
1,2-Dichloroethane
1,4-Dichlorobenzene
` 2-Butanone (MEK)
Benzene
Carbon tetrachloride
Chlorobenzene
Chloroform
Tetrachloroethene
Trlchloroethene
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
Units
Blank
Result
Reporting
Limit
Analyzed Quallflers
ug/L
NO
5.0
02/20/14 04:47
ug/L
NO
6.0
02/20/14 04:47
ug/L
NO
5.0
02/20/14 04:47
ug/L
ND
10.0
02/20/14 04:47
u9t-
NO
5.0
02/20/14 04:47
ug/L
NO
5.0
02/20/14 04:47
ug/L
NO
5.0
02/20/14 04:47
ug/L
NO
5.0
02/20/14 04:47
ug/L
ND
5.0
02/20/14 04:47
ug/L
ND
5.0
02/20/14 04:47
ug/L
NO
6.0
02/20/14 04:47
%
91
70.130
02/20/14 04:47
%
99
70-130
02/20/14 04:47
%
96
67-135
02/20/14 04:47
LABORATORY CONTROL SAMPLE: 1140666
Pace Analyticai 3ervicec, Inc,
9800 Kincey Ave. Suite 100
Huntersvills, NC 26076
[phone]
Parameter
Units
Spike
Cone.
LCS
Result
LCS
% Roo
% Roo
Limits Qualiflors
1,1-01chloroethene
ug/L
50
49.0
98
70-141 -�
1,2-Dichloroethane
ug/L
50
47.9
96
70-139
1,4-Dichlorobenzene
ug/L
50
46.7
93
70-141
2-Butanone (MEK)
ug/L
100
90.1
90
63-150
Benzene
ug/L
50
51.8
104
70-132
Carbon tetrachloride
ug/L
50
52.6
105
70-150
Chlorobenzene
ug/L
50
49.3
99
70-134
Chloroform
ug/L
50
47.7
95
70-130
Tetrachloroethene
ug/L
50
49,0
98
70-137
Trichloroethene
ug/L
50
48.8
98
70.131
Vinyl chloride
ug/L
50
41.9
84
56.144
1,2-Dichloroethane-d4 (S)
87
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
99
67-135
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/26/2014 05:06 PM without the written consent of pace Analytical Services, Inc..
Page 8 of 20

r aceAnalXical
i
WV.-w.pacala6s.com
QUALITY CONTROL DATA
Paco Analytical ueervicon, Inc,
9800 Klncey Ave. Suita lo0
Huntersville, NC 28078
.[phone]
Project: TCLP SLUDGE
Pace Project No.: 92189434
QC Batch: 0EXT/25962
Analysis Method: EPA8081
QC Batch Method: EPA 3510
Analysis Description: 8081 GCS TCLP Pesticides
Associated Lab Samples: 92189434001
METHOD BLANK: 1139109
Matrix: Water
_ Associated Lab Samples: 92189434001
Blank Reporting
I_ Parameter
Units
Result Limit
Analyzed Qualifiers
Chlordane (Technical)
ug/L
NO i 3.0
02/18/14 23:30
Endrin
ug/L
NO 0.50
02/18/14 23:30
gamma-BHC (Lindane)
ug/L
NO 0.50
02/18/14 23:30
Heptachlor epoxide
ug/L
NO 0.50
02/18/14 23:30
Methoxychlor
ug/L
NO 1000
02/18/14 23:30
I Toxaphene
ug/L
NO 3.0
02/18/14 23:30
I Decachlorobiphenyl(S)
%
85 10-138
02/18/14 23:30
Tetrachloro-m-xylene (S)
%
87 10.110
02/18/14 23:30
LABORATORY CONTROL SAMPLE:
1139110
Spike
Parameter
Units
Cone.
Endrin
ug/L
1.2
gamma-BHC (Lindane)
ug/L
1.2
Heptachlor epoxide
ug/L
1.2
Methoxychlor
ug/L
3.7
Decachlorobiphenyl (S)
%
Tetrachloro-m-xylene (S)
%
LCS
LCS
% Rec
Result
% Rec
Limits Quallflero
1.2
98
20.134 -
1.1
87
20-118
1.0
82
22-133
NO
90
44-150
84
10-138
82
10-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1139111
1139112
{-
MS
MSD
92189719001
Spike
Spike
MS
MSD
MS
MSD
% Rec
- Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits RPD Qual
Endrin
ug/L
NO
1.2
1.2
1.1
1.1
89
91
21-133 1
gamma-BHC (Lindane)
ug/L
NO
1.2
1.2
1.1
0.99
86
80
24-110 7
Heptachlor epoxide
ug/L
NO
1.2
1.2
0.92
0.91
75
74
50-160 1
Methoxychlor
ug/L
NO
3.7
3.7
NO
NO
87
87
50-150
Decachlorobiphenyl (S)
%
76
72
10.138
Tetrachloro-m-xylene (S)
%
76
67
10-110
Date: 02/26/2014 05:06 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 20

i
Pace Analytical Senrlcaa, Inc.
aceAnalytical � 9800 KinceyAvo. Suite 10o
Huntersville, NC 28078
/' wv vpacela6s.ccm (704)875=9092
L
QUALITY CONTROL DATA
Project: TCLP SLUDGE
iPace Project No.: 92189434
QC Batch: OEXT/16183 Analysis Method: EPA 8151
QC Batch Method: EPA 3510 Analysis Description: 8161 GCS Herbicides TCLP
Associated Lab Samples: 92189434001
METHOD BLANK: 834513 Matrix: Water
Associated Lab Samples: 92189434001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
2,4,5-TP (Siivex) mg/L ND 0,010 02/20/14 18:16
2,4-D mg/L NO 0,010 02/20/1418:16
2,4-DCAA (S) % 92 70-130 02/20/14 18:16
LABORATORY CONTROL SAMPLE:
834514
i
Spike LCS LCS
% Rae
Parameter
Units
Cone, Result % Roe
Limits Qualifiers
2,4,5-7P (Siivex)
mg/L
.012 0.014 115
47-146
2,4-D
mg/L
.06 01066 110
50-130
_ 2,4-DCAA (S)
%
94
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
634521
834522
MS
MSD
92189434001
Spike
Spike
MS
MSD
MS
MSD
% Roo
Parameter Units
Result
Cone.
Cone.
Result
Result
% Roe
% Roo
Limits RPD Qual
2,4,5-TP (Siivex) mg/L
NO
.012
.012
0.015
0,014
124
117
47.146 6
2,4-D mg/L
NO
.06
.06
0.066
- 0.066
110
110
50-130 .2
2,4-DCAA (S) %
94
95
70-130
Date: 02/26/2014 05:06 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 20

1
ace Analytical
� vrc^,vpacelabs.eom
QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92189434
QC Batch: OEXT/25961 Analysis Method: EPA 8270
QC Batch Method: EPA 3510 Analysis Description: 8270 TCLP MSSV
Associated Lab Samples: 92189434001
METHOD BLANK: 1139018
Associated Lab Samples: 92189434001
Parameter Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed Qualifiers
1,4-Dichlorobenzene
ug/L
NO
50.0
02/18/14 17:40
2,4,5-Trchlorophenol
ug/L
ND
50.0
02/18/14 17:40
2,4,6-Trlchlorophenol
ug/L
NO
50.0
02/18/14 17:40
2,4-Dinitrotoluene
ug/L
NO
50.0
02/18/14 17:40
2-Methylphenol(o-Cresol)
ug/L
NO
50.0
02/1811417:40
3&4-Methylphenol(m&p Cresol)
ug/L
NO
50.0
02118/1417:40
Hexachloro-1,3-butadiene
ug/L
NO
50.0
02/18/14 17:40
Hexachlorobenzene
ug/L
NO
50.0
02/18/14 17:40
Hexachloroethane
ug/L
ND
50.0
02/18/14 17:40
Nitrobenzene
ug/L
NO
50.0
02/18/14 17:40
Pentachlorophenol
ug/L
ND
100
02/18/1417:40
Pyridine
ug/L
NO
60.0
02/18/14 17:40
2,4,6-Tdbromophenol (S)
%
85
27-108
02/18/14 17:40
2-Fluorobiphenyl (S)
%
83
13-107
02/18/14 17:40
2-Fluorophenol (S)
%
49
10-110
02/18/14 17:40
Nitrobenzene-d5 (S)
%
69
12-102
02/18/14 17:40
Phenol-d6 (8)
%
36
10-110
02/18/14 17:40
Terphenyi-d14 (S)
%
113
21-132
02/18/14 17:40
Pace Analytical Services, Inc.
9800 Kincoy Ave. Suite 100
Huntersvllle, NO 28078
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
1139019
Units
Spike
Cone.
LCS
Result
LCS
% Rec
% Rec
Limits Qualiflors
1,4-Dichlorobenzene
ug/L
500
388
74
10-110
2,4,5-Trlchlorophenol
ug/L
500
444
89
39.108
2,4,6-Trlchlorophenol
ug/L
500
420
84
40.104
2,4-Dinitrotoluene
ug/L
500
473
95
42-109
2-Methylphenol(o-Cresol)
ug/L
500
393
79
31-110
3&4-Methylphenol(m&p Cresol)
ug/L
500
366
73
30-110
Hexachloro-1,3-butadiene
ug/L
500
363
73
10-110
Hexachlorobenzene
ug/L
500
427
85
39-121
Hexachloroethane
ug/L
500
341
68
10-110
Nitrobenzene
ug/L
500
458
92
32-101
Pentachlorophenol
ug/L
1000
B84
88
18-108
Pyridine
ug/L
500
212
42
10-110
2,4,6-Tribromophenol (S)
%
107
27.108
2-Fluorobiphenyl (S)
%
90
13-107
2-Fluorophenol(S)
%
58
10-110
Nitrobenzene-d5 (S)
%
86
12-102
Phenol-d6 (S)
%
43
10-110
Terphenyi-d14 (S)
%
106
21-132
Date: 02/26/2014 05:06 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 11 of 20

_
Pace Analytical
Services, Ina,
;a'.ccein Analj4ical e
9800 KlnceyAve. Suits 100
-
i mww.pacelabs.cam
Hunteraville, NC 2807a
r`
[phone]
QUALITY CONTROL DATA
Project: TCLP SLUDGE
i Pace Project No.: 92189434
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1139020
1139021
MS
MSD
92189722001
Spike
Spike
MS
MSD
MS
MSD
% Roe
Parameter
Units
Result
Cone.
Cone,
Result
Result
% Roe
% Roe
Limits
RPD Qual
1,4-Dichlorobenzene
ug/L
ND
500
600
327
352
65
70
30.150
—7
2,4,5-Trichlorophenol
ug/L
ND
500
500
432
420
86
84
30.150
3
2,4,6-Trichlorophenol
ug/L
ND
500
500
394
386
79
77
30.150
2
2-Methyiphenol(o-Cresol)
ug/L
ND
500
500
344
344
69
69
30-150
0
3&4-Methyiphenol(m&p
ug/L
ND
500
500
348
313
69
83
30-150
10
Cresol)
Hexachloro-1,3-butadiene
ug/L
ND
500
500
312
362
62
72
30-150
15
Hexachloro benzene
ug/L
ND
500
500
405
359
81
72
30-150
12
Hexachloroethane
ug/L
ND
500
500
343
339
69
68
30.150
1
Nitrobenzene
ug/L
ND
500
500
407
428
81
88
30-150
5
- Pentachlorophenol
ug/L
ND
1000
1000
869
845
87
85
30.180
3
i Pyridine
ug/L
ND
500
500
242
264
48
51
30-160
5
2,4,6-Tdbromophenol (S)
%
100
92
27-108
2-Fluorobiphenyl (S)
%
78
79
13-107
I 2-Fluorophenol (S)
%
57
60
10-110
i Nitrobenzene-d5 (S)
%
75
79
12-102
Phenol-d6 (S)
%
41
42
10-110
Terphenyi-d14 (S)
I
%
93
89
21.132
i_
A
Date: 02/26/2014 05:06 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 20

f
Pace Analytical Services, Inc.
a 16Analytical a 9800 Kincey Ave. Suite 100
Huntcraville, NC 28078
mv+r pacela6s.com [phone]
i
QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92189434
�- QC Batch: WET/29675 Analysis Method: EPA 1010
QC Batch Method: EPA 1010 Analysis Description: 1010 Flash Point, Closed Cup
Associated Lab Samples: 92189434001
SAMPLE DUPLICATE: 1144182
92188252001 Dup
Parameter Units Result Result RPD Qualifiers
Flashpoint deg F >200 >200
Date: 02/26/2014 05:06 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in -full,
without the written consent or Pace Analytical Services, Inc..
Page 13 of 20

aceAnalXical
Www.pacelabs.aom
Pace Analytical Service&, Inc.
5800 Kincey Ave, Suite 100
Huntersvills, NC 26078
[phone]
QUALITY CONTROL, DATA
Project: TCLP SLUDGE
Pace Project No.: 92189434
i
QC Batch: WET/46226
Analysis Method: SW-846 7.3.4.2
QC Batch Method: SW-846 7.3.4.2
Analysis Description: Reactive Sulfide
Associated Lab Samples: 92189434001
METHOD BLANK: 1332307
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Sulfide, Reactive mg/kg
I
NO 100 02/21/14 16:00
LABORATORY CONTROL SAMPLE: 1332308
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualiflera
Sulfide, Reactive mg/kg
200 187 93 77-110
SAMPLE DUPLICATE: 1332310
92189434001 Dup
Parameter Units Result Result RPD Qualifiers
Sulfide, Reactive mg/kg NO NO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/26/2014 05:06 PM without the written consent of Pace Analytical Services, Inc..
Page 14 of 20

�PaceAnalytical
mmpacelabs.com
QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92189434
QC Batch: WET/29498 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92189434001
SAMPLE DUPLICATE: 1137178
92189434001 Dup
Parameter Units Result Result RPD Qualifiers
pH at 25 Degrees C Std. Units 6.8 6.8 0
Date: 02/26/2014 05:06 PM -
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in Tull,
without the written consent or Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave, Suite 100
Huntaravllle, NC 28078
(704)1375.9092
Page 15 of 20

:r
.. ,ice Analytical
j
wmpace;abs.com
- I
QUALITY CONTROL DATA
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Hunteravillo, NC 28078
(704)876=9092
Project: TCLP SLUDGE
Pace Project No.: 92189434
QC Batch: WETA/28257
Analysis Method:
SW 846 7.3.3.2
QC Batch Method: SW-846 7.3.3.2
Analysis Description:
733C Reactive Cyanide
Associated Lab Samples: 92189434001
METHOD BLANK: 1332314
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Cyanide, Reactive
mg/kg
ND 0,050 02/20/14 16:21
LABORATORY CONTROL SAMPLE:
1332315
Spike LCS
LCS
% Rea
Parameter
Units
Cone, Result
% Rea
Limits Qualifiers
- Cyanide, Reactive
mg/kg
.5 0.44
88
71-123
MATRIX SPIKE SAMPLE:
1332316
60162779005 Spike
MS
MS % Roe
Parameter
Units
Result Cone.
Result
% Roe Llmita Qualifiers
l Cyanide, Reactive
mg/kg
ND 15
0,46
92 57-132
SAMPLE DUPLICATE: 1332317
60162779005 Dup
Parameter
Units
Result Result
RPD
Qualifiers
Cyanide, Reactive
mg/kg
ND ND
Date: 02/26/2014 05:06 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 16 of 20

Z!ZAnalXicalo
xmmpacelabs.corn
QUALIFIERS
PaceAnelyticel Services, Inc,
9800 Klncey Ave. Suite 100
Hunteravillo, NC 28078
[phone]
Project: TCLP SLUDGE
Pace Project No.: 92189434
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit,
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values,
-, LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270, The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PAST -A Pace Analytical Services -Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-K Pace Analytical Services - Kansas City
PASI-0 Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
Date: 02/26/2014 05:06 PM without the written consent of Pace Analytical Services, Inc_
Page 17 of 20

aceAnalytical o
i
mvel.pacelabsxom
r
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: TCLP SLUDGE
Pace Project No.: 92189434
Pace Analytical Services, Inc.
9800 Klncey Ave. Suite 100
Huntersviile, NC 28078
[phone]
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92189434001
TCLP Sludge
EPA 3510
OEXT/25962
EPA 8081
GCSV/16695
92189434001
TCLP Sludge
EPA 3510
OEXT/16183
EPA 8151
GCSV/10669
92189434001
TCLP Sludge
EPA 3010
MPRP/15245
EPA 6010
ICP/13833
92189434001
TCLP Sludge
EPA 7470
MERP/6180
EPA 7470
MERC/5964
92189434001
TCLP Sludge
EPA 3510
0EXT125961
EPA 8270
MSSV/8760
92189434001
TCLP Sludge
EPA 8260
MSV/25839
92189434001
TCLP Sludge
EPA 1010
WET129675
92189434001
TCLP Sludge
SW-846 7.3.4.2
WET/46226
92189434001
TCLP Sludge
EPA 9045
WET/29498
92189434001
TCLP Sludge
SW 846 7.3.3.2
WETA/28257
Date: 02/26/2014 05:06 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.,
Page 18 of 20

Document Name:
'�rra:inall�tical Sample Condition Upon Race
Document Number:
F-CHR-CS-03-revl
Client name:
UUCUIIIE'1Il r\1=VIa0U. 61e,W�111VV- —, .. —
Page 1 of 2
-� Issuin® Authority.
Pace Huntersville Quality Office
Courier: ❑ Fed Ex [IUPS❑ USPS❑ Client❑ Commercial❑ `_a.e Otfter__ _,
Custody Seal on Cooler/Box Present: ❑ yes o Seals Intact: ❑ yes ❑ no
❑ BubEa s ❑ None Other _
o tional
Proj=.Du®-Date:
P;r'o}::•flame,. _
Packing Material: ❑ Bubble Wrap to
Thermometer Used: IR Gun T1102 TO Type of Ice: FR
Blue None ❑( Samples on Ice, cooling process has begun
Temp Correction Factor T1102: No Correction T1301: No Correction pate and Initials of p rsogoxamining
Yes :NoNIA Corrected Cooler Temp.: L- -C Biological Tissue Is Frozen:contents: Le
Temp should be above freezing to Fi°C Comments:
Chain of Custody Present: -,{3-Ire-s ❑No ❑NIA 1.
Chain of Custody Filled- Out: es ONO ❑NIA 12,
_ _-.�.9_ampjeLNam0
A Signature on COC:_ _-2< ONO ❑NIA 4,
Samples Arrived within Hold Time: ONO ®NIA 5,
Short Hold Time Analysis (<72hr): ❑Yes ,PNS- ❑NIA 0.
Rush Turn Around Time Requested: ❑yes ,.ONe ❑NIA tT
Sufficient Volume: ❑yes fr3No ❑NIA 8.
Correct Containers Used: —DYes ONo ❑N/A 9. �,o qpI 'i V'
-Pace Containers Used: wee ONO ❑NIA
Containers Intact: esONo ®N/A 10.
Oyes ONO ©t'i/a 11,
Filtered volume received for Dissolved tests
Sample Labels match COC: ,I� es ONO t�N1A 12.
��' `Ir�t
/�
-Includes date/time/ID/Analysis Matrix:
_
All containers needing preservation have been checked. oyes ONO - /A 13,
All containers needing preservation are found to be In Dyes ONo A
compliance with EPA recommendation,
exceptlons: VOA, conform, TOC, O&G, WI-DRO (water) yes ONO
Samples checked for dechlorination: es []No ❑NIA 14,
Heads ace in VOA Vials (>6mm): Oyer 6`ONIA 15.
[Dyes ONO 00 16'.
Trip Blank Present:
Trip Blank Custody Seals Present ❑yea ONO
Pace Trip Blank Lot # (if purchased): -
Field Data Required? Y 1 N
Client Notification/ Resolution:
Person Contacted: Date/T)me:
Comments/ Resolution:
..r�_alare lahel_h0re
SCURF Review:Date: 1 '., ®...!�
�+ tl
SRF Review' ICJ Date: +�=Wr0,�'.'-�9!``-1-894�i,
Note: Whenever there is a discrepancy affecting North Carolina compliance
_ samples, a ropy of this form will be sent to the North Carolina DEHNR i .,IIIII�IIIII I
Certification Office (Lout of teme out of hold, Incorrect preservative, p,
incorrect containers) ��;___ _r•i�:�
Page 19 of 20

FaceAnalytical'
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CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All retewnl fields must be completed accuratoly.
Section A Section B
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ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO058505
Laboratory 1 Environmental
Conservation
Laboratory 2
Sample or CompositeDate 10/28/2014
Parameter (mg/Kg)' Class A Clas B
Aluminum
N/A
N/A
4,280
Ammonia Nitrogen
N/A
N/A
6,700
Arsenic
41
75
5.51
Cadmium
39
85
0.529
Calcium
N/A
N/A
40,700
Copper
1,500
4,300
267
Lead
300
840
14.1
Magnesium
N/A
N/A
7,290
Mercury
17
57
0.38
Molybdenum
N/A
75
5.95
Nickel
420
420
19.8
Nitrate -Nitrite Nitrogen
N/A
N/A
210
Percent Solids
N/A
N/A
1.80
PH (no units)
N/A
N/A
7.70
Phosphorus
N/A
N/A
2,600
Potassium
N/A
N/A
2,930
PAN (Inj./Inc.)
N/A
N/A
6,670
PAN (Surface)
N/A
N/A
3,320
Selenium
100
100
5.51
Sodium
N/A
N/A
39,100
SAR
N/A
N/A
6.27
TKN
N/A
N/A
5,900
Zinc
2,800
7,500
1500
Source Name Mallard Crossing W WTP
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations"
/4-C-M 02-14-2015
Signature of Prepater * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

i '-
FIELD LOADING ESTIMATES .
Facility Mallard Crossing VAVI?
Sampling Date 10/28/2014
% Solids 1.8
Mineralization Rate 0.3
Gallons per DT 13,322.68
PH 7.7
Sodium Absorpotion 6.27 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land .apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 5,900 lbs./1,000 gal 0.89
Potassium lbs./1,000 gal
0.44
Ammonia Nitrogen (mg/Kg) 6,700.00 lbs./1,000 gal 1.01
Phosphorus lbs./1,000 gal
0.39
Nitrate -Nitrite (mg/Kg) 210.00 lbs./1,000 gal 0.03
Calcium lbs./1,000 gal
6.11
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
1.09
PAN (mg/Kg) 3,320 lbs./1,000 gal 0.50
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 6,670 lbs./1,000 gal 1.00
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
'Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
5.51
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.53
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
267.00
Copper lbs./1,000 gal
0.04
Lead (mg/Kg)
14.10
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.38
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
19.80
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
5.51
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
1500.00
Zinc lbs./1,000 gal
0.23
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
5,900
3,320
6.64
2,580
5,900
6,670 13.34
-770
2,580
387
0.77
2,193
-770
-116 -0.23
-655
2,193
164
0.33
2,029
-655
-49 -0.10
-605
2,029
76
0.15
1,952
-605
-23 -0.05
-583
1,952
37
0.07
1,916
-583 .
-11 -0.02
-572
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 3,984 7.97
Total 6,472 12.94

�co9
www.encolabs.com
SAMPLE DETECTION SUMMARY
Client ID: Mallards Sludge
Lab ID:
C413811-01
Analvtg
Results
Flo
MU
E"
Units
Method Notes
% Solids
1.8
0.1
0.1
% by Weight
% Solids
Aluminum - Total
4280
116
551
mg/kg dry
EPA 6010C
Ammonia as N
6700
D
220
480
mg/kg dry
EPA 350.1
Calcium - Total
40700
B
308
1380
mg/kg dry
EPA 6010C QB-01
Copper - Total
267
10.5
27.5
mg/kg dry
EPA 6010C
Lead - Total
14.1
3
6.61
27.5
mg/kg dry
EPA 6010C
Magnesium - Total
7290
B
35.8
1380
mg/kg dry
EPA 6010C QB-01
Molybdenum - Total
5.95
J
5.51
27.5
mg/kg dry
EPA 6010C
pH
7.7
1.0
1.0
pH Units
EPA 9045D
Potassium - Total
2930
220
1380
mg/kg dry
EPA 6010C
Sodium - Total
39100
330
1380
mg/kg dry
EPA 6010C
Total Kjeldahl Nitrogen
5900
D
2300
2600
mg/kg dry
EPA 351.2
Total Solids
1.8
0.0010
0.0010
% by Weight
SM 2540G-1997
Zinc - Total
1500
60.6
138
mg/kg dry
EPA 6010C
Client ID: Mallards Sludge
Lab ID:
C413811-01RE1
Analft
Jtesults
Flag
MM
P_41.
Units
Method Notes
Phosphorus
2600
D
62
170
mg/kg dry
EPA 365.4
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 3 of 11

www.encolabs.com
ANALYTICAL RESULTS
Description: Mallards Sludge Lab Sample ID:C413811-01 Received: 10/28/14 12:50
L Matrix: Sludge - Sampled:10/28/14 10:05 Work Order: C413811
Project: Mallards -Annual Sludge Analysis Sampled By: Otis Fields % Solids: 1.82
I
Metals by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte WAS Numberl Results
Fla3
Units
RE
MU
PQ.L
Batch
Method
Analyzed
py Notes
Aluminum [7429-90-5]A
4280
mg/kg dry
1
116
551
4KO5014
EPA 6010C
11/07/14 13:14
JDH
Arsenic [7440-38-2]A
< 5.51
mg/kg dry
1
5.51
27.5
4KO5014
EPA 6010C
11/07/14 13:14
JDH
Cadmium [7440-43-9]A
< 0.529
mg/kg dry
1
0.529
2.75
4KO5014
EPA 6010C
11/07/14 13:14
JDH
Calcium [7440-70-2]A
40700
B
mg/kg dry
1
308
1380
4KO5014
EPA 6010C
11/07/14 13:14
JDH QB-01
Copper [7440-50-8]A
267
mg/kg dry
1
10.5
27.5
4KO5014
EPA 6010C
11/07/14 13:14
JDH
Lead [7439-92-1]A
14.1
J
mg/kg dry
1
6.61
27.5
4KO5014
EPA 6010C
11/07/14 13:14
JDH
Magnesium [7439-95-4]A
7290
B
mg/kg dry
1
35.8
1380
4KO5014
EPA 6010C
11/07/14 13:14
JDH QB-01
Mercury [7439-97-6]A
< 0.380
mg/kg dry
1
0.380
1.32
4KO4012
EPA 7471B
11/04/14 17:55
T1D
Molybdenum [7439-98-7]A
5.95
J
mg/kg dry
1
5.51
27.5
4KO5014
EPA 6010C
11/07/14 13:14
JDH
Nickel[7440-02-0]A
< 19.8
mg/kg dry
1
19.8
138
4KO5014
EPA 6010C
11/07/14 13:14
JDH
Potassium [7440-09-7]A
2930
mg/kg dry
1
220
1380
4KO5014
EPA 6010C
11/07/14 13:14
JDH
Selenium [7782-49-2]A
< 5.51
mg/kg dry
1
5.51
27.5
4KO5014
EPA 6010C
11/07/14 13:14
JDH
Sodium [7440-23-5]A
39100
mg/kg dry
1
330
1380
4KO5014
EPA 6010C
11/07/14 13:14
JDH
Zinc[7440-66-6]A
1500
mg/kg dry
1
60.6
138
4KO5014
EPA 6010C
11/07/14 13:14
JDH
Classical Chemistry Parameters
Analyte rCAS Numberl
Results
Elm
Units
RE
MDL
M
Batch
Method
Analyzed
ft Notes
Solids
1.8
% by Weight
1
0.1
0.1
4KO3019
% Solids
10/31/14 16:01
MMR
Ammonia as N [7564-41-7]
6700
D
mg/kg dry
90
220
480
4329005
EPA 350.1
10/30/14 09:56
SHA
Nitrate/Nitrite as N
< 210
D
mg/kg dry
97.5
210
520
4KO4005
EPA 353.2
11/04/14 13:18
SHA R-01
pH
7.7
pH Units
1
1.0
1.0
4329031
EPA 9045D
10/29/14 13:52
MMR
Phosphorus[7723-14-0]
2600
D
mg/kg dry
32
62
170
4331009
EPA 365.4
11/03/14 14:59
c1V
Total Kjeldahl Nitrogen
5900
D
mg/kg dry
100
2300
2600
4331008
EPA 351.2
11/03/14 11:55
c1V
Total Solids
1.8
% by Weight
1
0.0010
0.0010
4131024
SM 254OG-1997
10/31/14 16:01
MMR
i
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 11

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO043257
Laboratory 1 Environmental
Conservation
Laboratory 2
Sample or CompositeDate 11/24/2014
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
4,360
Ammonia Nitrogen
N/A
N/A
4,400
Arsenic
41
75
10.3
Cadmium
39
85
1.69
Calcium
N/A
N/A
12,900
Copper
1,500
4,300
79.6
Lead
300
840
8.86
Magnesium
N/A
N/A
4,430
Mercury
17
57
0.373
Molybdenum
N/A
75
7.39
Nickel
420
420
26.6
Nitrate -Nitrite Nitrogen
N/A
N/A
5
Percent Solids
N/A
N/A
1.40
PH (no units)
N/A
N/A
6.70
Phosphorus
N/A
N/A
21,000
Potassium
N/A
N/A
7,620
PAN (Inj./Inc.)
N/A
N/A
28,585
PAN (Surface)
N/A
N/A
26,385
Selenium
100
100
17.8
Sodium
N/A
N/A
9,910
SAR
N/A
N/A
2.26
TKN
N/A
N/A
85,000
Zinc
2,800
7,500
829
Source Name Nature Trails MHP W WTP
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

F,_
Li
FIELD LOADING ESTIMATES
Facility Nature Trails MHP WW'I'P
Sampling Date 11/24/2014
% Solids 1.4
Mineralization Rate 0.3
Gallons per DT 17,129.15
PH 6.7
Sodium Absorpotion 2.26 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 85,000 lbs./1,000 gal 9.92
Potassium lbs./1,000 gal
0.89 .
Ammonia Nitrogen (mg/Kg) 4,400.00 lbs./1,000 gal 0.51
Phosphorus lbs./1,000 gal
2.45
Nitrate -Nitrite (mg/Kg) 4.90 lbs./1,000 gal 0.00
Calcium lbs./1,000 gal
1.51
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.52
PAN (mg/Kg) 26,385 lbs./1,000 gal 3.08
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 28,585 lbs./1,000 gal 3.34
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
21800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
10.30
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.69
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
79.60
Copper lbs./1,000 gal
0.01
Lead (mg/Kg)
8.86
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.37
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
26.60
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
17.80
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
829.00
Zinc lbs./1,000 gal
0.10
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
TEN
PAN
PAN
Nitrogen
TEN
PAN PAN
Nitrogen
(mg/kg) (lbs/DT)
(mg/]Kg)
(mg/kg) (lbs/DT)
(mg/Eg)
85,000
26,385
52.77
58,615
85,000
28,585 57.17
56,415
58,615
8,792
17.58
49,823
56,415
8,462 16.92
47,953
49,823
3,737
7.47
46,086
47,953
3,596 7.19
44,356
46,086
1,728
3.46
44,358
44,356
1,663 3.33
42,693
44,358
832
1.66
43,526
42,693
800 1.60
41,893
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yi PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
1 Oral 41,474 Z5Z.95
Total 43,107 86.21

www.encolabs.com
SAMPLE DETECTION SUMMARY
Client ID: Natures Trail Sludge
Lab ID: C404078-01
Analvte
Results
flan
MPS
M
Units
Method
Notes
% Solids
1.4
0.1
0.1
% by Weight
% Solids
Aluminum - Total
4360
155
739
mg/kg dry
EPA 6010C
Ammonia as N
4400
D
170
370
mg/kg dry
EPA 350.1
Arsenic - Total
10.3
]B
7.39
36.9
mg/kg dry
EPA 6010C
QB-01
Cadmium - Total
1.69
1B
0.709
3.69
mg/kg dry
EPA 6010C
QB-01
Calcium - Total
12900
B
414
1850
mg/kg dry
EPA 6010C
QB-01
Copper - Total
79.6
14.0
36.9
mg/kg dry
EPA 6010C
Magnesium - Total
4430
B
48.0
1850
mg/kg dry
EPA 6010C
QB-01
Nitrate/Nitrite as N
4.9
]B
2.9
7.1
mg/kg dry
EPA 353.2
QB-01
pH
6.7
1.0
1.0
pH Units
EPA 9045D
Phosphorus
21000
D
360
1400
mg/kg dry
EPA 365.4
Potassium - Total
7620
295
1850
mg/kg dry
EPA 6010C
Selenium - Total
17.8
1
7.39
36.9
mg/kg dry
EPA 6010C
Sodium - Total
9910
443
1850
mg/kg dry
EPA 6010C
Total Kjeldahl Nitrogen
85000
D
1900
3400
mg/kg dry
EPA 351.2
Total Solids
1.4
0.0010
0.0010
% by Weight
SM 2540G-1997
Zinc - Total
829
81.2
185
mg/kg dry
EPA 6010C
L,I
I i
l
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 11

www.encolabs.com
Vi
ANALYTICAL RESULTS
i
Description: Natures Trail Sludge Lab Sample ID:C404078-01 Received: 11/24/14 10:30
Matrix: Sludge Sampled:11/24/14 09:30 Work Order: C404078
_I Project: Natures Trail -Annual Sludge Analysis Sampled By: Pete Saulsbury % Solids: 1.35
(Metals by EPA 6000/7000 Series Methods
- ^ - ENCO Cary certified analyte [NC 591]
Analvte [CAS Numberl
Results
Rn
1111b
RE
MOIL
EQ6
Batch
Method
Analyzed
ft
Notes
v Aluminum [7429-90-5]^
4360
mg/kg dry
1
155
739
4L08032
EPA 6010C
12/09/14 13:58
JDH
Arsenic [7440-38-2]^
10.3
JB
mg/kg dry
1
7.39
36.9
4L0B032
EPA 6010C
12/09/14 13:58
JDH
QB-01
Cadmium [7440-43-9]^
1.69
JB
mg/kg dry
1
0.709
3.69
4L08032
EPA 6010C
12/09/14 13:58
JDH
QB-01
Calcium [7440-70-2]^
12900
B
mg/kg dry
1
414
1850
4L08032
EPA 6010C
12/09/14 13:58
JDH
QB-01
1 Copper[744O-50-8]^
79.6
mg/kg dry
1
14.0
36.9
4L08032
EPA 6010C
12/09/14 13:58
JDH
Lead [7439-92-1]^
< 8.86
mg/kg dry
1
8.86
36.9
4L0B032
EPA 6010C
12/09/14 13:58
JDH
Magnesium [7439-95-4]^
4430
B
mg/kg dry
1
48.0
1850
4L08032
EPA 6010C
12/09/14 13:58
JDH
QB-01
Mercury [7439-97-6]^
< 0.373
mg/kg dry
1
0.373
1.30
4L01012
EPA 7471E
12/02/14 13:11
T11)
Molybdenum [7439-98-7]^
< 7.39
mg/kg dry
1
7.39
36.9
4L08032
EPA 6010C
12/09/14 13:58
JDH
�I Nickel[7440-02-O]^
< 26.6
mg/kg dry
1
26.6
185
4L08032
EPA 6010C
12/09/14 13:58
JDH
Potassium [7440-09-7]^
7620
mg/kg dry
1
295
1850
4L0B032
EPA 6010C
12/09/14 13:58
JDH
Selenium [7782-49-2]^
17.8
J
mg/kg dry
1
7.39
36.9
4L08032
EPA 6010C
12/09/14 13:58
JDH
Sodium [7440-23-5]^
9910
mg/kg dry
1
443
1850
4L08032
EPA 6010C
12/09/14 13:58
JDH
Zinc [7440-66-6]^
829
mg/kg dry
1
81.2
185
4L08032
EPA 6010C
12/09/14 13:58
JDH
Classical Chemistry Parameters
Analvte rCAS Numberl
Results
Fig
Units
DF
MU
POL
Batch
Method
Analyzed
)ly
Notes
_ % Solids
1.4
% by
1
0.1
0.1
41<25046
% Solids
11/25/14 14:24
MMR
Weight
Ammonia as N [7664-41-7] •
^i
4400
D
mg/kg'dry
51.43
170
370
4LOS028
EPA 350.1
12/09/14 09:59
SHA
Nitrate/Nitrite as N
4.9
JB
mg/kg dry
1
2.9
7.1
4L04004
EPA 353.2 ,
12/04/14 16:30
A78
QB-01
-� pH
6.7
pH Units
1
1.0
1.0
41(25056
EPA 9045D
11/25/14 16:01
MKS
Phosphorus [7723-14-0]
21000
D
mg/kg dry
200
360
1400
4L05013
EPA 365.4
12/08/14 12:58
SHA
�I Total Kjeldahl Nitrogen
85000
D
mg/kg dry
100
1900
3400
4L05012
EPA 351.2
12/08/14 11:25
SHA
Total Solids
1.4
% by
1
0.0010
0.0010
4K25045
SM 2540G-1997
11/25/14 14:24
MMR
_
Weight
9
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 11

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO064564 Source Name Neuse Colony WWTP
Laboratory 1 Environmental
Conservation
Laboratory 2
Sample or CompositeDate 11/4/2014
Parameter (mg/Kg) Class A Clas B
Aluminum
. N/A
N/A
3,480
Ammonia Nitrogen
N/A
N/A
130
Arsenic
41
75
32.7
Cadmium
39
85
1.71
Calcium
N/A
N/A.
21,700
Copper
1,500
4,300
155
Lead
.300
840
23.2
Magnesium
N/A
N/A
3,990
Mercury
17
57
1.05
Molybdenum
N/A
75
17.8
Nickel
420
420
64
Nitrate -Nitrite Nitrogen
N/A
N/A
3,100
Percent Solids
N/A
N/A
0.60
pH (no units)
N/A
N/A
7.10
Phosphorus
N/A
N/A
38,000
Potassium
N/A
N/A
5,630
PAN (Inj./Inc.)
N/A
N/A
25,391
PAN (Surface)
N/A
N/A
25,326
Selenium
100
100
17.8
Sodium
N/A
N/A
23,800
SAR
N/A
N/A
3.01
TKN
N/A
N/A
74,000
Zinc
2,800
7,500
1110
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
0-81- 02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

FIELD LOADING ESTIMATES
Facility Neuse Colony WWTP
Sampling Date 11/4/2014
% Solids 0.6
Mineralization Rate 0.3
Gallons per DT 39,968.03
pH 7.1
Sodium Absorpotion 3.01 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 74,000 lbs./1,000_ gal 3.70
Ammonia Nitrogen (mg/Kg) 130.00 lbs./1,000 gal 0.01
Nitrate -Nitrite (mg/Kg) 3,100.00 lbs./1,000 gal 0.16
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 25,326 lbs./1,000 gal 1.27
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 25,391 lbs./1,000 gal 1.27
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Limits (mg/Kg)
41
39
1,500
300
17
J
1st Year
2nd Year
3rd Year
4th Year
5th Year
Class B Ceiling
Limits (mg/Kg)
75
85
HEAVY METAL CONCENTRATION
Potassium lbs./1,000 gal 0.28
Phosphorus lbs./1,000 gal 1.90
Calcium lbs./1,000 gal 1.09
Magnesium lbs./1,000 gal 0.20
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
32.70
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.71
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
155.00
Copper lbs./1,000 gal
0.01
Lead (mg/Kg)
23.20
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
1.05
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
64.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
17.80
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
1110.00
Zinc lbs./1,000 gal
0.06
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
74,000
25,326
50.65
48,674
74,000
25,391 50.78
48,609
48,674
7,301
14.60
41,373
48,609
7,291 14.58
41,318
41,373
3,103
6.21
38,270
41,318
3,099 6.20
38,219
38,270
1,435
2.87
36,835
38,219
1,433 2.87
36,786
36,835
691
1.38
36,144
36,786
690 1.38
36,096
Equations
1 st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 37,856 75.71
Total 37,904 75.81

www.encolabs.com
SAMPLE DETECTION SUMMARY
Client ID: Neuse Colony Sludge
Lab ID: C413812-01
Analvte
Results
Flafl
MAL
EQL
Units
Method Notes
% Solids
0.6
0.1
0.1
% by Weight
% Solids
Aluminum - Total
3480
373
1780
mg/kg dry
EPA 6010C
Ammonia as N
130
8.0
18
mg/kg dry
EPA 350.1
Arsenic - Total
32.7
3
17.8
88.9
mg/kg dry
EPA 6010C
Calcium -Total
21700
B
995
4440
mg/kg dry
EPA 6010C QB-01
Copper - Total
155
33.8
88.9
mg/kg dry
EPA 6010C
Lead - Total
23.2
J
21.3
88.9
mg/kg dry
EPA 6010C
Magnesium - Total
3990
]B
116
4440
mg/kg dry
EPA 6010C 1-01
Nitrate/Nitrite as N
3100
D
710
1700
mg/kg dry
EPA 353.2
PH
7.1
1.0
1.0
pH Units
EPA 9045D
Phosphorus
38000
D
890
3500
mg/kg dry
EPA 365.4
Potassium - Total
5630
711
4440
mg/kg dry
EPA 6010C
Sodium - Total
23800
1070
4440
mg/kg dry
EPA 6010C
Total Kjeldahl Nitrogen
74000
D
4600
8500
mg/kg dry
EPA 351.2
Total Solids
0.56
0.0010
0.0010
% by Weight
. SM 2540G-1997
Zinc - Total
1110
196
444
mg/kg dry
EPA 6010C
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 10

(9m" 9OL)
www.encolabs.com
ANALYTICAL RESULTS
Description: Neuse Colony Sludge Lab Sample ID:C413812-01 Received: 11/04/14 13:00
Matrix: Sludge Sampled:11/04/14 09:50 Work Order: C413812
Project: Neuse Colony -Annual Sludge Analysis Sampled By: Van Gurley % Solids: 0.56
LMetals by EPA 6000/7000 Series Methods
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
EIg9
Units
AE
MDL
POL
Batch
Method
Analyzed
Note@
Aluminum [7429-90-5]^
3480
mg/kg dry
1
373
1780
4KO5014
EPA 6010C
11/07/14 13:16
JDH
Arsenic [7440-38-2]^
32.7
J
mg/kg dry
1
17.8
88.9
4KO5014
EPA 6010C
11/07/14 13:16
JDH
Cadmium [7440-43-9]^
< 1.71
mg/kg dry
1
1.71
8.89
4KO5014
EPA 6010C
11/07/14 13:16
JDH
Calcium [7440-70-2]^
21700
B
mg/kg dry
1
995
4440
4KO5014
EPA 6010C
11/07/14 13:16
JDH QB-01
Copper[7440-50-8]^
155
mg/kg dry
1
33.8
88.9
4KO5014
EPA 6010C
11/07/14 13:16
JDH
Lead [7439-92-1]^
23.2
J
mg/kg dry
1
21.3
88.9
4KO5014
EPA 6010C
11/07/14 13:16
JDH
Magnesium [7439-95-4]^
3990
JB
mg/kg dry
1
116
4440
4KO5014
EPA 6010C
11/07/14 13:16
JDH 3-01
Mercury[7439-97-6]^
< 1.05
mg/kg dry
1
1.05
3.66
41(10027
EPA 7471B
11/11/14 14:09
T1D
Molybdenum [7439-98-7]^
< 17.8
mg/kg dry
1
17.8
88.9
4KO5014
EPA 6010C
11/07/14 13:16
JDH
Nickel[7440-02-0]^
< 64.0
mg/kg dry
1
64.0
444
4KO5014
EPA 6010C
11/07/14 13:16
JDH
Potassium [7440-09-7]^
5630
mg/kg dry
1
711
4440
4KO5014
EPA 6010C
11/07/14 13:16
JDH
Selenium [7782-49-2]^
< 17.8
mg/kg dry
1
17.8
88.9
4KO5014
EPA 6010C
11/07/14 13:16
JDH
Sodium [7440-23-5]^
23800
mg/kg dry
1
1070
4440
4KO5014
EPA 6010C
11/07/14 13:16
JDH
Zinc [7440-66-6]^
1110
mg/kg dry
1
196
444
4KO5014
EPA 6010C
11/07/14 13:16
JDH
Classical Chemistry Parameters
Analyte rCAS Numberl
Results
Dig
Units
DE
MAL
POL
Batch
Method
Analyzed
ft Notes
0/6 Solids
0.6
% by Weight
1
0.1
0.1
4KO6028
% Solids
11/06/14 13:21
MMR
Ammonia as N [7664-41-7]
130
mg/kg dry
1
8.0
18
4KO7019
EPA 350.1
11/07/14 15:38
SHA
Nitrate/Nitrite as N
3100
D
mg/kg dry
97.5
710
1700
4K11002
EPA 353.2
11/11/14 12:27
SHA
PH
7.1
pH Units
1
1.0
1.0
4KO6024
EPA 9045D
11/06/14 14:44
MMR
Phosphorus[7723-14-0]
38000
D
mg/kg dry
200
890
3500
4KI2014.
EPA 365.4
11/17/14 13:17
SHA
Total Kjeldahl Nitrogen
74000
D
mg/kg dry
100
4600
8500
4K12008
EPA 351.2
11/17/14 10:46
SHA
Total Solids
0.56
% by Weight
1
0.0010
0.0010
4KO6026
SM 254OG-1997
11/06/14 13:21
MMR
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 10

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO038784 Source Name Neuse River Village
Laboratory 1 Fsvironmental
Conservation
Laboratory 2
Sample or CompositeDate 11/5/2014
Parameter (mg/Rg) Class A Clas B
Aluminum
N/A
N/A
10,400
Ammonia Nitrogen
N/A
N/A
11000
Arsenic
41
75
12.6
Cadmium
39
85
1.21
Calcium
N/A
N/A
30,700
Copper
1,500
4,300
192
Lead
300
840
15.2
Magnesium
N/A
N/A
4,890
Mercury
17
57
0.67
Molybdenum
N/A
75
12.6
Nickel
420
420
45.5
Nitrate -Nitrite Nitrogen
N/A
N/A
500
Percent Solids
N/A
N/A
0.80
PH (no units)
N/A
N/A
7.40
Phosphorus
N/A
N/A
26,000
Potassium
N/A
N/A
6,320
PAN (Inj./Inc.)
N/A
N/A
37,300
PAN (Surface)
N/A
N/A
31,800
Selenium
100
100
12.6
Sodium
N/A
N/A
13,000
SAR
N/A
N/A
1.62
TRN
N/A
N/A
97,000
Zinc
2,800
7,500
1140
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
(-c-AL. 02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CPR Part 503.9(r) and 15A NCAC 2T .1102 (26)

r� - AGMAN
Facility Neuse River Village
Sampling Date 11/5/2014
% Solids 0.8
Mineralization Rate 0.3
Gallons per DT 29,976.02
PH 7.4
FIELD LOADING ESTIMATES
Sodium Absorpotion 1.62 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land ripply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 97,000 lbs./1,000 gal 6.47
Ammonia Nitrogen (mg/Kg) 11,000.00 lbs./1,000 gal 0.73
Nitrate -Nitrite (mg/Kg) 500.00 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 31,800 lbs./1,000 gal 2.12
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 37,300 lbs./1,000 gal 2.49
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100.
2,800
7,500
i
1st Year
2nd Year
3rd Year
4th Year
5th Year
I
9
HEAVY METAL CONCENTRATION
Potassium lbs./1,000 gal. 0.42
Phosphorus lbs./1,000 gal 1.73
Calcium lbs./1,000 gal 2.05
Magnesium lbs./1,000 gal 0.33
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
12.60
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.21
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
192.00
Copper lbs./1,000 gal
0.01
Lead (mg/Kg)
15.20
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.67
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
45.50
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
12.60
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
1140.00
Zinc lbs./1,000 gal
0.08
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN
PAN
Nitrogen
TKN
(mg/kg) (Ibs/DT)
(mg/Kg)
TKN
(mg/kg)
(lbs/DT)
(mg/Kg)
97,000
31,800
63.60
65,200
97,000
37,300
74.60
59,700
65,200
9,780
19.56
55,420
59,700
8,955
17.91
50,745
55,420
4,157
8.31
51,264
50,745
3,806
7.61
46,939
51,264
1,922
3.84
49,341
46,939
1,760
3.52
45,179
49,341
925
1.85
48,416
45,179
847
1.69
44,332
Total 48,584 97.17
Total 52,668 105.34
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)

SAMPLE DETECTION SUMMARY
www.encolabs.com
Client ID: Neuse River Village Sludge
Lab ID: C413813-01
Analvte
Results
EIN
MPS
EM
Units
Method Notes
% Solids
0.8
0.1
0.1
% by Weight
% Solids
Aluminum -Total
10400
265
1260
mg/kg dry
EPA 6010C
Ammonia as N '
11000
D
510
1100
mg/kg dry
EPA 350.1
Cadmium - Total
1.21
0
1.21
6.31
mg/kg dry
EPA 6010C
Calcium - Total
30700
B
707
3160
mg/kg dry
EPA 6010C QB-01
Copper - Total
192
24.0
63.1
mg/kg dry
EPA 6010C
Magnesium - Total
4890
B
82.1
3160
mg/kg dry
EPA 6010C QB-01
PH
7.4
1.0
1.0
pH Units
EPA 9045D
--, Phosphorus
26000
D
630
2500
mg/kg dry
EPA 365.4
Potassium Total
6320
505
3160
mg/kg dry
EPA 6010C
Sodium - Total
13000
758
3160
mg/kg dry
EPA 6010C
Total Kjeldahl Nitrogen
97000
D
3300
6000
mg/kg dry
EPA 351.2
Total Solids
0.79
0.0010
0.0010
% by Weight
SM 2540G-1997
Zinc - Total
1140
139
316
mg/kg dry
EPA 6010C
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 11

www.encolabs.com
ANALYTICAL RESULTS
Description: Neuse River Village Sludge Lab Sample ID:C413813-01 Received: 11/05/14 14:46
Matrix: Sludge Sampled:11/05/14 13:15 Work Order: C413813
Project: Neuse River Village -Annual Sludge Sampled By: Van Gurley % Solids: 0.79
Metals by EPA 6000/7000 Series Methods
^ - ENco Cary certified analyte [NC 591]
Anahrte rCAS Numberl Results
Flan
MnM
DF
BDL
M
Batch
Method
Analyzed
Notes
Aluminum [7429-90-5]^
10400
mg/kg dry
1
265
1260
41(13030
EPA 6010C
11/14/14 14:16
JDH
Arsenic[7440-38-2]^
< 12.6
mg/kg dry
1
12.6
63.1
4K13030
EPA 6010C
11/14/14 14:16
JDH
Cadmium [7440-43-9]^
1.21
J
mg/kg dry
1
1.21
6.31
4K13030
EPA 6010C
11/14/14 14:16
JDH
Calcium [7440-70-2]^
30700
B
mg/kg dry
1
707
3160
4K13030
EPA 6010C
11/14/14 14:16
JDH QB-01
Copper[7440-50-8]^
192
mg/kg dry
1
24.0
63.1
4K13030
EPA 6010C
11/14/14 14:16
JDH
Lead [7439-92-1]^
< 15.2
mg/kg dry
1
15.2
63.1
4K13030
EPA 6010C
11/14/14 14:16
JDH
Magnesium [7439-95-4]^
4890
B
mg/kg dry
1
82.1
3160
41<13030
EPA 6010C
11/14/14 14:16
JDH QB-01
Mercury [7439-97-6]^
< 0.670
mg/kg dry
1
0.670
2.33
41<10027
EPA 7471B
11/11/14 14:11
T11)
Molybdenum [7439-98-7]^
< 12.6
mg/kg dry
1
12.6
63.1
4K13030
EPA 6010C
11/14/14 14:16
JDH
Nickel[7440-02-0]^
< 45.5
mg/kg dry
1
45.5
316
41<13030
EPA 6010C
11/14/14 14:16
JDH
Potassium [7440-09-7]^
6320
mg/kg dry
1
505
3160
4K13030
EPA 6010C
11/14/14 14:16
JDH
Selenium [7782-49-2]^
< 12.6
mg/kg dry
1
12.6
63.1
41<13030
EPA 6010C
11/14/14 14:16
JDH
Sodium [7440-23-5]^
13000
mg/kg dry
1
758
3160
41(13030
EPA 6010C
11/14/14 14:16
JDH
Zinc [7440-66-6]^
1140
mg/kg dry
1
139
316
41<13030
EPA 6010C
11/14/14 14:16
JDH
Classical Chemistry Parameters
Analvte rCAS Numberl
Results
Flan
Units
P
1 DL
POL
Batch
Method
Analyzed
Bt Notes
% Solids
0.8
% by Weight
1
0.1
0.1
4KO6028
% Solids
11/06/14 13:21
MMR
Ammonia as N [7664-41-7]
11000
D
mg/kg dry
90
510
1100
4K12005
EPA 350.1
11/12/14 11:35
SHA
Nitrate/Nitrite as N
< 500
D
mg/kg dry
97.5
500
1200
41<11002
EPA 353.2
11/11/14 12:30
SHA R-01
PH
7.4
pH Units
1
1.0
1.0
4KO6024
EPA 9045D
11/06/14 14:44
MMR
Phosphorus[7723-14-0]
26000
D
mg/kg dry
200
630
2500
4K12014
EPA 365.4
11/17/14 13:19
SHA
Total Kjeldahl Nitrogen
97000
D
mg/kg dry
100
3300
6000
4K12008
EPA 351.2
11/17/14 10:48
SHA
Total Solids
0.79
% by Weight
1
0.0010
0.0010
4KO6026
SM 2540G-1997
11/06/14 13:21
MMR
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 11

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FIELD LOADING ESTIMATES
Facility Neuse River WWTP
Sampling Date 1/13/2014
% Solids 3.78
Mineralization Rate 0.3
Gallons per DT 6,344.13
PH 7.58
Sodium Absorpotion 1.30 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 44,444 lbs./1,000 gal 14.01
Potassium lbs./1,000 gal
1.28
Ammonia Nitrogen (mg/Kg) 4,841.27 lbs./1,000 gal 1.53
Phosphorus lbs./1,000 gal
17.77
Nitrate -Nitrite (mg/Kg) 157.00 lbs./1,000,gal 0.05
Calcium lbs./1,000 gal
3.47
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
1.11
PAN (mg/Kg) 14,458 lbs./1,000 gal 4.56
Manganese lbs./1,000 gal
0.21
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
0.12
PAN (mg/Kg) 16,879 lbs./1,000 gal 5.32
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits. (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1st Y=
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
4.60
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
3.70
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
416.60
Copper lbs./1,000 gal
0.13
Lead (mg/Kg)
24.80
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
1.56
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
19.30
Nickel lbs./1,000 gal
0.01
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
705.20
Zinc lbs./1,000 gal
0.22
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
44,444
14,458
28.92
29,986
44,444
16,879 33.76
27,565
29,986
4,498
9.00
25,488
27,565
4,135 8.27
23,430
25,488
1,912
3.82
23,576
23,430
1,757 3.51
21,673
23,576
884
1.77
22,692
21,673
813 1.63
20,860
22,692
425
0.85
22,267
20,860
391 0.78
20,469
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (VM/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 22,177 44.35
Total 23,975 47.95

CifY of Raleigh Neuse River VI W Lab
WW Certification .# 511 EPA Lab Code NCO1029
Laboratory Report of Analysis
Sample Origination: Covered Aerobic Digeste
AOo�
c0a �~
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z
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co
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z0 R
2
rA
zR
IIa �'
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ae�
��:�
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N
Date
%
mglL
mglkg
mg/L
mglkg mglL ; mg/kg mg/L mglkg
mg/L
mg/kg
mg/L
mglkg
mg/L
mglkg
1/1/2014
1 /212014
1 /3/2014
1/4/2014
;
1/5/2014
1
1/6/2014
11712014
1/8/2014
1/9/2014
1/1012014
1/11/2014
1/12/2014
1/13/2014
CAMCB011314.
3.781
1,680�
44,444;
2,131
56,369 183.0W 4,841.271 5.940 157
14.69
386
547
14,459
638
16,879
1/14/2014
1/15/2014
!
f
1H6/2014
1/17/2014
1/18/2014
1119/2014
I
r
1 /20/2014
1/21/2014
i
1 /22/2014
IM/2014
I
1/24/2014
1/25/2014
'
1/26/2014
1 /27/2014
{
l
k
1/28/2014
1 /29/2014
1/30/2014
1/31/2014
Minimum
Maximum
Average
3.78
3.78
3.78
1,680;
1,680
1,680
44,444
44,444
44-444
2,131
2,131
2,131
56,369 183 4,841 5.940 157 15
56,369 183 4,841 5.940 157 15
56,369 1831 4,841 ` 5.940 1571 15
386
386
386
547
547
547.
14,459
14,459
144591
638
638
63RI
16,879
16,879
16,879
Darrell revs Date
Laboratory Supervisor

City of Raleigh Neuse River VMTP Lab
WW Certification # 51/ EPA Lab Code NC01029
;Laboratory Report of Analysis i
Sample Origination: Covered aerobic Digester
1C w
�m
HC7 °�i
R1 ca
Ui-
B1 ®
�C1>
'aeLa
QN
F""
U
Qy
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c
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2
a
43
F- 07
LL
f70-
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LL�
v
d
LL
t!) c�0i
N
U.
aa00.
0
W
Ul
. A w
LL
Date
%
%
%
%
SU
%
Count
counts/0
%
Count
counts/G
1/1/2014
'
1/2/2014
1/3/2014
1 /412014
1 /5/2014
1/6/2014
1/7/2014
1/8/2014
11/9/2014
1/1012014
1/11/2014
1/12/2014
1/13/2014
CAD#1 CB011314
CAD#1 CB0122140725
76
3.78
61
51
7.58
3.70
<2.00
<54.05
1/14/2014
� 1/15/2014
CAD#1 CB011314
CAD#1 CB0122140745
,
3.72
<2.00
j <53.76
1/16/2014
CAD#1CB011314
CAD#1CB0122140755'
3:64
<2.00
<54.95
1/1712014
CAD#1CB011314
CAD#1CB0123140725
3.66
<2.00
<54.64
1/18/2014
CAD#1CB011314
CADOIGB0123140735
l
3.66
4.00
109.29
1/19/2014
CAMCB011314
CAD#1CB0123140745
3.72
4.00
107.53
1/20/2014
CAD#1CB011314
CAD#1CB0127140735
3.58
<2.00
<55.87
1/21/2014
CAD#1CB011314
CAD#1CB0127140745
3.58
2.00
1 55.87
1/22/2014
CAD#1CB011314
CAD#1CB0127140755
3.64
<2.00
<54.95
1/23/2014
1/24/2014
1/25/2014
1/26/2014
1/27/2014
112=014
1/29/2014
i
1/30/2014
1/31/2014
(Minimum
3.781
61
51'
7.58
3.58
<2.00
<53.76
Mabmum
3.781
61
51
7.58
3.72
4.001
109.29
Average
1
1 3.781
611
611
7.58
3.66
<2.44
<66.77
Darrell Creuvs��V 'Vat ��
Laboratory Supervisor

City of Aaleigh Neuae River WWTP Lab Laboratory Report of Analysis �
WW Certification # 51/ EPA Lab Code NCO1029 Sample origination Covered Aerobic Digester
E
49
re
Date
mglkg
mglkg
mg/kg
mglkg
mglkg
mglkg
mglkg
mg/kg
mglkg
mglkg
mg/kg
1/112014
^-
1/2/2014
1/3/2014
1/412014-
�
1/5/20'14
1/6/2014
-
--
1/7/2014
1/9/2014
1/10/2014
1/11/2014
_
1/12/2014
_
1/13/2014
CADOC13011314
13,799.700
--
283.200
3.700
—
11,000.400
40.600
4.100
416.600
83,158.500
_
24.800
3,508,800
_652.-400
1/14/2014
1/1512014
1116/2014
--••-
-
--
j1/17/2014 - —_
__
_
--
—
11/18/2014
1/19/2014
1/20/2014
--
-
--
1/21/2014 --
1/2212014
1/23/2014
1/24/2014
1/26/2014
112612014
1 /27/2014
1/28/2014
1/29/2014
1/30/2014
1/31/2014
Minimum
13,799.700
283.200
3.700
11,000.400
40.600
4.100
416.600
83,158.500
24.800
3,508.800
662.406
Maximum
_
13,799.700
283.200
3.700
11,000.400
40.600
4.100
416.600
83,188,500
24,800
3,508.8001
652.400
Average
13,799.700
283.200
3.700
11,000.400
40.600
4.100
416.600
83,158,500
24.800
3,508.800
652.400
503 Ceiling Cone
85
3000
4300
840
603 EQ _
39
1200
1600
-
300
% 503 Ceiling Cone
4.35
1.35
9.69
2.95
503 EQ
9.49
3.38
27.77
8.2T
Darrell Crews Date
Laboratory Supervisor

City of Raleigh Neuse River VWVTP Lab
WW Certification # 51/ EPA Lab Code NC01029
iQ 'd
6i
d
y
C1
fl
Date
mglkg
mg/kg
mglkg
mglkg
mglkg
1/1/2014
-
1/2/2014
_....
1/3/2014
1/4/2014
�-
1/5/2014
1/6/2014
ifR614--
1/8/2014-
1/9/2014
1/10/2014
1/11/2014
1/1212014
1/13/2014
CAD#iCB011314
9.300
_
19.300
4,053.600
8.500
3,165.400
1/14/2014
1/15/2014
1/16/2014
1 /17/2014
_
1/18/2014
- —
-
-
111912014
1J20/2014-
1/21/2014
1/22/2014
1/23/2014 -
1/24/2014
1/25/2014
1/26/2014
1/27/2014
1 /28/2014
-
1/2912014
_
1/3012014
1131/2014
Minimum
9.300
19.300
4,053.600
8.500
3,165.400
Maximum
_
9,300
19.300
4,053.600
8.500
3,165.400
Average
9.300
19.300
4,053.600
8.500
3,165.400
503 Ceiling Cone
75
420
—
503 EQ
17
420
% 503 Ceiling Cone
12.40
4.60
_
% 503 EQ
64.71
4.60
Darrell Crews
Laboratory Supervisor

Laboratory Report of Analysis
Sample Origination: Covered Aerobic Diuester
W
V
7
Date
mglkg
mg/kg
mg/kg
mg
mg/kg
mg/kg
1/1/2014
_
1/2/2014
1/3/2014
�.
1/4/2014
1/5/2014
1/6/2014
1/7/2014 T
118/2014
1/9/2014
1/10/2014
1/11/2014
1/12/2014
1/13/2014
CAD#1 CB011314
40.900
62.200
705.200
4.600
5.000
1.66
1l1412014
1/15/2014
1/16/2014
1/17/2014
1/18/2014
1/19/2014
1/20/2014
1/21/2014
--
1/22/2014
1/23/2014
1/2412Q14
1/25/2014
1/26/2014
1/27/2014
1/28/2014
1/29/2014
1 /30/2014
1/31/2014
_
Minimum
40.900
52.200
•705.200
4.600
5.000
1.56
Maximum
40.900
62.200
705.200
4.600
5.000
1.56
Average
40.900
52.200
705.200
4.600
6.000
1.56
603 Ceiling Conc
7500
.75
100
57
503 EQ
28001
41
_ 100
17
503 Ceiling Conc
_
9.40
6.13
6.00
2.73_
% 503 EQ
25.19
11.22
5A0
9.15
Darrell Crews date
Laboratory Suprvisor

AGMAN
t FIELD LOADING ESTIMATES
Facility Neuse River WWTP
Sampling Date 2/17/2014
Solids 2.96
Mineralization Rate 0.3
Gallons per DT 8,101.63
I
pH 7.95
Sodium Absorpotion 1.60 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 78,209 lbs./1,000 gal 19.31 Potassium lbs./1,000 gal 1.40
.Ammonia Nitrogen (mg/Kg) 36,182.43 lbs./1,000 gal 8.93 Phosphorus lbs./1,000 gal 13.19
Nitrate -Nitrite (mg/Kg) 206.00 lbs./1,000 gal 0.05 Calcium lbs./1,000.gal 2.98
PLANT AVAILABLE NITROGEN SURFACE APPLIED Magnesium lbs./1,000 gal 1.07
PAN (mg/Kg) 30,90.5 lbs./1,000 gal 7.63 Manganese lbs./1,000 gal 0.16
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED Sulfur lbs./1,000 gal
PAN (mg/Kg) 48,996 lbs./1,000 gal 12.10 Molybdenum lbs./1,000 gal 0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
HEAVY METAL CONCENTRATION
HEAVY METAL LOADING
41
75
Arsenic (mg/Kg)
4.30
Arsenic lbs./1,000 gal
0.00
39
85
Cadmium (mg/Kg)
1.70
Cadmium lbs./1,000 gal
0.00
1,500
4,300
Copper (mg/Kg)
384.20
Copper lbs./1,000 gal
0.09
300
840
Lead (mg/Kg)
19.10
1 Lead lbs./1,000 gal
0.00
17
57
Mercury (mg/Kg)
1.82
Mercury lbs./1,000 gal
0.00
420
420
Nickel (mg/Kg)
22.00
Nickel lbs./1,000 gal
0.01
100
100
Selenium (mg/Kg)
6.20
Selenium lbs./1,000 gal
0.00
2,800
7,500
Zinc (mg/Kg)
507.00
Zinc lbs./1,000 gal
0.13
RESIDUAL NITROGEN CALCULATION
1 st Year
2nd Year
3rd Year
4th Year
5th Year
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
78,209
30,905
61.81
47,304
78,209
48,996 97.99
29,213
47,304
7,096
14.19
40,208
29,213
4,382 8.76
24,831
40,208
3,016
6.03
37,193
24,831
1,862 3.72
22,968
37,193
1,395
2.79
35,798
22,968
861 1.72
22,107
35,798
671
1.34
35,127
22,107
. 415 0.83
21,693
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 43,082 86.16
Total 56,516 113.03

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City of Raleigh Neuse River WWTP Lab
WW Certification # 51/ EPA Lab Code NCO1029
Laboratory Report of Analysis
Sample Origination: Covered Aerobic DtqeMe
4
El*i"rr .I
4.
x
rL
9L
u.,
j�! i i _,N �11. A"
N
P,
q ij�
do fti un Gil
2/112014
jt-
Rt1o1;i'..:, I" A�l
2/3/2014
T777
777
777�
2/512014
�i7/2014
2020.1
77.Ti -w.�,p
2/9/2014
y'.
2/1112014
I.
211312014
2/15/2014
w'! W10.1
J
2117/2014
CAD#2CB021714
CAD#2CB0303140735
77
2.96
64
47
7.95
2.76
<2.00
<72AS
F'CAD#XBW0:X1iW7liZ
2/19/2014
CAD#2CB021714
CAD#2CB0303140755
2.82
<2.00
<70.92
2J20)2
03140805-`:.
1Z8Z
_<2.00''
<
. ....
212U2014
CAD#2CB021714
CAD#2CB0304140730
2.90
<2.00
<68.97
'2
<2;00:.I:-,
4&­.
2iE2014
CAD#2CB021714
CAD#2CB0304140750
2.84
<2.00
I <70.42
=4Ili.40
::�l JI.,
0�
2/2MO14
2l2612014v
2)2712D14
2W20
Minimum
2.96
641
471
7.951
2.681
<2.00
<68.97
1 7
`471.
5
2�90
1Average
2.96
641
471
---- 7.951
2.801
<2.00
<71-391
1
/ bmil I " 3//p/2--pl/y _
-Darrell Crews Date
Laboratory Supervisor

City of Ralleigh Neuse River WWTP Lab
WW Certification # 51/ EPA Lab Code NCO1029
Laboratory Report of Analysis
Sample Origination Covered AerohIg_PjgggtM
-3.
E
4M,
01
Ji
—
4OW
A
9
NDit
2/112014
2/?IZ014:'*.::
J�r
2/3/2014
2�4120
2/612014
2 0
/6/2
217/2014
2/9/2014
2/1112014
211312014
, 7 .
211512014
2/16f2
2117/2014
CAMCB021714
16,228.500
284.900
1.700
12,072.700
26,600
4.400
384.200
70,710.400
19.100
4,316,6001
649.500
2/18
2/1912014
L;a
2/21/2014
21�
WNW
212312014
V2512014
2126/20f.�-
14.
2/27/2014
.............
a
N V
Minimum
15,228.500
284.900
1.700
12,072.700
25.600
4.400
384.200
70,710.400
19.100
4,315.500
649.500
Q
"j? m .
;.70-Q
- A...
- - -
APOP
1- -01-
'24-1
--
-�Z-AM 19 Q,
Average
15,228.500
284.900
1
12,072.700
25.600
4.400
384.200
70.710.400
19.100
4,315.500
449.500
- Q,
503 EQ
39
1200
1600
300
2
II -A
% 503 EQ
4.36
1 2.131
25.61[
6.371
1
1-4arm I MICrews Date
Laboratory Supervisor

City of Raleigh Neuae River WVVTP Lab
WW Certification # 51/ EPA Lab Code NCO1029
kDm 14
Darrell Crews Date
Laboratory Supervisor

Laboratory Report of Analysis
Sample Origination: Covered Aerobic Digester
U
Q !Z,
n�_ k
�0
Pat
211/2014
2/2*120fl.;—
t
21312014
21612014
7: 'i'm
21712014
202014
211112014
M 2J20 14
2/1312014
2114
.......
2/1512014
21 W2 0
2/1712014
CAD#2CB021714
74.400
39.100
507,000
4.300
6.200
1.82
2118/20
2119/2014
2l49/2 0 14
2/21/2014
_1Z
2123/2014
2125/2014
21271901 4
2-12P
Minimum
74.400
39,100
607.000
4.300
6.200
1.82
-.174 4 0 0
'39.100
5o7,..
"oOo
0
-.4.3 0
Average
74.400
39.100
507.000
4.300
6.200
1.82
503OCbilifig',C6na..:..
76
57.
503 EQ
2800
41
100
17
7 3
6.20
3;.�O.
% 503 EQ
18.11
10.49
6.20
10.73
Darrell Crews Date
Laboratory Suprvisor

AGMAN
FIELD LOADING ESTIMATES
(! Facility Neuse River WWIP
Sampling Date 8/27/2014
Solids 3.37
Mineralization Rate 0.3
Gallons per DT 7,115:97
pH 9.18
Sodium Absorpotion 1.44 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 56,558 lbs./1,000 gal 15.90
Potassium lbs./1,000 gal
1.74
Ammonia Nitrogen (mg/Kg) 47,359.05 lbs./1,000 gal 13.31 .
Phosphorus lbs./1,000 gal
11.90
__. Nitrate -Nitrite (mg/Kg) 174.00 lbs./1,000 gal 0.05
Calcium lbs./1,000 gal
3.60
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
1.10
PAN (mg/Kg) 26,613 lbs./1,000 gal 7.48
Manganese lbs./1,000 gal
0.22
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
6.84
PAN (mg/Kg) 50,293 lbs./1,000 gal 14.14
Molybdenum lbs./1,000 gal
0.00
_7
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
_. EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
i st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
4.40
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
4.50
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
345.10
Copper lbs./1,000 gal
0.10
Lead (mg/Kg)
28.00
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.37
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
24.60
Nickel lbs./1,000 gal
0.01
Selenium (mg/Kg)
5.20
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
1033.40
Zinc lbs./1,000 gal
0.29
RESIDUAL NITROGEN CALCULATION
Surface Application
Injectibn/Incorporation Application
Remaining
Remaining
Organic
Organic
TEN
PAN
PAN
Nitrogen
TKN
PAN PAN
Nitrogen
(mg/kg) (lbs/DT)
(mg/Kg)
(mg/kg) (lbs/DT)
(mg/Kg)
56,558
26,613
53.23
29,945
56,558
50,293 100.59
6,265
29,945
4,492
8.98
25,453
6,265
940 1.88
5,325
25,453
1,909
3.82
23,544
5,325
399 0.80
4,926
23$44
883
1.77
22,661
4,926
185 0.37
4,741
22,661
425
0.85
22,236
4,741
89 0.18
4,652
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
'Total 34,322 68.64 Total 51,906 103.81

City cif Raleigh Neuse River WWTP Lab
WW Certification # 511 EPA Lab Code NC01 029
August2014
Laboratory Report of Analysis
Sample Originafion: ::overed Aerobic Digester
Class•B.Oatch-ID
- ." !:. "'.
F F I
-Class B'Fecal Grab,
' .­ . Imes
T
..Digester -
4 d VS
be
A rage ve
_'-Class, Bi-�
TS
%
Class B,,. -
jv,
Volatile.,:
C onc
Reduction
H,
P %
SU
L
glass*,
;--,T.S.fecal:,�
Class'S:,,';;'
Count
ClissM.7:Clai§
Cor
Bt.L;
P;Cldft-B,'�
8/2712014
CAD#4CB082714
CAD94CB0902140733
77
� ,,37,7,
20
3.26
<2.00
<61.35
8128/2014'---;".:
GADAC[3082714'..
CAD94CB0902140743,
<2100
......
8/2912014
CAE)#4CB082714
CAD#4CS0902140753
3.38
<2.00
<59-17
813012014
CAP#4CB982714--
CAD#4CB0902140803<2.00'<62.11`
8/31/2014-
CAD#4CB082714
CAD#4CB0903140735
3.88
<2.00
<51.55
9/1j�.29141
.CAD#4CB082714`
CAD#4CB0903140745.
3.92,
'%1<2_M- tl
,:'•<51.02
"
902014
CAD#4CB082714
CADWE30903140755
4.10
<2.00
<48.78-
9/3t2014--.-'
Maximum '
77
3.37
56
62 =
9A B.."
4.10,'
<:ZOO
TOM
77
3.37
56
62
1 9.18
25.02
<14-00
<395.33
,Average-
TT
3.37
56
1 62-
9-18
1 3.57-•
7
<55.48J
Peo Mean
77
3.37
56-
1 62
1i 9-18
3.56
-e2,00
<56-22
I

City of Raleigh Neuse River WW Lab
WW Certification # 51/ EPA Lab Code NCO 1029
Laboratory Report of Analysis
Sample Origination: Covered Aerobic Digeste
ry,71�
lye_ " �. � •r �JJL���
Darnell Crews Date
Laboratory Supervisor

Laboratory Report of Analysis
Sample Origination: Covered Aemblc Digester
oa
m.:
Date
mglkg
.•'mglkg
mg/kg..
" mglk `:
mglkg.
'mg/kg
8/1/2014
8/2/2014
8/3/2014
8/4/2014
8/5/2014
8/6/2014
8/7/2014
8/8/2014
8/9/2014
8/10/2014
8/11/2014
8/12/2014
8/13/2014
8/14/2014
8/1512014
8/16/2014
8/17/2014
8/18/2014
8/19/2014
8/20/2014
8/21/2014
8/22/2014
8/23/2014
8/24/2014
8/25/2014
8/2612014
8/27/2014
CAD#4CB082714
99.000
43.500
1,033.400
4.400
5.200
0.37
8/28/2014
8/29/2014
8/30/2014
8131/2014
Minimum
99.000
43.500
1,033.400
4.400
5.200
0.37
Maximum
.99.000
43.500
1,033.400
. 4.40o
' "'5.200
0,37
Average
99.000
43.500
1,033.400
4.400
5.200
0,37
503 Ceiling Conc.
7600
' .. 76
503 EQ
2800
41
1001
17
503 Ceiling Canc
13,78
:..'.6,87.:
..:-6,20
-;:._:•0;68
% 503 EQ
36.911
10.73
6,20
2.20
Darrell Crews Date
Laboratory Suprvisor

City of Raleigh Neuse River WWTP Lab
WW Certification # 51/ EPA Lab Code NC01029
V
Ar
Date
-
mg/kg
' ,mglkg '-
mg/kg ;_
. _ mglkg
mg/kg
8/1/2014
8/2/2014
'
8/3/2014
8/4/2014
8/5/2014
8/6/2014
8/7/2014
8/8/2014
8/9/2014
8/10/2014
8/11/2014
8/12/2014
8/13/2014
8/14/2014
8/15/2014
8M 6/2014
8/17/2014
8/18/2014
8/19/2014
8/20/2014
_
8/21/2014
8/22/2014
8/23/2614
8/24/2014
8/25/2/ 014
8/26/2014
NIJ
8/27/2014
CAD#4CB082714
13,300
24,600
6.187.500
15,400
3,961.300
8/28/2014
8/29/2014
8/30/2014
8/31/2014
Minimum
13.300
24>600
6,187,500
16.400
3,961.300
Maximum
13.300
24.600
6,187.600
16,400
` 3.961,300
Average
13.300
24.600
6,187.600
15,400
3,961,300
503 Ceiling Conc
76
' . 420
'.
503 EQ
17
420
*603 Ceiling Copp
17:73
.5.86
% 503 EQ
78.24
6.86
Y�207Darrell Crews
Laboratory Supervisor

City of Raleigh Neuse River VVWTP Lab
WW Certification # 511 EPA Lab Code NC01029
Laboratory Report of Analysis
Sample origination Covereg Aerobic Dlaseter
ca u
U
e
g
e
Date
mg/kg
mg/kg
mglkg
mg/kg
mg/kg
mg/kg
-mg/kg.
mgikg
mglkg
mg/kg
mglkg
8/1/2014
8/2/2014
813/2014
8/412014
8/5/2014
8/8/2014
8/7/2014
8/8/2014
8/9/2014
8/1012014
-
8/11/2014
8/12/2014
8/13/2014
8/14/2014
8/15/2014
8/1612014
8/17/2014
8/18/2014
8/19/2014
8/20/2014
8/21 /2014
8122/2014
8/23/2014
8/24/2014
8125l2014
8/28/2014
8/27/2014
CAD#4CB082714
17,322.500
513.800
4.500
12,794,900
29,000
5.200
345.100
84,818.500
28.000
3,921.800
770,700
8128/2014.
8/29/2014
_-
8/3012014
8/3112014
Minimum
17,322.500
513.800
4.500
12,794.900
29.0001
5.200
346.100
84,816.600
28.000
3,921.600
770.700
Maximum
17,322.600
413.800
4.000
12,794.900
29,000
6.200.-:346.100
84,815.600
28,000:
3,0;1.900
. °770.700
Average
17,322.500
513.800
4,500
12,794.900
29.000
6.200
345,100
84,815.500
28.000
3.921,600
770,700
503 Ceiling Cone
86
_..
3000
._:!4300
'-`',
840
503 EQ
39
1200
1500
300
% 603 Ceiling Conc
% 503 EQ
11.54
2.42
23.01
9.33
Darrell Crews Date
Laboratory Supervisor

OESC
I
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Emily Fentress
City of Raleigh Neuse River WWTP
PO Box 590
Raleigh, NC 27602
Report Summary
Monday June 16, 2014
Report Number: L683721
Samples Received: 02/19/14
Client Project:
Description: TCLP Sampli
The analytical results in this report are based upon information supplied
by you, the client, and are for your exclusive use. If you have any
questions regarding this data package, please do not hesitate to call.
Entire Report Reviewed By:
Laboratory Certification Numbers
A411��e 1a4'4'tt-W
T. Alan Harvill , ESC Representative
A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - 01157CA, CT - PH-0197,
FL - E87487, GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016,
NC - ENV375/DW21704/BI0041, ND - R-140. NJ - TN002, NJ NELAP - TN002,
SC - 84004, TN - 2006, VA - 460132, WV - 233, AZ - 0612,
MN - 047-999-395, NY - 11742, WI - 998093910, NV - TN000032011-1,
TX - T104704245-11-3, OK - 9915, PA - 68-02979, IA Lab #364, EPA - TNO02
Accreditation is only applicable to the test methods specified on each scope of accreditation held
by ESC Lab Sciences.
This report may not be reproduced, except in full, without written approval from ESC Lab Sciences.
Where applicable, sampling conducted by ESC is performed per guidance provided
in laboratory standard operating procedures: 060302, 060303, and 060304.
Page 1 of 10

12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Emily Fentress
City of Raleigh Neuse River WWTP
Po BOX 590
Raleigh, NC 27602
Case Narrative
Monday June 16, 2014
Report Number: L683721
Samples Received: 02/19/14
Client Project:
Description: TCLP Sampling
Other Comments
L683721-01 in CORR WG707879. The pH was taken using 2 times the
normal amount of water to suspend the sample due to hydroscopic
nature of the field sample.
Page 2 of 10

OESCL•A,Q S•C•I•E•N•C•E•5
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
REPORT
OF ANALYSIS
Emily Fentress
June 16,2014
'- City of Raleigh Neuse River WWTP
PO Box 590
Raleigh, NC 27602
!
ESC
Sample
# L683721-01
Date Received February 19,
2014
Description TCLP Sampling
Site ID
Sample ID DEWATERED PRIMARY
Project
Collected By Fentress
Collection Date 02/17/14 14:00
Parameter
Result Det. Limit
Units
Limit
Method
Date/Time
By
Dil
Corrosivity
Non-Corrosiv
9045D
02/26/14
1121
SDC
1
Ignitability
See Footnote
Deg. F
D93/101
02/25/14
1643
DR
1
Reactive CN (SW846 7.3.3.2)
BDL
0.125
mg/kg
9012B
02/23/14
1207
1
Reactive Sulf.(SW846 7.3.4.1)
BDL
25.
mg/kg
9034/90
02/22/14
1651
AS
1
TCLP Extraction
-
1311
02/20/14
0710
MVE
1
Mercury
BDL
0.0010
mg/l
0.20
7470A
02/20/14
2104
CCE
1
Arsenic
BDL
0.050
mg/l
5.0
6010B
02/22/14
0815
JDG
1
Barium
BDL
0.15
mg/l
100
6010B
02/22/14
0815
JDG
1
Cadmium
BDL
0.050
mg/l
1.0
6010B
02/22/14
0815
JDG
1
Chromium
BDL
0.050
mg/l
5.0
6010B
02/22/14
0815
JDG
1
Lead
BDL
0.050
mg/l
5.0
6010B
02/22/14
0815
JDG
1
Selenium
BDL
0.050
mg/l
1.0
6010B
02/22/14
0815
JDG
1
Silver
BDL
0.050
mg/l
5.0
6010B
02/22/14
0815
JDG
1
TCLP ZHE Extraction
-
1311
02/22/14
0709
MVE
1
TCLP Volatiles
Benzene
BDL
0.050
mg/1
0.50
8260B
02/22/14
1532
RB
1
Carbon tetrachloride
BDL
0.050
mg/l
0.50
8260B
02/22/14
1532
RB
1
Chlorobenzene
BDL
0.050
mg/l
100
8260B
02/22/14
1532
RB
1
Chloroform
BDL
0.25
mg/l
6.0
8260B
02/22/14
1532
RB
1
1,2-Dichloroethane
BDL
0.050
mg/l
0.50
8260B
02/22/14
1532
RB
1
1,1-Dichloroethene
BDL
0.050
mg/l
0.70
8260B
02/22/14
1532
RB
1
2-Butanone (MEK)
BDL
0.50
mg/l
200.
8260B
02/22/14
1532
RB
1
Tetrachloroethene
BDL
0.050
mg/l
0.70
8260B
02/22/14
1532
RB
1
Trichloroethene
BDL
0.050
mg/l
0.50
8260B
02/22/14
1532
RB
1
Vinyl chloride
BDL
0.050
mg/1
0.20
8260B
02/22/14
1532
RB
1
Surrogate Recovery
Toluene-d8
105.
% Rec.
114.
8260B
02/22/14
1532
RB
1
Dibromofluoromethane
ill.
% Rec.
125.
8260B
02/22/14
1532
RB
1
a,a,a-Trifluorotoluene
103.
% Rec.
114.
8260B
02/22/14
1532
RB
1
4-Bromofluorobenzene
93.4
% Rec.
128.
8260B
02/22/14
1532
RB
1
TCLP Pesticides
Chlordane
BDL
0.0050
mg/l
0.030
8081A
02/21/14
1547
CBB
1
Endrin
BDL
0.0050
mg/l
0.020
8081A
02/21/14
1547
CBB
1
Heptachlor
BDL
0.0050
mg/l
0.0080
8081A
02/21/14
1547
CBB
1
L683721-01 (IGNITABILITY) - did not
ignite @ 170F
Page 3 of
10

'
OESC
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax (615)
758-5859
L•A•9 S•C-I•E•N•C�E•S
Tax I.D.
62-0814289
Est. 1970
REPORT OF ANALYSIS
Emily Fentress
June
16,2014
City of Raleigh Neuse River WWTP
PO Box 590
Raleigh, NC 27602
ESC
Sample
# L683721-01
Date Received February 19, 2014
Description TCLP Sampling
Site
ID
Sample ID DEWATERED PRIMARY
Project
Collected By Fentress
Collection Date 02/17/14 14:00
Parameter
Result
Det. Limit
Units
Limit
Method
Date/Time
By
Dil
Lindane
BDL
0.0050
mg/l
0:40
8081A
02/21/14
1547
CBB
1
Methoxychlor
BDL
0.0050
mg/1
10.
8081A
02/21/14
1547
CBB
1
Toxaphene
BDL
0.010
mg/1
0.50
8081A
02/21/14
1547
CBS
1
Surrogate Recovery
Decachlorobiphenyl
93.7
% Rec.
123.
8081A
02/21/14
1547
CBB
1
Tetrachloro-m-xylene
80.3
% Rec.
114.
8081A
02/21/14
1547
CBB
1
TCLP Herbicides
2,4,5-TP (Silvex)
BDL
.0.0020
mg/l
1.0
8151A
02/25/14
2020
KLM
1
2,4-D
BDL
0.0020
mg/l
10.
8151A
02/25/14
2020
KLM
1
Surrogate Recovery
2,4-Dichlorophenyl Acetic Acid
59.3
% Rec.
8151A
02/25/14
2020
KLM
1
TCLP Semi-Volatiles
1,4-Dichlorobenzene
BDL
0.10
mg/l
7.5
8270D
02/23/14
0831
KMF
1
2,4-Dinitrotoluene
BDL
0.10
mg/l
0.13
8270D
02/23/14
0831
KMF
1
Hexachlorobenzene
BDL
0.10
mg/1
0.13
8270D
02/23/14
0831
KMF
1
Hexachloro-1,3-butadiene
BDL
0.10
mg/1
0.50
8270D
02/23/14
0831
KMF
1
Hexachloroethane
BDL
0.10
mg/l
3.0
8270D
02/23/14
0831
KMF
1
Nitrobenzene
BDL
0.10
mg/l
2.0
8270D
02/23/14
0831
KMF
1
Pyridine
BDL
0.10
mg/l
5.0
8270D
02/23/14
0831
KMF
1
3&4-Methyl Phenol
0.11
0.10
mg/l
400
8270D
02/23/14
0831
KMF
1
2-Methylphenol
BDL
0.10
mg/l
200
8270D
02/23/14
0831
KMF
1
Pentachlorophenol
BDL
0.10
mg/l
100
8270D
02/23/14
0831
KMF
1
2,4,5-Trichlorophenol
BDL
0.10
mg/1'
400
8270D
02/23/14
0831
KMF
1
2,4,6-Trichlorophenol
BDL
0.10
mg/l
2.0
8270D
02/23/14
0831
KMF
1
Surrogate Recovery
2-Fluorophenol
26.4
% Rec.
87.0
8270D
02/23/14
0831
KMF
1
Phenol-d5
22.9
% Rec.
67.0
8270D
02/23/14
0831
KMF
1
Nitrobenzene-d5
58.3
% Rec.
120.
8270D
02/23/14
0831
KMF
1
2-Fluorobiphenyl
72.5
% Rec.
122.
8270D
02/23/14
0831
KMF
1
2,4,6-Tribromophenol
46.5
% Rec.
148.
8270D
02/23/14
0831
KMF
1
p-Terphenyl-dl4
82.8
% Rec.
149.
8270D
02/23/14
0831
KMF
1
BDL - Below Detection Limit
Det. Limit - Estimated Quantitation Limit(EQL)
Limit - Maximum Contaminant Level as established by the US EPA
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 02/26/14 16:54 Revised: 06/16/14 08:•58
L683721-01 (IGNITABILITY) - did not ignite @ 170F
Page 4 of 10

REPORT OF ANALYSIS
Emily Fentress
City of Raleigh Neuse River WWTP
PO Box 590
Raleigh, NC 27602
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-08142B9
Est. 1970
June 16,2014
ESC Sample # : L683721-02
Date Received February 19, 2014
Description TCLP Sampling
Sample ID CLASS A-RALEIGH PLUS
Collected By Fentress
Collection Date 02/17/14 09:50
Parameter Result
Det. Limit
Units
Site ID
Project
Limit Method
Date/Time
By
Dil
Corrosivity
Non-Corrosiv
9045D
02/26/14
1121
SDC
1
Ignitability
See Footnote
Deg. F
D93/101
02/25/14
1643
DR
1
Reactive CN (SW846 7.3.3.2)
BDL
0.125
mg/kg
9012B
02/23/14
1209
1
Reactive Sulf.(SW846 7.3.4.1)
BDL
25.
mg/kg
9034/90
02/22/14
1651
AS
1
TCLP Extraction
-
1311
02/20/14
0710
MVE
1
Mercury
BDL
0.0010
mg/1
0.20
7470A
02/20/14
2127
CCE
1
Arsenic
BDL
0.050
mg/l
5.0
6010B
02/25/14
0023
WBD
1
Barium
0.60
0.15
mg/1
100
6010B
02/25/14
0023
WBD
1
Cadmium
BDL
0.050
mg/1
1.0
6010B
02/25/14
0023
WBD
1
Chromium
BDL
0.050
mg/l
5.0
6010B
02/25/14
0023
WBD
1
Lead
BDL
0.050
mg/l
5.0
6010B
02/25/14
0023
WBD
1
Selenium
BDL
0.050
mg/l
1.0
6010B
02/25/14
0023
WBD
1
Silver
BDL
0.050
mg/1
5.0
6010B
02/25/14
0023
WBD
1
TCLP ZHE Extraction
-
1311
02/22/14
0709
MVE
1
TCLP Volatiles
Benzene
BDL
Carbon tetrachloride
BDL
Chlorobenzene
BDL
Chloroform
BDL
1,2-Dichloroethane
BDL
1,1-Dichloroethene
BDL
2-Butanone (MEK)
BDL
Tetrachloroethene
BDL
Trichloroethene
BDL
Vinyl chloride
BDL
Surrogate Recovery
Toluene-d8
105.
Dibromofluoromethane
108.
a,a,a-Trifluorotoluene
104.
4-Bromofluorobenzene
91.5
TCLP Pesticides
Chlordane
BDL
Endrin
BDL
Heptachlor
BDL
L683721-02 (IGNITABILITY)
- did not ignite @ 170F
0.050
mg/l
0.50
8260B
02/22/14
1549
RB 1
0.050
mg/l
0.50
8260B
02/22/14
1549
RB 1
0.050
mg/l
100
8260B
02/22/14
1549
RB 1
0.25
mg/l
6.0
8260B
02/22/14
1549
RB 1
0.050
mg/l
0.50
8260B
02/22/14
1549
RB 1
0.050
mg/l
0.70
8260B
02/22/14
1549
RB 1
0.50
mg/l
200
8260B
02/22/14
1549
RB 1
0.050
mg/1
0.70
8260B
02/22/14
1549
RB 1
0.050
mg/1
0.50
8260B
02/22/14
1549
RB 1
0.050
mg/l
0.20
8260B
02/22/14
1549
RB 1
% Rec.
114.
8260B
02/22/14
1549
RB 1
% Rec.
125.
8260B
02/22/14
1549
RB 1
% Rec.
114.
8260B
02/22/14
1549
RB 1
% Rec.
128.
8260B
02/22/14
1549
RB 1
0.0050
mg/l
0.030
8081A
02/21/14
1559
CBB 1
0.0050
mg/l
0.020
8081A
02/21/14
1559
CBB 1
0.0050
mg/l
0.0080
8081A
02/21/14
1559
CBB 1
Page 5 of 10

OESC
I
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814269
Est. 1970
Emily Fentress
June 16,2014
- City of Raleigh'Neuse River WWTP
PO Box 590
Raleigh, NC 27602
ESC
Sample
# L683721-02
Date Received February 19, 2014
Description TCLP Sampling
Site
ID
Sample ID CLASS A-RALEIGH
PLUS
Project
Collected By Fentress
Collection Date 02/17/14 09:50
Parameter
Result
Det. Limit
Units
Limit
Method
Date/Time
By
Dil
Lindane
BDL
0.0050
mg/l
0.40
8081A
02/21/14
1559
CBB
1
Methoxychlor
BDL
0.0050
mg/1
10.
8081A
02/21/14
1559
CBB
1
Toxaphene
BDL
0.010
mg/1
0.50
8081A
02/21/14
1559
CBB
1
Surrogate Recovery
Decachlorobiphenyl
86.0
% Rec.
123.
8081A
02/21/14
1559
CBB
1
Tetrachloro-m-xylene
79.2
% Rec.
114.
8081A
02/21/14
1559
CBB
1
TCLP Herbicides
2,4,5-TP (Silvex)
BDL
0.0020
mg/1
1.0
8151A
02/25/14
2034
KLM
1
2,4-D
BDL
0.0020
mg/1
10.
8151A
02/25/14
2034
KLM
1
Surrogate Recovery
2,4-Dichlorophenyl Acetic Acid
77.4
% Rec.
8151A
02/25/14
2034
KLM
1
TCLP Semi-Volatiles
1,4-Dichlorobenzene
BDL
0.10
mg/l
7.5
8270D
02/23/14
0854
KMF
1
2,4-Dinitrotoluene
BDL
0.10
mg/1
0.13
8270D
02/23/14
0854
KMF
1
Hexachlorobenzene
BDL
0.10
mg/1
0.13
8270D
02/23/14
0854
KMF
1
Hexachloro-1,3-butadiene
BDL
0.10
mg/1
0.50
8270D
02/23/14
0854
KMF
1
Hexachloroethane
BDL
0.10
mg/1
3.0
8270D
02/23/14
0854
KMF
1
Nitrobenzene
BDL
0.10
mg/1
2.0
8270D
02/23/14
0854
KMF
1
Pyridine
BDL
0.10
mg/1
5.0
8270D
02/23/14
0854
KMF
1
3&4-Methyl Phenol
BDL
0.10
mg/1
400
8270D
02/23/14
0854
KMF
1
2-Methylphenol
BDL
0.10
mg/1
200
8270D
02/23/14
0854
KMF
1
Pentachlorophenol
BDL
0.10
mg/1
100
8270D
02/23/14
0854
KMF
1
2,4,5-Trichlorophenol
BDL
0.10
mg/1
400
8270D
02/23/14
0854
KMF
1
2,4,6-Trichlorophenol
BDL
0.10
mg/1
2.0
8270D
02/23/14
0854
KMF
1
Surrogate Recovery .
2-Fluorophenol
35.2
% Rec.
87.0
8270D
02/23/14
0854
KMF
1
Phenol-d5
29.9
% Rec.
67.0
8270D
02/23/14
0854
KMF
1
Nitrobenzene-d5
68.5
% Rec.
120.
8270D
02/23/14
0854
KMF
1
2-Fluorobiphenyl
79.3
% Rec.
122.
8270D
02/23/14
0854
KMF
1
2,4,6-Tribromophenol
77.8
% Rec.
148.
8270D
02/23/14
0854
KMF
1
p-Terphenyl-dl4
84.9
% Rec.
149.
8270D
02/23/14
0854
KMF
1
BDL - Below Detection Limit
Det. Limit - Estimated Quantitation Limit(EQL)
Limit - Maximum Contaminant Level as established by the US EPA
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 02/26/14 16:54 Revised: 06/16/14 08:58
L683721-02 (IGNITABILITY) - did not ignite @ 170F
Page 6 of 10

Emily Fentress
City of Raleigh Neuse River WWTP
PO Box 590
Raleigh, NC 27602
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
June 16,2014
ESC Sample # : L683721-03
Date Received February 19,
2014
Description TCLP Sampling
Site ID
Sample ID CLASS B-CADlCB11314
Project
Collected By Fentress
Collection Date 02/17/14 09:30
Parameter
Result Det. Limit
Units
Limit
Method
Date/Time
By
Dil
Corrosivity
Non-Corrosiv
9045D
02/26/14
1121
SDC
1
Ignitability
See Footnote
Deg. F
D93/101
02/25/14
1643
DR
1
Reactive CN (SW846 7.3.3.2)
BDL
0.125
mg/kg
9012B
02/23/14
1210
1
Reactive Sulf.(SW846 7.3.4.1)
BDL
25.
mg/kg
9034/90
02/22/14
1651
AS
1
TCLP Extraction
-
1311
02/20/14
0710
MVE
1
Mercury
BDL
0.0010
mg/1
0.20
7470A
02/20/14
2107
CCE
1
Arsenic
BDL
0.050
mg/l
5.0
6010B
02/20/14
2349
ST
1
Barium
BDL
0.15
mg/1
100
6010B
02/20/14
2349
ST
1
Cadmium
BDL
0.050
mg/1
1.0
6010B
02/20/14
2349
ST
1
Chromium
BDL
0.050
mg/l
5.0
6010B
02/20/14
2349
ST
1
Lead
BDL
0.050
mg/l
5.0
6010B
02/20/14
2349
ST
1
Selenium
BDL
0.050
mg/l
1.0
6010B
02/20/14
2349
ST
1
Silver
BDL
0.050
mg/1
5.0
6010B
02/20/14
2349
ST
1
TCLP ZHE Extraction
-
1311
02/22/14
0709
MVE
1
TCLP Volatiles
Benzene
BDL
0.050
mg/1
0.50
8260B
02/22/14
1607
RB
1
Carbon tetrachloride
BDL
0.050
mg/l
0.50
8260B
02/22/14
1607
RB
1
Chlorobenzene
BDL
0.050
mg/l
100
8260B
02/22/14
1607
RB
1
Chloroform
BDL
0.25
mg/l
6.0
8260B
02/22/14
1607
RB
1
1,2-Dichloroethane
BDL
0.050
mg/l
0.50
8260B
02/22/14
1607
RB
1
1,1-Dichloroethene
BDL
0.050
mg/l
0.70
8260B
02/22/14
1607
RB
1
2-Butanone (MEK)
BDL
0.50
mg/l
200
8260B
02/22/14
1607
RB
1
Tetrachloroethene
BDL
0.050
mg/l
0.70
8260B
02/22/14
1607
RB
1
Trichloroethene
BDL
0.050
mg/l
0.50
8260B
02/22/14
1607
RB
1
Vinyl chloride
BDL
0.050
mg/l
0.20
8260B
02/22/14
1607
RB
1
Surrogate Recovery
Toluene-d8
106.
% Rec.
114.
8260B
02/22/14
1607
RB
1
Dibromofluoromethane
106.
% Rec.
125.
8260B
02/22/14
1607
RB
1
a,a,a-Trifluorotoluene
99.3
% Rec.
114.
8260B
02/22/14
1607
RB
1
4-Bromofluorobenzene
90.7
% Rec.
128.
8260B
02/22/14
1607
RB
1
TCLP Pesticides
Chlordane
BDL
0.0050
mg/l
0.030
8081A
02/21/14
1612
CBB
1
Endrin
BDL
0.0050
mg/l
0.020
8081A
02/21/14
1612
CBB
1
Heptachlor
BDL
0.0050
mg/l
0.0080
8081A
02/21/14
1612
CBB
1
L683721-03 (IGNITABILITY) - did not
ignite @ 170F
Page 7 of
10

i
JOESC
L-A•9 S•C-I•E•N•C•E•S
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
REPORT OF ANALYSIS
Emily Fentress
June
16,2014
City of Raleigh Neuse River WWTP
PO Box 590
Raleigh, NC 27602
ESC
Sample
# L683721-03
Date Received February 19, 2014
Description TCLP Sampling
Site
ID
Sample ID CLASS B-CADlCB11314
�
Project
Collected By Fentress
Collection Date 02/17/14 09:30
Parameter
Result
Det. Limit
Units
Limit
Method
Date/Time
By
Dil
Lindane
BDL
0.0050
mg/1
0.40
8081A
02/21/14
1612
CBB
1
Methoxychlor
BDL
0.0050
mg/1
10.
8081A
02/21/14
1612
CBB
1
Toxaphene
BDL
0.010
mg/1
0.50
8081A
02/21/14
1612
CBB
1
Surrogate Recovery
Decachlorobiphenyl
92.0
% Rec.
123.
8081A
02/21/14
1612
CBB
1
Tetrachloro-m-xylene
81.1
% Rec.
114.
8081A
02/21/14
1612
CBB
1
TCLP Herbicides
2,4,5-TP (Silvex)
BDL
0.0020
mg/1
1.0
8151A
02/25/14
2048
KLM
1
2,4-D
BDL
0.0020
mg/1
10.
8151A
02/25/14
2048
KLM
1
Surrogate Recovery
2,4-Dichlorophenyl Acetic Acid
100.
% Rec.
8151A
02/25/14
2048
KLM
1
TCLP Semi-Volatiles
1,4-Dichlorobenzene
BDL
0.10
mg/1
7.5
8270D
02/23/14
0918
KMF
1
2,4-Dinitrotoluene
BDL
0.10
mg/l
0.13
8270D
02/23/14
0918
KMF
1
Hexachlorobenzene
BDL
0.10
mg/1
0.13
8270D
02/23/14
0918
KMF
1
Hexachloro-1,3-butadiene
BDL
0.10
mg/1
0.50
8270D
02/23/14
0918
KMF
1
Hexachloroethane
BDL
0.10
mg/1
3.0
8270D
02/23/14
0918
KMF
1
Nitrobenzene
BDL
0.10
mg/1
2.0
8270D
02/23/14
0918
KMF
1
Pyridine
BDL
0.10
mg/l
5.0
8270D
02/23/14
0918
KMF
1
3&4-Methyl Phenol
BDL
0.10
mg/1
400
8270D
02/23/14
0918
KMF
1
2-Methylphenol
BDL
0.10
mg/1
200
8270D
02/23/14
0918
KMF
1
Pentachlorophenol
BDL
0.10
mg/1
100
8270D
02/23/14
0918
KMF
1
2,4,5-Trichlorophenol
BDL
0.10
mg/1
400
8270D
02/23/14
0918
KMF
1
2,4,6-Trichlorophenol
BDL
0.10
mg/1
2.0
8270D
02/23/14
0918
KMF
1
Surrogate Recovery
2-Fluorophenol
37.8
% Rec.
87.0
8270D
02/23/14
0918
KMF
1
Phenol-d5
29.3
% Rec.
67.0
8270D
02/23/14
0918
KMF
1
Nitrobenzene-d5
65.5
% Rec.
120.
8270D
02/23/14
0918
KMF
1
2-Fluorobiphenyl
78.5
% Rec.
122.
8270D
02/23/14
0918
KMF
1
2,4,6-Tribromophenol
70.5
% Rec.
148.
8270D
02/23/14
0918
KMF
1
p-Terphenyl-dl4
85.1
% Rec.
149.
8270D
02/23/14
0918
KMF
1
BDL - Below Detection Limit
Det. Limit - Estimated Quantitation Limit(EQL)
Limit - Maximum Contaminant Level as established by the US EPA
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 02/26/14 16:54 Revised: 06/16/14 08:58
L683721-03 (IGNITABILITY) - did not ignite @ 170F
Page 8 of 10

Attachment A
List
of Analytes with QC Qualifiers
Sample
Work
Sample
Number
Group
Type
Analyte
L683721-01
WG707374
SAMP
2,4,5-Trichlorophenol
WG707374
SAMP
2,4,6-Trichlorophenol
WG707850
SAMP
2,4,5-TP (Silvex)
L683721-02
WG707374
SAMP
2,4,5-Trichlorophenol
WG707374
SAMP
2,4,6-Trichlorophenol
WG707850
SAMP
2,4,5-TP (Silvex)
WG707328
SAMP
Silver
L683721-03
WG707850
SAMP
2,4,5-TP (Silvex)
Run
ID Qualifier .
R2887602 J3
R2887602 J3
R2888307 J3
R2887602 J3
R2887602 J3
R2888307 J3
R2887681 O1J6J3
R2888307 J3
Page 9 of 10

Attachment B
Explanation of QC Qualifier Codes
- Qualifier Meaning
J3 The associated batch QC was outside the established quality control range
for precision.
J6 The sample matrix interfered with the ability to make any accurate
determination; spike value is low
01 (ESC) The analyte failed the method required serial dilution test and/or
subsequent post -spike criteria. These failures indicate matrix
interference.
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC.
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods,it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
"unless qualified as 'R' (Rejected)."
Definitions
Accuracy - The relationship of the observed value of a known sample to the
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
Precision - The agreement between a set of samples or between duplicate samples.
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Surrogate - Organic compounds that are similar in chemical composition, extraction,
and chromotography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
TIC - Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
Page 10 of 10

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO060526 Source Name Pope Industrial Park
Laboratory 1 Environment
1, Inc.
Laboratory 2
Sample or CompositeDate 5/29/2014
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
7,438
Ammonia Nitrogen
N/A
N/A
289
Arsenic
41
75
2.5
Cadmium
39
85
0.7
Calcium
N/A
N/A
15,411
Copper
1,500
4,300
483
Lead
300
840
10
Magnesium
N/A
N/A
3,424
Mercury
17
57
0.58
Molybdenum
N/A
75
5
Nickel
420
420
11
Nitrate -Nitrite Nitrogen
N/A
N/A
34.89
Percent Solids
N/A
N/A
0.30
pH (no units)
N/A
N/A
7.00
Phosphorus
N/A
N/A
4,848
Potassium
N/A
N/A
8,638
PAN (Inj./Inc.)
N/A
N/A
8,442
PAN (Surface)
N/A
N/A
8,298
Selenium
100
100
5
Sodium
N/A
N/A
33,386
SAR
N/A
N/A
3.46
TKN
N/A
N/A
27,351
Zinc
2,800
7,500
488
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

FIELD LOADING ESTIMATES
Facility Pope Industrial Park
Sampling Date 5/29/2014
% Solids 0.3
Mineralization Rate 0.3
Gallons per DT 79,936.05
PH 7
Sodium Absorpotion 3.46 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land ripply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 27,351 lbs./1,000 gal 0.68
Potassium lbs./1,000 gal
0.22
Ammonia Nitrogen (mg/Kg) 289.00 lbs./1,000 gal 0.01
Phosphorus lbs./1,000 gal
0.12
Nitrate -Nitrite (mg/Kg) 34.89 lbs./1,000 gal U0
Calcium lbs./1,000 gal
0.39
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.09
PAN (mg/Kg) 8,298 lbs./1,000 gal 0.21
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 8,442 lbs./1,000 gal 0.21
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface.Application
1.0 Injection/Incorporation
EPA METAL LIMITS
-, 1stYear
2nd Year
3rd Year
i
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
2.50
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.70
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
483.00
Copper lbs./1,000 gal
0.01
Lead (mg/Kg)
10.00
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.58
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
11.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
488.00
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TIN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
27,351
8,298
16.60
19,053
27,351
8,442 16.88
18,909
19,053
2,858
5.72.
16,195
18,909
2,836 5.67
16,072
16,195
1,215
2.43
14,980
16,072
1,205 2.41
14,867
14,980
562
1.12
14,419
14,867
558 1.12
14,309
14,419
270
0.54
14,148
14,309
268 0.54
14,041
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 13,203 26.41
Total 13,310 26.62

POPE INDUSTRIAL PARK
C/O ESNVIROLINK
P.O. BOX 670
DAILEY ,NC 27007
FARANIETRRS
PH (not to be used For reporih(g)
Aluminum, (dry wt. basis), mg/kg
Arsente (dry wt. basis), uFgfkg
Calcium (dry wt, basis), mg/kg
Cadmium (dry wt, basis), mg/kg
Copper (dry wt. basis), mg/kg
Chromium, T.(dry %vt, basts),mg/1cg
Lead (dry weight basis), mg/kg
Magnesium (dry wt. basis), mg/kg
Mercury (dry wt. basis), mg/kg
Nickel (dry wt, basis), nngfkg
Potassium (dry wt. basis), mg/kg
Selenium (dry wt, basis), mg/kg
Sodium (dry wt, basis), mg/kg
Zinc (dry wt. basis), mg/kg
Total Solids, %
TKN (dry wt,), mg/Icg
Aunnonla Nitrogen (dry wt.),mg/kg
Phosphorus, T. (dry wt.), ing/kg
Nitrate -Nitrite (dry wt.), mg/kg
Plant Available Nitrogen, mg/kg
A-folybdemim (dry III, basis), mg/kg
Sludge
Analysis
Method
Sample
Date Aoalyst
Cole
7,0
05/29/14 TRB
450ORB-00
1438
06104/14 LFJ
EPA200.7
<2.5
07/02/14 MI
3113B.04
15411
06/04J14 LFJ
) PA200,7
0.7
06/06/14 MEL
3113B-04
483
06/04/14 LFJ
EPA200.7
7
06/04/14 LFJ
NPA200.7
10
07101/14 MBL
3113B-04
3424
06/04/14 LFJ
EPA200.7
0.58
06/19/14 A4TA4
245.1 R3.94
11
06/04/14 LFJ
EPA200.7
8638
06/04/14 LFJ
BPA200.1
<5,0
06104/14 MEL
3113B•04
33386
06/10/14 APIA-1
3111B-99
488
06/09114 MTM
3111B-99
0.30
05/30/14 MY
2540G-97
27351
06/05/14 ANO
351.2 R2-93
289
06/03/89 ALB
350.1 R2-93
4848
06/05/14 ALB
365.4 -74
34,89
06/04/14 ANO
353.2 R2-93
8198
06/06/14 SEJ
<5.0
06104(14 LFJ
EPA200,7
ID#t 63 A
DATE COLL$CTED1 05/29/14
DATERSPORTRD s 07/02/14
f
1113VI111411D aX 6 ��` •r

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Grannrille Farms, Inc. Class B Source Permit No. 02-39-107 Source None SGWASA W'11-1
Laboratory 1 Aleriach, Inc
Laboratory 2
Sample or CompositeDate 10/21/2014
Parameter (mg/Kg) Class A Clas B
136,000
AmmoN/A
303
uCaki.-
75
2.15
85
0303
N/A
593
CopperN/A
Copper
1,500
4,300
12-1
Lead
300
840
4.8t
Magnesium
N/A
N/A
282
Mercury
17
57
0.089
Molybden
N/A
75
0.757
Nickel
420
420
3.91
Nitrate Ktete 1�Iitrogen
N/A
N/A
303
Percent Solids
N/A
N/A
330
pH (no units)
N/A
N/A
630
Phosphorus
N/A
N/A
1210
Potassium
N/A
N/A
245
PAN (Inj./Inc.)
N/A
N/A
U21
PAN (Surface)
N/A
N/A
Z669
Selenium
100
100
152
Sodium
N/A
N/A
dt8
S
N/A
N/A
064
TKN
N/A
N/A
5"0
Zinc
2,8(10
7,500
31
"1 certify, under penalty of law, that Ibis document was prepared under my direction or supervision in accordance with a system designed to
assute that qua 'Nixed personnel properly gathered and evaluated the information submitted_ I am aware that there are significant penalties for
submitting false infotrnati including the possibility of fines and imprisonment for knowing violations:"
Signature o£ Peep xter Date
*P'reparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

A.GMAN
4 Facility SGWASA WTP
r
Sampling Date 10/21/2014
if
% Solids 3.3
Mineralization Rate 0.4
Gallons per DT 7,266.91
PH 6.3
FIELD LOADING ESTIMATES
Sodium Absorpotion 0.64 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio ,
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 5,840 lbs./1,000 gal 1,61
Ammonia Nitrogen (mg/Kg) 303.00 lbs./1,000 gal 0.08
Nitrate -Nitrite (mg/Kg) 303.00 lbs./1,000 gal 0.08
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 2,669 lbs./1,000 gal 0.73
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 2,821 lbs./1,000 gal 0.78
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Potassium lbs./1,000 gal
0.07
Phosphorus lbs./1,000 gal
0.33
Calcium lbs./1,000 gal
0.16
Magnesium lbs./1,000 gal
0.08
Manganese lbs./1,000 gal
2.92
Sulfur lbs./1,000 gal
6.47
Molybdenum lbs./1,000 gal
0.00
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
HEAVY METAL CONCENTRATION
HEAVY METAL LOADING
41
75
Arsenic (mg/Kg)
2.15
Arsenic lbs./1,000 gal
0.00
39
85
Cadmium (mg/Kg)
0.30
Cadmium lbs./1,000 gal
0.00
1,500
4,300
Copper (mg/Kg)
127.00
Copper lbs./1,000 gal
0.03
300
840
Lead (mg/Kg)
4.81
Lead lbs./1,000 gal
0.00
17
57
Mercury (mg/Kg)
0.09
Mercury lbs./1,000 gal
0.00
420
420
Nickel (mg/Kg)
3.91
Nickel lbs./1,000 gal
0.00
100
100
Selenium (mg/Kg)
1.52
Selenium lbs./1,000 gal
0.00
2,800
7,500
Zinc (mg/Kg)
30.00
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
1st Year
i
2nd Year
3rd Year
4th Year
5th Year
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
TEN
PAN
PAN
Nitrogen
TKN
PAN' PAN
Nitrogen
(mg/kg) (lbs/DT)
(mg/Eg)
(mg/kg) (lbs/DT)
(mg/Eg)
5,840
2,669
5.34
3,171
5,840
2,821 5.64
3,019
3,171
634
1.27
2,537
3,019
604 1.21
2,415
2,537
254
0.51
2,283
2,415
242 0.48
2,174
2,283
114
0.23
2,169
2,174
109 0.22
2,065
2,169
54
0.11
2,115
2,065
52 0.10
2,014
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 3,725 7.45
Total 3,826 7.65

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Contact Mickey Alston
Client: SGWASA-Wl'P
415 Central Ave. #B
Butner, NC 27509
Report Date: 11/4/2014
Date Sample Rcvd: 10/21/2014
Meritech Work Order #
102114132
Sample: WTP Sludge Tank Grab
10/21/14
Parameters
Result
Analysis Date Re portinglimft
Metbod
% Dry Weight
15.4 %
10/22/14
- %
SM 2540B
Ammonia, Nitrogen
< 64.9 mg/kg
10/22/14
64.9 mg/kg
EPA 350.1
TKN
Nitrate/Nitrite, Nitrogen
1,250 mg/kg
< 64.9 mg/kg
10/28/14
10/23/14
20 mg/kg
64.9 mg/kg
EPA 351.1
EPA 353.2
Nitrogen, total
1,250 nig/kg
10/30/14
20 nig/kg
EPA 353.2
Aluminum, total
Arsenic, total
29,200 mg/kg
11/3/14
2.50 mg/kg
EPA 200.7
Cadmium, total
0.461 mg/kg
< 0.065 mg/kg
11/3/14
11/3/14
47.8 mg/kg
0.065 mg/kg
EPA 200.7
EPA 200.7
Calcium, total
Chrolnium, total
127 mg/kg
11/3/14
10.0 mg/kg
EPA 200.7
Copper, total
21.9 tng/kg
27.3 mg/kg
11/3/14
11/3/14
0.250 mg/kg
1.00 mg/kg
CPA 200.7
EPA 200.7
Lead, total
Magnesium, total
1.03 mg/kg
60.4 mg/kg
11/3/14
11/3/14
2.0 mg/kg
EPA 200.7
Manganese, total
22ZO..
...........
10.0 mg/kg
.......0.250-mk
EPA 200.7
Mercury, total
Molybdenum, total
0.019 mg/kg
10/24/14
0.01 mg/kg
EPA 245.1
Nickel, total
<.0.162 mg/kg
0.838 mg/kg
11/3/14
0.162 mg/kg
EPA 200.7
Phosphorus, total
260 mg/kg
11/3/14
11/3/14
2.0 mg/kg
2.00 mg/kg
EPA 200.7
EPA 200.7
Potassittm, total
Selenium, total
52.4 mg/kg
11/3/14
20.0 .rng/kg
EPA 200.7
Sodium, total
< 0.325 ntg/kg
89.6 mg/kg
11/3/14
11/3/14
0.325 mg/kg
EPA 200.7
Sulfate
5,030 mg/kg
10/29/14
20.0 mg/kg
500 mg/kg
EPA 200.7
SW 846 9038
Zinc, total
pf1
6.42 nrg/kg
11/3/14
0.500 mg/kg
EPA 200.7
6.3 S.U.
10/22/14
1.0 - 14.0 S.U.
SM 4500-HB
I hereby certify that I have reviewed and approve these data.
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
XV0, Permit No. WQ0000838 Facility Name Granville Lanus, Inc. Crass B Source Pcrmic No. NIC0026824 Source Name SGWASA MVTP
Lahoratoryll Lfcrimch, Cne. \(aiteeh, Inc \ferilcch, [nc JEcritech, Inc
SampleorCompositeDate
Parameter (mg/Kg)
Aluminum
mmonia Nitrogen
Arsenic
Cadmium
i_ Calcium
Copper
Lead
Class A
NjA'
N/A
41
39
N/A
1,-00
300
Clas B
- NSA
N/A
--- 75
85
N/A
4,3Q0
840
2/7/20]4
27,700
16,700
L67
[.l7
[0,300
397
14.7
4/24/20t4
-
27,857
`1,180
`1.79
L17
9,642
4(!4
77.5
4,035
7/22/20I4
—
28,500
407--- -
2.03
t.63
1130(1
4It
126
Sr40
l0/21/2014
33,8100
—478
47.5
lA8
12,200
44(1
23
S,;bO
Magnesium
N/AV42O14.8
Mercu
17
C1.ISG
OLI
(1.053
Molybdenu
7 71
7-U
7.75
Nickel
;420
16.9
[8.8
[s.9
NitaateNiesitc.{itragcn
N/A
N/A
1,76U
t,730
2460
3,730
Percent Solids
N/A
NjA
3.[0
288
2.46
? t19
PH (no units)
N/A
N/A
-1.53
5.07
4.70
Iva
— Phosphorus
N/A
N/A
37,300
39,Cr43
39,703
44,300
Potassium
—PAN([mj./Inc.}
N/A
N/A
42513
4,724
5,-,3U
5,8tQ
�PAN
N/A
N/A
2[,400
22,276
13,815
[I,i05
(SurFace}
1'/A
NjA
I3,050
11,686
13,6[t
11,466
----- Selenium
100
100
167
1.79
6.79
4.78
sadiurn
N/A
N/A
2,160
2,114
2-790 --
3,�1
SAR
N/A
N/A
OBI
077
0.85
0,84
TKN
N/A
N/A
26, W
32,403
36 9(D7
25,4d10
Zinc
2,8Q0
7,500
"I certify, under penalty
oflaw,
that this
70
document
736
6S7
,5
assure that ned
Qualif
Personnel
was re
prepared
properly gathered and evaluated
under my din`ction or supervision in accordance with a system designed to
ned
submitting false information,
tlse iniumwa ian submitted I am aware that clrere are signi5cant penalties for
including the passibility of fines and imprisonment ror knoccitta violations
#
Signature of Pteparer
Date
*Preparer is defaced
in 49 CL
R Part s03.9(r) and 1SA NCAC 2T M02 (26)

FIELD LOADING ESTIMATES
Facility SGWASA WWFP
Sampling Date 2/7/2014
% Solids 3.1
Mineralization Rate 0.3
Gallons per DT 7,735.75
PH 4.53
Sodium Absorpotion 0.81 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 26,500 lbs./1,000 gal 6.85
Potassium lbs./1,000 gal
1.10
Ammonia Nitrogen (mg/Kg) 16,700.00 lbs./1,000 gal 4.32
Phosphorus lbs./1,000 gal
9.64
Nitrate -Nitrite (mg/Kg) 1,760.00 lbs./1,000 gal 0.46
Calcium lbs./1,000 gal
2.66
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
1.02
PAN (mg/Kg) 13,050 lbs./1,000 gal 3.37
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 21,400 lbs./1,000 gal 5.53
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
I
r_• 1st Year
I
_ 2nd Year
3rd Year
4th Year
i
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
1.67
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.17
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
397.00
Copper lbs./1,000 gal
0.10
Lead (mg/Kg)
14.70
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.50
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
14.80
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
1.67
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
763.00
. Zinc lbs./1,000 gal
0.20
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
TEN
PAN
PAN
Nitrogen
TKN
PAN PAN
Nitrogen
(mg/kg) (lbs/DT)
(mg/Rg)
(mg/kg) (lbs/DT)
(mg/Kg)
26,500
13,050
26.10
13,450
26,500
21,400 42.80
5,100
13,450
2,018
4.04
11,433
5,100
765 1.53
4,335
11,433
857
1.71
10,575
4,335
325 0.65
4,010
10,575
397
0.79
10,178
4,010
150 0.30
3,860
10,178
191
0.38
9,988
3,860
72 0.14
3,787
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NI3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
iotat 16,51L 33.uz Total 22,713 45.43

Meritech, Inc.
Environmental Laboratory
k, Laboratory Certification No.165
- Revised Date: 21712014
Contact: Brenda Johnson/ Will Lawson Report Date: 2/3/2014
Client: SGWASA- WWTP NPDES#: NC0026824
415 Central Ave..#B Project: Tanker Sludge 1st Qtr
Butner, NC 27509 Date Sample Rcvd: 1/16/2014
Meritech Work Order # 01161461 Sample: Tanker Sludge, Grab
Pa- rat eters BeSlllt Ana
1/16/14
% Dry Solids
3.10 %
yis Da
1/20/14
RainLimit
- %
Method
SM 2540B
- Chloride
Ammonia, Nitrogen
-
6,450 mg/kg
16,700 mg/kg
1/20/14
1/27/14
10.0 mg/kg
345 mg/kg
SM 4500 Cl C
EPA 350.1
TKN
Nitrate/Nitrite, Nitrogen
26,500 mg/kg
1,760 mg/kg
1/24/14
1/17/14
20 mg/kg
31.3 mg/kg
EPA 351.1
EPA 353.2
Nitrogen, total
28,300 mg/kg
1/27/14
20 mg/kg
EPA 353.2
Aluminum, total
Antimony, total
27,700 mg/kg
1/20/14
2.50 mg/kg
EPA 200.7
Arsenic, total
7.16 mg/kg
< 1.67 mg/kg
1/31/14
1/31/14
2.5 mg/kg
1.67 mg/kg
EPA 200.7
EPA 200.7
Cadmium, total
Calcium, total
1.17 mg/kg
1/31/14
0.200 mg/kg
EPA 200.7
Chromium, total
10,300 mg/kg
70.0 mg/kg
1/31/14
1/31/14
10.0 mg/kg
0.250 mg/kg
EPA 200.7
EPA 200.7
Copper, total
Iron, total
397 mg/kg
1/31/14
1.00 mg/kg
EPA 200.7
Lead, total
12,200 mg/kg
14.7 mg/kg
1/31/14
1/31/14
1.25 mg/kg
2.0 mg/kg
EPA 200.7
EPA 200.7
Magnesium, total
Mercury, total
3,930 mg/kg
1/31/14
10.0 mg/kg
EPA 200.7
Molybdenum, total
0.500 mg/kg
7.47 mg/kg
1/21/14
1/31/14
0.10 mg/kg
0.500 mg/kg
EPA 245.1
EPA 200.7
Nickel, total
Phosphorus, total
14.8 mg/kg
37,300 mg/kg
1/31/14
1/31/14
2.0 mg/kg
2.00 mg/kg
EPA 200.7
EPA 200.7
Potassium, total
Selenium, total
4,258 mg/kg
1131114
20.0 mglkg
EPA 200.7
Silver, total
< 1.67 mg/kg
1.33 mg/kg
1/31/14
1/31/14
1.67 mg/kg
1.0 mg/kg
EPA 200.7
EPA 200.7
Sodium, total
Sulfate
2,160 mg/kg
1/31/14
20.0 mg/kg
EPA 200.7
Zinc, total
24,200 mg/kg
763 mg/kg
1/20/14
1/31/14
500 mg/kg
0.500 mg/kg
SW 846 9038
EPA 200.7
i--
I * All calculated on the dry weight basis.
I hereby certify that I have reviewed and approve these data.
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

r
I
t_
' t�yt AGMAN
i Facility SGWASA WWTP
Sampling Date 4/24/2014
% Solids 2.88
Mineralization Rate 0.3
Gallons per DT 8,326.67
pH 5.07
FIELD LOADING ESTIMATES
Sodium Absorpotion 0.77 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land ripply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 32,400 lbs./11000 gal 7.78
Ammonia Nitrogen (mg/Kg) 1,180.00 lbs./1,000 gal 0.28
Nitrate -Nitrite (mg/Kg) 1,730.00 lbs./1,000 gal 0.42
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 11,686 lbs./1,000 gal 2.81
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 12,276 lbs./1,000 gal 2.95
Volatization Rate= 0.5 Surface Application
1.0 Injection/ Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
j 1st Year
I
2nd Year
3rd Year
4th Year
5th Year
i
HEAVY METAL CONCENTRATION
Potassium lbs./1,000 gal 1.13
Phosphorus lbs./1,000 gal 9.52
Calcium lbs./1,000 gal 2.32
Magnesium lbs./1,000 gal 0.97
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
1.79
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.17
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
404.00
Copper lbs./1,000 gal
0.10
Lead (mg/Kg)
17.50
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.16
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
16.90
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
1.79
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
736.00
. Zinc lbs./1,000 gal
0.18
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
TKN
PAN
PAN
PAN
Nitrogen
T
PAN PAN
Nitrogen
(lbs/DT)
(mg/4)
(mg/kg) (lbs/DT)
(mg/Yg)
32,400
11,686
23.37
20,714
32,400
12,276 24.55
20,124
20,714
3,107
6.21
17,607
20,124
3,019 6.04
17,105
17,607
1,321
2.64
16,286
17,105
1,283 2.57
15,822
16,286
611
1.22
15,676
15,822
593 1.19
15,229
15,676
294
0.59
15,382
15,229
286 0.57
14,944
l otal 17,U18 34.U4
Total 17,456 34.91
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/l6)

Meritech, Inc.
Environmental Laboratory
=3` Laboratory Certification No.165
s
Contact: Brenda Johnson/ Will Lawson
_. Client: Butner WWTP (SGWASA)
415 Central Ave. #B
Butner, NC 27509
Meritech Work Order # 040914119
Parameters
% Total Solids
Chloride
Ammonia, Nitrogen
TKN
Nitrate/Nitrite, Nitrogen
Nitrogen, total
Aluminum, total
Antimony, total
Arsenic, total
Cadmium, total
Calcium, total
Chromium, total
Copper, total
Iron, total
Lead, total
Magnesium, total
Mercury, total
Molybdenum, total
Nickel, total
Phosphorus, total
.Potassium, total
Selenium, total
Silver, total
Sodium, total
Sulfate
Zinc, total
Result
Sample: Tanker Sludge Grab
2.88 %
3;250 mg/kg
1,180 mg/kg
32,400 mg/kg
1,730 mg/kg
34,100 mg/kg
27,857 mg/kg
4.89 mg/kg
< 1.79 mg/kg
1.17 mg/kg
9,642 mg/kg
73.9 mg/kg
404 mg/kg
13,321 mg/kg
17.5 mg/kg
4,035 mg/kg
0.156 mg/kg
7.71 mg/kg
16.9 mg/kg
39,643 mg/kg
4,724 mg/kg
< 1.79 mg/kg
1.57 mg/kg
2,114 mg/kg
48,600 mg/kg
736 mg/kg
4/11/14
4/17/14
4/14/14
4/15/14
4/11/14
4/18/14
4/14/14
4/14/14
4/14/14
4/14/14
4/14/14
4/14/14
4/14/14
4/14/14
4/14/14
4/14/14
4/14/14
4/14/14
4/14/14
4/14/14
4114114
4/14/14
4/14/14
4/14/14
4/16/14
4/14/14
Revised Date.
Report Date:
NPDES#:
Project:
Date Sample Rcvd:
Reporting Limit
0-100
10 mg/kg
345 mg/kg
20 mg/kg
31.3 mg/kg
20 mg/kg
2.50 mg/kg
2.5 mg/kg
1.67 mg/kg
0.200 mg/kg
10.0 mg/kg
0.250 mg/kg
1.00 mg/kg
1.25 mg/kg
2.0 mg/kg
10.0 mg/kg
0.10 mg/kg
0.500 mg/kg
2.0 mg/kg
2.00 mg/kg
2 0, 0 mg/1(9
1.67 mg/kg
1.0 mg/kg
20.0 mg/kg
500 mg/kg
0.500 mg/kg
4/24/2014
4/22/2014
NCO026824
Tanker Sludge
4/9/2014
4/9/14
to
SM 2540B
SM 4500 Cl C
EPA 350.1
EPA 351.1
EPA 353.2
EPA 353.2
EPA 200.7
EPA 200.7
EPA 200.7
EPA 200.7
EPA 200.7
EPA 200.7
EPA 200.7
EPA 2003
EPA 200.7
EPA 200.7
EPA 245.1
EPA 200.7
EPA 200.7
EPA 200.7
EPA 200.7
EPA 200.7
EPA 2003
EPA 200.7
SW 846 9038
EPA 200.7
i
Lhereby certify that I have reviewed and approve these data.
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

V�r✓ LF3i
Facility SGWASA WWTP
Sampling Date 7/22/2014
% Solids 2.46
FIELD LOADING ESTIMATES
Mineralization Rate 0.3
Gallons per DT 9,748.30
PH 4.7
Sodium Absorpotion 0.85 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land ripply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 36,900 lbs./1,000 gal 7.57
Potassium lbs./1,000 gal
1.18
Ammonia Nitrogen (mg/Kg) 407.00' lbs./1,000 gal 0.08
Phosphorus lbs./1,000 gal
8.15
Nitrate -Nitrite (mg/Kg) 2,460.00 lbs./1,000 gal 0.50
Calcium lbs./1,000 gal
2.32
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
1.08
PAN (mg/Kg) 13,611 lbs./1,000 gal 2.79
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 13,815 lbs./1,000 gal 2.83
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Limits (mg/Kg)
41
1 st Year
fi 2nd Year
3rd Year
4th Year
5th Year
Class B Ceiling
Limits (mg/Kg)
75
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
2.03
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.63
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
431.00
Copper lbs./1,000 gal
0.09
Lead (mg/Kg)
19.60
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.61
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
18.80
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
6.79
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
687.00
Zinc lbs./1,000 gal
0.14
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
TEN
PAN
PAN
Nitrogen
TKN
PAN PAN
Nitrogen
(mg/kg) (Ibs/DT)
(mg/Kg)
(mg/kg) (lbs/DT)
(mg/Kg)
36,900
13,611
27.22
23,289
36,900
13,815 27.63
23,085
23,289
3,493
6.99
19,795
23,085
3,463 6.93
19,622
19,795
1,485
2.97
18,311
19,622
1,472 2.94
18,151
18,311
687
1.37
17,624
18,151
681 1.36
17,470
17,624
330
0.66
17,294
17,470
328 0.66
17,142
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 19,606 39.21
Total 19,758 39.52

Meritech, Inc.
Environmental Laboratory
t `
Laboratory
Certification No.165
;'ems" '•t
Report Date:
7/22/2014
Contact: Brenda Johnson/ Will
Lawson
NPDES#:
NC0026824
Client: SGWASA- WWTP
Project:
Tanker Sludge
415 Central Ave. #B
Date Sample Rcvd:
7/8/2014
Butner, NC 27509
Meritech Work Order # 07081439 Sample: Tanker Sludge Grab
7/8/14
Result
Analysis Date Roartmg
Limit,
Method
�ara�neters
% Total Solids
2.46 %
7/9/14
7/15/14
0-100 %
10 mg/kg
SM 2540B
SM 4500 CI C
Chloride
3,800 m
mg/kg
< 407 mg/kg
7/10/14
407 m
mg/kg g
EPA 350.1
Ammonia, Nitrogen
36,900 mg/kg
7/21/14
20 mg/kg
EPA 351.1
TKN
Nitrate/Nitrite, Nitrogen
2,460 mg/kg
9 14
7 / /
7/21/14
31.3 mg/kg
20 mg/kg
EPA 353.2
53.
EPA 353.2
Nitrogen, total
39,400 mg/kg
28,50mg/kg
mg/kg
7/16/14
2.50 mg/
EPA
Aluminum, total
Antimony, total
< 5.08 m k
g/ g
7 / 16 14 /
5.08 mg/kg
2.03 mg/kg
EPA 200.7
EPA 200.7
Arsenic, total
< 2.03 mg/kg
1.63 m
mg/kg g
7/16/14
7/16/14
0.200 mg/kg
EPA 200.7
Cadmium, total
Calcium, total
11,300 mg/kg
7/16/14
10.0 mg/kg
0.250 mg/kg
EPA 200.7
EPA 200.7
Chromium, total
72.4 mg/kg
431 to k
g/ g
7/16/14
7/16/14
1.00 mg/kg
EPA 200.7
Copper, total
Iron, total
14,500 mg/kg
7/16/14
1.25 mg/kg
2.0 mg/kg
EPA 200.7
EPA 200.7
Lead, total
19.6 mg/kg
5,240 mg/kg
7/16/14
7/1G/14
10.0 m k
mg/kg
EPA 200.7
Magnesium, total
Mercury, total
0.610 mg/kg
7/14/14
0.10 rng/ kg
0.500 mg/kg
EPA 245.1
EPA 200.7
Molybdenum, total
7.52 mg/kg
18.8 mg/kg
7/16/14
7/16/14
2.0 mg/kg
EPA 200.7
Nickel, total
Phosphorus, total
39,700 m
mg/kg g
7/16/14
2.00 mg/kg
20.0 mg/kg
EPA 200.7
EPA 200.7
Potassium, total
5,730.79 mg/kg
6.79 mg/kg
7/16/14
16 14
7/ /
1.67 mg/kg
EPA 200.7
Selenium, total
Silver, total
1.42 mg/kg
7/16/14
1.0 m k
g/ g
0.0
20.0 mg/kg
EPA 200.7
EPA 200.7
Sodium, total
2,780 mg/kg
2,520 mg/kg
7/16/14
7/16/14
mg/kg
SW 846 9038
Sulfate
Zinc, total
687 mg/kg
7/16/14
OS00 mg/kg
EPA 200.7
I hereby certify that have reviewed and approve these data- Laboratory Rep esentative
642 Tamco Road, Reidsville, North Carolina 27320
toi rigiM47-4748 fax.f3361342-1522

FIELD LOADING ESTIMATES
Facility SGWASA WWTP
Sampling Date 10/21/2014
% Solids 2.09
Mineralization Rate 0.3
Gallons per DT 11,474.07
pH 5
Sodium Absorpotion 0.84 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 25,400 lbs./1,000 gal 4.43
Potassium lbs./1,000 gal
1.02
Ammonia Nitrogen (mg/Kg) 478.00 lbs./1,000 gal 0.08
Phosphorus lbs./1,000 gal
7.72
Nitrate -Nitrite (mg/Kg) 3,750.00 lbs./1,000 gal 0.65
Calcium lbs./1,000 gal
2.13
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.93
PAN (mg/Kg) 11,466 . lbs./1,000 gal 2.00
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 11,705 lbs./1,000 gal 2.04
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling Class B Ceiling
Limits (mg/Kg) Limits (mg/Kg)
41 1 75
I
I st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
47.80
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
1.48
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
440.00
Copper lbs./1,000 gal
0.08
Lead (mg/Kg)
23.00
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.05
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
18.90
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
4.78
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
675.00
Zinc lbs./1,000 gal
0.12
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
25,400
11,466 22.93
13,934
25,400
11,705 23.41
13,695
13,934
2,090 4.18
11,844
13,695
2,054 4.11
11,641
11,844
888 1.78
10,956
11,641
873 1.75
10,768
10,956
411 0.82
10,545
10,768
404 0.81
10,364
10,545
198 0.40
10,347
10,364
194. 0.39
10,170
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 15,053 30.11
Total 15,230 30.46

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
i¢ . a •.:: a
Contact: Brenda Johnson/ Will Lawson
Client: SGWASA- W WTP
415 Central Ave. #B
Butner, NC 27509
Report Date:
NPDES#:
Project-:
Date Sample Rcvd:
10/21/2014•
NCO02.6824
Tanker Sludge
4th Qtr Monitoring
10/7/2014
Meritech Work Order #
100714106
Sample: Tanker Sludge Grali
10/7/14
Paranatel;s
Resul
Analysts Date Reporting Limit
Mahod
% Total Solids
Chloride
2.09 %
10/8/14
0-100 %
SM 2540B
Ammonia, Nitrogen
4,780 mg/kg
< 478 mg/kg
10/13/14
10/13/14
10 mg/kg
478 nig/kg
SM 4500 CI C
EPA 350.1
TEN
25,400 mg/kg
10/15/14
20 mg/kg
EPA 351.1
Nitrate/Nitrite, Nitrogen
3,750 mg/kg
10/8/14
31.3 mg/kg
EPA 353.2
Nitrogen, total
29,200 mg/kg
10/20/14
20 mg/kg
EPA 353.2
Aluminum, total
Antimony, total
33,800 mg/kg
10/15/14
2.50 mg/kg
EPA 200.7
Arsenic, total
< 12.0 mg/kg
< 47.8 mg/kg
10/15/14
10/15/14
12.0 mg/kg
47.8 mg/lcg
EPA 200.7
EPA 200.7
Cadmium, total
1.48 mg/kg
10/15/14
0.200 mg/kg
EPA 2003
Calcium, total
Chromium, total
12,200 mg/kg
10/15/14
10.0 ing/kg
EPA 200.7
Coliper, total
76.1 mg/kg
440 mg/kg
10/15/14
10/15/14
0.250 ;ng/kg
1.00 mg/kg
EPA 200.7
EPA 200.7
Iron, total
16,700 mg/1%
10/15/14
1.25 mg/kg
EPA 200.7
Lead, total
Magnesium, total
23.0 mg/kg
5,360 mg/1%
10/15/14
10/19/14
2.0 mg/kg
10.0 mg/1%
EPA 200.7
EPA 200.7
Man anese, total
mg/kg
10/15/14
0.250 mg`/kg
EPA 200.7
Mercury, total..
.0.053 -mg Ic
10/10/14
.0.05 ig/kg.
EPA 245.1
Molybdeifium,,total
.la
7.75 nig/jig
10/15/14
,f
0.500 ing/kg
EPA 200.7
Nickel, total
18.9 mg/kg
10/15/14
2.0 mg/kg
EPA 200.7
Phosphorus, total
44,300 mg/kg
10/19/14
2.00 mg/kg
EPA 200.7
Potassium , total
5,840 mg/kg
10/19/14
20.0 mg/kg
EPA 200.7
Selenium, total
< 4.78-mg/kg
10/15/14
4.78 nig/kg
EPA 200.7
Silver, total
2.63 nig/kg
10/15/14
1,0 mg/kg
EPA 200.7
Sodium, total
3,090 mg/kg
10/19/14
20.0 mg/kg
EPA 200.7
Sulfate
26,400 mg/kg
10/14/14
500 mg/kg
SW 846 9038
Zinc, total
675 mg/kg
10/15/14
0.500 mg/kg
EPA 200.7
I hereby certi/y that I have reviewed and approve these data.
Labon•atoiy Representative
642 Tamco Road, Reidsville, North Carolina 27320
tei.[phone] fax.[phone]

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NC0039586
Laboratory 1 A&L Eastern
Labs, Inc.
Laboratory 2
Sample or CompositeDate 1/5/2015
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
8,860
Ammonia Nitrogen
N/A
N/A
88,900
Arsenic
41
75
3
Cadmium
39
85
2
Calcium
N/A
N/A
135,000
Copper
1,500
4,300
408
Lead
300
840
85
Magnesium
N/A
N/A
4,630
Mercury
17
57
0.4
Molybdenum
N/A
75
22
Nickel
420
420
22
Nitrate -Nitrite Nitrogen
N/A
N/A
55,100.00
Percent Solids
N/A
N/A
0.09
pH (no units)
N/A
N/A
7.79
Phosphorus
N/A
N/A
5,060
Potassium
N/A
N/A
28,600
PAN (Inj./Inc.)
N/A
N/A
157,230
PAN (Surface)
N/A
N/A
112,780
Selenium
100
100
5.7
Sodium
N/A
N/A
66,000
SAR
N/A
N/A
1.44
TKN
N/A
N/A
133,000
Zinc
2,800
7,500
1210
Source Name Shearon Harris NPP
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
/4-C-IL 02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

.
AG112AN
FIELD LOADING ESTIMATES
Facility Shearon Harris NPP
Sampling Date 1/5/2015
% Solids 0.09
Mineralization Rate 0.3
Gallons per DT 266,453.50
pH 7.79
Sodium Absorpotion 1.44 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 133,000 lbs./1,000 gal 1.00
Potassium lbs./1,000 gal
0.21
Ammonia Nitrogen (mg/Kg) 88,900.00 lbs./1,000 gal 0.67
Phosphorus lbs./1,000 gal
0.04
_ Nitrate -Nitrite (mg/Kg) 55,100.00 lbs./1,000 gal 0.41
Calcium lbs./1,000 gal
1.01
PLANT AVAILABLE NI.TROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.03
PAN (mg/Kg) 112,780 lbs./1,000 gal 0.85
Manganese lbs./1,000 gal
0.00
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
0.23
PAN (mg/Kg) 157,230 lbs./1,000 gal 1.18
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/ Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
1st Year
2nd Year
3rd Year
4th Year
5th Year
420
100
2,800
420
100
7,500
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
3.00
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
2.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
408.00
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
85.00
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.40
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
22.00
Nickel lbs./1,000 gal
0:00
Selenium (mg/Kg)
5.70
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
1210.00
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
133,000
112,780
225.56
20,220
133,000
157,230 314.46
-24,230
20,220
3,033
6.07
17,187
-24,230
-3,635 -7.27
-20,596
17,187
1,289
2.58
15,898
-20,596
-1,545 -3.09
-19,051
15,898
596
1.19
15,302
-19,051
-714 -1.43
-18,336
15,302
287
0.57
15,015
-18,336
-344 -0.69
-17,993
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 117,985 235.97
Total 150,993 301.99

Page: 1 of 2
Report Number: 15-006-0202
Account Number: 46518
Submitted By: BOB WILSON/SCOTT CARP
Send To: HARRIS NUCLEAR PLANT
BOB WILSON
5413 SHEARON HARRIS RD
NEW HILL, NC 27562
Lab Number: 59482
Sample Id : HNP SST 2
A&L Eastern Laboratories, Inc.
P 762t Wlaiiepine i?flad 9bchmond, vorgin9a 23237 (808) i43,Ml F2X t804t 279-S94S
ws7rua�tsre�om
Project: STP WASTE WATER SLUDGE STORAGE TANK 2
NC CERT#257
REPORT OF ANALYSIS Date Sampled: 1/5/2015 11:30:00
Date Received: 01/06/2015 00:00
Date Reported: 01/13/2015
Total Solids "
0.09
900.0
100.0
JM
01/06/2015 16:20
SM-2540G
Moisture "
99.91
100.0
JM
01/06/2015 16:20
SM-2540G
Total Kjeldahl Nitrogen
13.30
133000
10.0
JM
01/07/2015 10:45
SM-4500-NH3C-TKN
Total Phosphorus
0.51
5060
100
km
01/08/2015 09:30
SW 6010C
Total Potassium
2.86
28600
100
km
01/08/2015 09:30
SW 6010C
Total Sulfur
3.06
30600
100
km
01/08/2015 09:30
SW 6010C
Total Calcium
13.50
135000
100
km
01/08/2015 09:30
SW 6010C
Total Magnesium
0.46
4630
100
km
01/08/2015 09:30
SW 6010C
Total Sodium
6.60
66000
100
km
01/08/2015 09:30
SW 6010C
Total Iron
4110
100
km
01/08/2015 09:30
SW 6010C
Total Aluminum
8860
100
km
01/08/2015 09:30
SW 6010C
Total Manganese
145
5
km
01/08/2015 09:30
SW 6010C
Total Copper
408
5
km
01/08/2015 09:30
SW 6010C
Total Zinc
1210
5
km
01/08/2015 09:30
SW 6010C
Ammonia Nitrogen
8.89
88900
10.0
JM
01/08/2015 09:00
SM-4500-NH3C
Organic N
4.41
44100
10.0
01/07/2015 10:45
CALCULATION
Nitrate+Nitrite-N
55100
2.00
JM
01/07/2015 09:30
SM-450ONO3F
Total Cadmium
<2.0
2.0
km
01/08/2015 09:30
SW 6010C
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N. series is on a wet basis.
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made A&UMM
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
Debbie Holt

Page: 2 of 2
Report Number: 15-006-0202 A&L Eastem Laboratories Inc.
i"��11 Account Number: 46518 7829 Wh9iepineStaad trchmond,V4nia23237 1804374MD8 Fax[phone]d446
Submitted By: BOB WILSON/SCOTT CARP t�v sem
Send To: HARRIS NUCLEAR PLANT
BOB WILSON
5413 SHEARON HARRIS RD
NEW HILL, NC 27562
Lab Number: 59482
Sample Id : HNP SST 2
Project: STP WASTE WATER SLUDGE STORAGE TANK 2
NC CERT#257
REPORT OF ANALYSIS Date Sampled: 1/5/2015 11:30:00
Date Received: 01/06/2015 00:00
Date Reported: 01/13/2015
Total Chromium
8
5
km
01/08/2015 09:30
SW 6010C
Total Nickel
22
5
km
01/08/2015 09:30
SW 6010C
Total Lead
85
5
km
01/08/2015 09:30
SW 6010C
Total Arsenic
<3.0
3.0
km
01/08/2015 09:30
SW 6010C
Total Mercury
<0.4
0.4
KM
01/08/2015 09:00
SW-7471B
Total Selenium
5.7
5.0
km
01/08/2015 09:30
SW 6010C
pH (Standard Units) * 7.79
2.00
JM
01/07/2015 09:29
SW-9045D
Total Volatile Solids 44.92
449200
100.0
JM
01/06/2015 16:20
SM-254OG
Total Molybdenum
22
5
km
01/08/2015 09:30
SW 6010C
Chloride
128000
200
JM
01/07/201511:40
SM-4500CI-D
Alkalinity (as CaCO3)
349000
100
JM
01/08/2015 15:29
SM-2320 B
Comments:
CCE, CL, SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES.SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE
PURPOSES.
SILVER TO FOLLOW
QUALIFIER: THE LRB WAS OUT OF LIMITS FOR "Mn".
THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Fe" AND
"Se". ALL OTHER QC DATA IS
ACCEPTABLE.
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
Debbie Holt

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQOOIH)838 Facility Name Granville Farms, Inc. Gass. 11 Source Permit No. IM1,113 046,102 Stmrce Name Sunset \VI'P
Laboratory1
City of $otky
City of Rocky
Cuy of Rocky
Mount
Ahnml
Mount
Laboratory 2
Mrritrch, ]nc.
T3critrch, luc.
Meriterh, Inc.
Sample orCompositeDate
4/21/2014
9/I(+/'3)14
11/12/2014
Parametcr (mg/Kg) Class A Clas B
Aluminum N/A N/A
12,941
5.193
4_M
Ammonia Nitrogen N/A N/A
152
1.17
165
Arsenic
41
75
1-47
1.9
1.7
Cadmium
39
85
0.294
0.219
0.219
Calcium
N/A
N/A
1,425 i
4r14
3.7tu
Copper
1,500
4,300
1.56
631
5.53
Lcad
300
840
a ffas
1 55
1.4
Magnesium
N/A
N/A
512
396
265
Mercury
17
57
0.058
2219
0.21')
Molybdenum
N/A
75
0.735
0.55
0.55
- Nickel
420
420
)29
141.2
99.2
Nitrate -Nitrite Nitrogen
N/A
N/A
11.50
2.36
15.20
Percent Solids
N/A
N/A
3.43
5.94
456
�6.11)
pH (no units)
N/A
N/A
7.30
6.53
Phosphorus
N/A
I N/A
915
l i)59
•lit
Potassium
N/A
N/A
368---
160
34-1�
PAN (Ini./Inc.)
N/A
N/A
3,192
2,838
2,061
PAN (Surface)
N/A
N/A
3,166
2,765
1,979
Selenium
100
100.
1.47
1.1
1.1
Sodium
N/A
N/A
397
6-15
684
SAR
N/A
N/A
0.42
0.62
().62
TKN
N/A
N/A
7,697
6,89
4.868
Zinc
2,800
7,500
--
27.6
- - --
71.5
- -- - --
51.1
"I certify, tinder penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there arc significant penalties for
sub tting false information, including the possibility of fines and imprisonment for knowing violations."
7, l,_ _Al -2-/, --2vi5
signature of Pre
p• er
#Preparer is do ned in 40 CFR Part 5039(r) and 15A NCAC 2T .1102 (26)
Date

` AGMAIV FIELD LOADING ESTIMATES
Facility Sunset rive VvTP
Sampling Date 4/21 /2014
% Solids 3.43
Mineralization Rate 0.40
Gallons per DT 6,991.49
pH 7.3
Sodium Absorpotion 0.42 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land ripply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 7,697 lbs./1,000 gal 2.20
Potassium lbs./1,000 gal
0.11
Ammonia Nitrogen (mg/Kg) 152.00 lbs./1,000 gal 0.04
Phosphorus lbs./1,000 gal
0.26
Nitrate -Nitrite (mg/Kg) 11.50 lbs./1,000 gal 0.00
Calcium lbs./1,000 gal
0.41
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Calcium lbs./1,000 gal
0.15
PAN (mg/Kg) 3,106 lbs./1,000 gal 0.89
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 3,182 lbs./1,000 gal 0.91
Molybdenum lbs./1,000 gal
'0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
1.47
Cadmium (mg/Kg)
0.29
Copper (mg/Kg)
1.56
Lead (mg/Kg)
8.68
Mercury (mg/Kg)
0.06
Nickel (mg/Kg)
12.90
Selenium (mg/Kg)
1.47
Zinc (mg/Kg)
27.60
Arsenic lbs./1,000 gal
0.00
Cadmium lbs./1,000 gal
0.00
Copper lbs./1,000 gal
0.00
Lead lbs./1,000 gal
. 0.00
Mercury lbs./1,000 gal
0.00
Nickel lbs./1,000 gal
0.00
Selenium lbs./1,000 gal
0.00
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN .
(mg/kg) (lbs/DT)
(mg/Kg)
T
(mg/kg) (lbs/DT)
(mg/Kg)
7,697
3,106 6.21
4,592
7,697
3,182 6.36
4,516
4,592•
918 1.84
3,673
4,516
903 1.81
3,612
3,673
367 0.73
3,306
3,612
361 0.72
3,251
3,306
165 0.33
3,141
3,251
163 0.33,
3,089
3,141
79 0.16
3,062
3,089
77 0.15
3,011
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 4,635 9.27
Total 4,686 9.37

AGMAN FIELD LOADING ESTIMATES
Facility Sunset Ave WI?
Sampling Date 9/16/2014
Solids 5.94
Mineralization Rate 0.40
Gallons per DT 4,037.17
pH 6.53
Sodium Absorpotion 0.62 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 7,697 lbs./1,000 gal 3.81
Ammonia Nitrogen (mg/Kg) 147.00 lbs./1,000 gal 0.07
Nitrate -Nitrite (mg/Kg) 2.36 lbs./1,000 gal 0.00
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 3,096 lbs./1,000 gal 1.53
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 3,169 lbs./1,000 gal 1.57
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
Potassium lbs./1,000 gal 0.08
Phosphorus lbs./1,000 gal 0.52 ,
Calcium lbs./1,000 gal 2.09
Calcium lbs./1,000 gal 0.20
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
1.10
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.22
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
6.71
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
14.50
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.22
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
143.20
Nickel lbs./1,000 gal
0.07
Selenium (mg/Kg)
1.10
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
71.50
Zinc lbs./1,000 gal
0.04
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN(mg/kg)
(lbs/DT)
(mg/Kg)
7,697
3,096 6.19
4,601
7,697
3,169 6.34
4,528
4,601
920 1.84
3,681
4,528
906 1.81
3,622
3,681
368 0.74
3,313
3,622
362 0.72
3,260
3,313
166 0.33
3,147
3,260
163 0.33
3,097
3,147
79 0.16
3,069
3,097
77 0.15
3,019
Equations
1 st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 4,628 9.26
Total 4,678 9.36

AGMAN FIELD LOADING ESTIMATES
Facility Sunset Ave WTP
Sampling Date 11/12/2014
% Solids 4.56
Mineralization Rate 0.40
Gallons per DT 5,258.95
pH 6.1
Sodium Absorpotion 0.62 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 4,868 lbs./1,000 gal 1.85
Potassium lbs./1,000 gal
0.13
Ammonia Nitrogen (mg/Kg) 165.00 lbs./1,000 gal 0.06
Phosphorus lbs./1,000 gal
0.17
Nitrate -Nitrite (mg/Kg) 15.20 lbs./1,000 gal 0.01
Calcium lbs./1,000 gal
1.41
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Calcium lbs./1,000 gal
0.10
PAN (mg/Kg) 1,979 lbs./1,000 gal 0.75
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 2,061 lbs./1,000 gal 0.78
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
1.10
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.22
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
5.53
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
1.40
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.22
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
99.20
Nickel lbs./1,000 gal
0.04
Selenium (mg/Kg)
1.10
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
51.10
. Zinc lbs./1,000 gal
0.02
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TEN
(mg/kg) (lbs/DT)
(mg/Rg)
TEN
(mg/kg) (lbs/DT)
(mg/Kg)
4,868
1,979 .3.96
2,889
4,868
2,061 4.12
2,807
2,889
578 1.16
2,311
2,807
561 1.12
2,245
2,311
231 0.46
2,080
2,245
225 0.45
2,021
2,080
104 0.21
1,976
2,021
101 0.20
1,920
1,976
49 0.10
1,927
1,920
48 0.10
1,872
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 2,941 5.88
Total 2,996 5.99

2014 City of Rocky Mount Ana"cal Report
WQ Permit Number: WQ0005568
Sample Identification: City of Rocky Mount
Residual Source WQ # or NPDES #: NC 0072133
Facility Name: Sunset Avenue Water Treatment Plant
ilesidnal Annivsic Data
Laboratories 1) City of Rocky Mount
performing 2) Meritech, Inc
analyses:
Parameter rn )
Ceiling Cone.
Limit
(mg/k )
Sample or Composite
Date
4121/14
91104
/1112114
Percent Solids (7)
NA
3.43%
5.94%
1 4.56%
ply (1)
7.30
6.53
1 6.10
Arsenic (2)
75
1.47
1.10
1 1.10
Cadmium (2)
85
0294
0.219
1 0.219
Copper (2)
4,300
1.56
6.71
5.53
Lead (2)
840
8.68
14.5
1.4
Mercury (2)
57
0.058
0.219
0.219
Molybdenum (2)
75
0.735
0.55
0.55
Nickel (2)
420
12.9
143.2
99.2
Selenium (2)
100
1.47
1.10
1.10
Zinc (2) _
7,500. _....._..27-.6
-
71.5
51.1
Total Phosphorus (1)
NA
915 --
------ 1059-----
452
INN 1) . _: �.. _ �. _
. _ NA.
7b9Z
-6869
Ammonia -Nitrogen (1)
NA
152
147
165
Nitrate and Nitrite (1)
NA
11.5
2.36
15.2
.Potassium (2) -
NA
368
160
344
Sodium (2)
NA
397
645
684
Magnesium (2)
NA
512
396
265
Calcium (2)
NA
1423
4214
3704
Silver (2)
NA
0.735
0.55
0.55
Aluminum (2)
NA
12941
5198
4804
. PAN
NA
1 3105
2765
1979
SAR (wet)
NA
0.42
0.54
0.62
PAN/Load( 5 0 gal)
NA
5.77
8.90
4.89
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
LabSunervisor/M naffer Date
(1) Analyses performed by City of Rocky Mount Laboratory
(2) Analyses performed by Meritech, Inc

Meritech, Inc.
Environmental Laboratory
Contact: Angela Boswell
Client: Rocky Mount, City of
PO Box 1180
Rocky Mount, NC 27802
Laboratory Certification No.165
Page 1
Revised Date; 512312014
Report Date: 5/19/2014
Date Sample Rcvd: 4/22/2014
Meritech Work Order #
042214107 Sample: SAPSL0421 Grab
4/21/14
Parameters
Result
Analysis Date
Reporting Limit
Method
% Total Solids
3.43 %
4/25/14
0-100 %
SM 2540B
Aluminum, total
12,941 mg/kg
4/25/14
.2.50 mg/kg
EPA 200.7
Arsenic, total
< 1.47 mg/kg
4/25/14
1.47 mg/kg
EPA 200.7
Cadmium, total
< 0.294 mg/kg
4/25/14
0.294 mg/kg
EPA 200.7
Calcium, total
1,423 mg/kg
4/25/14
10.0 mg/kg
EPA 200.7
Copper, total
1.56 mg/kg
4/25/14
0.325 mg/kg
EPA 200.7
Lead, total
8.68 mg/kg
4/25/14
0.500 mg/kg
EPA 200.7
Magnesium, total
512 mg/kg
4/25/14
10.0 mg/kg
EPA 200.7
Mercury, total
0.058 mg/kg
4/29/14
0.04 mg/kg
EPA 245.1
Molybdenum, total
< 0.735 mg/kg
4/25/14
0.735 mg/kg
EPA 200.7
Nickel, total
12.9 mg/kg
4/25/14
0.500 mg/kg
EPA 200.7
Potassium, total
368 mg/kg
4/25/14
20.0 mg/kg
EPA 200.7
Selenium, total
< 1.47 mg/kg
4/25/14
1.47 mg/kg
EPA 200.7
Silver, total
< 0.735 mg/kg
4/25/14
0.735 mg/kg
EPA 200.7
Sodium, total
397 mg/kg
4/25/14
20.0 mg/kg
EPA 200.7
Zinc, total
27.6 mg/kg
4/25/14
0.500 mg/kg
EPA 200.7
a�
Q•• Y ' 9
2014
Ell
%t��4 � J
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

Meritech, Inc.
_ Environmental Laboratory
Laboratory Certification No.165
y Page 2
Revised Date: 512312014
Contact: Angela Boswell Report Date: 5/19/2014
Client: Rocky Mount, City of
PO Box 1180
Rocky Mount, NC 27802 Date Sample Rcvd: 4/22/2014
4 A/Wat 1311- TCLP Metals
Meritech Work Order #
042214108 Sample: SAPSL0421 Grab
Collection Date:
4/21/14
Parameter
Results
AnalysisDet. Limn
Beg. Limi
Method
Arsenic
< 0.100 mg/L
4/29/14
0.100
5.0
EPA 200.7
Barium
1.60 mg/L
4/29/14
0.050
100.0
EPA 200.7
Cadmium
< 0.020 mg/L
4/29/14
0.020
1.0
EPA 200.7
Chromium
< 0.050 mg/L
4/29/14
0.050
5.0
EPA 200.7
Lead
< 0.100 mg/L
4/29/14
0.100
5.0
EPA 200.7
Mercury
< 0.02 mg/L
4/29/14
0.02
0.2
EPA 245.1
Selenium
< 0A00 mg/L
4/29/14
0.100
1:0
EPA 2003
Silver
< 0.050 mg/L
4/29/14
0.050
5.0
EPA 200.7
TCLP Organics
Paara etgr
Results
Analysis
Method
Pesticides 8080-
Attached
4/29/14
8080
Herbicides 8150
Attached
4/29/14
8150
Volatiles 8260
Attached
5/1/14
8260
Semi Vol. 8270
Attached
5/1/14
8270
Other Tests
Param Results Analysis Reporting Limit Method
Reactivity- Cyanide, total < 11.0 mg/kg 4/23/14 11.0 mg/kg EPA 335.4
lgnitability > 140 °F 4/23/14 - - EPA 1030
Corositvity- pH 6.6 S.U. 5/5/14 1.0 -14.0 S.U. SM 4500 HB
Reactivity- Sulfide, total 24.1 mg/kg 4/25/14 10 mg/kg SM 4500 SD
V
r,
2014
BY:
642 Tamco Road, Reidsville, North Carolina 27320
{._. tel.[phone] fax.[phone]

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Contact: Angela Boswell
Client: Rocky Mount, City of
PO Box 1180
Rocky Mount, NC 27802
Page 3
Revised Date: 512312014
Report Date: 5/19/2014
Date Sample Rcvd: 4/22/2014
Meritech Work Order -# 042214108 Sample: SAPSL0421 Grab Collection Date: 4/21/2014
1311- TCLP Pesticides & Herbicides
pesticide - SW-846 8081A
Analyst: Summit
Analysis Date: 4/29/14
Pgramete,
Results
Det. Limit
Reg. Limit
Dilution Factor
Heptachlor Epoxide
< 0.002 mg/L
0.002
0.008
1
Endrin
< 0.002 mg/L
.0.002
0.02
1
Chlordane
< 0.01 mg/L
0.01
0.03
1
Gamma - BHC
< 0.002 mg/L
0.002
0.4
1
Toxaphene
< 0.1 mg/L
0.1
0.5
1
Methoxychlor
< 0.002 mg/L
0.002
10.0
1
Heptachlor
< 0.002 mg/L
0.002
0.008
1
Analyst: Summit
Analysis Date: 4/29/14
Parameter Results Det. Limit Reg, Limit Dilution Factor
2,4-D < 5. mg/L 5.0 10.0 1
2,4,5-TP (Silvex) < 0.5 mg/L 0.5 1.0 1
1 hereby certify that 1 have reviewed and approve these data.
Laboratory Represent tive
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

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AGMAN FIELD LOADING ESTIMATES
W%-
Facility Tar River Regional WWTP
Sampling Date 1/10/2014
% Solids 2.04
Mineralization Rate 0.30
Gallons per DT 11,755.30
PH 7.03
Sodium Absorpotion 4.38 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 47,843 lbs./1,000 gal 8.14 Potassium lbs./1,000 gal 0.24
Ammonia Nitrogen (mg/Kg) 24,314.00 lbs./1,000 gal 4.14 Phosphorus lbs./1,000 gal 6.02
Nitrate -Nitrite (mg/Kg) 326.00 lbs./1,000 gal 0.06 Calcium lbs./1,000 gal 0.40
PLANT AVAILABLE NITROGEN SURFACE APPLIED Calcium lbs./1,000 gal 0.12
PAN (mg/Kg) 19,542 lbs./1,000 gal 3.32 Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED Sulfur lbs./1,000 gal
PAN (mg/Kg) 31,699 lbs./1,000 gal 5.39 Molybdenum lbs./1,000 gal 0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Limits (mg/Kg)
41
39
1,500
300
1 st Year
2nd Year
3rd Year
4th Year
5th Year
17
420
100
2,800
Class B Ceiling
Limits (mg/Kg)
75
85
4,300
840
57
420
100
7,500
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
2.08
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.04
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
483.00
Copper lbs./1,000 gal
0.08
Lead (mg/Kg)
41.70
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.75
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
30.40
Nickel lbs./1,000 gal
0.01
Selenium (mg/Kg)
2.08
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
538.00
Zinc lbs./1,000 gal
0.09
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
47,843
19,542
39.08
28,301
47,843
31,699 63.40
16,144
28,301
4,245
8.49
24,056
16,144
2,422 4.84
13,723
24,056
1,804
3.61
22,252
13,723
1,029 2.06
12,693
22,252
834
1.67
21,417
12,693
476 0.95
12,217
21,417
402
0.80
21,016
12,217
229 0.46
11,988
Equations
1 st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/I6)
Total 26,827 53.65
Total 35,855 71.71

i I
AGMAN FIELD LOADING ESTIMATES
- Facility Tar River Regional W WTP
Sampling Date 2/24/2014
% Solids 1.92
Mineralization Rate 0.30
Gallons per DT 12,490.01
pH 7.6
Sodium Absorpotion 0.78 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do_ Not Land Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
------- ---- - ---------
TKN (mg/Kg) 70,000 lbs./1,000 gal 11.21
Ammonia Nitrogen (mg/Kg) 26,510.00 lbs./1,000 gal 4.24
Nitrate -Nitrite (mg/Kg) 414.00 lbs./1,000 gal 0.07
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 26,716 lbs./1,000 gal 4.28
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 39,971 lbs./1,000 gal 6.40
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1st Year
2nd Year
3rd Year
4th Year
5th Year
Potassium lbs./1,000 gal 0.69
Phosphorus lbs./1,000 gal 5.42
Calcium lbs./1,000 gal 1.22
Calcium lbs./1,000 gal 0.37
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
5.21
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.77
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
635.00
Copper lbs./1,000 gal
0.10
Lead (mg/Kg)
58.20
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.63
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
42.70
Nickel lbs./1,000 gal
0.01
Selenium (mg/Kg)
5.21
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
740.00
Zinc lbs./1,000 gal
0.12
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(lbs/DT)
(mg/Rg)
T)iN
TEN
(mg/kg) (lbs/DT)
(mg/Rg)
70,000
26,716 33.43
43,284
70,000
39,971 79.94
30,029
43,284
6,493 12.99
36,791
30,029
4,504 9.01
25,525
36,791
2,759 5.52
34,032
25,525
1,914 3.83
23,610
34,032
1,276 2.55
32,756
23,610
885 1.77
22,725
32,756
614 1.23
32,142
22,725
426 0.85
22,299
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 37,858 75.72
Total 47,701 95.40

AGMAN FIELD LOADING ESTIMATES
Facility Tar River Regional WWTP
Sampling Date 3/11/2014
Solids 2.56
Mineralization Rate 0.30
Gallons per DT 9,367.51
pH 7.97
Sodium Absorpotion 1.02 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 91,758 lbs./1,000 gal 19.59
Ammonia Nitrogen (mg/Kg) 46,563.00 lbs./1,000 gal 9.94
Nitrate -Nitrite (mg/Kg) 85.00 lbs./1,000 gal 0.02
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 36,925 lbs./1,000 gal 7.88
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 60,207 lbs./1,000 gal 12.85
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Potassium lbs./1,000 gal 1.62
Phosphorus lbs./1,000 gal 7.02
Calcium lbs./1,000 gal 2.86
Calcium lbs./1,000 gal 0.56
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
HEAVY METAL CONCENTRATION
HEAVY METAL LOADING
41
75
Arsenic (mg/Kg)
0.39
Arsenic lbs./1,000 gal
0.00
39
85
Cadmium (mg/Kg)
1.47
Cadmium lbs./1,000 gal
0.00
1,500
4,300
Copper (mg/Kg)
543.00
Copper lbs./1,000 gal
0.12
300
840
Lead (mg/Kg)
49.60
Lead lbs./1,000 gal
0.01
17
57
Mercury (mg/Kg)
0.62
Mercury lbs./1,000 gal
0.00
420
420
Nickel (mg/Kg)
31.20
Nickel lbs./1,000 gal
0.01
100
100
Selenium (mg/Kg)
0.39
Selenium lbs./1,000 gal
0.00
2,800
7,500
Zinc (mg/Kg)
651.00
Zinc lbs./1,000 gal
0.14
RESIDUAL NITROGEN CALCULATION
1 St Year
2nd Year
3rd Year
4th Year
5th Year
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TEN
(mg/kg) (lbs/DT)
(mg/Kg)
TEN(mg/kg)
(lbs/DT)
(mg/]ig)
91,758
36,925
73.85
54,833
91,758
60,207 120.41
31,552
54,833
8,225
16.45
46,608
31,552
4,733 9.47
26,819
46,608
3,496
6.99
43,112
26,819
2,011 4.02
24,807
43,112
1,617
3.23
41,496
24,807
930 1.86
23,877
41,496
778
1.56
40,718
23,877
448 0.90
23,429
Equations
1 st Yr. PAN (mg/Kg)=(MR x (TKN-NI-I3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 51,040 102.08
Total 6M29 136.66

a
i
' AGMAN HELD LOADING ESTIMATES
Facility Tar River Regional WWTP
Sampling Date 4/15/2014
% Solids 2.54
Mineralization Rate 0.30
Gallons per DT 9,441.27
PH 8.02
Sodium Absorpotion 0.65 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 95,748 lbs./1,000 gal 20.28
Potassium lbs./1,000 gal
1.57
Ammonia Nitrogen (mg/Kg) 46,614.00 lbs./1,000 gal 9.87
Phosphorus lbs./1,000 gal
7.27
Nitrate -Nitrite (mg/Kg) 236.00 lbs./1,000 gal 0.05
Calcium lbs./1,000 gal
2.75
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Calcium lbs./1,000 gal
0.56
PAN (mg/Kg) 38,283 lbs./1,000 gal 8.11
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 61,590 lbs./1,000 gal 13.05
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
11500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
1.85
Cadmium (mg/Kg)
1.35
Copper (mg/Kg)
459.00
Lead (mg/Kg)
41.80
Mercury (mg/Kg)
0.02
Nickel (mg/Kg)
26.30
'Selenium (mg/Kg)
1.85
Zinc (mg/Kg)
637.00
Arsenic lbs./1,000 gal
0.00
Cadmium lbs./1,000 gal
0.00
Copper lbs./1,000 gal
0.10
Lead lbs./1,000 gal
0.01
Mercury lbs./1,000 gal
0.00
Nickel lbs./1,000 gal
U1
Selenium lbs./1,000 gal
0.00
Zinc lbs./1,000 gal
0.13
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (Ibs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
95,748
38,283 76.57
57,465
95,748
61,590 123.18
34,158
57,465
8,620 17.24
48,845
34,158
5,124 10.25
29,034
48,845
3,663 7.33
45,182
29,034
2,178 4.36
26,857
45,182
1,694 3.39
43,487
26,857
1,007 2.01
25,849
43,487
815 1.63
42,672
25,849
485 0.97
25,365
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 53,076 106.15 Total 70,383 140.77
1

ADMAN FIELD LOADING ESTIMATES
Facility Tar River Regional VIWTP
Sampling Date 5/7/2014
% Solids 2.94
Mineralization Rate 0.30
Gallons per DT 8,156.74
pH 7.94
Sodium Absorpotion 0.55 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land .Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 82,993 lbs./1,000 gal 20.35
Ammonia Nitrogen (mg/Kg) 41,088.00 lbs./1,000 gal 10.07
Nitrate -Nitrite (mg/Kg) 159.00 lbs./1,000 gal 0.04
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 33,275 lbs./1,000 gal 8.16
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 53,819 lbs./1,000 gal 13.20
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
1 st Year
2nd Year
3rd Year
4th Year
I
I .
5th Year
Potassium lbs./1,000 gal 1.53
Phosphorus lbs./1,000 gal 7.38
Calcium lbs./1,000 gal 2.77
Calcium lbs./1,000 gal 0.68
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
1.70
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.77
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
452.00
Copper lbs./1,000 gal
0.11
Lead (mg/Kg)
44.90
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.78
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
30.10
Nickel lbs./1,000 gal
0.01
Selenium (mg/Kg)
3.74
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
639.00
Zinc lbs./1,000 gal
0.16
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/]Kg)
TEN
(mg/kg) (lbs/DT)
(mg/Yg)
82,993
33,275
66.55
49,719
82,993
53,819 107.64
29,175
49,719
7,458
14.92
42,261
29,175
4,376 8.75
24,798
42,261
3,170
6.34
39,091
24,798
1,860 3.72
22,938
39,091
1,466
2.93
37,625
22,938
860 1.72
22,078
37,625
705
1.41
36,920
22,078
414 0.83 _
21,664
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NI3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/I6)
Total 46,073 92.15
Total 61,329 122.66

AGMAIV FIELD LOADING ESTIMATES
Facility Tar River Regional VAV P
Sampling Date 6/16/2014
Solids 2.08
Mineralization Rate 0.30
Gallons per DT 11,529.24
PH 7.03
Sodium Absorpotion 0.71 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 71,154 lbs./1,000 gal 12.34
Ammonia Nitrogen (mg/Kg) 21,394.00 lbs./1,000 gal 3.71
Nitrate -Nitrite (mg/Kg) 267.00 lbs./1,000 gal 0.05
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 25,892 lbs./1,000 gal 4.49
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 36,589 lbs./1,000 gal 6.35
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Potassium lbs./1,000 gal 1.43
Phosphorus lbs./1,000 gal 6.93
Calcium lbs./1,000 gal 2.17
Calcium lbs./1,000 gal 0.64
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
HEAVY METAL CONCENTRATION
HEAVY METAL LOADING
41
75
Arsenic (mg/Kg)
4.80
Arsenic lbs./1,000 gal
0.00
39
85
Cadmium (mg/Kg)
1.70
Cadmium lbs./1,000 gal
0.00
1,500
4,300
Copper (mg/Kg)
450.00
Copper lbs./1,000 gal
0.08
300
840
Lead (mg/Kg)
52.40
Lead lbs./1,000 gal
0.01
17
57
Mercury (mg/Kg)
0.82
Mercury lbs./1,000 gal
0.00
420
420
Nickel (mg/Kg)
27.30
Nickel lbs./1,000 gal
0.00
100
100
Selenium (mg/Kg)
4.80
Selenium lbs./1,000 gal
0.00
2,800
7,500
Zinc (mg/Kg)
660.00
Zinc lbs./1,000 gal
0.11
RESIDUAL NITROGEN CALCULATION
1 st Year
2nd Year
3rd Year
4th Year
5th Year
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
71,154
25,892
51.78
45,262
71,154
36,589 73.18
34,565
45,262
6,789
13.58
38,473
34,565
5,185 10.37
29,380
38,473
2,885
5.77
35,587
29,380
2,204 4.41
27,177
35,587
1,335
2.67
34,253
27,177
1,019 2.04
26,158
34,253
642
1.28
33,610
26,158
490 0.98
25,667
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 37,544 75.09
Total 45,487 90.97

AGMAN FIELD LOADING ESTIMATES
Facility Tar River Regional WWTP
Sampling Date 7/9/2014
% Solids 2.64
Mineralization Rate 0.30
Gallons per DT 9,083.64
PH 8.08
Sodium Absorpotion 0.66 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land ripply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 64,242 lbs./1,000 gal 14.14
Potassium lbs./1,000 gal
1.50
Ammonia Nitrogen (mg/Kg) 37,879.00 lbs./1,000 gal 8.34
Phosphorus lbs./1,000 gal
6.88
Nitrate -Nitrite (mg/Kg) 155.00 lbs./1,000 gal 0.03
Calcium lbs./1,000 gal
2.40
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Calcium lbs./1,000 gal
0.59
PAN (mg/Kg) 27,003 lbs./1,000 gal 5.95
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 45,943 lbs./1,000 gal 10.12
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Limits (mg/Kg)
41
1 st Year
2nd Year
3rd Year
4th Year
5th Year
39
1,500
300
17
420
100
2,800
Class B Ceiling
Limits (mg/Kg)
75
85
4,300
840
57
420
100
7,500
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
1.90
'Cadmium (mg/Kg)
1.48
Copper (mg/Kg)
443.00
. Lead (mg/Kg)
33.60
Mercury (mg/Kg)
0.68
Nickel (mg/Kg)
24.70
Selenium (mg/Kg)
1.90
Zinc (mg/Kg)
640.00
Arsenic lbs./1,000 gal
0.00
Cadmium lbs./1,000 gal
0.00
Copper lbs./1,000 gal
0.10
Lead lbs./1,000 gal
0.01
Mercury lbs./1,000 gal
0.00
Nickel lbs./1,000 gal
0.01
Selenium lbs./1,000 gal
0.00
Zinc lbs./1,000 gal
0.14
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
64,242
27,003
54.01
37,239
64,242
45,943 91.89
18,299
37,239
5,586
11.17
31,653
18,299
2,745 5.49
15,554
31,653
2,374
4.75
29,279
15,554
1,167 2.33
14,388
29,279
1,098
2.20
28,181
14,388
540 1.08
13,848
28,181
528
1.06
27,653
13,848
260 0.52
13,588
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 36,589 73.18
Total 50,654 101.31

&_ AGMAN FIELD LOADING ESTIMATES
Facility Tar River Regional WWTP
Sampling Date 8/15/2014
% Solids 2.56
Mineralization Rate 0.30
Gallons per DT 9,367.51
PH 8.18
Sodium Absorpotion 0.77 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 69,375 lbs./1,000 gal 14.81
Potassium lbs./1,000 gal
,1.54
Ammonia Nitrogen (mg/Kg) 44,063.00 lbs./1,000 gal 9.41
Phosphorus lbs./1,000 gal
6.21
Nitrate -Nitrite (mg/Kg) 414.00 lbs./1,000 gal 0.09
Calcium lbs./1,000 gal
2.60
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Calcium lbs./1,000 gal
0.48
PAN (mg/Kg) 30,039 lbs./1,000 gal 6.41
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 52,071 lbs./1,000 gal 11.12
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Limits (mg/Kg)
41
39
1,500
300
17
1 st Year
2nd Year
3rd Year
4th Year
5th Year
420
100
2,800
Class B Ceiling
Limits (mg/Kg)
75
85
4,300
840
57
420
100
7,500
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
1.95
Cadmium (mg/Kg)
1.68
Copper (mg/I(g)
484.00
Lead (mg/Kg)
53.50
Mercury (mg/Kg)
0.63
Nickel (mg/Kg)
29.70
Selenium (mg/Kg)
1.95
Zinc (mg/Kg)
671.00
Arsenic lbs./1,000 gal
0.00
Cadmium lbs./1,000 gal
0.00
Copper lbs./1,000 gal
0.10
Lead lbs./1,000 gal
0.01
Mercury lbs./1,000 gal
0.00
Nickel lbs./1,000 gal
0.01
Selenium lbs./1,000 gal
0.00
Zinc lbs./1,000 gal
0.14
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(m g/Kg)
TEN(mg/kg)
(lbs/DT)
(mg/Rg)
69,375
30,039 60.08
39,336
69,375
52,071 104.14
17,304
39,336
5,900 11.80
33,436
17,304
2,596 5.19
14,709
33,436
2,508 5.02
30,928
14,709
1,103 2.21
13,606
30,928
1,160 2.32
29,768
13,606
510 1.02
13,095
29,768
558 1.12
29,210
13,095
246 0.49
12,850
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 40,165 80.33
Total 56,525 113.05

AGMAN FIELD LOADING ESTIMATES
Facility Tar River Regional WWTP
Sampling Date 9/22/2014
% Solids 2.78
Mineralization Rate 0.30
Gallons per DT 8,626.19
PH 8.1
Sodium Absorpotion 0.88 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 67,266 lbs./1,000 gal 15.60
Potassium lbs./1,000 gal
1.67
Ammonia Nitrogen (mg/Kg) 42,806.00 lbs./1,000 gal 9.92
Phosphorus lbs./1,000 gal
8.40
Nitrate -Nitrite (mg/Kg) 292.00 lbs./1,000 gal 0.07
Calcium lbs./1,000 gal
3.25
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Calcium lbs./1,000 gal
0.75
PAN (mg/Kg) 29,033 1 lbs./1,000 gal 6.73
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 50,436 lbs./1,000 gal 11.69
Molybdenum lbs./1,000 gal
0.01
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
HEAVY METAL CONCENTRATION
HEAVY METAL LOADING
41
75
Arsenic (mg/Kg)
3.60
Arsenic lbs./1,000 gal
0.00
39
85
Cadmium (mg/Kg)
2.45
Cadmium lbs./1,000 gal
0.00
1,500
4,300
Copper (mg/Kg)
561.00
Copper lbs./1,000 gal
0.13
300
840
Lead (mg/Kg)
60.80
Lead lbs./1,000 gal
0.01
17
57
Mercury (mg/Kg)
0.06
Mercury lbs./1,000 gal
0.00
420
420
Nickel (mg/Kg)
35.40
Nickel lbs./1,000 gal
0.01
100
100
Selenium (mg/Kg)
3.60
Selenium lbs./1,000 gal
0.00
2,800
7,500
Zinc (mg/Kg)
734.00
Zinc lbs./1,000 gal
0.17
RESIDUAL NITROGEN CALCULATION
1 st Year
2nd Year
3rd Year
4th Year
5th Year
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TRIM
(mg/kg) (lbs/DT)
(mg/Kg)
67,266
29,033 58.07
38,233
67,266
50,436 100.87
16,830
38,233
5,735 11.47
32,498
16,830
2,525 5.05
14,306
32,498
2,437 4.87
30,061
14,306
1,073 2.15
13,233
30,061
1,127 2.25
28,933
13,233
496 0.99
12,736
28,933
543 1.09
28,391
12,736
239 0.48
12,498
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/I6)
Total 38,875 77.75
Total 54,768 109.54

• ; , AGMAN FIELD LOADING ESTIMATES
Facility Tar River Regional V/WTP
Sampling Date 11/6/2014
% Solids 2.46
Mineralization Rate 0.30
Gallons per DT 9,748.30
pH 7.87
Sodium Absorpotion 0.76 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land ripply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 67,642 lbs./1,000 gal 13.88
Ammonia Nitrogen (mg/Kg) 29,593.00 lbs./1,000 gal 6.07
Nitrate -Nitrite (mg/Kg) 391.00 lbs./1,000 gal 0.08
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 26,602 lbs./1,000 gal 5.46
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 41,399 lbs./1,000 gal 8.49
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Potassium lbs./1,000 gal 1.47
Phosphorus lbs./1,000 gal 6.80
Calcium lbs./1,000 gal 2.91
Calcium lbs./1,000 gal 0.77
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
HEAVY METAL CONCENTRATION
HEAVY METAL LOADING
41
75
Arsenic (mg/Kg)
2.03
Arsenic lbs./1,000 gal
0.00
39
85
Cadmium (mg/Kg)
2.03
Cadmium lbs./1,000 gal
0.00
1,500
4,300
Copper (mg/Kg)
545.00
Copper lbs./1,000 gal
0.11
300
840
Lead (mg/Kg)
56.50
Lead lbs./1,000 gal
0.01
17
57
Mercury (mg/Kg)
1.02
Mercury lbs./1,000 gal
0.00
420
420
Nickel (mg/Kg)
37.10
Nickel lbs./1,000 gal
0.01
100
100
Selenium (mg/Kg)
2.03
Selenium lbs./1,000 gal
0.00
2,800
7,500
Zinc (mg/Kg)
748.00
Zinc lbs./1,000 gal
0.15
RESIDUAL NITROGEN CALCULATION
1 st Year
2nd Year
3rd Year
4th Year
5th Year
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
67,642
26,602 53.20
41,040
67,642
41,399 82.80
26,243
41,040
6,156 12.31
34,884
26,243
3,936 7.87
22,307
34,884
2,616 5.23
32,268
22,307
1,673 3.35
20,634
32,268
1,210 2.42
31,058
20,634
774 1.55
19,860
31,058
582 1.16
30,475
19,860
372 0.74
19,488
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 37,167 74.33
Total 48,154 96.31

&AGMAN FIELD LOADING ESTIMATES
Facility Tar River Regional WWTP
Sampling Date 12/15/2014
% Solids 3.21
Mineralization Rate 0.30
Gallons per DT 7,470.66
pH 5.64
Sodium Absorpotion 0.81 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 54,829 lbs./1,000 gal 14.68
Potassium lbs./1,000 gal
1.36
Ammonia Nitrogen (mg/Kg) 6,231.00 lbs./1,000 gal 1.67
Phosphorus lbs./1,000 gal
7.76
Nitrate -Nitrite (mg/Kg) 2,645.00 lbs./1,000 gal 0.71
Calcium lbs./1,000 gal
3.45
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Calcium lbs./1,000 gal
0.83
PAN (mg/Kg) 20,340 lbs./1,000 gal 5.45
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 23,455 lbs./1,000 gal 6.28
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection /Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
HEAVY METAL CONCENTRATION
HEAVY METAL LOADING
41
75
Arsenic (mg/Kg)
3.12
Arsenic lbs./1,000 gal
0.00
39
85
Cadmium (mg/Kg)
3.12
Cadmium lbs./1,000 gal
0.00
1,500
4,300
Copper (mg/Kg)
458.00
Copper lbs./1,000 gal
0.12
300
840
Lead (mg/Kg)
49.20
Lead lbs./1,000 gal
0.01
17
57
Mercury (mg/Kg)
0.47
Mercury lbs./1,000 gal
0.00
420
420
Nickel (mg/Kg)
38.30
Nickel lbs./1,000 gal
0.01
100
100
Selenium (mg/Kg)
4.67
Selenium lbs./1,000 gal
0.00
2,800
7,500
Zinc (mg/Kg)
539.00
Zinc lbs./1,000 gal
0.14
RESIDUAL NITROGEN CALCULATION
1 st Year
2nd Year
3rd Year
4th Year
5th Year
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (Ibs/DT)
(mg/gg)
TEN
(mg/kg) (lbs/DT)
(mg/Rg)
54,829
20,340
40.68
34,489
54,829
23,455 46.91
31,374
34,489
5,173
10.35
29,316
31,374
4,706 9.41
26,668
29,316
2,199
4.40
27,117
26,668
2,000 4.00
24,667
27,117
1,017
2.03
26,100
24,667
925 1.85
23,742
26,100
489
0.98
25,611
23,742
445 0.89
23,297
Equations
1 st Yr. PAN (mg/Kg)=(MR x (TICN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (VIR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 29,218 58.44
Total 31,532 63.06

2014 City of Rocky Mount Analytical Report
Technical Services Laboratory
WQ Permit Number: WQ0005568
Sample Identification : City of Rocky Mount Biosolids
Residual Source WQ # orNPDES #: NC 0030317
Facility Name: Tar River Regional NVxArrP
Laboratoi 1) City of Rocky Mount
per➢onming 2) Meritech, Inc
analyses:
]Residual Analysis Data11/21/14 - Last load Land Applied in 2014.
Parameter (mg/kg)
Ceiling Cone_
Limit
(iLimit)
Sample or Composite Date
1110114
2/24114
3/11114
4/15114
5/7A4
6116114
7/9/14
8115/14
9)22114
111W14
12/1S/14
Digester ID that is being Land
Applied (hauled fmm):
Digester #:
2
2
1
4
3
2
3
4
1
2
4
Temperature °C (1)
31.7
39.2
26.6
33.7
31.9
42.5
36.9
32.8
33.2
33.2
23.1
Percent Solids (1)
NA
2.04%
1.92%
2.56%0 1
2.54%
2.94% 1
2.080/6
2.64% 1
2.56%
2.78%
2.46% 1
3.21 %
Percent Volatile Solids (1)
NA
63.8
63A
65.0 1
65.0
63.5
573
56.4 1
58.8
59.6
62.6
65.6
pI I (1)
7.03
7.60
7.97
8.02
7.94
7.03
8.08
8.18
8.1
7.87
5.64
Arsenic (2)
75
2.08
5.21
0.39
1.85
1.70
4.8
1.90
1.95
3.60
2.03
3.12
Cadmitun (2)
85
1.04
1.77
1.47
1.35
1.77
1.70
1.48
1.68
2.45
1.75
3.12
Copper (2)
4.300
483
635
543
459
452 1
450
443
484
561
545
458
Lead (2)
840
41.7
58.2
49.6
41.8
44.9
52.4
33.6
53.5
60.8
56.5
49.2
Mercury (2)
57
0.750
0.625
0.6200
0.017
0.782
0.820
0.682
0.625
0.061
1.02 1
0.467
Molybdenum (2)
75
12.2
16.9
20.0
21.6
15.4
9.18
9.05
19.1
23.3
21.7
1 13.6
Nickel (2)
420
30.4
42.7
31.2
26.3
30.1
27.3
24.7
29.7
35.4
37.1
1 38.3
Selenium (2)
100
2.08
5.21
0.39
1.85
3.74
4.80
1.90
1.95
3.60
2.03
4.67
Zinc (2)
7,500
538
740
651
637
639
660
640
671
734
748
539
Total Phosphorus (1)
NA
35392
33854
32891
34331
30102
39952
31250
29063
36223
33130
29003
TKN (1)
NA
47843
70000
91758
95748
82993
71154
64242
69375
67266
67642
54829
Ammonia -Nitrogen (1)
NA
24314
26510
46563
46614
41088
21394
37879
44063
42806
29593
6231
Nitrate and Nitrite (1)
NA
326
414
85
236
159
267
155
414
292
391
2645
15otassum (
N
1400
4310
7600
7407
6220
8270
6820
7230
7190
7150
5080
Sodium (2)
NA
6625
2190
3100
1948
1470
2460
1830
2200
2660
2530
2210
Magnesium (2)
NA
717
2280
2610
2644
2770
3690
2700
2240
3220
3730
3090
Calcium (2)
NA
2330
7600
13400
13000
11300
1 12500
10900
12200
14000
14200
12900
Silver (2)
NA
2.71
4.01
3.41
2.63
3.57
3.13
3.22
3.00
4.03
3.50
7.79
Aluminum (2)
NA
6880
8960
8880
11074
12600
10800
9470
18600
16600
16800
10200
PAN
NA
19542
26716
36925
38283
33274
25892
27004
30039
29033
26602
20340
SAR (wet)
NA
4.38
0.78
1.02
0.65
0.55
0.71
1 0.66
0.77
0.88
0.76
0.8
VAN/Load (lb/6500 pall
NA
21.6
27.8
51.2
52.7
53.0
29.2
1 38.6
41.7
43.8
35.5
35.4
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. 1 am aware that there are significant penalties for submitting false
information, including the ossibility of fines and imprisonment for knowing violations."
� ff �j
�f 2( li � tl�� 7 ✓�� (E31��i,��i' �,�/ '/c�/r^~'°�L' / �7 � 7' $
Lab Supervisor/Ma/Iager Date
(1) Analyses performed by City of Rock), Mount Laboratory
(2) Analyses performed by Meritech, Inc

Contact: Angela Boswell
Client: Rocky Mount, City of
PO Box 1180
Rocky Mount, NC 27802
Merltech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Page 1
Revised Date: 512312014
Report Date: 5/19/2014
Date Sample Rcvd: 4/22/2014
Meritech Work Order #
042214105 Sample: BF0415 Grab
4/15/14
RarameterS
Results
Analysis Date
ReportingLimit imit
Method
% Total Solids
2.54 %
4/22/14
0-100 %
SM 2540B
Aluminum, total
11,074 mg/kg
4/25/14
2.50 mg/kg
EPA 200.7
Arsenic, total
< 1.85 mg/kg
4/25/14
1.85 mg/kg
EPA 200.7
Cadmium, total
1.35 mg/kg
4/25/14
0.325 mg/kg
EPA 200.7
Calcium, total
13,000 mg/kg
4/25/14
10.0 mg/kg
EPA 200.7
Copper, total
459 mg/kg
4/25/14
0.325 mg/kg
EPA 200.7
Lead, total
41.8 mg/kg
4/25/14
0.500 mg/kg
EPA 200.7
Magnesium, total
2,644 mg/kg
4/25/14
10.0 mg/kg
EPA 200.7
Mercury, total
0.017 mg/kg
4/29/14
0.010 mg/kg
EPA 245.1
Molybdenum, total
21.6 mg/kg
4/25/14
0.812 mg/kg
EPA 200.7
Nickel, total
26.3 mg/kg
4/25/14
0.500 mg/kg
EPA 200.7
Potassium, total
7407 mg/kg
4/25/14
20.0 mg/kg
EPA 200.7
Selenium, total
< 1.85 mg/kg
4/25/14
1.85 mg/kg
EPA 200.7
Silver, total
2.63 mg/kg
4/25/14
0.812 mg/kg
EPA 200.7
Sodium, total
1,948 mg/kg
4/25/14
20.0 mg/kg
EPA 200.7
Zinc, total
637 mg/kg
4/25/14
0.500 mg/kg
EPA 200.7
Results reported on dry wt basis
CV
H
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

Contact: Angela Boswell
Client: Rocky Mount, City of
PO Box 1180
Rocky Mount, NC 27802
Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
1311- TCLF Metals
Meritech Work Order # 042214106
Parameter
esult
Page 2
Revised Date: 512312014
Report Date: 5/19/2014
Date Sample Rcvd: 4/22/2014
Sample: BF0415 Grab Collection Date: 4/15/14
Analysis Det. Limit Reg. Limit Method
Arsenic
< 0.100 mg/L
4/29/14
0.100
5.0
EPA 200.7
Barium
1.98 mg/L
4/29/14
0.050
100.0
EPA 200.7
Cadmium
< 0.020 mg/L
4/29/14
0.020
1.0
EPA 200.7
Chromium
< 0.050 mg/L
4/29/14
0.050
5.0
EPA 200.7
Lead
< 0.100 mg/L
4/29/14
0.100
5.0
EPA 200.7
Mercury
< 0.02 mg/L
4/29/14
0.02
0.2
EPA 245.1
Selenium
< 0.100 mg/L
4/29/14
0.100
1.0
EPA 200.7
Silver
< 0.050 mg/L
4/29/14
0.050
5.0
EPA 200.7
TCLP Organics
Aarameter
ResLjR5
Analysis
Method
Pesticides 8080
Attached
4/29/14
8080
Herbicides 8150
Attached
4/29/14
8150
Volatiles 8260
Attached
5/1/14
8260
Semi Vol. 8270
Attached
5/1/14
8270
Other Tests
Eugmeter Results AnalysisRegorting Limit Method
Reactivity- Cyanide, total < 17.3 mg/kg 4/23/14 17.3 mg/kg EPA 335.4
Ignitability > 140 OF 4/23/14 - - EPA 1030
Corositvity- pH 8.2 S.U. 5/5/14 1.0 - 14.0 S.U. SM 4500 HB
Reactivity -Sulfide, total 58.8 mg/kg 4/25/14 10 mg/kg SM 4500 SD
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

Meritech, Inc.
Environmental Laboratory
.a. Laboratory Certification No.165
Page 3
Revised Date: 512312014
Contact: Angela Boswell Report Date: 5/19/2014
Client: Rocky Mount, City of
PO Box 1180
Rocky Mount, NC 27802 Date Sample Rcvd: 4/22,/2014
Meritech Work Order # 042214106 Sample: BF0415 Grab Collection Date: 4/15/2014
1311- TCLP Pesticides & Herbicides
eesilgide - SW-816
8081A
Analyst: Summit
Analysis Date:
4/29/14
Parameter
Results Det. Limit
Reg. Limit Dilution Factor
Heptachlor Epoxide
< 0.002 mg/L 0.002
0.008
1
Endrin
< 0.002 mg/L 0.002
0.02
1
Chlordane
< 0.01 mg/L 0.01
0.03
1
Gamma - BHC
< 0.002 mg/L 0.002
0.4
1
Toxaphene
< 0.1 mg/L 0.1
0.5
1
Methoxychlor
< 0.002 mg/L 0.002
10.0
1
Heptachlor
< 0.002 mg/L 0.002
0.008
1
Uprbicides - SW-846
8151Q,
Analyst: Summit
Analysis Date:
4/29/14
Parameter
Results Dew Limit
Reg. Limit Dilution Factor
2,4-D
< 5 mg/L 5.0
10.0
1
2,4,5-TP (Silvex)
< 0.5 mg/L 0.5
1.0
1
6�2 .
I hereby certify that I have reviewed and approve these data. a.
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville farms, lnc. Class 13 Source Permit No. 111,Wlt) 0,16401
Laboratory 1
City of Rocky
City of Rocky
City of Rocky
Merited', Inc.
Mount
Mount
Mount
Laboratory 2
Merited', Inc.
Meritech, laic.
hacritech, Inc.
Sample orCompositcDatc
3/17/21114
4/21/2014
9/16/201.1
12/22/2014
Parameter (mg/Kg) Class A Clas B
Aluminum N/A N/A
7,210
5,5C6
14,000
8,490
44rvAmmomaNit.__..._._,.. ___._._.___,._.....,._,___._,_._...-....u._
rogen N/A N/A
174
230
......._._..___._
263
_.__....,.__.,....
205
Arsenic
W� 41
75
L62
0.943
0.57
0.97
Cadmium
39
85
0.325
0,189
0,113
0.194
Calcium
N/A
N/A
_ 2,860
4,962
3,785
2,660
Copper
1,500
4,300
0.325
2.13
t5
14
Lead
300
_ 840
8.47 _
11.4
11.9
7.3
Magnesium
N/A
N/A
731
570
441
465
�- Mercury,
w_. 17
�57�
0.062
0.039
wii.1 t3 Y
il.n7s -�
Molybdenum
N/A
75
0,812
0.472
0.283
0.48
Nickel
420
420
22.9
(15.3
44.6
39
Nitrate-Nitritc Nitrogen
N/A
N/A
3.25
1,88
5.49
1.01
Percent Solids
N/A
N/A
3.(t8
5.27
8.82
620
pH (no units)
N/A
N/A
3.90
5.41)
6.50
6.20
Phosphorus
N/A
N/A
763
1,093
1,308
1,147
Potassium
N/A
N/A
347
181
311�
260
PANc.
N/A
N/A
3,056
2,872
3,306
2,287
PAN Surface
N/A
N
757
3,175
2,184
_....Selenium
,..,_._100
100
1.62,..... _
0.943
0.57 ......._.__097
,.,...,.
Sodium
N/A
N/A
709
1,418
331
6.15
SAR
/A
N/A
0.58
1.16
0.40
0.75
w ,rKN
N/A
N/A
7,370
6,831
7,857
5,407
_._-.'line
� _2,800
7._.....,_,'500
_...,_.33.1. _..
_.__.. 43.8
39.4
25
Source Name Tar Ricer WIT
"1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel property gathered and evaluated the information submitted. 1 :rm aware that there arc significant penalties for
suhmitti g false information inc riling the possibility of fines and imprisonment for knowing violations"
L L I
t. i attire of Preparer * Date
reparer i.9 it `fmcd in 40 CPR Part 5019(r) and 15A NCAC 2T .1102 (26)

f AGAIA,N FIELD LOADING ESTIMATES
Facility Tar River WI'P
Sampling Date 3/17/2014
% Solids 3.07
Mineralization Rate 0.40
Gallons per DT 7,811.34
pH 5.9
Sodium Absorpotion 0.58 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 7,370 lbs./1,000 gal 1.89
Ammonia Nitrogen (mg/Kg) 174.00 lbs./1,000 gal 0.04
Nitrate -Nitrite (mg/Kg) 3.25 lbs./1,000 gal 0.00
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 2,969 lbs./1,000 gal 0.76
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 3,056 lbs./1,000 gal 0.78
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Potassium lbs./1,000 gal 0.09
Phosphorus lbs./1,000 gal 0.20
Calcium lbs./1,000 gal 0.73
Calcium lbs./1,000 gal 0.19
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
HEAVY METAL CONCENTRATION
HEAVY METAL LOADING
41
75
Arsenic (mg/Kg)
1.62
Arsenic lbs./1,000 gal
0.00
39
85
Cadmium (mg/Kg)
0.33
Cadmium lbs./1,000 gal
0.00
1,500
4,300
Copper (mg/Kg)
0.33
Copper lbs./1,000 gal
0.00
300
840
Lead (mg/Kg)
8.47
Lead lbs./1,000 gal
0.00
17
57
Mercury (mg/Kg)
0.06
Mercury lbs./1,000 gal
0.00
420
420,
Nickel (mg/Kg)
22.90
Nickel lbs./1,000 gal
0.01
100
100
Selenium (mg/Kg)
1.62
Selenium lbs./1,000 gal
0.00
2,800
7,500
Zinc (mg/Kg)
33.10
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
1st Yeat
r`
2nd Year
i
3rd Year
��- 4th Year
5th Year
Surface Application
Injection/Incorporation Application
Remaining
_
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (ms/DT)
(mg/Kg)
TKN
(mg/kg) (ms/DT)
(mg/]Kg)
7,370
2,969
5.94
4,401
7,370
3,056 6.11
4,314
4,401
880
1.76
3,521
4,314
863 1.73
3,451
3,521
352
0.70
3,169
3,451
345 0.69
3,106
3,169
158
0.32
3,011
3,106
155 0.31
Z951
3,011
75
0.15
2,935
2,951
74 0.15
2,877
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH31+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MIt/16)
ITotal 4,435 8.87 Total 4,493 8.99,,

AGMt1N FIELD LOADING ESTIMATES
Facility Tar River WI'P
Sampling Date 4/21/2014
% Solids 5.27
Mineralization Rate 0.40
Gallons per DT 4,550.44
pH 5.4
Sodium Absorpotion 1.16 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 6,831 lbs./1,000 gal 3.00
Potassium lbs./1,000 gal
0.08
Ammonia Nitrogen (mg/Kg) 230.00 lbs./1,000 gal 0.10
Phosphorus lbs./1,000 gal
0.48
Nitrate -Nitrite (mg/Kg) 1.88 lbs./1,000 gal 0.00
Calcium lbs./1,000 gal
2.18
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Calcium lbs./1,000 gal
0.25
PAN (mg/Kg) 2,757 lbs./1,000 gal 1.21
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 2,872. lbs./1,000 gal 1.26
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
I 2nd Year
3rd Year
4th Year
i
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
0.94
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.19
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
2.13
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
11.40
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.04
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
65.30
Nickel lbs./1,000 gal
0.03
Selenium (mg/Kg)
0.94
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
43.80
Zinc lbs./1,000 gal
0.02
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (ms/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
6,831
2,757 5.51
4,074
6,831
2,872 5.74
3,959
4,074
815 1.63
3,259
3,959
792 1.58
3,167
3,259
326 0.65
2,933
3,167
317 0.63
2,850
2,933
147 0.29
2,786
2,850
143 0.29
2,708
2,786
70 0.14
2,717
2,708
68 0.14
2,640
Equations
1st Yr. PAN (mg/Kg)=(MR x (T'KN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
1 -total 4,114 B./3 Total 4191 8.35

f
L_
1
. AGMAN FIELD LOADING ESTIMATES
Facility Tar River WI'P
Sampling Date 9/16/2014
% Solids 8.82
Mineralization Rate 0.40
Gallons per DT 2,718.91
PH 6.5
Sodium Absorpotion 0.40 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 7,857 lbs./1,000 gal 5.78
Potassium lbs./1,000 gal
0.23
Ammonia Nitrogen (mg/Kg) 263.00 lbs./1,000 gal 0.19
Phosphorus lbs./1,000 gal
0.96
Nitrate -Nitrite (mg/Kg) 5.49 lbs./1,000 gal 0.00
Calcium lbs./1,000 gal
2.78
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Calcium lbs./1,000 gal
0.32
PAN (mg/Kg) 3,175 lbs./1,000 gal 2.34
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 3,306 lbs./1,000 gal 2.43
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
0.57
Cadmium (mg/Kg)
0.11
Copper (mg/Kg)
15.00
Lead (mg/Kg)
11.90
Mercury (mg/Kg)
0.11
Nickel (mg/Kg)
44.60
Selenium (mg/Kg)
0.57
Zinc (mg/Kg)
39.40
Arsenic lbs./1,000 gal
0.00
Cadmium lbs./1,000 gal
0.00
Copper lbs./1,000 gal
0.01
Lead lbs./1,000 gal
0.01
Mercury lbs./1,000 gal
0.00
Nickel lbs./1,000 gal
0.03
Selenium lbs./1,000 gal
0.00
Zinc lbs./1,000 gal
0.03
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (ms/DT)
(mg/Kg)
TffiJ
(mg/kg) (lbs/DT)
(mg/Kg)
7,857
3,175
6.35
4,682
7,857
3,306 6.61
4,551
4,682
936
1.87
3,746
4,551
910 1.82
3,641
3,746
375
0.75
3,371
3,641
364 0.73
3,277
3,371
169
0.34
3,203
3,277
164 0.33
3,113
3,203
80
0.16
3,123
3,113
78 0.16
3,035
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 4,734 9.47
Total 4,822 9.64'

Y, AGIMAN FIELD LOADING ESTIMATES
Facility Tar River WI
Sampling Date 12/22/2014
% Solids 5.16
Mineralization Rate 0.40
Gallons per DT 4,647.44
pH 6.2
Sodium Absorpotion 0.69 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 5,407 lbs./1,000 gal 2.33
Potassium lbs./1,000 gal
0.11
Ammonia Nitrogen (mg/Kg) 205.00 lbs./1,000 gal 0.09
Phosphorus lbs./1,000 gal
0.49
Nitrate -Nitrite (mg/Kg) 1.01 lbs./1,000 gal 0.00
Calcium lbs./1,000 gal
1.14
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Calcium lbs./1,000 gal
0.20
PAN (mg/Kg) 2,184 lbs./1,000 gal 0.94
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 2,287 lbs./1,000 gal 0.98
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Limits (mg/Kg)
41
J 39
1,500
300
17
420
100
2,800
1st Year
2nd Year
3rd Year
4th Year
5th Year
Class B Ceiling
Limits (mg/Kg)
75
85
4,300
840
57
420
100
7,500
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
0.97
Arsenic,lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.19
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
14.00
Copper lbs./1,000 gal
0.01
Lead (mg/Kg)
7.30
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.08
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
39.00
Nickel lbs./1,000 gal
0.02
Selenium (mg/Kg)
0.97
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
25.00
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
'PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(-g/Kg)
5,407
2,184
4.37
3,223
5,407
2,287 4.57
3,120
3,223
645
1.29
2,578
3,120
624 1.25
2,496
2,578
258
0.52
2,320
2,496
250 0.50
Z247
2,320
116
0.23
2,204
2,247
112 0.22
2,134
2,204
55
0.11
2,149
2,134
53 0.11
2,081
Equations
1st Yr. PAN (mg/Kg)=(MR x (T'KN-NH3))+(VR x NH31+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 3,258 6.52
Total 3,326 6.65.

2014 City of Rocky Mount Analytical Report
WQ Permit Number: W00005568 Laboratories. 1) City of Rocky Mount
Sample Identification: City of Rocky Mount Biosolids performing 2) Meritech, Inc
Residual Source WQ # or NPDES #: NC 0072125 analyses:
Facility Name: Tar River Reservoir Water Treatment Plant
Residual Analysis vata
Parameter (mg/kg)
e, ,ng Conc.
L71111Y
(mg/kg)
Sample or Composite
Date
3/17/14
4/21/14
9/16/14
Percent Sol,ds (1)
NA
3.08%
5.27%
8.82%
pH (1)
5.9
5.4
6.5
Arsenic (2)
75
1.62
0.943
0.57
J6.2
Cadmium (2)
85
0.325
0.189
0.1 l3
Copper (2)'
4,300
0.325
2.13
15.0Lead
(2)
840
8.47
11.4
11.9Mercury
(2)
57
0.062
0.038
0.113Molybdenum
(2)
75
0.812
0.472
0.283
Nickel (2)
420
22.9
65.3
44.6
39.0
Selenium (2)
100
1.62
0.943
0.57
0.97
Zinc (2)
_7,500._„
,_•_33.1.
43.8
39.4
- 25.,
Total Phosphorus (1)
NA
763
1093 .
_ 1308
1147.3
TKN
NA- ..
.-7370
683.1
-- _.7857
5407.
Ammonia -Nitrogen (1)
NA
174
230
263
205
Nitrate and Nitrite (1)
NA
3.25
1.88
5.49
1.01
Potassium (2)
11FA
347
181
311
260
Sodium (2)
NA
769
1418
331
645
Magnesium {2)
NA
731
570
441
465
Calcium (2)
NA
2860
4962
3785
2660
Silver (2)
NA
0.812
0.472
0.283
0.48
Aluminum (2)
NA
7210
5566
14000
8490
PAN
NA
2969
2757
3175
2184
SAR (wet)
NA
0.58
1.16
0.40
0.69
FAN/Load (I /6500 gal)
NA
4.96
7.88
15.18
6.11
"t certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure
that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations."
Lab Supervisor/Manager Date
(1) Analyses performed by City of Rocky Mount Laboratory
(2) Anoly5es performed by Writech, lnc

Meritech, Inc.
Environmental. Laboratory
:Laboratory Certification No.165
Bosy%well
Client:, Rocky Mount, City of
PO Box 1180
Rocky Mount, NC 27802
Page 1
Revised Date. 512312014
Report Date:. 5/19/2014
Date Sample Rcvd 4/22./2014
Vf�1' (L�•SNYYOrr
13 11 - TCLP Metals
r Meritech Work Order # 042214109 '
jLi
Sample: TRR SL0421 Grab Collection Date:
4/21/14
Parameter
Results
Analysis Det. Limit
Reg. Limit
Method
Arsenic
< 0.100 mg/L
4/29/14: 0.100
-5:0
EPA.200.7
Barium
0.79S nag/L
4/29/14 0.050
100.0
EPA.200.7
Cadmium
<.0.020 mg/L
4/29/14 0.020
1.0
EPA.200.7
r Chromium
< 0.050 mg/L
4./29/14 0.050
5.0
EPA 200.7
-- Lead
< 0.100 mg/L
4/29J14 0.100
5.0
EPA 200.7
Mercury
< 0.02 mg/L
4/29114 0.02
0.2
EPA 245.1
Selenium.
< 0._10.0 mg/L
4/29/14 0.1-00
1.0
'EPA 200.7
Silver
< 0.080 mg/L
4/29/14 0.050
5.0
EPA 200.7
TCLP Organics
Parameter
r
Results
Analysis
Method
L Pesticides 8080
Attached
4/29114
8080
Herbicides 8150
Attached
5/1/14
-8150
Volatiles 826.0
Attached
5/1/14
8260
Semi Vol. 8270
Attached
5/1/14
8270
Other Tests
Parameter
Results
Analysis Reporting Limit
Method
Cj Reactivity -Cyanide, total
< 14.5 mg/kg
4/23/14 14.5. mg/kg
EPA 335.4
Ignitability
> .140 °F
4/23/14 - -
EPA 1030
Corositvity- pH
4.7 S.U.
5/5/14 1.0 -14.0 S.U.
SM 4500 HB
Reactivity -Sulfide, total
11.6 mg/kg
4/25J14 10 mg/kg
SM 4500 SD
k =E 1TV
MAY 9 %
6442 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
.per
Contact: Angela Boswell
Client: Rocky Mount, City of
PO Box 1180
Rocky Mount, NC 27802
Page 2
Revised Date: 512312014
Report Date: 5/19/2014
Date Sample Rcvd: 4/22/2014
Meritech Work Order #
042214110
Sample: TRR SL0421 Grab
4/21/14.
Parameters
Results
Analysis Date ReportingLimit imit
Method
% Total Solids
5.27 %
4/24/14
0-100 %
SM 2540B
Aluminum, total
5,566 mg/kg
4/25/14
2.50 mg/kg
EPA 200.7
Arsenic, total
< 0.943 mg/kg
4/25/14
0.943 mg/kg
EPA 200.7
Cadmium, total
< 0.189 mg/kg
4/25/14
0.189 mg/kg
EPA 200.7
Calcium,, total
4,962 mg/kg
4/25/14
10.0 mg/kg
EPA 200.7
Copper, total
2.13 mg/kg
4/25/14
0.325 mg/kg
EPA 200.7
Lead, total
11.4 mg/kg
4/25/14
0.500 mg/kg
EPA 200.7
Magnesium, total
570 mg/kg
4/25/14
10.0 mg/kg
EPA 200.7
Mercury, total
0.038 mg/kg
4/29/14
0.010 mg/kg
EPA 245.1
Molybdenum, total
0.472 mg/kg
4/25/14
0.812 mg/kg
EPA 200.7
Nickel, total
65.3 mg/kg
4/25/14
0.500 mg/kg
EPA 200.7
Potassium, total
181 mg/kg
4/25/14
20.0 mg/kg
EPA 200.7
Selenium, total
< 0.943 mg/kg
4/25/14
0.943 mg/kg
EPA 200.7
Silver, total
< 0.472 .mg/kg
4/25/14
0.472 mg/kg
EPA 200.7
Sodium, total
1,418 mg/kg
4/25/14
20.0 mg/kg
EPA 200.7
Zinc, total
43.8 mg/kg
4/25/14
0.500 mg/kg
EPA 200.7
W%F i I� j
2 9
642 'Tamco Road, Reidsville, North Carolina 2732.0
tel.[phone] fax.[phone]

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Page 3
f� Revised Date. 512312014
Contact: Angela Boswell Report Date: 5/19/2014
Client: Rocky Mount, City of
PO Box 1180
Rocky Mount, NC 27802 Date Sample Rcvd: 4/22/2014
Meritech Work Order # 042214109 Sample: TRRSL0421 Grab Collection Date: 4/21/2014
1311- TCLP Pesticides & Herbicides
Pesticide - SW-846 8081A
Analyst: Summit
Analysis Date:
4/29/14
ParameterResults
Det. Limit
Reg. Limit Dilution Factor
Heptachlor Epoxide
< 0,002 mg/L
0.002
0.008
1
Endrin
< 0.002 mg/L
0.002
0.02
1
- Chlordane
< 0.01 mg/L
0.01
0.03
1
Gamma - BHC
< 0.002 mg/L
0.002
0.4
1
Toxaphene
< 0.1 mg/L
0.1
0.5
1
Mothoxychlor
< 0.002 mg/L
0.002
10.0
1
Heptachlor
i
< 0.002 mg/L
0.002
0.008
1
Herbicides - SW-846 8151
Analyst: Summit
Analysis Date:
5/1/14
Parameter Results Det. Limit Reg; Limit Dilution Factor
2,4-D < 5 mg/L 5.0 10.0 1
2,4,5-TP (Silvex) < 0.5 mg/L 0.5 1.0 1
1 hereby certify that! have reviewed and approve these data. 6 . Rao
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

ANNUAL RIESIDUAL SAMPLING SUMMARY FORM
%KrQ Permit No. R'(1W0838 Facility Name Granville Farms, Inc. Class B Source Permit No. NC0020231 Source Name Town of inuisburg
Laboratory 1; rlild- Eastern
lAbs, Inc.
Laboratory 2
i
Sample orCompositeDate' 2/26/2014
Parameter (mg/Kg) Class A Clas B
Alnmiaumj N/A
Ammonia Nitrogen! N/A !
i
N/A
N/A
43.3W
28atp
Arsenic'
_
41 i
—39
- 75-
7
Cadmium!
--- Calcium
i 85 !
N/A N/A
13,800
Copper l
—
1,500 ( 4 0
627
Lead
-
- Alagnesium!
-- 3 00 i
N/A I_.
Sao
N/A
39
3,400
Aletcutyt
17
57 !
2.4
Molybdrnum�
Nickel
N/A: 75
4201,
6
1B
Nitrate -Nitrite Nitrogen{
N/A I
-N/A;
-98.40
Percent Solids!
�
N/- A
I
N/A
2.44
_
pl•i (no units)!
Phosphorus!
N/A j
N/A
N/A 1--
N/A j
7.96
25,8(ro
Potassium!
N/A
N/A
3,850
PAN (Inj /Inc.)!
N/A i
N/A!
37,248 -
PAN (Surface);
-�
N/A
N/A :
23,ogs
--
- Selenium i
- IUD
100 i--
-
Sodium!
---------
N/A
N/A
2 88o
SARI
TRN
-
-N/A
N/A
N/A
N/A j
0.89 --
5 "861)
Zinc
2,800-7,500
! —
�
liRU
^1 certit}•, under penalty o lacy, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified pe nnel properly gathered and evaluated the information subniiued. I am aware that there are significant penalties for
submitting false info lion, including th p ssibility of fines and imprisonment for knowing violations."
fa- ]s
Signature of Prep ` r j�/ Date
*Prepamr is de ed to 40 CFR Part 5 .9(r) and 15A NCAC 2T .1102 (26)

AGVIAN
FIELD LOADING ESTIMATES
Facility Louisburg WWTP
Sampling Date 2/26/2014
% Solids 2.44
Mineralization Rate 0.30
Gallons perDT 9,828.20
pH 7.96
Sodium Absorpotion 0.89 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 57,800 lbs./1,000 gal 11.76
Potassium lbs./1,000 gal
0.78
Ammonia Nitrogen (mg/Kg) 28,300.00 lbs./1,000 gal 5.76
Phosphorus lbs./1,000 gal
5.25
Nitrate -Nitrite (mg/Kg) 98.40 lbs./1,000 gal 0.02
Calcium lbs./1,000 gal
2.81
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.69
PAN (mg/Kg). 23,098 lbs./1,000 gal 4.70
Manganese lbs./1,0G0 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 37,248 lbs./1,000 gal 7.58
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling Class B Ceiling
Limits (mg/Kg) Limits (mg/Kg)
41 75
39 85
1,500 4,300
300 840
17 57
1st Year
2nd Year
3rd Year
4th Year
5th Year
420
100
2,800
420
100
7,500
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
7.00
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
2.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
627.00
Copper lbs./1,000 gal
0.13
Lead (mg/Kg)
39.00
. Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
2.40
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
18.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
1580.00
Zinc lbs./1,000 gal
0.32
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
T
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
57,800
23,098 46.20
34,702
57,800
37,248 74.50
20,552
34,702
5,205 10.41
29,496
20,552
3,083 6.17
17,469
29,496
2,212 4.42
27,284
17,469
1,310 2.62
16,159
27,284
1,023 2.05
26,261
16,159
606 1.21
15,553
26,261
492 0.98
25,769
15,553
292 0.58
15,261
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x N143)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (IvII2/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 32,031 64.06
Total 42,539 85.08

Page: 1 of 2
Report Number: 14-052-0205
Account Number: 45832
Submitted By: RICHARD COLLINS
Send To: TOWN OF LOUISBURG
JIMMY ELLINGTON
110 W NASH ST
LOUISBURG, NC 27549
Lab Number: 98004
Sample Id: SLUDGE
Aol Me Laboratories, Inc.
7621 Vftte; Pme Road Richmond, Virginia 23237 [phone] Fax (BD4) 279-6446
wiruw�leastem�com
Project: LOUISBURG SLUDGE
NC CERT # 257
REPORT OF ANALYSIS
Total Solids '
2.44
24400
100.0
JM
Moisture `
97.56
100.0
JM
Total Kjeldahl Nitrogen
5.78
57800
10.0
JM
Total Phosphorus
2.58
25800
100
KM
Total Potassium
0.39
3850
100
KM
Total Calcium
1.38
13800
100
KM
Total Magnesium
0.34
3400
100
KM
Total Sodium
0.29
2880
100
KM
Total Iron
26400
100
KM
Total Aluminum
43300
100
KM
Total Copper
627
5
KM
Total Zinc
1580
5
KM
Ammonia Nitrogen
2.83
28300
10.0
JM
Organic N
2.95
29500
10.0
Nitrate+Nitrite-N
98.4
2.00
JM
Total Cadmium
2.0
2.0
KM
Total Nickel
18
5
KM
Total Lead
39
5
KM
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis
Date Sampled: 2/19/2014 11:30:00
Date Received: 02/21/2014 00:00
Date Reported: 02/26/2014
02/21 /2014 14:10
02/21 /2014 14:10
02/24/2014 08:30
02/24/2014 13:07
02/24/2014 13:07
02/24/2014 13:07
02/24/2014 13:07
02/24/2014 13:07
02/24/2014 13:07
02/24/2014 13:07
02/24/2014 13:07
02/24/2014 13:07
02/24/2014 08:30
02/24/2014 08:30
02/24/2014 08:45
02/24/2014 13:07
02/24/2014 13:07
02/24/2014 13:07
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
Debbie Holt
SM-2540G
SM-2540G
SM-4500-NH3C-TKN
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SW 6010C
SM-4500-NH3C
CALCULATION
SM-450ONO3F
SW 6010C
SW 6010C
SW 6010C

Page: 2 of 2
Report Number: 14-052-0205
Account Number: 45832
Submitted By: RICHARD COLLINS
Send To: TOWN OF LOUISBURG
JIMMY ELLINGTON
110 W NASH ST
LOUISBURG, NC 27549
Lab Number: 98004
Sample Id: SLUDGE
Total Arsenic
Total Mercury
Total Selenium
pH (Standard Units)
Total Molybdenum
Chloride
Sodium Absorption
' A &L Fastem Laboratories, Inc.
76,21 WhitepineRoad R+ehmond,Vrgln1a23237 (804)74" 0i Fax(8D4)271-S448
wimw�leastemscm
Project: LOUISBURG SLUDGE
NC CERT # 257
REPORT OF ANALYSIS Date Sampled: 2/19/2014 11:30:00
Date Received: 02/21/2014 00:00
Date Reported: 02/26/2014
7.0
3.0
KM
02/24/201413:07
2.4
0.4
KM
02/24/2014 09:00
5.0
5.0
KM
02/24/201413:07
7.96
2.00
JM
02124/201410:30
6
5
KM
02/24/201413:07
2490
200
MW
02/24/2014 08:50
1.79
Comments:
QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Fe", "NH4-N", AND "S". ALL OTHER QC DATA IS ACCEPTABLE.
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
SW 6010C
SW-7471 B
SW 6010C
SW-9045D
SW 6010C
SM-4500CI-D
CALCULATION
Debbie Holt

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
xY�
Contact: Richard Collins
Client: Louisburg, Town of
Page 1
110 West Nash St,
Report Date:
10/20/2014
Louisburg NC 27549
NPDES#:
NCO020231
Date Sample Rcvd:
9/25/2014
Meritech Work Order # 09251442
Sample: Digestor Sludge
Collection Date:
9/25/2014
.13114 TCLP Metals
Pargine er
Results
Analysis
Det. Minit Reg. Limit
Method
Arsenic
Barium
< 0.100 mg/L
1.76 mg/L
10/9/14
0.100 5.0
EPA 200.7
Cadmium
< 0.020 nig/L
10/9/14
10/9/14
0,050 100.0
0.020 1.0
EPA 200.7
EPA 200.7
Chromiurit
< 0.050 tng/L
10/9/14
0.050 5.0
EPA 200.7
Lead
< 0.100 mg/L
10/9/14
0.100 5.0
EPA 200.7
Mercury
< 0.02 mg/L
10/7/14
0.02 0.2
EPA 245.1
Selenium
< 0.100 mg/L
10/9/14
0.100 1.0
EPA 200.7
SIlver
< 0.050 ntg/L
10/9/14
0.050 5.0
EPA 200.7
TCLP Organics
Paratnetet•
Results
Analysis
Met tQd
Volatiles 8260
Attached
10/2/14
8260
Semi Vol. 8270
Attached
10/8/14
8270
Other Tests
Parameter
Results
n sis A aly .
Reporting -Limit
Method
Ignitability
Will not ignite
9/25/14
- -
EPA 1030
pH
8.0 S.U.
10/6/14
1.0 -14.0 S.U.
SM 4500 FIB
Cyanide, total
< 0.500 mg/kg
10/3/14
0.500 mg/kg
EPA 33.5.4
Sulfide, total
6.1 tng/kg
9/29/14
5.0 mg/kg
SM 4500 SD
642 Tainco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Contact: Richard Collins
Client: Louisburg, Town of
110 West Nash St.
Louisburg NC 27549
Merltech Work Order # 09251442 Sample: Digestor Sludge
Page 2
Report Date: 10/20/2014
NPDES#: NCO020231
Date Sample Rcvd: 9/25/2014
Collection Date: 9/25/2014
13110 'TCLP Pesticides & Herbicides
Pesticide - SW-846_$01 1"
Analyst: Stunmit
Analysis Date: 10/13/14
Parameter
Results
Det. Limij
Reg. Limit
Dilution Factor
Methoxycltlor
< 0,002 mg/L
0.002
10.0
1
Toxaphene
< 0.10 mg/L
0.1
0.5
1
Gamma - BHC
< 0.002 mg/L
0.002
0.4
1
Chlordane
< 0.010 nig/L
0.01
0.03
1
Endrin
< 0.002 mg/L
0.002
0.02
1
Heptachlor Epoxide
< 0.002 ntg/L
0.002
0.008
1
Heptachlor
< 0.002 mg/L
0.002
0.008
1
Herbicides - SW-846 8151A
Analyst: Summit
Analysis Date: 10/10/14
Paraniete
Results
Det. Limit
Rom. Limit
Dilution raetor
2,4,5-TP (Silvex)
< 0.10 nig/L
0.10
0.5
1
2,4-D
< 0.10 mg/L
0.10
0.5
1
I hereby certify that I have reviewed and approve these data. f .
Laborato►y Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

MERITECH, INC.
Environmental Laboratories
E ' Laboratory Certificate #165
Client Louisburg
Project: TCLP
Client Sample, ID: Digestor Sludge
Sample Collection: 09/25/14
Meritech Sample ID: 09251442
1311 m TCLP ®raanics
Volntlles: SW-846 8260
Analysis: 10/02/14
Extracted:
09/29/ 14
Analyst: VwV
Parameter
Result
Units
Det. Limit
Reg, Limit
Dilution Factor
Benzene
< 0,0100
mg/],
0.0100
5.00
l0
Carbon Tetrachloride
< 0.0100
mg/L
0.0100
5.00
10
Clilorobenzene
< 0.0100
mg/1,
0.0100
l00
10
Chloroform
< 0.0100
mg/L
0.0100
6.0
10
1,2-Diclhtoroethnne
< 0.0100
mg/1,
0.0100
0.50
10
1,1-Dichlorocthene
<0.0100
mg/L
0.0100
0.70
10
Methyl Ethyl Ketone
< 0.100
mg/L
0.100
200
10
Teh•achloroctliylene
< 0.0100
mg/L
0.0100
0.70
10
Trichloroetiiene
< 0.0100
mg/L
0.0100
0.50
10
Vinyl Chloride
< 0,0200
mg/I.
0.020
0.20
10
Semi-Volntlles: SW-846 8270
Analysis; 10/08/14 Extracted: 09/29/14
Analyst: I'M
Parameter
Result
Un1tS
Det. Limit
Reg. Limit
Dilution Factor
1,4-Diellorobenzene
<0.100
mg/L
0.100
7.5
10
1-[exachlorobenzene
<0.100
mg/L
0.100
0.13
10
Hexachloro-1,3-butadicne
<0.100
mg/L
0.100
0.5
10
1-fcxacliloroethanc
<0.100
ing/L
0.100
3.00
10
c-cresol
<0.100
mg/L
0.100
200
10
m&p-cresol
<0.200
mg/L
0.200
200
10
Total cresols
<0.300
mg/L
0.300
200
10
Nitrobenzene
<0.100
mg/L
0.100
2.00
10
Pentachlorophenol
<0.500
mg/L
0.500
t00
10
Pyridine
<0.100
mg/L
0.100
5.0
10
2,4,5-Trichlorophenol
<0.100
mg/[,
0.100
400
10
2,4,6- Frichloropllenol
<0.100
mg/L
0.100
2.00
l0
2,4-Dinitrotoluene
<0.100
mg/L
0.100
0.13
10
I hereby certify that I !rave reviewed and approve these data. v fa
Laboratory Representative
642 Tamco Road * Reidsville, NC 27320
[phone] Ph * [phone] Fax

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc_ Claw 11 Source Permit No. N(.0020834 Source Name 7bwn of Warrcnum XVWlP
Laboratory I
W. Eastern
I. bs, Inc.
Laboratory 2
Sample or CompositeDate
3/ 12/2014
Parameter (mg/Kg) Class A Clas B
I -Aluminum N/A N/A
17;)011
Ammonia Nitrogen N/A N/A
7,730
Arsenic
41
75
4
---- Cadmium
39
85
2
Calcium
N/A
N/A
31,400
Copper
1,500
4,300
9-11)
Lead
300
840
29
- -Magnesium
N/A
N/A
2.430
Mercury
17
57
0.8
Illolybdenu
N/A
75
5
Nickel
420
420
16
Nitrate -Nitrite Nitrogen
N/A
N/A
68
Percent Solids
N/A
N/A
2.21)
pH (no units)
N/A
N/A
7.09
Phosphorus
N/A
N/A
20,000
Potassium
N/A
N/A
3,080
PAN (Ini./Inc.)
N/A
N/A
26.7-19
PAN (Surface)
N/A
N/A
2-1,881
�5
Selenium
100
4
` 100
—Sodium
N/A
N/A
2,280
SAR
N/A
N/A
0.49
TKN
N/A
N/A
70,900
Zinc
2,800
7,500
1,80
"I certify, tinder penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. 1 am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
.Q 1 Q 1- 3 6 / 41
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 5039(r) and 15A NCAC 2T .1102 (26)

e AGMAT
FIELD LOADING ESTIMATES
Facility Town of Warrenton WWTP
Sampling Date 3/12/2014
% Solids 2.2
Mineralization Rate 0.30
Gallons per DT 10,900.37
PH 7.09
` Sodium Absorpotion 0.49 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 70,900 lbs./1,000 gal 13.01
Potassium lbs./1,000 gal
0.57
Ammonia Nitrogen (mg/Kg) 7,730.00 lbs./1,000 gal 1.42
Phosphorus lbs./1,000 gal
3.67
Nitrate -Nitrite (mg/Kg) 68.20 lbs./1,000 gal 0.01
Calcium lbs./1,000 gal
5.76
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.45
PAN.(mg/Kg) 22,884 lbs./1,000 gal 4.20
Manganese lbs./1,000 gal
0.09
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
1.61
PAN (mg/Kg) 26,749 lbs./1,000 gal 4.91
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
1st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
4.00
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
2.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
940.00
Copper lbs./1,000 gal
0.17
Lead (mg/Kg)
29.00
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.80
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
16.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
1280.00
Zinc lbs./1,000 gal
0.23
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
70,900
22,884 45.77
48,016
70,900
26,749 53.50
44,151
48,016
7,202 14.40
40,813
44,151
6,623 13.25
37,528
40,813
3,061 6.12
37,752
37,528
2,815 5.63
34,714
37,752
1,416 2.83
36,337
34,714
1,302 2.60
33,412
36,337
681 1.36
35,655
33,412
626 1.25
32,785
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 33,245 70.49
Total 38,115 76.23

Page: 1 of 2
Report Number: 14-072-0214
Account Plumber: 46378
Submitted By: LINDA BOBBITT
Send To: TOWN OF WARRENTON WWTP
AL ALEXANDER
WARREN CO WWTP
POB.281
WARRENTON , NC 27589
Lab Number: 98368
Sample Id: BIOSOLID
99. A L Eastam Laborat®des Inc
7621 wsisep3rre Roan Rtchaxsaae®, YDrgin)a 23237 lsaap 7a3,%a1 Fax lase, rn-saas
bastsrrl.��m
Project: BIOSOLID
NC CERT#257
REPORT OF ANALYSIS Date Sampled: 3/12/2014 07:15:00
Date Received: 03/13/2014 00:00
Date Reported: 03/20/2014
Total Solids `
2.20
22000
100.0
JM
03/13/201414:50
SM-2540G
Moisture
97.80
100.0
JM
03/13/201414:50
SM-254OG
Total Kjeldahl Nitrogen
7.09
70900
10.0
JM
03/17/2014 08:44
SM-4500-NH3C-TKN
Total Phosphorus
2.00
20000
100
KM
03/14/201412:06
SW 6010C
Total Potassium
0.31
3080
100
KM
03/14/201412:06
SW 6010C
Total Sulfur
0.88
8790
100
KM
03/141201412:06
SW 6010C
Total Calcium
3.14
31400
100
KM
03/141201412:06
SW 6010C
Total Magnesium
0.24
2430
100
KM
03/14/201412:06
SW 6010C
Total Sodium
023
2280
100
KM
03/14/201412:06
SW 6010C
Total Iron
16000
100
KM
03/14/201412:06
SW 6010C
Total Aluminum
17900
100
KM
03/14/201412:06
SW 6010C
Total Manganese
512
5
KM
03/14/201412:06
SW 6010C
Total Copper
940
5
KM
03/14/201412:06
SW 6010C
Total Zinc
1280
5
KM
03/14/201412:06
SW 6010C
Ammonia Nitrogen
0.77
7730
10.0
JM
03/14/2014 08:50
SM-4500-NH3C
Organic N
6.32
63170
0.001
JM
03/20/201415:42
CALCULATION
Nitrate+Nitrite-N
68.2
2.00
JM
03/14/2014 08:50
SM-450ONO3F
Total Cadmium
2.0
2.0
KM
03/14/2014 12:06
SW 6010C
All values are on a dry, weight
basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in
whole or part, nor may any reference be made
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
Debbie Holt

Page: 2 of 2
Report Number: 14-072-0214
Account Number: 46378
Submitted By: LINDA BOBBITT
Send To: TOWN OF WARRENTON WWTP
AL ALEXANDER
WARREN CO WWTP
POB 281
WARRENTON , NC 27589
Lab Number: 98368
Sample Id: BIOSOLID
AL Eestem Leboretofies, Inc.
7621 Wdit one Road Rich=nd, Virg5nla 2323T (M)743-Mi Fax(W4t 27t4W
easRem.csem .
Project: BIOSOLID
NC CERT#257
REPORT OF ANALYS/S Date Sampled: 3/12/2014 07:15:00
Date Received: 03/13/2014 00:00
Date Reported: 03/20/2014
Total Chromium
31
5
KM
03/14/201412:06
SW 6010C
Total Nickel
16
5
KM
03/14/201412:06
SW 6010C
Total Lead
29
5
KM
03/14/201412:06
SW 6010C
Total Arsenic
4.0
3.0
KM
03/14)201412:06
SW 6010C
Total Mercury
0.8
0.4
KM
03/14/2014 09:00
SW-7471 B
Total Selenium
<5.0
5.0
KM
03/14/201412:06
SW 6010C
pH (Standard Units) ' 7.09
2.00
JM
03/14/2014 08:50
SW-9045D
Calcium Carbonate Equivalent 1.97
19700
100
JM
03/14/201413:20
AOAC 955.01
Total Molybdenum
5
5
KM
03/14/201412:06
SW 6010C
Comments:
CCE, SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES.
TCLP AND ICR TO FOLLOW
SENT TO ATT LAB
QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "TKN".
ALL OTHER QC DATA IS ACCEPTABLE.
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made 9�/W'mez—
to the work. the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization -
Debbie Holt

03/26/2014
A Ss L Lastern Labs
Attn: Tricia Stoss
7621 White pine Rd
North Chesterfield, VA 23237
Report No.: 031414-05
IJ
American Testing Technotogilsa 14-07 Ilt �Ijj I[ itlteHlAliif! 14-07246378 -0221
TOWN OF WARRENTON WWTP 03-13-2014
BIOSOLID/TCLP & ICR 1333:03
TOWN OF WARRENTON WWTP
WARREN CO WWTP
POB 281
WARRENTON' NC 27589
46378
Enclosed are the results of the samples) submitted to our laboratory on 03/14/2014.
All analyses were performed according to our laboratory's quality assurance program.
All sample results are reported on an "as -received" wet basis unless otherwise noted. The
test results meet requirements of the NELAP standards for methods listed on the
laboratory's current fields of accreditation (EPA 8260, 8082, 8081, 8151, 8270, 6010,
6020, 1010, 9045, 7471, 1010, 1311,150.1, 200.7, 200.8, and 245.1) except as noted.
Results apply only to the items submitted to the laboratory for analysis. Pursuant to
NELAP, this report may not be reproduced except in fall, and with written approval from
the laboratory,
If you have any questions please contact the laboratory manager at 330-634-9906 or via
email at sarnyOaniericantestinetmhnologies.com
` ATT is NELAP-accredited by the State of Florida, #k 871084. Other state accreditations include: North
Carolina, #670; Pennsylvania 468-05167; Vilest Virginia, #372.
The results relate only to the items tested. ATT shall have no liability to the client or client's customer with
respect to decisions or recommendations made, actions taken or courses of conduct implemented by either
the client or the client's customer as a result of or based upon the "rest Results. In no event shall ATT's
liability with respect to the Test Results exceed the amount paid to ATT by the client therefor.
1350 Home Avenue Akron, ON 44310
Toil Free: 877-634-9906 Phone; (330) 63 4-9908 Fax [phone] Website: www,AmericanTestingiechnotagies.com

A & L Eastern Labs
AM; Tricia Stoss
7621 White pine Rd
North Chesterfield, VA 23237
Date Received: 03/14/2014
Date Reported: 03/26/2014
Date Collected: 03/12/2014
Time Collected: 7:15
Client ID #: 99382
Laboratory ID #: 031414-05
Date of Analysis: 03/15/2014
Certificate of AnMI sis
Metals-TCLP (EPA 1311)
Parameter
Results,
912:19
Regulatory
Method
Limits
Number
Arsenic
<1.0
mg/1'
5.0
6010C
Barium
<10
mg/L
100.0
6010C
Cadmium
<0.5
mg/L
1.0
6010C
Chromium
<1.0
mg/L
5.0
6010C
Lead
<1.0
mg/L
5.0
6010C
Mercury
<0.02
mg/L
0.2
7470A
Selenium
<0.5
tng/L
1.0
6010C
Silver
<1.0
mg/L
5.0
6010C
Final rep rt reviewed by:
t
Lab -T alter
1350 Home Avenue Akron, OH 44310
Toil Free: 877-634-9906 Phone: [phone] Fax: [phone] Web -site: www.AmeecanTestingiechnologies.com

A & L Eastern Labs
Attn: Tricia Stoss
7621 White pine Rd
North Chesterfield, VA 23237
Date Received: 03/14/2014
Date Reported: 03/26/2014
Date Collected: 03/12, 014
Time Collected: 7:15
Client ID 4: 483$2
Laboratory ID #: 031414-05
Date of Analysis: 03/26/2014
Certificate of Analysis
Volatile&-TCLP (EPA 1311)
Parameter
Results
Units
Regulatory
Method
Umi
Number
Benzene
<0.1
mg/L
0.5
8260B
Carbon tetrachloride
<0.I
mg/L
0.5
8260D
Chlorobenzene
<0.I.
mg/L
100
8260B
Chloroform
<0.1
mg/L
6.0
8260B
1,2-Dichloroedma
<0.1
mg/L
0,5
82608
1, l-Dichloroethene
<0,1
mg/L
0.7
826013
Methyl ethyl ketone
<2.0
mg/L
200
8260E
Tetrachloroothene
<0.1
mg/L
0.7
8260B
Trichloroethene
<0.I
mg/L
0.5
8260B
Vinyl chloride
<0 2
mg/L
0.2
8260B
Final re 0,
� r viewed by:
L.ab at nager
1350 Home Avenue Akron, OH 4431.0
Toll Free: 377-634-9906 Phone: [phone] Fax: [phone] Website: vvww.Ameri(.anTestingrechnologies_com
r

L
American Testing Technologies, Inc.
A & L Eastern Labs
Attn: Tricia Stoss
7621 White pine Rd
North Chesterfield, VA 23237
Date Received: 03/14/2014
Date Reported: 03/26/2014
Date Collected: 03/12/2014
Time Collected: 7:15
Client 11) #_ 98382
Laboratory 1D #: 031414-05
Date of Analysis: 0.3/22/2014
Certifi_cate of Analysis
DNA-TCLP (EPA 1311)
Parameter Results nits Regulatory Method
Limits Number
44Dichlorobenzene <0.05 mg/L 7.5 8270C
2,4-Dinitrotoluene <0.05 mg/L 0.15 8270C
Hexachlarobenzene <0.05 ing/L 0.13 8270C
Hexachlorobutadiene <0.05 mg/L 0.5 8270C
Hexachloroethane <0.05 mg/L 3.0 8270C
Nitrobenzene <0.05 mg/L 2.0 8270C
Pyridine <0.05 mg/1, 5.0 8270C
o-Cresol <0.5 mg/L 200 8270C
m,p-Cresol <0.5 mg/L 200 8270C
Pentachiorophenol <0.5 rnWL 100 8270C
2,4,54'richlorophenol <0.5 mglL 400 8270C
2,4,6-Trichlorophenol <03 mg/L 2.0 8270C
Final re oY re iewed by:
1,ab ry a ger _
9.350 Home Avenue Akron, OH 4431.0
Toll Free: 877-634-9906 Phone: [phone] Fax. [phone] Website: www.AmericanTestingTechnoloi ies.com

A & L Eastern Labs
Ann. Tricia Stoss
7621 White pine Rd
Notch Chesterfield, VA 23237
Date Received: 03/14/2014
Date Reported: 03/26/2014
Date Collected: 03/12/2014
Time Collected: 7:15
Client ID #: 98382
Laboratory ID 4: 03 1414-05
Date of Analysis: 03/23/2014
C©rtiiicate of Analysis
Pesticides-TCLP (EPA 1311)
Parameter
Results
Units
Regulatory
Method
Limits
Number
Chlordane
<0.005
mg/L
0.03
8081B
Endrin
<0.005
mg/L,
0.02
808113
Heptachlor
<0.005
mg/L,
0.008
8081B
Heptachlor epoxide
<0.005
mgIL
0.008
8081 B
Luidane
<0.005
mg/L
0.4
8081B
Methoxychlor
<0.1
mg/ . L
10.0
80818
Toxaphene
<0.1
mg/L
0.5
808113
Final p reviewed by:
Lab ra nager
1350 Home Avenue Akron, OH 443i0
Toll Free: 877-634-9906 Phone: [phone] Fax: [phone] Website: www.AmericanTestingTechnologies.com

r,
American Testing Technologies, Inc.
f
L
A & L Eastern Labs
Attn: Tricia Stoss
7621 White pine Rd
North Chesterfield, VA 23237
Date Received: 03/14/2014
Date Reported. 03/26/2014
Date Collected: 03/12/2014
Time Collected: 7:15
Client ID 4: 98382
Laboratory ID #: 031414-05
Date of Analysis: 03/22/2014
Certificate of Analvsis
Herbieides-TC.LI? (EPA 1311)
Parameter Results Units
2,4-D <1.0 mg/L
2,4,5-TP (Silvex) <1.0 mg/L
Fuia1 report reviewed by:
t
Laborat r
Regulatory
Method
Limits
Num er
10.0
9151 A
1.0
8151A
1350 Home Avenue Akron, OH 44310
Toll Free: 877-634.9906 Phone: [phone] Fax: [phone] Website: www.AmericentestingTechnologies.com

Date Received: 03/14/2014
Date Reported: 03/26/2014
Date Collected: 03/12/2014
Time Collected: 7:15
Client ID ##: 98382
Laboratory iD 0. 031414-05
Certificate of Analysis
Paramete
a ul s
Unit
Method
Date of
Plumber
Analysis
Reactive Cyanides
<0.5
mg/I
7.3.3.2
03/21/2014
Reactive Sulfides
<25
mg/i
7.3.4.1
03/21/2014
PH (Lab)
6.75
S.U.
9045D
03/14/2014, @1330
Flash point
>140
OF
1010A
03/14/2014
Final r viewed by:
1
1350 Home Avenue Akron, OH 44310
Toll Free: 877-634-9906 Phone: [phone] Fax: [phone] Website: www.AmericanTestingTechnologies.com

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ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO065714 Source Name TradeNvinds WWTP
Laboratory 1 Environmental
Conservation
Laboratory 2
Sample or CompositeDate 10/28/2014
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
5,660
Ammonia Nitrogen
N/A
N/A
140
Arsenic
41
75
26.4
Cadmium
39
85
2.53
Calcium
N/A
N/A
32,000
Copper
1,500
4,300
330
Lead
300
840
49.9
Magnesium
N/A
N/A
6,920
Mercury
17
57
1.82
Molybdenu
N/A
75
26.4
Nickel
420
420
95
Nitrate -Nitrite Nitrogen
N/A
N/A
3,500.00
Percent Solids
N/A
N/A
0.40
pH (no units)
N/A
N/A
7.00
Phosphorus
N/A
N/A
2,400
Potassium
N/A
N/A
6,610
PAN (Inj./Inc.)
N/A
N/A
5,818
PAN (Surface)
N/A
N/A
5,748
Selenium
100
100
26.4
Sodium
N/A
N/A
18,100
SA R
N/A
N/A
1.51
TKN
N/A
N/A
7,400
Zinc
2,800
7,500
1000
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations"
02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

,�'
Facility Tradewinds WWTP
Sampling Date 10/28/2014
% Solids 0.4
Mineralization Rate 0.3
Gallons per DT 59,952.04
PH 7
FIELD LOADING ESTIMATES
Sodium Absorpotion 1.51 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land .Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 7,400 lbs./1,000 gal 0.25
Ammonia Nitrogen (mg/Kg) 140.00 lbs./1,000 gal 0.00
Nitrate -Nitrite (mg/Kg) 3,500.00 lbs./1,000 gal 0.12
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 5,748 lbs./1,000 gal 0.19
PLANT AVAILABLE NITROGEN INJECTEDANCORPORATED APPLIED
PAN (mg/Kg) 5,818 lbs./1,000 gal 0.19
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling Class B Ceiling
Limits (mg/Kg) Limits (mg/Kg)
41 75
39 85
1,500 4,300
300 840
17 57
420 420
100 100
2,800 7,500
1st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
Potassium lbs./1,000 gal 0.22
Phosphorus lbs./1,000 gal 0.08
Calcium lbs./1,000 gal 1.07
Magnesium lbs./1,000 gal 0.23
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
26.40
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
2.53
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
330.00
Copper lbs./1,000 gal
0.01
Lead (mg/Kg)
49.90
Lead lbs./1,000 gal
0.00•
Mercury (mg/Kg)
1.82
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
95.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
26.40
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
1000.00
Zinc lbs./1,000 gal
0.03
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(lbs/DT)
(mg/Kg)
T
(mg/kg) (lbs/DT)
(mg/Kg)
7,400
5,748
11.50
1,652
7,400
5,818 11.64
1,582
1,652
248
0.50
1,404
1,582
237 0.47
1,345
1,404
105
0.21
1,299
1,345
101 0.20
1,244
1,299
49
0.10
1,250
1,244
47 0.09
1,197
1,250
23
0.05
1,227
1,197
22 0.04
1,175
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/I6)
Total 6,173 12.35
Total 6,225 12.45

www.encolabs.com
SAMPLE DETECTION SUMMARY
Client ID: Tradewinds Sludge
Lab ID:
C413814-01
Analyte
Results
Flaa
MDL
PPOL
Units
Method
Notes
% Solids
0.4
0.1
0.1
% by Weight
% Solids
Aluminum - Total
5660
554
2640
mg/kg dry
EPA 6010C
Ammonia as N
140
12
26
mg/kg dry
EPA 350.1
Calcium -Total
32000
B
1480
6590
mg/kg dry
EPA 6010C
QB-01
Copper - Total
330
50.1
132
mg/kg dry
EPA 6010C
Lead - Total
49.9
3
31.7
132
mg/kg dry
EPA 6010C
Magnesium - Total
6920
B
171
6590
mg/kg dry
EPA 6010C
QB-01
Nitrate/Nitrite as N
3500
D
1000
2500
mg/kg dry
EPA 353.2
pH
7.0
1.0 -
1.0
pH Units
EPA 9045D
Potassium - Total
6610
1060
6590
mg/kg dry
EPA 6010C
Sodium - Total
18100
1580
6590
mg/kg dry
EPA 6010C
Total Solids
0.38
0.0010
0.0010
% by Weight
SM 2540G-1997
Zinc - Total
1000
290
659
mg/kg dry
EPA 6010C
Client ID: Tradewinds Sludge
Lab ID:
C413814-01RE1
Analyte
Results
Flag
MDL
P L
Units
Method
Notes
Phosphorus
2400
D
47
130
mg/kg dry
EPA 365.4
1�! Total Kjeldahl Nitrogen
7400
D
350
380
mg/kg dry
EPA 351.2
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 11

www.encolabs.com
ANALYTICAL RESULTS
Description: Tradewinds Sludge Lab Sample ID:C413814-01 Received: 10/28/14 12:50
Matrix: Sludge Sampled:10/28/14 08:50 Work Order: C413814
Project: Tradewinds-Annual Sludge Analysis Sampled By:Otis Fields % Solids: 0.38
" -
(Metals by EPA 6000/7000 Series Methods
A - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flaa
Units
DF
MDL
4
Batch
Method
Analyzed
Notes
Aluminum [7429-90-5]A
5660
mg/kg dry
1
554
2640
4KO5014
EPA 6010C
11/07/14 13:19
JDH
Arsenic [7440-38-2]A
< 26.4
mg/kg dry
1
26.4
132
4KO5014
EPA 6010C
11/07/14 13:19
JDH
Cadmium [7440-43-9]A
< 2.53
mg/kg dry
1
2.53
13.2
4KO5014
EPA 6010C
11/07/14 13:19
JDH
Calcium [7440-70-2]A
32000
B
mg/kg dry
1
1480
6590
4KO5014
EPA 6010C
11/07/14 13:19
JDH
QB-01
Copper[7440-50-8]A
330
mg/kg dry
1
50.1
132
4KO5014
EPA 6010C
11/07/14 13:19
JDH
Lead [7439-92-1]A
49.9
J
mg/kg dry
1
31.7
132
4KO5014
EPA 6010C
11/07/14 13:19
JDH
Magnesium [7439-95-4]A
6920
B
mg/kg dry
1
171
6590
4KO5014
EPA 6010C
11/07/14 13:19
JDH
QB-01
Mercury [7439-97-6]A
< 1.82
mg/kg dry
1
1.82
6.33
4KO4012
EPA 7471B
11/04/14 17:57
T1D
Molybdenum [7439-98-7]A
< 26.4
mg/kg dry
1
26.4
132
4KO5014
EPA 6010C
11/07/14 13:19
JDH
Nickel[7440-02-0]A
< 95.0
mg/kg dry
1
95.0
659
4KO5014
EPA 6010C
11/07/14 13:19
JDH
Potassium [7440-09-7]A
6610
mg/kg dry
1
1060
6590
4KO5014
EPA 6010C
11/07/14 13:19
JDH
Selenium [7782-49-2]A
< 26.4
mg/kg dry
1
26.4
132
4KO5014
EPA 6010C
11/07/14 13:19
JDH
Sodium [7440-23-5]A
18100
mg/kg dry
1
1580
6590
4KO5014
EPA 6010C
11/07/14 13:19
JDH
Zinc [7440-66-6]A
1000
mg/kg dry
1
290
659
4KO5014
EPA 6010C
11/07/14 13:19
JDH
Classical Chemistry Parameters
Analyte rCAS Numberl
Results
Flaa
Units
DF
MDL
PPOL
Batch
Method
Analyzed
By
Notes
Solids
0.4
% by Weight
1
0.1
0.1
4KO3019
% Solids
10/31/14 16:01
MMR
Ammonia as N [7664-41-7]
140
mg/kg dry
1
12
26
4329005
EPA 350.1
10/30/14 09:58
SHA
Nitrate/Nitrite as N
3500
D
mg/kg dry
97.5
1000
2500
4KO4005
EPA 353.2
11/04/14 13:19
SHA
pH
7.0
pH Units
1
1.0
1.0
4329031
EPA 9045D
10/29/14 13:52
MMR
Phosphorus [7723-14-0]
2400
D
mg/kg dry
5
47
130
4131009
EPA 365.4
11/03/14 15:00
civ
Total Kjeldahl Nitrogen
7400
D
mg/kg dry
3.08
350
380
4331008
EPA 351.2
11/03/14 14:40
clv
Total Solids
0.38
% by Weight
1
0.0010
0.0010
4331024
SM 254OG-1997
10/31/14 16:01
MMR
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 11

ANNUAL RESIDUA. SAMPLING SUMMARY ]FORM
WQ) Pcrnil No. iVQXPD11tWH Faci]iiy Name Gr mine FArms, Inc. fps It So-arce Pe5mit No. NUM73318 '. imme Namr- 9TT/Ivgplj X)Mill Valley wl%rr P
Laboratory I
Laboratory 2
Sample or CompositeDate
Parameter (mg/I(g) Class A C4as B
➢•iov+binaLr7
%lor.
4/24/M14
Almmioum
Ammonia Ni/rogen
N/A
N/A
N/A
N/A
3935
3,993
Arsenic
41
75
2.3
—
Cadmium
- - 39 -
— 85
--- 0.7
-^15,575 —
�_�- Calcium
- N/A
N/A
Copper
1,500
4,3W
1321
- — --
Lead
Magnesium
T390
N/A
840
°
° N/A
12
3,600
Merculy
17
57
021
- - -----
Molybdenum
-----
N/A
—
75
-------
6
-- —
---- ---- Nidkdl
420
420
11—
---
Nitrate-NiariteNit gen
_-_-- Percent Solids
pFI (no waits)
^N/A
- NSA
--N/A
- N/A
-----
— 0.63 _
N/A
N/A
6.R0
Phosphorus
N/A
N/A
6,397
— Potassium
N/A
N/A
9,118
PAN (Ini./Inc.)
N/A
N/A
4,831
PAN (Surface)
Selenium
----- --------- ---- - ---- --
Sodium
----------- ----
SAR
TIW
Zinc
N/A
100
N/A
N/A
2,835
100
N/A
5
10,513
1.56
6,7(.4
— 917 --
---------
N/A
N/A
2,800
--------
N/A
N/A
7,500
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility/oaf lines and imprisonment for knowing violations"
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (2 t)

FIELD LOADING ESTIMATES
Facility Whippoorwill Valley WWTP
Sampling Date 4/24/2014
% Solids 0.63
Mineralization Rate 0.3
Gallons per DT 38,064.79
pH 6.8
Sodium Absorpotion 1.56 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land ripply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 6,768 lbs./1,000 gal 0.36
Potassium lbs./1,000 gal
0.48
Ammonia Nitrogen (mg/Kg) 3,993.00 lbs./1,000 gal 0.21
Phosphorus lbs./1,000 gal
0.34
Nitrate -Nitrite (mg/Kg) 5.80 lbs./1,000 gal 0.00
Calcium lbs./1,000 gal
0.82
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,,000 gal
0.19
PAN (mg/Kg) 2,835 lbs./1,000 gal 0.15 -
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 4,831 lbs./1,000 gal 0.25
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface .Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
11500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
2.50
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.70
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
1321.00
Copper lbs./1,000 gal
0.07
Lead (mg/Kg)
12.00
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.21
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
11.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
917.00
Zinc lbs./1,000 gal
0.05
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TI{N
(mg/kg) (lbs/DT)
(mg/Kg)
TEN(mg/kg)
(lbs/DT)
(mg/Kg)
6,768
2,835
5.67
3,933
6,768
4,831 9.66
1,937
3,933
590
1.18
3,343
1,937
291 0.58
1,646
3,343
251
0.50
3,092
1,646
123 0.25
1,523
3,092
116
0.23
2,977
1,523
57 0.11
1,466
2,977
56
0.11
2,921
1,466
27 0.05
1,438
Equations
1st Yr. PAN (mg/Kg)=W x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
i
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total • 3,847 7.69 Total 5,330 10.66

mhd
7)RIVE:. PNON (252)
WHIPPOORWILL VALLEY (CLARKE)
C/O CLARKE UTILITIES LLC
223 HWY. 70 EAST
EAST POINTE 120 B
GARNER ,NC 27529-4062
Sludge
Analysis
Method
PARAMETERS
Sample
Date Analyst
Code
PH (not . to be used for reporting)
6.8
04/24/14 TRB
450OBB-00
Aluminum, (dry wt. basis), mg/kg
3435
05/06/14 LFJ
EPA200.7
Arsenic (dry wt. basis), mg/kg
C 2.5
05/07/14 MEL
3113B-04
Calcium (dry wt. basis), mg/kg
15575
05/06/14 LFJ
EPA200.7
Cadmium (dry wt. basis), mg/kg
0.7
05/15/14 MEL
3113B-04
Copper (dry wt. basis), mg/kg
1321
05/06/14 LFJ
EPA200.7
Chromium, T.(dry wt. basis),mg/kg
6
05/06/14 LFJ
EPA200.7
Lead (dry weight basis), mg/kg
12
05/06/14 MEL
3113B-04
Magneslum (dry wt. basis), mg/kg
3600
05/06/14 LFJ
EPA200.7
Mercury (dry wt. basis), mg/kg
0.21
05/08114 MTM
245.1 R3-94
Nickel (dry wt. basis), mg/kg
11
05/06/14 LFJ
EPA200.7
Potassium (dry wt. basis), mg/kg
9118
05/06/14 LFJ
EPA200.7
Selenium (dry wt. basis), mg/kg
<5.0
05/14/14 MEL
3113B-04
Sodium (dry wt. basis), mg/kg
10513
05/06/14 MTM
3111E-99
Zinc (dry wt. basis), mg/kg
917
05/07/14 MTM
3111B-99
Total Solids, %
0.63
04/25/14 CMC
254OG-97
TKN (dry wt.), mg/kg
6768
05/05/14 ANO
351.2 112-93
Aiatnaonia Nitrogen (dry. wt.),mg/kg
-3993
04/29/14 ALB
350.1 R2-93
Phosphorus, T. (dry wt.), mg/kg
6397
05/01/14 ALB
365.4 -74
Nitrate -Nitrite (dry wt.), mg/kg
5.80
04/30/14 ANO
353.2 R2-93
Plant Available Nitrogen, mg/kg
2835
05/14/14 SEJ
Molybdenum (dry wt. basis), mg/kg
6
05/06114 LFJ
EPA200.7
ID##: 433 A
DATE COLLECTED: 04/24/14
DATE REPORTED : 05/20/14
REVIEWED BY:

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO063615 Source Name Wildwood Green W WTP
Laboratory 1 Environmental
Conservation
Laboratory 2
Sample or CompositeDate 10/30/2014
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
3,550
Ammonia Nitrogen
N/A
N/A
57
Arsenic
41
75
6.11
Cadmium
39
85
0.586
Calcium
N/A
N/A
33,500
Copper
1,500
4,300
671
Lead
300
840
12.1
Magnesium
N/A
N/A
3,810
Mercury
17
57
0.342
Molybdenum
N/A
75
6.11
Nickel
420
420
22
Nitrate -Nitrite Nitrogen
N/A
N/A
1,900.00
Percent Solids
N/A
N/A
1.60
PH (no units)
N/A
N/A
7.00
Phosphorus
N/A
N/A
3,700
Potassium
N/A
N/A
2,130
PAN (Inj./Inc.)
N/A
N/A
3,290
PAN (Surface)
N/A
N/A
3,261
Selenium
100
100
14.1
Sodium
N/A
N/A
8,890
SAR
N/A
N/A
1.55
TKN
N/A
N/A
4,500
Zinc
2,800
7,500
1240
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations"
je-y-c' , 02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

FIELD LOADING ESTIMATES
Facility Wildwood Green WWTP
Sampling Date 10/30/2014
% Solids 1.6
Mineralization Rate 0.3
Gallons per DT 14,988.01
pH 7
Sodium Absorpotion 1.55 <5.0 Safe 5.0 -10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
NUTRIENT APPLICATION
TKN (mg/Kg) 4,500 lbs./1,000 gal 0.60
Potassium lbs./1,000 gal
0.28
Ammonia Nitrogen (mg/Kg) 57.00 lbs./1,000 gal 0.01
Phosphorus lbs./1,000 gal
0.49
Nitrate -Nitrite (mg/Kg) 1,900.00 lbs./1,000 gal 0.25
Calcium lbs./1,000 gal
4.47
PLANT AVAILABLE NITROGEN SURFACE APPLIED
Magnesium lbs./1,000 gal
0.51
PAN (mg/Kg) 3,261 lbs./1,000 gal 0.44
Manganese lbs./1,000 gal
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
Sulfur lbs./1,000 gal
PAN (mg/Kg) 3,290 lbs./1,000 gal 0.44
Molybdenum lbs./1,000 gal
0.00
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Limits (mg/Kg)
41
1st Year
2nd Y=
3rd Year
4th Year
5th Year
Class B Ceiling
Limits (mg/Kg)
75
HEAVY METAL CONCENTRATION HEAVY METAL LOADING
Arsenic (mg/Kg)
6.11
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.59
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
671.00
Copper lbs./1,000 gal
0.09
Lead (mg/Kg)
12.10
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.34
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
22.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
14.10
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
1240.00
Zinc lbs./1,000 gal
0.17
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
4,500
3,261
6.52
1,239
4,500
3,290 6.58
1,210
1,239
186
0.37
1,053
1,210
182 0.36
1,029
1,053
79
0.16
974
1,029
77 0.15
951
.974
37
0.07
937
951
36 0.07
916
937
18
0.04
920
916
17 0.03
899
Equations
1 st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16)
Total 3,580 7.16
Total 3,601 7.20

(9 �eo
www.encolabs.com
SAMPLE DETECTION SUMMARY
Client ID: Wildwood Sludge
Lab ID: C413815-01
Analyte
Results
Flaa
MDL
PPOL
Units
Method
Notes
% Solids
1.6
0.1
0.1
% by Weight
% Solids
Aluminum - Total
3550
128
611
mg/kg dry
EPA 6010C
Ammonia as N
57
2.7
6.0
mg/kg dry
EPA 350.1
Calcium - Total
33500
B
342
1530
mg/kg dry
EPA 6010C
QB-01
Copper - Total
671
11.6
30.5
mg/kg dry
EPA 6010C
Lead - Total
12.1
3
7.33
30.5
mg/kg dry
EPA 6010C
Magnesium - Total
3810
B
39.7
1530
mg/kg dry
EPA 6010C
QB-01
Nitrate/Nitrite as N
1900
D
240
580
mg/kg dry
EPA 353.2
pH
7.0
1.0
1.0
pH Units
EPA 9045D
Phosphorus
3700
D
690
1900
mg/kg dry
EPA 365.4
Potassium - Total
2130
244
1530
mg/kg dry
EPA 6010C
Selenium - Total
14.1
313
6.11
30.5
mg/kg dry
EPA 6010C
QB-01
Sodium - Total
8890
366
1530
mg/kg dry
EPA 6010C
Total Kjeldahl Nitrogen
4500
D
2600
2900
mg/kg dry
EPA 351.2
Total Solids
1.6
0.0010
0.0010
% by Weight
SM 2540G-1997
Zinc - Total
1240
67.2
153
mg/kg dry
EPA 6010C
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 11

�lCO
www.encolabs.com
ANALYTICAL RESULTS
Description: Wildwood Sludge Lab Sample ID:C413815-01 Received: 10/30/14 13:00
Matrix: Sludge Sampled: 10/30/14 09:00 Work Order: C413815
Project: Wildwood-Annual Sludge Analysis Sampled By: Peter Rhodes % Solids: 1.64
(Metals by EPA 6000/7000 Series Methods
Analyte rCAS Numberl
Results
Flaa
Units
DF
MDL
PQL
Batch
Method
Analyzed
By
Notes
Aluminum [7429-90-5]A
3550
mg/kg dry
1
128
611
4KO5014
EPA 6010C
11/07/14 13:29
JDH
Arsenic[7440-38-2]^
< 6.11
mg/kg dry
1
6.11
30.5
4KO5014
EPA 6010C
11/07/14 13:29
JDH
Cadmium [7440-43-9]^
< 0.586
mg/kg dry
1
0.5B6
3.05
4KO5014
EPA 6010C
11/07/14 13:29
JDH
Calcium [7440-70-2]A
33500
B
mg/kg dry
1
342
1530
4KO5014
EPA 6010C
11/07/14 13:29
JDH
QB-01
Copper[7440-50-B]A
671
mg/kg dry
1
11.6
30.5
4KO5014
EPA 6010C
11/07/14 13:29
JDH
Lead [7439-92-1]A
12.1
J
mg/kg dry
1
7.33
30.5
4KO5014
EPA 6010C
11/07/14 13:29
JDH
Magnesium [7439-95-4]A
3810
B
mg/kg dry
1
39.7
1530
4KO5014
EPA 6010C
11/07/14 13:29
JDH
QB-01
Mercury [7439-97-6]^
< 0.342
mg/kg dry
1
0.342
1.19
4KO4012
EPA 7471B
11/04/14 18:14
T1D
Molybdenum [7439-98-7]^
< 6.11
mg/kg dry
1
6.11
30.5
4KO5014
EPA 6010C
11/07/14 13:29
JDH
Nickel[7440-02-0]^
< 22.0
mg/kg dry
1
22.0
153
4KO5014
EPA 6010C
11/07/14 13:29
JDH
Potassium [7440-09-7]A
2130
mg/kg dry
1
244
1530
4KO5014
EPA 6010C
11/07/14 13:29
JDH
Selenium [7782-49-2]A
14.1
JB
mg/kg dry
1
6.11
30.5
4KO5014
EPA 6010C
11/07/14 13:29
JDH
QB-01
Sodium [7440-23-5]A
8890
mg/kg dry
1
366
1530
4KO5014
EPA 6010C
11/07/14 13:29
JDH
Zinc[7440-66-6]A
1240
mg/kg dry
1
67.2
153
4KO5014
EPA 6010C
11/07/14 13:29
JDH
Classical Chemistry Parameters
Analyte rCAS Numberl
Results
Flaa
Units
DF
MDL
PDL,
Batch
Method
Analyzed
By Notes
Solids
1.6
% by Weight
1
0.1
0.1
4KO3019
% Solids
10/31/14 16:01
MMR
Ammonia as N [7664-41-7]
57
mg/kg dry
1
2.7
6.0
4KO7019
EPA 350.1
11/07/14 15:39
SHA
Nitrate/Nitrite as N
1900
D
mg/kg dry
97.5
240
580
4KO4005
EPA 353.2
11/04/14 13:20
SHA
pH
7.0
pH Units
1
1.0
1.0
4130037
EPA 9045D
10/30/14 15:50
MMR
Phosphorus [7723-14-01
3700
D
mg/kg dry
320
690
1900
4J31009
EPA 365.4
11/03/14 13:22
clv
Total Kjeldahl Nitrogen
4500
D
mg/kg dry
100
2600
2900
4331008
EPA 351.2
11/03/14 11:59
clv
Total Solids
1.6
% by Weight
1
0.0010
0.0010
4331024
SM 254OG-1997
10/31/14 16:01
MMR
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 11

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0000838 Facility Name Granville Farms, Inc. Class B Source Permit No. NCO064378 Source Name Willowbrook W WTP
Laboratory 1 Environment
1, Inc.
Laboratory 2
Sample or CompositeDate 2/25/2014
Parameter (mg/Kg) Class A Clas B
Aluminum
N/A
N/A
2,717
Ammonia Nitrogen
N/A
N/A
3,759
Arsenic
41
75
2.5
Cadmium
39
85
0.6
Calcium
N/A
N/A
19,180
Copper
1,500
4,300
164
Lead
300
840
4
Magnesium
N/A
N/A
2,622
Mercury
17
57
0.11
Molybdenum
N/A
75
6
Nickel
420
420
12
Nitrate -Nitrite Nitrogen
N/A
N/A
7
Percent Solids
N/A
N/A
1.02
PH (no units)
N/A
N/A
5.90
Phosphorus
N/A
N/A
374
Potassium
N/A
N/A
4,705
PAN (Inj./Inc.)
N/A
N/A
9,782
PAN (Surface)
N/A
N/A
7,903
Selenium
100
100
5
Sodium
N/A
N/A
34,632
SAR
N/A
N/A
6.27
TKN
N/A
N/A
23,813
Zinc
2,800
7,500
499
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
� 02-14-2015
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

AGMAN
c
Facility Willowbrook WWTP
Sampling Date 2/25/2014
% Solids 1.02
Mineralization Rate 0.3
Gallons per DT 23,510.60
pH 5.9
FIELD LOADING ESTIMATES
Sodium Absorpotion 6.27 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION NUTRIENT APPLICATION
TKN (mg/Kg) 23,813 lbs./1,000 gal 2.03
Ammonia Nitrogen (mg/Kg) 3,759.00 lbs./1,000 gal 0.32
Nitrate -Nitrite (mg/Kg) 6.89 lbs./1,000 gal 0.00
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 7,903 lbs./1,000 gal 0.67
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 9,782 lbs./1,000 gal 0.83
Volatization Rate= 0.5 Surface Application
1.0 Injection /Incorporation
EPA METAL LIMITS
Potassium lbs./1,000 gal 0.40
Phosphorus lbs./1,000 gal 0.03
Calcium lbs./1,000 gal 1.63
Magnesium lbs./1,000 gal 0.22
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
HEAVY METAL CONCENTRATION
HEAVY METAL LOADING
41
75
Arsenic (mg/Kg)
2.50
Arsenic lbs./1,000 gal
0.00
39
85
Cadmium (mg/Kg)
0.60
Cadmium lbs./1,000 gal
0.00
1,500
4,300
Copper (mg/Kg)
164.00
Copper lbs./1,000 gal
0.01
300
840
Lead (mg/Kg)
4.00
Lead lbs./1,000 gal
0.00
17
57
Mercury (mg/Ig)
0.11
Mercury lbs./1,000 gal
0.00
420
420
Nickel (mg/Kg)
12.00
Nickel lbs./1,000 gal
0.00
100
100
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.00
2,800
7,500
Zinc (mg/Kg)
499.00
Zinc lbs./1,000 gal
0.04
RESIDUAL NITROGEN CALCULATION
1 St Year
2nd Year
3rd Year
4th Year
5th Year
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN
PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
23,813
7,903
15.81
15,910
23,813
9,782 19.56
14,031
15,910
2,387
4.77
13,524
14,031
2,105 4.21
11,926
13,524
1,014
2.03
12,510
11,926
894 1.79
11,032
12,510
469
0.94
12,040
11,032
414 0.83
10,618
12,040
226
0.45
11,815
10,618
199 0.40
10,419
Equations
1st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x )MR/2)
3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (TVR/4)
4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)= 5th Yr. TKN x (vlR/16)
Kotal 11,998 24.00
Total 13,394 26.79

Environment 1, Incorporated
P.O. BOX 70851 114 OAkMONT DRIVE PHONE [phone] ... �.
GREENV LLE, N.C. 27835-7085 FAX (252} 756-0-
WILLOWBROOK (CWS)
CAROLINA WATER SERVICE OF NC
315B HWY. 70 EAST
GARNER ,NC 27529
Sludge
Analysis
Method
PARAMETERS
Sample
Date Analyst
Code
PH, Units
5.9
02/28/14 TRB
450OBB-00
Aluminum, (dry wt. basis), mg/kg
2717
03/05/14 LFJ
EPA200.7
Arsenic (dry wt, basis), mg/kg
<2.5
03/18/14 MEL
3113B-04
Calcium (dry wt. basis), mg/kg
19180
03/05/14 LFJ
EPA200.7
Cadmium (dry wt. basis), mg/kg
0.6
03/26/14 MEL
3113B-04
Copper (dry wt. basis), mg/kg
164
03/05/14 LFJ
EPA200.7
Chromium, T.(dry wt. basis),mg/lig
5
03/05/14 LFJ
EPA200.7
Lead (dry weight basis), mg/kg
4
03/31/14 MEL
3113B-04
Magnesium (dry wt, basis), mg/kg
2622
03/05/14 LFJ
EPA200.7
Mercury (dry wt. basis), mg/kg
0.11
03/10/14 ADD
245.1 113-94
Nickel (dry wt.. basis), mg/kg
12
03/07/14 LFJ
EPA200.7
Potassium (dry wt, basis), mg/kg
4705
03/05/14 LFJ
EPA200.7
Selenium (dry wt. basis), mg/kg
<5.0
03/25/14 MEL
31138-04
Sodium (dry wt. basis), mg/kg
34632
03/19/14 MTM
3111E-99
Zinc (dry wt. basis), mg/kg
499
03/10/14 ADD
3111B-99
Total Solids, %
1.02
02/26/14 MDD
2540G-97
TKN (dry wt.), mg/kg
23813
03/10/14 ANO
351.2 R2-93
Ammonia Nitrogen (dry wt.),mg/kg
3759
03/04/14 ALB
350.1 R2-93
Phosphorus, T. (dry wt.), mg/kg
374
03/06/14 ALB
365A -74
Nitrate -Nitrite (dry wt.), mg/kg
6.89
03/05/14 ANO
353.2 112-93
Plant Available Nitrogen, mg/kg
7903
03/10/14 SE
Molybdenum (dry wt. basis), mg/kg
6
03/05/14 LFJ
EPA200.7
ID#: 623 A
DATE COLLECTED: 02/25/14
DATE REPORTED : 04/02/14
REVIEWED BY:!!�
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