HomeMy WebLinkAboutNCG120065_Correspondence RE DMRs and Tier II Monitoring_20190315ORANGE COUNTY
NOR 111 CA1 O1ANA
SOLID WASTE MANAGEMENT
1207 Eubanks Road
PO Box 17177
Chapel Hill, North Carolina 27516
March 11, 2019
John Hennessy
NPDES Compliance and Expedited Permit Supervisor
North Carolina Department of Environmental Quality
Division of Water Quality
Atten: DWQ Central File
1617 Mail Service Center
Raleigh, NC 27699-1617
RE: Orange County MSW & C&D Landfills, NCGI20065
Phone (919) 968-2788
Fax (919) 932-2900
MAR R
Vloaf,A
t-rI�iffing Section
Enclosed is the monthly Storm water Discharge Monitoring Report for February 2019. Orange County is
currently in Tier II monitoring for the facility due to high TSS. There were several measurable
storm/rain events during the month of February 2019. A sample was collected from each of the two
outfalls at the start of the rain event on February 20, 2019 approximately 30 minutes after it had begun.
Results indicate that the C&D outfall exceeds the threshold for fecal coliform. The MSW outfall does not
exceed any of the limits outlined in the County's NPDES permit. The results of the analysis are entered
on the enclosed Storm water DMR reporting form as well as copies of both analyses.
The landfill is surrounded by heavily wooded areas and wildlife is frequently spotted on the landfill
property which is the only way to explain fecal coliform presence in the discharge from C&D outfall.
The C&D landfill only accepts construction and demolition debris; therefore, which should not be a
source that would lead to the presence of fecal coliform.
Orange County continues to monitor the installed BMP's that help to control the amount of onsite erosion
and subsequent discharge of contaminated water. This includes monitoring of the growth of our
vegetative cover and minimizing the amount of disturbed land. If you have any questions, please contact
me a bwoodygorna eg_coun nc.gov or 919-358-0479.
Si
Bruce Woody,.
Orange County
Waste Department
Cc: Robert Williams, Director OCSWM
fj
(D Z Q I
� a ID. Z � o
ro
rD
o y, 0 �' ((DD
w c 0
p (D ri-
y
a-
� m
w °T-' V
ro
o- a ro C.
v @ v
cr _
o7Qul
r-
L° o m e
< �s
t0 rD a�
ro°
—x
ro 3
CD
m ro
a
3 a o
c.
o 1+ ,°a+
3 m
ro m o
ou
n CL
y + ro (D
m p P:
Q o
o n3 r
o ,3
A
03
w o
r
m
ti A
0 3
o
J?
m � Z
ro o (Do
(A CL
^� V7 (p to (D
(D
(D (n (D Z
(D p
rD m a) m
z
<
F� (D aj
O
O
Ln o
N (D O
O
N
N
A W N Y
m ° o
n o,
ro r+ 3
7 N ,0 ,<
Ln
v (D 0°
`+ 0'
m o
h rf Q
N 0
3
ILn
0 Ln
N N Q ti
CL n =
m
�'C-W C
rt flJ
�. En
ru
3
w
0 0
0
m
rt cn Ln
(D
m s
m �n
<. m � o
as as zr (o
m 3
n+ G rt
s m
v ro a m
N �
o ro
3 x
° CD
ro a o v
� _(D
m
ro C o
� 9
o o rP
0 (D
-cs ° �
0 (y rh
m v m m
v
ro � n v
m °� 3
n m r-
�ro �rD
3 - h
� O N �
m u�i ro
D 3 . (D
fD z rD
U1
-0 O
c
3
(D
O
r+
ram+
v
Q
0
a
`f
o
v
�J
3 o
�
C rt ayi
m
S
O -Os
5-
d
s
_3
g°
m
r
:3
v
ro
fu
Ol
fl_
N
0
0
0
N
C°
't
m
O
c
�
o
3
�
3
N
0
o
w
c
r-
M
O
O
CIA
Ul
o
CL
m
3
�
�a
o
4!
O
C
Z
9
D
5
Z
D
m
0
® D A
n
D m m
0 mO
Z 22 -
C) o o m
� v�
rn
o
n ❑Z
❑ to
0 m
D
❑EI 3
°
a 0 1�
ai ❑
A
0 4
:E ❑
®
V1
ro
❑
(D ❑
m
PTI
'O
m
❑
(A
D
v
m
w
C
3
m
M
b
14
0
='
n
ai
0
II�
v
M
-t
A
Y)
m
.S
m
v
`v
m
A
0
(D
n
=r
w
rt
m
m
(D' w c
w o
h
N
vT
y G Z3
fD-21
U
W
N
+\o`A (D
O
rwh
foD
:3 Q4 _S
w w
O_
o (D3
au
'•� w to
c ? C
h a
. w
� o � w
aao v h
h h
v
m ? m
-,'fD0
3
da3i � o
m
L
� o c (DC., O a
.a
CA 3
Q
UQ n O
,
sCD ��
Q w fD
o m
o L
o o
°*Qr
a
0 S' 6
rD-
�o CA
--h -0
LL 7C' rt N
O
CD �.
3
a m 0.
Q. cn
m = O
=
w o w
�
h CL O O
ro
CL
o (D m
.t O
3 Ln N
rF
in
3 SD O S
oq w 3 m
awa C
m
5. 0 w 0
o , <
,
N
0
h 00
rt M
o m 'D3
NJ
y � Q
=
n in y
on'
M
3 a-
'o
❑
rr
O
H
h O
z
\
CD
N
In
'-
N
O
i-�
N
w F, D o i
w
<.
v
Fm,
0•
On
0 •
n
-,L
r-;,-4
o Np
� �
o
�. O -< m
'mfl H W
w n
m
G m =
o (D mAa
v (D b
n <D
3 O m cn
z -< <
mto
rn a
>
rl n
DZn
tp
rn
fit
v O
t>
a m -t G
O
S 0 2
b
o
m
v 0
.. p :;z
m pa
C G) m
O m
I
D
h
=
O
m DD
o m
m
a n my
m
s ❑n
2 N
O m
0 ❑
m
s
O �
m
O D
a �
o m
ry z
O
Z
m
m
m
D
Ln
m
0
z
PU
d
Z
0
C
O
Q
m
fl.
C
Ul
O
O
(Ao
Z
O
O3v
A
y
n
0
�
o
C
_
N
�
Q7
W
m
n
N
3
Ol
3
O
v
N
II1
0
3
0
Cq
M
a
H
0
3
`G
O
G
fD
m
ca
3
dq
v
Ul
Ln
O
3
m
O
.O
O
h
?'
Ce==co
www.encolabs.com
SAMPLE SUMMARY/LABORATORY CHRONICLE
Client ID: C&D Outfall
Lab ID: CB17454-01
Sampled: 02/20/19 08:30
Received: 02/20/19 10:22
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Timefs)
Analysis Date/Timefs)
EPA 1664A
EPA 1664A
03/20/19
02/26/19 14:29
02/27/19 15:54
SM 254OD-2011
NO PREP
02/27/19
02/26/19 11:10
02/26/19 11:10
SM 4500H+B-2011
NO PREP
02/20/19 08:44
02/27/19 12:30
02/27/19 12:30
SM 5220D-2011
Same
03/20/19
02/26/19 11:59
02/26/19 17:27
Client ID: MSW Outfall
Lab ID: CB17454-02
Sampled: 02/20/19 08:30
Received: 02/20/19 10:22
Parameter
Preparation
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
SM 254OD-2011
NO PREP
02/27/19
02/26/19 11:10
02/26/19 11:10
SM 5220D-2011
Same
03/20/19
02/26/19 11:59
02/26/19 17:27
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full, Page 2 of 8
Ce==�Go
www.encolabs.com
SAMPLE DETECTION SUMMARY
77-1
Client ID: C&D Outfall
Lab ID:
CB17454-01
Anallyte
BAR MQL
POL
Units
Method Notes
Chemical Oxygen Demand
83
10
10
mg/L
SM 5220D-2011
pH
7.1
1.0
1.0
pH
SM 4500H+B-2011 Q-01
Temperature for pH (deg. C)
20
pH
SM 4500H+B-2011 Q-01
Total Suspended Solids
69
16
16
mg/L
SM 254OD-2011
Client ID: MSW Outfall
Lab ID:
CB17454-02
Analvte
Results
Flan MDL
POL
Units
Method Notes
Chemical Oxygen Demand
38
10
10
mg/L
SM 5220D-2011
Total Suspended Solids
12
2.9
2.9
mg/L
SM 2540D-2011
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 3 of 8
(� �60
www.encolabs.com
ANALYTICAL RESULTS
Description: C&D Outfall Lab Sample ID:CB17454-01 Received: 02/20/19 101
Matrix: Ground Water Sampled: 02/20/19 08:30 Work Order: CB17454
Project: Stormwater Sampled By: LEE CLOER
Classical Chemistry Parameters
^ - ENCO Cary certified awlyte [NC 5911
Analyte rCAS Numberl Results
Flao Units
OF
MDL POL
Batch Method
Analyzed
By Notes
Chemical Oxygen Demand^ 83
mg/L
1
10 10
91326023 SM 5220D-2011
02/26/19 17:27
JOC
PH 7.1
pH
1
1.0 1.0
9B27018 3M 4500H+B-2011
02/27/19 12:30
ASC Q-01
Temperature for pH (deg. C) 20
pH
1
91327018 3M 4500H+B-2011
02/27/19 12:30
ASC Q-01
Total Suspended Solids^ 69
mg/L
6.25
16 16
91326013 SM 254OD-2011
02/26/19 11:10
ASC
Classical Chemistry Parameters
Analyte rCAS Numberl Results Flag MaM DF MDL E Batch Method Analyzed @y Notes
Oil & Grease (HEM-SG7) Non -Polar Material 2.70 U mg/L 1 2.70 5.00 91326009 EPA 1664A 02/27/19 15:54 SMA
Description: MSW Outfall Lab Sample ID: CB17454-02 Received. 02/20/19 10:22
Matrix: Ground Water Sampled: 02/20/19 08:30 Work Order: CB17454
Project: Stormwater Sampled By: LEE CLOER
Classical Chemistry Parameters
^ - ENCO Cary certified anatyte [NC 5911
Analyte rCAS Numberl Results lag Units OF MDL POL Batch Method Analyzsd By Notes
Chemical Oxygen Demand' 38 mg/L 1 10 10 91326023 SM 5220D-2011 02/26/19 17:27 10C
Total Suspended Solids^ 12 mg/L 1.15 2.9 2.9 9B26013 SM 254OD-2011 02/26/19 11:10 ASC
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 8
�co
www.encolabs.com
QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 9826013 - NO PREP
Blank (9B26013-BLK3) Prepared & Analyzed: 02/26/2019 11:10
Spike Source %REC
RPD
Analyte
Result
Flaa
i4
Units
Level Result %REC Limits RPD
Limit
Notes
Total Suspended Solids
2.5
U
2.5
mg/L
LCS (91326013-BSI)
Prepared & Analyzed: 02/26/2019 11:10
Spike Source %REC
RPD
Anal vte
Result
Flao
P OL
Units
Level Result %REC Limits RPD
Limi
Notes
Total Suspended Solids
100
2.5
mg/L
100 105 80-120
Duplicate (9826013-DUPl)
Prepared & Analyzed: 02/26/2019 11:10
Source: CC00062-01
Spike Source %REC
RPD
Analyte
Resul
FLaa
POLL
Units
Level Result %REC Limits RPD
limil
Notes
Total Suspended Solids
1700
330
mg/L
1700 2
20
Duplicate (9B26013-DUP2)
Prepared & Analyzed: 02/26/2019 11:10
Source: CCO2124-01
Spike Source %REC
RPD
Analvte
Result
Flaa
IQ
Units
Level Result %REC Limits RPD
MMU
Notes
Total Suspended Solids
180
50
mg/L
160 9
20
Batch 9B26023 - Same
Blank (9B26023-BLK1)
Prepared: 02/26/2019 11:59 Analyzed: 02/26/2019 17:27
Spike Source %REC
RPD
Analvte
Result
Flao
_POL
ni
Level Result %REC Limits RPD
Limit
Notes
Chemical'Oxygen Demand
10
U
10
mg/L
LCS (9B26023-BS1)
Prepared: 02/26/2019 11:59 Analyzed: 02/26/2019 17:27
Spike Source %REC
RPD
Anal vte
Result
Rao
144
units
Level Result %REC Limits RPD
i i
Notes
Chemical Oxygen Demand
490
10
mg/L
500 97 90-110
Matrix Spike (9B26023-MS1)
Prepared: 02/26/2019 11:59 Analyzed: 02/26/2019 17:27
Source: CB11713-01
Spike Source %REC
RPD
Analyte
Result
Flaq
POL
Units
Level Result %REC Limits RPD
iiJM—ft
Notes
Chemical Oxygen Demand
520
10
mg/L
526 36 93 90-110
Matrix Spike Dup (9B26023-MSDI)
Prepared: 02/26/2019 11:59 Analyzed: 02/26/2019 17:27
Source: CB11713-01
Spike Source %REC
RPD
Analvte
Result
Flao
POL
Units
Level Result %REC Limits RPD
Limit
Notes
Chemical Oxygen Demand
550
10
mg/L
526 36 97 90-110 4
10
Batch 9027018 - NO PREP
LCS (9B27018-BS1)
Prepared & Analyzed: 02/27/2019 12:30
Spike Source %REC
RPD
Analvte
Result
Flao
POL
Units
Level Result %REC Limits RPD
limli
Notes
pH
7.0
1.0
pH
7.01 100 99-101
FINAL
This report relates only to
the sample as received by the laboratory, and may only be reproduced in full.
Page 5 of 8
E �te
www.encolabs.com
QUALITY CONTROL DATA
Classical Chemistry Parameters- Quality Control
Batch 9027018 - NO PREP - Continued
Duplicate (9627018-DUPi) Prepared & Analyzed: 02/27/2019 12:30
Source: CB17454-01
Spike Source %REC RPD
Anal vte Result Flaa POL Units Level Result %REC Limits RPD iknft Notes
pH 6.9 1.0 pH 7.1
3 25
Classical Chemistry Parameters - Quality Control
Batch 9B26009 - EPA 1664B
Blank (9B26009-BLK1) Prepared: 02/26/2019 14:29 Analyzed: 02/27/2019 15:54
Spike Source %REC RPD
Analyte Resul Flan POL Units Level Result %REC Limits RPD Iim' Notes
Oil & Grease (HEM-SGT) Non -Polar Material 2.70 U 5.00 mg/L
LCS (9826009-BSI) Prepared: 02/26/2019 14:29 Analyzed: 02/27/2019 15:54
Spike Source %REC RPD
Anal vte R4su1t F�9 POLni Level Result %REC kinIM RPD Limit Notes
Oil & Grease (HEM-SGT) Non -Polar Material 63.9 5.00 mg/L 75.2 85 64-132
LCS Dup (9B26009-BSDl) Prepared: 02/26/2019 14:29 Analyzed: 02/27/2019 15:54
Spike
Source
%REC
RPD
Analvte Result
Flan POL
Units
Level
Result
%REC
Limits RPD
MMA Notes
Oil & Grease (HEM-SGl) Non -Polar Material 77.0
5.00
mg/L
82.0
94
64-132 19
34
Matrix Spike (9B26009-MS3)
Prepared: 02/26/2019 14:29 Analyzed: 02/27/2019 15:54
Source: BC00811-01
Spike
Source
%REC
RPD
Analvte Result
Fla_4 POL
Units
Level
Result
%REC
Limits RPD
M11111 Notes
Oil & Grease (HEM -SG) Non -Polar Material 51.0
5.00
mg/L
77.8
2.70 U
66
64-132
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 6 of 8
www.encolabs.com
FLAGS/NOTES AND DEFINITIONS
B The analyte was detected in the associated method blank.
D The sample was analyzed at dilution.
I The reported value is between the laboratory method detection limit (MDL) and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
E The concentration indicated for this analyte is an estimated value above the calibration range of the
instrument. This value is considered an estimate.
MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content.
PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL.
N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater
confidence) to make a "tentative identification".
Greater than 25% concentration difference was observed between the primary and secondary GC column.
The lower concentration is reported.
[CALC] Calculated analyte - MDL/MRL reported to the highest reporting limit of the component analyses.
Q-01 Analysis performed outside of method - specified holding time.
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 7 of 8
D
c
D
Co
.,
m
o_
' I
i x :X j
�>
m
I
:x'x!
SIT
03
I i
I I
I
0
-!`•
I
11 I
1 I
I � I
1 1
I � I r J
I I I N
m' m m (7 D C
eff
N j a ON Z
w
a 3
3 CC C3 C,
_ O o
E D ( = x
d �y �J to
o' '?Z o "'
_ Co
\, v
CI`I a
m
m m .
� r
m m
m +
o p O U!� o w A K
X
N .�2. C
o
C
s
u
a� w m
z o �
N o m
K N s
0
m D
rn m
G
COD SM5220D x
rr
oliform, Fecal as E. coli
Q&G 1664A SGT n
z
H SM4500-H B D N n
C
SS SM2540D
N mJy-O
d
.0 v0
N N
W V n 0
N O
v
1 I j I I I j
i I I l l
CO
I i 3
6 o
CD
Z
m
@
m
II ji
I
i I 1 F I I-
j ! ! �°
O
m
D D
v� n�
�C
I c
I I 1 3
I
x
I CD
.a
`�
0- Sa
a
m e
Co
O
i I 3 -�
! i ! ! �
Q
CD
m
- c
0-
v
o
o
Cr
CL
0`
O_
3
Sample Preservation Verification
ENCO Cary
Work Order: '-CB17454
Project: Stormwater
Client: Orange County Solid Waste Mgmt. Department (OR Project #: [none]
Logged In: 20-Feb-19 10:25 Logged By: John C King
Preservation Check Performed By: ' , ` - ) 'r
C B 17454-01
Cont
Type
yp
Pres (pH)
Requirement
pH Checked t
In Control
Date/Tme
j
pH Adjusted Adjusted
Reagent Used/Comments
B
250mLA+H2SO4
<2
Y / N / AA
Y / N /(NA
C
250mLA+H2SO4
<2
Y / N / 6A
Y / N /DNA
E
250mLP+H2SO4
<2
VV N / NA
Y / /N ,/ NA
CB17454-02
Cont
yp
Type
Pres (pH)
Requirement
p Checked !
In Control
DateMme
pH Adjusted Adjusted
Reagent Used/Comments
B
250mLP+H2SO4
<2
Y,// N ! NA
Y ! / NA
Rea ent Name ID
1
2
pH Strip ID: (.,c�tn"� f
Rea ent Name ID Rea ent Name ID
3 5
4 1 --d 6
.,
C:IELMNT\Print\wko_PreservationCheck.rpt Page 1
aceAnalXical
wmpacelabsmm
I
Project: CB17454
Pace Project No.: 92418359
Raleigh Certification IDs
6701 Conference Drive, Raleigh, NC 27607
North Carolina Wastewater Certification #: 67
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
CERTIFICATIONS
North Carolina Bioassay Certification #: 16
North Carolina Drinking Water Certification #: 37731
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 10
aceAnalytical
www.pacelabs.com
r
SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Project: CB17454
Pace Project No.: 92418359
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92418359001 C&D Outfall SM 9222D-2006 WT 1 PASI-R
92418359002 MSW OutFall SM 9222D-2006 WT 1 PAST-R
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 10
aceAnalyticai®
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
(704)875-9092
Project: CB17454
Pace Project No.: 92418359
Sample: C&D Outfall Lab ID: 92418359001 Collected: 02/20/19 08:30 Received: 02/20/19 11:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
MBIO 9222D Fecal Coliform RAL Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006
Fecal Coliforms 4200 CFU/100 mL 1.0 1 02/20/19 14:04 02/21/19 12:10
Sample: MSW Outfall Lab ID: 92418359002 Collected: 02/20/19 08:30 Received: 02/20/19 11:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
MBIO 9222D Fecal Coliform RAL Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006
Fecal Coliforms 292 CFU/100 mL 1.0 1 02/20/19 14:04 02/21/19 12:10
Date: 02/25/2019 12:05 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 10
aceAnalytical
www.pacelabs.com
I
Project: CB17454
Pace Project No.: 92418359
QC Batch: 459491
QC Batch Method: SM 9222D-2006
Associated Lab Samples: 92418359001, 92418359002
METHOD BLANK: 2504013
Associated Lab Samples: 92418359001, 92418359002
Parameter Units
Fecal Coliforms CFU/100 mL
SAMPLE DUPLICATE: 2504015
Parameter
Fecal Coliforms
QUALITY CONTROL DATA
Analysis Method: SM 9222D-2006
Analysis Description: 9222D Fecal Coliform(MF) - RAL
Matrix: Water
Blank Reporting
Result Limit Analyzed
ND 1.0 02/2111912.10
Qualifiers
92418359002 Dup
Units Result Result RPD Qualifiers
CFU/100 mL 292 240 20
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/25/2019 12:05 PM without the written consent of Pace Analytical Services, LLC.
Page 5 of 10
aceAnalytical
www.pacelabs.com
QUALIFIERS
Project: CB17454
Pace Project No.: 92418359
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
PQL- Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-R Pace Analytical Services - Raleigh
Date: 02/25/2019 12:05 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 10
aceAnalytical
www.pacelabs.com
i
Project: CB17454
Pace Project No.: 92418359
Lab ID
92418359001
92418359002
Sample ID
C&D Outfall
MSW Outfall
Date: 02/25/2019 12:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Analytical
QC Batch Method QC Batch Analytical Method Batch
SM 9222D-2006 459491 SM 9222D-2006 459492
SM 9222D-2006 459491 SM 9222D-2006 459492
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC, Page 7 of 10
Document Name:
Document Revised: February 7, 2018
Sample Condition Upon Recefpt SCURj
Page 1 of 2
Document No.:
Issuing Authority:
y`
F-CAA-C3-033-Rev:06
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑
Client Name:
Lac o - C41W
Couriers
Custody. Seal Present? ❑Yes ',2110 Seals intact?
Huntersville ❑ Raleighle Mechanicsville[]
Project#: WV# . 92418359
Client
�J2118359
[]Yes ❑No — -- — -
Date/Initials Person ExaminingConten's
,Z -;;i- p 15
Packing Material. ❑Bubble Wrap ❑Bubble Bags one ❑ Other Biological Tissue Frozen?
Thermomet I ��O ❑Yes []No WIA
1R Gun ID: Type of ice: et ❑eiue []None
Cooler Temp VQ! t Correction Factor Add/Subtract (°C) D.
Temp should be above freezing to 6"C
Cooler Temp Corrected ('Cl.,_ v ^ _ []samples out of temp criteria. Samples on Ice, woling process
has begun
USDA Regulated Soll (❑ N/A, water sample)
Did samples orrfgin� in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples odginate from a foreign source (Internnally,
rly'-s 9mr, indudina Hawaii and Puerto Ricni7 FIYes 05-.
Comments/Discrepancy.,
Chain of Custody Present?
, Bras
ONO
❑N/A
L
Samples Arrived within Hold Time?
42riks
No
❑N/A
2.
Short Hold Time Analysis (42 hr.)?
ON.
N/A
3.
Rush Turn Around Time Requested?
ElYes
4a or
N/A
4.
Sufficient Volume?
fn
QN0
ON/A
S.
Correct'Containers Used?
-Pace Containers Used?
L,QYas
[)No
Na
i]N/A
N/A
6.
Containers Intact?
Yes
(]No
N/A
7.
Dissolved analysis: Samples Field Filtered?
Yes
No
A
8.
Sample Labels Match COC?
-Includes Date/Tlme/1D/Analysis Matrix
gj�<
[]No
(]N/A
9.
Headspace In VOA Vials (>5-6mm)�
[]Yes
❑No
A
10
Trip Blank Present?
Trip Blank Custody Seats Present?
[]Yes
Yes
[jNo
No
yjju/o,
/A
11.
COMMENTS/SAMPLE DISCREPANCY
Field Data Required? []Yes ❑No
_.,,, ,,,,^.. __,.,,,.-. •--.-. �,.. .....___.__ , .,_____ .., —_- - �'�"- "Lot lDofsplit containers:
T
CLIENT NCI7TFICATION/RESOLUTION
Person contacted:
Date/Time:
Project Manager SCURF Review; C Date:
T
Project Manager SRF Review: Date:
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptlons. VOA, Coliform, TOC, Oil and Grease, ORO/SQiS (water) DOC, LLHg
"Bottom half of box is to list number of bottle
Project # WO : ,r 2418359
ISM: SMO Due Date: 03/01/19
CLIENT 92—ENCO
u
Z
a°i v v
a u a
c c
a D
gg
m m �d
a a a
J J J
E E. E
U) ua1 O
rl N N
E 7 M N
a a a a
m In co
G
2
N
�'
7
t-i
m
C
m
.,�.
t
ei
a
m
V
2
y v a21
a o
m a
O d
^�n?7
u
Li m
3 a
J J J
E E E
of uo� ��71
N '.j
a a A.
so go no
rV
a
u
fQ
J
E
'.j
Q
a
2
N
A.
o
E
v
'S
d
o
y
H
`c
A
E
Q
w
�
r'1
ri
0
Q
v
r
°
rs
as
E
Q
w
�L''
r1
wr
U
Q
z
m
c
D
aE
d
J
E
cfa�
f..L4L
RI
t7
4
N
a
vv
o
2
aq
E
d
v
i'
4
v
v
in
�..
a
4
J
E
a
ry
t[t
t9
Q
u
"
J
E
o
t`%
rt$
U'
O
rA
t9
4
¢
U
Q
J
E
a
Of
l4
z
m
uutt3N
ro
Z
}
q
Ot
r,
?
¢
C++N
a
d
O
>
$
Of
o
>
d
?
d
0
>
p
A
W
fl
2
N
a
y
a
,y
"'
v
>
M
0
4
�
N
A
,�
y
J
>
I
?
Ic
m
+
E
.ryt
ul
w
6
az
L
to
J
E
0
N
N
rn
G
vi
s
`a
J
E
Ln
N
rq
m
z
w
°'
c
E
¢
J
E
a
r1l
O
Q
Z
c
�c7EE
ul
J
E
o
N
(p
>
a
v
aD
4
J
E
a
4t
C
1
I
I
N
2
I
NW\�
N
'N\\
\\�
3N'.
4
5
6
N
N
N\\
N\
r\�
N\�\N
N
NN\
I
I
8
N I I
�
1
N I
NN\N
N
N
10
NN11
u
pH Adjustment log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Tlme preservation
adjusted
Amount of Preservative
added
Lot#
11111�1- Whenever there is a discrepancv affecting Nortn Carolina cornpnance sampres. a copy or tors runn wm ue ben[ cu me nur ur t,arunoe ucntvn I---lun —J— l'...
Out of hold, incorrect preservative; out of temp, Incorrect containers.
SUBCONTRACT ORDER
ENCO Cary
CB17454
SENDING LABORATORY: RECEIVING LABORATORY:
ENCO Cary Tri-Test (Raleigh)
102-A Woodwinds Industrial Court 6701 Conference Drive
Cary, NC 27511 Raleigh, NC 27607
Phone: 919.467.3090 Phone :(919) 834-4984
Fax: 919.467.3515 Fax:
Project Manager: Chuck Smith Project State of Origin, North Carolina
Sub Lab ID Originating Lab ID Client Matrix Date Sampled Sample Comments
f ) ! C&D Outfall Ground Water 20-Feb-19 08:30
mama
Coliform, Fecal as E. coh 01-Mar-19 15;00 20-Feb-19 14:30
Containers Supplied:
Sterile250mLP+NaThlo (F)
Sub Lab ID Originating Lab ID Client Matrix Date Sampled Sample Comments
MSW Outfall Ground Water 20-Feb-19 08:30
IN A1619-MI,
Coliform, Fecal as E. coli 01-Mar-19 15-00 20-Feb-19 14:30
Containers Supplied:
Sterile250mLP+NaThio (C)
L, 2-zoli
Page 1 of I