NCG030698_Baseline Sample 2019_20190408

2�SENCO Laboratories
9g
Accurate. Timely. Respousive. luuavative.
102-A Woodwinds Industrial Court
Cary NC, 27511
Phone: [phone] FAX: [phone]
Friday, March 29, 2019
Atlantic Environmental Associates (AT025)
Attn: Candice Moore
2483 Reliance Ave.
Apex, NC 27539
RE: Laboratory Results for
Project Number: [none], Project Name/Desc: Boone Trail
ENCO Workorder(s): CC04438
Dear Candice Moore,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Tuesday, March 19, 2019.
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted in the project narrative if applicable. This report shall not be reproduced except in
full, without the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Stephanie Franz
Project Manager
Enclosure(s)
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 of Z7

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SAMPLE SUMMARY/LABORATORY CHRONICLE
Client ID: BooneTraill
Lab ID: CC04438-01
Sampled: 03/15/19 05:20
Received: 03/19/19 13:03
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis
Date/Time(sl
EPA 1664E
EPA 1664B
04/12/19
03/26/19
09:52
03/27/19
13:40
EPA 200.7
Same
09/11/19
03/20/19
15:09
03/25/19
12:48
EPA 608.3
EPA 3510C
03/22/19
04/30/19
03/21/19
13:04
03/25/19
18:59
EPA 608.3
EPA 3510C
03/14/20
03/20/20
03/21/19
13:11
03/25/19
18:59
EPA 624.1
Same
03/29/19
03/20/19
00:47
03/21/19
01:02
EPA 625.1
EPA 3510C MS
03/22/19
04/29/19
03/20/19
08:17
03/23/19
08:00
SM 2540D-2011
NO PREP
03/22/19
03/20/19
17:39
03/20/19
17:39
Client ID: BooneTrai12
Lab ID: CC04438-02
Sampled: 03/15/19 05:45
Received: 03/19/19 13:03
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis
Date/Time(s)
EPA 1664B
EPA 1664B
04/12/19
03/26/19
09:52
03/27/19
13:40
EPA 200.7
Same
09/11/19
03/20/19
15:09
03/25/19
13:55
EPA 608.3
EPA 3510C
03/22/19
04/30/19
03/21/19
13:04
03/25/19
19:15
EPA 608.3
EPA 3510C
03/14/20
03/20/20
03/21/19
13:11
03/25/19
19:15
EPA 624.1
Same
03/29/19
03/20/19
00:47
03/21/19
01:34
EPA 625.1
EPA 3510C MS
03/22/19
04/29/19
03/20/19
08:17
03/23/19
08:30
SM 254OD-2011
NO PREP
03/22/19
03/20/19
17:39
03/20/19
17:39
Client ID: BooneTrail3
Lab ID: CC04438-03
Sampled: 03/15/19 06:30
Received: 03/19/19 13:03
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis
Date/Time(s)
EPA 1664E
EPA 1664B
04/12/19
03/26/19
09:52
03/27/19
13:40
EPA 200.7
Same
09/11/19
03/20/19
15:09
03/25/19
13:57
SM 2540D-2011
NO PREP
03/22/19
03/20/19
17:39
03/20/19
17:39
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 2 Of 27

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SAMPLE DETECTION SUMMARY
Client ID: Boone Trail 1
Lab ID:
CC04438-01
Anala
Total Suspended Solids
Zinc - Total
Results
16
68.4
Flag
MDL
4.0
4.40
POLL
4.0
10.0
Units
mg/L
ug/L
Method Notes
SM 2540D-2011
EPA 200.7
Client ID: Boone Trail 2
Lab ID:
CC04438-02
Anala
Bis(2-ethylhexyl)phthalate
Copper- Total
Results
6.4
3.17
Flag
1
MDL
3.5
1.60
POLL
5.0
10.0
Units
ug/L
ug/L
Method Notes
EPA 625.1
EPA 200.7
Di-n-octylphthalate
7.0
1 4.7
10
ug/L
EPA 625.1
Total Suspended Solids
34
12
12
mg/L
SM 2540D-2011
Zinc - Total
86.6
4.40
10.0
ug/L
EPA 200.7
Client ID: Boone Trail 3
Lab ID:
CC04438-03
Anala
Results
Flag MDL
POLL
Units
Method Notes
Copper- Total
1.92
1 1.60
10.0
ug/L
EPA 200.7
Total Suspended Solids
15
7.1
7.1
mg/L
SM 2540D-2011
Zinc - Total
61.8
4.40
10.0
ug/L
EPA 200.7
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 3 Of 27

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ANALYTICAL RESULTS
Description: Boone Trail 1 Lab Sample ID:CC04438-01 Received: 03/19/19 13:03
Matrix: Water Sampled:03/15/19 05:20 Work Order: CC04438
Project: Boone Trail Sampled By: Mike Outlaw
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte MAS Numberl
Results Flag
Units
DF
MDL
I'Q
Batch
Method
Analyzed
By Notes
1,1,1-Trichloroethane [71-55-6]^
< 0.80
ug/L
1
0.80
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
1,1,2,2-Tetrachloroethane [79-34-5]^
< 0.54
ug/L
1
0.54
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
1,1,2-Trichloroethane [79-00-5]^
< 0.76
ug/L
1
0.76
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
1,1-Dichloroethane [75-34-3]^
< 0.62
ug/L
1
0.62
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
1,1-Dichloroethene [75-35-4]^
< 0.94
ug/L
1
0.94
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
1,2-Dichlorobenzene [95-50-1]^
< 0.73
ug/L
1
0.73
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
1,2-Dichloroethane [107-06-2]^
< 0.63
ug/L
1
0.63
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
1,2-Dichloropropane [78-87-5]^
< 0.80
ug/L
1
0.80
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
1,3-Dichlorobenzene [541-73-1]^
< 0.77
ug/L
1
0.77
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
1,4-Dichlorobenzene [106-46-7]^
< 0.76
ug/L
1
0.76
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
Acrylonitrile [107-13-1]
< 3.2
ug/L
1
3.2
10
9C19022
EPA 624.1
03/21/19 01:02
MRK
Benzene [71-43-2]^
< 0.71
ug/L
1
0.71
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
Bromodichloromethane [75-27-4]^
< 0.52
ug/L
1
0.52
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
Bromoform [75-25-2]^
< 0.75
ug/L
1
0.75
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
Bromomethane [74-83-9]^
< 0.95
ug/L
1
0.95
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
Carbon Tetrachloride [56-23-5]^
< 0.94
ug/L
1
0.94
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
Chlorobenzene [108-90-7]^
< 0.72
ug/L
1
0.72
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
Chloroethane [75-00-3]^
< 0.98
ug/L
1
0.98
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
Chloroform [67-66-3]^
< 0.80
ug/L
1
0.80
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
Chloromethane [74-87-3]^
< 0.82
ug/L
1
0.82
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
cis-1,3-Dichloropropene [10061-01-5]^
< 0.59
ug/L
1
0.59
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
Dibromochloromethane [124-48-1]^
< 0.44
ug/L
1
0.44
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
Ethylbenzene [100-41-4]^
< 0.69
ug/L
1
0.69
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
Methylene Chloride [75-09-2]^
< 2.0
ug/L
1
2.0
5.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
Tetrachloroethene [127-18-4]^
< 0.76
ug/L
1
0.76
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
Toluene [108-88-3]^
< 0.72
ug/L
1
0.72
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
trans-1,2-Dichloroethene [156-60-5]^
< 0.73
ug/L
1
0.73
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
trans-1,3-Dichloropropene [10061-02-6]^
< 0.73
ug/L
1
0.73
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
Trichloroethene [79-01-6]^
< 0.89
ug/L
1
0.89
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
Vinyl chloride [75-01-4]^
< 0.71
ug/L
1
0.71
1.0
9C19022
EPA 624.1
03/21/19 01:02
MRK
Surfooates
Results DF
Spike L v/
% Rec
% Rec Limits
Batch
Method
Anaivzed
Notes
4-Bromofluorobenzene
53 1
50.0
105 %
41-142
909022
EPA 624.1
03121119 01:02
MRK
Dibromofluoromethane
54 1
50.0
107 %
53-146
909022
EPA 624.1
03121119 01:02
MRK
Toluene-d8
51 1
50.0
101 %
41-146
909022
EPA 624.1
03121119 01:02
MRK
Semivolatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte MAS Numberl
Results Flag
Units
DF
MDL 4
Batch
Method
Analyzed
By Notes
1,2,4-Trichlorobenzene [120-82-1]^
< 3.3
ug/L
1
3.3
10
9C20003
EPA 625.1
03/23/19 08:00
DFM
1,2-Dichlorobenzene [95-50-1]^
< 3.2
ug/L
1
3.2
10
9C20003
EPA 625.1
03/23/19 08:00
DFM
1,3-Dichlorobenzene [541-73-1]^
< 3.4
ug/L
1
3.4
10
9C20003
EPA 625.1
03/23/19 08:00
DFM
1,4-Dichlorobenzene [106-46-7]^
< 3.2
ug/L
1
3.2
10
9C20003
EPA 625.1
03/23/19 08:00
DFM
2,4,6-Trichlorophenol[88-06-2]^
< 6.4
ug/L
1
6.4
10
9C20003
EPA 625.1
03/23/19 08:00
DFM
2,4-Dichlorophenol[120-83-2]^
< 6.5
ug/L
1
6.5
10
9C20003
EPA 625.1
03/23/19 08:00
DFM
2,4-Dimethylphenol[105-67-9]^
< 6.4
ug/L
1
6.4
10
9C20003
EPA 625.1
03/23/19 08:00
DFM
2,4-Dinitrophenol [51-28-5]^
< 7.7
ug/L
1
7.7
10
9C20003
EPA 625.1
03/23/19 08:00
DFM
2,4-Dinitrotoluene [121-14-2]^
< 3.2
ug/L
1
3.2
10
9C20003
EPA 625.1
03/23/19 08:00
DFM
FINAL
This report relates only to the
sample as received by the laboratory, and may only be reproduced in full.
I Page 4 Of 27

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ANALYTICAL RESULTS
Description: Boone Trail 1 Lab Sample ID:CC04438-01 Received: 03/19/19 13:03
Matrix: Water Sampled:03/15/19 05:20 Work Order: CC04438
Project: Boone Trail Sampled By: Mike Outlaw
Semivolatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results Flag
Units
DF
MDL
I'Q
Batch
Method
Analyzed
By Notes
2,6-Dinitrotoluene [606-20-2]A
< 2.9
ug/L
1
2.9
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
2-Chloronaphthalene [91-58-7]A
< 3.2
ug/L
1
3.2
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
2-Chlorophenol[95-57-8]A
< 7.4
ug/L
1
7.4
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
2-Methyl-4,6-dinitrophenol[534-52-1]A
< 6.0
ug/L
1
6.0
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
2-Nitrophenol[88-75-5]A
< 5.2
ug/L
1
5.2
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
3,3'-Dichlorobenzidine [91-94-1]A
< 3.3
ug/L
1
3.3
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
4-Bromophenyl-phenylether[101-55-3]A
< 3.3
ug/L
1
3.3
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
4-Chloro-3-methylphenol[59-50-7]A
< 7.3
ug/L
1
7.3
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
4-Chlorophenyl-phenylether [7005-72-3]A
< 3.2
ug/L
1
3.2
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
4-Nitrophenol[100-02-7]A
< 7.9
ug/L
1
7.9
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Acenaphthene [83-32-9]A
< 3.0
ug/L
1
3.0
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Acenaphthylene [208-96-8]A
< 9.6
ug/L
1
9.6
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Anthracene[120-12-7]A
< 3.0
ug/L
1
3.0
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Benzidine [92-87-5]A
< 7.1
ug/L
1
7.1
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Benzo(a)anthracene [56-55-3]A
< 3.2
ug/L
1
3.2
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Benzo(a)pyrene [50-32-8]A
< 3.2
ug/L
1
3.2
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Benzo(b)fluoranthene [205-99-2]A
< 3.4
ug/L
1
3.4
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Benzo(g,h,i)perylene [191-24-2]A
< 3.7
ug/L
1
3.7
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Benzo(k)fluoranthene [207-08-9]A
< 3.8
ug/L
1
3.8
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Bis(2-chloroethoxy)methane [111-91-1]A
< 3.3
ug/L
1
3.3
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Bis(2-chloroethyl)ether [111-44-4]A
< 3.8
ug/L
1
3.8
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Bis(2-chloroisopropyl)ether [108-60-1]A
< 3.5
ug/L
1
3.5
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Bis(2-ethylhexyl)phthalate [117-81-7]A
< 3.5
ug/L
1
3.5
5.0
9C20003
EPA
625.1
03/23/19
08:00
DFM
Butylbenzylphthalate [85-68-7]A
< 5.1
ug/L
1
5.1
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Chrysene [218-01-9]A
< 3.0
ug/L
1
3.0
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Dibenzo(a,h)anthracene [53-70-3]A
< 3.8
ug/L
1
3.8
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Diethylphthalate [84-66-2]A
< 3.0
ug/L
1
3.0
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Dimethylphthalate [131-11-3]A
< 3.0
ug/L
1
3.0
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Di-n-butylphthalate [84-74-2]A
< 3.2
ug/L
1
3.2
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Di-n-octylphthalate [117-84-0]A
< 4.7
ug/L
1
4.7
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
DPH (as Azobenzene)[103-33-3]
< 3.1
ug/L
1
3.1
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Fluoranthene[206-44-0]A
< 4.0
ug/L
1
4.0
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Fluorene [86-73-7]A
< 2.9
ug/L
1
2.9
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Hexachlorobenzene [118-74-1]A
< 3.0
ug/L
1
3.0
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Hexachlorobutadiene [87-68-3]A
< 4.1
ug/L
1
4.1
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Hexachlorocyclopentadiene [77-47-4]A
< 3.8
ug/L
1
3.8
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Hexachloroethane [67-72-1]A
< 3.0
ug/L
1
3.0
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Indeno(1,2,3-cd)pyrene [193-39-5]A
< 4.1
ug/L
1
4.1
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Isophorone [78-59-1]A
< 4.5
ug/L
1
4.5
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Naphthalene [91-20-3]A
< 3.6
ug/L
1
3.6
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Nitrobenzene [98-95-3]A
< 3.2
ug/L
1
3.2
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
N-Nitrosodimethylamine [62-75-9]A
< 3.8
ug/L
1
3.8
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
N-Nitroso-di-n-propylamine [621-64-7]A
< 4.5
ug/L
1
4.5
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
N-nitrosodiphenylamine/Diphenylamine
< 5.4
ug/L
1
5.4
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
[86-30-6/122-39-4]A
Pentachlorophenol[87-86-5]A
< 8.2
ug/L
1
8.2
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Phenanthrene [85-01-8]A
< 2.8
ug/L
1
2.8
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
Phenol[108-95-2]A
< 5.6
ug/L
1
5.6
10
9C20003
EPA
625.1
03/23/19
08:00
DFM
FINAL
This report relates only to the sample as received
by the
laboratory,
and may only be reproduced in full.
I Page 5 Of 27

00�
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ANALYTICAL RESULTS
Description: Boone Trail 1 Lab Sample ID:CC04438-01 Received: 03/19/19 13:03
Matrix: Water Sampled:03/15/19 05:20 Work Order: CC04438
Project: Boone Trail Sampled By: Mike Outlaw
Semivolatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 5911
Analyte MAS Numberl Results Flag Units DF MDL Q Batch Method Analyzed By Notes
Pyrene [129-00-0]A < 4.1 ug/L 1 4.1 10 9C20003 EPA 625.1 03/23/19 08:00 DFM
Surrogates
Results
DF
Spike L v/
% Rec
% Rec Limits
Batch
Method
Analyzed
Notes
2,4,6-Tribromophenol
88
1
100
88 %
47-128
9C20003
EPA 625.1
03123119 08:00
DFM
2-Fluorobiphenyi
41
1
50.0
82 %
44-102
9C20003
EPA 625.1
03123119 08:00
DFM
2-Fluorophenol
56
1
100
56 %
25-79
9C20003
EPA 625.1
03123119 08:00
DFM
Nitrobenzene-d5
41
1
50.0
82 %
43-112
9C20003
EPA 625.1
03123119 08:00
DFM
Phenol-d5
44
1
100
44 %
14-54
9C20003
EPA 625.1
03123119 08:00
DFM
Terphenyl-d14
50
1
50.0
101 %
65-122
9C20003
EPA 625.1
03123119 08:00
DFM
Semivolatile Organic Compounds by GC
^ - ENCO Cary certified analyte [NC 591]
Analyte FCAS Numberl
Results
Flag
Units
DF
MDL
4
Batch
Method
Analyzed
By Notes
4,4'-DDD [72-54-8]A
< 0.018
ug/L
1
0.018
0.050
9C21033
EPA 608.3
03/25/19 18:59
LSK
4,4'-DDE [72-55-9]A
< 0.036
ug/L
1
0.036
0.050
9C21033
EPA 608.3
03/25/19 18:59
LSK
4,4'-DDT [50-29-3]A
< 0.025
ug/L
1
0.025
0.050
9C21033
EPA 608.3
03/25/19 18:59
LSK
Aldrin [309-00-2]A
< 0.032
ug/L
1
0.032
0.050
9C21033
EPA 608.3
03/25/19 18:59
LSK
alpha-BHC [319-84-6]A
< 0.026
ug/L
1
0.026
0.050
9C21033
EPA 608.3
03/25/19 18:59
LSK
beta-BHC [319-85-7]A
< 0.022
ug/L
1
0.022
0.050
9C21033
EPA 608.3
03/25/19 18:59
LSK
Chlordane (n.o.s.) [57-74-9]
< 0.49
ug/L
1
0.49
0.50
9C21033
EPA 608.3
03/25/19 18:59
LSK
Chlordane (tech)[12789-03-6]A
< 0.36
ug/L
1
0.36
0.50
9C21033
EPA 608.3
03/25/19 18:59
LSK
delta-BHC [319-86-8]A
< 0.019
ug/L
1
0.019
0.050
9C21033
EPA 608.3
03/25/19 18:59
LSK
Dieldrin [60-57-1]A
< 0.017
ug/L
1
0.017
0.050
9C21033
EPA 608.3
03/25/19 18:59
LSK
Endosulfan I[959-98-8]A
< 0.016
ug/L
1
0.016
0.050
9C21033
EPA 608.3
03/25/19 18:59
LSK
Endosulfan II[33213-65-9]A
< 0.017
ug/L
1
0.017
0.050
9C21033
EPA 608.3
03/25/19 18:59
LSK
Endosulfan sulfate [1031-07-8]A
< 0.016
ug/L
1
0.016
0.050
9C21033
EPA 608.3
03/25/19 18:59
LSK
Endrin [72-20-8]A
< 0.014
ug/L
1
0.014
0.050
9C21033
EPA 608.3
03/25/19 18:59
LSK
Endrin aldehyde [7421-93-4]A
< 0.020
ug/L
1
0.020
0.050
9C21033
EPA 608.3
03/25/19 18:59
LSK
gamma-BHC [58-89-9]A
< 0.020
ug/L
1
0.020
0.050
9C21033
EPA 608.3
03/25/19 18:59
LSK
Heptachlor[76-44-8]A
< 0.018
ug/L
1
0.018
0.050
9C21033
EPA 608.3
03/25/19 18:59
LSK
Heptachlor epoxide [1024-57-3]A
< 0.018
ug/L
1
0.018
0.050
9C21033
EPA 608.3
03/25/19 18:59
LSK
PCB-1016/1242 [12674-11-2/53469-21-9]A
< 0.49
ug/L
1
0.49
0.50
9C21034
EPA 608.3
03/25/19 18:59
LSK
PCB-1221 [11104-28-2]A
< 0.46
ug/L
1
0.46
0.50
9C21034
EPA 608.3
03/25/19 18:59
LSK
PCB-1232 [11141-16-5]A
< 0.47
ug/L
1
0.47
0.50
9C21034
EPA 608.3
03/25/19 18:59
LSK
PCB-1248 [12672-29-6]A
< 0.49
ug/L
1
0.49
0.50
9C21034
EPA 608.3
03/25/19 18:59
LSK
PCB-1254 [11097-69-1]A
< 0.50
ug/L
1
0.50
0.50
9C21034
EPA 608.3
03/25/19 18:59
LSK
PCB-1260 [11096-82-5]A
< 0.47
ug/L
1
0.47
0.50
9C21034
EPA 608.3
03/25/19 18:59
LSK
Toxaphene [8001-35-2]A
< 0.48
ug/L
1
0.48
0.50
9C21033
EPA 608.3
03/25/19 18:59
LSK
Surrogates
2,4,5,E-TCMX
2,4,5,E-TCMX
Decachlorob/phenyl
Decachlorobiphenyl
Results
DF
Spike Lv/
% Rec
% Rec Limits
Batch
Method
0,86
1
1.00
86 %
38-142
9C21033
EPA 608.3
0,95
1
1.00
95 %
38-142
9C21034
EPA 608.3
0,93
1
1.00
93 %
34-159
9C21034
EPA 608.3
0,96
1
1.00
96 %
34-159
9C21033
EPA 608.3
Analyzed
By Notes
0312511918:59
LSK
0312511918:59
LSK
0312511918:59
LSK
0312511918:59
LSK
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 6 Of 27

(� �Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: Boone Trail 1 Lab Sample ID:CC04438-01 Received: 03/19/19 13:03
Matrix: Water Sampled:03/15/19 05:20 Work Order: CC04438
Project: Boone Trail Sampled By: Mike Outlaw
Metals by EPA 200 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte I'CAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
Copper[7440-50-8]^
< 1.60
ug/L
1
1.60
10.0
9C20032
EPA 200.7
03/25/19 12:48
]DH
Lead [7439-92-1]^
< 3.10
ug/L
1
3.10
10.0
9C20032
EPA 200.7
03/25/19 12:48
]DH
Zinc[7440-66-6]^
68.4
ug/L
1
4.40
10.0
9C20032
EPA 200.7
03/25/19 12:48
]DH
Classical Chemistry Parameters
^ - ENCO Cary certified analyte [NC 591]
Analyte I'CAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
Total Suspended Solids^
16
mg/L
1.6
4.0
4.0
9C20015
SM 2540D-2011
03/20/19 17:39
ASC
Classical Chemistry Parameters
^ - ENCO Jacksonville certified analyte [NC 442]
Analyte I'CAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
Oil & Grease (HEM-SGT) Non -Polar
< 2.70
mg/L
1
2.70
5.00
9C26004
EPA 1664E
03/27/19 13:40
SMA
Material^
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 7 Of Z7

0Nk"q09
www.encolabs.com
ANALYTICAL RESULTS
Description: Boone Trail 2 Lab Sample ID:CC04438-02 Received: 03/19/19 13:03
Matrix: Water Sampled:03/15/19 05:45 Work Order: CC04438
Project: Boone Trail Sampled By: Mike Outlaw
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte MAS Numberl
Results Flag
Units
DF
MDL
I'Q
Batch
Method
Analyzed
By Notes
1,1,1-Trichloroethane [71-55-6]^
< 0.80
ug/L
1
0.80
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
1,1,2,2-Tetrachloroethane [79-34-5]^
< 0.54
ug/L
1
0.54
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
1,1,2-Trichloroethane [79-00-5]^
< 0.76
ug/L
1
0.76
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
1,1-Dichloroethane [75-34-3]^
< 0.62
ug/L
1
0.62
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
1,1-Dichloroethene [75-35-4]^
< 0.94
ug/L
1
0.94
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
1,2-Dichlorobenzene [95-50-1]^
< 0.73
ug/L
1
0.73
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
1,2-Dichloroethane [107-06-2]^
< 0.63
ug/L
1
0.63
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
1,2-Dichloropropane [78-87-5]^
< 0.80
ug/L
1
0.80
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
1,3-Dichlorobenzene [541-73-1]^
< 0.77
ug/L
1
0.77
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
1,4-Dichlorobenzene [106-46-7]^
< 0.76
ug/L
1
0.76
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
Acrylonitrile [107-13-1]
< 3.2
ug/L
1
3.2
10
9C19022
EPA 624.1
03/21/19 01:34
MRK
Benzene [71-43-2]^
< 0.71
ug/L
1
0.71
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
Bromodichloromethane [75-27-4]^
< 0.52
ug/L
1
0.52
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
Bromoform [75-25-2]^
< 0.75
ug/L
1
0.75
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
Bromomethane [74-83-9]^
< 0.95
ug/L
1
0.95
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
Carbon Tetrachloride [56-23-5]^
< 0.94
ug/L
1
0.94
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
Chlorobenzene [108-90-7]^
< 0.72
ug/L
1
0.72
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
Chloroethane [75-00-3]^
< 0.98
ug/L
1
0.98
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
Chloroform [67-66-3]^
< 0.80
ug/L
1
0.80
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
Chloromethane [74-87-3]^
< 0.82
ug/L
1
0.82
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
cis-1,3-Dichloropropene [10061-01-5]^
< 0.59
ug/L
1
0.59
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
Dibromochloromethane [124-48-1]^
< 0.44
ug/L
1
0.44
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
Ethylbenzene [100-41-4]^
< 0.69
ug/L
1
0.69
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
Methylene Chloride [75-09-2]^
< 2.0
ug/L
1
2.0
5.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
Tetrachloroethene [127-18-4]^
< 0.76
ug/L
1
0.76
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
Toluene [108-88-3]^
< 0.72
ug/L
1
0.72
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
trans-1,2-Dichloroethene [156-60-5]^
< 0.73
ug/L
1
0.73
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
trans-1,3-Dichloropropene [10061-02-6]^
< 0.73
ug/L
1
0.73
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
Trichloroethene [79-01-6]^
< 0.89
ug/L
1
0.89
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
Vinyl chloride [75-01-4]^
< 0.71
ug/L
1
0.71
1.0
9C19022
EPA 624.1
03/21/19 01:34
MRK
Surfooates
Results DF
Spike L v/
% Rec
% Rec Limits
Batch
Method
Anaivzed
Notes
4-Bromofluorobenzene
53 1
50.0
106 %
41-142
909022
EPA 624.1
03121119 01:34
MRK
Dibromofluoromethane
48 1
50.0
96 %
53-146
909022
EPA 624.1
03121119 01:34
MRK
Toluene-d8
52 1
50.0
104 %
41-146
909022
EPA 624.1
03121119 0134
MRK
Semivolatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte MAS Numberl
Results Flag
Units
DF
MDL 4
Batch
Method
Analyzed
By Notes
1,2,4-Trichlorobenzene [120-82-1]^
< 3.3
ug/L
1
3.3
10
9C20003
EPA 625.1
03/23/19 08:30
DFM
1,2-Dichlorobenzene [95-50-1]^
< 3.2
ug/L
1
3.2
10
9C20003
EPA 625.1
03/23/19 08:30
DFM
1,3-Dichlorobenzene [541-73-1]^
< 3.4
ug/L
1
3.4
10
9C20003
EPA 625.1
03/23/19 08:30
DFM
1,4-Dichlorobenzene [106-46-7]^
< 3.2
ug/L
1
3.2
10
9C20003
EPA 625.1
03/23/19 08:30
DFM
2,4,6-Trichlorophenol[88-06-2]^
< 6.4
ug/L
1
6.4
10
9C20003
EPA 625.1
03/23/19 08:30
DFM
2,4-Dichlorophenol[120-83-2]^
< 6.5
ug/L
1
6.5
10
9C20003
EPA 625.1
03/23/19 08:30
DFM
2,4-Dimethylphenol[105-67-9]^
< 6.4
ug/L
1
6.4
10
9C20003
EPA 625.1
03/23/19 08:30
DFM
2,4-Dinitrophenol [51-28-5]^
< 7.7
ug/L
1
7.7
10
9C20003
EPA 625.1
03/23/19 08:30
DFM
2,4-Dinitrotoluene [121-14-2]^
< 3.2
ug/L
1
3.2
10
9C20003
EPA 625.1
03/23/19 08:30
DFM
FINAL
This report relates only to the
sample as received by the laboratory, and may only be reproduced in full.
I Page 8 Of 27

00�
www.encolabs.com
ANALYTICAL RESULTS
Description: Boone Trail 2 Lab Sample ID:CC04438-02 Received: 03/19/19 13:03
Matrix: Water Sampled:03/15/19 05:45 Work Order: CC04438
Project: Boone Trail Sampled By: Mike Outlaw
Semivolatile Organic Compounds
by GCMS
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
2,6-Dinitrotoluene [606-20-2]^
< 2.9
ug/L
1
2.9
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
2-Chloronaphthalene [91-58-7]^
< 3.2
ug/L
1
3.2
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
2-Chlorophenol[95-57-8]^
< 7.4
ug/L
1
7.4
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
2-Methyl-4,6-dinitrophenol[534-52-1]^
< 6.0
ug/L
1
6.0
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
2-Nitrophenol[88-75-5]^
< 5.2
ug/L
1
5.2
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
3,3'-Dichlorobenzidine [91-94-1]^
< 3.3
ug/L
1
3.3
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
4-Bromophenyl-phenylether[101-55-3]^
< 3.3
ug/L
1
3.3
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
4-Chloro-3-methylphenol[59-50-7]^
< 7.3
ug/L
1
7.3
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
4-Chlorophenyl-phenylether [7005-72-3]^
< 3.2
ug/L
1
3.2
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
4-Nitrophenol[100-02-7]^
< 7.9
ug/L
1
7.9
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Acenaphthene [83-32-9]^
< 3.0
ug/L
1
3.0
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Acenaphthylene [208-96-8]^
< 9.6
ug/L
1
9.6
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Anthracene[120-12-7]^
< 3.0
ug/L
1
3.0
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Benzidine [92-87-5]^
< 7.1
ug/L
1
7.1
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Benzo(a)anthracene [56-55-3]^
< 3.2
ug/L
1
3.2
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Benzo(a)pyrene [50-32-8]^
< 3.2
ug/L
1
3.2
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Benzo(b)fluoranthene [205-99-2]^
< 3.4
ug/L
1
3.4
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Benzo(g,h,i)perylene [191-24-2]^
< 3.7
ug/L
1
3.7
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Benzo(k)fluoranthene [207-08-9]^
< 3.8
ug/L
1
3.8
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Bis(2-chloroethoxy)methane [111-91-1]^
< 3.3
ug/L
1
3.3
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Bis(2-chloroethyl)ether [111-44-4]^
< 3.8
ug/L
1
3.8
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Bis(2-chloroisopropyl)ether [108-60-1]^
< 3.5
ug/L
1
3.5
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Bis(2-ethylhexyl)phthalate
6.4
ug/L
1
3.5
5.0
9C20003
EPA
625.1
03/23/19
08:30
DFM
[117-81-7]A
Butylbenzylphthalate [85-68-7]^
< 5.1
ug/L
1
5.1
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Chrysene [218-01-9]^
< 3.0
ug/L
1
3.0
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Dibenzo(a,h)anthracene [53-70-3]^
< 3.8
ug/L
1
3.8
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Diethylphthalate [84-66-2]^
< 3.0
ug/L
1
3.0
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Dimethylphthalate [131-11-3]^
< 3.0
ug/L
1
3.0
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Di-n-butylphthalate [84-74-2]^
< 3.2
ug/L
1
3.2
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Di-n-octylphthalate [117-84-0]A
7.0 1
ug/L
1
4.7
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
DPH (as Azobenzene)[103-33-3]
< 3.1
ug/L
1
3.1
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Fluoranthene[206-44-0]^
< 4.0
ug/L
1
4.0
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Fluorene [86-73-7]^
< 2.9
ug/L
1
2.9
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Hexachlorobenzene [118-74-1]^
< 3.0
ug/L
1
3.0
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Hexachlorobutadiene [87-68-3]^
< 4.1
ug/L
1
4.1
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Hexachlorocyclopentadiene [77-47-4]^
< 3.8
ug/L
1
3.8
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Hexachloroethane [67-72-1]^
< 3.0
ug/L
1
3.0
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Indeno(1,2,3-cd)pyrene [193-39-5]^
< 4.1
ug/L
1
4.1
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Isophorone [78-59-1]^
< 4.5
ug/L
1
4.5
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Naphthalene [91-20-3]^
< 3.6
ug/L
1
3.6
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Nitrobenzene [98-95-3]^
< 3.2
ug/L
1
3.2
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
N-Nitrosodimethylamine [62-75-9]^
< 3.8
ug/L
1
3.8
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
N-Nitroso-di-n-propylamine [621-64-7]^
< 4.5
ug/L
1
4.5
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
N-nitrosodiphenylamine/Diphenylamine
< 5.4
ug/L
1
5.4
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
[86-30-6/122-39-4]^
Pentachlorophenol[87-86-5]^
< 8.2
ug/L
1
8.2
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
Phenanthrene [85-01-8]^
< 2.8
ug/L
1
2.8
10
9C20003
EPA
625.1
03/23/19
08:30
DFM
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 9 Of 27

00�
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ANALYTICAL RESULTS
Description: Boone Trail 2 Lab Sample ID:CC04438-02 Received: 03/19/19 13:03
Matrix: Water Sampled:03/15/19 05:45 Work Order: CC04438
Project: Boone Trail Sampled By: Mike Outlaw
Semivolatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 5911
Analyte MAS Numberl Results Flag
Units
DF MDL I'Q Batch Method Analyzed By Notes
Phenol[108-95-2]A < 5.6
ug/L
1 5.6 10 9C20003 EPA 625.1 03/23/19 08:30 DFM
Pyrene [129-00-0]A < 4.1
ug/L
1 4.1 10 9C20003 EPA 625.1 03/23/19 08:30 DFM
Surrogates
Results
DF
Spike L v/
% Rec
% Rec Limits
Batch
Method
Ana/vied
Notes
2,4,6-Tribromophenol
92
1
100
92 %
47-128
9C20003
EPA 625.1
03123119 08:30
DFM
2-Fluorobiphenyi
39
1
50.0
77 %
44-102
9C20003
EPA 625.1
03123119 08:30
DFM
2-Fluorophenol
49
1
100
49 %
25-79
9C20003
EPA 625.1
03123119 08:30
DFM
Nitrobenzene-d5
35
1
50.0
69 %
43-112
9C20003
EPA 625.1
03123119 08:30
DFM
Phenol-d5
41
1
100
41 %
14-54
9C20003
EPA 625.1
03123119 0830
DFM
Terphenyl-d14
46
1
50.0
91 %
65-122
9C20003
EPA 625.1
03123119 0830
DFM
Semivolatile Organic Compounds by GC
^ - ENCO Cary certified analyte [NC 591]
Analyte FCAS Numberl
Results
Flag
Units
DF
MDL 4
Batch
Method
Analyzed
By Notes
4,4'-DDD [72-54-8]A
< 0.018
ug/L
1
0.018 0.050
9C21033
EPA 608.3
03/25/19 19:15
LSK
4,4'-DDE [72-55-9]A
< 0.036
ug/L
1
0.036 0.050
9C21033
EPA 608.3
03/25/19 19:15
LSK
4,4'-DDT [50-29-3]A
< 0.025
ug/L
1
0.025 0.050
9C21033
EPA 608.3
03/25/19 19:15
LSK
Aldrin [309-00-2]A
< 0.032
ug/L
1
0.032 0.050
9C21033
EPA 608.3
03/25/19 19:15
LSK
alpha-BHC [319-84-6]A
< 0.026
ug/L
1
0.026 0.050
9C21033
EPA 608.3
03/25/19 19:15
LSK
beta-BHC [319-85-7]A
< 0.022
ug/L
1
0.022 0.050
9C21033
EPA 608.3
03/25/19 19:15
LSK
Chlordane (n.o.s.) [57-74-9]
< 0.49
ug/L
1
0.49 0.50
9C21033
EPA 608.3
03/25/19 19:15
LSK
Chlordane (tech)[12789-03-6]A
< 0.36
ug/L
1
0.36 0.50
9C21033
EPA 608.3
03/25/19 19:15
LSK
delta-BHC [319-86-8]A
< 0.019
ug/L
1
0.019 0.050
9C21033
EPA 608.3
03/25/19 19:15
LSK
Dieldrin [60-57-1]A
< 0.017
ug/L
1
0.017 0.050
9C21033
EPA 608.3
03/25/19 19:15
LSK
Endosulfan I[959-98-8]A
< 0.016
ug/L
1
0.016 0.050
9C21033
EPA 608.3
03/25/19 19:15
LSK
Endosulfan II[33213-65-9]A
< 0.017
ug/L
1
0.017 0.050
9C21033
EPA 608.3
03/25/19 19:15
LSK
Endosulfan sulfate [1031-07-8]A
< 0.016
ug/L
1
0.016 0.050
9C21033
EPA 608.3
03/25/19 19:15
LSK
Endrin [72-20-8]A
< 0.014
ug/L
1
0.014 0.050
9C21033
EPA 608.3
03/25/19 19:15
LSK
Endrin aldehyde [7421-93-4]A
< 0.020
ug/L
1
0.020 0.050
9C21033
EPA 608.3
03/25/19 19:15
LSK
gamma-BHC [58-89-9]A
< 0.020
ug/L
1
0.020 0.050
9C21033
EPA 608.3
03/25/19 19:15
LSK
Heptachlor[76-44-8]A
< 0.018
ug/L
1
0.018 0.050
9C21033
EPA 608.3
03/25/19 19:15
LSK
Heptachlor epoxide [1024-57-3]A
< 0.018
ug/L
1
0.018 0.050
9C21033
EPA 608.3
03/25/19 19:15
LSK
PCB-1016/1242 [12674-11-2/53469-21-9]A
< 0.49
ug/L
1
0.49 0.50
9C21034
EPA 608.3
03/25/19 19:15
LSK
PCB-1221 [11104-28-2]A
< 0.46
ug/L
1
0.46 0.50
9C21034
EPA 608.3
03/25/19 19:15
LSK
PCB-1232 [11141-16-5]A
< 0.47
ug/L
1
0.47 0.50
9C21034
EPA 608.3
03/25/19 19:15
LSK
PCB-1248 [12672-29-6]A
< 0.49
ug/L
1
0.49 0.50
9C21034
EPA 608.3
03/25/19 19:15
LSK
PCB-1254 [11097-69-1]A
< 0.50
ug/L
1
0.50 0.50
9C21034
EPA 608.3
03/25/19 19:15
LSK
PCB-1260 [11096-82-5]A
< 0.47
ug/L
1
0.47 0.50
9C21034
EPA 608.3
03/25/19 19:15
LSK
Toxaphene [8001-35-2]A
< 0.48
ug/L
1
0.48 0.50
9C21033
EPA 608.3
03/25/19 19:15
LSK
Surrogates
Results
DF
Spikev/
%Rec
%RecLimits
Batch
Method
Analyzed
By Notes
2,4,5,E-TCMX
0.73
1
1.00
73 %
38-142
9C21034
EPA 608.3
0312511919:15
LSK
2,4,5,E-TCMX
0.82
1
1.00
82 %
38-142
9C21033
EPA 608.3
0312511919:15
LSK
Decachlorobiphenyl
0.71
1
1.00
71 %
34-159
9C21034
EPA 608.3
0312511919:15
LSK
Decachlorobiphenyl
0.84
1
1.00
84 %
34-159
9C21033
EPA 608.3
0312511919:15
LSK
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 10 Of 27

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ANALYTICAL RESULTS
Description: Boone Trail 2 Lab Sample ID:CC04438-02 Received: 03/19/19 13:03
Matrix: Water Sampled:03/15/19 05:45 Work Order: CC04438
Project: Boone Trail Sampled By: Mike Outlaw
Metals by EPA 200 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte I'CAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
Copper[7440-50-8]^
3.17
J
ug/L
1
1.60
10.0
9C20032
EPA 200.7
03/25/19 13:55
JDH
Lead [7439-92-1]^
< 3.10
ug/L
1
3.10
10.0
9C20032
EPA 200.7
03/25/19 13:55
JDH
Zinc[7440-66-6]^
86.6
ug/L
1
4.40
10.0
9C20032
EPA 200.7
03/25/19 13:55
JDH
Classical Chemistry Parameters
^ - ENCO Cary certified analyte [NC 591]
Analyte I'CAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
Total Suspended Solids^
34
mg/L
5
12
12
9C20015
SM 2540D-2011
03/20/19 17:39
ASC
Classical Chemistry Parameters
^ - ENCO Jacksonville certified analyte [NC 442]
Analyte I'CAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
By Notes
Oil & Grease (HEM-SGT) Non -Polar
< 2.70
mg/L
1
2.70
5.00
9C26004
EPA 1664E
03/27/19 13:40
SMA
Description: Boone Trail 3 Lab Sample ID:CC04438-03 Received: 03/19/19 13:03
Matrix: Water Sampled:03/15/19 06:30 Work Order: CC04438
Project: Boone Trail Sampled By: Mike Outlaw
Metals by EPA 200 Series Methods
^ - ENCO Cary certified analyte [NC 591]
Analyte fCAS Numberl
Results
Flag
Units
DF
MDL
POLL
Batch
Method
Analyzed
Ay Notes
Copper[7440-50-8]^
1.92
J
ug/L
1
1.60
10.0
9C20032
EPA 200.7
03/25/19 13:57
JDH
Lead [7439-92-1]^
< 3.10
ug/L
1
3.10
10.0
9C20032
EPA 200.7
03/25/19 13:57
JDH
Zinc[7440-66-6]^
61.8
ug/L
1
4.40
10.0
9C20032
EPA 200.7
03/25/19 13:57
JDH
Classical Chemistry Parameters
^ - ENCO Cary certified analyte [NC 591]
Analyte fCAS Numberl
Results
Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
Ay Notes
Total Suspended Solids^
15
mg/L
2.86
7.1
7.1
9C20015
SM 2540D-2011
03/20/19 17:39
ASC
Classical Chemistry Parameters
^ - ENCO Jacksonville certified analyte [NC 442]
Analyte fCAS Numberl
Results
Flag
Units
DF
MDL
POLL
Batch
Method
Analyzed
Ay Notes
Oil & Grease (HEM-SGT) Non -Polar
< 2.70
mg/L
1
2.70
5.00
9C26004
EPA 1664B
03/27/19 13:40
SMA
Material^
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 11 Of 27

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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 9C19022 - EPA 50308 MS
Blank (9C19022-BLK3) Prepared: 03/20/2019 00:47 Analyzed: 03/20/2019 15:38
Analvte
Result
Flaq
POL
Units
1,1,1-Trichloroethane
0.80
U
1.0
ug/L
1,1,2,2-Tetrachloroethane
0.54
U
1.0
ug/L
1,1,2-Trichloroethane
0.76
U
1.0
ug/L
1,1-Dichloroethane
0.62
U
1.0
ug/L
1,1-Dichloroethene
0.94
U
1.0
ug/L
1,2-Dichlorobenzene
0.73
U
1.0
ug/L
1,2-Dichloroethane
0.63
U
1.0
ug/L
1,2-Dichloropropane
0.80
U
1.0
ug/L
1,3-Dichlorobenzene
0.77
U
1.0
ug/L
1,4-Dichlorobenzene
0.76
U
1.0
ug/L
Acrylonitrile
3.2
U
10
ug/L
Benzene
0.71
U
1.0
ug/L
Bromodichloromethane
0.52
U
1.0
ug/L
Bromoform
0.75
U
1.0
ug/L
Bromomethane
0.95
U
1.0
ug/L
Carbon Tetrachloride
0.94
U
1.0
ug/L
Chlorobenzene
0.72
U
1.0
ug/L
Chloroethane
0.98
U
1.0
ug/L
Chloroform
0.80
U
1.0
ug/L
Chloromethane
0.82
U
1.0
ug/L
cis- 1,3-Dichloropropene
0.59
U
1.0
ug/L
Dibromochloromethane
0.44
U
1.0
ug/L
Ethylbenzene
0.69
U
1.0
ug/L
Methylene Chloride
2.0
U
5.0
ug/L
Tetrachloroethene
0.76
U
1.0
ug/L
Toluene
0.72
U
1.0
ug/L
trans-1,2-Dichloroethene
0.73
U
1.0
ug/L
trans-1,3-Dichloropropene
0.73
U
1.0
ug/L
Trichloroethene
0.89
U
1.0
ug/L
Vinyl chloride
0.71
U
1.0
ug/L
Spike Source %REC RPD
Level Result %REC Limits RPD Limit Notes
4-Bromofluorobenzene 51
u9/L
50.0 102 41-142
Dibromofluoromethane 51
u91L
50.0 102 53-146
Toluene-d8 49
u9/L
50.0 99 41-146
LCS (9C19022-BS1)
Prepared: 03/20/2019 00:47 Analyzed: 03/20/2019 13:32
Analvte
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Acrylonitrile
Benzene
FINAL
Spike
Source
%REC
Result Flaq
POL
Units
Level
Result %REC
Limits
21
1.0
ug/L
20.0
103
70-130
19
1.0
ug/L
20.0
97
60-140
19
1.0
ug/L
20.0
94
70-130
23
1.0
ug/L
20.0
116
70-130
18
1.0
ug/L
20.0
90
50-150
20
1.0
ug/L
20.0
101
65-135
19
1.0
ug/L
20.0
96
70-130
21
1.0
ug/L
20.0
103
35-165
18
1.0
ug/L
20.0
91
70-130
19
1.0
ug/L
20.0
96
65-135
69
10
ug/L
60.0
116
60-140
22
1.0
ug/L
20.0
108
65-135
This report relates only to
the sample as received by the
laboratory, and
may only be reproduced in
full.
RPD
RPD Limit Notes
Page 12 of 27

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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 9C19022 - EPA 5030E MS - Continued
LCS (9C19022-BS3) Continued Prepared: 03/20/2019 00:47 Analyzed: 03/20/2019 13:32
Spike
Source
%REC
Analvte
Result Flaq
POL
Units
Level
Result %REC
Limits
Bromodichloromethane
20
1.0
ug/L
20.0
98
65-135
Bromoform
18
1.0
ug/L
20.0
90
70-130
Bromomethane
18
1.0
ug/L
20.0
92
15-185
Carbon Tetrachloride
20
1.0
ug/L
20.0
98
70-130
Chlorobenzene
19
1.0
ug/L
20.0
93
65-135
Chloroethane
20
1.0
ug/L
20.0
98
40-160
Chloroform
21
1.0
ug/L
20.0
103
70-135
Chloromethane
17
1.0
ug/L
20.0
86
5-205
cis- 1,3-Dichloropropene
21
1.0
ug/L
20.0
104
25-175
Dibromochloromethane
20
1.0
ug/L
20.0
100
70-135
Ethylbenzene
20
1.0
ug/L
20.0
99
60-140
Methylene Chloride
20
5.0
ug/L
20.0
101
60-140
Tetrachloroethene
25
1.0
ug/L
20.0
124
70-130
Toluene
20
1.0
ug/L
20.0
100
70-130
trans-1,2-Dichloroethene
21
1.0
ug/L
20.0
104
70-130
trans-1,3-Dichloropropene
22
1.0
ug/L
20.0
109
50-150
Trichloroethene
19
1.0
ug/L
20.0
97
65-135
Vinyl chloride
20
1.0
ug/L
20.0
102
5-195
RPD
RPD Limit Notes
4-Bromofluorobenzene 51 ug/L 50.0 103 41-142
Dibromofluoromethane 51 ug/L 50.0 101 53-146
Toluene-d8 50 ug/L 50.0 101 41-146
Matrix Spike (9C19022-MS1) Prepared: 03/20/2019 00:47 Analyzed: 03/20/2019 14:04
Source: CC04697-05
Spike
Source
%REC
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits RPD
1,1,1-Trichloroethane
22
1.0
ug/L
20.0
0.80 U
109
70-130
1,1,2,2-Tetrachloroethane
18
1.0
ug/L
20.0
0.54 U
88
60-140
1,1,2-Trichloroethane
19
1.0
ug/L
20.0
0.76 U
97
70-130
1,1-Dichloroethane
23
1.0
ug/L
20.0
0.62 U
117
70-130
1,1-Dichloroethene
19
1.0
ug/L
20.0
0.94 U
96
50-150
1,2-Dichlorobenzene
20
1.0
ug/L
20.0
0.73 U
99
65-135
1,2-Dichloroethane
19
1.0
ug/L
20.0
0.63 U
97
70-130
1,2-Dichloropropane
21
1.0
ug/L
20.0
0.80 U
103
35-165
1,3-Dichlorobenzene
20
1.0
ug/L
20.0
0.77 U
99
70-130
1,4-Dichlorobenzene
20
1.0
ug/L
20.0
0.76 U
99
65-135
Acrylonitrile
74
10
ug/L
60.0
3.2 U
124
60-140
Benzene
22
1.0
ug/L
20.0
0.71 U
110
65-135
Bromodichloromethane
20
1.0
ug/L
20.0
0.52 U
101
65-135
Bromoform
18
1.0
ug/L
20.0
0.75 U
90
70-130
Bromomethane
19
1.0
ug/L
20.0
0.95 U
94
15-185
Carbon Tetrachloride
21
1.0
ug/L
20.0
0.94 U
104
70-130
Chlorobenzene
20
1.0
ug/L
20.0
0.72 U
98
65-135
Chloroethane
23
1.0
ug/L
20.0
0.98 U
115
40-160
Chloroform
22
1.0
ug/L
20.0
0.80 U
108
70-135
Chloromethane
22
1.0
ug/L
20.0
0.82 U
109
5-205
cis- 1,3-Dichloropropene
21
1.0
ug/L
20.0
0.59 U
104
25-175
Dibromochloromethane
21
1.0
ug/L
20.0
0.44 U
103
70-135
Ethylbenzene
21
1.0
ug/L
20.0
0.69 U
103
60-140
Methylene Chloride
20
5.0
ug/L
20.0
2.0 U
101
60-140
FINAL
This report relates only to
the sample as received by the
laboratory, and
may only be
reproduced in
full.
RPD
Limit Notes
Page 13 of 27

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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 9C19022 - EPA 5030E MS - Continued
Matrix Spike (9C39022-MS3) Continued Prepared: 03/20/2019 00:47 Analyzed: 03/20/2019 14:04
Source: CC04697-05
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits
RPD
Limit
Notes
Tetrachloroethene
38
1.0
ug/L
20.0
0.76 U
190
70-130
QM-07
Toluene
21
1.0
ug/L
20.0
0.72 U
104
70-130
trans-1,2-Dichloroethene
21
1.0
ug/L
20.0
0.73 U
105
70-130
trans-1,3-Dichloropropene
22
1.0
ug/L
20.0
0.73 U
111
50-150
Trichloroethene
22
1.0
ug/L
20.0
0.89 U
108
65-135
Vinyl chloride
24
1.0
ug/L
20.0
0.71 U
120
5-195
4-Bromofluorobenzene
53
ug/L
50.0
105
41-142
Dibromofluoromethane
50
ug/L
50.0
100
53-146
Toluene-d8
51
ug/L
50.0
101
41-146
Matrix Spike Dup (9C19022-MSD1)
Prepared: 03/20/2019 00:47 Analyzed: 03/20/2019 14:35
Source: CC04697-05
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits
RPD
Limit
Notes
1,1,1-Trichloroethane
21
1.0
ug/L
20.0
0.80 U
105
70-130
4
36
1,1,2,2-Tetrachloroethane
17
1.0
ug/L
20.0
0.54 U
83
60-140
7
61
1,1,2-Trichloroethane
19
1.0
ug/L
20.0
0.76 U
93
70-130
4
45
1,1-Dichloroethane
22
1.0
ug/L
20.0
0.62 U
110
70-130
6
40
1,1-Dichloroethene
19
1.0
ug/L
20.0
0.94 U
97
50-150
1
32
1,2-Dichlorobenzene
19
1.0
ug/L
20.0
0.73 U
94
65-135
5
57
1,2-Dichloroethane
20
1.0
ug/L
20.0
0.63 U
99
70-130
2
49
1,2-Dichloropropane
21
1.0
ug/L
20.0
0.80 U
103
35-165
0.2
55
1,3-Dichlorobenzene
19
1.0
ug/L
20.0
0.77 U
93
70-130
7
43
1,4-Dichlorobenzene
18
1.0
ug/L
20.0
0.76 U
91
65-135
9
57
Acrylonitrile
66
10
ug/L
60.0
3.2 U
111
60-140
11
60
Benzene
21
1.0
ug/L
20.0
0.71 U
105
65-135
5
61
Bromodichloromethane
20
1.0
ug/L
20.0
0.52 U
102
65-135
0.9
56
Bromoform
17
1.0
ug/L
20.0
0.75 U
86
70-130
5
42
Bromomethane
18
1.0
ug/L
20.0
0.95 U
91
15-185
2
61
Carbon Tetrachloride
20
1.0
ug/L
20.0
0.94 U
101
70-130
3
41
Chlorobenzene
19
1.0
ug/L
20.0
0.72 U
93
65-135
5
53
Chloroethane
22
1.0
ug/L
20.0
0.98 U
111
40-160
4
78
Chloroform
21
1.0
ug/L
20.0
0.80 U
103
70-135
5
54
Chloromethane
22
1.0
ug/L
20.0
0.82 U
110
5-205
2
60
cis- 1,3-Dichloropropene
20
1.0
ug/L
20.0
0.59 U
99
25-175
4
58
Dibromochloromethane
20
1.0
ug/L
20.0
0.44 U
98
70-135
5
50
Ethylbenzene
19
1.0
ug/L
20.0
0.69 U
97
60-140
6
63
Methylene Chloride
20
5.0
ug/L
20.0
2.0 U
101
60-140
0.7
28
Tetrachloroethene
37
1.0
ug/L
20.0
0.76 U
186
70-130
2
39
QM-07
Toluene
19
1.0
ug/L
20.0
0.72 U
95
70-130
9
41
trans-1,2-Dichloroethene
20
1.0
ug/L
20.0
0.73 U
102
70-130
3
45
trans-1,3-Dichloropropene
21
1.0
ug/L
20.0
0.73 U
104
50-150
7
86
Trichloroethene
21
1.0
ug/L
20.0
0.89 U
107
65-135
0.7
48
Vinyl chloride
22
1.0
ug/L
20.0
0.71 U
112
5-195
7
66
4-Bromofluorobenzene
52
ug/L
50.0
103
41-142
Dibromofluoromethane
50
U91L
50.0
100
53-146
Toluene-d8
50
ug/L
50.0
100
41-146
Semivolatile Organic Compounds by GCMS - Quality Control
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 14 Of 27

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QUALITY CONTROL DATA
Semivolatile Organic Compounds by GCMS - Quality Control
Batch 9C20003 - EPA 3510C MS
Blank (9C20003-BLK3) Prepared: 03/20/2019 08:17 Analyzed: 03/22/2019 23:01
Analvte
Result
Flaq
POL
Units
1,2,4-Trichlorobenzene
3.3
U
10
ug/L
1,2-Dichlorobenzene
3.2
U
10
ug/L
1,3-Dichlorobenzene
3.4
U
10
ug/L
1,4-Dichlorobenzene
3.2
U
10
ug/L
2,4,6-Trichlorophenol
6.4
U
10
ug/L
2,4-Dichlorophenol
6.5
U
10
ug/L
2,4-Dimethyl phenol
6.4
U
10
ug/L
2,4-Dinitrophenol
7.7
U
10
ug/L
2,4-Dinitrotoluene
3.2
U
10
ug/L
2,6-Dinitrotoluene
2.9
U
10
ug/L
2-Chloronaphthalene
3.2
U
10
ug/L
2-Chlorophenol
7.4
U
10
ug/L
2-Methyl-4,6-dinitrophenol
6.0
U
10
ug/L
2-Nitrophenol
5.2
U
10
ug/L
3,3'-Dichlorobenzidine
3.3
U
10
ug/L
4-Bromophenyl-phenylether
3.3
U
10
ug/L
4-Chloro-3-methylphenol
7.3
U
10
ug/L
4-Chlorophenyl-phenylether
3.2
U
10
ug/L
4-Nitrophenol
7.9
U
10
ug/L
Acenaphthene
3.0
U
10
ug/L
Acenaphthylene
9.6
U
10
ug/L
Anthracene
3.0
U
10
ug/L
Benzidine
7.1
U
10
ug/L
Benzo(a)anthracene
3.2
U
10
ug/L
Benzo(a)pyrene
3.2
U
10
ug/L
Benzo(b)fluoranthene
3.4
U
10
ug/L
Benzo(g,h,i)perylene
3.7
U
10
ug/L
Benzo(k)fluoranthene
3.8
U
10
ug/L
Bis(2-chloroethoxy)methane
3.3
U
10
ug/L
Bis(2-chloroethyl)ether
3.8
U
10
ug/L
Bi s(2-ch I o ro isopropyl)ether
3.5
U
10
ug/L
Bis(2-ethylhexyl)phthalate
3.5
U
5.0
ug/L
Butyl benzylphtha late
5.1
U
10
ug/L
Chrysene
3.0
U
10
ug/L
Dibenzo(a,h)anthracene
3.8
U
10
ug/L
Diethylphtha late
3.0
U
10
ug/L
Dimethylphthalate
3.0
U
10
ug/L
Di-n-butylphthalate
3.2
U
10
ug/L
Di-n-octylphthalate
4.7
U
10
ug/L
DPH (as Azobenzene)
3.1
U
10
ug/L
Fluoranthene
4.0
U
10
ug/L
Fluorene
2.9
U
10
ug/L
Hexachlorobenzene
3.0
U
10
ug/L
Hexachlorobutadiene
4.1
U
10
ug/L
Hexachlorocyclopentadiene
3.8
U
10
ug/L
Hexachloroethane
3.0
U
10
ug/L
Indeno(1,2,3-cd)pyrene
4.1
U
10
ug/L
Isophorone
4.5
U
10
ug/L
Naphthalene
3.6
U
10
ug/L
Spike Source %REC RPD
Level Result %REC Limits RPD Limit Notes
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 15 Of 27

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QUALITY CONTROL DATA
Semivolatile Organic Compounds by GCMS - Quality Control
Batch 9C20003 - EPA 3510C MS - Continued
Blank (9C20003-BLK3) Continued Prepared: 03/20/2019 08:17 Analyzed: 03/22/2019 23:01
Analvte
Result
Flaq
POL
Units
Nitrobenzene
3.2
U
10
ug/L
N-Nitrosodimethylamine
3.8
U
10
ug/L
N-Nitroso-di-n-propylamine
4.5
U
10
ug/L
N-nitrosodiphenylamine/Diphenylamine
5.4
U
10
ug/L
Pentachlorophenol
8.2
U
10
ug/L
Phenanthrene
2.8
U
10
ug/L
Phenol
5.6
U
10
ug/L
Pyrene
4.1
U
10
ug/L
Spike Source %REC RPD
Level Result %REC Limits RPD Limit Notes
2,4,6-Tribromophenol
93
u9/L
100 93 47-128
2-Fluorobiphenyl
43
u9/L
50.0 85 44-102
2-Fluorophenol
57
u9/L
100 57 25-79
Nitrobenzene-d5
41
u9/L
50.0 82 43-112
Phenol-d5
45
u9/L
100 45 14-54
Terphenyl-dM
49
u9/L
50.0 98 65-122
LCS (9C20003-BS3)
Prepared: 03/20/2019 08:17 Analyzed: 03/22/2019 23:31
Spike
Source
%REC
Analvte
Result Flaq
POL
Units
Level
Result %REC
Limi
1,2,4-Trichlorobenzene
33
10
ug/L
50.0
66
57-130
1,2-Dichlorobenzene
32
10
ug/L
50.0
64
32-129
1,3-Dichlorobenzene
31
10
ug/L
50.0
61
10-172
1,4-Dichlorobenzene
31
10
ug/L
50.0
63
20-124
2,4,6-Trichlorophenol
44
10
ug/L
50.0
87
52-129
2,4-Dichlorophenol
41
10
ug/L
50.0
81
53-122
2,4-Dimethylphenol
39
10
ug/L
50.0
78
42-120
2,4-Dinitrophenol
50
10
ug/L
50.0
100
5-173
2,4-Dinitrotoluene
45
10
ug/L
50.0
90
48-127
2,6-Dinitrotoluene
43
10
ug/L
50.0
86
68-137
2-Chloronaphthalene
40
10
ug/L
50.0
81
65-120
2-Chlorophenol
38
10
ug/L
50.0
75
36-120
2-Methyl-4,6-dinitrophenol
46
10
ug/L
50.0
91
53-130
2-Nitrophenol
40
10
ug/L
50.0
81
45-167
3,3'-Dichlorobenzidine
40
10
ug/L
50.0
79
8-213
4-Bromophenyl-phenylether
42
10
ug/L
50.0
85
65-120
4-Chloro-3-methylphenol
41
10
ug/L
50.0
82
41-128
4-Chlorophenyl-phenylether
44
10
ug/L
50.0
88
38-145
4-Nitrophenol
30
10
ug/L
50.0
59
13-129
Acenaphthene
42
10
ug/L
50.0
84
60-132
Acenaphthylene
42
10
ug/L
50.0
84
54-126
Anthracene
45
10
ug/L
50.0
89
43-120
Benzidine
7.1 U
10
ug/L
50.0
10-136
Benzo(a)anthracene
43
10
ug/L
50.0
87
42-133
Benzo(a)pyrene
45
10
ug/L
50.0
90
32-148
Benzo(b)fluoranthene
44
10
ug/L
50.0
87
42-140
Benzo(g,h,i)perylene
35
10
ug/L
50.0
71
5-195
Benzo(k)fluoranthene
45
10
ug/L
50.0
89
25-146
Bis(2-chloroethoxy)methane
41
10
ug/L
50.0
81
49-165
Bis(2-chloroethyl)ether
41
10
ug/L
50.0
81
43-126
Bis(2-chloroisopropyl)ether
37
10
ug/L
50.0
75
63-139
FINAL
This report relates only to
the sample as received by the
laboratory, and
may only be reproduced in
full.
RPD
RPD Limit Notes
J-06
Page 16 of 27

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QUALITY CONTROL DATA
Semivolatile Organic Compounds by GCMS - Quality Control
Batch 9C20003 - EPA 3510C MS - Continued
LCS (9C20003-BS3) Continued Prepared: 03/20/2019 08:17 Analyzed: 03/22/2019 23:31
Spike
Source
%REC
Analvte
Result Flaq
POL
Units
Level
Result %REC
Limits
Bis(2-ethylhexyl)phthalate
42
5.0
ug/L
50.0
84
29-137
Butyl benzylphtha late
52
10
ug/L
50.0
104
5-140
Chrysene
44
10
ug/L
50.0
88
44-140
Dibenzo(a,h)anthracene
37
10
ug/L
50.0
74
5-200
Diethylphtha late
45
10
ug/L
50.0
90
5-120
Dimethylphtha late
43
10
ug/L
50.0
86
10-120
Di-n-butylphthalate
47
10
ug/L
50.0
95
8-120
Di-n-octylphthalate
46
10
ug/L
50.0
91
19-132
Fluoranthene
47
10
ug/L
50.0
94
43-121
Fluorene
43
10
ug/L
50.0
86
70-120
Hexachlorobenzene
43
10
ug/L
50.0
86
8-142
Hexachlorobutadiene
32
10
ug/L
50.0
64
24-120
Hexachlorocyclopentadiene
31
10
ug/L
50.0
61
38-120
Hexachloroethane
29
10
ug/L
50.0
58
55-120
Indeno(1,2,3-cd)pyrene
37
10
ug/L
50.0
75
5-151
Isophorone
41
10
ug/L
50.0
81
47-180
Naphthalene
37
10
ug/L
50.0
74
36-120
Nitrobenzene
38
10
ug/L
50.0
76
54-158
N-Nitrosodimethylamine
29
10
ug/L
50.0
58
24-94
N-Nitroso-di-n-propylamine
41
10
ug/L
50.0
81
14-198
Pentachlorophenol
47
10
ug/L
50.0
94
38-152
Phenanthrene
44
10
ug/L
50.0
88
65-120
Phenol
25
10
ug/L
50.0
50
17-120
Pyrene
47
10
ug/L
50.0
95
70-120
RPD
RPD Limit Notes
2,4,6-Tribromophenol
86
u9/L
100 86 47-128
2-Fluorobiphenyl
41
u91L
50.0 82 44-102
2-Fluorophenol
56
u9/L
100 56 25-79
Nitrobenzene-d5
37
u9/L
50.0 74 43-112
Phenol-d5
45
u91L
100 45 14-54
Terphenyhd14
45
u9/L
50.0 89 65-122
Matrix Spike (9C20003-MS1)
Prepared: 03/20/2019 08:17 Analyzed: 03/23/2019 00:01
Source: CC04763-01
Analvte
1,2,4-Trichlorobenzene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
2,4, 6-Trich t o rop hen o f
2,4-Dichlorophenol
2,4-Dimethyl phenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methyl-4,6-din itrophenol
2-Nitrophenol
3,3'-Dich lorobenzidi ne
FINAL
Spike
Source
%REC
Result Flaq
POL
Units
Level
Result
%REC
Limits RPD
31
10
ug/L
50.0
3.3 U
62
44-142
33
10
ug/L
50.0
3.2 U
66
32-129
32
10
ug/L
50.0
3.4 U
63
10-172
32
10
ug/L
50.0
3.2 U
65
20-124
35
10
ug/L
50.0
6.4 U
70
37-144
38
10
ug/L
50.0
6.5 U
77
39-135
6.4 U
10
ug/L
50.0
6.4 U
32-120
17
10
ug/L
50.0
7.7 U
33
5-191
44
10
ug/L
50.0
3.2 U
88
53-130
44
10
ug/L
50.0
2.9 U
87
50-158
41
10
ug/L
50.0
3.2 U
83
60-120
41
10
ug/L
50.0
7.4 U
83
23-134
25
10
ug/L
50.0
6.0 U
50
5-181
35
10
ug/L
50.0
5.2 U
71
29-182
3.3 U
10
ug/L
50.0
3.3 U
5-262
This report relates only to
the sample as received by the
laboratory, and
may only be
reproduced in
full.
RPD
Limit Notes
QM-07
QM-07
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QUALITY CONTROL DATA
Semivolatile Organic Compounds by GCMS - Quality Control
Batch 9C20003 - EPA 3510C MS - Continued
Matrix Spike (9C20003-MS3) Continued Prepared: 03/20/2019 08:17 Analyzed: 03/23/2019 00:01
Source: CC04763-01
Spike
Source
%REC RPD
Analvte
Result
Flaa
POL
Units
Level
Result
%REC
Limits RPD Limit
Notes
4-Bromophenyl-phenylether
42
10
ug/L
50.0
3.3 U
84
53-127
4-Chloro-3-methylphenol
15
10
ug/L
50.0
7.3 U
30
22-147
4-Chlorophenyl-phenylether
44
10
ug/L
50.0
3.2 U
88
25-158
4-Nitrophenol
14
10
ug/L
50.0
7.9 U
27
5-132
Acenaphthene
8.2
J
10
ug/L
50.0
3.0 U
16
47-145
QM-07
Acenaphthylene
9.6
U
10
ug/L
50.0
9.6 U
33-145
QM-07
Anthracene
16
10
ug/L
50.0
3.0 U
33
27-133
Benzidine
7.1
U
10
ug/L
50.0
7.1 U
10-136
J-06
Benzo(a)anthracene
35
10
ug/L
50.0
3.2 U
69
33-143
Benzo(a)pyrene
3.2
U
10
ug/L
50.0
3.2 U
17-163
QM-07
Benzo(b)fluoranthene
51
10
ug/L
50.0
3.4 U
103
24-159
Benzo(g,h,i)perylene
29
10
ug/L
50.0
3.7 U
57
5-219
Benzo(k)fluoranthene
49
10
ug/L
50.0
3.8 U
97
11-162
Bis(2-chloroethoxy)methane
41
10
ug/L
50.0
3.3 U
83
33-184
Bis(2-chloroethyl)ether
43
10
ug/L
50.0
3.8 U
85
12-158
Bis(2-chloroisopropyl)ether
38
10
ug/L
50.0
3.5 U
77
36-166
Bis(2-ethylhexyl)phthalate
42
5.0
ug/L
50.0
3.5 U
85
8-158
Butyl benzylphtha late
46
10
ug/L
50.0
5.1 U
92
5-152
Chrysene
42
10
ug/L
50.0
3.0 U
84
17-168
Dibenzo(a,h)anthracene
43
10
ug/L
50.0
3.8 U
86
5-227
Diethylphtha late
45
10
ug/L
50.0
3.0 U
90
5-120
Dimethylphthalate
44
10
ug/L
50.0
3.0 U
88
5-120
Di-n-butylphthalate
46
10
ug/L
50.0
3.2 U
91
1-120
Di-n-octylphthalate
46
10
ug/L
50.0
4.7 U
91
4-146
Fluoranthene
43
10
ug/L
50.0
4.0 U
85
26-137
Fluorene
43
10
ug/L
50.0
2.9 U
85
59-121
Hexachlorobenzene
43
10
ug/L
50.0
3.0 U
87
5-152
Hexachlorobutadiene
33
10
ug/L
50.0
4.1 U
65
24-120
Hexachlorocyclopentadiene
41
10
ug/L
50.0
3.8 U
83
10-99
Hexachloroethane
30
10
ug/L
50.0
3.0 U
61
40-120
Indeno(1,2,3-cd)pyrene
39
10
ug/L
50.0
4.1 U
79
5-171
Isophorone
40
10
ug/L
50.0
4.5 U
80
21-196
Naphthalene
36
10
ug/L
50.0
3.6 U
71
21-133
Nitrobenzene
40
10
ug/L
50.0
3.2 U
80
35-180
N-Nitrosodimethylamine
31
10
ug/L
50.0
3.8 U
62
24-94
N-Nitroso-di-n-propylamine
41
10
ug/L
50.0
4.5 U
81
5-230
Pentachlorophenol
49
10
ug/L
50.0
8.2 U
98
14-176
Phenanthrene
35
10
ug/L
50.0
2.8 U
70
54-120
Phenol
5.6
U
10
ug/L
50.0
5.6 U
5-120
QM-07
Pyrene
29
10
ug/L
50.0
4.1 U
58
52-120
2,4,6-Tribromophenol
60
u91L
100
60
47-128
2-Fluorobiphenyl
42
u9/L
50.0
63
44-102
2-Fluorophenol
25
u9/L
100
25
25-79
Nitrobenzene-d5
37
u91L
50.0
75
43-112
Phenohd5
1.6
u9/L
100
2
14-54 Q5-03
Terphenyl-d14
40
u9/L
50.0
79
65-122
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 18 Of 27

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QUALITY CONTROL DATA
Semivolatile Organic Compounds by GCMS - Quality Control
Batch 9C20003 - EPA 3510C MS - Continued
Matrix Spike Dup (9C20003-MSD3) Prepared: 03/20/2019 08:17 Analyzed: 03/23/2019 00:32
Source: CC04763-01
Spike
Source
%REC
RPD
Analvte
Result
Flaa
POL
Units
Level
Result
%REC
Limits
RPD
Limit
Notes
1,2,4-Trichlorobenzene
31
10
ug/L
50.0
3.3 U
62
44-142
0.2
50
1,2-Dichlorobenzene
33
10
ug/L
50.0
3.2 U
66
32-129
0.1
25
1,3-Dichlorobenzene
32
10
ug/L
50.0
3.4 U
63
10-172
0.3
25
1,4-Dichlorobenzene
33
10
ug/L
50.0
3.2 U
66
20-124
2
25
2,4,6-Trichlorophenol
42
10
ug/L
50.0
6.4 U
85
37-144
20
58
2,4-Dichlorophenol
40
10
ug/L
50.0
6.5 U
81
39-135
5
50
2,4-Dimethyl phenol
6.4
U
10
ug/L
50.0
6.4 U
32-120
58
QM-07
2,4-Dinitrophenol
54
10
ug/L
50.0
7.7 U
108
5-191
106
132
2,4-Dinitrotoluene
46
10
ug/L
50.0
3.2 U
92
53-130
4
42
2,6-Dinitrotoluene
45
10
ug/L
50.0
2.9 U
89
50-158
2
48
2-Chloronaphthalene
42
10
ug/L
50.0
3.2 U
83
60-120
0.4
24
2-Chlorophenol
46
10
ug/L
50.0
7.4 U
92
23-134
11
61
2-Methyl-4,6-dinitrophenol
49
10
ug/L
50.0
6.0 U
99
5-181
65
203
2-Nitrophenol
41
10
ug/L
50.0
5.2 U
81
29-182
14
55
3,3'-Dichlorobenzidine
3.3
U
10
ug/L
50.0
3.3 U
5-262
108
QM-07
4-Bromophenyl-phenylether
43
10
ug/L
50.0
3.3 U
86
53-127
2
43
4-Chloro-3-methylphenol
18
10
ug/L
50.0
7.3 U
37
22-147
20
73
4-Chlorophenyl-phenylether
45
10
ug/L
50.0
3.2 U
90
25-158
2
61
4-Nitrophenol
27
10
ug/L
50.0
7.9 U
54
5-132
67
131
Acenaphthene
16
10
ug/L
50.0
3.0 U
32
47-145
64
48
QM-07,
QM-11
Acenaphthylene
9.6
U
10
ug/L
50.0
9.6 U
33-145
74
QM-07
Anthracene
22
10
ug/L
50.0
3.0 U
45
27-133
31
66
Benzidine
7.1
U
10
ug/L
50.0
7.1 U
10-136
25
QM-07
Benzo(a)anthracene
39
10
ug/L
50.0
3.2 U
78
33-143
12
53
Benzo(a)pyrene
3.2
]
10
ug/L
50.0
3.2 U
6
17-163
72
QM-07
Benzo(b)fluoranthene
51
10
ug/L
50.0
3.4 U
102
24-159
0.6
71
Benzo(g,h,i)perylene
33
10
ug/L
50.0
3.7 U
67
5-219
15
97
Benzo(k)fluoranthene
49
10
ug/L
50.0
3.8 U
97
11-162
0.4
63
Bis(2-chloroethoxy)methane
42
10
ug/L
50.0
3.3 U
84
33-184
2
54
Bis(2-chloroethyl)ether
42
10
ug/L
50.0
3.8 U
85
12-158
0.6
108
Bis(2-chloroisopropyl)ether
40
10
ug/L
50.0
3.5 U
80
36-166
4
76
Bis(2-ethylhexyl)phthalate
45
5.0
ug/L
50.0
3.5 U
89
8-158
5
82
Butyl benzylphtha late
53
10
ug/L
50.0
5.1 U
105
5-152
14
60
Chrysene
43
10
ug/L
50.0
3.0 U
87
17-168
3
87
Dibenzo(a,h)anthracene
42
10
ug/L
50.0
3.8 U
84
5-227
1
126
Diethylphtha late
46
10
ug/L
50.0
3.0 U
92
5-120
2
100
Dimethylphthalate
44
10
ug/L
50.0
3.0 U
89
5-120
1
183
Di-n-butylphthalate
48
10
ug/L
50.0
3.2 U
95
1-120
5
47
Di-n-octylphthalate
47
10
ug/L
50.0
4.7 U
93
4-146
2
69
Fluoranthene
47
10
ug/L
50.0
4.0 U
94
26-137
10
66
Fluorene
44
10
ug/L
50.0
2.9 U
89
59-121
4
38
Hexachlorobenzene
44
10
ug/L
50.0
3.0 U
89
5-152
2
55
Hexachlorobutadiene
32
10
ug/L
50.0
4.1 U
64
24-120
1
62
Hexachlorocyclopentadiene
40
10
ug/L
50.0
3.8 U
79
10-99
5
25
Hexachloroethane
30
10
ug/L
50.0
3.0 U
60
40-120
0.9
52
Indeno(1,2,3-cd)pyrene
41
10
ug/L
50.0
4.1 U
81
5-171
3
99
Isophorone
42
10
ug/L
50.0
4.5 U
84
21-196
5
93
Naphthalene
37
10
ug/L
50.0
3.6 U
74
21-133
3
65
Nitrobenzene
41
10
ug/L
50.0
3.2 U
82
35-180
2
62
FINAL
This report relates only to the sample as received by the
laboratory, and
may only be
reproduced in
full.
Page 19 Of 27

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QUALITY CONTROL DATA
Semivolatile Organic Compounds by GCMS - Quality Control
Batch 9C20003 - EPA 3510C MS - Continued
Matrix Spike Dup (9C20003-MSD3) Continued Prepared: 03/20/2019 08:17 Analyzed: 03/23/2019 00:32
Source: CC04763-01
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits
RPD
Limit Notes
N-Nitrosodimethylamine
33
10
ug/L
50.0
3.8 U
67
24-94
8
25
N-Nitroso-di-n-propylamine
43
10
ug/L
50.0
4.5 U
85
5-230
4
87
Pentachlorophenol
72
10
ug/L
50.0
8.2 U
144
14-176
39
86
Phenanthrene
40
10
ug/L
50.0
2.8 U
81
54-120
14
39
Phenol
5.6 U
10
ug/L
50.0
5.6 U
5-120
64 QM-07
Pyrene
36
10
ug/L
50.0
4.1 U
73
52-120
23
49
2,4,6-Tribromophenol 73
u91L
100
73
47-128
2-Fluorobiphenyl 44
u91L
50.0
88
44-102
2-Fluorophenol 38
u91L
100
38
25-79
Nitrobenzene-d5 40
u91L
50.0
79
43-112
Phenol-d5 7.9
u91L
100
8
14-54 QS-03
Terphenyhd14 45
u91L
50.0
91
65-122
Semivolatile Organic Compounds by GC - Quality Control
Batch 9C21033 - EPA 3510C
Blank (9C21033-BLK3) Prepared: 03/21/2019 13:04 Analyzed: 03/25/2019 16:27
Analvte
Result
Flaq
POL
Units
4,4'-DDD
0.018
U
0.050
ug/L
4,4'-DDE
0.036
U
0.050
ug/L
4,4'-DDT
0.025
U
0.050
ug/L
Aldrin
0.032
U
0.050
ug/L
alpha-BHC
0.026
U
0.050
ug/L
beta-BHC
0.022
U
0.050
ug/L
Chlordane (n.o.s.)
0.49
U
0.50
ug/L
Chlordane (tech)
0.36
U
0.50
ug/L
delta-BHC
0.019
U
0.050
ug/L
Dieldrin
0.017
U
0.050
ug/L
Endosulfan I
0.016
U
0.050
ug/L
Endosulfan II
0.017
U
0.050
ug/L
Endosulfan sulfate
0.016
U
0.050
ug/L
Endrin
0.014
U
0.050
ug/L
Endrin aldehyde
0.020
U
0.050
ug/L
gamma-BHC
0.020
U
0.050
ug/L
Heptachlor
0.018
U
0.050
ug/L
Heptachlor epoxide
0.018
U
0.050
ug/L
Toxaphene
0.48
U
0.50
ug/L
Spike Source %REC RPD
Level Result %REC Limits RPD Limit Notes
2, 4, 5, 6-TCMX 0.96 u91L 1.00 96 38-142
Decachlorobiphenyl 1.0 u91L 1.00 104 34-159
LCS (9C23033-BSI) Prepared: 03/21/2019 13:04 Analyzed: 03/25/2019 16:44
Spike
Source
%REC
Analvte
Result Flaq
POL
Units
Level
Result %REC
Limits
4,4'-DDD
0.99
0.050
ug/L
1.00
99
31-141
4,4'-DDE
0.90
0.050
ug/L
1.00
90
30-145
4,4'-DDT
1.1
0.050
ug/L
1.00
108
25-160
Aldrin
0.80
0.050
ug/L
1.00
80
42-122
FINAL
This report relates only to the sample as received by the
laboratory, and
may only be reproduced in
full.
RPD
RPD Limit Notes
Page 20 of 27

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QUALITY CONTROL DATA
Semivolatile Organic Compounds by GC - Quality Control
Batch 9C21033 - EPA 3510C - Continued
LCS (9C21033-BS3) Continued Prepared: 03/21/2019 13:04 Analyzed: 03/25/2019 16:44
Spike
Source
%REC
RPD
Analvte
Result
Flaq
POL
Units
Level
Result
%REC
Limits
RPD
Limit Notes
alpha-BHC
1.0
0.050
ug/L
1.00
103
37-134
beta-BHC
1.0
0.050
ug/L
1.00
100
17-147
delta-BHC
1.0
0.050
ug/L
1.00
101
19-140
Dieldrin
0.95
0.050
ug/L
1.00
95
36-146
Endosulfan I
0.89
0.050
ug/L
1.00
89
45-153
Endosulfan II
1.0
0.050
ug/L
1.00
103
10-202
Endosulfan sulfate
1.1
0.050
ug/L
1.00
109
26-144
Endrin
1.0
0.050
ug/L
1.00
105
30-147
Endrin aldehyde
0.99
0.050
ug/L
1.00
99
33-141
gamma-BHC
0.97
0.050
ug/L
1.00
97
32-127
Heptachlor
0.99
0.050
ug/L
1.00
99
34-111
Heptachlor epoxide
0.94
0.050
ug/L
1.00
94
37-142
2,4,5,E-TCMX
0.85
u9/L
1.00
85
38-142
Decachlorobiphenyl
0.76
u91L
1.00
76
34-159
Matrix Spike (9C21033-MSS)
Prepared: 03/21/2019 13:04 Analyzed: 03/25/2019 17:01
Source: CC04697-08
Spike
Source
%REC
RPD
Analvte
Result
Flaq
POL
Units
Level
Result
%REC
Limits
RPD
Limit Notes
4,4'-DDD
1.0
0.050
ug/L
1.00
0.018 U
100
31-141
4,4'-DDE
0.97
0.050
ug/L
1.00
0.036 U
97
30-145
4,4'-DDT
1.1
0.050
ug/L
1.00
0.025 U
110
25-160
Aldrin
0.83
0.050
ug/L
1.00
0.032 U
83
42-122
alpha-BHC
1.0
0.050
ug/L
1.00
0.026 U
103
37-134
beta-BHC
1.0
0.050
ug/L
1.00
0.022 U
100
17-147
delta-BHC
1.0
0.050
ug/L
1.00
0.019 U
102
19-140
Dieldrin
0.99
0.050
ug/L
1.00
0.017 U
99
36-146
Endosulfan I
0.94
0.050
ug/L
1.00
0.016 U
94
45-153
Endosulfan II
1.0
0.050
ug/L
1.00
0.017 U
105
10-202
Endosulfan sulfate
1.1
0.050
ug/L
1.00
0.016 U
108
26-144
Endrin
1.1
0.050
ug/L
1.00
0.014 U
108
30-147
Endrin aldehyde
1.0
0.050
ug/L
1.00
0.020 U
101
33-141
gamma-BHC
0.96
0.050
ug/L
1.00
0.020 U
96
32-127
Heptachlor
0.97
0.050
ug/L
1.00
0.018 U
97
34-111
Heptachlor epoxide
0.95
0.050
ug/L
1.00
0.018 U
95
37-142
2,4,5,E-TCMX
0.78
u9/L
1.00
76
38-142
Decachlorobiphenyl
0.83
u91L
1.00
83
34-159
Matrix Spike Dup (9C21033-MSD3)
Prepared: 03/21/2019 13:04 Analyzed: 03/25/2019 17:18
Source: CC04697-08
Spike
Source
%REC
RPD
Analvte
Result
Flaq
POL
Units
Level
Result
%REC
Limits
RPD
Limit Notes
4,4'-DDD
1.1
0.050
ug/L
1.00
0.018 U
111
31-141
10
25
4,4'-DDE
1.0
0.050
ug/L
1.00
0.036 U
105
30-145
8
25
4,4'-DDT
1.2
0.050
ug/L
1.00
0.025 U
122
25-160
10
25
Aldrin
0.90
0.050
ug/L
1.00
0.032 U
90
42-122
8
25
alpha-BHC
1.2
0.050
ug/L
1.00
0.026 U
115
37-134
11
25
beta-BHC
1.1
0.050
ug/L
1.00
0.022 U
111
17-147
10
25
delta-BHC
1.1
0.050
ug/L
1.00
0.019 U
112
19-140
9
25
Dieldrin
1.1
0.050
ug/L
1.00
0.017 U
108
36-146
9
25
FINAL
This report relates only to the sample as received by the
laboratory, and
may only be
reproduced in
full.
Page 21 Of 27

(� �Eo
www.encolabs.com
QUALITY CONTROL DATA
Semivolatile Organic Compounds by GC - Quality Control
Batch 9C21033 - EPA 3510C - Continued
Matrix Spike Dup (9C21033-MSD3) Continued Prepared: 03/21/2019 13:04 Analyzed: 03/25/2019 17:18
Source: CC04697-08
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits
RPD
Limit Notes
Endosulfan I
1.0
0.050
ug/L
1.00
0.016 U
102
45-153
8
25
Endosulfan II
1.2
0.050
ug/L
1.00
0.017 U
115
10-202
9
25
Endosulfan sulfate
1.2
0.050
ug/L
1.00
0.016 U
120
26-144
11
25
Endrin
1.2
0.050
ug/L
1.00
0.014 U
119
30-147
10
25
Endrin aldehyde
1.1
0.050
ug/L
1.00
0.020 U
110
33-141
9
24
gamma-BHC
1.1
0.050
ug/L
1.00
0.020 U
107
32-127
11
25
Heptachlor
1.1
0.050
ug/L
1.00
0.018 U
107
34-111
10
25
Heptachlor epoxide
1.0
0.050
ug/L
1.00
0.018 U
105
37-142
10
25
2,4,5,E-TCMX 0.89 ug/L 1.00 89 38-142
Decachlorobipheny/ 0.97 u9/L 1.00 97 34-159
Batch 9C21034 - EPA 3510C
Blank (9C23034-BLK3) Prepared: 03/21/2019 13:11 Analyzed: 03/25/2019 17:35
Analvte
Result
Flaa
POL
Units
PCB-1016/1242
0.49
U
0.50
ug/L
PCB-1221
0.46
U
0.50
ug/L
PCB-1232
0.47
U
0.50
ug/L
PCB-1248
0.49
U
0.50
ug/L
PCB-1254
0.50
U
0.50
ug/L
PCB-1260
0.47
U
0.50
ug/L
Spike Source %REC RPD
Level Result %REC Limits RPD Limit
2,4,5,6-TCMX 0.64 u91L 1.00 64 38-142
Decachlorobiphenyl 0.58 u91L 1.00 58 34-159
LCS (9C21034-BS1) Prepared: 03/21/2019 13:11 Analyzed: 03/25/2019 17:51
Notes
Spike Source %REC RPD
Analvte
Result Flaq POL
Units
Level Result %REC Limits RPD Limit Notes
PCB-1016/1242
9.2 0.50
ug/L
10.0 92 50-114
PCB-1260
8.8 0.50
ug/L
10.0 88 10-127
2,4,5,6-TCMX
0.88
u91L
1.00 88 38-142
Decachlorobiphenyl
0.66
u91L
1.00 66 34-159
Matrix Spike (9C21034-MS1)
Prepared: 03/21/2019 13:11 Analyzed: 03/25/2019 18:08
Source: CC04697-08
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits
RPD
Limit Notes
PCB-1016/1242
7.7
0.50
ug/L
10.0
0.49 U
77
50-114
PCB-1260
7.2
0.50
ug/L
10.0
0.47 U
72
10-127
2,4,5,E-TCMX
0.63
u91L
1.00
63
38-142
Decachlorobiphenyl
0.59
u9/L
1.00
59
34-159
Matrix Spike Dup (9C23034-MSD3)
Prepared: 03/21/2019 13:11 Analyzed: 03/25/2019 18:25
Source: CC04697-08
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits
RPD
Limit Notes
PCB-1016/1242
9.1
0.50
ug/L
10.0
0.49 U
91
50-114
16
25
PCB-1260
8.9
0.50
ug/L
10.0
0.47 U
89
10-127
21
25
2,4,5,E-TCMX
1.1
u91L
1.00
111
38-142
FINAL
This report relates only to
the sample as received by the
laboratory, and
may only be
reproduced in
full.
Page 22 Of 27

QUALITY CONTROL DATA
Semivolatile Organic Compounds by GC - Quality Control
Batch 9C21034 - EPA 3510C - Continued
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Matrix Spike Dup (9C21034-MSD3) Continued Prepared: 03/21/2019 13:11 Analyzed: 03/25/2019 18:25
Source: CC04697-08
Spike Source %REC RPD
Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes
Decachlorobiphenyl 1.2 u91L 1.00 121 34-159
Metals by EPA 200 Series Methods - Quality Control
Batch 9C20032 - EPA 3005A
Blank (9C20032-BLK3)
Prepared: 03/20/2019 15:09 Analyzed: 03/25/2019 12:44
Spike Source %REC RPD
Analvte
Result
Flaq
POL
Units
Level Result %REC Limits RPD Limit Notes
Copper
1.60
U
10.0
ug/L
Lead
3.10
U
10.0
ug/L
Zinc
4.40
U
10.0
ug/L
LCS (9C20032-BS1)
Prepared: 03/20/2019 15:09 Analyzed: 03/25/2019 12:51
Spike
Source
%REC
RPD
Analvte
Result
Flaq
POL
Units
Level
Result
%REC
Limits RPD
Limit
Notes
Copper
196
10.0
ug/L
200
98
85-115
Lead
191
10.0
ug/L
200
96
85-115
Zinc
197
10.0
ug/L
200
99
85-115
Matrix Spike (9C20032-MS1)
Prepared: 03/20/2019 15:09 Analyzed: 03/25/2019 12:59
Source: CCO1649-01
Spike
Source
%REC
RPD
Analvte
Result
Flaq
Q
Units
Level
Result
%REC
Limits RPD
Limit
Notes
Copper
203
10.0
ug/L
200
21.2
91
70-130
Lead
194
10.0
ug/L
200
3.10 U
97
70-130
Zinc
265
10.0
ug/L
200
14.5
125
70-130
Matrix Spike Dup (9C20032-MSD3)
Prepared: 03/20/2019 15:09 Analyzed: 03/25/2019 13:02
Source: CCO1649-01
Spike
Source
%REC
RPD
Analvte
Result
Flaq
POL
Units
Level
Result
%REC
Limits RPD
Limit
Notes
Copper
202
10.0
ug/L
200
21.2
90
70-130 0.5
30
Lead
197
10.0
ug/L
200
3.10 U
99
70-130 2
30
Zinc
268
10.0
ug/L
200
14.5
127
70-130 1
30
Post Spike (9C20032-PS3)
Prepared: 03/20/2019 15:09 Analyzed: 03/25/2019 13:11
Source: CCO1649-01
Spike
Source
%REC
RPD
Analvte
Result
Flaq
Q
Units
Level
Result
%REC
Limits RPD
Limit
Notes
Copper
0.200
0.0100
mg/L
0.200
0.0212
90
80-120
Lead
0.196
0.0100
mg/L
0.200
0.00138
97
80-120
Zinc
0.266
0.0100
mg/L
0.200
0.0145
126
80-120
QM-08
Classical Chemistry Parameters - Quality Control
Batch 9C20015 - NO PREP
Blank (9C20015-BLK3) Prepared & Analyzed: 03/20/2019 17:39
Spike Source %REC RPD
Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes
Total Suspended Solids 2.5 U 2.5 mg/L
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 23 Of 27

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 9C20015 - NO PREP - Continued
LCS (9C20015-BS3) Prepared & Analyzed: 03/20/2019 17:39
Spike Source %REC
RPD
Analvte
Result Flaq
Q
Units
Level Result %REC Limits
RPD
Limit Notes
Total Suspended Solids
97
2.5
mg/L
100 97 80-120
Duplicate (9C20015-DUP3)
Prepared & Analyzed: 03/20/2019 17:39
Source: CCO0846-01
Spike Source %REC
RPD
Analvte
Result Flaq
POL
Units
Level Result %REC Limits
RPD
Limit Notes
Total Suspended Solids
180
31
mg/L
180
2
20
Duplicate (9C20015-DUP2)
Prepared & Analyzed: 03/20/2019 17:39
Source: CB18507-01
Spike Source %REC
RPD
Analvte
Result Flaq
POL
Units
Level Result %REC Limits
RPD
Limit Notes
Total Suspended Solids
160
25
mg/L
170
8
20
Classical Chemistry Parameters - Quality Control
Batch 9C26004 - EPA 1664E
Blank (9C26004-BLK3) Prepared: 03/26/2019 09:52 Analyzed: 03/26/2019 16:07
Spike Source %REC RPD
Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes
Oil & Grease (HEM-SGT) Non -Polar Material 2.70 U 5.00 mg/L
LCS (9C26004-BS3) Prepared: 03/26/2019 09:52 Analyzed: 03/26/2019 16:07
Spike Source %REC RPD
Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes
Oil & Grease (HEM-SGT) Non -Polar Material 78.8 5.00 mg/L 80.0 98 64-132
LCS Dup (9C26004-BSDI) Prepared: 03/26/2019 09:52 Analyzed: 03/26/2019 16:07
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
Oil & Grease (HEM-SGT) Non -Polar Material
80.3
5.00
mg/L
80.3
100
64-132 2
34
Matrix Spike (9C26004-MS1)
Prepared: 03/26/2019 09:52 Analyzed: 03/26/2019 16:10
Source: BC00989-02
Spike
Source
%REC
RPD
Analvte
Result Flaq
POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
Oil & Grease (HEM-SGT) Non -Polar Material
85.7
5.00
mg/L
79.4
2.70 U
108
64-132
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 24 Of 27

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FLAGS/NOTES AND DEFINITIONS
B The analyte was detected in the associated method blank.
D The sample was analyzed at dilution.
J The reported value is between the laboratory method detection limit (MDL) and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
E The concentration indicated for this analyte is an estimated value above the calibration range of the
instrument. This value is considered an estimate.
MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content.
PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL.
N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater
confidence) to make a "tentative identification".
P Greater than 25% concentration difference was observed between the primary and secondary GC column.
The lower concentration is reported.
[CALC] Calculated analyte - MDL/MRL reported to the highest reporting limit of the component analyses.
7-06 The associated laboratory control sample exhibited low bias; the reported result should be considered to
be a minimum estimate.
QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based
on acceptable LCS recovery.
QM-08 Post -digestion spike did not meet method requirements due to confirmed matrix effects (dilution test).
QM-11 Precision between duplicate matrix spikes of the same sample was outside acceptance limits.
QS-03 Surrogate recovery outside acceptance limits
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 25 of 27

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Page 26 of 27

Sample Preservation Verification
ENCO Cary
Work Order:
CC04438
Project:
Boone Trail
Client:
Atlantic Environmental Associates (AT025)
Project #:
[none]
Logged in:
19-Mar-19 14:31
Logged By:
John C King
Preservation Check Performed By: Date/Time:
CC04438-01
Cont
Type
Pres (pH)
Requirement
pH Checked /
In Control
pH Adjusted Date/Time
Adjusted
Reagent Used/Comments
D
250mLA+H2SO4
<2
Y / N /
Y / N / 6A
E
250mLA+H2SO4
<2
Y/ N/
Y/ N/
F
250mLP+HNO3
<2
Y / N / NA
Y / / NA
CC04438-02
Cont
Type
Pres (pH)
Requirement
pHChecked /
In Control
pH Adjusted DateMme
Adjusted
Reagent Used/Comments
D
250mLA+H2SO4
<2
Y/ N/ N
Y/ N/ &
E
250mLA+H2SO4
<2
Y/ N/ A
Y/ N/
F
250mLP+HNO3
<2
Y / N / NA
I Y le / NA
CC04438-03
Cont
Type
Pres (pH)
pH Checked !
pH Adjusted Date/Time
Reagent Used/Comments
Requirement
In Control
Adjusted
B
250mLA+H2SO4
<2
Y / N / A/
Y / N / �A
C
250mLP+HNO3
<2
/ N / NA
Y N / NA
Rea ent Name ID
1
2
pH Strip ID:
Rea ent Name ID
3
4
Rea ent Name ID
5
6
Page 27 of 27
C:\ELMNT\Print\wko_PreservationCheck.rpt e 1