WQ0003396_Additional Information_20190422

arauco
CERTIFIED MAIL 7018 2290 00014576 3399
RETURN RECEIPT REQUESTED
Ashley Kabat, Environmental Engineer
North Carolina Department of Environmental Quality
Division of Water Resources
512 North Salisbury Street
1617 Mail Service Center
Raleigh, NC 27699-1617
Subject: Application No. WQ0003396
Dear Ms. Ashley Kabat,
985 Corinth Road
Moncure, North Carolina 27559
Tel:[phone]
Toll Free: 855-427-2826
Fax:[phone]
April 22, 2019
Please find the responses to the Additional Information Request for Application No. WO0003396.
A. Cover Letter
1. See attached lab analysis results for Boiler Water Blowdown from MDF and Cooling
Water Tower Blowdown from Particleboard.
2. See attached Wastewater Spray Irrigation System Management Plan for
recommended irrigation rate for the fields. In addressing B.1. Arauco will be retiring
the spray system for field 10. This would eliminate 2,572,896 gallons of water per year
and change the daily loading to 39,525 gallons per day.
3. Arauco would like to remove the closed -loop treatment systems and reclaimed water
systems from the permit but keep the following pieces of equipment from these
systems to be repurposed as a pretreatment system for future connection to the City
of Sanford wastewater pipeline. The equipment to be kept is as follows:
• 1 500-gallon calcium hydroxide mix tank with agitator and a 3.8 gpm metering
pump
• 1 4,000-gallon scrubber conditioning tank with agitator and dual (2) 21.3 gpm
tank transfer pumps
• 1 500-gallon screen water buffer tank with dual 129.6 gpm transfer pump
• 1 100,000-gallon screened water tank with agitator and dual 119.6 gpm
transfer pumps
• 1 500-gallon "overflow' tank with dual 4.4 gpm transfer pumps

• A flocculent and coagulant dosing system prior to the screw press
• 1 Huber screw press
• 1500-gallons screw press buffer tank with agitator and dual 153.6 gpm screw
press out feed pump
• 3 340-gallon storage tanks and a flocculent, coagulant, and neutralizer dosing
system prior to one pipe flocculator
• 1 dissolved air floatation (DAF) clarifier
• 1 4,000-gallon sludge tank with mixer and dual 6 gpm sludge tank transfer
pumps
• A flocculent and coagulant dosing system to serve 1 Huber sludge screw press
with conveyor to send dewatered and pressed wood chip sludge to the fuel
pile
• 1 500-gallon sludge screw press buffer tank with agitator and dual 9 gpm
buffer tank transfer pumps
• 1 500-gallon DAF outfeed buffer tank with dual 188.8 gpm out feed transfer
pimps
• 1 30,000-gallon mill water storage tank
• 2 87.1 gpm mill water transfer pumps (#1 and #2)
• 2 squeeze water screens
• 1 6,800-gallon squeeze water tank with agitator
• 2 8.2 gpm plug screw flush water pumps
• 2 32.7 gpm excess squeeze water pumps
• 1 squeeze water heat exchanger
• 1 9,000-gallon squeeze water storage tank
• 2 30.9 gpm squeeze water pumps
• Various pumps (not individually listed) for transporting wastewater from
various MDF mill process areas to the wastewater treatment system
• Continued operation of wastewater storage lagoon (Pond #5)
• Continued operation of a 126,000 gpd wastewater treatment and surface
irrigation facility
4. Arauco would like to change the flow limit to a flow measurement. We would like to
measure the total influent flow at Pond 3 and the effluent flow directly after Pond 3.
If the influent flow minus the effluent flow is a negative value, this would signify more
water is being treated than entering the system and be complying with our permit.
We would like this number to be calculated on a monthly average.
B. Site Map
1. Arauco has elected to stop using the center pivot spray irrigator on field 10 to avoid
the potential of wastewater entering the wetland that is within close proximity to field
10.

If you have any questions or need additional information, please reach out to Yvonne Couts,
Moncure Environmental Manager, at 919-545-5848 or [e-mail].
Sincerely,
a4
Jeff McMillian
Plant Manager

NCO Laboratol es
AceHrate. Timely. Responsive. Innovative.
102•A Woodwinds Industrial Court
Cary NC, 27511
Phone: [phone] FAX: [phone]
Monday, April 22, 2019
Arauco North America, Inc. (UN039)
Attn: Yvonne Couts
985 Corinth Road
Moncure, NC 27559
RE: Laboratory Results for
Project Number: [none], Project Name/Desc: Wastewater Permit Testing
ENCO Workorder(s): CCO5006
Dear Yvonne Couts,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Monday, April 8, 2019.
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted in the project narrative if applicable. This report shall not be reproduced except in
full, without the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Kz7
Franz
Project Manager
Enclosure(s)
FINAL This report relates only to the sample as received by the laboratory, and may only se reproduced in full. I Page 1 of 39

�uco
vvww.encolabs.com
SAMPLE SUMMARY/LABORATORY CHRONICLE
Client ID: MDFBOIIer
Lab ID: CC05006-01
Sampled: 04/09/19 09:00
Received: 04/0811910.28
parame
premarallion
Hold Date/Time(s)
Prep Date/Timers)
Analysis Date/Timefs)
Co0lert 18
NO PREP
04/08/19 16:55 04/09/19
12:47 04/08/19
14:43
04/09/19 11:07
CSU Method
NO PREP
O1/O1/22
04/09/19
15:54
04/11/19 15:11
EPA 200.7
Same
10/05/19
04/09/19
15:54
04/11/19 12:00
EPA 300.0
NO PREP
05/06/19
04/15/19
11:54
04/15/19 19:37
EPA 351.2
Same
05/06/19
04/22/19
14:39
G4115/19 13:44
EPA 353.2
NO PREP
04/10/19 09:00
04/09/19
09:26
04/D9/19 11:26
EPA 353.2
ICALCI
04/10/19 09:DO
04/21/19
10:19
04/21/19 13:45
EPA 420.1
Same
05/06/19
04/15/19
07:50
04/15/19 14:37
EPA 524.2
Same
04/22/19
04/08/19
09:18
04/08/19 12:37
EPA 624.1
Same
04/22/19
04/08/19
12:56
04/08/19 23:42
SM 2540C-2011
NO PREP
04/15/19
04/09/19
13:55
D4/09/19 13:55
SM 4500H+8-2011
NO PREP
04/08/19 D9:14
04/11/19
12:07
04/11/19 12:07
SM 5210 B-2011
NO PREP
04/10/19 09:00
04/10/19
08:24
04/10/19 08:24
SM 5220D-2011
Sarre
05/06/19
04/09/19
13:18
04/09/19 19:56
SM 5310B-2011
Same
05/06/19
04/11/19
12:00
04/12/19 01:42
Client ID: MDF Boller
Lab ID: CC05006-01REI
Sampled: 04/08/19 09:00
Received: 04/08/19 10:28
Parameter
PIPAaratipn
Hdd Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 350.1
NO PREP
05/06/19
04/18/19
08:50
04/18/19 12:48
EPA 353.2
NO PREP
05/06/19
04/21/19
10:19
04/21/19 13:45
EPA 624.1
Same
04/22/19
04/09/19
12:24
04/10/19 01:57
Client 1D: MDF Boller
Lab ID: CC05006-01RE2
Sampled: 04/08/19 09:00
Received: 04/O9/19 10.28
Parameter
Preparation
Hold Date/Timefsl
Prey Date/Timefs)
Analysis Date/Time(s)
EPA 365.4
Same
05/06/19
D4/12/19
11:25
04/15/19 17:55
Client ID: PB Cooling Tearer
tab ID: C005006-02
Sampled: 04/08/19 09:05
Received: 04/03/19 10:28
Parame
Coldert 18
preparation
NO PREP
Hold DateTme(sl
04/08/19 17:00 04/D9/19
prep Date/Tinm(s)Mae
12:47 D4/08/19
14:43
Apabrsis Date/Time(sl
04/09/19 11:07
CSU Method
NO PREP
01/01/22
04/09/19
15:54
04/11/29 15:11
EPA 200.7
Same
10/05/19
04/09/19
15:54
04/11/19 12:02
EPA 300.0
NO PREP
O5/06/19
04/15/19
11:54
04/15/19 19:52
EPA 353.2
NO PREP
04/10/19 09:05
04/09/19
09:26
04/09/19 11:29
EPA 353.2
ICIALC)
04/10/19 D9:05
04/21/19
10:19
04/21/19 13:46
EPA 420.1
Same
05/06/19
04/15/19
07:50
04/15/19 14:37
EPA 524.2
Same
04/22/19
04/08/19
09:18
D4/08/19 13:12
EPA 624.1
Same
D4/22/19
04/08/19
12:56
04/09/19 00:14
SM 2540C-2011
NO PREP
04/15/19
34/09/19
13:55
04/09/19 13:55
SM 4500H+B-2011
NO PREP
04/08/19 09:19
04/11/19
12:07
04/11/19 12:07
SM 5210 B-2011
NO PREP
04/10/19 09:05
04/10/19
08:24
0411D/19 08:24
SM 5220D-2011
Same
05/06/19
04/09/19
13:18
04/09/19 19:56
SM 5330B-2011
Same
05/06/19
04/11/19
12:00
04/12/19 01:42
ClientID: PBCooling Tower
lab ID: CC05066-02RE1
Sampled: 04/08/19 09:05
Received: 04/08/19 10:28
Parameter
preparation
Hold Date/Timers)
Prep Date/iimels)
Analysis Date/Timefsl
EPA 350.1
NO PREP
05/06/19
D4/18/19
08:50
04118/1912:50
EPA 351.2
Same
05/06/19
04/12/19
14:39
04/15/19 15:58
EPA 353.2
NO PREP
05/06/19
04/21/19
10:19
04/21/19 13:46
EPA 365.4
Same
05/06/19
04/12/19
12:25
04/15/19 16:53
EPA 624.1
Same
04/22/19
04/09/19
12:24
04/10/19 02:27
RNAL This rePom relates only to the sample as r vved by me laboratory, and may only be reproduced In V1, Page 2 Of 39

w .enmlabsxom
SAMPLE SUMMARY/LABORATORY CHRONICLE
Client ID: Trip Blank
Lab ID: CCO5006-03
Sampled: 04/08/19 09:00
Received: 04/08/19 10:28
Parameter
preparation
Hold Date/Time(s)
Prep Date/Timefsl
Analysis Date/Timess)
EPA 524.2
Same
04/22/19
04/08/19 09:18
04/08/19 13:47
EPA 624.1
Same
04/22/19
04/08/19 12:56
04/09/19 00:45
Client ID: Trip Blank
Lab ID: CC05006-03RE1
Sampled: 04/08/19 09:00
Received: 04/08/19 10:28
Parameter
preparation
hold Date/Timefsl
Pred Date/Tirmi
Analysis Date/Timi
EPA 624.1
Same
04/22/19
04/09/19 12:24
04/10/19 02:58
FINAL This report relates only to the sample as received by the laboatory, and may only be reproduced In full. I Page 3 of 39

I t
www.encolabs.wm
SAMPLE DETECTION SUMMARY
Client ID: MDF Boiler
Lab ID:
CCOS006-01
ADah¢e
Riesu
Has
E=
Em
Ihtlts
Method
5=1
Calcium - Total
34400
39.0
100
tg/L
EPA 200.7
Chemical Oxygen Demand
23
30
10
mg/L
SM 5220D-2011
Chloride
67
2.2
5.0
mg/L
EPA 300.0
Magnesium -Total
10700
29.0
100
ug/L
EPA 200.7
Nitrate as N
6.8
D
0.20
0.50
mg/L
EPA 353.2
PH
7.8
1.0
1.0
PH
SM 4500H+B-2011
Q01
Sodium - Total
94200
400
500
ug/L
EPA 20D.7
Sodium Adsorption Ratio
3.58
[blank]
CSII Method
Temperature for PH (deg. Q
19
pH
SM 4500H+B-2011
OOi
Total Dissolved Solids
450
50
50
mg/L
SM 2540C-2011
Total Kjeldahl Nitrogen
590
D
26
48
mg/L
EPA 351.2
Total Organic Carbon
5.0
0.34
1.0
mg/L
SM 5310E-2011
Client ID: MDF Boller
Lab ID:
CCO5006-OIRE1
Anal Yt4
Results
flag
MR
EQL
Melts
Method
II41C4
Ammonia as N
0.053
3
0.045
0.10
mg/L
EPA 350.1
Nitrate/NBrite as N
6.8
D
0.20
0.50
mg/L
EPA 353.2
Client ID: MDF Boiler
Lab ID:
0005006.01RE2
ABa y e
Results
ilao
Hu
EQL
17DRs
MsihtZQ
!{ffirP6
Phosphorus
1.4
0.025
0.10
mg/L
EPA 365.4
Client ID: PS Cooling Tower
Lab ID:
CC05006-02
Anal 1Qg
Results
Hag
Hu
EQL
Ifflu
Matllga
h2cm
Calcium - Total
33400
39.0
100
ug/L
EPA 200.7
Chemical Oxygen Demand
21
30
10
mg/L
SM 5220D-2011
Chloride
68
2.2
5.0
mg/L
EPA 30D.0
Magnesium - Total
10600
29.0
100
Ug/L
EPA 200.7
Nitrate as N
6.5
D
0.20
0.50
mg/L
EPA 353.2
PH
7.9
1.0
1.0
PH
SM 4500H+8-2011
Q-01
Sodium - Total
91400
400
500
ug/L
EPA 200.7
Sodium Adsorption Ratio
3.52
[blank]
CSU Method
Temperature far PH (deg. Q
20
PH
SM 4500H+B-2011
QOl
Total Dissolved Solids
440
50
50
mg/L
SM 2540C-2011
Total Organic Carbon
5.1
0.34
1.0
mg/L
SM 5310B-2011
Client ID: PB Coding Tower
Lab ID: CC05006-02RE1
AOa112:
RffiYlff
Hag
Hu
PAL
mom
MsfficC
tlP3es
Nitrate/Nitrite as N
6.5
D
0.20
0.50
mg/L
EPA 353.2
Phosphorus
1.5
0.025
0.10
mg/L
EPA 365.4
Total Kjeldahi Nitrogen
0.64
0.26
0.48
mil
EPA 351.2
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In UK I Page 4 Of 39

v .encolabs.mm
ANALYTICAL RESULTS
Description: MDF Boiler Lab Sample IMCC05006-01 Received: 04/08/19 10;
Matrix: Waste Water Sampled:04/08/19 09:00 Work Order: CC05006
Project: Wastewater Permit Testing Sampled By: Yvonne Coats
Volatile Organic Compounds by GCMS
^ -fAYDC ry fedamaW [AC 59i]
Analvte [CASNumberl
Results
gap
Units
PF
MQL
POL
]1PSsh
Method
gDabaap
By
N4t4t
1,1,1,2-Tetmchloroetham [630-20b]^
0.17
U
tg/L
1
0.17
1.0
9DOBD29
EPA 624.1
04/08/19 23:42
MRK
1,1,1-Tnchluroetham[71-55-6]A
0.12
U
u9/1.
1
0.12
1.0
9DDB029
EPA 624.1
D4/08/1923:42
MRK
QL-02
1,1,2,2-TebaMbroethane[79.345]A
0.28
U
ug/L
1
0.28
1.0
9DD8029
EPA 624.1
04/08/1923:42
MRK
1,1,2-Trkhloroetham [79.00-5]^
0.14
U
ug/L
1
0.14
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
1,1-Dichlomathane [75-34-3]A
0.13
U
ug/L
1
0.13
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
1,1-Dirhloroethene[75-354]^
0.21
U
ug/L
1
0.21
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
1,1-DlUtbropropene[563-58-6]^
0.15
U
ug/L
1
0.15
1.0
9D08D29
EPA 624.1
D4/08/1923:42
MRK
1,2,3-Trkhlorobenzem [87-61fi]A
0.01
U
u9/L
1
0.01
1.0
9DD8029
EPA 624.1
04/08/19 23:42
MRK
1,2,3-Trichlompropane[96-184]^
0.23
U
ug/L
1
0.23
1.0
9DD8029
EPA 624.1
04108/1923:42
MRK
1,2,4Trichlorobenzere[320-82-11A
0.14
U
U91L
1
0.14
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
1,2,4Trimethylbemene[95-63-6]^
0.10
U
ug/L
1
0.10
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
1,2-Dibromo-3-chloropropane[96-12-81^
0.48
U
ug/L
1
0.48
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
1,2-Dibromoeftm[106-93411
0.66
U
ug/L
1
0.66
1.0
9DD8029
EPA 624.1
04108/1923:42
MRK
1,2-Dichlorobenzene [95-50-1]^
0.19
U
ug/L
1
0.19
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
1,2-Dichloroetham[107-05-2]^
0.21
U
u9/1.
1
0.21
1.0
9DWO29
EPA 624.1
04/08/19 23:42
MRK
QL-02
1,2-Dkhloroompane[78-87-5]1
0.10
U
ug/L
1
0.10
1.0
9D08029
EPA 624.1
04/08/1923:42
MRK
1,35-Trimethylberrzene [308-67-8]^
D.30
U
ug/L
1
0.30
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
1,3-Dichlorobenwm I541-73-1]A
0.15
U
ug/L
1
0.15
1.0
9D0S029
EPA 624.1
D4/08/19 23:42
MRK
1,3-Dkhloropmpane[142-28-9]1
0.16
U
ug/L
1
0.16
1.0
9DD8029
EPA 624.1
04/08/19 23:42
MRK
1,4-Dkhlorobenzene [10646-7]A
0.19
U
ug/L
1
0.19
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
1,4-Dioxane[123-91-1]A
25
U
ug/L
1
25
60
9D09025
EPA 624.1
04/10/1901:57
MRK
2,2-Dichloropropane [59420-7]^
0.28
U
ug/L
1
0.28
1.0
9D08D29
EPA 624.1
04/08/19 23:42
MRK
2-Butanone [78-93-3]^
1.3
U
U91L
1
1.3
5.0
9DDS029
EPA 624.1
04/08/19 23:42
MRK
2-ChlDroethyl Vinyl Ether I110-75-8]A
1.1
U
ug/L
1
1.1
5.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
2-Chlorotoluene[9549.8]^
0.08
U
ug/L
1
0.08
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
2-Hexanone [591-78-6]A
0.88
U
ug/L
1
0.88
5.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
3-Chloropropene [107-05-1]^
0.11
U
ug/L
1
0.11
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
4-Chbrotduene [106434]^
0.07
U
ug/L
1
0.07
1.0
9DO8029
EPA 624.1
04/08/19 23:42
MRK
4-1sopropyltoluene [99-87-6]^
0.08
U
ug/L
1
0.08
1.0
9D08029
EPA 624A
04/08/19 23:42
MRK
4-Methyl-2-penanone[308-30-1]^
1.1
U
ug/L
1
1.1
5.0
9D08029
EPA 624.1
D4/08/1923:42
MRK
Acetone [67-64-11A
10
U
ug/L
1
10
20
9D08029
EPA 624.1
04/08/19 23:42
MRK
Acetonivile [75-05-8]^
5.0
U
ug/L
1
5.0
30
9DO8029
EPA 624.1
04/08/19 23:42
MRK
QL-02
Acrolein [307-D2-8]^
4.0
U
ug/L
1
4.0
10
9D08029
EPA 624.1
04/08/19 23:42
MRK
Acrylondnle[107-13-1]^
3.5
U
ug/L
1
3.5
10
9D08029
EPA 624.1
04/08/1923:42
MRK
Benzene [7143-2]^
0.15
U
U91L
1
0.15
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
Bromobenzene[108-86-1]^
0.16
U
ug/L
1
0.16
1.0
9DD8D29
EPA 624.1
04/08/19 23:42
MRK
Bromochloromedtaw [7497-5]1
0.48
U
ug/L
1
0.48
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
Bromodichloromethane[75-274]^
0.0010
U
mg/L
1
0.0010
9D08028
EPA 524.2
04/08/1912:37
RAM
Bromodichloromethane[75-274]^
0.17
U
ug/L
1
0.27
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
Bromoform [75-25-2]^
0.0010
U
mg/L
1
0.0010
9D08028
EPA 524.2
04/08/1912:37
RAM
Bromoform [75-25-2]^
0.22
U
ug/L
1
0.22
1.0
9DD8029
EPA 624.1
04/08/19 23:42
MRK
Bromomethane [74-83-9]^
0.14
U
ug/L
1
0.14
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
Carbon disurrde [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
Carbon tetrachloride [56-23-5]A
0.17
U
ug/L
1
0.17
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK QL-02
Chlorobenzene[108-90-7]^
0.17
U
ug/L
1
0.17
1.0
9D0B029
EPA 624.1
04/08/19 23:42
MRK
Chloroethane [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
Chloroform [67-66-3]^
0.0010
U
mg/L
1
0.0010
9DD8028
EPA 524.2
04/08/19 12:37
RAM
FINAL this report relates only to the sample as recelved by the laboratory, aW may only be reproduced in roll. I Page 5 of 39

www.encoiabs.com
ANALYTICAL RESULTS
Description: MDF Boiler
Lab Sample ID:CC05006-01 Received: 04/08/19 10:28
Matrix: Waste Water
Sampled: 04/08/19 09:00 Work Order. 0005006
Project: Wastewater Permit Testing
Sampled By: Yvonne Couts
Volatile Organic Compounds by GCMS
Analyte iGS Numberl
moults
Fin
Units
RE
Hu
pt L
gait h
Metbod
Am
fy Notes
Chloroform [67-66-3]1
0.18
U
ug/L
1
0.18
1.0
9D08029
EPA 624.1
D4/08/19 23:42
MRK
Chloromethane [74-87-3]^
0.13
U
ug/L
1
0.23
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
ChWoprem [126-99-8]^
0.64
U
Ug/L
1
0.64
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
cis-1,2-Dkhbroethene[156-59-2]1
0.15
U
ug/L
1
0.15
1.0
9DD8029
EPA 624.1
D4/08/19 23:42
MRK
cis-1,3-Dichloropropere [50061-01-5]A
0.20
U
ug/L
1
0.20
1.0
9DD8029
EPA 624.1
04/08/19 23:42
MRK
Dibromochloranethane [12448-1]A
0.0010
U
mg/L
1
0.0010
9D08028
EPA 524.2
04/08/1912:37
RAM
Dibromochioromethane[12448-I]A
0.17
U
ug/L
1
0.17
1.0
9DO8029
EPA 624.1
D4/08/19 23:42
MRK
Dibromomethane [74-95-3]^
0.27
U
ug/L
1
0.27
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
Dichlorodi8uoromethane [75-71-8]^
0.20
U
ug/L
1
0.20
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
Ethyl Methacrylate [9763-2]^
0.38
U
ug/L
1
0.38
1.0
9DO8029
EPA 624.1
04/08/19 23:42
MRK
Ethylbenzene[1W-4141^
0.13
U
ug/L
1
0.13
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
Freon 113 [76-13-1]1
0.35
U
ug/L
1
0.35
2.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
Hezachlorobut diene [87-68-3]^
0.22
U
ug/L
1
0.22
1.0
9DD8029
EPA 624.1
04/08/19 23:42
MRK
Iodomethane[74-884]^
1.7
U
ug/L
1
1.7
5.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
lsobuM alcohol [78-83-1]^
11
U
ug/L
1
11
50
9D08029
EPA 624.1
04/08/19 23:42
MRK QL-02
Isopropyl Ether [108-20-3]1
0.05
U
ug/L
1
0.05
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
Isopropylbenzene [98-82-8]^
0.14
U
ug/L
1
0.14
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
m,p'Xylenes[108-38-3/10642-3]A
0.17
U
ug/L
1
0.17
2.0
9DD8029
EPA 624.1
04/08/19 23:42
MRK
Methacrylonitnle [ 126-98-71A
4.9
U
ug/L
1
4.9
10
9DD8029
EPA 624.1
04/08/19 23:42
MRK
Methyl Methacrylate [80626]A
0.51
U
Ug/L
1
0.51
1.0
9DD8029
EPA 624.1
04/08/19 23:42
MRK
Methylene chloride [75-09-2]^
0.23
U
U91L
1
0.23
1.0
9DD8029
EPA 624.1
D4/08/19 23:42
MRK
Methyl-tert-Butyl Egan[1634-044]^
0.16
U
u9/1.
1
0.16
1.0
9DO8029
EPA 624.1
04/08/19 23:42
MRK
Naphthalene [91-20-3]1
0.11
U
ug/L
1
0.11
1.0
9DO8029
EPA 624.1
04/08/19 23:42
MRK
n-Butyl Beruere [104-51-8]A
0.06
U
ug/L
1
0.06
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
n-Propyl Beraene [10365-1]^
0.12
U
ug/L
1
0.12
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
o-Xylene [9547-6r
0.06
U
ug/L
1
0.06
1.0
9DO8029
EPA 624.1
04/08/19 23:42
MRK
Propiondrile[107-12-0]^
5.0
U
ug/L
1
5.0
10
9D08029
EPA 624.1
D4/08/19 23:42
MRK
set-Butylbenzere (135-98-8]A
0.10
U
U9/1-
1
0.10
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
5tyrene[10042-5]A
0.11
U
ug/L
1
0.11
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
tert-Butylbenzene (98-06-6]A
0.17
U
UWL
1
0.17
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
Tetrachlo oethene [127-184]A
0.17
U
ug/L
1
0.17
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK QL-02
Toluene [108-88-3]A
0.14
U
ug/L
1
0.14
1.0
9D08029
EPA 624.1
D4/08/19 23:42
MRK
Total Trlhalomethanes^
0.0010
U
mg/L
1
0.0010
9DO8028
EPA 524.2
04/08/1912:37
RAM
tans-1,2-Dkhbrcethene[156-60-5]^
0.21
U
ug/L
1
0.21
1.0
9D08029
EPA 624.1
04108/1923:42
MRK
taro-1,3-DicFJaopropene[10061-026]^
0.15
U
ug/L
1
0.15
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
trans-1,4-Dichloro-2-butane (110-576]^
0.70
U
ug/L
1
0.70
1.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
Trkhloroethene[79-016]A
0.15
U
ug/L
1
0.15
1.0
9D08029
EPA 624.1
D4/08/1923:42
MRK
TrichloroRmiometham [75694]^
0.24
U
ug/L
1
0.24
1.0
9DO8029
EPA 624.1
04/08/19 23:42
MRK
Vinyl acetate (108-054]A
0.95
U
ug/L
1
0.95
5.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
Vinyl chloride [75-014]A
0.32
U
U91L
1
0.32
1.0
9DO8029
EPA 624.1
04/08/19 23:42
MRK
Xylenes(Total)(1330.20-7]A
0.24
U
Ug/L
1
0.24
3.0
9D08029
EPA 624.1
04/08/19 23:42
MRK
sunvoiftelF
2E Spike
°
%Rat Llmltr
BdLflh
M! $
BY II4SL5.
1,2-Dxhb,0benzene-d4
28
I
15.0
111 %
70-130
9D08018
EPA 524.2
0410411912:37
&M
4-8mmofluorrbamaoe
27
1
25.0
107 %
70.130
9D08028
EPA 524.2
041081191237
84M
4-BmmoMror0beume
58
1
50.0
116 %
53-136
9D08029
EPA 624.1
0410811923.42
MRK
4-8romo0uombenzene
57
1
50.0
113%
53-136
9D09025
EPA 624.1
0411ry1901:57
MRK
DlMomoOuaromethane
54
1
50.0
107%
67-129
9D08029
EPA 624.1
04IV811923:42
MRK
nfu
This mXft relates only to the sample
as received by the laboratory, and
may only
be reproduced
in NO.
I Page 6 of 39

ANALYTICAL RESULTS
Description: MOF Boiler
Matrix: Waste Water
Project: Wastewater Permit Testing
Lab Sample ID:CCO5006-01
Sampled: 04/08/19 09:00
Sampled By: Yvonne Courts
Volatile Organic Compounds by GCMS
�uco
w .encelabs.com
Received: 04/08/19 10:28
Work Order: CC05006
Sumwates
Resu/tr
OF
$pike LN
^/o Rec %Rec Limits
Satch
Ana/vred
NY
Notes
Dibromo9cnromelharre
58
1
50.0
116 %
67-129
9DO9025
EPA 624.1
04110119 01.57
MRK
Tolwe oB
52
1
50.0
103%
59-134
9008029
EPA 624.1
04108/1923:41
MRK
Tolwfn d8
60
1
50.0
119 %
59-134
9DO9025
EPA 624.1
04110119 01.'57
MRK
Metals by EPA 200 Series Methods
^ -ENCO Cary ce bfied anatyie(NC 59I1
Analyte rCAS Numbed
Results
Has
Units
PE
MIA
Em
Batch
Method
AnalYFe4
Am
Notes
Calcium[7440.70-2]^
34400
ug/L
1
39.0
100
9DO9035
EPA 200.7
04/11/1912:00
JDH
Magnesium[7439-95-4]A
10700
ug/L
1
29.0
100
9DO9035
EPA 200.7
04/11/1912:00
JDH
Sodium [7440.23-Sr
94200
ug/L
1
400
500
9DO9035
EPA 200.7
04/11/19 12:00
JDH
Classical Chemistry Parameters
^ -FNCO 6ry rertiheNautyle (NC 59IJ
Analv[e rCASNumberl
Results
F[ag
modli
PE
MU
EM
Batch
Method
Analwed
By
Notes
Ammonia as N [7664-41-7]^
0.OS3
J
mg/L
1
0.045
0.10
9D18015
EPA 350.1
04/18/1912:48
MKS
Biochemical Oxygen Demand-
2.0
U
mg/L
1
2.0
2.0
9D10003
SM 5210 114011
04/10/19 08:24
JOC
Chemical Oxygen Demand^
23
mg/L
1
10
10
9DO9009
SM 5220D-2011
04/09/19 19:56
JOC
Chloride [15887-00-6]^
67
mg/L
1
2.2
5.0
9D15014
EPA 300.0
04/15/1919:37
MKS
Nitrate as N [14797-55-81
6.8
D
mg/L
5
0.20
0.50
[CALL]
EPA 353.2
04/21/19 13:45
MKS
Nitrate/Nitrite as Ne
6.8
D
mg/L
5
0.20
0.50
9D21002
EPA 353.2
04/21/1913:45
MKS
Nitrite as N [14797-65-0]^
0.017
U
mg/L
1
0.017
0.10
9DO9018
EPA 353.2
04/09/1911:26
NMN
PHA
7.8
PH
1
1.0
1.0
9D11005 SM 4500H+B-2011
04/11/1912:07
ASC
Q-01
Phosphorus[7723-14-0]^
1.4
mg/L
1
0.025
0.10
9D12018
EPA 365.4
04/15/1917:55
MKS
Sodium Adsorption Ratio
3.58
[blank]
1
9DO9035
CSU Method
04/11/19 15:11
JDH
Temperature for pH (deg. C]
19
PH
1
9D31005 5M 450011+8-2011
04/11/19 12:07
ASC
Q-01
Total Dissolved Solids-
450
mg/L
1
50
50
9DO9003
SM 254OC-2011
04/09/19 13:55
JOC
Total Kjeldahl Nitrogen-
590
D
mg/L
100
26
48
9D12017
EPA 351.2
04/15/19 13:44
MKS
Microbiological Parameters
^ -EA o Gy rerofied analyte(NC 59I1
Analyte rCAS Numbed Results
III
Units
DF
P L
Batch
Method
AFL nal ed
B
_I
N to
Coliform, Fecal^
1.0
U
MPN/100 mL
1
1.0
9D09011
Colilert 18
04/09/19 11:07
MKS
Classical Chemistry Parameters
^ -ER Orlando rerofied analyte[NC 4241
Analyte FCAS Numbed Results
fiag
Units
2E
MOL
POE
Batch
Meth
ADalned
By
Notes
Phenolics^
0.034
U
mg/L
1
0.034
0.050
9D12035
EPA 420.1
04/15/1914:37
ASR
Total Organic CarbonA
5.0
mg/L
1
0.34
1.0
9DIO016 SM 531OB-2011
04/12/1901:42
Slit
FINAL 1n15 report relates only to the sample as received by the laboatory, and may only be reproduced In Pon. I Page 7 0f 39

vrarW.encolabs.com
ANALYTICAL RESULTS
Description: PB Cooling Tower
Lab Sample ID:
CC05006-02
Received: 04/08/19 10:28
Matrix: Waste Water
Sampled:
04/08/19 09:05
Work Order. CC05006
Project: Wastewater Permit Testing
Sampled BV:Yvonne Couts
Volatile Organic Compounds by GCMS
A -r errrnadedawmfn sni/
Analvte rCAS Numberl
Results
Flao
units
PFF HU
l2L
B;agh
Method
Arelvxd
B1! R91m
1,1,1,2-TetrachbroeMane[630.20-6]^
0.17
U
ug/L
1 0.17
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
1,1,1-Trkhbrce0tane [71-55-6]A
0.12
U
ug/L
1 0.12
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK QL-02
1,1,2,2-Tetrachloroethane[79-34-5]A
0.28
U
ug/L
1 0.28
1.0
9D06029
EPA 624.1
04109/1900:14
MRK
1,1,2-Trichloroethane [79.O0-5]A
0.14
U
Ug/L
1 0.14
1.0
9DO8029
EPA 624.1
04/09/19 OD: 14
MRK
1,1-Dkhloroe0wne[75-343]A
0.13
U
ug/L
1 0.13
1.0
9D08029
EPA 624.1
D4/09/1900:14
MRK
1,1-01Chtoroethene[75-35-4]A
0.21
U
ug/L
1 0.21
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
1,1-Dkhlompropene[563-58-6]A
0.15
U
ug/L
1 0.15
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
1,2,3-Trichlorobsrzene [87-61-6]A
0.01
U
ug/L
1 0.01
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
1,2,3-Trichlompropane [96-184]A
0.23
U
U9/1-
1 0.23
1.0
9DD8029
EPA 624.1
04/09/19 00:14
MRK
1,2A-Trichbrobenzene [320-82-1]A
0.14
U
ug/L
1 0.14
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
1,2,4-Tdmethylberuene [95-63-6]A
0.10
U
ug/L
1 0.10
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
1,2-1)ibromo-3chloropropane [95-12-8]A
OAS
U
ug/L
1 0.48
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
1,2-Dibromoethane [106-934]A
0.66
U
ug/L
1 0.66
1.0
9D0OD29
EPA 624.1
04/09/19 00:14
MRK
1,2-Dkhlorobenzene [95-50-11A
0.19
U
u9/1.
1 0.19
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
1,2-Dbhlorcethane [307-06-2]A
0.21
U
ugrl-
1 0.21
1.0
9D0W29
EPA 624.1
04/09/19 00:14
MRK QL-02
1,2-Dkhloroproparte [78-87-5]A
0.10
U
ug/L
1 0.10
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
1,3,5-Trimethybenzere[108-67-8]A
0.30
U
ug/L
1 0.30
1.0
9DD8029
EPA 624.1
04109/1900:14
MRK
1,3-Dichlorobenzere[541-73-1]A
0.15
U
ug/L
1 0.15
1.0
9D08029
EPA 624.1
04/09/19 OD: 14
MRK
1,3-Dichloropropane[142-28-911
0.16
U
ug/L
1 0.16
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
1,40khlorobenzene [106-46-7]A
0.19
U
ug/L
1 0.19
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
1,4-Dimcam[123-91-1]A
25
U
ug/L
1 25
60
9D09025
EPA 624.1
04/10/1902:27
MRK
2,2-Dichloropropme, [594-20-7]A
0.28
V
ug/L
1 0.28
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
2-Buthnone[78-93-3]1
1.3
U
ug/L
1 1.3
5.0
9DDB029
EPA 624.1
04109/1900:14
MRK
2.Chloroethyl Vinyl Ether [110-75-8]A
1.1
U
ug/L
1 1.1
5.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
2{hiorotoltena [95-49-B]A
0.08
U
ug/L
1 0.08
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
2-Ilmnone 1591-78-5]A
0.88
U
ug/L
1 0.88
5.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
3-Chloroproperre[107-05-1]A
0.11
U
ug/L
1 0.11
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
4-Chlomookene[10643-4]1
0.07
U
Ug/L
1 0.07
1.0
9D08029
EPA 624.1
04/09/1900:14
MRK
4-1supropyltoluere[99-876]A
0.08
U
ug/L
1 O.OB
1.0
9DD8029
EPA 624.1
04/09/19 00:14
MRK
4-Methyl-2-pentaritme [108-10-1]1
1.1
U
ug/L
1 1.1
5.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
Acetone [67-64-1]A
30
U
u9/1.
1 10
20
9D08029
EPA 624.1
04/09/19 DO:14
MRK
Acetonhdle [75-05-8]A
5.0
U
ug/L
1 5.0
10
9D08029
EPA 624.1
D4/09/19 00: 14
MRK QL-02
Acrotem [107-02-B]A
4.0
U
ug/L
1 4.0
10
9D08029
EPA 624.1
04/09/19 00:14
MRK
Actylortrile[107-13-1]A
3.5
U
ug/L
1 3.5
10
9DO8029
EPA 624.1
04/09/1900:14
MRK
Benzene[7143-2]A
0.15
U
ug/L
1 0.15
1.0
9DO8029
EPA 624.1
04/09/1900!14
MRK
Bromobenzene [108-86-1]A
0.16
U
ug/L
1 0.16
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
Bmmochluromethane[74-97-5]A
0.48
U
Ug/L
1 0.48
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
BromodichbromeMane[75-27-4]A
0.0010
U
mg/L
1
0.0010
9D08028
EPA 524.2
04/08/1913:12
SAM
Bromodichloromethane[75-274]A
0.17
U
Ug/L
1 0.17
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
Bronwform[75-25-2]A
0.0010
U
mg/L
1
0.0010
9D08028
EPA 524.2
D4/08/1913:12
SAM
Brorroform [75-25-2]A
0.22
U
119/1-
1 0.22
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
Bromomethane [74,83-9]A
0.14
U
ug/L
1 0.14
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
Carbon disulfide [75-15-0]A
1.5
U
ug/L
1 1.5
5.0
9D08029
EPA 624.1
34/09/19 00:14
MRK
Carbon tetradllodde, [56.23-5]A
0.17
U
ug/L
1 0.17
1.0
9D0B029
EPA 624.1
04/09/19 00:14
MRK QL-02
Chlombemene[108-90-7]A
0.17
U
ug/L
1 0.17
1.0
9D08029
EPA 624.1
04/09/1900:14
MRK
Chbroethane[75-00-3]A
0.23
U
ug/L
1 0.23
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
Chloroform [67-66-3]A
0.0010
U
mg/L
1
0.0010
9D08028
EPA 524.2
04/08/19 1112
SAM
riwu This report relates only
to the sample
as received by me laboratory, and may only be reproduced
in roil.
I Page 8 of 39

ANALYTICAL RESULTS
Description: PS Cooling Tower Lab Sample ID: CC05006-02
Matrix: Waste Water
Project: Wastewater Permit Testing
Sampled:04/08/19 09:05
Sampled By: Yvonne Couts
www.encelabs,com
Received: 04/08/19 10:28
Work Order: CC05006
IVolatile Organic Compounds by GCMS
A -E can, teroireN arty 1e 591)
Analvte rCASNumberl
lteed1b;
fin
PAM
OF
MDR
EU
AlitCh
Method
Analyzed
j]x ]y21112
Chloroform [67-66-31A
0.18
U
ug/L
1
0.18
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
Chlorometharte [74-87-3]1
0.13
U
u9/1.
1
0.13
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
Chloroprem[126-99-8]A
0.64
U
ug/L
1
0.64
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
cis-1,2-Dlchlomethene [156-59-2]A
0.15
U
u9/1-
1
0.15
1.0
9D08029
EPA 624.1
D4/09/19 00:14
MRK
cis-1,3-Dichbropropem[10061-01-5]A
0.20
U
ug/L
1
0.20
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
Dibromochbromethane [12448-1]A
0.0010
U
mg/L
1
0.0010
9D08028
EPA 524.2
04/08/19 13:12
BAM
Dibromochloromethane [12448-1]A
0.17
U
ug/L
1
0.17
1.0
9DO8D29
EPA 624.1
04/09/19 DO:14
MRK
Dibromomethane [74A5-3]A
0.27
U
uyL
1
0.27
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
DiChlorodlflmnomethane [75-71-8]A
D.20
U
ug/L
1
0.20
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
Ethyl MethaayWte [97-63-2]A
0.38
U
ug/L
1
0.38
1.0
9DD8029
EPA 624.1
04/09/19 00:14
MRK
Ethylbervene[300-414]A
0.13
U
ug/L
1
0.13
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
Freest 113 [76-13-1]1
0.35
U
ug/L
1
0.35
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
HezatltbrobuWdiene[87-68-3]A
0.22
U
ug/L
1
0.22
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
IodonieUtane [74-W4]A
1.7
U
ug/L
1
1.7
5.0
9D08029
EPA 624.1
04/09/19 OD: 14
MRK
Isobutyl alcohol 178-83.1]A
11
U
ug/L
1
11
50
9D08029
EPA 624.1
04/09/19 00:14
MRK QL-02
Isopropyl Ether [108-20-3]A
0.05
U
ug/L
1
0.05
1.0
9DD8029
EPA 624.1
04/09/19 00:14
MRK
Isopropylberizene [98-82-8]A
0.14
U
U911-
1
0.14
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
m,p-Xylenes [108-38-3/306-42-3]A
0.17
U
ug/L
1
0.17
2.0
9DD8029
EPA 624.1
04/09/19 00:14
MRK
Methauylonitrlle[126-98-7]A
4.9
U
ug/L
1
4.9
10
9D08029
EPA 624.1
04/09/19 00:14
MRK
Methyl Methacrylate [8D-62-6]A
0.51
U
ug/L
1
0.51
2.0
9DD8029
EPA 624.1
04/09/19 00:14
MRK
Methylene chloride [75-09-2]A
0.23
U
ug/L
1
0.23
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
Methykert-Butyl Wier[1634-044]A
0.16
U
u9/L
1
0.16
1.0
9DOBD29
EPA 624.1
04109/1900:14
MRK
Naphthalene [91-2D-3]A
0.11
U
ug/L
1
0.11
1.0
9D08029
EPA 624.1
04/09/19 DO: 14
MRK
"utyl Benzene [10451-8]A
0.06
U
tg/L
1
0.06
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
n-Propyl Benzene [103-65-1]A
0.12
U
U9/1-
1
0.12
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
c-Xylene[9547-6]A
0.06
U
ug/L
1
0.06
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
Propiwitrile [107-12-0]A
5.0
U
ug/L
1
5.0
10
9D08029
EPA 624.1
04/09/19 00:14
MRK
sec-Butylbouene [135-98-8]A
0.10
U
ug/L
1
0.10
1.0
9D08029
EPA 624.1
04/09/1900:14
MRK
Styrene[10042-5]A
0.11
U
ug/L
1
0.11
1.0
9008029
EPA 624.1
D4/09/19 00:14
MRK
tert-Butylbenzene [98-06-6]A
0.17
U
ug/L
1
0.17
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
Tetrachloroetherte [127-184]A
0.17
U
ug/L
1
0.17
1.0
9D08029
EPA 624.1
D4/09/19 00:14
MRK QL-02
Toluene[108-88-3]A
0.14
U
ug/L
1
0.14
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
Total TdhalonethanesA
0.0010
U
mg/L
1
0.0010
9DO8028
EPA 524.2
D4/08/1913:12
BAM
trans-1,2-Dichlorcedtene [156-60-5]1
0.21
U
ug/L
1
0.21
1.0
9DD8029
EPA 624.1
04/09/19 00:14
MRK
trans-1,3-Dichloropropene[IDD61-02-6]1
0.15
U
ug/L
1
0.15
1.0
9D0B029
EPA 624.1
04/09/19 00:14
MRK
tens-1,4-Dichloro-2-butene[310-57-6]A
0.70
U
ug/L
1
0.70
1.0
9DO8029
EPA 624.1
04/09/19 00:14
MRK
Tnchloroethene[79-01.6]A
0.15
U
ug/L
1
0.15
1.0
9D08029
EPA 624.1
04109/1900:14
MRK
Trkhbrofluoronethane[75-694]A
0.24
U
ug/L
1
0.24
1.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
Vinyl acetate [108-054]A
0.95
U
ug/L
1
0.95
5.0
9D08029
EPA 624.1
04/09/19 00:14
MRK
Vinyl chloride [75-01-4]A
0.32
U
u9/L
1
0.32
1.0
9D0BD29
EPA 624.1
04/09/19 00:14
MRK
Xylenes(Total)[1330-20-7]A
0.24
U
ug/L
1
0.24
3.0
9DDS029
EPA 624.1
04/09/19 00:14
MRK
Aaroeahas
Resu/Gs
DE
Spike I
%Rec
%Rec
L
dQH(YZad
By Notes
1,1-DychbWbW d4
18
1
25.0
Ill %
70-130
9D08028
EPA 524.2
04/08/1913.12
84M
4-EmmoActiwbenzene
27
1
25.0
106 %
70-130
9D08028
EPA 524.2
0410811913.12
84M
4-eroftwfiwtobenzene
70
1
50.0
140 %
53-136
9D08029
EPA 524.1
OV0119 00.14
MRK QS 03
4-Brona91.nrobenzene
57
1
50.0
115%
53-136
9D09023
EPA 624.1
04110119 02 27
MRK
Dibromoflwromelhane
51
1
50.0
104 %
67-129
9D08029
EPA 624.1
0410911900:14
MRK
Ht This
report relates only
to the sample as reasyed by the bboatory, and may only be reproduces
in U.
I Page 9 0] 39

v7ww.encolabs.com
ANALYTICAL RESULTS
Description: PB Cooling Tower
Lab Sample ID:CCO5006-02 Received: 04/08/19 10:28
Matrix: Waste Water
Sampled: 04/08/19 09:05 Work Order: CCO5006
Project: Wastewater Permit Testing
Sampled By:Yvonne Couts
Volatile Organic Compounds by GCMS
^ . FNl/1I-Mr Is, I
51fimwates Resu/Ls
DF
SPriI
%Rec
%Rec Cimler
Ba
MNI
Md/vxd
By Notes
DMIMMoNuoromerhane 58
1
50.0
116 %
67-129
9DO9025
EGA 6141
04110119 0217
MRK
roluyi -d8 52
1
50.0
10491
59-134
9DD8029
EPA 624.1
04109119 00.-14
MRK
To/ue/Ie-& 58
I
50.0
116 %
59-134
9009025
EPA 624.1
04110119 02,27
MRK
Metals by EPA 200 Series Methods
^ -es Co ferry Celabed anall4e [MC 5911
Analyte rCAS Numberl Result£
flog
unite
PE
KU M
$Ai6h
Method
Analyzed
pY Note
Calcium [7440-70-21^ 33400
ug/L
1
39.0 100
9D09035
EPA 200.7
04/11/19 12:02
JDH
Magnesium[7439-95-4]A 10600
ug/L
1
29.0 100
9DO9035
EPA 200.7
04/11/1912:02
JDH
Sodium [7440-23-5]A 91400
ug/L
1
400 500
9DO9035
EPA 200.7
04/11/19 12:02
JDH
Classical Chemistry Parameters
^ - EMCo [ary rem5ro a/
Analyte rCAS Numberl
Ammonia as N [7664-01-71A
Biochemical Oxygen Demand^
Chemical Oxygen Demand^
Chloride [16887-00-6]A
Nitrate as N [14797-55-8)
Nitrate/Nitrite as NA
Nitrite as N [14797-65-01A
pHA
Phosphorus [7723-14-0]A
Sodium Adsorption Ratio
Temperature for pH (deg. C)
Total Dissolved Solids -
Total Kjeldahl NitrogenA
Parameters
^ -£Am Gry remi
Analytic fCAS Numberl
Coliform, Fecal -
f149 1/Llti
0.045
U
mg/L
2.0
U
mg/L
21
mg/L
68
mg/L
6.5
D
mg/L
6.5
D
mg/L
0.017
U
mg/L
7.9
PH
1.5
mg/L
3.52
[blank]
20
PH
440
mg/L
0.64
mg/L
FF MU P4L Batch Method Analyzed @Y Notes
1 0.045 0.10 9D18015 EPA 350.1 04/18/19 12:50 MKS
1 2.0 2.0 9D10003 SM 5210 8-2011 04/10/19 08:24 JOC
1 10 10 9D09009 SM 5220D-2011 04/09/19 19:56 JOC
1 2.2 5.0 9D15014 EPA 300.0 04/15/19 19:52 MKS
5 0.20 0.50 [CALC] EPA 353.2 04/21/19 13:46 MKS
5 0.20 0.50 9D21002 EPA 353.2 04/21/19 13:46 MKS
1 0.017 0.10 9DO9018 EPA 353.2 04/09/1911:29 NMN
1 1.0 1.0 9D11005 5M 4500H+B-2011 04/11/19 12:07 ASC Q-01
1 0.025 0.10 9D12018 EPA 365.4 04/15/19 16:53 MKS
1 9DO9035 CSU Method 04/11/19 15:11 JDH
1 9D11005 5M 4500H+6-2011 04/11/19 12:07 ASC Q-01
1 50 50 9DO9003 SM 254OC-2011 04/09/19 13:55 JOC
1 0.26 0.48 9D12017 EPA 351.2 04/15/19 15:58 MKS
Results Fiale Units OF PQL Batch Method Analyzed By Note
1.0 U MPN/100 mL 1 1.0 9DO9011 Coblert 18 04/09/19 11:07 MKS
JClassical Chemistry Parameters
^ -EMCo 6Nando ee/LBMa vAre [MC 424]
Analyte rCAS Numberl Results
flag MD&
PF MOIL
EQL
RaLrb Method Analyzed @Y Notes
PhenalicsA 0.034
U mg/L
1 D.034
0.050
9D12035 EPA 420.1 04/15/1914:37 ASR
Total Organic Carbon^ 5.1
mg/L
1 0.34
1.0
9D10016 SM 531OB-2011 04/12/19 01:42 S1R
FINAL This report relates only to the sample as received by me laboato, and may only be reproduced in toll. I Page 10 of 39

w .encolabs.cum
ANALYTICAL RESULTS
Description: Trip Blank Lab Sample ID:CC05D06-03 Received: 04/08/19 10:28
Matrix: Water Sampled: 04/08/19 09:00 Work Order: CC05006
Project: Wastewater Permit Testing Sampled By: ENCO
Compounds by GCMS
Analyte fCAS Numberl
Reader
fLaR
Motu
OF
HU
PQL
Alli7Gh
Method
Analyzed
ft
Notes
1,1,1,2-Tebachbrcethane(630-20-6]1
0.17
U
ug/L
1
0.17
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
1,1,1-Trichbroetham[71-55-6]^
0.12
U
ug/L
1
0.12
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
QL-02
1,1,2,2-Tebachbroethane[79-34-5]A
0.28
U
ug/L
1
0.28
1.0
9M029
EPA 624.1
04/09/19 00:45
MRK
1,1,2-Trichbroethane[79-00-5]^
0.14
U
ug/L
1
0.14
1.0
9D08029
EPA 624.1
04/09/1900:45
MRK
1,1-0ichlorue0tzne[75-34-3]A
0.13
U
ug/L
1
0.13
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
1,1-Dkhbroe!Ji n [75-3541A
0.21
U
ug/L
1
0.21
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
1,1-Dichloropropene[563-58-6]1
0.15
U
ug/L
1
0.15
1.0
9D08029
EPA 624.1
04/0911900:45
MRK
1,2,3-Trichlorobenzene(87-61-6]1
0.01
U
ug/L
1
0.01
1.0
9D08029
EPA 624.1
D4/09/1900:45
MRK
1,2,3-Trichloropropane[96-18-4]^
0.23
U
u9/1.
1
0.23
1.0
9DO8029
EPA 624.1
04/09/19 00:45
MRK
1,2,4-Trbhlorobenzene[120-82-1]^
0.14
U
ug/L
1
0.14
1.0
9D08029
EPA 624.1
04/09/1900:45
MRK
1,2,4-Trimethylbemene[95-63.6]^
0.10
U
ug/L
1
0.10
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
1,2-Dibromo-3-chbropropane[96-12-8]A
0.48
U
ug/L
1
0.48
1.0
9DD8029
EPA 624.1
04/09/1900:45
MRK
1,2-Dibromoethane[506-934]A
0.66
U
ug/L
1
0.66
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
1,2-Dbhlorobemmne[95-50.1]^
0.19
U
ug/L
1
0.19
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
1,2-Dichloroethaoe[307-06-2]^
0.21
U
ug/L
1
0.21
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
QL-02
1,2-Dichloropropane[78-87-5]^
0.10
U
ug/L
1
0.10
1.0
9DO8029
EPA 624.1
04/09/19 00:45
MRK
1,3,5-Trimethylbereene[108-67-B]^
0.30
U
ug/L
1
0.30
1.0
9D0W29
EPA 624.1
04/09/19 00:45
MRK
1,3-Dichlorobenzene[541-73-1]^
0.15
U
ug/L
1
0.15
1.0
9D08029
EPA 624.1
04109/1900:45
MRK
1,3-DichbroprWane[142-28-9]^
0.16
U
ug/L
1
0.16
1.0
9D08029
EPA 624.1
04109/1900:45
MRK
1,4-Dichlombenzene[106-46-7]^
0.19
U
ug/L
1
0.19
1.0
9D0B029
EPA 624.1
04/09/19 00:45
MRK
1,4-Dioxam[123-91-1]^
25
U
ug/L
1
25
60
9D09025
EPA 624.1
04/10/1902:58
MRK
2,2-Dkhbropropane[594-20-7]^
0.28
U
ug/L
1
0.28
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
2-Butancre[78-93-3]^
1.3
U
ug/L
1
1.3
5.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
2-Chbrcethyl Vinyl Ether [110-75-8]^
1.1
U
ug/L
1
1.1
5.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
2-ChbrotDimm[9549.8]^
0.08
U
ug/L
1
0.08
1.0
9DD8029
EPA 624.1
04109/1900:45
MRK
2-Hexanone[591-78-61^
0.88
U
ug/L
1
0.88
5.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
3-Chloropropene[307-05-1]^
0.11
U
Ug/L
1
0.11
1.0
9D08029
EPA 624.1
04/09/1900:45
MRK
4-Chlorotoluene[106-434]^
0.07
U
U91L
1
0.07
1.0
9D08029
EPA 624.1
04/09/1900:45
MRK
4-Isopropyltolmm [99-87-6]^
0.08
U
Ug/L
1
0.08
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
4-Methyl-2-pentamre[108-10-1]^
1.1
U
ug/L
1
1.1
5.0
9DO8029
EPA 624.1
04/09/19 00:45
MRK
Acetone(67-64-1]^
10
U
ug/L
1
10
20
9D08029
EPA 624.1
04/09/19 00:45
MRK
Acehmilbile[75-05-8]^
5.0
U
ug/L
1
5.0
10
9D08029
EPA 624.1
04/0911900:45
MRK
QL-02
Acrolein[107-02-8]^
4.0
U
ug/L
1
4.0
10
9D08029
EPA 624.1
04/09/19 00:45
MRK
Acrylonitrile[307-13-1]^
3.5
U
ug/L
1
3.5
10
9DD8029
EPA 624.1
04/09/19 00:45
MRK
Benzene [7143-2]^
D.15
U
ug/L
1
0.15
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Bromobenzene[108-86-1]^
0.16
U
ug/L
1
0.16
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Bromochloranetha a [74-97-5]1
0.48
U
ug/L
1
0.48
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Bromodichloromethane [75-274]^
0.0010
U
mg/L
1
0.0010
9D08028
EPA 524.2
04/08/19 13:47
BAM
Bromodichloromethane [75-27-4]^
0.17
U
ug/L
1
0.17
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Bromoform [75-25-2]^
0.0010
U
mg/L
1
0.0010
9D08028
EPA 524.2
04/08/19 13:47
BAM
Bromoform [75-25-2]^
0.22
U
ug/L
1
0.22
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Bromomethane [74-83-9]^
0.14
U
ug/L
1
0.14
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Carbon disu8ide [75-15-0]^
1.5
U
ug/L
1
1.5
5.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Carbon tetrachloride [56-23-5]^
0.17
U
ug/L
1
0.17
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
QL-02
Chbrobenzene[108-90.7]^
0.17
U
ug/L
1
0.17
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Chloroet are [75-00-3]^
0.23
U
ug/L
1
0.23
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Chloroform [67-66-3]^
0.0010
U
mg/L
1
0.0010
9D08028
EPA 524.2
04/08/19 13:47
8AM
nlN
this report relates only to the sample as rerelved by me laboratory, ans may only be repnxl c
in toll.
I Page 11 Of 39

www.encolabs.com
AMALYTICAL RESULTS
Description: Trip Blank
Lab Sample ID; CC05006-03
Received: 04/08/1910:28
Matrix: Water
Sampled:04/08/1909:00
Work Order. CCO5006
Project: Wastewater Permit Testing
Sampled By: ENCO
Volatile Organic Compounds by GCMS
^ -EALD Gry ce VAed awlOe 7 191,
Analvte rcASNumber]
Results
Flan
3tLt6
DE
MPL
EQL
eandt
Metbod
Ana31¢11d
By notes
Chloroform [67-66-3]^
0.18
U
ug/L
1
0.18
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Chlorameftm[74-87-31A
0.13
U
tg/L
1
0.13
1.0
9DDS029
EPA 624.1
04/09/19 00:45
MRK
Chloroprene[126-99-8]A
0.64
U
ug/L
1
0.64
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
cis-1,2-0khbroetherte[156-59-2]A
0.15
U
ug/L
1
0.15
1.0
9D08029
EPA 624.1
04/09/1900:45
MRK
cis-1,3-Dlchbropropts a [10061-01-5]A
0.20
U
ug/L
1
0.20
1.0
9D08029
EPA 624.1
D4/09/19 00:45
MRK
DibromochbromeMam [12448-1]A
0.0010
U
mg/L
1
0.0010
9D08028
EPA 524.2
04/08/1913:47
RAM
Dibromochbmrnethane[12448-1]^
0.17
U
u9/1.
1
0.17
1.0
9D08029
EPA 624.1
04/0911900:45
MRK
Dibrornomethane [74.95-3]A
0.27
U
ug/L
1
0.27
1.0
9DO8029
EPA 624.1
04/09/19 D0:45
MRK
Dkhbrodifluwomethane[75-71-8]A
0.20
U
Ug/L
1
0.20
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Ethyl Methacrybte [97-63-2]A
0.38
U
Ug/L
1
0.38
1.0
9DD8029
EPA 624.1
04/09/19 00:45
MRK
Ethylbenzene[10D-414]^
0.13
U
ug/L
1
0.13
1.0
9D08029
EPA 624.1
04109/1900:45
MRK
Freon 113 [76-13-11A
0.35
U
ug/L
1
0.35
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Heicachlorobubdlene [87-68-3]1
0.22
U
ug/L
1
0.22
1.0
9DO8029
EPA 624.1
04/09/19 00:45
MRK
]odomethane[74.884]A
1.7
U
Ug/L
1
1.7
5.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Isobutyl alcohol [78-83-1]A
11
U
Ug/L
1
11
50
9DD8029
EPA 624.1
04/09/19 00:45
MRK QL-02
Isopropyl Ether [108-20-3]A
0.05
U
ug/L
1
0.05
1.0
9D08029
EPA 624.1
04/09/19 DDAS
MRK
Isopropylbeo:ene [98-82-8]^
0.14
U
ug/L
1
0.14
1.0
9D08029
EPA 624.1
D4/09/19 00:45
MRK
m,p-Xylenes[108-38-3/106-42-3]A
0.17
U
ug/L
1
0.17
2.0
9DD8029
EPA 624.1
04/09/19 00:45
MRK
Methacrybnibile[126A8-7]^
4.9
U
ug/L
1
4.9
10
9D08029
EPA 624.1
04/09/19 W:45
MRK
Methyl Methacrylate [80-62-6]A
0.51
U
ug/L
1
0.51
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Methylene chloride [75-09-2]A
0.23
U
U91L
1
0.23
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Methylrert-Butyl Ether[1634-04-4]^
0.16
U
ug/L
1
0.16
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Naphthalene,[91-2D-3]^
0.11
U
ug/L
1
0.11
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
rt-Butyl Benzene[10451-8]A
0.06
U
ug/L
1
0.06
1.0
9DO8029
EPA 624.1
04109/1900:45
MRK
n-Propyl Benzene[30365-1]A
0.12
U
ug/L
1
0.12
1.0
9D08029
EPA 624.1
04109/1900:45
MRK
o-Xylene [9547-6]^
0.06
U
ug/L
1
0.06
1.0
9D08029
EPA 624.1
04/09/19 D0:45
MRK
Propionirile[107-12-0]A
5.0
U
ug/L
1
5.0
10
9DO8029
EPA 624.1
04/09/19 00:45
MRK
sec-Butylbenzene[135-986]A
0.10
U
ug/L
1
0.10
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Styrerte[10042-5]A
0.11
U
ug/L
1
0.11
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
ten-Butylbenzene[98-06-6]^
0.17
U
ugiL
1
0.17
1.0
9DO8029
EPA 624.1
04/09/19 00:45
MRK
Tetrachbroethene [127-184]A
0.17
U
ug/L
1
0.17
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK QL-02
Toluene [108-W3]A
0.14
U
ug/L
1
0.14
1.0
9DD8029
EPA 624.1
04/09/19 00:45
MRK
Total Tnhabmethanes^
0.0010
U
m9/L
1
0.0010
9DO8028
EPA 524.2
04/08/1913:47
BAM
trans-1,2-Dichkaoethene jl%-60-5]A
0.21
U
ug/L
1
0.21
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
tens-1,3-Dkldoropropene[10061-026]A
0.15
U
ug/L
1
0.15
1.0
9D08029
EPA 624.1
D4/09/19 00:45
MRK
trans-1,4-Dichkxo-2-butene[110-576]A
0.70
U
ug/L
1
0.70
1.0
9DO8029
EPA 624.1
04/09/19 00:45
MRK
Tnchlorcedtene (79-016)A
0.15
U
ug/L
1
0.15
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Trichbrodwromethane [7569.4]A
0.24
U
Ug/L
1
0.24
1.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Vinyl acetate [108-054]A
0.95
U
ug/L
1
0.95
5.0
9D08029
EPA 624.1
04/09/19 00:45
MRK
Vinyl chloride[75-014]A
0.32
U
ug/L
1
0.32
1.0
9D08029
EPA 624.1
04/09/19 D0:45
MRK
Xylenes (Total) [1330-20-771
0.24
U
ug/L
1
0.24
3.0
9DD8029
EPA 624.1
D4/09119 00:45
MRK
Siannoat"
2E
SWAna le/
%Qe[
%Ree
LlmRs
BdJ1y1A
sr Notes
1,1-OxMombenzene-d4
28
1
25.0
111 %
70.130
9D08028
FPA 524.2
0110811913:47
BAM
4-8mmaNuorrxi zewe
16
1
25.0
106%
70-130
9D08018
EPA 524.2
0410811913:47
AW
4-8mmo9uwobeaa6M
56
1
50.0
113 %
53-136
9DO8029
EPA 624.1
0410911900:45
MRK
4-BmmoAuaolriume
57
1
50.0
114 %
53-136
9DO9025
EPA 624.1
04110119 02:58
MRK
Dibm flLv omecharw
52
1
50.0
104 %
67-129
9D0V29
EPA 624.1
04IV911900:45
MRK
RT The report rebtes only
to the sample as receiyed by the hbcn toy, am may only
be reproduced
in fu8.
I Page 12 Of 39

w .encolabs.wm
ANALYTICAL RESULTS
Description: Trip Blank Lab Sample ID: CCO5006-03 Revived: 04/08/19 10:28
Matrix: Water Sampled:04/08/19 09:00 Work Order: CCO5006
Project: Wastewater Permit Testing Sampled By: ENCO
(Volatile Organic Compounds by GCMS
^ - ENCO 6ry reri amlNe[NC 5911
Surrogates R�gl—d�
Df
Soike [N
ale Rec
%Reg [im1Ls
Batch
MeA
By Notes
Dibrom Hotta tni 59
1
50.0
117 %
67-129
9DO9025
EGA 624.1
041JO119 01:58
MRK
Toluene -dB 53
1
50.0
106 %
59-134
9DO9029
EGA 624.1
04109119 00.45
MRK
Toluene-d8 58
1
50.0
117 %
59-134
9D09015
EGA 624.1
04110119 02.58
MRK
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page: 13 Of 39

www.encolabs.com
QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Hatch 9DO8028 - EPA 524.2
Blank (9D08028-BLK1) Prepared: 04/08/2019 09:18 Analyzed: 04/08/201912:02
Spike
Source
a/.REC
RPD
Anal Y[e
RSE1dt
HIM
P91
Units
Level
Result %REC
Limi RPD
(,(mit Notes
Bromodkhloromethane
0.0010
U
0.0010
mg/L
Bromoform
0.0010
U
0.0010
mg/L
Chloroform
0.0010
U
0.0010
mg/L
Dibromochlorometham
0.0010
U
0.0010
mg/L
Total Trihakimethanes
0.0010
U
0.0010
mg/L
1,2-V0W&0denzerard4
27
zg2
25.0
109
70-130
4-8mnwlwtVb ¢ene
26
"94
25.0
105
70-130
LCS (90H08028-13SI)
Prepared: 04/08/2019 09:18 Analyzed: 04/08/2019 10:51
Spike
Source
%REC
RPD
Ana(
Result
Hag
PM
Units
Level
Re,Eu(t %REC
Limb RPD
Limit Hotel
Bromodbhbromethane
0.0052
0.0010
mg/L
0.00500
105
70-130
Bromoform
0.0044
0.0D10
mg/L
0.00500
89
70-130
Chloroform
0.0051
0.0010
mg/L
0.00500
101
70.130
Dibromochbromethane
0.0054
0.0010
mg/L
0.00500
108
70-130
1,2-Oichkirodenzene-d4
29
WL
25.0
115
70-130
4-Brpmofluorobmzene
29
10
25.0
115
70-130
Balch 9DO8029 - EPA 50305 MS
Blank (9008029-BLK1)
Prepared: 04/08/2019 00:56 Analyzed: 04/D8/2019 14:48
Spike
Source
%REC
RPD
Anal ffls
Result
Hag
M
Units
Level
Basin %REC
Limits RPD
Limit Notes
1,1,1,2-Tetwhloroetham
0.17
U
1.0
ug/L
1,1,1-Trichlometbane
0.12
U
1.0
ug/L
1,1,2,2-Tebachloroethane
0.28
U
1.0
ug/L
1,1,2-Trichkxoethane
0.14
U
1.0
ug/L
1,1-Dbhknoethmie
0.13
U
1.0
ug/L
1,1-Dichloroetbene
0.21
U
1.0
ug/L
1,1-Dbhloropropene
0.15
U
1.0
ug/L
1,2,3-Trichbrobenzene
0.01
U
1.0
ug/L
1,2,3-Trichkvopropane
0.23
U
1.0
ug/L
1,2,4-Trkhbroberuene
0.14
U
1.0
ug/L
1,2,4-Trimethylbenzene
0.10
U
1.0
ug/L
1,2-Dibromo-3KhbroproPane
0.48
U
1.0
ug/L
1,2-Dibromoethane
0.66
U
1.0
ug/L
1,2-Dichlorobenzene
0.19
U
1.0
ug/L
1,2-Dichbroelham
0.21
U
1.0
u9/L
1,2-Dichlompmpane
0.10
U
1.0
ug/L
1,3,5-Trimethylbenzene
0.30
U
1.0
ug/L
1,3-Dbhlorobemne
0.15
U
1.0
ug/L
1,3-Dichloropropane
0.16
U
1.0
ug/L
1,4-Dichlombenzme
0.19
U
1.0
ug/L
1,4-Dimame
25
U
60
ug/L
2,2-Dkhkiropropane
0.28
U
1.0
ug/L
2-Butanone
1.3
U
5.0
ug/L
2-Chloroethyl Vinyl Ether
1.1
U
5.0
ug/L
2-Chlorotohrene
0.08
U
1.0
ug/L
RNA
This report relates only to the sample in, received by the
koomtory, and
may only be reproau<ea in M.
Page 14 Of 39

CNCO
www.encolabs.com
QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 9008029 - EPA 5030ABMS - Continued
Blank (9D08029-13M) Continued Prepared: 04/08/2019 00:56 Analyzed: 04/08/2019 14:48
Anal vte
Result
Ran
POL
Units
2-Heranoce
0.88
U
5.0
ug/L
3-Chlompropene
0.11
U
1.0
ug/L
4-Chlorotoluene
0.07
U
1.0
ug/L
4-Iscpropyltoluene
0.08
U
1.0
ug/L
4-Methyl-2-pentanone
1.1
U
5.0
ug/L
Acetone
10
U
20
ug/L
Acetonitrile
5.0
U
10
ug/L
Acrolein
4.0
U
10
ug/L
Acrylonitnle
3.5
U
10
ug/L
Benzene
0.15
U
1.0
ug/L
Bromobenzene
0.16
U
1.0
ug/L
Bromochloromethane
0.48
U
1.0
ug/L
Bromodichlorometharie
0.17
U
1.0
ug/L
Bromoform
0.22
U
1.0
ug/L
Bromomethane
0.14
U
1.0
ug/L
Carbon disulifide
1.5
U
5.0
ug/L
Carbon tetrachloride
0.17
U
1.0
ug/L
Chlorobenzene
0.17
U
1.0
ug/L
Chlorcethane
0.23
U
1.0
ug/L
Chloroform
0.18
U
1.0
ug/L
Chlorometharie
0.13
U
1.0
ug/L
Chloroprene
0.64
U
1.0
ug/L
cis-1,2-Dichlorcethene
0.15
U
1.0
ug/L
cis-1,3-Dichloropropene
0.20
U
1.0
ug/L
Dibmmochloromethane
0.17
U
1.0
ug/L
Dibromomethane
0.27
U
1.0
ug/L
Dlchlorodifluoromethane
0.20
U
1.0
ug/L
Ethyl Methacrylate
0.38
U
1.0
ug/L
Ethylbenzene
0.13
U
1.0
ug/L
Freon 113
0.35
U
1.0
ug/L
Hexachlorobutadiene
0.22
U
1.0
ug/L
Iodomethane
1.7
U
5.0
ug/L
Isobutyl alcohol
11
U
50
ug/L
Isopropyl Ether
0.05
U
1.0
ug/L
lsopropylbenzene
0.14
U
1.0
ug/L
m,p-Xylenes
0.17
U
2.0
ug/L
Methwrylonibile
4.9
U
10
ug/L
Methyl Methacrylate
0.51
U
1.0
u9/L
Methylene chloride
0.23
U
1.0
ug/L
Methyl-tert-Butyl Ether
0.16
U
1.0
ug/L
Naphthalene
0.11
U
1.0
ug/L
n-Butyl Benzene
0.06
U
1.0
ug/L
n-Propyl Benzene
0.12
U
1.0
ug/L
o-Xylene
0.06
U
1.0
ug/L
Propionibile
5.0
U
10
ug/L
sec-Butylbenzene
0.10
U
1.0
ug/L
Styrene
0.11
U
1.0
ug/L
tert-Butylbenzene
0.17
U
1.0
ug/L
Tetrachlorcethene
0.17
U
1.0
ug/L
Spike Source %REC
Level Result %REC Limits RPD
licLit
RPD
Notes
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 15 of 39

www.encolabs.com
QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 9DO8029 - EPA 5030B MS - Continued
Blank (9D08029-BLKl) Continued
Prepared: 04/08/2019 00:56 Analyzed: 04/08/2019 14:48
Spike Source
^/oREC
RPD
Anal vte
Resin
Hag
P12L
Units
Level Result
%REC
Limits RPD
Limit Notes
Toluene
0.14
U
1.0
ug/L
tans-1,2-Dichlorcethene
0.21
U
1.0
ug/L
trans-1,3-Dichloropropene
0.15
U
1.0
ug/L
trans-1,4-Dichloro-2-butene
0.70
U
1.0
ug/L
Trichlorcethene
0.15
U
1.0
ug/L
Trkhlorofluoromethane
0.24
U
1.0
ug/L
Vinyl acetate
0.95
U
5.0
ug/L
Vinyl chloride
0.32
U
1.0
ug/L
%ylenes (Total)
0.24
U
3.0
ug/L
4-eiomo77uombewene
55
u9/L
50.0
110
53-136
DINO/➢00wromethaw
53
u9/L
50.0
106
67-129
To/uenrd8
51
ug/L
50.0
101
59-134
LCS (911,08029-651)
Prepared: 04/08/2019 00:56 Analyzed: 04/08/2019 13:45
Spike Source
%REC
RPD
Ana1L'tS
Result
Hag
EOL
Units
Level Result
%REC
Limits RPD
Limit Notes
1,1, 1,2-Tetnachlorcethane
18
1.0
ug/L
20.0
92
71-117
1,1,1-Trichloroethane
26
1.0
ug/L
20.0
132
70-130
QL-02
1,1,2,2-Tetrachloroethane
15
1.0
ug/L
20.0
76
60-140
1,1,2-Trichlorcethane
17
1.0
ug/L
20.0
86
70-130
1,1-Dichbrcethane
23
1.0
ug/L
20.0
114
70-130
1,1-Dichloroethene
23
1.0
ug/L
20.0
116
50-150
1,1-Dichoropropane
23
1.0
ug/L
20.0
115
70-129
1,2,3-Tdchkxobenzene
20
1.0
ug/L
20.0
101
62-117
1,2,3-Trkhloropropane
19
1.0
ug/L
20.0
93
58-140
1,2,4-Trichlorobenzem
21
1.0
ug/L
20.0
105
59-122
1,2,4-Trimethylbenzene
17
1.0
ug/L
20.0
87
74-123
1,2-Dibromo-3-chloropropane
17
1.0
ug/L
20.0
86
37-157
1,2-Dibromoetham
20
1.0
ug/L
20.0
99
66-123
1,2-Dichlorobemene
18
1.0
ug/L
20.0
92
65-135
1,2-Dichlorcethane
28
1.0
ug/L
20.0
139
70-130
QL-02
1,2-Dichloropropane
19
1.0
ug/L
20.0
94
35-165
1,3,5-Trimethylbemene
18
1.0
ug/L
20.0
89
77-129
1,3-Dichlorobenzene
18
1.0
ug/L
20.0
88
70-130
1,3-Dichloropropane
18
1.0
ug/L
20.0
92
60-129
1,4-Dichlorobenzene
17
1.0
ug/L
20.0
86
65-135
1,4-Dloxane
25
U
60
ug/L
20.0
10-200
2,2-Dichloropropane
26
1.0
ug/L
20.0
130
21-167
2-Butanone
20
5.0
ug/L
20.0
99
36-135
2-Chloroethyl Vinyl Ether
36
5.0
ug/L
40.0
90
5-225
2-Chlorotoluen,
16
1.0
ug/L
20.0
80
73-135
2-Hexanone
16
5.0
ug/L
20.0
80
36-191
3-CNoropropene
19
1.0
ug/L
20.0
96
17-147
4-Chlorotoluene
17
1.0
ug/L
20.0
83
76-134
4-Isopropyltolaene
17
1.0
ug/L
20.0
85
75-127
4Methyl-2-pentanone
18
5.0
ug/L
20.0
89
56-166
Acetone
29
20
ug/L
20.0
147
10-158
Acetonitrile
160
10
ug/L
20.0
777
30-200
QL-02
Acrolein
24
10
ug/L
40.0
61
6o-140
FINAL This
report relates only to the
sample as
received by the
laboratory, and may only be reproduced in full.
Page 16 of 39

EUS 00)
www.encolabs.com
QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 9DO8O29 - EPA 5O3OB MS - Continued
LCS (9D08029-BS1) Continued Prepared: 04/0812019 00:56 Anah/zetl: 04JOB12019 13:45
$Pike
Source
%REC
Apt
gu�dL
pim PM
Unkli
Level
Result %REC
Limits RPD
Acrylonioile
52
10
ug/L
60.0
86
60-140
Benzene
19
1.0
ug/L
20.0
96
65-135
Bromobemene
21
1.0
ug/L
20.0
104
72-115
Bmmochloromethane
25
1.0
u9/1.
20.0
127
74-128
Brortwdichbromethane
24
1.0
ug/L
20.0
121
65-135
Bromoform
20
1.0
ug/L
20.0
100
70-130
Bromonledaane
18
1.0
U9/1.
20.0
92
15-185
Carbon disulfide
18
5.0
ug/L
20.0
92
65-173
Carbon tetrachloride
28
1.0
Ug/L
20.0
138
70-130
Chlombenzene
19
1.0
ug/L
20.0
97
65-135
Chloroethzne
23
1.0
ug/L
20.0
116
40-160
Chloroform
24
1.0
ug/L
20.0
118
70-135
Chloromethane
16
1.0
ug/L
20.0
80
5-205
Chloroprene
24
1.0
ug/L
20.0
121
33-148
cis-1,2-Dichloroethene
19
1.0
ug/L
20.0
95
69-120
cis-1,3-Dkhloropmpene
21
1.0
ug/L
20.0
105
25-175
Dibronlochloromethane
22
1.0
ug(L
20.0
108
70-135
Dibromomethaice
22
1.0
ug/L
20.0
111
76-124
Dknlmodi8uoromethane
25
1.0
ug/L
20.0
125
25-161
Ethyl Methacrylate
19
1.0
ug/L
20.0
94
51-113
EBrylbenzene
19
1.0
ug/L
20.0
93
60-140
Freon 113
44
1.0
ug/L
40.0
111
D-200
ll l hlerobutadlene
21
1.0
ug/L
20.0
106
63.114
Iodomethane
17
5.0
ug/L
20.0
87
34-140
Isobutyl akohol
790
50
ug/L
20.0
NR
10-200
Isopropyl Ether
19
1.0
ug/L
20.0
95
45-117
lsopmpylbenzene
21
1.0
ug/L
20.0
103
81-136
m,p-Xylenes
38
2.0
ug/L
40.0
94
79-121
McUacrylonioile
32
30
ug/L
20.0
159
10.200
Methyl MethacMate
21
1.0
ug/L
20.0
SOS
48-126
Methylene chloride
18
1.0
ug/L
20.0
91
60-140
Methyl-tert-Butyl Ether
23
1.0
ug/L
20.0
116
10-127
Naphthalene
19
1.0
ug/L
20.0
96
50-127
n-Butyl Benzene
17
1.0
ug/L
20.0
85
68-126
n-Propyl Benzene
19
1.0
ug/L
20.0
95
76-125
o-Xylene
19
1.0
Ug/L
20.0
95
71-125
Propiombile
17
10
ug/L
20.0
86
10-184
sec-Butylbemene
17
1.0
ug/L
20.0
85
75-122
Styrene
19
1.0
ug/L
20.0
95
78-120
tert-BuNlbenzene
17
1.0
ug/L
20.0
87
70-137
Tetrachlorcethene
34
1.0
ug/L
20.0
171
70-130
Toluene
18
1.0
ug/L
20.0
88
70-130
trans-1,2-Dichloroethene
22
1.0
ug/L
20.0
112
70-130
trans-1,3-Dichloropropene
21
1.0
ug/L
20.0
105
50-150
trans-1,4-Dkhlora-2-butene
16
1.0
ug/L
20.0
81
10-142
Trichloroethene
23
1.0
ug/L
20.0
113
65-135
Tnchlorofluoromethane
27
1.0
ug/L
20.0
136
50-150
Vinyl acetate
22
5.0
ug/L
20.0
112
10-19B
Vinyl chloride
19
1.0
ug/L
20.0
95
5-195
RPD
Lialft Notes
QL-02
QL-02
QL-02
FlN This report relates only to the sample as received by the laboratory, and may only be rmroEuced in f rl
Page 17 of 39

www.encola is.com
QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 9DO8019 - EPA 5030E MS - Continued
LCS (9D08029-ESI) Continued Prepared: 04/08/2019 00:56 Analyzed: D4/08/2019 13:45
Spike
Source
%REC
RPD
Anal llg
Resul
Hag EQL
(Rill;
Level
Result
%REC
Ljmif5 RPD
Limit Notes
Xyknes (Total)
57
3.0
u9/1-
60.0
94
77-121
4-8iomo8comeenzene
56
WIL
50.0
113
53-136
Dibramo0uoronref "
53
194
50.0
106
67-129
Toluene -a
51
U91L
50.0
102
59.134
Matrix Spike (9D08029-MSI)
Prepared: 04/08/2019 00:56 Analyzed: 04/08/2019 12:41
Source: CCO5678-03
Spike
Source
%REC
RPD
Anal
Rasa
Hag E41
11n1b
Level
Result
%REC
Limits RPD
Lilla Notes
1,1,1,2-Tebazhloroetham
is
1.0
ug/L
20.0
0.17 U
92
71-117
1,1,1-Trkhloroethaw
29
1.0
ug/L
20.0
0.12 U
146
70-130
QM-07
1,1,2,2-Tetrachbrcethane
15
1.0
ug/L
20.0
0.28 U
76
6D-140
1,1,2-Trkhbroethane
19
1.0
ug/L
20.0
0.14 U
93
70-130
1,1-Dkhloroethane
24
1.0
ug/L
20.0
0.13 U
120
70-130
1,1-Dkhkin ethene
23
1.0
ug/L
20.0
0.21 U
115
50-150
1,1-Dkhkiropropene
23
1.0
u9/1.
20.0
0.15 U
113
70-129
1,2,34rihloroberuz!ne
21
1.0
u9/L
20.0
0.01 U
106
62-117
1,2,3-Trichloropropam
20
1.0
ug/L
20.0
0.23 U
99
58-140
1,2,4-Trichkxobenzene
20
1.0
ug/L
20.0
0.14 U
101
59-122
1,2,4-Tdmethylbenzene
17
1.0
ug/L
20.0
0.10 U
87
74.123
1,2-Dibromo-3chloropropane
19
1.0
ug/L
20.0
0.48 U
94
37-157
1,2-Dibromoethane
20
1.0
ug/L
20.0
0.66 U
98
49-155
1,2-Dkhlorobenzene
18
1.0
ug/L
20.0
0.19 U
89
65-135
1,2-Dichlocetham
29
1.0
ug/L
20.0
0.21 U
143
70-130
QM-07
1,2-Dkhkimpropane
18
1.D
ug/L
20.0
0.10 U
89
35-165
1,3,5-Tnmethylbenzene
18
1.0
u9/L
20.0
0.30 U
91
77-129
1,3-Dirhlorobenzene
18
1.0
ug/L
20.0
0.15 U
91
7D-130
1,3-Dkhloropropane
19
1.0
ug/L
20.0
0.16 U
94
60-129
IA-Dkhlorobenzene
17
1.0
ug/L
20.0
0.19 U
86
65-135
1,4Dioxane
170
60
ug/L
20.0
25 U
860
10-200
QM-07
2,2-Dichlompropane
25
1.0
ug/L
20.0
0.28 U
123
21-167
2-Butanone
21
5.0
ug/L
20.0
1.3 U
103
36-135
2-Chloroethyl Vinyl Ether
36
5.0
ug/L
40.0
1.1 U
89
5-225
2-ChlorotAiene
16
1.0
ug/L
20.0
0.08 U
81
73-135
2-Hexannom
17
5.0
ug/L
20.0
0.88 U
83
36-191
3-Chloropropene
19
1.0
ug/L
20.0
0.11 U
95
17-147
4Chlorotoluene
16
1.0
ug/L
20.0
0.07 U
80
76-134
4-Isopropyltoluene
18
1.0
ug/L
20.0
0.08 U
88
75-127
4-Methyl-2-pentanone
18
5.0
ug/L
20.0
1.1 U
88
56-166
Acetone
30
20
ug/L
20.0
10 u
152
10-M
Acetonrtrile
170
1D
ug/L
20.0
5.0 U
830
10-200
QM-07
Acrolein
23
10
ug/L
40.0
4.0 U
57
60-140
QM-07
Acrylomtrile
46
10
ug/I.
60.0
3.5 U
77
60.140
Benzene
20
1.0
Ug/L
20.0
0.15 U
99
65-135
Bromobemene
21
1.0
ug/L
20.0
0.16 U
105
72-115
BrornoChloromethane
26
1.0
U9/1.
20.0
0.48 U
129
74.128
QM-07
Bromodkhloromethane
25
1.0
ug/L
20.0
0.17 U
125
65-135
Bromoform
20
1.0
ug/L
20.0
D.22 U
102
70.130
Bromomethane
22
1.0
ug/L
20.0
0.14 U
111
15-185
Carbon disulfide
19
5.0
ug/L
20.0
1.5 U
94
65-173
DIAL
This report relates only to the sample as
received by the
laboratory, am may, only be reproduces in M.
Page 18 D( 39

ENS ' iiis,))
www.encolabs.com
QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 9DOS029 - EPA 50308_AIS - Continued
Matrix Spike (9D08029-MS3) Continued Prepared: 04/08/2019 00:56 Analyzed: D4/08/2019 12:41
Source: CCO5678-03
Spike
Source
%REC
RPD
Apace
Result
pap EQL
Units
Level
Re911S
%REC
Limits RPD
Maui Notes
Carbon tetrachloride
28
1.0
ug/L
20.0
0.17U
142
70-130
QM-07
Chlorobenzene
19
1.0
ug/L
20.0
0.17 U
95
65-135
Chioroeftim
21
1.0
ug/L
20.0
0.23 U
107
40-160
Chloroform
23
1.0
ug/L
20.0
0.18 U
117
70-135
Chloromethane
IS
LD
ug/L
20.0
0.13 U
74
5-205
Chkwoprene
24
1.0
ug/L
20.0
0.64 U
122
33-148
cis-1,2-Dichlorcethene
21
1.0
ug/L
20.0
0.15 U
103
69-120
cis-1,3-Dichkxopropene
19
1.0
ug/L
20.0
0.20 U
97
25-175
Dibromochkxomethane
21
1.0
ug/L
20.0
0.17 U
107
70-135
Dibromome0ane
21
1.0
ug/L
20.0
0.27 U
107
76-124
Dkhlorodi8uorornethane
26
1.0
ug/L
20.0
0.20 U
129
25-161
Ethyl Methacrylate
18
1.0
ug/L
20.0
0.38 U
91
51-113
Ethylbenzene
19
1.0
u9/1-
20.0
0.13 U
93
60-140
Freon 113
50
1.0
ug/L
40.0
0.35 U
125
0-200
Hexachlorobutadiene
21
1.0
u9/L
20.0
0.22 U
106
63-114
Iodometham
19
5.0
ug/L
20.0
1.7 U
97
34-140
Isobutyl alcohol
840
50
ug/L
20.0
11 U
NR
10.200
QM-07
Isopropyl Ether
20
1.0
ug/L
20.0
0.05 U
101
45-117
Isopropylbenzene
21
1.0
Ug/L
20.0
0.14 U
103
81-136
m,p-Xylenes
38
2.0
ug/L
40.0
0.17 U
95
79-121
Methacrylonitril2
34
10
ug/L
20.0
4.9 U
172
10-200
Methyl MethacMate
22
1.0
ug/L
20.0
0.51 U
110
48-126
Methylene chloride
19
1.0
u9/1-
20.0
0.23 U
95
6D-140
Methyl-tert-Butyl Ether
23
LD
ug/L
20.0
0.16 U
114
10-127
Naphthalene
19
1.0
ug/L
20.0
0.11 U
95
50-127
n-Butyl Benzene
17
1.0
ug/L
20.0
0.06 U
86
68-126
n-Propyl Benzene,
18
1.0
ug/L
20.0
0.12 U
92
76-125
o-Xylece
19
1.0
ug/L
20.0
0.06 U
95
71-125
Propionitrile
18
10
ug/L
20.0
5.0 U
88
10-184
sec-Butylbenzeire
17
1.0
ug/L
20.0
0.10 U
85
75-122
Styrene
19
1.0
ug/L
20.0
0.11 U
96
73-120
tert-Butylberzene
18
1.0
ug/L
20.0
0.17 U
88
70-137
Tebzchloroed a
27
1.0
ug/L
20.0
0.17 U
135
7D-130
QM-07
Toluene
17
1.0
ug/L
20.0
0.14 U
84
70-130
trans-1,2-Dichlorcethene
22
1.0
ug/L
20.0
0.21 U
110
70-130
trans-1,3-Dichloropropene
21
1.0
u9/L
20.0
0.15 U
107
50.150
tans-1,4-Dichlorc-2-butene
18
1.0
ug/L
20.0
0.70 U
92
10-142
Trichloroethene
23
1.0
ug/L
20.0
0.15 U
117
65-135
Trkhlorolluoromethane
28
1.0
ug/L
20.0
0.24 U
140
50-150
Vinyl acetate
25
5.0
ug/L
20.0
0.95 U
124
30.198
Vinyl chloride
21
1.0
ug/L
20.0
0.32 U
104
5-195
Xylenes (Total)
57
3.0
ug/L
60.0
0.24 U
95
77-121
4-Brom lvixobpz¢nle
56
u3/L
50.0
112
53-136
Dibrom illuvonWhaoe
53
40
50.0
106
67-129
Takerre-dB
51
U91L
50.0
102
59.134
Matrix Spike Dup (9008029-MSD1)
Prepared: 04/08/2019 00:56 Analyzed: 04/08/2019 13:13
Source: CCO5678-03
Spike
Source
"/.REC
RPD
Anal yffi
Result
Elm PQL
Lh M
Level
Rggylt
%REC
Limits RPD
Limit Notes
MWL This report relates only to the sample as
received by the laboratory, and
may only be re,inxAcea
in mil.
Page 19 Of 39

www.encolabs.com
QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 9DO8029 - EPA 5030A MS - Continued
Matrix Spike Cup (9D08029-MSD3) Continued
Prepared: 04/DB/2019 00:56 Analyzed: 04/08/2019 13:13
Source: CC05678-03
Spike
Soucee
%REC
RPD
Anal vte
Result Hall
PQL
11C1ts
Level
Remit
%REC
Limits
RPD
LIM11
Notes
1,1,1,2-Tetrachbroethane
18
1.0
ug/L
20.0
0.17 U
92
71-117
0.7
25
1,1,1-Trichloroeftm
29
1.0
ug/L
20.0
0.12U
145
70-130
0.8
36
QM-07
1,1,2,2-Tetrachbrce0ane
16
1.0
ug/L
20.0
0.28 U
80
60-140
5
61
1,1,2-Trichbroetham
17
1.0
ug/L
20.0
0.14 U
87
70-130
6
45
1,1-Dichbroethane
26
1.0
ug/L
20.0
0.13U
128
70.130
7
40
1,1-Dichlomethene
25
1.0
ug/L
20.0
0.21 U
123
5D-150
7
32
1,1-Dichloropropene
25
1.0
ug/L
20.0
0.15 U
126
70-129
10
25
1,2,3-Trkhlorobemmne
21
1.0
ug/L
20.0
0.01 U
106
62-117
0.05
25
1,2,3-Tdchloropropane
21
1.0
U9/1,
20.0
0.23 U
106
58-140
7
25
1,2,4-Trkhlorobenzene
20
1.0
U91L
20.0
0.14 U
101
59-122
0.4
25
1,2,4-Trimethylbenzene
18
1.0
ug/L
20.0
0.10 U
90
74-123
4
25
1,2-Dibromo-3-chbmpropane
17
1.0
ug/L
20.0
0.48 U
87
37-157
7
25
1,2-Dibromcethane
21
1.0
ug(L
20.0
0.66 U
103
49-155
5
25
1,2-Dichbrobenzene
19
1.0
ug/L
20.0
0.19 U
94
65-135
6
57
1,2-Dichloroethane
29
1.0
ug/L
20.0
0.21 U
145
70.130
1
49
QM-07
1,2-Dlchbropropane
19
1.0
ug/L
20.0
0.10 U
93
35-165
5
55
1,3,5-Trimethylbename
18
1.0
ug/L
20.0
0.30U
90
77-129
1
25
1,3-Dkhlorobenume
19
1.0
ug/L
20.0
0.15 U
93
70.130
2
43
1,3-Dichbropropane
18
1.0
u9/L
20.0
0.16 U
92
60-129
2
25
1,4-Dichlorobemerte
18
1.0
ug/L
20.0
0.19 U
91
65-135
5
57
1,4Dioxane
25 U
60
ug/L
20.0
25 U
10-200
50
QM-07,
QR-05
2,2-Dichioropropane
28
1.0
ug/L
20.0
0.28 U
140
21-167
13
25
2-Butanone
22
5.0
ug/L
20.0
1.3 U
110
36-135
6
25
2-Chlorcethyl Ynyl EOrer
35
5.0
ug/L
40.0
1.1 U
88
5-225
1
71
2-Chbrotoluene
17
1.0
ug/L
20.0
0.08 U
83
73-135
2
25
2-11exenone
16
5.0
ug/L
20.0
D.88 U
82
36-191
2
25
3-Chbropropene
20
1.0
Ug/L
20.0
0.11 U
99
17-147
4
25
4-Chlono oluene
17
1.0
U9/L
20.0
0.07 U
85
76-134
6
25
4-IsopropyRoluene
18
1.0
ug/L
20.0
0.08 U
88
75-127
0.6
25
4-Methyl-2-penanone
18
5.0
ug/L
20.0
1.1 U
92
56-166
4
25
Acetone
33
20
ug/L
20.0
SOU
167
10.158
9
25
QM-07
Acetonioile
170
10
ug/L
20.0
5.0 U
842
10-200
1
25
QM-07
Acrolein
24
10
ug/L
40.0
4.0 U
59
6D-140
5
60
QM-07
Acrylonbile
52
10
ug/L
60.0
3.5 U
87
60-140
13
60
Benzene
20
1.0
Ug/L
20.0
0.15 U
99
65-135
0.2
61
Brumobenzene
21
1.0
ug/L
20.0
0.16 U
107
72-115
2
25
Bromochbrome0ane
28
1.0
ug(L
20.0
0.48 U
139
74-128
8
25
QM-07
Bromodichbromethane
24
1.0
ug/L
20.0
0.17 U
121
65-135
4
56
Bromoform
20
1.0
ug/L
20.0
0.22 U
101
70-130
1
42
Bromomethane
23
1.0
ug/L
20.0
0.14 U
113
15-185
2
61
Carbon disulfide
19
5.0
Ug/L
20.0
1.5 U
96
65-173
2
25
Carbon tetrachloride
29
1.0
ug/L
20.0
0.17 U
145
70-130
2
41
QM-07
Chbrobemene
19
1.0
ug/L
20.0
0.17 U
96
65-135
1
53
Chloroethane
24
1.0
ug/L
20.0
0.23 U
119
40-160
11
78
Chloroform
25
1.0
ug/L
20.0
0.18 U
126
70-135
7
54
Chloromethane
18
1.0
ug/L
20.0
0.13 U
92
5-205
21
60
Chbroprene
27
1.0
U9/1.
20.0
0.64 U
134
33-148
9
25
cis-1,20chloroethene
21
1.0
ug/L
20.0
0.15 U
107
69-120
4
25
cis-1,3-Dichloropropene
22
1.0
ug/L
20.0
0.20 U
109
25-175
12
58
H101
This report relates only to the
sample as
received by 8K
laboratory, and may only be nyroduced in fuL
Page
20 D1 39

www.encolabs.com
QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 9DO9029 - EPA 5030B MS - Continued
Matrix Spike Dup (9D08029-MSDI) Continued Prepared: 04/08/2019 00:56 Analyzed: 04/08/2019 13:13
Source: CCO5678-03
$Pike
Source
%REC
RPD
Anal yLe
Result
Flaq
P91
Units
Level
gLgdL
%REC
LkilM
RPD
LIMR Notes
Dibromochloromethane
23
1.0
ug/L
20.0
0.17 U
113
70-135
5
50
Dibra romethane
23
1.0
ug/L
20.0
0.27 U
113
76-124
5
25
Dichlorooilluoromeniane
28
1.0
ug/L
20.0
0.20 U
142
25-161
10
25
Ethyl Metmcrylate
18
1.0
U9/1.
20.0
0.38 U
92
51-113
2
25
Ethylbenzene
19
1.0
u9/1-
20.0
0.13 U
97
60-140
5
63
Freon 113
48
1.0
ug/L
40.0
0.35 U
120
0-200
4
25
Nexachbrobutadiene
22
1.0
u9/1.
20.0
0.22 U
110
63-114
4
25
lodomethane
21
5.0
ug/L
20.0
1.7 U
103
34-140
6
25
isobulyl alcohol
970
50
ug/L
20.0
it U
NR
10-200
14
25 QM-07
Isopropyl Ether
20
1.0
ug/L
20.0
0.05 U
102
45-117
1
25
Isopropylbenzene
21
1.0
ug/L
20.0
0.14 U
103
81-136
0.5
25
m,p-Xyienes
39
2.0
ug/L
40.0
0.17 U
99
79-121
4
25
Methacrylonitrile
34
10
u9/1.
20.0
4.9 U
168
10-200
2
25
Methyl MethacMate
18
1.0
ug/L
20.0
0.51 U
91
48-126
19
25
Methylene chloride
19
1.0
ug/L
20.0
0.23 U
97
60-140
2
28
Methyl-tert-Butyl Ether
23
1.0
ug/L
20.0
0.16 U
117
10-127
2
25
Naphthalene
19
1.0
ug/L
20.0
0.11 U
93
50-127
2
25
n-Butyl Benzene
18
1.0
ug/L
20.0
0.06 U
92
68-126
7
25
n-Propyl Benzene
19
1.0
ug/L
20.0
0.12 U
93
76-125
0.8
25
c-Xylene
20
1.0
ug/L
20.0
0.06 U
99
71-125
4
25
Propionibile
16
10
ug/L
20.0
5.0 U
79
10-184
12
25
sec-Butylbenzene
18
1.0
ug/L
20.0 -
0.10 U
91
75-122
7
25
Styrene
19
1.0
ug/L
20.0
0.11 U
94
73-120
2
25
ten-BuMbenzene
is
1.0
ug/L
20.0
0.17 U
90
70-137
3
25
Tetachloroethene
28
1.0
ug/L
20.0
0.17 U
139
70-130
2
39 QM-D7
Toluene
18
1.0
ug/L
20.0
0.14U
91
70-130
8
41
tans-1,2-Dichlorcethene
24
1.0
ug/L
20.0
0.21 U
121
70-130
10
45
tans-1,3-Dkhlonompene
23
1.0
ug/L
20.0
0.15 U
113
50-150
5
86
tans-1,4-Dkhkso-2-butene
15
1.0
ug/L
20.0
0.70 U
76
10-242
20
25
Trkhloroethene
24
1.0
ug/L
20.0
0.15 U
118
65-135
0.7
48
Trichloro0uoromethane
32
1.0
ug/L
20.0
0.24 U
160
50-150
13
84 QM-07
Vinyl acetate
26
5.0
ug/L
20.0
0.95 U
129
1D-398
4
25
Vinyl chloride
22
1.0
ug/L
20.0
0.32 U
112
5-195
7
66
Xylenes (Total)
59
3.0
ug/L
60.0
0.24 U
99
77-121
4
16
4-lkp mzene
56
ug/L
50.0
112
53-136
DibromolluoiwrreOWne
55
L91L
50.0
110
67-129
Tolrrcy &
50
WL
50.0
101
59-134
Batch 9DMO25 - EPA 5WOB MS
Blank (91I09025-81.14(I)
Prepared: 04/09/2019 12:24 Analyzed: 04/09/2019 17:54
Spike
Source
%REC
RPD
Anal
Result
Elag
E01
UnRs
Level
Result
%REC
Limi
RPD
Limit Notes
1,1,1,2-Tetachlacethane
0.17
U
1.0
ug/L
'
1,1,1-Trichbroethane
0.12
U
1.0
ug/L
1,1,2,2-Tetwhloroetham
0.28
U
1.0
ug/L
1,1,2-Trichlorcethane
0.14
U
1.0
ug/L
1,1-Dichloroethane
0.13
U
1.0
ug/L
1,1-Dichlorcethene
0.21
U
1.0
ug/L
FINAL
This report relates only to
the sample as
rererved by the ulwratm, am may only be rwn t;ucm in roll.
Page 21 Of 39

www.encolabs.com
QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 9DO9O25 - EPA 50308 MS- Continued
Blank (91309025-BLKI) Continued Prepared: 04/09/2019 12:24 Analyzed: 04/09/201917:54
Anal
Result
flag
C0L
Units
1,1-Dichloropropene
0.15
U
1.0
ug/L
1,2,3-Trichlorobenzen,
0.01
U
1.0
ug/L
1,2,3-Trkhloropropane
0.23
U
1.0
ug/L
1,2,4-Trkhlorobenzene
0.14
U
1.0
ug/L
1,2,4-Trimethylbenzene
0.10
U
1.0
ug/L
1,2-Dibromo-3-chloropropane
0.48
U
1.0
ug/L
1,2-Dibromcethane
0.66
U
1.0
ug/L
1,2-Dichlombenzene
0.19
U
1.0
ug/L
1,2-Dichlorcethane
0.21
U
1.0
ug/L
1,2-Dkhloroprupane
0.10
U
1.0
ug/L
1,3,5-Trimethyibemene
0.30
U
1.0
ug/L
1,3-Dichlorobenzene
0.15
U
1.0
ug/L
1,3-Dichloropropane
0.16
U
1.0
ug/L
1,4-Dichlombenzene
0.19
U
1.0
ug/L
1,4-Dioxam
25
U
60
ug/L
2,2-Dichlompropane
0.28
U
1.0
ug/L
2-Butanone
1.3
U
5.0
ug/L
2-Chlorcethyl Vinyl Ether
1.1
U
5.0
ug/L
2-Chlorotoluene
0.08
U
1.0
ug/L
2-Hexanone
0.88
U
5.0
ug/L
3-Chloropropene
0.11
U
1.0
ug/L
4Chlorotoluene
0.07
U
1.0
ug/L
4-Isopropykoluene
0.08
U
1.0
ug/L
4-Methyl-2-pentanone
1.1
U
5.0
ug/L
Acetone
10
U
20
ug/L
Acetonitrile
5.0
U
10
ug/L
Acmlein
4.0
U
10
ug/L
Acrylonitrile
3.5
U
10
ug/L
Benzene
0.15
U
1.0
ug/L
Bromoberuene
0.16
U
1.0
og/L
Bromochloromethane
0.48
U
1.0
ug/L
Bromoo¢hloromethane
0.17
U
1.0
ug/L
Bromoform
0.22
U
1.0
ug/L
Bromomethane
0.14
U
1.0
ug/L
Carbon disulfide
1.5
U
5.0
ug/L
Carbon tetrachloride
0.17
U
1.0
ug/L
Chlorobenzene
0.17
U
1.0
ug/L
Chloroethane
0.23
U
1.0
ug/L
Chloroform
0.18
U
1.0
ug/L
Chloromethane
0.13
U
1.0
ug/L
Chloroprene
0.64
U
1.0
ug/L
cis-1,2-Dkhlorcethene
0.15
U
1.0
ug/L
cis-1,3-Dichloropropene
0.20
U
1.0
ug/L
Dibromochloromethane
0.17
U
1.0
ug/L
Dibromomethane
0.27
U
1.0
ug/L
Dichlorodiguoromethane
0.20
U
1.0
ug/L
Ethyl Methacrylate
0.38
U
1.0
ug/L
Ethylbenzene
0.13
U
1.0
ug/L
Freon 113
0.35
U
1.0
ug/L
Spike Source %REC RPD
Level Result %REC Undi[z RPD Umit Notes
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced! in W. I Page 22 of 39

www.encolabs.com
QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 9DO9O15 - EPA 50305 MS - Continued
Blank (910,09025-01.11[3) Continued Prepared: 04/09/2019 12:24 Analyzed: 04/09/2019 17:54
Anal YSB
Result
Elao
Pat
Units
He hlorobuddiene
0.22
U
1.0
ug/L
lodomethane
1.7
U
5.0
ug/L
Isobutyl akohol
11
U
50
ug/L
Isopropyl Ether
0.05
U
1.0
ug/L
Isopropylbenzene
0.14
U
1.0
ug/L
m,p-Xylems
0.17
U
2.0
ug/L
Methacrylonitrile
4.9
U
10
ug/L
Methyl MethacMate
0.51
U
1.0
ug/L
Methylene chloride
0.23
U
1.0
ug/L
Methyl-tert-Butyl Ether
0.16
U
1.0
ug/L
Naphthalene
0.11
U
1.0
ug/L
n-Butyl Benzene
0.06
U
1.0
ug/L
n-Prapyl Benzene
0.12
U
1.0
ug/L
o-Xylene
0.06
U
1.0
ug/L
Propionitrile
5.0
U
30
ug/L
set-Butylbenzene
0.10
U
1.0
ug/L
Styrene
0.11
U
1.0
ug/L
tert-Butylbenzene
0.17
U
1.0
ug/L
Tetrwhloroethene
0.17
U
1.0
ug/L
Toluene
0.14
U
1.0
ug/L
trans-1,2-Dichloroethene
0.21
U
1.0
ug/L
trans-1,3-Dichloropropene
0.15
U
1.0
ug/L
trans-1,4-Dichloro-2-butene
0.70
U
1.0
ug/L
Tnchlorbethene
0.15
U
1.0
ug/L
Trichlorofluoromethane
0.24
U
1.0
ug/L
Vinyl acetate
0.95
U
5.0
ug/L
Vinyl chloride
0.32
U
1.0
ug/L
Xylenes (Total)
0.24
U
3.0
ug/L
Spike Source ^7oREC RPD
Level Result a/.REC Limits RPD Limit titer
4-Bromo$orobenzene
56
ay/L
50.0 113 53-136
Dibromofluommethane
57
UVIL
50.0 113 67-119
To/ue 08
58
u91L
50.0 116 59-134
LCS (9D09025-B51)
Prepared: 04/09/2019 12:24 Analyzed: 04/09/2019 14: 18
Analste
1, 1, 1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetmchloroethane
1, 1,2-Trichlorwthane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichlorobenzene
1, 2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Tnrnethylbenzene
1,2-Dibromo-3-chbropropane
1,2-Dibromoethane
1,2-Dichlorobenzene
RNAL
Spike
Source
^7oREC
ResulS
Elan P91
units
Level
Result ^7oREC
Limits RPD
21
1.0
ug/L
20.0
103
71-117
21
1.0
ug/L
20.0
105
70-130
23
1.0
ug/L
20.0
113
60-140
21
1.0
ug/L
20.0
105
70-130
24
1.0
ug/L
20.0
120
70-130
20
1.0
ug/L
20.0
101
50-150
21
1.0
ug/L
20.0
105
70.129
23
1.0
ug/L
20.0
117
62-117
21
1.0
ug/L
20.0
104
58-140
22
1.0
ug/L
20.0
ill
59-122
22
1.0
ug/L
20.0
110
74-123
22
1.0
ug/L
20.0
112
37-157
20
1.0
ug/L
20.0
102
66-123
21
1.0
ug/L
20.0
107
65-135
This report relates
only to the sample as received by the laboratory, and
may only be reproduced in
full.
RPD
1.1IDS Rotes
Page 23 of 39

ENS
www.encolabs.wm
QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 9DO9025 - EPA 50308 MS - Continued
LCS (9D09025-BS1) continued Prepared: 04/09/2019 12:24 Analyzed: 04109/201914:18
Spike
Source
%REC
Am
ROAM
FFlao EQL
units
Level
Result WoREC
Mard RPD
1,2-Dkhlomethane
22
1.0
ug/L
20.0
110
70-130
1,2-Dkhlompropane
21
1.0
ug/L
20.0
107
35-165
1,3,5-Tnmethybenzene
22
1.0
ug/L
20.0
112
77-129
1,3-Dichbrobemene
22
1.0
u9/L
20.0
109
70-130
1,3-Dkhioroprop me
19
1.0
ug/L
20.0
97
60-129
1,4-Dkhbrobenzene
22
1.0
u9/L
20.0
308
65-135
1,4-1)iw ne
59
3 60
ug/L
20.0
295
10-200
2,2-Dkhbropropane
26
1.0
ug/L
20.0
130
21-167
2-Butanone
25
5.0
u9/L
20.0
125
36-135
2-Otloroethyl Mmyl Ether
38
5.0
u9/L
40.0
95
5-225
2-Lhbrotoluene
21
1.0
ug(L
20.0
107
73-M
2-1-letmnone
23
5.0
ug/L
20.0
113
36-191
3-Chbropropene
22
1.0
ug/L
20.0
110
17-147
4-Chbrooduene
21
1.0
ug/L
20.0
107
76-134
4-lsopropykoluere
22
1.0
u9/L
20.0
Ili
75-127
4-Methyl-2-pentanone
23
5.0
ug/L
20.0
117
56-166
Acetone
26
20
ug/L
20.0
130
MASS
Acetonitrile
28
10
ug/L
20.0
142
10-200
Acmlein
39
10
ug/L
40.0
97
60-140
Acrylonitrile
71
10
uWL
60.0
118
60-140
Benzene
22
1.0
ug/L
20.0
109
65-135
Bromobenzene
20
1.0
ug/L
20.0
100
72-115
Bromochbromethane
23
1.0
ug/L
20.0
114
7+128
Bromodkhbrometha a
23
1.0
tg/L
20.0
116
65-135
Bromoform
21
1.0
u9/1-
20.0
103
70-130
Bromomethane
20
1.0
ug/L
20.0
101
15.185
Carbon disulfide
23
5.0
ug/L
20.0
114
65-173
Carbon tetrachloride
23
1.0
ug/L
20.0
113
70-130
Chbroberuehe
20
1.0
ug(L
20.0
101
65-135
Chlomethane
25
1.0
ug/L
20.0
124
4D-160
Chloroform
22
1.0
ug/L
20.0
108
70-135
Chbromethaw
22
1.0
ug/L
20.0
110
5-205
Chbroprene
23
1.0
ug/L
20.0
114
33-148
cis-1,2-Dkhloroetnene
21
1.0
ug/L
20.0
104
69-120
cis-1,3-Dichloropropene
22
1.0
ug/L
20.0
ill
25-175
DibroimMoromethane
23
1.0
u9/1.
20.0
116
70-135
Dibronlomethare
22
1.0
ug/L
20.0
109
76-124
Dichlorodifluommethzne
21
1.0
ug/L
20.0
107
25-161
Ethyl Methacrylate
22
1.0
ug/L
20.0
108
51-113
Ethylbenzene
20
1.0
ug/L
20.0
100
60.140
Freon 113
19
1.0
u9/L
20.0
97
0-200
Hezachlorobutadiene
24
1.0
ug/L
20.0
118
63-114
Iodomethane
19
5.0
ug/L
20.0
95
34-140
Isobutyl alcohol
580
50
ug/L
20.0
NR
10-200
Isopropyl Ether
24
1.0
ug/L
20.0
119
45-117
Isopropylberuene
21
1.0
ug/L
20.0
107
81-136
m,p-Xylenes
40
2.0
ug/L
40.0
99
79-121
Methacrylonitrile
37
10
ug/L
20.0
183
10-200
Methyl Metlacrylate
23
1.0
ug/L
20.0
113
48-126
RPD
Limit Motu
QL-02
QL-02
QL-02
QL-02
FINAL This report relates only to the sample as reue by the laboratory, amol may only be reproducM in full
Page 24 of 39

www.encolabs.com
QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 9009025 - EPA 50308 MS - Continued
LCS (91309025-851) Continued Prepared: 04/D9/201912:24 Analyzed: 04/09/201914:18
spike
Source
%REC RPD
Anal vtG
Rewlt
Bag M
Units
Level
ges,lt %REC
Lim ltd< RPD Limi
Methylene chloride
24
1.0
ug/L
20.0
120
60-140
Methyken-Butyl Ether
24
1.0
ug/L
20.0
119
10-127
Naphthalene
25
1.0
U91L
20.0
123
50.127
n-Butyl Benzene
23
1.0
ug/L
20.0
115
68-126
n-Propyl Benzene
21
1.0
hg/L
20.0
106
76-125
a-Xylene
20
1.0
ug/L
20.0
101
71-125
Propionitile
28
30
ug/L
20.0
141
10-184
sec-Butylbenzene
22
1.0
ug/L
20.0
1D8
75-222
Styrene
21
1.0
U91L
20.0
107
78-120
tet-Butylbenvene
21
1.0
ug/L
20.0
106
70-137
Tetrachbroethene
21
1.0
ug/L
20.0
103
70-130
Toluene
21
1.0
ug/L
20.0
105
70-130
trans-1,2-DidOoroetiene
22
1.0
u9/1.
20.0
108
70-130
trans-1,3-Dichbropropene
23
1.0
ug/L
20.0
117
50-150
trans-1,4Dichimo-2-butene
25
1.0
ug/L
20.0
126
1D-142
Trichlomethene
20
1.0
ug/L
20.0
100
65-135
Trkhbrofiwasmethane
24
1.0
ug/L
20.0
121
50-150
Vinyl acetate
29
5.0
U91L
20.0
143
10-198
Vinyl chbride
23
1.0
ug/L
20.0
117
5-195
Xyknes(Total)
60
3.0
ug/L
60.0
100
77-121
40romoAuxodenzene 54 0$2 50.0 109 53-136
0ibOMMAX01hed3re 53 WL 50.0 107 67-129
7oluenrdB 57 WAL 50.0 113 59-134
Matrix Spike (9D09025-MSI) Prepared: 04/09/2019 12:24 Analyzed: 04/09/2019 15:22
Source: CCO5678-07
Spike
Source
%REC
911ab6C
Result
Flag FOL
Uniti
Level
Result
%REC
Limits
1,1,1,2-Tetrachbroethare
22
1.0
ug/L
20.0
0.17 U
109
71-117
1,1,1-Trichlorcethane
22
1.0
ug/L
20.0
0.12 U
112
70.130
1,1,2,2-Tetmchloroethane
22
1.0
ug/L
20.0
0.28 U
108
60-140
1,1,2-Trichbroethane
22
1.0
ug/L
20.0
0.14 U
108
70.130
1,1-Dirhbroethane
26
1.0
ug/L
20.0
0.13 U
128
70-130
1,1-Dichloroethem
22
1.0
ug/L
20.0
0.21 U
108
50-150
1,1-Dkhbropropene
23
1.0
u9/L
20.0
0.15 U
114
70-129
1,2,3-Trichloroberzerie
22
1.0
ug/L
20.0
0.01 U
109
62-117
1,2,3-Trkhbropropare
20
1.0
ug/L
20.0
0.23 U
98
58-140
1,2,44r01orobenzene
22
1.0
ug/L
20.0
0.14 U
110
59-122
1,2,4Trimethylbenzene
23
1.0
u9/1.
20.0
0.10 U
115
74-123
1,2-Dibromo-3-chbropropane
20
1.0
ug/L
20.0
0.48 U
99
37-157
1,2-Dibromoethare
21
1.0
ug/L
20.0
0.66 U
103
49-155
1,20chlorobenre a
22
1.0
ug/L
20.0
0.19 U
110
65-135
1,2-Dichloroethane
22
1.0
ug/L
20.0
0.21 U
ISO
70-130
1,2-Dichlompropare
23
1.0
u9/L
20.0
0.10 U
115
35-165
1,3,5-Trimetlrylbemene
23
1.0
ug/L
20.0
0.30 U
116
77-129
1,3-Dichlorobensne
22
1.0
ug/L
20.0
0.15 U
112
70-130
1,3-Dichloropropane
20
1.0
ug/L
20.0
0.16 U
100
60-129
1,4Dkhbmbenzene
22
1.0
u9/1.
20.0
0,19 U
110
65-135
1,4-Ditatare
25
U 60
ug/L
20.0
25 U
10-200
2,2-Dichloroprop m
29
1.0
ug/L
20.0
0.28 U
144
21-167
Rn
"a, report relates ordy to the sample as
received by the Wbaatoy, and may mly be repm lu al in full.
Notes
RPD
RPD UMft Notes
QM-07
Page 25 of 39

www.encolabs.com
QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch OD09025 - EPA 5030E MS - Continued
Matrix Spike (9D09025-MSI) Continued Prepared: 04/09/201912:24 Analyzed: 04/09/201915:22
Source: CCO5678-07
Spike
Source
%REC
RPD
Basalt
rim CQL
Units
Level
Result
%REC
Limits
RPD LiNii Notes
2-Butanone
26
5.0
ug/L
20.0
1.3 U
128
36-135
2-Chloroethyl Vinyl Ether
38
5.0
ug/L
40.0
1.1 U
94
5-225
2-Chlomtuluem
22
1.0
ug/L
20.0
0.08 U
112
73-135
2-Heav one
21
5.0
Ug/L
20.0
0.88 U
105
36-291
3.Chlompropene
24
1.0
ug/L
20.0
0.11 U
121
17-147
4-Chbrotoluem
22
1.0
ug/L
20.0
0.07 U
111
76-134
4lsopropyltolueae
23
1.0
t91L
20.0
0.08 U
115
75-127
4-Methyl-2-pentanone
22
5.0
ug/L
20.0
1.1 U
109
56-166
Acetone
25
20
ug/L
20.0
IOU
123
ID-158
Acetonibile
27
10
u9/1.
20.0
5.0 U
135
10-200
Acroleln
37
10
Ug/L
40.0
4.0 U
93
60-140
Acrybnitrile
72
10
Ug/L
60.0
3.5 U
119
60-140
Benzene
23
1.0
ug/L
20.0
0.15 U
117
65-135
Bromoberuene
20
1.0
u9/1.
20.0
D.16 U
102
72-115
Brongchbmmethane
23
1.0
ug/L
20.0
0.48 U
116
74-128
Bmmodbhlommethane
24
1.0
t9/1-
20.0
0.17 U
121
65-135
Bmmokxm
20
1.0
ug/L
20.0
0.22 U
99
70-130
Bromomethane
22
1.0
ug/L
20.0
0.14 U
SOB
15-185
Carbon disulride
26
5.0
ug/L
20.0
1.5U
130
65-173
Carbon tetrachloride
23
1.0
ug/L
20.0
0.17 U
116
70-130
Chlombenzene
21
1.0
ug/L
20.0
0.17 U
107
65-135
Chlomedlane
28
1.0
ug/L
20.0
0.23 U
139
40-160
Chloroform
24
1.0
ug/L
20.0
0.18 U
119
7D-135
Chlommethane
26
1.0
ug/L
20.0
0.13 U
128
5-205
Chloroprene
25
1.0
ug/L
20.0
0.64 U
127
33-148
cis-1,2-Dbhloroethene
22
1.0
ug/L
20.0
0.15 U
112
69-120
cis-1,3-Dichloropropene
24
1.0
ug/L
20.0
0.20U
119
25-175
Dibmmochloromethane
23
1.0
ug/L
20.0
0.17 U
115
70-135
Dibmwinethane
22
1.0
ug/L
20.0
0.27 U
110
76-124
DichlorodiDuoromethane
25
1.0
ug/L
20.0
0.20 U
123
25-161
Ethyl Methacrylate
22
1.0
ug/L
20.0
D.38 U
108
51-113
Edrylbenzene
21
1.0
ug/L
20.0
0.13 U
107
60-140
Freon 113
44
1.0
ug/L
20.0
0.35 U
219
0-200
QM-07
Hexachlorobutadiene
22
1.0
ug/L
20.0
0.22 U
111
63-114
lodornethane
21
5.0
ug/L
20.0
1.7 U
107
34-140
Isobutyl alcohol
570
SD
Ug/L
20.0
11 U
NR
10-200
QM-07
Iwpropyl Ether
26
1.0
ug/L
20.0
0.05 U
13D
45-117
QM-07
lsopmpylbenzene
22
1.0
ug/L
20.0
0.14 U
110
81-136
m,p-Xylenes
43
2.0
ug/L
40.0
D.17 U
106
79-121
Methacrylondrile
36
10
ug/L
20.0
4.9 U
181
10-200
Methyl Methacrylam
22
1.0
ug/L
20.0
0.51 U
108
48-126
Methylene chloride
27
1.0
ug/L
20.0
0.23 U
134
60-140
Methyl-tert-Butyl Ether
25
1.0
ug/L
20.0
0.16 U
123
1D.127
Naphthalene
22
1.0
ug/L
20.0
0.11 U
112
50-127
n-Butyl Benzene
24
1.0
ug/L
20.0
0.06 U
120
68-126
n-Pmpyl Benzene
22
1.0
ug/L
20.0
0.12 U
111
76-125
o-Xylene
21
1.0
ug/L
20.0
0.06 U
107
71-125
Propionitrlle
27
10
u9/L
20.0
5.0 U
133
10-184
sec-Butylbenzene
22
1.0
ug/L
20.0
0.10 U
112
75-122
Fll A
This report relates only to the sample as
received by the
laboratory, and may only be reproduced in full.
Page 26 Of 3S

EN
www.encolabs.com
QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 9009025 - EPA 5030B MS - Continued
Matrix Spike (91)01 Continued
Prepared: 04/09/201912:24 Analyzed: 04/09/201915:22
Source: CC05678-07
Spike
Source
%REC
RPD
AnalAe
Result Dag
POL
Units
Level
Re
%REC
UMBE
RPD
lalmit
Notes
Styrene
22
1.0
ug/L
20.0
0.11 U
109
73-120
ten-BuMbenzene
22
1.0
ug/L
20.0
0.17 U
108
70.137
Teirwhlnroelhene
26
1.0
ug/L
20.0
0.17 U
132
70-130
QM-07
Toluene
23
1.0
ug/L
20.0
0.14 U
113
70.130
tans-1,2-Dichloroethene
23
1.0
ug/L
20.0
0.21 U
117
70-130
trans-1,3-Dichlompropene
24
1.0
ug/L
20.0
0.15 U
120
50.150
trans-1,4-Dichbro-2-butene
24
1.0
ug/L
20.0
0.70 U
121
10-142
Trirhbroethene
21
1.0
ug/L
20.0
0.15 U
107
65-135
Trkhbro0uoromethane
27
1.0
ug/L
20.0
0.24 U
134
50-150
Vinyl acetate
29
5.0
ug/L
20.0
0.95 U
147
10-198
Vinyl chlowde
26
1.0
ug/L
20.0
0.32 U
129
5-195
Xylenes (Total)
64
3.0
ug/L
60.0
0.24 U
107
77-121
4-B/pmo0uw0bwzgne
53
4/1
50.0
105
53-136
Diblomofivarome0/ane
55
L91L
50.0
109
67-129
Tolue 08
57
14A
50.0
114
59-134
Matrix Spike pop (9D0902S-MSD1)
Prepared: 04/09/2019 12:24 Analyzed: 04/D9/2019 15:53
Source: CC0567"7
Spike
Source
%REC
RPD
Anal v[e
Result Hap
POL
y01ts
Level
Re
%REC
UW=
RPD
LjmR
Nam£
1,1,1,2-Tetrech1oroethane
21
1.0
ug/L
20.0
0.17U
105
71-117
4
25
1,1,1-Trlchlorcetham
22
1.0
ug/L
20.0
0.12 U
110
70-130
2
36
1,1,2,2-Tetwhloroethane
21
1.0
ug/L
20.0
0.28U
106
60-140
2
61
1,1,2-Trichbrcethane
21
1.0
ug/L
20.0
0.14 U
104
70.130
4
45
1,1-Dichbroetham
25
1.0
ug/L
20.0
0.13 U
124
70.130
3
40
1,1-Dkhlomethere
22
1.0
ug/L
20.0
0.21 U
toe
50-150
0
32
1,1-Dichloropropene
22
1.0
ug/L
20.0
0.15 U
112
70-129
2
25
1,2,3-Trkhkrroben ere
22
1.0
Ug/L
20.0
0.01 U
110
62-117
1
25
1,2,3-Trkhbropropane
19
1.0
ug/L
20.0
0.23 U
97
58-140
0.7
25
1,2,4-Trichlorobemm
21
1.0
ug/L
20.0
0.14 U
107
59-122
2
25
1,2,4-Trimethylbenzene
23
1.0
ug/L
20.0
0.10 U
113
74-123
2
25
1,2-Dlbromo-3chloropropane
21
1.0
ug/L
20.0
0.48 U
106
37-157
7
25
1,2-Dibromoetham
20
1.0
ug/L
20.0
0.66 U
SDO
49-155
2
25
1,2-Dkhkxobenzene
22
1.0
ug/L
20.0
0.19 U
109
65-135
0.5
57
1,2-Dichlometham
22
1.0
ug/L
20.0
0.21 U
109
70-130
0.6
49
1,2-Dkhloropropam
22
1.0
ug/L
20.0
0.10 U
111
35-165
4
55
1,3,5-Trimethylbenzene
23
1.0
ug/L
20.0
0.30 U
115
77-129
1
25
1,3-Dbhloroberizene
22
1.0
ug/L
20.0
0.15 U
111
70-130
0.9
43
1,3-Dichloropropane
19
1.0
ug/L
20.0
0.16 U
97
60-129
2
25
1,4-Dkhlorobemene
22
1.0
ug/L
20.0
0.19 U
109
65-135
0.8
57
1 4-Dioxane
25 U
60
ug/L
2D.0
25 U
10-200
50
QM-07
2,2-Dkhlompropane
29
1.0
ug/L
20.0
0.28 U
143
21-167
0.9
25
2-Butarsine
23
5.0
ug/L
20.0
1.3 U
117
36-135
9
25
2-Chbroethyl Vinyl Ether
39
5.0
ug/L
40.0
1.1 U
97
5-225
2
71
2-Chlorotoluere
22
1.0
ug/L
20.0
0.08 U
110
73-135
2
25
2-Hexanore
21
5.0
ug/L
20.0
0.88 U
103
36-191
2
25
3-Chbropropere
23
1.0
ug/L
20.0
0.11 U
115
17-147
5
25
4-Chlorotoluen ,
22
1.0
ug/L
20.0
0.07 U
112
76-134
0.2
25
4-1wpropyltoluene
23
1.0
ug/L
20.0
0.08 U
114
75-127
0.8
25
4-Methyl-2-pentanom
22
5.0
ug/L
20.0
1.1 U
1D9
56-166
0.3
25
nbiAL
mis report reuses only m we
sample as
received by tte laborson,, and
may only be reproduce! in full.
Page
27 D1 39

ENVMS
'4111111,
w .encolabs.com
QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Barth OD00025 - EPA 5030E MS - Cmbfflued
Matrix Spike Dup (9D09025-MSD1) Continued
Prepared: 04/09/2019 12:24 Analyzed: W09/2019 15:53
Source: CCOS678.07
Spike
Source
%REC
RPD
Anal Yffi
Resul[ 6aa
PQL
Units
Level
Result
%REC
Limits
RPD
Limit Notes
Acetone
24
20
ug/L
20.0
IOU
118
10-158
4
25
Acetonitrile
25
10
ug/L
20.0
5.0 U
126
10-200
7
25
Acrolein
40
/0
ug/L
40.0
4.0U
100
60-140
7
60
Aaylonitnle
71
10
ug/L
6D.0
3.5 U
119
60.140
0.5
60
Benzene
22
1.0
ug/L
20.0
0.15 U
112
65-135
4
61
Bromobenzene
20
1.0
ug(L
20.0
0.16 U
100
72-115
2
25
Bromodrloromethane
23
1.0
u9/1-
20.0
0.48 U
116
74-128
0.04
25
Brumodichloromethxne
23
1.0
ug/L
20.0
0.17 U
115
65-135
5
56
Bromoform
20
1.0
u9/L
20.0
0.22 U
99
70-130
0.1
42
Bromomelhane
22
1.0
ug/L
20.0
0.14 U
108
15-185
0.4
61
Carbon disulfide
26
5.0
ug/L
20.0
1.5 U
128
65-173
2
25
Carbon tetrachloride
23
1.0
ug/L
20.0
0.17 U
114
70-130
2
41
Orlorobenzene
21
1.0
ug/L
20.0
0.17 U
104
65-135
3
53
Chbroethane
27
1.0
ug/L
20.0
0.23 U
136
40-160
2
78
Chloroform
23
1.0
ug/L
20.0
0.18 U
115
70-135
4
54
Chloromethane
25
1.0
ug/L
20.0
0.13 U
123
5-205
5
60
Chloroprene
2S
1.0
ug/L
20.0
0.64 U
125
33-148
2
25
cis-3,2-Dichkxoethene
22
1.0
ug/L
20.0
OAS U
110
69-120
2
25
cis-1,3-Dichloropropene
23
1.0
ug/L
20.0
0.20 U
116
25-175
2
58
Dibronnchloromethane
23
1.0
ug/L
20.0
0.17 U
114
70.135
0.7
50
Dibromomethane
21
1.0
ug/L
20.0
0.27U
105
76-124
5
25
Dichlurodifluuromedune
25
1.0
ug/L
20.0
0.20 U
126
25-161
2
25
Ethyl Mrahacrylate
21
1.0
ug/L
20.0
0.38 U
104
51-113
4
25
Ethylbenzene
21
1.0
ug/L
20.0
0.13 U
104
60-140
3
63
Freon 113
43
1.0
ug/L
20.0
0.35 U
213
0-200
3
25
Nexachlorobutadiene
23
1.0
ug/L
20.0
0.22 U
114
63-114
3
25
lodomethane
21
5.0
ug/L
20.0
1.7U
107
34-140
0.4
25
Isobutyl alcohol
580
50
ug/L
20.0
11 U
NR
10-200
2
25 QM-07
Isopropyl Ether
25
1.0
u9/1.
20.0
0.05 U
127
45-117
3
25 QM-07
Lsopropylbenzene
22
1.0
ug/L
20.0
0.14 U
109
81-136
0.9
25
m,p-Xylenes
41
2.0
ug/L
40.0
0.17 U
103
79-121
3
25
Methacrylonibile
35
10
u9/L
20.0
4.9U
177
10-200
2
25
Methyl MethacMate
22
1.0
ug/L
20.0
0.51 U
110
48-126
1
25
Methylene chloride
26
1.0
ug/L
20.0
0.23 U
132
6D-140
2
28
Methyl-tert-Butyl Ether
24
1.0
UWL
20.0
0.16 U
121
10-127
1
25
Naphthalene
23
1.0
ug/L
20.0
0.11 U
114
SD-127
2
25
n-Butyl Benzene
23
1.0
u9/L
20.0
0.06 U
117
68-126
2
25
n-Propyl Benzene
22
1.0
ug/L
20.0
0.12 U
109
76-125
3
25
o-Xylene
21
1.0
ug/L
20.0
0.06 U
104
71-125
3
25
Proplonitrile
26
10
ug/L
20.0
5.0 U
131
10-184
1
25
sec-Butylbeazene
22
1.0
ug/L
20.0
0.10 U
111
75-122
0.9
25
Styrene
21
1.0
ug/L
20.0
0.11 U
107
73-120
2
25
tert-Butylbenzene
22
1.0
ug/L
20.0
0.17 U
109
70-137
0.6
25
Tetrachlorcethene
28
1.0
u9/1-
20.0
0.17 U
139
70-130
6
39 QM-07
Toluene
22
1.0
u9/1.
20.0
0.14 U
110
70-130
3
41
trans-1,2-Dichloroethene
23
1.0
ug/L
20.0
0.21 U
113
70-130
3
45
trans-1,3-Dichloropropene
24
1.0
ug/L
20.0
0.15 U
119
50-150
0.7
86
trans-1,4-Dichloro-2-butene
24
1.0
ug/L
20.0
0.70 U
120
ID-142
1
25
Trichloroethem
21
1.0
ug/L
20.0
0.15 U
106
65-135
0.8
48
HT L
this report relates only to the
ample as
received by the
laboratory, and may only be reproduced in full.
Page 28 Of $9

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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Balch 9DO9025 - EPA 5030E AfS - Continued
Matrix Spike Dup (9D09025-MSD1) Continued
Prepared: 04/09/201912:24 Analyzed: 04/D9/201915:53
Source: CCO5678-07
Spike Source
%REC
RPO
Anal f6e Result Hag
Pol
Uni
Level Result
%REC
Limits RPD
Lima Notss-
Trichkxofluoromethane 26
Lo
U91L
20.0 0.24 U
132
50-M 1
84
Vinyl acetate 28
5.0
Ug/L
20.0 0.95 U
140
10-198 5
25
Vinyl chloride 26
1.0
ug/L
20.0 0.32 U
130
5-195 1
66
Xylenes (Total) 62
3.0
ug/L
60.0 0.24 U
104
77-121 3
16
4-eromo0iarobenzefle 53
U91L
50.0
105
53-136
DibromofluaomechaW 55
WIL
50.0
110
67-129
Toluene-d8 57
WL
50.0
115
59-134
Metals by EPA 200 Series Methods - Quality Control
Batch 9009035 - EPA 3005A
Blank (91309035-BLKI)
Prepared: 04/09/2019 15:54 Analyzed: 04/11/2019 11:24
Spike Source %REC RPD
Anal lZe
Result flan
P01
Uflb
Level Result %REC Limits RPD L1Lu( Notes
Calcium
39.0 U
100
ug/L
Magnesium
29.0 U
100
ug/L
Sodium
400 U
500
ug/L
LCS (91009035-10SI)
Prepared: 04/09/2019 15:54 Analyzed: 04/11/201911:36
Spike
Source
%REC
RPD
Amahft
Result
Dan
Pol
units
Level
Result
%REC
Limits RPD
Lima Notes
Calcium
2170
100
Ug/L
20DO
IDS
BS-115
Magnesium
2070
100
ug/L
2000
104
85-115
Sodium
I0D00
Soo
ug/L
10000
100
85-115
Matrix Spike (9D09035-M51)
Prepared: 04/09/2019 15:54 Analyzer: 04/11/201911:39
Source: CCO4976-01
Spike
Source
%REC
RPD
Aea11Qa
995UR
FJa9
Poi
Units
Level
Result
%REC
Limits RPD
Lima Notes_
Calcium
2530
100
ug/L
2000
531
SOD
70-130
Magnesium
2640
100
ug/L
2000
507
107
70-130
Sodium
11400
500
ug/L
IDD00
1370
101
70-130
Matrix Spike cup (9D09035-MSD1)
Prepared: 04/09/2019 15:54 Analyzed: 04/11/201911:42
Source: CC04976-01
Spike
Source
%REC
RPD
Ana
Result
Hag
P4l
Units
Level
Resua
%REC
Limits RPD
Limit Notes -
Calcium
2540
100
ug/L
2000
531
100
70-130 0.4
30
Magnesium
2610
100
ug/L
2000
507
105
70-130 1
30
Sodium
11300
Soo
ug/L
300D0
1370
99
7D-130 1
30
Post Spike (9D09035-P51)
Prepared: 04/09/2019 15:54 Analyzed: 04/11/2019 11:44
Source: CCO4976-01
Spike
source
%REC
RPD
Anal 9ta
Result
Hag
EQL
units
Level
Result
%REC
Limits RPD
Lima Notes
Calcium
2.61
0.100
ng/L
2.00
0.531
104
80.120
Magnesium
2.70
0.100
mg/L
2.00
0.507
110
80-120
Sodium
11.8
0.500
mg/L
10.0
1.37
105
80-120
Classical Chemistry Parameters- Quality Control
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in far. I Page 29 Of 39

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 9DO9003 - NO PREP
Blank (9DO9003-BLR3) Prepared Is Analyzed: 04/09/2019 13:55
Spike Source %REC RPD
Anal lrse Result flan P91 Units Level Result %REC Lime RPD Limit Notes
Total Dissolved Solids 50 U 50 mg/L
LCS (9DO9003-BSI) Prepared & Analyzed: 04/09/2019 13:55
Spike Source %REC
RPD
Anal ltie
Result
ula9
RS)L
units
Level Result %REC Limits
RPD
Limit Notes
Total Dissolved Solids
1000
50
mg/L
1000 100 80-120
Duplicate (9DO9003-DUPl)
Prepared & Analyzed: 04/09/2019 13:55
Source: CC03353-01
Spike Source %REC
RPD
AOahft
Result
Elan
POL
Units
Level Result %REC Limits
RPD
Limit Notes
Total Dissolved Solids
2200
100
mg/L
2200
0.4
20
Duplicate (9DO9003-DUP2)
Prepared is Analyzed: D4/D9/2019 13:55
Source: CC03353-02
Spike Source %REC
RPD
Anal Yte
ResuR
E69
PQL
Units
Level Result %REC Limits
RPD
Limit Notes
Total Dissolved Solids
2000
100
mg/L
2000
2
20
Batch 9009009 - Same
Blank (9D09009-BLR3)
Prepared: 04/09/2019 13:18 Analyzed: 04/09/2019 19:56
Spike Source %REC RPD
.AnalM Result flag POL units Level Result %REC Limits RPD Limit Notes
Chemical Oxygen Demand 10 U 10 mg/L
LCS (9DO9009-851) Prepared: 04/09/201913:18 Analyzed: 04/09/2019 19:56
Spike Source ^/DREG
RPD
Anal ytg Result
Ron Pat
units
Level Result %REC Limits RPD
Limit Notes
Chemical Oxygen Demand 480
10
mg/L
500 97 90-110
Matrix Spike (9D09009-MS1)
Prepared: 04/09/201913:18 Analyzed: D4/09/2019 19:56
Source: CCO4638.02
Spike Source %REC
RPD
Anal y(p Result
Flag p9L
Units
Level Result RAREC Limits RPD
Limit Notes
Chemical Oxygen Demand 510
10
m9/L
526 23 93 90-110
Matrix Spike pop (91)(19009-MSD3)
Prepared: 04/09/2019 13:18 Analyzed: 04/09/2019 19:56
Source: CCO4838-02
Spike Source %REC
RPD
Anal vte
Result Rao
POL
units
Level Result RAREC Limits RPD
Lir i Notes
Chemical Oxygen Demand
530
10
mg/L
526 23 95 90-110 2
30
Batch 9DO9018 - NO PREP
Blank(9D09018-BLR3)
Prepared: 04/09/2019 09:26 Analyzed: 04/09/2019 11:25
Spike Source 0sbREC
RPD
Anal ne
Result Dag
POL
UORS
Level Result %REC Liits RPD
Limit Notes
Nitrite as N
0.017 U
0.10
mg/L
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 30 of 39

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 9D09018 - NO PREP - Continued
LCS (9D09018-BSI) Prepared: 04/09/2019 09:26 Analyzed: 04/09/201911:13
Spike Source ^/aREC
FUND
Ana lf6e Result
Ham PQL
Units
Level Result %REC Lim! RPD
L'OpiS Notes
Nitrite as N 1.0
0.10
mg/L
1.00 100 90-110
Matrix Spike (9D09038-MS3)
Prepared: 04/09/2019 09:26 Analyzed: 04/09/2019 11:27
Source: CC05006-01
Spike Source %REC
RIND
Anal Yte Result
Hag NX
U11[b
Level Result s/aREC Limits RPD
kliflat Notes
Nitrite as N 0.93
0.10
mg/L
1.00 0.017 U 93 90-110
Matrix Spike Dup (9D09018-MSDI)
Prepared: 04/09/2019 09:26 Analyzed: 04/09/2019 11:28
Source: CC05006-01
Spike
Source ^/oREC
RPD
Anal lde R55 It HN PL
Units Level
Result %REC Limits RPD
ILMA Not"
Nitrite as N 0.96 0.10
mg/L 1.00
0.017 U 96 90-110 3
10
Batch 9009035 - EPA 3005A
Blank (gD09035-BLK1) Prepared: 04/09/2019 15:54 Analyzed: 04/11/2019 15: 11
Spike Source %REC RPD
Anal v[e Resul Hag COL Units Level Result %REC Limits RPD Limit Notes
Sodium Adsorption Rau. 0.00 U [blank]
Batch 9DI0003 - NO PREP
Blank (9D30003-8LK1) Prepared & Analyzed: D4/30/2019 08:24
Spike Source °/oREC RPD
Anal v[e Result Hag IQ Units Level R sul %REC Limits RPD Limit Notes
Biochemical Oxygen Demand 2.0 U 2.0 mg/L
LCS (9D10003-BSI) Prepared & Analyzed: 04/10/2019 08:24
Spike
Source
%REC
RPD
AnalYte
Result Hap POL
Units
Level
Result
o/aREC Limits RPD
1.1011 Notes
Biochemical Oxygen Demand
190 2.0
mg/L
198
94 85-115
Duplicate (91),10003-DUPI)
Prepared & Analyzed: 04/10/2019 08:24
Source: CC01553-01
Spike
Source
%REC
RPD
Anal v[e
Basel S Hag EQL
UnA5
Level
Result
%REC MmitE RPD
Limit Notes
Biochemical Oxygen Demand
890 2.0
mg/L
890
0.7
30
Batch 9DI1005 - NO PREP
LCS (9D1100S-B51) Prepared & Analyzed: 04/11/2019 10:26
Spike Source %oREC
RPD
AOalYLe
Result Hag Pill
Units
Level Result %REC Limi RPD
Lunt Notes
pH
7.0 1.0
pH
7.01 99 99-101
Duplicate (9D1100S-DUP1)
Prepared & Analyzed: 04/11/2019 12:07
Source: CCO2185-01
Spike Source o/ REC
RPD
Anal vte
Result Hag POL
Untu
Level Result %REC Linni RPD
Lialft Notes
pH
6.3 1.0
pH
6.3 0.8
25
Batch 9D12017 - Same
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in U. Page 31 of 39

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Blank (9D12017-13M) Prepared: 04/12/2019 14:39 Analyzed: 04/15/2019 11:50
Spike Source %REC RPD
Anal Yt€ Result flag POL Umu Level Result %REC Limits RPD Lima Notes
Total Kjeldahl Nitrogen 0.26 U 0.48 mg/L
LCS (9DI2017-BSI) Prepared: 04/12/2019 14:39 Analyzed: 04/15/2019 12:22
Spike Source %REC
RPD
Anal v[e
Result
flan
POL
llDlts
Level Resul[ %REC Limits RPD
�L.pli it Notes
Total Kjeldahl Nitrogen
13
0.48
mg/L
12.1 104 90-110
Matrix Spike (9D12017-M51)
Prepared: 04/12/2019 14:39 Analyzed: 04/15/201915:46
Source: CC00074-OLRE1
Spike Source %li
RPD
Anal vte
Result
Flag
P01
units
Level Result %REC Limits RPD
Limit Notes
Total Kjeldahl Nitrogen
130
D
4.8
mg/L
4.85 120 166 90-110
QM-07
Matrix Spike (9D12017-MS2)
Prepared: 04/12/2019 14:39 Analyzed: 04/15/2019 13:18
Source: CCO1623-01
Spike Source %REC
RPD
Anal vte
Resul
)lag
PQ_L
Unit$
Level Result %REC LIIDIi4 RPD
Limit Notes_
Total Kjeldahl Nitrogen
17
0.48
mg/L
4.85 12 ill 90-I10
QM-07
Matrix Spike Dup (910,12017-MSDIL)
Prepared: 04/12/2019 14:39 Analyzed: 04/15/2019 15:48
Source: CC00074-01REI
Spike Source %REC
RPD
Anal v[e
Result
Flag
POL
Units
Level Result %REC Und RPD
kmil Notes.
Total Kjeldahl Nitrogen
130
D
4.8
mg/L
4.85 120 95 90-110 3
10
Batch 9D12018 - Same
Blank (9D12018-61.11(I)
Prepared: 04/12/2019 11:25 Analyzed: 04/15/2019 14:20
Spike Source %REC RPD
Analyte Resul Flan t4 Units Level Result %REC Limits RPD Limit Note$
Phosphorus 0.025 U 0.10 mg/L
LCS (9D12018-BSI) Prepared: 04/12/2019 11:25 Analyzed: 04/15/2019 14:21
Spike Source %REC
RPD
Anal vee Result
Elan
POL
units
Level Resul[ ^/DREG Limits RPD
Lima Notes
Phosphorus 1.6
0.10
mg/L
1.60 100 80-120
Matrix Spike (9D12018-1,451)
Prepared: 04/12/201911:25 Analyzed: 04/15/201916:47
Source: CC00074.OLREI
Spike Source %REC
RPD
Anal Result
Flag
POL
U-Olts
Level Result %REC Limits RPD
Limit Notes
Phosphorus 8.0
D
0.50
mg/L
0.640 7.5 81 80-120
Matrix Spike Cup (9D12018-MSD1)
Prepared: 04/12/2019 11:25 Analyzed: 04/15/2019 16:49
Source: CC00074-OIREI
Analvte
Phosphorus
Batch 9D15014 - NO PREP
Spike Source %REC
Result Flag POL t111M Level Result %REC Limi RPD
8.3 D 0.5D mg/L 0.640 7.5 124 80-120 3
RPD
Limit Notes
25 QM-07
FINAL This report relates only to the sample as received by me laboratory, and may only be reproduced in M. Page 32 Of 39

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch OD15014 - NO PREP - Continued
Blank (9D35014-81.11[I)
Prepared: 04/15/2019 11:54 Analyzed: 04/15/2019 17:41
Spike Source %REC
RPD
Anab3e
Read
flag
POL
Units
Level Result %REC Limits RPD
Limit
Now
Chloride
2.2
U
5.0
mg/L
LCS (9D15014-BS1)
Prepared: 04/15/2019 11:54 Analyzed: 04/15/2019 17:56
Spike Source %REC
RPD
Anal Yte
Result
Etacl
POL
Units
Level Result %REC Limits RPD
limit
Notes
Chloride
50
5.0
mg/L
50.0 100 90-110
Matrix Spike (9D15014-MSl)
Prepared: 04/15/2019 11:54 Analyzed: 04/15/2019 18:10
Source: CC05609-01
Spike Source %REC
RPD
Anatift
Resul
flag
Pffi
ni
Level Result °/aREC LImISF RPD
Limit
Notes
Chloride
110
E
5.0
mg/L
20.0 96 90 90-110
QM-07
Matrix Spike (9D35014-MS2)
Prepared: 04/15/2019 11:54 Analyzed: 04/15/2019 18:39
Source: CC05610-02
Spike Source %REC
RPD
Anall
ResaR
Bag
POL
Units
Level Result %REC Limits RPD
11031
Notes
Chloride
23
5.0
mg/L
20.0 3.8 97 90-110
Matrix Spike Dup (9D35014-MSDI)
Prepared: 04/15/2019 11:54 Analyzed: 04/15/2019 18:25
Source: CC05609-01
Spike Source a/.REC
RPD
Anal
Result
flag
PM
Units
Level Result %REC Limi RPD
MaliMalft
Notes
Chloride
110
E
5.0
mg/L
20.0 96 95 90-110 0.8
10
QM-07
Matrix Spike Dup (gD15D14-MSD2)
Prepared: 04/15/2019 11:54 Analyzed: 04/15/201918:54
Source: CC05610-02
Spike Source %REC
RPD
Amll
Resul
Bag
PQL
Units
Level Result %REC Limits RPD
Limit
Notes
Chloride
24
5.0
mg/L
20.0 3.8 100 90-110 3
10
Batch 9D16036 - NO PREP
Blank (9D16036-BLKI)
Prepared: 04/16/2019 15:23 Analyzed: 04/16/2019 18:42
Spike Source %REC
RPD
Anal vte
Resul
Bag
POL
Units
Level Result %REC Limits RPD
Limit
Notes
Nitrate/Nitrite as N
0.041
U
0.10
mg/L
LCS (9D16036-851)
Prepared: 04/16/2019 15:23 Analyzed: 04/16/2019 18:41
Spike Source %REC
RPD
Anal v[e
Resell
Bag
POL
UDlts
Level Result a/.REC Limits RPD
Lima
Notes
Nitrate/Nitrite as N
1.3
0.10
mg/L
1.25 105 90-110
Matrix Spike (91EI36036-MSS)
Prepared: 04/16/2019 15:23 Analyzed: 04/16/201918:46
Source: CC00074-01
Spike Source %REC
RPD
Anal vte
Result;
Bag
POL
Units
Level Result a/.REC Limits RPD
MaliMalit
Notes
Nitrate/Nitrite as
0.77
0.10
mg/L
0.521 0.23 104 90-110
Matrix Spike (9D36036-MS2)
Prepared: 04/16/2019 15:23 Analyzed: 04/16/201918:55
Source: CC01623-01
Spike Source °/.REC
RPD
Anal vte
Result
Bag
PM
units
Level Result %REC Limits RPD
Limit
Notes
FINAL
mis report relates only to
the sample as
received by the laboratory, and may only be reproducetl in full.
Page 33 Of 39

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 9D15035 - NO PREP - Continued
Matrix Spike (910,36036-MS2) Continued
Prepared: 04/16/2019 15:23 Analyzed: 04/161201918:55
Source: CC0L623-01
Spike Source %REC
RPD
Anal YL
Result
Flag
PQL
Units
Level Result %REC Limits RPD
Limit
Notes
Nitrate/Nitrite as N
36
2.0
mg/L
10.0 24 117 90-110
QM-07
Matrix Spike Dup (9D16036-101SDI)
Prepared: 04/16/2019 15:23 Analyzed: 04/16/201918:48
Source: CC00074-01
Spike Source %REC
RPD
Anal vte
Result
Ran
PQL
Units
Level Result ^/oREC Limits RPD
Lima
Notes
Nitrate/Nitrite as N
0.79
0.10
mg/L
0.521 0.23 108 90-110 3
10
Batch 9DIS015- NO PREP
Blank (9D3801S-BLK1)
Prepared: 04/18/2019 08:50 Analyzed: 04/18/2019 10:36
Spike Source %REC
RPD
AnalYte
Result
Rag
PQL
units
Level Result °/oREC Lim RPD
Limit
Notes
Ammonia as N
0.045
U
0.10
mg/L
LCS (9DISOIS-BSI)
Prepared: 04/18/2019 08:50 Analyzed: 04/18/2019 10:38
Spike Source %REC
RPD
Anal vte
Result
Ran
PDL
Unitr
Level Result %REC Limits RPD
Limit
Notes
Ammonia as N
1.0
0.10
mg/L
1.00 102 90-110
Matrix Spike (9D38015-MSi)
Prepared: 04/18/2019 08:50 Analyzed: 04/18/2019 10:42
Source: CB18508.02
Spike Source %REC
RPD
Anal l2e
Result
Rag
NIL
units
Level Result %REC Limits RPD
Limit
Notes
Ammonia as N
0.37
0.10
mg/L
0.389 0.045 U 96 90-110
Matrix Spike (9D38015-MS2)
Prepared: 04/18/2019 08:50 Analyzed: 04/18/2019 10:47
Source: CCO2812-OIRE1
Spike Source ^/oREC
RPD
Anal tAe
Result
Rao
PQL
LIM
Level Result %REC Limits RPD
Limit
Notes
Ammonia as N
20
E
1.0
mg/L
4.00 16 93 90-110
QM-07
Matrix Spike Dup (9D18015-MSDI)
Prepared: 04/18/2019 08:50 Analyzed: 04/I8/2019 10:43
Source: CB18508-02
Spike Source %REC
RPD
Anal vte
Result
Rag
PQL
units
Level Result %REC Limits RPD
Lialk
Notes
Ammonia as N
0.37
0.10
m9/L
0.389 0.045 U 95 90-110 1
10
Batch 9021002 - NO PREP
Blank (9D21002-BLK3)
Prepared: 04/21/2019 10:19 Analyzed: 04/21/2019 13:17
Spike Source %REC
RPD
Anal vte
Resul
Rag
PAL
Units
Level Result %REC Limits RPD
Limit
Notes
Nitrate/Nitrite as
0.041
U
0.10
mg/L
LCS (9D23002-BSI)
Prepared: 04/21/2019 10:19 Analyzed: 04/21/2019 13:16
Spike Source %REC
RPD
Anal vte
Result
Rag
P_2
units
Level Result %REC Limits RPD
Limit
Notes
Nitrate/Nitrite as N
1.3
0.10
mg/L
1.25 101 90-110
FINAL mis report relates only to the sample as received by Me laboratory, and may only be reproduced in till. I Page 34 of 39

vvkamr.encolabs.com
QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 9D210O1- NO PREP - Continued
Matrix Spike (9D21002-MS3)
Prepared: 04/21/2019 10:19 Analyzed: 04/21/2019 13:21
Source: CC05609-01
Spike Source %REC
RPD
Anal lRg Result
Han
P41
Units
Level Result %REC Limits Rpl)
LLit Notes
Nitrate/Nitrite as N 0.54
0.10
mg/L
0.521 0.041 U 103 90-110
Matrix Spike (9D21002-MS2)
Prepared: 04/21/2019 10:19 Analyzed: 04/21/2019 13:26
Source: CC05610-02
Spike Source %REC
RPD
Anal Yte Result
Rag
P06
units
Level Result %REC klinits RPD
Limit Notes
Nitrate/Nitrite as N 0.50
0.10
mg/L
0.521 0.041 U 96 90-110
Matrix Spike Dup (9D21002-MSDI)
Prepared: 04/21/2019 10:19 Analyzed: 04/21/2019 13:23
Source: CC05609-01
Spike Source %REC
RPD
Anal v[e Respit
Rag
Q
Units
Level Result %REC Limits RPD
Limit Notes
Nitrate/Nitrite as N 0.55
0.10
mg/L
0.521 0.041 U 106 90-110 2
10
Matrix Spike Dup (9D21002-MSD2)
Prepared: 04/21/2019 10:19 Analyzed: 04/21/201913:28
Source: CCO5610-02
Spike Source %REC
RPD
Anah to Result
Ran
PQL
units
Level Result %REC Limits RPD
Limit Notes
Nitrate/Nitrite as N 0.49
0.10
mg/L
0.521 0.041 U 93 90-110 3
10
Microbiological Parameters -Quality Control
Batch 9DO9011- NO PREP
Duplicate (9D09012-DUPI)
Prepared: 04/08/2019 14:43 Analyzed: 04109/201911:07
Source: CC05006-01
Spike Source %REC
RPD
Anal Yte Result
Rag
POL
units
Level Resul o/aREC Limits RPD
1:111111 Notes
Coliform, Fecal 1.0
1.0
MPN/100 mL
1.0 U
25
Classical Chemistry Parameters - Quality Control
Batch 901O016 - NO PREP
Blank (9D10016-BLR3)
Prepared: 04/11/2019 12:00 Analyzed: 04/12/2019 01:42
Spike Source %REC
RPD
Ana1124 Result
flag
PQL
units
Level Result %REC Limits RPD
Limit Notes
Total Organic Carbon 0.34
U
1.0
mg/L
LCS (9D10016-6SI)
Prepared: 04/11/2019 12:00 Analyzed: 04/12/2019 01:42
Spike Source %REC
RPD
Anal v[e R4sul
FFlao
PM
units
Level Result %REC Limits RPD
Limit Notes_
Total Organic Carton 36
1.0
mg/L
40.0 91 85-115
Matrix Spike (9D10016-M51)
Prepared: 04/11/2019 12:00 Analyzed: 04/12/2019 01:42
Source: CCOSD06-01
Spike Source %REC
RPD
Analvte Result
flan
PQL
units
Level Result %REC Limits RPD
Limit Notes.
Total Organic Carbon 41
1.0
mg/L
40.0 5.0 91 85-115
Matrix Spike Dup (9D10016-MSD1)
Prepared: 0-4/11/2019 12:00 Analyzed: 04/12/2019 01:42
Source: CC05006-01
Spike Source %REC
RPD
Analvte Result
Rag
PQL
Units
Level Result %REC Limits RPD
LimS Notes
FINAL This report relates only to
the sample
as received by the
laboratory, and may only be reproduced in Ml.
Page 35 of 39

FJVdeal Vale
vrww.encolabs.com
QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 9010016 - NO PREP - Continued
Matrix Spike Dup (9D10016-MSDI) Continued Prepared: 04/11/201912:00 Analyzed: 04/12/2019 01:42
Source: CC05006-01
Spike Source %REC RPD
Anal vte RisgIlt Flail PGL Units Level Result %REC Limits RPD Lima Notes
Total Organic Carbon 42 1.0 mg/L 40.0 5.0 92 85-115 0.7 21
Batch 9D12035 - NO PREP
Blank (9D12035-BLK3) Prepared: 04/15/2019 07:50 Analyzed: 04/15/2019 14:37
Spike Source %REC RPD
Anal Result Dag P41 Unitr Level Resul[ %REC Limits RPD Limit Notes
Phenolics 0.034 U 0.050 mg/L
LCS (9D12035-1151) Prepared: 04/15/2019 07:50 Analyzed: 04/15/2019 14:37
Spike Source %REC
RPD
Anal ylg Rem&
Elm
P41
Unit£
Level Result %REC Limits RPD
Limit Notes
Phenolics 0.53
0.050
mg/L
0.500 106 90-110
Matrix Spike (9D12035-M51)
Prepared: 04/15/2019 07:50 Analyzed: 04/15/2019 14:37
Source: ACO2591-01
Spike Source %REC
RPD
Anal vte Result
13ao
P91
Units
Level Resul[ %REC Limits RPD
Limit N.0tei
Phenolics 0.50
0.050
mg/L
0.500 0.034 U 100 90-110
Matrix Spike Dup (91)12035-MSDI)
Prepared: 04/15/2019 07:50 Analyzed: 04/15/2019 14:37
Source: ACO2591-01
Spike Source %REC
RPD
.Anal Result
flag
M
Units
Level Result %REC Lim! & RPD
Limit N91ei
Phenolics 0.50
0.050
mg/L
0.500 0.034 U 100 90-110 0.7
10
FINAL This report relates only to the sample as received by the laboratory, and may only be reWodpced In Nll. I Page 36 Of 39

EN
www.encolabs.com
FLAGS/NOTES AND DEFINITIONS
0 The analyte was detected in the associated method blank.
D The sample was analyzed at dilution.
I The reported value is between the laboratory method detection limit (MDL) and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
U The anayte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
E The concentration indicated for this analyte is an estimated value above the calibration range of the
instrument. This value is considered an estimate.
MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content.
PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL.
N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater
confidence) to make a "tentative identification".
P Greater than 25% concentration difference was observed between the primary and secondary GC column.
The lower concentration is reported.
[CALL] Calculated analyte - MDUMRL reported to the highest reporting limit of the component analyses.
Q-01 Analysis performed outside of method - specified holding time.
QL-02 The associated laboratory control sample exhibited high bias; since the result is ND, there is no impact.
QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based
on acceptable LCS recovery.
QR-05 The RPD value for the sample duplicate or MS/MSD was outside of QC acceptance limits.
QS-03 Surrogate recovery outside acceptance limits
nrut This report relates only to the sample as ommyM by the btmrator,, and may only be wnol cea to U. I Page 37 of 39

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Page 38 of 39T
r.

Sample Preservation Verification
ENCO Cary
Work Order: CCO5006
Client: Arauco North America, Inc. (UN039)
ce- - - Nhk�
Project: Wastewater Permit Testing
Project #: [none]
Logged In: 08-Apr-19 11:44 --�� Logged By: John C King
Preservation Check Performed By: 1 T Date/Time: q-g'�R //5�)
rrnsnna-nl
Cont
Type
Pres (pH)
Requirement
W Checked /
In Control
pH Adjusted Dateffime
Adjusted
Reagent Used/Comments
B
250m1-A+H2SO4
<2
/ N / NA
Y / / NA
C
250mLP+H2SO4
<2
/ N / NA
Y / / NA
D
250mLP+HNO3
<2
/ N / NA
Y / / NA
92
Cont
Type
res (pH)
Requirement
pH Checked /
in Control
H Adjusted ate✓Tme
p I Adjusted
Reagent Used/Comments
9
B
250mLA+H2SO4
<2
/ N / NA
Y / / NA
C
25DmLP+H2SO4
<2
/ N / NA
Y / NA
D
250mLP+HNO3
<2
/ N / NA
Y / Njl NA
Rea ent Name ID
1
2
pH Strip ID:
Rea ent Name ID
3
� 1-7�d
Rea ent Name ID
5
6
C\ELMNT\Print\wko_PreservationCheck. rpt
Page 39 of 39
e1

&I
Engineers and Soil Scientists
Agri -Waste Technology, Inc.
501 North Salem Street
Suite 203
Apex, NC 27502
919-859-0669
www.agriwaste.00m
March 28, 2019
Yvonne Couts
Arauco North America
958 Corinth Road
Moncure, NC 27559
Subject: Wastewater Spray Irrigation System Management Plan
Permit WQ0003396 - Arauco North America
958 Corinth Road
Moncure, NC 27559
Chatham County
Dear Yvonne:
The purpose of this report is to discuss the current irrigation system and offer a management plan
for future operation to minimize or eliminate wastewater pending and runoff.
Preliminary Information
Occasionally the irrigation system has experienced ponding and poor drainage in the irrigation
fields. As a result, Arauco has engaged the use of pump and haul equipment to minimize
irrigation events and prevent the ponding conditions which are a permit violation. The pump and
haul activity has been permitted and all available information indicates that pump and haul will
be available for the foreseeable future.
Irrigation fields have been stressed in the past with heavy hydraulic and sodium loading. The site
is not capable of accepting the volumes allowed by the permit of 52 inches per year for fields 02,
03, 06, 07, 08, 09, and 10. Field 04 and 05 presently have an annual hydraulic limit of 12.74
inches. Hourly rates in the permit range from 0.20 to 0.60 inches per hour. These rates are not
being exceeded and the actual rate will be discussed below. It is a function of the irrigation pivot
speed, which is set at 100% and thus offering the lowest rate possible. Tables below will offer
recent calibration data supporting the rates.
The fields have been sprigged to hybrid bermudagrass and are in very good shape overall. In past
years, row crops have been attempted with mixed results. Historically, fields 02, 03, and 10 have

been more sensitive to wetness and ponding than the others. These three fields still have minor
ponding and bare areas but the extent is not significant. Fields 06, 07, and 08 have some very
minor areas of wet soils and bare spots. Fields 04 and 05 have the best topography to shed
surface water. Past assessments from 2016 and prior have shown poor crop health and large areas
of bare ground. Compared to recent history, the ground cover is excellent and offers great
erosion control and infiltrative capacity. The crop is hybrid bermudagrass with mixed areas of
yellow nutsedge and minor areas of crabgrass, johnsongrass, and a few mixed broadleaf weeds.
As required by the permit, a calibration was performed several years ago. That report and details
are available upon request. The key issue relevant to this project is the irrigation rate, as that is
critical to assessing runoff and ponding potential. The calibration data are presented in Table 1
below.
Table 1 - Calibration Data- irrigation rates
FIELD
NUMBER
MEASURED
APPLICATION
RATE in/hr
PERMITTED RATE
(in/hr)
COMPLIANT?
02
0.20
0.60
YES
03
0.23
0.60
YES
04
0.13
0.20
YES
05
0.14
0.20
YES
06
0.20
0.35
YES
07
0.20
0.60
YES
08
0.23
0.60
YES
09
0.15
0.60
YES
10
0.16
0.60
YES
All application rates are well under the permitted rate. The system has been operated for years
and the present application rates have proven effective and conservative enough for the soils,
given the proper irrigation conditions. This will be discussed more in the irrigation scheduling
section.
Sites have gentle topography with slopes of 0 to 6 percent, but mostly 1-2 percent. This gentle
slope condition enhances infiltration potential. Fields 04 and 05 have the best topography to shed
natural surface water. Further, they also have the lowest application rate. These fields should be
prioritized for irrigation when conditions are not yet suitable for irrigation on other fields.
Irrigation Scheduling
The key goal to any non -discharge irrigation system is operation to prevent ponding and runoff.
Permitted rates as shown above are acceptable for the soils and site topography. Annual limits
will not be approached, and have not been for many years.
The discussion below is based on the soils at the site. In brief, the soils have a sandy loam and
fine sandy loam surface texture 8-10 inches thick. Below this surface layer the soils are clay
loam and clay. The subsoil layer has experienced some clay dispersion over the past, and thus
soil structure in the subsoil is weak to non-existent. This affects the deep permeability rate of
these soils, and therefore a very slow and conservative drainage rate will be assumed. The

irrigation scheduling discussion below will be based upon the top 8 inches of soil, and its
wetting/drying cycles. Irrigation volumes will be discussed in terms of irrigation depth (inches)
per event. The operator can assess what total wastewater volume may be potentially irrigated
based upon these conditions. No daily or weekly volume can be developed as all irrigation events
are strictly a function of weather conditions in the 4-8 days prior to a selected irrigation event.
Also included is a water balance developed using local weather data and the drainage factor
discussed above. The water balance is a theoretical tool that can give estimated volumes of
irrigation potential. Day-to-day operation will be based upon the checkbook irrigation scheduling
method discussed below
Checkbook Method of Imaation Schedulin¢
Irrigation scheduling is best performed by close monitoring of the site conditions, weather
conditions, and maintaining detailed weather and application records. This method is referred to
as "the checkbook method". It starts with a known point of soil moisture, and works off of inputs
and losses over time, typically per day. Inputs are rainfall and irrigation events. Losses are
evaporation, transpiration, and deep soil drainage. Rainfall and irrigation events will be
measured. Losses will be calculated based on local weather historical data and based on the soil
conditions. For purpose of this evaluation, soil drainage will not be measured but estimated on a
very conservative basis as described above.
All fields will be defined as one zone as site conditions are similar, with these noted exceptions:
1) Fields 02, 03, and 10, due to topography and landscape position, are the most sensitive to
ponding. These three fields, for purpose of this report, are grouped into Zone A.
2) Fields 06, 07, 08, and 09 are in good shape and have similar properties. These four fields,
for purpose of this report, are grouped into Zone B.
3) Fields 04 and 05 have the best topography potential to shed natural rainfall and these will
more readily accept irrigation events. These two fields, for purpose of this report, are
grouped into Zone C.
Since the irrigation system applies approximately 0.2 inches of wastewater per irrigation event
with one full pivot run- i.e. the full 360-degree circle, the soils need the ability to accept this
irrigation depth without ponding. The table below (Table 2.) will set irrigation events based on
weather conditions. The assumptions are:
1) Starting point is soil saturation. This can be assumed after any irrigation event or after
any rainfall event at least 0.3 inches or greater in depth. Rainfall amounts less than 0.3
inches should be accounted for and prorated.
2) The maximum water holding capacity in the top 8 inches of soil is 2.4 inches of water.
3) That a decent cover crop is maintained on the fields. This will enhance
evapotranspiration.
Table 2. Irrigation Events after a saturation event.
MONTH
LAG TIME'
BEST CONDITIONS2
POOR CONDIITONS3
May -Sept
4 days
3 days
6 days
April, October
1
6 days
4 days
8 days
Nov -March
8 days
6 days
10 days

1-For Zone C fields, reduce by one day. For Zone A fields, add 2 days.
2- Best Conditions means full sun with some wind and low humidity. In the winter, best
conditions also means that the winter overseed (ryegrass) has good coverage.
3- Poor Conditions means overcast with high humidity and low wind.
The DWR monthly NDMR record keeping forms is a good tool to use to track irrigation events
and rainfall, and could be used as the management tool to record data and schedule irrigation
events.
Water Balance
An attached water balance was performed to estimate average potential irrigation for this site. It
is not intended to change the permit or override any permit conditions. It is based on a worst year
in five for weather conditions (also called 80te percentile weather data). Therefore, it can be used
as a general planning tool to estimate long-term irrigation potential. Although the water balance
shows monthly irrigation amounts, this tool should not be used for irrigation scheduling. The
checkbook method above, with tracking of rain and irrigation events, is the main tool to be used.
Assumptions for this water balance are:
1) Drainage of 0.1 for the slowly permeable subsoil
2) Most conservative drainage factor of 0.04 applied.
3) 50,000 gallons per day flow
4) All fields treated the same
The water balance shows that 16.8 inches annually could be applied, on average. However, make
sure that the permit limits for fields 04 and 05 (12.74 inches per year) are not exceeded.
Table 3. Irrigation Capacity from Water Balance
Field
Area acres
Application Depth in/
Volume (gallons/year)
2
3.64
16.8
1660,521
3
2.27
16.8
1,035 544
4
4.58
12.74 *
1,584,414
5
4.63
12.74 *
1,601,711
6
5.67
16.8
2,586 580
7
5.65
16.8
2,577,457
8
2.83
16.8
1,291,009
9
4.58
16.8
2,089,336
10
TOTAL
5.64
16.8 2,572,896
16,999,468
*Restricted by permit limit
Annual irrigation volume: 16,999,468 gallons per year or 46,574 gallons per day (assuming 365-
day operation).
SUMMARY COMMENTS
Present irrigation rates are acceptable for this system and soils. Operators are cautioned to run
only one irrigation cycle and not to reverse pivots, resulting in application depths exceeding 0.2
inches per event. The above summaries are based on presumed weather conditions, and actual

operation may be potentially higher or lower than the figures stated. Using the water balance
approach, an average daily flow of 46,574 gallons is permissible. Detailed irrigation scheduling
such as using the checkbook method may allow enhanced irrigation volumes.
Maximum irrigation potential can be realized with 7-day operation. An irrigation event should
not take place if a rainfall event of 0.5 inches or higher is predicted within 24 hours after the
irrigation event.
There may be vulnerable areas in each field where shallow subsurface drainage allows water to
weep out at low areas. These must be monitored before and during each irrigation event. These
areas may prevent the site from drying as predicted with the above related comments.
We appreciate the opportunity to assist you. Please contact us with any questions, concerns, or
comments upon review of this information.
Sincerely,
Karl Shaffer, LSS
Summary of Attachments
Attachment 1: Water Balance Revision