Loading...
HomeMy WebLinkAboutNC0004944_Fact Sheet_20190401Fact Sheet NPDES Permit NC0004944 Permit Writer (email address): Sergei Chernikov, Ph.D. (sergei.chernikov@ncdenr.gov) Date: October 1, 2018 Division/Branch: NC Division of Water Resources/NPDES Complex Permitting Fact Sheet Template: Version 09Jan2017 Permitting Action: ❑ Renewal ❑ Renewal with Expansion ❑ New Discharge ❑x Modification (Fact Sheet should be tailored to mod request) 1. Basic Facility Information Facility Information Applicant/Facility Salisbury Investments I, LLC / Edge Water Treating, LLC Name: (formerly DuraFiber Technologies, Inc.; Performance Fibers Operations, Inc.; INVISTA, S.a.r.l; KOSA; and Hoechst Celanese) Applicant Address: 5320 Old Pineville Rd., Charlotte, NC 28217 Facility Address: 7401 Statesville Blvd., Salisbury, NC 28147 Permitted Flow: 2.305 MGD Facility Type/Waste: MAJOR Industrial; 10% domestic, 90% industrial Facility Class: Class WW-3 Treatment Units: • Bar screen and grit removal; • Chlorine contact (sanitary wastes) • Two covered equalization tanks; • Three aeration basins (one out -of —service); • Anaerobic groundwater treatment unit (out -of -service); • Three secondary clarifiers (one out -of -service); • Three aerated polishing ponds; • Chemical additional facilities; • Aerobic digestion; • Sludge dewatering; and • Instrumented flow measurement. Pretreatment Program? N/A County: Rowan Region Mooresville Edge Water Treating, LLC is a proposed Centralized Waste Treatment (CWT) facility. As such, 40 CFR 437 Subpart D Federal guidelines are applicable. This is a former OCPSF facility Page 1 of 22 Fact Sheet NPDES Permit NC0004944 that recently discontinued production at this site. The facility will accept numerous waste stream from different clients, the limits in the permit were calculated based on the EPA development documents for CWT facilities that contained the list of pollutants and their concentrations typically present in CWT treatment plants. The facility was originally permitted in 1980 at a flow of 1.2 MGD. In 1992 a flow modification request accompanied the permit renewal application. At that time, Hoechst Celanese requested an increase in total flow from 1.2 MGD to 2.305 MGD to accommodate the discharge of remediated groundwater associated with a RCRA site stabilization plan. During the same period, USGS was requested to evaluate critical low flows and the average flow of the receiving stream. The flows provided by USGS were half what they had been when the permit was developed at 1.2 MGD. DWQ modeled the wastewaters in 1993 and established water quality based limits for BOD and ammonia nitrogen. The facility requested 3 tiers based on the different flow volumes to allow for potential growth. The facility has a separate stormwater permit. 2. Receiving Waterbody Information: Receiving Waterbody Information Outfalls/Receiving Stream(s): 001 / North Second Creek Stream Segment: 12-108-21 Stream Classification: C Drainage Area (mi2): 116 Summer 7Q10 (cfs) 6.9 Winter 7Q10 (cfs): 23 30Q2 (cfs): Average Flow (cfs): 116 IWC (% effluent): 34 303(d) listed? / parameter: No Subject to TMDL? / parameter: No Subbasin/HUC: Yadkin -Pee Dee 03-07-06; 03040102 USGS Topo Quad: Salisbury, N.C. Page 2 of 22 Fact Sheet NPDES Permit NC0004944 3. Effluent Data Summary Effluent data is summarized below for 2011-2016. However, the facility has discontinued production of the OCPSF materials and this summary might not be representative of the future discharges. Table. Effluent Data Summary Parameter Units Average Max Min Permit Limit Flow MGD 1.189 2.188 2.305 BOD pounds/day 9.9 73.0 60.0/149.0 NH3N pounds/day 1.8 77.0 23.0/46.0 TSS pounds/day 31.0 246.0 96.0/294.0 pH SU 8.8 6.4 6.0-9.0 Temperature °C 25.0 7.0 DO mg/l 14.4 5.9 >5.0 TN pounds/day 1.5 2.3 TP pounds/day 0.5 0.9 Fecal Coliform #/100 ml 14.4 240 MA -Monthly Average, WA -Weekly Average, DM -Daily Maximum 4. Instream Data Summary The facility discharges to North Second Creek in the Yadkin -Pee Dee River Basin. It is not listed on the 303(d) list of impaired waters. As a member of the Yadkin Pee Dee River Basin Association (YPDRBA), Edge Water Treating collects instream data at two stations. The upstream station, Q4030000, is located on Second Creek at Highway 81 and Sherrills Ford Road upstream of both Edge Water Treating and the Second Creek WWTP. The downstream station, Q4165000, is located on Second Creek at US 61 near Salisbury and is downstream of both facilities. This permit requires instream monitoring for temperature, conductivity, and dissolved oxygen. The monitoring is provisionally suspended due to the facility's membership in the YPDRBA. Review of instream data for the period 1/2006 — 12/2010 indicates that the dissolved oxygen standard of 5 mg/1 and pH standard of 6.0 — 9.0 were maintained, and there were no apparent differences between upstream and downstream stations. Is this facility a member of a Monitoring Coalition with waived instream monitoring (YIN). YES Name of Monitoring Coalition: Yadkin Pee Dee River Basin Association Page 3 of 22 Fact Sheet NPDES Permit NC0004944 5. Compliance Summary The facility reported 1 NH3-N limit violation in 2012. The facility passed 20 of 20 quarterly chronic toxicity tests. 6. Water Quality -Based Effluent Limitations (WQBELs) Dilution and Mixing Zones In accordance with 15A NCAC 2B.0206, the following streamflows are used for dilution considerations for development of WQBELs: 1Q10 streamflow (acute Aquatic Life); 7Q10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMIX model results): N/A If applicable, describe any mixing zones established in accordance with 15A NCAC 2B.0204(b): N/A Oxygen -Consuming Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD= 30 mg/1 for Municipals) may be appropriate if deemed more stringent based on dilution and model results. If permit limits are more stringent than TBELs, describe how limits were developed: water quality based limits for BOD were determined for the 1993 permit application based on DWQ's draft wasteload allocation dated May 24, 1993. DWQ's modeling analysis predicted a minimum DO of 5 mg/L based on a discharge of 1.574 MGD, 131 pounds/day BOD5, and 17 pounds/day ammonia nitrogen. The modeling used a typical CBOD decay rate and a CBOD/BOD ratio. These values were adjusted using site specific information, and a Monthly Average BOD limit of 150 pounds/day was established for the summer months with ammonia nitrogen limits of 23 pounds/day monthly average and 46 pounds/day daily maximum. BOD limitations determined using the technology based effluent guidelines were used to set winter BOD limitations. However, given the current level of production and the decreased process and sanitary flows BOD limitations for this permit were limited by the technology based effluent guidelines. Ammonia and Total Residual Chlorine Limitations Limitations for ammonia are based on protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/L (summer) and 1.8 mg/L (winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non -Municipals. Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 µg/L) and capped at 28 µg/L (acute impacts). Due to analytical issues, all TRC values reported below 50 µg/L are considered compliant with their permit limit. Limitations for ammonia were based on a model. The limits were not changed in this permit renewal. Page 4 of 22 Fact Sheet NPDES Permit NC0004944 Reasonable Potential Analysis (RPA) for Toxicants The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of 1/ detection limit for "less than" values; and 4) streamflows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. A reasonable potential analysis was conducted on effluent toxicant data from the EPA development documents for CWT facilities. The RPA was conducted for 3 different tiers, please see attached. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. Based on this analysis, the following permitting actions are proposed for this permit: Effluent Limit with Monitoring. The following parameters will receive a water quality - based effluent limit (WQBEL) since they demonstrated a reasonable potential to exceed applicable water quality standards/criteria. In some cases, these limits were substituted with the production based limits (TBELS) if the TBELS were more stringent: Total Arsenic, Total Cadmium, Total Chlorinated Phenolic Compounds (based on 2,4,6 trichlorophenol), Total Phenolic Compounds, Trivalent Chromium, Hexavalent Chromium, Total Copper, Total Lead, Total Nickel, Total Selenium, Total Silver, Total Zinc, Total Antimony, Carbazole, Bis(2-ethylhexyl) phthalate, Butylbenzyl phthalate, and Fluoranthene. Toxicity Testing Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits issued to Major facilities or any facility discharging "complex" wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Describe proposed toxicity test requirement: This is a Major Industrial Facility and a chronic WET limit at 34.0% effluent will continue on a quarterly frequency (2.305 MGD flow). Two additional tiers for 0.5 MGD (10% effluent) and 1.0 MGD (18% effluent) were added to the permit. Page 5 of 22 Fact Sheet NPDES Permit NC0004944 Mercury Statewide TMDL Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA's mercury fish -tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 pounds/year), and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point sources (-2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging quantifiable levels of mercury (>1 ng/1) will receive an MMP requirement. Industrials are evaluated on a case -by -case basis, depending if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/1) and/or if any individual value exceeds a TBEL value of 47 ng/l Based on the potential mercury concentration of 17 µg/L (extracted from the EPA development document), the TBEL of 47 ng/L was added to the permit. Other TMDL/Nutrient Management Strategy Considerations If applicable, describe any other TMDLs/Nutrient Management Strategies and their implementation within this permit: NA. Other WQBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: N/A. If applicable, describe any special actions (HQW or ORW) this receiving stream and classification shall comply with in order to protect the designated waterbody: N/A. If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H. 0107( c)(2)(B), 40CFR 122.47, and EPA May 2007 Memo: N/A If applicable, describe any water quality standards variances proposed in accordance with NCGS 143-215.3(e) and 15A NCAC 2B.0226 for this permit renewal: N/A 7. Technology -Based Effluent Limitations (TBELs) Industrials (if not applicable, delete and skip to next Section) Describe what this facility produces: CWT wastewater treatment. List the federal effluent limitations guideline (ELG) for this facility: 40 CFR 437 Subpart D for New Sources. If the ELG is based on production or flow, document how the average production/flow value was calculated: This ELG is based on flow. Limits were calculated for 3 tiers: 0.2285 MGD, 0.5285 MGD, and 1.2335 MGD. Please see attached. For ELG limits, document the calculations used to develop TBEL limits: Please see attached. If any limits are based on best professional judgement (BPJ), describe development: N/A Document any TBELs that are more stringent than WQBELs: N/A Document any TBELs that are less stringent than previous permit: N/A Page 6 of 22 Fact Sheet NPDES Permit NC0004944 8. Antidegradation Review (New/Expanding Discharge): The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation review in accordance with 15A NCAC 2B.0201. Each applicant for a new/expanding NPDES permit must document an effort to consider non -discharge alternatives per 15A NCAC 2H.0105 (c) (2). In all cases, existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: N/A 9. Antibacksliding Review: Sections 402(o)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(l) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or WQBELs may be less stringent based on updated RPA or dilution). Are any effluent limitations less stringent than previous permit (YES/NO): NO If YES, confirm that antibacksliding provisions are not violated: NA 10. Monitoring Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 2B.0500; 2) NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10/22/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(o) of the Clean Water Act, and therefore anti -backsliding prohibitions would not be triggered by reductions in monitoring frequencies. For instream monitoring, refer to Section A. (1.). 11. Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was finalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. Effective December 21, 2020, NPDES regulated facilities will be required to submit additional NPDES reports electronically. This permit contains the requirements for electronic reporting, consistent with Federal requirements. 12. Summary of Permitting Actions: Current Permit Conditions and Changes from the previous permit. Two additional tiers were added to the permit. The CWT TBELS were compared to the WQBELS and the more stringent limits were used. Page 7 of 22 Fact Sheet NPDES Permit NC0004944 Tier I (0.5 MGD), New Tier Parameter Current Permit Proposed Change Basis for Condition/Change Flow No requirement 0.5 MGD 15A NCAC 2B .0505 BOD5 No requirement MA 101.0 lb/day MA-TBEL, based on 40 CFR DM 300.0 lb/day 437 Subpart D NSPS. DM -based on WQ model. NH3-N No requirement MA 23.0 lb/day WQBEL. Based on the WQ DM 46.0 lb/day model. TSS No requirement MA 21.5 lb/day TBEL, based on 40 CFR 437 DM 56.4 lb/day Subpart D NSPS. Oil and Grease No requirement MA 72.4 lb/day TBEL, based on 40 CFR 437 DM 242.0 lb/day Subpart D NSPS. Fecal coliform No requirement MA 200 /100mL WQBEL. State WQ standard, DM 400 /100mL 15A NCAC 2B .0200 DO No requirement > 5 mg/L WQBEL. State WQ standard, 15A NCAC 2B .0200 pH No requirement 6.0 — 9.0 SU WQBEL. State WQ standard, 15A NCAC 2B .0200 DO, Temp., No requirement Instream monitoring. 15A NCAC 2B .0500 Conductivity, Total Mercury No requirement 47.0 ng/L - annual Based on statewide TMDL average. implementation strategy. Toxicity Test No requirement Chronic limit, 10.0% WQBEL. No toxics in toxic effluent. amounts. 15A NCAC 2B.0200 and 15A NCAC 2B.0500 CWT No requirement Add limits. 40 CFR 437 Subpart D NSPS parameters Chromium III No requirement MA 1,166 µg/L Limits are based on RPA. DM 7,609 µg/L Chromium VI No requirement MA 108.9 µg/L Limits are based on RPA. DM 134.5 µg/L Total Hardness No requirement Monitoring upstream Needed to implement and in the effluent dissolved metal standards. added WQBEL. State WQ standard, 15A NCAC 2B .0200. MGD — Million gallons per day, MA - Monthly Average, WA — Weekly Average, DM — Daily Max Page 8 of 22 Fact Sheet NPDES Permit NC0004944 Tier II (1.0 MGD), New Tier Parameter Current Permit Proposed Change Basis for Condition/Change Flow No requirement 1.0 MGD 15A NCAC 2B .0505 BOD5 No requirement MA 150.0 lb/day WQBEL. Based on WQ DM 300.0 lb/day model. NH3-N No requirement MA 23.0 lb/day WQBEL. Based on the WQ DM 46.0 lb/day model. TSS No requirement MA 49.8 lb/day TBEL, based on 40 CFR 437 DM 130.5 lb/day Subpart D NSPS. Oil and Grease No requirement MA 167.5 lb/day TBEL, based on 40 CFR 437 DM 559.8 lb/day Subpart D NSPS. Fecal coliform No requirement MA 200 /100mL WQBEL. State WQ standard, DM 400 /100mL 15A NCAC 2B .0200 DO No requirement > 5 mg/L WQBEL. State WQ standard, 15A NCAC 2B .0200 pH No requirement 6.0 — 9.0 SU WQBEL. State WQ standard, 15A NCAC 2B .0200 DO, Temp., No requirement Instream monitoring. 15A NCAC 2B .0500 Conductivity, Total Mercury No requirement 47.0 ng/L - annual Based on statewide TMDL average. implementation strategy. Toxicity Test No requirement Chronic limit, 18.0% WQBEL. No toxics in toxic effluent. amounts. 15A NCAC 2B.0200 and 15A NCAC 2B.0500 CWT No requirement Add limits. 40 CFR 437 Subpart D NSPS parameters Chromium III No requirement MA 641.8 µg/L Limits are based on RPA. DM 4,257 µg/L Chromium VI No requirement MA 60.0 µg/L Limits are based on RPA. DM 75.3 µg/L Total Hardness No requirement Monitoring upstream Needed to implement and in the effluent dissolved metal standards. added WQBEL. State WQ standard, 15A NCAC 2B .0200. MGD — Million gallons per day, MA - Monthly Average, WA — Weekly Average, DM — Daily Max Page 9 of 22 Fact Sheet NPDES Permit NC0004944 Tier III (2.305 MGD) Parameter Current Permit Proposed Change Basis for Condition/Change Flow 2.305 MGD No change 15A NCAC 2B .0505 BOD5 MA 60.0 lb/day MA 150.0 lb/day MA -based on WQ model. The DM 149.0 lb/day DM 300.0 lb/day DM-TBEL, based on 40 CFR 437 Subpart D NSPS. NH3-N MA 23.0 lb/day MA 23.0 lb/day WQBEL. Based on the WQ DM 46.0 lb/day DM 46.0 lb/day model. TSS MA 96.0 lb/day MA 49.8 lb/day TBEL, based on 40 CFR 437 DM 294.0 lb/day DM 130.5 lb/day Subpart D NSPS. Oil and Grease No requirement MA 167.5 lb/day TBEL, based on 40 CFR 437 DM 559.8 lb/day Subpart D NSPS. Fecal coliform MA 200 /100mL MA 200 /100mL WQBEL. State WQ standard, DM 400 /100mL DM 400 /100mL 15A NCAC 2B .0200 DO > 5 mg/L > 5 mg/L WQBEL. State WQ standard, 15A NCAC 2B .0200 pH 6.0 - 9.0 SU 6.0 - 9.0 SU WQBEL. State WQ standard, 15A NCAC 2B .0200 DO, Temp., Instream monitoring. Instream monitoring. 15A NCAC 2B .0500 Conductivity, Total Mercury No requirement 47.0 ng/L - annual Based on statewide TMDL average. implementation strategy. Toxicity Test Chronic limit, 34.0% Chronic limit, 34.0% WQBEL. No toxics in toxic effluent. effluent. amounts. 15A NCAC 2B.0200 and 15A NCAC 2B.0500 CWT No requirement Add limits. 40 CFR 437 Subpart D NSPS parameters Chromium III No requirement MA 1,166 µg/L Limits are based on RPA. DM 7,609 µg/L Chromium VI No requirement MA 108.9 µg/L Limits are based on RPA. DM 134.5 µg/L Total Nitrogen No requirement 90.41b/day - annual Limits are added to freeze average nitrogen load and prevent deterioration of the nutrient impaired stream. Page 10 of 22 Fact Sheet NPDES Permit NC0004944 Total Hardness No requirement Monitoring upstream Needed to implement and in the effluent dissolved metal standards. added WQBEL. State WQ standard, 15A NCAC 2B .0200. MGD — Million gallons per day, MA - Monthly Average, WA — Weekly Average, DM — Daily Max All tiers also contain an Electronic Reporting Special Condition based on the EPA Electronic Reporting Rule of 2015. 13. Fact Sheet Addendum (if applicable): Were there any changes made since the Draft Permit was public noticed (Yes/No): No 14. Fact Sheet Attachments (if applicable): • RPA Spreadsheet Summary • CWT calculation 15. Comparison of TBELs and WQBELs Tier I (0.5 MGD) TBEL's are based on a Process flow of 0.2285 MGD Parameter WQBEL TBEL Permit Limit BOD5 MA 150.0 lb/day MA 101.0 lb/day MA 101.0 lb/day DM 300.0 lb/day DM 310.6 lb/day DM 300.0 lb/day NH3-N MA 23.0 lb/day N/A MA 23.0 lb/day DM 46.0 lb/day DM 46.0 lb/day Cr(III) MA 1,166 µg/L N/A MA 21.6 µg/L DM 7,609 µg/L DM 74.7 µg/L Cr(III)/Total Cr ratio: Calculations are based on the Cr(III)/Total Cr ratio MA 0.91 and TBEL Total Cr limit DM 0.98 Cr(VI) MA 108.9 µg/L N/A MA 2.1 µg/L DM 134.5 µg/L DM 1.6 µg/L The limits are calculated by subtracting Cr(III) limits from TBEL Total Cr limit Total Cr N/A MA 23.7 µg/L MA 23.7 µg/L DM 76.3 µg/L DM 76.3 µg/L Page 11 of 22 Fact Sheet NPDES Permit NC0004944 As MA 1,486 µg/L MA 19.9 µg/L MA 19.9 µg/L DM 2,858 µg/L DM 99.3 µg/L DM 99.3 µg/L Cd MA 5.84 µg/L MA 10.2 µg/L MA 5.84 µg/L DM 27.2 µg/L DM 17.2 µg/L DM 17.2 µg/L Total Phenol MA 9,203 µg/L MA 1,080 µg/L MA 1,080 µg/L DM 9,203 µg/L DM 3,650 µg/L DM 3,650 µg/L Chlorinated MA 30.7 µg/L MA 106 µg/L MA 30.7 µg/L Phenol DM N/A DM 155 µg/L DM 155 µg/L Cu MA 78.0 µg/L MA 216 µg/L MA 78.0 µg/L DM 88.0 µg/L DM 659 µg/L DM 88.0 µg/L CN MA 49.5 µg/L MA 178 mg/L MA 49.5 µg/L DM 184.9 µg/L DM 500 mg/L DM 184.9 µg/L Pb MA 29.1 µg/L MA 160 µg/L MA 29.1 µg/L DM 634.6 µg/L DM 350 µg/L DM 350 µg/L Hg Limits are based on Statewide Mercury TMDL - 47.0 ng/L Annual average Sb MA 6,338 µg/L MA 31.2 µg/L MA 31.2 µg/L DM 6,338 µg/L DM 111 µg/L DM 111 µg/L Mo MA 19,806 µg/L MA 965 µg/L MA 965 µg/L DM 19,806 µg/L DM 1,010 µg/L DM 1,010 µg/L Ni MA 368.7 µg/L MA 309 µg/L MA 309 µg/L DM 2,818 µg/L DM 794 µg/L DM 794 µg/L Se MA 49.5 µg/L MA 69.8 µg/L MA 49.5 µg/L DM 470.8 µg/L DM 176 µg/L DM 176 µg/L Ag MA 0.594 µg/L MA 12.2 µg/L MA 0.594 µg/L DM 2.49 µg/L DM 31.8 µg/L DM 2.49 µg/L Zn MA 1,057 µg/L MA 252 µg/L MA 252 µg/L DM 1,057 µg/L DM 657 µg/L DM 657 µg/L Sn MA 7,625 µg/L MA 36.7 µg/L MA 36.7 µg/L DM 7,625 µg/L DM 95.5 µg/L DM 95.5 µg/L Acetone MA 19,806 µg/L MA 7,970 µg/L MA 7,970 µg/L DM 19,806 DM 30,200 µg/L DM 19,806 µg/L Acetophenone MA 80,216 µg/L MA 56.2 µg/L MA 56.2 µg/L DM 80,216 µg/L DM 114 µg/L DM 114 µg/L 2-Butanone MA 257,483 µg/L MA 1,850 µg/L MA 1,850 µg/L Page 12 of 22 Fact Sheet NPDES Permit NC0004944 DM 257,483 µg/L DM 4,810 µg/L DM 4,810 µg/L Carbazole MA 11.9 µg/L MA 276 µg/L MA 11.9 µg/L DM N/A DM 598 µg/L DM 598 µg/L Pyridine MA 12,874 µg/L MA 182 µg/L MA 182 µg/L DM 12,874 µg/L DM 370 µg/L DM 370 µg/L Bis(2- MA 3.66 µg/L MA 101 µg/L MA 3.66 µg/L ethylhexyl)phthal DM N/A DM 215 µg/L DM 215 µg/L ate Butylbenzyl MA 0.99 µg/L MA 88.7 µg/L MA 0.99 µg/L Phthalate DM N/A DM 188 µg/L DM 88.7 µg/L Fluoranthene MA 198 µg/L MA 26.8 µg/L MA 26.8 µg/L DM 198 µg/L DM 53.7 µg/L DM 53.7 µg/L Tier II (1.0 MGD) TBEL's are based on a Process flow of 0.5285 MGD Parameter WQBEL TBEL Permit Limit BOD5 MA 150.0 lb/day MA 233.6 lb/day MA 150.0 lb/day DM 300.0 lb/day DM 718.5 lb/day DM 300.0 lb/day NH3-N MA 23.0 lb/day N/A MA 23.0 lb/day DM 46.0 lb/day DM 46.0 lb/day Cr(III) MA 641.8 µg/L N/A MA 25.1 µg/L DM 4,256.8 µg/L DM 86.4 µg/L Cr(III)/Total Cr ratio: Calculations are based on MA 0.91 the Cr(III)/Total Cr ratio and TBEL Total Cr limit DM 0.98 Cr(VI) MA 60.0 µg/L N/A MA 2.5 µg/L DM 75.3 µg/L DM 1.8 µg/L The limits are calculated by subtracting Cr(III) limits from TBEL Total Cr limit Total Cr N/A MA 27.6 µg/L MA 27.6 µg/L DM 88.2 µg/L DM 88.2 µg/L As MA 758.4 µg/L MA 19.9 µg/L MA 19.9 µg/L DM 1,599 µg/L DM 99.3 µg/L DM 99.3 µg/L Cd MA 3.22 µg/L MA 10.2 µg/L MA 3.22 µg/L DM 15.2 µg/L DM 17.2 µg/L DM 15.2 µg/L Page 13 of 22 Fact Sheet NPDES Permit NC0004944 Total Phenol MA 4,752 µg/L MA 1,080 µg/L MA 1,080 µg/L DM 4,752 µg/L DM 3,650 µg/L DM 3,650 µg/L Chlorinated MA 15.8 µg/L MA 106 µg/L MA 15.8 µg/L Phenol DM N/A DM 155 µg/L DM 155 µg/L Cu MA 42.9 µg/L MA 216 µg/L MA 42.9 µg/L DM 49.2 µg/L DM 659 µg/L DM 49.2 µg/L CN MA 27.3 µg/L MA 178 mg/L MA 27.3 µg/L DM 103.5 µg/L DM 500 mg/L DM 103.5 µg/L Pb MA 16.0 µg/L MA 160 µg/L MA 16.0 µg/L DM 355 µg/L DM 350 µg/L DM 350 µg/L Hg Limits are based on Statewide Mercury TMDL - 47.0 ng/L Annual average Sb MA 3,489 µg/L MA 31.2 µg/L MA 31.2 µg/L DM 3,489 µg/L DM 111 µg/L DM 111 µg/L Mo MA 10,903 µg/L MA 965 µg/L MA 965 µg/L DM 10,903 µg/L DM 1,010 µg/L DM 1,010 µg/L Ni MA 203 µg/L MA 309 µg/L MA 203 µg/L DM 1,577 µg/L DM 794 µg/L DM 794 µg/L Se MA 27.3 µg/L MA 69.8 µg/L MA 27.3 µg/L DM 263.4 µg/L DM 176 µg/L DM 176 µg/L Ag MA 0.327 µg/L MA 12.2 µg/L MA 0.327 µg/L DM 1.394 µg/L DM 31.8 µg/L DM 1.394 µg/L Zn MA 591.2 µg/L MA 252 µg/L MA 252 µg/L DM 591.2 µg/L DM 657 µg/L DM 591.2 µg/L Sn MA 4,197 µg/L MA 36.7 µg/L MA 36.7 µg/L DM 4,197 µg/L DM 95.5 µg/L DM 95.5 µg/L Acetone MA 10,903 µg/L MA 7,970 µg/L MA 7,970 µg/L DM N/A DM 30,200 µg/L DM 30,200 µg/L Acetophenone MA 44,158 µg/L MA 56.2 µg/L MA 56.2 µg/L DM 44,158 µg/L DM 114 µg/L DM 114 µg/L 2-Butanone MA 141,741 µg/L MA 1,850 µg/L MA 1,850 µg/L DM 141,741 µg/L DM 4,810 µg/L DM 4,810 µg/L Carbazole MA 6.54 µg/L MA 276 µg/L MA 6.54 µg/L DM N/A DM 598 µg/L DM 598 µg/L Pyridine MA 7,087 µg/L MA 182 µg/L MA 182 µg/L Page 14 of 22 Fact Sheet NPDES Permit NC0004944 DM 7,087 µg/L DM 370 µg/L DM 370 µg/L Bis(2- MA 2.02 µg/L MA 101 µg/L MA 2.02 µg/L ethylhexyl)phthal DM N/A DM 215 µg/L DM 215 µg/L ate Butylbenzyl MA 0.545 µg/L MA 88.7 µg/L MA 0.545 µg/L Phthalate DM N/A DM 188 µg/L DM 188 µg/L Fluoranthene MA 109 µg/L MA 26.8 µg/L MA 26.8 µg/L DM 109 µg/L DM 53.7 µg/L DM 53.7 µg/L Tier III (2.305 MGD) TBEL's are based on a Process flow of 1.2335 MGD Parameter WQBEL TBEL Permit Limit BOD5 MA 150.0 lb/day MA 545.4 lb/day MA 150.0 lb/day DM 300.0 lb/day DM 1,574 lb/day DM 300.0 lb/day NH3-N MA 23.0 lb/day N/A MA 23.0 lb/day DM 46.0 lb/day DM 46.0 lb/day Cr(III) MA 345.1 µg/L N/A MA 25.4 µg/L DM 2,359 µg/L DM 88.1µg/L Cr(III)/Total Cr ratio: Calculations are based on the Cr(III)/Total Cr ratio MA 0.91 and TBEL Total Cr limit DM 0.98 Cr(VI) MA 32.2 µg/L N/A MA 2.5 µg/L DM 41.7 µg/L DM 1.5 µg/L The limits are calculated by subtracting Cr(III) limits from TBEL Total Cr limit Total Cr N/A MA 27.9 µg/L MA 27.9 µg/L DM 89.6 µg/L DM 89.6 µg/L As MA 334.7 µg/L MA 19.9 µg/L MA 19.9 µg/L DM 886.2 µg/L DM 99.3 µg/L DM 99.3 µg/L Cd MA 1.73 µg/L MA 10.2 µg/L MA 1.73 µg/L DM 8.44 µg/L DM 17.2 µg/L DM 8.44 µg/L Total Phenol MA 2,231 µg/L MA 1,080 µg/L MA 1,080 µg/L DM N/A DM 3,650 µg/L DM 3,650 µg/L Chlorinated MA 7.4 µg/L MA 106 µg/L MA 7.4 µg/L Phenol DM N/A DM 155 µg/L DM 155 µg/L Page 15 of 22 Fact Sheet NPDES Permit NC0004944 Cu MA 23.1 µg/L MA 216 µg/L MA 23.1 µg/L DM 27.3 µg/L DM 659 µg/L DM 27.3 µg/L CN MA 14.7 µg/L MA 178 mg/L MA 14.7 µg/L DM 57.3 µg/L DM 500 mg/L DM 57.3 µg/L Pb MA 8.62 µg/L MA 160 µg/L MA 8.62 µg/L DM 196.8 µg/L DM 350 µg/L DM 196.8 µg/L Hg Limits are based on Statewide Mercury TMDL - 47.0 ng/L Annual average Sb MA 1,876 µg/L MA 31.2 µg/L MA 31.2 µg/L DM 1,876 µg/L DM 111 µg/L DM 111 µg/L MO MA 5,863 µg/L MA 965 µg/L MA 965 µg/L DM 5,863 µg/L DM 1,010 µg/L DM 1,010 µg/L Ni MA 109.1 µg/L MA 309 µg/L MA 109.1 µg/L DM 873.8 µg/L DM 794 µg/L DM 794 µg/L Se MA 14.7 µg/L MA 69.8 µg/L MA 14.7 µg/L DM 146 µg/L DM 176 µg/L DM 146 µg/L Ag MA 0.176 µg/L MA 12.2 µg/L MA 0.176 µg/L DM 0.773 µg/L DM 31.8 µg/L DM 0.773 µg/L Zn MA 327.7 µg/L MA 252 µg/L MA 252 µg/L DM 327.7 µg/L DM 657 µg/L DM 327.7 µg/L Sn MA 2,257 µg/L MA 36.7 µg/L MA 36.7 µg/L DM 2,257 µg/L DM 95.5 µg/L DM 95.5 µg/L Acetone MA 5,863 µg/L MA 7,970 µg/L MA 5,863 µg/L DM N/A DM 30,200 µg/L DM 30,200 µg/L Acetophenone MA 23,743 µg/L MA 56.2 µg/L MA 56.2 µg/L DM 23,743 µg/L DM 114 µg/L DM 114 µg/L 2-Butanone MA 76,213 µg/L MA 1,850 µg/L MA 1,850 µg/L DM 76,213 µg/L DM 4,810 µg/L DM 4,810 µg/L Carbazole MA 3.52 µg/L MA 276 µg/L MA 3.52 µg/L DM N/A DM 598 µg/L DM 598 µg/L Pyridine MA 3,811 µg/L MA 182 µg/L MA 182 µg/L DM 3,811 µg/L DM 370 µg/L DM 370 µg/L Bis(2- MA 1.08 µg/L MA 101 µg/L MA 1.08 µg/L ethylhexyl)phthal DM N/A DM 215 µg/L DM 215 µg/L ate Page 16 of 22 Fact Sheet NPDES Permit NC0004944 Butylbenzyl MA 0.293 µg/L MA 88.7µg/L MA 0.293 µg/L Phthalate DM N/A DM 188 µg/L DM 188 µg/L Fluoranthene MA 58.6 µg/L MA 26.8 µg/L MA 26.8 µg/L DM 58.6 µg/L DM 53.7 µg/L DM 53.7 µg/L 16. Changes in the Final Permit • The limits for barium, molybdenum, aniline, and 2,3-dichloroaniline were removed from the permit because these compounds were removed from the CWT regulations in 2003. • The water quality based limits for Ni (Monthly Average) were corrected for all 3 tiers, now they are based on the appropriate classification of the receiving stream (C-class). • The annual average nitrogen limit was added to the permit to freeze nitrogen load and prevent further deterioration of the nutrient impaired waterbody. The limit is based on the total nitrogen concentration of 4.7 mg/L reported by the previous owner of the facility. The total nitrogen data was extracted from the following DMRs: 08/1992-08/1993 and 01/2009- 12/2009. • The permit limits for trivalent and hexavalent chromium were reduced to make them consistent with the Effluent Guidelines calculations. Page 17 of 22 Fact Sheet NPDES Permit NC0004944 NPDES Implementation of Instream Dissolved Metals Standards - Freshwater Standards The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Therefore, metal limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 1. NC Dissolved Metals Water Quality Standards/Aquatic Life Protection Parameter Acute FW, µg/l (Dissolved) Chronic FW, µg/l (Dissolved) Acute SW, µg/l (Dissolved) Chronic SW, µg/l (Dissolved) Arsenic 340 150 69 36 Beryllium 65 6.5 --- --- Cadmium Calculation Calculation 40 8.8 Chromium I11 Calculation Calculation --- --- Chromium VI 16 11 1100 50 Copper Calculation Calculation 4.8 3.1 Lead Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 8.2 Silver Calculation 0.06 1.9 1 0.1 Zinc Calculation Calculation 90 1 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness dependent standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 2B.0200 (e.g., arsenic at 10 µg/l for human health protection; cyanide at 5 µg/L and fluoride at 1.8 mg/L for aquatic life protection). Table 2. Dissolved Freshwater Standards for Hardness -Dependent Metals The Water Effects Ratio (WER) is equal to one unless determined otherwise under 15A NCAC 02B .0211 Subparagraph (11) (d) Metal NC Dissolved Standard, µg/1 Cadmium, Acute WER*{1.136672-[ln hardness](0.041838)} e^10.9151 [In hardness]- 3.1485} Cadmium, Acute Trout waters WER*{1.136672-[ln hardness](0.041838)} e^{0.9151[ln hardness] - 3.62361 Cadmium, Chronic WER*{1.101672-[In hardness](0.041838)} e^{0.7998[ln hardness]- 4.4451 } Chromium III, Acute WER*0.316 e^{0.8190[ln hardness]+3.7256} Chromium III, Chronic WER*0.860 e^{0.8190[ln hardness]+0.6848} Copper, Acute WER*0.960 e"{0.9422[ln hardness]-1.7001 Page 18 of 22 Fact Sheet NPDES Permit NC0004944 Copper, Chronic WER*0.960 • e^{0.8545[ln hardness]-1.7021 Lead, Acute WER* { 1.46203- [ln hardness] (0.145712)1 e^ { 1.273 [ln hardness] - 1.460 } Lead, Chronic WER* { 1.46203- [ln hardness] (0.145712)) e^ { 1.273 [ln hardness] - 4.705 } Nickel, Acute WER*0.998 e^{0.8460[ln hardness]+2.255} Nickel, Chronic WER*0.997 e^{0.8460[ln hardness]+0.0584} Silver, Acute WER*0.85 • e^{1.72[ln hardness]-6.59} Silver, Chronic Not applicable Zinc, Acute WER*0.978 e^10.8473[In hardness]+0.884} Zinc, Chronic WER*0.986 e^10.8473[In hardness]+0.884} General Information on the Reasonable Potential Analysis (RPA) The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved and hardness -dependent standards requires additional consideration in order to establish the numeric standard for each metal of concern of each individual discharge. The hardness -based standards require some knowledge of the effluent and instream (upstream) hardness and so must be calculated case -by -case for each discharge. Metals limits must be expressed as `total recoverable' metals in accordance with 40 CFR 122.45(c). The discharge -specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on default translator values developed for each metal (more on that below), but it is also possible to consider case -specific translators developed in accordance with established methodology. RPA Permitting Guidance/WQBELs for Hardness -Dependent Metals - Freshwater The RPA is designed to predict the maximum likely effluent concentrations for each metal of concern, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the critical low -flow values for the receiving stream. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. 1. To perform a RPA on the Freshwater hardness -dependent metals the Permit Writer compiles the following information: • Critical low flow of the receiving stream, 7Q10 (the spreadsheet automatically calculates the 1Q10 using the formula 1Q10 = 0.843 (s7Q10, cfs) 0.993 • Effluent hardness and upstream hardness, site -specific data is preferred Page 19 of 22 Fact Sheet NPDES Permit NC0004944 • Permitted flow • Receiving stream classification 2. In order to establish the numeric standard for each hardness -dependent metal of concern and for each individual discharge, the Permit Writer must first determine what effluent and instream (upstream) hardness values to use in the equations. The permit writer reviews DMR's, Effluent Pollutant Scans, and Toxicity Test results for any hardness data and contacts the Permittee to see if any additional data is available for instream hardness values, upstream of the discharge. If no hardness data is available, the permit writer may choose to do an initial evaluation using a default hardness of 25 mg/L (CaCO3 or (Ca + Mg)). Minimum and maximum limits on the hardness value used for water quality calculations are 25 mg/L and 400 mg/L, respectively. If the use of a default hardness value results in a hardness -dependent metal showing reasonable potential, the permit writer contacts the Permittee and requests 5 site -specific effluent and upstream hardness samples over a period of one week. The RPA is rerun using the new data. The overall hardness value used in the water quality calculations is calculated as follows: Combined Hardness (chronic) _ (Permitted Flow, cfs *Avg. Effluent Hardness, mg/L) + (s7O10, cfs *Avg. Upstream Hardness, mg/L) (Permitted Flow, cfs + s7Q10, cfs) The Combined Hardness for acute is the same but the calculation uses the 1 Q1 0 flow. 3. The permit writer converts the numeric standard for each metal of concern to a total recoverable metal, using the EPA Default Partition Coefficients (DPCs) or site -specific translators, if any have been developed using federally approved methodology. EPA default partition coefficients or the "Fraction Dissolved" converts the value for dissolved metal at laboratory conditions to total recoverable metal at in -stream ambient conditions. This factor is calculated using the linear partition coefficients found in The Metals Translator: Guidance for Calculating a Total Recoverable Permit Limit from a Dissolved Criterion (EPA 823-B-96-007, June 1996) and the equation: Cdiss — 1 Ctota1 1 + { [Kpo] [ss(i+a)] [10-6] } Where: ss = in -stream suspended solids concentration [mg/1], minimum of 10 mg/L used, 4. The numeric standard for each metal of concern is divided by the default partition coefficient (or site -specific translator) to obtain a Total Recoverable Metal at ambient conditions. Page 20 of 22 Fact Sheet NPDES Permit NC0004944 In some cases, where an EPA default partition coefficient translator does not exist (ie. silver), the dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. For more information on conversion factors see the June, 1996 EPA Translator Guidance Document. 5. The RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7010 + Ow) (Cwq) — (s7Q10)(Cb) Qw Where: Ca = allowable effluent concentration (µg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (µg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (µg/L or mg/L) Qw = permitted effluent flow (cfs, match s7Q10) s7Q10 = summer low flow used to protect aquatic life from chronic toxicity and human health through the consumption of water, fish, and shellfish from noncarcinogens (cfs) * Discussions are on -going with EPA on how best to address background concentrations Flows other than s7Q10 may be incorporated as applicable: 1Q10 = used in the equation to protect aquatic life from acute toxicity QA = used in the equation to protect human health through the consumption of water, fish, and shellfish from carcinogens 30Q2 = used in the equation to protect aesthetic quality 6. The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality -Based Toxics Control published in 1991. 7. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. 8. The Total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium Water Quality Standards. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium III or VI. In these Page 21 of 22 Fact Sheet NPDES Permit NC0004944 cases, the projected maximum concentration (95th %) for total chromium will be compared against water quality standards for chromium III and chromium VI. 9. Effluent hardness sampling and instream hardness sampling, upstream of the discharge, are inserted into all permits with facilities monitoring for hardness -dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. 10. Hardness and flow values used in the Reasonable Potential Analysis for this permit included: Parameter Value Comments (Data Source) Average Effluent Hardness (mg/L) [Total as, CaCO3 or Ca+M )] 25.0 Default value Average Upstream Hardness (mg/L) [Total as, CaCO3 or Ca+M ] 25.0 Default value 7Q10 summer cfs 0 Lake or Tidal 1Q10 cfs 0 Lake or Tidal Permitted Flow (MGD) 2.1 For dewaterin Page 22 of 22