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1.0062263694294868 1.0062548354215215 1.0062827313279452 58 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1000000000000001 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2 2.1 2.2000000000000002 2.2999999999999998 2.4 2.5 2.6 2.7 2.8 2.9 3 3.1 3.2 3.3 3.4 3.5 3.6 3.7 3.8 3.9 4 4.0999999999999996 4.2 4.3 4.4000000000000004 4.5 4.5999999999999996 4.7 4.8 4.9000000000000004 5 5.0999999999999996 5.2 5.3 5.4 5.5 5.6 5.7 5.8 5.9 6 6.1 9/11/2013 10/30/2013 80 51.612903225806448 42.193548387096776 18.600000000000001 24.999999999999996 25 26.490857300376735 30.595351798790194 25 25 25 25 25 24.999999999999996 0.14894186714057803 0.81798763542966491 0.25249557720918481 0.58987911307921359 3.239611736850295 0.14894186714057803 0.50864341996156726 0.25249557720918481 0.58987911307921359 2.0144646713560923 23.813113368978001 183.06590693171381 0.20226449122363688 117.73254526741752 905.0817858548595 11 16 1 11 16 2.7393136541333787 3.6400696193855371 0.34760044138413848 7.8806391707256838 10.471993662870069 0.54096834392178628 13.882172793482731 0.18390125003894109 2.94162407165387 75.487104032969768 16.095897708649439 144.91783768523806 0.43232123555859853 37.231337220463082 335.20869614001487 25 0.06 0.29639788810883572 1 0.06 0.29639788810883572 36.497894063420418 36.201765105502204 0.28798937317506229 126.73347513150829 125.70521164159749 6.5 65 1 6.5 65 150 340 1 150 340 4Date: 1040000 -0.74360000000000004 1250000 -0.70379999999999998 2800000 -0.8 3360000 -9.3039999999999998E-2 4000000 -1.1307 490000 -0.57189999999999996 0.252 0.20200000000000001 1 0.34799999999999998 0.184 0.432 1 0.28799999999999998 n BDL=1/2DL Std Dev. Mean Stream Class C.V. Mult Factor = Max. Pred Cw Max. Value Data Cyanide PQL RECOMMENDED ACTION PARAMETER 30Q2 (cfs) Max Pred Cw n = Interpolate to find Mult. Factor cv = value 1 address = value 1 = value 2 address = value 2 = Interpolated MF value = PRELIM. RESULTS which truncates to Pick upper & lower Mult. Factors and interpolate: Round to 2 dec. places to get MF: Date Results REASONABLE POTENTIAL RESULTS Allowable Cw No limit (Action Level parameter) No limit MaxPredCw << Acute MaxPredCw < Acute MaxPredCw > Chronic MaxPredCw < Chronic Monitoring not necessary in permit MaxPredCw << Chronic Hit(s) # Det. Monitor 1/month Revise daily max. limit C Monitor 1/week Continue to monitor at 2/month Monitor 2/month No limit - assuming no tox (Action Level parameter) Units ug/L Facility Name Acute: Chronic: MaxPredCw >> Chronic MaxPredCw > Acute MaxPredCw >> Acute N/A REMOVE? MONITOR? DAILY MAX LIMIT? MO AVG LIMIT? NO DATA Daily max limit Mo. avg. limit (keep wk. avg. if existing) Sample recommendations: LTMP Y N Monitoring Frequencies 2B .0500 Parameter Location Class I Class II Class III Class IV Frequency Effluent Limited pH E 2/Month Daily 3/Week Temp, C BOD5 TSS NH3-N Fecal Col. TN TP Water Quality Limited D.O. TRC Conductivity I, E U, D 1/Week 1/Month See notes below. 2/Week 3/Week* Notes: TN, TP Monitoring All facilities >= 0.05 MGD will monitor TN and TP Those < 0.05 MGD will monitor if discharging to NSW For French Broad, Broad, Savannah, New Watauga, Little Tennessee, and Hiwassee: - >= 0.05 MGD - monitor semi-annually >= 1.0 MGD - monitor quarterly For all other river basins: - monitor monthly * Upstream and downstream monitoring in WQ-limited waters is to be conducted 3/Week during Jun, Jul, Aug, and Sep; and 1/Week during the rest of the year.</t For the Neuse, Tar-Pamlico, and any other river basins classified as NSW, use limits and monitoring requirements according to the basin's permitting strategy.</t>< 7Q10s (cfs) 7Q10w (cfs) QA (cfs) Receiving Stream Type Chronic Modifier Acute NPDES Permit Outfall Flow, Qw (MGD) Name Msg02 Msg03 Msg07 Msg04 Msg08 Msg05 Msg09 Msg06 Msg01 Msg10 Msg00 Fac_Name IWC_30Q2 =rpa!$L$8 IWC_7Q10s =rpa!$L$6 IWC_7Q10w =rpa!$L$7 IWC_QA =rpa!$L$9 NPDES Stream_Class WWTP_Grade No chronic standard or criterion No acute standard or 1/2 FAV < No Data Entered > Workbook Names: Table 1. Project Information Table 2. Parameters of Concern =input!$B$10 =input!$B$11 =input!$B$12 =input!$B$13 =input!$B$14 =input!$B$5 =input!$B$6 =input!$B$7 =input!$B$8 =input!$B$9 =input!$E$5:$K$5 =input!$E$6:$K$6 =input!$E$7:$K$7 =input!$E$8:$K$8 =input!$E$9:$K$9 =input!$E$10:$K$10 =input!$E$11:$K$11 =input!$E$12:$K$12 =input!$E$13:$K$13 =input!$E$14:$K$14 =input!$E$15:$K$15 =input!$E$16:$K$16 =input!$E$17:$K$17 Find row in M.F. Table - Find column in M.F. Table - Data Source(s) Par02 Par03 Par04 Par05 Par06 Par07 Par08 Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Par18 Par19 =input!$E$18:$K$18 =input!$E$19:$K$19 =input!$E$20:$K$20 =input!$E$21:$K$21 =input!$E$22:$K$22 1Q10s (cfs) Jan. 09 < Feb. 09 PQL = 10 No PQL or a lower PQL of 9 Per Memo Dated 7-15-2010 Arsenic FW HH Beryllium NC Cadmium Fluoride Lead Mercury ng/L Molybdenum Nickel A Selenium Par20 Par21 Par22 Qw (MGD) = 1Q10S (cfs) = 7Q10S (cfs) = 7Q10W (cfs) = 30Q2 (cfs) = Avg. Stream Flow, QA (cfs) = Receiving Stream: Stream Class: TR WS WWTP/WTP Class: =input!$B$16 _1Q10__cfs _7Q10s__cfs _7Q10w__cfs _30Q2__cfs Qw__MGD QA__cfs =input!$B$15 HQWF Par_01 Par_02 Par_03 Par_04 Par_05 Par_06 Par_07 Par_08 Par_09 Par_10 Par_11 Par_12 Par_13 Par_14 Par_15 Par_16 Par_17 Par_18 Par_19 Par_20 Par_21 Par_22 =input!$E$23:$K$23 =input!$E$24:$K$24 =input!$E$25:$K$25 =input!$E$26:$K$26 =input!$E$5:$E$26 =input!$G$5:$G$26 =input!$F$5:$F$26 =input!$H$5:$H$26 =input!$I$5:$I$26 =input!$J$5:$J$26 =input!$K$5:$K$26 =input!$N$6 =rpa!$L$5 IWC_1Q10S Print_Area Print_Titles =rpa!$C1:$P$99 =rpa!$1:$2 RPA Tab only: INPUT Tab only: =input!$A$1:$K$26 DATA Tab only: =data!$A$2:$GP$204 Receiving_Stream No Data (new Permit, New Waste Stream) - apply Monthly Monitoring, Pollutant of concern Follow directions for data entry. In some cases a comment menu list the available choices or a dropdown menu will provide a list you may select from. Error message occur if data entry does not meet input criteria. RPALIST _Data01 _Data02 _Data03 _Data04 _Data05 _Data06 _Data07 _Data08 _Data09 _Data10 _Data11 _Data12 _Data13 _Data14 _Data15 _Data16 _Data17 _Data18 _Data19 _Data20 _Data21 _Data22 =data1$D5:$D$204 =data1$M5:$M$204 =data1$V5:$V$204 =data1$AE5:$AE$204 =data1$AN5:$AN$204 =data1$AW5:$AW$204 =data1$BF5:$BF$204 =data1$BO5:$BO$204 =data1$BX5:$BX$204 =data1$CG5:$CG$204 =data1$CP5:$CP$204 =data1$CY5:$CY$204 =data1$DH5:$DH$204 =data1$DQ5:$DQ$204 =data1$DZ5:$DZ$204 =data1$EI5:$EI$204 =data1$ER5:$ER$204 =data1$FA5:$FA$204 =data1$FJ5:$FJ$204 =data1$FS5:$FS$204 =data1$GB5:$GB$204 =data1$GK5:$GK$204 Û REQUIRED DATA ENTRY USE MENU BUTTON TO SELECT POSSIBLE "RECOMMENDED ACTION" =rpa1$y$64:$y$77 UNITS TYPE (1) Applied Standard PAR # NO WQS HH/WS Total Phenolic Compounds For all dischargers to all waters of the state: For dischargers to Water Supply (WS) streams that chlorinate the effluent: The following is a list of Chlorinated Phenolic Compounds detected using US EPA Method 625: at 1.0 ug/L. Concentrations of all chlorinated phenolic compounds, detected above the PQL, using US EPA Method 625 data , should be summed * and compared to the 1.0 ug/L water supply water quality standard for “ chlorinated phenolic compounds”. (EPA Parameter Code: 34034) Additional chlorinated phenolic compounds MAY be reported. < If reported above the PQL, the additional chlorinated compounds should be added to the five chlorinated compounds listed above to calculate the total chlorinated phenolics in the sample. NOTE: these additional compounds are NOT required to be reported by 40 CFR Part 136 regulations for US EPA Method 625. summed with the chlorinated data for comparison to the Water Supply standard for chlorinated phenolics: Narrative a esthetic “ Total Phenolic Compounds” water quality standard (300 ug/L). Data should be supplied using US EPA Method 420.1 (colorimetric) or US EPA Method 420.4 (automated colorimetric), and will be labeled “Phenols” or “Total Recoverable Phenolics”. (EPA Parameter Code: 32730) “ Chlorinated Phenolic Compounds” in Water Supply classified waters is an a esthetic standard * The following US EPA Method 625 reported non-chlorinated phenolic compounds SHOULD NOT be 4-chloro-2-methylphenol 6-chloro-3-methylphenol</t></si> 3-chlorophenol 4-chlorophenol 2,3-dichlorophenol </t></si> 2,3,6-trichlorophenol 2,4,5-trichlorophenol 2,3,4,6-tetrachlorophenol</t></si> 2,5-dichlorophenol 2,6-dichlorophenol 3,4-dichlorophenol </t></si> p-cresol (4-methylphenol)     o-cresol (2-methylphenol)           </t></si> 2-Nitrophenol 4-Nitrophenol Phenol </t></si 2,4-Dimethylphenol 2,4-Dinitrophenol 2-Methyl-4,6-dinitrophenol </t></si 4-chloro-3-methylphenol pentachlorophenol</t></si>< mg/L No RP , Predicted Max ≥ 50% of Allowable Cw - apply Quarterly Monitoring No RP , Predicted Max ≥ 50% of Allowable Cw - defer to LTMP No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required RP for Limited Dataset (n<8 samples) - apply Quarterly Monitoring RP for Limited Dataset (n<8) but 2 values > Allowable Cw - apply Monthly Monitoring with Limit WWTP/WTP Class ppt µg/L lb/d rdb Use "PASTE SPECIAL-Values" then "COPY" . Maximum data points = 58 Statistically 58 points are the maximum number of points allowed under this RPA program. Data fields were estbalished to allow only 58 data point entries. All worksheets are "Protected" Reasonable Potential Multiplying Factors - Calculator Confidence Level Upper Boundary of the Effluent Distribution (Percentile Value Not To Exceed) Coefficient of Variation The "mf calculator" is password "Protected" MAXIMUM DATA POINTS = 58 New freshwater RPA based on 95% probability/95% confidence 1) assumes only chroinc dilution known A. When Model is applied (Check box activated): B. When Model is not applied (Check box NOT activated): OTHER CHANGES FROM PREVIOUS RPA PROGRAM: Additional messages will appear to alert user if more than 58 data points were enter and no predicted values will be calculated C. When paremeter's "Impaired?" check box is activated: 2) does NOT make any automatic adjustements to WQS calculations 1) automtically activtes the "IMPAIRED" message alert on the "RPA" page for that parameter 2) assumes user will insert appropriate flow values for "7Q10s (cfs)", "7Q10w (cfs)", "30Q2 (cfs)", "QA (cfs)" to define chronic dilution in terms of " IWC %" , "IWC %" is the same for all stream flows NOTE: If new or expanding discharge and receiving stream impaired, will need to evaluate if additional waste load is allowed 3) automatically assigns the entered chronic IWC % to the "IWC @ 7Q10s", "IWC @ 7Q10w", "IWC @ 30Q2", "IWC @ QA" values used in chronic WQS calculations (See "RPA" page) 3) "1Q10s (cfs)" automatically defaults to no acute dilution, acute IWC = 100% , "IWC @ 1Q10s" = 100% which is used in acute WQS calculatons (See "RPA" page) 3) automatically calculates chronic-based IWC % for the "IWC @ 7Q10s", "IWC @ 7Q10w", "IWC @ 30Q2", "IWC @ QA" values used in chronic WQS calculations (See "RPA" page) 1) assumes user will insert appropriate flow values for "7Q10s (cfs)", "7Q10w (cfs)", "30Q2 (cfs)", "QA (cfs)" , "Flow Qw (MGD) " for chronic IWC % calculations, IWC % will vary according to flows 3) "1Q10s (cfs)" is automatically calculated bases on entered "7Q10s (cfs)" flow 4) automatically calculates acute-based IWC% for the "IWC @ 1Q10s" value used in acute WQS calculations (See "RPA" page) 2) Added new calculation feature to count nondetects when both "<" and a value are entered for each data set, used to calculate detected entries 1) Amended "ERR" alert on data sets entreies to activate if "<" entered but no value entered, does not effect RPA calculation, ERR message only 3) Amended "Comments" drop down menu - per Juile 4) Turned the Chronic toxicity concentration message off on the RPA page - per Julie 2/10/14: ON "data" page changed highlighted area from blue shades to gray 5/2/14 rdb 1) Increased rounding factor on all calculated IWC% to 7 decimals 2) Increased display for all calkculated to 6 decimals places. 5/5/14 rdb Increased rounding factor on all calculated IWC% to 9 decimals 5/21/14 rdb Removed ROUND function from all IWC% calculations 7/31/14 rdb Moved RPA page tile blocks down one row so header text was separated Combined Hardness Chronic Combined Hardness Acute In accordance with Federal Regulations, permit limitations must be written as Total Metals per 40 CFR 122.45(c) Receiving Stream summer 7Q10 (CFS) Receiving Stream summer 7Q10 (MGD) Rec. Stream Total Suspended Solids -Fixed Value-(mg/L) Combined Hardness chronic (mg/L) Combined Hardness Acute (mg/L) Instream Wastewater Concentration (Chronic) Instream Wastewater Concentration (Acute) 1Q10 Flow Limit [MGD] 10 Dissolved Metals US EPA Translators - using Default Partition Coefficients (streams) Maximum Allowable Effluent Concentration (MAEC) as a Total Metal = Dissolved Metal ÷ Translator [ug/l] Cd -Trout streams</t> Chromium VI Chromium, Total Beryllium Arsenic (d) Dissolved Metals & Hardness Determination v. 5/27/2010</t></si><si><t>I. How to Determine Hardness for use with Dissolved Freshwater Standards for Permitting Purposes</t></si><si><r><t>HARDNESS - Use 25 mg/L, express I. How to Determine Hardness for use with Dissolved Freshwater Standards for Permitting Purposes HARDNESS - Use 25 mg/L, expressed as CaCO 3 or Ca+Mg, as the default Hardness OR To determine a Hardness value for permit limit development, use the following equation: < Hardness        = </ (Hardness instream (a) , mg/L * 7Q10, MGD)+(Hardness effluent (b) , mg/L* Plant flow, MGD) ( mass balance ) (7Q10, MGD + Plant flow, MGD)</t></r></si><si><t>(a)    Use the median instream Hardnes (a)    Use the median instream Hardness value of the ambient 8-digit HUC data collected by the Division of Water Quality.  To find the 8-digit HUC hardness value for your facility, Click Here. (b)    For the purpose of this estimation, use the facility's median effluent Hardness value, if available.  The Division will request the permittee to sample effluent hardness once/month and submit one to two years of data with the permit renewal application. If no effluent hardness data is submitted, a default of 25 mg/L will be applied. II. To Develop Dissolved Metal concentrations for permitting purposes use the Freshwater Standards for Hardness Dependent Metals listed in Table A below. Table A: Dissolved Freshwater Standards for Hardness Dependent Metals Metal Cadmium, Acute {1.136672-[ln hardness](0.041838)} · e^{0.9151 [ln hardness]-3.1485}  Cadmium, Acute (Trout Waters) {1.136672-[ln hardness](0.041838)} · e^{0.9151[ln hardness]-3.6236} Cadmium, Chronic {1.101672-[ln hardness](0.041838)} · e^{0.7998[ln hardness]-4.4451} Chromium III, Acute 0.316 · e^{0.8190[ln hardness]+3.7256} Chromium III, Chronic 0.860 · e^{0.8190[ln hardness]+0.6848} Copper, Acute 0.960 · e^{0.9422[ln hardness]-1.700} Copper, Chronic 0.960 · e^{0.8545[ln hardness]-1.702} Lead, Acute {1.46203-[ln hardness](0.145712)} · e^{1.273[ln hardness]-1.460} Lead, Chronic {1.46203-[ln hardness](0.145712)} · e^{1.273[ln hardness]-4.705} Nickel, Acute 0.998 · e^{0.8460[ln hardness]+2.255} Nickel, Chronic 0.997 · e^{0.8460[ln hardness]+0.0584} Silver, Acute 0.85 · e^{1.72[ln hardness]-6.59} Silver, Chronic Not applicable Zinc, Acute 0.978 · e^{0.8473[ln hardness]+0.884} Zinc, Chronic 0.986 · e^{0.8473[ln hardness]+0.884} Complete information on all the proposed Surface Water Quality Standards can be viewed at: http://h2o.enr.state.nc.us/csu/trirev_SW.html. US EPA Translators using Default Partition Coefficients (DPC) v. 6/2/2010</t></si><si><r><t xml:space="preserve">Translator equation using Default Partition Coefficients = </t></r><r><rPr><sz val="12"/><rFont val="Tahoma"/><fa Translator equation using Default Partition Coefficients = </ 1                        </t></r></si><si><r>< [1 + (Kpo * TSS </t></r><r><rPr><vertAlign val="superscript"/><sz val="12"/><rFont val="Ta (1+ a ) * 10 -6 )] Kpo and  a  are constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A default value of 10 mg/L Total Suspended Solids (TSS) will be used. Table A contains the Default Partition Coefficients for the equation. Table B contains the calculated translators using the default partition coefficients for streams. TABLE A. Default Partition Coefficients STREAMS Metal (1) Kpo a Cu Zn Pb Cr (III) (2) Cd Ni (1) Delos, C.G., et al. Technical Guidance for Performing Waste Load Allocations. Book II: Streams and Rivers. Chapter 3: Toxic Substances, For the U.S. EPA. (EPA-440/4-84-022)</t (2) Linear partition coefficients shall not apply to the Chromium VI numerical criterion. The approved analytical method for Chromium VI measures only the dissolved form. Therefore, permit limits for Chromium VI shall be expressed in the dissolved form.  See 40 CFR § 122.45(c)(3).</t TABLE B. US EPA Translators Using stream Default Partition Coefficients TSS = 10 mg/L Chromium III Copper Silver Zinc Trout Water Supply Human Health Water Supply Aquatic Life WQS Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Human Health COMBINED HARDNESS (mg/L) 9/9/15: COMPLETED REVISIONS FOR METAL TRANSLATOR FEATURE 1) Added tabs for "HUC Hardness" (lookup table for HUC hardness values), "Hardness Equations" (summary of translator formulas, metals impacted, general info), "Dss to Total Hardness Calculator" (calcution sheet for metal translator, impacted chronic and acute wqs)</ 2) Revised "Input" page Table 1: 3) Revised "Input" pade Table 2: - Removed Par01 "Arsenic" line - Revised Par02 " Arsenic" line to reflect Human Health and Water Supply criterion, Chronic = 10 mg/L, Acute = "N/A" - Revised Par04 "Cadmium" line: a) "WQS" input with drop down menu to select applicable criterion c) "Modifier" input display only based on "WQS" selection including conditional method for info dispaly - Revised Par05 "Chloride (AL)" line: b) "Chronic" display only for applicable value including conditional method for info display based on "WQS" selection d) "Name" display only based on "WQS" selection including conditional metdod fro info display - New user input for "8 Digit HUC Number" uisng drop down menu for lookup HUC Hardness, required entry, brown highlight - New display only for calculated "Effluent Hardness (Median)" including conditional method for info display, brown highlight - New display only for designed "HUC Hardness (Median)" incuding conditionla method for info display, brown highlight - New display only for calculated "Combined Hardness Chronic" for metal translator application, brown highlight - New display only for calculated "Combined Hardness Acute" for metal translator application, brown highlight d) Conditonal controls to activate error nessages, brown highlight - Added new column for "WQS" designation incuding assigning applicable WQS where fixed - Added new error message "CHECK WQS", conditonal control based on "WQS" entry for Cadmium, Chlorides, Molybdeum, Nickel - Revised text in error message - Revised "Chromium, Total" line: a) Removed Par08 label - Added new "Chromium III" line: c) brown highlight b) brown highlight a) Assigned Par08 label, applicable text in "WQS", "Type", Modifier", Units" a) Assigned applicable text in "WQS", "Type", Modifier", Units" - Revised Par09 "Copper (AL)" line: - Added new Par08 "Chromium VI" line: - Revisd Par12 "Lead" line: - Revised Par15 "Nickel" line: - Revised Par14 "Molybdenum" lime: e) Conditonal controls to activate error nessages d) Conditonal controls to activate error nessages - Revised Par17 "Silver (AL)" line: - Revised Par18 "Zinc (AL)" line: - Added new brown highlight "Metal Translator Data Entry" label box 3) Revised "Data" page: a) Reference to Par01 "Arsenic" removed b) New label "Effluent Hardness (monthly average)" added c) "Mult Factor =" and "Max. Pred Cw" removed, text and calcuation d) "10% value" and "Median value" added, text and calculation including conditional method for info display e) Assigned name "Effluent_Median" and "effluent_10" to calculated values - Revised Par01 "Arsenic" entry, text, and calculations ("1") - all effluent hardness data to be entered in this section for used to calculate eflluent hardness factors - Removed "Impaired ?" column, conditional display, references 4) Revised "RPA" page: - Removed all features assocaited with "Impairment" - Added new display only for calculated "COMBINED HARDNESS (mg/L)", Chonic and Acute, conditional method for info display - Assigned name for "HUC Number" - Revised "Receiving Stream" display to include selected HUC Number in text - Removed unused display features for WET % (previouly hidden) - Revised "Arsenic" lines: a) Par01 "Arsenic" line removed b) "Allowable Cw" Acute" and "Chronic" conditional metfhod revised fro info display inculding rounding value - Revised "Cadmium", "Chromium VI", "Copper (AL)", "Lead", "Nickel", "Silver (AL)", "Zinc (AL)" llines: b) Par02 "Arsenic" references used for display to calculate "Acute" and Chronic" allowable Cw a) "NC WQS/Chronic" and 1/2 FAV/Acute" conditional method revised for info display, no rounding 5) Revised "Dss to Total Metal Hardness Calculator" page a) "CdMAE_AC" - Cadmium calculated metal translator Acute value b) "CdMAE_CH" - Cadmium calculated metal translator Chronic value c) "CuMAE_AC" - Copper calculatd metal translator Acute value d) "CuMAE_CH" - Copper calculated metal translator Chronic value e) "Cr_Total_AC" - Total Chromium calculated meatl translator Acute value f) "Cr_Total_CH" - Total Chromium calculated metal translator Chronic value h) "CrIIIMAE_CH" - Chromium III calculated metal tramslator Chronic value g) "CrIIIMAE_AC" - Chromium III calculated metal translator Acute value. i) "CrVIMAE_AC" - Chromium VI calculated metal translator Acute value j) "CrVINAE_CH" - Chromium VI calculatd metal translator Chronic value m) "PbMAE_CH" - Lead calculated metal translator Chronic value k) "PbMAE_AC" - Lead calculated metal translator Acute value n) "NiMAE_AC" - Nickel calculated metal translator Acute value o) "NiMAE_CH" - Nickel calculated metal translator Chroniv value q) "AuMAE_CH" - Silver calculated metal translator Chronic value p) "AuMAE_AC" - Silver calculated metal translator Acute value r) "ZnMAE-AC" - Zinc calculated metal translator Acute value s) "ZnMAE_CH" - Zinc calculated metal translator Chronic value t) "tss" - assigned TSS harness factor u) "CHA" - calculated combined acute hardness value v) "CHC" - calculated combined chronic hardness value - Assigned names for: b) "Chronic" and "Acute" inputs to display calculated metal translator values including conditional method for info display based on "WQS" selection, no rounding b) "Chronic" and "Acute" inputs to display calculated metal translator values, no rounding a) "Chronic" and "Acute" inputs to display calculated metal translator values, no rounding - Added conditional methods to formulas for info display and to incorporate names, no rounding 6) Set up passwortd to protect all pages 'rpa2015' f) PQL condition removed from calculation method for data displayed Par01 Aquactic Life Chronic (HH): Chronic (FW): 1&2 IWC% @ 7Q10S = < IWC% @ 1Q10S = IWC% @ 7Q10W = IWC% @ 30Q2 = IW%C @ QA = H No detects . 1/12/16 ADDED ARSENIC AQUATIC LIFE PARAMETER BACK TO ACTIVE RPA EVALUATION 1) Inserted "Aresenic, Aquatic Life, C, 50, FW, N/A, µg/L" in first row "INPUT" Table 2, Par01 2) Updated program names to reflect addition of new Arsenic Aquatic Life parameter 4) Amended labels on "Data" to show H for hardnes and Par01-Par22 for paremeters 1) Reformatted IWC calculation cells to show caculated value as general (number value will always be displayed) 2) Revised IWC calculation formula to x by 100 to mimic % 4) Revised all calculations using IWC values "Acute", "Chronic" to divide by 100 to correct for IWC % value 1/12/16 REVISED IWC CALCULATIONS TO SHOW FULL DISPLAY on "RPA" 3) Revised IWC calculation labels to include "%" 1/12/16 REVISED SPREADSHEET TO INDICATE NO DETECT AND MDL 2) Revised "RPA" all parameters Max Pred CW cell formatting to display " NO DETECTS" when required to display no detects 1) Revised "Data" Par01-Par22 Max Value cell conditional statement to display "NO DETECTS" when data set has all no detects 3) Revised "RPA" alert message (under Chronic labels) conditional statement to display "Max MDL = <2 x max adjusted data set value>" when data set has all no detects 1/12/16: Corrected formula error in mf formula Par01 to use corrected data set ("Data") 4) Revised "RPA" drop menu to add "No detects" to list and display Revised "RPA" Cadmium, Copper, Lead, Nickel, Silver, Zinc Acute and Chronic cell conditional statements to have cell display blank if WQS is blank or WQS displays "NO DATA" 3) Inserted "Arsenic" Aquatic Life parameter and cell programming in Arsenic section "RPA" as Chronic and added drop down menu feature Acute (FW): ! Par23 Par24 Pa11 1/21-29/16: 1) Expanded parameter list and program features to add two additional parameters, (Par08) "Chromium III" & (Par09) "Chromium VI". This included adding two new data input sections on "Data" tab with 2) For consistency rearranged display, "Input" & "RPA" tabs, to be "Chromium III", "Chromium VI", "Chromium, Total". All features and programing unique to each display was revised accordingly. 3) Corrected Arsenic - Aquatic Life, Berylium Chronic and Acute values on "Input" tab to be exported from metal translator table. 5) Revised combined hardness acute (CHA) and combined hardness chronic (CHC) conditional formulas to assign 25 as hardness value when HUC hardness is NA. 4) Revised "Input" tab HUC Hardness (median) display conditional formula to display "default 25 mg/L (HUC Hard Med = NA mg/l)" when HUC hardness is NA. 6) Revised "RPA" tab Chromium, Total Reasonable Potential Results section to remove Acute and Chronic labels and allowable Cw calulation/display, area now blank except for MDL feature display. 8) Revised "RPA" tab Acute and Chronic conditional formulas for active parameters to display either "IWC?" or "IWC/DATA?" as default until appropraite data is provided. 9) Removed label from "Input" tab. 7) Revised "RPA" tab Chromium III and Chromium VI Reasonable Potential Results sectons to remove display of values for n, #Det, Max Pred Cw, area blank except for display features from added condtional formulas that reference Chromium, Total display and data.</ new corresponding RPA evalutaion, non-detect evaluation, formulas for each new data input section; adding two new parameter summary sections to "RPA" tab; revising exsiting parameter designation</ to new assigned name (Par10 - Par24), data set (_Data08 - _Data24), non-detects (_ND08 - _ND24).</ NOTE: All RPA evaluation data is generated on each parameter "Data" section and imported to that parameter's "RPA" section, thus, RPA evaluation data can be displayed/used when programmed to do so. 2-chlorophenol 2,4-dichlorophenol 2,4,6-trichlorophenol</t></si>< 10) Corrected chlorinated list ("Input" & "Data" tabs) lists, now shows correct 2,4,6-trichlorophenol for Method 625. Par01 & Par02 Here’s the Chromium breakdown:< a. </t></ No Monitoring required if all Total Chromium samples are < the Chromium VI Allowable C w b. </t>< Maintain Total Chromium monitoring or defer to LTMP if all Total Chromium samples are < 50 µg/L but  > the Allowable C w for Chromium VI.< c. </t></ Monitor Total Chromium and Chromium VI, along with a limit for Chromium VI if any Total Chromium sample is  ≥  5 0 µg/L   and  ≥ to the Allowable C w for Chromium VI but &< the Allowable Cw for Chromium III. d. </t>< Limit both Chromium III and Chromium VI when any Total Chromium sample is ≥ 50 µg/L and ≥ to the Allowable Cw for Chromium III. Monitor for Total Chromium and Chromium Vi, report the calculated Chromium III. 2/16/16: 1) Revised "Diss to Total Metal Calculator" page: a- If HUC Hard Med = NA or less than 25 mg/L then default HUC Hard Med to 25 mg/L b- If Effluent Hard Med less than 25 then default Effluent Hard Med to 25 mg/L c- If stream class is WS and Effluent Hard Med is greater than 99.9999 mg/L then default Effluent Hard Med to 99 mg/L revised the existing calculation input/display cells for Effluent & HUC Hardness Median to show the applied hardness value based on new conditional formula as follows added new cells to display actual calculated Effluent & HUC Median values and to display "Apply Water Supply Criterion" when applicable (stream class is Water Supply based and Efflunet Hard Med exceeds 99.999 mg/L) 2) Revised "input" page dipplay HUC Hardness (Median) to show NA when HUC table value is NA. See task notes Revised "input"page model feature to b- Revise cell formula 1Q10s (cfs) to display 1Q10s flow when model feature activated or calculate from 7Q10s flow when model feature NOT activated and 7Q10s flow displayed c- Revised instructions narrartive that is visible only when model feature is activated a- Add new model 1Q10S input cell that is visible on;y when model feature is activated 2/3/16: 2/9/16: Revised "data" page Effluent Hardness (Median) cell formula to display 99 whenstream class is WS and Effluent Hard Med is greater than 99.999 mg/L Revised "input" page Effluent Hardness (Median) cell formula to display "default 99 mg/L (Efflunet Hard Med = <actual value> mg/L)" when stream class is WS and Effluent Hard Med is greater than 99.999 mg/L Added new display messages to "rpa" page that are visible only when the steam class is water supply Chromium, Total (t) Ni - WS streams (t) Par25 Chronic (WS): Par17 & Par18 Chlorinated Phenolic Compounds Added new WS WQC button to "input" page, activates effluent hardness to apply WS WQC standards, does NOT set parameter modifiers, still must do modifers individually Set up both Nickel Par17 & Par18 to use same data entries Added Nickel WS parameter to "input" page Added Nichel WS to "rpa" page, revised both Nickel parametesr to share commom data, Nickel WS has no Acute standard so only list acute for FW Changed Par22-25 modifier cells to be set automtically based on WQS entry. 17&18 Changed display font color phenols, chlorinared phenols menus Cadmium (d) Chromium III (d)(h) Chromium VI (d) Copper (d)(h) Lead (d)(h) Nickel (d)(h) Silver (d)(h,acute) Zinc (d)(h) The Human Health standard for Nickel in Water Supply Streams is 25 mg/L which is Total Recoverable metal standard.</t></si> The Human Health standard for Arsenic is 10 µg/L which is Total Recoverable metal standard.</t></si> (d) = dissolved metal standard. See 15A NCAC 02B .0211 for more information. (h) = hardness-dependent dissolved metal standard. See 15A NCAC 02B .0211 for more information. (t) = based upon measurement of total recoveable metal. See 15A NCAC 02B .0211 for more information. 2/19/16: 2/22/16: Make text changes per Julie direction. Dissolved to Total Metal Calculator COMMENTS (identify parameters to PERCS Branch to maintain in facility's LTMP/STMP): 2/24/16: Added to " Diss to Total Metal Calculator" page: 1) Comment section for PERCS info or other to allow user to add commentary 2) Added Facility name to display based on input page 3) Added NPDES permit# to display based on input page NOTE: User can either highlight desire print area or use GOTO feature to set up desired print arae. When in print mode set up, will need to designate "Print Selection". 4) Set up new Name "PERCS_page" as print area for table and other PERCS info for GOTO use. ` HUC Number Upstream Hardness H1 H2 Average Value = password all sheets = rpa2016a 10th Per value 3/18/16: Added Upstream Hardness calculation feature using measured upstream data: Removed HUC table and HUC hardness lookup features from calculations and program. 1) INPUT display shows "Upstream Hardess" status and how upstream data is applied 2) DATA has new Upstream Hardness input sheet to accept upstream hardness data used to calculate number of data enties, data set average, data set 10th percentile value 3) Diss to Total Metal Calculator determines which upstream hardness to apply, if the number of data entries exceed 30 then the average value is used, if the number of data enties are less than 30 then the 10th percentile value is used. Anytime the applied upstream hardness is less than 25 mg/L then a default value of 25 mg/L is applied.</ Note: HUC number is an available option on the INPUT as an informational input only to use as a display label for other portion of the progam and has no Data Validation features. Effluent Hardness 4/26/16: 1) Changed all upstream hardness median calculations to average calculations. 2) Removed any greater than 99.999 defaults from upstream hardness conditional statements. Upstream average will be actual execpt when less than 25, then 25 is the default. 3) Changed all effluent hardness median calculations to average calculations. Conditional statements for WS still apply, efflunet average value above 99.999 default to 99. 4) Any conditional statement referring to median hardness were revised. 5) Removed "(AL)" from parameter labels as no longer applicable. Per Julia want to use average values for both the effluent and upstream hardness calculations. Defaults to be the same as was applied in the HUC base RPA. 6) Renamed RPA to describe features ACCH ACAH 4/27/16: Per Julia when WS is being applied, the combined acute and chroinc hardness needs to default to 100 if the combined hardness exceeds 100. Made changes: 1) Set up new cells to calculate combined acute and chronic hardness, defined cells as program names ACCH & ACAH. 2) Revised the conditional statemenst for CHC and CHA to default to 100 if ACCH & ACAH exceed 100 when WS was applied. 4) Revised RPA page Combined Hardness Acut and Chronic displays conditional statemenst to indicate defaults 3) Revised INPUT page Combined Acute and Chronic display condtitional statements to indicate defaults 4/28/16: Note Action Level designation no longer allowed per EPA. RP shown - apply Monthly Monitoring with Limit 4/28/16: Revised RPA page drop menu "Recommended Action" list to remove RP Action Level text and change "RP non action level…" text to state "RP shown…". Fixed programming errors so "NO DETECTS" display feature on RPA page for Nickel and Chromium VI now function. Added statement to 2B .0500 RULES page "4/28/16: Note Action Level designation no long allowed per EPA." 4/29/16: Added ROUND function to conditional statements on INPUT page hardess displays to limit hardness value display to 2 decimal points. Revised upstream default conditional factor to 24.9999 on INPUT page to allow actual upstream hardness of 25 to be displayed as non-default value. 5/6/16: Removed less than 25 mg/L default from all effluent and upstream hardness conditional programming TotCh>50 ≥ 5/11/16: Added new conditional display to Total Chromium Pred Cw box RPA page to compare Total Chromium data to Cr III and Cr VI Allowable Cw Added new conditional display to Total Chromium Allowable Cw box RPA page to indicate maximum Total Chromium value entered NC STANDARDS OR EPA CRITERIA 6/13/16: Corrected INPUT tab to align Dats Source(s) text box at top. Revised title block text RPA tab to state "NC STANDARDS OR EPA CRITERIA", removed "NC WQS" from Chronic label, and removed 1/2 FAV from Acute label. Effluent Hardness Average (mg/L) Upstream Hardness Average (mg/L) 6/14/16: Revised conditions for calculated combined hardness acute and chroinc to default to 400 mg/L if calculated value exceeded 400 mg/L Corrected label on DISS … page to indicate average for effluent and upstream hardness Revised conditions for INPUT page display combined hardness acute and chroinc to indicate when default 400 mg/L applied To appy a Model IWC %: Once the "Flow, Qw (MGD)" and and the "CHRONIC DILUTION FACTOR = " values are entered, the 7Q10s (cfs) flow is calculated and displayed. Enter the calculated "7Q10s (cfs)" flow value in Table 1. 7/13/16: User will need to enter calculated 7Q10s displayed in Model narrative box to Table 1 7Q10s, (cfs) entry box. 1Q10s is calculated once the calculated 7Q10s (cfs) is entered in Table1. Revised Model input feature when activated to calculate Model 7Q10s (cfs) flow based on entry of Qw, MGD and CHRONIC DILITION FACTOR (from Model) and display in Model narrative box. Revised narrative in Model narrative box with new instructions, new messages to alert user on actions needed and/or completed to correctly enter Model 7Q10s (cfs) in Table 1. Remove conditions and features assocaited with entry of Model Acute IWC % . Antimony Barium Sulfates Thallum Belews Steam Station I NC0024406 Dan River WS-IV no limit add limit 003 -decanting DMRs evaluated separately Must Designate One: C = Carcinogen NC = Non-carcinogen WQS Standards Designate Applicable Standard: A = Aesthetic Standard FW = Freshwater Aquatic Life Standard HH = Human Health Standard for human consumption organism and water TR = Trout Aquatic Life Standard WS = Water Supply Standard for human consumption water This “npdes rpa” workbook was developed by and for the use of the North Carolina Division of Water Quality for the purpose of conducting Reasonable Potential Analyses under the NPDES permit program. It is a working tool for DWQ staff and may be distributed to others at no charge so long as it contains this acknowledgement. Portions of the workbook are lightly protected to prevent accidental alteration, and DWQ cannot guarantee that any copy so distributed is unaltered. Please contact the Point Source Branch to request an original copy. </a:t></a:r><a:r><a:rPr lang="en-US" sz="1600" b="0" i NCDWQ, 2009 Please see the 'user_guide' worksheet for instructions on the use of this workbook. CHECK IF HQW OR ORW WQS CHECK TO APPLY MODEL Apply WS Hardness WQC DEFINE DEFINE Additional guidance on RPA 2010 revision v.Freshwater07282010: I. < TABLE 1, the Input page : a. The 1Q10 flow will automatically be determined when the 7Q10 is entered. II. In TABLE 2 , under the Input page , enter the parameter Type and Modifier as follows: </a:t>< TYPE: MODIFIERS: ___ ___________________________ < C = Carcinogen NC = Non-carcinogen </a:t></a:r>< FW = Freshwater Aquatic Life Standards < </a:t></a:r>< A = Aesthetic < </a:t></a:r>< WS = Water Supply, human health associated with water & organism consumption HH = Human Health associated with organism consumption</a:t></a:r><a: </ III. When entering sample results on the "data" sheet as shown to the right: a. Data numbers (sample results) and &<'s can be copied and pasted but should be entered by clicking Paste </a: Special and Values. b. If a PQL is listed, a sample result less than the PQL will be< recognized at the PQL limit. Example , </a: the PQL for < Cyanide is 10 ug/L. Entering a sample such as < 9 ug/L will result in a BDL=1/2 DL of 5 ug/L because it recognizes the sample result is less than the PQL. If you want the sample to be recognized at that lower PQL level, d ecrease or remove the PQL. In the example on the right, if you want the BDL=1/2 DL to equal 4.5 the PQL on the Input Table for Cyanide would have to be removed or lowered. IV. RPA sheet and limit calculations: Freshwater (FW) To delete a parameter from the chart, simply click on the parameter number on the left , right click, hit delete and entire row. Calculated limits are determined as follows: a. Chronic and acute, Aquatic Life standards for all parameters, carcinogenic(C) or non-carcinogenic(NC), will be divided by the 7Q10 and 1Q10, respectively. b. Non-carcinogenic (NC) parameters with Human Health standards (HH and WS) will be divided by the 7Q10 to give a chronic standard. c . Carcinogenic parameters with Human Health standards (HH and WS) will be divided by the mean annual average flow (QA) to give a chronic standard. d. Parameters with Aesthetic standards such as Phenolic Compounds are divided by the 30Q2 flow. Saltwater (S) Go to the Saltwater RPA. All the rules listed above are the same for saltwater aquatic life standards. Instead of using FW (Freshwater) as the MODIFIER, use S (Saltwater). If you would like No Dilution to be allowed, simply enter the word "< Tidal" under Stream Info. on Table 1 . Dissolved to Total Metal Calculator Do NOT enter any data directly into this spreadsheet. Enter data onto “Table 1” under the Input Sheet and enter “Effluent Hardness” under the Data Sheet. In accordance with 40 CFR 122.45 (c ), permits are, have and must be written as total metals. This calculator has been inserted into the RPA to calculate Total Metal allowable allocations once Table 1 has been completed (Input Sheet) and Effluent hardness has been entered (Data Sheet). Following the spreadsheet from left to right. First the allowable allocations for the dissolved metals will appear for all the metals listed once Table 1 is complete and effluent hardness entered. Use a default value of 25 mg/L if no hardness data is available. Second, the Dissolved Metal allocations are divided by the Translators to determine the Total Metals that can be allocated to the Permittee. These Total Metals values are automatically inserted into Table 2 and are the allowable Total Metal allocations determined for the Permittee prior to allowing for dilution. See Input sheet Table 2. The final acute and chronic values shown under the RPA sheet are the Total Metal values listed in Table 2 divided by the acute and chronic IWC, respectively.   The Translators used in the freshwater RPA are the Partition Coefficients published by US EPA in 1984. They are TSS dependent equations and can be found listed with the WQS hardness dependent equations under the sheet labeled Equations. A fixed TSS value of 10 mg/L is used to calculate the Translator values. Pretreatment Facilities – PERCS will need a copy of the Dissolved to Total Metal Calculator spreadsheet and the RPA sheet along with the Final Permit. Pretreatment Facilities are required to renew their Headwords Analysis after renewal of their permits. Since all their metal allocations are likely to change PERCS needs to see any new metal permit limits and the allowable allocations for the dissolved metals to assess Maximum Allowable Headworks Loading (MAHL) numbers for each metal based on the Combined Hardness values used in the permit writers RPA calculations.< For Cadmium, Lead, Nickel, Chromium and Beryllium , if all the effluent sampling data for the last three to five years shows the pollutant at concentrations less than the Practical Quantitative Level (PQL), it is not likely a limit or monitoring will be put in the permit. However, if the estimated NPDES permit limit is less than the Practical Quantitative Limit (particularly, Cadmium and Lead) and the pollutant is believed to be present, to assess compliance with the new standards and for future permit limit development, monitoring for the pollutant will be required. If the facility is monitoring for the pollutant in its Pretreatment LTMP, no monitoring is needed in the permit. For monitoring and compliance purposes if Total Chromium < the Chromium VI chronic Total Metal limitation – no limit or monitoring is required. </a:t></a:r></a:p></xdr:txBody></xdr:s Example for Cadmium (streams) Given : TSS = 10 mg/L Kpo = 4.00E + 06 a = -1.1307 Translator   = </a 1                             </a:t></a:r></a:p><a:p><a:pP [1 + (Kpo * TSS </a:t></a:r><a:r><a:rPr lang="en (1+ a ) * 10 -6 )]  </a:t></a:r><a:endPa  = </a:t></a:r><a:r><a: 1                              </a:t></a:r></a:p><a:p><a:pP  [1 + (4.00x10</a:t></a:r><a:r><a:rPr lang 6 * 10 1-1.1307) * 10 -6 )]  </a:t></a:r  = </a:t></a:r><a:r><a: 1                              </a:t></a:r></a:p><a:p><a:pP  [1+2.960465]</a:t></a:r></a:p><a:p><a:pPr algn="l" rtl  </a:t></a:r><a:endPa  = 0.252</a:t></a:r><a:endPa   Using the Tool The general sequence of steps for completing the RPA is as follows: Setup (‘in’ sheet)-Begin with a blank copy of the ‘npdes rpa 200403.xls’ file. (Permit writers: To generate a blank copy, double-click on the RPA template (‘npdes rpa 200403.xlt’) or on the shortcut to the template, located on the NPDES server.) -Enter the facility, receiving stream, and other project-specific information in Table 1 of the ‘in’ sheet. The information will automatically populate the ‘rpa’ sheet. -Enter the parameter names, applicable standards, and other information for the Pollutants of Concern (POCs, up to 15) in Table 2 of the ‘in’ sheet. The POC names will automatically populate both the ‘rpa’ and the ‘data’ sheets. -Table 2 already includes relevant information on the most common parameters. Users can change the table’s contents to include different parameters or to adjust for a saltwater discharge. DO NOT cut-and-paste or click-and-drag the existing POC cells in order to re-arrange them. Instead, copy-and-paste the cells, then go back and delete the originals. (Just trust me on this.) -Hide any rows in the ‘rpa’ and ‘data’ sheets that are not needed for the RPA. The file includes a toolbar with custom to simplify this. -Enter new POC information into the appropriate cells. Be sure to update all of the information for each parameter to be changed. -Once the information is entered, you can sort it by Parameter (or whatever column you choose) to get it in the preferred order. Data Entry -Prepare the raw effluent data for each POC and enter it in the appropriate columns in the ‘data’ sheet. -There are three data columns for each parameter: the Date, the “<” indicator (if needed; any character will work), and the data value. Enter the data accordingly. It is sometimes easier to use the ‘blank’ sheet or other sheet to arrange the raw data, and then copy it into the ‘data’ sheet. -Values entered as “less than detection” using the “<” character (actually, any character in that column) will automatically be halved for the calculations that follow. The sheet also counts any values less than the PQL (see Table 2 on the ‘in’ sheet) as “less than detection”. User’s Guide RPA Tool March 21, 2009 The RPA Tool is an Excel workbook, ‘npdes rpa 200403.xls, developed and maintained by the NCDWQ’s NPDES Permitting Units. The Unit’ permit writers use the Tool to evaluate effluent data from individual wastewater treatment plants and determine whether limits for certain pollutants of concern (typically, heavy metals, cyanide, and toxic organics) are warranted. It evaluates the magnitude and variability of the data and determines whether there is a reasonable potential that the discharge will cause a contravention of applicable water quality standards and criteria. If such reasonable potential is found, the permit writer uses the results of the analysis to determine appropriate permit limits for the parameter(s). The Tool employs statistical methods described in the U.S. EPA’s Technical Support Document for Water Quality-based Toxics Control, March 1991, EPA/505/2-90-001, available for download at http://yosemite.epa.gov/water/owrccatalog.nsf/e673c95b11602f2385256ae1007279fe/025cb4267d4d9fd585256b060072539a?OpenDocument&CartID=8774-040144. Overview The RPA workbook consists of six spreadsheets: ack is the introductory screen and explains to terms of use of the RPA tool. in is the initial data entry sheet for project-specific information and the pollutants of concern. rpa is the main worksheet of the tool. It serves as a summary report of the RPA’s results and includes the permit writer’s recommendations for each parameter. data contains the raw effluent data for each pollutant of concern. Most of the statistical calculations are carried out on this sheet. mf table is the standard Multiplication Factor table used in the tool. The MF is a function of the number of samples (n) and the Coefficient of Variation (CV, the standard deviation of a data set divided by its mean). blank is a blank sheet which can be used to organize effluent data prior to entering the data in the ‘data’ sheet. Of course, you can add others if the need arises. The first five sheets are “protected” to prevent unintentional (and undetected) changes in the spreadsheet’s programming or content. However, certain portions of the ‘in,’ ‘rpa,’ and ‘data’ sheets - highlighted in light blue - are unlocked for data entry. Unfortunately, the “protect” feature in Excel prevents certain changes (some formatting, for instance) that would be useful and would not corrupt the workbook. To get around this, the sheets include macros that allow the user to unlock (and re-lock) the sheets when changes are needed (more on that below). Review Results-The ‘data’ sheet calculates the maximum predicted concentration for each POC and returns it to the ‘rpa’ sheet (Col. K). The ‘rpa’ sheet compares this result with the maximum concentrations allowed by the acute standard (no instream dilution) and the chronic standard (dilution included) and reports whether the maximum predicted value is more than or less than the maximum allowed (Col. L). It also presents an automated response, suggesting a permitting action based on these results. Enter Recommendations - At this point, the permit writer must evaluate the results in the ‘rpa’ sheet, along with any other relevant factors, and recommend what limits and/or monitoring to include in the new permit. Enter these notes in Column M.< Misc. notes: ‘mf table’</w:t></w:r><w:r - n = 1-200, CV = 0.1-6.1- values based on 99% probability to not exceed, with 99% confidence REASONABLE POTENTIAL ANALYSIS Par05 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 Par06 Use "PASTE SPECIAL, Values" then "COPY" . Maximum data points = 58 Par07 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 Par08 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 Par09 Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 Chlorides Chlorinated Phenolic Compounds Total Phenolic Compounds Chromium Ill Chromium VI Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 570 570 Std Dev. 66.6815 1 Std Dev. NO DATA 1 7.3 7.3 Std Dev. 0.0000 1 Std Dev. NO DATA 1 Std Dev. NO DATA 2 620 620 Mean 519.9 2 Mean NO DATA 2 Mean 7.3000 2 Mean NO DATA 2 Mean NO DATA 3 600 600 C.V. 0.1283 3 C.V. NO DATA 3 C.V. (default) 0.6000 3 C.V. NO DATA 3 C.V. NO DATA 4 590 590 n 34 4 n 0 4 n 1 4 n 0 4 n 0 5 550 550 5 5 5 5 6 560 560 Mult Factor = 1.0 6 Mult Factor = N/A 6 Mult Factor = 6.20 6 Mult Factor = N/A 6 Mult Factor = N/A 7 520 520 Max. Value 650.0 mg/L 7 Max. Value N/A ug/L 7 Max. Value 7.3 ug/L 7 Max. Value N/A pg/L 7 Max. Value N/A pg/L 8 560 560 Max. Pred Cw 669.5 mg/L 8 Max. Pred Cw N/A ug/L 8 Max. Pred Cw 45.3 ug/L 8 Max. Pred Cw N/A pg/L 8 Max. Pred Cw N/A pg/L 9 620 620 9 9 9 9 10 650 650 10 10 10 10 11 590 590 11 11 11 11 12 590 590 12 12 12 12 13 560 560 13 13 13 13 14 560 560 14 14 14 14 15 480 480 15 15 15 15 16 540 540 16 16 16 16 17 540 540 17 17 17 17 18 460 460 18 18 18 18 19 430 430 19 19 19 19 20 510 510 20 20 20 20 21 520 520 21 21 21 21 22 420 420 22 22 22 22 23 430 430 23 23 23 23 24 501 501 24 24 24 24 25 520 520 25 25 25 25 26 428 428 26 26 26 26 27 540 540 27 27 27 27 28 470 470 28 28 28 28 29 360 360 29 29 29 29 30 471.8 471.8 30 30 30 30 31 469.5 469.5 31 31 31 31 32 480.1 480.1 32 32 32 32 33 479.7 479.7 33 33 33 33 34 485.1 485.1 34 34 34 34 35 35 35 35 35 36 36 36 36 36 37 37 37 37 37 38 38 38 38 38 39 39 39 39 39 40 40 40 40 40 41 41 41 41 41 42 42 42 42 42 43 43 43 43 43 44 44 44 44 44 45 45 45 45 45 46 46 46 46 46 47 47 47 47 47 48 48 48 48 48 49 49 49 49 49 50 50 50 50 50 51 51 51 51 51 52 52 52 52 52 53 53 53 53 53 54 54 54 54 54 55 55 55 55 55 56 56 56 56 56 57 57 57 57 57 58 58 58 58 58 - 4 - NC0024406_Worksheets 003 decanting_20190322, data 8/13/2021 REASONABLE POTENTIAL ANALYSIS Par10 Use "PASTE SPECIAL, Values" then "COPY" . Maximum data points = 58 Pall Use "PASTE SPECIAL, Values" then "COPY" . Maximum data points = 58 Par12 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 Par13 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 Par14 Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 Chromium, Total Copper Cyanide Fluoride Lead Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results Date BDL=1/2DL Results 1 < 1 0.5 Std Dev. 0.0000 1 < 5 2.5 Std Dev. 171.0695 1 < 10 5 Std Dev. 0.0000 1 1000 1000 Std Dev. 134.6185 1 48.3 48.3 Std Dev. 37.1006 2 < 1 0.5 Mean 0.5000 2 < 5 2.5 Mean 32.5291 2 Mean 5.00 2 700 700 Mean 796.9565 2 64.3 64.3 Mean 39.0400 3 < 1 0.5 C.V. (default) 0.6000 3 < 5 2.5 C.V. 5.2590 3 C.V. (default) 0.6000 3 900 900 C.V. 0.1689 3 81.6 81.6 C.V. (default) 0.6000 4 < 1 0.5 n 5 4 < 5 2.5 n 32 4 n 1 4 900 900 n 23 4 < 1 0.5 n 5 5 < 1 0.5 5 < 5 2.5 5 5 1000 1000 5 < 1 0.5 6 Mult Factor = 2.32 6 < 5 2.5 Mult Factor = 1.73 6 Mult Factor = 6.20 6 900 900 Mult Factor = 1.08 6 Mult Factor = 2.32 7 Max. Value 0.5 pg/L 7 < 5 2.5 Max. Value 970.00 ug/L 7 Max. Value 5.0 ug/L 7 900 900 Max. Value 1000.0 ug/L 7 Max. Value 81.600 ug/L 8 Max. Pred Cw 0 DETECTS pg/L 8 < 5 2.5 Max. Pred Cw 1678.10 ug/L 8 Max. Pred Cw 0 DETECTS ug/L 8 800 800 Max. Pred Cw 1080.0 ug/L 8 Max. Pred Cw 189.312 ug/L 9 9 < 5 2.5 9 9 800 800 9 10 10 < 5 2.5 10 10 900 900 10 11 11 < 5 2.5 11 11 700 700 11 12 12 < 5 2.5 12 12 700 700 12 13 13 < 5 2.5 13 13 600 600 13 14 14 < 5 2.5 14 14 900 900 14 15 15 < 5 2.5 15 15 900 900 15 16 16 < 5 2.5 16 16 900 900 16 17 17 < 5 2.5 17 17 600 600 17 18 18 < 5 2.5 18 18 600 600 18 19 19 < 5 2.5 19 19 700 700 19 20 20 < 5 2.5 20 20 900 900 20 21 21 1 1 21 21 800 800 21 22 22 < 5 2.5 22 22 600 600 22 23 23 970 970 23 23 630 630 23 24 24 < 5 2.5 24 24 24 25 25 < 5 2.5 25 25 25 26 26 < 5 2.5 26 26 26 27 27 < 5 2.5 27 27 27 28 28 1.19 1.19 28 28 28 29 29 1.46 1.46 29 29 29 30 30 1.71 1.71 30 30 30 31 31 1.69 1.69 31 31 31 32 32 1.38 1.38 32 32 32 33 33 33 33 33 34 34 34 34 34 35 35 35 35 35 36 36 36 36 36 37 37 37 37 37 38 38 38 38 38 39 39 39 39 39 40 40 40 40 40 41 41 41 41 41 42 42 42 42 42 43 43 43 43 43 44 44 44 44 44 45 45 45 45 45 46 46 46 46 46 47 47 47 47 47 48 48 48 48 48 49 49 49 49 49 50 50 50 50 50 51 51 51 51 51 52 52 52 52 52 53 53 53 53 53 54 54 54 54 54 55 55 55 55 55 56 56 56 56 56 57 57 57 57 57 58 58 58 58 58 - 5 - NC0024406_Worksheets 003 decanting_20190322, data 8/13/2021 REASONABLE POTENTIAL ANALYSIS Par15 Use "PASTE SPECIAL, Par16 Use "PASTE SPECIAL, Par17 & Par18 Use "PASTE SPECIAL- Par19 Use "PASTE SPECIAL- Par20 Use "PASTE SPECIAL - Values" then "COPY" . Values" then "COPY" . Values" then "COPY" . Values" then "COPY" . Values" then "COPY" . Mercury Maximum data points Molybdenum Maximum data points Nickel Maximum data points Selenium Maximum data points Silver Maximum data points = 58 = 58 = 58 = 58 = 58 Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 Std Dev. NO DATA 1 22 22 Std Dev. 11.0647 1 2.07 2.07 Std Dev. 2.2154 N 00 00 M I` Ln CO M CO U0 U0 CO O7 O7 O7 up M up CO I` M CD Ns O7 O7 U0 I` O 00 I` I` O ti Cfl Ln C'') C'') lf') 6QD QD 6 64 4 4 C'') N 4 4 CO QD 6 6 6 6 64 64 d7 6 6 I` ti 00 I` d7 O QD ti QD QD O7 N CO CO M N- LO CO M CO L0 L0 CO O7 O7 O7 up 00 up CO I` M O7 Ns O7 O7 L0 I` O 00 I` I` O Ns Cfl l� C'') CO lf') 6Cfl QD 6 64 4 4 C'') N 4 4 CO CO 6 6 lf') lf') lf') 4 6� d7 lf') lf') I` ti 00 I` d7 O QD ti QD QD O7 N CO (0 CO I` 00 O7 O N CO (0 CO I` 00 O7 O N CO (0 CO I` 00 O7 O N CO (0 CO I` 00 O7 O N CO (0 CO I` 00 O7 O N CO (0 CO I` 00 N N N N N N N N N N CO CO CO CO CO CO CO CO CO CO (0 up (0 up (0 up (0 up (0 O O O O O O O O O O O O O O O O O N O O O O O N V V V V V V V V V V V V V V V V V V V V V V N CO Lc, CO ti CO O) O ,- N CO Lc, QD ti CO O) O ,- N CO Lc, QD ti CO O) O ,- N CO Lc, QD ti CO O7 O ,- N CO Lc, QD ti CO O7 O ,- N CO Lc, QD ti CO N N N N N N N N N N CO CO CO CO CO CO CO CO CO CO lf) lf) lf) lf) lf) lf) lf) lf) lf) 2 Mean NO DATA 2 25 25 Mean 22.9667 2 4.24 4.24 Mean 5.0918 3 C.V. NO DATA 3 16 16 C.V. (default) 0.6000 3 5.41 5.41 C.V. 0.4351 4 n 0 4 16.3 16.3 n 6 4 6.4 6.4 n 11 5 5 14.5 14.5 5 1.48 1.48 6 Mult Factor = N/A 6 44 44 Mult Factor = 2.14 6 4.92 4.92 Mult Factor = 1.48 7 Max. Value N/A ng/L 7 Max. Value 44.0 ug/L 7 6.19 6.19 Max. Value 9.9 pg/L 8 Max. Pred Cw N/A ng/L 8 Max. Pred Cw 94.2 ug/L 8 5.23 5.23 Max. Pred Cw 14.6 pg/L 9 9 9 5.3 5.3 10 10 10 4.88 4.88 11 11 11 9.89 9.89 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 17 17 17 18 18 18 19 19 19 20 20 20 21 21 21 22 22 22 23 23 23 24 24 24 25 25 25 26 26 26 27 27 27 28 28 28 29 29 29 30 30 30 31 31 31 32 32 32 33 33 33 34 34 34 35 35 35 36 36 36 37 37 37 38 38 38 39 39 39 40 40 40 41 41 41 42 42 42 43 43 43 44 44 44 45 45 45 46 46 46 47 47 47 48 48 48 49 49 49 50 50 50 51 51 51 52 52 52 53 53 53 54 54 54 55 55 55 56 56 56 57 57 57 58 58 58 - 6 - NC0024406_Worksheets 003 decanting_20190322, data 8/13/2021 REASONABLE POTENTIAL ANALYSIS Par21 Use "PASTE SPECIAL, then "COPY" . Maximum data points = 58 Par22 Use "PASTE SPECIAL, Values" then "COPY" . Maximum data points = 58 Par23 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 Par24 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 Par25 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 ZincValues" Antimony Barium Sulfates Thallum Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 2 2 Std Dev. 4.3417 1 1.22 1.22 Std Dev. 0.4387 1 0.075 0.075 Std Dev. 0.0108 1 160 160 Std Dev. 27.5124 1 1.35 1.35 Std Dev. 0.3652 2 6.75 6.75 Mean 7.1518 2 1.37 1.37 Mean 0.8180 2 0.076 0.076 Mean 0.0802 2 150 150 Mean 148.5759 2 1.09 1.09 Mean 0.9020 3 9.67 9.67 C.V. 0.6071 3 < 1 0.5 C.V. (default) 0.6000 3 0.077 0.077 C.V. (default) 0.6000 3 150 150 C.V. 0.1852 3 0.588 0.588 C.V. (default) 0.6000 4 5.25 5.25 n 11 4 < 1 0.5 n 5 4 0.077 0.077 n 6 4 150 150 n 58 4 0.583 0.583 n 6 5 < 1 0.5 5 < 1 0.5 5 0.074 0.074 5 140 140 5 0.561 0.561 6 < 5 2.5 Mult Factor = 1.69 6 Mult Factor = 2.32 6 0.102 0.102 Mult Factor = 2.14 6 160 160 Mult Factor = 1.00 6 1.24 1.24 Mult Factor = 2.14 7 6 6 Max. Value 13.0 ug/L 7 Max. Value 1.370000 pg/L 7 Max. Value 0.102000 mg/L 7 150 150 Max. Value 310.000000 mg/L 7 Max. Value 1.350000 pg/L 8 12 12 Max. Pred Cw 22.0 ug/L 8 Max. Pred Cw 3.178400 pg/L 8 Max. Pred Cw 0.218280 mg/L 8 170 170 Max. Pred Cw 310.000000 mg/L 8 Max. Pred Cw 2.889000 pg/L 9 12 12 9 9 9 160 160 9 10 9 9 10 10 10 170 170 10 11 13 13 11 11 11 150 150 11 12 12 12 12 140 140 12 13 13 13 13 150 150 13 14 14 14 14 140 140 14 15 15 15 15 150 150 15 16 16 16 16 150 150 16 17 17 17 17 150 150 17 18 18 18 18 310 310 18 19 19 19 19 230 230 19 20 20 20 20 150 150 20 21 21 21 21 150 150 21 22 22 22 22 140 140 22 23 23 23 23 140 140 23 24 24 24 24 140 140 24 25 25 25 25 140 140 25 26 26 26 26 150 150 26 27 27 27 27 140 140 27 28 28 28 28 150 150 28 29 29 29 29 140 140 29 30 30 30 30 140 140 30 31 31 31 31 140 140 31 32 32 32 32 120 120 32 33 33 33 33 140 140 33 34 34 34 34 150 150 34 35 35 35 35 140 140 35 36 36 36 36 130 130 36 37 37 37 37 130 130 37 38 38 38 38 140 140 38 39 39 39 39 140 140 39 40 40 40 40 130 130 40 41 41 41 41 120 120 41 42 42 42 42 120 120 42 43 43 43 43 140 140 43 44 44 44 44 150 150 44 45 45 45 45 140 140 45 46 46 46 46 150 150 46 47 47 47 47 140 140 47 48 48 48 48 150 150 48 49 49 49 49 140 140 49 50 50 50 50 170 170 50 51 51 51 51 170 170 51 52 52 52 52 160 160 52 53 53 53 53 160 160 53 54 54 54 54 147.9 147.9 54 55 55 55 55 137.5 137.5 55 56 56 56 56 116.6 116.6 56 57 57 57 57 117.9 117.9 57 58 58 58 58 117.5 117.5 58 - 7 - NC0024406_Worksheets 003 decanting_20190322, data 8/13/2021 Belews Steam Station NC0024406 Qw (MGD) = 18.60 1Q1OS (cfs) = 65.40 7Q 10S (cfs) = 80.00 7Q 10W (cfs) = 160.00 30Q2 (cfs) = 195.00 Avg. Stream Flow, QA (cfs) = 576.00 Receiving Stream: Dan River HUC WS-IV Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 WWTP/WTP Class: IWC% @ 1Q1OS = 30.5953518 IWC% @ 7Q 10S = 26.4908573 IWC% @ 7Q 1 OW = 15.26770111 IWC% @ 30Q2 = 12.88031095 IW%C @ QA = 4.766628639 Stream Class: Outfall 003 -decanting Qw=18.6MGD COMBINED HARDNESS (mg/L) Acute = 25 mg/L Chronic = 25 mg/L YOU HAVE DESIGNATED THIS RECEIVING STREAM AS WATER SUPPLY Effluent Hard: 0 value > 100 mg/L Effluent Hard Avg = 25 mg/L PARAMETER TYPE (1) NC STANDARDS OR EPA CRITERIA _i a N H REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION Chronic Applied Acute Standard rl # Det. Max Pred Cw Allowable Cw Arsenic Arsenic C C 150 FW(7Q10s) 340 10 HH/WS(Qavg) ug/L ug/L 29 29 9.7 Acute (FW): 1,111.3 _ _ _ __ _ ______________________________ Chronic (FW)_566.2 Novalue > Allowable Cw______________________________ Chronic (HH): 209.8 No value > Allowable Cw no limit Cadmium NC 0.5899 FW(7Q10s) 3.2396 ug/L 6 1 Note: n < 9 Limited data set 1.070 Default C.V. Acute: 10.589 _ _ _ _ _ _ _ _ _ _______________________________ Chronic: 2.227 No value > Allowable Cw no limit Chlorides NC 250 WS(7Q10s) mg/L 34 34 669.5 Acute: NO WQS —_ _ _ _ -Chronic: ---- 943.7 -— No value > Allowable Cw no limit -—-—-—-—-—-—-—-—-—-—-—-—-—-— Chromium III NC 117.7325 FW(7Q10s) 905.0818 µg/L 0 0 N/A Acute: 2,958.2 --Chron_ _ ic: - — -— 444.4 -— no limit -—-—-—-—-—-—-—-—-—-—-—-—-—-— Chromium VI NC 11 FW(7Q10s) 16 µg/L 0 0 N/A Acute: 52.3 Chronic:-----41.5 ------------------------------ no limit Chromium, Total NC µg/L 5 0 Note: n < 9 Limited data set NO DETECTS Max MDL = 1 no limit Copper NC 7.8806 FW(7Q10s) 10.4720 ug/L 32 7 1,678.10 Acute: 34.23 —_ _ ---- _ _ -Chronic: 29.75 ------------------------------ 1 value(s) > Allowable Cw add limit Fluoride NC 1800 FW(7Q10s) ug/L 23 23 1,080.0 Acute: NO WQS Chronic: 6,794.8 No value > Allowable Cw no limit Lead NC 2.9416 FW(7Q10s) 75.4871 ug/L 5 3 Note: n < 9 Limited data set 189.312 Default C.V. Acute: 246.727 ___ _ ____ _ ____add Chronic: 11.104 3 value(s) > Allowable Cw limit ___________________________ Page 8 of 21 NC0024406_Worksheets 003 decanting_20190322, rpa 8/13/2021 Belews Steam Station NC0024406 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Outfall 003 -decanting Qw=18.6MGD Mercury NC 12 FW(7Q10s) 0.5 ng/L 0 0 N/A Acute: NO WQS Chronic:-----45.3 ----------------------------- evaluated separately Molybdenum NC 160 WS(7Q10s) ug/L 6 6 Note: n < 9 Limited data set 94.2 Default C.V. Acute: NO WQS ___ _ ____ _ ______________________________ Chronic: 604.0 No value > Allowable Cw no limit Nickel Nickel NC NC 37.2313 FW(7Q10s) 335.2087 25.0000 WS(7Q10s) µg/L µg/L 11 11 14.6 Acute (FW): 1,095.6 _ _ _ ____ ______________________________ Chronic (FW)_140.5 No value > Allowable Cw__ Chronic (WS): 94.4 No value > Allowable Cw no limit _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Selenium NC 5 FW(7Q10s) 56 ug/L 43 43 11.1 Acute: 183.0 Chronic:-----18.9 ----------------------------- No value > Allowable Cw no limit Zinc NC 126.7335 FW(7Q10s) 125.7052 ug/L 11 9 22.0 Acute: 410.9 --Chron_ _ ic: - — -— 47_8.4 ----------------------------- No value > Allowable Cw no limit Antimony NC 5.6 WS(7Q10s) µg/L 5 2 Note: n < 9 Limited data set 3.17840 Default C.V. Acute: NO WQS ___ _ ____ _ _ _____________________________ Chronic: 21.13937 No value > Allowable Cw no limit Barium NC 1 WS(7Q10s) mg/L 6 6 Note: n < 9 Limited data set 0.21828 Default C.V. Acute: NO WQS ___ _ ____ _ ______________________________ Chronic: 3.77489 No value > Allowable Cw no limit Sulfates NC 250 WS(7Q10s) mg/L 58 58 310.00000 Acute: NO WQS Chronic: --- 943.72182 No value > Allowable Cw no limit Thallum NC 2 HH(7Q10s) µg/L 6 6 Note: n < 9 Limited data set 2.88900 Default C.V. Acute: NO WQS _ _ _ _ _ _ _ _ ______________________________ Chronic: 7.54977 No value > Allowable Cw no limit Page 9 of 21 NC0024406_Worksheets 003 decanting_20190322, rpa 8/13/2021 Monitoring Frequencies 2B .0500 Effluent Limited pH E Temp, C E BOD5 I, E TSS I, E NH3-N E Fecal Col. E TN E TP E Water Quality Limited Parameter Location D.O. D.O. pH Temp, C Temp, C BOD5 TSS NH3-N TRC Fecal Col. Fecal Col. Conductivi Conductivi TN TP E U, D E E U, D I, E I, E E E E U, D E U, D E E 2/Month 1/Week 2/Month 2/Month 1/Month 2/Month 1/Week 3/Week 1/Week 3/Week 1/Week 3/Week 1/Week 3/Week 2/Month 1/Week 1/Week 3/Week See notes below. See notes below. Frequency Daily Daily Daily Daily 3/Week Daily Class I 1/Week 1/Week 2/Month Daily 1/Week 2/Month 2/Month 1/Month 2/Week 2/Month 2/Month 1/Week 1/Week Class II 1/Week 1/Week 1/Week Daily 1/Week 1/Week 1/Week 2/Month 2/Week 1/Week 1/Week 1/Week Class III 3/Week 3/Week* 3/Week Daily 3/Week* 3/Week 3/Week 1/Week 3/Week 3/Week 3/Week* 3/Week 1/Week 3/Week* See notes below. See notes below. Class IV Daily 3/Week* Daily Daily 3/Week* Daily Daily 3/Week Daily Daily 3/Week* Daily 3/Week* Notes: * Upstream and downstream monitoring in WQ-limited waters is to be conducted 3/Week during Jun, Jul, Aug, and Sep; and 1/Week during the rest of the year. TN, TP Monitoring All facilities >= 0.05 MGD will monitor TN and TP Those < 0.05 MGD will monitor if discharging to NSW For the Neuse, Tar -Pamlico, and any other river basins classified as NSW, use limits and monitoring requirements according to the basin's permitting strategy. For French Broad, Broad, Savannah, New Watauga, Little Tennessee, and Hiwassee: - >= 0.05 M - monitor semi-annually - >= 1.0 MG - monitor quarterly For all other river basins: - >= 0.05 M - monitor quarterly - >= 1.0 MG - monitor monthly Per Memo Dated 7-15-2010 RPA Condition Pennit Monitoring Frequency 1 RPA Exists Monitor Monthly and add Permit Limit 2.RPA Exists but Action Levels (Cu, Zn, Ag ,Fe, Cl) Monitor Quarterly in conjunction with Tox Test 3a.RPA Exists but Dataset Limited (n< 8 samples) 3b. RPA exists, dataset limited, but 2 values > allowable Cw Monitor Quarterly Monitor Monthly and add Permit Limit 4.No RPA (Predicted Max > 50% of Allowable) Monitor Quarterly (or defer to Pretreat LTMP) 5.NoRPA (Predicted Max < 50% Allowable) No Monitoring 6a.No Data (New Permit, New Waste Stream) 6b. New Greensand or Conventional WTP Monitor Monthly for Toxic Pollutants of Concern Monitor Quarterly for Toxic Pollutants of Concern password all sheets = rpa2016a 4/28/16: Note Action Level designation no longer allowed per EPA. Msg00 Msg01 Msg02 Msg03 Msg04 Msg05 Msg06 Msg07 Msg08 Msg09 Msg10 < No Data Entered > MaxPredCw < Acute MaxPredCw < Chronic MaxPredCw « Acute MaxPredCw « Chronic MaxPredCw > Acute MaxPredCw > Chronic MaxPredCw » Acute MaxPredCw » Chronic No acute standard or 1/2 FAV No chronic standard or criterion NO DATA MONITOR? MONITOR? REMOVE? REMOVE? DAILY MAX LIMIT? MO AVG LIMIT? DAILY MAX LIMIT? MO AVG LIMIT? N/A N/A Sample recommendations: Daily max limit Monitor 1/month Monitor 1/week Monitor 2/month Monitoring not necessary in permit No limit No limit - assuming no tox (Action Level parameter) No limit (Action Level parameter) Continue to monitor at 2/month Mo. avg. limit (keep wk. avg. if existing) Revise daily max. limit Reasonable Potential Multiplying Factors - Calculator 95.0% Confidence Level Upper Boundary of the Effluent Distribution (Percentile Value Not To Exceed) 95.0% Coefficient of Variation Coefficient of Variation n 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2.0 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 2.9 3.0 3.1 3.2 3.3 3.4 3.5 3.6 3.7 3.8 3.9 4.0 4.1 4.2 1 1.00 1.39 1.92 2.63 3.55 4.73 6.20 7.98 #### 12.60 1.4i 18.72 22.35 26.38 30.78 35.57 40.73 46.26 52.14 58.37 64.94 71.84 79.06 86.58 94.41 102.53 ##### 119.62 128.56 137.76 147.21 156.91 16b.84 177.00 187.38 197.98 208.78 219.79 231.00 242.40 253.99 265.76 277.71 2 1.00 1.27 1.61 2.03 2.53 3.11 3.79 4.57 5.43 6.38 7.41 8.51 9.69 10.94 12.25 13.61 15.03 16.49 18.00 19.55 21.14 22.75 24.40 26.08 27.79 29.51 31.26 33.03 34.82 36.63 38.45 40.28 42.13 43.99 45.86 47.74 49.64 51.54 53.44 55.36 57.28 59.21 61.15 3 1.00 1.22 1.48 1.79 2.15 2.55 3.00 3.49 4.03 4.60 5.20 5.84 6.49 7.17 7.87 8.59 9.32 10.06 10.81 11.58 12.34 13.12 13.90 14.68 15.46 16.25 17.04 17.83 18.62 19.41 20.21 21.00 21.79 22.58 23.36 24.15 24.94 25.72 26.50 27.28 28.06 28.84 29.61 4 1.00 1.19 1.40 1.65 1.93 2.25 2.59 2.95 3.34 3.74 4.16 4.60 5.04 5.50 5.96 6.42 6.89 7.36 7.84 8.31 8.79 9.26 9.73 10.20 10.68 11.14 11.61 12.07 12.54 13.00 13.45 13.91 14.36 14.81 15.25 15.70 16.14 16.58 17.01 17.44 17.87 18.30 18.72 5 1.00 1.16 1.35 1.56 1.80 2.05 2.32 2.61 2.91 3.23 3.55 3.87 4.21 4.54 4.88 5.21 5.55 5.89 6.22 6.56 6.89 7.22 7.54 7.87 8.19 8.51 8.82 9.13 9.44 9.75 10.05 10.36 10.65 10.95 11.24 11.53 11.82 12.10 12.38 12.66 12.94 13.21 13.48 6 1.00 1.15 1.31 1.50 1.70 1.91 2.14 2.38 2.63 2.88 3.14 3.40 3.66 3.92 4.18 4.44 4.70 4.96 5.21 5.46 5.71 5.96 6.20 6.44 6.68 6.91 7.14 7.37 7.60 7.82 8.04 8.25 8.47 8.68 8.89 9.10 9.30 9.50 9.70 9.90 10.09 10.29 10.48 7 1.00 1.13 1.28 1.45 1.62 1.81 2.01 2.21 2.42 2.63 2.84 3.06 3.27 3.48 3.69 3.90 4.11 4.32 4.52 4.72 4.91 5.10 5.29 5.48 5.67 5.85 6.02 6.20 6.37 6.54 6.71 6.88 7.04 7.20 7.36 7.51 7.67 7.82 7.97 8.12 8.26 8.41 8.55 8 1.00 1.12 1.26 1.40 1.56 1.73 1.90 2.07 2.25 2.44 2.62 2.80 2.98 3.16 3.33 3.51 3.68 3.85 4.01 4.17 4.33 4.49 4.64 4.79 4.94 5.09 5.23 5.37 5.51 5.64 5.78 5.91 6.03 6.16 6.29 6.41 6.53 6.65 6.77 6.88 6.99 7.11 7.22 9 1.00 1.11 1.24 1.37 1.51 1.66 1.81 1.97 2.12 2.28 2.44 2.60 2.75 2.90 3.05 3.20 3.34 3.49 3.62 3.76 3.89 4.02 4.15 4.27 4.40 4.52 4.63 4.75 4.86 4.97 5.08 5.19 5.29 5.40 5.50 5.60 5.69 5.79 5.88 5.98 6.07 6.16 6.25 10 1.00 1.10 1.22 1.34 1.47 1.60 1.74 1.88 2.02 2.16 2.30 2.43 2.57 2.70 2.83 2.95 3.08 3.20 3.32 3.43 3.55 3.66 3.77 3.87 3.97 4.07 4.17 4.27 4.36 4.46 4.55 4.64 4.72 4.81 4.89 4.97 5.06 5.13 5.21 5.29 5.36 5.44 5.51 11 1.00 1.10 1.20 1.32 1.43 1.55 1.68 1.80 1.93 2.05 2.18 2.30 2.41 2.53 2.64 2.75 2.86 2.97 3.07 3.17 3.27 3.36 3.46 3.55 3.63 3.72 3.80 3.89 3.97 4.05 4.12 4.20 4.27 4.34 4.41 4.48 4.55 4.62 4.68 4.75 4.81 4.87 4.94 12 1.00 1.09 1.19 1.29 1.40 1.51 1.63 1.74 1.85 1.96 2.07 2.18 2.29 2.39 2.49 2.59 2.68 2.78 2.87 2.95 3.04 3.12 3.20 3.28 3.36 3.43 3.50 3.57 3.64 3.71 3.78 3.84 3.90 3.97 4.03 4.09 4.15 4.20 4.26 4.31 4.37 4.42 4.47 13 1.00 1.09 1.18 1.27 1.37 1.48 1.58 1.68 1.79 1.89 1.99 2.08 2.18 2.27 2.36 2.45 2.53 2.61 2.69 2.77 2.84 2.92 2.99 3.06 3.12 3.19 3.25 3.31 3.37 3.43 3.49 3.55 3.60 3.66 3.71 3.76 3.81 3.86 3.91 3.96 4.00 4.05 4.09 14 1.00 1.08 1.17 1.26 1.35 1.44 1.54 1.63 1.73 1.82 1.91 2.00 2.08 2.17 2.25 2.32 2.40 2.47 2.54 2.61 2.68 2.74 2.81 2.87 2.93 2.98 3.04 3.09 3.15 3.20 3.25 3.30 3.35 3.39 3.44 3.48 3.53 3.57 3.61 3.66 3.70 3.74 3.77 15 1.00 1.08 1.16 1.24 1.33 1.41 1.50 1.59 1.68 1.76 1.84 1.92 2.00 2.07 2.15 2.22 2.29 2.35 2.41 2.48 2.54 2.59 2.65 2.70 2.76 2.81 2.86 2.91 2.95 3.00 3.04 3.09 3.13 3.17 3.21 3.25 3.29 3.33 3.36 3.40 3.44 3.47 3.51 16 1.00 1.07 1.15 1.23 1.31 1.39 1.47 1.55 1.63 1.71 1.78 1.85 1.93 1.99 2.06 2.12 2.19 2.24 2.30 2.36 2.41 2.46 2.51 2.56 2.61 2.65 2.70 2.74 2.78 2.83 2.86 2.90 2.94 2.98 3.01 3.05 3.08 3.12 3.15 3.18 3.21 3.24 3.28 17 1.00 1.07 1.14 1.21 1.29 1.36 1.44 1.51 1.59 1.66 1.73 1.79 1.86 1.92 1.98 2.04 2.10 2.15 2.20 2.25 2.30 2.35 2.39 2.44 2.48 2.52 2.56 2.60 2.64 2.67 2.71 2.74 2.78 2.81 2.84 2.87 2.90 2.93 2.96 2.99 3.02 3.05 3.08 18 1.00 1.06 1.13 1.20 1.27 1.34 1.41 1.48 1.55 1.62 1.68 1.74 1.80 1.86 1.91 1.97 2.02 2.07 2.11 2.16 2.20 2.25 2.29 2.33 2.36 2.40 2.44 2.47 2.51 2.54 2.57 2.60 2.63 2.66 2.69 2.72 2.75 2.77 2.80 2.83 2.85 2.88 2.90 19 1.00 1.06 1.12 1.19 1.26 1.32 1.39 1.45 1.51 1.58 1.64 1.69 1.75 1.80 1.85 1.90 1.95 1.99 2.03 2.08 2.12 2.15 2.19 2.23 2.26 2.30 2.33 2.36 2.39 2.42 2.45 2.48 2.51 2.53 2.56 2.58 2.61 2.63 2.66 2.68 2.70 2.72 2.75 20 1.00 1.06 1.12 1.18 1.24 1.30 1.36 1.42 1.48 1.54 1.59 1.65 1.70 1.75 1.79 1.84 1.88 1.92 1.96 2.00 2.04 2.07 2.11 2.14 2.17 2.20 2.23 2.26 2.29 2.31 2.34 2.37 2.39 2.42 2.44 2.46 2.48 2.51 2.53 2.55 2.57 2.59 2.61 21 1.00 1.05 1.11 1.17 1.23 1.29 1.34 1.40 1.45 1.51 1.56 1.61 1.65 1.70 1.74 1.78 1.82 1.86 1.90 1.93 1.96 2.00 2.03 2.06 2.09 2.12 2.14 2.17 2.19 2.22 2.24 2.27 2.29 2.31 2.33 2.35 2.37 2.39 2.41 2.43 2.45 2.47 2.49 22 1.00 1.05 1.11 1.16 1.22 1.27 1.32 1.38 1.43 1.48 1.52 1.57 1.61 1.65 1.69 1.73 1.77 1.80 1.84 1.87 1.90 1.93 1.96 1.99 2.01 2.04 2.06 2.09 2.11 2.13 2.15 2.18 2.20 2.22 2.24 2.25 2.27 2.29 2.31 2.33 2.34 2.36 2.37 23 1.00 1.05 1.10 1.15 1.20 1.25 1.31 1.35 1.40 1.45 1.49 1.53 1.57 1.61 1.65 1.68 1.72 1.75 1.78 1.81 1.84 1.87 1.89 1.92 1.94 1.97 1.99 2.01 2.03 2.05 2.07 2.09 2.11 2.13 2.15 2.16 2.18 2.20 2.21 2.23 2.24 2.26 2.27 24 1.00 1.05 1.09 1.14 1.19 1.24 1.29 1.33 1.38 1.42 1.46 1.50 1.54 1.57 1.61 1.64 1.67 1.70 1.73 1.76 1.78 1.81 1.83 1.86 1.88 1.90 1.92 1.94 1.96 1.98 2.00 2.02 2.03 2.05 2.07 2.08 2.10 2.11 2.13 2.14 2.16 2.17 2.18 25 1.00 1.04 1.09 1.14 1.18 1.23 1.27 1.32 1.36 1.40 1.43 1.47 1.51 1.54 1.57 1.60 1.63 1.66 1.68 1.71 1.73 1.76 1.78 1.80 1.82 1.84 1.86 1.88 1.90 1.91 1.93 1.95 1.96 1.98 1.99 2.01 2.02 2.04 2.05 2.06 2.08 2.09 2.10 26 1.00 1.04 1.09 1.13 1.17 1.21 1.26 1.30 1.34 1.37 1.41 1.44 1.48 1.51 1.54 1.56 1.59 1.62 1.64 1.66 1.69 1.71 1.73 1.75 1.77 1.79 1.80 1.82 1.84 1.85 1.87 1.88 1.90 1.91 1.93 1.94 1.95 1.97 1.98 1.99 2.00 2.01 2.02 27 1.00 1.04 1.08 1.12 1.16 1.20 1.24 1.28 1.32 1.35 1.39 1.42 1.45 1.48 1.50 1.53 1.55 1.58 1.60 1.62 1.64 1.66 1.68 1.70 1.72 1.73 1.75 1.77 1.78 1.80 1.81 1.82 1.84 1.85 1.86 1.88 1.89 1.90 1.91 1.92 1.93 1.94 1.95 28 1.00 1.04 1.08 1.12 1.15 1.19 1.23 1.26 1.30 1.33 1.36 1.39 1.42 1.45 1.47 1.50 1.52 1.54 1.56 1.58 1.60 1.62 1.64 1.66 1.67 1.69 1.70 1.72 1.73 1.74 1.76 1.77 1.78 1.79 1.81 1.82 1.83 1.84 1.85 1.86 1.87 1.88 1.89 29 1.00 1.04 1.07 1.11 1.15 1.18 1.22 1.25 1.28 1.31 1.34 1.37 1.40 1.42 1.44 1.47 1.49 1.51 1.53 1.55 1.56 1.58 1.60 1.61 1.63 1.64 1.66 1.67 1.68 1.70 1.71 1.72 1.73 1.74 1.75 1.76 1.77 1.78 1.79 1.80 1.81 1.82 1.83 30 1.00 1.03 1.07 1.10 1.14 1.17 1.20 1.24 1.27 1.29 1.32 1.35 1.37 1.39 1.42 1.44 1.46 1.48 1.49 1.51 1.53 1.54 1.56 1.57 1.59 1.60 1.61 1.63 1.64 1.65 1.66 1.67 1.68 1.69 1.70 1.71 1.72 1.73 1.74 1.75 1.76 1.76 1.77 31 1.00 1.03 1.06 1.10 1.13 1.16 1.19 1.22 1.25 1.28 1.30 1.33 1.35 1.37 1.39 1.41 1.43 1.45 1.46 1.48 1.50 1.51 1.52 1.54 1.55 1.56 1.57 1.59 1.60 1.61 1.62 1.63 1.64 1.65 1.66 1.66 1.67 1.68 1.69 1.70 1.71 1.71 1.72 32 1.00 1.03 1.06 1.09 1.12 1.15 1.18 1.21 1.24 1.26 1.28 1.31 1.33 1.35 1.37 1.39 1.40 1.42 1.43 1.45 1.46 1.48 1.49 1.50 1.51 1.53 1.54 1.55 1.56 1.57 1.58 1.59 1.60 1.60 1.61 1.62 1.63 1.64 1.64 1.65 1.66 1.66 1.67 33 1.00 1.03 1.06 1.09 1.12 1.14 1.17 1.20 1.22 1.24 1.27 1.29 1.31 1.33 1.34 1.36 1.38 1.39 1.41 1.42 1.43 1.45 1.46 1.47 1.48 1.49 1.50 1.51 1.52 1.53 1.54 1.55 1.56 1.56 1.57 1.58 1.59 1.59 1.60 1.61 1.61 1.62 1.63 34 1.00 1.03 1.05 1.08 1.11 1.14 1.16 1.18 1.21 1.23 1.25 1.27 1.29 1.31 1.32 1.34 1.35 1.37 1.38 1.39 1.41 1.42 1.43 1.44 1.45 1.46 1.47 1.48 1.49 1.49 1.50 1.51 1.52 1.53 1.53 1.54 1.55 1.55 1.56 1.57 1.57 1.58 1.58 35 1.00 1.03 1.05 1.08 1.10 1.13 1.15 1.17 1.20 1.22 1.23 1.25 1.27 1.29 1.30 1.32 1.33 1.34 1.36 1.37 1.38 1.39 1.40 1.41 1.42 1.43 1.44 1.45 1.45 1.46 1.47 1.48 1.48 1.49 1.50 1.50 1.51 1.51 1.52 1.53 1.53 1.54 1.54 36 1.00 1.02 1.05 1.07 1.10 1.12 1.14 1.16 1.18 1.20 1.22 1.24 1.25 1.27 1.28 1.30 1.31 1.32 1.33 1.34 1.35 1.36 1.37 1.38 1.39 1.40 1.41 1.42 1.42 1.43 1.44 1.44 1.45 1.46 1.46 1.47 1.47 1.48 1.48 1.49 1.49 1.50 1.50 37 1.00 1.02 1.05 1.07 1.09 1.11 1.13 1.15 1.17 1.19 1.21 1.22 1.24 1.25 1.26 1.28 1.29 1.30 1.31 1.32 1.33 1.34 1.35 1.36 1.36 1.37 1.38 1.39 1.39 1.40 1.41 1.41 1.42 1.42 1.43 1.43 1.44 1.45 1.45 1.45 1.46 1.46 1.47 38 1.00 1.02 1.04 1.06 1.08 1.10 1.12 1.14 1.16 1.18 1.19 1.21 1.22 1.23 1.25 1.26 1.27 1.28 1.29 1.30 1.31 1.32 1.32 1.33 1.34 1.35 1.35 1.36 1.37 1.37 1.38 1.38 1.39 1.39 1.40 1.40 1.41 1.41 1.42 1.42 1.43 1.43 1.43 39 1.00 1.02 1.04 1.06 1.08 1.10 1.12 1.13 1.15 1.16 1.18 1.19 1.21 1.22 1.23 1.24 1.25 1.26 1.27 1.28 1.29 1.29 1.30 1.31 1.31 1.32 1.33 1.33 1.34 1.34 1.35 1.36 1.36 1.37 1.37 1.37 1.38 1.38 1.39 1.39 1.40 1.40 1.40 40 1.00 1.02 1.04 1.06 1.07 1.09 1.11 1.12 1.14 1.15 1.17 1.18 1.19 1.20 1.21 1.22 1.23 1.24 1.25 1.26 1.26 1.27 1.28 1.29 1.29 1.30 1.30 1.31 1.31 1.32 1.32 1.33 1.33 1.34 1.34 1.35 1.35 1.35 1.36 1.36 1.37 1.37 1.37 41 1.00 1.02 1.03 1.05 1.07 1.08 1.10 1.12 1.13 1.14 1.15 1.17 1.18 1.19 1.20 1.21 1.21 1.22 1.23 1.24 1.24 1.25 1.26 1.26 1.27 1.27 1.28 1.29 1.29 1.29 1.30 1.30 1.31 1.31 1.32 1.32 1.32 1.33 1.33 1.33 1.34 1.34 1.34 42 1.00 1.02 1.03 1.05 1.06 1.08 1.09 1.11 1.12 1.13 1.14 1.15 1.16 1.17 1.18 1.19 1.20 1.21 1.21 1.22 1.23 1.23 1.24 1.24 1.25 1.25 1.26 1.26 1.27 1.27 1.28 1.28 1.28 1.29 1.29 1.29 1.30 1.30 1.30 1.31 1.31 1.31 1.32 43 1.00 1.01 1.03 1.04 1.06 1.07 1.09 1.10 1.11 1.12 1.13 1.14 1.15 1.16 1.17 1.18 1.18 1.19 1.20 1.20 1.21 1.21 1.22 1.22 1.23 1.23 1.24 1.24 1.25 1.25 1.25 1.26 1.26 1.26 1.27 1.27 1.27 1.28 1.28 1.28 1.28 1.29 1.29 44 1.00 1.01 1.03 1.04 1.05 1.07 1.08 1.09 1.10 1.11 1.12 1.13 1.14 1.15 1.15 1.16 1.17 1.17 1.18 1.18 1.19 1.20 1.20 1.20 1.21 1.21 1.22 1.22 1.22 1.23 1.23 1.23 1.24 1.24 1.24 1.25 1.25 1.25 1.25 1.26 1.26 1.26 1.26 45 1.00 1.01 1.03 1.04 1.05 1.06 1.07 1.08 1.09 1.10 1.11 1.12 1.13 1.13 1.14 1.15 1.15 1.16 1.16 1.17 1.17 1.18 1.18 1.19 1.19 1.19 1.20 1.20 1.20 1.21 1.21 1.21 1.22 1.22 1.22 1.22 1.23 1.23 1.23 1.23 1.24 1.24 1.24 46 1.00 1.01 1.02 1.03 1.05 1.06 1.07 1.08 1.08 1.09 1.10 1.11 1.11 1.12 1.13 1.13 1.14 1.14 1.15 1.15 1.16 1.16 1.17 1.17 1.17 1.18 1.18 1.18 1.19 1.19 1.19 1.19 1.20 1.20 1.20 1.20 1.21 1.21 1.21 1.21 1.21 1.22 1.22 47 1.00 1.01 1.02 1.03 1.04 1.05 1.06 1.07 1.08 1.08 1.09 1.10 1.10 1.11 1.12 1.12 1.13 1.13 1.13 1.14 1.14 1.15 1.15 1.15 1.16 1.16 1.16 1.16 1.17 1.17 1.17 1.17 1.18 1.18 1.18 1.18 1.19 1.19 1.19 1.19 1.19 1.19 1.20 48 1.00 1.01 1.02 1.03 1.04 1.05 1.05 1.06 1.07 1.08 1.08 1.09 1.09 1.10 1.10 1.11 1.11 1.12 1.12 1.12 1.13 1.13 1.13 1.14 1.14 1.14 1.14 1.15 1.15 1.15 1.15 1.16 1.16 1.16 1.16 1.16 1.17 1.17 1.17 1.17 1.17 1.17 1.18 49 1.00 1.01 1.02 1.03 1.03 1.04 1.05 1.05 1.06 1.07 1.07 1.08 1.08 1.09 1.09 1.10 1.10 1.10 1.11 1.11 1.11 1.12 1.12 1.12 1.12 1.13 1.13 1.13 1.13 1.13 1.14 1.14 1.14 1.14 1.14 1.14 1.15 1.15 1.15 1.15 1.15 1.15 1.15 50 1.00 1.01 1.01 1.02 1.03 1.04 1.04 1.05 1.05 1.06 1.06 1.07 1.07 1.08 1.08 1.08 1.09 1.09 1.09 1.10 1.10 1.10 1.10 1.11 1.11 1.11 1.11 1.11 1.12 1.12 1.12 1.12 1.12 1.12 1.13 1.13 1.13 1.13 1.13 1.13 1.13 1.13 1.14 51 1.00 1.01 1.01 1.02 1.03 1.03 1.04 1.04 1.05 1.05 1.06 1.06 1.06 1.07 1.07 1.07 1.08 1.08 1.08 1.08 1.09 1.09 1.09 1.09 1.09 1.10 1.10 1.10 1.10 1.10 1.10 1.10 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.12 1.12 1.12 52 1.00 1.01 1.01 1.02 1.02 1.03 1.03 1.04 1.04 1.04 1.05 1.05 1.05 1.06 1.06 1.06 1.06 1.07 1.07 1.07 1.07 1.07 1.08 1.08 1.08 1.08 1.08 1.08 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.10 1.10 1.10 1.10 1.10 1.10 53 1.00 1.00 1.01 1.01 1.02 1.02 1.03 1.03 1.03 1.04 1.04 1.04 1.04 1.05 1.05 1.05 1.05 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.08 1.08 1.08 1.08 1.08 1.08 1.08 1.08 1.08 1.08 54 1.00 1.00 1.01 1.01 1.01 1.02 1.02 1.02 1.03 1.03 1.03 1.03 1.04 1.04 1.04 1.04 1.04 1.04 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.06 1.07 1.07 55 1.00 1.00 1.01 1.01 1.01 1.01 1.02 1.02 1.02 1.02 1.02 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 56 1.00 1.00 1.00 1.01 1.01 1.01 1.01 1.01 1.01 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 1.03 57 1.00 1.00 1.00 1.00 1.00 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 58 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2.0 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 2.9 3.0 3.1 3.2 3.3 3.4 3.5 3.6 3.7 3.8 3.9 4.0 4.1 4.2 Coefficient of Variation 4.3 4.4 4.5 4.6 4.7 4.8 4.9 5.0 5.1 5.2 5.3 5.4 5.5 5.6 5.7 5.8 5.9 6.0 6.1 n 289.83 302.12 314.57 327.19 339.96 352.88 365.95 37J.1i 3jz.53 406.03 419.66 433.43 447.33 461.35 475.50 489.76 504.15 518.65 533.27 1 63.09 65.03 66.98 68.93 70.89 72.85 74.81 76.78 78.75 80.72 82.69 84.67 86.64 88.62 90.60 92.58 94.56 96.54 98.52 2 30.38 31.15 31.92 32.68 33.44 34.20 34.96 35.72 36.47 37.22 37.97 38.71 39.46 40.20 40.93 41.67 42.40 43.13 43.86 3 19.14 19.56 19.98 20.39 20.80 21.21 21.61 22.02 22.42 22.82 23.21 23.61 24.00 24.39 24.77 25.16 25.54 25.92 26.30 4 13.75 14.02 14.28 14.55 14.81 15.06 15.32 15.57 15.82 16.07 16.32 16.56 16.81 17.05 17.29 17.53 17.76 18.00 18.23 5 10.66 10.85 11.04 11.22 11.40 11.58 11.76 11.93 12.10 12.28 12.45 12.62 12.78 12.95 13.11 13.28 13.44 13.60 13.76 6 8.69 8.83 8.96 9.10 9.23 9.37 9.50 9.63 9.75 9.88 10.01 10.13 10.25 10.37 10.49 10.61 10.73 10.85 10.96 7 7.33 7.43 7.54 7.65 7.75 7.85 7.95 8.05 8.15 8.25 8.34 8.44 8.53 8.63 8.72 8.81 8.90 8.99 9.08 8 6.34 6.42 6.51 6.59 6.67 6.76 6.84 6.91 6.99 7.07 7.15 7.22 7.30 7.37 7.44 7.52 7.59 7.66 7.73 9 5.58 5.65 5.72 5.79 5.86 5.93 5.99 6.06 6.12 6.19 6.25 6.31 6.37 6.43 6.49 6.55 6.61 6.66 6.72 10 5.00 5.05 5.11 5.17 5.23 5.28 5.34 5.39 5.44 5.50 5.55 5.60 5.65 5.70 5.75 5.80 5.85 5.89 5.94 11 4.52 4.57 4.62 4.67 4.72 4.77 4.81 4.86 4.90 4.95 4.99 5.03 5.08 5.12 5.16 5.20 5.24 5.28 5.32 12 4.14 4.18 4.22 4.26 4.30 4.35 4.38 4.42 4.46 4.50 4.54 4.57 4.61 4.65 4.68 4.72 4.75 4.78 4.82 13 3.81 3.85 3.89 3.92 3.96 3.99 4.03 4.06 4.10 4.13 4.16 4.19 4.22 4.26 4.29 4.32 4.35 4.37 4.40 14 3.54 3.57 3.60 3.64 3.67 3.70 3.73 3.76 3.79 3.82 3.84 3.87 3.90 3.93 3.95 3.98 4.00 4.03 4.05 15 3.30 3.33 3.36 3.39 3.42 3.44 3.47 3.50 3.52 3.55 3.57 3.60 3.62 3.65 3.67 3.69 3.71 3.74 3.76 16 3.10 3.13 3.15 3.18 3.20 3.23 3.25 3.27 3.30 3.32 3.34 3.36 3.38 3.40 3.42 3.44 3.46 3.48 3.50 17 2.92 2.95 2.97 2.99 3.01 3.03 3.06 3.08 3.10 3.12 3.14 3.16 3.17 3.19 3.21 3.23 3.25 3.26 3.28 18 2.77 2.79 2.81 2.83 2.85 2.87 2.89 2.90 2.92 2.94 2.96 2.97 2.99 3.01 3.02 3.04 3.06 3.07 3.09 19 2.63 2.65 2.66 2.68 2.70 2.72 2.73 2.75 2.77 2.78 2.80 2.81 2.83 2.84 2.86 2.87 2.89 2.90 2.91 20 2.50 2.52 2.54 2.55 2.57 2.58 2.60 2.61 2.63 2.64 2.66 2.67 2.68 2.70 2.71 2.72 2.74 2.75 2.76 21 2.39 2.41 2.42 2.44 2.45 2.46 2.48 2.49 2.50 2.52 2.53 2.54 2.56 2.57 2.58 2.59 2.60 2.61 2.63 22 2.29 2.30 2.32 2.33 2.34 2.36 2.37 2.38 2.39 2.40 2.42 2.43 2.44 2.45 2.46 2.47 2.48 2.49 2.50 23 2.20 2.21 2.22 2.23 2.25 2.26 2.27 2.28 2.29 2.30 2.31 2.32 2.33 2.34 2.35 2.36 2.37 2.38 2.39 24 2.11 2.12 2.13 2.15 2.16 2.17 2.18 2.19 2.20 2.21 2.22 2.23 2.24 2.25 2.25 2.26 2.27 2.28 2.29 25 2.03 2.04 2.06 2.07 2.08 2.09 2.09 2.10 2.11 2.12 2.13 2.14 2.15 2.16 2.16 2.17 2.18 2.19 2.20 26 1.96 1.97 1.98 1.99 2.00 2.01 2.02 2.03 2.04 2.04 2.05 2.06 2.07 2.07 2.08 2.09 2.10 2.10 2.11 27 1.90 1.91 1.91 1.92 1.93 1.94 1.95 1.96 1.96 1.97 1.98 1.99 1.99 2.00 2.01 2.01 2.02 2.03 2.03 28 1.84 1.84 1.85 1.86 1.87 1.88 1.88 1.89 1.90 1.90 1.91 1.92 1.92 1.93 1.94 1.94 1.95 1.95 1.96 29 1.78 1.79 1.79 1.80 1.81 1.82 1.82 1.83 1.84 1.84 1.85 1.85 1.86 1.87 1.87 1.88 1.88 1.89 1.89 30 1.73 1.73 1.74 1.75 1.75 1.76 1.77 1.77 1.78 1.78 1.79 1.80 1.80 1.81 1.81 1.82 1.82 1.83 1.83 31 1.68 1.68 1.69 1.70 1.70 1.71 1.71 1.72 1.72 1.73 1.74 1.74 1.75 1.75 1.76 1.76 1.76 1.77 1.77 32 1.63 1.64 1.64 1.65 1.65 1.66 1.66 1.67 1.67 1.68 1.68 1.69 1.69 1.70 1.70 1.71 1.71 1.72 1.72 33 1.59 1.59 1.60 1.60 1.61 1.61 1.62 1.62 1.63 1.63 1.64 1.64 1.65 1.65 1.65 1.66 1.66 1.67 1.67 34 1.55 1.55 1.56 1.56 1.57 1.57 1.58 1.58 1.58 1.59 1.59 1.60 1.60 1.60 1.61 1.61 1.61 1.62 1.62 35 1.51 1.51 1.52 1.52 1.53 1.53 1.53 1.54 1.54 1.55 1.55 1.55 1.56 1.56 1.56 1.57 1.57 1.57 1.58 36 1.47 1.48 1.48 1.49 1.49 1.49 1.50 1.50 1.50 1.51 1.51 1.51 1.52 1.52 1.52 1.53 1.53 1.53 1.54 37 1.44 1.44 1.45 1.45 1.45 1.46 1.46 1.46 1.47 1.47 1.47 1.48 1.48 1.48 1.48 1.49 1.49 1.49 1.50 38 1.41 1.41 1.41 1.42 1.42 1.42 1.43 1.43 1.43 1.43 1.44 1.44 1.44 1.45 1.45 1.45 1.45 1.46 1.46 39 1.38 1.38 1.38 1.38 1.39 1.39 1.39 1.40 1.40 1.40 1.40 1.41 1.41 1.41 1.41 1.42 1.42 1.42 1.42 40 1.35 1.35 1.35 1.35 1.36 1.36 1.36 1.37 1.37 1.37 1.37 1.37 1.38 1.38 1.38 1.38 1.39 1.39 1.39 41 1.32 1.32 1.32 1.33 1.33 1.33 1.33 1.34 1.34 1.34 1.34 1.34 1.35 1.35 1.35 1.35 1.35 1.36 1.36 42 1.29 1.29 1.30 1.30 1.30 1.30 1.31 1.31 1.31 1.31 1.31 1.32 1.32 1.32 1.32 1.32 1.32 1.33 1.33 43 1.27 1.27 1.27 1.27 1.28 1.28 1.28 1.28 1.28 1.28 1.29 1.29 1.29 1.29 1.29 1.29 1.30 1.30 1.30 44 1.24 1.24 1.25 1.25 1.25 1.25 1.25 1.26 1.26 1.26 1.26 1.26 1.26 1.26 1.27 1.27 1.27 1.27 1.27 45 1.22 1.22 1.22 1.22 1.23 1.23 1.23 1.23 1.23 1.23 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.25 46 1.20 1.20 1.20 1.20 1.20 1.21 1.21 1.21 1.21 1.21 1.21 1.21 1.21 1.22 1.22 1.22 1.22 1.22 1.22 47 1.18 1.18 1.18 1.18 1.18 1.18 1.18 1.19 1.19 1.19 1.19 1.19 1.19 1.19 1.19 1.19 1.20 1.20 1.20 48 1.16 1.16 1.16 1.16 1.16 1.16 1.16 1.16 1.17 1.17 1.17 1.17 1.17 1.17 1.17 1.17 1.17 1.17 1.17 49 1.14 1.14 1.14 1.14 1.14 1.14 1.14 1.14 1.14 1.15 1.15 1.15 1.15 1.15 1.15 1.15 1.15 1.15 1.15 50 1.12 1.12 1.12 1.12 1.12 1.12 1.12 1.12 1.12 1.13 1.13 1.13 1.13 1.13 1.13 1.13 1.13 1.13 1.13 51 1.10 1.10 1.10 1.10 1.10 1.10 1.10 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.11 52 1.08 1.08 1.08 1.08 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 53 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 1.07 54 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.06 1.06 1.06 1.06 55 1.03 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 1.04 56 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 57 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 1.01 58 4.3 4.4 4.5 4.6 4.7 4.8 4.9 5.0 5.1 5.2 5.3 5.4 5.5 5.6 5.7 5.8 5.9 6.0 6.1 I Multiplication Factor RPMFs as f(n,CV,Confidence,UpperBound) 400.00 350.00 300.00 250.00 200.00 150.00 100.00 50.00 0.00 y 1.1 0.1 1 4 7 10 13 16 19 22 25 n ❑ 350.00-400.00 ❑ 300.00-350.00 ❑ 250.00-300.00 ❑ 200.00-250.00 ❑ 150.00-200.00 ❑ 100.00-150.00 ❑ 50.00-100.00 ❑ 0.00-50.00 9/11/2013 rdb New freshwater RPA based on 95% probability/95% confidence Statistically 58 points are the maximum number of points allowed under this RPA program. Data fields were estbalished to allow only 58 data point entries. Additional messages will appear to alert user if more than 58 data points were enter and no predicted values will be calculated All worksheets are "Protected" The "mf calculator" is password "Protected" OTHER CHANGES FROM PREVIOUS RPA PROGRAM: A. When Model is applied (Check box activated): 1) assumes only chroinc dilution known 2) assumes user will insert appropriate flow values for "7Q10s (cfs)", "7Q10w (cfs)", "30Q2 (cfs)", "QA (cfs)" to define chronic dilution in terms of "IWC %", "IWC %" is the same for all stream flows 3) automatically assigns the entered chronic IWC % to the "IWC @ 7Q10s", "IWC @ 7Q10w", "IWC @ 30Q2", "IWC @ QA" values used in chronic WQS calculations (See "RPA" page) 3) "1 Q10s (cfs)" automatically defaults to no acute dilution, acute IWC = 100% ,"IWC @ 1 Q10s" = 100% which is used in acute WQS calculatons (See "RPA" page) B. When Model is not applied (Check box NOT activated): 1) assumes user will insert appropriate flow values for "7Q10s (cfs)", "7Q10w (cfs)", "30Q2 (cfs)", "QA (cfs)" , "Flow Qw (MGD)" for chronic IWC % calculations, IWC % will vary according to flows 3) automatically calculates chronic -based IWC % for the "IWC @ 7Q10s", "IWC @ 7Q10w", "IWC @ 30Q2", "IWC @ QA" values used in chronic WQS calculations (See "RPA" page) 3) "1 Q10s (cfs)" is automatically calculated bases on entered "7Q10s (cfs)" flow 4) automatically calculates acute -based IWC% for the "IWC @ 1 Q10s" value used in acute WQS calculations (See "RPA" page) C. When paremeter's "Impaired?" check box is activated: 1) automtically activtes the "IMPAIRED" message alert on the "RPA" page for that parameter 2) does NOT make any automatic adjustements to WQS calculations NOTE: If new or expanding discharge and receiving stream impaired, will need to evaluate if additional waste load is allowed 10/30/2013 rdb 1) Amended "ERR" alert on data sets entreies to activate if "<" entered but no value entered, does not effect RPA calculation, ERR message only 2) Added new calculation feature to count nondetects when both "<" and a value are entered for each data set, used to calculate detected entries 3) Amended "Comments" drop down menu - per Juile 4) Turned the Chronic toxicity concentration message off on the RPA page - per Julie 2/10/14: ON "data" page changed highlighted area from blue shades to gray 5/2/14 rdb 1) Increased rounding factor on all calculated IWC% to 7 decimals 2) Increased display for all calkculated to 6 decimals places. 5/5/14 rdb Increased rounding factor on all calculated IWC% to 9 decimals 5/21/14 rdb Removed ROUND function from all IWC% calculations 7/31/14 rdb Moved RPA page tile blocks down one row so header text was separated 9/9/15: COMPLETED REVISIONS FOR METAL TRANSLATOR FEATURE 1) Added tabs for "HUC Hardness" (lookup table for HUC hardness values), "Hardness Equations" (summary of translator formulas, metals impacted, general info), "Dss to Total Hardness Calculator" (calcution sheet for metal translator, impacted chronic and acute wqs) 2) Revised "Input" page Table 1: - New user input for "8 Digit HUC Number" uisng drop down menu for lookup HUC Hardness, required entry, brown highlight - New display only for calculated "Effluent Hardness (Median)" including conditional method for info display, brown highlight - New display only for designed "HUC Hardness (Median)" incuding conditionla method for info display, brown highlight - New display only for calculated "Combined Hardness Chronic" for metal translator application, brown highlight - New display only for calculated "Combined Hardness Acute" for metal translator application, brown highlight - Assigned name for "HUC Number" 3) Revised "Input" pade Table 2: - Removed "Impaired ?" column, conditional display, references - Added new column for "WQS" designation incuding assigning applicable WQS where fixed - Added new error message "CHECK WQS", conditonal control based on "WQS" entry for Cadmium, Chlorides, Molybdeum, Nickel - Revised text in error message - Added new brown highlight "Metal Translator Data Entry" label box - Removed Par01 "Arsenic" line - Revised Par02 " Arsenic" line to reflect Human Health and Water Supply criterion, Chronic = 10 mg/L, Acute = "N/A" - Revised Par04 "Cadmium" line: a) "WQS" input with drop down menu to select applicable criterion b) "Chronic" and "Acute" inputs to display calculated metal translator values including conditional method for info display based on "WQS" selection, no rounding c) "Modifier" input display only based on "WQS" selection including conditional method for info dispaly d) Conditonal controls to activate error nessages, brown highlight - Revised Par05 "Chloride (AL)" line: a) "WQS" input with drop down menu to select applicable criterion b) "Chronic" display only for applicable value including conditional method for info display based on "WQS" selection c) "Modifier" input display only based on "WQS" selection including conditional method for info dispaly d) "Name" display only based on "WQS" selection including conditional metdod fro info display e) Conditonal controls to activate error nessages - Revised "Chromium, Total" line: a) Removed Par08 label b) "Chronic" and "Acute" inputs to display calculated metal translator values, no rounding c) brown highlight - Added new "Chromium III" line: a) Assigned applicable text in "WQS", "Type", Modifier", Units" b) "Chronic" and "Acute" inputs to display calculated metal translator values, no rounding c) brown highlight - Added new Par08 "Chromium VI" line: a) Assigned Par08 label, applicable text in "WQS", "Type", Modifier", Units" b) "Chronic" and "Acute" inputs to display calculated metal translator values, no rounding c) brown highlight - Revised Par09 "Copper (AL)" line: a) "Chronic" and "Acute" inputs to display calculated metal translator values, no rounding b) brown highlight - Revisd Par12 "Lead" line: a) "Chronic" and "Acute" inputs to display calculated metal translator values, no rounding b) brown highlight - Revised Par14 "Molybdenum" lime: a) "WQS" input with drop down menu to select applicable criterion b) "Chronic" display only for applicable value including conditional method for info display based on "WQS" selection c) "Modifier" input display only based on "WQS" selection including conditional method for info dispaly d) Conditonal controls to activate error nessages - Revised Par15 "Nickel" line: a) "WQS" input with drop down menu to select applicable criterion b) "Chronic" and "Acute" inputs to display calculated metal translator values including conditional method for info display based on "WQS" selection, no rounding c) "Modifier" input display only based on "WQS" selection including conditional method for info dispaly d) Conditonal controls to activate error nessages, brown highlight - Revised Par17 "Silver (AL)" line: a) "Chronic" and "Acute" inputs to display calculated metal translator values, no rounding b) brown highlight - Revised Par18 "Zinc (AL)" line: a) "Chronic" and "Acute" inputs to display calculated metal translator values, no rounding b) brown highlight 3) Revised "Data" page: - Revised Par01 "Arsenic" entry, text, and calculations ("1 ") - all effluent hardness data to be entered in this section for used to calculate eflluent hardness factors a) Reference to Par01 "Arsenic" removed b) New label "Effluent Hardness (monthly average)" added c) "Mult Factor =" and "Max. Pred Cw" removed, text and calcuation d) "10% value" and "Median value" added, text and calculation including conditional method for info display e) Assigned name "Effluent_Median" and "effluent_10" to calculated values f) PQL condition removed from calculation method for data displayed 4) Revised "RPA" page: - Removed all features assocaited with "Impairment" - Added new display only for calculated "COMBINED HARDNESS (mg/L)", Chonic and Acute, conditional method for info display - Revised "Receiving Stream" display to include selected HUC Number in text - Removed unused display features for WET % (previouly hidden) - Revised "Arsenic" lines: a) Par01 "Arsenic" line removed b) Par02 "Arsenic" references used for display to calculate "Acute" and Chronic" allowable Cw - Revised "Cadmium", "Chromium VI", "Copper (AL)", "Lead", "Nickel", "Silver (AL)", "Zinc (AL)" (lines: a) "NC WQS/Chronic" and 1/2 FAV/Acute" conditional method revised for info display, no rounding b) "Allowable Cw" Acute" and "Chronic" conditional metfhod revised fro info display inculding rounding value 5) Revised "Dss to Total Metal Hardness Calculator" page - Assigned names for: a) "CdMAE_AC" - Cadmium calculated metal translator Acute value b) "CdMAE_CH" - Cadmium calculated metal translator Chronic value c) "CuMAE_AC" - Copper calculatd metal translator Acute value d) "CuMAE_CH" - Copper calculated metal translator Chronic value e) "Cr_Total_AC" - Total Chromium calculated meatl translator Acute value f) "Cr_Total_CH" - Total Chromium calculated metal translator Chronic value g) "CrIIIMAE_AC" - Chromium III calculated metal translator Acute value. h) "CrIIIMAE_CH" - Chromium III calculated metal tramslator Chronic value i) "CrVIMAE_AC" - Chromium VI calculated metal translator Acute value j) "CrVINAE_CH" - Chromium VI calculatd metal translator Chronic value k) "PbMAE_AC" - Lead calculated metal translator Acute value m) "PbMAE_CH" - Lead calculated metal translator Chronic value n) "NiMAE_AC" - Nickel calculated metal translator Acute value o) "NiMAE_CH" - Nickel calculated metal translator Chroniv value p) "AuMAE_AC" - Silver calculated metal translator Acute value q) "AuMAE_CH" - Silver calculated metal translator Chronic value r) "ZnMAE-AC" - Zinc calculated metal translator Acute value s) "ZnMAE_CH" - Zinc calculated metal translator Chronic value t) "tss" - assigned TSS harness factor u) "CHA" - calculated combined acute hardness value v) "CHC" - calculated combined chronic hardness value - Added conditional methods to formulas for info display and to incorporate names, no rounding 6) Set up passwortd to protect all pages 'rpa2015' 1/12/16 ADDED ARSENIC AQUATIC LIFE PARAMETER BACK TO ACTIVE RPA EVALUATION 1) Inserted "Aresenic, Aquatic Life, C, 50, FW, N/A, pg/L" in first row "INPUT" Table 2, Par01 2) Updated program names to reflect addition of new Arsenic Aquatic Life parameter 3) Inserted "Arsenic" Aquatic Life parameter and cell programming in Arsenic section "RPA" as Chronic and added drop down menu feature 4) Amended labels on "Data" to show H for hardnes and Par01-Par22 for paremeters 1/12/16 REVISED IWC CALCULATIONS TO SHOW FULL DISPLAY on "RPA" 1) Reformatted IWC calculation cells to show caculated value as general (number value will always be displayed) 2) Revised IWC calculation formula to x by 100 to mimic 3) Revised IWC calculation labels to include "%" 4) Revised all calculations using IWC values "Acute", "Chronic" to divide by 100 to correct for IWC % value 1/12/16 REVISED SPREADSHEET TO INDICATE NO DETECT AND MDL 1) Revised "Data" Par01-Par22 Max Value cell conditional statement to display "NO DETECTS" when data set has all no detects 2) Revised "RPA" all parameters Max Pred CW cell formatting to display "NO DETECTS" when required to display no detects 3) Revised "RPA" alert message (under Chronic labels) conditional statement to display "Max MDL = <2 x max adjusted data set value> when data set has all no detects 4) Revised "RPA" drop menu to add "No detects" to list and display 1/12/16: Corrected formula error in mf formula Par01 to use corrected data set ("Data") Revised "RPA" Cadmium, Copper, Lead, Nickel, Silver, Zinc Acute and Chronic cell conditional statements to have cell display blank if WQS is blank or WQS displays "NO DATA" 1/21-29/16: 1) Expanded parameter list and program features to add two additional parameters, (Par08) "Chromium III" & (Par09) "Chromium VI". This included adding two new data input sections on "Data" tab with new corresponding RPA evalutaion, non -detect evaluation, formulas for each new data input section; adding two new parameter summary sections to "RPA" tab; revising exsiting parameter designation to new assigned name (Par10 - Par24), data set (_Data08 - _Data24), non -detects (_ND08 - _ND24). 2) For consistency rearranged display, "Input" & "RPA" tabs, to be "Chromium III", "Chromium VI", "Chromium, Total". All features and programing unique to each display was revised accordingly. 3) Corrected Arsenic - Aquatic Life, Berylium Chronic and Acute values on "Input" tab to be exported from metal translator table. 4) Revised "Input" tab HUC Hardness (median) display conditional formula to display "default 25 mg/L (HUC Hard Med = NA mg/I)" when HUC hardness is NA. 5) Revised combined hardness acute (CHA) and combined hardness chronic (CHC) conditional formulas to assign 25 as hardness value when HUC hardness is NA. 6) Revised "RPA" tab Chromium, Total Reasonable Potential Results section to remove Acute and Chronic labels and allowable Cw calulation/display, area now blank except for MDL feature display. 7) Revised "RPA" tab Chromium III and Chromium VI Reasonable Potential Results sectons to remove display of values for n, #Det, Max Pred Cw, area blank except for display features from added condtional formulas that reference Chromium, Total display and data. NOTE: All RPA evaluation data is generated on each parameter "Data" section and imported to that parameter's "RPA" section, thus, RPA evaluation data can be displayed/used when programmed to do so. 8) Revised "RPA" tab Acute and Chronic conditional formulas for active parameters to display either "IWC?" or "IWC/DATA?" as default until appropraite data is provided. 9) Removed label from "Input" tab. 10) Corrected chlorinated list ("Input" & "Data" tabs) lists, now shows correct 2,4,6-trichlorophenol for Method 625. See task notes 2/3/16: Revised "input"page model feature to a- Add new model 1 Q10S input cell that is visible on;y when model feature is activated b- Revise cell formula 1 Q10s (cfs) to display 1 Q10s flow when model feature activated or calculate from 7Q10s flow when model feature NOT activated and 7Q10s flow displayed c- Revised instructions narrartive that is visible only when model feature is activated 2/9/16: Revised "input" page Effluent Hardness (Median) cell formula to display "default 99 mg/L (Efflunet Hard Med = <actual value> mg/L)" when stream class is WS and Effluent Hard Med is greater than 99.999 mg/L Revised "data" page Effluent Hardness (Median) cell formula to display 99 whenstream class is WS and Effluent Hard Med is greater than 99.999 mg/L Added new display messages to "rpa" page that are visible only when the steam class is water supply 2/16/16: 1) Revised "Diss to Total Metal Calculator" page: added new cells to display actual calculated Effluent & HUC Median values and to display "Apply Water Supply Criterion" when applicable (stream class is Water Supply based and Efflunet Hard Med exceeds 99.999 mg/L) revised the existing calculation input/display cells for Effluent & HUC Hardness Median to show the applied hardness value based on new conditional formula as follows a- If HUC Hard Med = NA or less than 25 mg/L then default HUC Hard Med to 25 mg/L b- If Effluent Hard Med less than 25 then default Effluent Hard Med to 25 mg/L c- If stream class is WS and Effluent Hard Med is greater than 99.9999 mg/L then default Effluent Hard Med to 99 mg/L 2) Revised "input" page dipplay HUC Hardness (Median) to show NA when HUC table value is NA. 2/19/16: Added new WS WQC button to "input" page, activates effluent hardness to apply WS WQC standards, does NOT set parameter modifiers, still must do modifers individually Added Nickel WS parameter to "input" page Added Niche! WS to "rpa" page, revised both Nickel parametesr to share commom data, Nickel WS has no Acute standard so only list acute for FW Set up both Nickel Par17 & Par18 to use same data entries Changed Par22-25 modifier cells to be set automtically based on WQS entry. Changed display font color phenols, chlorinared phenols menus 2/22/16: Make text changes per Julie direction. 2/24/16: Added to " Diss to Total Metal Calculator" page: 1) Comment section for PERCS info or other to allow user to add commentary 2) Added Facility name to display based on input page 3) Added NPDES permit# to display based on input page 4) Set up new Name "PERCS_page" as print area for table and other PERCS info for GOTO use. NOTE: User can either highlight desire print area or use GOTO feature to set up desired print arae. When in print mode set up, will need to designate "Print Selection". 3/18/16: Removed HUC table and HUC hardness lookup features from calculations and program. Note: HUC number is an available option on the INPUT as an informational input only to use as a display label for other portion of the progam and has no Data Validation features. Added Upstream Hardness calculation feature using measured upstream data: 1) INPUT display shows "Upstream Hardess" status and how upstream data is applied 2) DATA has new Upstream Hardness input sheet to accept upstream hardness data used to calculate number of data enties, data set average, data set 10th percentile value 3) Diss to Total Metal Calculator determines which upstream hardness to apply, if the number of data entries exceed 30 then the average value is used, if the number of data enties are less than 30 then the 10th percentile value is used. Anytime the applied upstream hardness is less than 25 mg/L then a default value of 25 mg/L is applied. 4/26/16: Per Julia want to use average values for both the effluent and upstream hardness calculations. Defaults to be the same as was applied in the HUC base RPA. 1) Changed all upstream hardness median calculations to average calculations. 2) Removed any greater than 99.999 defaults from upstream hardness conditional statements. Upstream average will be actual execpt when less than 25, then 25 is the default. 3) Changed all effluent hardness median calculations to average calculations. Conditional statements for WS still apply, efflunet average value above 99.999 default to 99. 4) Any conditional statement referring to median hardness were revised. 5) Removed "(AL)" from parameter labels as no longer applicable. 6) Renamed RPA to describe features 4/27/16: Per Julia when WS is being applied, the combined acute and chroinc hardness needs to default to 100 if the combined hardness exceeds 100. Made changes: 1) Set up new cells to calculate combined acute and chronic hardness, defined cells as program names ACCH & ACAH. 2) Revised the conditional statemenst for CHC and CHA to default to 100 if ACCH & ACAH exceed 100 when WS was applied. 3) Revised INPUT page Combined Acute and Chronic display condtitional statements to indicate defaults 4) Revised RPA page Combined Hardness Acut and Chronic displays conditional statemenst to indicate defaults 4/28/16: Fixed programming errors so "NO DETECTS" display feature on RPA page for Nickel and Chromium VI now function. Revised RPA page drop menu "Recommended Action" list to remove RP Action Level text and change "RP non action level..." text to state "RP shown...". Added statement to 2B .0500 RULES page "4/28/16: Note Action Level designation no long allowed per EPA." 4/29/16: Added ROUND function to conditional statements on INPUT page hardess displays to limit hardness value display to 2 decimal points. Revised upstream default conditional factor to 24.9999 on INPUT page to allow actual upstream hardness of 25 to be displayed as non -default value. 5/6/16: Removed less than 25 mg/L default from all effluent and upstream hardness conditional programming 5/11/16: Added new conditional display to Total Chromium Pred Cw box RPA page to compare Total Chromium data to Cr III and Cr VI Allowable Cw Added new conditional display to Total Chromium Allowable Cw box RPA page to indicate maximum Total Chromium value entered 6/13/16: Revised title block text RPA tab to state "NC STANDARDS OR EPA CRITERIA", removed "NC WQS" from Chronic label, and removed 1/2 FAV from Acute label. Corrected INPUT tab to align Dats Source(s) text box at top. 6/14/16: Revised conditions for calculated combined hardness acute and chroinc to default to 400 mg/L if calculated value exceeded 400 mg/L Revised conditions for INPUT page display combined hardness acute and chroinc to indicate when default 400 mg/L applied Corrected label on DISS ... page to indicate average for effluent and upstream hardness 7/13/16: Revised Model input feature when activated to calculate Model 7Q10s (cfs) flow based on entry of Qw, MGD and CHRONIC DILITION FACTOR (from Model) and display in Model narrative box. User will need to enter calculated 7Q10s displayed in Model narrative box to Table 1 7Q10s, (cfs) entry box. 1 Q10s is calculated once the calculated 7Q10s (cfs) is entered in Tablel . Revised narrative in Model narrative box with new instructions, new messages to alert user on actions needed and/or completed to correctly enter Model 7Q10s (cfs) in Table 1. Remove conditions and features assocaited with entry of Model Acute IWC % . Date: 8/13/2021 Dissolved to Total Metal Calculator Do NOT enter any data directly into this spreadsheet. Enter data onto "Table 1" under the Input Sheet and enter "Effluent Hardness" under the Data Sheet. In accordance with 40 CFR 122.45 (c ), permits are, have and must be written as total metals. This calculator has been inserted into the RPA to calculate Total Metal allowable allocations once Table 1 has been completed (Input Sheet) and Effluent hardness has been entered (Data Sheet). 1) Following the spreadsheet from left to right. First the allowable allocations for the dissolved metals will appear for all the metals listed once Table 1 is complete and effluent hardness entered. Use a default value of 25 mg/L if no hardness data is available. Second, the Dissolved Metal allocations are divided by the Translators to determine the Total Metals that can be allocated to the Permittee. These Total Metals values are automatically inserted into Table 2 and are the allowable Total Metal allocations determined for the Permittee prior to allowing for dilution. See Input sheet Table 2. The final acute and chronic values shown under the RPA sheet are the Total Metal values listed in Table 2 divided by the acute and chronic IWC, respectively. 2) The Translators used in the freshwater RPA are the Partition Coefficients published by US EPA in 1984. They are TSS dependent equations and can be found listed with the WQS hardness dependent equations under the sheet labeled Equations. A fixed TSS value of 10 mg/L is used to calculate the Translator values. 3) Pretreatment Facilities - PERCS will need a copy of the Dissolved to Total Metal Calculator spreadsheet and the RPA sheet along with the Final Permit. Pretreatment Facilities are required to renew their Headwords Analysis after renewal of their permits. Since all their metal allocations are likely to change PERCS needs to see any new metal permit limits and the allowable allocations for the dissolved metals to assess Maximum Allowable Headworks Loading (MAHL) numbers for each metal based on the Combined Hardness values used in the permit writers RPA calculations. 4) For Cadmium, Lead, Nickel, Chromium and Beryllium, if all the effluent sampling data for the last three to five years shows the pollutant at concentrations less than the Practical Quantitative Level (PQL), it is not likely a limit or monitoring will be put in the permit. However, if the estimated NPDES permit limit is less than the Practical Quantitative Limit (particularly, Cadmium and Lead) and the pollutant is believed to be present, to assess compliance with the new standards and for future permit limit development, monitoring for the pollutant will be required. If the facility is monitoring for the pollutant in its Pretreatment LTMP, no monitoring is needed in the permit. 5) For monitoring and compliance purposes if Total FACILITY: Belews Steam Station NPDES PERMIT: NC0024406 Dissolved to Total Metal Calculator In accordance with Federal Regulations, permit limitations must be written as Total Metals per 40 CFR 122.45(c) Receiving Stream summer 7Q10 (CFS) PARAMETER 80.0000 Receiving Stream summer 7Q10 (MGD) Rec. Stream 1Q10 [MGD] 51.6129 42.1935 NPDES Flow Limit [MGD] Total Suspended Solids -Fixed Value- (mg/L) 18.6000 1 10 Dissolved Metals Chronic Acute [ug/l] [ug/l] US EPA Translators- using Default Partition Coefficients (streams) Maximum Allowable Effluent Concentration (MAEC) as a Total Metal =Dissolved Metal Translator Chronic Acute Combined Hardness chronic (mg/L) 25.000 Combined Hardness Acute (mg/L) 25.000 Instream Wastewater Concentration (Chronic) 26.4909 Instream Wastewater Concentration (Acute) 30.5954 Upstream Hardness Average (mg/L) 25 Upstream Hard Avg (mg/L) = EFF Hard Avg (mg/L) = Effluent Hardness Average (mg/L) 25 25 25 [ug/I] [ug/I] Cadmium (d) Cd -Trout streams Chromium III (d)(h) Chromium VI (d) Chromium, Total (t) Copper (d)(h) Lead (d)(h) Nickel (d)(h) Ni - WS streams (t) Silver (d)(h,acute) Zinc (d)(h) 0.15 0.15 24 11 2.7 0.54 16 0.06 36 0.82 0.51 183 16 3.6 14 145 0.30 36 0.252 0.252 0.202 1.000 0.348 0.184 0.432 1.000 0.288 0.59 0.59 117.73 11.00 N/A 7.88 2.94 37.23 3.24 2.01 905.08 16.00 N/A 10.47 75.49 335.21 25 N/A 0.06 0.30 126.73 125.71 Beryllium Arsenic (d) 6.5 150 65 340 1.000 1.000 6.5 150 65 340 COMMENTS (identify parameters to PERCS Branch to maintain in facility's LTMP/STMP): (d) = dissolved metal standard. See 15A NCAC 02B .0211 for more information. (h) = hardness -dependent dissolved metal standard. See 15A NCAC 02B .0211 for more information. (t) = based upon measurement of total recoveable metal. See 15A NCAC 02B .0211 for more information. The Human Health standard for Nickel in Water Supply Streams is 25 mg/L which is Total Recoverable metal standard. The Human Health standard for Arsenic is 10 µg/L which is Total Recoverable metal standard. ACAH ACCH Dissolved Metals & Hardness Determination v. 5/27/2010 I. How to Determine Hardness for use with Dissolved Freshwater Standards for Permitting Purposes HARDNESS - Use 25 mg/L, expressed as CaCO, or Ca+Mg, as the default Hardness OR To determine a Hardness value for permit limit development, use the following equation: Hardness (mass balance) (Hardness instream(a), mg/L * 7Q10, MGD)+(Hardness effluent(b), mg/L* Plant flow, MGD) (7Q10, MGD + Plant flow, MGD) (a) Use the median instream Hardness value of the ambient 8-digit HUC data collected by the Division of Water Quality. To find the 8-digit HUC hardness value for your facility Click Here. (b) For the purpose of this estimation, use the facility's median effluent Hardness value, if available. The Division will request the permittee to sample effluent hardness once/month and submit one to two years of data with the permit renewal application. If no effluent hardness data is submitted, a default of 25 mg/L will be applied. II. To Develop Dissolved Metal concentrations for permitting purposes use the Freshwater Standards for Hardness Dependent Metals listed in Table A below. Table A: Dissolved Freshwater Standards for Hardness Dependent Metals Metal pg/L Cadmium, Acute {1.136672-[In hardness](0.041838)} • e^{0.9151 [In hardness]-3.1485} Cadmium, Acute (Trout Waters) {1.136672-[In hardness](0.041838)} • e^{0.9151[In hardness]-3.6236} Cadmium, Chronic {1.101672-[In hardness](0.041838)} • e^{0.7998[In hardness]-4.4451} Chromium III, Acute 0.316 • e^{0.8190[In hardness]+3.7256} Chromium III, Chronic 0.860 • e^{0.8190[In hardness]+0.6848} Copper, Acute 0.960 • e^{0.9422[In hardness]-1.700} Copper, Chronic 0.960 • e^{0.8545[In hardness]-1.702} Lead, Acute {1.46203-[In hardness](0.145712)} • e^{1.273[In hardness]-1.460} Lead, Chronic {1.46203-[In hardness](0.145712)} • e^{1.273[In hardness]-4.705} Nickel, Acute 0.998 • e^{0.8460[In hardness]+2.255} Nickel, Chronic 0.997 • e^{0.8460[In hardness]+0.0584} Silver, Acute 0.85 • e^{1.72[In hardness]-6.59} Silver, Chronic Not applicable Zinc, Acute 0.978 • e^{0.8473[In hardness]+0.884} Zinc, Chronic 0.986 • e^{0.8473[In hardness]+0.884} Complete information on all the proposed Surface Water Quality Standards can be viewed at: http://h2o.enr.state.nc.us/csu/trirev SW.html. US EPA Translators using Default Partition Coefficients (DPC) Translator equation using Default Partition Coefficients = 1 v. 6/2/2010 [1 + (Kpo * TSS (1+a) * 10-6)] Kpo and a are constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A default value of 10 mg/L Total Suspended Solids (TSS) will be used. Table A contains the Default Partition Coefficients for the equation. Table B contains the calculated translators using the default partition coefficients for streams. TABLE A. Default Partition Coefficients STREAMS Metal (1) Kpo a Cu 1.04E+06 -0.7436 Zn 1.25E+06 -0.7038 Pb 2.80E+06 -0.8 Cr (III) (2) 3.36E+06 -0.09304 Cd 4.00E+06 -1.1307 Ni 4.90E+05 -0.5719 (1) Delos, C.G., et al. Technical Guidance for Perfo ming Waste Load Allocations. Book II: Streams and Rivers. Chapter 3: Toxic Substances, For the U.S. EPA. (EPA-440/4-84-022) (2) Linear partition coefficients shall not apply to the Chromium VI numerical criterion. The approved analytical method for Chromium VI measures only the dissolved form. Therefore, TABLE B. US EPA Translators PARAMETER US EPA Translators Using stream Default Partition Coefficients TSS = 10 mg/L Cadmium 0.252 Chromium III 0.202 Chromium VI 1 Chromium, Total N/A Copper 0.348 Lead 0.184 Nickel 0.432 Silver 1 Zinc 0.288 Example for Cadmium (streams) Given: TSS = 10 mg/L Kpo = 4.00E + 06 a =-1.1307 Translator = 1 [1 + (Kpo * TSS (1*00 * 10-6)] [1 + (4.00x106 * 101-1.13°0 * 10-6)] [1+2.960465] = 0.252