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HomeMy WebLinkAboutCAMA Annual Appendix A2018 CAMA Annual Interim Monitoring Report April 30, 2019 Duke Energy Carolinas, LLC - Marshall Steam Station SynTerra APPENDIX A CORRESPONDENCE WITH NCDEQ ROY COOPER Governor MICHAEL S. REGAN Secretaq S. JAY ZIMMERMAN Director May 1, 2017 Paul Draovitch Senior Vice President Environmental, Health & Safety Duke Energy 526 South Church Street Mail Code EC3XP Charlotte, North Carolina 28202 Subject: Response to the February 2, 2017 Letter from Duke Energy Revised Interim Monitoring Plans for 14 Duke Energy Facilities Dear Mr. Draovitch: The North Carolina Department of Environmental Quality (DEQ) has received and reviewed your February 2, 2017 letter that was in response to our letters dated December 21, 2016 and January 11, 2017 regarding facility Interim Monitoring Plans. DEQ has considered Duke Energy's comments and is providing the attached revised Interim Monitoring Plans for the respective facilities. Due to ongoing internal discussions regarding DEQ's position on surface water sampling, the attached plans only contain references to groundwater monitoring locations. Once a final internal position has been determined, DEQ may elect to provide Duke Energy with surface sampling locations to incorporate into the revised Interim Action Plans. For clarification, we have also provided the minimum expected groundwater sampling analyte list. The attached revised facility Interim Monitoring Plans shall be conducted on a quarterly basis commencing the third quarter of calendar year 2017 pursuant to 15A NCAC 02L .0 110, until Corrective Action Plans are accepted for the individual facilities or as directed otherwise by DEQ. The quarterly sampling events will be conducted in conjunction with planned compliance monitoring sampling events for three quarters during the calendar year, supplemented with an additional sampling event conducted at each facility in order to provide four rounds of monitoring data to evaluate seasonal fluctuations during a year -long timeframe. If sampling an individual groundwater location is problematic, please call the Regional Office that manages the facility to discuss issues. Any changes to interim monitoring network and sampling requirements must be discussed with the respective Regional Offices and coordinated by official correspondence from the DEQ Central Office. Document the results of the four quarters of sampling and analysis during the calendar year as an annual interim monitoring plan report for each subject coal ash facility submitted by April 3 01h of State of North Carolina I Environmental Quality I Division of Water Resources Water Quality Regional Operations Section 1636 Mail Service Center I Raleigh, North Carolina 27699-1636 919-707-9129 - - - - - - - - - - - - - - - - - - - - - - - - - - - the following year. The respective annual monitoring reports shall include figures, tables, cross - sections, maps, and time -series plots in a manner that provides an integrated, comprehensive interpretation of site conditions and plume status. Reports submitted in a data summary format will not be approved as an acceptable documentation of the monitoring program. In order to optimize the groundwater monitoring at each facility, DEQ will be removing the groundwater monitoring condition from the NPDES permits as they are reissued. Duke Energy shall continue to monitor the compliance wells separately under the individual NPDES permits until the NPDES permits are reissued with no groundwater monitoring condition. At that time, the compliance wells shall continue to be monitored per the attached revised interim monitoring plans under the authority of 15A NCAC 02L .0110. The DEQ is open to consider further optimization of the interim monitoring plan program following a qualitative and quantitative review of site -specific data. A thorough analysis of spatial and temporal trends related to contaminant distribution that include determination of background conditions and identification of areas impacted by coal ash residuals must be provided as a decision framework to support improvements to long-term monitoring programs. If you have any questions, please feel free to contact Steve Lanter at (919) 807-6444. Sincerely, S. Jay i erman, P.G., Director Division of Water Resources Attachments: Revised Interim Monitoring Plans for the 14 coal ash facilities cc: WQROS Regional Offices WQROS Central File Copy Revised Allen Steam Station Interim Monitoring Plan — Groundwater Only Sample for Wells to be Sampled Radionuclides Regional Office Notes M AB-1 OD AB-1 OS AB -I ID x AB-12D AB-12S Recommend redevelopment due to elevated turbidity. AB-13D x Radionuclide sample requested by MRO AB-13S x Radionuclide sample requested by MRO AB-14BR AB-14D Recommend redevelopment due to elevated turbidity. AB-IR AB-2 AB-20D AB-20S Recently installed and should be added to IGWMP - Based on review of analytical (submitted on 2/20/2017), water quality at AB-2 I BRL is AB-21BRL x acceptable and this location appears to vertically delineated (pending background for Cr6+, V) Radionuclide sample requested by MRO Based on review of analytical (submitted on 2/20/2017), AB-21D has water quality issues (i.e., grout contamination). Since this well is located along a major flow transect beneath the basin this AB-21D x well should be reinstalled to more accurate reflect site conditions beneath the basin in the deep flow layer. Radionuclide sample requested by MRO AB -21 S x Radionuclide sample requested by MRO AB-21 SL x Radionuclide sample requested by MRO Recently installed and should be added to IGWMP - Recommend redevelopment due to water quality AB-22BR issues. Also, due to observed concentrations of Boron a lower bedrock well is warranted for vertical delineation at this location. AB-22D AB-22S Recommend redevelopment due to elevated turbidity. Allen Steam Station Page 1 of 9 May 1, 2017 Location not delineated horizontally or vertically. GWA-23D located upgradient, has water quality issues and therefore does not provide valid analytical for determination of horizontal delineation. Also, this location needs vertical AB-23BRU delineation due to Arsenic exceedances observed in the shallow well thus warranting reinstallation. Based on review of analytical (submitted on 2/20/2017) AB-23BRU continues to have water quality issues (i.e., grout contamination) and should be reinstalled. AB-23S Recommend monitoring pH — historically observed fluctuating. Recently installed and should be added to IGWMP - Based on review of analytical (submitted on . AB-24BR 2/20/2017), water quality at AB-24BR is acceptable and location appears to be vertically delineated (pending background for Mn, V) Based on review of analytical (submitted 2/20/2017), AB-24D has water quality issues (i.e., AB-24D grout contamination). This well is located along a major flow transect beneath the basin and should be reinstalled to more accurately represent groundwater quality at this location. AB-24S AB-24SL Recommend monitoring pH — historically observed fluctuating. GWA-3BR has consistently had pH >10 since installation and therefore is not representative of actual site conditions. Because of the above mentioned issues as well as purposes of modeling (geochem. and fate and transport), it is recommended that AB-25BR be reinstalled. Based on review of analytical (submitted on 2/20/2017) AB-24BR (pending background AB-25BR X determination for Mn and V) provides delineation to the west of AB-25 BR; but GWA-3BR continues to have water quality issues and at this time does not provide delineation to the east toward the river. GWA-3BR should be reinstalled to delineate exceedances observed at AB-25BR. Once AB- 25BR is reinstalled this location will be reevaluated to determine if additional vertical delineation is warranted. Radionuclide sample requested by MRO Allen Steam Station Page 2 of 9 May 1, 2017 GWA-3BR has consistently had pH >10 since installation and therefore is not representative of actual site conditions. Because of the above mentioned issues as well as purposes of modeling (geochem. and fate and transport), it is AB-25BRU X recormuended that AB-25BRU be reinstalled. Based on review of analytical (submitted on 2/20/2017), AB-25BRU continues to have water quality issues and should be reinstalled. Radionuclide sample requested by MRO AB-25S X Radionuclide sample requested by MRO AB-25SL X Radionuclide sample requested by MRO AB-26S Recently installed and should be added to IGWMP — Based on review of analytical (submitted on AB-27BR 2/20/2017), elevated concentration of total chromium was observed thus warranting installation of a lower bedrock well for vertical delineation. AB-27D Recommend redevelopment due to elevated turbidity. AB-27S Due to water quality issues at this location, AB-28D discontinue sampling. AB-30D is in close proximity and is representative of site conditions. AB-28S AB-29D AB-29S Due to water quality issues at this location, AB-29SL discontinue sampling. AB-29S does not have water quality issues and is representative of site conditions. AB-2D AB-30D AB-30S Recommend redevelopment due to elevated turbidity. AB-31 S AB-32D AB-32S pH has been observed fluctuating and has had turbidity issues. Recommend redevelopment and AB-33D X reevaluation during next sampling event to determine path forward. Radionuclide sample requested by MRO AB-33S X Radionuclide sample requested by MRO Allen Steam Station Page 3 of 9 May 1, 2017 AB-34D AB-34S Based on review of analytical (submitted on 2/20/2017), water quality at AB-35BR is acceptable and location appears to be vertically delineated AB-35BR X (pending background for Mn and V). Reinstallation is not warranted at this time. Radionuclide sample requested by MRO AB-35D has consistently had pH >/= 10 since installation and therefore is not representative of actual site conditions. Because of the above mentioned issues as well as purposes of modeling (geochem. and fate and transport), it is recommended that AB-35D be reinstalled since it is AB-35D X located along a major flow transect. Based on review of analytical (submitted on 2/20/2017), AB-35D continues to have water quality issues and should be reinstalled. Radionuclide sample requested by MRO AB-35S X Radionuclide sample requested by MRO AB-36D Monitor pH AB-36S AB-37D AB-37S Recently installed and should be added to IGWMP - Based on review of analytical (submitted on AB-38BR 2/20/2017), water quality at AB-38BR is acceptable and location appears to be vertically delineated (pending background for Co, Mn, and V). AB-38D AB-38S AB-39D AB-39S AB-4BR X AB-4D X AB-4S X AB-5 AB-6A X AB-6R X AB-9D X AB-9S X BG-1D X BG-ID has water quality issues and warrants reinstallation. Since this well is not viable sample Allen Steam Station Page 4 of 9 May 1, 2017 location at the present GWA-26S/D should remain in the sampling program until BG-ID is reinstalled and deemed representative of background conditions at the site. Based on review of analytical (submitted on 2/20/2017), BG-1D continues to have water quality issues and should be reinstalled. GWA-26S/D should remain in the IGWMP. Radionuclide sample requested by MRO BG-1 S X Radionuclide sample requested by MRO Slated for reinstallation, but does not appear to have BG-2BR X been replaced based on review of analytical (submitted on 2/20/2017). BG-2D X BG-2S X BG-3D BG-3S BG-4BR BG-41) Recommend redevelopment due to elevated turbidity. Monitor pH. BG-4S Slated for reinstallation, but does not appear to have GWA-14D been replaced based on review of analytical (submitted on 2/20/2017). GWA-14S GWA-15D GWA-15S GWA-16D GWA-16S GWA-17D X Radionuclide sample requested by MRO GWA-17S X Radionuclide sample requested by MRO Due to the observed upward trend of conductivity at the AB- 1R location and uncertainty in regard to what is effecting water quality at this location, GWA-18S/D should remain in the sampling program to continue to assess potential impact from the basin. Also, it is located along a major flow GWA-18D transect so for purposes of modeling (geochem. and fate and transport) it should continue to be sampled. Based on review of analytical (submitted on 2/20/2017), GWA-18D has water quality issues (pH 9.4 and has been observed trending upward since installation) and reinstallation is recommended. Allen Steam Station Page 5 of 9 . May 1, 2017 Due to the observed upward trend of conductivity at the AB-lR location and uncertainty in regard to what is effecting water quality at this location GWA-18S GWA-18S/D should remain in the sampling program to continue to assess potential impact from the basin and it is located along a major flow transect so for purposes of modeling (geochem. and fate and transport) it should continue to be sampled. GWA-19S/D should remain in the sampling program as 273 (South Point Rd) being a topographic divide is in question in regards to the DBR flow layers. This location is also located along a major flow transect so for purposes of GWA-19D modeling (geochem. and fate and transport) it should continue to be sampled. Based on review of analytical (submitted on 2/20/2017), GWA-19D has water quality issues (pH 10.3 has been observed trending upward since installation) and reinstallation is recommended. GWA-19S/D should remain in the sampling program as 273 (South Point Rd) being a topographic divide is in question in regards to the GWA-19S DBR flow layers. This location is also located along a major flow transect so for purposes of modeling (geochem. and fate and transport) it should continue to be sampled. GWA-1BR X GWA-lD X GWA-1 S X Recommend redevelopment due to elevated pH GWA-21BR X (9.5) and then reevaluate for determination of replacement. Slated for reinstallation, but does not appear to have GWA-21D X been replaced based on review of analytical (submitted on 2/20/2017). GWA-21 S X GWA-22D GWA-22S Recommend redevelopment due to elevated turbidity. Due to proximity of WSWs, GWA-23D should be reinstalled to monitor deep flow layer for potential influence from the basin. GWA-23D Based on review of analytical (submitted on 2/20/2017), GWA-35D continues to have water quality issues and should be reinstalled. Allen Steam Station Page 6 of 9 May 1, 2017 GWA-23S Based on review of analytical (submitted on 2/20/2017), GWA-24BR continues to have water quality issues and should be reinstalled as GWA-24BR previously reconnnended. This location is in close proximity to WSWs located west of the basin and provides invaluable data. This well should be reinstalled. Based on review of analytical (submitted on GWA-24D 2/20/2017), water quality at GWA-24D is acceptable and location appears to be vertically delineated (pending background for V, Cr6+). Based on review of analytical (submitted on 2/20/2017), GWA-24S still has not been sampled to GWA-24S date due to insufficient water volume. This location is in close proximity to WSWs located west of the basin and provides invaluable data. This well should be reinstalled. BG-ID has water quality issues and warrants reinstallation. Since this well is not viable sample location at the present GWA-26S/D should remain in the sampling program until BG-1D is reinstalled and deemed representative of background GWA-26D conditions at the site. Based on review of analytical (submitted on 2/20/2017), GWA-26D should continue to be included in the IGWMP. Note: Recoimnend monitoring pH (observed fluctuating above standard) — may be beneficial to redevelop well. BG-ID has water quality issues and warrants reinstallation. Since this well is not viable sample location at the present GWA-26S/D should remain in the sampling program until BG-1 D is reinstalled GWA-26S and deemed representative of background conditions at the site. Based on review of analytical (submitted on 2/20/2017), GWA-26S should continue to be included in the IGWMP. GWA-2D X GWA-2S X GWA-3BR has consistently had pH >10 since installation and therefore is not representative of GWA-3BR X actual site conditions (located along major flow transect). Based on review of analytical (submitted on Allen Steam Station Page 7 of 9 May 1, 2017 2/20/2017), GWA-3BR should be reinstalled for delineation of exceedances observed at AB-25BR. GWA-31) X Recommend redevelopment due to elevated turbidity and fluctuating pH. GWA-3S X Recently installed and should be added to IGWMP - Based on review of analytical (submitted on GWA-4BR X 2/20/2017) water quality at GWA-4BR is acceptable and location appears to be vertically delineated (pending background for Mn, V). GWA-4D X GWA-4S X Slated for reinstallation, but does not appear to have GWA-5BR X been replaced based on review of analytical (submitted on 2/20/2017). GWA-5D X GWA-5S X Historically, GWA-6BR has not exhibited water quality issues (elevated pH), however, based on GWA-6BR X review of analytical (submitted on 2/20/2017), this location has pH >12. Recommend reevaluation during next sampling event for determination of path forward. GWA-6DA X GWA-6S X GWA-7D X GWA-7S X GWA-8D GWA-8S Recommend redevelopment due to elevated GWA-91) X turbidity. Radionuclide sample requested by MRO GWA-9S X Radionuclide sample requested by MRO Recently installed and should be added to IGWMP - Based on review of analytical (submitted on 2/20/2017) water quality at GWA-9BR is GWA-9BR X acceptable and location appears to be vertically delineated (pending background for Mn, V). Radionuclide sample requested by MRO Allen Steam Station Page 8 of 9 May 1, 2017 Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium (total) TOC (total) Chromium Total Antimony Calcium Iron Nickel Strontium Combined Uranium Arsenic Chloride Lead Potassium Sulfate TSS (total) Barium Chromium Magnesium Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radium 228 TDS Zinc Allen Steam Station Page 9 of 9 May 1, 2017 Revised Asheville Steam Electric Plant Interim Monitoring Plan — Groundwater Only Wells to be Sampled for Radionuclides Radionuclides (X) Regional Office Notes ABMW-11BR AMW-03B X AMW-1B X AMW-2A AMW-213 water level only APZ-30 water level only B-1 water level only B-1-A water level only B-2 water level only CB-1 X CB-1BR water level only CB-1BRL water level only CB-1D X CB-8BR X CB-81) water level only CB-9BR X CB-9SL X GW-lBR GW-1D GW-2 X GW-3 X GW-4 X GW-5 X MW-3D X MW-5BR MW-5D MW-8S X MW-10 X MW-11 MW-11D MW-13BR MW-13D MW-14BR MW-15A X MW-15BR water level only MW-15D X MW-16A X Asheville Steam Electric Plant Page 1 of 2 May 1, 2017 MW-16BR x MW-17A x MW-18BR x MW-18BRL x MW-18D x MW-19BR water level only MW-20A MW-21D x MW-22BR x MW-22D x MW-23BR MW-23DL MW-23DU MW-24S x MW-6BR x MW-6D x MW-6S x MW-7BR water level only MW-8BR MW-9B-'R. x MW-9D x MW-9S x P-102 water level only P-103 PZ-16 Needs to be replaced and added to IMP. PZ-17D x PZ-17S x PZ-19 x PZ-22 x Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium (total) TOC (total) Chromium Total Antimony Calcium Iron Nickel Strontium Combined Uranium Arsenic Chloride Lead Potassium Sulfate TSS (total) Barium Chromium Magnesium Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radium 228 TDS Zinc Asheville Steam Electric Plant Page 2 of 2 May 1, 2017 Revised Belews Creek Steam Station Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides (X) Regional Office Notes AB-1BR AB -ID AB-1S AB-2D AB-2S AB-3D AB-3S AB-4BR Measure pH, if still high, do not sample AB-4BRD AB-4D AB-4S AB-4SL Measure pH, if still high, do not sample AB-5D AB-5S AB-5SL AB-6D AB-6S AB-6SL AB-7D AB-7S AB-8D AB-8S AB-8SL AB-9BR AB-9BRD AB-9D AB-9S BC-23A BC-28 BCSW-007 BCSW-008 BCSW-018A BCSW-019 BCW W-002 BG-ID BG-1 S X BG-2BR Belews Creek Steam Station Page 1 of 4 May 1, 2017 BG-2D x BG-2S x BG-3D BG-3S x GWA-IOD If pH still high, do not sample. GWA-10S GWA-I I D GWA-11S GWA-12BR GWA-12D GWA-12S GWA-16BR GWA-16D If pH still high, do not sample. GWA-16S GWA-17D GWA-17S GWA-18D GWA-18S GWA-18SA GWA-19BR GWA-19D GWA-19S GWA-19SA GWA-IBR x GWA-11) x GWA-1S x GWA-20BR GWA-20D GWA-20S GWA-20SA GWA-21D GWA-21S GWA-22D GWA-22S GWA-23D GWA-23S GWA-24BR GWA-24D x GWA-24S x GWA-25BR x GWA-26BR x Belews Creek Steam Station Page 2 of 4 May 1, 2017 GWA-26D X GWA-26S X GWA-27BR GWA-27D GWA-27S GWA-2D GWA-2S GWA-30D X GWA-30S X GWA-31 D GWA-31 S GWA-32D GWA-32S GWA-3D GWA-3 S GWA-4D If the well is still there, please sample. GWA-5BR2 If the well is still there, please sample. GWA-5D If the well is still there, please sample. GWA-5S If the well is still there, please sample. GWA-6D X GWA-6S X GWA-7D X GWA-7S X GWA-8D X GWA-8S X GWA-9BR GWA-9D GWA-9S MW-102D MW-102S MW-104BR MW-104D MW-104S MW-200BR X MW-200D X MW-200S X MW-201BR MW-201D MW-202BR MW-202D MW-202S Belews Creek Steam Station Page 3 of 4 May 1, 2017 MW-203BR MW-203D MW-203S MW-204D MW-204S MW-3 X Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium (total) TOC (total) Chromium Total Antimony Calcium Iron Nickel Strontium Combined Uranium Arsenic Chloride Lead Potassium Sulfate TSS (total) Barium Chromium Magnesium Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radium 228 TDS Zinc Belews Creek Steam Station . Page 4 of 4 May 1, 2017 Devised Buck Combined Cycle Station Interim Monitoring Plan — Groundwater Only Wells to be Sample for Sampled Radionuclides Regional Office Notes (X) AB -ID Recently installed and should be added to IGWMP — Based on review of analytical (submitted on AB-1 OBR 2/13/2017), Boron was observed in exceedance of 2L standard thus warranting installation of a lower bedrock well for purposes of vertical delineation. AB-1 OD AB-10S Recommend reinstallation for vertical delineation - pH >10 since well was installed in 2015 (5 sampling events). This well is also located along and major flow transect identified at the site so for modeling purposes this well should be reinstalled. AB-2BR X Based on review of analytical (submitted on 2/13/2017), AB-2BR continues to have water quality issues and reinstallation is warranted for vertical delineation at this location (exceedance of Antimony was observed above IIVIAC). Radionuclide sample added by MRO. AB-21) X Radionuclide sample added by MRO. AB-2S X Radionuclide sample added by MRO. AB-2SL X Radionuclide sample added by MRO. AB-3D AB-3S Discontinue sampling AB-4BR. Based on review of AB-4BR analytical (submitted on 2/13/2017), water quality at AB-4BRL is acceptable (pending background for V, Cr6+). Recently installed and should be added to IGWMP - Based on review of analytical (submitted on AB-4BRL 2/13/2017), water quality at AB-4BRL is acceptable (pending background for V, Cr6+) and this location appears to be vertically delineated. AB-4BRU AB-4S Due to water quality issue (pH trending upward), AB-4SL recommend redevelopment of well and reevaluation during next sampling event for determination of path forward. Buck Combined Cycle Station Page 1 of 6 May 1, 2017 According to historical analytical, this location was only sampled once in R2 and has not been sampled since then. I assume this is due to the high pH indicating grout contamination at this location. Based AB-5BRU X on review of analytical for AB-5S/SL (submitted on 2/13/2017), vertical delineation (As, Cr6+, Fe, Mn, V) is warranted and this well should be reinstalled. Radionuclide sample added by MRO. AB-5S X Radionuclide sample added by MRO. AB-5SL X Radionuclide sample added by MRO. AB-6BRU AB-7BRU AB-7S AB-8BRU AB-8 S Based on review of analytical (submitted on 2/13/2017), AB-9BR has water quality issues (i.e., grout contamination). Exceedances of TDS, Sb, and V were observed. This well can be reinstalled and AB-9BR X results reevaluated to determine if additional vertical. delineation is necessary or a lower bedrock can be installed and AB-9BR abandoned due to water quality issues. Radionuclide sample added by MRO. Based on review of analytical (submitted on 2/13/2017), AB-9BRU has water quality issues (i.e., grout contamination). Exceedances of B, TDS, Sb, and V were observed. AB-9BRU should be reinstalled to evaluate contaminant migration from the AB-9BRU X basin toward the Yadkin River. (Note: this location was documented as AB-9D on the data submittal — recommend updating applicable tables/figures for field staff and ensuring the proper ID is shown on the well tag.) Radionuclide sample added by MRO. Recommend redevelopment of this location due to AB-9S X elevated turbidity. Radionuclide sample added by MRO. AS -ID AS-1 S AS-2D AS-3D AS-3 S Buck Combined Cycle Station Page 2 of 6 May 1, 2017 Slated for reinstallation, but does not appear to have BG-IBR been replaced based on review of analytical (submitted on 2/13/2017). Slated for reinstallation, but does not appear to have BG-lD been replaced based on review of analytical (submitted on 2/13/2017). Need to evaluate V exceedance observed (historically elevated). BG-IS BG-2D X Radionuclide sample added by MRO. BG-2S X Radionuclide sample added by MRO. Radionuclide sample added by MRO. BG-3BRU X (Note: this location was documented as BG-3D on the data submittal — recolm-nend updating applicable tables/figures for field staff and ensuring the proper ID is shown on the well tag.) BG-3S X Radionuclide sample added by MRO. pH appears to be fluctuating above standard — GWA-1013 recommend redevelopment and reevaluation for upcoming sampling event. GWA-IOS GWA-11D GWA-11S GWA-12BRU X GWA-12S X GWA- I 3D has water quality issues, however, MW- 13D is in close proximity to GWA- I 3D and receptors GWA-13D and has no water quality issues. MW-1 3D should be utilized for sampling — discontinue sampling GWA- 13D. GWA-13SR Slated for installation, but does not appear to have been installed based on review of analytical GWA-14BR X (submitted on 2/13/2017). Radionuclide sample added by MRO. Due to close proximity of well to WSWs and GW flow direction observed on maps this well should be reinstalled to monitor potential migration in the deep flow layer from ash basin toward receptors. GWA-14D X Based on review of analytical (submitted 2/13/2017), GWA- I 4D should be reinstalled due to water quality issues (i.e., grout contamination). Radionuclide sample added by MRO. GWA-14S X Radionuclide sample added by MRO. Buck Combined Cycle Station Page 3 of 6 May 1, 2017 Due to elevated concentration of Cobalt, additional horizontal and vertical delineation is warranted for GWA-15D X this location. A bedrock well should be installed at this location and a S/D well pair should be installed to the east of GWA-15S/D. GWA-15S X GWA-16BR X Installation pending property access GWA-16D X Installation pending property access GWA-16S X Installation pending property access GWA-17S According to historical analytical, this location was only sampled twice, in R5 and R7, and has not been sampled since then. I assume this is due to the high GWA-18D X pH indicating grout contamination at this location. Based on review of analytical (sampled 9/28/2016), vertical delineation (TDS, Cr(tot), Sb, Fe) is warranted and this well should be reinstalled. GWA-18S X pH appears to be fluctuating above standard — GWA-19D X recommend redevelopment and reevaluation for upcoming sampling event. GWA-19S X pH appears to be fluctuating above standard — GWA-1D X recommend redevelopment and reevaluation for upcoming sampling event. GWA-1 S X GWA-20D X GWA-20S X GWA-22D X Based on review of analytical (submitted on 2/13/2017), GWA-2BR has water quality issues (i.e., GWA-2BR X grout contamination). This well is located on a major flow transect and is protective of nearby receptors and should be reinstalled at this location. GWA-2BRU X GWA-2S X GWA-3BR X GWA-3BRU X GWA-3S X GWA-4D X GWA-4S X GWA-5BRU X GWA-5 S X Based on review of analytical (submitted on GWA-6BR X 2/13/2017), exceedances of SO4 and TDS were observed at GWA-6BR. Due to the observed Buck Combined Cycle Station Page 4 of 6 May 1, 2017 exceedances, vertical delineation at this location is warranted. A lower bedrock well should be installed at this location to further evaluate concentrations of SO4 and TDS. Radionuclide sample added by MRO. GWA-6BRU X GWA-6S X GWA-7D X GWA-7S X GWA-8D GWA-9BR historically had water quality issues, but based on review of analytical (submitted on 2/13/2017), water quality at GWA-9BR is acceptable GWA-9BR X and appears to be vertically delineated (pending background for V). Radionuclide sample added by MRO. GWA-9D X GWA-9S X Compliance monitoring well — was not sampled in R8, but is sampled 3x/year per NPDES pennit. Exceedances of SO4 and TDS have been observed in each sampling event to date. GWA-12S/BRU MW-1 OD provides horizontal delineation for this location, but vertical delineation is warranted. Installation of a lower bedrock at GWA-6BR as reconunended above can be utilized to provide vertical delineation at this location. Recently installed and should be added to IGWMP - Based on review of analytical (submitted on 2/13/2017), exceedance of Boron was observed at MW-1 IBR X MW-11BR. Due to the Boron exceedance (leading edge constituent), vertical delineation at this location is warranted. A lower bedrock well should be installed at this location to further evaluate Boron concentrations. Compliance monitoring well — historically had water MW-11D X quality issues (turbidity above 10 NTU). Recommend redevelopment of well in attempt to reduce turbidity. MW-1 l S X MW-12D MW-12S MW-13D MW-ID MW-IS MW-2S Buck Combined Cycle Station Page 5 of 6 May 1, 2017 MW-2D MW-3D X MW-3S X MW-4D MW-4S MW-5D MW-5S MW-6BR X pH appears to be trending upward (currently at 9). Recommend redevelopment and evaluation. MW-6D X MW-6S X MW-7D MW-7S MW-8BR X Recently installed and should be added to IGWMP — Based on review of analytical (submitted on 2/13/2017), MW-8BR has water quality issues (i.e., grout contamination). This location should be reinstalled to provide accurate data south of Cell 1. MW-8D X MW-8S X MW-9D X MW-9S X Minimum Parameters to be Analyzed Aluminum Boron I Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium (total) TOC (total) Chromium Total Antimony Calcium Iron Nickel Strontium Combined Uranium Arsenic Chloride Lead Potassium Sulfate TSS (total) Barium Chromium Magnesium. Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radium 228 TDS Zinc Buck Combined Cycle Station Page 6 of 6 May 1, 2017 Revised Cape Fear Steam Electric Plant Interim MonitorinI4 Plan - Groundwater Only Wells to be Sampled Sample for Radionuclides (X) Regional Office Dotes ABMW-1 X ABMW-lBR X ABMW-1 S X ABMW-2SL ABMW-2SU ABMW-3 X ABMW-3BR ABMW-3SR X ABMW-4 X ABMW-4S X ABMW-5BR ABMW-5 S BGMW-4 X BGTMW-4 X CMW-01 X CMW-02 CMW-03 X CMW-5R not yet installed CMW-06 X CMW-07 X CMW-08 X CTMW-01 X CTMW-02 CTMW-07 CTMW-08 X MW-09 MW-09BR MW-10 X MW-IOBR X MW-1 OBRL MW-10D MW-11 X MW-12 X MW-12BR MW-13 MW-15BR X MW-15SL X Cape Fear Stearn Electric Plant Page 1 of 3 May 1, 2017 MW-15SU X MW-16BR X MW-16S X MW-17BR MW-17SL X MW-17SU X MW-18S X MW-19S MW-20BR MW-20S MW-21BR MW-21 SL X MW-21 SU X MW-22BR MW-22S MW-23BR MW-23D X MW-23S X MW-24D X MW-24S X MW-5BRR MW-6BR X MW-9 X MW-9BR X PZ-1 PZ-10 PZ-2 PZ-3D PZ-3S PZ-4 PZ-5 X PZ-6 PZ-7 PZ-8 Cape Fear Steam Electric Plant Page 2 of 3 May 1, 2017 Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium (total) TOC (total) Chromium Total Antimony Calcium Iron Nickel Strontium Combined Uranium Arsenic Chloride Lead Potassium Sulfate TSS (total) Barium Chromium Magnesium Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radian 228 TDS Zinc Cape Fear Steam Electric Plant Page 3 of 3 May 1, 2017 Revised James E. Rogers Energy Complex Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides (X) Regional Office Notes AB-1D AB-1 S AB-2D AB-2S AB-3BR AB-3I AB-3 S X AB-3 SL X AB-4BR AB-4D AB-4S X AB-4SL X AB-5BR AB-5BRU AB-5S X AB-6BR AB-6I7 AB-6S X AS -ID AS-1 SB AS-2BR AS-2D X AS-2S X AS-3BRU AS-4D AS-4S AS-5BRU AS-5 S AS-6D AS-6S AS-7D AS-7S X BG-ID X BG-1 S X BG-2D X CCPMW-ID X CCPMW-1S X James E. Rogers Energy Complex Page 1 of 5 May 1, 2017 CLMW-1 X CLMW-2 CLMW-3D X CLMW-3S X CLMW-5D CLMW-5S CLMW-6 CLP-1 water level only CLP-2 water level only GWA-101) GWA-10S GWA-1 1BRU X GWA-1 1 S X GWA-12BRU GWA-12S ,GWA-13BR GWA-14BR GWA-14D GWA-14S GWA-113RU GWA-20BR X GWA-20D X GWA-20S X GWA-21BR X GWA-21BRU X GWA-21D GWA-21S X GWA-22D GWA-22S X GWA-23D GWA-24BR GWA-24D GWA-24S GWA-25S GWA-25D water level only GWA-26S GWA-26D water level only GWA-27BR X GWA-27D-A X GWA-28BR I GWA-28BRU I James E. Rogers Energy Complex - Page 2 of 5 May 1, 2017 GWA-289 GWA-29D X GWA-2BR X GWA-2BRU X GWA-2S X GWA-30BR GWA-30BRU water level only GWA-30S GWA-31BR-A GWA-31D GWA-32D GWA-32BR water level only GWA-33BR GWA-33D GWA-33S GWA-34S GWA-35D GWA-35S GWA-36D X GWA-36S X GWA-37D GWA-37S GWA-38D GWA-38S GWA-39S water level only GWA-3D X GWA-40S water level only GWA-42S water level only GWA-43D GWA-43 S GWA-44BR GWA-44D GWA-44S GWA-45D GWA-45S GWA-46D GWA-47D GWA-48BR GWA-48S GWA-4D X GWA-4S X James E. Rogers Energy Complex Page 3 of 5 May 1, 2017 GWA-5BRU GWA-5 S GWA-6S GWA-61) water level only IB-3D I3-3S X MW-lOD MW-10S MW-11D MW-11 S X MW-20D MW-20DR MW-21 BR MW-21 D MW-22BR MW-22DR MW-23D MW-23DR MW-23S MW-24D X MW-24DR X MW-25DR MW-2D-A MW-30D X MW-30S X MW-32BR X MW-32D X MW-32S X MW-34S MW-54BRU MW-36BRU MW-36S MW-38BR X MW-38D X MW-38S X MW-40BRU MW-40S MW-42D MW-42S MW-8D MW-8S X James E. Rogers Energy Complex Page 4 of 5 May 1, 2017 U5-lD U5-1S U5-2BR U5-2D X U5-2S-SL-A X U5-3D U5-4D U5-4S U5-5BR U5-5D X U5-6D U5-6S U5-8BR U5-8D U5-8S Minimum )Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thall irm Alkalinity Cadmium H Molybdenum Sodium (total) TOC (total) Clromiuomiumm Total Antimony Calcium Iron Nickel Strontium Combined Uranium Arsenic Chloride Lead Potassium (total) Sulfate TSS Barium Chromium Magnesium Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radium 228 TDS Zinc James E. Rogers Energy Complex Page 5 of 5 May 1, 2017 Revised Ilan River Combined Cycle Station Interim Monitoring ]Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides (X) Regional Office Notes AB-10D Measure pH, if still high, not sample. AB-10S AB-lOSL AB-15S AB-25BR AB-25D AB-25 S AB-30BR AB-30D AB-30S AB-35BR AB-5D AB-5S AS-12S AS-2D AS-8BR AS-8D BG-ID X Measure pH, if still high, not sample. BG-1 OD X BG-10S X BG-1 OBR X BG-5D BG-5S GWA-lOD GWA-12D GWA-12S GWA-14D GWA-14S GWA-15D GWA-16D GWA-16S GWA-17D GWA-18D X GWA-20D GWA-20S GWA-4D GWA-4S Dan River Combined Cycle Station Page 1 of 3 May 1, 2017 GWA-513R GWA-5BRD GWA-61) x GWA-6S x GWA-71) GWA-7S GWA-8BR GWA-81) GWA-8S GWA-9D x GWA-9S x MW-10 x MW-10D x MW-11 x MW-1 ID x MW-12 x MW-12D x MW-21D MW-21S MW-22BR x MW-22D x MW-22S x MW-23BR MW-23D MW-308BR MW-310BR MW-*31 1BR MW-314BR MW-315BR MW-317BR MW-317BRL MW-318D MW-9 MW-91) OW-308D OW-310D Dan River Combined Cycle Station Page 2 of 3 May 1, 2017 Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium (total) TOC (total) Chromium Total Antimony Calcium Iron Nickel Strontium Combined Uranium Arsenic Chloride Lead Potassium (total) Sulfate TSS Barium Chromium Magnesium Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radium 228 TDS Zinc Dan River Combined Cycle Station Page 3 of 3 May 1, 2017 Revised. H. F. Lee Energy Complex Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides (X) Regional Office Notes ABMW-1 ABMW-1 S X AMW-11 BC AMW-11 S X AMW-12BC AMW-12S AMW-13BC AMW-13S AMW-14BC AMW-14S AMW-15BC AMW-15S AMW-16BC AMW-17BC AMW-17S AMW-18S X AMW-6RBC AMW-9BC BGMW-10 BGMW-9 BW-1 CCR-100S X CMW-10 CMW-5 CMW-6R CMW-7 CMW-8 CTMW-1 CW-1 CW-2 CW-3 CW-4 DMW-1 DMW-2 DMW-3 IABMW-1 IABMW-1 S X H. F. Lee Energy Complex Page 1 of 2 May 1, 2017 IABMW-2S IABMW-3 IABMW-3S X IMW-04BC IMW-05BC IMW-lBC IMW-1 S X IMW-2BC IMW-3BC IMW-3S X IMW-4S X IMW-5S X LLMW-1 LLMW-1 S LLMW-2 LLMW-2S MW-1 MW-2 MW-3 X SMW-3 SMW-4 SMW-5 Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium xavalent Molybdenum Sodium (total) TOC (total) Chromium Total Antimony Calcium Iron Nickel Strontium Combined Uranium Arsenic Chloride Lead potassium Sulfate TSS (total) Barium Chromium Magnesium Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radium 228 TDS Zinc H. F. Lee Energy Complex Page 2 of 2 May 1, 2017 Revised Marshall Steam Station Interim MonitorinI4 Plan — Groundwater Only Sample for Wells to be Sampled Radionuclides Regional Office Notes M Recently installed and should be added to IGWMP — Based on review of analytical (submitted 2/13/2017), water quality at this AB-IOBR location is acceptable and location appears to vertically delineated (pending background for Fe, Mn, Cr6+) AB-10D AB_10S AB-10SL -1 1D AB-1 I S Recently installed and should be added to IGWMP — Based on review of analytical (submitted 2/13/2017), water quality is AB-12BR x acceptable and location appears to be vertically delineated. Radionuclide sample added by MRO. AB-12D x Radionuclide sample added by MRO. AB_12S x Radionuclide sample added by MRO. AB-12SL x Radionuclide sample added by MRO. AB-13D AB_13S AB_14D AB_14S AB-15BR AB-15D AB_15S AB-15SL AB-16D AB_16S AB_17D AB_17S AB_18D AB_18S Based on review of analytical (submitted 2/13/17), exceedance of standard for Boron was AB-IBR x observed (historically has not been above standard, but concentrations have been trending upward since installation). Further evaluation of this exceedances is warranted. Reconunend re - Marshall Steam Station Page 1 of 6 May 1, 2017 evaluating after next round of sampling and if Boron continues to exceed standard at this location a lower bedrock well will be warranted for vertical delineation. AB-1D X AB-1 S X AB-20D Recommend additional development due to elevated pH. Will reevaluate next round of sampling. AB-20S AB-21 D AB-21 S AB-2D X AB-2S X AB-3D AB-3 S AB-4D AB-4S AB-4SL AB-5BR X AB-5D X AB-5 S X AB-6BR Based on review of analytical (submitted 2/13/2017), AB-6BR has water quality issues (i.e., grout contamination) and exceedance of Barium was observed. This well should be reinstalled to more accurately represent groundwater quality at this location. AB-6D AB-6S AB-7D AB-7S AB-8D AB-8S AB-9BR AB-9D AB-9S AL-1BR X Recently installed and should be added to IGWMP — Based on review of analytical (submitted 2/13/2017), water quality is acceptable and this location appears to be vertically delineated. Radionuclide sample added by MRO. AL-1 D X Marshall Steam Station Page 2 of 6 May 1, 2017 AL-1 S X AL-2BR Recently installed and should be added to IGWMP — Based on review of analytical AL-2BRL (submitted 2/13/2017), water quality is acceptable and this location appears to be vertically delineated. AL-2D AL-2S Recently installed and should be added to IGWMP — Based on review of analytical AL-3BR (submitted 2/13/2017), Boron exceedance was observed thus warranting vertical delineation at this location. AL-3D AL-3 S Recently installed and should be added to IGWMP — Based on review of analytical AL-4BR (submitted 2/13/2017), Boron exceedance was observed thus warranting vertical delineation at this location. AL-4D Slated for reinstallation, but does not appear to have been replaced based on review of analytical BG-1BR X (submitted on 2/13/2017). Radionuclide sample added by MRO. BG-ID X Radionuclide sample added by MRO. BG-1 S X Radionuclide sample added by MRO. BG-2BR X Radionuclide sample added by MRO. Recommend redevelopment due to elevated BG-2S X turbidity. Radionuclide sample added by MRO. BG-3BR X Radionuclide sample added by MRO. Observed exceedance of Barium, based on location of this background well it is highly unlikely this is attributable to ash handling at the BG-31) X site. Further evaluation of exceedance is warranted. Radionuclide sample added by MRO. Observed exceedances of Barium and Cr(tot), based on location of this background well it is BG-3S X highly unlikely this is attributable to ash handling at the site. Further evaluation of these exceedances is warranted. Marshall Steam Station Page 3 of 6 May 1, 2017 Recommend redevelopment due to elevated turbidity. Radionuclide sample added by MRO. GWA-1BR X Recommend redevelopment due to elevated turbidity. GWA-lD X GWA-1 S X Slated for reinstallation, but does not appear to GWA-21) have been replaced based on review of analytical (submitted on 2/13/2017). GWA-2S GWA-3D GWA-3S GWA-4D GWA-4S GWA-5D GWA-5S GWA-6D X GWA-6S X GWA-7D GWA-7S GWA-8D GWA-8S GWA-9BR GWA-10D GWA-10S GWA-11BR X No analytical available, well was not installed prior to sampling event. Based on review of analytical (submitted 2/13/2017), Boron exceedance was observed thus GWA-11D X warranting a bedrock well for vertical delineation at this location. A bedrock well was previously recommended for installation and was installed after this sampling event. Based on review of analytical (submitted 2/13/2017), Boron, Selenium and sulfate exceedances were observed thus warranting horizontal delineation toward the east near the GWA-11 S X cove. A shallow well was previously recommended to be installed downgradient of GWA-11 S/D near the cove for purposes of horizontal delineation. This location will be difficult to access due to very soft ground due to the proximity of the lake. A shallow well should Marshall Steam Station Page 4 of 6 May 1, 2017 be installed for evaluation and determination if additional assessment is necessary. GWA-12BR X GWA-12D X In previous sampling events water quality issues were not observed, however, during this sampling event water quality issues have been observed. Further evaluation of this is warranted during next round sampling for determination of path forward. GWA-12S X GWA-13DA Based on review of analytical (submitted 2/13/2017), water quality remains an issue at this location. It was recently redrilled and has been sampled twice (pH>9). Recommend redevelopment and reevaluation during next sampling event to determine path forward. GWA-13S GWA-14D No analytical available, well was not installed prior to sampling event. GWA-14S No analytical available, well was not installed prior to sampling event. GWA-15S X No analytical available, well was not installed prior to sampling event. MS-8 MS-10 X MS-1 I MS-13 Mw- 1 MW-IOD X MW-10S X MW-I ID MW-1 I S MW-12D MW-12S MW-13D MW-13S MW-14BR X MW-14D X MW-14S X MW-2 MW-3 MW-4 X MW-4D X MW-5 MW-6D X Marshall Steam Station Page 5 of 6 May 1, 2017 MW-6S X MW-7 Water level only MW-7S X MW-7D X MW-7S X MW-8D X MW-8S X MW-9D X MW-9S X OB-1 (Dry Ash Basin) OB-1 (Dry Ash Landfill) Water level only Minimum Parameters to be Analyzed Aluminum Boron . Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium (total) TOC (total) Chromium Total Antimony Calcium Iron Nickel Strontium Combined Uranium Arsenic Chloride Lead Potassium Sulfate TSS (total) Barium Chromium Magnesium Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radium 228 TDS Zinc Marshall Steam Station Page 6 of 6 May 1, 2017 Revised Mayo Steam Electric Plant Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides (X) Regional Office Notes ABMW-1 X ABMW-2 ABMW-2BR ABMW-2BRL ABMW-3 ABMW-3S ABMW-4 X ABMW-4BR ABMW-4D BG-1 X BG-2 X CW-1 CW-1D CW-2 X CW-2D X CW-3 CW-4 CW-5 CW-6 X MW-10BR X MW-11BR MW-12D X MW-12S X MW-13BR MW-14BR MW-15BR water level only MW-16BR X MW-16D X MW-16S MW-2 MW-3 X MW-3BR MW-4 MW-5BR MW-8BR MW-9BR water level only MW-9BRL Mayo Steam Electric Plant Page 1 of 2 May 1, 2017 Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium (total) TOC (total) Chromium Total Antimony Calcium Iron Nickel Strontium Combined Uranium Arsenic Chloride Lead Potassium Sulfate TSS (total) Barium Chromium Magnesium Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radium 228 TDS Zinc Mayo Steam Electric Plant Page 2 of 2 May 1, 2017 Revised Riverbend Steam Station Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides (X) Regional Office Notes AB-1D Measure pH, if still >I 0, not sample. AB-1 S AB-21) AB-2S AB-3BR AB-31) AB-3S AB-41) AB-4S AB-51) AB-5S AB-5SL AB-613RU AB-6S AB-71) AB-71 AB-7S AB-81) AB-8S AS-11) AS-1S AS-2D AS-2S AS-3D AS-3S AS-3SA BG-ID Measure pH, if still >10, not sample. BG-1S BG-2BR BG-21) BG-2S BG-3D BG-3S BG-4BR x BG-4D x BG-4S x BG-5BR Riverbend Steam Station Page 1 of 4 May 1, 2017 BG-5D C-113RU Measure pH, if still >I 0, not sample. C-is C-21) C-2S GWA-10BRU Measure pH, if still >10, not sample. GWA-10D GWA-10S GWA-11D GWA-1 1 S GWA-12D x GWA-12S x GWA-14D GWA-14S GWA-151) GWA-15S x GWA-IBRU GWA-lD GWA-lS GWA-20BR Measure pH, if still >I 0, not sample. GWA-20D Measure pH, if still > 10, not sample. GWA-20S GWA-21BR GWA-21D GWA-21S GWA-22BR GWA-22BR-A x GWA-22D x GWA-22S x GWA-23BR Measure pH, if still >I 0, not sample. GWA-23D Measure pH, if still > 10, not sample. GWA-23S GWA-2BR x GWA-213RU x Measure pH, if still > 10, not sample. GWA-2S x GWA-3BR GWA-31) GWA-3S-A GWA-4BR Measure pH, if still >I 0, not sample. GWA-41) x GWA-4S x Riverbend Steam Station Page 2 of 4 May 1, 2017 GWA-5D GWA-5S GWA-6D X Measure pH, if still >10, not sample. GWA-6S X GWA-7BR GWA-7D GWA-7S GWA-8D X . GWA-8S X GWA-9BR X GWA-9D X GWA-9S X MW-10 X MW-11DR MW-11 SR MW-12 MW-13 MW-14 X MW-15 MW-15BR MW-15D Measure pH, if still >10, not sample. MW-ID MW-1 S MW-2D MW-2S MW-2S-A MW-3D MW-3S MW-4D MW-4S MW-5D MW-5S MW-6D MW-6S MW-7BR X Measure pH, if still >10, not sample. MW-7D X MW-7SR X MW-8D MW-8I MW-8S MW-9 X Riverbend Steam Station Page 3 of 4 May 1, 2017 MW-9BR X Measure pH, if still >10, not sample. MW-9D X Measure pH, if still >10, not sample. Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium (total) TOC (total) Chromium Total Antimony Calcium Iron Nickel Strontium Combined Uranium Arsenic Chloride Lead Potassium Sulfate TSS (total) Barium Chromium Magnesium Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radium 228 TDS Zinc Riverbend Steam Station Page 4 of 4 May 1, 2017 Revised Roxboro Stearn Electric Plant Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides (X) Regional Office Notes ABMW-1 X ABMW-lBR X ABMW-2 X ABMW-2BR X ABMW-3 ABMW-3BR ABMW-3BRL ABMW-4 X ABMW-4BR X ABMW-5 X ABMW-5D X ABMW-6 ABMW-6BR ABMW-7 ABMW-7BR ABMW-7BRL BG-1 X BG-lBR X BG-1BRL X CW-1 CW-2 X CW-2D X CW-3 CW-3D CW-4 CW-5 X GMW-10 GMW-11 GMW-6 X GMW-7 GMW-8 GMW-9 MW-1BR MW-2BR MW-3BR X MW-4BR MW-4BRL water level only Roxboro Steam Electric Plant Page 1 of 2 May 1, 2017 MW-5BR X MW-5D X MW-6BR X MW-6D X MW-7BR MW-8BR MW-9BR X MW-10BR X MW-11BR X MW-12BR MW-13BR X MW-14BR X MW-15BR X MW-15D X MW-16BR X MW-17BR X MW-18BR X MW-18D X MW-19BRL X MW-2 X MW-20BRL MW-21 BRL water level only MW-22BR MW-22D MW-23BR X MW-24BR MW-25BR MW-26BR Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium (total) TOC (total) Chromium Total Antimony Calcium Iron Nickel Strontium Combined Uranium Arsenic Chloride Lead PotassiumSulfate TSS (total) Barium Chromium Magnesium Radium 226 Sulfide Vanadium Beryllium Cobalt . Manganese Radium 228 TDS Zinc Roxboro Steam Electric Plant Page 2 of 2 May 1, 2017 Revised L. V. Sutton Enemy Complex Interim Monitoring Plan — Groundwater Only Wells to be Sample for Radionuclides (X) Regional Office NotesSampled AW-1C AW-2C AW-2D AW-3C X AW-4C X AW-5C AW-5D AW-6D AW-6E AW-7D AW-8C AW-9C AW-9D MW-05C X MW-05CD X MW-05D X MW-05E MW-12 MW-16D MW-20 MW-20D MW-23D X MW-23E X MW-27C X MW-31C X MW-36C X MW-37B X MW-37C X MW-37CD X MW-37D X MW-37E X MW-38B MW-38C X MW-38D X MW-39B MW-39C X MW-39D X MW-40B L. V. Sutton Energy Complex Page 1 of 2 May 1, 2017 MW-40C X MW-40D X MW-41E MW-6C MW-8 X SMW-IC SMW-2C SMW-3C SMW-4C SMW-5C SMW-6C SMW-6D Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium (total) TOC (total) Chromium Total Antimony Calcium Iron Nickel Strontium Combined Uranium Arsenic Chloride Lead Potassium Sulfate TSS (total) Barium Chromium Magnesium Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radium 228 TDS Zinc L. V. Sutton Energy Complex Page 2 of 2 May 1, 2017 Revised W. H. Weatherspoon Bower Plant Interim Monitoring Plan — Groundwater Only Wells to be Sample for Radionuclides (X) Regional Office NotesSampled ABMW-01 AW-01 D AW-01I AW-01 S AW-02D AW-02S AW-03D AW-03I AW-03S BW-01 BW-02D BW-02I BW-02S X BW-03D X BW-03I X BW-03S X CCR-101-BG CAMA X CW-01 CW-02 CW-03 X MW-01 X MW-02 X MW-03 X MW-04 X MW-05 X MW-06 X MW-07 X MW-08D X MW-08I X MW-08S (OW-8) X MW-33D MW-33I MW-33S MW-41D MW-41I MW-44D MW-44I X W. H. Weatherspoon Power Plant Page 1 of 2 May 1, 2017 MW-44S MW-44SA X MW-49D MW-49I X MW-52 X MW-53D MW-53I MW-54D MW-55D X MW-55I X PW-1 (DEP 2) PZ-01 PZ-02 PZ-03 Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium (total) TOC (total) Chromium Total Antimony Calcium Iron Nickel Strontium Combined Uranium Arsenic Chloride Lead Potassium Sulfate TSS (total) Barium Chromium Magnesium Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radium 228 TDS Zinc W. H. Weatherspoon Power Plant Page 2 of 2 May 1, 2017 /n DUKE ENERGY, June 12, 2017 Mr. S. Jay Zimmerman, P.G. Director, Division of Water Resources North Carolina Department of Environmental Quality 1611 Mail Service Center Raleigh, NC 27699-1611 RE: Response to DEQ Letter Dated May 1, 2017 Revised Interim Monitoring Plan for 14 Duke Energy Facilities Dear Mr. Zimmerman: Paul Draovitch Senior Vice President Environmental, Health & Safety 526 South Church Street EC3XP Charlotte, NC 28202 980. 373.0408 Duke Energy is in receipt of the above -referenced letter which identifies by site the groundwater monitoring wells to be sampled on a quarterly basis beginning in Quarter 3 (July 1). Duke Energy, along with our consultants, has reviewed the list and offers minor changes. Duke Energy requests a meeting with Regional Office and Central Office personnel to discuss these changes to the Interim Monitoring Plan (IMP) such that sampling beginning in July can proceed smoothly. Duke Energy proposes the following changes by site: Allen Steam Station Remove well BG-1D from the IMP and replace with recently installed well BG-1DA* Remove well BG-2BR from the IMP and replace with recently installed well BG-2BRA* Remove well GWA-14D from the IMP and replace with recently installed well GWA-14DA Remove well GWA-21D from the IMP and replace with recently installed well GWA-21DA* Remove well GWA-3BR from the IMP and replace with recently installed well GWA-3BRA* Remove well GWA-4BR from the IMP and replace with recently installed well GWA-4BRA* Remove well GWA-5BR from the IMP and replace with recently installed well GWA-SBRA* The need for any additional groundwater monitoring wells will be discussed in the near term. *- Sample for radionuclides also Asheville Steam Electric Plant Wells MW-23BR and MW-8BR should be utilized for water level only Well PZ-16 has turbidity issues and needs to be removed from the IMP. Any discussion regarding this well replacement will be discussed in the near term. Add wells GW-1*, CB-2, CB-311, CB-4, CB-46, CB-5, CB-6, CS-7, CB-8 and CB-9* to the IMP. *- Sample for radionuclides also Belews Creek Steam Station Remove well BG-2BR from the IMP and replace with recently installed well BG-2BRA Remove well GWA-10D from the IMP and replace with recently installed well GWA-10DA Remove well GWA-16D from the IMP and replace with recently installed well GWA-16DA Remove well GWA-18S from the IMP. Its replacement well (GWA-18SA) is already part of the IMP Mr. Jay Zimmerman Letter June 12, 2017 Remove well GWA-19S from the IMP. Its replacement well (GWA-19SA) is already part of the IMP Remove well GWA-20S from the IMP. Its replacement well (GWA-20SA) is already part of the IMP Remove well BC-23A from the IMP. This well is associated with the Craig Road Landfill, not the ash basin Remove well BC-28 from the IMP. This well is associated with the Craig Road Landfill, not the ash basin Remove Area of Wetness locations BCSW-007, BCSW-008, BCSW-018A, BCSW-019 and BCWW-002 from the IMP. The IMP should only include groundwater locations per DEQ letter dated May 1, 2017. Buck Combined Cycle Station Remove well AB-9BR from the IMP and replace with recently installed well AB-9BRA* Remove well AB-913RU from the IMP and replace with recently installed well AB-9BRUA* Remove well BG-1BR from the IMP and replace with recently installed well BG-1BRA Remove well BG-1D from the IMP and replace with recently installed well BG-1DA Remove well GWA-18D from the IMP and replace with recently installed well GWA-18DA* Remove well GWA-2BR from the IMP and replace with recently installed well GWA-2BRA* Remove well GWA-9BR from the IMP and replace with recently installed well GWA-9BRA* Remove well MW-8BR from the IMP and replace with recently installed well MW-8BRA* Recommend removing well AB-5S from the IMP since two pore water wells exist at the AB-5 cluster. Duke will continue to sample AB-5SL at this location which is already part of the IMP. Well AB-813RU is actually well AB-81). Please update the IMP. Monitoring wells GWA-16S*, GWA-16D*, and GWA-16BR* have been installed off -site at 1085 Leonard Road. These wells are already part of the IMP. The need for any additional groundwater monitoring wells will be discussed in the near term. *- Sample for radionuclides also CaPe_Fear Steam Electric Plant Wells MW-9 and MW-9BR are listed twice. In one case they are listed for radionuclide analysis, in the other case, they are not listed for radionuclide analysis. Duke Energy requests these two wells be included in the IMP and also sampled for radionuclides with the duplicate listing removed. Cliffside Steam Station aka James E. Rogers Energy Cam lex Remove well AB-3SL from the IMP; well will be replaced at a later date by well AB-3SLA* Remove well MW-11D from the IMP; well will be replaced at a later date by well MW-11DA Remove well MW-42D from the IMP and replace with recently installed well MW-42DA Remove well MW-30D from the IMP; well will be replaced at a later date by well MW-30DA* Add recently installed well BG-1BRA* to the IMP Add recently installed well AS-6BRA to the IMP Add well US-41111 and recently installed well U5-4BRA to the IMP (U5-4BR was not abandoned after replacement) Add recently installed well GWA-29BRA* to the IMP Add recently installed well AB-3BRUA to the IMP Add recently installed well AS-7BRA to the IMP Remove well AB-3BR from the IMP (obstruction in well) Remove well GWA-21D from the IMP (this well does not exist) Remove well GWA-22D from the IMP and add well GWA-22BRU to the IMP (well GWA-22D does not exist) Remove well GWA-48S from the IMP (this well does not exist) Remove wells IB-3S and I13-31) from the IMP as these wells have been abandoned Remove well U5-3D from the IMP as this well has been abandoned Mr. Jay Zimmerman Letter June 12, 2017 Change wells BG-2D, GWA-33BR and GWA-45D in the IMP to water levels only *- Sample for radionuclides also Dan River Combined Cycle Station Remove well BG-1D from the IMP and replace with recently installed well BG-1DA* Remove well AS-12S from the IMP as it has been abandoned Remove well GWA-18D from the IMP as it has been abandoned *- Sample for radionuclides also H.F. Lee Energy Complex No comments Marshall Steam Station Recommend removing wells AB-10S, AB-12S, AB-15S and AB-4S from the IMP since two pore water wells exist at these clusters. Duke will continue to sample the'SL' wells at these clusters which are already part of the IMP. Remove well AB-6BR from the IMP and replace with recently installed well AB-6BRA Remove well BG-1BR from the IMP and replace with recently installed well BG-1BRA* Remove well GWA-2D from the IMP and replace with recently installed well GWA-2DA The need for any additional groundwater monitoring wells will be discussed in the near term. *- Sample for radionuclides also Mayo Steam Electric Plant No comments Riverbend Steam Station Remove well GWA-22BR from the IMP. Its replacement well (GWA-22BR-A*) is already part of the IMP. Remove well MW-2S from the IMP. Its replacement well (MW-2S-A*) is already part of the IMP. Well GWA-10D is actually well GWA-10BRU (part of IMP). Please update the IMP. Well GWA-1D is actually well GWA-IBRU (part of IMP). Please update the IMP. Monitoring wells AB-3611, AB-31), AB-3S, AB-41), AB-4S, AB-51), AB-5S, AB-5SL, AB-71), AB-71, AB-7S, AS- 1D, AS -IS, AS-21), AS-2S, AS-31), AS-35, and AS-3S-A have been abandoned due to ash basin closure activities. Please remove these wells from the IMP. Monitoring wells AB-6BRU and AB-6S are anticipated to be abandoned in June 2017 due to ash basin closure activities. Please remove these wells from the IMP. Monitoring well MW-12 was historically abandoned. Please remove this well from the IMP. Monitoring wells BG-ID, C-1BRU, GWA-20D, GWA-23D, MW-15D, MW-7BR*, MW-9BR*, and MW-9D* are currently being replaced. Duke Energy will update the regional office once the 'new' well names are known. *- Sample for radionuclides also Roxboro Steam Electric Plant Add wells BG-1BRL and MW-23BR for water level only Add wells BG-1BRLR*, MW-11D*, MW-23BRR*, MW-27BR, MW-28BR, MW-28BR, MW-30BR, MW-31BR, MW-32BR, MW-33BR, GPMW-1S, GPMW-ID, GPMW-IBR, GPMW-2D, GPMW-2BR, GPMW-3D & GPMW-3BR to the IMP. *- Sample for radionuclides also 3 Mr. Jay Zimmerman Letter June 12, 2017 L.V. Sutton Energy Complex Remove well MW-SE (abandoned) and add replacement well MW-SR-E to the IMP. Remove well AW-61) (abandoned) and add replacement well AW-6R-D to the IMP. Remove well AW-6E (abandoned) and add replacement well AW-6R-E to the IMP. Remove well AW-713 (abandoned) and add replacement well AW-7R-D to the IMP. Remove well MW-12 (abandoned) and add replacement well MW-12R to the IMP. Remove well MW-31C (abandoned) and add replacement well MW-31R-C* to the IMP. Well MW-6C has been abandoned and needs to be removed from the IMP. Add wells MW-7C, MW-11, MW-19, MW-21C, MW-228, MW-22C, MW-23B, MW-23C, MW-24R-B, MW- 24R-C, MW-2713, MW-288, MW-28C, MW-32C* and MW-33C* to the IMP. *- Sample for radionuclides also W. H. Weatherspoon Power Plant Include well ABMW-1 within the IMP for radionuclides also. Remove wells BW-21 and BW-2D from the IMP due to turbidity and/or grout contamination. These wells will be used for water level only. The official well name is CCR-101-13G, rather than CCR-101-BG CAMA (remove the CAMA from the name). Please update the IMP accordingly. Again, Duke Energy requests a meeting with Regional Office and Central Office personnel in the near future to discuss these changes. If you have any questions or need any clarification regarding the information provided, please contact Ed Sullivan at ed.sullivan duke -ever .com or at 980-373-3719 at your convenience. Respe fully su mitte Paul Draovitch SVP — Environmental, Health & Safety CC' Mr. Ed Sullivan — Duke Energy Ms. Kathy Webb —SynTerra Mr. Mark Filardi — HDR, Inc. M r F .y Water Resources Environmental Quality December 20, 2017 ROY COOPER Governor MiCHAEL S. REGAN Secretary LINDA CULPEPPER Interim Director Paul Draovitch a Senior Vice President 3 Environmental, Health & Safety Duke Energy n 526 South Church Street-3Y:.J�..+�f�. Mail Code EC3XP Charlotte, North Carolina 28202 Subject: Revised Interim Monitoring Plans for 14 Duke Energy Facilities 1st Quarter 2018 Dear Mr. Draovitch: The North Carolina Department of Environmental Quality (DEQ) is providing the attached revised Interim Monitoring Plans (IMPs) for the respective coal ash facilities. Per our agreement, the DEQ will be providing Duke Energy with updated IMPs quarterly until the individual facility Corrective Action Plans are approved. Also, per our agreement, Duke Energy will include and begin sampling any newly installed groundwater assessment wells as part of the facility IMP and the DEQ will formally include it in the subsequent updated quarterly IMP. The attached IMPS only contain references to groundwater monitoring locations. Sampling at surface water locations that were identified as part of the May 1, 2017 communication from DEQ to Duke Energy regarding revised IlvIPS at the facilities is expected to continue pending finther notice. DEQ may elect to provide Duke Energy with additional surface sampling locations to incorporate into the revised IMPs at a future time. For clarification, we have also provided the minimum expected groundwater sampling analyte list. The attached revised facility IMPS shall be conducted on a quarterly basis commencing the fourth quarter of calendar year 2017 pursuant to 15A NCAC 02L .0110, until Corrective Action Plans are accepted for the individual facilities or as directed otherwise by the DEQ. The quarterly sampling events will be conducted in conjunction with planned compliance monitoring sampling events for three quarters during the calendar year, supplemented with an additional sampling event conducted at each facility in order to provide four rounds of monitoring data to evaluate seasonal fluctuations during a year -long timeframe. If sampling an individual groundwater location is problematic, please call the Regional Office that manages the facility to discuss issues. Any changes to IMPS and sampling requirements must be discussed with the respective Regional Offices and coordinated by official correspondence from the DEQ Central Office. Since Duke Energy will submit updated Comprehensive Site Assessments in the near future, the requirement for an annual monitoring report submitted by April 30th for each respective coal -: `lNothtng Compares stale of North Carolina I Environmental Quality I Division of Warr Resources Water Quality Regional Operations section 1636 Mail service Center I Raleigh, North Carolina 27699-1636 919-707-9129 facility as set forth in the May 1, 2017 letter will be extended to a date in 2018 that will be later defined. In order to optimize the groundwater monitoring at each facility, DEQ will be removing the groundwater monitoring condition from the NPDES permits as they are reissued. Duke Energy shall continue to monitor the compliance wells separately under the individual NPDES permits until the NPDES permits are reissued with no groundwater monitoring condition. At that time, the compliance wells shall continue to be monitored per the attached revised IMPs under the authority of 15A NCAC 02L .0110. The DEQ is open to consider further optimization of the IMPS following a qualitative and quantitative review of site -specific data. A thorough analysis of spatial and temporal trends related to contaminant distribution that include determination of background conditions and identification of areas impacted by coal ash residuals must be provided as a decision framework to support improvements to long-term monitoring programs. If you have any questions, please feel free to contact Steve Lanter at (919) 807-6444. Sincerely, 4SZ?merm�an,P.C. Division of Water Resources Attachments: Revised Interim Monitoring Plans for the 14 coal ash facilities cc: WQROS Regional Offices WQROS Central File Copy Revised_ Allen Steam Station Interim Monitoring Plan — Groundwater Onlv Wells to be Sampled Sample for Radionuclides Regional Office Notes X AB-101) — AB-10S AB-11D x AB-12D AB-12S AB-13D X AB-! 3S x AB-14BR AB-14D AB-1 R AB-2 AB-20D AB-20S AB-21 BRL x AB-21D Sample to be analyzed for total boron and sulfate onl . AB-21 S x AB-21 SL x AB-22BRL AB-22BR AB-22D AB-22S AB-23BRU Sample to be analyzed for total boron and sulfate only. AB-23S AB-24BR AB-24D Sample to be analyzed for total boron and sulfate only. AB-24S r� AB-24SL AB-25BR Sample to be analyzed for total boron and sulfate onl . Sample to be analyzed for total boron and sulfate only. x 1 x AB-25BRU AB-25S AB-25 SL AB-26D AB-26S AB-27BR AB-27D Allen Steam Station Page 1 of 5 December 20, 2017 Sample for Wells to be Sampled Radionuclides Regional Office Notes X AB-27S AB-28D AB-28S AB-29D -- AB-29S AB-29SL AB-2D _ T AB-30D AB-30S AB-31 S AB-32D AB-32S AB-33D AB-33 S AB-34D AB-34S _ AB-35BR X AB-35D Sample to be analyzed for total boron and sulfate only. AB-35S AB-36D AB-36S AB-37D AB-37S AB-38BR AB-38D AB-38S _ AB-39D AB-39S AB4BR X AB-4D X AB-4S X AB-5 AB-6A X AB-6R X AB-91) X - ^4- AB-9S X BG-1 DA _ X Note: BG-1D has been abandoned and thus removed from the IMP. BG-1 DA was installed as replacement well. j BG-1 S X Allen Steam Station Page 2 of 5 December 20, 2017 Wells to be Sampled Sample for Radionuclides X -- Regional Office Notes Note: BG-2BR has been abandoned and thus removed from the IMP. BG-2BRA was installed as re lacement well. BG-2BRA X BG-2D X BG-2S X BG-3D BG-3S BG-4BR BG-4D BG4S GWA-14DA Note: GWA-14D has been abandoned and thus removed from the IMP. GWA-14DA was installed as replacement well. GWA-14S GWA-15D GWA-15S GWA-16D GWA-16S GWA-17D X GWA-17S x GWA-18D GWA-l8S GWA-19D Sample to be analyzed for total boron and sulfate only. GWA-19S GWA-IBR X GWA-lD X GWA-1 S X GWA-21 BR X GWA-21 DA x Note: GWA-21 D has been abandoned and thus removed from the IMP. GWA-21 DA was installed as replacement well. GWA-21 S X GWA-22D GWA-22S GWA-23D Sample to be analyzed for total boron and sulfate only. GWA-23S GWA-24BR GWA-24D GWA-24SA Note: GWA-24S has been abandoned and thus removed from the IMP. GWA-24SA was installed as re lacement well. Allen Steam Station Page 3 of 5 December 20, 2017 - ---- 'I Wells to be Sampled Sample for Radionuclides X - -- -- -- - - Regional Office Notes GWA-26D _ GWA-26Sr GWA-2D X GWA-2S X GWA-313RA X Note: GWA-3BR has been abandoned and thus removed from the IMP. GWA-3BRA was installed as replacement well. GWA-3D X Y GWA-3S X GWA4BRA X Note: GWA4BR has been abandoned and thus removed from the IMP. GWA4BRA was installed as replacement well. _ GWA4D X �^ GWA-4S X i GWA-SBRA X Note: GWA-5BR has been abandoned and thus removed from the IMP. GWA-5BRA was installed as replacement well. GWA-5D X GWA-5S X GWA-613RA _ X _ Note: GWA-6BR has been abandoned and thus removed from the IMP. GWA-613RA was installed as replacement well. GWA-6DA x GWA-6S X _ GWA-7D X — GWA-7S X GWA-8D GWA-8S GWA-9D GWA-9S X GWA-9BR X Allen Steam Station Page 4 of 5 December 20, 2017 Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 _ Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Allen Steam Station Page 5 of 5 December 20, 2017 Revised Asheville Steam Electric Plant interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides X Regional Office Notes ABMW-11BR AMW-03B X AMW-lB X AMW-2A AMW-2B water level only APZ-30 water level only B-L water level only B-1-A water level only B-2 water level only CB-1 X CB-1BR water level only CB-1BRL water level only CB -ID X CB-8BR X CB-81) water level only CB-9BR X CB-9SL X GW-1BR GW-ID GW-2 X GW-3 X GW-4 X GW-5 X MW-3D X MW-5BR MW-5D MW-8S X MW-10 X MW-11 MW-11D MW-13BR - -- MW-13D MW-14BR MW-15A X - MW-15BR water level only MW-15D X MW-16A X Asheville Steam Electric Plant Page 1 of 3 December 20, 2017 MW-16BR X _ MW-17A X MW-18BR X MW-18BRL X MW-18D X MW-19BR water level only MW-20A _ MW-21D X�� MW-22BR X MW-22D X MW-23BR MW-23DL {� M W-23DU MW-24S X MW-6BR X MW-6D X MW-6S X MW-7BR water level only MW-8BR MW-9BR x MW-9D X MW-9S X P-102 water level only P-103 PZ-16 Needs to be replaced and added to IMP. PZ-17D X PZ-17S X PZ-19 X PZ-22 X Asheville Steam Electric Plant Page 2 of December 20, 2017 Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Asheville Steam Electric Plant Page 3 of 3 December 20, 2017 Revised Belews Creek Steam Station Interim Monitoring -Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides X Regional Office Notes AB-1 BR AB-1 D AB-1 S AB-2D AB-2S AB-3D AB-3 S AB4BR Measure pH, if still high, do not sample AB-4BRD AB-4D AB-4S AB4SL Measure pH, if still high, do not sample AB-5D AB-5S AB-5SL AB-6D AB-6S AB-6SL AB-7D AB-7S AB-8D AB-8S AB-8SL AB-9BR AB-9BRD Measure pH. if pH is still high, do not sample. AB-9D AB-9S BG-1 D BG-1 S X Dry 7/19/17; continue monitoring BG-2BRA Replaced BG-2BR BG-2D X BG-2S X BG-3D BG-3S GWA-10DA GWA-I0S GWA-11D Belews Creek Steam Station Page 1 of 4 December 20, 2017 GWA-11 S GWA-12BR GWA-12D GWA-12S GWA-16BR Measure pH. If pH is still high, do not sample. GWA-16DA GWA-16S GWA-17D GWA-17S GWA-18D GWA-18SA GWA-19BR GWA-19D GWA-19SA GWA-IBR X Measure pH. If pH is still high, do not sample. GWA-1D X GWA-1 S X GWA-20BR GWA-20D GWA-20SA GWA-21 D GWA-21 S GWA-22D GWA-22S GWA-23D GWA-23 S GWA-24BR GWA-24D X GWA-24S X Insufficient Volume 7/21/17; continue monitoring GWA-25BR X GWA-26BR X GWA-26D X GWA-26S X GWA-27BR GWA-27D GWA-27S GWA-2D GWA-2S GWA-30D x Measure pH. If pH is still high, do not sample. GWA-30S x GWA-31 D Belews Creek Steam Station Page 2 of 4 December 20, 2017 GWA-31 S GWA-32D GWA-32S GWA-3D GWA-3S Insufficient Volume 7/21/17; continue monitoring GWA-6D X GWA-6S X GWA-7D X GWA-7SA X GWA-8D X GWA-8S X GWA-9BR GWA-9D GWA-9S MW-104BR Measure pH. If pH is still high, do not sample. MW-104D MW-104S MW-200BR X MW-200D X MW-200S X MW-201 BR MW-201D MW-202BR MW-202D MW-202S MW-203BR MW-203D MW-203S MW-204D M W-204S MW-3 }i Belews Creek Steam Station Page 3 of December 20, 2017 Minimum Parameters to be Analyzed Aluminum Boron Copper Mercua Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Ma mesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Belews Creek Steam Station Page 4 of 4 December 20, 2017 Revised Buck Combined Cycle Station Interim Monitoring Plan — Groundwater Only Wellsto be Sampled j Sample for Radionuclides _ Regional Office Notes — -- AB -ID AB-1 OBR A13-10BRL AB-1 OD AB-IOS AB-2BR Sample to be analyzed for total boron and sulfate only. AB-2D X—~ AB-2 S X AB-2SL X AB-3D AB-3S AB-4BRL AB-4BRU AB-4S AB-4SL AB-SBRU X AB-5S X AB-5SL X AB-6BRU AB-7BRU A134S { AB-BBRU AB-8S AB-9BRA X Note: AB-9BR has been abandoned and thus removed from the IMP. AB-9BRA was installed as replacement well. AB-9BRUA X Note: AB-9BRU has been abandoned and thus removed from the 1MP. AB-9BRUA was installed as replacement well. AB-9S X AS-1 D AS -IS AS-2D AS-3D AS-3S { j BG-1 BRA Note: BG-1 BR has been abandoned and thus removed from the IMP. BG-1 BRA was installed as replacement well. Buck Combined Cycle Station Page 1 of 4 December 20, 2017 Wells to be Sampled Sample for Radionuclides X ' Regional Office Notes - J BG-IS- BG-21) X BG-2S -- X BG-3BRU X BG-3S X GWA-10D GWA-10S GWA-11 D GWA-11 S GWA-12BRU ���-- GWA-12S � GWA-13D GWA-13SR GWA-14BR GWA-14D Sample to be analyzed for total boron and sulfate only. GWA-14S X GWA-15BR X GWA-15D X GWA-155 X GWA-16BR X GWA-16D X GWA-16S X �� �---�.—.Y�_ ,�.�..__.-.... W,�... .- -�---- ---- • - GWA-175 �...,�—�. GWA-18DA X Note: GWA-18D has been abandoned and thus removed from the IMP. GWA-18DA was installed as replacement well. GWA-18S X GWA-19D X ..,�.-.-....w__..,-.___._.�........�T�.�v,.-.,,....,�..�_ .. GWA-19S X GWA-1 D X GWA-1 S X GWA-20D X GWA-20S X GWA-22D X GWA-2BRA X Note: GWA-2BR has been abandoned and thus removed from the IMP. GWA-2BRA was installed as replacement well. GWA-2BRU X GWA-2S X GWA-3BR X Buck Combined Cycle Station Page 2 of 4 December 20, 2017 Wells to be Sample for Sampled -Radionuclides Regional Office Notes ._ . rvt GWA-3BRU X GWA-3S X GWA-4D X G WA-4S X GWA-SBRU X GWA-5S X GWA-6BR X GWA-6BRL X GWA-6BRU X GWA-6S X GWA-7D X GWA-7S X GWA-SD Note: GWA-91311 has been abandoned and thus GWA-9BRA X removed from the IMP. GWA-9BRA was installed as i. replacement well. GWA-9D X GWA-9S X MW-1 OD MW-11 BR X MW-1 ] BRL X j MW-11D X MW-l1S X MW-12D MW-12S MW-I3D MW-ID MW-1 S MW-3D X MW-3S X MW-4D MW-4S MW-5D MW-5S MW-6BR X MW-6D X MW-6S X MW-7D MW-7S Buck Combined Cycle Station Page 3 of 4 December 20, 2017 Wells to be Sample for Sampled Radionuclides Regional Office Notes Note: MW-8BR has been abandoned and thus MW-8BRA X removed from the IMP. MW-8BRA was installed as replacement well. MW-8D X MW-8S X MW-9D X - M W-9S X Minimum Parameters to be Analyzed Aluminum Boron Coe2er Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Buck Combined Cycle Station Page 4 of 4 December 20, 2017 Revised Cape Fear Steam Electric Plant Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides X Regional Office Notes ABMW-1 X ABMW-1 BR X ABMW-1 S X ABMW-2SL ABMW-2SU ABMW-3 X ABMW-3BR ABMW-3SR X ABMW-4 X ABMW-4S X ABMW-5BR ABMW-5S BGMW-4 X BGTMW-4 X CMW-01 X CMW-02 CMW-03 X CMW-5R Installed 7/I9/17 CMW-06 X CMW-07 X CMW-08 X CTMW-01 X CTMW-02 CTMW-07 CTMW-08 X MW-10 X MW-1 OBR X MW-l0BRL MW-lOD MW-11 X MW-12 X MW-12BR MW-13 MW-15BR X MW-15SL X MW-15SU X MW-16BR X Cape Fear Steam Electric Plant Page I of December 20, 2017 MW-16S X MW-17BR MW-17SL X X MW-17SU MW-18S X MW-19S MW-20BR MW-20S MW-21BR MW-21SL X MW-21 SU x— -- MW-22BR MW-22S MW-23BR Duke indicated in email sent 9-18-17 this well location is designated MW-24BR MW-23D X MW-23S X MW-24BR X MW-24S X MW-SBRR MW-6BR X MW-9 X _ MW-9BR X PZ-10 PZ-3 D PZ-3S PZ-4 PZ-5 X PZ-6 PZ-7 PZ-8 -- Cape Fear Steam Electric Plant Page 2 of 3 December 20, 2017 Minimum Parameters to be Analvzed Aluminum Boron Copper Mercury Selenium Thallium ' Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic ' Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium i. Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium -Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Cape Fear Steam Electric Plant ' Page 3 of 3 December 20, 2017 Revised James E. Rogers Energy Complex Interim Monitoring Plan - Groundwater Only Wells to be Sampled Sample for Radionuclides X Regional Office Notes -- - AB-1 D AB -IS - AB-2D -- —� AB-2 S AB-3BR AB-3I AB-3S X AB-3SL X AB-4BR AB-4D AB-4S X AB-4SL X AB-5BR AB-5BRU AB-5S X AB-6B R AB-6D AB-6S X AS -ID AS-i SB AS-2BR AS-2D X AS-2S X AS-3BRU AS-4D AS-4S AS-513RU AS-5S AS-6D AS-6S AS-713 - ---� AS-7S X BG-ID X BG-IS X BG-2D X CCPMW-ID X CCPMW-1 S X - James E. Rogers Energy Complex Page 1 of 5 December 20, 2017 CLMW-1 X T CLMW-2 CLMW-3D X CLMW-3S X CLMW-SD CLMW-5S CLMW-6 CLP-1 water level only CLP-2 water level only GWA-1OD GWA-lOS GWA-11BRU X GWA-11 S X GWA-12BRU GWA-12S GWA-13BR GWA-14BR GWA-14D GWA-14S GWA-1BRU GWA-20BR X GWA-20D X GWA-20S X GWA-2113R X GWA-21BRU X ; GWA-21 D GWA-21S X ^� GWA-22D GWA-22S X GWA-23D GWA-24BR �^ GWA-24D GWA-24S GWA-25S GWA-25D _ water level only GWA-26S GWA-26D ~� ~ _ water level only GWA-27BR X GWA-27D-A X — T' GWA-28BR GWA-28BRU James E. Rogers Energy Complex Page 2 of 5 December 20, 2017 GWA-28S GWA-29D X GWA-2BR X GWA-2BRU X GWA-2S X GWA-30BR GWA-30BRU water level only GWA-30S GWA-31 BR -A GWA-31D ~� GWA-32D GWA-32BR water level only GWA-33BR GWA-33D GWA-33S GWA-34S -_ GWA-35D GWA-35S GWA-36D X GWA-36S GWA-37D GWA-37S GWA-38D GWA-38S GWA-39S water level only GWA-3D X GWA40S water level only GWA-42S water level only GWA-43D GWA-43S _ GWA-44BR GWA-44D GWA-44S G WA-45D GWA-45S GWA-46D GWA-47D GWA-48BR GWA48S GWA-4D X GWA-4S James E. Rogers Energy Complex Page 3 of December 20, 2017 GWA-5BRU GWA-5S GWA-6S GWA-6D water level only IB-3D .v.t IB-3S X MW-10D MW-10S MW-11D MW-11S X MW-20D _ MW-20DR MW-21BR MW-21D MW-22BR M W-22DR J MW-23D MW-23DR M W-23 S M W-24D X MW-24DR MW-25DR MW-2D-A _ MW-30D X MW-30S X MW-32BR X MW-32D X MW-32S X M W-34S MW-34BRU MW-36BRU MW-36S MW-38BR X MW-38D X MW-38S X MW-40BRU MW-40S MW-42D MW-42S MW-8D MW-8S X James E. Rogers Energy Complex Page 4 of 5 December 20, 2017 U5-1D U5-1S U5-2BR U5-2D X U5-2S-SL-A X U5-3D U5-4D U5-4S U5-5BR U5-5D X U5-6D U5-6S U5-8BR U5-8D U5-8S Minimum Parameters to be Analyzed Aluminum Boron Copper Mercua Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids James E. Rogers Energy Complex Page 5 of 5 December 20, 2017 Revised Dan River Combined Cvcle Station Interim Monitoring Plan — Ground►vater Only Wells to be Sampled Sample for Radionuclides X Regional Office Notes AB-30BR AB-30D AB-30S AB-35BR AB-5D AB-5 S AS-12S AS-8BR AS-8D BG-IDA X Insufficient volume 8/24/17; continue motoring BG-10D X BG-10S X BG-1013R X BG-5D BG-5S GWA-lOD GWA-12D GWA-12S GWA-14D GWA-14S GWA-15D GWA-16D GWA-16S GWA-17D GWA-20D GWA-20S GWA-4D G WA-4S GWA-5BR GWA-SBRD GWA-6D X GWA-6S X GWA-7D GWA-7S GWA-8BR GWA-8D GWA-8S Dan River Combined Cycle Station Page 1 of 2 December 20, 2017 GWA-9D X GWA-9S X MW-10 X Dry 8/24/17; continue monitoring MW-lOD X MW-11 X Dry 8/24/17; continue monitoring MW-I 1D X MW-12 X MW-12D X MW-21D MW-21S MW-22BR X MW-22D X M W-22S X MW-23BR M W-23D MW-317BR MW-317BRL MW-9 Dry 8/24/17; continue monitoring MW-9D Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Dan River Combined Cycle Station Page 2 of 2 December 20, 2017 Revised H. F. Lee Energv Complex Interim Monitoring Plan - Ground►vater Only Wells to be Sampled Sample for Radionuclides X Regional Office Notes ABMW-1 ABMW-1 S X AMW-11 BC AMW-11S X AMW-12BC AMW-12S _ Y AMW-13BC AMW-13S AMW-14BC AMW-14S AMW-15BC AMW-15S AMW-16BC AMW-17BC AMW-17S AMW-18S X AMW-6RBC AMW-9BC AMW-19S Well pairs AMW-19-23 S/BC were added to the list. AMW-19BC AMW-20S AMW-20BC AMW-21 S AMW-21 BC AMW-22S AMW-22BC AMW-23 S AMW-23BC BGM W-10 BGMW-9 BW-1 CCR-100S X CMW-10 CMW-5 CMW-6R CMW-7 CMW-8 H. F. Lee Energy Complex Page I of 3 December 20, 2017 CTMW-1 CW-1 _ CW-2 _ CW-3 C W-4 --r --- --.-._ t.--- DMW-I DMW-2 DMW-3 IABMW-1 � ?C IABMW-IS IABMW-2S IABMW-3 -- - - -- -- IABMW-3S X------ IM W-04BC _ IMW-05BC IMW-IBC IMW-1 S-- IMW-2BC IMW-3BC IMW-3S X IMW-4S X IMW-5 S X LLMW-1 LLMW-1 S ---- - LLMW-2 LLMW-2S MW-1 M W-2 MW-3 SMW-3 SMW-4 SMW-5 H. P. Lee Energy Complex Page 2 of 3 December 20, 2017 Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium -Magnesium_ Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids H. F. Lee Energy Complex rage 3 of 3 December 20, 2017 Revised Marshall Steam Station Interim Monitoring Plan — Groundwater Onlv Wells to be Sampled Sample for Radionuclides X Regional Office Notes AB -I OBR AB-1013 AB-1 OS AB-IOSL AB-11D AB-11 S AB-12BR X AB-12D X AB-12S X AB-12SL X AB-13D AB-13S AB-14D AB-14S AB-15BR AB-15D AB-15S AB-15SL AB-16D AB-16S AB-17D AB-17S AB-18D AB-18S AB-1 BRL AB-1 BR X AB-1D X AB -IS X AB-20D AB-20S AB-21 D AB-21 S AB-2D X AB-2S X AB-3D AB-3 S A13 4D Marshall Steam Station page 1 of 5 December 20, 2017 Wells to be Sampled Sample for Radionuclides X Regional Office Notes �......�... _ A134S AB-4SL AB-5BR X AB-5D X AB-5S X AB-6BRL AB-6BRA Note: AB-6BR has been abandoned and thus removed from the IMP. A13-613RA was installed as replacement well. AB-6D AB-6S AB-7D AB-7S AB-$D AB -SS AB-9BR AB-9D AB-9S AL-1 BR X AL-1 D AL -IS AL-2B R AL-2BRLL AL-2BRL J AL-2D -- AL-2S AL-3BR AL-3D AL-3 S AB-4BRL AL-4BR _ AL4D BG-1 BRA x Note: BG-1 BR has been abandoned and thus removed from the IMP. BG-1 BRA was installed as replacement well. BG-ID X BG-1 S X BG-2BR X BG-25 X BG-3BR X Marshall Steam Station Page 2 of 5 December 20, 2017 Wells to be Sampled Sample for Radionuclides , Regional Office Notes X X BG-3D BG-3 S X - GWA-1 BR X GWA-1 D X GWA-1 S X GWA-2DA Note: GWA-21) has been abandoned and thus removed from the IMP. GWA-2DA was installed as replacement well. GWA-2S GWA-3D GWA-3S GWA-4D GWA-4S GWA-5D GWA-5S GWA-6D X GWA-6S X GWA-7D GWA-7S GWA-8D GWA-8S GWA-9BR 1 GWA-lOD GWA-IOS GWA-11BR X _ GWA-11D X GWA-11 S X GWA-12BR X Sample to be analyzed for total boron and sulfate only. ` GWA-12D GWA-12S X GWA-13DA Sample to be analyzed for total boron and sulfate only. GWA-13S GWA-14D GWA-14S GWA-15S X MS-8 T - MS-10 X MS-11 Marshall Steam Station Page 3 of 5 December 20, 2017 Wells to be Sampled Sample for Radionuclides X Regional Office Notes MS-13 MW-1 MW-lOD _ x MW-10S X ~ry MW-l1D u� MW-11S MW-12D MW-12S _ MW-13D MW-13S MW-14BR X MW-14D x MW-14S x MW-2 MW-3 MW-4 X MW-4D X M W-5 M W-6D X MW-6S X MW-7 Water level only MW-7D X MW-7S X MW-81) X MW-8S X M W-9D X —._��-- MW-9S X 013-1 (Dry Ash Basin) OB-1 (Dry Ash Landfill) Water level only Marshall Steam Station Page 4 of 5 December 20, 2017 Minimum Parameters to be Analyzed Aluminum T Boron Copper Mercury_Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Marshall Steam Station Page 5 of 5 December 20, 2017 Revised Mavo Steam Electric Plant Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides X Regional Office Notes ABMW-1 X ABMW-2 ABMW-2BR ABMW-2BRL ABMW-3 ABMW-3S ABMW-4 X ABMW-4BR ABMW-4D BG-1 X BG-2 X CW-1 CW-1 D CW-2 X CW-2D X CW-3 CW-4 CW-5 CW-6 X MW-1013R X MW-11BR water level only MW-12D X MW-12S X MW-13BR MW-14BR MW-15BR water level only MW-16BR X MW-16D X MW-16S _ MW-18D New installation MW-18BR New installation MW-19D New installation MW-19BR New installation MW-2 MW-3 X MW-3BR MW-4 Mayo Steam Electric Plant Pagel of 2 December 20, 2017 MW-5BR MW-8BR MW-9BR water level only MW-9BRL Minimum Parameters to be Analvzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavaient Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium _ Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Mayo Steam Electric Plant Page 2 of 2 December 20, 2017 Revised Riverbend Steam Station Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides X Regional Office Notes AB -ID Measure pH, if still >10, not sample. AB -IS AB-2D AB-2S AB -SD AB-8S BG-1 DA BG-IS BG-2BR BG-2D BG-2S BG-3D BG-3S BG-4BR X BG-4D X BG-4S X BG-5BR BG-5D C-1BRUA C-1 S C-2D C-2S GWA-10BRU Measure pH, if still >10, not sample. GWA-10S GWA-11D GWA-11S GWA-12D X GWA-12S X GWA-13D GWA-13S GWA-14D GWA-14S GWA-15D GWA-15S X GWA-1BRU GWA-I S GWA-20BR Measure pH, if still >10, not sample. Riverbend Steam Station Page] of 3 December 20, 2017 GWA-20DA GWA-20S GWA-21 BR GWA-21 D GWA-21 S GWA-22BR-A GWA-22D GWA-22S x GWA-23BR Measure pH, if still >10, not sample. GWA-23DA GWA-23S GWA-2BR X GWA-2BRU X Measure pH, if still >10, not sample. GWA-2S X GWA-3BR GWA-3D GWA-3S-A GWA4BR Measure pH, if still >10, not sample. GWA-4D GWA-4S GWA-5D GWA-5S GWA-6D x Measure pH, if still >10, not sample. GWA-6S x GWA-7BR GWA-7D GWA-7S GWA-8D X GWA-8S X GWA-9BR X GWA-9D X GWA-9S X MW-l0 X MW-1 i DR MW-11 SR MW-13 MW-14 MW-15 MW-15BR MW-15DA MW-1 D Riverbend Steam Station Page 2 of 3 December 20, 2017 MW-IS MW-2D M W-2S-A MW-3D MW-3S MW-4D MW-4S MW-5D MW-5S MW-6D MW-6S MW-7BRA X MW-7D X MW-7SR X MW-8D MW-81 MW-8S MW-9 X MW-9BRA X MW-9DA X Minimum Parameters to be Analyzed Aluminum Boron Copper --Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Riverbend Steam Station Page 3 of 3 December 20, 2017 Revised Roxboro Steam Electric Plant Interim Monitorin Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides X Regional Office Notes ABMW-1 X, water Ievel only ABMW-1BR X ABMW-2 X water level only ABMW-2BR X ABMW-3 ABMW-3BR ABMW-3BRL ABMW-4 X ABMW-4BR X ABMW-5 X ABMW-5D X ABMW-6 ABMW-6BR ABMW-7 water level only ABMW-7BR ABMW-7BRL BG-I X BG-1BR X BG-1 BRL water level only BG-1BRLR X New installation BG-2BR X New installation, Duke email 12-5-17 well id correction to BG-2BR CW-1 CW-2 X CW-2D X CW-3 CW-3D CW-4 - CW-5 X GMW-10 GMW-1 I GMW-6 X GMW-7 GMW-8 GMW-9 MWA BR MW-2BR Roxboro Steam Electric Plant Page I of 3 December 20, 20I7 MW-3BR X MW-4BR MW-4BRL water level only MW-5BR X MW-5D X MW-6BR X MW-6D X MW-7BR MW-8BR MW-9BR X MW-IOBR X MW-1 1BR X MW-11 D X New installation MW-12BR MW-13BR X MW-14BR X MW-15BR X MW-15D X MW-16BR �- X MW-17BR X MW-18BR X MW-18D X MW-19BRL X M W-2 X MW-20BRL MW-21BRL water level only MW-22BR MW-22D MW-23BR water level only MW-23BRR New installation MW-24BR - MW-25BR MW-26BR MW-27BR New installation MW-28BR New installation MW-29BR New installation MW-30BR New installation MW-3]BR New installation MW-32BR New installation MW-33BR New installation GPMW-1 S New installation Roxboro Steam Electric Plant Page 2 of 3 December 20, 2017 GPMW-1 D New installation GPMW-lBR New installation GPMW-2D New installation GPMW-2BR New installation GPMW-3D New installation GPMW-3BR New installation Minimum Parameters to be Analvzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Roxboro Steam Electric Plant Page 3 of 3 December 20, 2017 Revised L.V. Sutton Energy Complex Interim Monitoring Plan — Groundwater Onlv Wells to be Sampled Sample for Radionuclides X Regional Office Notes AW-lC AW-2C AW-2D AW-3C X AW-4C X AW-5C AW-5D AW-6R-D installed in 1st Qtr. 2017 to replace AW-6 AW-6R-E Installed in 1 st Qtr. 2017 to replace AW-6E AW-7R-D Installed in lst Qtr. 2017 to replace AW-713 AW-08C T� y AW-09C AW-09D MW-05C X T w- MW-05CD X MW-05D X MW-05R-E Replaced MW-5E MW-7C MW-8 X MW;SE X MW-1 1 MW-12R Installed in 1st Qtr. 2017 to replace MW-12 MW-16D MW-19 MW-20 MW-20D MW-2IC M W-22B MW-22C M W-23B M W-23C MW-23D X T MW-23E X MW-24R-B MW-24R-C MW-27B MW-27C X MW-28B MW-28C L.V. Sutton Energy Complex Page 1 of 2 December 20, 2017 MW-31 R-C X Installed in 1 st Qtr. 2017 to replace MW-31 C MW-32C X MW-33C X MW-36C X MW-37B _ X ! MW-37C X MW-37CD X MW-37D X MW-37E X MW-38B MW-38C X MW-38D X MW-39B MW-39C X MW-39D X MW40B MW40C MW40D — MW-4l E - SMW-01C SMW-02C SMW-03C SMW-04C SMW-5C SMW-06C _ w L SMW-06D Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium_ Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids L.V. Sutton Energy Complex Page 2 of 2 December 20, 2017 Revised W. H. Weatherspoon Power Plant Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides (X) Regional Office Notes AW-01 D AW-Ol I AW-01 S AW-02D AW-02S AW-03D AW-03I AW-03S BW-01 B W-02D BW-021 BW-02S x BW-03D X BW-03I X BW-03S X BW4D X Installed October 2017 BW41 X Installed October 2017 BW4S X Installed October 2017 CCR-101-BG CAMA x CW-01 CW-02 CW-03 X MW-01 X M W-02 X MW-03 X MW-04 X M W-05 X MW-06 X MW-07 X MW-33D MW-33I MW-33S MW-41 D MW41I MW-52 X MW-53D MW-53I W. H. Weatherspoon Power Plant Page 1 of 2 December 20, 2017 MW-54D MW-55D X MW-551 X PW-1 (DEP 2) Minimum Parameters to be Analvzed Aluminum Boron Copper Mereug Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids W. H. Weatherspoon Power Plant Page 2 of 2 December 20, 2017 1 01- Water Resources Environmental Quality April 6, 2018 Paul Draovitch Senior Vice President Environmental, Health & Safety Duke Energy 526 South Church Street Mail Code EC3XP Charlotte, North Carolina 28202 Subject: Revised Interim Monitoring Plans for 14 Duke Energy Facilities 2nd Quarter 2018 Dear Mr. Draovitch: ROY COOPER Governor MICHAEL S. REGAN Secretary LINDA CULPEPPER Interim Director The North Carolina Department of Environmental Quality (DEQ) is providing the attached revised Interim Monitoring Plans (IMPs) for the respective coal ash facilities. Per our agreement, DEQ will be providing Duke Energy with updated IMPs quarterly until the individual facility Corrective Action Plans are approved, and Duke Energy will include and begin sampling any newly installed groundwater assessment wells as part of the facility IMP which DEQ will formally include in the subsequent IMPs. The attached IMPs only contain references to groundwater monitoring locations. Sampling at surface water locations that were identified as part of the May 1, 2017 communication from DEQ to Duke Energy regarding revised IMPs at the facilities is expected to continue pending further notice. For clarification, we have also provided the minimum expected groundwater sampling analyte list. The attached revised facility IMPs shall be conducted on a quarterly basis commencing the fourth quarter of calendar year 2017 pursuant to 15A NCAC 02L .0110, until Corrective Action Plans are approved for the individual facilities or as directed otherwise by DEQ. The quarterly sampling events will be conducted in conjunction with planned compliance monitoring sampling events for three quarters during the calendar year, supplemented with an additional sampling event conducted at each facility in order to provide four rounds of monitoring data to evaluate seasonal fluctuations during a year -long timeframe. If sampling an individual groundwater location is problematic, please contact the appropriate Regional Office. Since Duke Energy is in the process of submitting Comprehensive Site Assessments, the requirement for an annual monitoring report submitted by April 30th for each respective coal facility as set forth in the May 1, 2017 letter will be extended to a date in 2018 that will be later defined. •'-->'^Nothtng Compares :,__ State of North Carolina I Environmental Quality I Division of Water Resources Water Quality Regional Operations Section 1636 Mail Service Center I Raleigh, North Carolina 27699-1636 919-707-9129 In order to optimize the groundwater monitoring at each facility, DEQ will be removing the groundwater monitoring condition from the NPDES permits as they are reissued. Duke Energy shall continue to monitor the compliance wells separately under the individual NPDES permits until the NPDES permits are reissued with no groundwater monitoring condition. At that time, the compliance wells shall continue to be monitored per the attached revised IMPS under the authority of 15A NCAC 02L .0110. DEQ is open to consider further optimization of the IMPs following a qualitative and quantitative review of site -specific data. A thorough analysis of spatial and temporal trends related to contaminant distribution that include determination of background conditions and identification of areas impacted by coal. ash residuals must be provided as a decision framework to support improvements to long-term monitoring programs. If you have any questions, please feel free to contact the appropriate Regional Office or Steve Lanter (Central Office) at (919) 807-6444. Sincerely, S. y _ 1 erman, P.G. Division of Water Resources Attachments: Revised Interim Monitoring Plans for the 14 coal ash facilities cc: WQROS Regional Offices WQROS Central File Copy Revised Allen Steam Station Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides (A) Regional Office Notes AB-10D AB-10S AB-11D X AB-12D AB-12S AB-13D X AB-13S X AB-14BR AB-14D AB-1R AB-2 AB-20D AB-20S AB-21 BRL X AB-21D Sample to be analyzed for total boron and sulfate only. AB-21 S X AB-21 SL X AB-22BRL Need to discuss additional assessment potentially needed at this location. AB-22BR AB-22D AB-22S AB-23BRU Sample to be analyzed for total boron and sulfate only. AB-23S Sample to be analyzed for total boron and sulfate onl\ . AB-24BR AB-24D AB-24S AB-24SL AB-25BR Sample to be analyzed for total boron and sulfate only. AB-25BRU Sample to be analyzed for total boron and sulfate only. AB-25 S X AB-25SL X AB-26D AB-26S AB-27BR Allen Steam Station Page 1 of 5 March 29, 2018 Sample for Wells to be Sampled Radionuclides Regional Office Notes (X) AB-27D AB-27S AB-28D AB-28S AB-29D AB-29S AB-29SL AB-2D AB-30D AB-30S AB-31 S AB-32D AB-32S AB-33D X AB-33S X AB-34D AB-34S AB-35BR X AB-35D Sample to be analyzed for total boron and sulfate onl . AB-35S X AB-36D AB-36S AB-37D AB-37S AB-38BR AB-38D AB-38S AB-39D AB-39S AB-4BR X AB-4D X AB-4S X AB-5 AB-6A X AB-6R X AB-9D X AB-9S X BG-lDA X Note: BG-lD has been abandoned thus removed from the IMP. BG-1DA was installed as replacement well. Allen Steam Station Page 2 of 5 March 29, 2018 Sample for Wells to be Sampled Radionuclides t Xf_ Regional Office Notes BG-1 S X BG-2BRA-2 X Note: BG-2BR has been abandoned thus removed from the IMP. BG-2BRA-2 was installed as replacement well. BG-2D X BG-2S X BG-3D X BG-3S X BG-4BR X BG-4D X BG-4S X GWA-14DA Note: GWA-14D has been abandoned thus removed from the IMP. GWA-14DA was installed as replacement well. Monitor pH closely. GWA-14S GWA-15D GWA-15S GWA-16D GWA-16S GWA-17D X GWA-17S X GWA-18D GWA-18S GWA-19D Sample to be analyzed for total boron and sulfate only. GWA-19S GWA-lBR X GWA-1D X GWA-1 S X GWA-21 BR X GWA-21DA X Note: GWA-21D has been abandoned thus removed from the IMP. GWA-21DA was installed as replacement well. _ GWA-21 S X GWA-22D GWA-22S GWA-23D Sample to be analyzed for total boron and sulfate only. GWA-23S X GWA-24BR Allen Steam Station Page 3 of 5 March 29, 2018 Sample for Wells to be Sampled Radionuclides Regional Office Notes (X.) GWA-24D Note: GWA-24S has been abandoned thus removed GWA-24SA from the IMP. GWA-24SA was installed as replacement well. GWA-26D GWA-26S GWA-2D X GWA-2S X Note: GWA-3BR has been abandoned thus removed from the IMP. GWA-3BRA was installed as replacement well. GWA-3BRA X Replacement well appears to have water quality issues (elevated pH). Need to discuss potential replacement. GWA-3D X GWA-3S X Note: GWA-4BR has been abandoned thus removed GWA-4BRA X from the IMP. GWA-4BRA was installed as a replacement well. GWA-4D X GWA-4S X Note: GWA-5BR has been abandoned thus removed from the IMP. GWA-5BRA was installed as replacement well. GWA-5BRA X Need to discuss additional assessment potentially needed at this location. GWA-5D X GWA-5S X Note: GWA-6BR has been abandoned thus removed GWA-6BRA X from the IMP. GWA-6BRA was installed as replacement well. Note: GWA-6D has been abandoned thus removed GWA-6DA X from the IMP. GWA-6DA was installed as replacement well. GWA-6S X GWA-7D X GWA-7S X GWA-8D GWA-8S GWA-9D X GWA-9S X GWA-9BR X Allen Steam Station Page 4 of 5 March 29, 2018 Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Total Vanadium Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Allen Steam Station Page 5 of 5 March 29, 2018 Revised Asheville Steam Electric Plant Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides (x Regional Office Notes ABMW-11BR AMW-03B X AMW-lB X AMW-2A AMW-2B water level only APZ-30 water level only B-1 water level only B-1-A water level only B-2 water level only CB-1 X CB -I BR water level only CB-1BRL water level only CB-lD X water level only CB-8BR X CB-8D CB-9BR X CB-9SL X GW-lBR GW-1D GW-2 X GW-3 X GW-4 X GW-5 X MW-3D X MW-5BR MW-5D MW-8S X MW-10 X MW-11 MW-11D MW-13BR MW-13D MW-14BR MW-15A X MW-15BR water level only MW-15D X MW-16A X Asheville Steam Electric Plant Page 1 of 3 March 29, 2018 MW-16BR X MW-17A X MW-18BR X MW-18BRL X MW-18D X MW-19BR water level only MW-20A MW-21D X MW-22BR X MW-22D X MW-23BR MW-23DL MW-23DU MW-24S X MW-6BR X MW-6D X MW-6S X MW-7BR water level only MW-8BR water level only MW-9BR X MW-9D X MW-9S X P-102 water level only P-103 PZ-17D X PZ-17S X PZ-19 X PZ-22 X CB-2 CB-3R X CB-4 X CB-4B X CB-5 CB-6 CB-7 CB-8 X CB-9 X GW-1 X CCR-101BR X CCR-102D X CCR-102S X Asheville Steam Electric Plant Page 2 of 3 March 29, 2018 CCR-103BR CCR-103D CCR-104D X CCR-105BR CCR-105D X EXT-01 X EXT-02 AS-5BR Potential pH issues; recommend redevelopment AS-5BRL Potential pH issues; recommend redevelopment MW-15BRL X MW-16BRL X MW-16D MW-17BRL X MW-20BRL X MW-25BR X MW-25BRL X MW-25 S MW-26BRL X MW-26S PZ-17BRL X Minimum Parameters to be Analyzed Aluminum Boron Co er Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Asheville Steam Electric Plant Page 3 of 3 March 29, 2018 Belews Creek Steam Station Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides x) Regional Office Notes AB-1 BR AB-1D AB-1 S AB-2D AB-2S AB-3D AB-3S AB-4BR Measure all field parameters plus water level, if pH is still high, do not sample for lab analyses AB-4BRD - AB-4D AB-4S AB-4SL Measure all field parameters plus water level, if pH is still high, do not sample for lab analyses AB-4SAP AB-5D AB-5S AB-5SL AB-6D AB-6S AB-6SL AB-7D AB-7S AB-8D AB-8S AB-8SL AB-9BR AB-913RD Measure all field parameters plus water level, if pH is still high, do not sample for lab analyses AB-9D AB-9S BG-1 D Measure water level if not dry; collect all filed parameters if possible; if there is some water but not enough water for all samples, please collect samples for boron, sulfate, chloride, TDS only. _ BG-1 S X BG-2BRA BG-2D X BG-2S X Belews Creek Steam Station Page 1 of 4 March 29, 2018 BG-3D BG-3S GWA-10DA GWA-10S GWA-11D GWA-11 S GWA-12BR GWA-12D GWA-12S GWA-16BR Measure all field parameters plus water level, if pH is still high, do not sample for lab analyses... GWA-16DA GWA-16S GWA-17D GWA-17S GWA-18D GWA-18SA GWA-19BR GWA-19D GWA-19SA GWA-lBR X Measure all field parameters plus water level, if pH is still high, do not sample for lab analyses GWA-lD X GWA-1 S X GWA-20BR GWA-20D GWA-20SA GWA-21D GWA-21 S GWA-22D GWA-22S GWA-23D GWA-23S GWA-24BR GWA-24D X GWA-24S X Measure water level if not dry; collect all filed parameters if possible; if there is some water but not enough water for all samples, please collect samples for boron, sulfate, chloride, TDS only. GWA-25BR X GWA-26BR X GWA-26D X GWA-26S X Belews Creek Steam Station Page 2 of 4 March 29, 2018 GWA-27BR GWA-27D GWA-27S GWA-2D GWA-2S GWA-30D X Measure all field parameters plus water level; if pH is still high, do not sample for_lab analyses GWA-30S X GWA-31D GWA-31 S GWA-32D GWA-32S GWA-3D GWA-3S Measure water level if not dry; collect all filed parameters if possible; if there is some water but not enough water for all samples, please collect samples for boron, sulfate, chloride, TDS only. GWA-6D X GWA-6S X GWA-7D X GWA-7SA X GWA-8D X GWA-8S X GWA-9BR GWA-9D GWA-9S MW-104BR Measure all field parameters plus water level, if pH is still high, do not sample for lab analyses MW-104D MW-104S MW-200BR X MW-200D X MW-200S X MW-201 BR MW-201D MW-202BR MW-202D MW-202S MW-203BR MW-203D MW-203 S MW-204D MW-204S Belews Creek Steam Station Page 3 of 4 March 29, 2018 MW-3 X EX-OB-1 EX-OB-2 Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Belews Creek Steam Station Page 4 of 4 March 29, 2018 Revised Buck Combined Cr cle Station Interim Monitorina Plan — Groundwater Onh Wells to be Sampled Sample for Radionuclides X Regional Office Notes AB -ID AB-1 OBR AB-1 OBRL AB-1 OD AB-10S AB-2BR X Sample to be analyzed for total boron and sulfate onlN . AB-2D X AB-2S X AB-2SL X AB-3D AB-3 S AB4BRL Water quality continues to be an issue (elevated pH). Need to discuss potential replacement. AB-4BRU AB-4S AB-4SL AB-5BRU X Volume has been insufficient to collect sample since 2015. Continue to monitor water level during each sampling event and if volume is sufficient for sampling then collect the sample accordingly. AB-5 S X AB-5SL X AB-6BRU AB-7BRU AB-7S AB-8BRUA Note: AB-8BRU has been abandoned thus removed from the IMP. AB-8BRUA was installed as replacement well. AB-8S AB-9BRA X Note: AB-9BR has been abandoned thus removed from the IMP. AB-9BRA was installed as replacement well. Monitor pH closely. AB-9BRUA X Note: AB-9BRU has been abandoned thus removed from the IMP. AB-9BRUA was installed as replacement well. AB-9S X AS-lD AS -IS Buck Combined Cycle Station Page 1 of 4 Mach 29, 2018 Wells to be Sampled Sample for Radionuclides Regional Office Notes AS-2D AS-3D AS-3 S BG-1BRA X Note: BG-1BR has been abandoned thus removed from the IMP. BG-1BRA was installed as replacement well. BG-1 S X BG-lDA X Note: BG-1D has been abandoned thus removed from the IMP. BG-lDA was installed as replacement well. Water quality still an issue (appears to be grout contaminated). Need to discuss potential replacement. BG-2D X BG-2S X BG-3BRU X BG-3 S X GWA-1 OD GWA-10S GWA-11D GWA-11 S GWA-12BRU X GWA-12S X GWA-13D GWA-13SR GWA-14BR X GWA-14D X Sample to be analyzed for total boron and sulfate only. GWA-14S X GWA-15BR X GWA-15D X GWA-15S X GWA-16BR X GWA-16D X GWA-16S X GWA-17S GWA-18DA X Note: GWA-1.81) has been abandoned thus removed from the IMP. GWA-18DA was installed as replacement well. Need to discuss possible additional assessment in this location sulfate/TDS . GWA-18S X Buck Combined Cycle Station Page 2 of 4 Mach 29, 2018 Wells to be Sampled Sample for Radionuclides Regional Office Notes GWA-19D X GWA-19S X GWA-1D X GWA-1 S X GWA-20D X GWA-20S X GWA-22D X Note: GWA-2BR has been abandoned thus removed from the IMP. GWA-2BRA was installed as re placement well. GWA-2BRA X GWA-2BRU X GWA-2S X GWA-3BR X GWA-3BRU X GWA-3 S X GWA-4D X GWA-4S X GWA-5BRU X GWA-5S X GWA-6BR X GWA-6BRL X GWA-6BRU X GWA-6S X Volume has been insufficient to collect sample since 2016. Continue to monitor water level during each sampling event and if volume is sufficient for samplingsamplLng then collect the sample accordingly. GWA-7D X GWA-7S X GWA-8D GWA-9BRA X Note: GWA-9BR has been abandoned thus removed from the IMP. GWA-9BRA was installed as replacement well. GWA-9D X GWA-9S X MW-10D MW-11BR X MW-11BRL X MW-11D X MW-1 l S X MW-12D MW-12S MW-13D Buck Combined Cycle Station Page 3 of 4 Mach 29, 2018 Wells to be Sampled Sample for Radionuclides X Regional Office Notes MW-ID MW-IS MW-3D X MW-3S X MW-4D MW-4S MW-5D MW-5S MW-6BR X MW-6D X MW-6S X MW-7D MW-7S MW-8BRA X Note: MW-8BR has been abandoned thus removed from the IMP. MW-8BRA was installed as re )lacement well. MW-8D X MW-8S X MW-9D X MW-9S X Minimum Parameters to be Analvzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Ma neesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Buck Combined Cycle Station Page 4 of 4 Mach 29, 2018 Revised Cape Fear Steam Electric Plant Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides (X Regional Office Notes ABMW-1 X ABMW-1BR X ABMW-1 S X ABMW-2SL ABMW-2SU ABMW-3 X ABMW-3BR ABMW-3SR X ABMW-4 X ABMW-4S X ABMW-5BR ABMW-5S BGMW-4 X BGTMW-4 X CMW-01 X CMW-02 CMW-03 X CMW-5R CMW-06 X CMW-07 X CMW-08 X CTMW-01 X CTMW-02 CTMW-07 CTMW-08 X MW-10 X MW-lOBR X MW-10BRL MW-10D MW-11 X MW-12 X MW-12BR MW-13 MW-15BR X MW-15SL X MW-15SU X MW-16BR X Cape Fear Steam Electric Plant Page 1 of 3 March 29, 2018 MW-16S X MW-17BR MW-17SL X MW-17SU X MW-18S X MW-19S MW-20BR MW-20S MW-21 BR MW-21 SL X MW-21 SU X MW-22BR MW-22S MW-23BR MW-23D X MW-23S X MW-24BR X MW-24S X MW-5BRR MW-6BR X MW-9 X MW-9BR X PZ-1 PZ-10 PZ-2 PZ-3D PZ-3S PZ-4 PZ-5 X PZ-6 PZ-7 PZ-8 Cape Fear Steam Electric Plant Page 2 of 3 March 29, 2018 Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Cape Fear Steam Electric Plant Page 3 of 3 March 29, 2018 Revised James E. Rogers Ener?,y Complex Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides (X) Regional Office Notes Redevelop. Sample for boron only. AB-1BR0 AB-lD AB-1S AB-2BRO Redevelop. Sample for boron only. AB-2D AB-2S AB-3BRUA AB-3I AB-3 S X AB-3SLA X AB-4BR AB-4D AB-4S X AB-4SL X AB-5BR AB-5BRU AB-5 S X AB-6BR AB-6D AB-6S X AS-1D AS-1 SB AS-2BR AS-2D X AS-2S X AS-3BRU AS-4D AS-4S AS-5BR AS-5BRU AS-5S AS-6BRA AS-6D AS-6S X AS-7BRA AS-7D AS-7S James E. Rogers Energy Complex Page 1 of 6 March 29, 2018 AS-8D AS-8S BG 1-BRA BG-ID X BG-1 S X BG-21) Water level only CCPMW-lD X CCPMW-1 S X CCPMW-2D Water level only CCPMW-2S Water level only CCPMW-3D Water level only CCPMW-3S Water level only CCPMW-4 Water level only CCPMW-5 Water level only CCPMW-6D Water level only CCPMW-6S Water level only CCPTW-lD Water level only CCPTW-1 S Water level only CCPTW-2 Water level only CLMW-1 X CLMW-2 CLMW-3D X CLMW-3S X CLMW-5D CLMW-5S CLMW-6 CLP-1 Water level only CLP-2 Water level only CLP-3 Water level only CLP-4 Water level only GWA-1 OD GWA-lOS GWA-11BRU X GWA-11 S X GWA-12BRU GWA-12S GWA-13BR GWA-14BR GWA-14D GWA-14S GWA-1BRU James E. Rogers Energy Complex Page 2 of 6 March 29, 2018 GWA-20BR X GWA-20D X GWA-20S X GWA-21 BR X GWA-21 BRU X GWA-21 S X GWA-22BRU GWA-22S X GWA-23D GWA-24BR GWA-24D GWA-24S GWA-25S GWA-25D Water level only GWA-26S GWA-26D Water level only GWA-27BR X GWA-27D-A X GWA-28BR GWA-28BRU GWA-28S GWA-29BRA GWA-29D X GWA-2BR X GWA-2BRU X GWA-2S X GWA-30BR GWA-30BRU Water level only GWA-30S GWA-31BR-A GWA-31D GWA-32D GWA-32BR Water level only GWA-33BR GWA-33D GWA-33S GWA-34S GWA-35D GWA-35S GWA-36D X GWA-36S X James E. Rogers Energy Complex Page 3 of 6 March 29, 2018 GWA-37D GWA-37S GWA-38D GWA-38S GWA-39S Water level only GWA-3D X GWA-40S Water level only GWA-42S Water level only GWA-43D GWA-43S GWA-44BR GWA-44D GWA-44S GWA-45D Water level only GWA-45 S GWA-46D GWA-47D GWA-48BR GWA-4BR Water level only GWA-4D X GWA-4S X GWA-51D GWA-54D GWA-54BRO GWA-54S GWA-56D GWA-56S GWA-5BRU GWA-5S GWA-6S GWA-6D Water level only MW-10D MW-10S MW-11BRO Redevelop. Sample for boron only. MW-11DA MW-11S X MW-20D MW-20DR MW-21 BR MW-21D MW-22BR James E. Rogers Energy Complex Page 4 of 6 March 29, 2018 MW-22DR MW-23D MW-23DR MW-23S MW-24D X MW-24DR X MW-25DR MW-2D-A MW-30D X MW-30DA X MW-30S X MW-32BR X MW-32D X MW-32S X MW-34S MW-34BRU MW-36BRU MW-36S MW-38BR X MW-38D X MW-38S X MW-40BRU MW-40S MW-42DA MW-42S MW-8D MW-8S X U5-1D U54 S U5-2BR U5-2D X U5-2S-SL-A X U5-4BRA U5-4D U5-4S U5-5BR U5-5D X U5-6D U5-6S U5-8BR U5-8D James E. Rogers Energy Complex Page 5 of 6 March 29, 2018 U5-8S CCR12-S CCR-12D CCR-13D CCR-15D CCR-IB-1 S CCR-IB-ID CCR-IB-3S CCR-IB-3D CCR-U5-4S Sample 1st Quarter 2018 only CCR-U5-4D Sample 1st Quarter 2018 only CCR-7S Sample 1st Quarter 2018 only CCR-7D Sample 1st Quarter 2018 only Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids James E. Rogers Energy Complex Page 6 of 6 March 29, 2018 Dan River Combined Cycle Station Interim Monitorin Plan — Groundwater Onh Wells to be Sampled Sample for Radionuclides lX� Regional Office Notes AB-30BR AB-30D X AB-30S BG-1DA Measure water level if not dry; collect all filed parameters if possible; if there is some water but not enough water for all samples, please collect samples for boron, sulfate, chloride, TDS only. BG-10D X BG-10S X BG-10BR X BG-5D BG-5 S GWA-10D GWA-12D GWA-12S GWA-14D GWA-14S GWA-15D GWA-16D GWA-16S GWA-17D GWA-20D GWA-20S GWA-4D GWA-4S GWA-5BR GWA-5BRD GWA-6D X GWA-6S X GWA-7D GWA-7S GWA-8BR GWA-8D GWA-8S GWA-9D X GWA-9S X MW-11 X Measure water level if not dry; collect all filed parameters ifpossible; if there is some water but not Dan River Combined Cycle Station Page 1 of 2 March 29, 2018 enough water for all samples, please collect samples for boron, sulfate, chloride, TDS only. MW-11D X MW-12 X MW-12D X MW-21D MW-21 S MW-22BR X MW-22D X MW-22S X MW-23BR MW-23D MW-317BR MW-317BRL Minimum Parameters to be AnaLyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Dan River Combined Cycle Station Page 2 of 2 March 29, 2018 Revised H. F. Lee Energy- Complex Interim Monitoring; Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides X Regional Office Notes ABMW-1 ABMW-1 S X AMW-11BC AMW-11 S X AMW-12BC AMW-12S AMW-13BC AMW-13S AMW-14BC AMW-14S AMW-15BC AMW-15S AMW-16BC AMW-17BC AMW-17S AMW-18S X AMW-6RBC AMW-9BC AMW-19S AMW-19BC AMW-20S AMW-20BC AMW-21 S AMW-21BC AMW-22S AMW-22BC AMW-23S AMW-23BC BGMW-10 BGMW-9 BW-1 CCR-100S X CMW-10 CMW-5 CMW-6R CMW-7 CMW-8 H. F. Lee Energy Complex Pagel of 3 March 29, 2018 CTMW-1 CW-1 CW-2 CW-3 CW-4 DMW-1 DMW-2 DMW-3 IABMW-1 IABMW-1 S X IABMW-2S IABMW-3 IABMW-3S X IMW-04BC IMW-05BC IMW-lBC IMW-1 S X IMW-2BC IMW-3BC IMW-3S X IMW-4S X IMW-5S X LLMW-1 LLMW-1 S LLMW-2 LLMW-2S MW-1 MW-2 MW-3 X SMW-3 SMW-4 SMW-5 H. F. Lee Energy Complex Page 2 of 3 March 29, 2018 Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids H. F. Lee Energy Complex Page 3 of 3 March 29, 2018 Revised Marshall Steam Station Interim Monitoring Plan — Groundwater Onlv Wells to be Sampled AB-l0BR Sample for Radionuclides Regional Office Notes AB-10D AB-10S AB-10SL AB-11D AB-11 S AB-12BR X AB-12D X AB-12S X AB-12SL X AB-13D AB-13S AB-14D AB-14S AB-15BR AB-15D AB-15S AB-15SL AB-16D AB-16S AB-17D AB-17S AB-18D AB-18S Need to discuss additional assessment potentially needed at this location. AB-1BRL X AB-1BR X AB-1D X AB-1S X AB-20D AB-20S AB-21 D AB-21 S AB-2D X AB-2S X AB-3D AB-3S Marshall Steam Station Page 1 of 5 March 29, 2018 Wells to be Sampled Sample for Radionuclides ]C Regional Office Notes AB-4D AB-4S AB-4SL AB-5BR X AB-5D X AB-5 S X AB-6BRL AB-6BRA Note: AB-6BR has been abandoned and thus removed from the IMP. AB-6BRA was installed as replacement well. AB-6D AB-6S AB-7D AB-7S AB-8D AB-8S AB-9BR AB-9D AB-9S AL-113R X Monitor closely, boron concentrations are trending upward. AL -ID X AL-1 S X AL-2BR AL-2BRL AL-2BRLL Need to discuss additional assessment potentially needed at this location. AL-2D AL-2S AL-3BR AL-3D AL-3 S AL-4BRL AL-4BR AL-4D BG-1BRA X Note: BG-1BR has been abandoned and thus removed from the IMP. BG-1BRA was installed as re lacement well. BG-ID X BG-1 S X BG-2BR X Marshall Steam Station Page 2 of 5 March 29, 2018 Wells to be Sampled Sample for Radionuclides X Regional Office Notes BG-2S BG-3BR X BG-3D X BG-3S X GWA-1BR X GWA-1D X GWA-1 S X GWA-2DA Note: GWA-21) has been abandoned and thus removed from the IMP. GWA-2DA was installed as replacement well. GWA-2S GWA-3D GWA-3S GWA-4D GWA-4S GWA-5D GWA-5S GWA-6D X GWA-6S X GWA-7D GWA-7S GWA-8D GWA-8S GWA-9BR GWA-10D GWA-10S GWA-11BR X GWA-11D X GWA-11 S X GWA-12BR X GWA-12D Sample to be analyzed for total boron and sulfate only. GWA-12S X GWA-13DA Sample to be analyzed for total boron and sulfate onl% . GWA-13S GWA-14D GWA-14S GWA-15S X MS-8 Marshall Steam Station Page 3 of 5 March 29, 2018 Wells to be Sampled MS-10 MS-11 Sample for Radionuclides[Xl X Regional Office Notes MS-13 MW-1 MW-10D X MW-lOS X MW-11D MW-11 S MW-12D MW-12S MW-13D MW-13S MW-14BR X MW-14D X MW-14S X MW-2 MW-3 MW-4 X MW-4D X MW-5 MW-6D X MW-6S X MW-7 Water level only MW-7D X MW-7S X MW-8D X MW-8S X MW-9D X MW-9S X OB-1 (Dry Ash Basin) OB-1 (Dry Ash Landfill) Water level only Marshall Steam Station Page 4 of 5 March 29, 2018 Minimum Parameters to be Anal zed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Marshall Steam Station Page 5 of 5 March 29, 2018 Revised Mai o Steam Electric Plant Interim Monitoring- Plan — Groundwater Only Sample for Wells to be Sampled Radionuclides X Regional Office Notes ABMW-1 X _ _ ABMW-2 ABMW-2BR ABMW-2BRL ABMW-3 ABMW-3S ABMW-4 X ABMW-4BR ABMW-4D BG-1 X BG-2 X CW-1 CW-lD CW-2 X CW-2D X CW-3 CW-4 CW-5 CW-6 X MW-10BR X MW-11BR water level only MW-12D X MW-12S X MW-13BR MW-14BR MW-15BR water level only MW-16BR X MW-16D X MW-16S MW-18D MW-18BR MW-19D MW-19BR MW-2 MW-3 X MW-3BR MW-4 Mayo Steam Electric Plant Page 1 of 2 March 29, 2018 MW-5BR MW-8BR MW-9BR water level only MW-9BRL Minimum Parameters to be Analyzed Aluminum Boron Co er Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt I Manganese Radium 228 Dissolved Zinc Solids Mayo Steam Electric Plant Page 2 of 2 March 29, 2018 Riverbend Steam Station Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides (X1 Regional Office Notes AB-11) Measure all field parameters plus water level, if pH still high, not sample for lab analyses. AB -IS AB-2D AB-2S AB-8D AB-8S BG-lDA BG-1 S BG-2BR BG-2D BG-2S BG-3D BG-3S BG-4BR X BG-4D X BG-4S X BG-5BR BG-5D GWA-10BRU Field parameters plus water level, if pH still high, not sample for lab analyses. GWA-10S GWA-11D GWA-11 S GWA-12D X GWA-12S X GWA-13D GWA-13S GWA-14D GWA-14S GWA-15D GWA-15S X GWA-1BRU GWA-1 S GWA-20BR GWA-20DA GWA-20S GWA-21BR Riverbend Steam Station Page 1 of 3 March 29, 2018 GWA-21D GWA-21 S GWA-22BR-A X GWA-22D X GWA-22S X GWA-23BR Field parameters plus water level, if pH still high, not sample for lab analyses. GWA-23DA GWA-23S GWA-2BR X GWA-2BRU X GWA-2S X GWA-3BR GWA-3D GWA-3S-A GWA-4BR GWA-4D X GWA-4S X GWA-5D GWA-5S GWA-6D X GWA-6S X GWA-7BR GWA-7D GWA-7S GWA-8D X GWA-8S X GWA-9BR X GWA-9D X GWA-9S X MW-10 X MW-11DR MW-11 SR MW-13 MW-14 X MW-15 MW-15BR MW-15DA MW-1D MW-1 S MW-2D MW-2S-A Riverbend Steam Station Page 2 of 3 March 29, 2018 MW-3D MW-3S MW-4D MW-4S MW-5D MW-5S MW-6D MW-6S MW-7BRA X MW-7D X MW-7SR X MW-8D MW-8I MW-8S MW-9 X MW-9BRA X MW-9DA X OB-1 Water level only OB-2 Water level only Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Riverbend Steam Station Page 3 of 3 March 29, 2018 Revised Roxboro Steam Electric Plant Interim Monitorine Plan — Groundwater Only Wells to be Sampled ABMW-1 ABMW-lBR Sample for Radionuclides X - X Regional Office Notes water level ABMW-2 X water level only ABMW-2BR _ X ABMW-3 ABMW-3BR ABMW-3BRL ABMW-4 X ABMW-4BR X ABMW-5 X ABMW-5D X ABMW-6 ABMW-6BR ABMW-7 water level only ABMW-7BR ABMW-7BRL BG-1 X BG-lBR X BG-1BRL water level only BG-1BRLR X BG-2BR X CW-1 CW-2 X CW-2D X CW-3 CW-3D CW-4 CW-5 X GMW-10 GMW-11 GMW-6 X GMW-7 GMW-8 GMW-9 MW-1BR MW-2BR MW-3BR X Roxboro Steam Electric Plant Page 1 of 3 March 29, 2018 MW-4BR MW-4BRL water level only MW-5BR X MW-5D X MW-6BR X MW-6D X MW-7BR MW-8BR MW-9BR X MW-10BR X MW-11BR X MW-11D X MW-12BR MW-13BR X MW-14BR X MW-15BR X MW-15D X MW-16BR X MW-17BR X MW-18BR X MW-18D X MW-19BRL X MW-2 X MW-20BRL MW-21BRL water level only MW-22BR MW-22D MW-23BR water level only MW-23BRR MW-24BR MW-25BR MW-26BR MW-27BR MW-28BR MW-29BR MW-30BR MW-31BR MW-32BR MW-33BR GPMW-1 S GPMW-lD Roxboro Steam Electric Plant Page 2 of 3 March 29, 2018 GPMW-lBR GPMW-2D GPMW-2BR GPMW-3D GPMW-3BR Minimum Parameters to be Analyzed Aluminum 1 Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Roxboro Steam Electric Plant Page 3 of 3 March 29, 2018 Revised L.V. Sutton Enenry Complex Interim Monitorin Plan — Groundwater Only• Wells to be Sampled Sample for Radionuclides x Regional Office Notes AW-1 C AW-2C AW-2D AW-3C X AW-4C X AW-5C AW-5D AW-6R-D AW-6R-E AW-7R-D AW-08C AW-09C AW-09D MW-05C X MW-05CD X MW-05D X MW-05R-E MW-7C MW-8 X MW-8E X MW-11 MW-12R MW-16D MW-19 MW-20 MW-20D MW-21C MW-22B MW-22C MW-23B MW-23C MW-23D X MW-23E X MW-24R-B MW-24R-C MW-27B MW-27C X MW-28B MW-28C L.V. Sutton Energy Complex Page 1 of 2 March 29, 2018 MW-31R-C X MW-32C X MW-33C X MW-36C X MW-37B X MW-37C X MW-37CD X MW-37D X MW-37E X MW-38B MW-38C X MW-38D X MW-39B MW-39C X MW-39D X MW-40B MW-40C MW-40D MW-41E SMW-01 C SMW-02C SMW-03C SMW-04C SMW-5C SMW-06C SMW-06D Minimum Parameters to be Analvzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids L.V. Sutton Energy Complex Page 2 of 2 March 29, 2018 'Revised W. H. Weatherspoon Power Plant Interim Monitoring Plan — Groundwater OnIN Wells to be Sampled Sample for Radionuclides (g) Regional Office Notes AW-01D AW-01I AW-01 S AW-02D AW-02S AW-03D AW-03I AW-03S BW-01 BW-02S X BW-03D X BW-03I X BW-03S X BW-4D X BW-4I X BW4S X CCR-101-BG CAMA X CW-01 CW-02 CW-03 X MW-01 X MW-02 X MW-03 X MW-04 X MW-05 X MW-06 X MW-07 X MW-33D MW-33I MW-33S MW-41D MW-41I MW-52 X MW-53D MW-53I MW-54D MW-55D X W. H. Weatherspoon Power Plant Page 1 of 2 March 29, 2018 MW-55I i X PW-1 (DEP 2) Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium MaLinesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids W. H. Weatherspoon Power Plant Page 2 of 2 March 29, 2018 s� ti Water Resources Environmental Quality June 29, 2018 Paul Draovitch Senior Vice President Environmental, Health & Safety Duke Energy 526 South Church Street Mail Code EC3XP Charlotte, North Carolina 28202 Subject: Revised Interim Monitoring Plans for 14 Duke Energy Facilities 3rd Quarter 2018 Dear Mr. Draovitch: ROY COOPER Governor MICHAEL S. REGAN Secretary LINDA CULPEPPER Interim Director The North Carolina Department of Environmental Quality (DEQ) is providing the attached revised Interim Monitoring Plans (IMPS) for the respective coal ash facilities. Per our agreement, DEQ will be providing Duke Energy with updated IMPs quarterly until the individual facility Corrective Action Plans are approved, and Duke Energy will include and begin sampling any newly installed groundwater assessment wells as part of the facility IMP which DEQ will formally include in the subsequent IMPs. The attached IMPS only contain references to groundwater monitoring locations. DEQ may elect to require establishment of surface water monitoring program in the future related to the ongoing IMPs or corrective action performance monitoring. The requirement for an annual monitoring report for each respective coal facility as set forth in the May 1, 2017 letter submitted will be due April 30, 2019. The attached revised facility IMPS shall be conducted on a quarterly basis pursuant to 15A NCAC 02L .0110, until Corrective Action Plans are approved for the individual facilities or as directed otherwise by DEQ. The quarterly sampling events will be conducted in conjunction with planned compliance monitoring sampling events for three quarters during the calendar year, supplemented with an additional sampling event conducted at each facility in order to provide four rounds of monitoring data to evaluate seasonal fluctuations during a year -long timeframe. If sampling an individual groundwater location is problematic, please contact the appropriate Regional Office. In order to optimize the groundwater monitoring at each facility, DEQ will be removing the groundwater monitoring condition from the NPDES permits as they are reissued. Duke Energy shall continue to monitor the compliance wells separately under the individual NPDES permits until the NPDES permits are reissued with no groundwater monitoring condition. At that time, the compliance wells shall continue to be monitored per the attached revised IMPs under the authority of 15A NCAC 02L .0110. -r—'--Nothing Compares State of North Carolina I Environmental Quality I Division of Water Resources Water Quality Regional Operations Section 1636 Mail Service Center I Raleigh, North Carolina 27699-1636 919-707-9129 DEQ is open to consider further optimization of the IMPs following a qualitative and quantitative review of site -specific data. A thorough analysis of spatial and temporal trends related to contaminant distribution that include determination of background conditions and identification of areas impacted by coal ash residuals must be provided as a decision framework to support improvements to long-term monitoring programs. If you have any questions, please feel free to contact the appropriate Regional Office or Steve Lanter (Central Office) at (919) 807-6444. Sincerely, Jon Ris aard, Section Chief Animal Feeding Operations and Groundwater Attachments: Revised Interim Monitoring Plans for the 14 coal ash facilities cc: WQROS Regional Offices WQROS Central File Copy Revised Allen Steam Station Interim Monitoring Plan — Groundwater Onh Wells to be Sampled Sample for Radionuclides (X) Regional Office Notes _ _ AB-10D AB-10S AB-11D X AB-12D AB-12S AB-13D X AB-13S X AB-14BR Monitor pH. AB-14D AB-1R AB-2 AB-20D Monitor pH. AB-20S AB-21BRL X Monitor pH. AB-21D Sample to be analyzed for total boron and sulfate only. AB-21 S X AB-21 SL X AB-22BRL Need to discuss possible additional assessment needed at this location... please contact MRO. AB-22BR AB-22D AB-22S AB-23BRU Sample to be analyzed for total boron and sulfate only. AB-23S AB-24BR AB-24D Sample to be analyzed for total boron and sulfate on! . AB-24S AB-24SL AB-25BR Sample to be analyzed for total boron and sulfate only. A13-25BRU Sample to be analyzed for total boron and sulfate only. AB-25S X A113-25SL X Monitor pH. AB-26D AB-26S AB-27BR Monitor boron concentrations due to increasing trend observed. Allen Steam Station Pagel of 5 June 29, 2018 Wells to be Sampled Sample for Radionuclides (X) Regional Office Notes AB-27D — AB-27S AB-28D Monitor pH. Additional development may be necessary. AB-28 S AB-29D Monitor boron concentrations due to increasing trend observed. AB-29S AB-29SL Elevated pH. AB-2D AB-30D AB-30S AB-31 S AB-32D Sample was not collected 3/2/2018. Sample must be collected as indicated in this IMP. If a sample is not collected justification must be provided with data submittal. AB-32S AB-33D X Continues to exhibit water quality issues (elevated H). Please contact MRO to discuss further. AB-33S X AB-34D AB-34S AB-35BR X Monitor chromium concentration. AB-35D Sample to be analyzed for total boron and sulfate only. AB-35S X AB-36D AB-36S AB-37D AB-37S AB-38BR AB-38D AB-38S AB-39D AB-39S AB-4BR X AB-4D X AB-4S X AB-5 AB-6A X AB-6R X Allen Steam Station Page 2 of 5 June 29, 2018 Sample for Wells to be Sampled Radionuclides AB-9D X AB-9S X BG-1DA X Regional Office Notes Note: BG-1D has been abandoned thus removed from the IMP. BG-1DA was installed as replacement well. BG-1 S X BG-213RA-2 X Note: BG-2BR has been abandoned thus removed from the IMP. BG-2BRA-2 was installed as replacement well. Continues to exhibit water quality issues (elevated H). Please contact MRO to discuss further. BG-2D X BG-2S X BG-3D X BG-3S X BG-4BR X BG-4D X BG-4S X GWA-14DA Note: GWA-14D has been abandoned thus removed from the IMP. GWA-14DA was installed as replacement well. Monitor pH. Additional well development may be necess GWA-14S GWA-15D GWA-15S GWA-16D GWA-16S GWA-17D X GWA-17S X GWA-18D GWA-18S GWA-19D Sample to be analyzed for total boron and sulfate only. GWA-19S GWA-1BR X GWA-lD X GWA-1 S X GWA-21BR X Monitor pH. Additional development may be necessary. Allen Steam Station Page 3 of 5 June 29, 2018 Sample for Wells to be Sampled Radionuclides Regional Office Notes (X) Note: GWA-21D has been abandoned thus removed GWA-21DA X from the IMP. GWA-21DA was installed as X replacement well. GWA-21 S GWA-22D GWA-22S GWA-23D Sample to be analyzed for total boron and sulfate only. GWA-23S X GWA-24BR Monitor pH. Additional development may be necessary. GWA-24D Note: GWA-24S has been abandoned thus removed from the IMP. GWA-24SA was installed as GWA-24SA replacement well. Monitor chromium concentration. GWA-26D GWA-26S GWA-2D X GWA-2S X Note: GWA-3BR has been abandoned thus removed from the IMP. GWA-3BRA was installed as GWA-3BRA X replacement well. Well should be replaced ASAP ... please contact MRO to discuss. GWA-3D X GWA-3S X GWA-4BR X Monitor boron concentrations due to increasing trend observed. GWA-4D X GWA-4S X Note: GWA-5BR has been abandoned thus removed from the IMP. GWA-5BRA was installed as GWA-5BRA X replacement well. Need to discuss possible additional assessment in this location sulfate/TDS ... please contact MRO. GWA-5D X GWA-5S X Note: GWA-6BR has been abandoned thus removed GWA-6BRA X from the IMP. GWA-6BRA was installed as replacement well. Allen Steam Station Page 4 of 5 June 29, 2018 Wells to be Sampled GWA-6DA Sample for Radionuclides X Regional Office Notes Note: GWA-61) has been abandoned thus removed from the IMP. GWA-6DA was installed as replacement well. GWA-6S X GWA-7D X GWA-7S X GWA-8D GWA-8S Monitor chromium concentrations. GWA-9BR X GWA-9D X GWA-9S X Minimum Parameters to be Analvzed Aluminum Boron Copper Alkalinity Cadmium Hexavalent Antimony Arsenic Barium Beryllium Chromium Calcium Iron Chloride Chromium Cobalt Lead Manganese Mercury Selenium Molybdenum Sodium Nickel Potassium Radium 226 Radium 228 Strontium Sulfate Sulfide Total Dissolved Solids Thallium Total Organic Carbon Total Combined Uranium Total Suspended Solids Vanadium Zinc Allen Steam Station Page 5 of 5 June 29, 2018 Revised Asheville Steam Electric Plant Interim Monitoring_= Plan — Groundwater Onlv Wells to be Sampled Sample for Radionuclides Regional Office Notes M _ X ABMW-11BR AMW-03B AMW-1B X AMW-2A AMW-2B water level only APZ-30 water level only B-1 water level only B-1-A water level only B-2 water level only CB-1 X CB-lBR water level only CB-1BRL water level only CB-lD X CB-8BR X CB-8D water level only CB-9BR X CB-9SL X GW-1BR GW-lD GW-2 X GW-3 X GW-4 X GW-5 X MW-3D X MW-5BR MW-5D MW-8S X MW-10 X MW-11 MW-11D MW-13BR MW-13D MW-14BR MW-15A X MW-15BR water level only X X MW-15D MW-16A Asheville Steam Electric Plant Page 1 of 3 June 29, 2018 MW-16BR X MW-17A X MW-18BR X MW-18BRL X MW-18D X MW-19BR water level only MW-20A MW-21D X MW-22BR X MW-22D X MW-23BR MW-23DL MW-23DU MW-24S X MW-6BR X MW-6D X MW-6S X MW-7BR water level only MW-8BR water level only MW-9BR X MW-9D X MW-9S X P-102 water level only P-103 PZ-17D X PZ-17S X PZ-19 X PZ-22 X CB-2 CB-3R X CB-4 X CB-4B X CB-5 CB-6 CB-7 CB-8 X CB-9 X GW-1 X CCR-101BR X CCR-102D X CCR-102S X Asheville Steam Electric Plant Page 2 of 3 June 29, 2018 CCR-103BR CCR-103D CCR-104D X CCR-105BR CCR-105D X EXT-01 X EXT-02 AS-5BR Potential pH issues; recommend redevelopment AS-5BRL Potential pH issues; recommend redevelopment MW-15BRL X MW-16BRL X MW-16D MW-17BRL X MW-20BR X MW-25BR X MW-25BRL X MW-25S MW-26BRL X MW-26S PZ-17BRL X Minimum Parameters to be Analyzed Aluminum Boron Copper Mercug Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium nesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Asheville Steam Electric Plant Page 3 of 3 June 29, 2018 Belews Creek Steam Station Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides Regional Office Notes AB-1BR AB -ID AB-1 S AB-2D AB-2S AB-3D AB-3 S AB-413R Measure all field parameters plus water level, if pH is still high, do not sample for lab analyses AB-4BRD AB-4D AB-4S AB-4SL Measure all field parameters plus water level, if pH is still high, do not sample for lab analyses AB-4SAP AB-5D AB-5S AB-5SL AB-6D AB-6S AB-6SL AB-7D AB-7S AB-8D AB-8S AB-8SL AB-9BR AB-913RD Measure all field parameters plus water level, if pH is still high, do not sample for lab analyses AB-9D AB-9S BG-1D BG-1 S X Measure water level if not dry; collect all filed parameters if possible; if there is some water but not enough water for all samples, please collect samples for boron, sulfate, chloride, TDS only. BG-2BRA BG-2D X BG-2S X Belews Creek Steam Station Page 1 of 4 June 29, 2018 BG-3D BG-3S GWA-10DA GWA-lOS GWA-11D GWA-11 S GWA-12BR GWA-12D GWA-12S Measure all field parameters plus water level, if pH is still high, do not sample for lab analyses GWA-16BR GWA-16DA GWA-16S GWA-17D GWA-17S GWA-18D GWA-18SA GWA-19BR GWA-19D GWA-19SA GWA-lBR X Measure all field parameters plus water level, if pH is still high, do not sample for lab analyses GWA-1D X GWA-1 S X GWA-20BR GWA-20D GWA-20SA GWA-21 D GWA-21 S GWA-22D GWA-22S GWA-23D GWA-23S GWA-24BR GWA-24D X GWA-24S X Measure water level if not dry; collect all filed parameters if possible; if there is some water but not enough water for all samples, please collect samples for boron, sulfate, chloride, TDS only. GWA-25BR X GWA-26BR X GWA-26D X GWA-26S X Belews Creek Steam Station Page 2 of 4 June 29, 2018 GWA-27BR GWA-27D GWA-27S GWA-2D GWA-2S GWA-30D X Measure all field parameters plus water level, if pH is still high, do not sample for lab analyses GWA-30S X GWA-31D GWA-31 S GWA-32D GWA-32S GWA-3D GWA-3S Measure water level if not dry; collect all filed parameters if possible; if there is some water but not enough water for all samples, please collect samples for boron, sulfate, chloride, TDS only. GWA-6D X GWA-6S X GWA-7D X GWA-7SA X GWA-8D X GWA-8S X GWA-9BR GWA-9D Measure all field parameters plus water level, if pH is still high, do not sample for lab analyses GWA-9S MW-104BR MW-104D MW-104S MW-200BR MW-200D x MW-200S MW-201 BR MW-201 D MW-202BR MW-202D MW-202S MW-203BR MW-203D MW-203 S MW-204D MW-204S Belews Creek Steam Station Page 3 of 4 June 29, 2018 MW-3 X EX-OB-I EX-OB-2 Minimum Parameters to be Anah•zed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Belews Creek Steam Station Page 4 of 4 June 29, 2018 Revised Buck Combined Cycle Station Interim Monitoring Plan — Groundwater Onlv Wells to be Sampled Sample for Radionuclides M Regional Office Notes AB -ID AB-10BR AB-10BRL Water quality continues to be an issue (elevated pH indicative of grout contamination). Well should be replaced ASAP... please contact MRO to discuss. AB-10D AB-10S AB-2BR X Sample to be analyzed for total boron and sulfate only. AB-2D X AB-2S X AB-2SL X AB-3D AB-3 S AB-4BRL _ Water quality continues to be an issue (elevated pH). Well should be replaced ASAP ... please contact MRO to discuss. AB-4BRU AB-4S AB-4SL AB-5BRU X Volume has been insufficient to collect sample since 2015. Continue to monitor water level during each sampling event and if volume is sufficient for sampling then collect the sample accordingly. AB-5S X AB-5 SL X AB-6BRU AB-7BRU AB-7S AB-8BRU AB-8S AB-9BRA X Note: AB-9BR has been abandoned thus removed from the IMP. AB-9BRA was installed as replacement well. AB-9BRUA X Note: AB-9BRU has been abandoned thus removed from the IMP. AB-9BRUA was installed as replacement well. AB-9S X AS -ID AS-1 S Buck Combined Cycle Station Page 1 of 4 June 29, 2018 Wells to be Sampled Sample for Radionuclides Regional Office Notes AS-2D AS-3D _ AS-3S BG-1BRA X Note: BG-1BR has been abandoned thus removed from the IMP. BG-1BRA was installed as replacement well. Monitor chromium concentration observed. BG-1 S X BG-1DA X Note: BG-lD has been abandoned thus removed from the IMP. BG-1DA was installed as replacement well. Water quality still an issue (appears to be grout contaminated). Well should be replaced ASAP... please contact MRO to discuss. BG-2D X BG-2S X BG-3BRU X BG-3 S X GWA-lOD GWA-10S GWA-11D GWA-11 S GWA-12BRU X GWA-12S X GWA-13D Monitor TDS concentration observed 2/19/18. GWA-13SR GWA-14BR X GWA-14D X Sample to be analyzed for total boron and sulfate onl . GWA-14S X GWA-15BR X GWA-15D X GWA-15S X GWA-16BR X GWA-16D X GWA-16S X GWA-17S GWA-18DA X Note: GWA-18D has been abandoned thus removed from the IMP. GWA-18DA was installed as replacement well. Need to discuss possible additional assessment in this location (sulfate/TDS) ... please contact MRO. Buck Combined Cycle Station Page 2 of 4 June 29, 2018 Wells to be Sampled GWA-18S Sample for Radionuclides (X Regional Office Notes Monitor pH. X GWA-19D X GWA-19S X GWA-1D X GWA-1 S X GWA-20D X GWA-20S X GWA-22D X GWA-2BRA X Note: GWA-2BR has been abandoned thus removed from the IMP. GWA-2BRA was installed as replacement well. GWA-2BRU X GWA-2S X GWA-3BR X GWA-3BRU X GWA-3S X GWA-4D X GWA-4S X GWA-5BRU X. GWA-5S X GWA-6BR X GWA-6BRL X Need to discuss possible additional assessment in this location sulfate/TDS ... please contact MRO. GWA-6BRU X GWA-6S X Volume has been insufficient to collect sample since 2016. Continue to monitor water level during each sampling event and if volume is sufficient for sampling then collect the sample accordin 1 . GWA-7D X GWA-7S X GWA-8D GWA-9BRA X Note: GWA-9BR has been abandoned thus removed from the IMP. GWA-9BRA was installed as replacement well. Need to discuss water quality issues and potential well replacement ASAP... please contact MRO. GWA-9D X GWA-9S X MW-10D MW-11BR X MW-11BRL X Buck Combined Cycle Station Page 3 of 4 June 29, 2018 Wells to be Sampled MW-11D Sample for Radionuclides X Regional Office Notes MW-11 S X MW-12D MW-12S MW-13D MW-lD MW-1S MW-3D X MW-3S X MW-4D MW-4S MW-5D MW-5S MW-6BR X MW-6D X MW-6S X MW-7D MW-7S MW-8BRA X Note: MW-8BR has been abandoned thus removed from the IMP. MW-8BRA was installed as replacement well. Monitor sulfate and TDS due to increasing concentrations. MW-8D X MW-8S X MW-9D X MW-9S X Minimum Parameters to be Analyzed Aluminum Boron Cop2er Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Antimony Calcium Iron Nickel Strontium Total CombinedUranium Arsenic Chloride Lead Potassium Sulfate Total SuspendedSolids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radium 228 Total Dissolved Solids Zinc Buck Combined Cycle Station Page 4 of 4 June 29, 2018 Revised Cape Fear Steam Electric Plant Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides M Regional Office Notes ABMW-1 X ABMW-1BR X ABMW-1 S X ABMW-2SL ABMW-2SU ABMW-3 X ABMW-3BR ABMW-3 SR X ABMW-4 X ABMW-4S X ABMW-5BR ABMW-5S BGMW-4 X BGTMW-4 X CMW-01 X CMW-02 CMW-03 X CMW-5R CMW-06 X CMW-07 X CMW-08 X CTMW-01 X CTMW-02 CTMW-07 CTMW-08 X MW-10 X MW-10BR X MW-l0BRL MW-10D MW-11 X MW-12 X MW-12BR MW-13 MW-15BR X MW-15SL X MW-15SU X MW-16BR X Cape Fear Steam Electric Plant Page 1 of 3 June 29, 2018 MW-16S X MW-17BR MW-17SL X MW-17SU X MW-18S X MW-19S MW-20BR MW-20S MW-21BR MW-21 SL X MW-21 SU X MW-22BR MW-22S MW-23BR MW-23D X MW-23S X MW-24BR X MW-24S X MW-5BRR MW-6BR X MW-9 X MW-9BR X PZ-1 PZ-10 PZ-2 PZ-3D PZ-3 S PZ-4 PZ-5 X PZ-6 PZ-7 PZ-8 Cape Fear Steam Electric Plant Page 2 of 3 June 29, 2018 Minimum Parameters to be Anab zed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Cape Fear Steam Electric Plant Page 3 of 3 June 29, 2018 Revised James E. Rogers Enerzy Complex Interim Monitoring, Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides M Regional Office Notes AB-1BRO AB-1D AB -IS AB-2BRO AB-2D AB-2S AB-3BRUA AB-3I AB-3 S X AB-3 SLA X AB-4BR AB-4D AB-4S X AB-4SL X AB-5BR AB-5BRU AB-5 S X AB-6BR AB-6D AB-6S X AS -ID AS-1 SB AS-2BR AS-2D X AS-2S X AS-3BRU AS-4D AS-4S AS-5BR AS-5BRU AS-5S AS-6BRA AS-6D AS-6S AS-7BRA AS-7D AS-7S X James E. Rogers Energy Complex Page 1 of 6 June 29, 2018 AS-8D AS-8S BG1-BRA BG-1D X BG-1 S X BG-21) Water level only CCPMW-lD X CCPMW-1 S X CCPMW-2D Water level only CCPMW-2S Water level only CCPMW-3D Water level only CCPMW-3S Water level only CCPMW-4 Water level only CCPMW-5 Water level only CCPMW-6D Water level only CCPMW-6S Water level only CCPTW-lD Water level only CCPTW-1 S Water level only CCPTW-2 Water level only CLMW-1 X CLMW-2 CLMW-3D X CLMW-3S X CLMW-5D CLMW-5S CLMW-6 CLP-1 Water level only CLP-2 Water level only CLP-3 Water level only CLP-4 Water level only GWA-1 OD GWA-lOS GWA-11BRU X GWA-11 S X GWA-12BRU GWA-12S GWA-13BR GWA-14BR GWA-14D GWA-14S GWA-1BRU James E. Rogers Energy Complex Page 2 of 6 June 29, 2018 GWA-20BR X GWA-20D X GWA-20S X GWA-21 BR X GWA-21 BRU X GWA-21 S X GWA-22BRU GWA-22S X GWA-23D GWA-24BR GWA-24D GWA-24S GWA-25 S GWA-25D Water level only GWA-26S GWA-26D Water level only GWA-27BR X GWA-27D-A X GWA-28BR GWA-28BRU GWA-28S GWA-29BRA GWA-29D X GWA-2BR X GWA-2BRU X GWA-2S X GWA-30BR GWA-30BRU Water level only GWA-30S GWA-31 BR -A GWA-31D GWA-32D GWA-32BR Water level only GWA-33BR GWA-33D GWA-33S GWA-34S GWA-35D GWA-35S GWA-36D X GWA-36S X James E. Rogers Energy Complex Page 3 of 6 June 29, 2018 GWA-37D GWA-37S GWA-38D GWA-38S GWA-39S Water level only GWA-3D X GWA-40S Water level only GWA-42S Water level only GWA-43D GWA-43S GWA-44BR GWA-44D GWA-44S GWA-45D Water level only GWA-45S GWA-46D GWA-47D GWA-48BR GWA-4BR Water level only GWA-4D X GWA-4S X GWA-51D GWA-54D GWA-54BRO GWA-54S GWA-56D GWA-56S GWA-5BRU GWA-5 S GWA-6S GWA-6D Water level only MW-1 OD MW-10S MW-11 BRO Redevelop. Sample for boron only. MW-11DA MW-11 S X MW-20D MW-20DR MW-21 BR MW-21D MW-22BR James E. Rogers Energy Complex Page 4 of 6 June 29, 2018 MW-22DR MW-23D MW-23DR MW-23S MW-24D X MW-24DR X MW-25DR MW-2D-A MW-30D X MW-30DA X MW-30S X MW-32BR X MW-32D X MW-32S X MW-34S MW-34BRU MW-36BRU MW-36S MW-38BR X MW-38D X MW-38S X MW-40BRU MW-40S MW-42DA MW-42S MW-8D MW-8S X U5-1D U5-1 S U5-2BR U5-2D X U5-2S-SL-A X U5-4BRA U5-4D U5-4S U5-5BR U5-5D X U5-6D U5-6S U5-MR U5-8D James E. Rogers Energy Complex Page 5 of 6 June 29, 2018 U5-8S CCR12-S CCR-12D CCR-13D CCR-15D CCR-IB-1 S CCR-IB-ID CCR-1B-3 S CCR-IB-3D CCR-U5-4S Sample V Quarter 2018 only CCR-U5-4D Sample V Quarter 2018 only CCR-7S CCR-7D AB-3-MA15 Pump test well. AB-3-LA15 Pump test well. AB-4-UA15 Pump test well. AB-4-LA15 Pump test well. CCR-7S CCR-7D CCR-8D CCR-U5-3D CCR-U5-3S Minimum Parameters to be Analyzed Aluminum Boron C er Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids James E. Rogers Energy Complex Page 6 of 6 June 29, 2018 Dan River Combined Cycle Station Interim Monitoring Plan — Groundwater Onl% Wells to be Sampled Sample for Radionuclides Regional Office Notes AB-30BR AB-30D AB-30S BG-1 DA X Measure water level if not dry; collect all filed parameters if possible; if there is some water but not enough water for all samples, please collect samples for boron, sulfate, chloride, TDS only. BG-10D X BG-10S X BG-10BR X BG-5D BG-5S GWA-10D GWA-12D GWA-12S GWA-14D GWA-14S GWA-15D GWA-16D GWA-16S GWA-17D GWA-20D GWA-20S GWA-4D GWA-4S GWA-5BR GWA-SBRD GWA-6D X GWA-6S X GWA-7D GWA-7S GWA-8BR GWA-8D GWA-8S GWA-9D X GWA-9S X MW-11 X Measure water level if not dry; collect all filed parameters ifpossible; if there is some water but Dan River Combined Cycle Station Page 1 of 2 June 29, 2018 not enough water for all samples, please collect samples for boron, sulfate, chloride, TDS only. MW-11D X MW-12 X MW-12D X MW-21D MW-21 S MW-22BR X MW-22D X MW-22S X MW-23BR MW-23D MW-317BR MW-317BRL Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Dan River Combined Cycle Station Page 2 of 2 June 29, 2018 Revised H. F. Lee Energy Complex Interim Monitoring Plan — Groundwater Only Wells to be Sampled ABMW-1 ABMW-1 S Sample for Radionuclides (X) X Regional Office Notes AMW-11BC _ AMW-11S X AMW-12BC AMW-12S AMW-13BC AMW-13S AMW-14BC AMW-14S AMW-15BC AMW-15S AMW-16BC AMW-17BC AMW-17S AMW-18S X AMW-6RBC AMW-9BC AMW-19S AMW-19BC AMW-20S AMW-20BC AMW-21 S AMW-21BC AMW-22S AMW-22BC AMW-23 S AMW-23BC BGMW-10 BGMW-9 BW-1 CCR-100S X CMW-10 CMW-5 CMW-6R CMW-7 CMW-8 H. F. Lee Energy Complex Page 1 of 3 June 29, 2018 CTMW-1 CW-1 CW-2 CW-3 CW-4 DMW-1 DMW-2 DMW-3 IABMW-1 IABMW-1 S X IABMW-2S IABMW-3 IA 3MW-3 S X IMW-04BC IMW-05BC IMW-1BC IMW-1S X IMW-2BC IMW-3BC IMW-3S X IMW-4S X IMW-5S X LLMW-1 LLMW-1 S LLMW-2 LLMW-2S MW-1 MW-2 MW-3 X SMW-3 SMW-4 SMW-5 H. F. Lee Energy Complex Page 2 of 3 June 29, 2018 Minimum Parameters to be Analyzed Aluminum Boron Co er Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids H. F. Lee Energy Complex Page 3 of 3 June 29, 2018 Revised Marshall Steam Station Interim Monitorin Plan — Groundwater Onl Sample for Wells to be Sampled Radionuclides Regional Office Notes AB-10BR AB-10D AB-10S AB-10SL AB-1 ID AB-11 S AB-12BR X AB-12D X AB-12S X AB-12SL X AB-13D AB-13S AB-14D Increasing trend in boron concentrations observed. AB-14S AB-15BR AB-15D AB-15S AB-15SL Increasing trend in boron and TDS concentrations observed. AB-16D AB-16S AB-17D AB-17S AB-18D Need to discuss possible additional assessment in this location (increasing boron concentrations) ... please contact MRO. AB-18S �. AB-1BRL X AB-lBR X Increasing trend in boron concentrations observed. AB-lD X Increasing trend in boron concentrations observed. AB -IS X AB-20D AB-20S AB-21 D AB-21 S Increasing trend in boron, chloride and arsenic concentrations observed. AB-21) X Monitor boron concentrations. AB-2S X Marshall Steam Station Page 1 of 5 June 29, 2018 Sample for Wells to be Sampled Radionuclides Regional Office Notes X _ AB-3D AB-3S Increasing trend in observed COI concentrations. AB-4D AB-4S AB-4SL AB-5BR X Monitor TDS concentrations due to observed increasing trend. AB-5D X Increasing trend in boron and thallium AB-5S X concentrations observed. Are there other site activities that are contributing or has historically contributed to the COIs observed at this location? AB-6BRL Monitor sulfate concentrations. Note: AB-6BR has been abandoned and thus removed from the IMP. AB-6BRA was installed as replacement well. AB-6BRA Water quality remains an issue (elevated pH). Boron has doubled since last sampling event. Recommend additional well development prior to next sampling event and we will reevaluate the next round of sampling results. AB-6D AB-6S AB-7D AB-7S AB-8D AB-8S AB-9BR AB-9D AB-9S AL-lBR X Monitor closely, boron concentrations are trending upward near 2L standard. AL-11) X Increasing trend in boron concentrations observed. AL-1 S X Increasing trend in boron concentrations observed. AL-2BR Increasing trend in boron concentrations observed. AL-2BRL Increasing trend in boron concentrations observed. Need to discuss possible additional assessment in AL-2BRLL this location (increasing boron concentrations) ... please contact MRO. Marshall Steam Station Page 2 of 5 June 29, 2018 Sample for Wells to be Sampled Radionuclides Regional Office Notes X Increasing trend in boron, TDS and selenium AL-21) concentrations observed. Increasing trend in boron, TDS and chromium AL-2S concentrations observed. Water quality issues remain (elevated pH). Please AL-3BR contact MRO to discuss possible well replacement. AL-31) Increasing trend in boron concentrations observed. AL-3S Monitor pH. Recommend additional well AL-4BRL development prior to next sampling event and we will reevaluate the next round of sampling results. Increasing trend in boron and TDS concentrations AL-4BR observed. Increasing trend in boron and TDS concentrations AL-41) observed. Note: BG-lBR has been abandoned and thus BG-1BRA X removed from the IMP. BG-1BRA was installed as replacement well. BG-lD X BG-1 S X BG-2BR X BG-2S X BG-3BR X BG-3D X BG-3S X GWA-lBR X GWA-1D X GWA-1 S X Note: GWA-21) has been abandoned and thus removed from the IMP. GWA-2DA was installed as replacement well. GWA-2DA Well continues to exhibit elevated pH (likely grout contamination). Well should be replaced ASAP. GWA-2S GWA-3D GWA-3 S GWA-4D GWA-4S GWA-5D GWA-5S _ GWA-6D X X GWA-6S Marshall Steam Station Page 3 of 5 June 29, 2018 Wells to be Sampled GWA-7D GWA-7S GWA-8D GWA-8S GWA-9BR GWA-1 OD GWA-10S GWA-11BR GWA-11 D GWA-11 S GWA-12BR GWA-12D GWA-12S GWA-13DA GWA-13S GWA-14D GWA-14S GWA-15S MS-8 MS-10 MS-11 MS-13 MW-1 MW-10D MW-10S MW-11D MW-1 l S MW-12D MW-12S MW-13D MW-13S MW-14BR MW-14D MW-14S MW-2 MW-3 MW-4 Sample for Radionuclides X X X X X 94 Regional Office Notes trend in boron concentrations observed. Sample to be analyzed for total boron and sulfate Sample to be analyzed for total boron and sulfate only. Marshall Steam Station Page 4 of 5 June 29, 2018 Wells to be Sampled MW-4D Sample for Radionuclides (X ) X Regional Office Notes MW-5 MW-6D X Increasing trend in boron concentrations observed. MW-6S X MW-7 Water level only MW-7D X MW-7S X MW-8D X MW-8S X MW-9D X MW-9S X OB-1 (Dry Ash Basin) 013-1 (Dry Ash Landfill) Water level only Minimum Parameters to be Anal► zed Aluminum Boron Copper Mercury Molybdenum Selenium Sodium Thallium Total Organic Alkalinity Cadmium Hexavalent Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Vanadium Barium Chromium Maenesium Radium 226 Sulfide Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Marshall Steam Station Page 5 of 5 June 29, 2018 Revised Mayo Steam Electric Plant Interim Monitoring Plan — Groundwater Only Sample for Wells to be Sampled Radionuclides (X) Regional Office Notes ABMW-1 X ABMW-2 ABMW-2BR ABMW-2BRL ABMW-3 ABMW-3S ABMW-4 X ABMW-4BR ABMW-4D BG-1 X BG-2 X CW-1 CW-lD CW-2 X CW-2D X CW-3 CW-4 CW-5 CW-6 X MW-10BR X MW-11BR water level only MW-12D X MW-12S X MW-13BR MW-14BR MW-15BR water level only MW-16BR X MW-16D X MW-16S MW-18D MW-18BR MW-19D MW-19BR MW-2 MW-3 X MW-3BR MW-4 Mayo Steam Electric Plant Page 1 of 2 June 29, 2018 MW-5BR MW-8BR MW-9BR water level only MW-9BRL Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Mayo Steam Electric Plant Page 2 of 2 June 29, 2018 Riverbend Steam Station Interim Monitoring- Plan — Groundwater OWN - Wells to be Sampled Sample for Radionuclides (X) Regional Office Notes AB-11) Measure all field parameters plus water level, if pH still high, not sample for lab analyses. AB-1 S Not sample. Please evaluate whether the well needs to be redeveloped or replaced.. AB-2D AB-2S AB-8D AB-8S BG-1DA BG-1 S BG-2BR BG-2D BG-2S BG-3D BG-3S BG-4BR X Not Sample. Please evaluate whether this well should be replaced because the well has not been sampled since 5/23/2017 due to high pH BG-4D X BG-4S BG-5BR X BG-5D GWA-10BRU Field parameters plus water level, if pH still high, not sample for lab analyses. GWA-10S GWA-11D GWA-11 S GWA-12D X GWA-12S X GWA-13D GWA-13S GWA-14D GWA-14S GWA-15D GWA-15S X GWA-1BRU GWA-1 S GWA-20BR GWA-20DA Riverbend Steam Station Pagel of 3 June 29, 2018 GWA-20S GWA-21BR GWA-21 D GWA-21 S GWA-22BR-A X GWA-22D X GWA-22S X GWA-23BR Not Sample if pH is still high, but. please evaluate whether this well should be replaced. GWA-23DA GWA-23 S GWA-2BR X GWA-2BRU X GWA-2S X GWA-3BR GWA-3D GWA-3 SA GWA-4BR GWA-4D X GWA-4S X GWA-5D GWA-5S GWA-6D X GWA-6S X GWA-7BR GWA-7D GWA-7S GWA-8D X GWA-8S X GWA-9BR N GWA-9D X GWA-9S X MW-10 X MW-11DR MW-11 SR MW-13 MW-14 X MW-15 MW-15BR MW-15DA MW-1D MW-1S Riverbend Steam Station Page 2 of 3 June 29, 2018 MW-2D MW-2SA MW-3D MW-3S MW-4D MW-4S MW-5D MW-5S MW-6D MW-6S MW-7BRA X MW-7D X MW-7SR X MW-8D MW-8I MW-8S MW-9 X MW-9BRA X MW-9DA X OB-1 Water level only OB-2 Water level only Minimum Parameters to be Analyzed Aluminum Boron CTper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Riverbend Steam Station Page 3 of 3 June 29, 2018 Revised Roxboro Steam Electric Plant Interim Monitoring; Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides M Regional Office Notes water level only ABMW-1 X ABMW-1BR X ABMW-2 X water level only ABMW-2BR X ABMW-3 ABMW-3BR ABMW-3BRL ABMW-4 X ABMW-4BR X ABMW-5 X ABMW-5D X ABMW-6 ABMW-6BR ABMW-7 water level only ABMW-7BR ABMW-7BRL BG-1 X BG-lBR X BG-1BRL water level only BG-1 BRLR X BG-2BR X CW-1 CW-2 X CW-2D X CW-3 CW-3D CW-4 CW-5 X GMW-10 GMW-11 GMW-6 X GMW-7 GMW-8 GMW-9 MW-1BR MW-2BR MW-3BR X Roxboro Steam Electric Plant Page 1 of 3 June 29, 2018 MW-4BR MW-4BRL water level only MW-5BR X MW-5D X MW-6BR X MW-6D X MW-7BR MW-8BR MW-9BR X MW-IOBR X MW-11BR X MW-11D X MW-12BR MW-13BR X MW-14BR X MW-15BR X MW-15D X MW-16BR X MW-17BR X MW-18BR X MW-18D X MW-19BRL X MW-2 X MW-20BRL MW-21BRL water level only MW-22BR MW-22D MW-23BR water level only MW-23BRR MW-24BR MW-25BR MW-26BR MW-27BR MW-28BR MW-29BR MW-30BR MW-31 BR MW-32BR MW-33BR GPMW-1 S GPMW-ID Roxboro Steam Electric Plant Page 2 of 3 June 29, 2018 GPMW-1BR GPMW-2D GPMW-2BR GPMW-3D GPMW-3BR Minimum Parameters to be Analyzed Aluminum Boron Copper Mercu Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium May Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Roxboro Steam Electric Plant Page 3 of 3 June 29, 2018 Revised L.V. Sutton Enerly Complex Interim Monitorin Plan — Groundwater On1F Wells to be Sampled Sample for Radionuclides M Regional Office Notes AW-lC AW-2C AW-2D AW-3C X AW-4C X AW-5C AW-5D AW-6R-D AW-6R-E AW-7R-D AW-08C AW-09C AW-09D MW-05C X MW-05CD X MW-05D X MW-05R-E MW-7C MW-8 X MW-8B X MW-8D X MW-8E X MW-11 MW-12R MW-16D MW-19 MW-20 MW-20D MW-21C MW-22B MW-22C MW-23B MW-23C MW-23D X MW-23E X MW-24R-B MW-24R-C MW-27B MW-27C X L.V. Sutton Energy Complex Page 1 of 2 June 29, 2018 MW-28B MW-28C MW-31 R-C X MW-32C X MW-33C X MW-36C X MW-37B X MW-37C X MW-37CD X MW-37D X MW-37E X MW-38B MW-38C X MW-38D X MW-39B MW-39C X MW-39D X MW-40B MW-40C MW-40D MW-41B X MW-41C X MW-41D X MW-41E SMW-01 C SMW-02C SMW-03C SMW-04C SMW-5C SMW-06C SMW-06D Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Antimony Calcium Iron Nickel Strontium Total CombinedUranium Arsenic Chloride Lead Potassium Sulfate Total Suspended Solids Barium Chromium Ma nesium Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radium 228 Total Dissolved Zinc Solids L.V. Sutton Energy Complex Page 2 of 2 June 29, 2018 Revised W. H. Weatherspoon Power Plant Interim MonitorinE Plan — Groundwater OnIY Wells to be Sampled Sample for Radionuclides (X) Regional Office Notes AW-01D AW-01I AW-01 S AW-02D AW-02S AW-03D AW-03I AW-03S BW-01 BW-02S X BW-03D X BW-03I X BW-03S X BW-4D X BW-4I X BW4S X CCR-101-BG CAMA X CW-01 CW-02 CW-03 X MW-01 X MW-02 X MW-03 X MW-04 X MW-05 X MW-06 X MW-07 X MW-33D MW-33I MW-33S MW-41D MW-41I MW-52 X MW-53D MW-53I X MW-54D MW-55D W. H. Weatherspoon Power Plant Page 1 of 2 June 29, 2018 MW-55I X PW-1 (DEP 2) Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids W. H. Weatherspoon Power Plant Page 2 of 2 June 29, 2018 NORTH CAROLINA Roy COOPED EnidewmentalQuality c MICHAEL S. PEGAN 50"W"), LINDA CULPEPPER trtterbn Vir+eaor September 28, 2018 Paul Draovitch Senior Vice President Environmental, Health & Safety Duke Energy 526 South Church Street Mail Code EC3XP Charlotte, North Carolina 28202 Subject: Revised Interim Monitoring Plans for 14 Duke Energy Facilities 4'' Quarter 2018 Dear Mr. Draovitch: The North Carolina Department of Environmental Quality (DEQ) is providing the attached revised Interim Monitoring Plans (IMPs) for the respective coal ash facilities. Per our agreement, DEQ will be providing Duke Energy with updated IMPs quarterly until the individual facility Corrective Action Plans are approved or as directed otherwise by DEQ, and Duke Energy will include and begin sampling any newly installed groundwater assessment wells as part of the facility IMP which DEQ will formally include in the subsequent IMPs. The attached IMPs only contain references to groundwater monitoring locations. DEQ may elect to require establishment of surface water monitoring program in the future related to the ongoing IMPs or corrective action performance monitoring. The requirement for an annual monitoring report for each respective coal facility as set forth in the May 1, 2017 letter submitted will be due April 30, 2019. The attached revised facility IMPs shall be conducted on a quarterly basis pursuant to 15A NCAC 02L .0110, until Corrective Action Plans are approved for the individual facilities or as directed otherwise by DEQ. The quarterly sampling events will be conducted in conjunction with planned compliance monitoring sampling events for three quarters during the calendar year, supplemented with an additional sampling event conducted at each facility in order to provide four rounds of North Carolina Department of Environmental Quality I Division of Water Resources JAFOGW Section 512 North Salisbury Street 11636 Mail Service Center I Raleigh, North Carolina 27699-1636 919.707.9129 monitoring data to evaluate seasonal fluctuations during a year -long timeframe. If sampling an individual groundwater location is problematic, please contact the appropriate Regional Office. In order to optimize the groundwater monitoring at each facility, DEQ will be removing the groundwater monitoring condition from the NPDES permits as they are reissued. Duke Energy shall continue to monitor the compliance wells separately under the individual NPDES permits until the NPDES permits are reissued with no groundwater monitoring condition. At that time, the compliance wells shall continue to be monitored per the attached revised IMPS under the authority of 15A NCAC 02L .0110. DEQ is currently participating in reviews to optimize the groundwater monitoring programs at the Duke Energy coal ash facilities. This review process will result in revisions to the current groundwater monitoring programs until corrective action is implemented at the respective facilities and may streamline the effort related to quarterly IMP changes. If you have any questions, please feel free to contact the appropriate Regional Office or Steve Lanter (Central Office), at (919) 707-3667. Sincerely, r` Jon Ri ard, Section Chief Animal Feeding Operations and Groundwater Attachments: Revised Interim Monitoring Plans for the 14 coal ash facilities cc: WQROS Regional Offices WQROS Central File Copy Revised Allen Steam Station Interim Monitoring Plan — Groundwater Only Sample for Wells to be Sampled Radionuclides Regional Office Notes M AB-10D AB-10S Monitor cobalt and manganese concentrations (increasing). AB-11D X AB-12D AB-12S AB-13D X AB-13S X AB-14BR AB-14D AB-lR AB-2 AB-20D AB-20S AB-21BRL X Sample to be analyzed for total boron and sulfate AB-21D onl . AB-21 S X AB-21 SL X AB-21 SS X Duke Energy proposed installation of bedrock and lower bedrock well to be installed near the AB-10 AB-22BRL location and will be utilized for delineation pui- poses for AB-22 meet' 8/30/2018 . AB-22BR AB-22D AB-22S AB-23BRU Sample to be analyzed for total boron and sulfate only. AB-23S AB-24BR Sample to be analyzed for total boron and sulfate AB-24D only. A13-24S Monitor arsenic and iron concentrations (increasing). AB-24SL Monitor boron and TDS concentrations (increasing and boron close to 2L). Sample to be analyzed for total boron and sulfate AB-25BR onl . AB-25BRU Sample to be analyzed for total boron and sulfate only. Allen Steam Station Page 1 of 5 September 28, 2018 Wells to be Sampled Sample for Radionuclides (XI Regional Office Notes AB-25S X AB-25SS X AB-25SL X AB-26D AB-26S AB-27BR AB-27D AB-27S Monitor iron and manganese concentrations (increasing). AB-28D Elevated pH. Recommend additional development may be beneficial in attempt to improve water quality. AB-28S AB-29D Monitor boron concentrations (increasing). AB-29S AB-29SS AB-29SL Elevated pH. Recommend additional development may be beneficial in attempt to improve water uali . AB-2D AB-30D AB-30S Monitor arsenic concentrations (increasing). AB-31 S AB-32D Monitor boron and sulfate concentrations (increasing). AB-32S AB-33D X Continues to exhibit water quality issues (elevated pH). Pending IMP reduction discussions. AB-33S X AB-33SS X AB-34D AB-34S Monitor sulfate and TDS concentrations increasin ). AB-35BR X AB-35D Sample to be analyzed for total boron and sulfate only. AB-35PWS X AB-35S X AB-36D AB-36S AB-37D AB-37S AB-38BR Allen Steam Station Page 2 of 5 September 28, 2018 Sample for Wells to be Sampled Radionuclides x Regional Office Notes - - AB-38D AB-38S AB-38SS AB-39D AB-39S AB-4BR X AB-4D X AB-4S X AB-5 AB-6A X AB-6R X Monitor total radium concentrations (increasing). AB-9D X Monitor iron due significant increase observed last sampling event 6/1/2018 . AB-9S X BG-lDA X Note: BG-lD has been abandoned thus removed from the IMP. BG-lDA was installed as replacement well. Monitor chromium concentrations. BG-1 S X BG-2BRA2 X Note: BG-2BR has been abandoned thus removed from the IMP. BG-2BRA-2.was installed as replacement well. Continues to exhibit water quality issues (elevated pH). Additional development may be beneficial in attempt to improve water quality. BG-2D X BG-2S X BG-3D X BG-3S X BG-4BR X BG-4D X BG-4S X GWA-14DA Note: GWA-14D has been abandoned thus removed from the IMP. GWA-14DA was installed as replacement well. Elevated pH. Additional development may be beneficial in attempt to improve water quality. GWA-14S GWA-15D GWA-15S Allen Steam. Station Page 3 of 5 September 28, 2018 Wells to be Sampled Sample for Radionuclides ill Regional Office Notes GWA-16D GWA-16S GWA-17D X GWA-17S X GWA-18D GWA-18S GWA-19D Sample to be analyzed for total boron and sulfate only; however, if water quality comes into compliance, a full sample suite (per IMP) should be collected at this location. GWA-19S GWA-1BR X GWA-ID X GWA-1 S X GWA-21BR X Note: GWA-21D has been abandoned thus removed from the IMP. GWA-21DA was installed as replacement well. GWA-21DA X GWA-21 S X GWA-22D GWA-22S GWA-23D Sample to be analyzed for total boron and sulfate only; however, if water quality comes into compliance, a full sample suite (per IMP) should be collected at this location. GWA-23S X GWA-24BR GWA-24D GWA-24SA Note: GWA-24S has been abandoned thus removed from the IMP. GWA-24SA was installed as replacement well. GWA-26D GWA-26S GWA-2D X GWA-2S X GWA-3BRA X Note: GWA-3BR has been abandoned thus removed from the IMP. GWA-3BRA was installed as replacement well. Additional development may be beneficial in . attempt to iml)rove water quality. GWA-3D X GWA-3S X Allen Steam Station Page 4 of 5 September 28, 2018 Sample for Wells to be Sampled Radionuclides GWA-4BR X Regional Office Notes Additional development may be beneficial in attempt to improve water quality. GWA-4D X GWA-4S X GWA-5BRA X Note: GWA-5BR has been abandoned thus removed from the IMP. GWA-5BRA was installed as replacement well. Duke Energy proposed installation of lower bedrock well for vertical delineation pugoses. GWA-5D X GWA-5S X GWA-6BRA X X Note: GWA-6BR has been abandoned thus removed from the IMP. GWA-6BRA was installed as replacement well. Note: GWA-6D has been abandoned thus removed from the IMP. GWA-6DA was installed as replacement well. GWA-6DA GWA-6S X GWA-7D X Monitor TDS concentrations (increasing). GWA-7S X GWA-8D Monitor TDS concentrations (increasing). GWA-8S GWA-9BR X GWA-9D X GWA-9S X Minimum Parameters to be Analvzed Aluminum Boron Copper Mercury Selenium Thallium Total Organic Carbon Alkalinity Cadmium Hexavalent Chromium Molybdenum Sodium Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Allen Steam Station Page 5 of 5 September 28, 2018 Revised Asheville Steam Electric Plant Interim Monitoring Plan — Groundwater OnIN Wells to be Sampled Sample for Radionuclides x Regional Office Notes ABMW-11 BR AMW-1B X AMW-2A AMW-213 water level only AMW-3B X APZ-30 water level only AS-5BR redevelopment needed AS-5BRL redevelopment needed B-1 water level only B-IA water level only B-2 water level only CB-1 X CB-1BR water level only CB-1BRL water level only CB-1D X CB-2 CB-3R X CB-4 X CB-4B X CB-5 CB-6 CB-7 CB-8 X CB-8BR X CB-81) water level only CB-9 X CB-9BR X CB-9SL X CCR-100SL X CCR-100BR X CCR-100BRL X CCR-101BR X CCR-102D X CCR-102S X CCR-103BR CCR-103D CCR-104D X Asheville Steam Electric Plant Page 1 of 4 September 28, 2018 CCR-105BR CCR-105D X EXT-1 X EXT-2 EXT-A GW-1 X GW-1BR GW-lD GW-2 X GW-3 X GW-4 X GW-5 X MW-3D X MW-5BR MW-5D MW-6BR X MW-6D X MW-6S X MW-7BR water level only MW-8BR water level only MW-8S X MW-9BR X MW-9D X MW-9S X MW-10 X MW-11 MW-11D MW-13BR MW-13D MW-14BR MW-15A X MW-15BR water level only MW-15BRL X MW-15D X MW-16A X MW-16BR X MW-16BRL X MW-16BRLL X MW-16D X MW-17A X MW-17BRL X Asheville Steam Electric Plant Page 2 of 4 September 28, 2018 MW-18BR X MW-18BRL X MW-18D X MW-19BR water level only MW-20A MW-20BR X MW-20BRL X MW-21D X MW-22BR X MW-22D X MW-23BR MW-23DL MW-23DU MW-24S X MW-25BR X MW-25BRL X MW-25 S MW-26BR X MW-26BRL X MW-26S P-102 water level only P-103 PZ-17BRL X PZ-17D X PZ-17S X PZ-19 X PZ-22 X Minimum Parameters to be Analvzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Asheville Steam Electric Plant Page 3 of 4 September 28, 2018 Asheville Steam Electric Plant Page 4 of 4 September 28, 2018 Revised Belews Creek Steam Station Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides Regional Office Notes AB-lBR AB-lD AB-1 S AB-2D AB-2S AB-3D AB-3 S AB-4BR Measure all field parameters plus water level, if pH is still high, do not sample for lab analyses AB-4BRD AB-4D AB-4S Measure all field parameters plus water level, if pH is still high, do not sam )le for lab analyses AB-4SL AB-4SAP AB-5D AB-5 S AB-5SL AB-6D AB-6S AB-6SL AB-7D AB-7S AB-8D AB-8S AB-8SL AB-9BR AB-913RD Measure all field parameters plus water level, if pH is still high, do not sam le for lab analyses AB-9D AB-9S BG-1D BG-1 S X Measure water level if not dry; collect all filed parameters if possible; if there is some water but not enough water for all samples, please collect samples for boron, sulfate, chloride, TDS only. BG-2BRA BG-2D X BG-2S X Belews Creek Steam Station Page 1 of 4 September 28, 2018 BG-3D BG-3S GWA-10DA GWA-10S GWA-11D GWA-11 S GWA-12BR GWA-12D GWA-12S GWA-16BR Measure all field parameters plus water level, if pH is still high, do not sample for lab analyses GWA-16DA GWA-16S GWA-17D GWA-17S GWA-18D GWA-18SA GWA-19BR GWA-19D GWA-19SA GWA-lBR X Measure all field parameters plus water level, if pH is still high, do not sample for lab analyses GWA-lD X GWA-1 S X GWA-20BR GWA-20D GWA-20SA GWA-21D GWA-21 S GWA-22D GWA-22S GWA-23D GWA-23 S GWA-24BR GWA-24D X GWA-24S X Measure water level if not dry; collect all filed parameters if possible; if there is some water but not enough water for all samples, please collect samples for boron, sulfate, chloride, TDS only. GWA-25BR X GWA-26BR X GWA-26D X GWA-26S X Belews Creek Steam Station Page 2 of 4 September 28, 2018 GWA-27BR GWA-27D GWA-27S GWA-2D Measure all field parameters plus water level, if pH is still high, do not sample for lab analyses GWA-2S GWA-30D X GWA-30S X GWA-31 D GWA-31 S GWA-32D GWA-32S GWA-3D GWA-3S Measure water level if not dry; collect all filed parameters if possible; if there is some water but not enough water for all samples, please collect samples for boron, sulfate, chloride, TDS only. X X X X X X GWA-6D GWA-6S GWA-7D GWA-7SA GWA-8D GWA-8S GWA-9BR GWA-9D GWA-9S MW-104BRA MW-104D MW-104S MW-200BR MW-200D x MW-200S MW-201BR MW-201 D MW-202BR MW-202D MW-202S MW-203BR MW-203D MW-203 S MW-204D MW-204S Belews Creek Steam Station Page 3 of 4 September 28, 2018 MW-3 X EX-OB-I EX-OB-2 Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Belews Creek Steam Station Page 4 of 4 September 28, 2018 Revised Buck Combined Cycle Station Interim Monitoring Plan — Groundwater Only Wells to be Sample for Sampled Radionuclides Regional Office Notes M AB -ID AB-1 OBR Monitor barium, boron, sulfate and vanadium (increasing). Monitor TDS concentrations (increasing). AB-1 OBRL Water quality continues to be an issue (elevated pH indicative of grout contamination). Recommend additional development prior to next sampling event. AB-1 OD Monitor boron concentrations (increasing). AB-10S Monitor chromium concentrations (significant increase last sampling event). AB-2BR Sample to be analyzed for total boron and sulfate onl . AB-2D X AB-2S X AB-2SL X A13-3D Monitor manganese concentrations (increasing). A13-3S Monitor arsenic, barium, iron, and manganese concentrations (increasing). Water quality continues to be an issue (elevated pH). AB-4BRL Recommend additional development prior to next sampling event. AB-4BRU AB-4S Monitor arsenic and manganese concentrations (increasing). Monitor iron and manganese concentrations AB-4SL (significantly increased during last event compared to historical data). Volume has been insufficient to collect sample since AB-SBRU X 2015. Continue to monitor water level during each sampling event and if volume is sufficient for sampling then collect the sample accordingly. AB-5S X Monitor boron and iron concentrations (increasing). AB-5SL X AB-6BRU AB-7BRU AB-7S MRO is aware of the labeling inconsistency. AB-8BRU Please label the well correctly in the field to avoid future discrepancies and sample accordingly. AB-8S Monitor arsenic and boron concentrations (increasing). Buck Combined Cycle Station Page 1 of 5 September 28, 2018 Wells to be Sample for Sampled Radionuclides Regional Office Notes _ _[_x1 Note: AB-9BR has been abandoned thus removed from the IMP. AB-9BRA was installed as AB-9BRA X replacement well. Monitor total radium concentrations (increasing). Note: AB-9BRU has been abandoned thus removed AB-9BRUA X from the IMP. AB-9BRUA was installed as replacement well. Water quality continues to be an issue (turbidity). AB-9S X Recommend additional development prior to next sampling,event. AS-113 Monitor boron concentrations (increasing). AS-1 S Monitor nickel concentrations (increasing). AS-2D AS-3D AS-3S Monitor iron and manganese concentrations (significantly increased during last sampling, event). Note: BG-1BR has been abandoned thus removed BG-1BRA X from the IMP. BG-1BRA was installed as replacement well. BG-1 S X Note: BG-11) has been abandoned thus removed from the IMP. BG-lDA was installed as replacement well. BG-1DA X Water quality still an issue (appears to be grout contaminated). Recommend additional development prior to next sampling event. BG-2D X BG-2S X BG-3BRU X Monitor total radium concentrations (increasing). BG-3 S X GWA-10D GWA-10S GWA-11D GWA-11 S GWA-12BRU X GWA-12S X GWA-13D Monitor iron and TDS concentrations (increasing). GWA-13SR Volume has been insufficient to collect sample. GWA-14BR X Continue to monitor water level during each sampling event and if volume is sufficient for sampling then collect the sample accordingly. Buck Combined Cycle Station Page 2 of 5 September 28, 2018 Wells to be Sampled Sample for Radionuclides l Regional Office Notes GWA-14D Sample to be analyzed for total boron and sulfate only. GWA-14S X GWA-15BR X Water quality continues to be an issue (elevated pH). Recommend additional development prior to next sampling event. GWA-15D X Monitor total radium concentrations (increasing). GWA-15S X GWA-16BR X GWA-16D X GWA-16S X GWA-17S GWA-18DA X Note: GWA-18D has been abandoned thus removed from the IMP. GWA-18DA was installed as replacement well. Per meeting on 8/30/2018, MRO and Duke Energy agreed to redevelop well prior to next sampling event. We will review results of next sampling event to determine if reinstallation is necessary. GWA-18S X GWA-19D X GWA-19S X GWA-ID X GWA-IS X Monitor chromium concentrations (increasing). GWA-20D X GWA-20S X Monitor cobalt, iron, and manganese concentrations (significantly increased during last sampling event as com ared to historical data . GWA-22D X GWA-2BRA X Note: GWA-2BR has been abandoned thus removed from the I1VIP. GWA-2BRA was installed as replacement well. GWA-2BRU X Monitor total radium concentrations (increasing). GWA-2S X GWA-3BR X GWA-3BRU X Monitor total radium concentrations (increasing). GWA-3S X GWA-4D X GWA-4S X Monitor TDS concentrations (increasing). GWA-SBRU X Monitor boron concentrations (increasing). GWA-5 S X GWA-6BR X Buck Combined Cycle Station Page 3 of 5 September 28, 2018 Wells to be Sample for Sampled Radionuclides Regional Office Notes (X) Monitor sulfate and TDS concentrations (increasing). This location warrants delineation. In meeting on GWA-6BRL X 8/30/2018, MRO and Duke Energy discussed installation of a new bedrock well (closer to the GWA-12 cluster) for purposes of horizontal and vertical delineation. Please update MRO on status. GWA-6BRU X Volume has been insufficient to collect sample since GWA-6S X 2016. Continue to monitor water level during each sampling event and if volume is sufficient for sampling then collect the sample accordingly. GWA-7D X GWA-7S X GWA-8D Note: GWA-9BR has been abandoned thus removed from the IMP. GWA-9BRA was installed as replacement well. GWA-9BRA X Water quality continues to be an issue (elevated pH). Recommend additional development prior to next Sampling event. GWA-9D X Monitor manganese concentrations (increasing). GWA-9S X Monitor manganese concentrations (increasing). MW-10D MW-11BR X MW-11BRL X Monitor manganese concentrations (increasing). Water quality continues to be an issue (turbidity). MW-11D X Recommend additional development prior to next sampling event. MW-1 l S X MW-12D Water quality continues to be an issue (turbidity). MW-12S Recommend additional development prior to next sampling event. MW-13D MW-ID MW-1 S Monitor boron concentrations (increasing). MW-3D X MW-3S X MW-4D Monitor boron concentrations (increasing). MW-4S MW-51) Monitor boron concentrations (increasing). MW-5S Buck Combined Cycle Station Page 4 of 5 September 28, 2018 Wells to be Sample for Sampled Radionuclides Regional Office Notes MW-6BR X MW-6D X MW-6S X Monitor manganese concentrations (increasing). MW-7D MW-7S Note: MW-8BR has been abandoned thus removed from the IMP. MW-8BRA was installed as replacement well. MW-8BRA X Monitor sulfate and TDS concentrations (increasing). Per meeting on 8/30/2018, MRO and Duke Energy agreed to redevelop well prior to next sampling event. We will review results of next sampling event to determine if reinstallation is necess MW-8D X MW-8S X MW-9D X MW-9S X Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Buck Combined Cycle Station Page 5 of 5 September 28, 2018 Revised Cape Fear Steam Electric Plant Interim Monitoring_ Plan — Groundwater Onli Wells to be Sampled Sample for Radionuclides (X Regional Office Notes ABMW-1 X ABMW-lBR X ABMW-1 S X ABMW-2SL ABMW-2SU _ ABMW-3 X ABMW-3BR ABMW-3 SR X ABMW-4 X ABMW-4S X ABMW-5BR ABMW-5S BGMW-4 X BGTMW-4 X CMW-01 X CMW-02 CMW-03 X CMW-5R CMW-06 X CMW-07 X CMW-08 X CTMW-01 X CTMW-02 CTMW-07 CTMW-08 X MW-10 X MW-10BR X MW-10BRL MW-10D MW-11 X MW-12 X MW-12BR MW-13 MW-15BR X MW-15SL X MW-15SU X MW-16BR X Cape Fear Steam Electric Plant Page 1 of 3 September 28, 2018 MW-16S X MW-17BR MW-17SL X MW-17SU X MW-18S X MW-19S MW-20BR MW-20S MW-21BR MW-21 SL X MW-21 SU X MW-22BR MW-22S MW-23BR MW-23D X MW-23S X MW-24BR X MW-24S X MW-5BRR MW-6BR X MW-9 X MW-9BR X PZ-1 PZ-10 PZ-2 PZ-3D PZ-3S PZ-4 PZ-5 X PZ-6 PZ-7 PZ-8 Cape Fear Steam Electric Plant Page 2 of 3 September 28, 2018 Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Ma nesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Cape Fear Steam Electric Plant Page 3 of 3 September 28, 2018 Revised James E. Rogers Energy Complex Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides (X) Regional Office Notes AB-1BROR Replaced AB-1BRO due to casing damage AB -ID AB -IS AB-2BRO AB-2D AB-2S AB-3BRUA AB-3I AB-3 S X AB-3 SLA X AB-4BR AB-4D AB-4S X AB-4SL X AB-5BR AB-5BRU AB-5 S X AB-6BR AB-6D AB-6S X AS-1D AS-1 SB AS-2BR AS-2D X AS-2S X AS-3BRU AS-4D AS-4S AS-5BR AS-5BRU AS-5S AS-6BRA AS-6D AS-6S AS-7BRA AS-7D AS-7S X James E. Rogers Energy Complex Page 1 of 6 September 28, 2018 AS-8D AS-8S BG 1-BRA BG-1D X BG-1 S X BG-2D Water level only CCPMW-1D X CCPMW-1 S X CCPMW-2D Water level only CCPMW-2S Water level only CCPMW-3D Water level only CCPMW-3S Water level only CCPMW-4 Water level only CCPMW-5 Water level only CCPMW-6D Water level only Water level only CCPMW-6S CCPTW-lD Water level only CCPTW-1 S Water level only CCPTW-2 Water level only CLMW-1 X CLMW-2 CLMW-3D X CLMW-3S X CLMW-5D CLMW-5S CLMW-6 CLP-1 Water level only CLP-2 Water level only CLP-3 Water level only CLP-4 Water level only GWA-10D GWA-10S GWA-11BRU X GWA-11 S X GWA-12BRU GWA-12S GWA-13BR GWA-14BR GWA-14D GWA-14S GWA-1BRU James E. Rogers Energy Complex Page 2 of 6 September 28, 2018 GWA-20BR X GWA-20D X GWA-20S X GWA-21 BR X GWA-21 BRU X GWA-21 S X GWA-22BRU GWA-22S X GWA-23D GWA-24BR GWA-24D GWA-24S GWA-25 S GWA-25D Water level only GWA-26S GWA-26D Water level only GWA-27BR X GWA-27D-A X GWA-28BR GWA-28BRU GWA-28S GWA-29BRA GWA-29D X GWA-2BR X GWA-2BRU X GWA-2S X GWA-30BR GWA-30BRU Water level only GWA-30S GWA-31 BR -A GWA-31D GWA-32D GWA-32BR Water level only GWA-33BR GWA-33D GWA-33S GWA-34S GWA-35D GWA-35S GWA-36D X GWA-36S X James E. Rogers Energy Complex Page 3 of 6 September 28, 2018 GWA-37D GWA-37S GWA-38D GWA-38S GWA-39S Water level only GWA-3D X GWA-40S Water level only GWA-42S Water level only GWA-43D GWA-43 S GWA-44BR GWA-44D GWA-44S GWA-45D Water level only GWA-45 S GWA-46D GWA-47D GWA-48BR _ Water level only GWA-4BR GWA-4D X GWA-4S X GWA-51D GWA-54D GWA-54BRO GWA-54S GWA-56D GWA-56S GWA-5BRU GWA-5 S GWA-6S GWA-6D Water level only MW-10D MW-10S MW-11BRO Redevelop. Sample for boron only. MW-11DA MW-11 S X MW-20D MW-20DR MW-21BR MW-21D MW-22BR James E. Rogers Energy Complex Page 4 of 6 September 28, 2018 MW-22DR MW-23D MW-23DR MW-23S MW-24D X MW-24DR X MW-25DR MW-2D-A MW-30D X MW-30DA X MW-30S X MW-32BR X MW-32D X MW-32S X MW-34S MW-34BRU MW-36BRU MW-36S MW-38BR X MW-38D X MW-38S X MW-40BRU MW-40S MW-42DA MW-42S MW-8D MW-8S X U54D U5-1 S U5-2BR U5-2D X U5-2S-SL-A X U5-4BRA U5-4D U5-4S U5-5BR U5-5D X U5-6D U5-6S U5-8BR U5-8D James E. Rogers Energy Complex Page 5 of 6 September 28, 2018 U5-8S CCR12-S CCR-12D CCR-13D CCR-15D CCR-IB-1 S CCR-IB-11) CCR-IB-3S CCR-IB-3D CCR-U5-4S Sample 1" Quarter 2018 only CCR-U5-4D Sample V Quarter 2018 only CCR-7S CCR-7D AB-3-MA15 Pump test well. AB-3-LA15 Pump test well. AB-4-UA15 Pump test well. AB-4-LA15 Pump test well. CCR-7S CCR-7D CCR-8D CCR-U5-3D CCR-U5-3S CCR-U5-4BR AS7I IB-6S IB-6D IB-7S IB-7D Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Iron Nickel Carbon Antimony Calcium Strontium Total Combined Potassium Uranium Arsenic Chloride Lead Sulfate Total Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radium 228 Total Dissolved Zinc Solids James E. Rogers Energy Complex Page 6 of 6 September 28, 2018 Revised Dan River Combined C cle Station Interim Monitoring Plan — Groundwater Only Sample for Wells to be Sampled Radionuclides (X) BG-1 DA X Regional Office Notes _ Measure water level if not dry; collect all filed parameters if possible; if there is some water but not enough water for all samples, please collect samples for boron, sulfate, chloride, TDS only. BG-10D X BG-10S X BG-10BR X BG-5D BG-5S GWA-10D GWA-12D GWA-12S GWA-14D GWA-14S GWA-15D GWA-16D GWA-16S GWA-17D GWA-20D GWA-20S GWA-4D GWA-4S GWA-5BR GWA-SBRD GWA-6D X GWA-6S X GWA-7D GWA-7S GWA-8BR GWA-8D GWA-8S GWA-9D X GWA-9S X MW-12 X MW-12D X MW-21D X MW-21 S MW-22BR Dan River Combined Cycle Station Page 1 of 2 September 28, 2018 MW-22D X MW-22S X MW-23BR MW-23D MW-317BR MW-317BRL Minimum Parameters to be Analvzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Dan River Combined Cycle Station Page 2 of 2 September 28, 2018 Revised H. F. Lee Energv Complex Interim Monitoring Plan — Groundwater Only Wells to be Sample for Sampled Radionuclides M ABMW-1 ABMW-1 S X AMW-11BC AMW-11 S X AMW-12BC AMW-12S AMW-13BC AMW-13S AMW-14BC AMW-14S AMW-15BC AMW-15S AMW-16BC AMW-17BC AMW-17S AMW-18S X AMW-6RBC AMW-9BC AMW-19S AMW-19BC AMW-20S AMW-20BC AMW-21 S AMW-21BC AMW-22S . AMW-22BC AMW-23 S AMW-23BC BGMW-10 BGMW-9 BW-1 CCR-100S X CMW-10 CMW-5 CMW-6R CMW-7 CMW-8 H. F. Lee Energy Complex Page 1 of 3 September 28, 2018 CTMW-1 CW-1 CW-2 CW-3 CW-4 DMW-1 DMW-2 DMW-3 IABMW-1 IABMW-1 S X IABMW-2S IABMW-3 IABMW-3S X IMW-04BC IMW-05BC IMW-1BC IMW-1 S X IMW-2BC IMW-3BC IMW-3S X IMW-4S X IMW-5S X LLMW-1 LLMW-1 S LLMW-2 LLMW-2S MW-1 MW-2 MW-3 X SMW-3 SMW-4 SMW-5 IMW-6S IMW-7S H. F. Lee Energy Complex Page 2 of 3 September 28, 2018 Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Sodium Thallium Total Organic g Carbon Alkalinity y Hexavalent Cadmium Chromium Molybdenum Total Antimony Calcium Iron Nickel Strontium Combined _. Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended + Sulfide Solids Vanadium Barium Chromium Magnesium Radium 226 Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids H. F. Lee Energy Complex Page 3 of 3 September 28, 2018 Revised Marshall Steam Station Interim Monitorin Plan — Groundwater Onl Wells to be Sampled Sample for Radionuclides [ X) Regional Office Notes AB-10BR AB-1 OD AB-10S AB-1 OSL Monitor boron concentrations (increasing). AB=11D AB-11 S AB-12BR X AB-12D X AB-12S X Monitor boron concentrations (increasing). AB-12SL X AB-13D AB-13S AB-14D Monitor boron concentrations (increasing). AB-14DU AB-14S AB-15BR AB-15D AB-15S AB-15SL AB-16D AB-16DU AB-16S AB-17D AB-17S AB-18D Monitor boron, iron, manganese, sulfate, and TDS concentrations (increasing). AB-18DU AB-18S AB-1BRLL X AB-1BRL X Monitor boron and total radium concentrations (increasing). Duke proposed additional well installation for delineation purposes. AB-113R X Monitor boron, iron, manganese, TDS, and total radium concentrations (increasing). AB-lD X Monitor boron, TDS, and total radium . concentrations (increasing). AB-1 S X Monitor total radium concentrations (increasing). Marshall Steam Station Page 1 of 5 September 28, 2018 Sample for Wells to be Sampled Radionuclides Regional Office Notes (X) AB-20D AB-20S _ Monitor boron concentrations (increasing). AB-21 D AB-21 S Monitor arsenic, boron, chloride, and TDS concentrations increasin . AB-2D X Monitor total radium concentrations (increasing). AB-2S X Monitor total radium concentrations (increasing). AB-3D AB-3S AB-4D AB-4S Monitor selenium concentrations (significant increase last event compared to historical data), AB-4SL AB-5BR X Monitor sulfate and TDS concentrations (increasing). AD-5D X AB-5DU X AB-5 S X AB-613RL Monitor TDS concentrations (increasing). Note: AB-6BR has been abandoned and thus removed from the IMP. AB-6BRA was installed as replacement well. AB-6BRA Water quality remains an issue (elevated pH). Recommend additional well development prior to next sampling event. AB-6D AB-6S AB-7D AB-7DU AB-7S AB-8D AB-8DU AB-8S AB-9BR AB-9D AB-9S AL-1BR X Monitor boron and TDS concentrations L7 AL -ID F:i (increasing). Marshall Steam Station Page 2 of 5 September 28, 2018 Wells to be Sampled Sample for Radionuclides Regional Office Notes AL -IS X AL-2BR Monitor boron, chromium, sulfate, and TDS concentrations (increasing). AL-2BRL AL-2BRLL Duke proposed additional well installation for delineation purposes. AL-2D AL-2S AL-3BR Water quality remains an issue (elevated pH). Recommend additional well development prior to next sampling event. AL-3D Monitor boron and chromium concentrations increasin . AL-3 S AL-4BRL Elevated pH. Recommend additional well development prior to next sampling event. AL-4BR Monitor boron, sulfate and TDS concentrations (increasing). AL-4D BG-1BRA X Note: BG-lBR has been abandoned and thus removed from the IMP. BG-1BRA was installed as replacement well. BG-lD X BG-1 S X BG-2BR X BG-2S X BG-3BR X BG-3D X BG-3S X GWA-lBR X GWA-lD X GWA-1 S X GWA-2DA Note: GWA-2D has been abandoned and thus removed from the IMP. GWA-2DA was installed as replacement well. Need to discuss potential replacement. GWA-2S GWA-3D GWA-3 S Marshall Steam Station Page 3 of 5 September 28, 2018 Wells to be Sampled GWA-4D GWA-4S Sample for Radionuclides A) Regional Office Notes GWA-5D GWA-5S GWA-6D X GWA-6S X GWA-7D GWA-7S GWA-8D GWA-8S Monitor chromium concentrations (increasing). GWA-9BR GWA-10D GWA-10S Monitor boron concentrations (slight increase). GWA-11BR X GWA-11D X GWA-11 S X Sample to be analyzed for total boron and sulfate only. Sample to be analyzed for total boron and sulfate only. GWA-12BR X GWA-12D GWA-12S X GWA-13DA GWA-13S GWA-14D GWA-14S GWA-15S X Monitor boron concentrations (increasing). GWA-15D X MS-8 MS-10 X MS-11 MS-13 MW-1 MW-10D X MW-10S X MW-11D MW-1 lS MW-12D MW-12S MW-13D Marshall Steam Station Page 4 of 5 September 28, 2018 Sample for Wells to be Sampled Radionuclides _ x MW-13S MW-14BR X MW-14D X MW-14S X Regional Office Notes Monitor boron and TDS concentrations (increasing). Monitor cobalt concentrations (increasing). Monitor chromium, iron, and TDS concentrations increas' MW-2 MW-3 MW-4 X MW-4D X MW-5 MW-61) X Monitor boron concentrations (increasing). MW-6S X MW-7 Water level only MW-71) X Monitor boron concentrations (increasing). MW-7S X MW-8D X Monitor TDS concentrations (increasing). . MW-8S X Monitor TDS concentrations (increasing). MW-9D X Monitor boron concentrations (increasing). MW-9S X Monitor TDS concentrations (increasing). OB-1 (Dry Ash Basin) Monitor iron concentrations (significant increase). OB-1 (Dry Ash Landfill) Water level only Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Marshall Steam Station Page 5 of 5 September 28, 2018 Revised Ma\ o Steam Electric Plant Interim Monitoring Plan — Groundwater Only Sample for Wells to be Sampled Radionuclides (X) Regional Office Notes ABMW-1 X ABMW-2 ABMW-2BR ABMW-2BRL ABMW-3 ABMW-3S ABMW-4X X Well was replaced due to storm runoff damage. ABMW-4 was abandoned. ABMW-4BR ABMW-4D BG-1 X BG-2 X CW-1 CW-lD CW-2 X CW-2D X CW-3 CW-4 CW-5 CW-6 X MW-l0BR X MW-11BR water level only MW-12D X MW-12S X MW-13BR MW-14BR MW-15BR water level only MW-16BR X MW-16D X MW-16S MW-18D MW-18BR MW-19D MW-19BR MW-2 MW-3 X MW-3BR Mayo Steam Electric Plant Page 1 of 2 September 28, 2018 MW-4 MW-5BR MW-8BR MW-9BR water level only MW-9BRL Minimum Parameters to be Anal► zed Aluminum Boron Copper Meran Selenium Thallium Total Organic Alkalinity Cadmium Hexavalent Molybdenum Sodium Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Mayo Steam Electric Plant Page 2 of 2 September 28, 2018 Revised L.V. Sutton Enerzy Complex Interim Monitorin Plan — Groundwater Onl Sample for Wells to be Sampled Radionuclides (x) Regional Office Notes _ _ AW-IC AW-2C AW-2D AW-3C X AW-4C X AW-5C AW-5D AW-6R-D AW-6R-E AW-7R-D AW-08C AW-09C AW-09D MW-05C X MW-05CD X MW-05D X MW-05R-E MW-7C MW-8 X MW-8B X MW-8D X MW-8E X MW-11 MW-12R MW-16D MW-19 MW-20 MW-20D MW-21C MW-22B MW-22C MW-23B MW-23C MW-23D X MW-23E X MW-24R-B MW-24R-C MW-27B MW-27C X L.V. Sutton Energy Complex Page 1 of 2 September 28, 2018 MW-28B MW-28C MW-31R-C X MW-32C X MW-33C X MW-36C X MW-37B X MW-37C X MW-37CD X MW-37D X MW-37E X MW-38B MW-38C X MW-38D X MW-39B MW-39C X MW-39D X MW-40B MW-40C MW-40D MW-41B X MW-41 C X MW-41D X MW-41 E SMW-01 C SMW-02C SMW-03C SMW-04C SMW-5C SMW-06C SMW-06D Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Nickel Strontium Carbon Total Combined Antimony Calcium Iron Uranium Arsenic Chloride Lead Potassium Sulfate Total Suspended Solids Barium Chromium Magnesium Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radium 228 Total DissolvedSolids Zinc L.V. Sutton Energy Complex Page 2 of 2 September 28, 2018 Revised Riverbend Steam Station Interim Monitoring Plan — Groundwater Only Wells to be Sampled _ AB-1D Sample for Radionuclides (X) Regional Office Notes Measure all field parameters plus water level, if pH still high, not sample for lab analyses. AB -IS Not sample. Please evaluate whether the well needs to be redeveloped or replaced. AB-2D AB-2S AB-8D AB-8S BG-1DA BG-1 S BG-2BR BG-2D BG-2S BG-3D BG-3S BG-4BR X Not Sample. Please evaluate whether this well should be replaced because the well has not been sample since 5/23/2017 due to high pH BG-4D X BG-4S X BG-5BR BG-5D GWA-10BRU Field parameters plus water level, if pH still high, not sample for lab analyses. GWA-10S GWA-11D GWA-11 S GWA-12D X GWA-12S X GWA-13D GWA-13S GWA-14D GWA-14S GWA-15D GWA-15S X GWA-1BRU GWA-1 S GWA-20BR GWA-20DA Riverbend Steam Station Page 1 of 3 September 28, 2018 GWA-20S GWA-21BR GWA-21D GWA-21 S GWA-22BR-A X GWA-22D X GWA-22S X GWA-23BR Not Sample if pH is still high, but. please evaluate whether this well should be replaced. GWA-23DA GWA-23S GWA-2BR X GWA-2BRU X GWA-2S X GWA-3BR GWA-3D GWA-3SA GWA-4BR GWA-4D X GWA-4S X GWA-5D GWA-5S GWA-6D X GWA-6S X GWA-7BR GWA-7D GWA-7S GWA-8D X GWA-8S X GWA-9BR X GWA-9D X GWA-9S X MW-10 X MW-11DR MW-11 SR MW-13 MW-14 X MW-15 MW-15BR MW-15DA MW-ID MW-1 S Riverbend Steam Station Page 2 of 3 September 28, 2018 Minimum Parameters to be Analyzed Aluminum Boron Copper MercuIN Molybdenum I Selenium Sodium Thallium Alkalinity Cadmium Hexavalent Total Organic Chromium i Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Vanadium_ Barium Chromium Magnesium Radium 226 Sulfide Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids Riverbend Steam Station Page 3 of 3 September 28, 2018 Revised Roxboro Steam Electric Plant Interim Monitorin Plan — Groundwater Onl Wells to be Sampled Sample for Radionuclides (X) Regional Office Notes water level only ABMW-1 X ABMW-lBR X X ABMW-2 water level only ABMW-2BR X ABMW-3 ABMW-3BR ABMW-3BRL Abandoned as part of the WW redirect (leachate work) Abandoned as part of the W W redirect (leachate work ABMW-5 X ABMW-5D X ABMW-6 ABMW-6BR ABMW-7 water level only ABMW-7BR ABMW-7BRL BG-1 X BG-lBR X BG-1BRL water level only BG-1BRLR X BG-2BR X CCR-113D Recently installed well for CCR program adds a downgradient data point CCR- 113BR Recently installed well for CCR program adds a downgradient data point CW-1 CW-2 X CW-2D X CW-3 CW-3D CW-4 CW-5 X GMW-10 GMW-11 GMW-6 GMW-7 X Roxboro Steam Electric Plant Page 1 of 3 September 28, 2018 GMW-8R Well replaced, GWM-8 was abandoned GMW-9 MW-lBR MW-2BR MW-3BR X MW-4BR MW-4BRL water level only MW-5BR X MW-5D X MW-6BR X MW-6D X MW-7BR MW-8BR MW-9BR X MW-10BR X MW-1 lBR X MW-11D X MW-12BR MW-13BR X MW-14BR X MW-15BR X MW-15D X MW-16BR X MW-17BR X MW-18BR X MW-18D X MW-19BRL X MW-2 X MW-20BRL MW-21BRLR Replaced, MW-21BRLR was abandoned MW-22BR MW-22D MW-23BR water level only MW-23BRR MW-24BR MW-25BR MW-26BR MW-27BR MW-28BR MW-29BR MW-30BR Roxboro Steam Electric Plant Page 2 of 3 September 28, 2018 MW-31BR MW-32BR MW-33BR GPMW-1 S GPMW-ID GPMW-1BR GPMW-2D GPMW-2BR GPMW-3D GPMW-3BR Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Ma esium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese I Radium 228 Dissolved Zinc _I Solids Roxboro Steam Electric Plant Page 3 of 3 September 28, 2018 Revised L.V. Sutton Energy Complex Interim Monitoring Plan — Groundwater Only Wells to be Sampled Sample for Radionuclides - A) Regional Office Notes - -- AW-1 C AW-2C AW-2D AW-3C X AW-4C X AW-5C AW-5D AW-6R-D AW-6R-E AW-7R-D AW-08C AW-09C AW-09D MW-05C X MW-05CD X MW-05D X MW-05R-E MW-7C MW-8 X MW-8B X MW-8D X MW-8E X MW-11 MW-12R MW-16D MW-19 MW-20 MW-20D MW-21C MW-22B MW-22C MW-23B MW-23C MW-23D X MW-23E X MW-24R-B MW-24R-C MW-27B MW-27C X L.V. Sutton Energy Complex Page 1 of 2 September 28, 2018 MW-28B MW-28C MW-31 R-C X MW-32C X MW-33C X MW-36C X MW-37B X MW-37C X MW-37CD X MW-37D X MW-37E X MW-38B MW-38C X MW-38D X MW-39B MW-39C X MW-39D X MW40B MW-40C MW-40D MW-41B X MW-41C X MW-41D X MW-41 E SMW-01 C SMW-02C SMW-03C SMW-04C SMW-5C SMW-06C SMW-06D Minimum Parameters to be Analyzed Aluminum Boron Copper Mercury Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Antimony Calcium Iron Nickel Strontium Total Combined Uranium Arsenic Chloride Lead Potassium Sulfate Total Suspended Solids Barium Chromium Ma nesium Radium 226 Sulfide Vanadium Beryllium Cobalt Manganese Radium 228 Total Dissolved Zinc Solids L.V. Sutton Energy Complex Page 2 of 2 September 28, 2018 Revised W. H. Weathersnoon Power Plant Interim MonitorinE Plan — Groundwater Only Wells to be Sampled AW-01D Sample for Radionuclides �� Regional Office Notes AW-01I AW-01 S AW-02D AW-02S AW-03D AW-03I AW-03S BW-01 BW-02S X BW-03D X BW-03I X BW-03S X BW-4D X BW-4I X BW4S X CCR-101-BG CAMA X CW-01 CW-02 CW-03 X MW-01 X MW-02 X MW-03 X MW-04 X MW-05 X MW-06 X MW-07 X MW-33D MW-33I MW-33S MW-41D MW-41I MW-52 X MW-53D MW-53I X _ MW-54D MW-55D W. H. Weatherspoon Power Plant Page 1 of 2 September 28, 2018 MW-55I X PW-1 (DEP 2) Minimum Parameters to be Analyzed Aluminum Boron Copper Mercua Selenium Thallium Alkalinity Cadmium Hexavalent Molybdenum Sodium Total Organic Chromium Carbon Total Antimony Calcium Iron Nickel Strontium Combined Uranium Total Arsenic Chloride Lead Potassium Sulfate Suspended Solids Barium Chromium Ma esium Radium 226 Sulfide Vanadium Total Beryllium Cobalt Manganese Radium 228 Dissolved Zinc Solids W. H. Weatherspoon Power Plant Page 2 of 2 September 28, 2018 J y Water Resources Environmental Quality June 15, 2018 Paul Draovitch Senior Vice President Environmental, Health & Safety Duke Energy 526 South Church Street Mail Code EC3XP Charlotte, North Carolina 28202 Subject: Approval of Revised Background Threshold Values Marshall Steam Station Dear Mr. Draovitch: ROY COOPER Governor MICHAEL S. REGAN Secretary LINDA CULPEPPER Interim Director The North Carolina Department of Environmental Quality's (DEQ) Division of Water Resources (DWR) has reviewed Duke Energy's calculated revised provisional background threshold values (PBTVs) for soil and groundwater for the subject facility. DWR reviewed the calculated PBTVs based on background data provided in the revised Comprehensive Site Assessment (January 2018), using the Revised Statistical Methods for Developing Reference Background Concentrations for Groundwater and Soil at Coal Ash Facilities dated May 26, 2017 and additional guidance provided in the December 7, 2017 email from Steve Lanter to Ed Sullivan and John Toepfer. DWR hereby approves all accepted PBTVs for groundwater and soil as outlined in the attached tables. These accepted PBTVs shall become the Background Threshold Values (BTVs) for the facility and will serve as a basis for the proposed remedial alternatives in the upcoming Corrective Action Plans. Per 15A NCAC 02L .0202(b)(3), where naturally occurring substances exceed the established groundwater standard, the standard shall be the naturally occurring concentration as determined by the Director. Therefore, BTVs calculated above the groundwater standards or Interim Maximum Allowable Concentrations (IMACs) in accordance with the provisions in 15A NCAC 02L .0202 and accepted by DWR, shall become the enforceable groundwater standard. Otherwise, the enforceable groundwater standards shall be those listed under 15A NCAC 02L .0202(h) including any effective IMAC s. For soils, PBTVs that are calculated above the DEQ Division of Waste Management Inactive Hazardous Sites Branch's (IHSB) Preliminary Soil Remediation Goals (PSRG) for the protection of groundwater shall become the BTVs for use in developing an appropriate corrective action strategy. For compounds that do not have an established PSRG, but do have a groundwater standard (i.e. chloride and sulfate) pursuant to 15A NCAC 02L .0202, use the calculation provided in the PSRG table to establish a PSRG if the required site -specific data are available. The PSRG table can found under the IHSB website at: https:Hdeq.nc.gov/about/divisions/waste-management/Werf md-section/inactive- hazardous-sites-program. —'7�' Nothing C=pares ,., State of North Carolina I Environmental Quality I Division of Water Resources Water Quality Regional Operations Section 1636 Mail Service Center I Raleigh, North Carolina 27699-1636 919-707-9129 The attached tables outline DWR's concurrence/non-concurrence with Duke Energy's proposed calculated PBTVs for groundwater and soil. For all of Duke Energy's calculated PBTVs that are listed as acceptable, DWR hereby approves those values. For those BTVs not found acceptable, justification is provided on the attachment and Duke Energy is responsible for providing revised values for review and approval. For any BTVs found to be unacceptable due to an inadequate dataset, Duke Energy shall continue to collect data until an adequate dataset is achieved and a valid statistical calculation can be performed. Along with the specific comments provided on the attachments, DWR offers the following general comments with regards to the BTVs: • Please note that the IHSB's PSRG table was revised in February 2018. With respect to the constituents being evaluated for the CSA, the following PSRG values have been revised. o PSRG for Aluminum is currently 110,000 mg/kg. o PSRG for Chromium is currently 3.8 mg/kg. o PSRG for Molybdenum is currently 7.1 mg/kg. o PSRG for Vanadium is currently 350 mg/kg. DWR recognizes that, as new information is gathered going forward, the approved BTVs may be refined. Thus, there will be need for a periodic review and recalculation of the BTVs. The timeframes for the periodic review will be established by DWR at a later date and any revised BTVs will be subject to approval by DWR's Director. If you have any questions, please contact Brandy Costner (Mooresville Regional Office) at (704) 663- 1699 or Steve Lanter (Central Office) at (919) 807-6444. Sincerely, Linda Culpepper, Director Division of Water Resources Attachments cc: MRO WQROS Regional Office Supervisor WQROS Central File Copy Marshall Steam Station - Groundwater Background Threshold Values (6/15/2018) Parameter Reporting Units Duke Energy Calculated PBTVs from CSA Report (January 31, 2018) 15A NCAC Standard or IMAC DWR Concurrence (Acceptable/Not Acceptable) Comments Flow Unit Flow Flow Unit Shallow Deep Bedrock Shallo,* Deep Bedrock H S.U. 4.6-6A 5.7-6.9 5.6-7.6 6.5-8.5 Acce lablc Acceptable Acceptable Alkalini mg/L 63 204 108 NE Acceptable Acceptable Acceptable Aluminum jtL1.1, 757 128 300 NE Accc table Acceptable Acceptable juitirnorly A91L 0.5 OS 0.5 1 Acceptable Acceptable Acceptable Arsenic jtF1, 0.4 0.6 0.6 10 Acceptable Acceptable Accr table Barium t 'L 310 127 435 700 Acceplable Acceptable Acceptable Beryllium lip -I. 0.2 0.1 1 0.2 4 Acceptable Acceptable Acceptable Bicarbonate mg'L. 63 204 108 NE Acce table Acceptable Acceptable Boron L 50 50 50 700 Acceptable Acceptable Acceptable Cadmium i g L 0.08 0.08 0.08 2 Acceptable Acceptable Acceptable Calcium m '1 10.7 13.1 15 NE Acceptable Acceptable Acceptable CaT1113nate m •IL 5 5 5 NE Acceptable Acceptable Acceptable Ebb ride mg/L 5.5 4.7 4.5 250 Acceptable Acceptable Acceptable Chromitim(VI) L 5.7 3 3.9 NA Acce table Acceptable Acce table Chnimium L 16.5 7.6 8.3 10 Acceptable Acceptable Acceptable Cobalt L 1.2 1.9 2.8 1 Acceptable Accc table Acce table Copper t 'L 3.8 2.8 4.2 1,000 Acec fable Acceptable Acceptable Iron L 744 272 792 300 Acceptable Acceptable Acce table Lead JLVIL 0.3 0.1 0.2 15 A[te Whle Acceptable Acceptable Maemaiuni nw!L 1.8 14.4 13.2 NE Acceptable Acceptable Acceptable Mattyaricsc JIUL 75.3 141 26.6 50 Acceptable Acceptable Acceptable Mercury "L 0.2 0.2 0.2 1 Acceptable Acceptable Acceptable Methane jiv L 10 10 10 NE Acce iable Acceptable Acceptable Molybdenum PgL 0.5 3.2 3 NE Acceptable Acceptable Acceptable Nickel L 9.9 7.5 7.2 100 Acceptable Acceptable Acceptable Nitralc+Nitrite mg-N/L 2.7 1A 0.4 ll* Acceptable Acceptable Potassium mv.1 5 7.8 9.8 NE I Acceptable -Acceptable Acceptable Acceptable Selenium VgL 0.5 0.5 0.5 20 Acceptable Acc table Acceptable Removed 10 as an outlier in the shallow Sodium m L 9.1 29.2 14 NE Acce fable Acceptable Acceptable Strontium t • L 303 665 253 NE Acc lablr Acceptable Acceptable Sulfate rML 4.2 17.7 18.4 250 Acceptable Acceptable Acceptable Sulfide m g IL 0.1 0.1 0.1 NE Acceptable Acceptable Acceptable TDS mL/L 140 193 216 500 Acceptable Acceptable Acceptable Thallium jS L 0.1 0.1 0.1 0.2 Acceptable Acceptable Acceptable Toc, mvL 1 1 1 NE Acceptable Acceptable Acce.table Vanadium L 5.6 3.8 16 0.3 Acceptable Acceptable Acceptable Zinc PPL 19.2 17 11.9 1,000 Acce sable Acceptable Acceptable Radium (Total) pCill, 3 2.8 5.7 NE Accc tabk Acceptable Acceptable Uranium (Total) A&mL 0.0005 0.0005 0.0005 NE Acceptable Acceptable Acceptable NA - M1Or Appl�anl! ND - Not Detected NE - Not Established mg/L - milligrams per liter pCi/L - picocuries per liter Radium (Total) - Radium-226 and Radium-228 combined ;The I SA NCAC 02L Standard is 10 mg/L for Nitrate and 1 mg/L for Nitrite (added for a total of I l mg/L) S.U. - Standard Unit TOC - Total Organic Carbon TDS - Total Dissolved Solids µg/mL - micrograms per milliliter µg/L - micrograms per liter Uranium (Total) - Uranium-233, Uranium-234, Uranium-236, and Uranium-238 combined Page 1 of 1 Marshall Steam Station - Soil Background Threshold Values (6/15/2018) Parameter Reporting Units Duke Energy Calculated PBTVs from CSA Report (January 31, 2018) PSRG Protection of Groundwater (as of February 2018) DWR Concurrence (Acceptable/Not Acceptable) Comments H S.U. 4.7-6.1 NA Acceptable Aluminum mwkg 56A37 110,000 Acceptable Antimony mg/kg 0.65 0.9 Acceptable Arsenic mg/kg 4.697 5.8 Acceptable Barium mg/kg 819 580 Acceptable Beryllium tn&g 3.9 63 Acceptable Boron mg/kg 8.7 45 Acceptable Normal UTL=10.69 Cadmium mg/kgmg?kg 0.11 3 Acceptable Calcium m k = 1.500 NE Acceptable Chloride mg/kp, 13 NE* Acceptable Chromium mg/kg 32.8 4 Acceptable Cobalt mg,kg 53.1 0.9 Acceptable Copper LaWkg 180 700 Acceptable Iron mg/kgmgikg 78,228 150 Acceptable Lead m 82.5 270 Acceptable Magnesium mgikg 32,462 NE Acceptable Manganese mg/kg 2,872 65 Acceptable Mercury mg/kg 0.1 1 Acceptable Molybdenum mg/kg 3.5 7.1 Acceptable Nickel mg/kg 18.6 130 Acceptable Normal UTL=19.55 Nitrate as N) m 0.56 NE Acceptable Potassium mg/-kgmg/-kg 29,937 NE Acceptable Selenium m 1.77 2.1 Acceptable Gamma UTL=2.44 Sodium mg/kg 394 NE Not Acceptable Provide rationale on why the maximum concentration was used. Strontium mg/kg 7.53 NE Acceptable Normal UTL=8.59 Sulfate mWkg 36 NE* Acceptable Thallium my kg 1.1 0.28 Acceptable Vanadium m 210 350 Acceptable Zinc mg,-,-kgmg,-,-kg 125 1200 Acceptable *Constituent has 2L Standard or IMAC. Use calculation in the PSRG table to determine value. NA - Not applicable (dataset contains zero valid samples) ND - Non -Detect NE - Not Established mg/kg - milligrams per kilogram S.U. - Standard Unit