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NC0024406_Application_20190322
Belews Creek Steam Station: Effluent Guidelines Rule Justification for Applicability Dates A. Introduction Duke Energy (Duke) is working diligently to develop and refine an optimized schedule for the installation and upgrades to wastewater treatment systems to comply with the Steam Electric Power Generating Effluent Limitation Guidelines (ELG) at seven coal-fired stations in North Carolina. Duke submits the following information as a justification for appropriate applicability dates for compliance with the new Effluent Guidelines Rule (ELG Rule) (80 Fed. Reg. 67,838 (Nov. 3, 2015)) at Belews Creek Steam Station (BCSS), located in Belews Creek, North Carolina. BCSS consists of two coal fired generating units with nameplate generating capacities of 1,110 MW each for a total of capacity of 2,220 MW. The station currently discharges treated bottom ash transport water, and FGD wastewater. Under normal plant operations, fly ash is collected dry and either disposed in a permitted on -site landfill or transported offsite for beneficial reuse. If the dry fly ash collection system is not operating, the fly ash is sluiced to the ash basin in which the transport water is treated in the ash basin and subsequently discharged through outfall 003. Bottom ash from the boilers is sluiced with transport water to the ash pond. The transport water is treated by the ash pond system and is discharged through outfall 003. The FGD blowdown flows to a physical / chemical treatment system followed by a biological treatment system and discharges through internal outfall 002 to the ash basin. The ELG Rule sets a range of possible applicability dates for compliance with the new BAT limits for bottom ash transport water (zero discharge) and FGD wastewater (numeric limits for selenium, arsenic, mercury, and nitrate/nitrite), as well for fly ash transport water (zero discharge). The regulation provides that all permits issued after the effective date of the rule (January 4, 2016) should contain applicability dates for compliance with the BAT limits, and that those dates should be "as soon as possible" but not sooner than November 1, 2018 and not later than December 31, 2023. For BOSS, since the plant's final NPDES permit will be issued after January 4, 2016, but before November 1, 2018, EPA specifically instructs permit writers to "apply limitations based on the previously promulgated BPT limitations or the plant's other applicable permit limitations until at least November 1, 2018." 80 Fed. Reg. at 67,883, col. 1 (emphasis added). As the rule makes clear, however, BAT limits may apply — depending on the individual circumstances of the facilities subject to the rule — any time within the window of November 1, 2018 to December 31, 2023. In selecting an appropriate applicability date for each waste stream subject to the new BAT limits, the permitting authority is called upon to determine an "as soon as possible" date. The ELG Rule provides a very specific definition for "as soon as possible." The permit writer — when supplied with appropriate information by the permittee — must consider a range of factors that affect the timing of compliance. Those factors are as follows: (1) Time to expeditiously plan (including to raise capital), design, procure, and install equipment to comply with the requirements of this part. (2) Changes being made or planned at the plant in response to: (i) New source performance standards for greenhouse gases from new fossil fuel - fired electric generating units, under sections 111, 301, 302, and 307(d)(1)(C) of the Clean Air Act, as amended, 42 U.S.C. 7411, 7601, 7602, 7607(d)(1)(C); (ii) Emission guidelines for greenhouse gases from existing fossil fuel -fired electric generating units, under sections 111, 301, 302, and 307(d) of the Clean Air Act, as amended, 42 U.S.C. 7411, 7601, 7602, 7607(d); or (iii) Regulations that address the disposal of coal combustion residuals as solid waste, under sections 1006(b), 1008(a), 2002(a), 3001, 4004, and 4005(a) of the Solid Waste Disposal Act of 1970, as amended by the Resource Conservation and Recovery Act of 1976, as amended by the Hazardous and Solid Waste Amendments of 1984, 42 U.S.C. 6906(b), 6907(a), 6912(a), 6944, and 6945(a). (3) For FGD wastewater requirements only, an initial commissioning period for the treatment system to optimize the installed equipment. (4) Other factors as appropriate. 40 C.F.R. § 423.11(t). The wastewater treatment systems at BCSS will undergo significant modifications and in most cases complete replacement to comply with the revisions to the ELG Rule. Duke would like sufficient time to select, design and install the most cost effective technology at BCSS to comply with the ELG limits and reduce the burden to the ratepayers. We have prepared a preliminary timeline for planning, designing, procuring, constructing and optimizing the technology once it is selected, for each applicable waste stream. Based on our preliminary analysis, we request the following applicability dates: Bottom Ash Transport Water: To convert the wet bottom ash transport system at BCSS to a closed loop system, Duke plans to install a remote mechanical drag chain system (RMDS). Duke would like to request May 31, 2021 as the applicability date for the no discharge of bottom ash transport water, assuming a permit effective date of December 1, 2016. Duke anticipates that equipment will be installed by December 31, 2019 to comply with the North Carolina -Coal Ash Management Act (NC -LAMA) and the Coal Combustion Residual (CCR) rule. These rules, however, only regulate the material, not the water. As discussed below, Duke will need a 17 month window to optimize the system to operate as a zero discharge system. This additional time is needed to account managing the installation and optimization of four RMDS being installed in N. Carolina simultaneously. In addition, the extent and complexity of the permits required are unknown at this time. Duke, therefore, allocated 6 months to account for potential permitting delays. FGD wastewater: The FGD wastewater treatment system at BCSS contains the model technology EPA used as the basis for the best available technology (BAT) limits for FGD wastewater, physical / chemical treatment followed by biological treatment. However, the BAT limits were based on data from BCSS and Allen Steam Station while the stations were primarily using coal from the Central Appalachian region. Based on Duke's experience with the treatment of FGD wastewater, the variability in the coal can affect the performance of the biological treatment system. In a memorandum from EPA, Variability in Flue Gas Desulfurization Wastewater: Monitoring and Response dated Sept. 30, 2015, EPA 2 acknowledges data from Allen and BCSS show selenium concentration can sometimes become elevated. In addition, EPA stated "The coal characteristics could alter the characteristics of the FGD purge stream...". EPA further stated plants should acquire information on the variability of the system "over a long enough time that will included variability in plant operations such as shutdowns, fuel switches (preferably for all fuel types burned at the plant), variability in electricity generating loads, periods with high ORP, etc." Given the fact BCSS may use a variety of fuels and recent data indicates the current system would be challenged to meet the ELG limits for FGD wastewater, Duke would like to request November 30, 2020 as the applicability date for the BAT limits for FGD wastewater. This time is necessary to investigate the variability in the system, evaluate technologies needed to provide additional treatment to consistently meeting the ELG limits and design, install and commission the additional treatment components. Fly Ash Transport Water: Fly ash is handled dry during normal operation; therefore, Duke is not requesting an applicability date for the zero discharge of fly ash transport water beyond November 1, 2018. The following provides necessary information justifying the requested applicability dates provided above. B. Bottom Ash Transport Water As stated above, significant portions of the bottom ash transport system at BCSS will need to be replaced to comply with the no discharge limit of bottom ash transport water (BATW). The rule identified dry handling or closed -loop systems as the BAT technology basis for control of pollutants in bottom ash transport water. Specifically, a mechanical drag system (MDS) was identified as the technology basis for a dry handling system, where as a RMDS was identified as the technology basis for a closed -loop system. Duke is planning on installing a RMDS at BCSS to handle bottom ash dry. The system will be designed to operate in a closed -loop mode to meet the zero discharge limits for BATW. Duke anticipates 54 months from the effective date of the permit will be needed to design, install and commission the RMDS as a zero discharge system based on the following preliminary timeline. It is important to note Duke will be installing RMDS at four stations in N. Carolina; therefore, additional time is needed compared to a single installation to account for managing multiple projects simultaneously. Remote Mechanical Drag System (RMDS) Activity Duration Months Design' 6 • Siting 3 • Engineering 5 Procurement 12 Potential Permitting Delays 6 Construction/Tie-in 13 Optimization & Operational Experience 2 17 • Commissioning 2 • Start -Up 6 Total: 54 3 1) The design tasks has been initiated and Duke estimates an additional 6 months from the permit effective (assuming Dec. 1, 2016) will be needed to complete the design. 2) Even though is it estimated that commissioning and start-up can occur in 8 months, Duke anticipates needing a 17 month window to obtain the necessary operating time at full load and account for commissioning / optimizing occurring at multiple facilities simultaneously. Assuming a permit effective date of December 1, 2016, Duke estimates the system can be installed and operated to comply with the zero discharge limit of BATW on or before May 31, 2021. To design, procure, construct and optimize the RMDS at BCSS to operate as a closed -loop system, the following steps must be taken: Desi ng & Engineering Duke has initiated the design phase, but, due to the simultaneous implementation of programs, such as the CCR Rule and NC-CAMA across applicable sites in North Carolina, engineering and technology resources are limited. Duke, therefore, estimates the design and engineering process will take an additional 6 months from the permit effective date. Some of the activities within the water balance and siting task will occur concurrently; however the design cannot be completed until the siting task is completed. The permitting process, if necessary, will be initiated in the design and engineering phase, but it is assumed permit receipt / approval will be conducted concurrently with the design and procurement phase and will be completed prior to the construction phase. The following tasks will need to be completed. Water Balance The first step in the design process of the RMDS is to develop a detailed water balance of the current BATW. To operate the system as a zero discharge system, there is a balance between the inputs of water into the system and the outputs of water through evaporation and bottom ash removal. This is necessary to determine if any additional treatment of the BATW is needed to avoid increase in fines and concentration of other constituents that could affect equipment operability. In addition, several non-BATW waste streams are currently commingled and treated along with BATW. The flow of these waste streams will be rerouted from the BATW system to a new wastewater treatment system. This will require the streams to be characterized for both volumetric flow and constituent make-up in order to size and design an appropriate treatment system. It is important to note that not all waste streams discharge continuously or simultaneously. Some waste streams discharge intermittently based on activity occurrence, such air preheater and precipitator washes, while others may only discharge under certain rainfall events. In addition, many waste streams do not discharge if the unit is not running. With most coal-fired units operating in an infrequent mode, the opportunities to collect samples are limited and the operation schedule could affect the schedule of this task. Upon completion of the water balance, detailed engineering of the RMDS system and piping reroutes of non-BATW can commence. 2 Siting The RMDS will need to be sited appropriately to avoid any historical or current coal combustion product disposal (CCP) sites and avoid construction areas that will be used to complete closure of the ash basins at BOSS. In addition, Duke will attempt to site the system to avoid waters of the U.S. (WOTUS). However, based on the final siting of the system, WOTUS may not be avoided, and permits from the U.S. Army Corps of Engineers may be required. Permitting If WOTUS cannot be avoided, then permitting from the U.S. Army Corps of Engineers (USACE) will be needed. At this time, it is unknown whether a USACE permit will be required or the type of permit that may be required (nationwide permit (NPW) or individual permit). Duke, therefore, has included 12 months in the schedule to prepare and obtain any necessary USACE permits. Once the RMDS is commissioned, the permitted discharge flows will change drastically. The amount of water discharged could be reduced by as much as 85%. In addition, these flows typically were treated along with the BATW in the ash basin. Duke, therefore, will need to design, and construct a new treatment system for these low volume wastes. The size and technology of the treatment system will be determined based on the water characterization study discussed above. Additionally, based on the final siting of the low volume wastewater treatment system, a new outfall may be needed for the discharge of the effluent from this new wastewater treatment system. With significant changes to the characteristics of the permitted discharge, Duke anticipates a NPDES permit modification will be required to revise the permit to account for the changes in flow and constituent make-up. Even though the permitting task will be initiated during the design and engineering phase, it is expected to continue through the procurement phase and up to the construction phase. In addition, the extent and complexity of the permits required are unknown at this time. The required permits will be evaluated during the engineering and design phase. Since the time needed to prepare the permit applications and the time needed to receive the permits is uncertain, Duke allocated 6 months to account for potential permitting delays. Procurement After the design is complete, Duke will initiate the process to procure the necessary outside resources to construct and install the new wastewater treatment systems. This process will involve the following steps: Evaluate potential vendors for proposal solicitation; Develop and submit request for proposal (RFP) to selected vendors; Conduct a review and vendor selection based on the received bids; Develop required contract documents; Acquire materials (potentially from overseas), which involves: o Shipment, and o Equipment Fabrication — Fabrication and inspection of equipment. 5 RMDS have a fabrication queue that is dependent on total industry -wide demand. Duke, therefore, has allocated 12 months to acquire the necessary materials. Construction Once all the necessary materials are procured, Duke estimates construction of the RMDS will take approximately 13 months. In addition, the tie-in of the RMDS to each individual generating unit will need to occur during outages, which are anticipated to occur between March to May and October to November depending on generation demand. Optimization and Operational Experience As stated above, Duke is planning to have the equipment installed by December 31, 2019 at the latest to meet the obligations under LAMA, in addition, to any CCR requirements. Again, these rules regulate the bottom ash material, not the transport water. Given the system will continue to utilize water to transport bottom ash, time will be needed to gain operational experience and optimize the system to meet the zero discharge limit. Duke estimates a 17 month window will be required to gain the necessary operational experience and fine-tune the system. The 17 month window is estimated based on the potential that the station may only be operating at full load during the winter and summer months and account for commissioning / optimizing occurring at multiple facilities simultaneously. In addition, with NCDEQ approving the implementation date of January 31, 2021 for Marshall Steam Station, Duke would like to stagger the commissioning / optimization activities for BCSS by 4 months. C. New Wastewater Treatment System As discussed above, with the removal of several non-BATW waste streams from the bottom ash transport system, a new wastewater treatment system will need to be designed and constructed for co - treatment of low volume waste and other regulated process streams per the CCR rule, ELGs, and NDPES permitting requirements. The activities associated with the new wastewater treatment system will be conducted concurrently with the other design activities at the site. These waste streams are not subject to the applicability date in the ELG rule, therefore, Duke is not requesting a compliance date, but this task will need to be completed prior to the effective date of the zero discharge of BATW. Duke anticipates 30 months will be needed to design, install and commission the new wastewater treatment system, based on the following preliminary timeline. New Wastewater Treatment System Activity Duration(Months) Siting 3 Engineering 6 Procurement 3 Construction/Tie-in 9 Commissioning 3 Start -Up 6 Total: 30 6 D. FGD Wastewater The FGD wastewater treatment system at BCSS contains the model technology EPA used as the basis for the BAT limits for FGD wastewater, physical / chemical treatment followed by biological treatment. However, the BAT limits were based on data from BCSS and Allen Steam Station while the station was primarily using coal from the Central Appalachian region. Based on Duke's experience with the treatment of FGD wastewater, variability in the coal can affect the performance of the biological treatment system. This was evident based on data collected from the FGD wastewater treatment systems at Allen and BCSS in 2014 and 2015 when the stations were using coal from regions other than Central Appalachian. In a memorandum from EPA, Variability in Flue Gas Desulfurization Wastewater: Monitoring and Response dated Sept. 30, 2015, EPA acknowledges data from Allen and BCSS show the selenium concentration can sometimes become elevated. In addition, EPA stated "The coal characteristics could alter the characteristics of the FGD purge stream...". EPA further stated plants have between three to eight years to conduct the necessary studies to properly design the treatment system and plants should investigate the variability of the FGD purge stream to inform the design process. EPA went on to state plants should acquire information on the variability of the system over a "long enough time that will included variability in plant operations such as shutdowns, fuel switches (preferably for all fuel types burned at the plant), variability in electricity generating loads, periods with high ORP, etc." EPA further recognizes that designing, procuring, installing, and optimizing an FGD wastewater treatment system is a complicated and time-consuming undertaking, involving much study and careful planning. For example, EPA states: "For plants that are planning to include fuel flexing in their operations, in the years prior to the installation and operation of the FGD wastewater treatment system, the plant should consider sampling the untreated FGD wastewater to evaluate the wastewater characteristics that are present based on the differing fuel blends. Based on those characteristics, the plant will be better able to design a system that can properly treat its FGD wastewater given variability that might occur at the plant, and it will be better prepared to adjust chemical dosages in the chemical precipitation system to mitigate the variability in the wastewater that enters the biological treatment system." Response to Comments, p. 5-387. EPA also states: "While EPA has based the effluent limitations and standards for selenium and nitrate/nitrite (as N) for FGD wastewater based on the performance of the Allen and Belews Creek biological treatment systems, EPA does not contend that every plant in the industry can simply take the design parameters from those two plants, install the biological treatment system, and meet the effluent limitations. Each plant will need to work with engineering and design firms to assess the wastewater characteristics present at their plant to determine the most appropriate technologies and design the system accordingly meet the effluent limitations. Therefore, some plants may need to design the bioreactors to provide additional bed contact time (as provided by the 7 hydraulic residence time and volume of biomass and carbon substrate), while other plants may find they need less." Response to Comments, p. 5-389 Duke is requesting 48 months from the effective date of the permit to study the variability of the system, evaluate additional treatment needs and design, install and commission additional treatment components to meet the BAT limits based on the following preliminary timeline. FGD WWT Upgrade Activity Duration (Months) Design & Engineering 21 • Evaluate Variability in the System 12 • Technology Evaluation 7 • Engineering 2 Procurement 8 Construction/Tie-in 7 Start-up & Optimization' 12 • Start -Up 2 • Commissioning 6 Total: 48 1) Duke is allocating a 12 month window to complete the commissioning and start-up under all expected operating conditions from full load to partial load to periods of no load and under varying fuel types. Assuming a permit effective date of December 1, 2016, Duke estimates the system can be installed and commissioned to meet the BAT limits on or before November 30, 2020. To design, procure, construct and commission the FGD WWT system at BOSS, the following steps must be taken: Design & Engineering As with the RMDS, engineering and technology resources are limited due to regulatory requirements for concurrent implementation of programs, such as the CCR Rule and NC-CAMA across applicable sites in North Carolina. Duke is, therefore, estimating 21 months to complete the design and engineering phase of the project. Evaluate Variability in the System As stated by EPA and with Duke's agreement, plants need to conduct studies of the variability of the system over a long enough period of time that will include variability in plant operations such as shutdowns, fuel switches (preferably for all fuel types burned at the plant), variability in electricity generating loads, periods with high ORP, etc. to design an effective treatment system. With the need to evaluate different fuel types to maintain economic viability of the station, Duke estimates at least an additional 12 months after the permit effective date will be required to investigate variability in the system. Technology Evaluation Duke has significant experience in the design, construction and operation of biological treatment systems for selenium reduction. Based on Duke's experience, biological treatment alone may not be a fool proof technology based on the characteristics of the coal. Duke, therefore, is obligate to evaluate cost effective technology that ensures the FGD limits can be met under all conditions, including fuel type, electricity load, etc. At a minimum, Duke will be evaluating the addition of ultrafiltration to the backend of the treatment system. Duke will be working closely with utility organizations, such as the EPRI, to identify other suitable technologies for the removal of selenium from FGD wastewater and additional filtration steps that may be required to meet the limits. Duke estimates an additional 7 months after the completion of the investigation of variability in the system will be required to complete the technology evaluation. Engineering Upon completion of the investigation of variability in the system and technology evaluation, engineering and design of the system can be conducted and Duke has estimated two months for this effort. Procurement After the design is complete, Duke will initiate the process to procure the necessary outside resources to construct and install the new wastewater treatment systems. This process will involve the following steps: — Evaluate potential vendors for proposal solicitation; — Develop and submit a request for proposal (RFP) to selected vendors; — Conduct a review and vendor selection based on the received bids; — Develop required contract documents; — Acquire materials (potentially from overseas), which involves: o Shipment, and o Equipment Fabrication Fabrication and inspection of equipment. Duke has allocated 8 months to acquire the necessary materials. Construction / Tie In Once all the necessary materials are procured, Duke estimates construction of the FGD WWT will take approximately 7 months to complete. In addition, the tie-in of the additional components to the existing FGD WWT will need to occur during outages, which are anticipated to occur between March to May and October to November depending on generation demand. Commissioning & Start-up Duke estimates that commissioning and start-up of the FGD WWT will take 8 months to complete, 2 months for startup and 6 months for commissioning. Duke, however, is allocating a 12 month window to complete the commissioning and start-up under all expected operating conditions from full I load to partial load to periods of no load and under varying fuel and other operating conditions. This will allow the identification of necessary actions that need to be completed and necessary communications protocol in order to maintain and operate the system to comply with the limits. E. EPA Provided A Range of Applicability Dates To Allow For Coordination Across Regulatory Requirements and to Promote Orderly Decisions The steam electric industry is in the midst of major transitions driven by new environmental regulatory requirements in the air, waste, and water arenas. In the ELG Rule, EPA explicitly acknowledged the complications of planning and executing ELG retrofits while developing and executing compliance strategies under the other rules. EPA made it clear that the range of applicability dates provided in the ELG Rule are supposed to be implemented in a manner that avoids stranded costs and promotes orderly decision making. For instance, EPA states: "From an environmental protection/coordination standpoint, with the increased use of flue gas desulfurization scrubbers and flue gas mercury controls in response to air pollution -related requirements, this rule makes sense from a holistic environmental protection perspective and from the perspective of coordinating across rules affecting the same sector. This final ELG controls the discharges associated with these particular waste streams." Response to Comments, p. 8-388. EPA also states that the permitting authority may "account for time the facility needs to coordinate all the requirements of this rule, along with other regulatory requirements, to make the correct planning and financing decisions, and to implement the new requirements in an orderly and feasible way." Response to Comments, p. 8-129. At BCSS, we need to coordinate our ELG implementation strategy with CCR and NC -LAMA rules. For both the CCR and CAMA rules, we are evaluating the current CCR ash pond to determine whether the ponds meet the locational restrictions of 40 C.F.R. § 257.60 - .64. The future of the ash pond under both of these rules will determine whether it is available or not to receive legacy wastewaters (i.e., those wastewaters generated before the applicability date for bottom ash transport water retrofits) and continue to receive non-BATW. In addition, as discussed above, the final determination of the extent of the ash pond, as well as the closure method could have significant ramifications for the siting of the RMDS. F. ELG Implementation Should be Coordinated with the Clean Power Plan (CPP) to Avoid Stranded Costs The ELG Rule clearly contemplates that the compliance timelines for its requirements should account for any applicable obligations under the CPP. However, the affected units at BCSS will not know their individual obligations under the CPP until well after November 1, 2018. As promulgated by EPA, the CPP's emission guidelines do not apply directly to units. Instead, states are responsible for developing state plans setting forth requirements applicable to individual units that implement those emission guidelines. These state plans are subject to review and approval by EPA. If EPA determines that the state has not submitted an approvable plan, then EPA will promulgate a federal plan in its 10 place. The timeline the CPP provides for developing and reviewing these state plans involves numerous steps. The initial deadline for state plan submittal was September 6, 2016. 40 C.F.R. § 60.5760(a). The vast majority of states were expected to seek and obtain a two-year extension for final state plan submittal until September 6, 2018. See id. § 60.5760(b). However, the Supreme Court issued a stay of the CPP on February 8, 2016. Thus, the timing of the requirements of the CPP is uncertain at this time, as we wait further decisions by the Supreme Court. Duke would like to request the option to revise the applicability dates for the ELG requirements if the stay of the CPP is lifted and the operation of BCSS will be affected. Statements in the Response to Comments regarding stranded costs apply to any rule, not just the CPP. EPA explains in the Response to Comments that it provided flexibility in applicability dates so that facilities could consider all new regulatory requirements and then have an adequate time to plan and implement accordingly, and thus avoid stranded costs: "EPA is sensitive to the need to provide sufficient time for steam electric power plants to understand, plan for, and implement any changes to their operation to meet their environmental responsibilities, and agrees with the commenter that transparency of requirements is important for minimizing "stranded investments." ...Furthermore, as described in the preamble, the final rule provides time for plant owners or operators to implement changes to plant operations in order to meet the final limitations and standards, as well as flexibility to permitting authorities in implementing the final rule. The Agency specifically considered the timing of requirements of other environmental regulations in establishing implementation requirements for the ELGs, in order to provide steam electric power plants time to consider and implement their strategy for compliance." Response to Comments, p. 8-388. Even though the implementation and effects of the CPP are uncertain, North Carolina Department of Environmental Quality (NCDEQ) is justified providing flexibility in the applicability dates from other regulatory requirements such as the CCR and NC-CAMA, as discussed above. G. The Proposed Schedules Help To Maintain BCSS's Availability to the Grid, Which Promotes Grid Reliability Duke developed the proposed BATW retrofit schedule and its applicability date with grid reliability in mind. The dispatch of units at BCSS varies throughout the year. Typically at least one unit is operating throughout the year and both units are typically dispatched from December to March and June thru September. Therefore, the final tie-in schedule will avoid these months and more than likely tie-ins will need to occur across more than one outage. EPA explicitly notes that the permitting authority should consider grid reliability in setting applicability dates: "EPA's decision is also designed to allow, more broadly, for the coordination of generating unit outages in order to maintain grid reliability and prevent any potential impacts on 11 electricity availability, something that public commenters urged EPA to consider." 80 Fed. Reg. at 67,854, col. 2. See also Response to Comments, p. 8-138. Also, EPA clearly anticipated that much of the new technology required for retrofits to bottom ash transport water and FGD wastewater systems would be constructed in a manner that would not interrupt routine facility operations, and then tied in during regularly scheduled plant or unit outages. According to the preamble, the timing of the final rule "enables facilities to take advantage of planned shutdown or maintenance periods to install new pollution control technologies." 80 Fed. Reg. at 67,854, col. 2. EPA also recognizes that tie-ins of new equipment may need to occur across more than one outage. EPA states: "the need to span installation of equipment over separate unit outages [is] a consideration that can be incorporated into the permit writer's determination of the `as soon as possible' date, assuming the plant provides documentation demonstrating such a need." Response to Comments, p. 8-54. 12 Attachment 6 Arsenic, Selenium & Mercury Monitoring in Fish Muscle Tissue from the Dan River, NC August 2016 NPDES application renewal Belews Creek Steam Station NCO024406 Belews Creek Steam Station NPDES Permit No. NCO024406 Arsenic, Selenium, and Mercury Monitoring in Fish Muscle Tissue from the Dan River, NC Duke Energy August 2016 Table of Contents Page 1.0 Introduction....................................................................................................................... 1 2.0 Study Site Description and Sampling Locations............................................................... 1 3.0 Target Species................................................................................................................... 1 4.0 Field Sampling Methods................................................................................................... 1 5.0 Laboratory Processing and Selenium Analysis................................................................. 2 6.0 Data Analysis and Reporting............................................................................................ 2 7.0 References......................................................................................................................... 2 List of Tables Page Table 1 Arsenic, selenium, and mercury concentrations in axial muscle of fish from the upper Cape Fear River during May 2014.......................................................................... 3 List of Figures Figure 1 Upper Cape Fear River arsenic, selenium, and mercury monitoring locations............ Page 0 1 1.0 Introduction Duke Energy owns and operates the Belews Creek Steam Station (BCSS) located on the upper Dan River near Pine Hall in Stokes County, NC. The BCSS National Pollutant Discharge Elimination System (NPDES) Permit (No. NC0024406 Section A 12) requires monitoring of trace elements (arsenic, selenium, and mercury) in fish tissues near the ash pond discharge once per permit cycle. Fish samples were collected in accordance to the Belews Creek Dan River annual monitoring program and the resulting data are submitted in this report. 2.0 Study Site Description and Sampling Locations Fish were collected from three locations on the Dan River (Figure 1). These locations were upstream (A') and downstream (B and E) of the BCSS ash basin discharge to the Dan River. 3.0 Target Species The target fish species were Golden Redhorse and Redbreast Sunfish. As recommended by the US Environmental Protection Agency (EPA), an attempt was made to limit the smallest fish to 75% of the largest fish total length by species depending on availability (US EPA 2000). 4.0 Field Sampling Methods Fish were collected using electrofishing procedures as specified in the DEP Biology Program Procedures Manual (Procedure NR-00080, Rev. 1). DEP holds North Carolina Biological Laboratory Certification # 006 from the North Carolina Division of Water Resources for its lab located at New Hill, NC. Only live fish that showed little or no signs of deterioration were retained for analysis. Retained fish were identified to species, measured for total length (mm), weighted (g), individually tagged (Floy tags), placed on ice and transferred to a freezer within 24 hours of collection. Surface water quality parameters consisting of temperature, pH, dissolved oxygen, specific conductance and turbidity were recorded during each sampling, at each sampling location. Other noteworthy environmental conditions including river flow conditions and weather conditions were recorded and are available upon request. 1 5.0 Laboratory Processing and Arsenic, Selenium and Mercury Analysis All fish samples were processed in the New Hill Trace Element Laboratory according to procedure NR-00107 (Rev. 4) Trace Element Monitoring Laboratory Procedure. The processed samples (lyophilized left axial muscle; right muscle occasionally included when needed) were analyzed for arsenic, selenium, and mercury by x-ray spectrophotometry. Quality control was achieved by use of replicates and certified reference materials. The remaining fish carcasses were archived and will be kept for at least two years in the event that re -analysis is needed. 6.0 Data Analysis and Reporting Arsenic, selenium, and mercury concentrations (converted to µg/g fresh weight) in the fish muscle tissue collected during 2014 are shown in Table 1. In addition to the length and weight of each fish, the dry -to -fresh weight ratios are presented to convert the arsenic, selenium, and mercury concentrations fresh weight values back to dry weight values. The arsenic, mercury, and selenium concentrations in fish tissues were low and show no indication of bioaccumulation from operations of the BCSS ash basin discharge to the Dan River. In addition, all fish collected during 2014 were well below the US EPA Screening Values for Recreational Fishermen of 1.2 µg/g (fresh weight) for arsenic (US EPA 2000), and below the NC human consumption advisory level of 10 µg/g (fresh weight) for selenium. One Golden Redhorse from location B (downstream) had a mercury concentration of 0.40 µg/g fresh weight. The remaining fish were below the were below the North Carolina Health Directors Action Advisory Level of 0.40 µg/g fresh weight (NCDHHS 2006), 7.0 References NCDHHS. 2006. Health effects of methylmercury and North Carolina's advice on eating fish. North Carolina Occupational and Environmental Epidemiology Branch. Raleigh, NC. U.S. EPA. 2000. Guidance for assessing chemical contaminant data for use in fish advisories. Vol. 1. Fish sampling and analysis. Third edition. EPA 823-B-00-007. United States Environmental Protection Agency, Office of Water, Washington, DC. F) Table 1. Arsenic, selenium, and mercury concentrations (fresh weight) in axial muscle of fish collected from the Dan River during August 2014 at locations upstream (A'), near (B), and downstream (E) of the BCSS ash basin discharge to the Dan River Fish Species Location Month Length (mm) Weight (g) As (µg/g) Se (µg/g) Hg (µg/g) Dry -to -Fresh' Weigh Ratio Redbreast Sunfish Upstream Aug 146 53 0.18 0.33 0.15 0.205 Redbreast Sunfish Upstream Aug 149 58 0.16 0.31 0.18 0.203 Redbreast Sunfish Upstream Aug 137 38 0.16 0.29 0.20 0.220 Redbreast Sunfish Upstream Aug 131 33 0.14 0.25 0.09 0.206 Redbreast Sunfish Upstream Aug 147 56 0.13 0.27 <0.06 0.210 Redbreast Sunfish Upstream Aug 141 50 0.12 0.23 0.20 0.206 Golden Redhorse Upstream Aug 328 338 0.21 0.25 0.24 0.209 Golden Redhorse Upstream Aug 350 401 0.14 0.32 <0.06 0.212 Golden Redhorse Upstream Aug 349 410 0.17 0.21 0.17 0.209 Golden Redhorse Upstream Aug 347 391 0.12 0.26 0.21 0.201 Golden Redhorse Upstream Aug 341 380 0.11 0.19 0.12 0.186 Golden Redhorse Upstream Aug 345 390 0.12 0.24 0.11 0.202 Redbreast Sunfish Downstream Aug 145 54 0.20 0.60 0.22 0.200 Redbreast Sunfish Downstream Aug 141 46 0.13 0.72 0.06 0.205 Redbreast Sunfish Downstream Aug 141 50 0.15 0.61 0.08 0.197 Redbreast Sunfish Downstream Aug 153 66 0.14 0.41 0.14 0.196 Redbreast Sunfish Downstream Aug 152 58 0.14 0.96 0.24 0.199 Redbreast Sunfish Downstream Aug 151 57 0.12 0.53 0.09 0.203 Golden Redhorse Downstream Aug 378 522 0.17 0.67 0.39 0.191 Golden Redhorse Downstream Aug 346 435 0.17 0.78 0.40 0.200 Golden Redhorse Downstream Aug 368 471 0.15 0.64 0.37 0.213 Golden Redhorse Downstream Aug 344 390 0.12 0.51 0.26 0.197 Golden Redhorse Downstream Aug 362 460 0.16 0.78 0.24 0.200 Golden Redhorse Downstream Aug 366 456 0.13 0.68 0.25 0.199 Redbreast Sunfish Downstream Aug 147 54 0.20 0.86 0.21 0.201 Redbreast Sunfish Downstream Aug 157 69 0.15 0.67 <0.06 0.210 Redbreast Sunfish Downstream Aug 173 98 0.17 0.57 0.17 0.209 Redbreast Sunfish Downstream Aug 155 66 0.15 0.73 0.11 0.202 Redbreast Sunfish Downstream Aug 170 96 0.14 0.50 0.10 0.201 Redbreast Sunfish Downstream Aug 148 57 0.16 0.53 0.16 0.204 Golden Redhorse Downstream Aug 288 236 0.12 0.42 0.13 0.190 Golden Redhorse Downstream Aug 278 210 0.16 0.38 0.15 0.198 Golden Redhorse Downstream Aug 300 272 0.18 0.50 0.17 0.200 Golden Redhorse Downstream Aug 260 159 0.16 0.35 0.11 0.194 Golden Redhorse Downstream Aug 285 225 0.14 0.31 0.07 0.196 Golden Redhorse Downstream Aug 298 257 0.16 0.39 0.16 0.194 * To convert to a dry weight, divide the fresh weight concentrations by the dry -to -fresh weight ratio. 3 �*- Virninin Figure 1. Dan River arsenic, selenium, and mercury monitoring locations. Monitoring locations A' , B, and E in the Dan River upstream and downstream of the ash basin discharge of BCSS, Stokes County, NC. 4 Attachment 7 Assessment of Balanced and Indigenous Populations in Belews Reservoir August 2016 NPDES application renewal Belews Creek Steam Station NCO024406 ASSESSMENT OF BALANCED AND INDIGENOUS POPULATIONS IN BELEWS RESERVOIR For Belews Creek Steam Station: NPDES No. NCO024406 Water Resources DUKE ENERGY Corporate EHS Services McGuire Environmental Center 13339 Hagers Ferry Road Huntersville, NC 28078 August 2016 TABLE OF CONTENTS EXECUTIVE SUMMARY................................................................................................ iv LIST OF TABLES............................................................................................................. vii LIST OF FIGURES.......................................................................................................... viii LITERATURE CITED............................................................................L-1 CHAPTER 1- INTRODUCTION........................................................................................1-1 HISTORY AND PHYSICAL DESCRIPTION.................................................................. 1-1 Historical Perspective...................................................................................................... 1-1 StudyArea Description................................................................................................... 1-2 REGULATORY CONSIDERATIONS............................................................................. 1-4 STATION OPERATION AND NPDES THERMAL COMPLIANCE ............................. 1-4 CHAPTER 2- WATER QUALITY AND SEDIMENT CHEMISTRY ........................... 2-1 INTRODUCTION.............................................................................................................. 2-1 MATERIALS AND METHODS....................................................................................... 2-2 FieldMethods.................................................................................................................. 2-2 Laboratory Analytical Methods...................................................................................... 2-3 HydrologicData Methods............................................................................................... 2-4 Water Quality and Sediment Data Analysis Methods ..................................................... 2-4 RESULTS AND DISCUSSION......................................................................................... 2-4 Regional Precipitation and Management of Belews Reservoir Surface Elevations........ 2-4 Water Quality Monitoring Results.................................................................................. 2-5 Sediment Arsenic and Selenium Concentrations.......................................................... 2-10 SUMMARY..................................................................................................................... 2-12 CHAPTER 3- MACROINVERTEBRATES...................................................................... 3-1 INTRODUCTION.............................................................................................................. 3-1 MATERIALS AND METHODS....................................................................................... 3-1 WaterQuality.................................................................................................................. 3-1 Benthic Density and Diversity Monitoring..................................................................... 3-1 SeleniumMonitoring...................................................................................................... 3-2 RESULTS AND DISCUSSION......................................................................................... 3-3 Substrate.......................................................................................................................... 3-3 11 WaterQuality.................................................................................................................. 3-3 Benthic Diversity and Density Monitoring..................................................................... 3-3 Hexagenia....................................................................................................................... 3-5 SeleniumMonitoring...................................................................................................... 3-5 SUMMARY....................................................................................................................... 3-7 CHAPTER 4- FISH.............................................................................................................. 4-1 INTRODUCTION.............................................................................................................. 4-1 MATERIALS AND METHODS....................................................................................... 4-2 Spring Electrofishing Survey.......................................................................................... 4-2 SeleniumMonitoring...................................................................................................... 4-2 RESULTSAND DISCUSSION......................................................................................... 4-3 Spring Electrofishing Survey.......................................................................................... 4-3 SeleniumMonitoring...................................................................................................... 4-5 SUMMARY....................................................................................................................... 4-6 LITERATURE CITED........................................................................................................ I iii EXECUTIVE SUMMARY Aquatic populations residing in Belews Reservoir were adversely impacted by selenium contained in ash basin effluent from the Belews Creek Steam Station (BOSS) from 1976 — 1985. During 1984, BCSS began dry fly -ash collection to eliminate most selenium and other trace element inputs to the ash basin. The ash basin discharge was rerouted from Belews Reservoir to the Dan River in 1985. Since that time, aquatic populations in Belews Reservoir have recovered, and both Duke Energy and North Carolina Department of Environment and Natural Resources (NCDENR) have acknowledged that balanced and indigenous populations now reside in the reservoir. In addition to continued environmental monitoring in Belews Reservoir, monitoring at locations uplake and downlake of the BCSS ash basin discharge in the Dan River was initiated in 1984 and is ongoing. Duke Energy continues to monitor aquatic populations per the approved monitoring program in both the Dan River and Belews Reservoir. This report covers water quality, sediment chemistry, macroinvertebrate, and fish community monitoring results from Belews Reservoir from 2011 — 2015. The BCSS is typically operated as a baseload generating station and the yearly capacity factor (actual generation divided by potential generation, expressed as a percentage) during 2011 — 2015 has ranged from 65.4 to 82.5 %. During this period BCSS has fully complied with the thermal limits of the station's NPDES permit. As in previous years, Belews Reservoir Dam spillage remained relatively infrequent throughout 2011 — 2015. Controlled spillway releases primarily conformed to a seasonal pattern with spillage occurring during periods when the reservoir was near full pond. Virtually all former ash sluice -related trace elements have been removed from the water column with concentrations in Belews Reservoir during 2011 — 2015 less than applicable state water quality standards, action levels, and often less than current analytical reporting limits. Minor and gradual increases reported prior to 2011 for Belews Reservoir pH, specific conductance, alkalinity, and major dissolved ionic constituents (i.e., calcium, magnesium, chloride, and to slightly lesser extent, sodium, potassium, and silica) were not as evident in 2011 — 2015. The minimal, or lack of, increase was in part due to the relatively normal rainfall patterns and resulting inflows to Belews Reservoir as compared to the drought conditions evident in recent prior years 1998 - 2002 and 2007 — 2008. Overall, Belews Reservoir nutrient concentrations remain relatively low throughout most of the reservoir, which continues to be classified as an oligotrophic waterbody. Watershed inputs contribute to increased nutrient concentrations in the uplake region. uv Concentrations of arsenic and selenium in Belews Reservoir surficial fine sediments during 2011— 2015 were similar to levels reported since 2000. Arsenic and selenium concentrations in the deeper sediments of Belews Reservoir remain elevated relative to reference sites. However, recent sediment arsenic, and particularly selenium concentrations downlake in the shallower littoral areas are approaching the concentrations long -observed in the relatively unaffected uplake area of the reservoir. Belews Reservoir continues to support a diverse macroinvertebrate community reservoir - wide. Taxa numbers were somewhat lower during 2011 — 2015 than during the previous five-year period, but were within historical ranges. All three macroinvertebrate sampling locations periodically demonstrated higher densities than any recorded at these locations since 1991. Selenium concentrations in Belews Reservoir macroinvertebrates during 2011 — 2015 continued to indicate reduced levels and variability compared to results reported in the 1980's.. Comparable to historical trends, macroinvertebrates and plankton collected from the uplake Location 405.0 generally had lower selenium concentrations than other locations. Selenium concentrations in macroinvertebrates and plankton from downlake Locations 418.0 and 419.3 exceeded concentrations measured uplake, but showed the same decreasing trend over time. The results of this ongoing monitoring program indicate that legacy selenium concentrations in the lentic food web continue to decline, and the operation of BCSS is not having a detrimental impact on the macroinvertebrate community of Belews Reservoir. A total of 22 species represented bt seven families, dominated by sunfish (Centrarchidae) were collected in the 2011 — 2015 fish community assessment. Fish survey metrics associated with species composition, catch, and ecological function represent a self- sustaining balanced and indigenous fish community in Belews Reservoir, were consistent with previously reported data since 1994. Uplake and midlake regions had the highest fish species diversity and catch, likely due to higher relative concentrations of phosphorous, organic carbon, total suspended solids, and turbidity from watershed inputs. Conversely, discharge and downlake regions had the lowest fish species diversity and catch, reflective of oligotrophic conditions. ►v Mean selenium concentrations in Redear Sunfish and Largemouth Bass remained well below levels considered detrimental to fish reproduction and the 10-µg/g, wet weight, concentration considered safe for human consumption. Belews Reservoir continues to support a diverse fish and macroinvertebrate community reservoir -wide. Results of long-term monitoring continue to indicate that a balanced and indigenous aquatic community exists in Belews Reservoir. k,Pjl Table LIST OF TABLES Title 1-1 Belews Reservoir sampling locations and monitoring summary for 2011 Page 2015.............................................................................................................................1-6 1-1 BCSS average monthly and yearly capacity factors (percent) from January 2011 through December 2015.........................................................................................7 2-1 Analytical methods used to determine chemical and physical constituents in Belews Reservoir during 2011 — 2015...................................................................... 2-13 3-1 General descriptions of the substrate found at sampling locations in Belews Reservoir during July of 2011 — 2015......................................................................... 3-8 3-2 Dissolved oxygen (mg/L) concentrations and temperatures (°C) recorded from locations in Belews Reservoir at the times of macroinvertebrate collections................................................................................................................... 3-9 3-3 Densities (No./m2) of macroinvertebrates collected from Location 405.1 from2006 — 2015...................................................................................................... 3-10 3-4 Densities (No./m2) of macroinvertebrates collected from Location 410.2 from2006 — 2015...................................................................................................... 3-13 3-5 Densities (No./m2) of macroinvertebrates collected from Location 418.1 from2006 — 2015...................................................................................................... 3-16 4-1 Pollution tolerance rating, trophic guild of adults, and fish species collected during studies of Belews Reservoir, 1994 — 2015...................................................... 4-7 4-2 Species composition by number of electrofishing samples collected from Belews Reservoir, 2011 — 2015.................................................................................. 4-8 4-3 Species composition by biomass (kg) of electrofishing samples collected from Belews Reservoir, 2011 — 2015.......................................................................... 4-9 vii LIST OF FIGURES Figure Title Page 1-1 Belews Reservoir sampling locations during 2011 —2015 ........................................... 1-8 1-2 Daily average dam spillage temperatures during 2011 — 2015, compared to daily average near -surface water temperatures recorded in the Belews Creek arm of the reservoir (Location 419.2)......................................................................... 1-9 2-1 Annual cumulative precipitation at Greensboro, NC during 1996 — 2015 (2011 — 2015 data highlighted), and at the USGS Pine Hall, NC station during2009 — 2015................................................................................................... 2-15 2-2 Monthly cumulative precipitation at Greensboro, NC during 2001 — 2015................ 2-16 2-3 Monthly cumulative precipitation for the USGS Pine Hall station during 2011 — 2015 compared to Greensboro, NC airport precipitation ....................................... 2-16 2-4 Belews Reservoir daily average surface elevations during 2001 — 2015. Full pond elevation is 725 ft (approximately 221 m) above mean sea level (msl)........... 2-17 2-5 Hourly average BCSS CCW intake and flow -weighed discharge temperatures, and CCW flow during 2011...................................................................................... 2-17 2-6 Hourly average BCSS CCW intake and flow -weighed discharge temperatures, and CCW flow during 2012...................................................................................... 2-18 2-7 Hourly average BCSS CCW intake and flow -weighed discharge temperatures, and CCW flow during 2013...................................................................................... 2-18 2-8 Hourly average BCSS CCW intake and flow -weighed discharge temperatures, and CCW flow during 2014...................................................................................... 2-18 2-9 Hourly average BCSS CCW intake and flow -weighed discharge temperatures, and CCW flow during 2015...................................................................................... 2-19 2-10 Winter (w) and summer (s) thermal profiles at the Belews Reservoir Dam forebay (Location 416.0) during 2011 — 2015.......................................................... 2-19 2-11 Winter (w) and summer (s) thermal profiles near the BCSS CCW intake (Location 418.0) during 2011 — 2015....................................................................... 2-19 2-12 Winter (w) and summer (s) thermal profiles at the main Reservoir confluence with the BCSS CCW connecting canal (Location 410.0) during 2011-2015 ............................................................................................................... 2-20 2-13 Winter (w) and summer (s) thermal profiles at the confluence of Belews and East Belews Creek (Location 419.3) during 2011 — 2015........................................ 2-20 2-14 Historical trend for Belews Reservoir summer thermocline depth, measured at the Belews Reservoir Dam forebay (Location 416.0)........................................... 2-21 2-15 Winter 2011 Belews Reservoir water temperature isotherms ................................... 2-21 2-16 Winter 2012 Belews Reservoir water temperature isotherms ................................... 2-22 2-17 Winter 2013 Belews Reservoir water temperature isotherms ................................... 2-22 2-18 Winter 2014 Belews Reservoir water temperature isotherms ................................... 2-23 2-19 Winter 2015 Belews Reservoir water temperature isotherms ................................... 2-23 2-20 Summer 2011 Belews Reservoir water temperature isotherms ................................. 2-24 viii Figure LIST OF FIGURES Title Page 2-21 Summer 2013 Belews Reservoir water temperature isotherms ................................. 2-24 2-22 Summer 2013 Belews Reservoir water temperature isotherms ................................. 2-25 2-23 Summer 2014 Belews Reservoir water temperature isotherms ................................. 2-25 2-24 Summer 2015 Belews Reservoir water temperature isotherms ................................. 2-26 2-25 Winter (w) and summer (s) DO profiles at the Belews Reservoir Dam forebay (Location 416.0) during 2011 — 2015.......................................................... 2-26 2-26 Winter (w) and summer (s) DO profiles near the BCSS CCW intake (Location 418.0) during 2011 — 2015....................................................................... 2-27 2-27 Winter (w) and summer (s) DO profiles at the main Reservoir confluence with the BCSS CCW connecting canal (Location 410.0) during 2011 — 2015........................................................................................................................... 2-27 2-28 Winter (w) and summer (s) DO profiles at the confluence of Belews and East Belews Creek (Location 419.3) during 2011 — 2015........................................ 2-27 2-29 Winter 2011 Belews Reservoir DO isopleths............................................................ 2-28 2-30 Winter 2012 Belews Reservoir DO isopleths............................................................ 2-28 2-31 Winter 2013 Belews Reservoir DO isopleths............................................................ 2-29 2-32 Winter 2014 Belews Reservoir DO isopleths............................................................ 2-29 2-33 Winter 2015 Belews Reservoir DO isopleths............................................................ 2-30 2-34 Summer 2011 Belews Reservoir DO isopleths......................................................... 2-30 2-35 Summer 2012 Belews Reservoir DO isopleths......................................................... 2-31 2-36 Summer 2013 Belews Reservoir DO isopleths......................................................... 2-31 2-37 Summer 2014 Belews Reservoir DO isopleths......................................................... 2-32 2-38 Summer 2015 Belews Reservoir DO isopleths......................................................... 2-32 2-39 Spatial -temporal distribution of Belews Reservoir pH, 1977 — 2015........................ 2-33 2-40 Temporal trend in surface pH measured at Belews Reservoir Dam forebay, 1977-2015 ............................................................................................................... 2-33 2-41 Spatial -temporal distribution of Belews Reservoir specific conductance, 1977-2015 ............................................................................................................... 2-34 2-42 Temporal trend in surface specific conductance measured at Belews Reservoir Dam forebay, 1977 — 2015....................................................................... 2-34 2-43 Spatial -temporal distribution of Belews Reservoir alkalinity (as mg CaCO3/L), 1977 — 2015............................................................................................ 2-35 2-44 Temporal trend in surface alkalinity concentrations measured at Belews Reservoir Dam forebay, 1977 — 2015....................................................................... 2-35 2-45 Spatial -temporal distribution of Belews Reservoir calcium concentrations, 1977-2015 ............................................................................................................... 2-36 2-46 Temporal trend in surface calcium concentrations measured at Belews Reservoir Dam forebay, 1977 — 2015....................................................................... 2-36 2-47 Spatial -temporal distribution of Belews Reservoir magnesium concentrations, 1977-2015 ............................................................................................................... 2-37 ix LIST OF FIGURES, Continued Figure Title Page 2-48 Temporal trend in surface magnesium concentrations measured at Belews Reservoir Dam forebay, 1977 — 2015....................................................................... 2-37 2-49 Spatial -temporal distribution of Belews Reservoir sodium concentrations, 1977 — 2015............................................................................................................... 2-38 2-50 Temporal trend in surface sodium concentrations measured at Belews Reservoir Dam forebay, 1977 — 2015....................................................................... 2-38 2-51 Spatial -temporal distribution of Belews Reservoir potassium concentrations, 1977 — 2015............................................................................................................... 2-39 2-52 Temporal trend in surface potassium concentrations measured at Belews Reservoir Dam forebay, 1977 — 2015....................................................................... 2-39 2-53 Spatial -temporal distribution of Belews Reservoir chloride concentrations, 1977 — 2015............................................................................................................... 2-40 2-54 Temporal trend in surface chloride concentrations measured at Belews Reservoir Dam forebay, 1977 — 2015....................................................................... 2-40 2-55 Spatial -temporal distribution of Belews Reservoir sulfate concentrations, 1977 — 2015............................................................................................................... 2-41 2-56 Temporal trend in surface sulfate concentrations measured at Belews Reservoir Dam forebay, 1977 — 2015....................................................................... 2-41 2-57 Spatial -temporal distribution of Belews Reservoir silica (as elemental Si) concentrations, 1977 — 2015..................................................................................... 2-42 2-58 Temporal trend in surface silica (as elemental Si) concentrations measured at Belews Reservoir Dam forebay, 1977 — 2015....................................................... 2-42 2-59 Spatial -temporal distribution of Belews Reservoir iron concentrations, 1977 — 2015........................................................................................................................ 2-43 2-60 Spatial -temporal distribution of Belews Reservoir manganese concentrations, 1977 — 2015..................................................................................... 2-43 2-61 Spatial -temporal distribution of Belews Reservoir aluminum concentrations, 1977 — 2015............................................................................................................... 2-44 2-62 Spatial -temporal distribution of Belews Reservoir ammonia -nitrogen concentrations, 1977 — 2015..................................................................................... 2-44 2-63 Spatial -temporal distribution of Belews Reservoir nitrate+nitrite-nitrogen concentrations, 1977 — 2015..................................................................................... 2-45 2-64 Spatial -temporal distribution of Belews Reservoir total nitrogen concentrations concentrations, 1977 — 2015............................................................. 2-45 2-65 Spatial -temporal distribution of Belews Reservoir orthophosphate concentrations, 1977 — 2015..................................................................................... 2-46 2-66 Spatial -temporal distribution of Belews Reservoir total phosphorus concentrations, 1977 — 2015..................................................................................... 2-46 2-67 Spatial -temporal distribution of Belews Reservoir total organic carbon concentrations, 1977 — 2015..................................................................................... 2-47 2-68 Spatial -temporal distribution of Belews Reservoir turbidity, 1977 — 2015............... 2-47 X LIST OF FIGURES, Continued Figure Title Page 2-69 Spatial -temporal distribution of Belews Reservoir total suspended solids concentrations, 1977 — 2015..................................................................................... 2-48 2-70 Spatial -temporal distribution of Belews Reservoir total recoverable arsenic concentrations, 1977 — 2015..................................................................................... 2-48 2-71 Spatial -temporal distribution of Belews Reservoir total recoverable cadmium concentrations, 1977 — 2015...................................................................... 2-49 2-72 Spatial -temporal distribution of Belews Reservoir total recoverable copper recoverable concentrations, 1977 — 2015.................................................................. 2-49 2-73 Spatial -temporal distribution of Belews Reservoir total recoverable selenium concentrations, 1977 — 2015...................................................................... 2-50 2-74 Spatial -temporal distribution of Belews Reservoir total recoverable zinc concentrations, 1977 — 2015..................................................................................... 2-50 2-75 Arsenic and selenium in surficial fine sediments collected from upper Belews Reservoir, 1984 — 2015. (DL = concentration reported as below detectionlimit).......................................................................................................... 2-51 2-76 Arsenic and selenium in shallow littoral surficial fine sediments collected from lower Belews Reservoir, 1984 — 2015. (DL = concentration reported as below detection limit)........................................................................................... 2-51 2-77 Arsenic and selenium in mid -depth surficial fine sediments collected from lower Belews Reservoir, 1984 — 2015. (DL = concentration reported as below detection limit)............................................................................................... 2-52 2-78 Arsenic and selenium in deep surficial fine sediments collected from lower Belews Reservoir, 1984 — 2015. (DL = concentration reported as below detectionlimit).......................................................................................................... 2-52 3-1 Total number of taxa collected annually from Locations 405.1, 410.2, and 418.1 from 2006 — 2015............................................................................................ 3-21 3-2 Density (No./m2) of macroinvertebrates collected annually from Locations 405.1, 410.2, and 418.1 from 2006 — 2015............................................................... 3-22 3-3 Density (No./m2) of Oligochaeta, Diptera, Corbicula, and Others collected annually from Location 405.1 (uplake) from 2006 — 2015....................................... 3-23 3-4 Density (No./m2) of Oligochaeta, Diptera, Corbicula, and Others collected annually from Location 410.2 (downlake) during 2006 — 2015 ............................... 3-24 3-5 Density (No./m2) of Oligochaeta, Diptera, Corbicula, and Others collected annually from Location 418.1 (downlake) during 2006 — 2015 ............................... 3-25 3-6 Hexagenia densities at locations in Belews Reservoir during summer and spring periods of 2012 — 2015.................................................................................. 3-26 3-7 Selenium concentrations (µg/g, wet weight) in Diptera collected from three locations in Belews Reservoir during 1984 — 2015.................................................. 3-27 3-8 Selenium concentrations (µg/g, wet weight) in Corbicula collected from three locations in Belews Reservoir during 1984 — 2015......................................... 3-28 xi LIST OF FIGURES, Continued Figure Title Page 3-9 Selenium concentrations (µg/g, wet weight) in the plankton collected from three locations in Belews Reservoir during 1985 — 2015......................................... 3-29 4-1 Number of fish collected during spring electrofishing, 1994 — 2015, at four Belews Reservoir sampling regions.......................................................................... 4-10 4-2 Weight (kg) of fish collected during spring electrofishing, 1994 — 2015, at four Belews Reservoir sampling regions.................................................................. 4-10 4-3 Number of fish species collected during spring electrofishing, 1994 — 2015, at four Belews Reservoir sampling regions.............................................................. 4-11 4-4 Mean relative weight (Wr), with 95% confidence interval, of Largemouth Bass collected in Belews Reservoir 1994 — 2015..................................................... 4-11 4-5 Mean relative weight (Wr), with 95% confidence interval, of Largemouth Bass by Belews Reservoir region, 1994 — 2015........................................................ 4-12 4-6 Mean selenium concentrations (wet weight) in Redear Sunfish muscle tissue collected annually from four locations in Belews Reservoir, 1995 — 2015.............. 4-12 4-7 Mean selenium concentrations (wet weight) in Largemouth bass muscle tissue collected annually from four locations in Belews Reservoir, 2007- 2015........................................................................................................................... 4-13 x1i CHAPTER I INTRODUCTION HISTORY AND PHYSICAL DESCRIPTION Historical Perspective Belews Creek Steam Station (BCSS) is a two -unit, coal-fired electric generating plant located on Belews Reservoir, in Stokes County, North Carolina. The reservoir, impounded primarily to supply once -through condenser cooling water (CCW), first reached full pond in 1973, followed by commercial operation of BCSS Unit I in August 1974, and Unit 2 in December 1975. Each 1, 11 0-megawatt' BCSS unit is cooled by CCW pumped at a maximum rate of 33.1 m3/s (1,170 cfs). As in the past, BCSS was operated as a baseload generating station from 2011 - 2015. In 1976 a sharp decline in the Belews Reservoir fishery was observed and eventually linked with the discharge of BCSS ash basin effluent to the reservoir (Cumbie and Van Horn 1978; Olmsted et al. 1986). A decline in the game fish population, documented reservoir -wide except for a remote headwater area, was specifically attributed to reproductive impairment and failure of recruitment caused by selenium. The impact of selenium on the Belews Reservoir fishery was exacerbated by the lengthy retention time of the reservoir, approximately 1,500 days under normal conditions. The extremely low rate of reservoir outflow via dam spillage facilitated accumulation of selenium within the water column and sediments, leading to selenium enrichment by the lowermost tier of the lentic food web, and subsequent trophic transfer to sensitive receptor species (in particular, fish) via the food web. By 1984, Duke Energy implemented dry fly -ash collection at BCSS to eliminate most wet ash sluicing, and therefore reducing selenium and other trace element inputs to the ash basin. To further facilitate the eventual recovery of the reservoir ecosystem, the ash basin discharge to Belews Reservoir was rerouted to the Dan River in November 1985. Monitoring of water and sediment chemistry, in addition to macroinvertebrate and fish populations, has been 1 Unit capacity ratings were reduced from a previous 1,120 megawatts in October 2008 following installation of wet flue gas desulfurization (scrubber) systems. 1-1 ongoing since the termination of the ash basin discharge to the reservoir (Table 1-1 and Figure 1-1). Results of regular monitoring by Duke Energy have effectively documented the recovery of the reservoir and its biological communities over time. Duke Energy and the North Carolina Department of Environment and Natural Resources (NCDENR) have acknowledged that macroinvertebrate and fish populations in Belews Reservoir have substantially recovered from the selenium contamination episode and that a balanced and indigenous aquatic community now exists in the reservoir. As required by the National Pollutant Discharge Elimination System (NPDES) permit for BCSS (NCDENR 2005b, 2007a, 2009, 2012), this report summarizes 2011 — 2015 results from the ongoing monitoring effort to assess water and sediment chemistry, macroinvertebrates, and fish in Belews Reservoir. In addition to continuing environmental monitoring in Belews Reservoir, monitoring by Duke Energy at Dan River locations upstream and downstream of the re -located BCSS ash basin discharge was initiated in 1984. Results of the Dan River monitoring program are in an annual report submitted to NCDENR, and are not included in this report. Study Area Description Belews Reservoir was constructed principally as a cooling water source for BCSS, and has no hydroelectric generation capability. The reservoir has a surface area of 1,563 hectares (3,863 acres) at full pond elevation (221 in, or 725 ft msl). The upstream catchment is relatively small, comprised of only an additional 1,630 hectares (4,028 acres; NCDENR 2010a). Belews Reservoir is comprised of distinct regions, which in part relate to its principle tributaries: the West Belews Creek arm; the Belews Creek arm; and the main body of the reservoir, wherein their confluence lies (termed the "downlake" region in this and earlier reports; Figure 1-1). The upper portion of the West Belews Creek arm of the reservoir receives heated effluent from the BCSS once -through CCW system. The West Belews Creek arm is physically separated from the remainder of Belews Reservoir, except for a 1.5-km, man-made canal that facilitates the return of heated CCW effluent to the Belews Creek arm. 1-2 Within the downlake region of Belews Reservoir, a high degree of uniformity in water quality is normally evident. This is principally due to a forced circulation pattern induced by the operation of the combined 66.3-m3/s (2,340-cfs) capacity BCSS CCW pumps. The CCW system flow rate significantly exceeds typical inflow rates from combined reservoir tributaries (estimated to average 2.8 m3/s [98 cfs]; Cumbie 1978). Particularly during the thermally stratified portion of the year, BCSS CCW pumping effectively maintains a circulation pattern within the epilimnion of the downlake region. During the period of time that ash basin effluent was discharged to Belews Reservoir in the 1970s and early 1980s, this circulation pattern was instrumental in mixing diluted coal ash -associated trace elements throughout the downlake region of Belews Reservoir. Moving southward from the downlake region into the Belews Creek arm, beginning at about 1 km from the BCSS CCW discharge canal, one encounters a narrow portion of the reservoir historically termed the "midlake" region. This region represents a transitional area, situated between the reservoir's headwaters and the downlake region. In this portion of the reservoir, the upper part of the water column typically reflects downlake water quality as influenced by the edge of the BSCC thermal plume. However, the deeper portion of the midlake water column typically reflects water quality more like that observed in the headwater portion of the reservoir (i.e., cooler water, with greater concentrations of nutrients and suspended solids). Following the fish population collapse that occurred in the 1970s and early 1980s, this midlake region was considered a key indicator area in reservoir -wide assessments, and was closely monitored to assess the early stages of recovery of the fish community. The uppermost headwater section of the Belews Creek arm lies upstream and south of US Highway 158, and has been termed the "uplake" region in this and other reports. Physical restrictions to reservoir mixing attributable to the Highway 158 bridge and causeway, in addition to two similar infrastructure "pinch points" (another road bridge and a former rail crossing) located slightly downstream within the midlake region, serve to hydrologically isolate the uplake from the downlake region. Because of these physical restrictions and the nearby tributary inflow, the relatively shallow (i.e., < 5 m) uplake area was exceptional compared to the balance of Belews Reservoir in retaining its indigenous fish community throughout the 1970s and 1980s. 1-3 REGULATORY CONSIDERATIONS Aside from the aforementioned requirement for ongoing environmental studies in both Belews Reservoir and the Dan River, the BCSS NPDES permit establishes daily thermal limits. Because Belews Reservoir was conceived and constructed as an industrial cooling pond, however, regulatory thermal limits do not apply within the reservoir. The station's NPDES permit establishes a discharge maximum thermal limit (32 °C, or 89.6 T) at the Belews Reservoir spillway for the protection of downstream water quality. The limit applies during actual spillway releases (NCDENR 2005b, 2007a, 2009, 2012). Duke Energy continuously monitors Belews Reservoir forebay (at the spillway) and actual spillage temperatures to assure compliance with the permitted thermal maximum limit. Reference reservoir temperatures are also continuously recorded from near -surface at a midlake site (Location 419.2). STATION OPERATION AND NPDES THERMAL COMPLIANCE BCSS effectively maintained its role as a base load generating station throughout the most recent five-year period. Annual net capacity factors (actual generation divided by potential generation, expressed as a percentage) for the station were 82.5, 71.7, 64.5, 69.2, and 64.4 % for the years 2011 — 2015, respectively (Table 1-2). Routine maintenance outages of generating units were evident as unit -specific reductions in the monthly capacity data, occurring throughout the five-year period. During 2011 — 2015, BCSS complied with the thermal maximum permitted for Belews Reservoir Dam spillage, 32 T. As in previous years, Belews Reservoir Dam spillage remained relatively infrequent throughout 2011 — 2015. Frequency of spillway operation ranged from a minimum of 20 days per year in 2015 to a maximum of 102 days per year in 2011. Controlled spillway releases primarily conformed to a seasonal pattern with spillage occurring during periods when the reservoir was near full pond, i.e., normally winter -spring, with spillage requirements typically triggered by short-term local precipitation patterns (Figure 1-2). 1-4 2011 — 2015 BELEWS LAKE MONITORING PROGRAM The Duke Energy Belews Reservoir monitoring program remained unchanged following the last reported results (Duke Energy 2011). The program encompasses water quality monitoring, sediment, macroinvertebrate, and fish trace element screening, macroinvertebrate and fish community assessments. The scope of annual monitoring activities is provided in Table 1-1, with reference to sample locations identified on Figure 1- 1. The remainder of this report is dedicated to a summary and discussion of the 2011 — 2015 Belews Reservoir monitoring results. 1-5 Table 1-1. Belews Reservoir sampling locations and monitoring summary for 2011 — 2015. Location Water Quality Analyses Sediment Elemental Analyses Macroinvertebrate Quantitative Analyses Macroinvertebrate Elemental Analyses Fish Community / Elemental Analyses 405.0 • • • 405.1 • 410.0 • • 410.2 • • 416.0 • 417.1 • 417.2 • 418.0 • • 418.1 • • 418.3 • 419.1 • 419.2 • • 419.3 • 419.4 • 422.0 • 1-6 Table 1-2. BCSS average monthly and yearly capacity factorsA (percent) from January 2011 through December 2015. 2011 2012 2013 2014 2015 Mont h Unit 1 Unit 2 Statio n Unit 1 Unit 2 Statio n Unit 1 Unit 2 Statio n Unit 1 Unit 2 Statio n Unit 1 Unit 2 Statio n Jan 96.93 89.55 93.24 68.91 87.64 78.27 82.11 61.71 71.91 93.46 89.49 91.47 70.97 78.14 74.56 Feb 92.68 96.00 94.34 52.38 88.41 70.39 84.63 79.93 82.28 92.54 94.85 93.70 93.49 90.91 92.20 Mar 72.18 74.40 73.29 59.74 43.54 51.64 91.32 43.32 67.32 88.42 88.45 88.44 89.32 73.96 81.64 Apr 29.87 81.19 55.53 90.88 16.10 53.49 36.27 41.05 38.66 90.24 38.32 64.28 10.15 61.17 35.66 May 86.95 75.44 81.20 89.46 83.97 86.71 46.07 83.51 64.79 61.98 75.37 68.67 30.46 65.51 47.99 Jun 92.98 93.73 93.35 87.74 84.35 86.05 85.45 81.38 83.42 82.96 86.29 84.62 78.34 77.53 77.94 J u l 94.14 88.93 91.53 94.79 90.42 92.60 87.09 84.15 85.62 70.23 81.18 75.71 86.97 85.86 86.42 Aug 94.22 95.62 94.92 87.46 80.48 83.97 84.21 59.32 71.76 83.00 80.96 81.98 72.36 68.50 70.43 Sep 89.24 80.60 84.92 69.48 46.37 57.93 84.76 34.68 59.72 71.78 65.37 68.57 73.33 62.98 68.15 OCt 90.94 62.93 76.93 74.18 5.12 39.65 10.50 88.89 49.69 90.54 0.00 45.11 81.61 33.19 57.40 Nov 87.76 85.47 86.61 86.51 70.98 78.74 0.00 93.23 46.08 94.75 0.00 47.21 23.17 67.36 45.26 DeC 55.80 72.21 64.01 83.18 78.79 80.99 20.63 85.44 53.04 19.85 22.37 21.11 31.36 39.42 35.39 Year 81.97 83.01 82.49 78.73 64.68 71.70 59.42 69.72 64.52 78.31 60.22 69.24 61.79 67.04 64.42 A Unit -specific capacity factors were obtained from the Duke Energy Microgads database (2011 - 2015 data). 1-7 Spillway • Bel. Lake Stokes County North Carolina 417.2 i INK 2.00 17,..1 Tto&. Duwnlake EF Zone 8.0 BCSS ❑l 418.1 ,"I 410.2 410.0 11� _�� Sampling Locations (See Table 1-1) ❑❑ Electrofishing 41❑❑ 9Zones .1 41 Hwy 65 419.2 • 419.40 Hwy 158 405.0- / (� 405.1 0 0.5 1 2 Miles 0 0.75 1.5 3 Kilometers Figure 1-1. Belews Reservoir sampling locations during 2011 2015. 1-8 40 35 30 U 25 W D 20 aD n P_ 15 10 3 D Jan-11 • Spillage Temperature - Midlake Temperature - - - Spillage Thermal Limit (32' C) ■ Jan-12 Jan-13 Jan-14 Jan-15 Jan-16 Date Figure 1-2. Daily average dam spillage temperatures during 2011 — 2015, compared to daily average near -surface water temperatures recorded in the Belews Creek arm of the reservoir (Location 419.2). 1-9 CHAPTER 2 WATER QUALITY AND SEDIMENT CHEMISTRY INTRODUCTION This chapter summarizes the results of the continuing water quality and sediment chemistry monitoring programs conducted at Belews Reservoir since 1977 and 1984, respectively. The water quality and sediment chemistry portion of the Belews Reservoir monitoring program is comprised of semi-annual (winter and summer) water quality sampling, and annual reservoir sediment sampling. These programs have served to assess the effects of rerouting the BCSS ash basin discharge away from Belews Reservoir. As discussed in Chapter 1, rerouting of the ash basin effluent (and installation of a dry fly -ash collection system) was undertaken in response to toxicity concerns caused by elevated concentrations of coal ash combustion trace elements, principally selenium, in Belews Reservoir. Previous research (Duke Power 1994, 1995, 1996, 1996b, 1997, 1998, 19995, 2000, 2001 a, 2001b, 2002, 2003, 2004, 2005; Duke Energy 2006a, 2006b, 2007, 2008, 2009a, 2009b, 2010a, 2011b, 2012, 2013, 2014; Harden et al. 1988; Lewis et al. 1988) indicated that re- routing the ash basin discharge has had minimal impact on the Dan River, but a distinct and positive effect on Belews Reservoir water quality. Water column arsenic and selenium concentrations in Belews Reservoir decreased substantially during the first year the ash pond effluent was diverted to the river and have remained near or below detectable levels ever since. Sediment trace element concentrations in the downlake areas of Belews Reservoir continue to be elevated with respect to non -impacted uplake sites. However, data collected over the past several years suggest that these downlake concentrations have substantially declined in the littoral areas of the reservoir, while remaining elevated in the deepest regions. 2-1 MATERIALS AND METHODS Field Methods In -situ Belews Reservoir water quality was monitored at seven locations (Table 1-1 and Figure 1-1) semiannually (summer and winter) during 2011 — 2015. Sample locations were the same as those previously employed in past Belews Reservoir studies and comprise the following: 405.0 (uplake); 419.2 and 419.3 (two midlake locations); 410.0 (BCSS condenser cooling water [CCW] discharge confluence with the Belews Creek arm of the reservoir); 418.0 (BCSS CCW intake); 418.3 (former BCSS ash basin discharge); and 416.0 (forebay of the Belews Reservoir Dam). In -situ analyses were performed by Duke Energy Environmental Services personnel .2 Vertical profiles of in -situ parameters (temperature, dissolved oxygen [DO], pH and specific conductance) were collected with a field -calibrated Hydrolab DataSondeo. Profile sampling included surface (0.3 m) measurements, and, except for the shallow cove Location 418.3, sequential measurements collected at one -meter intervals, to within 0.5 in above bottom. Water samples for laboratory analyses were collected with a Kemmerer bottle at surface (0.3 m) and approximately one meter above bottom, except for the cove location (418.3), where only surface samples were obtained. Water samples for a wide array of analytes were collected during 2011 — 2015 at all locations except Location 419.2, where only samples for arsenic and selenium were collected. Samples for soluble nutrients (i.e., ammonia-N, nitrite+nitrate-N, orthophosphate, and dissolved organic carbon) were filtered (0.45-µm) in the field. All samples were preserved (acidified and / or iced) in the field immediately following collection. Sediment sampling for evaluation of selected trace element concentrations was conducted at four Belews Reservoir locations during 2011 — 2015, and was similar to that described previously (Duke Power 2001a; Duke Energy 2006a, 2011). In the main body of Belews Reservoir, sediments were obtained from three sites corresponding to distinct bottom depths: Location 417.1 (2 to 3 in deep); Location 417.2 (5 to 7 m); and Location 422.0 (25 to 30 m). Uplake sediment samples (Location 405.0; 3 to 5 m) were also collected for comparative purposes. Five replicate cores were obtained from each location. Cores were collected with 2 The Duke Energy Environmental Services organization is certified by the North Carolina Division of Water Quality (DWQ) under the Field Parameter Certification program (certificate number 5193). 2-2 a 50.8-mm internal diameter Kajak-Brinkhurst gravity corer fitted with cellulose acetate butyrate core liner tubes. Upon collection, sediment cores were sealed with polyethylene end caps, with site water overlaying the intact water -sediment interface. Cores were maintained in an upright position to preserve the sediment -water interface, stored on ice, and subsequently refrigerated upon return to the laboratory. Laboratory Analytical Methods Water Analytical methods and sample preservation techniques employed during 2011 — 2015 are summarized in Table 2-1. The majority of laboratory water quality analyses were performed by the Duke Energy Carolinas, LLC analytical laboratory, Huntersville, NC (NC Division of Water Quality [DWQ] Laboratory Certification program, certificate number 248). Selected parameters, however, were analyzed by alternate state -certified commercial laboratories. Prism Laboratories, Inc., Charlotte, NC (NC DWQ certificate number 402) determined biochemical oxygen demand (BOD), and turbidity analyses for all 2011 through summer 2015 samples. Since 2001, trace element concentrations of water samples have been analyzed as "total recoverable" elemental concentration, which incorporates a dilute acidic digestion of the sample (USEPA 1994). This technique was distinct from the analytical method for trace elements employed during the period 1988 — 2000, when acid -preserved samples were analyzed by atomic absorption spectroscopy direct injection, i.e., samples were not acid - digested. Sediment Upon return to the laboratory, fine-suspendable sediments were siphoned from the top 2-3 mm of each core, sieved through a 63-µm plastic (Nitexo) screen, and then deposited onto a pre -weighed 0.45-µm Millipore° acetate membrane filter. Filters were subsequently dried at room temperature and analyzed by non-destructive neutron activation analysis at the Nuclear Services Laboratory, North Carolina State University, Raleigh, NC. Quality assurance measures for sediment trace element concentrations (expressed as µg element/g sediment) employed internal standards and National Institute of Standards and Technology or International Atomic Energy Agency reference materials for calibration. 2-3 Hydrologic Data Methods Hydrologic data (i.e. rainfall) were retrieved from two local area monitoring stations, a National Weather Service (NWS) monitoring site at Greensboro, NC and a United States Geological Survey (USGS) station near Pine Hall, NC. Belews Reservoir elevation data were retrieved from the Duke Energy Plant Information (PI) system. Annual and monthly rainfall totals and daily Belews Reservoir pond elevations are depicted graphically for use in discussions of trends in water quality. Water Quality and Sediment Data Analysis Methods Data analyses employed both statistical and graphical methods. Water quality and sediment analyte concentrations reported as less than method reporting limits, were set to the limit prior to graphical display or statistical analysis. Time series plots were used to assess seasonal and inter -annual trends in CCW and reservoir temperatures. Reservoir -wide temperature and DO data collected semi-annually were assessed using both vertical profile and areal contour plots. Box and whisker plots (showing median, 25% and 75% quartiles, and data range) were produced for water chemistry analytes, by sample location and pre- defined year groupings (i.e., during ash basin inputs: 1977 — October 1985; initial ecosystem recovery period: November 1985 — 1995; and successive 5-year reporting intervals: 1996 — 2000; 2001 — 2005; 2006 — 2010; and 2011 — 2015), to permit examination of spatial and temporal trends. Graphical long-term temporal trending was used to facilitate examination of hydrologic or other factors on selected water chemistry parameters. RESULTS AND DISCUSSION Regional Precipitation and Management of Belews Reservoir Surface Elevations The five-year monitoring period summarized in this report exhibited precipitation patterns (2011 — 2015) that were near normal in comparison to the two previously reported periods that experienced some prolonged drought periods in 2002 - 2003 and 2007 - 2008 (Figures 2- 1 through 2-3; NCDC 2007-2015; USGS 2016). Local precipitation, as measured by the National Weather Service (NWS) at Greensboro, NC and the (USGS) station near Pine Hall, NC was at, or slightly above, normal for calendar years 2011, 2012, and 2015. Precipitation was just slightly below normal for calendar years 2012 and 2014. 2-4 Belews Reservoir elevations were maintained closer to full pool elevation in the 2011 - 2015 monitoring period in comparison to the previous monitoring periods (Figure 2-4). This was largely a result of more normal precipitation patterns in 2011 - 2015 relative to the previous reporting period (2006 - 2010) that experienced prolong drought conditions from 2007 through 2008. Supplemental pumping in 2011 - 2015 also aided in maintaining pool elevations in Belews Reservoir. Water Quality Monitoring Results Water Temperature Seasonal ranges in Belews Reservoir water temperatures during 2011 — 2015 were consistent with previously monitored years, as evident from CCW records, temperature profiles, and isotherm plots (Figures 2-5 through 2-9; 2-15 through 2-24). Furthermore, temperature profiles from 2011 - 2015 exhibited similar winter and summer thermal patterns characteristic of Belews Reservoir that have been observed and discussed in previous reports (Duke Energy 2006a, 2011). Winter vertical temperature profiles measured downlake at the Belews Reservoir Dam forebay (416.0) and BCSS intake (418.0) locations indicated typical near -uniformity with depth, ranging from about 10.5 to 13.5 °C (Figures 2-10 and 2-11) [Note that winter 2014 profiles were collected in March where other years' winter monitoring was completed in February. The March 2014 profiles reflect slight warming in the upper water column that would be consistent with collecting this data later in the calendar year.]. Temperature profiles at Location 410.0 (CCW discharge; Figure 2-12), and to a lesser extent Location 419.3 (midlake; Figure 2-13), reflect warming of the upper water column by the buoyant thermal plume from BCSS, in both winter and summer monitoring events. Over the five- year period, 2011 — 2015, minimum winter temperatures occurred reservoir -wide during the winter of 2015. The ranges of summer profile temperatures during 2011 — 2015 were generally typical of long-term trends for each monitoring location (Figures 2-10 through 2-13). Main reservoir (Location 416.0) surface temperatures were between 29.0 and 33.0'C. The warmest summer epilimnetic temperatures reservoir -wide were observed in August 2011 (38.6 °C) at the confluence of the CCW connecting canal [i.e. Location 410.0 (Figure 2-12)]. Hypolimnetic 2-5 temperatures in mid -summer were indicative of preceding late winter water temperatures (i.e., about 10 to 13.5 'Q. As previously reported in BIP reports (Duke Power Company 1996; Duke Power 2001 a; Duke Energy 2006a, 2011), changes in the summer physical -chemical structure of Belews Reservoir were observed following installation of a hypolimnetic air injection system designed to improve the efficiency of the BCSS CCW system. This air injection system, installed in 1985 at a depth of 17 meters below full pond elevation, creates an up -welling of cooler metalimnetic and hypolimnetic water for condenser cooling (Griggs 1985; Duke Power Company 1996). In earlier years, summertime operation of the system effectively deepened the late summer thermocline (i.e., region of maximum observed decline in temperature per depth unit) depth by approximately seven to eight meters below that observed previously (Figure 2-14). Similar thermal effects have been documented for other waterbodies subjected to hypolimnetic aeration (Labaugh 1980; Schladow and Fisher 1995). Significantly reduced operation of the hypolimnetic aeration system was reported previously (Duke Energy 2011). Reservoir -wide summer temperatures and resulting thermocline depths from 2011 - 2015 indicated limited, to non-existent, use of this system once again in the current monitoring period. Reduced aeration system operation has allowed a relatively greater reserve of cooler water to remain available (from depths down to 17 meters) for an extended period throughout the summer. Two-dimensional contour plots of water temperature isotherms illustrate the relative consistency in thermal gradients in Belews Reservoir. Besides the CCW thermal plume itself (in the immediate vicinity of Location 410.0), the most extreme thermal gradient occurring in wintertime occurs between the Belews Reservoir headwaters to downlake approximately 2 km into the midlake region of the Belews Creek arm of the reservoir, just above the vicinity of Location 419.3 (Figures 2-15 through 2-19). During the summer stratified period, a maximal thermal gradient generally occurs reservoir -wide, encompassing a vertical differential of about 15 to 16 °C across an approximate 8-m to 10-m layer of water centered near elevation 210 m msl (Figures 2-20 through 2-24). Summer isotherm distributions indicate that uplake temperatures are only marginally cooler with respect to the main portion of Belews Reservoir. 2-6 Dissolved Oxygen Belews Reservoir epilimnetic DO profiles (Figures 2-25 through 2-28) consistently exceeded the state water quality standard of 5 mg/L (NCDENR 2007b) during 2011 — 2015. Periodic monitoring, most recently in 2009 by the North Carolina DWQ (NCDENR 2010a), has also indicated adequate summer DO concentrations in the surface waters of Belews Reservoir. Summer DO profiles from 2011 - 2015 exhibited a metalimnetic depression in oxygen concentrations coincident with the thermocline depth, as has been reported previously (Duke Energy 2011). This phenomenon, which is characteristic of southeastern reservoirs that undergo pronounced seasonal thermal stratification, is caused by the thermocline acting as a density barrier. This density gradient at the thermocline impedes vertical settling to the extent that overlying oxygen -consuming material settles to this depth and subsequently depletes the DO. During 2011 — 2015, metalimnetic DO depression was most clearly demonstrated at Location 410.0 (Figure 2-27). Two-dimensional contour plots of DO isopleths further illustrate the seasonal distribution of DO throughout the reservoir in 2011 - 2015. Very little spatial differentiation in DO concentrations were evident in winter due to virtually complete mixing of the water column with reservoir -wide DO concentrations of 6 mg/L and above (Figures 2-29 through 2-33). Summer 2011 — 2015 DO isopleths depict consistent prevalence of adequate DO concentrations reservoir -wide in the epilimnion (Figures 2-34 through 2-38), but also variation year -by -year in the degree of DO depletion in the deeper regions of the reservoir. Water Chemistry Spatial -temporal depictions of water chemistry parameters are provided in Figures 2-39 through 2-74. Earlier reports (Harden et al. 1988; Lewis et al. 1988; Harden 1991; Duke Power Company 1996) noted changes in Belews Reservoir water quality, particularly in decreasing levels of alkalinity, calcium, sulfate, and specific conductance, coincident with the termination of ash basin discharges to the reservoir in late 1985. Changes were most noteworthy at Location 418.3, a cove that formerly received ash basin discharge. Downlake locations, where concentrations of constituents associated with ash pond effluent (i.e., dissolved minerals and trace elements) had never risen to the incipient levels measured at Location 418.3, and have shown less dramatic, but consistent, declines over the years. During 1996 — 2000 many water quality indicators were measured at levels similar to those 2-7 observed a decade after termination of ash pond sluice inputs to the reservoir (Duke Power 2001a). However, specific conductance and concentrations of potassium and sulfate continued to decline at downlake and midlake locations. Reservoir -wide monitoring of water column concentrations since 2000 has confirmed that declining trends formerly noted for selected conservative mineral constituents have abated, and in some instances, concentrations have actually increased in recent years, as influenced by repeated occurrences of drought conditions in the watershed. Reservoir -wide in situ pH measurements were consistent with the previous reporting period values. Reservoir -wide pH measurements from 2011 - 2015 as with the previous monitoring period were elevated with respect to data collected since 2000 (Figure 2-39). These pH shifts can be driven by changes in major ion concentrations, which in turn are further influenced by watershed meteorology (e.g., drought; Figure 2-40). For example, gradual increases in Belews Reservoir calcium and until recent years, decreases in sulfate concentrations, appear consistent with the observed temporal pH trends. Specific conductance (Figures 2-41 and 2-42), alkalinity (Figures 2-43 and 2-44), calcium (Figures 2-45 and 2-46), magnesium (Figures 2-47 and 2-48), sodium (Figure 2-49 and 2-50), potassium (Figure 2-51 and 2-52), chloride (Figures 2-53 and 2-54), and silica (Figure 2-57 and 2-58) were fairly consistent with the previous reporting period. Specific conductance, calcium, and chloride showed signs of continued, but extremely minimal, increases in these constituents. However, alkalinity, magnesium, potassium, and silica during 2011 — 2015 appeared to remain constant compared to the previous reporting period. Overall, trends in these parameters indicated the inflows (and supplemental pumping) to the reservoir were sufficient in 2011 - 2015 to offset some of the minor increasing trends in these parameters reported in recent monitoring periods as a result of prolonged drought conditions. Belews Reservoir sulfate concentrations (Figures 2-55 and 2-56) peaked in the early 1980s as a result of the introduction of ash pond effluents. Concentrations of sulfate were in steady decline after the 1985 termination of the effluent until 1998. Subsequently, sulfate concentrations have remained relatively stable, including through the 2011 - 2015 reporting period. Iron (Figure 2-59), manganese (Figure 2-60), and aluminum (Figure 2-61) concentrations demonstrated either no or negligible decrease compared to recent years. Maximum concentrations of these cationic metals have historically been associated with either reduced W, redox conditions occurring seasonally in the hypolimnion, or samples containing higher suspended solids concentrations, as typically collected uplake at Location 405.0, above the Highway 158 bridge. Concentrations of major nutrients (Figures 2-62 through 2-66) in Belews Reservoir have historically been, and continue to be, consistently low and indicative of an oligotrophic waterbody (Weiss and Kuenzler 1976; NCDEHNR 1992; NCDENR 2005a, 2010a). Elevated and variable phosphorous, and to a lesser extent, organic nitrogen concentrations are frequently encountered near the Belews Reservoir headwaters, in addition to deep midlake samples typically influenced by headwater inflows. Watershed nutrient contributions to Belews Creek are in part evidenced by water quality trends in Kernersville Reservoir, located several kilometers southwest and uplake of Location 405.0 on the uppermost reach of Belews Creek. That small water supply reservoir has exhibited increased concentrations of phosphorus and total Kjeldahl nitrogen in recent years, spurring undesirable algal blooms (NCDENR 2010a). Elevated phosphorus concentrations encountered uplake, as influenced by Belews Reservoir headwaters, are consistent with greater productivity, and higher number of fish species and biomass observed uplake compared to further downlake regions (see Chapters 3 and 4). Similar uplake-to-downlake differences were routinely observed for total organic carbon (Figure 2-67), turbidity (Figure 2-68), total suspended solids (Figure 2-69), and as mentioned previously, iron (Figure 2-59), manganese (Figure 2-60), and aluminum (Figure 2-61). Belews Reservoir aqueous trace element concentrations (Figures 2-70 through 2-74) consistently remained below applicable state water quality standards and action levels throughout 2011 — 2015 (NCDENR 2007b). Typical of previous monitoring, all aqueous cadmium concentrations measured in Belews Reservoir during 2011 — 2015 were less than the laboratory reporting limit (1 µg/L). Similarly, for lead, water column concentrations were below reporting limits (1 µg/L). All total and dissolved copper concentrations remained below 2 µg/L throughout the five-year period (with 81 % remaining below the reporting limit of 1 µg/L). Once -elevated aqueous arsenic and selenium concentrations measured at the cove formerly receiving ash basin effluent (Location 418.3) dropped precipitously just two years after the effluent was routed to the Dan River. Since the late 1980s, water column concentrations of arsenic (Figure 2-70) and selenium (Figure 2-73) at all downlake and midlake locations have declined to minimal levels, predominantly occurring below detectable quantities. During this 2-9 timeframe and inclusive of the 2011 — 2015 period, arsenic and selenium concentrations measured in the water column downlake have remained undifferentiated from those measured in the remote headwater portion of Belews Reservoir (Location 405.0). In fact, during the 2011 - 2015 monitoring period 100% of the samples analyzed for selenium and 98 % of samples analyzed for arsenic were below analytical reporting limits (1 µg/L). Sediment Arsenic and Selenium Concentrations Distinct reservoir depth -dependent concentration differences in downlake Belews Reservoir fine (< 63 µm) surficial sediments have been noted historically, with deeper locations concentrating significantly (a < 0.001) more of either trace element than progressively shallower locations (Figures 2-75 through 2-78; Duke Power Company 1996, 2001a). Cumbie (1984) and Harden (1991) reported this depth -associated correlation for Belews Reservoir and hypothesized differential mobilization and deposition of selenium and arsenic - containing material from shallow to deep areas of the reservoir. This process, termed "sediment focusing" by Likens and Davis (1975) has been observed in other waterbodies (Davis and Ford 1982). The potential magnitude of this effect appears to be predominately related to mean basin slope (Blais and Kalff 1995). Graphical analysis of sediment selenium and arsenic concentrations suggests that following significant reservoir -wide reductions from 1985 to 2000, concentrations have become relatively stable in the last 15+ years (Figures 2-75 through 2-78). While deep (> 25 m) sediment selenium concentrations are substantially reduced from those measured decades earlier, as was true for arsenic, profundal sediment concentrations clearly remain the most elevated in the system. Low sediment selenium concentrations at the uplake site (Location 405.0) are typical of "background" or unimpacted locations and have remained virtually unchanged over time. With the exception of the deepest profundal sediments (> 25 meters deep; Location 422.0), over the years sediment trace element concentrations in the main body of Belews Reservoir (particularly Location 417.1 and to a slightly less extent, Location 417.2) have been reduced to a similar magnitude as observed uplake (Location 405.0). The similarity of downlake littoral concentrations with uplake sediment results, coupled with the lack of a diminishing trend in recent years for these sites, suggest that a relatively static level of "near background" concentrations has been achieved reservoir -wide in the shallow zones. Given the overall absence of decreasing trends in recent years, future reductions in Belews Reservoir sediment 2-10 trace element concentrations should be anticipated to occur very gradually (i.e., over a scale of decades). Correspondingly greater trace element concentrations measured at the deepest site also appear to have stabilized over the past decade. Due to the relatively low productivity and resultant low accumulation rate of organic sediment deposition in Belews Reservoir, higher concentrations of selenium and arsenic in the deepest reservoir sediments are anticipated to also remain unchanged in the near term. Fortunately, however, maximum concentrations still found in the spatially limited deep zone represent a relatively minor fraction, and less important component, of the reservoir habitat for potential Belews Reservoir receptor organisms. 2-11 SUMMARY Belews Reservoir water quality has improved measurably since the mid-1980s in relation to the original selenium -induced biological population collapse and resulting diversion of ash basin discharge from Belews Reservoir. Virtually all former ash sluice -related trace elements have been removed from the water column with concentrations in Belews Reservoir during 2011 — 2015 and once again were less than applicable state water quality standards, action levels, and often less than current analytical reporting limits. Water quality data from 2011 - 2015 indicate conditions in Belews Reservoir continue to be amenable to the maintenance and propagation of a diverse warm water aquatic community commensurate with the nutrients afforded by an oligotrophic waterbody. Belews Reservoir nutrient concentrations continued to remain relatively low except for the uplake area of the reservoir, where most nutrient inputs have occurred historically. The reservoir's thermal and DO structure in 2011 - 2015, were again similar to years prior that have seen the continued recovery of the Belews Reservoir fishery. Minor and gradual increases reported in recent years (Duke Energy 2011) for Belews Reservoir pH, specific conductance, alkalinity, and major dissolved ionic constituents (i.e., calcium, magnesium, chloride, and to slightly lesser extent, sodium, potassium, and silica) were not as evident in 2011 - 2015. The minimal, or lack of, increase was in part due to the relatively normal rainfall patterns and resulting inflows to Belews Reservoir as compared to the drought conditions evident in recent prior years 1998 - 2002 and 2007 - 2008. These increases, if continued in the future under drought conditions, are of no special significance to the recovery of Belews Reservoir fishery. Concentrations of arsenic and selenium in Belews Reservoir surficial fine sediments during 2011 — 2015 were similar to levels reported since 2000. Arsenic and selenium concentrations in the deeper sediments of Belews Reservoir remain elevated relative to the reference site. However, monitoring in the past 15+ years indicates that sediment arsenic and selenium concentrations found downlake are fairly stabilized. Additionally, concentrations of arsenic and selenium, but particularly selenium concentrations found downlake in shallower littoral areas (i.e., ideal warm water fish and spawning habitat), are very near the low magnitude of concentrations long -observed in the relatively unaffected uplake area of the reservoir. 2-12 Table 2-1. Analytical methods used to determine chemical and physical constituents in Belews Reservoir during 2011 - 2015. Parameter Method (EPA / APHA / ASTM)3 Preservation Reporting Limit Alkalinity, Total Total inflection point titration 6 °C 0.01 meq/L as EPA 310.1 CaCO3 Aluminum Atomic emission/ICP 0.5% HNO3 0.05 mg/L EPA 200.7 Arsenic, Total ICP mass spectrometry 0.5% HNO3 2.0 pg/L4 Recoverable EPA 200.8 1.0 pg/L5 Biochemical Oxygen EPA 405.1 6 °C 2-3 mg/L6 Demand Cadmium, Total ICP mass spectrometry 0.5% HNO3 0.5 pg/L7 Recoverable EPA 200.8 1.0 pg/L8 Calcium Atomic emission/ICP 0.5% HNO3 0.03 mg/L EPA 200.7 Carbon, Dissolved EPA 415.1 6 °C; 0.1 mg/L Organic 0.5% H2SO4 Carbon, Total EPA 415.1 6 °C; 0.1 mg/L Organic 0.5% H2SO4 Chloride Colorimetric 6 °C 1.0 mg/L EPA 325.2 Conductance, Temperature -compensated in -situ 0.1 pS/cm9 Specific nickel or graphite electrode APHA 2510 Copper, Dissolved ICP mass spectrometry 0.5% HNO3 2.0 pg/Ld EPA 200.8 1.0 pg/Le Copper, Total ICP mass spectrometry 0.5% HNO3 2.0 pg/Ld Recoverable EPA 200.8 1.0 pg/Le Iron, Total Atomic emission/ICP 0.5% HNO3 0.01 mg/L Recoverable EPA 200.7 Lead, Total ICP mass spectrometry 0.5% HNO3 2.0 pg/Ld Recoverable EPA 200.8 1.0 pg/Le Magnesium Atomic emission/ICP 0.5% HNO3 0.03 mg/L10 EPA 200.7 0.005 mg/Lh Manganese, Total ICP mass spectrometry 0.5% HNO3 1.0 pg/L Recoverable EPA 200.8 1. USEPA 1983 2. APHA et al. 1998 3. ASTM 2005, 2009 3 References: 4 2006 - 2008 5 2009 - 2010 6 Variable by sample run 8 2006 - February 2009 August 2009 - 2010 so Instrument sensitivity furnished in lieu of laboratory reporting limit 2006 - 2009 2-13 Table 2-1. (Continued) Parameter Method (EPA / APHA / ASTM) Preservation Reporting Limit Nitrogen, Ammonia Colorimetric 6 °C 0.02 mg/L EPA 350.1 0.5% H2SO4 Nitrogen, Nitrite+Nitrate Colorimetric 6 °C 0.02 mg/L EPA 353.2 0.5% H2SO4 Nitrogen, Total Colorimetric 6 °C; 0.1 mg/L Kjeldahl EPA 351.2 0.5% H2SO4 Phosphorus, Colorimetric 6 °C 0.005 mg/L Orthophosphate EPA 365.1 Phosphorus, Total Colorimetric 6 °C 0.005 mg/L EPA 365.1 Oxygen, Dissolved Temperature -compensated in -situ 0.01 mg/L polarographic cell APHA 4500-0 G 1 Luminescent (LDO) sensor ASTM D888-0912 pH Temperature -compensated in -situ 0.01 unit' glass electrode APHA 4500-H Potassium Atomic emission/ICP 0.5% HNO3 0.25 mg/L EPA 200.7 Selenium, Total ICP mass spectrometry 0.5% HNO3 2.0 pg/Ld Recoverable EPA 200.8 1.0 pg/Le Silica (as Si) APHA 4500Si-F 6 °C 0.5 mg/L Sodium Atomic emission/ICP 0.5% HNO3 1.5 mg/L EPA 200.7 Solids, Total Gravimetric 6 °C 20 mg/L APHA 2540 B Solids, Total Gravimetric 6 °C 0.10-5.0 mg/Lf Suspended APHA 2540 D Sulfate Ion chromatography 6 °C 1.0 mg/L EPA 300.0 Temperature NTC thermistor in -situ 0.01 od APHA 2550 Turbidity Turbidimetric 6 °C 0.4 NTU EPA 180.1 Zinc ICP mass spectrometry 0.5% HNO3 1.0 pg/Lk EPA 200.8 2.0 pg/L 11 2006 - February 2009 12 August 2009 - 2010 2-14 iRM 160 Mf E 120 c 100 v 80 aD ► .1 20 0 Cfl ti CO M O N M 'r LO CO f-- CO M CD CD c'� u7 M M M M CD0 0 0 0 0 0 0 0 0 rn rn rn rn ID 0 0 0 0 0 0 0 0 0 0 0 o a a o N N N N N N N N N N N N N N N CV Date Figure 2-1. Annual cumulative precipitation at Greensboro, NC during 1996 — 2015 (2011 — 2015 data highlighted), and at the USGS Pine Hall, NC station during 2009 — 2015. 2-15 30 25 61 0 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 Date Figure 2-2. Monthly cumulative precipitation at Greensboro, NC during 2001 — 2015. 25 20 V15 c 0 co Q 10 n 9 _ _ _ 7 { N N_ N_ N_ N N [2 C2 C2 M_ [2 [2 2m V V 12 �2 �21 'P O O a O O d O O O O O O O O O O O O O O O O O O O O O O O O N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N Month 1 Year Figure 2-3. Monthly cumulative precipitation for the USGS Pine Hall station during 2011 — 2015 compared to Greensboro, NC airport precipitation. 2-16 725 723 E 721 W 717 715 1 Mi sin zr- elevation data S pple ental punning from a ive 221 220 M m 0 219 218 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 Date Figure 2-4. Belews Reservoir daily average surface elevations during 2001 — 2015. Full pond elevation is 725 ft (approximately 221 m) above mean sea level (msl). 50 U 40 30 20 a� 10 0 75 N 5D --- —------------- -- 25---------------------------------------------------- _CC�111-.1 ---- 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dee Figure 2-5. Hourly average BCSS CCW intake and flow -weighed discharge temperatures, and CCW flow during 2011. 2-17 50 & 40 o 30 20 10 0 75 --------- — ------------------------------------------------------ 50 .. . ...... ............. ....... W 25 cc 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Figure 2-6. Hourly average BCSS CCW intake and flow -weighed discharge temperatures, and CCW flow during 2012. 50 40 30 20 10 0 75 - -- ------- ------- ----- ----- - ------- ----- - ----- ------- ------- ----- -- ---------- 50 . .... E25 . . . . . . ............... ....... ............. . cc W_ Flow 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Figure 2-7. Hourly average BCSS CCW intake and flow -weighed discharge temperatures, and CCW flow during 2013. 50 40 30 20 10 0 75 --------------------------------------------------------------------------------------- 50 25 - - ----------------- 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Figure 2-8. Hourly average BCSS CCW intake and flow -weighed discharge temperatures, and CCW flow during 2014. 2-18 50 U 40 o 30 20 10 0 75 5D - ----- ---- 25 - CCW Foy -- 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Figure 2-9. Hourly average BCSS CCW intake and flow -weighed discharge temperatures, and CCW flow during 2015. Temperature CC) Temperature CC) 0 5 10 15 20 25 30 35 40 45 0 5. 10 15 20 25 30 35 40 45 0 5 10 15 E 20 r Y v 25 30 35 40 45 0 5 10 15 E 20 r Y m 25 0 30 35 40 45 Figure 2-10. Winter (w) and summer (s) thermal profiles at the Belews Reservoir Dam forebay (Location 416.0) during 2011 — 2015. Temperature CC) Temperature CC) 0 5 10 15 20 25 30 35 40 45 0 5. 10 15 20 25 30 35 40 45 0 5 10 15 E 20 L m 25 G 30 35 40 45 0 5 10 15 E 20 s Y iu 25 G 30 35 40 45 Figure 2-11. Winter (w) and summer (s) thermal profiles near the BCSS CCW intake (Location 418.0) during 2011 — 2015. 2-19 0 5 10 15 E 20 L m 25 0 30 35 40 45 Temperature (°C) Temperature ff) 0 5. 10 15 20 25 30 35 40 45 0 5. 10 15 20 25 30 35 40 45 0 5 10 I5 20 L m 25 30 35 40 45 Figure 2-12. Winter (w) and summer (s) thermal profiles at the main Reservoir confluence with the BCSS CCW connecting canal (Location 410.0) during 2011 — 2015. Temperature (°C) Temperature (°C) 0 5 10 15 20 25 30 35 40 45 0 5 10 15 20 25 30 35 40 45 0 5 to is 20 L v 25 0 30 35 40 45 0 5 10 15 20 L m 25 a 30 35 40 45 Figure 2-13. Winter (w) and summer (s) thermal profiles at the confluence of Belews and East Belews Creek (Location 419.3) during 2011 — 2015. 2-20 D 5 10 E m 15 W 20 25 liil f pl n i e atibri systern • • • rMMCD "M V LOWrl—MMM "M V LOWr—WMM NC'7 V L!']COrOO O)O�NC] V L!7 rrrcocpoOCOcOMcOcOcOoOMMMMmMMMMMID 000 000 Or r rnrnrnrnrnrnrnrnrnrnrnrnrnrnrn2 g?g? rnrnrn0000000CDC3CD 000 r r r r r r N N N N N N N N N N N N N N N N Date Figure 2-14. Historical trend for Belews Reservoir summer thermocline depth, measured at the Belews Reservoir Dam forebay (Location 416.0). e 0 Co 0 W 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-15. Winter 2011 Belews Reservoir water temperature isotherms. 2-21 E 0 E C 0 76 W 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-16. Winter 2012 Belews Reservoir water temperature isotherms. E 0 0 1= 0 6 W 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-17. Winter 2013 Belews Reservoir water temperature isotherms. 2-22 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-18. Winter 2014 Belews Reservoir water temperature isotherms. 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-19. Winter 2015 Belews Reservoir water temperature isotherms. 2-23 ;_ 0 CO CO E C 0 0 w 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-20. Summer 2011 Belews Reservoir water temperature isotherms. 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-21. Summer 2012 Belews Reservoir water temperature isotherms. 2-24 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-22. Summer 2013 Belews Reservoir water temperature isotherms. 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-23. Summer 2014 Belews Reservoir water temperature isotherms. 2-25 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-24. Summer 2015 Belews Reservoir water temperature isotherms. DO (mg/1) DO (mg/1) 0 2 4 6 S 10 12 0 2' 4 6 8 10 12 0 0 —F6-11 11 —Aug-11 5 —F6-12 5 —Aug-12 —Fetr13 —Aug-13 10 —M, 14 __ 10 —Aug-14 —F6-15 —Aug-15 i5 15 E 20 E 20 L L a° 25 L EL m 25 in O 30 30 35 35 40 40 I W -----___- S 45........................ ........................ ......................... ......................... ........... -.............. 45-........... ..... ..........................................- - ........................' Figure 2-25. Winter (w) and summer (s) DO profiles at the Belews Reservoir Dam forebay (Location 416.0) during 2011 — 2015. 2-26 DO (mg/1) DO (mg/1) 0 2 4 6 8 10 12 0 2 4 6 8 10 12 0 5 30 15 20 L m 25 0 30 35 40 45 Figure 2-26. Winter (w) and summer (s) DO profiles near the BCSS CCW intake (Location 418.0) during 2011 — 2015. DO (mg/1) DO (mg/1) 0 2 4 6 8 10 12 0 2 4 6 8 10 12 0 5 10 15 20 L F+ v 25 0 30 35 40 45 0 5 10 15 20 L m 25 0 30 35 40 45 0 5 10 I5 20 L m 25 30 35 40 45 Figure 2-27. Winter (w) and summer (s) DO profiles at the main Reservoir confluence with the BCSS CCW connecting canal (Location 410.0) during 2011 — 2015. DO (mg/1) DO (mg/1) 0 2 4 6 8 10 12 0 2 4 6 8 10 12 0 5 10 15 20 L m 25 0 30 35 40 45 0 5 10 15 20 L w 25 30 35 40 45 Figure 2-28. Winter (w) and summer (s) DO profiles at the confluence of Belews and East Belews Creek (Location 419.3) during 2011 — 2015. 2-27 ;_ 0 Co Co E C 0 0 w 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-29. Winter 2011 Belews Reservoir DO isopleths. E 0 0 0 0 0 W 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-30. Winter 2012 Belews Reservoir DO isopleths. 2-28 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-31. Winter 2013 Belews Reservoir DO isopleths. 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-32. Winter 2014 Belews Reservoir DO isopleths. 2-29 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-33. Winter 2015 Belews Reservoir DO isopleths. 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-34. Summer 2011 Belews Reservoir DO isopleths. 2-30 ;_ 0 E 0 w 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-35. Summer 2012 Belews Reservoir DO isopleths. ;_ 0 Co 0 0 0 W 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-36. Summer 2013 Belews Reservoir DO isopleths. 2-31 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-37. Summer 2014 Belews Reservoir DO isopleths. 8 6 4 2 0 2 4 6 8 10 12 14 16 Distance from Belews Dam (km) Figure 2-38. Summer 2015 Belews Reservoir DO isopleths. 2-32 10 9 8 D U) 7 _ Q 4 ui ui o ui o u2 u) u) o un o u� LC) u) CD LC) u� uO ui CDui o ui ui u7 CD u) o u� uO u) CD r) o u� uO u) CD ui c co m o o r r co m o o r r co m o o r r co m o o r r m m o o r r co m o o r r co m o o m r rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o o c r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N I'— u7 Co r co r � u) CO r co r 1'- u7 co r co r r— u7 CO r CO r 1— u) CO r co r r- u7 CO r m r r— u7 CO r x r~ m M o 0 o r m M o 0 o r m M o 0 o r co rn o 0 o r- oo rn o 0 o r m m o 0 o r- m rn o c Of of of C� O N 61 61 61 Ci Q N of of of Ci Q N of of of C� O N of 61 O Q N of of of Q Q N of of of O C r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N F 418.0 418.3 416.0 410.0 419.3 419.2 Sample Dates/ Location Figure 2-39. Spatial -temporal distribution of Belews Reservoir pH, 1977 — 2015. 10.0 9.5 - 9.0 8.5 8.0 U) 7.5 _ CL 7.0 6.5 6.0 5.5 5.0 r- 6 Q Ln r- m cO � r- m cO uy r- rn c2 L,n ti i- m CO co CO CO rn rn rn m 0) o a a CD0 6Y 6i M 67 67 6i C 7 M 6] 67 67 rn O O Cl CD CD CD CD CD r r r r r r r r r r r r N N N N N N N N Sample Date 405.0 er inat on of ash basin discharge to lake 1998 - 002 20 7 - 2008 rou ht d oug t ® � 4 O 0 0 0 0 °°0° ° ° o o 0 0°0 0 00 0°0 ° o °° ° 0 0 Figure 2-40. Temporal trend in surface pH measured at Belews Reservoir Dam forebay, 1977 — 2015. 2-33 500 400 CIS, U U) i 200 100 11 i I 0 U�UoUo2 �UuoUo�JJoUo2LnLnoLno�LnuouoL��ouo�LLOCDLn cornoorrcornoorroornoorrmrnoorrcvrnoorrmrnoorrmrnoor rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn D o 0 0 0 r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r+ M CO r CO r r+ � [O r CO r CO r [O r n L 7 CO r CO r n [O r [O r n ll") [O r f0 r n lf) [O r [O r r`vo00or`vasvoor--mtovvvtiwa;vvvr+vMvvvti W tovoor.- aOt�vvo O] 2 O] C7 cD N O] ! A (A C7 cD N (A 2 (A C7 cD N CA C 2 C 2 C7 cD N CA CA CA C7 cD N (A (A (A c— C7 N (A (A !M! (7 (7 N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N 418.0 418.3 416.0 410.0 419.3 419.2 405.0 Sample Dates/ Location Figure 2-41. Spatial -temporal distribution of Belews Reservoir specific conductance, 1977 2015. 200 175 150 125 _ 100 U) ZL 75 50 25 Tenr inat on of as ba in dischE rge o lake 4 0 0 20C 7 - 2008 0 19 8 - 00 d oug t rou ht 0 °o°o® ®o 0 °o oo° • • 00 0 0° o0 Q °�O goo ® o® �o 0 a r r m co CO 0 CO rn rn rn rn 0 0 0 0 0 0 o rn rn rn rn rn rn rn rn o 0 0 0 0 0 0 0 r r r r r r r r r � r r N N N N N N N N Sample Date Figure 2-42. Temporal trend in surface specific conductance measured at Belews Reservoir Dam forebay, 1977 — 2015. 2-34 50 !II J M 0 30 U 20 n ' o u' o u2 'MO o ui o u2 u' u� v u' a u2 u' u� o u' o ui ui ui o ui v u� u' u' o u' o u� u" u" o ui c n rn CD 0 0 CDrn rn CD 0 0 o rn rn CD 0 0 CDrn rn CD 0 0 o rn rn o 0 0 CDrn rn CD 0 0 CDrn rn o o C - r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N f� u7 Co r Co r r'- u7 Co r Co r � u1 CO r CO r 1� u7 Co r CO r r- u7 CO r co r r- u1 CO r Co r r- u7 CO r CC -Co Q CD r_.MM CDor_.aoG) CD rCoM CD r__corn000r_.00 rn000rCoa) c 9 0 0 Ci Q N d1 d1 d1 C� O N o) o) o) Ci O N o) d1 d1 Ci O N of of of C� O N 61 61 d1 Q Q N d1 of of C� C - r r N N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N F 418.0 1 418.3 1 416.0 410.0 1 419.3 419.2 405.0 Sample Dates / Location Figure 2-43. Spatial -temporal distribution of Belews Reservoir alkalinity (as mg CaCO3/L), 1977 — 2015. 40 35 30 25 10 5 Tei-mination of a h b sin isc arg to lake 20 7 - 200S 19 8 - 002 rou ht drought 0 O ®- 0 0 T, ® 0 o 00 o 0 0 O O O O p � QO o ©oo 000 O0> 0 0 0 0 0 0 0 00 I* D r__M r CO LO r__CD r CO U ti CD r CD lf] r- Cr) r- r- co e0 co CO CO rn rn M rn a a a a a a2 o2 rn �2 w w o 0 0 0 0 0 0 0 CV N N N N . . N Sample Date Figure 2-44. Temporal trend in surface alkalinity concentrations measured at Belews Reservoir Dam forebay, 1977 — 2015. 2-35 50 40 J 30 C 10 0 T. ; k. ; . 4 � -- T 4 ui u� o u� o u� u� u� v u� v u� u� u� v ui o ui u) ui o u) o a2 uO u0 o '0 o u� u0 u0 o u) v u2 u) u) v u) v u2 m rn o o r r co rn o o r r corn o o r r m M o o r r co m o o r r co m o o r r co m o o r rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 0 r - N N N N - r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N 1+ u7 co r co r I- u) CO r CO r r� u1 CO r CO r 1+ u7 CO r CO r 1� u7 CO r CO r 1� u7 CO r [O r r� co m o 0 o r-- co rn o 0 o r-- co rn o 0 o r` m M o 0 o r-- co M o 0 o r-- co rn o 0 o r-- corn o 0 0 Of 6i 6i Q Q N 61 Q O N 61 61 61 O O N O) 07 07 O c3 N 6i 6i D Q Q N d5 d5 6i O O N 62 6) 61 O O N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N 418.0 418.3 416.0 410.0 419.3 419.2 405.0 4 5 0 Sample Dates/ Location Figure 2-45. Spatial -temporal distribution of Belews Reservoir calcium concentrations, 1977 — 2015. 30 25 20 J 15 10 5 er inat on of ash bas in discharge to lake • 0 °O 199 - 002 2097 - 008 ° di ht • • • � o o °oo °oo 0 00 000 0 0 0 0 0 r__ M r CO rn r-- rn CO rr, r` M CO rn r- M r, rn r- rl- co ea co ca CO rn rn M rn o 0 0 0 0 a� o� CD a� rn � a� a) w a� w w o 0 0 0 0 0 0 0 N N N N CV N N N Sample Date Figure 2-46. Temporal trend in surface calcium concentrations measured at Belews Reservoir Dam forebay, 1977 — 2015. 2-36 ::t 1 0 uiuiouiou�uOuOvu�ou2u� no no nui�n ou�vu2u�u�ou�vu�u�u�vu�v u�uou�ouioui aDMC.C. aornoorrao rnoorrcorn oorraornoorraornoor r'cornoor rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 0 r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N rl- u7 CO r CO r � u) [O r Co r 1'- u7 co r CO r 1+ u1 Co r Co r 1— u7 CO r CO r 1— u) CO r CO r r— u7 CO r CO r r-ma) CDOroorn000r aorn000r__ao rn000r_.aorn000r_.00rnoo or-corn000 M Of Of 0 0 (V 6f 6f 07 Q Q N 6i 07 07 O O N Of 61 6i Q Q N 6i 6i 6i Q O N 61 61 61 O O N 6i Of Of O O N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N 418.0 418.3 416.0 410.0 419.3 419.2 405.0 Sample Dates/ Location Figure 2-47. Spatial -temporal distribution of Belews Reservoir magnesium concentrations, 1977 — 2015. 5_D 4.5 4.0 3.5 3.0 J M 2.5 E 2.0 1.5 1.0 0.5 00 Termination of ash 1pasin dis har a to lake 20 7 - 2 008 1998 - 2002 drought rou ht 0 ♦° ° o 0 0 00 00 00 00 ro 0 0 0 o 00 00 0 0 r__ M M rn r__ M M rr, r` rn M rn r-- M r, rn r- rl- ca oo co ca CO rn rn M rn a a a a a a� o� CD a� rn a� a� w a� w w o 0 0 0 0 0 0 0 N N N N CV N N N Sample Date Figure 2-48. Temporal trend in surface magnesium concentrations measured at Belews Reservoir Dam forebay, 1977 — 2015. 2-37 16 14 12 10 8 4 2 0 ui u) v u) v u2 u� u� v LO v u� un u) v ui v u2 u) ui v ui v u2 LO LO v LO v u� LO LO v u) v u2 u� un v u� v u2 m M v o r r m M v o r r m M v v r r m M v v r r CO M v o r r m M v v r r Cn M v v r rn rn v v o o rn rn v o v v rn rn v v v v 0 rn v v v v rn rn v v o o rn rn v v v v rn rn v v v o r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N 1+ u7 CO r CO r � � 1 CO r CO r P" �11 CO r CO r 1+ u7 CO r CO r r� U7 CO r CO r r� U7 CO r [O r 1- u 1 CO r CO r r- ao rn v v v r` m rn v v v r` m rn v v v r` m rn v v v r~ m M v v v �r- ao M v v v �r- ao rn v v v M M M Cl C7 N CA M M Cl C7 N CA M M C7 C D N CA (A M C7 C7 N CA CA CA C7 C7 N CA CA CA O C , N [A C D [A C7 C , N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N 418.0 418.3 416.0 410.0 419.3 419.2 405.0 Sample Dates/ Location Figure 2-49. Spatial -temporal distribution of Belews Reservoir sodium concentrations, 1977 — 2015. A 9 8 7 6 J 5 E 4 3 2 1 D Tom iinat on of ash bas in disch r e to lake 20D - 008 199 - 002 di ought oug o 0 ° 0 00 00 0 0 00 ° ® • o ® o oQo 4 ® + 0 • • r__ M r M rn r-- M M u, ti M � M rn r-- M r, rn r- CO rn rn rl- co CO co ca M rn a a a a a �2 �2 w w o 0 0 0 0 0 0 0 N N N N CV N N N Sample Date Figure 2-50. Temporal trend in surface sodium concentrations measured at Belews Reservoir Dam forebay, 1977 — 2015. 2-3 8 i'! J 07 4 E 3 2 1 1 1 0 u)u)ou)ou)u7u7ou7ou7u7u7ou7ou7u7u7vuOvuOuOu7vu ouOuOuOou7ou7u7u7ou7ou7 co m o o r r co m o o r r co m o o r r m m o o r r co m o o r r co m o o r r co m o o r rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 0 r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N ti u7 co r co r r'- u7 CO r CO r ti uJ CO r CO r ti U1 CO r CO r 1� U1 CO r CO r r- u7 CO r CO r I- u7 CO r CO r r Co M o 0 o r ao M o 0 o r` co rn o 0 o r__ Co rn o 0 o r Co rn o 0 o r~ m M o 0 o r- m rn o 0 0 6i 6i 6i Q Q N 6i 6i 6i Q O N Of Of Of C O N Of l3) O O (V O Q N 6i 6i 6i Q Q N 6i Of Of O O N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N 418.0 418.3 416.0 410.0 419.3 419.2 405.0 Sample Dates/ Location Figure 2-51. Spatial -temporal distribution of Belews Reservoir potassium concentrations, 1977 — 2015. 8 7 5 5 J 4 E 3 2 1 er inat on of ash basin discharge to lake 19 8 -�002 ruht 20 7 - 2008 drought ® Q o Q � o oQ © o o0 0 0 0° 00 0 0 0 o o° o0 00 0 0 D r__ M r CO u7 r-- (Mr CO rr) r` M r CO rn r- M r, L r- rl- co ea co ca CO a� rn rn M rn a a a a a a� o� CD a) w w o 0 0 0 0 0 0 0 N N N N CV N N N Sample Date Figure 2-52. Temporal trend in surface potassium concentrations measured at Belews Reservoir Dam forebay, 1977 — 2015. 2-39 10 8 J $ rM E Isl i 0 ui u� o u) o u2 u� u7 v u) v u� uM uM v 8 o u2 uM ui o u� o ai u� u� o CD o u� u) M o CD v u� uD u) v CD v `2 m rn o o r r m rn o o r r m rn o o r r m rn o o r r m rn o o r r m rn o o r r m rn o o r rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 0 r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N 1+ u7 CO r CO r � � 1 CO r CO r 1'- u 1 CO r CO r 1+ u7 CO r CO r 1'- u7 CO r CO r 1- u7 CO r (O r 1- u 1 CO r CO r r__ m M o 0 o r m M o 0 o r m M o 0 o r__ M M o 0 o r m M o 0 o r m M o 0 o r- oo rn o 0 0 1A CA CA C7 C7 N [A [A [A CD O N [A [A [A C3 C7 N (A (A (A C3 C7 N CA CA CA Cl C7 N CA CA CA O O N [A CA [A O O N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N 418.0 418.3 416.0 1 410.0 1 419.3 1 419.2 1 405.0 Sample Dates/ Location Figure 2-53. Spatial -temporal distribution of Belews Reservoir chloride concentrations, 1977 — 2015. 12 10 8 J CD 6 E 4 2 er inat on of ash. basin discharge to lake 200 - 2008 19 8 - 002 di ought drought 0 0 0 0 0 o ° o o 0 0 0 0 ® 0 0 0 w 0 00 o 0 0 00 0 � o00 g 00 s a D r__ M r CO rn r__ rn CO rr, r` M CO rn r__ rn c+, rn r- rl- co ea co ca CO rn rn M rn a a a a a 0) CD a� rn � a� � w � w w o 0 0 0 0 0 0 0 N N N N CV CV CA N Sample Date Figure 2-54. Temporal trend in surface chloride concentrations measured at Belews Reservoir Dam forebay, 1977 — 2015. 2-40 180 ( xi i 160 140 120 J 100 80 60 40 20 t_ 0 uiunvu)ouiunu)vnjC wMCDCD rcornoor MI CDCDrnrnooC r r N N N N r r N Ncl 1+u7 CO rEO rr'- n-)COr cc r�MMo0orMMoc Of 6i 61 Ci O N 67 Ci C r r r N N r r r N 418.0 418.3 ui u" v u", o ui LO u� o u7 v ui ui u� v u� v u� ui ui o u� v ui ui ui o u� v u� W m o o r r ao m o o n co m o o r r M m o o r r M m o o r r rn rn o o c:, c:, cD c:, cD cD cD c:, o o r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N 1+ u7 CO r CO r 1+ u7 co r [O r 1+ u7 CO r CO r ti Lo CO r CO r 1+ uJ Co r CO r r__ M rn o 0 o r__ M M o 0 o r` m M o 0 o r__ M M o 0 o r__ M M o 0 0 Of 62 61 O O N Of 67 67 O O N Of 6i 61 Q O N Of Of 6i O O N Of Of 4 Cl CD N r r r N N r r r N N r r r N N r r r N N r r r N N 416.0 1 410.0 1 419.3 1 419.2 1 405.0 Sample Dates/ Location Figure 2-55. Spatial -temporal distribution of Belews Reservoir sulfate concentrations, 1977 — 2015. 50 40 30 J E 20 10 a ti w CO uO ti o) CO LO r a) M Ln r 0) c*� Ln r- r- co m co co co rn m CO M rn o 0 0 0 0 rn a� rn rn rn a� rn 0) rn rn rn rn o 0 0 0 0 0 0 0 r r r r• r r r r• r• !• r r N N N N N N N N Samp#e Date er inat on of ash basin discharge to lake 0 0 0 0 000 0 • O O6� O O ° ® 19 8 -2002 20 7 - #08 oab + rou ht d ou ht o Q'o O O 6 Op O O O + •• Figure 2-56. Temporal trend in surface sulfate concentrations measured at Belews Reservoir Dam forebay, 1977 — 2015. 2-41 8 7 6 5 CO 4 0, E 3 2 1 0 u7 u7 o u) o ui u7 u) o u) o u� u7 u7 o ui o u� u7 un o Lo o ui u7 u) o uo o u2 u7 u7 o uD o u� u7 u� o u) o u� co m o o r r m m o o r r co m o o r r co rn o o r r m m o o r r oo m o o n co m o o r m rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 0 r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r� u7 (o r co r 1+ u) CO r CO r r- u7 CO r (O r r- u) CO r m r r- u) Co r CO r r- u7 CO r m r r- ui) CO r CO r r~ m M o 0 o r__ co M o 0 o r m M o 0 o r m M o 0 o r� m M o 0 o r co rn o 0 o r co rn o 0 0 6i Of 07 O Q N of 07 07 Q Q N of of Of O O (V of 61 Q Q N of of Q O 04 of of of O O N of 6) Q O N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N 418.0 418.3 416.0 410.0 419.3 419.2 405.0 Sample Dates Location Figure 2-57. Spatial -temporal distribution of Belews Reservoir silica (as elemental Si) concentrations, 1977 — 2015. 10 9 8 7 6 J 5 4 3 2 1 Terminat on Of aSh basin disch r e to lake 19 98 - 20022007 - 008 drought ® ®aa m o ® o 0 ao 0 000�o 0 0 o ® � 0 0 °0 8 4 4 0 a r- r- co Co 00 00 co 6r rn M CD rn o 0 0 0 0 rn rn rn rn rn rn rn rn rn rn rn o 0 0 0 0 0 0 0 r r r r• r r r r• r r r r N N N N N N N N Sample Date Figure 2-58. Temporal trend in surface silica (as elemental Si) concentrations measured at Belews Reservoir Dam forebay, 1977 — 2015. 2-42 10 i 0.01 0.001 u7 v u� o ui u7 u7 v u� v u� u7 u7 o u� v u� u� u� o ui o u� u� u� o u� o ui u7 u7 v u� o ui u7 u7 o u0 v u� 0 rn v v r r m rn v o r r m rn o o r r m rn o o r r m rn o v r r m rn v v r r m rn o o r r nrnvvoornrnvoCDCD CD CD CD CD oornrnvvoornrnoovv - r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N u7 CO rCC1 rr� u7 CO rCO rti u7 CO rO rr- u1 CO rto r1-u1 CO rEO r1� u7 CO rCO r1- �s7 CO rCO r M rn v v v r__ M rn O O O r__ T M Q O O rh m rn 0 0 0 r` m rn v v v r m rn v v v r- M M Q O O 9 rn rn O 0 N rn rn rn Q O C 4 rn rn rn Q O C 4 rn rn rn 0 0 N rn rn rn 0 0 N rn rn rn O O N rn rn rn Q O N - r r N N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N 418.0 1 418.3 1 416.0 1 410.0 419.3 1 419.2 1 405.0 Sample Dates/ Location Figure 2-59. Spatial -temporal distribution of Belews Reservoir iron concentrations, 1977 2015. 10 1 0.001 In M O Lo O 42 47 M O Ln O Lo Lo O UJ O� tr) m O m O �iJ 47 U7 On O ccO Ln O U'7 47 m On O m rn O O r r CO rn O O r r m rn 0 O r r m rn O O r r co rn 0 0 r r m rn O O r r m m 0 0 r rn rn o 0 o O rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 0 rn DRCCc r r N N N N -r N N N (V r r N N N N r r N N N N -N (V N 04 r r N N N N r r N N N N ru) (D r (p r r-. m (D r (p r r__ Lo (D r (p r r+ m Co r (p r r-. 47 O r O r r-. � (D r CO r r- 4) CO r (p r n MM0CD r__W rn000n Co M0 CD 1'-0 rn00 Or__COM CD nmrn 00O r- co rn000 rn rn rn O O N rn rn rn O v N rn rn rn O O N rn rn rn v O N rn rn rn v O N rn rn rn O Co N rn rn rn v v N r r r N N r r r N (V r r r N N r r r (V N r r r N N r r r N N r r N N 418.0 418.3 416.0 410.0 419.3 419.2 405.0 Sample Dates/ Location Figure 2-60. Spatial -temporal distribution of Belews Reservoir manganese concentrations, 1977 — 2015. 2-43 14 12 10 8 J E 6 ALI , ----------- 4- 4 0 IT I LO U.) O (n OU.) u-) O (D O (D (n O LO O (D LO O LO O LO LO O {A O Ui 0 O L O {A LO O L O 00 O O O 00 O O O w O O O 00 O O O w O O O 00 O O O 00 O O O CF)o00 o0oa�a�o0oa� o0oa� o0oMMo00 a�CDo0 N N N N N N N N N N N N N N N N N N N N N I- LO O CD r__ (D w CD 1- M (D (D r` LO (D (D r` 0 (D � (D r` M (D � (D r— M CD � (D 1- v a) O O r` 00 a) O O r` 00 O O O r._ 00 a) O O r` 00 M O O r` 00 d) O O � 00 d) O O O W O O O W W d) O O O O O O O W O W O O W O W O O W O W O O O W W O O � � � N N N N � � � N N � � � N N N N N N � � � N N 418.0 418.3 416.0 410.0 419.3 419.2 405.0 Sample Dates / Location Figure 2-61. Spatial -temporal distribution of Belews Reservoir aluminum concentrations, 1977 — 2015. A IC J z r C7 z 0.4 0) E 0_2 0 u7�nvv�nu �nCDu�vu� wMCDCD �aornvvr rn rn v v v v rn rn vvv o r r N N N N r r N N N N r- UD (D r (D r n (1) (D r (D r r-WM CD Or-WMCDCD0 ai a7 a 0 0 04 a7 a7 a7 O O N r r r N N r r r N N 418.0 418.3 lil�, 11� ' �n v u� v ui LO u� v u, omcDcD comcDcD co n rn v v v v rn rn v v v v rn rn v v c - r N N N N r r N N N N r r N N a r (D r 1� �f'J CD r [D r 1� �s7 CD r m - o o M v v v r- M S) v v v r- M M v c 11 O a7 O O N a) O O O O N O a7 a7 O C - r r N N r r r N N r r r N (\ 416.0 1 410.0 1 419.3 Sample Dates/ Location � � � � i � ��I I 7 U-) v 47 v u7 47 �L'1 v u7 v 1 0 M 0 0 r r M O CD CDr n rn CD CDv v rn rn CD CD CD CD- r N N N N r r N N N N - �f7 (D r [D r n 111 [D r CD r -aosvvvr__MG) vv 11 O a7 O O N Of a) 6} O O N - r r N N r r r N N 419.2 1 405.0 Figure 2-62. Spatial -temporal distribution of Belews Reservoir ammonia -nitrogen concentrations, 1977 — 2015. 2-44 Imi 0.4 J z 0.3 0.1 0 wMCD CD na�nwMCDC�C rn rn v v v v rn rn v v C r r N N N N r r N N (\ r� W M r C D r� T M r [C r(n(57000rO)Q7OC CTi (A (37 O O ( -20 C37 (02 O C r r r N N r r r N C\ 418.0 418.3 na nauigaCDu)C 7 M O O r r M M O O r r M M 0 0 r n rn v v CD v rn rn v v CD CDrn rn v CDC - r N N N N r r N N N N r r N N C\ 111 [O r [O r 1+ li1 [O r [O r UJ CO r . mrnvvvr__mrnvvvrmrnvC 9 (3) !02 O O N (A (A (A O O N (A (7f (7f O C - r r N N r r r N N r r r N C\ 416.0 1 410.0 1 419.3 C,'0 '0'0C, �a J M O CD r r M M O O r n rn v v v v rn rn v v v - r N N N N r r N N N U) (O r CO r 1+ U) CO r [O -000) CD r'a0rnvv 9 (3) (A C O N (7f (A 61 O O - r r N N r r r N N 419.2 1 405.0 Sample Dates/ Location Figure 2-63. Spatial -temporal distribution of Belews Reservoir nitrate+nitrite-nitrogen concentrations, 1977 — 2015. 1.2 M xi r m __ 75 1.0 J 0.6 0.4 fflFrMEMENNEENUT �ME������� I IMMENEEMI�������LJ���SSS! 0.0 LO � O U7 O U7 U7 U7 O U7 O U'7 U7 U7 O U) O U'7 U'7 O U'7 O U'7 U'7 U7 O U7 O �f7 U7 U7 O �iJ O �f7 U7 O C I17 ih O O r r [17 ih O O r r [l7 CTi O O r r [7D CA O O r r [37 CA O O r r M M O O r r M M O O r (A to 0 0 0 CD to to 0 0 0 0 CA CA O O O O iT CA O O CO CO CA CA O O CO CO CA CA O O CO CO CA CA O O C r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r- N N N N r r N N n ti U) CO r CO r ti U) CO r W r r'- U7 W r W r ti U7 W r W r r'- U7 W r CO r 1'- U7 CD r CO r ti U) CO r CC r+ M M O O O r+ M M O O O r- w M O O O r+ w M O O O r- w M 0 0 0 n w M 0 0 0 n CA M O C 61 01 61 O O N 01 01 61 O O N CTi CTi CTi S O N (T1 (A (A S O N (A (A (A O O N CA CA CA O O N CA CA (T1 O C r r r N N r r r CV CV r r r CV CV r r r CN CV r r r CN N r r r N N r r r N CC 418.0 1 418.3 1 416.0 1 410.0 1 419.3 1 419.2 1 405.0 Sample Dates/ Location Figure 2-64. Spatial -temporal distribution of Belews Reservoir total nitrogen concentrations, 1977 — 2015. 2-45 1I0i1 ��a J 0.04 31ION 0.02 0.01 �_- 0 u0u)vu)vuiuiuiOL"ou�u.LOvu)vuiuiL.ouiou�u.L.vu�vL unu)ouiouiLOLOOu)ou� m rn v v r r m rn o o r r co rn v v r r m rn o o r r m rn v v r r co rn o o r r Co rn o v r rn rn v v v o rn rn o 0 o cm rn v v v o rn rn o 0 0 o rn rn v v v o rn rn o 0 0 o rn rn o v o 0 r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N h U7 O r O r h U7 O r O r h u7 O r O r h U7 O r O r h u7 O r O r h u1 O r O r h u7 O r O r h TMCO h T M O O O r__ m rn O O O h Co 6] O O O -CO rn O O O h cD rn O O O h OO O] O O O rn rn rn O O N rn rn rn O O N rn rn rn O O N rn rn rn O O N rn rn rn O O N rn rn rn O O N rn rn rn O O N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N 418.0 418.3 416.0 410.0 419.3 419.2 405.0 Sample Dates/ Location Figure 2-65. Spatial -temporal distribution of Belews Reservoir orthophosphate concentrations, 1977 — 2015. 0.16 (K lakirru 03 j ( A u ) 0.14 0.12 0.10 a, 0.08 0.06 0.04 0.02 - T T 4 0.00 �unoLOoLOtotooinou!��oinoininMoinoD MCDMo�Minouno nMMotooM CO rn CD CDr r COrn CD CDr r m rn CD CDr r m rn CD CDr r m rn CD CDr r m rn CD CDr r co rn CD CDr rn rn CD CD0 o rn rn CD 0 o CD rn CD 0 0 o rn rn CD 0 0 CD rn o 0 0 Cs rn o 0 0 C1 rn rn o 0 0 0 N CV N N r r N N N N r r CV CV N N r r N N N N r CV CV N N r r N N N N r r N N N N fM1 U7 CO r (D r h LO (D r (D r h U7 (D r (D r h M O r O r 1, M O r (D r h U7 CO r O r h U) CO r (D r h O rn000h M rn000 h Q7rn 000 h MM CCD0O h00 rn 00O C. rnC, D7 rn000 rn rn rn v v N rn rn rn O O N rn rn rn v v N rn rn rn O O N rn rn rn v v N rn rn rn O O N rn rn rn v v N r r r N N r r r CV N r r r (V (V r r r N r r r N N r r r N N r r r N N 418.0 418.3 416.0 410.0 419.3 419.2 405.0 Sample Dates/ Location Figure 2-66. Spatial -temporal distribution of Belews Reservoir total phosphorus concentrations, 1977 — 2015. 2-46 9 8 7 6 J 5 4 3 2 1 0 u-)u7 ou7vL'flu-)u7o u-) u7u7 u7ou7v�s7 u�uivu� our uiuiou�o uiuiu�v u�ou2 uiu� our oui wm vvrrao rn0 yr rw rnvvrr aornvv rr wmcDcD rmmcD Orr mm 00 r rn rn v v v v rn rn o v v O rn rn v v v v rn rn v v O O rn rn v v v v rn rn v o 0 0 rn rn o o v o r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r u) (O r (O r � u) (O r (O r r- u) (O r (O r r- u) (O r (O r r- uJ (O r (O r r- u 1 (D r CO r r- u 1 CO r CO r rao rnvvvr_. TM vv ors TM CD v rCo8) vo r__aomOO vr__aorn ovo r__M rnv vv O 62 O2 O O 04 O 6i 6i O O N 6i Of Of O O (V 6i Of G O O N Of Of Of C O N Of O O O O N Of 6) 6i O O N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N 418.0 418.3 416.0 410.0 419.3 419.2 405.0 Sample Dates/ Location Figure 2-67. Spatial -temporal distribution of Belews Reservoir total organic carbon concentrations, 1977 — 2015. 150 _ _. • 125 100 F 75 z 50 25 T I 0 z ui u) O u) O u2 u) u) O u) O u� u) ui O ui v u� ui ui O u) O u2 u) u) O u) o u� un un O ui O u2 ui uj O ui O u� m rn o o r r ao rn v v r r CO rn v v r r co m y Orr oo rn v v r r co rn v C. r r m m C. C. r rn rn o o O v rn rn v v v v m m v v v O m m v 0 0 0 rn rn v v O v rn rn v v v v rn rn v v v o r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N n u) CO r (p r r+ u) (O r (p r n u) LD r (p r n u) LO r (p r n (p r (p r n u) (p r (p r n u) LO r (p r tim 6] 000 ti m 61000 tic. m 000 r� D7 OfOOO rim 61000 ti m 61000 I- cc) m 000 m 6i 6i O O N 0 0 0 0 O N O m m O O N dD O7 O7 O O N O] O O O O N 0 0 0 0 O N m m M O O N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N 418.0 418.3 416.0 410.0 419.3 419.2 405.0 Sample Dates/ Location Figure 2-68. Spatial -temporal distribution of Belews Reservoir turbidity, 1977 — 2015. 2-47 70 60 50 40 J E 30 20 10 0 o 00002 m momo�o 0000w�moWo��0000�o �n0002 �n D000� cornoor�mmcDcD mrnOO r�mrncD oom cDC) QDrnoor�mrnOOr rn rn o 0 0 o rn rn O o 0 o rn rn o 0 0 o rn rn 0 0 0 0 rn rn o 0 0 o rn rn o 0 0 o rn rn o 0 0 0 r r N N N N r r N N N CV r r CV CV N N r r N N N N r r CV (V N N r r N N 44 r r CV CV CV CV f� �!) L0 r (0 r t` Ln (0 r (0 f� 4") (0 r L0 r 1- u7 (0 r (0 r f- lI7 (0 r L0 r 1-41 C0 r L0 r f- L!') CO r CO r r-m m 000 r-m rn OOO r-m m Q OO 1-w m OOO r-w m 0001-m rn 000 r-co m OOO rn rn rn O O N rn rn rn O O N rn rn rn O O N rn rn rn O O N rn rn rn O O N rn rn rn O O N rn rn rn ScN r r r N N r r r R N r r r N (V r r r 2 2 r r r N (V r r r N 21 r r r N N 418.0 418.3 416.0 410.0 419.3 419.2 405.0 Sample Dates/ Location Figure 2-69. Spatial -temporal distribution of Belews Reservoir total suspended solids concentrations, 1977 — 2015. 90 ( ald u 3 0 80 70 60 J 50 �l 40 30 20 10 T 7 T Ln In O uO O n Ln Ln O LO o 'Ln Ln M O a) O u� Ln Ln O Ln O n M M O Ln O �n Ln Ln O Ln O n to to O In O u2 m rn O O r r CO rn O o r r m rn O O r r m rn o o r r m rn O o r r 00 rn o Orr 03 rn O O r rn rn 0 0 0 o rn rn o 0 0 0 rn rn O 0 0 o rn rn CRCCrn rn CCCCrn rn o 0 0 o rn rn O 0 0 0 r r N N N N r r N N N N r r N N N N r r N N N N r r N N N (V r r N N N N r r N N N N r- M (0 r (0 r n U7 (0 r (0 r M1 M m r (0 r M1 W) m r (0 r n M (0 r (0 r n Wn (0 r (0 r n 4O W r (0 r 1__m rn 00011_m rn 00011_m rn 0001-m a) CD 1 m rn0001-m rn0001 m rn000 rn rn rn O O N rn rn rn O 0 N rn rn rn O O N rn rn rn 0 0 N rn rn rn O O N rn rn rn 0 0 N rn rn rn O O N r r r N N r r r (V N r r r N N r r r N N r r r N " r r r N N r r r N N 418.0 418.3 416.0 410.0 419.3 419.2 405.0 Sample Dates/ Location Figure 2-70. Spatial -temporal distribution of Belews Reservoir total recoverable arsenic concentrations, 1977 — 2015. J 0) i it.7 %A1] 1.5 1.0 0.5 0.0 u7 u7 O u) v u i u7 u7 O u O O u2 uO u7 o u) v �n '0 un v u i o u2 u7 un o u� o u i u7 u7 v u� o u i u7 a7 O Ln v u� mrnoorrmrnoorrmrnoorrmrnvorrmrnovrrmrnvvrrmmcDcD rnrnooc:,c:, ovrnrn000c:, cD(=, cDcD cDornrnoovv r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N � uj m r m r r u) m r m r l� ui m r m r l� un m r m r r- u) m r co r r- uo m r m r r- ui m r m r ti m M o v v ti m M o v v r_. m rn v v v r m rn v v o r m rn v v v r_. m am v v v r- m a; v v v O2 O2 12 Q O N Of 6i 67 O O N O Of Of O O N 67 O O O O N 6i 61 Of C O N 6i 6i 67 O O N 6i Of 6i Q O N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N r r r N N 418.0 418.3 416.0 410.0 419.3 419.2 405.0 Sample Dates/ Location Figure 2-71. Spatial -temporal distribution of Belews Reservoir total recoverable cadmium concentrations, 1977 — 2015. 30 ,, 20 10 0 w)momommmomoLoLow)oLooLoLotootooLnLoLooLnou3LoLootootofLOoLOoL m rn O O r r m rn 0 Orr ao rn o o r r m rn O O r r m rn o o r r ao a, O O r r m rn o o r rn rn CC0 0 rn rn CC0 o rn rn o 0 0 o rn rn O 0 0 o rn rn o 0 0 o rn rn O 0 0 0 rn rn o 0 0 0 r r cV N N N r r cV N N N r r N N N N r r cV cV N N r r N N N N r r cV cV N N r r N N N N r1 m m r mr r1 m m rm rn u)m r mr rn a)mr mr rn Ln m r m r r-. wn m r mr r-Lnmrmr 1 m 0 0 0 0 n m 0 0 0 0 n m m 0 0 0 1 m 0 0 0 0 r m M D 0 0 n m 07 0 0 0 1— m m 0 0 0 62 61 61 v v N 61 61 61 v 0 CO O O O O N m 61 01 v O N Oi Oi 6i DC N O O 61 v v N 61 6D 6D O O N r r r [V (V r r r N N r r r N N � r r N C' r r r CV CV r r r" 04 r r r N N 418.0 418.3 416.0 410.0 419.3 419.2 405.0 Sample Dates / Location Figure 2-72. Spatial -temporal distribution of Belews Reservoir total recoverable copper recoverable concentrations, 1977 — 2015. 2-49 140 120 100 80 J 60 40 20 ui u7 O u� O u2 u) u7 O ui O u2 ui um O S O u� u7 u7 O ui O u� u� u� O S O ui ui ui O S O u2 M ui O 8 O m rn O o r r m rn o O r r m rn o o r r m rn O O r r m rn o o r r m rn o o r r m rn 0 0 r rn rn 0 0 0 0 rn rn O 0 0 0 rn rn O 0 0 o rn rn O 0 0 0 rn rn O 0 0 0 rn rn O 0 0 0 rn rn 0 0 0 r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N N r r N N N 1+ uJ CO r CO r r'- u7 CO r CO r 1+ O CO r m r r- u7 CO r CO r r- u7 CO r CO r ti uJ CO r CO r r- u7 CO r CO r__ m rn o C D o r m rn o 0 o r__ m rn o C D o r m rn o C D o r m rn o 0 o r__ m rn o 0 o r- m rn o 0 rn rn rn 0 O N rn rn rn O O N rn rn rn O O N rn rn rn 0 0 N rn rn rn O O N rn rn rn O O N rn rn rn 0 0 r - r N N r r r N R. r r r N N r r r N N r r r N N r r r N N r r r N N 418.0 1 418.3 1 416.0 1 410.0 1 419.3 1 419.2 1 405.0 Sample Dates/ Location Figure 2-73. Spatial -temporal distribution of Belews Reservoir total recoverable selenium concentrations, 1977 — 2015. 120 100 60 40 20 OOMM�Mt-D��20 CD MCD OCDc -D 0 rn Oo c NN - N N C, rl- M M r C D r r� M M r C{ n Q7rnO0Or�OCI'0 OC rn rn rn O O N rn rn rn O C r r r N N r r r N n 418.0 1 418.3 7 rn 0 O r r M rn O O r n '0 rn 0 0 0 0 rn rn O O c C, u'7 CO r Cp r r+ u'7 CO r CC M rn 0 0 0 n M rn O C n rn rn O O N rn rn rn O C - r r CV CV r r r N C% 416.0 1 410.0 u7 O u7 O �f'] u7 O u7 O u7 u'7 u7 O u7 O m rn O O r r m rn O O r r m rn O O r rn rn 0 0 CI rn rn O 0 0 Cs rn rn 0 CC r r N N N N r � N N N N r r N N N u7 LO r Cp r f� u7 LO r CO r f� u7 LO r CD n C A rn 0 0 0 n C A rn 0 0 0 r__ C X1 rn 0 0 !r,,-, rn rn O O N rn rn rn O O N rn rn rn 0 0 r r N N r r r N N r r r N N 419.3 1 419.2 1 405.0 Sample Dates/ Location Figure 2-74. Spatial -temporal distribution of Belews Reservoir total recoverable zinc concentrations, 1977 — 2015. 2-50 200 150 c N E =o (n 100 .37 0 V LO C0 1� 00 m O N CO V LO m ti 00 m O N m V L!) C0 f+ cO m O � N Z2 m m 0 0 0 V �f] o0 OD o0 COoD m m m m m m m m m m 0 0 0 0 0 o r rn m m m m rn m m m m rn m rn m rn m o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 r r r r N N. N. N. N. N N N N N N N Location 405.0 (Uplake, Depth = 5 m) ♦ As o As (DL value) ■ Se ❑ Se (DL value) Date Figure 2-75. Arsenic and selenium in surficial fine sediments collected from upper Belews Reservoir, 1984 — 2015. (DL = concentration reported as below detection limit) 200 150 c N E a (n 100 -Tim 0 V LO C0 1� 00 m O N CO V LO m 1- CC) m O N CO ':I-LO C0 I-- oD m O � N CO V� CD CD [O OD 00 00 rn m m m rn m rn m rn m o 0 0 0 0 0 0 0 0 0{ m m m m m m m m m m m m m m m m o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 r r r r r r r N N N N N N N N N N N N N N N N ............. Location 417.1 (Downfake, Depth = 2 to 3 m) ♦ As ,>As (DL value) ■ Se ❑ Se (DL value) ii 2 • lk ■ Date Figure 2-76. Arsenic and selenium in shallow littoral surficial fine sediments collected from lower Belews Reservoir, 1984 — 2015. (DL = concentration reported as below detection limit) 2-51 200 150 c N E =o (n 100 -Tim 0 V LO (0 ti 00 M O N c'i V LO I� 4 N ['7 V �!'] CO ti ap m O N [*] c0 c0 c0 OD c0 CO m 67 M M m M m M M M O O O O O CDC3 CD CD CDr rn rn rn rn rn rn rn M rn rn rn rn rn rn rn rn CD 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 r r r r N N N N N N N N N N N N N N N N Location 417.2 (Downlake, Depth = 5 to 7 m) ♦ As oAs (DL value) ■ Se ❑ Se (DL value) . s i , Date Figure 2-77. Arsenic and selenium in mid -depth surficial fine sediments collected from lower Belews Reservoir, 1984 — 2015. (DL = concentration reported as below detection limit) 200 150 c N E (n 100 -Tim 0 V LO (0 ti 00 M (D N CO V LO (0 ti 00 6) O CV m V L!] CO f+ e0 m O c2 V u2 CD CD [O OD 00 CO rn 6rn rn rn rn 67 rn rn rn rn O O O O O O O O O O{ rn rn rn w w rn rn rn rn rn rn rn rn rn rn o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 r r r r r r r r N N" N" N""" N N N N N N N Location 422.0 ■ (Downlake, Depth = 25 to 30 m) ♦ ♦As ' + oAs (DL value) + • ■ Se + i . ❑ Se (DL value) . ■ ■ . s = + ■ L7 Date Figure 2-78. Arsenic and selenium in deep surficial fine sediments collected from lower Belews Reservoir, 1984 — 2015. (DL = concentration reported as below detection limit) 2-52 CHAPTER 3 MACROINVERTEBRATES INTRODUCTION A benthic macroinvertebrate and plankton monitoring program was implemented in 1984 to monitor and quantify bioaccumulation of selenium in select benthic macroinvertebrates and planktonic organisms in Belews Reservoir. This program was initiated as a result of contamination caused by ash basin effluent from BCSS during the station's early operational years. In 1985, the BCSS ash basin discharge was rerouted from Belews Reservoir to the Dan River. Since that time, contaminant levels in macroinvertebrates and plankton have been used, along with fish community, fish tissue contaminant levels, and Reservoir chemistry data, as indicators of ecological recovery in the Reservoir. An additional aspect of the monitoring program was implemented in 1991 and examined the density and diversity of selected Belews Reservoir macroinvertebrates. MATERIALS AND METHODS Water Quality Beginning in 2005, in conjunction with each macroinvertebrate sampling event, water temperature and dissolved oxygen (DO) were taken just above the sediment at each location using a pre -calibrated YSI Model 55 handheld DO meter. Starting in 2008, DO values were measured in situ using a pre -calibrated Hach®HQ40d water quality meter. Benthic Density and Diversity Monitoring Benthic macroinvertebrate sampling in Belews Reservoir was conducted annually in July of each year from 2011 — 2015. Samples were collected from three locations in Belews Reservoir: Location 405.1 (uplake); Location 410.2 (downlake near the BCSS condenser cooling water discharge canal); and Location 418.1 (downlake in the vicinity of the old BCSS ash basin discharge, Table 1-1 and Figure 1-1). A Ponar dredge was used to collect five replicate bottom 3-1 samples from each location. Samples were collected from two to three meters to bracket the depth of peak benthic abundance (Brinkhurst 1974). Samples were washed in a 500-µm mesh sieve, the retained material placed into jars, preserved individually with 70% ethanol containing rose bengal stain, and returned to the laboratory for analyses. Substrate characterization at each sampling location was based on visual assessment during the sieving process. Organisms were sorted in the laboratory and identified to the lowest practical taxonm. Macroinvertebrate densities (organisms per square meter of bottom area) were calculated proportionally from the mean of the five replicate Ponar grab samples at each site. An assessment of the balanced and indigenous nature of the benthic community was determined by comparing macroinvertebrate densities and taxa abundance among the three sampling locations and with historical data. At the request of NCDENR, Duke Energy began spring monitoring of Hexagenia populations at locations on Belews Reservoir in 2012 and continued that monitoring through 2015. Monitoring was conducted in March or April at the same sampling locations listed above. Five replicates were collected with a Ponar dredge and preserved in 70 % ethanol with rose bengal stain. All Hexagenia were counted in each replicate and numbers among the five replicates were averaged to give a density in No./m2 for each location. Selenium Monitoring Benthic macroinvertebrates (Corbicula and Diptera) were collected once each year in May, while plankton samples were collected each year in September for trace element analyses. Samples were collected from three locations in Belews Reservoir: Locations 405.0, 418.0, and 419.3 (Table 1-1 and Figure 1-1). Benthic macroinvertebrate samples were collected with a 1,000-µm mesh kick net at wadeable depths along the shoreline at each location. Sample sorting was performed in the field. Individual organisms (Corbicula and Diptera) were removed from the sample detritus, grouped as described above in containers, preserved on ice, and returned to the laboratory. Plankton samples (consisting of both phytoplankton and zooplankton) were collected at each location using an 80-µm mesh plankton net. The net was allowed to sink to a depth of three to five meters, pulled to the surface, and towed slowly behind a boat until a plankton sample of sufficient volume was collected. Collected plankton were sieved and blotted, 'From 2001 through 2015 oligochaetes were identified to the lowest possible taxa, whereas in prior years they had been only identified to order (Oligochaeta). 3-2 placed in containers on ice, and transported back to the laboratory. Until 2013, all samples were frozen upon return to the laboratory and remained frozen until their delivery to the Nuclear Services Laboratory at North Carolina State University where they were analyzed for selenium content by neutron activation analysis (NAA). Starting in 2014, whole organism composite samples representing two replicates, whenever possible, were sent to Duke Energy's Environmental Sciences laboratory at New Hill, NC for trace element analysis to determine concentrations (µg/g dry weight) of selenium in selected macroinvertebrate target groups collected in the summer (reference Procedure NR 00107). Selenium concentrations in target organisms were expressed as µg/g wet weight. Selenium bioconcentration data were analyzed graphically by taxon and region. RESULTS AND DISCUSSION Substrate Substrate composition was typically similar at all three locations and was comprised primarily of varying proportions of silt, sand and organic matter (Table 3-1). Silt was the primary constituent on most sampling dates at Locations 405.1 and 410.2, while organic matter was most commonly predominant at Location 418.1. Substrate characteristics may influence benthic macroinvertebrate density and diversity, but with the similarities observed among sampling locations, substantial differences in benthic taxa diversity and density among sites attributable to substrate variation would not be expected. Water Quality Water temperatures observed during sampling from 2011 — 2015 ranged from 27.9 to 34.1 °C (Table 3-2). The lowest temperature each year occurred at Location 405.1, while maximum temperatures were observed at Location 410.2, just below the BCSS discharge. The DO concentrations observed from 2011 — 2015 ranged from 6.67 to 7.90 mg/L (Table 3-2). The highest DOs were most often recorded at Location 405.1, while the lowest concentrations were typically observed at Location 410.2. Benthic Diversity and Density Monitoring 3-3 Benthic taxa abundance from 2011 - 2015 varied by year and location. Taxa numbers appeared slightly less variable than density data (Tables 3-3 through 3-5 and Figure 3-1). Numbers ranged from 17 at Location 405.1 in 2011 to 37 at Location 418.1 in 2012 (Tables 3-3 through 3-5 and Figure 3-1). No clear patterns in taxa abundance were evident from year to year at Locations 410.2 and 418.1. At Location 405.1, taxa abundance increased each year from the five-year minimum in 2011 to the five-year maximum in 2015 (Table 3-3 and Figure 3-1). At Locations 410.2 and 418.1 taxa numbers showed annual variations each year with the five-year maxima observed in 2013 and 2012, respectively (Tables 3-4 and 3-5 and Figure 3-1). The highest numbers of taxa among locations were observed at Location 405.1 from 2013 through 2015, while maxima were observed at Location 418.1 in 2011 and 2012. During the previous five-year study, total taxa numbers ranged from 21 to 39, thus indicating that overall taxa abundance during 2011 - 2015 was somewhat lower than during the last five-year period. Macroinvertebrate densities varied among replicates from 2011 - 2015 and mean densities varied among years and locations. Mean annual densities ranged from 1,325/m2 in 2013 at Location 418.1 to 13,457/m2 in 2011 at Location 410.2 (Table 3-3 and Figure 3-2). Graphical presentation of the last ten years of reported data indicated that mean macroinvertebrate densities were variable and exhibited no clear trends (Figure 3-1). Additionally, variability among replicates was as much as 100%. This type of variability is often common among macroinvertebrate communities in lakes and reservoirs (Duke Energy 2009a, 2010). Comparisons of year to year densities from 2011 - 2015 revealed that the highest mean annual density from Location 405.1 (10,6097/m3) occurred in 2013, while maximum values at Locations 410.2 (13,457/m3) and 418.1 (10,071/m) were observed in 2011 (Tables 3-3 through 3-5 and Figure 3-2). Spatially, densities were highest at Location 405.1 in 2012 and 2013, while Location 410.2 demonstrated the maximum in 2011. Mean macroinvertebrate densities from 2011 - 2015 most often appeared to be higher than during the previous five-year period. Several exceptionally high mean annual densities were reported: specifically at Location 405.1 in 2013, and Locations 410.2 and 418.1 in 2011. These mean annual densities were higher than any reported from these locations since 1991 (Duke Power Company 1996, 2001; Duke Energy 2006, 2011). The record high annual density at Location 405.1 in 2013 was comprised of a very high number of nematodes, while Locations 410.2 and 418.1 in 2011 had exceptionally high numbers of Diptera (Tables 3-3 through 3-5 and Figures 3-3 through 3-5). The causative factors of these high densities and specific compositions is not known. 3-4 Since the substrate at the three Belews Reservoir regions are somewhat similar and past water chemistry and chlorophyll data (Duke Energy 2006, 2011) show greater concentrations of major nutrients and chlorophyll uplake versus downlake, the uplake location (405.1) might be expected to support higher benthic macroinvertebrate densities than the downlake locations (410.2, 418.1). Although Location 405.1 exhibited maximum spatial densities during four of the past five years, macroinvertebrate densities in Belews Reservoir have most frequently exhibited no clear spatial trend from the uplake region (more nutrients) to the oligotrophic downlake regions (Duke Energy 2011). During 2011 — 2015, macroinvertebrate samples were comprised primarily of Oligochaeta and Diptera at all locations. "Others" (primarily nematodes) were dominant at Location 405.1 in 2013 and constituted high proportions of macroinvertebrate densities at Locations 410.2 and 418.1 in 2011 (Tables 3-3 through 3-5 and Figures 3-3 through 3-5). Comparatively high numbers of Corbicula were observed at Location 410.2 in 2013 and Location 418.1 in 2011. Annual mean densities for these groups of organisms varied from year to year, but oligochaetes and dipterans collectively generally dominated collections at all three locations each year. During years prior to 2001, oligochaetes were only identified to Order Oligochaeta. After 2001, oligochaetes were identified to the lowest practicable taxon. Collectively, for the five years 2011 — 2015, the numbers of oligochaete taxa identified by location were: Location 405.1 - 14 taxa, Location 410.2 - 11 taxa, and Location 418.1 - 12 taxa (Tables 3-3 through 3-5). Hexagenia Spring Hexagenia were typically found in comparatively low numbers from 2012 — 2015. Numbers ranged from 0/m2 at Location 418.1 in 2012 to 809/m2 at Location 405.1 in 2015 (Figure 3-6). This represented variability consistent with total densities in Belews Reservoir, as in most reservoirs. The annual average number of spring Hexagenia was highest in 2015 and lowest in 2012. Spatially, Location 405.1 consistently yielded the highest numbers of spring Hexagenia. A comparison of summer and spring Hexagenia populations at Belews Reservoir locations showed that average summer densities were higher than spring densities at Locations 418.1 and 410.2, while spring densities at Location 405.1 were consistently higher than those of the summer periods. This type of distribution clearly showed the considerable variability of both spring and summer Hexagenia populations. Selenium Monitoring 3-5 Selenium detection limits varied from year to year, as well as among sample organisms within a given year. During 2001 — 2005, analyses of the Diptera had been hampered by collections of smaller than optimal biomass, resulting in numerous elevated NAA detection limits (Figure 3-7 and Duke Energy 2006a). Extremely small sample biomass can lead to magnified errors due to analytical interferences (including interferences from not -targeted elements) and result in elevated detection limits (Scott Lassell, Manager of Nuclear Services, North Carolina State University, personal communication). During the 2006 — 2010 reporting period, 16 of 102 sample results from analyses of Corbicula, Diptera, and plankton were reported below detection. Of these, 14 were Diptera samples with two being composed of Corbicula. This was much lower than during the previous report period when 52 dipteran samples were reported below detection (Duke Energy 2011). During the 2011 — 2015 reporting period no samples were below detection limits; however, at Location 405, insufficient biomass of Diptera and Corbicula were collected to get analytical results (Figures 3-7 and 3-8). Whole organism selenium concentrations in macroinvertebrates from the three locations in Belews Reservoir from 2011 — 2015 most often continued to indicate similar or slightly variable concentrations compared to previously reported data (Figures 3-7 through 3-9). Based on data from 1985 to 2004, recent selenium levels appear to have dropped to near background levels. Comparable to historical trends, organisms collected from Location 405.0 generally had the lowest selenium concentrations. Macroinvertebrate selenium concentrations from the Diptera and Corbicula at all locations showed little variability over the past five years as compared to previous data and concentrations at all locations were in the mid to low historical ranges. During 2012 and 2013, Corbicula showed slight increases at Locations 405.0 (2013) and 419.3 (2012 — 2013). Dipterans showed a slight increase in selenium concentrations at Location 419.3 in 2012 and 2013, and at Location 418.0 during 2011 — 2013 (Figures 3-7 through 3-9). Selenium concentrations in plankton during 2011 — 2015 showed some similar spatial trends as Corbicula and Diptera with higher concentrations at Locations 418.0 and 419.3 compared to Location 405 (Figure 3-9). At Location 405.0, concentrations remained very low, while a sharp increase was noted among plankton at Location 419.3 in 2012. At Location 418.0, a less notable increase was also observed in 2012. Compared to 2006 — 2010, overall selenium concentrations in plankton were generally similar. 3-6 QTTAfAfAD17 Belews Reservoir continues to support a diverse macroinvertebrate community Reservoir -wide. Taxa numbers were somewhat lower during 2011 — 2015 than during the previous five-year period, but were within historical ranges. No clear spatial patterns in taxa abundance were evident; however, taxa numbers during 2011 — 2015 were somewhat lower than during the previous five-year period. Total numbers of taxa at Location 405.1 showed annual increases from 2011 through 2015, while annual taxa numbers at Locations 410.2 and 418.1 varied from year to year. Benthic macroinvertebrate densities demonstrated typical spatial and temporal variability. Mean annual densities during 2011 — 2015 were most often higher than during the previous five-year period and several exceptionally high mean densities were reported. All three locations periodically demonstrated higher densities than any recorded at these locations since 1991. Notably high numbers of nematodes (Location 405.1) and dipterans (Locations 410.2 and 418.1) were reported. Macroinvertebrates were comprised primarily of Oligochaeta and Diptera at all locations. "Others", primarily Nematoda, were dominant at Location 405.1 in 2013 and constituted high proportions of densities at other locations. Corbicula were occasionally abundant. Low numbers of Hexagenia were observed during both spring and summer sampling periods. Selenium concentrations in Belews Reservoir macroinvertebrates during 2011 — 2015 continued to indicate low concentrations and variability when compared to results reported much earlier in the study. This would appear to indicate that current levels are at near background concentrations. Comparable to historical trends, macroinvertebrates and plankton collected from Location 405.0 generally had lower selenium concentrations than other locations likely due to its being the far afield from the initial ash basin discharge. Selenium concentrations in macroinvertebrates and plankton from Locations 418.0 and 419.3 showed similar trends, with some fluctuations in the low range during 2011 —2015. The results of this ongoing monitoring program indicate that legacy selenium concentrations in the lentic food web continue to decline or remain stable over time, and that the operation of BCSS is not having a detrimental impact on the macroinvertebrate community of Belews Reservoir. 3-7 Table 3-1. General descriptions of the substrate found at sampling locations in Belews Reservoir during July of 2011 — 2015. Substrates are listed with the most prevalent type first. Organic matter is typically composed of small sticks, leaf and / or grass fragments. Date 405.1 410.2 418.1 silt silt organic sand organic matter 7/21/11 organic matter silt matter sand sand silt silt organic sand sand matter 7/18/12 organic organic silt matter matter sand sand silt organic silt organic matter 7/24/13 organic matter sand matter sand silt sand organic sand silt matter 7/24/14 organic silt matter sand silt sand sand sand organic organic 7/29/15 organic matter matter matter silt silt Table 3-2. Dissolved oxygen (mg/L) concentrations and temperatures (°C) recorded from locations in Belews Reservoir at the times of macroinvertebrate collections. Locations Parameter Date 405.1 410.2 418.1 7/21 /11 27.9 34.1 31.7 7/18/12 30.0 34.1 31.9 Temp. (°C) 7/24/13 27.9 33.5 31.0 7/24/14 28.0 32.5 30.1 7/29/15 30.0 33.5 31.8 7/21 /11 7.90 7.02 7.32 Dissolved 7/19/07 7.78 7.45 7.65 oxygen (mg/L) 7/24/13 7.80 6.96 7.40 7/24/14 6.67 7.31 7.24 7/29/15 7.23 7.01 7.38 3-9 Table 3-3. Densities (No./m2) of macroinvertebrates collected from Location 405.1 from 2006 — 2015. Taxa 2006 2401 2008 2409 MO 2011 2D12 2U13 2014 2015 Annelida Hirundinea Glossi honidae 1-lelobdella sta nalis 465 Oli ochaeta Tubificida Naididae 171 1 1 91 26 Rrcteonais lomondi 17 9 9 Bratislavia bilon ate 17 Hero spp. 43 17 Vero di itata 129 654 198 26 Bero obtuse 17 Hero trifrda 17 9 Was Spp. 9 Was behni ni 9 Nais communis 155 17 9 Nais variabilis 77 207 215 77 Prishna brevisel-a 9 Pnslina phimaseta 9 Fnstirra sima 112 9 9 FWShnella Spp. 9 Prislinella osbomi 43 Stoalia laeustris 103 Tubificidae 740 103 1721 155 198 1533 52 215 Aulodnlus limnnhius 267 808 77 34 26 387 474 }lulodnlus pigueff 293 1,326 370 3,453 611 1033 3039 336 241 8ranchima sowerbyi 52 43 26 52 43 52 103 9 11dribs tem letont 146 umnodrilus hoffineisteri 17 9 9 Potamothrix vejdovs4i 77 Tubifex tubAx 86 34 26 379 Pol chaeta. Sabellida Sabellidae Marrayunlca specxkw 17 9 Arthro oda Insecta Arachnoidea Arrenunrs spp. 9 Col eo era G rinidae Dineutus spp. 9 Diptera Cerato 0 onidae Pal om a-Bezzia cam lex 171 34 261 17 601 103 215 95 60 Chaoboridae Chaoborus Vp. 26 232 26 129 181 77 Chooborus punclipenis 69 Chi ran amid ae-Ch i ron omi n ae Table 3-3. (Continued). 3-10 Taxa 2OOfi 2007 2008 2009 2010 2011 2012 2013 2014 2015 Chironomus spp. 121 77 17 43 129 129 172 17 77 293 Clado elms Vp. 129 276 17 224 34 52 86 9 172 77 Oadotanytarsus spp. 95 608 34 26 207 775 301 319 Gncoto us bicinctus 9 Cfypfochironoinus spp. 60 43 26 34 17 34 52 77 69 cfyptotendipes WP. 310 17 17 43 52 52 146 Cicrotendi es spp. 9 Glyptotendipes spp. 241 1093 Hamischia 9 17 ANcrochironomus Vp. 9 172 9 ANothauma spp. 95 9 26 17 M)othauma bicome 17 Pa astiella spp. 1,877 189 9 439 34 26 129 1257 732 585 Paraclado elms Udine 26 Paralauterbomiella - ni rohalteralis 198 189 34 34 60 9 polypedilum spp. 9 PolypeaYlum halterale 69 482 26 95 164 284 405 69 258 121 PO)yPelfflum scalaenum 17 1641 69 Pseudochironomus spp. 9 17 stem ellina 3pp. 26 9 9 34 17 stictochironomus spp. 43 9 155 60 stictochironomus QrMnctus 17 Tianytarsus spp. 861 947 17 276 1031 26 353 293 207 112 Chironamidae-Orthoc adiinae oicocladius spp. 17 E oicocladius Havens 9 Paraiaiettenella spp. 9 Paraelnocnemus spp. 69 Chironomidae-Tanypodinae Ablabesinyie annulata 121 103 52 9 2151 181 198 43 164 Ablabesmyn2janta 9 Ablabesm a mallochi 26 9 Ablaboamyiia rham he 26 Oinotanypus pinguis 9 codotanypus spp. 121 60 1641 189 267 852 250 26 284 207 Dialmabatrsta pulchra 9 Procladius 629 181 43 387 60 284 568 603 542 250 Tan us Wp. 95 60 17 1343 146 EphemerDpLera Baetidae Centro Blum spp. 9 Caenis yp. 17 E hemerellidae E hemeridae Hexa ema spp. 86 26 26 26 86 121 43 60 129 MegalDptera Sialidae sialis spp. 34 95 146 86 112 491 52 17 95 95 3-11 Table 3-3. (Continued). Taxa 2006 2001 2008 2009 2010 2011 2012 2013 2014 2015 Odonata-Aniso era Gam hidae Gom huS spp. 9 Trichoptera H dro s chidae Gerald s the spp. 95 Hydroptilidae Orthotrichfa spp. 9 LepLoceridae Oecelis spp. 9 17 9 17 26 17 Triaenodes spp. 43 Mollusca Pelecypoda Heterodontida Corbiculidae Gorbicula tiumfma 594 232 121 91 26 9 164 155 34 Unionidae Afeumanfa spp. 34 Veneroida 5 haeriidae sphagnum spp. 9 86 103 60 9 Nematoda 138 1,429 69 267 784 3814 60 Total Density for Year No.fm) 7,588 7,723 1,491 6,174 3,270 5,604 7,913 10,697 4,192 4,704 Total Taxa for Year 39 351 22 31 27 111 291 331 341 35 3-12 Table 3-4. Densities (No./m2) of macroinvertebrates collected from Location 410.2 from 2006 — 2015. Taxa 2i}46 2i}47 2008 2009 201D 2D11 2012 2013 2D14 2015 Annelida Hirudines Glossi homidae Helobdella sta nalis 9 9 Oli ochaeta Branchiobdellida Branchiobdellidae 34 Tubificida Naididae 1T Monais pechnata 26 34 Dero spp. 17 9 9 26 Dero di itata 517 69 Dero tlabdfi er 155 26 Dero Inhda 1989 Dero va a 362 Nais bretscheri 9 Naffs commUnis 9 9 Nais venabilis 112 103 387 17 Pristina ae uiseta 9 Pristina lima 9 9 9 FWstinella osbomi 26 9 Tubificidae 164 250 276 293 138 1369 69 112 60 172 Aulodrilus limnabius 17 52 155 258 Aulodrilus piguati 52 43 341 77 9 Aulodrilus plunsete 1 17 Branchirua sowerb i 129 129 103 60 43 129 172 34 Umnodnlus hottmeisten 9 Pol chaets Sabellida Sabellidae khnayunfda Speciosa 17 43 Arthra oda Acan Insecta Di era Cerato 0 onidae Di9syhelee spp. 34 Pal om ia-Bezzia complex 129 301 1,050 387 7T 3461 52 396 60 Chaoboridae Chaoborus Chi ran amid ae-Gh i ran omi n ae ChironomUs Spp. 9 Clado elrnu 164 60 95 232 9 1188 Ciadotanytersus Spp. 9 9 258 9. 9 3-13 Table 3-4. (Continued). Taxe 2a46 2a47 2448 2D49 2010 2411 2012 2013 2014 2015 DyPtochimnomus spp. 9 69 17 9 86 129 26 60 17 Dyptotendipes spp. 52 86 430 654 52 9 878 69 Dicrotendi es rreomodestus 9 69 43 34 Nilothauma Spp. 9 9 34 f+lilothauma bicome 9 Pa astiella spp. 34 26 138 448 138 17 Paralauterbomiella - ni mholterale 17 17 paratanytarsus Poiypedilurn haltemie 112 26 95 86 439 207 224 17 77 PseudachirorromusVp. 34 26 112 60 250 121 198 Stem ellina spp. 17 52 34 9 34 Stenochirommus Stictochirorromus spp. 26 52 9 103 34 198 Stictochironomus cattranius 9 261 77 Tanytarsus spp. 52 52 17 60 9 9 60 Chi ron amid ae-Orth oc I ad i i n a e cdcoto us spp. 9 Crtcoto us bicinctus 26 Paraiaietteriella 5pp. 26 17 207 26 9 Chi ronomidae-Tan odinae Ablabeamyra Vp. 17 138 43 Ablabesm -a annulata 26 43 17 Ablabesm a janta 17 121 Ablabesmyia mallochi 9 9 9 146 Ablabeamyra ram he gp. 1 341 138 517 77 GOG)Otanypus spp. 86 103 43 121 26 146 232 396 Dialmabatista pulchra 241 34 396 620 594 680 232 52 Labrundinia Procladius yp. 181 267 706 155 %dadius bellus 17 164 121 189 95 Ephemeroptera Baetidae Pseudocentro trloides spp Pseudodoeon spp. 232 69 Caenidae Caerris app. 9 1,455 26 E hemeridae Hexa enia spp. 121 34 164 293 129 654 637 26 301 Megalaptera Sialidae Sialis spp. 9 17 17 Odonata-AnisGptera Corduliidae Neurocorduha Didympps tmnsversa 3-14 Table 3-4. (Continued). Taxe 2a46 2a47 2008 2009 2010 2011 2012 2013 2014 2015 kbcromia SPP. 17 Go-m hidae Gom hus Vp. 9 Odc)nata-ZydDpLera Coena rionidae tschfrrrra spp. 9 Tricha era Hydropblidae ceratopsyche spp. 310 H ro fr)a crthotrrchta spp. 9 Leptoceridae Oecefis spp. 34 9 43 9 62 9 Mollusca Gasta oda Anc cldae Fefrissra spp. 17 P'h sidae Ph se spp. 9 Pelecypoda Hetero-dontids Corbiculidae Corbicule flumirrea 60 611 17 3,702 207 387 1016 732 26 Veneroida 5 haerlldae S heenu.m soe. 26 Nematoda 60 999 17 1,266 2299 77 34 17 Total De nsity for Year No.fm' 1,430 2,507 4,410 7,715 4,067 13,457 2,161 5,312 2,576 3,459 Total Taxa for Year 22 3D 31 27 21 25 15 29 21 26 3-15 Table 3-5. Densities (No./m2) of macroinvertebrates collected from Location 418.1 from 2006 — 2015. Taxes 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 Annelida 17 Hirudines Rh nchobdellida Glossi honiidae Gloiobdells elon ata 9 Hdobdella spp. 9 g Hdobdella sta nabs 7 43 Oli ochaeta Branchiabdellida Branchiobdellidae 112 43 Tubificida 14C Naididae 17 9 Monais pechnata 208 Sratislavia unidentata Dero Spp. 62 27C Dero di itata Dero tlabelli er 189 293 232 g Dero tritida 207 Dero va a 17 91. Naffs eommunis 9 Nais vanuMis 258 129 9 F shm lima 17 26 34 9 F stinella jenfcnae 9 F stinella osbomi 9 Slimna uppendiculata 9 g S aria laeustris 17 Ve-dovs lla somata 17 Tubifiddae 43 771 1211 284 413 1886 362 112 Aulodnlus limnobius 9 Aulodnlus pigueli 9 146 52 568 9 Aulodnlus lurida 0 9 Sothnoneurum veldovskyanuir 9 Sranchinra sowerb 20-1i 155 241 293 215 103 164 138 26 Urnnodrilus hottmeisten 9 9 Tubitex harmani Tubitex tubitex 9 Lumbriculida Lumbriculidae S odnlus herin ianus Pd chaeta 5abellida 5abellidae Uanuyunfau Weciosa 9 26 Arthro oda Crustacea 3-16 Table 3-5. (Continued). Taxa 2aa8 20a7 2aa8 ZDD9 2a1a 2a11 2012 2013 2D14 2a15 Annelida 17 Hirudinea Rh nchobdellida Glossi honiidae Gloiobdells elon eta 9 f {elobdella spp. 9 9 Helobdelle sta nabs 77 43 Oli ochaeta Branchiobdellida Branchiobdellidae 112 43 Tubiflcida 146 Naididae 17 9 Monais pecknate 258 Bratislavia unidentata Dora spp. 52 276 Dero di itata 9 Dero tlabelll er 189 293 232 9 Dero hitida 207 Dero va a 17 9 Nuis communis 9 Nigis venaMis 258 129 9 Pristina lima 17 26 34 9 Pristineha jenpanae 9 FWstrneha osbomi 9 5lavima a endiculata 9 9 aria lecustnz 17 Veidovskyella somata 17 Tubificidae 43 77 121 284 413 1886 362 112 Aulodrilus limnobius 9 Aulodrilus pigueti 9 146 62 668 9 Aulodrilus phifista 0 9 Bothrioneurum voidovskyanum 9 Branchima sowerbyi 250 156 241 293 216 103 164 138 26 Urnnodrilus hot{rneisteri 9 9 Tubitex hammani Tubitex tubitex Lumbriculida Lumbriculidae S odrilus herin ianris Pol chaeta Babellida 5abellidae kfangyunida vociose 9 26 ArthropcFda Cru stare a 3-17 Table 3-5. (Continued). Taxa 2U06 20U7 2DDS 20M 2010 2011 2012 2013 2014 2015 Am hi oda Talitridae Hyalehe arteca 9 103 Insecta Di era Coleoptera Elmidae Cerato 0 onidae Allucaudom is spp. Dasyhelea &pp. 26 P,al om ia-Sezzie complex 198 232 396 336 181 1317 C37 '' 103 Chaoboridae Chaoborus spp. Chiron omid ae-Ch iron omi n a e Chironomus &pp. 60 17 Clado elms 9 9 103 232 26 17 Cladotanytarsus Vp. 9 103 Cricoto us bicinctus 17 clyptochironomus yp. 9 91 17 52 26 77 43 26 9 9 cfyPtotendipas 3pp. 17 601 379 379 112 413 758 17 52 Dicrotendti es spp. 17 Cicrotendti es neomodestus kilothauma spp. 9 26 9 26 pa estiella spp. 172 69 103 96 Paralauterbomiella - ni rohalterale Poiypediium flavum 9 Poiypedilum halterale 77 69 201 52 17 103 198 103 34 polypediium illinoiense 26 Polypedilum walaenum Pseudochirorromus spp. 43 95 17 9 26 stem ellina spp. 17 9 17 17 stictochironomus spp. 69 stictochironomus catfranius 121 207 69 129 stictochironomus spp. 9 Tanytarsus spp. 17 270 9 77 9 52 52 60 77 3f- Trrbelos spp. Chironomidae-Orthocladiinae oicocladius flavens 17 N317ocladius spp. Orthocladius &pp. paraiaiefferiella spp. 17 17 9 ry2 9 9 Chiron omidae-Tan odinae Ablabesm -a Vp. 17 17 Abligbesmyie anmlata 26 1' A blabesmyia janta 224 f;113 34 77 3-18 Figure 3-5. (Continued). Taxa 20D6 2DO7 2DO8 2DO9 2D1D 2D11 2D12 2013 2D14 2D15 Ablabesm a mallochi 103 189 60 60 43 77 103 129 146 9 A blabesmyia ram he gp. 52 491 465 387 694 86 coe)otanypus 17 69 156 172 672 9 Dialmabatista pulchna 9 17 52 34 17 Procladius spp. 267 207 293 181 129 568 1,490 138 387 439 Focladius bellus Ti ulidae Antocha spp. 9 EphemeropteFa Baetidae Pseudocloeon spp. 129 215 Caenidae Caenis spp. 17 26 17 E hemeridae Hexa ema spp. 43 77 43 103 620 482 9 34 Megaloptera 5ialidae Sialis spp. 17 26 9 Odonata-Anisoptera Corduliidae Neumcordulia spp. 17 Macmmiidae 9 Macromia spp- Odonata-ZygopfLera Coena rionidae Argia 9 9 17 17 1=nalla ma spp. 9 Trichoptera H dra s chidae ceratopsyche yp. 189 cheymatopsyche spp f l dro s the venularis Leptaceridae Necto s the spp. 9 Oecetis spp. 34 17 9 43 9 77 129 9 Trianenodes s Pal centro odidae PO)yGentropus spp. 241 17 77 43 f-n Mallusca Gastro Oda Ph sidae Ph sa dpp. 17 26 43 Pulmonata Planorbidae Pelecvlloda Hetero-dontida Corbiculidae Gorbicula fluminea 241 52 1,352 1,197 482 1,162 551 17 3-19 Table 3-5. (Continued). Tam 2DD6 2007 2DD8 2009 2D1D 2D11 2012 2013 2014 2D15 Unionidae 9 Veneroida 5 haeridae 5 haerium spp. 9 Nematoda 138 112 60 336 189 620 77 43 Nemertea Eno la Ha lonemertea Tetra stemmatidae prostoma gfeecens 26 26 77 17 9 Plat helminthes Turbellaria Trcladida Planerdiae Du esfs spp 60 Total Density for Year No.1m 1,834 2,569 4,514 4,582 2,688 10,071 6,322 1,325 1,842 1,618 Total Taxa for Year 22 28 34 34 2-6 28 37 18 26 18 3-20 40 35 30 - 25 0 CO 20 r 75 �2 15 10 5 0 ��#I#I=��#I#����#I#Yid[#I#lti���#7�[#��#�ifi���+�if�►�#7�K��#�i���#�iE� Year/Location Figure 3-1. Total number of taxa collected annually from Locations 405.1, 410.2, and 418.1 from 2006 — 2015. 3-21 12,000 11,000 10.000 9.000 8.000 7,000 6,000 c 5,000 4.000 3,000 2,000 1,000 0 ON 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 Sample Dates/Locations Figure 3-2. Density (No./m2) of macroinvertebrates collected annually from Locations 405.1, 410.2, and 418.1 from 2006 — 2015. 3-22 y f�f 4,500 4.000 3.500 3.000 O Z 2. 500 D 2, 000 O 1,500 1,000 500 0 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 m0figochaeta mDiptera ■Corbicufa o0ther Figure 3-3. Density (No./m2) of Oligochaeta, Diptera, Corbicula, and Others collected annually from Location 405.1 (uplake) from 2006 — 2015. 3-23 5, 000 4,500 4,000 3,500 r 3, 000 tis 2,500 AD 2,000 1,600 1,000 500 0 1� 2006 2007 2008 23�-D 2010 2011 2012 2013 2014 2015 ❑Oligachaeta ❑Diptera ■Corbicula ❑Other Figure 3-4. Density (No./m2) of Oligochaeta, Diptera, Corbicula, and Others collected annually from Location 410.2 (downlake) during 2006 - 2015. 3-24 5,000 4,500 3,500 N E 3, 000 O z �1 2,500 LD .75 2, 000 O 1,500 1,000 500 0 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 ❑ Oligoc haeta ■ ❑i ptera ■ Corbicuia ❑ Other Figure 3-5. Density (No./m2) of Oligochaeta, Diptera, Corbicula, and Others collected annually from Location 418.1 (downlake) during 2006 — 2015. 3-25 9001 ------------------------------------- S00 700 E 6 600 z a� - 500 c a� a 400 a }c a, z 300 Mol*i*] 100 r7 2012 2013 2014 2015 ■405-1 (Summer) ©405.1 (spring) ❑ 410.2 (Summer ❑ 410.2 (Spring) ■ 418-1 (Summer) 0418.1 (Spring) Figure 3-6. Hexagenia densities at locations in Belews Reservoir during summer and spring periods of 2012 — 2015. 3-26 25 20 Location 405 • • • . i. ♦� . x -CT LO m r-- m M O r" M 4 4] m r— m M O r" M-;T L. m r- m C l O r C, M L. mmmmmmmmmmmmmmmmaaaaCDCDC3aaa� OY 0Y O} O} 0Y O} 0Y O} O} 0Y 0Y O} O} 0Y O} O} CD CD d d CD CD d CD CD d d d d d d d 25 20 Location 418 ----------------------------------------------------------------------------------------------------- .♦!� mot• � # * �!! _+! 0 IZrLO mr-- mMCD M�LO ca r-- mM f=3 c��Li co`mmcD' o2'j 2 o� ai rn ai o2 rn rn rn rn rn of o� os ai o� oD d d d d d d d d d d d O 0 0 Q o r r r r r r r r r r r r r r r r c W r c. r c. r r W c. i c. r r W r. i c. r c. i c w c v 25 20 Location 419.3 � � t a V Ln CO r-- m M d- N M V LO CO r-- m M d " M V Ln (O rx m M d LY M V r C rn rn rn rn rn rn rn rn rn rn rn rn rn rn rn rn o o m o 0 0 0 0 0 CD. 0 0 0 C. 0 0 r r r r r r r r r r r r r r r r n... n.. n... n.. n Figure 3-7. Selenium concentrations (µg/g, wet weight) in Diptera collected from three locations in Belews Reservoir during 1984 — 2015. (Red symbols represent value below the indicated detection limit). 3-27 s 5 4 m 3 2 1 Location 405 ff ul SO r— m M O CA CO y 47 SO r- m M CD, CA m 'ET 47 CO r- CDQ] O (V m y 4D m m m m m m rn m m m m m m m m o 0 0 0 0 0 0 0 0 0 rn rn rn rn rn rn rn rn rn rn rn rn rn rn rn o 0 o a o 0 0 0 0 0 o a o o a o cv cw cv cv cv cv cw cv cv cv ri cv cw cv cv cv Location 418 25 24 5 0 v it m M m M o M M v M M o CD cn v Sri m r~ m rn— —— c2 v a. ��mmmmmmmmmmmmmmaoaaaaaaaa� mmmmmmmmmmmmmmmmaoaaaa.......... Location 419.3 25 20 :44 =ss ff v a. m m rn a n cn v ri m r m rn a n cn v ri m r m rn a n n2 v m m m m m m rn rn rn rn rn rn rn rn rn rn o 0 0 0 0 0 0 0 0 0 rn rn rn rn rn rn rn rn rn rn rn rn rn rn rn rn o 0 0 0 0 0 0 0 0 0 0 0 0 0 CD- . .. n n n n n n n n n n . cv cv Figure 3-8. Selenium concentrations (µg/g, wet weight) in Corbicula collected from three locations in Belews Reservoir during 1984 — 2015. (Red symbols represent values below the indicated detection limit). 3-28 5 4 Location 405 ♦ ♦ �[} CO M1 CU C31 C7 N CT1 41 SO M1 DO M CC7 DI DO DO CU CU CU C3] 4] 4] Ol C31 C31 C31 4] 4] 4] 7 C7 C7 O CD C7 C3 C3 C3 CD.4] 4] Ql F! C 2 CA 42 42 O2 C31 C31 C31 4] 4] 4] C7 C7 C7 O O O C3 C3 C3 O O O O C3 C3 C7 � � � � � Cam! Cam! Cam! N N N N N N N N N N N N N Location 418 5 4 ♦ 47 CO M1 m mm C7 ; CY mm -A 4l SO M1 W CR C7 � CN! C�7 � LN CO M1 m 4� O N C2 � 4} Loon Coon m m m rn R rn rn rn rn rn rn rn rn o c- 0 0 - 0 0 c o o t Cn Cn Cn rn rn ar Cn Cn CT, rn rn rn Cn Cn Cn c 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 r r r r r r r r r r r r r r r . . . . . . . . . . . . . . . N Location 419.3 5 ♦ ♦ s # Z ♦ ♦ ♦ + + + s + 4 0 rn CO M1 m M a r n m V rn CO M1 M M a r n c r V rn CO M1 M rn D r n rn V rn MMMMMM rn M M M M M M M M C� o Cj Cj Cj Cj Cj Cj C� C� r C7Y C7Y C7Y C7Y C7Y C7Y C7Y C7Y C7Y C7Y C7Y C7Y C7Y C7Y C7Y CD 4 C7 C3 C3 C7 C3 C3 C D O CD C- C- C- O C7 r r r r r r r r r r r r r r r CV CV " CN CN .... CV CV CV CV CV CV CN Figure 3-9. Selenium concentrations (µg/g, wet weight) in the plankton collected from three locations in Belews Reservoir during 1985 — 2015. (Red symbols represent values below the indicated detection limit). 3-29 47 CO M1 m mm C7 ; CY mm -A 4l SO M1 W CR C7 � CN! C�7 � LN CO M1 m 4� O N C2 � 4} Loon Coon m m m rn R rn rn rn rn rn rn rn rn o c- 0 0 - 0 0 c o o t Cn Cn Cn rn rn ar Cn Cn CT, rn rn rn Cn Cn Cn c 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 r r r r r r r r r r r r r r r . . . . . . . . . . . . . . . N Location 419.3 5 ♦ ♦ s # Z ♦ ♦ ♦ + + + s + 4 0 rn CO M1 m M a r n m V rn CO M1 M M a r n c r V rn CO M1 M rn D r n rn V rn MMMMMM rn M M M M M M M M C� o Cj Cj Cj Cj Cj Cj C� C� r C7Y C7Y C7Y C7Y C7Y C7Y C7Y C7Y C7Y C7Y C7Y C7Y C7Y C7Y C7Y CD 4 C7 C3 C3 C7 C3 C3 C D O CD C- C- C- O C7 r r r r r r r r r r r r r r r CV CV " CN CN .... CV CV CV CV CV CV CN Figure 3-9. Selenium concentrations (µg/g, wet weight) in the plankton collected from three locations in Belews Reservoir during 1985 — 2015. (Red symbols represent values below the indicated detection limit). 3-29 CHAPTER 4 FISH INTRODUCTION The North Carolina Wildlife Resources Commission (NCWRC) and Duke Energy have monitored the fish community in Belews Reservoir since 1972. From 1972 through 1994, taxa diversity and relative abundance were estimated using cove rotenone surveys (Van Horn 1978; Barwick and Harrell 1997). This monitoring was related to a significant decline in fish populations attributed to selenium contamination from the Belews Creek Steam Station (BCSS) ash basin from 1976 through 1985 (Cumbie and Van Horn 1978; Olmsted et al. 1986). Once selenium inputs into the reservoir were eliminated, trace element concentrations in fish tissue gradually declined and the fish community slowly recovered (Barwick and Harrell 1997). Due to this recovery and its associated sport -fish potential, the NCWRC and Duke Energy decided to alter sampling methodology in Belews Reservoir to collect data that were more specific to fish management objectives (and phase out the use of toxicants to sample fish). Thus, spring electrofishing surveys of the reservoir were initiated in 1994, along with a final cove rotenone survey (Duke Power Company 1996). Routine annual monitoring of trace elements in the muscle tissue of multiple fish species was initiated in 1994 with the advent of the spring electrofishing program. This chapter summarizes diversity and relative abundance of littoral fish and selenium concentrations in fish muscle tissue from 1994 through 2015. Collection, analysis, and reporting of contaminant concentrations in fish muscle tissue from the Dan River (receiving water from the rerouted BCSS ash basin discharge) are reported annually elsewhere (Duke Power 2001a, 2002, 2003, 2004, and 2005; Duke Energy 2006b, 2007, 2008, 2009b, 2010a, 2011, 2012, 2013, 2014). 4-1 MATERIALS AND METHODS Spring Electrofishing SurveX Electrofishing surveys were conducted in Belews Reservoir in March or April, 2011 — 2015. Five 300-m shoreline transects, identical to transects historically surveyed since 1994, were surveyed at four regions (Figure 1-1): uplake above the Highway 158 bridge in the vicinity of Location 405.0, midlake between the Highway 65 and 158 bridges in the vicinity of Location 419.2, discharge below Highway 65 in the vicinity of the BCSS thermal discharge and Location 410.2, and downlake in the vicinity of the former BCSS ash basin discharge to Belews Reservoir and Location 418.1. Between 2011 and 2013 all four regions were sampled. Because the Uplake and Midlake regions were very similar in habitat, productivity, and fish metrics (i.e., species composition and biomass) only three of the regions (Midlake, Discharge, and Downlake) were sampled in 2014 and 2015. Transects included habitats representative of those found in Belews Reservoir. Shallow flats where the boat could not access within 3 to 4 m of the shoreline were excluded. All sampling was conducted during daylight, when water temperatures were expected to be between 15 and 20 'C. Surface water temperature (°C) was measured with a calibrated thermistor at each transect. Stunned fish were collected by two netters and identified to species. Fish were enumerated and weighed in aggregate by taxon, except for black basses, where total length (mm) and weight (g) were obtained for each individual collected. Catch per unit effort (number of individuals/1,500 m) and the number of species were calculated for each region. Condition (Wr) based on relative weight was calculated for Largemouth Bass Micropterus salmoides >150 mm long, using the formula Wr = (W/WS) x 100, where W = weight of the individual fish (g) and Ws = length -specific mean weight (g) for a fish as predicted by a weight -length equation for that species (Neumann et. al. 2012). Condition was compared among years and among regions with analysis of covariance (ANCOVA, a = 0.05) and Tukey's pairwise comparison (Analytical Software 2008; SAS 2010). Selenium Monitoring Selenium concentrations were measured in skeletal muscle tissue of Redear Sunfish Lepomis microlophus and Largemouth Bass collected during spring electrofishing at each of four locations, listed from midlake to downlake: 419.4, 419.1, 410.2, and 418.1 (Figure 1-1). Uplake collections at 419.4 were discontinued in 2014 because of similarity to the other Cyd uplake area 419.1. Following the standard operating procedures for fish tissue assessments (NCDENR 2013b), three composite samples (each with three individuals) in 2011, 2012, and 2013 were collected per species at each location such that the total length of the shortest fish was >75% of the total length of the longest fish within each composite. In 2014 and 2015, the same collection procedures above were followed, except for that six fish per species per site were collected. Fish were placed in labeled polyethylene bags and remained on ice until returned to the lab. Once at the lab, they were frozen until processed. Epaxial muscle tissue was extracted from each fish within each composite and placed in an acid -washed polyethylene vial. From 2011 to 2013, Selenium concentration (µg/g, wet weight) was determined from composite samples by neutron activation analysis at the North Carolina State University Nuclear Services Laboratory in Raleigh, NC. From 2014 to 2015, individual fish tissue samples were sent to the Duke Energy's Environmental Sciences laboratory at New Hill, NC for trace elements analyses to determine concentrations (µg/g, dry weight) of selenium. Graphical methods were used to examine temporal and spatial trends of selenium concentration in fish skeletal muscle. RESULTS AND DISCUSSION Spring Electrofishin Sg urveX Potential effects of BCSS on Belews Reservoir fish populations were assessed through annual spring surveys during March or April, 2011 — 2015. A diverse fish community was present from 2011 to 2015 representing 22 species (excluding two hybrid centrarchid species) and 8 families, totaling 16,677 individuals (Tables 4-1 and 4-2). Sunfishes (Centrarchidae = 77.8%), shad (Clupeidae = 11.7%), and minnows (Cyprinidae = 5.6%) numerically dominated catches. The remaining fish families each contributed less than 4% of the total catch as follows: temperate bass (Moronidae = 1.2%), catfish (Ictaluridae = 1.1 %), darters and perch (Percidae = 2.7%), and livebearers (Poeciliidae 0.01 %). A total of 1,267 kg of fish were collected, primarily consisting of minnows (41.0%) and sunfishes (47.2%) (Table 4-3). Catfishes contributed 7.6%, while the remaining fish families each contributed less than 5% of the total biomass as follows: shad (3.4%), temperate bass (1.0%), darters and perch (0.6%), and livebearers (< 0.01%). Alewife Alosa pseudoharengus and Spotted bass Micropterus punctulatus were collected for the first time during the 2011 to 4-3 2015 fish surveys. No threatened or endangered species have been collected during the studies. Mean numbers of fish/1,500 in collected in March or April (2011 — 2015) varied with the highest value observed at the uplake region (2,318), intermediate at the midlake (1,135), and downlake (549) regions, and lowest at the discharge (356) region (Figures 4-1). Mean biomass (kg) of fish/1,500 in collected in March or April (2011 — 2015) varied with the highest value observed at the uplake region (219.2), intermediate at the midlake (64.6) and discharge (32.3) regions, and lowest at the downlake region (25.1) (Figure 4-2). Mean number of species of fish/1,500 in collected in March or April (2011 — 2015) varied with the highest mean value observed at the uplake region (15), intermediate at the midlake (14) and lowest at the downlake (9) and discharge (9) region (Figure 4-3). Fish community metrics were similar at the discharge and downlake regions principally due to BCSS pumping maintaining a circulation pattern within the epilimnion of the two regions (Chapter 1). Data were generally similar to those collected during past study periods (Duke Power Company 1996; Duke Power 2001a; Duke Energy 2006a; Duke Energy 2011). A total of 32 species and two hybrid centrarchid species have been recorded from electrofishing surveys in Belews Reservoir since 1994 (Table 4-1). Variation in the abundance of individual species has long been noted (Van Horn 1978; Duke Power Company 1996; Barwick and Harrell 1997; Duke Power 200lb; Duke Energy 2006a; Duke Energy 2011). Analysis of Belews Reservoir fish collected by Duke Energy since 1994 (77,082 individuals captured from 1994 to 2015) indicates that the three most abundant species are Bluegill Lepomis macrochirus (51.6%), Threadfin Shad Dorosoma petenense (11.7%), and Redbreast Sunfish Lepomis auritus (8.7%). Multiple species (n = 23) constituted less than 1.0% of the total number collected from 1994 to 2015. Once the fish population recovered from selenium contamination, Bluegill were gravimetrically dominant in rotenone surveys from 1991 to 1994 (Barwick and Harrell 1997). Bluegill were also numerically dominant from trammel net and electrofishing surveys from 1974 to 1976 (Van Horn 1978), and in electrofishing surveys since 1994 (Duke Power Company 1996; Duke Power 2001 a; Duke Energy 2006a, 2011). Largemouth Bass condition by year (1994 — 2015) differed significantly (P < 0.0001) with Wr means ranging from 79.8 (1994) to 92.7 (2006) (Figure 4-4). Relative weight means were between 80.0 and 90.0 in most years, 1994 — 1995 and 2004 — 2006 were similarly low (79.7- 79.3) and high (91.0 — 92.7), respectively. Largemouth Bass condition by region also MI differed significantly (P < 0.0001) with means ranging from 81.4 (discharge) to 87.9 (uplake) (Figure 4-5). Although statistically significant, the mean largemouth bass Wr between regions (between 80 and 90) suggest that on average, largemouth bass throughout Belews Reservoir generally exhibit the same body condition. In addition to Largemouth Bass condition values, the number, biomass, and number of species of fish were generally higher uplake relative to downlake. Similar uplake-to- downlake differences were observed for nutrient concentrations of total nitrogen (Figure 2- 64), total phosphorus (Figure 2-66), total organic carbon (Figure 2-67), and total suspended solids (Figure 2-69). These data are consistent with the greater productivity observed uplake relative to downlake, which is more oligotrophic. The observed spatial heterogeneity in fish community metrics in Belews Reservoir is similar to that of other Piedmont reservoirs in North and South Carolina (Duke Energy 2009a, 2010b) and supports the spatial heterogeneity noted by Siler et al. (1986). The authors reported that the number and biomass of fish were higher uplake than downlake due to higher levels of nutrients and resulting higher productivity uplake versus downlake. Other factors that shape the longitudinal heterogeneity pattern (from uplake to downlake) in fish communities in reservoirs are increasing reservoir depth, changing physical habitat, increasing amount of open water, increasing wind exposure, and different species preferences to these patterns (Gido et al 2002). Selenium Monitoring Annual mean selenium concentrations in the muscle tissue of Redear Sunfish (2011 — 2015) and Largemouth Bass (2011 — 2015) collected from Belews Reservoir ranged from 0.83 to 2.96 µg/g (wet weight) and from 0.92 to 2.73 µg/g, respectively (Figures 4-6 and 4-7). Mean selenium concentrations in Redear Sunfish and Largemouth bass were typically lower at locations furthest from the former ash basin discharge (419.4 or 419.1) and highest at locations influenced by the operations of the former ash basin discharge during the early years of BCSS (410.2 or 418.1). Mean selenium concentrations in Redear Sunfish have declined at areas sampled since 1995 and remained consistent in Largemouth Bass since 2007. Concentrations are below levels considered detrimental to fish reproduction (Cumbie and Van Horn 1978; Gillespie and 4-5 Baumann 1986) and well below the 10-µg/g, wet weight, concentration considered safe for human consumption (NCDHH 2O07). SUMMARY Fish survey metrics associated with species composition, catch (number of individuals and species/ 1,500m), and fish heath (Wr's and Se concentrations) represent a self-sustaining balanced and indigenous fish community in Belews Reservoir (2011 — 2015), consistent with previous data since 1994. A total of 22 species, two centrarchid hybrid species, and seven families, dominated by sunfish (Centrarchidae) were collected from 2011-2015. Two new species were collected since 2011. The fish metrics represent sufficient food web organisms and are similar to that of other Piedmont reservoirs in North and South Carolina (Duke Energy 2009a, 2010b) The spatial heterogeneity of Belews Reservoir water quality and fish community metrics is similar to that noted by Siler et al. (1986). Uplake and midlake regions had the highest fish species diversity and catch, likely due to higher relative concentrations of phosphorous, organic carbon, and total suspended solids from watershed inputs (Chapter 2). Conversely, discharge and downlake regions had the lowest fish species diversity and catch, reflective of oligotrophic conditions. Mean selenium concentrations in Redear Sunfish and Largemouth Bass remained below levels considered detrimental to fish reproduction (Cumbie and Van Horn 1978; Gillespie and Baumann 1986) and well below the 10-µg/g, wet weight, concentration considered safe for human consumption (NCDHH 2O07). Belews Reservoir continues to maintain multiple trophic levels of fish, including necessary food web organisms, for a self-sustaining balanced and indigenous fish population. Table 4-1. Pollution tolerance rating, trophic guild of adults, and fish species collected during studies of Belews Reservoir, 1994 — 2015. Total number of species excludes hybrid fishes. Tolerance Troohic guild Duke Power Co. Duke Power Duke Fnemv Duke Fnemv Duke Fnemv Alosa pseudoharengus Alewife Intermediate Insectiwre X Dorosoma cepedianum Gizzard shad Intermediate Insectiwre X X X X X Dorosoma petenense Threadfin shad Intermediate Omniwre X X X X X Cyprinidae Ctenopharyngodon idella Grass carp Tolerant Herbivore X X Cypdnella labrosa Satinfn shiner Tolerant Insectivore X X X X X Cypdnus carpio Common carp Tolerant Omnivore X X X X X Hybognathus regius Eastern silvery minnow Intermediate Herbivore X Lythums ardens Rosefin shiner Intermediate Insectiwre X Notemigonus crysoleucas Golden shiner Tolerant Omnivore X X X X Pimephales promelas Fathead minnow Tolerant Omniwre X Catostomidae Catostomus commersonii White sucker Tolerant Omnivore X X x X Moxostoma collapsum Notchlip redhorse Intermediate Insectivore X X X Moxostoma erythrurum Golden redhorse Intermediate Insectivore X X Ictaluridae Ameiurus brunneus Snail bullhead Intermediate Insectivore X Ameiurus catus White catfish Tolerant Omnivore X X X X X Ameiurus nebulosus Brown bullhead Tolerant Omnivore X X X Ameiurus platycephalus Flat bullhead Tolerant Insectiwre X X X X Ictalurus punctatus Channel catfish Intermediate Omniwre X X X X X Pybdictis olivans Flathead catfish Intermediate Pisciwre X X Poeciliidae Gambusia holbrooki Eastern mosquitofish Tolerant Insectiwre X X X Moronidae Moron americans White perch Intermediate Pisciwre X X X X X Centrarchidae Lepomis auritus Redbreast sunfish Tolerant Insectiwre X X X X X Lepomis cyanellus Green sunfish Tolerant Insectiwre X X X X X Lepomis gibbosus Pumpkinseed Intermediate Insectiwre X X X Lepomis gulosus Warmouth Intermediate Insectiwre X X X X X Lepomis macrochirus Bluegill Intermediate Insectiwre X X X X X Lepomis microlophus Redearsunfish Intermediate Insectiwre X X X X X Lepomis hybrid Hybrid sunfish Tolerant Insectiwre X X X X X Micropterus punctulatus Spotted bass Intermediate Pisciwre X Micropterus salmoides Largemouth bass Intermediate Pisciwre X X X X X Micropterus hybrid Hybrid black bass Intermediate Pisciwre X Pomoxis annularis White crappie Intermediate Pisciwre X X X X X Pomoxis nigromaculatus Black crappie Intermediate Pisciwre X X X X X Percidae Pema flavescens Yellow perch Intermediate Pisciwre X X X X X Total number of species 23 24 24 23 22 4-7 Table 4-2. Species composition by number of electrofishing samples collected from Belews Reservoir, 2011 — 2015. Upstream Downstream Percent Common name Uplake Midlake Discharge Downlake Total composition Clupeidae Alewife 20 20 0.12% Gizzard shad 55 24 4 7 90 0.54% Threadfin shad 1387 451 1,838 11.02% Cyprinidae Grass carp 3 1 4 0.02% Satinfin shiner 360 227 3 148 738 4.43% Common carp 129 32 19 10 190 1.14% Catostomidae White sucker 1 1 0.01% Ictaluridae White catfish 1 1 0.01% Channel catfish 84 78 8 2 172 1.03% Flathead catfish 1 1 2 1 5 0.03% Poeciliidae Eastern mosquitofish 1 1 0.01% Moronidae White perch 189 10 199 1.19% Centrarchidae Redbreast sunfish 2 334 200 477 1,013 6.07% Green sunfish 35 222 19 36 312 1.87% Warmouth 7 14 7 38 66 0.40% Bluegill 3750 3079 878 1536 9,243 55.42% Redear sunfish 100 208 309 103 720 4.32% Hybrid sunfish 4 92 111 199 406 2.43% Spotted bass 1 4 10 15 0.09% Largemouth bass 269 322 186 186 963 5.77% Hybrid black bass 2 2 0.01% White crappie 161 18 179 1.07% Black crappie 37 16 1 54 0.32% Percidae Yellow perch 377 68 445 2.67% Total number of individuals 6,954 5,202 1,778 2,743 16,677 100.00% Total number of soecies 19 19 15 11 22 4-8 Table 4-3. Species composition by biomass (kg) of electrofishing samples collected from Belews Reservoir, 2011 - 2015. Common name Upstream Uplake Midlake Downstream Discharge Downlake Total (kg) Percent composition Clupeidae Alewife 0.15 25.75 2.03% Gizzard shad 13.31 7.40 1.32 3.71 8.51 0.67% Threadfin shad 6.57 1.95 8.51 0.67% Cyprinidae Grass carp 9.94 4.70 14.64 1.16% Satinfin shiner 1.07 0.85 0.01 0.38 2.32 0.18% Common carp 342.97 85.88 48.76 23.56 501.17 39.54% Catostomidae White sucker 0.15 0.15 0.01% Ictaluridae White catfish 1.21 1.21 0.10% Channel catfish 35.90 33.60 7.67 0.88 78.05 6.16% Flathead catfish 16.68 0.21 0.12 0.09 17.10 1.35% Poeciliidae Eastern mosquitofish 0.00 0.00 0.00% Moronidae White perch 11.60 1.14 12.73 1.00% Centrarchidae Redbreast sunfish 0.01 8.89 3.87 8.61 21.38 1.69% Green sunfish 0.42 4.50 0.28 0.55 5.75 0.45% Warmouth 0.05 0.14 0.10 0.56 0.86 0.07% Bluegill 60.76 34.08 6.98 12.94 114.75 9.05% Redear sunfish 10.64 22.49 15.25 6.87 55.24 4.36% Hybrid sunfish 0.07 3.31 3.39 6.95 13.73 1.08% Spotted bass 0.01 1.63 1.19 2.82 0.22% Largemouth bass 105.69 103.38 72.19 60.18 341.44 26.94% Hybrid black bass 0.27 0.27 0.02% White crappie 29.91 3.70 33.60 2.65% Black crappie 4.85 2.68 0.25 7.78 0.61% Percidae Yellow perch 6.85 1.11 7.96 0.63% Total biomass of individuals 657.69 322.85 161.52 125.28 1,267.35 100.00% Total number of species 19 19 15 11 22 4,000 3,500 3,000 E 0 2,500 L a 2,000 z � 1,500 2 LL 1,000 500 0 Year Figure 4-1. Number of fish collected during spring electrofishing, 1994 — 2015, at four Belews Reservoir sampling regions. 400 350 300 E 0 250 �n r 200 Y 150 LL 100 50 0 Year Figure 4-2. Weight (kg) of fish collected during spring electrofishing, 1994 — 2015, at four Belews Reservoir sampling regions. 4-10 25 E 20 0 0 LO r 0 15 z 0 N� o���o� �oaA Q CNo`1�� �Nrb Nl�k`ti��h Year Figure 4-3. Number of fish species collected during spring electrofishing, 1994 — 2015, at four Belews Reservoir sampling regions. 100 95 90 85 80 75 1 9h1 'y000 'l�'LOVE 160h e Ile ILe 11P Ile Ile -01, -0 > -601 'LOP -e .6,h Year Figure 4-4. Mean relative weight (W), with 95% confidence interval, of Largemouth Bass collected in Belews Reservoir 1994 — 2015. Numbers of fish by year are listed above value. 4-11 90 88 86 84 82 80 Uplake Midlake Discharge Downlake Region Figure 4-5. Mean relative weight (Wr), with 95% confidence interval, of Largemouth Bass by Belews Reservoir region, 1994 — 2015. Numbers of fish by region are listed above value. 6.0 419.4 419.1 410.2 418.1 5.0-k------------------------------------------------------------------------------ 1.D 4----- 0 0 t• 00 M a r N M It 0 C0 t< Ca 07 a r N M It 0 M M M M M O O O O O O O O O O r r r r r r r r r r r N N N N N N N N N N N N N N N N Year Figure 4-6. Mean selenium concentrations (wet weight) in Redear Sunfish muscle tissue collected annually from four locations in Belews Reservoir, 1995 — 2015. 4-12 3.5 ----------------------------------------------------------- 419.4 419.1 410.2 —418.1 3.0 -- -------------------------------------------------------- 2.5------- - ---------------------------- ---------- a'2.0 ----- ----- ----------- ------ - ---- ------ 1.5------------------------------- ---------------- 1.0------------------------- --------------------------- 0.5 + M 2007 2008 2009 2010 2011 2012 2013 2014 2015 Year Figure 4-7. 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Raleigh, NC. L-5 North Carolina Department of Environment and Natural Resources (NCDENR). 2005a. Basinwide assessment report: Roanoke River Basin. April 2005. NCDENR, Division of Water Quality. Raleigh, NC. NCDENR. 2005b. National Pollutant Elimination System Permit: Belews Creek Steam Station (Permit No. NC0024406). NCDENR, Division of Water Quality. Raleigh, NC. NCDENR. 2007a. National Pollutant Elimination System Permit: Belews Creek Steam Station (Permit No. NC0024406). NCDENR, Division of Water Quality. Raleigh, NC. NCDENR. 2007b. "Redbook" Surface waters and wetlands standards. NC Administrative Code 15A NCAC 02B .0100, .0200 & .0300, Amended effective May 1, 2007. NCDENR, Division of Water Quality. Raleigh, NC. NCDENR. 2009. National Pollutant Elimination System Permit: Belews Creek Steam Station (Permit No. NC0024406). NCDENR, Division of Water Quality. Raleigh, NC. NCDENR. 2010a. Reservoir & reservoir assessments: Roanoke Basin. Intensive Survey Unit, Division of Water Quality, NCDENR. Raleigh, NC. NCDENR. 2010b. Letter to Ronald E. Lewis, March 9, 2010. NPDES Permit Modification, Permit No. NC0024406, Belews Creek Steam Station, Stokes County. NCDENR. 2012. National Pollutant Elimination System Permit: Belews Creek Steam Station (Permit No. NC0024406). NCDENR, Division of Water Quality. Raleigh, NC. NCDENR 2013a. Standard operating procedure biological monitoring: stream fish community assessment program. North Carolina Department Natural Resources, Division of Water Resources. Raleigh, NC. NCDENR. 2013b. Standard operating procedures fish tissue assessments. North Carolina Department of Environment and Natural Resources, Division of Water Resources, Environmental Services Section, Intensive Survey Branch. December 2013, Version 1.2. Raleigh, NC. North Carolina Department of Health and Human Services (NCDHH). 2007. NC Fish advisory action levels for DDT, DDE, DDD, dioxins, mercury, PCBs, PBDEs, and selenium. April 2007. NCDHH NC Occupational and Environmental Epidemiology Branch. Raleigh, NC. W Olmsted, LL, DJ Degan, JS Carter, and PM Cumbie. 1986. Ash basin effluents as a concern of fisheries managers: A case history and perspective. Pages 261-269 in Hall GE, Van Den Avyle MJ, editors. Reservoir Fisheries Management: Strategies for the 80's. Reservoir Committee, Southern Division American Fisheries Society. Bethesda, MD. SAS Institute Inc. 2010. SAS OnlineDoc89.3. SAS Institute Inc. Cary, NC. Schladow, DG and IH Fisher. 1995. The physical response of temperate lakes to artificial destratification. Limnology and Oceanography 40(2): 359-373. Siler, JR, WJ Foris, and MC Mclnerny. 1986. Spatial heterogeneity in fish parameters within a reservoir. Pages 122-136 in GE Hall and MJ Van Den Avyle, editors. Reservoir Fisheries Management: Strategies for the 80's. Reservoir Committee, Southern Division American Fisheries Society. Bethesda, MD. United States Environmental Protection Agency (USEPA). 1983. Methods for the chemical analysis of water and wastes. Environmental Monitoring and Support Lab, Office of Research and Development. Cincinnati, OH. USEPA. 1994. Methods for the determination of metals in environmental samples. Supplement I. EPA/600/R-94/111. Office of Research and Development, Washington, DC. United States Geological Survey (USGS). 2016. Water resources data, National Water Information System web site: USGS water for North Carolina. (Accessed: 7/5/2016) Web address: http://waterdata.usgs.gov/nc/nwis Van Horn, SL. 1978. Development of the sport fish potential of an industrial cooling lake. North Carolina Wildlife Resources Commission. Federal aid in sport fish restoration, final report, Project F-23. Raleigh, NC. Weiss, CM and EJ Kuenzler. 1976. The trophic state of North Carolina lakes. Department of Environmental Sciences and Engineering, School of Public Health, University of North Carolina at Chapel Hill. Report No. 119. Weiss, CM and TP Anderson. 1978. Belews Reservoir, a summary of a seven year study (Aug 1970 — June 1977) to assess environmental effects of a coal-fired power plant on a cooling pond. Department of Environmental Sciences and Engineering, School of Public Health, University of North Carolina at Chapel Hill. Report No. 475. L-7 Attachment 8 Aerial Photo Future Retention Basin Location August 2016 NPDES application renewal Belews Creek Steam Station NCO024406 �m C—A Z m E—A i i 1 1 2 3 4 5 6 7 8 9 ` h �� a(♦ l; � A, tit \ x�`i ,y*,,. F '+J = %�"�• �*� '7�t ����y� 4 s„ s PIPE CORRIDOR TO OUTFALL 1, HOLDING BASIN ° HOLDING AND RETENTION BASIN CHEMICAL TREATMENT AREA PINE HALL ASH POND CAP UNDERFLOW SUMP r PIPE CORRIDOR FROM PINE HALL ASH POND CAP UNDERFLOW SUMP A 08/23/16 SBP ISSUED FOR OWNER REVIEW o no. I date I by I ckd I description no. I date I by I ckd U 4 Z:\CLIENTS\ENR\DUKEENR\WTRREDIRPROG\88673_BELEWSCREEK\DESIGN\MECH\CADD\SITE LAYOUTS\88673-SKM-173.DWG 8/23/2016 11:12 AM SBPOWERS i RETENTION BASIN fw PIPE CORRIDOR TO HOLDING AND RETENTION BASIN AREA A _ WATER REDIRECTION SUM COAL PILE RUNOFF DISCHARGE PIPING COAL PILE RUNC r �\\✓Jf description 5 6 7 8 Em BURNS N&MMONNELL 9400 WARD PARKWAY KANSAS CITY, MO 64114 816-333-9400 FIRM LICENSE NO. C-1435 9 t—A--� m t—C__� [—D--� TITLE WATER REDIRECTION PROGRAM F SITE LAYOUT GENERAL ARRANGEMENT FOR BELEWS CREEK STEAM STATION U1 &2 DUKE DWG TYPE: DFOTR: SBP ENEnK%.7Y® JOB NO: 88673 CHKD: STOKES COUNTY, NC DATE: 08/23/16 ENGR: FILENAME: 88673-SKM-173.dwg APPD: DWG SIZE DRAWING NO. REVISION ARCH E1 30.0"x42.0" SKM-173 A 10 Attachment 9 Ash Basin Free Water Volume Calculation August 2016 NPDES application renewal Belews Creek Steam Station NCO024406 AECOM Memorandum AECOM 704 522 0330 tel 6000 Fairview Road 704 522 0663 fax Suite 200 Charlotte, NC 28210 www.aecom.com Joyce Dishmon, Sr. Environmental Specialist, CCP To Permitting Page cc Duke Energy— Belews Creek Steam Station Subject NPDES Renewal Support —Ash Basin Capacity Devin Secore, EIT From R. Kula Kulasingam, PhD., PE Date August 17, 2016 Dear Ms. Dishmon, Duke Energy (Duke) requested AECOM to assist in supporting the NPDES Permit renewal for the Belews Creek Steam Station by performing available free water volume estimates for the Active Ash Basin (ash basin). The current NPDES Permit has a requirement at all times a free water volume (FWV) equivalent to the sum of the maximum 24-hour plant discharges plus all stormwater to the pond resulting from a 10-year, 24-hour storm, when using a runoff coefficient of 1.0, be maintained. This report includes required calculations to demonstrate there will be sufficient FWV capacity in the ash basin for ash volume and stormwater runoff for the next 5 years at a water surface elevation of 749.0 ft, which is the lowest water elevation the ash basin currently operates at. To calculate the FWV capacity of the ash basin, Duke provided AECOM with yearly and monthly ash tonnage deposited into the ash basin from 2011- July 2016. AECOM converted this tonnage to volume using a density of 55 Ibs per cubic foot, which is the density used in the previous NPDES permit renewal provided by Duke. Duke also provided the 24-hour plant discharge volume in the dry weather detention of a maximum of 17.9 MGD. Duke added 10% to this flow and converted to acre-feet to get an estimated 24-hour discharge volume of 60.42 acre-feet. The 10-year, 24-hour stormwater runoff volume is calculated by multiplying the ash basin drainage area of 742.6 acres, used in the previous NPDES update, by the 10-year, 24-hour rainfall depth of 5.1 inches. This yields a total stormater runoff of 324.91 acre-feet. The total required FWV was calculated as the sum of the maximum 24-hour plant discharge volume and the 10-year, 24-hour runoff volume, to equal 385.33 acre-feet. The water volume was calculated as 2,972 acre-feet by comparing the 2014 bathymetric surface to a water surface at elevation 749.0 ft in AutoCAD Civil 3D . Figure 1 attached provides this comparison by showing the depth of water in the ash pond. AECOM The table below shows the actual and estimated volume consumed by ash deposited from 2014 through 2021. The reason AECOM chose to start at 2014 was because that is the year when the latest bathymetry was provided. Using data provided by Duke on ash consumption, AECOM was able to estimate the total bottom ash, 730,940 tons, which will be sluiced to the ash basin by December 2021. Fly ash is being handled dry and disposed in a landfill. AECOM understands the FGD waste stream is handled separately in the FGD waste water treatment system. This treated water is assumed to be included in the 17.9 MGD. The coal consumed was estimated from August 2016- December 2021 by averaging the previous years and adding 10% to be conservative. Estimated Actual or Estimated Estimated Total Bottom Ash to Time Period Coal Consumption % Ash' Ash Production Ash Basin (1000's tons) (1000s's tons) (1000's tons)' 2014 4887.66 9.54% 466.28 93.26 2015 4593.14 8.73% 400.98 80.20 Jan 2016 -July 2016 2139.86 10.44% 223.40 44.68 August 2016 -Dec. 1681.32 2016 10.44% 175.53 35.11 2017 4203.29 9.79% 411.40 82.28 2018 4813.95 9.79% 471.17 94.23 2019 5086.96 9.79% 497.89 99.58 2020 5188.70 9.79% 507.84 101.57 2021 5275.18 9.79% 516.31 103.26 TOTAL 37870.05 9.79% 3670.80 734.16 1 Ash production estimated by Duke . ' Duke estimates that 20% of total ash production is bottom ash and sluiced to ash basin . 3 Calculation assumes an in -place density of 55 lbs. per cubic foot to be consistent with previous NPDES permit. Estimated Total Storage Volume Required through 2021 = Ash Basin Storage @ Pond Elevation 749.0' = Estimated Solids to Ash Basin from 2014 - December 2021 Available Storage = Available Storage > Required Storage 385.3 acre-feet 2,972.00 acre-feet 613.00 acre-feet 2,359.22 acre-feet Sufficient Capacity through 2021 Although there are uncertainties in the amount of ash produced/disposed in the ash basin, AECOM believes based on the information provdued by Duke and the calculations presented herein, that adequate FWV can be maintained at the Ash Basin at Belews Creek Steam Station till the end of 2021. AECOM AECOM appreciates this opportunity to be of continued service to Duke Energy, and we ask that you contact us at 704-522-0330 if you have any questions or require additional information. Sincerely, AECOM Kula Kulasingam, PE Project Manager Attachments: Figure 1 Free Water Volume Diagram �L Aw6t,�- Devin Secore, EIT Civil Engineer 2 4 7 8 FIGURE 1 REV. A � � -� \ \\ � NLEGEND )))ASH BASIN WASTE BOUNDARY (APPROXIMATE) EXISTING SITE FEATURE (APPROXIMATE) DUKE ENERGY PROPERTY BOUNDARY \ \ \ 11(i, sue\ ` IMPACT BASIN OUTLET STRUCTURE (OUTFACE 003) � ASH BASIN COMPLIANCE BOUNDARY >\`\ \�Y �- --`I1 �'l EXISTING MINOR CONTOUR (S FT) \ \ll y/'/ '�\ /ll// I/ EXISTING MAJOR CONTOUR (25 FT) • • WETLANDS HDR, 2015 I I / 1 I I �STREAM /l\ I I I 1 \ I / _`\\ \ ° SUITABLE HABITAT NORTHERN LONG-EARED 1 1 / BAT. SMALL WHORLED POGONIA (HDR, 2015) Cj I,/ //1%JI 1 1/ll l Il� 1 i/// /// /�'// j-- -�\1 1 I I \ 1 \ \ - AREAS UNDER WATER DURING THE 2014 BATHYMETRY ///11 l/ \\ �/// 1 ` \ SPILLWAY OUTLET /( // / 1\ \ �� - ////// / / / / •/ • NO BATHYMETRY AVAILABLE A— CONDUIT I / f ul 1° IJI%%ii�\�\ � / / / I,l l\�j�_"!I/(l/�//✓/%/I111 `o//,�h/i// i l // 6-/\�\a\ry\ \ �! / ////- -,`/,or/I/ f \ �ti/�_�-�`� I�IIII \\ \ \\ 1 // / /o I III /J11\ \\1 ll��\\\\ I II '/� p / // I % //� ` �/ /III ♦///�5- ' \.�/j — // / ^\`� \\ •75— / /�/ . \ r1 I I 11 I // / 15 "/ //// ///\olf«J �/ \\_ \\\\\\�\\\)�. ♦ ==s75 _ _= %/ //%'i/// / l / 1 1 ) \\� \ \� \\Q _ 700-- /�I�'//'/I/r %/ /'1/ ! �^\\ '�` �\1`\I \`_ it/ I I\`-'% 1 ^\\ 1 It \\\r, \ ° / 750rr� ♦\- 1 I `�-/� /� \�----- / /1\\ �`\\\\ \�' \ ACTIVE SPILLWAY RISER INTAKEf'/�/r _---_ - __ 11\ '/ / - \ \\ 1 1 FREE WATER DEPTH STRUCTURE �I /' I I!_/ _,- 7zs \�;��/ `\_ _ --_' - _ _ „•/ �� ACTIVE ASH BASIN l/-- _ _ _ OFT WATER DEPTH /— 0 FT TO 10 FT WATER DEPTH B— /i MAIN DAM (STOKE-116) ' _ _ _ r // ' � ' \ 775 yy 10 FT TO 25 FT WATER DEPTH — \� AAA / / I � h^h 125 / /' ~ \ _ \ �oS i l\ �\ i /�' / / / •8 `.... _ ^ \ \ I( 25 FT TO 50 FT WATER DEPTH 50 FT TO 100 FT WATER DEPTH I If 745 1 I 1 \\v ASH BASIN \ 1 lip// 1 /i (APPROX. WATER ELEVATION = 749 FT.) r \ \\�\` \`/ /• I \ 1�v/// y il/ � � 11//• y�/ 1 l /j ii REFERENCE I \ � \ ' -- � — � _ � \ \ � � `/I�" • • Il l / 1/�//� � I % 1. BASIS OF BEARINGS: NC GRID NAD83/2011. ELEVATIONS ARE BASED ON NAV088. /' �V I / / II l I I I 2. THE DUKE ENERGY PROPERTY BOUNDARY, ASH BASIN BOUNDARY, AND ASH / // ryy �35 r�'i'/ l \� \ / ,• II/// ) / j//,// j1 I BASIN COMPLIANCE BOUNDARY PRESENTED IN THIS DRAWING ARE TAKEN FROM "COMPREHENSIVE SITE ASSESSMENT REPORT- BELEWS CREEK STATION ASH C BASIN" PREPARED BY HDR FOR DUKE ENERGY AND SUBMITTED TO NCDEQ PERMIT NO. NCO024406) SEPTEMBER 9, 2015. ,1 3. TOPOGRAPHIC SURVEY WAS PERFORMED BY WSP IN APRIL 2014 AND SUBMITTED I �• ' — _ _ _ 1 I 1 / •� _._..- — -- _ / // ` \ \ \ \ TO DUKE ENERGY IN JULY 2015. THE PLANIMETRIC LOCATION ON THIS MAP IS C ON (/ / / p/ I \ \ \\ \ \ ) ) 20 4EDHE IMAGERY CAPTURED IS MAPPING UPTABLE TO CREATE 1O'LLE00'ESCALE MAPPING m AND CONTOURS D AN INTERVAL 10 ' S AND MEETS THE NATIONAL MAP y ACCURACY STANDARDS FOR 1' = 100' SCALE MAPPING. DATA PROVIDED WHERE 1 1 �/ CLEAR AND VISIBLE ON THE IMAGERY IS WITHIN T OF ITS TRUE POSITION. p 11 r� \/dl �Q / • I / 1 I 111111 —��—__ / r, / /// �—' {1/ / ''• • \ 4. BY ONTOURS SHOWN JUNE 01UNDERWATER ARE FROM BATHMETRIC SURVEY CONDUCTED / l h '� f 1 \� /I / / I \ \\\\ � I)\ If I doll , \ / %%ice' �/ba• _ ( �� / / / / / �'��' / I/ ° / - _ �� / /�l jr / /// // 1 .1./ .If 0 500 1000 If J 1 1 l c ^ I 1 i i ===I Feet TITLE FREE WATER VOLUME DIAGRAM / \ / I j c /// / f / \\ `♦ ��� STOKES COUNTY, NORTH CAROLINA F-034z FOR ISSUED FOR REVIEW \ N.C. ENGINEERING LICENSE NO. SEAL SCALE: 1"=500' DES: DMS —� �� DUKE DWG TYPE:.DWG DFTR: DMS JOB NO: 60432132 CHKD: AW A \ ` ENERGY., DATE: 7-7-16 ENGR: KK l /\ \ \ FILENAME: EXISTING CONDITIONS HEAT DIAGRAM.DWG APPD: KK cbo \\\\\\\ / / \_ I 1 I ///� // ° 1;\1\\11�\\\ DWG DRAWING NO. REVISION zzNSID FIGURE1 \ A a 1 2 3 2 TENTHS 10 20 30 3 4 5 6 1 8 DUKE ENERGY, August 29, 2016 Mr. Jeff Poupart NC Division of Water Resources NPDES Wastewater Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Subject: Duke Energy Carolinas, LLC. Belews Creek Steam Station NPDES Permit No. NCO024406 Stokes County Permit Renewal and Amendment to Pending Major Modification Application Dear Mr. Poupart: 13e1ews Creek Steam Station Duke Energy Carolinas 3195 Pine Hall Road Belews Creek, NC 27009 Duke Energy Carolinas (Duke) requests the subject permit be renewed and reissued. The above referenced permit expires on February 28, 2017. This request is in addition to the currently pending request for modification of the subject NPDES permit dated July 29, 2014. As mandated by North Carolina Administrative Code 15A NCAC 21-1.0105(e), this permit application is being submitted at least 180 days prior to expiration of the current permit. Please find enclosed one signed original and two copies of the NPDES renewal application, which includes the following items: • EPA Form 1; • EPA Form 2C; • Attachment 1 - Site Map showing the location of all Qutfalls (internal and final); • Attachment 2 - Current and Future Waste Flow chart and description of waste Flows through the facility in accordance with EPA Form 2C Item II -A; • Attachment 3 - Narrative description of sources of pollution and treatment technologies in accordance with EPA Form 2C Item II-B; • Attachment 4 - Alternate Schedule Request for 316(b); • Attachment 5 - Alternate Steam Electric Effluent Guidelines (ELG) Schedule Justification; • Attachment 6 - Arsenic, Selenium & Mercury Monitoring in Fish Muscle Tissue from the Dan River, NC: • Attachment 7 - Assessment of Balanced and Indigenous Populations in Belews Reservoir; • Attachment 8 - Aerial Photo Future Retention Basin Location • Attachment 9 - Ash Basin Free Water Volume Calculation Condition A(9) of the current permit requires that Belews Creek Steam Station (BCSS) comply with the Cooling Tower Intake Structure Rule per 40 CFR 125.95- As allowed under 1125.95(ax2), Duke requests an alternate schedule for the submission of the applicable 316(b) information for Belews Creek (Attachment 4 — Alternate Schedule Request for 316(b)). Belews Creek Steam Station NPDES Renewal Application NC0024406 Stokes County August 2016 Page 2 of 5 Condition (12) of the current permit requires BCSS to conduct fish tissue monitoring near ash pond discharge (Outfall 003) once during the permit term and submit the results with the NPDES permit renewal application. The attached report, Attachment 6 Arsenic, Selenium, and Mercury Monitoring in Fish Muscle Tissue from the Dan River, NC, contains fish tissue sampling data collected in 2014. Condition A(15) of the current permit for BCSS requires that Duke request a continuation of the 316(A) thermal variance in accordance with 40 CFR Part 125, Subpart H and Section 122.21(1)(6). The reapplication shall include a basis for continuation such as: 1. The permittee must request the variance be continued. Response: Duke hereby request continuation of the 316(a) variance reflected in the reissued Permit for the Belews Creek Steam Station. 2. Plant operating conditions and load factors are unchanged and are expected to remain so for the term of the reissued permit. Response: BCSS operating conditions and load factors are unchanged and are expected to remain so for the term of the reissued permit. 3. There are no changes to the plant discharges or other discharges in the plant site which could interact with the thermal discharges. Response: There have been no changes to BCSS discharges since the current NPDES permit issuance in 2012. 4. There are no changes to the biotic community of the receiving waterbody which would impact the previous 316 (a) variance determination. Response: As determined by Duke's environmental monitoring, since issuance of the current NPDES permit there have been no changes to the biotic community of Belews Lake which would impact the previous 316(a) determination. The attached report, Attachment 7 - Assessment of Balanced and Indigenous Populations in Belews Reservoir, indicates the continued existence of a healthy aquatic population in Belews Reservoir. Therefore, this report also supports renewal of the current alternate thermal monitoring requirements of Outfall 001. This permit renewal request includes modifications to the treatment system and discharges that will be necessary to comply with recently enacted Iaws and regulations including the Federal Steam Electric Effluent Guidelines (ELG), Federal Coal Combustion Residual (CCR) rule, the North Carolina Coal Ash Management Act of 2014 (LAMA) and HB 630 of 2016. With reissuance of this permit, Duke Energy requests that NCDEQ staff incorporate the following changes in the renewed NPDES permit: I. Duke requests an alternate compliance date for compliance with Steam Electric Effluent Guidelines in accordance with the request found in Attachment 5 - Alternate Steam Electric Guidelines (ELG) Schedule Justification. 2. Duke intends to construct a new, lined retention basin to treat flows currently directed to the active ash basin with the exception of ash sluice wastewater. CAMA and CCR rule will prohibit continued ash sluice wastewater flows to the existing ash basin at BCSS. Projects are underway to convert ash handling of all ash (both bottom and fly ash) to 100% dry handling and disposal systems at BCSS. The newly Belews Creek Steam Station NPDES Renewal Application NCO024406 Stokes County August 2016 Page 3 of 5 constructed retention basin will discharge through Gutfall 003. Duke has included a process flow diagram of the future wastewater flow on the site to help with visualizing these changes (Attachment 2 — Current and Future Flow chart and description of waste flows through the facility). The lined retention basin will be approximately 1 l acres in area and have the capability to have addition of flocculent and pH adjustment chemicals. The retention basin will consist of two basins: primary and secondary. The primary basin is where the majority of any solids settling will occur, while the secondary basin provides adequate retention period for settling of fine particles. Additionally, the retention basin will have a cell where various vacuumed sediments and solids can be decanted prior to disposal of materials into onsite landfill. A holding basin will be constructed for high volume flows such as air heater washes, process washes, etc. The holding basin will be designed for batch processing and will be approximately 7 acres in area. The holding basin will have a chemical feed system for adjusting pH and adding polymer to enhance settling. Treated wastewater wil I be transferred to the primary basin of the retention basin. An emergency overflow will be constructed in the retention basin as a structural safety measure to allow for controlled release in the event of meteorological event in excess of a design storm. It is anticipated that any release from this basin would be very infrequent. Duke requests that the emergency overflow to the existing effluent channel be listed as a contributing flow to outfall 003 as part of the renewal. An aerial photo with planned location of the basin can be found in Attachment S. 3. To comply with Federal ELGs for the bottom ash system, there is an allowance to route the bottom ash sluice water to the FGD system. BCSS will reroute the bottom ash sluice water to the FGD system at a future timeframe. Bottom ash from the boilers will be sluiced to submerged flight conveyors and dewatered, and the ash solids will be Iandfilled. Ash sluicing water will be recirculated in a closed loop system with make-up provided from service water for evaporation and water loss through trucked transport ash moisture. 4. Duke intends to add an ultrafiltration system to the existing FGD wastewater treatment system at a future timeframe to comply with Federal ELGs for FGD wastewater, 5. Duke requests specific authorization that upon ceasing flows to the ash basin, decanting and dewatering of the basin through existing NPDES Outfall 003 can occur. Specific authorization for decanting and dewatering is a condition currently in the NPDES permit at Sutton and Marshall. Duke requests specific authorization that the ash basin may be decanted and dewatered and an explicit statement of the permit limits associated with that activity. A characterization of the ash basin interstitial water has been previously provided July 22, 2015. Decanting and dewatering will ultimately flow to Dan River. 6. BCSS uses an anhydrous ammonia vapor suppression system in case of unintended release of anhydrous ammonia from the six 60,000 gallon anhydrous ammonia tanks. In the event of an emergency operation of the system due to a release of anhydrous ammonia flow from the vapor suppression system will flow to the coal yard sump where it will be pumped to the ash basin and will potentially contain significant concentrations of ammonia. Upon completion of the retention basin, test flows and emergency operation flows will be directed to the retention basin as described in item #2. Vapor suppression system tests are conducted quarterly. Flow rate for Vapor Suppression system maintenance testing will be approximately 172 gallons per minute. Actual flow rate for emergency operation of the vapor suppression will be determined by emergency. Duke requests concurrence in the permit that any impacts associated with the emergency operation of this system do not constitute a violation of the permit. Duke request Belews Creek Steam Station NPDES Renewal Application NCO024406 Stokes County August 2016 Page 4 ofs this flow be added to the list of flows tributary to Outfall 003 and, upon completion, the new retention basin described in item #2 if this submittal. 7. Duke Energy is currently designing an extraction well system to provide accelerated groundwater remediation. The extracted groundwater will be treated prior to discharge through outfall 003. Treatment of the discharge may be provided by introducing the groundwater as a waste stream to the ash basin/retention basin or a new direct groundwater treatment system. 8. Area of Wetness (AOW) Permit coverage Disposition — Duke has previously notified DEQ of, and/or requested permit coverage for AOWs at BCSS, as set out in the following table. Date of Notification/Permit Re uest Affected AOWs July 29, 2014 S-1 to S-1 l October 31, 2014 A to 1, HD-01 to HD-27, Parshall Flume, TF-01 to TF-03 Januag 8, 2106 S-12 to S-14 June 1, 2016 S-14, S-l5 AOWs designated as A to 1, HD-01 to HD-27, TF-01 to TF-03, and the Parshall Flume have been eliminated or consolidated as part of an engineered weighted filter overlay project which flows to outfall 003 via the existing effluent channel (from the point of origin to the point of discharge) established in I984 when the ash basin discharge was rerouted from Belews Reservoir to the Dan River. Duke requests that the conveyances carrying these flows also be deemed effluent channels from their point of origin to the point where they flow into the main effluent channel to the Dan River. Based upon further review, Duke withdraws requests for coverage from areas previously identified at S-01, S-03, S-04 and S-05. This request is based on location of the respective AOW's and/or review of sampling data that confirms the lack of pollutants associated with plant activities being released to Waters of the State from these points. Duke requests that DEQ provide concurrence or acknowledgement of this request in the NPDES Fact Sheet for the permit. Duke requests permit coverage for the remaining AOWs as follows: S-10, S-11 and S-15. All of these points commingle below the ash basin dam at the point identified as S-15. Duke requests effluent channel designation from the point of origin of each of these flows to the point identified as "S-15" on our AOW map where these flows enter the preexisting effluent channel to the Dan River. Consequently, Duke requests that all flows contributing to S-10, S-11 and S-15 be identified in the permit or fact sheet as contributing flows to NPDES Outfall 003. • S-06 and S-12. These two points commingle at the point identified as "S-6". Consequently, Duke requests effluent channel designation from the point of origin of these flows to point where they enter Belews Reservoir. • S-13 and S-14. These two points commingle at the point identified as "S-14". Consequently, Duke requests effluent channel designation from the point of origin of these flows to point where they enter Belews Reservoir. • S-02, S-07, S-08, and S-09. Duke requests effluent channel designation for S-02 from the point of origin to the point where this flow enters the Dan River. Duke requests effluent Belews Creek Steam Station NPDES Pcneaal Application NCO024406 Stokes County August 2016 Page 5 of 5 channel designation for S-07 from the point of origin to the point where this flow enters waters of the State. Duke requests effluent channel designation for S-08 and S-09 from the point of origin to the point where these flows enter Belews Reservoir. Finally, Duke requests notification that this application is complete. Should you have any questions regarding this submittal or require additional information, please contact Joyce Dishmon at 336-623-0238 or email Joyce. D ishmon-d duke-ener=v.com. I certify under penalty of lrnv, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submittingfalse information, including the possibility of fines and imprisonment for knowing violations. Sincerely, Reginald D. Anderson General Manager 111, Regulated Stations Belews Creek Steam Station Power Generating Carolinas East Attachments Cc: NCDEQ cc: Sergei Chernikov Joyce Dishmon, Sr Env Specialist Keeley McCormick, EHS Field Support 11 Please print or type in the unshaded areas only !)ill -in areas are spaced for elite tvoe. Le.. 12 characterslnch). For Approved OMB No. 2040-0086. Approval expires 5-31-92 FORM U.S. ENVIRONMENTAL PROTECTION AGENCY I. EPA I.D. NUMBER GENERAL INFORMATION S PA NCDOQ0856591 T1A J F Consolidated Permits Program GENERAL (Read the "General 1namcdons" before starting.) 1 2 13 14 is LABEL ITEMS GENERAL INSTRUCTIONS I. EPA I.D. NUMBER If a printed label has been provided, affix ilIn the des�r�led race. Review the Information carB-ha noted il�any of it is through rotted clai m tt fill-in area III. FACILITY NAME ropriate below. Also, if any of �r a ted data is absent area to the to of the label V. FACILITY PLEASE PLACE LABEL space the Mforrrfatlon that shoulld IN THIS SPACE appear] provide It In the proper MAILING LIST LIST In area js . If the label Is taro� to and , you need not ate Rems I, III, V, and VI(except VI-B whkh must be completed ragarrilessp). all items VI. FACILITY �Complete ns�trtflabel Refer tohe esrp LOCATION for detailed ricer t and for the legal authorization under which this data is colet:led. IL POLLUTANT CHARACTERISTICS IIIIIIIII Complete A " J to determine whether you need to s any permit applicatlan to the A i you answer yes" to at questions, you must submit this form and the supplemental from listed In the fallowing the Mark W In the box in the third column if "no" parenttresis question. "no" the supplemental form Is attached. If you answer to each question, you need not submit a of these forms. You may answer If your activity is excluded from permit irements see Section C of the Instructions See also Section D of the Ensbuct(ons for definitions of bold-faced terms. SPECIFIC QUESTIONS SPECIFIC QUESTIONS X MNO K"XFORM FORM YES NO ATTACHED YE ATTACHED A. s this c a pu c y awns which rasu in a discharge to waters of the U.S.? 2A) ❑ ® ❑ s or i ex erg or a J include a concentrated nimal ❑ ® ❑ (FORM reeding oppeeration or aquatic animal a discharge on faellii y wof the ?hkh (FORM 2B) 1a 17 t9 t9 20 21 s this facility which cuffenOy results n discharges to waters of the U.S. other than s this Proposal faciiii aMar 60-00—se In A or S above) wh wIH result in a discharge those desrlibad in A or 8 above? FORM 2C 22 23 24 to waters of the U.S.? FORM 201 25 20 27 s or will this facillity teat. store, or pose hazardous wastes? (FORM 3) ❑ ® ❑ F Do you or will you Inpa at this faclity industrialor municipal effluent below the lowermost stratum ❑ ® ❑ containingwithin one quarter mile of the well bore underground sources of drinking water? M 4 29 29 30(FOR 31 32 33 you or you it this facility any produced water other ffu which are brought to h Doyou or you at u I processes such as m1hirrg suffer by the the surface In connection with conventional oil or ❑ ® ❑ rasclt process solution mining of minerals, In ❑ ® ❑ natural gas production. Injed fluids used for situ combustion of fossil fuel, or recovery of Auld nced ve ry of for storage oil of quidnatural gas or inject hydrocarbons? geathemud energy? (FORM 4) FORM 4 34 35 38 37 1 39 39 s fts facility a 5roposed stationary source which is the 28 Industrial listed j Is this facilSyr a pro eta nary aourca is NOT the 28 Industrial one of categories In the Instructions and will emit ❑ ® ❑ which one of categories listed In the instructions ❑ ® ❑ which potentially 100 tons per year of any air po0ulant reguleted and which will potentially emit 250 tons per year of any air pollutant under Iha Clean Air Act and may affect or be regulated under" Clean Air Act and may affect located in an attainment area? FORM 5) 1-40-1 41 1 42 or be located 1n an attainment an? FORM 43 44 45 Ill. NAME OF FACILITY SKIP I Belews Creek Steam Station 1 15 1 15--9 1 30 a9 IV. FACILITY CONTACT A. NAME & TITLE(last, first & tide B. PHONE laree code & no. Keeley McCormick, EHS Professional 1! 336 445 0204 2 15 16 45 4a 49 1 1 49 51 1 1 52 55 V. FACILITY MAILING ADDRESS A. STREET OR P.O. BOX 9 3195 Pine Hall Road 15 18 45 B. CITY OR TOWN I C STATE D ZIP CODE Belews Creek NC 27009 a 15 1a � -- 40 1 41 42 1 47 51 Vl. FACILITY LOCATION A. STREET ROUTE NO. OR OTHER SPECIFIC IDENTIFIER 3195 Pine Hall Road s is 1a 45 B. COUNTY NAME Stokes 46 70 C. CITY OR TOWN D STATE E. ZIP CODE I F. CQUINTY CODE Belews Creek NC 27009 034 147 $ 15 18 40 1 51 1 a 54 EPA FORI13510.1 (8-90) CONTINUED ON REVERSE CONTINUED FROM THE FRONT VII. SIC CODES 4-di ' in orderof ri A. FIRST B. SECOND c 4911 (specify) Electric Services 7 s (specify) s 16 17 16 to C THIRD D. FOURTH c (specify) (specify) 15 16 17 1 15 1 15 Ta Vlll. OPERATOR INFORMATION A. NAME I B. Is the name [Wed In Item Duke Energy Carolinas, LLC VIII-A also the owner? S ® YES [:]NO 1 to 55 C. STATUS OF OPERATOR EnW ft approodate btterinto the enswerbox if "Other" D. PHONE area code & no. F = FEDERAL M = PUBLIC (other than federal orstate) P (specify) 336 0204 S = STATE O = OTHER (specify) Electric Utility A �flg�21 122 Sd 16 18 25 P = PRIVATE t5 E STREET OR PO BOX 3195 Pine Hall Road 26 56 F. CITY OR TOWN G STATE H ZIP CODE IX. INDIAN LAND Belews Creek NC 27009 Is the facility located an Indian lands? 1 42 42 47 st ❑ YES ® NO B is t6 40 X. EXISTING ENVIRONMENTAL PERMITS A NPDES Oischa s to Surface Wated D PSD Air Emissions from Prolmed Sources 9 ° 01983T25, Non-PSD, Air 9 N ' NCO024406 1s t6 1 17 1 1a 30 ,5 ,e n 19 30 B. IC Unde round Inischlion ofRulds E OTHER s (Specify) ° 85-03,85-04,85-05 Industrial Landfill 9 1 16 17 t8 30 TU ' 9 15 16 1T t8 30 C. RCRA Hazardous Wastes E OTHER s (Specify) 9 ' NCDO00856591 T ° WQ0000452 Distribution of residual 9 15 16 17 t8 30 15 16 17 13 30 Solids XI. MAP Attach to this application a topographic map of the area extending to at least one mile beyond property boundaries. The map must show the outline of the facility, the location of each of its existing and proposed intake and discharge structures, each of Its hazardous waste treatment, storage, or disposal facilities, and each well where it injects fluids underground Include all springs. rivers and other surface water bodles in the map area. See instructions for precise requirements. Xli. NATURE OF BUSINESS(provide a brief descri tfon Coal Fired Electric Generation XIII. CERTIFICATION see instnictions l certify under penalty of law that l have personally examined and am familiar with the (nfomration submitted in this application and all attachments and that based on my inquiry of those persons immediately responsible far obtaining the information contained in the application, l believe that the information is true, accurate and eamplete I r aware that there are significant penalties for submitting false information, including the ssibof fine and imprisonmente A. NAME & OFFICIAL TITLE (type or print) B. SIG IkTORE C. DATE SIGNED Reginald D. Anderson, GM-111, Regulated Stations p COMMENTS FOR OFFICIAL USE ONLY C 15 16 55 EPA FORM 3510-1 18-90) EPA I D NUMBER (rnpyfrom Item 1 of Form 1) Form Approved. NCDO00856591 OMB No 2040-0086. Please print or type in the unshaded areas only Approval expires 3-31-98 FORM U S ENVIRONMENTAL PROTECTION AGENCY FOR PERMIT TO DISCHARGE WASTEWATER 2C EPA EXISTING MANUFACTURING," IS/COMMERCIAL, MINING AND SILVICULTURE OPERATIONS NPOES Consolidated Permits Program i. OUTFALL LOCATION For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A. OUTFALL NUMBER (list) B LATITUDE C. LONGITUDE 0. RECEIVING WATER (name) t DEG. 2. MIN. 3. SEC. 1. DEG 22 M:N. 3, SEC C01 36 16 49.5 80 03 39.8 Belews Lake CO3 36 18 22.0 80 04 50.7 Dan River via Effluent Channel CO2 36 17 8.0 80 03 53.8 Ash Basin (Internal Outfall) :I. FLOWS. SOURCES OF POLLUTION. AND TREATMENT TECHNOLOGIES A. Attach a line drawing showing the water flow through the facility Indicate sources of Intake water operations contributing wastewater to the effluent, and treatment units labeled to cotsespand to the more detailed descriptions in Item B Construct a water balance on the line drawing by showing average flows between .ntakes. operations treatment units, and outfalls. If a water balance cannot be determined (e.g. lbr certain mining acbWhes), provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures. B. For each outfall, provide a description of- (1) All operations contributing wastewater to the effluent Indud ng process wastewater, sanitary wastewater, cooling water and storm water runoff, (2) The average flow contributed by each operation and (3) The treatment received by the wastewater Continue on additional sheets if necessary. 1. OUT- 2. OPERATION(S) CONTRIBUTING FLOW 3. TREATMENT FALL NO. (list) a. OPERATION (L.u) b AVERAGE FLOW (include units) a. DESCRIPTION b. LIST CODES FROM TABLE 2C-1 J4 l Once Through Cooling Water Discharge to %urf"e water 4A Miscellaneous Equipment 127E MM Non -Contact Cooling Water 003 Asti Settling Pond 9 MOD Coagulation, Sedimentation, Neutralization, 2D 1U Discharge from Storm Drain Ion Exchange, Surface water Dischazrge 2A ZJ Retention Basin (Future Usel 9A 002 Flue Gas Desulfurization Wastewater D 7 MGD Sedimentation to 2rC fInternal outfall) Coagulation. Chemical Precipitation 2L Reduction, Neutralization 3C Belt Filtration, Landfill sc s0 Ultrafiltration (Future) OFFICIAL USE ONLY(effluent gWtdelmessub-categenes) EPA Form 3510-2C (8-90) PAGE 1 of 4 CONTINUE ON REVERSE CONTINUED FROM THE FRONT C Except for storm runoff, leaks. or spills are any of the discharges described in Items Il-A or 8 intermittent or seasonal? ❑ YES (rnmplere the fallvwtng table) m NO (b to s wa.111) 3 FREQUENCY 4. FLOW a DAYS PER B. TOTAL VOLUME 2 OPERATION(S WEEK b. MONTHS a. FLOW RATE (in mg!) (1peri). with meat) 1 OUTFALL CONTRIBUTING FLOW (rpeeh PER YEAR C DURATION 1 LONGTERM 2, MAXIMUM 1 LONGTERM 2 MAXIMUM NUMBER (hit) (het) amrmgc) (ipecifymemgri AVERAGE DAILY AVERAGE DAILY (Ind. 3) III PRODUCTION A. Does an effluent guideline limitation promulgated by EPA under Section 304 of the Clean Water Act apply to your facility? ® YES (complete Item Ill.0) ❑ NO (ga to Section 1l1) 8 Are the limitations in the applicable effluent guideline expressed in terms of production (or other measure of operatioon)? ❑ YES (complete Item I/1-0 ® NO (V to Section III) C If you answered "yes' to Item III-B, list the quantity which represents an actual measurement of your level of production, expressed in the terms and units used in the applicable effluent guideline and indicate the affected outfalls 1 AVERAGE DAILY PRODUCTION 2. AFFECTED OUTFACES lint out all number. ) ( f a QUANTITY PER DAY b. UNITS OF MEASURE c. OPERATION. PRODUCT. MATERIAL, ETC. (rl -tfy) IV IMPROVEMENTS A. Are you now requited by any Federal, State or local authority to meet any implementation schedule for the construction, upgrading or operations of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this apppication? This includes, but is not limited to, permit conditions, administrative or enforcement orders enforcement compliance schedule letters, stipulations court orders, and grant or loan conditions, ® YES (complete the follrnreng table) ❑ NO (Xu la !fern IV-B) 1. IDENTIFICATION OF CONDITION, 2. AFFECTED OUTFALLS 3 BRIEF DESCRIPTION OF PROJECT 4• FINAL COMPLIANCE DATE AGREEMENT, ETC a NO b, SOURCE OF DISCHARGE a. REQUIRED b, PROJECTED North Carolina Coal Ash 003 Ash Sluice The act requires closure of ash basin. 5/17123 5/17/23 Management Act of 2014 B. OPTIONAL: You may attach additional sheets describing any additional water pollution control programs (or other environmental projects which may affect your discharges) you now have underway or which you plan. Indicate whether each program Is now underway or planned, and indicate your actual or planned schedules for construction. ❑ MARK -X' IF DESCRIPTION OF ADDITIONAL CONTROL PROGRAMS IS ATTACHED EPA Form 3510-2C (8-90) PAGE 2 of 4 CONTINUE ON PAGE 3 EPA I D NUMBER {copy -from Item 1 ofxorm I) CONTINUED FROM PAGE 2 Nct)000856591 V INTAKE AND EFFLUENT CHARACTERISTICS A, B, & C See -nstructions before proceeding —Complete one set of tables for each outfall —Annotate the outfall number In the spare provided NOTE Tables VA V-B and V-C are included on separate sheets numbered V-1 through V-9 D. Use the space below to lost any of the pollutants listed In Table 2r-3 of the Instructions which you know or have reason to believe is discharged or may be discharged from any outfall For every pollutant you list. briefly describe the reasons you believe it to be present and report any analytical data in your possession 1 POLLUTANT 2 SOURCE 1 POLLUTANT 2 SOURCE Asbestos Trace amount in insulation, wire coatings, and harnesses. Trace amounts may be washed down drains in plant area during maintenance activities. Str nt um Trace elements occasionally Ura ium found in coal. Van ..ium Zir on um VI POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS Is any pollutant listed in hem V-C a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? ® YES (list.11.ruch pulbremu /Wou, ) ❑ NO (Inv m lean V1 B) The following substances may be contained in c-al: Antimony Arsenic Beryllium Cadmium Chromium Copper Lead Mercury Nickel Selenium Silver Thallium Zinc EPA Form 3510-2C (8-90) PAGE 3 of 4 CONTINUE ON REVERSE CONTINUED FROM THE FRONT VII BIOLOGICAL TOXICITY TESTING DATA Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? © YES {tdrm the resr(i) a.Jde:cnbe rhetrputpases be",) ❑ NO (ga ro Section Vill) Toxicity testing is performed as required by the station's current NPDES permit. The acute toxicity test is conducted and reported quarterly for the ash basin discharge (Outfall 003). VIII CONTRACT ANALYSIS INFORMATION Were any of the analyses reported in Item V performed by a contract laboratory or consulting firm? ® YES (tilt the name address, and teleph,me number r f and pollutants analyzed by El NO (Sat ra Section LI) each such laharruary ar firm below) A. NAME B.AODRE55 C TELEPHONE D. POLLUTANTS ANALYZED (ana code R n,,.) (Est) Ct:ke Energy Analytical Lab 13339 Hagers Ferry Road 990-675-5245 Metasls, COD, TKN, KCJ 248 Hunteraville, NC 28078 Nitrate -nitrite, TP, Oil Grease, TSS, TOC, Bromide, Sulfate, Flouride 11,ealy Lab 106 Vantage Point Dirve 003-701-9700 BOD, Fecal ColiEormColor, u 329 West Columbia, SC 29172 Sulifide, Sulfite, Surfactanta, Cyanide, Phenol, Volatiles, Semi-volatiles Acid compounds, PCBs, Mercury u£,, Inc. 2040 Savage Road 84]-g56-e171 Radiology NCR 233 Charleston, SC 29417 Pace Analytical 9800 Kincey Avenue, Suite 100 :4 8-s 9092 Aawonia Nitrogen NCR 633 Hunteraville, NC 28078 Dioxins and Furan Cape Fear Analytical 3306 Kitty Hawk Road, Suite 120 91n.- ' 0421 an affiliate of The GEL Group Wilmington, NC 28405 NCR 065-1519-1 IX CERTIFICATION 1 car* under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that quaEBed personnel property gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the inthnnation, the information submitted is, to the best of my knowledge and belief, true, accurate and complete. 1 am aware that there are signfiicantpenalties far submitting false information, including the possibility of line and imprisonment for knowing violations. A. NAME 6 OFFICIAL TITLE (type ar print) B PHONE NO. (area code & no.) ft=inal D. Anderson, GM III - 'lated Stati.;ns !336) 445-0501 C SIGNATURE D DATE SIGNED 91,2 -06 EPA Form 3510-2C. (6-96) PAGE 4 of 4 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this Information EPA I.D. NUMBER (cop),fry,nr liens I r fl'nrm !) on separate sheets (use the same formal] instead of completing these pages. NCDO008 565 91 SEE INSTRUCTIONS. OUTFALL NO. V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C) Doi PART A —You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 3. UNITS 4, INTAKE 2. EFFLUENT (.apecifyifblank) (oprnrrral) b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM a. MAXIMUM DAILY VALUE (ifarwilahle) (ifaladable) AVERAGE VALUE d. NO. OF a. CONCEN- Is. NO. OF � 1. POLLUTANT CONCENTRATION (2) MASS CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES a. Biochemical Oxygen <2 <24336 1 mg/1 lbs/d Demand (Hilt)) b. Chemical Oxygen <20 <243361 1 mg/1 lbs/d Demand (COD) c. Total Organic Carbon 3.6 43805.0 1 mg/1 lbs/d (TOO d. Total Suspended <5 <60840 1 mg/1 lbs/d Solids(7;L1j Solids e.Ammonia (ay M) <0.1 <1216.8 1 mg/1 lbs/d VALUE VALUE VALUE VALUE (,Flow 1459 1459 1459 365 MGD N/A g. Temperature VALUE VALUE VALUE �C VALUE (uiefer) h. Temperature IVALUE VALUE VALUE �C VALUE (srrnrnscr) 31 MINIMUM IMUM MINIMUM MAXIMUM I. pH '7 .37 r STANDARD UNITS PART B — Mack'X' in column 2-a for each pollutant you know or have reason to believe is present. Mark 'X" in column 2•b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence In your discharge. Complete one table for each outfall. See the instructions for additional details and requirements 2. MARK'X' 3. EFFLUENT 4. UNITS 5. INTAKE (nprrona4 1 POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM AVERAGE AND a b. a. MAXIMUM DAILY VALUE (rfaywrluhlc) (ifaynilahlc) VALUE CAS NO. BELIEVED BELIEVED d. NO. OF a. CONCEN• b. NO. OF f I It) tll It) (�furulluhlc) PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES a. Bromide 0.11 1338.5 1 Mg/1 lbs/d (24959-67-9) Is. Chlorine, Total <0 . 05 <608 .4 mg/1 lbs/d Residual c. Color x <5 N/A N/A N/A Std Unit N/A d. Fecal Coliform X 36 N/A N/A N/A CFU/100 N/A e.Fruortda (ts9sa-as-B) X 0.15 1825.2 1 mg/1 lbs/d 1.Nivate-Nitrile X I 0.01 121.7 1 mg/1 i lbs/d (as M EPA Form 3510-2C (8-90) PAGE V-1 CONTINUE ON REVERSE ITEM V-8 CONTINUED FROM FRONT 2. MARK'X' 3. EFFLUENT 4. UNITS 5. INTAKE (optic rat) 1 POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM AND a b. a. MAXIMUM DAILY VALUE (faradahle) (rfavadahle) AVERAGE VALUE CAS NO, BELIEVED BELIEVED d. NO. OF a. CONCEN- b. NO. OF (1) (1) (1) (1) fifalwrlahle) PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES g. Nitrogen, ` / Total Organic(as X Cl. 31 3772.1 1 mg/1 Zbs/d N) Grasse h. Oil and G Grease X <5 <60840 1 mg/1 Zbs/d I Phosphorus (as P), Total 0.014 170.4 1 mg/1 lbs/d (T723-14.0) J. Radioactivity (1) Alpha, Total x <0.00476 N/A NIA N/A 1 pCi/L N/A (2) Beta. Total x <1.68 N/A N/A N/A 1 pCi/1 N/A (3)Radurm, Total x <0.0934 N/A N/A N/A 1 pCi/1 N/A (4) Radium 226. x 0.978 N/A N/A N/A 1 pCi/1 N/A Total k. Sulfate 9.5 115597 1 mg/1 lbs/d (14808.79A) 1. S s'de V /� <1 <12168 1 mg/1 lbs/d m_ Sulfde (aTyo.) X <2 <24336 1 mg/1 lbs/d (1426545-3) n. Surfactants x 0.093 1131.6 1 mg/1 Zbs/d o. Aluminum. Total X 0.102 1241.1 1 mg/1 lbs/d (7429-90.5) p. Barium, Total (7440-39-3) ` n 0.019 231.2 Z Mg/1 lbs/d q. Boron, Total (7440-42-8) X 0.072 1 mg/1 lbs/d (7 "G-484) r x <1 <12.2 1 ug/1 lbs/d al (7a 9-,8") X 0.120 1460.2 1 mg/1 lbs/d t. Magnesium, Total X 3.28 39911.2 1 mg/1 lbs/d (7439.954) u. Molybdenum, Total X 1.38 16.8 1 Ug/1 lbs/d (7439-98.7) v. Manganese, Total (7439.96.5) X 0.011 133.8 1 mg/1 lbs/d w Tin, Total (7440.315) x<0 . f1 <121 . 7 1 mg/1 lb5/d x. Titanium, Total X <6 .8 1 mg/1 lbs/d (7440.32.5) EPA Form 3510-2C (8-90) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D. NUMBER (cupyjmni keno l oft orm I) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NCDO00856591 001 PART C - If you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GCIMS fractions you must lest for Mark in column 2-a for all such GCIMS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondary industries, nonprocess wastewater oultalls, and nonrequired GGMS hactions), mark 'X' in column 2-b for each pollutant you know or have reason to believe is present. Mark 'X' in column 2-c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitrile, 2,4 dinitrophenol, or 2-methyl-4, 6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully Complete one table (all 7 pages) for each outfall. See instructions for additional details and requirements. 2. MARK'X' 3. EFFLUENT 4 UNITS 5. INTAKE (rip emal) 1. POLLUTANT to. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a_ q_ a. MAXIMUM DAILY VALUE (Tar-dahle) VALUE (rfamitahle) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED d. NO. OF a. CONCEN- b. NO. OF {tl (1) {sI fly (rfa, dable) REQUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS NALYSES METALS, CYANIDE, AND TOTAL PHENOLS I M. Antimony, Total X <1 <12.2 1 ug/1 lbs/d (7440.38-0) 2M. Arsenic, Total <1 <12.2 1 Ug/1 lbs/d (7440-38-2) 3M. Beryllium, Total <1 <12.2 1 Ug/1 Zbs/d (7440-41-7) 4M. Cadmium, Total �/ X <p 1 <1.2 1 Ug/1 lbs/d (7440-43-9) SM. Chromium, <1 <12.2 1 Ug/1 Zbs/d Total (744047-3) 6M. Copper, Total \/ X <0.005 <60.8 1 mg/1 lbs/d (7440-50-B) 7M. Lead, Total <1 <12.2 1 ug/1 lbs/d (7439.92-1 J SM. Mercury. Total <0.5 <0.006 1 rig/1 lbs/d (7439.97-0) 9M. Nickel, Total <1 <12.2 1 Ug/1 lbs/d (7440-02-0) 10M.Selenium, c1 <12.2 1 Ug/1 lbs/d Total (778249-2) 11M. Silver, Total <1 <12.2 1 ug/1 lbs/d (7440-22.4) 12M.Thallium, c0.2 <2.4 1 Ug/1 lbs/d Total (7440-26-D) 13M. Zinc. Total (744D-66-6) v 0.008 97.3 1 mg/1 1bs/d 14M. Cyanide, Total (57-12-5) �/ /� <0.01 121.7 1 mg/1 lbs/d ISM. Phenols, �/ 0.0072 87.6 1 mg/1 bs/d Total /\ DIOXIN 2,3,7,3-Tetra- DESCRIBE RESULTS Result- cio pgli. - Procedure for preparation, analyaia and reporting of analytical data are controleed by Cape Fear Analytical LLC thlorodibenzo-P- X 4CFA1 as Standard operating Procedure (SOP). The data discussed has been analyzed with CR-OA-F-002 RM 14. Flaw data reports areprxessed and 4-0 Dioxin(176") reviewed by analyst using the TargetLynx software package. EPA Form 3510-2C (8.90) PAGE V-3 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2. MARK W 3. EFFLUENT 4. UNITS 5. INTAKE (oprrruraq 1 POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a b a a. MAXIMUM DAILY VALUE (farailahle) VALUE (rfaearlahle) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED d. NO. OF a. CONCEN- {t} (11 (1j (1) (rfatiaflohlc) REOUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MAS5 CONCENTRATION f2) MASS ANALYSES TRATION b. MASS CONCENTRATION 121 MASS NALYSES GC1MS FRACTION - VOLATILE COMPOUNDS 1V Accroiein (107-02-8) <5.0 <60.8 1 ug/l lbs/d (1071� 1e x <5.0 <60.8 1 ug/l lbs/d 3V. Benzene (71-43-2) �/ /� c2.0 c24.3 1 ug/1 lbs/d 4V. Bis (( \ Ether (542.88-1) /X\ 5V Bromoform (75-25.2) <2.0 <24 .3 1 ug/l lbs/d 6V Carbon ' Tetrachloride X <2.0 <24.3 1 ug/l lbs/d (56-23-5) TV. Chlorobenzene �/ c2.0 c24.3 1 ug/1 lbs/d (108-W7) /� 8V. Chbrodl- \ / bromornethane X <2.0 <24.3 1 ug/l lbs/d (124-48-1) 9V. Chloroethane (75A0.3) /� x <2.0 <24.3 i ug/1 lbs/d 10V 2-Chloro- - I ethylvinylEther X <5.0 <60.8 1 ug/l lbs/d (110-75-8) 11 V. Chloroform (67-66.3) �/ /� <2.0 <24.3 1 ug/l lbs/d 12V Dichloro- hromorneMane <2.0 <24.3 1 ug/l lbs/d (75-27.4) 13V Dichloro- difluoromethane <2.0 <24.3 1 ug/l lbs/d (75-71-8) 14V.1,1-Dichloro- ethane(75,34.3) �/ x <2.0 <24.3 1 ug/l lbs/d 15V 1,2-Dichloro- ethane (107.)6.2) <2.0 <24.3 1 u /l g lbs/d X <2.0 <24.3 1 ug/l lbs/d eth lens 5.35.4 Y f 1 Prop ne (7"7 5 x <2 . 0 <24.3 1 ug/1 lbs/d 18V 1,3.Dichloro- \ / propylene X <2.0 <24.3 1 ug/l lbs/d (542-75.6) 19V Ethybenzene <2.0 <24.3 1 ug/l lbs/d (100.41-4) Methyl X c2.0 <24.3 1 ug/l lbs/d Bromide (74-83-9) Bro 21V. Methyl <2.0 <24.3 1 ug/l lbs/d Chloride (74-87-3) EPA Form 3510-2C (8-90) PAGE V4 CONTINUE ON PAGE V-5 r`nrJTINI wn mnm PAr.P V_A 2. MARK'X' 3. EFFLUENT 4. UNITS 5. INTAKE (opli nral) 1 POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a. b. r: a. MAXIMUM DAILY VALUE (rfaradahle) VALUE (rfaradahle) AVERAGE VALUE CAB NUMBER TESTING BELIEVED BELIEVED d. NO. OF a. CONCEN- b. NO. OF III 01 (tl {ll (rfararlahlr) REQUIRED PRESENT ABSENT CONCENTRATION (21 MASS CONCENTRATION (21 MASS CONCENTRATION (2►MASS ANALYSES TRATION b. MASS CONCENTRATION (2)MASS NALYSES GClMS FRACTION - VOLATILE COMPOUNDS (c arramcd 22V Methylene <2.0 <24.3 1 ug/1 lbs/d Chloride (75-09-2) 23V 1,1.2,2- Tetrachbmethane x <2.0 <24.3 1 ug/1 lbs/d 79.34-5 24V Tetrachbro- <2.0 <24.3 1 ug/1 lbs/d ethylene (127-18-4) 25V Toluene <2.0 <24.3 1 ug/1 lbs/d 4108-68-3) 26V 1,2-Trans- Dichlomethylene x <2.0 <24.3 1 ug/1 lbs/d 156 60 5 27V 11,1-Trichlaro- c2.0 <24.3 1 ug/1 lbs/d ethane (71-55-6) 28V 1.1,2-Trirhbro- X <2.0 <24.3 Z ug/1 lbs/d ethane (79-a0-5) 29V Trichbro- <2.0 <24.3 1 ug/1 lbs/d ethylene (79-01-6) 30V Trichloro- ` , euoromethene X <2.0 <24.3 1 ug/1 lbs/d 7"9-4 ' ` 31V Vinyl Chloride <2.0 <24.3 1 ug/1 lbs/d (75-01-4) GCIMS FRACTION -ACID COMPOUNDS IA.2-Chlamphenol <1 , 6 <19 . 5 1 ug/1 lbs/d (95-57-8) 2A.2.4-Dichloro- <1.6 <19.5 1 ug/1 lbs/d phenol(120.83-2) 3A.2,4-Dimethyl- <1.6 <19.5 1 ug/1 lbs/d phenol(105.67-9) 4A. 4 6-Dinftro-0- X <8.0 <97.3 1 ug/1 lbs/d Cresol (534-62-1) SA.2,4-Dinkro- x <8.0 <97.3 1 ug/1 ibs/d phenol151-28-5} 6A.2-Nitmphenol c3.2 c38.9 1 ug/1 lbs/d (88-75.5) 7A.4-Nitrophenol <8 , 0 <97.3 1 ug/1 1bs/d (100.02-7) BA.P-Chbro-M- <1.6 <19.5 1 ug/1 lbs/d Cresol(59-50-7) 9A. Pentachloro- X < 8 . 0 <97.3 1 ug/1 lbs/d phenol (87-86-5) 10A l x <1.6 <19.5 1 ug/1 lbs/d (1ae-95-2) 95•z� /� I1A.2,4,6-Trirhbm- X <1.6 <19.5 1 ug/1 lbs/d r phenol (88-05-2)1 EPA Form 3510-2C (8-90) PAGE V-5 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2. MARK'X' 3. EFFLUENT 4. UNITS 5. INTAKE (aptumal) 1 POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a b a MAXIMUM DAILY VALUE (If-wilahle) VALUE (faimrlahle) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BEI IEVED d. NO. OF a. CONCEN- b. NO OF (1) (1) (1) j11 (rfavarlahle) REOUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (21 MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES GC/MS FRACTION - BASE(NI=UTRAL COMPOUNDS IB.Acenaphthene <1,6 <19.5 1 ug/1 lbs/d (83-32-9) 2B. Acenaphtylene �/ <1.6 <19.5 1 ug/1 lbs/d (20a-Va-a) /� (z Anth7`cene <1.6 <19 , 5 1 ug/i lbs/d 2-87 $zidine c8.0 <97.3 1 ug/1 lbs/d 5B. Benzo (a) Anthracene X <1.6 <19.5 1 ug/1 lbs/d (66-55-3) X c? .6 <19-5 1 ug/1 lbs/d 5D-3zo Pyrene60. Pyrene (StY32-B) 7B. 3.4-Senzo- fluoranlhens : 1 . G <19. 5 1 ug/1 lbs/d (zo5 99 z1 BB. Benzo (ghri Perylene (191-24-2) c 1.5 c 19.5 1 u 1 g/ lbs d / 9B. Benzo (1) Fluoranthene X <1.6 <19.5 1 ug/1 lbs/d {207-08-9} 10B. Bis {Id'Jth,n} rr1Ha7)Methane �( <1.6 <19.5 1 ug/1 lbs/d (111-91-11 , ` 118, Sis (24'hlun� esh).4Ether X <1.6 19.5 1 ug/1 lbs/d 4111-44-4) 12B Bis (2- Cidomi vipn.-;�) e^ Ether (1024M-1) 13B. Bis (24 rinf- Oiwrj•nPhlhalate X <1.6 <19.6 1 ug/1 lbsid (117-81-7) 148.4-Bromophenyl Phenyl Ether <1.6 <19.5 1 ug/1 lbs/d (101-55-3) 15B. Bu4i Benzyl <1 . 6 <19 . 5 1 u 1 g/ lbs/d Phthalate (85.68-7) 16B.2-ChWo- naphthalene X c1.6 <19.5 1 ug/1 lbs/d (91-53-7) 17B. 4-Chbro- phenyl Phenyl Ether <1.6 <19.5 1 ug/1 lbs/d (7005-72-3) 18B.Chrymne (218-01-9) <1.6 <19.5 1 ug/1 lbs/d 19B. Dibenzo (a.h) Anlhracene <1.6 <19.5 1 ug/1 lbs/d (53-70-3) 208.1.2-Dichiaro- benzene195.50-1) <1.6 <19.5 1 u 1 g/ lbs d / 21B.1,3-Dkbloro benzene (541-73-1) c. 16 <. 195 1 u 1 g/ lbs d / EPA Form 3510.2C (8.90) PAGE V-6 CONTINUE ON PAGE V-7 - 2. MARK W 3. EFFLUENT 4 UNITS 5. INTAKE (olnomwl) 1 POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONGTERM AND a. b. a a. MAXIMUM DAILY VALUE (rjarwrluhle) VALUE (ifaraduhle) d. NO. OF a CONCEN- AVERAGE VALUE b NO OF (1y CONCENTRATION (21 MASS (1) CONCENTRATION (2) MASS (1) CONCENTRATION 121 MASS {11 CONCENTRATION (2} h1A55 CAS NUMBER {rfurwiluhlc) TESTING REQUIRED BELIEVED PRESENT BELIEVED ABSENT ANALYSES TRATION b, MASS ANALYSES GC/MS FRACTION - BASEINEUTRAL COMPOUNDS (corrunncA 228.1.4-Dlchloro- <1.6 <19.5 1 ug/1 lbs/d benzene(106-46-7) 23B.3,3-Dichloro• <8.0 <97.3 1 ug/1 lbs/d benzidine (91.94-1) 248,Diethyl Phthalate (B4.66-2) v el.6 <19.5 1 ug/1 lbs/d 258. pimethyl Phthalate <1.6 c19.5 ug/1 lbs/d (131 -11-3) 268,DI-N-Butyl �/ x <1.6 <19.5 ug/1 lbs/d Phthalate (64-74.2j 278.2,4-Dinitro- <3.2 <38.9 1 ug/1 lbs/d toluene (121-14-2) 28B.2,6-Dinitro- <3.2 <38.9 1 ug/1 lbs/d toluene (606-20.2) 29B.DI-N-Odyl \/ x <1.6 <19.5 1 ug/1 Zbs/d Phthalate (117-8") 308. 1,2-Diphenyt- hydrazine (asAza- X <1 , 6 <19.5 Z ug/1 lbs/d benzene)(122-66.7) 3 18, Fluoranthene v <1.6 <19.5 1 ug/1 Zbs/d (206-44-0) 32B. Fluorene <1 <19.5 1 ug/1 Zbs/d (66.73-7) .6 338, achkmD- x c1.6 <19.5 1 ug/1 Zbs/d benzen (118-74 benzene (1 i 6-741) /\ 348 kexachWo- v <1.6 <19.5 1 ug/1 lbs/d butadiene (87.66-3) 35B. Hexachloro- cyclopentadlene <1.6 <19.5 1 ug/1 Zbs/d (77-47.4) 36BHexachlom- <8.0 <97.3 1 ug/1 lbs/d ethane (67-72-1) (1,2,3-coPyrene c1.6 t19.5 1 ug/1 lbs/d (193-39.5) 38B.Isophorone v <1.6 <19.5 1 ug/1 lbs/d (7B 5s t) 39B. Naphthalene �/ x <1.6 <19 5 1 ug/1 lbs/d (91-�) 45-95-3) robenzene x c1.6 <19.5 1 ug/1 Zbs/d (96-95- 418. N•Nilro sodimethylamine - I <1.6 <19.5 1 ug/1 lbs/d (62a5 9) ,�(` 423, N-Nitrosodi N-Propylamine X <1.6 <19.5 1 ug/1 lbs/d (621-64-7) EPA Farm 3510.2C (8-90) PAGE V-7 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2. MARK'X' 3. EFFLUENT 4. UNITS 5. INTAKE (optional) 1. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONGTERM AND a. b. a a. MAXIMUM DAILY VALUE (+furuNuble) VALUE (rfarurlable) AVERAGE VALUE CAS NUMBER TESTtNG BELIEVED BELIEVED d. NO OF a. CONCEN- b. NO OF (1) (1) (1) (1) (rfmwilahlc) REQUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2J MASS CONCENTRATION (2} MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MA55ANALYSES GC/MS FRACTION — BASEINEUTRAL COMPOUNDS {ernninned) 438. N-Nitro- sodiphenylamehe <1.6 <19.5 1 ug/l lbs/d 186.30.6) a.Phenenthrene <1,6 <19.5 1 ug/l lbs/d �12 9*M)e X 1 <1.6 <19.5 1 ug/l lbs/d B. 1,2,4-Tri- 4(120- chk46 benzene <1. 5 <19 . 5 1 ug/1 lbs/d 120-82-1) GCIMS FRACTION —PESTICIDES 1P. Aldrin (309-00-2) 2P. a-BHC (319.84.6) 3P I)-BHC (319.85-7) 4P. r-BHC (SB-89.9} 5P. &BHC (319.86-8) 6P. Chlordane (57-74.9) 7P 4,4'-DDT (50-29-3) OP 4,4'-DDE (72.55-9) 9P 4,4'-DDD (72-54-8) 10P. DfeNdn (60.57-1) 11P. a-Enosulfan (115-29-7) 12P. p-Endosuflan (115-29-7} 13P. Endosulfan Sulfate (1031.07-8) 14P Endrin (72-20-8) 15P Endrin Aldehyde (7421-93-4) 16P Heptachlor (76.44.8) EPA Form 3510-2C (8-90) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D. NUMBER (cfjp),f+*)m llem l iflvrm 1) OUTFALL NUMBER CONTINUED FROM PAGE V-8 NCDO00856591 001 2. MARK *X' 3. EFFLUENT 4. UNITS S. INTAKE (oprmnul) 1. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a. b. c a. MAXIMUM DAILY VALUE (facw+lahle) VALUE (fa+wdahle) IANALYSES AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED d. NO. OF a. CONCEN- (1) {,� (1) (faswrlahle) REQUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRA7ION (2) MASS CONCENTRATION (2) MASS TRATION b. MASS CONCENTRATION (2) MASS NALYSES GC1MS FRACTION — PESTICIDES (ranuuued) 17P. Heptachlor Epoxide (1024-57-31 18P PCB•1242 X <0.4 <4.9 1 ug/l lbs/d (53469.21-9) P-69.1) 4 x <0.4 <4.9 1 ug/l lbs/d 11 20P PCB-1221 <0.4 <4 1 ug/l lbs/d (11104-25-2) .9 21P PCB-1232 {11141-16.5) <0.4 <4.9 1 u 1 J/ lbs/d 22P PCB-1248 (12672-29-6) X eO.4 <4.9 1 u 1 g/ lbS/d 23P PCB-1260 (11096-82-5) a0.4 <4.9 1 ug/l lbs/d 24P. PCB-1016 (12674-11-2) <0,4 <4.9 Z ug/1 lbs/d 25P.Toxaphene (8001-35.2) EPA Farm 3510-2C (8-90) PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY You may report some or all of this information EPA I.D. NUMBER (cop)-fnmi Item I rfFornr 1) on separate sheets (use the same formal) instead of completing these pages. NCD0008565 91 SEE INSTRUCTIONS, I i OUTFALL NO. V INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C) 003 PART A —You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outran. See instructions for additional details. 3. UNITS 4. INTAKE 2. EFFLUENT (ywof•tfblank) (upetmal) b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM a. MAXIMUM DAILY VALUE (furwilable) (fuinilnhlc) AVERAGE VALUE d. NO. OF a. CONCEN- b. NO. OF tt) 1 POLLUTANT CONCENTRATION (2) MASS CONCENTRATION RATION (2) MASS (1) CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES a. Biochemical Oxygen <2 .0 <58 1 mg/1 lbs/d Demand (Rot)) b. Chemical Oxygen Demand (C711)) <20 <584 1 m 1 9/ lbs/d c. TotalOrganic Carbon 3.4 99.2 1 mg/1 lbs/d d. Total Suspended Solids (NN) <5 <146 1 m 1 g/ lb5 d / e. Ammonia (ay N) <0.1 <2.9 1 mg/1 lbs/d VALUE VALUE VALUE VALUE i. Flow 3.5 9.69 5 MGD N/A g. Temperature VALUE VALUE VALUE VALUE (to -tiller) h. h. Temperature VALUE VALUE VALUE VALUE (summer) 24 'C MINIMUM MAXIMUM MINIMUM MAXIMUM I. pH 7.69 STANDARD UNITS PART B — Mark'X' in column 2-a for each pollutant you know or have reason to believe is present. Mark 'X" in column 2-b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additional details and requirements. 2. MARK'X' 3. EFFLUENT 4. UNITS 5. INTAKE (oprrnnul) 1 POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM AVERAGE AND a b. s. MAXIMUM DAILY VALUE (ifamiluhlc) (rfuiwiluhle) VALUE CAS NO. BELIEVED BELIEVED d. NO. OF a. CONCEN- b. NO. OF (1) (1) (1) (1) (furwilablc) PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION 12) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES a. Bromide (24959.67-9) 4.9 143 1 mg/1 lbs/d bb.esidChlorine, Total �/ <0 .05 <1 . 5 1 mg/1 lbs/d c. Color X <5 .0 N/A N/A N/A 1 Std Unit N/A d. Fecal Coliform X 1 N/A N/A N/A 1 CFU/ 100 N/A e. Fluoride {16984-4a8) 0.63 18.4 1 mg/1 lbs/d IgsteNitrile X <0.01 <0.29 1 mg/1 lbs/d EPA Form 3510-2C (8-90) PAGE V-1 CONTINUE ON REVERSE ITFIU V-R rt IMIJI IFn FRnRA FRnIJT 2. MARK'X' 3. EFFLUENT 4. UNITS 5. INTAKE (apmuural) 1. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM AND a b a. MAXIMUM DAILY VALUE (farwmlahle) (favailahle) AVERAGE VALUE CAS NO. BELIEVED BELIEVED d. NO. OF a. CONCEN- b. NO. OF (1) (1) (1) (1) (farwrlahle) PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES g. Total Organic 0.42 12.3 1 mg/1 lbs/d M h. Oil <5 <146 1 mg/1 lbs/d Grease ease G i Phosphorus ` (as P), Total X 0.022 0.64 1 mg/1 lbs/d (7723.14 0) J. Radioactivity (1) Alpha, Total x cO.702 N/A N/A N/A 1 pCi/L N/A (2)Bela, Total x I(].0 N/A N/A N/A Z pCi/L N/A (3) Radium, X 0,639 N/A N/A N/A 1 pCi/L N/A Total (4) Radium 226. x 0.491 N/A N/A N/A 1 pCi/L N/A Total k. S (a`.sO.) o,) x 160 4670 1 mg/1 lbs/d (14803-79.8) I.Sulf-ide (ar S) X c1. <29.2 1 mg/1 lbs/d m. Sull'iX (aiW.Srl)) c2. c58.4 1 mg/1 lbs/d (14265.45.3) n. surfactants x 0.068 1.98 1 mg/1 lbs/d o. Aluminum, Toler x -55 1.6 1 mg/1 lbs/d (7429.90.5) p. Barium Total (7440-39-3) ` n 0.102 2.98 1 mg/1 lbs/d (744r��otal x 256.6 1 mg/1 lbs/d r.Cobah.Total x 1.62 0.047 1 ug/1 Zbs/d 17440-484) s. Iron. Total 0.032 0.93 1 mg/1 lbs/d (7439-89-8) t, Magnesium, Total X 46.5 1357.3 1 mg/1 lbs/d (7439.95-4) u. Molybdenum. Total x 94 1.28 Z ug/1 lbs/d (7439.98-7) v. Manganese, Total X 0.236 6.9 1 mg/1 lbs/d (7439.96-5) w Tin, Total (7440-31.5) <0 .O1 <0 .3 1 mg/1 lbs/d x. Titanium, Total X c0.005 c0.15 1 mg/1 lbs/d (744tx32.6) EPA Form 3510-2C (8-90) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D. NUMBER (rapyfrt)m item I off-orm 1) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NCDO00856591 003 PART C - If you are a primary Industry and this outfall contains process wastewater, refer to Table 2o-2 in the instructions to determine which of the GCIMS fractions you must test for. Mark *X' in column 2-a for all such GCIMS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondary industries, nonprocess wastewater outtatls, and nonrequired GC/MS fractions), mark 'X' in column 2-b for each pollutant you know or have reason to believe is present. Mark 'X' in column 2-c for each pollutant you believe is absent. It you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it wilt be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolem, acrylonitrde, 2.4 dinitrophenol, or 2-methyl4, 6 dinitrophenot, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged Note that there are 7 pages to this part; please review each carefully Complete one table (all 7 pages) for each outfall See instructions for additional details and requirements 2. MARK 'X' 3 EFFLUENT 4. UNITS 5. INTAKE (nptional) 1 POLLUTANT b MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONGTERM AND a b c a. MAXIMUM DAILY VALUE (rfurailahle-) VALUE (rfarvnlahle) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVER d. NO, OF a CONCEN- b, NO OF 0) fit) 4t] 11] ( at-adahle) REQUIRED PRESENT ABSENT CONCENTRATION 12 MASS CONCENTRATION (21 MASS CONCENTRATION {26 MA55 ANALYSES TRATION b. MASS CONCENTRATION {21 MASS ANALYSES METALS, CYANIDE, AND TOTAL PHENOLS I Antxnony,Total X <1 <0.03 1 Ug/1 lbs/d (7440.36-0) 2M. Arsenic, Total 2.95 0.086 1 ug/1 lbs /d (7440.38.2) 3M. Beryllium, Total <1 <0.03 1 ug/1 lbs/d (7440.41-7) 4M. Cadmium, Total 0.309 0.009 1 ug/1 lbs/d (7440-43-9) 5M. Chromium, <1 <0.03 1 u 1 g/ lbs/d Total (70"M 7-3) 6M.CCor.Total <0.005 <0.001 1 mg/1 lbs/d 7Lead, Total X <1 <0.03 1 ug/1 lbs/d (7439-92439.92-1) 8M. Mercury. Total 0.938 .00003 1 ng/1 lbs/d (7439-97-6) 9M. Nickel, Total 9.89 0.289 1 ug/1 1bs/d (7440-02-0) 10M. Selenium, 9.47 0 . 276 1 ug/1 lbs/ d Total (7782-49.2) 11 M. Silver, Total �/ X <1 <0.03 1 ug/1 lbs/d (7440-22-4) 12M. Thallium, 1.24 0.036 1 u 1 g/ lbs d / Total (7440-28-0) (7440.886.6) Total X0.013 0.38 1 Mg/1 lbs/d 14M. Cyanide, Total (57-12-5) X <0.01 <0.29 1 m 1 g/ lbs d / Total Phenols, 0.0073 0.21 1 mg/1 lbs/d DIOXIN 2,3,7,8-Tetra- DESCRIBE RESULTS Result- <10 pg/L - Procedure for preparation, analysis and reporting of analytical data are controleed by Cape Fear Analytical LWchlorodibenzo-P- X (CFAr as Standard Operating Procedure {SOP). The data discussed has been analyzed with CR-oA-F-002 REV* 14 Raw data reports areprocessed and Dioxin (1764.01-6) reviewed by analyst using the TargetLynx software package EPA Form 3510.2C (8-90) PAGE V-3 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2. MARK'X' 3. EFFLUENT 4. UNITS 5. INTAKE (quaural) 1 POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONGTERM AND a_ b. C. a. MAXIMUM DAILY VALUE (rfavarlahle) VALUE (rfavarlahle) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED d. NO. OF a. CONCEN- b. NO. OF (1) (1) {i) (1) (rfaradahle) REQUIRED PRESENT ASSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES GClMS FRACTION - VOLATILE COMPOUNDS 1V Accaolsin <5.0 <0.15 1 ug/1 lbs/d (107-02.8) 2V AcrAmibile <5.0 <0.15 1 ug/1 lbs/d (107-13-1) 3V. Benzene (71-43-2) <2.0 <0.06 1 ug/1 lbs/d 4V. Sis (Cldarw ` , mrdlnf) Ether X 1 (542.88.1) 5V Bromoform <2.0 <0.06 1 ug/1 lbs/d (75-25-2} Carbon Tet TeVadrloride X <2.0 <a . as 1 ug/1 lbs/a (56.23.5) Chlorobenzene X <2.0 <0.06 1 ug/1 lbs/d (1 8V Chlorodi- \ / bromomethane x <2.0 <0.06 1 ug/1 lbs/d (124-48-1) 9V Chlorcethane �/ <2.0 <0.06 1 ug/1 lbs/d (75.00-3) /� 10V. 2-Chloro- ethylvinylEther X <5.0 <0.15 1 ug/1 lbs/d (110-75.8) Chloroform 67- (67-6fr3) j� V <2.0 <0.06 1 ug/1 lbs/d 12V. Dichloro- bromarnethane <2.0 <0.06 1 ug/1 lbs/d (75.27-4) 13V. Dichkwo- ' dilluoromelhane X <2.0 <0.06 1 ug/1 lbs/d (75-71.8) 14V.1,1-Oichloro- <2.0 <0.06 1 ug/1 lbs/d ethane (75-34-3} 15V.1,2-Dichloro �/ <2 0 <0.06 Z ug/1 lbs/d ethane (107-06-2) /� • 16V 1,1-Dichtoro- <2.0 <0.06 1 ug/1 lbs/d ethylene (75-35a1) 1,loro- X <2.0 <0.06 1 ug/1 lbs/d pro(78-67-5) propane (7& i8V 1,3-0ichtaro- pmpylene X <2.0 <0.06 1 ug/1 lbs/d (542-75-6) 19V. Elhylbenzene X <2.0 <0.06 1 ug/1 lbs/d (100-41-4) 20V. Methyl x <2 0 <0.06 1 ug/1 lbs/d Bromide (74.83-9) 21V. Methyl <2.0 <0.06 1 ug/1 lbs/d Chloride (74-a7-3) EPA Form 3510-2C (8-9D) PAGE V4 CONTINUE ON PAGE V-5 CONTINUED FROM PAGE V4 2. MARK •X' 3, EFFLUENT 4. UNITS 5. INTAKE (oplitmal) 1 POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a. b. C. a. MAXIMUM DAILY VALUE (ifamlahle) VALUE (+farTNlahle) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED d. NO OF a. CDNCEN- b NO, OF JANALYSES (jarurlahlc) REQUIRED PRESENT ABSENT CONCENTRATION {2) MASS CONCENTRATION {2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENITRATION (2) MASS GC/MS FRACTION - VOLATILE COMPOUNDS (rrmrmr+e+n 22V Methylene <2.0 <0.06 1 ug/1 lbs/d Chloride (7549.2) 23V 1,1,2,2- Tetrachlo thane X <2.0 <0.06 1 ug/1 lbs/d 79-34-5 24V. Tetrachtaro- i <2.0 <0.06 1 ug/1 lbs/d ethylene (127-18-d) 25V Toluene X <2.0 <0.06 1 ug/1 lbs/d (10"a 3) 26V 1,2-Trans- Dichlomethylene X <2.0 <0.06 1 ug 1 lbsld 15B GO S 2thane(1-Trk) x <2.0 <0.06 1 ug/1 lbs/d elhena {71-55�8y /� 28V 1,1,2-Trichbro- <2.0 <0.06 1 ug/1 lbs/d ethane (79-00-5) 29VTrk:hloro- ethylene (79-01-6) <2.0 <0.06 1 u 1 g/ lbs d / 30V Trichbra nuoromethane X <2.0 <0.06 1 ug/1 lbs/d 75 69 4 31V VinylChbride x <2.0 <0.06 1 ug/1 lbs/d (75A1-4) /\ GC1MS FRACTION - ACID COMPOUNDS IA. 2- hllomphenol <1.6 <0.05 1 ug/1 lbs/d X a1.6 <0.05 1 ug/1 lbs/d pheno (120.8) 3A.2,4-Dtmethyl- <1.6 <0.05 1 ug/1 lbs/d phenol (105-67-9) 4A.4 6-Dmitro-0- <B , 0 <0.23 1 u 1 g/ lbs d / Cresol(534-52-1) 5A.2,4-Dinitro- <8,0 <0.23 1 ug/1 lbs/d phenol151-28-5) 6A.2-Nitmphenol <3.2 <0.09 1 ug/1 lbs/d (88-75.5) 7100-02-7) trophenol V <g , 0 <0.23 1 ug/1 lbs/d (100.02 BA. X <1.6 <0.05 1 ug/1 lbs/d oll(5950-7) Cresol (59.50-7J 9A.Pentachloro- �( <8.0 <0.23 1 ug/1 lbs/d phenol (87.86.5) 10A.Phenol (108-95.2) X <1.6 <0.05 1 ug/1 lbs/d 11A,2,4,6-Tridrlaro- �/ <1.6 <0.05 1 ug/1 lbs/d phenol (68-OS2) /� EPA Form 3510-2C (8-90) PAGE V-5 CONTINUE ON REVERSE MNTIN"m FRn U T14F FRnNT 2. MARK'X' 3. EFFLUENT 4. UNITS 5. INTAKE (ulmanul) 1. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a b a. MAXIMUM DAILY VALUE (ifavarlahle) VALUE (Ifara+lahle) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED d. NO. OF a. CONCEN- b. NO. OF (t) It} {1) {1} (iforailahle) REQUIRED PRESENT ABSENT CONCENTRATION {2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b_ MASS CONCENTRATION (2) MASS NALYSES GC1MS FRACTION - BASEINEUTRAL COMPOUNDS 18,Acenaphthene <1.6 <0.05 1 ug/l lbs/d (83.32-9) 28,Acenaphtylene <1.6 <0.05 1 ug/l lbs/d (2W96-B) 3B.Anthracene v <1.6 <0.05 1 ug/l lbs/d (120-12-7) 4B. Benzidine X <8 <0 1 ug/l lbs/d (92-87-5) .0 .23 50, Senzo (a) Anthracene <1.6 <0.05 1 ug/l lbs/d (56-55-3) 6B.Benzo(a) <1.6 <0.05 1 ug/l lbs/d Pyrene (50.32-e) 78. 3,4-Senzo- 0uoranthene <1.6 <0.05 1 ug/l lbs/d (205.99.2) BB. Benzo(ghr) <1.6 <0.05 1 ug/l lbs/d Perylene (191-24-2) 98. Benzo (1) Flumanthene X <1.6 <0.05 1 ug/l ibs/d (207-)B-g) 10B. 813 (24'hlarrr rrhim))Methane <1.6 <0.05 1 ug/l lbs/d (111-91-1J 11B. Bis (2-Chlnh� edg!)Ether <1.6 <0.05 1 ug/l lbs/d (111 44 4) 12B. Bis (7- CljlanrnanmP3'l) Ether(1o2.80.1} 13B. Bis (2411p)f- lwxyl)Phthalate �( <1.6 <0.05 1 ug/l lbs/d (117-81-7) ' ` 14B. 4-Bromophenyl Phenyl Ether <1.6 <0.05 1 ug l lbs/d (101-55-3) 15B. Butyl Benzyl V <1.6 <0.05 1 ug/l ibs/d Phthalate (85.68-7) 168. 2-Chlaro- naphthalene <1.6 <0.05 1 ug/l lbs/d (91-58-7) 178. 4-Chloro- phenyl Phenyl Ether <1.6 <0.05 1 ug/l lbs'd (7005-72-3) 18B. Chrysene <1.6 <0.05 1 ug/l lbs/d (218-01-9) 198, Dibenzo (µh) Anthracene <1.6 <0.05 1 ug/1 lbs/d (53.70-3) 20B.1.2-13ichbru- <1.6 <0.05 1 ug/l lbs/d benzene (95-50-1) 218.1.3-DkAlaro- <1.6 <0.05 1 ug/1 lbs/d benzene (541-73 1) EPA Form 3510-2C (8-90) PAGE V-6 CONTINUE ON PAGE V-7 CONTINUED FROM PAGE V-6 2. MARK W 3, EFFLUENT 4. UNITS 5 INTAKE (upumrol) 1 POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND a b, c, a. MAXIMUM DAILY VALUE (rfarwilahlej VALUE (efamoduble) AVERAGE VALUE CAS NUMBER TESTING BELIEVED 0WEVED d. NO. OF a. CONCEN- b NO OF (1} {�] (1) {w) (rfrnwrlahlc) REQUIRED PRESENT ABSENT CONCENTRATION (2► MASS CONCENTRATION (2] MASS COMCENTRATION {2] MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS NALYSES GC/MS FRACTION - BASEINEUTRAL COMPOUNDS (crHrrrnrrcA X <1.6 <0.05 1 ug/1 lbs/d benzene benzene (106-48-7} /� 23B.3,3-DichMv- <8.0 <0.23 1 ug/1 lbs/d benMine (91-94-1 ) 240.DIethyl Phthalate (54-66-2) <1.6 <0.05 1 u g/ 1 lbs/d ethyl al Phthalate hth Phthalatt e <1.6 <0.05 1 ug/1 lbs/d (131 -1 1-3) 26B. DI-N-Butyl �/ x <1.6 <0.05 1 ug/1 lbs/d Phthalate (84-74-2) 278 2."tnKro- <3.2 <0.09 1 ug/1 lbs/d toluene (121-14-2) 288 2,6-Din-Vo- v <3 <0.09 1 ug/1 lbs/d to4uene (606.20.2) .2 29B Di-N-Octyl \/ x <1.6 <0.05 1 ug/1 lbs/d Phthalate (117-84-0) 30B.1,2-Diphenyl- hydrazine(asAza- <1.6 <0.05 1 ug/1 lbs/d benzene)(122.65.7) 319. Fkroranthene <1.6 <0 05 1 ug/1 lbs/d (205 44-0) . 328. x/ <1.6 <0.05 1 ug/1 lbs/d 6_73.7) (86-73.7j /� 33B. Hexachlaro <1.6 <0.05 I ug/1 lbs/d benzenejll&74-1) 345. Hexachloro- <1.6 <0.05 1 ug/1 lbs/d butadlene (87-68-3) 358. Hexachkxo- cyclopentediene <8.0 <0.23 1 ug/1 lbs/d (77.47.4) 36ans(67-72-1) hloro- X <1.6 <0.05 1 ug/1 lbs/d ethane (67 37B.Indeno (i,2,3-cMPyrene <1.6 <0.05 1 ug/1 lbs/d (193.39-5) 36B.Isophorone <1.6 <0.05 1 ug/1 lbs/d (78-59-1) 39B.Naphthalene <1.6 <0.05 1 ug/1 lbs/d (91-20-3) 40B.NItmbenzene <1.6 <0.05 1 ug/i lbs/d (96-95-3) swim N-Nethyo sodimethylamine <1.6 <0.05 1 ug/1 lbs/d (62-75-9) 42B. N-Nitrosod]- N-Propylamine c1.6 <0.05 Z ug/1 lbs/d (621-64.7) EPA Form 3510-2C (8-90) PAGE V-7 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2. MARK'X' 3. EFFLUENT 4. UNITS 5. INTAKE (npurman 1 POLLUTANT b. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. a. LONG TERM AND a. b. C a, MAXIMUM DAILY VALUE (rfarnduhle) VALUE (ifurrrrluhlr) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED d. NO. OF a. CONCEN- b NO OF (1) (1) {i1 III (rfumluhlc) REQUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (21 MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS NALYSES GCIMS FRACTION — BASEINEUTRAL COMPOUNDS (cruuinuet4 43B. N-Nitro- sodiphenylamine X <1.6 <0.05 1 ug/l 1bs/d (86 30-6) 44B. Phenanthrene (85.01-8) �/ ^ <1.6 c0.05 1 ugjl lbsfd � 12s m) X c1.6 <0.05 3 ug/l lbs/d 466. 1,2,4-Tri- chlobenz X <1. 6 <0.05 1 ugf 1 lbs d (120- 2-11ene f 120.82-1 } GCIMS FRACTION — PESTICIDES 1P Aldrin (309-00-2) 2P u-BHC (319-84-6) 3P, p-BHC (319.85.7) 4P, 1-BHC 158-89-9) SP b-BHC (319-86-8) 6P Chlordane (57-74-9) 7P. 4,4'-DDT (50.29-3) 8P 4,4'-ODE (72.55.9) 9P 4,4'-DDD (72-54-8) 1013 Dieldrin (60.57-1) 11P n-Enosulfan (115.29 7) 12P. (1•Endosultan (115-29-7) 13P.Endosulfan Sulfala (103"7-6) 14P Endrin (72-2D-8) 15P. Endnn Aldehyde (7421-934) 16P. Heptachlor (7644-8) EPA Form 3510-2C (8-90) PAGE V-B CONTINUE ON PAGE V-9 EPA I D. NUMBER (caprfrrrm lrem ! ifFarer I) OUTFALL NUMBER NCD000856591 003 rnuTwl IFn FRn1u aar,F V.R 2. MARK'X' 3. EFFLUENT 4. UNITS 5. INTAKE (nprnsrul) I. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM AND 8. b c. a. MAXIMUM DAILY VALUE (rfatwrlahle) VALUE (i/availahlc) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED {1j d. NO. OF a. CONCEN- b. NO. OF 111 f1) (1) (rf ulull(Ah) REQUIRED PRESENT ABSENT CONCENTRATION R 1 MASS CONCENTRATION (R) MASS CONCENTRATION (2) MASS ANALYSE$ TRATION b MASS CONCENTRATION (2) MASS NALYSES GCIM$ FRACTION — PESTICIDES (zvnuraecal) 17P Heptachlor EpoYrde (1024-57-3) 18P. PCB-1242 <0.40 <0.12 1 ug/l lbs/d (SM69-21-9) 19P. PCB-1254 <0.40 <0. 12 1 ug/l lbs/d (11097-69-1) 20P PCs-1221 x <0.40 <0.12 1 ug/l lbs/d (11104.28.2) 21P PCB-1232 \/ x <0.40 <0.12 1 ug/l lbs/d (11141-16-5) 22P. PCB-1248 (12672-29-6) \� x <0.40 <0.12 1 ug/l lbs/d 23P..PPCB-15260 I ^ <0.40 <0.12 i ug/l lbs/d 24P. PCB-1016 (12674-11-2) X <0.40 <0.12 1 u /l g lbs{d 25P Toxaphene 7 (8001-35-2) EPA Form 3510-2C (8-90) PAGE V-9 Attachment 1 Site Map August 2016 NPDES application renewal Belews Creek Steam Station er rA (i w ' GOP ` t �,�' 1 • L, r `s� k 41 Basin36*1 :� ! r 002 M /A V r l K } ,I G -n ✓ i 1 t 1) USGS7,5MimAeSeries TopogralAwOuaftNb. Bebwelake(NC) DISCHARGE LOCATION MAP FIGURE I$O1OB° aPjmp ap,-- 6ti�-,dwddro+l NPDES Permit No: NC002"06 Z) Property line i t.. ation provided by Duke Energy wW its app vxmu te. • hidcates epprmdmWe location of home ass rued to be supplied by private d"ng wager well. (Sowm Stakes CauAy GISAonal (zone)) DUKE ENERGY — — BELEWS CREEK STEAM STATION Drawn By: Chad Hearn SCALE STOKES COUNTY, NORTH CAROLINA Pr'ojed Manage►: Big Meer ClIent Duke Energy 0 0.125 0.25 0b Date: 05I291Y011 Attachment 2 Current and Future Waste Flow Charts August 2016 NPDES application renewal Belews Creek Steam Station NCO024406 I Intake Area I I Water Treatment I I Ash Sluice I Attachment 2 Form 2C — Item II -A Description of Current Waste Flows Through Facility Station Equipment Cooling Water Low & High Pressure Service Water Condenser Cooling Water I RCW Cooler I aIntake Screen Backwash 3.85 Power House Sump MGD Yard Holding Sump 12 MGD 0.03 Condenser Feedwater I Chemical Holding Pond MG[ 2.7 0.a5 MGD Storm Water Hydrogen & Oil Cooler Belews Reservoir System 0.08 Outfal 1001 !T Storm Water MGD 1218 MGD 0) m m a to Coal Yard Sumps Consolidated Sump system 0.7 < 0.19 MGD MGD Seepage Seepage Ash Basin O AUI 003 Dan > 9 MGD River 0.019 MGD West Holding Pump 0.7 MGD FGD Treated Belews Creek Steam Station August 2016-Current Flow Condition Attachment 2 Form 2C — Item II -A Description of Future Waste Flows Through Facility Storm Water 0.08 MGD 0.35 urn or 0.867 Station Equipment Low & High Pressure Hydrogen & Oil Cooler Cooling Water Service Water System Belews Reservoir Condenser Cooling Water Outfall 001 1278 MGD RCW Cooler Storm Water 0.47 0.02 MGD Intake Area M D Intake Screen Backwash Seepage Existing Ash Basin 3.85 Closure Power House Sump MGD Yard Holding Sump Consolidated Sump FGD Treated Wastewater Wastewater system Flows ° 14.2 Outfall 002 MGD MGD 0.7 MGD WaterTreatment CondenserFeedwater Water Relocate Sump I > Retention Basin Outfall 003 6.3 MGD Ammonia, Ash & Fuel Coal Yard Runoff West Holding Sump Storage Runoff 0.019 0.08 MGD 0.014 MGD MGD Coal Yard Runoff Basin Holding Basin I Dan River I Belews Creek Steam Station August 2016-Future Flow Condition Attachment 3 Narrative Description of Sources of Pollution and Treatment Technologies August 2016 NPDES application renewal Belews Creek Steam Station NCO024406 Belews Creek Steam Station, Stokes County NPDES Permit Renewal and Reissuance Attachment 3 — Supplemental Information Permit #NC0024406 August 2016 Page 1 of 9 Introduction Belews Creek Steam Station (BCSS) located in Stokes County, North Carolina, is a two -unit coal- fired electric generating plant with a capacity of 2,220 megawatts (MW). The station began commercial operations in 1974 with Unit 1 (1,110 MW) followed by Unit 2 (1,110 MW) in 1975. Cooling water for BCSS is provided by Belews Reservoir, a man-made reservoir formed when Duke Energy built the facility. Chemical constituents contained in the discharge from the permitted outfalls will, in part, be representative of the naturally -occurring chemical quality and quantity of the intake water and will also have chemical constituents of such quality associated with similar discharges for fossil generating facilities of the size, type, and in this geographical location. Either all or part of the elements in the Periodic Table, either singularly on in any combination, may from time to time be contained in the discharge. Plant waste streams are directly or indirectly discharged to either Belews Reservoir (Outfall 001) or Dan River via effluent channel (Outfall 003). Each component of the discharges are described below. Outfall 001— Condenser Cooling Water System (CCWS) Outfall 001 is the discharge from the Condenser Cooling Water System (CCWS) to Belews Reservoir. Various wastewater streams combine in the CCWS prior to discharge. These flows consist of Condenser Cooling Water (CCW), Intake Screen Backwash, Recirculated Cooling Water (RCW), Hydrogen and Oil Coolers and Station equipment cooling water. Condenser Cooling Water Raw water from Belews Reservoir is passed through condensers and auxiliary equipment on a "once -through" basis to cool equipment and condense exhaust steam from the turbines. Cooling water passes through a network of tubes in the condenser and selected heat exchangers (e.g. turbine lube oil coolers, condensate coolers, miscellaneous closed system coolers). Raw water in the condenser tubes absorbs heat from a closed system of highly purified exhaust steam from the turbines and converts it back to water. The condensed exhaust steam is returned to the boilers and recycled in this loop a number of times. The raw cooling water is returned to the reservoir. No chemicals are added and only heat rejected from the condensers and auxiliary equipment is absorbed, hence the term "once through, non -contact cooling water" is applied. The condensers at BCSS are cleaned mechanically. Normally, amertap balls clean the tubes on a continuous basis while the plant is operating. Periodically, metal scrapers, plastic scrapers or rubber plugs are forced through the tubes to rid them of scale or other deposits. Each unit at BCSS has four condenser cooling water (CCW) pumps. Normal plant operation of the CCW pumps is based on intake and discharge temperatures and unit loads. To avoid a system trip that would suddenly reduce the discharge flow at Outfall 001, each unit is on an independent system. This practice leads to higher reliability factor for the units and protection of aquatic life taking refuge in the discharge canal during cold weather. Belews Creek Steam Station, Stokes County NPDES Permit Renewal and Reissuance Attachment 3 — Supplemental Information Permit #NC0024406 August 2016 Page 2 of 9 Intake Screen Backwash Each unit has four stationary intake screens (18 ft x 23 ft) which are removed for cleaning. The intake screens are backwashed as needed at a rate of 500 gpm for approximately five minutes each. The total volume of water used is 0.02 MGD. Intake screen backwash is discharged back into the station intake. The debris removed is collected within a cleaning basin and consists of twigs, leaves, and other material indigenous to Belews Reservoir. Recirculated Coolinz Water (RCW) System The RCW system is a closed loop cooling water system. Depending on the temperature of the raw reservoir water and the operation of BCSS, once through non -contact CCW is passed through the RCW coolers to maintain the closed loop cooling water within the RCW system at <95°F. RCW system supplies cooling water to various equipment and is composed of a storage tank, three 50% capacity RCW pumps, two 100% capacity heat exchangers (RCW coolers), and associated piping and valves for the two units. Recirculated cooling water is supplied from the CCW system to the RCW storage tank (capacity of 19,000 gallons) and makeup water is added, as required per tank level and temperature controls. The maximum flow of CCW through each of the two RCW coolers is 5360 gpm or 7.72 MGD. Non -contact cooling water discharged from the RCW coolers combines with the condenser cooling water and is discharged through Outfall 001. RCW System contains maintenance chemicals in order to prevent corrosion. The primary chemical used in the RCW system is sodium nitrite. Microbiocides are also used at very low concentrations. The potential exists for the RCW system to have minor tube leaks, due to material corrosion. Tube leaks from the RCW system discharge into the CCW system, which discharges into Belews Reservoir through Outfall 001. Routine monitoring of the RCW system for nitrite concentrations and the inventory of make-up water provides input that assists in determining a tube leak. Once a leak is identified, corrective measures are implemented to minimize and repair the leak. During routine maintenance the process water from the RCW system drains to floor drains where it is pumped to the ash basin/retention basin (Outfall 003). During a leak and/or routine maintenance, the concentration of the maintenance chemical will not exceed the No Observed Effect Concentrations (NOEL) at either Outfall 001 or 003. Hydrogen and Oil Coolers Once through non -contact cooling water is supplied from the Low Pressure Service Water (LPSW) System that draws water from the CCW system to hydrogen and oil coolers. The system consists of two High Pressure Generator Hydrogen Coolers (maximum combined flow of 3,900 gpm), four Low Pressure Generator Hydrogen Coolers (maximum combined flow of 3,520 gpm), and two Turbine Lube Oil Coolers (maximum combined flow of 7,400 gpm) for each unit. A maximum of 43 MGD of cooling water can flow through these coolers when both BCSS units are operated at full load. Discharge from these coolers combines with the condenser cooling water flow and discharges through Outfall 001. Station Equipment Cooling Water Once through non -contact cooling water is supplied from the Low and High Pressure Service Water System to the bearings of the induced draft (ID) fans to remove excess heat. No Belews Creek Steam Station, Stokes County NPDES Permit Renewal and Reissuance Attachment 3 — Supplemental Information Permit #NC0024406 August 2016 Page 3 of 9 chemicals are added to the once through raw reservoir water discharged to Belews Reservoir. The rate of flow through the control equipment is approximately 0.86 MGD when both BCSS units are operated at full load. This effluent also includes chiller once through water. Containment Flushinz/Wash Waters Infrequently, service water (raw water from Belews Reservoir) will be used to test the integrity of onsite containment structures and for wash water in water trucks at the landfill site. There are no chemicals added to the service water. The water is routed back to Belews Reservoir through some stormwater drains. Internal Outfall 002—Treated FGD Wet Scrubber Wastewater The Wet Flue Gas Desulfurization (FGD) system was installed at Belews Creek in 2008 for the reduction of Sulfur Dioxide (SO2) from the stack gas. The FGD system follows the electrostatic precipitators (which removes fly ash) and also the Selective Catalytic Reduction (SCR) systems (which uses anhydrous ammonia for nitrogen oxide (NOx) control). The use of this equipment entails the use of or production of: calcium sulfite, vanadium pentoxide, calcium carbonate, and sulfur. Sulfur Dioxide is produced from the coal combustion process. The FGD system removes SO2 by a reaction using a limestone -water slurry. The FGD system will collect the flue gas after it passes through the electrostatic precipitator and route the gas to the absorber tank. As the gas rises through the tank to the outlet at the top, the gas passes through a spray header. An atomized slurry of water and limestone droplets is continually sprayed through this header into the stream of flue gas. The SO2 in the flue gas reacts with the calcium in the limestone and produces calcium sulfite (CaSO3). This CaSO3 slurry falls to the bottom of the tank where a stream of air is injected to oxidize the slurry to form gypsum (CaSO4•H20). The gypsum slurry is drawn off the absorber tank and pumped to a hydrocyclone where solids are removed and part of the slurry is sent to a vacuum belt filter for dewatering. Part of the slurry is blown down primarily to keep the FGD chloride concentration below 12,000 ppm. This waste is sent to a wastewater treatment system in order to remove solids, metals and reduce the temperature. Initially, the wastewater is sent to an equalization tank to allow for a more constant flow and solid loading to the next treatment steps. The wastewater from the equalization tank is pumped through three reaction tanks where pH is adjusted, metal treatment and coagulation occurs. In the event of a maintenance issue with the reaction tanks a bypass line will be installed to route the flow around the reaction tanks to continue treatment further downstream of the reaction tanks. After the treatment occurs in the reaction tanks, the wastewater is sent to two clarifiers in order to reduce the solid loading. Once the wastewater leaves the clarifiers the pH is readjusted and the wastewater is cooled by a heat exchanger. The treated wastewater is then pumped to a two stage biological treatment system in order to reduce the metal concentrations. The treated wastewater is mixed with the cooling water from the heat exchanger in order to reduce the chloride concentration. This treated wastewater is then discharged to the ash basin/retention basin via Internal Outfall 002. The following chemicals are utilized in the FGD wastewater treatment system: hydrated lime, ferric chloride, polymer, hydrochloric acid, and nutrients. Belews Creek Steam Station, Stokes County NPDES Permit Renewal and Reissuance Attachment 3 — Supplemental Information Permit #NC0024406 August 2016 Page 4 of 9 To comply with Federal Steam Electric Effluent Guidelines (ELG) for FGD wastewater, an ultrafiltation system will be added to the existing FDG wastewater system at a future timeframe. To comply with Federal ELG guidelines for bottom ash system, there is an allowance to route the bottom ash sluice water to FGD system. BCSS will route the bottom ash sluice water to the FGD system at a future timeframe. Bottom ash from the boilers will be sluiced to submerged flight conveyors, dewatered, and the ash solids will be landfilled. Ash sluicing water will be recirculated in a closed loop system with make-up provided from service water for evaporation and water loss through trucked transport ash moisture. More detail on these two projects and projected timeframes can be found in attached Attachment 5 - Alternate Steam Electric guidelines (ELG) Schedule Justification. To comply with CAMA 2014 and Federal CCR rule, BCSS will reroute the FGD treated wastewater to future retention basin at a future timeframe. Outfall 003 — Ash Basin and Future Retention Basin The ash basin accommodates flows from the power house sumps, yard holding sump, ash sluice lines, consolidated sump, coal yard runoff basins and sumps, occasional minor hydrated lime and/or limestone slurry system leakage, and rainfall run-off from the watershed of the basin. Seepage from the engineered toe drains and through the dam flow to the Dan River via the existing effluent channel to Outfall 003. This includes seepage identified in permit application amendments in July 2014, October 2014, and December 2014. The retention basin, upon completion will accommodates flows from the power house sumps, yard holding sump, consolidated sump, coal yard runoff basins and sumps, miscellaneous low volume wastestreams, occasional minor hydrated lime and/or limestone slurry system leakage, and rainfall run- off from the watershed of the basin. Yard Holdinz Sump Wastewater can accumulate in the yard holding sump from the power house sumps. Power House Sumps The Power House Sumps discharge to the yard holding sump and include wastewater from water treatment equipment, floor wash water, equipment cooling water, low volume waste, and miscellaneous leaks. ❖ Water Treatment System The water treatment system consist of one retention tank, three pressure filter, two activated carbon filters, one Reverse Osmosis (RO) system, and one set of makeup demineralizers. The pressure filters each have a capacity of 250 gpm. The pressure filter media is composed of rock and sand, therefore all backwash discharge to organic buildup from service water. Makeup demineralizers are operated in sequence (one cell at a time). Regeneration of these cells is required approximately every 40 days. Each regeneration requires 120 gallons of 66' Be sulfuric acid and 600 gallons of 50% sodium hydroxide. As average dilute waste chemical and Belews Creek Steam Station, Stokes County NPDES Permit Renewal and Reissuance Attachment 3 — Supplemental Information Permit #NC0024406 August 2016 Page 5 of 9 rinse flow of 0.34 MGD is realized (for two hours per regeneration). The diluted acid and caustic are discharged to the yard holding sump and then pumped to the ash basin/retention basin. The useful life of the resin varies and when replacement is needed the spent resin is sluiced to the basin. The RO system is cleaned on an as needed basis using Osmonics AD-20 (275-lbs), Biomate MBC 781 (2.5 gallons), sodium laurylsulfate (10 lbs) and sodium hydroxide (4L). ❖ Condensate Feedwater System The condensate feedwater system provides continuous flow -through boiler feedwater to BCSS supercritical pressure boilers. Condensate polishing demineralizers of the powdered resin type are used to filter feedwater. The mixed anion -cation powdered resin provides filtering and ion exchange. Spent resins and associated wastes are pumped to the ash basin/retention basin for treatment and disposal. ❖ Evaporative Losses, Soot Blowing Exhaust steam from the turbine is used periodically to blow soot off the outside of the boiler tubes. Thus, some of the condensate feedwater is evaporated in the boiler. ❖ Turbine and Boiler Room Drain System Turbine and boiler room drains receive flow from once through non -contact cooling water of the Station air conditioning system, fire protection system, washdown, and miscellaneous Station uses. Station Air Conditioning Once through non -contact cooling water is supplied from the Low Pressure Service Water System to cool the Station air conditioning equipment. A maximum combined flow of 3.46 MGD of cooling water can flow through two chiller units. No chemicals are added to the once through raw reservoir waste that drains to the Station sumps where it is pumped to the ash basin/retention basin. ❖ Fire Protection, Wash down, and Miscellaneous Station Uses The fire protection system, washdown, and miscellaneous station uses from closed system drainage, cleaning, and testing can contain: • Corrosion inhibitors, e.g. Calgon CS and Betz, Powerline 3201 • Biocides, e.g. Calgon H-300 and H-510 • Laboratory wastes • Cleanings (e.g. small heat exchangers) Dispersant, e.g. polyacrylamide • Wetting agent, e.g. disodium fluorescing dye • Detergent, e.g. tri-sodium phosphate • Leak testing, e.g. disodium fluorescing dye • Miscellaneous system leakage's (small leaks from pump packing and seals, valve seals, pipe connections) • Moisture separators on air compressor precipitators • Floor wash water Belews Creek Steam Station, Stokes County NPDES Permit Renewal and Reissuance Attachment 3 — Supplemental Information Permit #NC0024406 August 2016 Page 6 of 9 • Emergency firefighting water • Ash sluice system overflow • Low volume Wastewater ❖ Groundwater (GW) Remediation A GW remediation system was used to recover free petroleum product that leaked from a underground storage tank. A total fluids recovery system was used to recover contaminated groundwater and free product from the site. Remediation system equipment was used to remove the petroleum from the recovered groundwater, and the reclaimed petroleum was transported off -site for treatment while the treated wastewater was discharged to the ash basin/retention basin via the Power House sump. A maximum flow rate of approximately 0.03 MGD was discharged to the ash basin/retention basin from the groundwater remediation system. Remediation is complete and BCSS has closed out the system under UST Requirements. ❖ Fly and Bottom Ash Sluicing Electrostatic precipitators are used to remove fly ash from the stack gases. The ash is treated in the flue gas ductwork with SO3 conditioning to improve removal efficiency. Typically, the dry flyash captured in these precipitators is collected in temporary storage silos for subsequent disposal in a permitted on -site landfill or for recycling in off -site ash utilization projects. If the system that collect the dry -fly ash is not operating, then the fly ash can be sluiced to the ash basin. Bottom ash form the boilers is usually water sluiced to holding cells for recycling activities per reuse permit #WQ0007211. In the case of equipment failure or immediately following an outage, service water is used to sluice the ash to the ash basin. Electrostatic precipitators are normally cleaned by mechanically rapping the wires and plates inside the precipitator. Before major precipitator work is performed they are cleaned by a wash down. The wash water is pumped to the ash basin from the yard drain sumps. As a contingency measure, if the levels of regulated parameters are increasing one option that may be periodically implemented is to sluice service water (from Belews Reservoir) to the ash basin to co -manage the various waste streams that are discharging to the ash basin. To comply with Federal ELG guidelines for bottom ash system, there is an allowance to route the bottom ash sluice water to FGD system. BCSS will route the bottom ash sluice water to the FGD system at a future timeframe. Bottom ash from the boilers will be sluiced to submerged flight conveyors, dewatered, and the ash solids will be landfilled. Ash sluicing water will be recirculated in a closed loop system with make-up provided from service water for evaporation and water loss through trucked transport ash moisture. Coal Yard Runoff Basin and Sumps The coal yard covers approximately 51.5 acres. The average rainfall run-off is 0.08 MGD. This run-off is based on 40 inches of rain per year with 50% run-off. During winter, freeze conditioning agents (i.e. diethylene glycol) may be added to coal by a vendor prior to shipment or sprayed on the coal pile to prevent freezing. Based on an application rate of two pints of 50 ppm diethylene glycol per ton of coal and 10,000 tons of coal per train load, the addition of Belews Creek Steam Station, Stokes County NPDES Permit Renewal and Reissuance Attachment 3 — Supplemental Information Permit #NC0024406 August 2016 Page 7 of 9 freezing agents will not significantly alter the coal pile run-off waste stream and the discharge of the ash basin/retention basin at Outfall 003. Floor wash water from equipment in the coal handling area and the remaining drainage from the coal yard flows to the coal yard sumps where it is then pumped to the ash basin/retention basin. An anhydrous ammonia vapor suppression system is used in case of emergency release from the anhydrous ammonia tanks. The system is set to activate at a concentration of 300 ppm of ammonia. During normal operations intermittent low volume discharges of ammoniated water generated during product delivery and quarterly system testing offloading of anhydrous ammonia is collected in two aboveground collection tanks. These tanks are refreshed by adding water and draining tanks simultaneously until conductivity is lowered. For an emergency situations the water is collected in the tank farm containment and then drained through the sump into the North coal yard sump where it is pumped to the ash basin/retention basin. Service water is pumped from Belews Reservoir. Consolidated Sump The consolidated sump includes wastewater from the sanitary waste system, the stormwater collection pond, the limestone unloading facility sump and leachate from the dry fly ash and gypsum landfills. The wastewater is pumped to a two train 18 acre Constructed Wetland Treatment System (CWTS) prior to discharge to the ash basin/retention basin. The sanitary waste for the plant received primary treatment in a 600,000 gallon capacity aerated lagoon. The lagoon discharges to a concrete chlorine contact chamber. To polish the effluent, the sanitary waste system routes a circuit of water treated with chlorine to the consolidated sump which is routed to the ash basin/retention basin. The expected flow from the sanitary treatment system is less than 10,000 gallons per day. The stormwater collection pond collects stormwater run-off form the gypsum and limestone stockpiles as well as some of the limestone track area around the unloading facility. If the pumps for the sump fail, there is an overflow to Belews Reservoir, possibly resulting in intermittent discharge. There are two on -site landfills at Belews Creek, the FGD Residue landfill and the Craig Road Ash landfill. These landfills are located southeast of the power station. The leachate and the contact stormwater from these landfills is collected and pumped to the ash basin/retention basin. The FGD Residue landfill accepts gypsum. The Craig Road Ash landfill stores flyash, gypsum, that is not suitable for beneficial use and clarifier sludge from FGD wastewater treatment system. This material is filter pressed before it is placed in the landfill. Both landfills began operation in 2008. Ash Basin Run-off Natural drainage area of Ash Basin is 655 acres. Station yard drainage area pumped to the Ash Basin is 87.6 acres. Based on forty inches of rain per year with fifty percent run-off and the watershed area of the ash basin, the yearly average rainfall run-off to the ash basin is approximately 0.47 MGD. Belews Creek Steam Station, Stokes County NPDES Permit Renewal and Reissuance Attachment 3 — Supplemental Information Permit #NC0024406 August 2016 Page 8 of 9 Groundwater Extraction Well System Duke Energy is currently designing an extraction well system to provide accelerated groundwater remediation. The extracted groundwater will be treated prior to discharge through outfall 003. Treatment of the discharge may be provided by introducing the groundwater as a waste stream to the ash basin/retention basin or a new direct groundwater treatment system. Boiler and Filter Cleaninz Wastes BCSS has two supercritical boilers that are cleaned on an as needed basis. Tube inspections are done during outages to determine when cleaning is needed. The chemical cleaning wastes are collected for off -site disposal by third party vendor. The chemicals and approximate amounts for one boiler cleaning are as follows: Chemical Amount Hydroxyacetic Acid 50,312 lbs Formic Acid* 20,598 lbs Ammonium Hydroxide*(26°Bd") 2,063 lbs Ammonium BiFlouride* 4,249 lbs Hydrazine 718 lbs Corrosion Inhibitor (Proprietary) 500 lbs The Reverse Osmosis (RO) system is used to treat raw water from Belews Reservoir. The RO system is cleaned approximately 4-6 times per year. The RO cleaning wastes are pumped to the ash basin/retention basin. Chemical and approximate quantities for one RO cleaning are listed below: Chemical Amount Osmonics AD-20 275 lbs Biomate MBC 781 2.5 gal Sodium Laurylsulfate 10 lbs Sodium Hydroxide* 15 gal The condensate polisher filters are cleaned with sodium hydrosulfite approximately once every five years. The chemicals and approximate quantity used per year for this cleaning is listed below: Chemical Amount Sodium Hydrosulfate 3,000 lbs Belews Creek Steam Station, Stokes County NPDES Permit Renewal and Reissuance Attachment 3 — Supplemental Information Permit #NC0024406 August 2016 Page 9 of 9 *These chemicals are present in amounts greater than the reportable quantity as identified under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). If a spill of any of these chemicals were to occur, in most cases, the spill would be routed to the ash basin/retention basin for treatment. These chemicals are being identified to qualify for the spill responsibility exemption under 40 CFR 117 and CERCLA. \ Hazardous and Toxic Substances Table 2c-3: At BCSS, the potential for toxic and hazardous substances being discharged is very low. In reference to Item V-D of Form 2-C, the substances identified under Table 2c-3 that may be in the discharge are as follows: Acetaldehyde, Asbestos, Benzoyl Chloride, Butyl Acetate, Cresol, Cyclohexane, Cyclohexanone, Epichlorohydrin, Fornaldehyde, Furfural, Monoethyamine, Naphthenic Acid, Pyethrins, Styrene, Triethanolamine, Vanadium, Vinyl acetate, Xylene, and Zirconimum and also during the course of the year products such as commercial cleaners and laboratory reagents may be purchased which contain very low levels of a substance found in Table 2c-3. It is not anticipated that these products will impact the ash basin/retentions basin's capacity to comply with its toxicity limits, since their concentrations are extremely low. 40 CFR 117 and CERCLA Hazardous Substances: The table below identifies hazardous substances located on -site that may be released to the ash basin/retention basin during a spill in quantities equal to or greater than the reportable quantity (RQ) levels as referenced in 40 CFR 117, 302 and 355. This list is being provided in order to qualify for the spill report ability exemption provided under 40 CFR 117 and the Comprehensive Environmental Response Compensation and Liability Act (CERCLA). These values below represent the maximum quantities on -site that could be released at one time and sent to the ash basin/retention basin. They do not reflect quantities that are discharged through typical use. CHEMICAL AMOUNT OW SOURCE Ammonia 4,055,000 General Site Sodium 10 Warehouse Sodium Hydroxide 25,520 Water Treatment Room Sulfuric Acid 61,228 Water Treatment Room Ash Basin Capacity Part III Section R of the existing NPDES permit for BCSS requires the permittee to provide and maintain at all times a minimum free water volume (between the top of the sediment level and the minimum discharge elevation) equivalent to the sum of the maximum 24 hour plant discharge plus all direct rainfall and all run-off flows to the ash basin resulting from a 10 year, 24 hour rainfall event, when using a run-off coefficient of 1.0, see Attachment 9 - Ash Basin Free Water Volume Calculation. Attachment 4 Alternate Schedule Request for 316(b) August 2016 NPDES application renewal Belews Creek Steam Station NCO024406 Attachment 4 - Alternate Schedule Request §316(b) of the Clean Water Act Belews Creek Steam Station Final regulations to establish requirements for cooling water intake structures at existing facilities were published in the Federal Register on August 15, 2014 (i.e. regulations implementing §316(b) of the Clean Water Act) with an effective date of October 14, 2014. Per §125.91(a)(1)-(3) Applicability, the Belews Creek Steam Station (BCSS) is subject to the requirements at §125.94 through §125.99 (316(b) requirements) based on the following: The facility is defined as an existing facility (i.e. commenced construction prior to January 17, 2002); — The facility is a point source discharge; The facility uses a cooling water intake with a design intake flow (DIF) of greater than 2 million gallons (MGD) to withdraw water from waters of the U.S.; and Twenty-five percent or more of the water withdraws on an actual intake flow basis are exclusively used for cooling purposes. Per §125.98(b) Permitting requirements, 316(b) requirements are implemented through the NPDES permit. Facilities subject to the final rule are required to develop and submit application materials identified at §122.21(r). The actual intake flow (AIF) of the facility determines which submittals will be required. Facilities with an AIF of 125 MGD or less are required to submit material identified at §122.21(r)(2)-(8), whereas, facilities with an AIF greater than or equal to 125 MGD are required to submit materials presented in §122.21(r)(9)-(13), in addition to information identified at §122.21(r)(2)- (8). The AIF withdrawn by the station from Belews Creek Reservoir is above the 125 MGD threshold; therefore, Duke Energy is planning on completing the following 316(b) submittals: • §122.21(r)(2) Source Water Physical Data • §122.21(r)(3) Cooling Water Intake Structure Data • §122.21(r)(4) Source Water Baseline Biological Characterization Data • §122.21(r)(5) Cooling Water System Data • §122.21(r)(6) Chosen Method(s) of Compliance with Impingement Mortality Standard • §122.21(r)(7) Entrainment Performance Studies • §122.21(r)(8) Operational Status • §122.21(r)(9) Entrainment Characterization Study • §122.21(r)(10) Comprehensive Technical Feasibility and Cost Evaluation Study • §122.21(r)(11) Benefits Valuation Study • §122.21(r)(12) Non -water Quality and Other Environmental Impacts Study • §122.21(r)(13) Peer Review The regulation states the owner of a facility whose current effective permit expires after July 14, 2018, must submit the above information when applying for a subsequent permit and the owner of a facility whose current effective permit expires on or before July 14, 2018 may request an alternate schedule for the submission of the above information. As allowed under §125.95(a)(2), Duke Energy would like to request an alternate schedule for the submittals listed above. Duke Energy would like to request the 316(b) submittals, with the exception of §122.21(r)(6) Chosen Method(s) of Compliance with Impingement Mortality Standard, for BCSS be required with the subsequent permit renewal application due after July 14, 2018. Since BCSS is subject to the entrainment best technology available (BTA) determination, a compliance schedule to complete §122.21(r)(6) Chosen Method(s) of Compliance with Impingement Mortality Standard will be requested to be included in the permit upon issuance of the entrainment BTA determination. The alternate schedule request is justified based on the following: Information requested in §122.21(r)(2), (3), and (5) were completed under the remanded rule; however, this information must be updated to reflect current operations and information requested in §122.21(r)(4) is substantially different from the remanded rule. Information requested in §122.21(r)(6) — r(12) are new provisions and these submittals must be developed. For the §122.21(r)(13) Peer Review, Duke Energy estimates this could take up to 12 months to complete. This, also, takes into account the other six Duke Energy stations in N. Carolina and two stations in S. Carolina that will be undergoing the peer review process concurrently. Additionally, the United States Environmental Projection Agency (USEPA) — Headquarters (HQ) have indicated guidance is being prepared to assist in interpreting and implementing the rule requirements, however, this guidance is not expected to be issued until the 316(b) litigation is completed, which is not expected to occur until 2017. 1 Refer to §125.95(a)(1) and (2) Attachment 5 Alternate Steam Electric Effluent Guidelines (ELG) Schedule Justification August 2016 NPDES application renewal Belews Creek Steam Station NCO024406 Dishmon, Joyce Martin From: Craig, Nathan D Sent: Monday, August 15, 2016 3:27 PM To: Dishmon, Joyce Martin Cc: Kennedy, William; Henderson, Derek L; Langley, Shannon; Baker, Richard E Jr Subject: BC ELG Applicability Justification Attachments: BCSS Extension Justification 8 15 16.docx Please find attached the Belews Creek ELG applicability date justification. We are requesting the following applicability dates: Bottom Ash Transport Water: May 31, 2021 (based on 54 months from an effective permit date of Dec. 1, 2016) FGD Wastewater: November 30, 2020 (based on 48 months from an effective permit date of Dec. 1, 2016) Fly Ash Transport Water: November 1, 2018 Breakdown of the schedule for BATW and FGD wastewater is provided below. Please let me know if you have any comments or concerns. Nathan Craig Lead Environmental Specialist, Environmental Programs Duke Energy Corporation 1 526 South Church St. I Charlotte, NC 28202 0: 704-382-9622 1 nathan.craig@duke-energy.com Remote Mechanical Drag System (RMDS) Activity Duration (Months) Design' 6 • Siting 3 • Engineering 5 Procurement 12 Potential Permitting Delays 6 Construction/Tie-in 13 Optimization & Operational Experience 17 • Commissioning 2 • Start -Up 6 Total: 54 1) The design tasks has been initiated and Duke estimates an additional 6 months from the permit effective (assuming Dec. 1, 2016) will be needed to complete the design. 2) Even though is it estimated that commissioning and start-up can occur in 8 months, Duke anticipates needing a 17 month window to obtain the necessary operating time at full load and account for commissioning / optimizing occurring at multiple facilities simultaneously. FGD WWT Upgrade Activity Duration (Months) Design & Engineering 21 • Evaluate Variability in the System 12 • Technology Evaluation 7 • Engineering 2 Procurement 8 Construction/Tie-in 7 Start-up & Optimization' 12 • Start -Up 2 • Commissioning 6 Total: 48 1) Duke is allocating a 12 month window to complete the commissioning and start-up under all expected operating conditions from full load to partial load to periods of no load and under varying fuel types.