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WQ0014248_Residual Annual Report 2018_20190304
Town of Cheraw Public Utility Department February 25, 2019 Mr. Sonia Gregory NCDENR/DWQ/Water Quality Section Information Processing Unit Raleigh, NC 27699-1617 Dear Ms. Gregory: RFr,,FI\IFD MAR 0 Y 2019 DWR SECTION INIFOWATION PROCESSING UNIT Enclosed is the annual Biosolids marketing and distribution report. Please contact me if you have any questions or comments. Sincerely, Sherry Turner Town of Cheraw N�DlN��GQ�pWR RE�E MAR _ � 2019 Non_piscn Unit perm►rtin9 Post Office Box 219 1 Cheraw, South Carolina 29520 1 843-537-8440 1 F: 843-537-8442 1 www.cheraw.com ANNUAL LAND APPLICATION CERTIFICATION FORM Permit#: W00014248 County: Chesterfield Year: 2018, Facility Name (as shown on permit): Land Application Operator: Town of Cheraw Phone: (843)�5�7-8440 Land application of residual solids as allowed by the permit occurred during the past calender year? ® Yes ❑ No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A: Total number of application fields in permit: Total number of fields land application occurred during the year: Total amount of dry tons applied during the year for all application sites: 292.4 Total number of acres land application occurred during the year: 1 402 Part B: Facility was compliant during calendar year 2018 with all conditions of the land application permit (including but not limited to items 1-12 below) issued by the Division of Water Quality. ® Yes ❑ No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits -in Table 1 of 40 CFR Part 503.13 or the Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed in accordance with the crop management plan. 11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 12. All buffer requirements as specified on the permit were maintained during each application of residuals. "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Sherry Turner / Operator of Record Z 4t, n� Permittee Name and Title (type or print) Signatur of Permittee Date Signature of Preparer* (if different from Permittee) * Preparer is defined in 40 CFR Part 503.9 (r) Date Signiture of Land Applier Date (if different from Permittee and Preparer) Author Daryl D. Merritt DENR FORM ACF (7/2002) ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM PERMIT #: W00014248 FACILITY NAME: Town of Cheraw PHONE: (843) 537-8440 COUNTY: Chesterfield OPERATOR: FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C) ® Distribution and Marketing (complete Parts A, B, and C) Was the facility in operation during the past calendar year? ® Yes ❑No No If No skin parts A. B. C and certifv form below Part A*: Part B*: Month Sources s include NPDES # if () ( applicable) Volume (dry tons) Recipient Information Admendment/ Bulking Agent Residual In Product Out Name(s) Volume (dry tons) Intended use(s) January SCO020249 24.35 30.44 54.79 Allan Baucom 283.76 crops February 8.90 7.03 15.93 Allan Baucom 280.59 crops March April May June July August September October November December Totals: Annual (dry tons): 33.25 37.47 70.72 564.35 Admendment(s) used: Lime Bulking Agent(s) used: * If more space than given is required, please attach additional information sheet(s). ❑ Check box if additional sheet(s) are attached Part C: Facility was compliant during calendar year 2018 with all conditions of the permit (including but not limited to items 1-3 below) issued by the Division of Water Quality. ® Yes ❑ No If No, please provide a written description why the facility was not compliant. 1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached 2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 3. No contravention of Ground Water Quality Standards occurred at a monitoring well. "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false informaiton, including the possibility of fines and imprisonment for knowing violations. Signature & Permittee Date Signature of Preparer** Date (if different from Permittee) **Preparer is defined in 40 CFR Part 503.9(r) Author Daryl D. Merritt DENR FORM DMSDF (7/2002) TOWN OF CHERAW WASTEWATER TREATMENT FACILITY BIOSOLIDS REPORT 2018 PRESS MONTH HOURS DRY CAKE SOLIDS T. TONS LIME USED % LIME TOTAL DRY PROD. LIME $/ TON PROD. POLY $/ TON CAKE LBS. POLY/ TON CAKE LBS. POLY USED JAN 117.00 30.44 24.35 44.44 54.79 3.61 110.00 FEB 43.00 7.03 8.90 55.87 15.93 3.91 27.50 MAR 62.00 24.26 1.13 27.50 APR 187.00 68.87 2.60 178.76 MAY 217.00 121.05 1.48 178.75 JUN 284.00 107.15 2.31 247.50 J U L 306.00 113.96 0.87 99.62 AUG 349.92 107.56 2.17 233.75 SEP 168.10 48.39 1.99 96.25 OCT 271.00 89.91 1.07 96.25 NOV 150.00 52.45 3.15 165.00 DEC 114.00 40.97 3.02 123.75 TOT 2,269.02 812.04 33.25 70.72 1,584.63 AVG 189.09 67.67 16.63 50.16 35.36 ERR ERR 1.95 132.05 MIN 43.00 7.03 8.90 44.44 15.93 ERR ERR 0.87 27.50 MAX 349.92 121.05 24.35 55.87 54.79 ERR ERR 3.91 247.50 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: W00014248 Laboratory: Facility Name: Town of Cheraw NPDES # or WQ#: SCO020249 WWTP Name: Town of Cheraw WWTP Recidnal Annlvd-v nntn 1) Davis & Brown Labs 2) Clemson University 3) 4) 5) Sample or Composite Date 1 /17/18 165.50 1 /17/1 E 3/21 /18 3/21 /18 5/16/18 5/16/18 7/18/18 7/18/18 9/19/18 9/19/18 11 /20/18 11 /20/1 Percent Solids 61.46 65.80 65.74 63.80 62.84 64.70 62.24 71.40 70.20 70.60 68.77 Arsenic 1.44 1.66 0.989 2.07 0.995 0.967 Cadmium 0.988 0.988 0.989 0.995 0.995 0.967 Chromium 35.8 34.1 28.3 37.4 37.8 56.7 ,b Copper 22.7 25.5 23.5 27.2 28.5 30.0 Lead 0.988 0.988 0.989 0.995 1.47 0.967 A Mercury 0.032 0.030 0.029 0.029 0.023 0,026 F Molybdenum 3.95 3.95 3.96 3.98 3.98 3.87 W Nickel 9.31 10.6 11.0 12.9 13.5 14.5 Selenium 0.988 0.988 0.989 0.995 0.995 0.967 Zinc 181 257 318 295 351 309 TKN 13521 14352 14394 10900 14694 11938 Ammonia -Nitro e 325.4 456.3 954.8 0 284.9 290.8 Nitrate and Nitrite 4.00 7.00 61.00 143.0 87.99 49.99 Total Phosphorus 5727 5727 7789 6869 9160 8928 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." � .7-z1-t Signature RPreparer Date Author Daryl D. Merritt DENR FORM RSSF (7/2002) ANNUAL METALS FIELD LOADING SUMMARY FORM Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Town of Cheraw Total Dry Tons Applied (Annual): 69.83 Permit #: W00014248 Cation Exchange Capacity (non 503 only): Operator: Allan an Baucom Owner: Acres Used: 182 Acres Permitted: Site #: Dockery Field #: Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): re"Wff IN M. Annual Heavy Metal Field Loadings (Calculated in lbs/acre): ® 1 • ` ____________ "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, includin a possibility fines and imprisonment for knowing violations" Signature of Land Appher Date Author Daryl D. Merritt DENR FORM MFLSF (7/2002) ANNUAL, LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD. Facility Name: Owner: Town of Cheraw Site #: Dockery Field #: PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Permit #: WQ0014248 Operator: Allan Baucom Acres Utilized: 182 Annual Dry Tons Applied:' 69.8 Cation Exchange Capacity (non 503): Acres Permitted: A Specify Totals Per Acre Solids As Deci- Dry Tons Per Acre Residual Sources (Summarize) site Cond. Di y' Wet, moirt Inches Preci P' Past 24 Hrs. Appli- cation Meth- od** Voli- tila- zation Rate* Miner- ala- zation Rate TKN Ammo nia- Ni- trogen Ni- trate- Ni- trogen PAN 1 PAN 2 Must Select Crop 1 or Crop P P 2 Cu.Yd. Report Totals in Gal. Crop I Crop 2 Jan N/A N/A .6348 0.38 S 0.5 13521 325.4 4.00 TOTALS: J As Cd Cr Cu Pb HR Mo Ni Se Zn P I PAN 1 PAN 2 Lime Applied Annuallbs/acre .0017 .0011 .1093 .0693 .0011 .00004 .0046 .0284 .0011 .2100 7.082 1 Date lbs/ac Current Cumulative lbs/acre .0017 .0011 .1093 .0693 .0011 .00004 .0046 .0284 .0011 .2100 Prior Years Cumulative lbs/acre Permitted C. P. L. R. * * * Permit PAN Limit Ist/2nd Cro "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false Information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S -Surface, IN -Injection, INC -Incorporation Signature of Land Applier Date **Volitilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 ***C.P.L.R.: Cumulative Pollutant Loading Rate Author Daryl D. Merritt DENR FORM FSF (7/2002) 1� 1 Grower: A L Baucom Farm: 222 DOCKERY-FIELDS A Field: 222 DOCKERY-FIELDS A Year: 2018 Op. Instance : Instance - 1 IN 222 DOCKERY-FIELDS +114 Field - Name A(208.67 ac) ZX Als 6o 35.4 4.898747, -79.812270) Flo W,q f) -4 1 1`4 � 2/1412019 10:05:38 AM Ag Leader Technology SMS Advanced Page 1 of 1 ANNUAL METALS FIELD LOADING SUMMARY FORM Attach this form to the corresponding Field Loading Summary Form to be submitted in Anngal Report Facility Name: Permit #: Operator: Acres Used: Town of Cheraw WQ0014248 Allan Bauco[n Total Dry Tons Applied (Annual): Cation Exchange Capacity (non 503 only): 202 Acres Permitted: Owner: Site #: Prince Field #: 92.1 Residual Analysis Data (Heavy Metals and Total Phosphorus use me&e. % Solids use Raw Percent #)r mm Annual Heavy Metal Field Loadings (Calculated in lbs/acre): "t certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility fines and imprisonment for knowing violations" a Uf Signature of Land Applier D to Author Daryl D. Merritt DENR FORM MFLSF (7/2002) Annual Heavy Metal Field Loadings (Calculated in lbs/acre): "t certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility fines and imprisonment for knowing violations" a Uf Signature of Land Applier D to Author Daryl D. Merritt DENR FORM MFLSF (7/2002) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD. Facility Name: Owner: Town of Cheraw Site #: Prince Field #: PLACE A "NIA" IN A BLANK OR BOX WHEN NOT APPLICABLE. Permit #:WQ0014248 Annual Dry Tons Applied: 92.1 Operator: Allan Baucom Cation Exchange Capacity (non 503): Acres Utilized: 202 Acres Permitted: A Specify ecf Tot s Per Acre Solids As Deci- Dry Tons Per Acre Residual Sources (Summarize) site Cond. Dry, Wet, Inches Preci Past 24 Hrs. Appli- cation Meth- od** Voli- tila- zation Rate* Miner- ala- nation Rate TIQV Ammo nia- Ni- trogen Ni- trate- Ni- trogen PAN 1 PAN 2 Must Select Cro or P 1 Cro P 2 CuNd. Report Totals in Gal.Moist Crop I Crop 2 Jan N/A N/A .6348 .46 S 0.5 13521 325.4 4.00 TOTALS: As Cd Cr Cu Pb Ni Se Zn P PAN 1 PAN 2 Lime A lied Annuallbs/acre .0020 .0014 .0503 .0319 .0014 .0131 .0014 .2542 8.573 Date lbs/ac Current Cumulative lbs/acre MHMO .0020 .0014 .0503 .0319 .0014 .0131 .0014 .2542 Prior Years Cumulative lbs/acre Permitted C. P. L. R. * * * Permit PAN Limit 1 st/2nd Crop "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for ubmitting false information, including the possibility of fines and imprisonment for knowing violations." 2 a e, *Application Method: S - Surface, IN'- Injection, INC - Incorporation Signature of Land Applier Date **Volitilization Rate: Surface - 0.5, Injection/Incorporation -1.0 ***C.P.L.R.: Cumulative Pollutant Loading Rate Author Daryl D. Merritt DENR FORM FSF (7/2002) Boundary 2018 - 224 PRINCE Grower: A L Baucom Farm: 224 PRINCE Field: 224 PRINCE Year: 2018 Operation : Boundary Crop / Product: NO Product Instance : Instance - 1 Field - Name 224 PRINCE(271.16 ac) xodo ikIA 0,1 9.4 /0V 1&1,4 �, qs- 0 Lo,t, V f- ( (�,i (( IN C-, 2/14/2019 10:05:10 AM Ag Leader Technology SMS Advanced Page 1 of 1 ANNUAL METALS FIELD LOADING SUMMARY FORM Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Town of Cheraw Total Dry Tons Applied (Annual): 0014248 Cation Exchange Capacity (non 503 only): Allan Bauccm Owner: 130 Acres Permitted: Site #: Red Hill Field #: 48.9 Residual Analysis Data (Heavy Metals and Total Phosphorus use mgtkg, % Solids use Raw Percent #): OF M---- Total Phos- phorusEEEEEEEEEEEE Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total Phos- phorus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for siobin-l"ino fake infeirmAtinn, includinethepossibilityo fines and imprisonm 2 c Signature of Land Applier Date -,- A (1 EA—R, FW:K10 1:r10KA AAM QC /7Mnn0\ 3 i ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD. Facility Name: Owner: Town of Cheraw Site #: Red Hill Field #: PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Permit #: WQ0014248 Annual Dry Tons Applied: 48.9 Operator: Allan Baucom Cation Exchange Capacity (non 503): Acres Utilized: 130 Acres Permitted: A Specify Totals Per Acre Solids As Des Dry Tons Per Acre Residual Sources (Summarize) site Cond. Dry, Moist Wet, Inches Precip. Past 24 Hrs. Appli- cation Meth- od** Voli- tila- zation Rate* Miner- ala- zation Rate TKN Ammo nia- Ni- trogen Ni- trate- Ni- trogen PAN I PAN 2 Must Select Crop 1 or Crop 2 'Gal. CuNd. Report Totals in Gal. Crop I Crop 2 Jan N/A N A .6348 0.38 S 0.5 13521 325.4 4.00 TOTALS: As Cd Cr Cu Pb Hg Mo Ni Se Zn P I PAN 1 PAN 2 Lime A lied Annual lbs/acre .0017 .0011 .1093 .0693 .0011 .00004 .0046 .0284 .0011 .2100 7.082 Date lbs/ac Current Cumulative lbs/acre .0041 .0011 .1387 .1041 .0011 .00004 .0046 .0427 .0011 .3746 . 0024 0 .0294 .0348 1 0 0 0 1.0143 1 0 .1646 Prior Years Cumulative lbs/acre Permitted C. P. L. R. * * * Permit PAN Limit 1 st/2nd Crop dt7 _ _�11 _ _ 1 _ •. ftruty, under penacty of taw, tnat ims aocument was prepared under my direction or supervision In accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of tines and imprisonment for knowing violations." *Application Method: S -Surface, IN •Injection, INC -Incorporation Signature of Land Applier Date **Volitilization Rate: Surface - 0.5, Injection/Incorporation -1.0 ***C.P.L.R.: Cumulative Pollutant Loading Rate Author Daryl D. Merritt DENR FORM FSF (7/2002) C�) Boundary 2018 - 221 RED HILL Grower: A L Baucom Farm: 221 RED HILL Field: 221 RED HILL Year:2018 Operation : Boundary Crop / Product: NO Product Op. Instance :Instance - 1 3X Field -Name ',221 RED HILL(130.63 ac) Woo (b,19A �t/V'o/�jf/� � r f 040�6� a n (34.907577,-79.836362) (7'7 L 201 S� cro - soy �q;j 5 r 2/14/2019 10:06:00 AM Ag Leader Technology SMS Advanced Page 1 of 1 ANNUAL METALS FIELD LOADING SUMMARY FORM Attach this form to the corresponding Field Loading Summary Form to be submitted in Annpal Report Facility Name: Town of Cheraw Total Dry Tons Applied (Annual): 9.5 Permit #: W00014248 Cation Exchange Capacity (non 503 only): Operator: Acres Used: Allan Baucom Owner: 30 Acres Permitted: Site #: James HancocWield #: Residual Analysis Data (Heavy Metals and Total Phosphorus use mglkg, % Solids use Raw Percent #): LM cm Annual Heavy Metal Field Loadin (Calculated in lbstacre): Annual Heavy Metal Field Loadin (Calculated in lbstacre): Total Phos- "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including a possibility o tines and imprisonm knowing violations" L a Signature of Land Applier Date Author Daryl D. Merritt DENR FORM MFLSF (7/2002) ANNUAL. LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD. PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Town of Cheraw Permit #: WQ0014248 Annual Dry Tons Applied:' 9.5 Owner: Operator: Allan Baucom Cation Exchange Capacit (non 503)• Site #: James Hancock Field #: Y Acres Utilized: 30 Acres Permitted: A Totals per Acre o Solids As Deci- DD' Tons Per Acre Residual Sources (Summarize i eMust Cond. Dt y Wet,Hrs. Inches Precip. Past 24 Appli- cation Meth- od** Voli- tila- zation Rate* Miner- ala- zation Rate TI{IVNi- Ammo nia- trogen Ni- trate- Ni- trogen PAN 1 PAN 2 Select Crop 1 or Crop 2 rReport Cro 1 P Cro 2 P Jan NIA N/A .634E 0.32 S 0.5 13521 325.4 4.00 TOTALS: As Cd Cr Cu I Pb Hg Mo Ni Se Zn P PAN 1 PAN 2 Lime A lied Annuallbs/acre .0014 .0010 .0350 .0222 0.001 .0000 .0039 .0091 .0010 .1769 5.964 Date I lbs/ac Current Cumulative Ibs/acre .0161 .0010 .0682 .0474 0.0011 .0000 .0039 .0201 .0010 .3734 .0021 0 .0332 .0252 0 0 0 .0110 1 0 1.1965 Prior Years Cumulative Ibs/acre Permitted C. P. L. R. * * * Permit PAN Limit 1 st/2nd Crop it I certify, under penalty of law, that this document was prepared under my direction or supervision In accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation Signature of Land Applier Date **Volitilization Rate: Surface - 0.5, Injection/Incorporation -1.0 ***C.P.L.R.: Cumulative Pollutant Loading Rate Author Daryl D. Merritt DENR FORM FSF (7/2002) Lw'oundalry 2018 - 220 JAMES HANCOCK-Fl (34M5035, -79.803620) Grower: A L Baucorn -- Farm: 220 JAMES HANCOCK-F1 Field: 220 JAMES HANCOCK-F1 Year: 2018 Operation : Boundary Crop / Product: NO Product Instance : Instance - 1 Field - Name 220 JAMES HANCOCK-FI(30.04 ac) A 1,4 on of 1V' cry - soli alis wb(� Y: k t P', C, 2/14/2019 10:06:26 AM Ag Leader Technology SMs Advanced Page 1 of I ANNUAL METALS FIELD LOADING SUMMARY FORM Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Cheraw , Town of Total Dry Tons Applied (Annual): 20.3 Permit #: WQ0014248 Cation Exchange Capacity (non 503 only): Operator: Allan Baucom Owner: Acres Used: 64 Acres Permitted: Site #: Chad Little Field #: Residual Analysis Data (Heavy Metals and Total Phosphorus use mgft, % Solids use Raw Percent #): posite Non Date Annual Heavy Metal Field Loadings (Calculated in Ibstacre): son Total Phos- "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, inZ77� ty o fines and imprisonnum for knowing violations" L z rt Signature of Land Applier Date Author Daryl D. Merritt DENR FORM MFLSF (7/2002) ANNUAL, LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD. PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Town of Cheraw Permit #: WQ0014248 Annual Dry Tons Applied: 20.3 Owners Operator: Allan Baucom Cation Exchange Capacity (non 503): Site #: Chad Little Field #: I Acres Utilized: 64 Acres Permittod- A Specily Totals per Acre W Solids As Deci- Mal Dry Tons Per Acre Residual Sources (Summarize) Site Cond. Dt y Wet' Moist Inches Precip. Past 24 Hrs. Appli- cation Meth- od** Voli- tila- zation Rate* Miner- ala- zation Rate TKIN Ammo nia- Ni- trogen Ni- trate- Ni- trogen PAN 1 PAN 2 Must Select Crop 1 or Crop 2 rRepmt Crop1 Crop 2 P Jan N/A N/A .6348 0.32 S 0.5 13521 325.4 4.00 TOTALS: As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN 1 PAN 2 Lime A lied Annuallbs/aere Current Cumulative Ibs/acre 0014 0010 0350 0.922 0010 .0000 .0039 .0091 .0010 .1769 5.964 .0014 .0010 .0350 .0222 .0010 .0000 .0039 .0091 .0010 .1769 .� _ .■_ Date lbs/ac Prior Years Cumulative lbs/acre Permitted C. P. L. R. * * * Permit PAN Limit 1 st/2nd Crop UT ..a34N.1 _-1_ _fa_ _r a__ -...V, »..— x,..■.o.■ y .,. ,an, W.,at, aa,10 aava.umcin. woo purpareu unuer my uirecuon or supervision in accordance with a system ! designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of tines and imprisonment for knowing violations." *Application Method: S - Surface IN - Injection, INC - Incorporation < —r--- � PP � j poration Signature of Land Applier Date **Volitilization Rate: Surface - 0.5, Injection/Incorporation -1.0 ***C.P.L.R.: Cumulative Pollutant Loading Rate Author Daryl D. Merritt DENR FORM FSF (7/2002) L Boundary 2018 - 033-Chad-Little (35.088426,—80.388380) Grower: A L Baucom Farm : 033 Chad -Little Field: 033-Chad-Little Year:2018 Operation : Boundary Crop / Product: NO Product Instance : Instance - 1 Field - Name ,033-Chad-Little(104.99 ac) /0061�/A oil RYA (32+) ,1QI 1� Coy — G o/',l 2/14/2019 10:08:34 AM Ag Leader Technology SMS Advanced Rage 1 of 1 ANNUAL METALS FIELD LOADING SUMMARY FORM Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Town of Cheraw Total Dry Tons Applied (Annual): 43.2 WQ0014248 Cation Exchange Capacity (non 503 only): Operator: Allan Baucom Acres Used: 110 Acres Permitted: Owner: Site #: Gainey Field #: Residual Analysis Data (Heavy Metals and Total Phosphorus use ml;/k9, % Solids use Raw Percent #)• Total Phos- Annual Heavy Metal Field Loadin (Calculated in lbs/acre): NFA certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, inchg the possibility o fines and imprisonmentfor knowing violations" Z ZK Signature of Land Applier Date Author Daryl D. Merritt DENA FORM MFLSF (7/2002) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD. PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Townof Cheraw Permit #: WQ0014248 Owner: Operator: Allan Bauccrn Site #: Gainey Field #: Acres Utilized: 110 Annual Dry Tons Applied: Cation Exchange Capacity (non 503): Acres Permitted: A Specify Tot Is � per Acre o Solids As Deci- Dry Tons Per - Residual Sources (Summarize) Site Cond. Dry, y, Wet, -MoistAcre Inches Precip. Past 24 Hrs. Appli- cation Meth- ad** Voli- tila- zation Rate* Miner- ala- zation Rate TKN Ammo nia- Ni- trogen Ni- trate- Ni- trogen PAN 1 PAN 2 Must Select Crop 1 or Crop 2 'Gal. Cu.Yd. Report Totals in Gal. Crop I Crop 2 Jan N/A N/A .0348 0.39 S 0.5 13521 325.4 4.00 TOTALS: As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN 1 PAN 2 Lime A lied Annual lbs/acre .0017 .0012 .0426 .0270 .0012 .00004 .0047 .0111 .0012 .2155 7.268 Date Ibs/ac Current Cumulative lbs/acre . 0017 .0012 .0426 .0270 .0012 .00004 .0047 .0111 .0012 .21931 Prior Years Cumulative lbs/acre Permitted C. P. L. R.*** Permit PAN Limit 1 stl2nd Crop I cerdiy, under penalty or law, that mts document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation Signature of Land Applier bate **Volitilization Rate: Surface - 0.5, Injection/Incorporation -1.0 ***C.P.L.R.: Cumulative Pollutant Loading Rate Author Daryl D. Merritt DENR FORM FSF (7/2002) Boundary 2018 - 233 Gainey all Grower: A L Bauc-mm-- Farm :233 Gainey Field: 233 Gainey all Year. 2018 Operation : Boundary Crop/ Product: No Product 2/14/2019 10:03:45 AM Ag Leader Technology SMS Advanced Page 1 of 1 ANNUAL METALS FIELD LOADING SUMMARY FORM Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Town of Cheraw Total Dry Tons Applied (Annual): 71.1 Permit #: WiQ0014248 Cation Exchange Capacity (non 503 only): Operator: Allan Baucan Owner: Acres Used: 186 Acres Permitted: Site #: Gibson Field #: Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent*): WE RMT111 I Total Phos- Lphorus!MWEEMEENEENE Annual Heavy Metal Field Loadings (Calculated in lbs/acre): "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including e possibility o fines and imprisonmenMr knowing violations" 4 9- - I A-4— - -,;: � �1— �—e 0 � 0 �- � � Z Signature of Land Applier Date Author Daryl D. Merritt DENR FORM MFLSF (7/2002) ANNUAL. LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD. PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Town of Cheraw Permit #: WQ0014248 Annual Dry Tons Applied: 71.1 Owner: Operator: Allan Baucom Cation Exchan a Ca it ( Cal Site #: Gibson Field #: g pac y non }, Acres Utilized: 186 Acres Permitted: La Specify Totals Per Acre Solids As Deci- Dry Tons Per Acre Residual Sources (Summarize) site Cond. Dry, Wet, Inches Precip. Past 24 Hrs. Appli- cation M eth- od** Voli- tila- nation Rate* Miner- ala- zation Rate TICIV Ammo nia- Ni- trogen Ni- trate- Ni- Ni- trogen PAN I PAN 2 Must Select Crop 1 or Crop 2 Gal. CuNd. Report Totals in Gal. Crop I Crop 2 Feb N/A N/A .6348 0.38 S 0.5 13521 325.4 4.00 TOTALS: As Cd Cr Cu Pb HR Mo Ni Se Zn P PAN 1 PAN 2 Lime A lied Annual lbs/acre Current Cumulative lbs/acre . 0017 .0011 .0415 .0263 .0011 .0000 .0046 .0108 .0011 .2100 7.082 .0017 .0011 .0415 .0263 .0011 .0000 .0046 .0108 .0011 .2100 Date lbs/ac Prior Years Cumulative lbs/acre Permitted C. P. L. R. * * * Permit PAN Limit Is ndCro A SPA U11J, UAIUV. FCna11y v1 taw, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are signiflcant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Z Z`F 1 *Application Method: S - Surface, IN - Injection, INC - Incorporation Signature of Land Applier Date **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0 ***C.P.L.R.: Cumulative Pollutant Loading Rate Author Daryl D. Merritt DENR FORM FSF (7/2002) Boundary 2018 - 236 Gibson all (34.679157,-79.353373) Grower: A L Baucom Farm :236 Gibson Field: 236 Gibson all Year:2018 Operation : Boundary Crop / Product: NO Product Op. Instance : Instance -1 Field - Name 236 Gibson all(226.72 ac) Apfl,P� 9AD/45/4 Oki 3 KA zie k-td 100011.4 o v, m,4 zG C g crap W k4A soj,60ms EFL, 5�:fLe / 0 C.- 2/14/2019 10:03:20 AM Ag Leader Technology sM5 Advanced Page 1 of 1 ANNUAL METALS FIELD LOADING SUMMARY FORM Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Town of Cheraw Total Dry Tons Applied (Annual): 59 Permit #: WQ0014248 Cation Exchange Capacity (non 503 only): Operator: Allan Baucom Owner: Acres Used: 148 Acres Permitted: Site #: Baines Field #: Residual Analvsis Data fHeavv Metals and Total Phosnhnnm imp ma/ka cL c.,uae .,ve 1D.,... t e,.,.e... �►�. Annual Heavv Metal Field Loadings (Calculated in lhc/arra)- _________________ NOME �EMEEEEEENEEEEI I %Mrwy, under penalty o[ law, inat ttus document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including a possibility o es and imprison or knowing violations" ��" Z Signature of Land Applier Da e Author Daryl D. Merritt DENR FORM MFLSF (7/2002) ANNUAI. LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD. PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility.Name: Town of Cheraw Permit #: WQ0014248 Annual Dry Tons Applied: 59 Owner: Operator: Allan Baucam Cation Exchange Capacity (non 503): Site #: Baines Field #: Acres Utilized: 14R Acrac PPrmittPrl- A s c;f Tot is �. per Acre Solids As Deci- Dry Tons Per Acre Residual Sources (Summarize) Site o Cond. y Wet' st Inches Precip. Past 24 Hrs. Appli- cation Meth- od** Voli- tila- zation Rate* Miner- ala- nation Rate TICK Ammo nia- Ni- trogen Ni- trate- Ni- trogen PAN 1 PAN 2 Must Select Crop 1 or Crop 2 Gal • CuNd. Report Totals in Gal. Crop 1 P Crop 2 P Feb N/A N/A .6348 0.40 S 0.5 13521 325.4 4.00 TOTALS: Annual lbs/acre Current Cumulative lbs/acre As Cd Cr Cu Pb —HR Mo Ni Se Zn P PAN 1 PAN 2 0013 0012 0437 .0277 .0012 00004 .0048 .0114 .0012 .2211 7.455 0018 .0012 0437 .0277 .0012 00004 .0048 -0114 .0012 .2211 Lime A Date lied lbs/ac Prior Years Cumulative lbs/acre Permitted C. P. L. R. * * * Permit PAN Limit 1 st/2nd Crop 46T..-.6=0L. -ra---. ---.r1 -- --.., — —a. %—--"asacu- vy a., piuparCu unuer my u,recuon or supervision In accornance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." z Z`f ( *Application Method: S - Surface, IN - Injection, INC - Incorporation Signature of Land Applier f Da a **Volitilization Rate: Surface - 0.5, Injection/Incorporation -1.0 ***C.P.L.R.: Cumulative Pollutant Loading Rate Author Daryl D. Merritt DENR FORM FSF (7/2002) L 2/14/2019 10:04:06 AM Boundary 2018 - 232 Baines all Grower: A L Baucom Farm :232 Baines Field: 232 Baines all Year: 2018 Operation : Boundary Crop / Product: NO Product Ag Leader Technology SMS Advanced Page 1 of 1 ANNUAL METALS FIELD LOADING SUMMARY FORM Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Total Dry Tons Applied (Annual): 150.5 W00014248 Cation Exchange Capacity (non 503 only): Operator: Allan Baucom Owner: Acres Used: 350 Acres Permitted: Site #: Dehy Field #: Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg% Solids use Raw Percent #1• Town of Cheraw 0 MR - Annual Heavy Metal Field Loading Calculated in lbstacre : Total Phos- "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including a possibility o fines and imprisonMsWor knowing violations" Zj z Signature of Land Applier Date Author Daryl D. Merritt DENR FORM MFLSF (7/2002) ANNUAL, LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD. PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Town of Cheraw Permit #: WQ0014248 Annual Dry Tons Applied:' 150.5 Owner: Operator: Allan Baucom Cation Exchange Capacity (non 543): Site #: Dehy Field #: Acres Utilized: 350 Acrec Pprrnittprl- A A S cif Tot4ls Per Acre Solids As Deci- Dry Tons Per Acre Residual Sources (Summarize) site Cond. Dry, Wet, Inches Precip. Past 24 Hrs. Appli- cation Meth- od** Voli- tila- nation Rate* Miner- ala- nation Rate TKN Ammo nia- Ni- trogen Ni- trate- Ni- trogen PAN 1 PAN 2 Must Select Crop 1 or Crop 2 'Gal. CuNd. Report Totals in Gal. Crop 1 Crop 2 Feb N/A N/A .6348 0.43 S__J 0.5 13521 325.4 4.00 TOTALS: Annuallbs/acre Current Cumulative Ibs/acre As Cd Cr Cu Pb RR Mo Ni Se I Zn P PAN 1 PAN 2 .0019 .0013 .0470 .0298 .0013 .0000 .0052 .0122 .0013 .2376 8.014 .0019 .0013 .0470 .0298 .0013 .0000 .0052 .0122 .0013 .2376 Lime Applied Date lbs/ac Prior Years Cumulative lbs/acre Permitted C. P. L. R.*** Permit PAN Limit 1 stl2nd Crop 49T ..LOLL. .--1_ .la_ •+.r, r ■■o...y v. 444n1 aa■oa s5210 uvI,UAIMin wab prupareu unuer my uirection or supervision In accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 4-j�'i -L� -"� �' Z vIld *Application Method: S - Surface, IN - Injection, INC - Incorporation Signature of Land A Tier ** g PP D to Volitilization Rate. Surface - 0.5, Injection/Incorporation -1.0 ***C.P.L.R.: Cumulative Pollutant Loading Rate Author Daryl D. Merritt DENR FORM FSF (7/2002) L Boundary 2018 - 227 Dehy All Grower: A L Baucom Farm : 227 Dehy Field: 227 Dehy All Year:2018 Operation : Boundary Crop / Product: NO Product Op. Instance : Instance - 1 Field - Name in 227 Dehy A11(389.52 ac) +ked ZOO orl I)-q,4 1,a) ca fib A ao 2:264 (34.717294,-79.380800) (2 3 7 t) 2.01CAIr - whtat -50/6q5 2/14/2019 10:04:24 AM Ag Leader Technology SMS Advanced Page 1 of 1 Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Receipt Date: 11-Jan-18 Client #: 168 Report Date: 01-Feb-18 Sample Date: 11-Jan-18 SDG #: SDG-123313 Approved By: Van Ward Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst LSID-272213 INF 1-10-18-001 Biochemical Oxygen Demand 364 2 mg/L SM 5210B 1/11/2018 11:08 AE LSID-272214 EFF 1-10-18-002 Chemical Oxygen Demand 235 20 mg/L EPA 410.4 1/17/2018 13:43 JW Biochemical Oxygen Demand >67.0 2 mg/L SM 5210B SDF 1/11/2018 11:08 AE LSID-272215 BIOSOLIDS 1-11-18-500 Acid Digestion (Solids) YES EPA 200.2 S11A TCLP, Pesticides BRL mg/L EPA 8081A S I lA 1/19/2018 11:28 SH TCLP, Herbicides BRL mg/L EPA 8151A SI lA 1/19/2018 19:57 UH Magnesium, Total 1330 45.6 mg/kg SW846 6010C S I IA/D 1/22/2018 18:53 10 Page 1 ACCESS ALWICA ,., INC. ANALYTICAL REPORT Cy 11121►111 Davis & Brown P.O. Box 15038 Quinby SC 29506 ATTENTION Scott Fields PROJECT ID 272215 LABORATORY REPORT NUMBER 1801977 DATE January 26, 2018 Primary Data Review By Secondary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: Ashley Amick Project Manager, Access Analytical aamick@axs-inc.com - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PChI Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 5 Ifr1iri1-4 DAVIS & BROWN 124 W. MclverRoad PH: 843-665-6746 PAGE # -OF _ Florence, SC 24501 FAX: 843-656.2208 REGULATORY: NO CHAIN OF CUSTODY RECORDTURNAROUND TIME: _Pt _STANDARD RUSH P2 CLIENT: SAMPLE ANALYSIS REQUESTED ¢ K O of USE CODES TO INDICTATE IF SAMPLE WAS FILTERED OR PRESERVED: A = HNO, B=HCL O=H,SOa F=FILTRATION C=NAOH E=NA,SZOo G=ZINCACETATE Pfesefvative m o. EE <% e a of Lu Q Z O ,S7 _` 4. ADDRESS: PROGRgMM REA D = DRINKING WATER G=GROUNDWATER S=SOLID SL=SLUDGE W = WASTEWATER O=OTHER PLEASE PRINT LEGIBLY PHONE FAX: SAMPLE ID DATE TIME INITIAL NOTES LAB ID Fill in the Numleraf Containers for EACH Tesf SAMPLER SIGNATURE FLOWINFO ICE ICE NO PACK RECEIPT TEMP: �y o0 Rallnq d Dal%�: / Tim.: tjftl(s C%+zt7 Relinquished by Date: Time: Ralinquished oy: Date: Time:. . Received by: j 0-; j Time: I l /I�� R ceivetl by Date: Time: Received by: Date: Time: Comments: I55UED: NOVEMBER 2012 i Page 2 cf 5 Analytical Environmental Services, Inc Dater 26-Jan-18 Client: Davis & Brown Project: 272215 Case Narrative Lab ID: 1801977 At the request ofAngela Martin via email on 1/19/18, Total Magnesium analysis is needed. Analytical Environmental Services, Inc Date: 26-Jan-18 Client: Davis & Brown Client Sample ID: 272215 Project Name: 272215 Collection Date: 1/11/2018 8:00:00 AM Lab ID: 1801977-001 Matrix: Solid Reporting Dilution Analyses Result Qual Units BatchlD Date Analyzed Analyst Limit Factor PESTICIDES, TCLP SW1311/8081B (SW3510C) Cl-lordane BRL 0.0050 mg/L 254356 1 01/19/2018 11:28 SH Endrin BRL 0.0010 mg/L 254356 1 01/19/2018 11:28 SH gamma-BHC BRL 0.00050 mg/L 254356 1 01/19/2018 11:28 SH Heptachlor BRL 0.00050 mg/L 254356 1 01/19/2018 11:28 SH Heptachlor epoxide BRL 0.00050 mg/L 254356 1 01/19/2018 11:28 SH Methoxychlor BRL 0.0050 mg/L 254356 1 01/19/2018 11:28 SH Toxaphene BRL 0.050 mg/L 254356 1 01/19/2018 11:28 SH Sun: Decachlorobiphenyl 68.6 40.2-124 %REC 254356 1 01/19/2018 11:28 SH Surr: Tetrachloro-m-xylene 72.5 44.9-128 %REC 254356 1 01/19/2018 11:28 SH HERBICIDES, TCLP SW1311/8151A (SW3510C) 2,4,5-TP (Silvex) BRL 0.20 mg/L 254355 1 01/19/2018 19:57 UH 2,4-D BRL 0.20 mg/L 254355 1 01/19/2018 19:57 UH Sun: DCAA 79.5 50.4-133 %REC 254355 1 01/19/2018 19:57 UH METALS, TOTAL SW6010D (SW3050B) Magnesium 1330 45.6 mg/Kg-dry 254439 1 01/22/201818:53 IO PERCENT MOISTURE D2216 Percent Moisture 40.0 0 wt% R361479 1 01/23/2018 13:00 00 Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit , H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 4 of 5 IA.NALYnQU F. "-MON&1F.I, rA1. AES SseI2cMiNic. 1. Client Name: Access Analytical, Inc. 2. Carrier: fed Ex O UPS 7 USPS❑ Client Counerl I Othei 3. 4. S. 6. 7. 8. 9. 10. 11. 12. SAMPLE/COOLER RECEIPT CHECKLIST AES Work Order Number: 1801977 r......o•ets Shipping container/cooler received in good condition? • damaged leaking other Custody seals present on shipping container? • Custody seals intact on shipping container? • Temperature blanks present? • Cooler temperature(s) within limits of 0-6°C? [See item 13 and 14 for temperature recordings.] Q © © Cooling initiated for recently collected samples / ice present J ' Chain of Custody (CDC) present? • U 0- Chain of Custody signed, dated, and timed when relinquished and received? • Sampler name and/or signature on COC? • Were all samples received within holding time? • TAT marked on the COC? • If no TAT indicated, proceeded with standard TAT per Terms & Conditions. �. 13. Cooler 1 Temperature 2.4 14. Cooler 5 Temperature 15. Comments: 16. 17. 18. 19. 20. 21. 22. 23. 24. 25, 26. °C Cooler 2 Temperature °C Cooler 3 Temperature °C Cooler 4 Temperature °C °C Cooler 6 Temperature °C Cooler 7 Temperature °C Cooler 8 Temperature °C I certify that I have completed sections 1-15 (dated initials). MJ 1-12-18 ..__ .._ ure e•�a. [omments Were sample containers intact upon receipt? • Custody seals present on sample containers? Custody seals intact on sample containers? 0• Do sample container labels match the COC? Q O O incomplete info I_ other ❑ no label I=_ other Are analyses requested indicated on the COC? • Were all of the samples listed on the COC received? O © o samples received but not listed on CDC samples listed on CDC not received ❑ Was the sample collection date/time noted? • Did we receive sufficient sample volume for indicated analyses? • Were samples received in appropriate containers? Were VOA samples received without headspace (< 1/4" bubble)? Were trip blanks submitted? • listed on CDC not listed on CDC 27. Comments: This section only applies to samples where pH can be I certify that I have completed sections 16-27 (dated initials). checked at Sample Receipt. yes No N/A Details Comments 28. Have containers needing chemical preserv 29. Containers meet preserv 30. Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms. VOCs and Oil & GreaseiTPH. I certify that I have completed sections 28-30 (dated Initials). Checklist 6.9.17 Rev 2 ....4a.t CP 1-12-18 ation been checked? ation guidelines? Was pH adjusted at Sample Receipt? ' • • • CP 1-12-18 Page 5 of 5 CP 1-12-18 Page 5 of 5 DAVIS & DROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by a data qualifier or a flag next to the result. This table summarizes the possible Data Qualifiers that may be associated with this report. A BOD result showed toxic tendencies. B The BOD data is suspect due to a failed quality control check (GGA). C The BOD data is suspect due to a failed quality control check (Blanks). D Results are reported on a dry weight basis. H Sample was analyzed beyond the accepted holding time J Estimated value. Presence of the compound was confirmed but less than the reported detection limit. L Results based on colony counts outside the acceptable range. The ideal range for the fecal coliform test is 20 - 60 colonies. MS Sample matrix spike percent recovery was outside the accepted range. O Sampled, but analysis lost or not performed P Sample was not properly preserved upon receipt. G LCS or MS exceeds the control limits. S Sample was analyzed by another SC certified Lab. SC Seed Correction outside the accepted range of 0.60 - 1.4 mg/L. (BOD) Seed Correction outside the accepted range of 0.60 - 1.4 mg/L (CBOD) SD Results reported are derived from suspect data. SS BOD results derived from supersaturated D.O. values. Sample(s) were aerated per the supersaturation procedure in Standard Methods 5210B SDF Sample Dilutions did not meet the requirement of DO depletion of at least 2.0 mg/L, or die sample dilutions did not meet the requirement of DO residual of at least 1.0 mg/L. Davis & Brown is reporting these results as valid data. T Storage Condition: Temperature above 60 C due to power outage. V Analyte detected in the associated method blank. Note: the value in the blank shall not be subtracted from the sample result. Revision 04/17 WSF Dataqual.wpd DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S 1 South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratory Clemson University S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S11 South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016; 99006001 Note: S 11 A indicates AES Laboratory (98016); S 11 G indicates GCAL Laboratory (73006); S H P indicates Pace Analytical (96042001); S 11 TS indicates Test America Savannah (98001) S 11TP indicates Test America Pittsburg(89014) S12 AASHTO R18 Certified S 13 South Carolina Lab Certification Number: 96012 S 14 South Carolina Lab Certification Number: 89002 S 16 South Carolina Lab Certification Number: 84004 S 17 South Carolina Lab Certification Number: 96037001 S18 South Carolina Lab Certification Number: 95005 S 19 South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S26 North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 S29 South Carolina Lab Certification Number: 32566 S30 Galbraith Laboratories, Inc. Knoxville TN Roision 08117 Da[aqual(SubLabs)p2 .i% pd 1241M McIver Road PH:.749-693.9746 P`1GE # OF L_ BROWNDAVIS & Florence, SC 29501 FAX: 842-656-2208 L2L5 REGULATORY: ty SIC CHAIN OF CUSTODYRECORDTURUr . RUSH P CLIENT: / r S}aq PI..E ANALYSIS REQI I'- Tc0 t F-�1.;-z=acR,=nESERurn:, A=HNo, All.T Cvi7 PRESERVED fi-Sr7 A=14NOr �•reSetJ.:a�;e j 1 I i { I Gbci�'i. d`I' �L✓/J � G=HCL D=H,SOa F=m-'RATION C = NAOH ' = NA>S,0,i G=ZNCACETATE u i ADDRESS: PROGr,4.1 AREA: D=DRINKINGHATER Q i c I G=GROUNDPIATER S=SOLID GL=SLUDGE 'r1=WASTEINATER O=OTHER PLEASE PRINT LEGIBLY - Li a ! f{ < 0 PHONE: FAX: V O SA iPLE U] DATE T`.MEt- NOTES LAB lD x Fill is the Nufmber of CcntainA; s ic: EACH Test ; L- a_ -00 I(-(t.t i©jsp- & Ci) t i f I E I I!! 21-22-15 {tfl yioo�— i('t('(e Afo 15,Z C, C- j �}} I Lindcu.el M Gcoxy (orI I 1 i I I i �Xcc�z 2 S-TP Sriv. t I I j I t I i � SAMPLER SIGNATURE FL04>ItdFO {��^ ICE Y NO PACK Tsc:P: �.0 cC Re{ingalshtd � : Date: V Ti!;i�': (V 1'e'mc .rd h1 Ju:c: 7ir:�e: idalingcishcr. by: Dole; eceh r d f; - Date: ! me' P „e::y 0:3:9' �-.c iirtc.=.ived'ay., pate: Tina: " -� l�t� 0'Ia 1, cfttlr� Cammerix: U Priority Pollutants List PesticidesM� Parameter CAS No. Aldrin 309-00-2 alpha-BHC 319-84-6 beta-BHC 319-85-7 delta-BHC 319-86-8 gamma-BHC (Lindane) 58-89-9 Chlordane 12789-03-6 Dieldrin 60-57-1 4,4'-DDD 72-54-8 4,4'-DDE 72-55-9 4,4'-DDT 50-29-3 Endrin 72-20-8 Endosulfan sulfate 1031-07-8 Endrin aldehyde 7421-93-4 Endosulfan-i 959-98-8 Endosulfan-II 33213-65-9 Heptachlor 76-44-8 Heptachlor epoxide 1024-57-3 Methoxychlor 72-43-5 Toxaphene 8001-35-2 Aroclor 1016 12674-11-2 Aroclor 1221 11104-28-2 Aroclor 1232 11141-16-5 Aroclor 1242 53469-21-9 Aroclor 1248 12672-29-6 Aroclor 1254 11097-69-1 Aroclor 1260 11096-82-5 Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Receipt Date: 15-Feb-18 Client #: 168 Report Date: 21-Feb-18 Sample Date: 15-Feb-18 SDG #: SDG-123876 Approved By: Lab Sample ID: LSID-273421 Van Ward Sample ID: BIOSOLIDS Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst Priority 2 YES 2/21/2018 12:48 WSF Acid Digestion (Solids) YES EPA 200.2 2/16/2018 10:30 JR Aluminum, Total 4800 39.6 mg/kg SW846 6010C 2/20/2018 15:41 JR Calcium, Total 144900 989 mg/kg SW846 6010C 2/20/2018 15:41 JR Magnesium, Total 1060 39.6 mg/kg SW846 6010C 2/20/2018 15:41 JR Page 1 DAVIS &BROWN 124 W. McIver Road PH: 843-665-6746 AGE # _OF_ Floreves, SC 29501 FAX: 843-656-2208 y REGULATORY: YQ$ NO CHAIN OF CUSTODY RECORD TURNAROUND TIME: _-Pi _STANQARD RUSH CLIENT: SAMPLE ANA�YS'S REQUESTED _P2 USE CODES TO INDICTATE !F SAMPLE WAS ProservaWe p � � FILTERED OR PRESERVED: A - HNO, 8 = HCL D = H,50, F = FILTRATION � ADDRESS: m w S L C= NAOH E= NAa%Q, G- ZtNCACETATE c Z ,'a PROGRAM AREA: D=DRINKING WATER c z Cr Q G=GROUNDWATER S=SOLID SL•SLUDGE a Le u. O a Q v Q r!-�7� 3 6 Q 'r W= WASTEWATER O-OTHER PHONE: pqX. PLEASE PRINT LEGIBL uY a I— -- ,- Y" (� p a- SAMPLE 10 cArE TIME INITIAL NOTES LAB ID - Fill In 'he Number of Containers for EACH Test �nP E� a-}�-►$-ooa •is-lig CSa3 As C 2 ! 1 �✓ 2�--J1-i2 SAMPLER SIGNATURE FLOWINFO - ICE. ICE NO PACK RECEIPT, I TEIdP: ,• oC Re qutshed by: Date: Time, R uished b Data; Time Y Relinquished by: Date: ?Buie; •, Received rDate; by Dat - / T a Received by: Dot.. Time Comments: ` IASLJEa' NOvrutAF.. Nlt� CHERAW ALKALINE BIOSOLIDS SOIL AMENDMENT CHEMICAL CHARACTERISTICS AND LAND APPLICATION RATES SIOSOLIDS SAMPLE DATE: January 17, 2018 METALS Biosolids Metal Content, ppm Maximum Allowable Metal Content, ppm Maximum Maximum Allowable Application App. Rate, Rate, #/Acre/Yr. DT/Acre/Yr. Maximum Application Rate, WT/Acre/Yr. Arsenic, Total 1.44 41.00 1.80 384.13 625.00 Cadmium, Total 0.99 ' 39.00 1.70 528.76 860.32 Chromium, Total 35.80 1200.00 134.00 1150.23 1871.51 Copper, Total 22.70 1500.00 67.00 907.01 1475.77 Lead, Total 0.99 ' 300.00 13.00 4043.42 6578.95 Mercury, Total 0.03 ' 17.00 0.75 7202.34 11718.75 Molybdenum, Total 3.95 ' 18.00 0.80 62.24 101.27 Nickel, Total 9.31 420.00 18.70 617.24 1004.30 Selenium, Total 0.99 ' 36.00 4.50 1399.65 2277.33 Zinc, Total 181.00 1525.00 125.00 212.22 345.30 PCB BRL 1.60 ' Actual metal content less than amount indicated Biosolids Biosolids Nutrient Nutrient Content, Content, ppm % Crop/Soil Requirement, #/Acre " Maximum Application Rate, DT/Acre/Yr. Maximum Application Rate, WT/Acre/Yr. Ammonium Nitrogen 200.00 0.02 Organic Nitrogen 8110.00 0.81 Incorporated Available Nitrogen 5030.00 0.50 120.00 7.33 11.93 Surface Available Nitrogen 4970.00 0.50 120.00 7.42 12.07 Phosphorus as P205 3520.00 0.35 80.00 6.98 11.36 Potassium as K20 1185.00 0.12 50.00 12.97 21.10 Calcium, Total 165265.00 16.53 Calcium as CaO 231371.00 23.14 Calcium as CaCO3 (CCE) 490570.00 49.06 2000.00 1.25 2.04 Magnesium, Total 1290.00 0.13 Manganese 30.00 0.00 Sodium 215.00 0.02 Percent Moisture 38.54 " These are typical values and must be adjusted based upon specific site conditions DT is Dry Tons of Biosolids. WT is Wet Tons of Biosolids. CERTIFICATION: This biosolid product has been produced by the Town of Cheraw's Wastewater Treatment Plant by a treatment process that pasteurized plant residual solids using high temperature and lime (calcium oxide). The Town of Cheraw certifies that this biosolid complies with the Environmental Protection Agency regulations 40 CFR Part 503 for a "Class A" product and has a metal and nutrient content as presented above. DIRECTIONS FOR USE: This biosolid is intneded to be used as a soil amendment. The biosolid land application rate shall not exceed the most restrictive Maximum Application Rate as indicated in the table above. The application rate for nitrogen, phosphorus, potassium, and calcium is dependent upon the crop grown and site soil characteristics. The user should contact the Clemson Extension Service (843-623-2134) and/or the Soil Conservation Service (843-623-2187) for assistance in determining the proper application rate for each crop and site. In no case shall the land application rate exceed the agronomic rate for the crop grown. User should also refer to the Clemson Extension Service Circular #476 titled "Lime and Fertilizer Recommendations." THIS PRODUCT IS HIGHLY ALKALINE AND SHOULD BE HANDLED ACCORDINGLY. AVOID PROLONGED CONTACT WITH THE SKIN. AVOID CONTACT WITH THE EYES. THE TOWN OF CHERAW IS NOT RESPONSIBLE FOR IMPROPER USE OR HANDLING OF THIS BIOSOLID PRODUCT. Mr. Ricky D. Ingram, Public Utility Director P. 0. Box 219; Cheraw, SC 29520 Telephone: 843-537-8440 FAX: 843-537-8442 PRODUCT USER NAME: ADDRESS: LOCATION OF USE: QUANTITY RECEIVED: RECEIVED BY: Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Client #: 168 Sample Date: 17-Jan-18 SDG #: SDG-123418 Lab Sample ID: LSID-272435 Sample ID: 1-17-18-500 BIOSOLIDS South Carolina Certification Number: 21117 Receipt Date: 18-Jan-18 Report Date: 06-Feb-18 Approved By: Van Ward Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst Arsenic, TCLP <0.250 0.25 mg/1 1311/6010C/747 S11A 1/23/2018 19:47 JR Barium, TCLP <0.500 0.5 mg/l 1311/6010C/747 S11A 1/23/2018 19:47 JR Cadmium, TCLP <0.025 0.025 mg/l 1311/6010C/747 S11A 1/23/2018 19:47 JR Chromium, TCLP <0.050 0.05 mg/l 1311/6010C/747 S11A 1/23/2018 19:47 JR Lead, TCLP <0.050 0.05 mg/l 1311/6010C/747 SI lA 1/23/2018 19:47 JR Mercury, TCLP <0.004 0.004 mg/l 1311/6010C/747 S11A 1/25/2018 16:56 AS Selenium, TCLP <0.100 0.1 mg/l 1311/6010C/747 SHA 1/23/2018 19:47 JR Silver,TCLP <0.025 0.025 mg/1 1311/6010C/747 S11A 1/23/2018 19:47 JR TCLP Metals PASS P/F 1311/6010C/747 2/1/2018 17:05 WSF Ignitability >180 Deg. F. D93 / 1010A S11A 1/23/2018 13:00 LM TCLP Extraction (Solids) YES EPA 1311 S 11A Acid Digestion (Solids) YES EPA 200.2 1/19/2018 9:00 JR TCLP, Volatiles BRL mg/L EPA 624 / 8260 SI lA 1/25/2018 17:06 MD TCLP Semi-Volatiles BRL mg/L EPA 625 / 8270 S11A 1/23/2018 19:14 YH Selenium, Total <0.988 0.988 mg/kg EPA 7010 / 6010 1/22/2018 11:17 AE TCLP, Pesticides BRL mg/L EPA 8081A SI lA 1/24/2018 13:50 SH TCLP, Herbicides BRL mg/L EPA 8151A S11A 1/24/2018 11:49 UH pH (Waste) 11.95 S.U. EPA 9045D 2/6/2018 15:00 LM pH (Waste) measured in water at 21.3 Deg. C. EPA 9045D 2/6/2018 15:00 LM Percent Moisture 32.9 0.1 wt% SW846 3540 1/18/2018 16:30 ML Page 4 Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Receipt Date: 18-Jan-18 Client #: 168 Report Date: 06-Feb-18 Sample Date: 17-Jan-18 By: �. Approved SDG #: SDG-123418 Lab Sample ID: LSID-272435 Van Ward Sample ID: 1-17-18-500 BIOSOLIDS Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst Aluminum, Total 5230 19.8 mg/kg SW846 6010C 1/19/2018 13:48 JR Arsenic, Total 1.44 0.988 mg/kg SW846 6010C 1/22/2018 1 L 17 AE Cadmium, Total <0.988 0.988 mg/kg SW846 6010C 1/19/2018 14:19 JR Chromium, Total 35.8 0.988 mg/kg SW846 6010C 1/19/2018 14:19 JR Copper, Total 22.7 0.988 mg/kg SW846 6010C 1/19/2018 14:19 JR Lead, Total <0.988 0.988 mg/kg SW846 6010C 1/19/2018 14:19 JR Molybdenum, Total <3.95 3.95 mg/kg SW846 6010C 1/19/2018 13:14 JR Nickel, Total 9.31 0.988 mg/kg SW846 6010C 1/19/2018 14:19 JR Zinc, Total 181 0.988 mg/kg SW846 6010C 1/19/2018 14:19 JR Mercury, Total <0.032 0.032 mg/kg SW846 7470A 1/24/2018 13:00 CG PCB BRL mg/kg SW846 8082A S11A 1/25/2018 11:27 SH Reactivity, Cyanide <1.00 1 mg/kg SW846 9010/90 Sl IA 1/26/2018 15:00 AK Reactivity, Sulfide <100 100 mg/kg SW846 9030/90 S11A 1/24/2018 9:45 AK Paint Filter PASS P/F SW846 9095B SI IA 1/23/2018 9:00 LM Page 5 Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Receipt Date: 18-Jan-18 Client #: 168 Report Date: 06-Feb-18 Sample Date: 18-Jan-18 SDG #: SDG-123418 Approved By:+' Lab Sample ID: LSID-272436 Van Ward Sample ID: 1-18-18-500 Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst Fecal Coliform <305 305 MPN/gm SM 9221 A.3/92 1/18/2018 13:45 LM Percent Solids 65.5 0.1 wt°/o SW846 3540 1/24/2018 10:00 ML Page 6 s ANALYTICAL REPORT CLIENT Davis & Brown P.O. Box 15038 Quinby SC 29506 ATTENTION Ashley Amick PROJECT ID 272435 LABORATORY REPORT NUMBER 1801E92 DATE January 30, 2018 Primary Data Review By Secondary Data Review By Ashley Amick Chris Pafford Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - AIHA-LAP,LLC Laboratory I13:100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 8 A r a<<1 AZ S P fI u-oD -- 414 rs,--)I B10'g 124 W. McIver Road PH: 843-666.6746 PAGE# _OF '"_ ®A `I' BROWN M •1! R �Y Florence, SC 29501 FAX: 843-666-2208 REGULATORY: YES NO ^ ® ppoogg����yy ppYY e�gggg ggam�++ y RECORD ..-.. &�/'D/!' .IN ®F �s,P:fa7 ®�Y .Iti�B�®fYD TURNAROUNDTIME: Pi _STANDARD RUSH _P2 CLIENT: SAMPLE ANALYSIS REQUESTED W ( a USE CODES TO INDICTATE IF SAMPLE WAS FILTERED OR PRESERVED: A = HNO, B=HCL D=H2SO4 F=FILTRATION C = NAOH E= NAyS,O, G - ZINCACETATE Presemelive _ w E U 0T tii W Z OU 4 P J �_ vT 1� `.-'{�)�• T Q� ADDRESS: PROGRAMAREA: D=DRINKING WATER G= GROUNDWATER S =SOLID SL= SLUDGE W= WASTEWATER O=OTHER PLEASE PRINT LEGIBLY PHONE; FAX: SAMPLE ID DATE TtR9E INITIAL NOTES LAB ID FlII in'fhe Number of Containers for EACH Test' '- SAMPLER SIGNATURE FLOW INFO ICE: ICE Y NO PACK RECEIPT TEMP: o C Rolinqui �l.Y D" a: Time: Relinquished by Dale; Time: Relinquished by: Date: Tim.: Received by: pale: Timte::=•/_`\' Received by Date; Time; Re aived b : r Date Time: go", Comments: Page 2 of 8 Analytical Environmental Services, Inc Date: 31-Jan-18 Client: Davis & Brown Project: 272435 Case Narrative Lab ID: 1801E92 Semi Volatile Organic Analysis by Method 8270D/1311: Due to sample matrix, sample 1801E92-001 required dilution during analysis resulting in elevated reporting limits. Page 3 of 8 Analytical Environmental Services, Inc Date: 30-Jan-18 Client: Davis & Brown Client Sample ID: 272435 Project Name: 272435 Collection Date: 1/17/2018 1:30:00 PM Lab ID: 1801E92-001 Matrix: Solid Analyses y Result Reporting Limit Qual Units BatchlD Dilution Factor Date Analyzed Analyst VOLATILES, TCLP SW 1311/8260B (SW5030B) 1,1-Dichloroethene BRL 0.10 mg/L 254770 20 01/25/2018 17:06 MD 1,2-Dichloroethane BRL 0.10 mg/L 254770 20 01/25/2018 17:06 MD 2-Butanone BRL 0.20 rrrg/L 254770 20 01/25/2018 17:06 MD Benzene BRL 0.10 mg/L 254770 20 01/25/2018 17:06 MD Carbon tetrachloride BRL 0.10 mg/L 254770 20 01/25/2018 17:06 MD Chlorobenzene BRL 0.10 mg/L 254770 20 01/25/2018 17:06 MD Chloroform BRL 0.10 mg/L 254770 20 01/25/2018 17:06 MD Tetrachloroethene BRL 0.10 mg/L 254770 20 01/25/2018 17:06 MD Trichloroethene BRL 0.10 mg/L 254770 20 01/25/2018 17:06 MD Vinyl chloride BRL 0.040 mg/L 254770 20 01/25/2018 17:06 MD Surr:4-Bromofluorobenzene 92 64.3-123 %REC 254770 20 01/25/2018 17:06 MD Surr: Dibromofluoromethane 88.3 71.7-127 %REC 254770 20 01/25/2018 17:06 MD Sun: Toluene-d8 101 75.1-118 %REC 254770 20 01/25/2018 17:06 MD Sulfide, Reactive SW846-7.3 (SW7.3.4.2) Sulfide, Reactive BRL 100 mg/Kg 254655 1 01/24/2018 09:45 AK SEMIVOLATILES ORGANICS, TCLP SW1311/8270D (SW3510C) 1,4-Dichlorobenzene BRL 0.50 mg/L 254553 5 01/23/2018 19:14 YH 2,4,5-Trichlorophenol BRL 0.50 mg/L 254553 5 01/23/2018 19:14 YH 2,4,6-Trichlorophenol BRL 0.50 mg/L 254553 5 01/23/2018 19:14 YH 2,4-Dinitrotoluene BRL 0.50 mg/L 254553 5 01/23/2018 19:14 YH Hexachlorobenzene BRL 0.50 mg/L 254553 5 01/23/2018 19:14 YH Hexachlorobutadiene BRL 0.50 mg/L, 254553 5 01/23/2018 19:14 YH Hexachloroethane BRL 0.50 mg/L 254553 5 01/23/2018 19:14 YH m,p-Cresol BRL 0.50 mg/L 254553 5 01/23/2018 19:14 YH Nitrobenzene BRL 0.50 mg/L 254553 5 01/23/2018 19:14 YH o-Cresol BRL 0.50 mg/L 254553 5 01/23/2018 19:14 YH Pentachlorophenol BRL 2.5 mg/L 254553 5 01/23/2018 19:14 YH Pyridine BRL 0.50 mg/L 254553 5 01/23/2018 19:14 YH Cresols, Total BRL 0.50 mg/L 254553 5 01/23/2018 19:14 YH Surr:2,4,6-Tribromophenol 87.9 50.2-144 %REC 254553 5 01/23/2018 19:14 YH Surr:2-Fluorobiphenyl 76.1 50.7-124 %REC 254553 5 01/23/2018 19:14 YH Surr:2-Fluorophenol 84.8 43.8-120 %REC 254553 5 01/23/2018 19:14 YH Surr:4-Terphenyl-dl4 94 60.1-138 %REC 254553 5 01/23/2018 19:14 YH Surr: Nitrobenzene-d5 81.2 50.3-124 %REC 254553 5 01/23/2018 19:14 YH Surr: Phenol-d5 89 47-121 %REC 254553 5 01/23/2018 19:14 YH POLYCHLORINATED BIPHENYLS SW8082A (SW3550C) Aroclor 1016 BRL 33 ug/Kg 254611 1 01/25/2018 11:27 SH Aroclor 1221 BRL 33 ug/Kg 254611 1 01/25/2018 11:27 SH Qualifiers: . Value exceeds maximum contaminant level E Estimated (value above quantitation range) BRL Below reporting limit S Spike Recovery outside limits due to matrix H Holding times for preparation or analysis exceeded Narr See case narrative • N Analyte not NELAC certified NC Not confirmed B Analyte detected in the associated method blank < Less than Result value > Greater than Result value J Estimated value detected below Reporting Limit Page 4 of 8 Analytical Environmental Services, Inc Date: 30-Jan-18 Client: Davis & Brown Client Sample ID: 272435 Project Name: 272435 Collection Date: 1/17/2018 1:30:00 PM Lab ID: 1801E92-001 Matrix: Solid Analyses Result Reporting Qua[ Dilution Units BatchID Date Analyzed Analyst Limit Factor POLYCHLORINATED BIPHENYLS SW8082A (SW35500 Aroclor 1232 BRL 33 ug/Kg 254611 1 01/25/2018 11:27 SH Aroclor 1242 BRL 33 ug/Kg 254611 1 01/25/2018 11:27 SH Aroclor 1248 BRL 33 ug/Kg 254611 1 01/25/2018 11:27 SH Aroclor 1254 BRL 33 ug/Kg 254611 1 01/25/2018 11:27 SH Aroclor 1260 BRL 33 ug/Kg 254611 1 01/25/2018 11:27 SH Surr: Decachlorobiphenyl 71.2 45.6-131 %REC 254611 1 01/25/2018 11:27 SH Sun: Tetrachloro-m-xylene 65.3 47.1-130 %REC 254611 1 01/25/2018 11:27 SH PESTICIDES,TCLP SW1311/8081B (SW3510C) Chlordane BRL 0.0050 mg/L 254515 1 01/24/2018 13:50 SH Endrin BRL 0.0010 mg/L 254515 1 01/24/2018 13:50 SH gamma-BHC BRL 0.00050 mg/L 254515 1 01/24/2018 13:50 SH Heptachlor BRL 0.00050 mg/L 254515 1 01/24/2018 13:50 SH Heptachlor epoxide BRL 0.00050 mg/L 254515 1 01/24/201813.50 SH Methoxychlor BRL 0.0050 mg/L 254515 1 01/24/2018 13:50 SH Toxaphene BRL 0.050 mg/L 254515 1 01/24/2018 13:50 SH Sun: Decachlorobiphenyl 80.9 40.2-124 %REC 254515 1 01/24/2018 13:50 SH Sun: Tetrachloro-m-xylene 66.9 44.9-128 %REC 254515 1 01/24/2018 13:50 SH Paint Filter Liquids Test E9095B Free Liquid Negative 0 ml R361418 1 01/23/2018 09:00 LM MERCURY,TCLP SW1311/7470A (SW7470A) Mercury BRL 0.00400 mg/L 254643 1 01/25/201816:56 AS Ignitability SW1010A Ignitability 180 0 > T R361482 1 01/23/201813:00 LM ICP METALS, TCLP SW 1311/6010C (SW3010A) Arsenic BRL 0.250 mg/L 254596 1 01/23/201819:47 JR Barium BRL 0.500 mg/L 254596 1 01/23/201S 19:47 JR Cadmium BRL 0.0250 mg/L 254596 1 01/23/201819:47 JR Chromium BRL 0.0500 mg/L 254596 1 01/23/201819:47 JR Lead BRL 0.0500 mg/L 254596 1 01 /23/2018 19:47 JR Selenium BRL 0.100 mg/L 254596 1 01/23/201819:47 JR Silver BRL 0.0250 mg/L 254596 1 01/23/201819:47 JR HERBICIDES,TCLP SW1311/8151A (SW3510C) 2,4,5-TP (Silvex) BRL 0.20 mg/L 254514 1 01/24/2018 11:49 UH 2,4-D BRL 0.20 mg/L 254514 1 01/24/2018 11:49 UH Sun: DCAA 63.7 50.4-133 %REC 254514 1 01/24/2018 11:49 UH Qualifiers: " Value exceeds maximum contaminant level E Estimated (value above quantitation range) BRL Below reporting limit S Spike Recovery outside limits due to matrix H Holding times for preparation or analysis exceeded Narr See case narrative N Analyte not NELAC certified NC Not confirmed B Analyte detected in the associated method blank < Less than Result value > Greater than Result value J Estimated value detected below Reporting Limit Page 5 of 8 Analytical Environmental Services, Inc Date: 30-Jan-18 Client: Davis & Brown Client Sample ID: 272435 Project Name: 272435 Collection Date: 1/17/2018 1:30:00 PM Lab ID: 1801E92-001 Matrix: Solid Reporting - Dilution Limit Factor Analyses Result Qual Units BatchID Date Analyzed Analyst Cyanide, Reactive SW846-7.3 (SW7.3.3.2) Cyanide, Reactive BRL 1.00 -./Kg 254828 1 01/26/2018 15:00 AK Qualifiers: * value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 6 of 8 ANALyncAL Fimji O urum Ai. AES ,st?Rt'tc&4,1NC. 1. Client Name: Access Analytical, Inc. 2. Carrier: FedEx ❑• UPS ❑ USPS❑ Client❑ Courier❑ Othei 3. 4. S. 6. 7. 8. 9. 10. 11. 12. SAMPLE/COOLER RECEIPT CHECKLIST AES Work Order Number: 1801E92 \ " Shipping container/cooler received in good condition? damaged ❑ leaking _ other_ Custody seals present on shipping container? • Custody seals intact on shipping container? • Temperature blanks present? • Cooler temperature(s) within limits of 0-(?C? [See item 13 and 14 for temperature recordings.] © I. Q Cooling initiated for recently collected samples / ice present Chain of Custody (COC) present? • Chain of Custody signed, dated, and timed when relinquished and received? • Sampler name and/or signature on COC? • Were all samples received within holding time? •' TAT marked on the COC? • If no TAT indicated, proceeded with standard TAT per Terms & Conditions. 13. Cooler 1 Temperature 0.4 14_ Cooler 5 Temperature 15. Comments: 16. 17, 18. 19. 20. 21. 22. 23. 24. 25. 26, oc Cooler 2 Temperature °C Cooler 3 Temperature oC Cooler 4 Temperature oc oc Cooler 6 Temperature °C Cooler 7 Temperature °C Cooler 8 Temperature °C I certify that I have completed sections 1-15 (dated initials). TO 1/19/18 Were sample containers intact upon receipt? • Custody seals present on sample containers? Custody seals intact on sample containers? 0• Do sample container labels match the COC? Q © © incomplete info L illegible ❑ no label ❑ other ❑ Are analyses requested indicated on the COC? • Were all of the samples listed on the COC received? Q Q © samples received but not listed on CDC samples listed on CDC not received Was the sample collection date/time noted? • Did we receive sufficient sample volume for indicated analyses? • Were samples received in appropriate containers? Were VOA samples received without headspace (< 1/4" bubble)? Were trip blanks submitted? • 1 listed on CDC not listed on CDC U 27. Comments: This section only applies to samples where pH can be I certify that I have completed sections 16-27 (dated initials). checked at Sample Receipt. Yes No N/A Details Comments 28. 29. ve 30. AJJ 1/20/18 Ha containers needing chemical preservation been checked? • • Containers meet preservation guidelines? • Was pH adjusted at Sample Receipt? • Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & Grease/TPH. 1 certify that I have completed sections 28-30 (dated Initials). AJJ 1/20/18 Checklist 6.9.17 Rev 2t A Page 7 of 8 Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & Grease/TPH. 1 certify that I have completed sections 28-30 (dated Initials). AJJ 1/20/18 Checklist 6.9.17 Rev 2t A Page 7 of 8 Analytical Environmental Services, Inc Date: 31-Jan-18 Client: Davis & Brown Project Name: 272435 Dates Report Lab Order: 1801 E92 Lab Sample ID Client Sample ID Collection Date Matrix Test Name TCLP Date Prep Date Analysis Date 1801E92-001A 272435 1/17/2018 1:30:OOPM Solid VOLATILES, TCLP Leached 01/22/2018 1/25/2018 9:08:00AM 01/25/2018 1801E92-001B 272435 1/17/2018 1:30:OOPM Solid TCLP SEMIVOLATILES ORGANICS 01/22/2018 1/23/2018 1:00:00 PM 01/23/2018 1801E92-001B 272435 1/17/2018 1:30:OOPM Solid HERBICIDES, TCLP Leached 01/22/2018 1/23/201811:30:00AM 01/24/2018 1801E92-001B 272435 1/17/2018 1:30:OOPM Solid MERCURY, TCLP Leached 01/22/2018 1/25/201811:00:00AM 01/25/2018 1801E92-001B 272435 1/17/2018 1:30:OOPM Solid ICP METALS, TCLP Leached 01/22/2018 1/23/2018 2:16:00 PM 01/23/2018 1801E92-001B 272435 1/17/2018 1:30.00PM Solid PESTICIDES, TCLP Leached 01/22/2018 1/23/201810:40:00AM 01/24/2018 1801E92-001B 272435 1/17/2018 1:30:OOPM Solid POLYCHLORINATED BIPHENYLS 1/241201810:30:OOAM 01/25/2018 1801E92-001C 272435 1/17/2018 1:30:OOPM Solid IGNITABILITY 01/23/2018 1801E92-001C 272435 1/17/2018 1:30:OOPM Solid Cyanide, Reactive 1/26/20182:30:00PM 01/26/2018 1801E92-001C 272435 1/17/2018 1:30:OOPM Solid Sulfide, Reactive 1124/20189:15:00AM 01/24/2018 1801E92-001C 272435 1/17/2018 1:30:OOPM Solid Paint Filter Liquids Test 01/23/2018 Page 8 of 8 DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by a data qualifier or a flag next to the result. This table summarizes the possible Data Qualifiers that may be associated with this report. A BOD result showed toxic tendencies. B The BOD data is suspect due to a failed quality control check (GGA). C The BOD data is suspect due to a failed quality control check (Blanks). D Results are reported on a dry weight basis. H Sample was analyzed beyond the accepted holding time J Estimated value. Presence of the compound was confirmed but less than the reported detection limit. L Results based on colony counts outside the acceptable range. The ideal range for the fecal coliform test is 20 - 60 colonies. MS Sample matrix spike percent recovery was outside the accepted range. O Sampled, but analysis lost or not performed P Sample was not properly preserved upon receipt. G LCS or MS exceeds the control limits. S Sample was analyzed by another SC certified Lab. SC Seed Correction outside the accepted range of 0.60 - 1.4 mg/L. (BOD) Seed Correction outside the accepted range of 0.60 - 1.4 mg/L (CBOD) SD Results reported are derived from suspect data. SS BOD results derived from supersaturated D.O. values. Sample(s) were aerated per the supersaturation procedure in Standard Methods 5210B SDF Sample Dilutions did not meet the requirement of DO depletion of at least 2.0 mg/L, or the sample dilutions did not meet the requirement of DO residual of at least 1.0 mg/L. Davis & Brown is reporting these results as valid data. T Storage Condition: Temperature above 60 C due to power outage. y Analyte detected in the associated method blank. Note: the value in the blank shall not be subtracted from the sample result. Revision 04/17 WSF Dataqual.wpd Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. Sl South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratory Clemson University S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S,1--1-- South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016; 99006001 Note: S 1 lA indicates AES Laboratory (98016); S 11 G indicates GCAL Laboratory (73006); S11P indicates Pace Analytical (96042001); S11TS indicates Test America Savannah (98001) S 11 TP indicates Test America Pittsburg (89014) -512 AASHTO R18 Certified S 13 South Carolina Lab Certification Number: 96012 S 14 South Carolina Lab Certification Number: 89002 S 16 South Carolina Lab Certification Number: 84004 S17 South Carolina Lab Certification Number: 96037001 S 18 South Carolina Lab Certification Number: 95005 S 19 South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S26 North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 S29 South Carolina Lab Certification Number: 32566 S30 Galbraith Laboratories, Inc. Knoxville TN Revision 08/17 Dataqual (SubLabs)p2 .wpd DAVIS &BROWN 124 W. Mchw Road PH: 842-665-6746 PAGE # �_ OFKM Florence, SC 29501 FAX: 843-6562208 `iL 4' / le REGULATORY: YES NO CHAIN OF CUSTODY RECORD 77— � DARD RUSH MD TWE: —_P2 CLIENT: V (//'' ((�� J) ea L..-) SAMPLE ANALYSIS REOUESTED a a USE CODES TO INOICTATE IF SAMPLE WAS FILTERED OR PRESERVED: A = HNOs B = HCL D - Hs30. F e FILTRATION C = NAOH E = NAxSxOs O = ZINCACETATE pnes�a�e E o a E W 2 U # _^ P� .1- y Vt ADDRESS: PROGRAM AREA: D a DRINKING WATER G=GROUNDWATER S=SOUD SLs SLUDGE W e WASTEWATER O-OTHER PLEASE PRINT LEGIBLY PHONE: FAX: SAMPLE ID DATE TIME wIT�AL NOTES LAB ID I-lgr-►g o Ka A c 1 1 Fill in the Number of Containers for EACH Test b�► 2�-Ztk32. >< -►g-tg Aso s � l \ 2'a-Z�k33 I -air 01,6 (7- g - Soo t-t -t4 1330 k C (- (X• a'' Soo t-t -14 Of L s SAMPLER SIGNATURE --,A,CK AC UU FLOW INFO FICE:ICE oC quished by: DMe: ^ (� Ti�:� fl ResngWa by I �O 4 Reenquianetl Oy: Date: Time; ReesW Date: I_ TSS,�� Q AA- 1sVV tl by Date: 8 `ln e: // �T� Received by: Dale: Time: Comments: Ia UtU: nuvicemcrc<uic A N I M A L W A S T E A N A L Y S I S R E P O R T Agricultural Service Laboratory LAB No. 10102 Clemson University TURNER, SHERRY ACCOUNT COMRLBR PO BOX 219 DATE 01/31/2018 CHERAW SC 29520 STOLSON@CHERAW.COM SAMPLE NO. 01171850 MANURE: OTHER STORAGE: COVERED -----------------RESULTS REPORTED ON AN AS -SAMPLED BASIS---------------------- lbs/ton Ammonium Nitrogen 0.02 % 0.40 Organic Nitrogen 0.81 % 16.22 Nitrate Nitrogen ---------------------------------------------------------- 2.46 ppm 0.00 =---- INCORPORATED AVAILABLE NITROGEN ESTIMATE 10.06 SURFACE AVAILABLE NITROGEN ESTIMATE 9.94 --------------------------------------------------------------- Phosphorus as P205 0.35 % 7.04 Potassium as K20 0.12 % 2.37 Calcium 16.53 % 330.53 Magnesium 0.13 % 2.58 Sulfur 0.17 % 3.44 Zinc 176.39 ppm 0.35 Copper 23.35 ppm 0.05 Manganese 29.50 ppm 0.06 Sodium 213.88 ppm 0.43 Moisture 38.54 % Calcium Carbonate Equivalency 49.06 % 981.14 ------------------------------------------------------------------------------ INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - 80% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be incorporated into the soil within hours of application. Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. Available nitrogen calculations are estimates and if nitrate-N was not re- quested the amount of available nitrogen may be slightly more than reported. Also, the actual amount may be more or less than the estimate depending on the composition of the manure, soil type, and environmental conditions. All of the potash in the animal waste should be plant available in the first year of application. Although not all of the phosphorous is available in the first year, its availability should be comparable to that in commercial fertilizers. The rate of animal waste to apply for crop production is dependent on the nutrient content of the waste, method of application and incorporation, soil test, crop to be grown, and previous manure applications. In most cases, the plant available nitrogen content of the waste is used to determine the rate of % moisture % solids lbs. solids/ton lbs. solids/500 tons 38.54 61.46 1229.2 614600 % ppm lbs/ton % ppm lbs/ton as -sampled as -sampled as -sampled dry ton dry ton dry Ammonium Nitrogen 0.02 200 0.4 0.032541 325.4149 0.65083 Organic Nitrogen 0.811 8110 16.22 1.319557 13195.57 26.39115 Nitrate Nitrogen 0.000246 2.46 0.00492 0.000400 4.002603 0.008005 Incorporated Available Nitrogen Estimate 0.503 5030 10.06 0.818418 8184.185 16.36837 Surface Available Nitrogen Estimate 0.497 4970 9.94 0.808656 8086.56 16.17312 Phosphorus as P2O5 0.352 3520 7.04 0.57273 5727.302 11.4546 Potassium as K2O 0.1185 1185 2.37 0.192808 1928.083 3.856167 Calcium 16.5265 165265 330.53 26.88985 268898.5 537.7969 Magnesium 0.129 1290 2.58 0.209893 2098.926 4.197852 Sulfur 0.172 1720 3.44 0.279857 2798.568 5.597136 Zinc 0.017639 176.39 0.35278 0.0287 286.9997 0.573999 Copper 0.002335 23.35 0.0467 0.003799 37.99219 0.075984 Manganese 0.00295 29.5 0.059 0.0048 47.9987 0.095997 Sodium 0.021388 213.88 0.42776 0.0348 347.9987 0.695997 Calcium Carbonate Equivalency 49.057 490570 981.14 79.81939 798193.9 1596.388 January 2018 Dads & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate ®f Analysis Client: CHERAW, TOWN OF P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURINER Client #: 168 Sample Date: 13-Mar-18 SDG #: SDG-124340 South Carolina Certification Number: 21117 Receipt Date: 15-Mar-18 Report Date: 05-Apr-18 Approved By: Van Ward Lab Director Parameter Result Reporting Limit Unit Method Flag Date Time Analyst LSID-274431 1004-C Cyanide <0.010 0.01 mg/L SM 4500 CN-C & S 1 lA 3/22/2018 10:15 AK LSID-274432 BIOSOLIDS Semi -Volatile Organics BRL mg/kg . EPA 8270D S 11A 3/27/2018 13:04 YH LSID-274433 03-15-18-001INF Biochemical Oxygen Demand 445 2 mg/L SM 5210B 3/15/2018 12:26 AE LSID-274434 03-15-18-002 EFF Biochemical Oxygen Demand 20.1 2 mg/L SM 5210B 3/15/2018 12:26 AE LSID-274435 3-15-18-002-G EFF Oil & Grease, Hexane 16.3 5 mg/L EPA 1664B 3/19/2018 14:30 CG Page 1 ACCESS ANALYnCAL, INC. ANALYTICAL REPORT CLIENT Davis & Brown P.O. Box 15038 Quinby SC 29506 ATTENTION Scott Fields PROJECT ID 274431 LABORATORY REPORT NUMBER 1803H85 DATE March 23, 2018 Primary Data Review By Secondary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: Ashley Amick Project Manager, Access Analytical aamick@axs-inc.com Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 4 Acees5/A�5 cry DAVIS ,pt, V I S & BROWN 124 W.McIver Road PH., 943-665.6746 PAGE #I _ OF 4`� BROWN V i Vl Florence,SC 295501 88443-656-2208 REGULATORY: YES NO en ,Ag �Ge. q.�F�A�X: 6Ylry7l/` I o cusrO6,i' REco ® TURNAROUNDSTANDARD S• RUSH P' - _P2 CLIENT: �l�lS � Jn SAMPLE ANALYSIS REQUESTED Q o a USE CODES TO INDICTATEIF SAMPLE WAS FILTERED OR PRESERVED: A-HN% 6=HCL D=HzSO4 F=FILTRATION C -NAOH E-NAaS1% G=ZINCACETATE Preseivallve 'w o. E U aW W Z FQ-- ZO C) F tO-- - ADDRESS: - • PROGRAM AREA: D=DRINKING WATER G = GROUNDWATER S = SOLID SL = SLUDGE W = WASTEWATER O=OTHER PLEASE PRINT LEGIBLY PHONE: FAX:° SAMPLE ID DATE TIME INITIAL NOTES LAB ID 2-4�51 Ilbb l Fill In the Number of Containers for EACH Test W SAMPLER SIGNATURE - FLOWINFO • ICEr ICE E NO PACK RECEIP,7 O TEMP: AC Relinqu d py: Da Ills 3 fsl 6 Relinquished by Date: Time; Relinquished by: Date: Time: Received by: Date: Time: Received by Data: Time: Received by: Data: Time: Comments: ' lbuutu: IVUYCMtlCtt LVI'G - Page 2 of 4 Analytical Environmental Services, Inc Date: 23-Mar-18 Client: Davis & Brown Client Sample ID: 274431 Project Name: 274431 Collection Date: 3/13/2018 11:00:00 AM Lab ID: 18031-185-001 Matrix: Waste Water Reporting uuunon Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor Total Cyanide (SM4500 CN-C, E) (SM4500-CN-E) Cyanide, Total BRL 0.010 mg/L 257837 1 03/22/2018 10:15 AK Qualifiers: ' Value exceeds maximum contaminant level E Estimated (value above quantitation range) BRL Below reporting limit S Spike Recovery outside limits due to matnx H Holding times for preparation or analysis exceeded Narr See case narrative N Analyte not NELAC certified NC Not confirmed B Analyte detected in the associated method blank < Less than Result value > Greater than Result value 7 Estimated value detected below Reporting Limit Page 3 of 4 N t d�NAm-ric , �" F.b71TRDN1FtTti'P SI. :1E5 SRR�RCAS, F:YC. 1. client Name: ACCESS ANALYTICAL 2: Carrier: FedEx ❑• UPS ❑ USPS❑ Client❑ Courier❑ Othel 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. SAMPLE/COOLER RECEIPT CHECKLIST AES Work Order Number: 18031-185 Yes N. NIA rl-ilc Shipping container/cooler received in good condition? m damaged ❑ leaking �_ other - Custody seals present on shipping container? Custody seals intact on shipping container? Temperature blanks present? e Cooler temperature(s) within limits of 0-6°C? [See item 13 and 14 for temperature recordings.] Q ® ® Cooling initiated for recently collected samples / ice present Chain of Custody (COC) present? m Chain of Custody signed, dated, and timed when relinquished and received? a Sampler name and/or signature on COC? • Were all samples received within holding time? • TAT marked on the COC? If no TAT indicated, proceeded with standard TAT per Terms & Conditions. 0 13. Cooler 1 Temperature 0.1 14. Cooler 5 Temperature 15. Comments: 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. °C Cooler 2 Temperature °C Cooler 3 Temperature °C Cooler 4 Temperature oC °C Cooler 6 Temperature °C Cooler 7 Temperature °C Cooler 8 Temperature °C I certify that 1 have completed sections 1-15 (dated initials). S5 3/16/18 Yes Nn N/A nor�nc r.........,..�.. Were sample containers intact upon receipt? • Custody seals present on sample containers? Custody seals intact on sample containers? Do sample container labels match the COC.v ®° ® ® incompleteinfo ❑ illegible ❑no label ❑ other ElAre analyses requested indicated on the COC? • Were all of the samples listed on the COC received? E) ® ® samples received but not listed on COC ❑ samples listed on CDC not received ❑ Was the sample collection date/time noted? • Did we receive sufficient sample volume for indicated analyses? o Were samples received in appropriate containers? Were VOA samples received without headspace (< 1/4" bubble)?9 # Were trip blanks submitted? a IlistedonCOC %, not listed on COC ❑ 27. Comments: This section only applies to samples where pH can be I certify that I have completed sections 16-27 (dated initials). BU 3/16/18 checked at Sample Receipt, Yes No N/A Details Comments 28. Have containers needing chemical preserv 29. 30. Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms. VOCs and Oil & Grease/FPH. _ I certify that 1 have completed sections 28-30 (dated initials Checklist 6.9.17 Rev 2 Locked, =' BU 3/16/18 Page 4 of 4 ation been checked? Containers meet preservation guidelines? Was pH adjusted at Sample Receipt? • s e ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Davis & Brown P.O. Box 15038 Quinby SC 29506 ATTENTION Scott Fields PROJECT ID 274432 LABORATORY REPORT NUMBER 1803L71 DATE March 29, 2018 Primary Data Review By Secondary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: Ashley Amick Project Manager, Access Analytical aamick@axs-inc.com - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified Laboratory # E87582 - AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCNI Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 4 � I S 924 W. McIver Road PH. 843.665-6746 � � PAGE # OF T �`b 1a• o� Florence, SC DAVIS 29501 FAX: 843-656-2208 , ' REGULATORY: YES NO ++MAI�d OF CUSTODY Cd"8 YYdd��'' TURNAROUND TIME; _Pt CLIENT: _Y _STANDARD RUSH P2 • SAMPLE ANALYSIS REQUESTED USE CODES TO INDICTATE IF SAMPLE WAS Preservative �J QJ` Lx BTU -✓ FILTERED OR PRESERVED: A = HN% .B=HCL D=HzSO1 F=FILTRATION vl ADDRESS: yv - w { a7 C = NAOH E = NAe,5i0, G = ZINCACETATE PROGRA,14ARE4: D = DRINKING WATER a z G j UCl d G = GROUNDWATER S=SOLID SL=SLUDGE (9 m U O J .� p v-o s ual W=WASTEWATER O=OTHER PHONE: FAX: PLEASE PRINT LEGIBLY d t4 '�, 4 Lv 0 0 i SAMPLE ID DATE TIME INITIAL NOTES LAB lD Fill in the Number of Catitainers for EACH Test " 2�Lf43z �( i L 17- EL SAMPLER SIGNATURE , FLOWINFO IC • ICE . YE NO PACK RECEIPT TEMP: ja, by: Oate:Time: Relinquished by Date; Time; Re!nquishcd by: Date: Time: R�d : Datc• (Time: , l awed by Date: Time: Received by: Date: Time: �.t i ., 5 Comments: - GSUED: NOVEMBER2012 Page 2 of 4 Analytical Environmental Services, Inc Date: 29-Mar-18 Client: Davis & Brown Client Sample ID: 274432 Project Name: 274432 Collection Date: 3/14/2018 3:30:00 PM Lab ID: 18031-71-001 Ntatrix: Solid Analyses Result Reporting Qual Units BatchlD miunon Date Analyzed Analyst Limit Factor TCL-SEMIVOLATILE ORGANICS SW8270D (SW3550C) 2,4-Dinitrotoluene BRL 550 ug/Kg-dry 257882 1 03/27/2018 13:04 YH Hexachlorobenzene BRL 550 ug/Kg-dry 257882 1 03/27/2018 13:04 YH Surr:2,4,6-Tribromophenol 0 48.2-133 S %REC 257882 1 03/27/2018 13:04 YH Surr:2-Fluorobiphenyl 92.8 50.2-120 %REC 257882 1 03/27/2018 13:04 YH Surr:2-Fluorophenol 0 41.6-120 S %REC 257882 1 03/27/2018 13:04 YH Surr:4-Terphenyl-d14 101 52.1-122 %REC 257882 1 03/27/2018 13:04 YH Surr: Nitrobenzene-d5 90.4 41.4-120 %REC 257882 1 03/27/2018 13:04 YH Surr: Phenol-d5 19 45.7-120 S %REC 257882 1 03/27/2018 13:04 YH PERCENT MOISTURE D2216 Percent Moisture 40.1 0 Wt/a R366540 1 03/28/2018 15:00 AK Qualifiers: + Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 3 of 4 ;_. av�ra�sc..v, CMear�<s:,. " Save ass:,rJt AFS�S�24ZRONh7F\iaL SAMPLE/COOLER RECEIPT CHECKLIST FRi'tCP4, 1. Client Name: Access Analytical, Inc. AES Work Order Number: 1803L71 2. Carrier: FedEx °❑ UPS ❑ USPS❑ Client❑ Courier❑ Othei vac N. N/A ❑armilc rnmmantc 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. Shipping container/cooler received in good condition? • damaged ❑ leaking ❑ other❑ Custody seals present on shipping.container? Custody seals intact on shipping container? #: • Temperature blanks present? m Cooler temperature(s) within limits of 0-6eC? [See item 13 and 14 for temperature recordings.] ® ® Cooling initiated for recently collected samples / ice present ❑ Chain of Custody (COC) present? o Chain of Custody signed, dated, and timed when relinquished and received. o Sampler name and/or signature on COC? • Were all samples received within holding time? • TAT marked on the COC? If no TAT indicated, proceeded with standard TAT per Terms & Conditions. U 13. Cooler 1 Temperature 1.1 14. Cooler 5 Temperature 15. Comments: 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. °C Cooler 2 Temperature °C Cooler 3 Temperature °C Cooler 6 Temperature °C Cooler 7 Temperature Vac Nn N/A °C Cooler 4 Temperature °C °C Cooler 8 Temperature °C I certify that I have completed sections 1-15 (dated initials). MJ 3/21/18 naraac r- -, Were sample containers intact upon receipt? o Custody seals present on sample containers? ' Custody seals intact on sample containers? • _ Do sample container labels match the COC? ®° ® ® incomplete info ❑ illegible ❑ no label El other ElAre analyses requested indicated on the COC? Were all of the samples listed on the COC received? ® ® sls received but not listed on COC El© ampe samples listed on CDC not received ❑ Was the sample collection date/time noted? o Did we receive sufficient sample volume for indicated analyses? m Were samples received in appropriate containers? Were VOA samples received without headspace (< 1/4" bubble)? Were trip blanks submitted? o listed on CDC I_ not listed on COC ❑ 27. Comments: This section only applies to samples where pH can be I certify that I have completed sections 16-27 (dated initials). MDP 3/22/18 checked at Sample Receipt. Yes No N/A Details Comments 28. 29. 30. ` Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & Grease/TPH. I certify that I have completed sections 28-30 (dated initials Checklist 6.9.17 Rev 2 Page 4 of 4 Have containers needing chemical preservation been checked? Containers meet preservation guidelines? DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S 1 South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 I South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratory Clemson University S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S 11 South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016; 99006001 Note: S 11 A indicates AES Laboratory (98016); S 11 G indicates GCAL Laboratory (73006); S 11 P indicates Pace Analytical (96042001); S 11 TS indicates Test America Savannah (98001) S 11TP indicates Test America Pittsburg89014) S 12 AASHTO R18 Certified S 13 South Carolina Lab Certification Number: 96012 S 14 South Carolina Lab Certification Number: 89002 S 16 South Carolina Lab Certification Number: 84004 S 17 South Carolina Lab Certification Number: 96037001 S 18 South Carolina Lab Certification Number: 95005 S 19 I South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S26 North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 S29 South Carolina Lab Certification Number: 32566 S30 Galbraith Laboratories, Inc. Knoxville TN Recision 08117 Dataqual(SuKabs)p2. wpd ;i'"A A - 3 0 um a 0 e-A v e %;p cx IM m �.j vv INJ .. ..... Florence, ........r+ rcoau SC 29501 PH: FAX: 843-665.6746 843-656-2208 L „y PAGE # l OF f REGULATORY: fE NO CLIENT: �,�,%' ��5°��Pd.9/ di 7 �3���,p� RECORD TURNAROUND TIME: _P1 f�ST..PSQARD RUSH P2 "'— ( O(n�l1 C4 Vvl%r SAMPLE ANALYSIS REQUESTED Pres.native G - i,; SJ ° " °' USE CCOES TC IR'DICTATE:F SAFAFLE WA3 FXTEERED OR?RESE.?bEO: A=HNO, 9 = HCL D = HzSO, ADDRESS: ;n Pz j 0 a �G �� =1 Q Z 11,14 j F = FILTRATION C= NAOH E= NA_,S:O, G= ZINCACETATE PP.OGRAI%,API=A: D=DRINKING WATER U 5 n G=GROUNDWATER S=SOLID SL=SLUDGE � O u r �-- < W=WASTEWATER O=OTHER PHONE: ` cA 'Z 6 < C a . PLEASE PRINTLEGIBLY SAMPLE IC DATE Ti(<,7E • Itd,T.43! NOTES L•`6I0 C ppcLc„� ,� 3 t3 cy - -. ."•• s ' ' ( _ .., rJ€ in the NDm' e er of Ccnta inersforEACHT.t' t[s� SAMPLER SIGNATURE IE RF-10WINF101 tCE: ICE y� X -AEY S NO PACK RECEIPT C`.1/r�o0 Relinquished by; Date TEbfR:Ti^v(' P.elin h.c Fy Cate• , by. Da t.; Tim.; /l"r I c .3 Rec�vec b T' ' •� .6'ny Jy1Dat Tim , P..caiveu b r'`-� _ '�t ^ -% • t � ,. VL !1 yr z'� Y. :Gate. Time: f Comments: Yi �LLSQ .I L (AS✓' c18-[et�"f (e.w:-{' o'{' D, t.3 +�IL {Zsv' Va"Pui p as:-g'-zrs o" 1SJUCLi: NUIEMEER2012 CHERAW ALKALINE BIOSOLIDS SOIL AMENDMENT CHEMICAL CHARACTERISTICS AND LAND APPLICATION RATES BIOSOLIDS SAMPLE DATE: March 21, 2018 METALS Biosolids Metal Content, ppm Maximum Allowable Metal Content, ppm Maximum Maximum Allowable Application App. Rate, Rate, #/Acre/Yr. DT/Acre/Yr. Maximum Application Rate, WT/Acre/Yr. Arsenic, Total 1.66 41.00 1.80 356.42 542.17 Cadmium, Total 0.99 ' 39.00 1.70 565.58 860.32 Chromium, Total 34.10 1200.00 134.00 1291.67 1964.81 Copper, Total 25.50 1500.00 67.00 863.64 1313.73 Lead, Total 0.99 ' 300.00 13.00 4325.00 6578.95 Mercury, Total 0.03 ' 17.00 0.75 8217.50 12500.00 Molybdenum, Total 3.95 18.00 0.80 66.57 101.27 Nickel, Total 10.60 420.00 18.70 579.88 882.08 Selenium, Total 0.99 " 36.00 4.50 1497.12 2277.33 PCB BDL 1.60 " Actual metal content less than amount indicated Biosolids Biosolids Nutrient Nutrient Content, Content, ppm % Crop/Soil Requirement, #/Acre "" Maximum Application Rate, DT/Acre/Yr. Maximum Application Rate, WT/Acre/Yr. Ammonium Nitrogen 300.00 0.03 Organic Nitrogen 9135.00 0.91 Incorporated Available Nitrogen 5725.00 0.57 120.00 6.89 10.48 Surface Available Nitrogen 5635.00 0.56 120.00 7.00 10.65 Phosphorus as P205 3765.00 0.38 80.00 6.98 10.62 Potassium as K20 1585.00 0.16 50.00 10.37 15.77 Calcium, Total 200050.00 20.01 Calcium as CaO 280070.00 28.01 Calcium as CaCO3 (CCE) 492600.00 49.26 2000.00 1.33 2.03 Magnesium, Total 1315.00 0.13 Manganese 30.00 0.00 Sodium 265.00 0.03 Percent Moisture 34.26 These are typical values and must be adjusted based upon specific site conditions DT is Dry Tons of Biosolids. WT is Wet Tons of Biosolids. CERTIFICATION: This biosolid product has been produced by the Town of Cheraw's Wastewater Treatment Plant by a treatment process that pasteurized plant residual solids using high temperature and lime (calcium oxide). The Town of Cheraw certifies that this biosolid complies with the Environmental Protection Agency regulations 40 CFR Part 503 for a "Class A" product and has a metal and nutrient content as presented above. DIRECTIONS FOR USE: This biosolid is intneded to be used as a soil amendment. The biosolid land application rate shall not exceed the most restrictive Maximum Application Rate as indicated in the table above. The application rate for nitrogen, phosphorus, potassium, and calcium is dependent upon the crop grown and site soil characteristics. The user should contact the Clemson Extension Service (843-623-2134) and/or the Soil Conservation Service (843-623-2187) for assistance in determining the proper application rate for each crop and site. In no case shall the land application rate exceed the agronomic rate for the crop grown. User should also refer to the Clemson Extension Service Circular #476 titled "Lime and Fertilizer Recommendations." THIS PRODUCT IS HIGHLY ALKALINE AND SHOULD BE HANDLED ACCORDINGLY. AVOID PROLONGED CONTACT WITH THE SKIN. AVOID CONTACT WITH THE EYES. THE TOWN OF CHERAW IS NOT RESPONSIBLE FOR IMPROPER USE OR HANDLING OF THIS BIOSOLID PRODUCT. Mr. Doug Stowe, Public Utility Director P. 0. Box 219; Cheraw, SC 29520 Telephone: 843-537-8440 FAX: 843-537-8442 PRODUCT USER NAME: LOCATION OF USE: QUANTITY RECEIVED: RECEIVED BY: Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Receipt Date: 22-Mar-18 Client #: 168 Report Date: 13-Apr-18 Sample Date: 22-Mar-18 Approved By:/ AA►+— SDG #: SDG-124448 Van Ward Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst Biochemical Oxygen Demand 26.2 2 mg/L SM 5210B 3/22/2018 12:32 JR LSID-274672 Acid Digestion (Solids) Selenium, Total Percent Moisture Aluminum, Total Arsenic, Total Cadmium, Total Chromium, Total Copper, Total Lead, Total Molybdenum, Total Nickel, Total Mercury, Total PCB 3-21-18-500 YES EPA 200.2 3/26/2018 9:00 AE <0.988 0.988 mg/kg EPA 7010 / 6010C 3/28/2018 17:42 JR 34.2 0.1 wt% SW846 3540 3/28/2018 10:07 ML 5300 39.5 mg/kg SW846 6010C 3/27/2018 14:35 JR 1.66 0.988 mg/kg SW846 6010C 3/28/2018 17:42 JR <0.988 0.988 mg/kg SW846 6010C 3/26/2018 16:05 AE 34.1 0.988 mg/kg SW846 6010C 3/26/2018 16:05 AE 25.5 0.988 mg/kg SW846 6010C 3/26/2018 16:05 AE <0.988 0.988 mg/kg SW846 6010C 3/26/2018 16:05 AE <3.95 3.95 mg/kg SW846 6010C 4/3/2018 15:34 JR 10.6 0.988 mg/kg SW846 6010C 3/26/2018 16:05 AE <0.030 0.03 mg/kg SW846 7470A 4/2/2018 12:35 CG BRL mg/kg SW846 8082A S1lA 3/27/2018 21:50 SH Page 2 CCss ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Davis & Brown P.O. Box 15038 Quinby SC 29506 ATTENTION Scott Fields PROJECTID 274669-274672 LABORATORY REPORT NUMBER 1803095 DATE April 02, 2018 Primary Data Review By Secondary Data Review By / Ashley Amick Chris Pafford Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCNI Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 9 124 W. McIver Road PH. 843-665-6746 DAVISEM & BROWN /9Flloorreencne,, SC, 29601 �g� y�aTq�t9F�AY. 88443-666-22088 REGULATORY: YES NO ,' .. 8/IrY/"5®0N ®� 8/6/a7114/BJ. U. RECORD SANIFLE ANALYSIS REQUESTED NT: Z o cam! gL O om py^� FRII I V by for INFO i 5��as PAGE # OF TURNAROUND TIME: _P1 _ _STANDARD RUSH _P2 USE CODES TO INDICTATE IF SAMPLE WAS FILTERED OR PRESERVED: A = HNO� B=HCL D=HySO,i F=FILTRATION C = NAOH E = NA.S,O, G = 2INCACETATE PROGRAM AREA: D=DRINKING WATER Lu E G=GROUNDWATER S=SOLID SL=SLUDGE W = WASTEWATER O=OTHER O O a PLEASE PRINT LEGIBLY NOTES LABID S ICE NO) PACK : ' 0 oC Page 2 of 9 Analvtical Environmental Services, Inc Date: 2-Apr-18 Client: Davis & Brown Project: 274669-274672 Case Narrative Lab ID: 1803095 pH Analysis by Method SW9045D: Sample for pH analysis by Method SW9045D was received and analyzed outside holding time requirement of "immediate or 15 minutes." Page 3 of 9 Analytical Environmental Services, Inc Date: 2-Apr-18 Client: Davis & Brown Client Sample ID: 274669 Project Name: 274669-274672 Collection Date: 3/21/2018 2:00:00 PM Lab ID: 1803095-001 Matrix: Soil Analyses Result Reporting Limit Qual Units BatchID Dilution Factor Date Analyzed Analyst VOLATILES, TCLP SW1311/8260B (SW5030B) 1,1-Dichloroethene BRL 0.10 mg/L 258075 20 03/29/2018 11:33 CC 1,2-Dichloroethane BRL 0.10 mg/L 258075 20 03/29/2018 11:33 CC 2-Butanone BRL 0.20 mg/L 258075 20 03/29/2018 11:33 CC Benzene BRL 0.10 mg/L 258075 20 03/29/2018 11:33 CC Carbon tetrachloride BRL 0.10 mg/L 258075 20 03/29/2018 11:33 CC Chlorobenzene BRL 0.10 mg/L 258075 20 03/29/2018 11:33 CC Chloroform BRL 0.10 mg/L 258075 20 03/29/2018 11:33 CC Tetrachloroethene BRL 0.10 mg/L 258075 20 03/29/2018 11:33 CC Trichloroethene BRL 0.10 mg/L 258075 20 03/29/2018 11:33 CC Vinyl chloride BRL 0.040 mg/L 258075 20 03/29/2018 11:33 CC Surr:4-Bromofluorobenzene 93.2 64.3-123 %REC 258075 20 03/29/2018 11:33 CC Sun: Dibromofluoromethane 112 71.7-127 %REC 258075 20 03/29/2018 11:33 CC Sun: Toluene-d8 102 75.1-118 %REC 258075 20 03/29/2018 11:33 CC Sulfide, Reactive SW846-7.3 (SW7.3.4.2) Sulfide, Reactive BRL 100 mg/Kg 258071 1 03/27/2018 10:30 AK SEMWOLATILES ORGANICS, TCLP SW1311/8270D (SW3510C) 1,4-Dichlorobenzene BRL 0.10 mg/L 258146 1 03/29/2018 17:06 EI 2,4,5-Trichlorophenol BRL 0.10 mg/L 258146 1 03/29/2018 17:06 EI 2,4,6-Trichlorophenol BRL 0.10 mg/L 258146 1 03/29/2018 17:06- EI 2,4-Dinitrotoluene BRL 0.10 mg/L 258146 1 . 03/29/2018 17:06 EI Hexachlorobenzene BRL 0.10 mg/L 258146 1 03/29/2018 17:06 EI Hexachlorobutadiene BRL 0.10 mg/L 258146 1 03/29/2018 17:06 EI Hexachloroethane BRL 0.10 mg/L 258146 1 03/29/2018 17:06 EI m,p-Cresol BRL 0.10 mg/L 258146 1 03/29/2018 17:06 EI Nitrobenzene BRL 0.10 mg/L 258146 1 03/29/2018 17:06 EI o-Cresol BRL 0.10 mg/L 258146 1 03/29/2018 17:06 EI Pentachlorophenol BRL 0.50 rag/L 258146 1 03/29/2018 17:06 El Pyridine BRL 0.10 mg/L 258146 1 03/29/2018 17:06 EI Cresols, Total BRL 0.10 mg/L 258146 1 03/29/2018 17:06 El Surr:2,4,6-Tribromophenol 95.6 50.2-144 %REC 258146 1 03/29/2018 17:06 EI Surr:2-Fluorobiphenyl 90.9 50.7-124 %REC 258146 1 03/29/2018 17:06 El Sun:2-Fluorophenol 96.7 43.8-120 %REC 258146 1 03/29/2018 17:06 El Sun:4-Terphenyl-d14 113 60.1-138 %REC 258146 1 03/29/2018 17:06 El Sun: Nitrobenzene-d5 92.2 50.3-124 %REC 258146 1 03/29/2018 17:06 El Sun: Phenol-d5 97.7 47-121 %REC 258146 1 03/29/2018 17:06 EI POLYCHLORINATED BIPHENYLS SW8082A (SW3550C) Aroclor 1016 BRL 48 ug/Kg-dry 258046 1 03/27/2018 21:20 SH Aroclor 1221 BRL 48 ug/Ko dry 258046 I 03/27/2018 21:20 SH Qualifiers: ' Value exceeds maximum contaminant level E Estimated (value above quantitation range) BRL Below reporting limit S Spike Recovery outside limits due to matrix H Holding times for preparation or analysis exceeded Narr See case narrative N Analyte not NELAC certified NC Not confirmed B Analyte detected in the associated method blank < Less than Result value > Greater than Result value I Estimated value detected below Reporting Limit Page 4 of 9 Analytical Environmental Services, Inc Date: 2-Apr-18 Client: Davis & Brown Client Sample ID: 274669 Project Name: 274669-274672 Collection Date: 3/21/2018 2:00:00 PM Lab ID: 1803095-001 Matrix: Soil Analyses Result Reporting Limit Qual Units BatchID vuuaon Factor Date Analyzed Analyst POLYCHLORINATED BIPHENYLS SW8082A (SW3550C) Aroclor 1232 BRL 48 ug/Kg-dry 258046 1 03/27/2018 21:20 SH Aroclor 1242 BRL 48 ug/Kg-dry 258046 1 03/27/2018 21:20 SH Aroclor 1248 BRL 48 ug/Kg-dry 258046 1 03/27/2018 21:20 SH Aroclor 1254 BRL 48 ug/Kg-dry 258046 1 03/27/2018 21:20 SH Aroclor 1260 BRL 48 ug/Kg-dry 258046 1 03/27/2018 21:20 SH Surr: Decachlorobiphenyl 88.3 45.6-131 %REC 258046 1 03/27/2018 21:20 SH Sun: Tetrachloro-m-xylene 68.2 47.1-130 %REC 258046 1 03/27/2018 21:20 SH PESTICIDES, TCLP SW 1311/8081B (SW3510C) Chlordane BRL 0.0050 mg/L 258280 1 03/29/2018 19:02 SH Endrin BRL 0.0010 rng/L 258280 1 03/29/2018 19:02 SH gamma-BHC BRL 0.00050 mg/L 258280 1 03/29/2018 19:02 SH Heptachlor BRL 0.00050 mg/L 258280 1 03/29/2018 19:02 SH Heptachlor epoxide BRL 0.00050 mg/L 258280 1 03/29/2018 19:02 SH ivlethoxychlor BRL 0.0050 rng/L, 258280 1 03/29/2018 19:02 SH Toxaphene BRL 0.050 mg/L 258280 1 03/29/2018 19:02 SH Surr: Decachlorobiphenyl 81.7 40.2-124 %REC 258280 1 03/29/2018 19:02 SH Surr: Tetrachloro-m-xylene 80.2 44.9-128 %REC 258280 1 03/29/2018 19:02 SH Paint Filter Liquids Test E9095B Free Liquid Negative 0 ml R366719 1 03/30/2018 10:24 LM MERCURY, TCLP SW1311/7470A (SW7470A) Mercury BRL 0.00400 rng/L 258194 1 03/29/2018 00:59 AS Laboratory Hydrogen Ion (pH) SW9045D (SW9045D) pH 6.41 0.01 H pH Units 258287 1 03/29/2018 11:15 BD Ignitability SW1010A Ignitability 180 0 > °F R366718 1 03/30/201811:00 LM ICP METALS, TCLP SW1311/6010C (SW3010A) Arsenic BRL 0.250 mg/L 258244 1 03/29/201815:05 10 Barium BRL 0.500 tng/L 258244 1 03/29/201815:05 IO Cadmium BRL 0.0250 mg/L 258244 1 03/29/201815:05 IO Chromium BRL 0.0500 mg/L 258244 1 03/29/2018 t5:05 IO Lead BRL 0.0500 mg/L 258244 1 03/29/201815:05 IO Selenium BRL 0.100 mg/L 258244 1 03/29/201815:05 10 Silver BRL 0.0250 mg/L 258244 1 03/29/201815:05 IO HERBICIDES, TCLP SW1311/8151A (SW3510C) Qualifiers: ' Value exceeds maximum contaminant level E Estimated (value above quantitation range) BRL Below reporting limit S Spike Recovery outside limits due to matrix H Holding times for preparation or analysis exceeded Narr See case narrative N Analyte not NELAC certified NC Not confirmed B Analyte detected in the associated method blank < Less than Result value > Greater than Result value S Estimated value detected below Reporting Limit Page 5 of 9 Analytical Environmental Services, Inc Date: 2-Apr-18 Client: Davis & Brown Client Sample ID: 274669 Project Name: 274669-274672 Collection Date: 3/21/2018 2:00:00 PM Lab ID: 1803095-001 Matrix: Soil Reporting Dilution Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor HERBICIDES, TCLP SW1311/8151A 2,4,5-TP (Silvex) 2,4-D Surr: DCAA Cyanide, Reactive SW846-7.3 Cyanide, Reactive PERCENT MOISTURE D2216 Percent Moisture Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value BRL 0.20 BRL 0.20 45.6 50.4-133 BRL 1.00 30.3 0 (SW3510C) mg/L 258279 I 03/30/201816:39 UH mg/L 258279 1 03/30/201816:39 UH S REC 258279 1 03/30/201816:39 UH (SW7.3.3.2) mg/Kg 257979 1 03/26/201812:00 AK wt% R366664 1 03/29/201813:00 00 E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative - NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 6 of 9 Analytical Environmental Services, Inc Date: 2-Apr-18 Client: Davis & Brown Client Sample ID: 274672 Project Name: 274669-274672 Collection Date: 3/21/2018 1:00:00 PM Lab ID: 1803095-002 Nlatrix: Soil Analyses Result Reporting Qual Units uuunon BatchID Date Analyzed Analyst Limit Factor POLYCHLORINATED BIPHENYLS SW8082A (SW3550C) Aroclor 1016 BRL 68 ug/Kg-dry 258046 1 03/27/2018 21:50 SH Aroclor 1221 BRL 68 ug/Kg-dry 258046 l 03/27/2018 21:50 SH Aroclor 1232 BRL 68 ug/Kg-dry 258046 1 03/27/2018 21:50 SH Aroclor 1242 BRL 68 ug/Kg-dry 258046 1 03/27/2018 21:50 SH Aroclor 1248 BRL 68 ug/Kg-dry 258046 1 03/27/2018 21:50 SH Aroclor 1254 BRL 68 ug/Kg-dry 258046 1 03/27/2018 21:50 SH Aroclor 1260 BRL 68 ug/Kg-dry 258046 1 03/27/2018 21:50 SH Surr: Decachlorobiphenyl 52.9 45.6-131 %REC 258046 1 03/27/2018 21:50 SH Surr: Tetrachloro-m-xylene 54 47.1-130 %REC 258046 1 03/27/2018 21:50 SH PERCENT MOISTURE D2216 Percent Moisture 51.0 0 wt% R366664 1 03/29/2018 13:00 00 Qualifiers: " Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 7 of 9 ENS7RDN1411-4C. SAMPLE/COOLER RECEIPT CHECKLIST AES .SER,9tCF.S, PSC. 1. Client Name: ACCESS ANALYTICAL 2. Carrier: FedEx ❑s UPS E USPS❑ Client❑ Courier[] Othel AES Work Order Number: 1803095 vcc Mn M/A n—H. Shipping container/cooler received in good condition? o damaged ❑ leaking ❑ other,❑ Custody seals present on shipping container? e Custody seals intact on shipping container? Temperature blanks present? Cooler temperature(s) within limits of 0-6°C? [See item 13 and 14 for temperature recordings.] ® ® Cooling initiated for recently collected samples / ice present ❑ Chain of Custody (CDC) present? • Chain of Custody signed, dated, and timed when relinquished and received? • Sampler name and/or signature on CDC? • Were all samples received within holding time? TAT marked on the CDC? a I U I If no TAT indicated, proceeded with standard TAT per Terms & Conditions. U 13. Cooler 1 Temperature 1.3 14. Cooler 5 Temperature 15. Comments: 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. °C Cooler 2 Temperature °C Cooler 3 Temperature °C Cooler 4 Temperature °C °C Cooler 6 Temperature °C Cooler 7 Temperature °C Cooler 8 Temperature °c I certify that I have completed sections 1-15 (dated initials). Were sample containers intact upon receipt? Custody seals present on sample containers? Custody seals intact on sample containers? Do sample container labels match the COC.v ®° ® ® ❑ incomplete info ❑ illegibleno label ❑ other ❑ Are analyses requested indicated on the CDC? Were all of the samples listed on the COC received? ®° ® ® samples received but not listed on CDC ❑ samples listed on CDC not received ❑ Was the sample collection date/time noted? Did we receive sufficient sample volume for indicated analyses? • Were samples received in appropriate containers? Were VOA samples received without headspace (< 1/4" bubble)? Were trip blanks submitted? listed on CDC F not listed on CDC ❑ 27. Comments: . This section only applies to samples where pH can be I certify that I have completed sections 16-27 (dated initials). AIJ 3/24/18 checked at Sample Receipt. yes No N/A Details comments 28. 29. 30. lWas Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & Grease/TPH. I certify that I have completed sections 28-30 (dated initials Locked', n; Checklist 6.9.17 Rev 2 ...--'��� s.. AJJ 3/24/18 Page 8 of 9 Have containers needing chemical preservation been checked? Containers meet preservation guidelines? Analytical Environmental Services, Inc Date: 2-Apr-18 Client: Davis & Brown Project Name: 274669-274672 Dates Report Lab Order: 1803095 Lab Sample ID Client Sample ID Collection Date Matrix Test Name TCLP Date Prep Date Analysis Date 1803095-001A 274669 3/21/2018 2:00:OOPM Soil VOLATILES, TCLP Leached 03/27/2018 3/27/20189:44:00AM 03/29/2018 1803095-001B 274669 3/21/2018 2:00:OOPM Soil IGNITABILITY 03/30/2018 1803095-001B 274669 3/21/2018 2:00:OOPM Soil TCLP SEMIVOLATILES ORGANICS 03/28/2018 3/29/2018 7:50:00 AM 03/29/2018 1803095-0018 274669 3/212018 2 OO:00PM Soil HERBICIDES, TCLP Leached 03/28/2018 3/29/2018 1:00:00 PM 03/30/2018 1803095-001 B 274669 3/212018 2:00:OOPM Soil MERCURY, TCLP Leached 03282018 31282018 9:13:00 PM 03292018 1803095-0018 274669 3/212018 2:00:OOPM Soil ICP METALS, TCLP Leached 03282018 3/292018 11:42:00 AM 03292018 1803095-0018 274669 3/212018 2:00:OOPM Soil PESTICIDES, TCLP Leached 03282018 3/29/2018 1:00:00 PM 03/292018 1803095-001B 274669 3/212018 2:00:OOPM Soil Cyanide, Reactive 3/26/201811:30:00AM 03262018 1803095-001B 274669 3/212018 2:OO:OOPM Soil Sulfide, Reactive 3127201810:00:00AM 03272018 1803095-001B 274669 3/212018 2:00:OOPM Soil POLYCHLORINATED BIPHENYLS 3/27201811:00:00AM 03272018 1803095-0018 274669 3/212018 2:00:OOPM Soil Laboratory Hydrogen Ion (pH) 3/292018 11:15:00 AM 03292018 1803095-0018 274669 3/212018 2:OO:OOPM Soil Paint Filter Liquids Test 03/302018 1803095-001B 274669 3212018 2:00:OOPM Soil PERCENT MOISTURE 03292018 1803095-002A 274672 3212018 1:00:OOPM Soil POLYCHLORINATED BIPHENYLS 3/27201811:00:00AM 03/272018 1803095-002A 274672 3/212018 1:00:OOPM Soil PERCENT MOISTURE 03292018 Page 9 of 9 DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by a data qualifier or a flag next to the result. This table summarizes the possible Data Qualifiers that may be associated with this report. A BOD result showed toxic tendencies. B The BOD data is suspect due to a failed quality control check (GGA). C The BOD data is suspect due to a failed quality control check (Blanks). D Results are reported on a dry weight basis. H Sample was analyzed beyond the accepted holding time J Estimated value. Presence of the compound was confirmed but less than the reported detection limit. L Results based on colony counts outside the acceptable range. The ideal range for the fecal coliform test is 20 - 60 colonies. MS Sample matrix spike percent recovery was outside the accepted range. O Sampled, but analysis lost or not performed P Sample was not properly preserved upon receipt. G LCS or MS exceeds the control limits. S Sample was analyzed by another SC certified Lab. SC Seed Correction outside the accepted range of 0.60 - 1.4 mg/L. (BOD) Seed Correction outside the accepted range of 0.60 - 1.4 mg/L (CBOD) .SD Results reported are derived from suspect data. SS BOD results derived from supersaturated D.O. values. Sample(s) were aerated per the supersataration procedure in Standard Methods 5210B SDF Sample Dilutions did not meet the requirement of DO depletion of at least 2.0 mg/L, or the sample dilutions did not meet the requirement of DO residual of at least 1.0 mg/L. Davis & Brown is reporting these results as valid data. T Storage Condition: Temperature above 60 C due to power outage. V Analyte detected in the associated method blank. Note: the value in the blank shall not be subtracted from the sample result. Revision 04/17 WSF Dataqual.vvpd Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S 1 South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratory Clemson University S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S11 South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016; 99006001 Note: S11A indicates AES Laboratory'(98016); S11G indicates GCAL Laboratory (73006); S11P indicates Pace Analytical (96042001); S 11TS indicates Test America Savannah (98001) S 11TP indicates Test America Pittsburg (89014) S 12 AASHTO RI 8 Certified S 13 South Carolina Lab Certification Number: 96012 S14 South Carolina Lab Certification Number: 89002 S 16 South Carolina Lab Certification Number: 84004 S17 South Carolina Lab Certification Number: 96037001 S 18 South Carolina Lab Certification Number: 95005 S 19 South Carolina Lab Certification Number: 23104 S20 -South Carolina -Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S26 North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 S29 South Carolina Lab Certification Number: 32566 S30 Galbraith Laboratories, Inc. Knoxville TN Revision 08/17 Dataqual (SubLabs)p2 .N pd DAVIS & BROWN REGULATORY: (F NO 0w-& SAMPLE ID DATE TIME iGtna LayUVn J S«%� 3-Zt-tQ t�Eao 51.T- C 5Ls C As C, t 124 W. McIver Road PH: 845-665.6746 Florence, SC 29501 FAX. • 843-656-2208 CHAIN ®F CUSTODY RECORD I - INFO PAME# _I_ OF _ TURNAROUND 77ME: P7 STANDARD RUSH _P2 USE COOES TO mlm--A 1F SAMPLE WAS FIL TERED OR PRESERVED: A=HNO, B=HCL D=H=SO4 F=FILTRATION C=NAOH E=NAiSiO, G=21NCACETATE PROGRAMAREa ,• D- DRINIDNG WATER G = GROUNDWATER S=SOLID SL=SLUDGE m W=WASTEWATER O=OTHER PLEASE PRINT LEGIBLY O tr a NOTES LAB ID s Z�t�q Vi Se, AN, Ar, Cd , Gh, l W 1 2 ICE NO PACK EIPT P: C Tim.: Time: A N I M A L W A S T E A N A L Y S I S R E P O R T Agricultural Service Laboratory LAB No. 30479 Clemson University TURNER, SHERRY ACCOUNT COMRLBR PO BOX 219 DATE 04/03/2018 CHERAW SC 29520 STOLSON@CHERAW.COM SAMPLE NO. 03211850 MANURE: OTHER STORAGE: COVERED -----------------RESULTS REPORTED ON AN AS -SAMPLED BASIS---------------------- lbs/ton Ammonium Nitrogen 0.03 % 0.60 Organic Nitrogen 0.91 % 18.27 Nitrate Nitrogen --------------------------------------------------------------- 4.60 ppm 0.01 INCORPORATED AVAILABLE NITROGEN ESTIMATE 11.45 SURFACE AVAILABLE --------------------------------------------------------------- NITROGEN ESTIMATE 11.27 Phosphorus as 2205 0.38 % 7.53 Potassium as K20 0.16 % 3.17 Calcium 20.01 % 400.10 Magnesium 0.13 % 2.63 Sulfur 0.18 % 3.55 Zinc 168.96 ppm 0.34 Copper 26.30 ppm 0.05 Manganese 28.93 ppm 0.06 Sodium 262.97 ppm 0.53 Moisture 34.26 % Calcium Carbonate Equivalency 49.26 % 985.20 ------------------------------------------------------------------------------ INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - 80% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be incorporated into the soil within hours of application. Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. Available nitrogen calculations are estimates and if nitrate-N was not re- quested the amount of available nitrogen may be slightly more than reported. Also, the actual amount may be more or less than the estimate depending on the composition of the manure, soil type, and environmental conditions. All of the potash in the animal waste should be plant available in the first year of application. Although not all of the phosphorous is available in the first year, its availability should be comparable to that in commercial fertilizers. The rate of animal waste to apply for crop production is dependent on the nutrient content of the waste, method of application and incorporation, soil test, crop to be grown, and previous manure applications. In most cases, the plant available nitrogen content of the waste is used to determine the rate of % moisture % solids lbs. solids/ton lbs. solids/500 tons 34.26 65.74 1314.8 657400 % ppm lbs/ton % ppm lbs/ton as -sampled as -sampled as -sampled dry ton dry ton dry Ammonium Nitrogen 0.03 300 0.6 0.045634 456.3432 0.912686 Organic Nitrogen 0.9135 9135 18.27 1.389565 13895.65 27.7913 Nitrate Nitrogen 0.000460 4.6 0.0092 0.000700 6.997262 0.013995 Incorporated Available Nitrogen Estimate 0.5725 5725 11.45 0.870855 8708.549 17.4171 Surface Available Nitrogen Estimate 0.5635 5635 11.27 0.857165 8571.646 17.14329 Phosphorus as P2O5 0.3765 3765 7.53 0.572711 5727.107 11.45421 Potassium as K2O 0.1585 1585 3.17 0.241101 2411.013 4.822026 Calcium 20.005 200050 400.1 30.43048 304304.8 608.6097 Magnesium 0.1315 1315 2.63 0.20003 2000.304 4.000608 Sulfur 0.1775 1775 3.55 0.270003 2700.03 5.400061 Zinc 0.016896 168.96 0.33792 0.025701 257.0125 0.514025 Copper 0.00263 26.3 0.0526 0.004001 40.00608 0.080012 Manganese 0.002893 28.93 0.05786 0.004401 44.00669 0.088013 Sodium 0.026297 262.97 0.52594 0.040002 400.0152 0.80003 Calcium Carbonate Equivalency 49.26 492600 985.2 74.93155 749315.5 1498.631 March 2018 CHERAW ALKALINE BIOSOLIDS SOIL AMENDMENT CHEMICAL CHARACTERISTICS AND LAND APPLICATION RATES BIOSOLIDS SAMPLE DATE: May 16, 2018 METALS Biosolids Metal Content, ppm Maximum Allowable Metal Content, ppm Maximum Maximum Allowable Application App. Rate, Rate, #/Acre/Yr. DT/Acre/Yr. Maximum Application Rate, WT/Acre/Yr. Arsenic, Total 0.99 ' 41.00 1.80 571.85 910.01 Cadmium, Total 0.99 ' 39.00 1.70 540.08 859.45 Chromium, Total 28.30 1200.00 134.00 1487.73 2367.49 Copper, Total 2150 1500.00 67.00 895.80 1425.53 Lead, Total 0.99 300.00 13.00 4130.03 6572.30 Mercury, Total 0.03 17.00 0.75 8125.86 12931.03 Molybdenum, Total 3.96 ' 18.00 0.80 63.47 101.01 Nickel, Total 11.00 420.00 18.70 534.14 850.00 Selenium, Total 0.99 ' 36.00 4.50 1429.63 2275.03 PCB BDL 1.60 Actual metal content less than amount indicated Biosolids Nutrient Content, ppm Biosolids Nutrient Content, % Crop/Sal Requirement, #/Acre " Maximum Application Rate, DT/Acre/Yr. Maximum Application Rate, WT/Acre/Yr. Ammonium Nitrogen 600.00 0.06 Organic Nitrogen 8445.00 0.84 Incorporated Available Nitrogen 5610.00 0.56 120.00 6.72 10.70 Surface Available Nitrogen 5430.00 0.54 120.00 6.94 11.05 Phosphorus as P205 4895.00 0.49 80.00 5.14 8.17 Potassium as K20 2120.00 0.21 50.00 7.41 11.79 Calcium, Total 216490.00 21.65 Calcium as CaO 303086.00 30.31 Calcium as CaCO3 (CCE) 460695.00 46.07 2000.00 1.36 2.17 Magnesium, Total 1385.00 0.14 Manganese 40.00 0.00 Sodium 385.00 0.04 Percent Moisture 37.16 These are typical values and must be adjusted based upon specific site conditions DT is Dry Tons of Biosolids. WT is Wet Tons of Biosolids. CERTIFICATION: This biosolid product has been produced by the Town of Cheraw's Wastewater Treatment Plant by a treatment process that pasteurized plant residual solids using high temperature and lime (calcium oxide). The Town of Cheraw certifies that this biosolid complies with the Environmental Protection Agency regulations 40 CFR Part 503 for a "Class A" product and has a metal and nutrient content as presented above. DIRECTIONS FOR USE: This biosolid is intneded to be used as a soil amendment. The biosolid land application rate shall not exceed the most restrictive Maximum Application Rate as indicated in the table above. The application rate for nitrogen, phosphorus, potassium, and calcium is dependent upon the crop grown and site soil characteristics. The user should contact the Clemson Extension Service (843-623-2134) and/or the Soil Conservation Service (843-623-2187) for assistance in determining the proper application rate for each crop and site. In no case shall the land application rate exceed the agronomic rate for the crop grown. User should also refer to the Clemson Extension Service Circular #476 titled "Lime and Fertilizer Recommendations." THIS PRODUCT IS HIGHLY ALKALINE AND SHOULD BE HANDLED ACCORDINGLY. AVOID PROLONGED CONTACT WITH THE SKIN. AVOID CONTACT WITH THE EYES. THE TOWN OF CHERAW IS NOT RESPONSIBLE FOR IMPROPER USE OR HANDLING OF THIS BIOSOLID PRODUCT. Mr. Doug Stowe, Public Utility Director P. 0. Box 219; Cheraw, SC 29520 Telephone: 843-537-8440 FAX: 843-537-8442 PRODUCT USER NAME ADDRESS: - INTENDED USE: LOCATION OF USE: QUANTITY RECEIVED: RECEIVED BY: Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Receipt Date: 18-May-18 Client #: 168 Report Date: 08-Jun-18 Sample Date: 16-May-18 Approved By: SDG #: SDG-125389 4V*Ak— Lab Sample ID: LSID-276640 Van Ward Sample ID: BIOSOLIDS-5-16-18-500 Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst Acid Digestion (Solids) YES EPA 200.2 5/21/2018 9:20 JR Selenium, Total <0.989 0.989 mg/kg EPA 7010 / 6010 5/23/2018 16:24 JR Percent Moisture 36.2 0.1 wt°/a SW846 3540 5/21/2018 14:23 ML Aluminum, Total 5040 39.6 mg/kg SW846 6010C 5/23/2018 10:27 JR Arsenic, Total <0.989 0.989 mg/kg SW846 6010C 5/23/2018 16:24 JR Cadmium, Total <0.989 0.989 mg/kg SW846 6010C 5/21/2018 15:44 JR Chromium, Total 28.3 0.989 mg/kg SW846 6010C 5/21/2018 15:44 JR Copper, Total 23.5 0.989 mg/kg SW846 6010C 5/21/2018 15:44 JR Lead, Total 0.989 0.989 mg/kg SW846 6010C 5/21/2018 15:44 JR Molybdenum, Total <3.96 3.96 mg/kg SW846 6010C 5/23/2018 9:19 JR Nickel, Total 11.0 0.989 mg/kg SW846 6010C 5/21/2018 15:44 JR Mercury, Total <0.029 0.029 mg/kg SW846 7470A 5/30/2018 12:45 CG PCB BRL mg/kg SW846 8082A Si IA/D 5/25/2018 15:42 UH Page 1 ACCESS ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Davis & Brown P.O. Box 15038 Quinby SC 29506 ATTENTION Scott Fields PROJECTID 276640 LABORATORY REPORT NUMBER 1805N54 DATE May 30, 2018 Primary Data Review By Secondary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: Ashley Amick Project Manager, Access Analytical aamick@axs-inc.com - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCNI Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781,4243 or toll fee at 883.315.4243 Page 1 of 4 Analytical Environmental Services, Inc Date: 30-May-18 Client: Davis & Brown Client Sample ID: 276640 Project Name: 276640 Collection Date: 5/ 16/2018 9:25:00 AM Lab ID: 1805N54-001 Nlatrix: Solid Analyses Result Reporting Limit Qual C`nits BatchID Dilution Factor Date Analyzed Analyst POLYCHLORINATED BIPHENYLS SW8082A (SW3550C) Aroclor 1016 BRL 45 ug/Kg-dry 261240 1 05/25/2018 15:42 UH Aroclor 1221 BRL 45 ugiKg-dry 261240 1 05/25/2018 15:42 UH Aroclor 1232 BRL 45 ugiKg-dry 261240 1 05/25/2018 15:42 UH Aroclor 1242 BRL 45 ug/Kg-dry 261240 1 05/25/2018 15:42 UH Aroclor 1248 BRL 45 ug/Kg-dry 261240 1 05/25/2018 15:42 UH Aroclor 1254 BRL 45 u&Kg-dry 261240 l 05/25/2018 15:42 UH Aroclor 1260 BRL 45 ug/Kg-dry 261240 1 05/25/2018 15:42 UH Surr: Decachlorobiphenyl 75.7 45.6-131 %REC 261240 I 05/25/2018 15:42 UH Surr: Tetracbloro-m-xylene 78.2 47.1-130 %RFC 261240 1 05/25/2018 15:42 UH PERCENT MOISTURE D2216 Percent Moisture 25.4 0 wt"/a R371508 1 05/29/2018 18:15 CG Qualifiers: . Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Crater than Result value E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value 7 Estimated value detected below Reporting Limit Page 3 of 4 P+.V UONXTENTAL •AES SERCiC&S NC. 1. Clientdame: Access Analytical, Inc. 2. Carrier: FeclEx ❑ UPS ❑ USPS❑ ClientC Courier❑ Othel 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. SAMPLE/COOLER RECEIPT CHECKLIST AES Work Order Number: 1805N54 Yes No N/A Details Comments Shipping container/cooler received in good condition? • damaged ❑ leaking ❑ othen❑ - Custody seals present on shipping container? Custody seals intact on shipping container? 110- • Temperature blanks present? Cooler temperature(s) within limits of 0-6oC? [See item 13 and 14 for temperature recordings.] ® 0, Cooling initiated for recently collected samples / ice present ❑ Chain of Custody (COC) present? • ' Chain of Custody signed, dated, and timed when relinquished and received? no Sampler name and/or signature on COC? • Were all samples received within holding time? • TAT marked on the COC? • If no TAT indicated, proceeded with standard TAT per Terms & Conditions. LE! 13. Cooler 1 Temperature 1.9 14. Cooler 5 Temperature 15. Comments: 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. oc Cooler 2 Temperature oC Cooler 3 Temperature °C Cooler 4 Temperature °C oC Cooler 6 Temperature °C Cooler 7 Temperature °C Cooler 8 Temperature °c I certify that I have completed sections 1-15 (dated initials). AJJ 5/22/18 Yes No N/A Details Comments Were sample containers intact upon receipt? •0 11 0 1' Custody seals present an sample containers? G 0" Custody seals intact on sample containers? Do sample container labels match the COC? G ® ® incomplete info ❑ illegible ❑ no label ❑ other ❑ Are analyses requested indicated on the COC? • Were all of the samples listed on the COC received? E) - ® ® samples received but not listed on COC ❑ samples listed on COC not received ❑ Was the sample collection date/time noted? Iof Did we receive sufficient sample volume for Indicated analyses? Were samples received in appropriate containers? • Were VOA samples received without headspace (< 1/4" bubble)? Were trip blanks submitted? • Ilisted on COC 7 not listed on COC ❑ 27. Comments: This section only applies to samples where pH can be I certify that I have completed. sections 56-27 (dated initials). ES 5/23/18 checked at Sample Receipt. Yes No N/A Details Comments 28. Have containers needing chemical preserv 29. Containers meet preserv 30. Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & GreasefrPH. I certify that 1 have completed sections 28-30 (dated initials Checklist 6.9.17 Rev ES 5/23/18 Page 4 of 4 ation been checked? ation guidelines? Was pH adjusted at Sample Receipt? • - � DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by a data qualifier or a flag next to the result. This table summarizes the possible Data Qualifiers that may be associated with this report. A BOD result showed toxic tendencies. B The BOD data is suspect due to a failed quality control check (GGA). C The BOD data is suspect due to a failed quality control check (Blanks). D Results are reported on a dry weight basis. H Sample was analyzed beyond the accepted holding time J Estimated value. Presence of the compound was confirmed but less than the reported detection limit. L Results based on colony counts outside the acceptable range. The ideal range for the fecal coliform test is 20 - 60 colonies. MS Sample matrix spike percent recovery was outside the accepted range. O Sampled, but analysis lost or not performed P Sample was not properly preserved upon receipt. G LCS or MS exceeds the control limits. S Sample was analyzed by another SC certified Lab. SC Seed Correction outside the accepted range of 0.60 - 1.4 mg L. (BOD) Seed Correction outside the accepted range of 0.60 - 1.4 mg L (CBOD) SD Results reported are derived from suspect data. SS BOD results derived from supersaturated D.O. values. Sample(s) were aerated per the supersaturation procedure in Standard Methods 5210B SDF Sample Dilutions did not meet the requirement of DO depletion of at least 2.0 mg/L, or the sample dilutions did not meet the requirement of DO residual of at least 1.0 mg/L. Davis & Brown is reporting these results as valid data. T Storage Condition: Temperature above 60 C due to power outage. y Analyte detected in the associated method blank. Note: the value in the blank shall not be subtracted from the sample result. Revision 04/17 WSF Dataqual.wpd Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S 1 South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratory Clemson University S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S 11 South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016; 99006001 Note: S 1 lA indicates AES Laboratory (98016); S 11 G indicates GCAL Laboratory (73006); S 11 P indicates Pace Analytical (96042001); S 1ITS indicates Test America Savannah (98001) S 11 TP indicates Test America Pittsburg (89014) S 12 AASHTO R18 Certified S 13 South Carolina Lab Certification Number: 96012 S 14 South Carolina Lab Certification Number: 89002 S 16 South Carolina Lab Certification Number: 84004 S 17 South Carolina Lab Certification Number: 96037001 S 18 South Carolina Lab Certification Number: 95005 S 19 South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S26 . North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 S29 South Carolina Lab Certification Number: 32566 S30 Galbraith Laboratories, Inc. Knoxville TN Revision 08/17 Dataqual (SubLabs)p2.ivpd joDAVIS & BROWN Florence, SCr 9501 FAX, • 843--666-2208 PAGE All ! OF REGULATORY: ff: NO CHA/A( OF CUSTODY RECORD TURNAROUND TIME: P I _STANDARD RUSH R2 CLIENT: SAMPLE ANA4YSIS REOL ESTEC ¢ C uSE CODES TO INDIC 1.47E IF SAMPLE WAS FILTERED OR PRESERVED: A - HNO, 8 - HCL 0 - HAOA F - FILTRATION C - NAOH E = NA2S-0t G - ZINCACETATE Preservative 5 U L'ai, a w Z L °* i IO- N Q► +t cc -Q, 1DDRESS: �`RGGRAMAREA; D = DRINKING WATER G=GROUNDWATER S-SOLID SL-SLUDGE W - WASTEWATER O-OTHER PLEASE PRINT LEGIBLY -HONE: FAX: SAMPLE ID DATE TIME INITIAL NOTES LA8 ID p (�lOSO C[ efS - Fill in the Numoerof Containers for EACH Test I i I i i I :AMPLER SIGNATURE --• ' FLOW INFO ICE ICE Y S NO PACK RECEIPT ,-., r-MP: $iLoc IaGnquisf:ed bv: Date:Time: Rednqu d C Date: Time:qse 'ec ad Dator `` 'itme ad ny n at.. �, 1J Tirt:a: I'f(C` Received ny: DateTme ommems: A N I M A L WASTE ANALYS IS R E P O R T Agricultural Service Laboratory LAB No. 50790 Clemson University TURNER, SHERRY ACCOUNT COMRLBR PO BOX 219 DATE 06/04/2018 CHERAW SC 29520 STOLSON@CHERAW.COM SAMPLE NO. 05161850 MANURE: OTHER STORAGE: COVERED -----------------RESULTS REPORTED ON AN AS -SAMPLED BASIS---------------------- lbs/ton Ammonium Nitrogen 0.06 % 1.20 Organic Nitrogen 0.84 % 16.89 Nitrate Nitrogen --------------------------------------------------------------- 38.33 ppm 0.08 INCORPORATED AVAILABLE NITROGEN ESTIMATE 11.22 SURFACE AVAILABLE NITROGEN ESTIMATE 10.86 --------------------------------------------------------------- Phosphorus as P205 0.49 % 9.79 Potassium as K20 0.21 % 4.24 Calcium 21.65 % 432.98 Magnesium 0.14 % 2.77 Sulfur 0.20 % 4.02 Zinc 199.84 ppm 0.40 Copper 33.93 ppm 0.07 Manganese 40.22 ppm 0.08 Sodium 382.71 ppm 0.77 Moisture 37.16 % Calcium Carbonate Equivalency 46.07 % 921.39 ------------------------------------------------------------------------------ INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - 80% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be incorporated into the soil within hours of application. Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. Available nitrogen calculations are estimates and if nitrate-N was not re- quested the amount of available nitrogen may be slightly more than reported. Also, the actual amount may be more or less than the estimate depending on the composition of the manure, soil type, and environmental conditions. All of the potash in the animal waste should be plant available in the first year of application. Although not all of the phosphorous is available in the first year, its availability should be comparable to that in commercial fertilizers. The rate of animal waste to apply for crop production is dependent on the nutrient content of the waste, method of application and incorporation, soil test, crop to be grown, and previous manure applications. In most cases, the plant available nitrogen content of the waste is used to determine the rate of % moisture % solids Ibs. solids/ton Ibs. solids/500 tons 37.16 62.84 1256.8 628400 % ppm Ibs/ton % ppm Ibs/ton as -sampled as -sampled as -sampled dry ton dry ton dry Ammonium Nitrogen 0.06 600 1.2 0.095481 954.8059 1.909612 Organic Nitrogen 0.8445 8445 16.89 1.343889 13438.89 26.87778 Nitrate Nitrogen 0.003833 38.33 0.07666 0.006100 60.99618 0.121992 Incorporated Available Nitrogen Estimate 0.561 5610 11.22 0.892743 8927.435 17.85487 Surface Available Nitrogen Estimate 0.543 5430 10.86 0.864099 8640.993 17.28199 Phosphorus as P2O5 0.4895 4895 9.79 0.778962 7789.624 15.57925 Potassium as K2O 0.212 2120 4.24 0.337365 3373.647 6.747295 Calcium 21.649 216490 432.98 34.45099 344509.9 689.0197 Magnesium 0.1385 1385 2.77 0.220401 2204.01 4.40802 Sulfur 0.201 2010 4.02 0.31986 3198.6 6.397199 Zinc 0.019984 199.84 0.39968 0.031801 318.014 0.636028 Copper 0.003393 33.93 0.06786 0.005399 53.99427 0.107989 Manganese 0.004022 40.22 0.08044 0.0064 64.00382 0.128008 Sodium 0.038271 382.71 0.76542 0.060902 609.0229 1.218046 Calcium Carbonate Equivalency 46.0695 460695 921.39 73.31238 733123.8 1466.248 May 2018 CHERAW ALKALINE BIOSOLIDS SOILAMENDMENT CHEMICAL CHARACTERISTICS AND LAND APPLICATION RATES BIOSOLIDS SAMPLE DATE: July 18, 2018 METALS Biosolids Metal Content, ppm Maximum Allowable Metal Content, ppm Maximum Allowable App. Rate, #/Acre/Yr. Maximum Application Rate, DT/Acre/Yr. Maximum Application Rate, WT/Acre/Yr. Arsenic, Total 2.15 41.00 1.80 260.93 419.23 Cadmium, Total 1.03 ' 39.00 1.70 512.68 823.72 Chromium, Total 38.79 1200.00 134.00 1075.11 1727.37 Copper, Total 28.21 1500.00 67.00 739.14 1187.57 Lead, Total 1.03 ' 300.00 13.00 3920.50 6299.01 Mercury, Total 0.03 ' 17.00 0.75 7760.41 12468.52 Molybdenum, Total 4.13 ' 18.00 0.80 60.32 96.91 Nickel, Total 13.38 420.00 18.70 434.98 698.88 Selenium, Total 1.03 ' 36.00 4.50 1357.10 2180.43 PCB BRL 1.60 Actual metal content less than amount indicated Biosolids Biosolids Nutrient Nutrient Content, Content, ppm % Crop/Soil Requirement, #/Acre "" Maximum Application Rate, DT/Acre/Yr. Maximum Application Rate, WT/Acre/Yr. Ammonium Nitrogen 0.00 0.00 Organic Nitrogen 6695.00 0.67 Incorporated Available Nitrogen 4160.00 0.42 120.00 8.98 14.42 Surface Available Nitrogen 4160.00 0.42 120.00 8.98 14.42 Phosphorus as P2O5 4275.00 0.43 80.00 5.82 9.36 Potassium as K2O 1575.00 0.16 50.00 9.88 15.87 Calcium, Total 245590.00 24.56 Calcium as CaO 343826.00 34.38 Calcium as CaCO3 (CCE) 490685.00 49.07 2000.00 1.27 2.04 Magnesium, Total 1555.00 0.16 Manganese 45.00 0.00 Sodium 118875.00 11.89 Percent Moisture 37.76 " These are typical values and must be adjusted based upon specific site conditions DT is Dry Tons of Biosolids. WT is Wet Tons of Biosolids. CERTIFICATION: This biosolid product has been produced by the Town of Cheraw's Wastewater Treatment Plant by a treatment process that pasteurized plant residual solids using high temperature and lime (calcium oxide). The Town of Cheraw certifies that this biosolid complies with the Environmental Protection Agency regulations 40 CFR Part 503 for a "Class A" product and has a metal and nutrient content as presented above. DIRECTIONS FOR USE: This biosolid is intneded to be used as a soil amendment. The biosolid land application rate shall not exceed the most restrictive Maximum Application Rate as indicated in the table above. The application rate for nitrogen, phosphorus, potassium, and calcium is dependent upon the crop grown and site soil characteristics. The user should contact the Clemson Extension Service (843-623-2134) and/or the Soil Conservation Service (843-623-2187) for assistance in determining the proper application rate for each crop and site. In no case shall the land application rate exceed the agronomic rate for the crop grown. User should also refer to the Clemson Extension Service Circular #476 titled "Lime and Fertilizer Recommendations.' THIS PRODUCT IS HIGHLY ALKALINE AND SHOULD BE HANDLED ACCORDINGLY. AVOID PROLONGED CONTACT WITH THE SKIN. AVOID CONTACT WITH THE EYES. THE TOWN OF CHERAW IS NOT RESPONSIBLE FOR IMPROPER USE OR HANDLING OF THIS BIOSOLID PRODUCT. Mr. Ricky D. Ingram, Public Utility Director P.O. Box 219; Cheraw, SC 29520 Telephone: 843-537-8440 FAX: 843-537-8442 PRODUCT USER NAME: QUANTITY RECEIVED: RECEIVED BY: Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Receipt Date: 19-Jul-18 Client #: 168 Report Date: 03-Aug-18 Sample Date: 18-Jul-18 Approved 8y:i SDG #: SDG-126403 Van Ward Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst LSID-278872 SOURCE WATER Total Organic Carbon 3.8 0.5 mg/L SM 531OB-2011 7/25/2018 13:08 SF LSID-278873 FINISHED WATER Total Organic Carbon 1.8 0.5 mg/L SM 5310B-2011 7/25/2018 13:08 SF LSID-278874 7-18-18-001INF Biochemical Oxygen Demand 319 2 mg/L SM 5210B 7/19/2018 11:05 AE LSID-278875 7-18-18-002 EFF Biochemical Oxygen Demand 16.9 2 mg/L SM 5210B 7/19/2018 11:05 AE LSID-278876 7-18-18-500 BIO Acid Digestion (Solids) YES EPA 200.2 7/23/2018 11:00 AE Selenium, Total <0.995 0.995 mg/kg EPA 7010 / 601OD 7/24/2018 11:51 AE Percent Moisture 35.3 0.1 wt% SW846 3540 7/23/2018 11:32 ML Aluminum, Total 5110 39.8 mg/kg SW846 601OD 7/25/2018 14:19 JR Arsenic, Total 2.07 0.995 mg/kg SW846 601OD 7/24/2018 11:51 AE Cadmium, Total <0.995 0.995 mg/kg SW846 6010D 7/23/2018 15:01 AE Chromium, Total 37.4 0.995 mg/kg SW846 6010D 7/23/2018 15:01 AE Page 1 Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Receipt Date: 19-Jul-18 Client #: 168 Report Date: 03-Aug-18 Sample Date: 18-Jul-18 Approved By: SDG #: SDG-126403 Van Ward Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst Copper, Total 27.2 0.995 mg/kg SW846 6010D 7/23/2018 15:01 AE Lead, Total <0.995 0.995 mg/kg SW846 601OD 7/23/2018 15:01 AE Molybdenum, Total <3.98 3.98 mg/kg SW846 601OD 7/24/2018 16:42 JR Nickel, Total 12.9 0.995 mg/kg SW846 601OD 7/23/2018 15:01 AE Mercury, Total <0.029 0.029 mg/kg SW846 7470A 7/25/2018 13:00 CG PCB BRL mg/kg SW846 8082A S L lA 7/27/2018 12:14 UH Page 2 Zy. ANALYTICAL,, INC. ANALYTICAL REPORT CLIENT Davis & Brown P.O. Box 15038 Quinby SC 29506 ATTENTION Scott Fields PROJECT ID 278876 LABORATORY REPORT NUMBER 1807K84 DATE July 31, 2018 Primary Data Review By Secondary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: Ashley Amick Project Manager, Access Analytical aamick@axs-inc.com Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 4 0 la.DAVIS & BROWN 124 W. Mcfver Road PH: $43-665-6746 PAGE # ( OF i Florence, SC 29601 FAX'' 843-65&2208 REGULATORY: YES NO CHA/N OF CUSTODY RECORD TURNAROUND TIME: P1 _STANDARD RUSH _py CLIENT: 'I V5 a a/� iW� , SAMPLE ANALYSIS REQUESTED Q Lu Q O nm. USE CODES TO INDICTATE IF SAMPLE WAS FILTERED OR PRESERVED: A=KIND, B = HCL D - H,90, F - FILTRATION C - NAOH E - NANO, G = ZINCACETATE pBaervatwe a E U0 12 (1) Li w ¢ * J ADDRESS: PROGRAMAREA: 0=DRINKING WATER G = GROUNDWATER S = SOLID SL= SLUDGE W m WASTEWATER 0-OTHER PLEASE PRINT LEGIBLY PHONE: FAX: SAMPLE ID DATE TIME INITIAL NOTES LAB ID tit) V � � FlII in the Number of Containers for EACH Test S 'tr tat trQ_ SAMPLER SIGNATURE FLOW INFO ICE YES NO PACK RECEIPT TEMP: YO C Ra9nqu" b : Oele; T.ma: r8 Ib Relinqutshed b/ Dale: Time: Relinquished by. Date: Time: RecewWd by. Date: Time: R ived by Date: +^ Time: ReceNed by: Date: - Time; Comments: ISSUED: NOVEMBER 2012 Page 2 of 4 Analytical Environmental Services, Inc Date: 31-Jul-18 Client: Davis & Brown Client Sample ID: 278876 Project Name: 278876 Collection Date: `'-' 7/18/2018 10:10:00 AM Lab ID: 1807K84-001 Matrix: Solid Analyses Result Reporting Limit Qual Units BatchID Dilution Factor Date Analyzed Analyst POLYCHLORINATED BIPHENYLS SW8082A (SW3550C) Aroclor 1016 BRL 53 ❑g/Kg-dry 264518 1 07/27/2018 12:14 UH Aroclor 1221 BRL 53 ug/Kg-dry 264518 1 07/27/2018 12:14 UH Aroclor 1232 BRL 53 ug/K. dry 264518 1 07/27/2018 12:14 UH Aroclor 1242 BRL 53 ug/Ko dry 264518 1 07/27/2018 12:14 UH Aroclor 1248 BRL 53 ug/Ko dry 264518 1 07/27/2018 12:14 UH Aroclor 1254 BRL 53 ug/Ko dry 264518 1 07/27/2018 12:14 UH Aroclor 1260 BRL 53 ug/Ko dry 264518 1 07/27/2018 12:14 UH Surr: Decachlorobiphenyl 50.4 45.6-131 %REC 264518 1 07/27/2018 12:14 UH Surr: Tetrachloro-m-xylene 65.9 47.1-130 %REC 264518 1 07/27/2018 12:14 UH PERCENT MOISTURE D2216 Percent Moisture 37.1 0 wt%. R376252 1 07/27/2018 11:05 SA Qualifiers: ' Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 3 of 4 efl 1 li.Yni.7MCAf. ' FF ENvrxaNntr+N. SAMPLE/COOLER RECEIPT CHECKLIST A$S .rl'RI"T M%1tYC. 1. client Name: Access Analytical, Inc. AES Work Order Number: 1807K84 2. Carrier: FeclEx FE I UPS F- USPS I^ Client Courier0 Othel ri-il. 3. 4. S. 6. 7. 8. 9. 10. 11. 12. Comments Shipping container/cooler received in good condition? damaged ❑ leaking other _ Custody seals present on shipping container? • Custody seals intact on shipping container? I • Temperature blanks present? • Cooler temperature(s) within limits of 0-eC? [See item 13 and 14 for temperature recordings.] Q Q O Cooling initiated for recently collected samples / ice present Chain of Custody (CDC) present? • Chain of Custody signed, dated, and timed when relinquished and received? • Sampler name and/or signature on COC? • Were all samples received within holding time? • TAT marked on the COC? 1 01 U I If no TAT indicated, proceeded with standard TAT per Terms & Conditions. �. 13. Cooler 1 Temperature 4.1 14. Cooler 5 Temperature 15. Comments: 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. °C Cooler 2 Temperature °C Cooler 3 Temperature °C Cooler 4 Temperature °C °C Cooler 6 Temperature °C Cooler 7 Temperature °C Cooler 8 Temperature °C I certify that I have completed sections 1-15 (dated Initials). Ml 7/24/18 Were sample containers intact upon receipt? • Custody seals present on sample containers? Custody seals intact on sample containers? 0• Do sample container labels match the COC? Q O O incomplete info L illegible no label F7 other I^] Are analyses requested indicated on the COC? • Were all of the samples listed on the CDC received? Q Q © samples received but not listed on COC L] samples listed on COC not received ❑ Was the sample collection date/time noted? • Did we receive sufficient sample volume for indicated analyses? • Were samples received in appropriate containers? • Were VOA samples received without headspace (< 1/4" bubble)? Were trip blanks submitted? I on histedonCOC not listed on COC 27. Comments: This section only applies to samples where pH can be I certify that I have completed sections 16-27 (dated initials). MH 7/24/18 checked at Sample Receipt. Yes No N/A Details Comments 28. Have containers needing chemical preserv 29. Containers meet preserv 30. Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms. VOCs and Oil & Grease/TPH. I certify that I have completed sections 28-30 (dated Initials Checklist 6.9.17 Rev 2 Locked MH 7/24/18 Page 4 of 4 ation been checked? ation guidelines? Was pH adjusted at Sample Receipt? ' • DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S 1 South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratory Clemson University S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S11 South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016; 99006001 Note: S 11 A indicates AES Laboratory (98016); S 11 G indicates GCAL Laboratory (73006); S11P indicates Pace Analytical (96042001); S11TS indicates Test America Savannah (98001) S 11 TP indicates Test America Pittsburg (89014) S 12 AASHTO R18 Certified S 13 South Carolina Lab Certification Number: 96012 S 14 South Carolina Lab Certification Number: 89002 S 16 South Carolina Lab Certification Number: 84004 S 17 South Carolina Lab Certification Number: 96037001 S 18 South Carolina Lab Certification Number: 95005 S19 South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S26 North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification- Number: 32571 S29 South Carolina Lab Certification Number: 32566 S30 Galbraith Laboratories, Inc. Knoxville TN ReN9sion 08(17 Dataqual (SubLabs)p2 .wpd v `A' 124 F✓, McIver Road PH: 943•d85.6746 PAGE # _ _ OFIn f DAVIS BROWN YY Florence, SC 29501 843-65&2208 FAX: �?' _I_ o CHAIR► OF CUSTODY RECORD TURNA�rouNo nMF: _PI REGULATORY: NO RUSH p2 :L1ENT: SAMPLE ANALB18 FE+31JESTED I USE COOE3 TO GROICTA TZ t+' SAMPLE WAS Preservative - � Flt -FIRED OR PRE^>ERVED. A- NNOs v i I i 1 C7 L✓"�•- `� 1. xM 8-4CL 0=Ha50, F=FILTRATION C- NAOH E- NArS,O+ G- ZINCACETATE %OGRESS: FF;OGRAMAREA: D a DRINKING WATER s E h E G =GROUNDWATER S =SOLID St = SLUDGE U U 1 i W=WASTEWATER 0-OTHER m 0 4� 4 PLEASE PRINT LEGIBLY -HONE; FAX: I ( I a C) t e SAMPLE IC DATE TIME ?AnT'AL NOTES LAB 10 Fill in the Number of Containers for EACH Test -(y-(Y (3SK 50- Cr t f'r.rer t,+u is g f3S� i sue' ( I i C 1 j j LJ i EF4 see .... ........... 7 _7 1 . ..... %AMPLER SIGNATURE FLOW iNFO ICE Y NO PACK {1 C R£CF?PT 'eligquistted bY' Date- Time: Reline st+ed by Data: 'i� e- Relingtusaed ey: Dale Tme: ecerved 'Jat� Tine R r Date: Dale. Tune amnreats: iSUEO' NC.7`JEh9k1tK LV7L CHERAW, TOWN OF PRELIMINARY 23-Jul-18 Note: Some or all results may not be finalized. Lab Sample ID LSID-276640 SDG # SDG-125389 Sample Point BIOSOLIDS-5-16-18-500 Analysis Parameter Name Method Result MDL Units Date Analysis Time Analyst Molybdenum, Total SW846 6010C <3.96 3.96 mg/kg 5/23/2018 9:19 AM JR Lead, Total SW846 6010C 0.989 0.989 mg/kg 5/21/2018 3:44 PM JR Copper, Total SW846 6010C 23.5 0.989 mg/kg 5/21/2018 3:44 PM JR Chromium, Total SW846 6010C 28.3 0.989 mg/kg 5/21/2018 3:44 PM JR Cadmium, Total SW846 6010C <0.989 0.989 mg/kg 5/21/2018 3:44 PM JR Arsenic, Total SW846 6010C <0.989 0.989 mg/kg 5/23/2018 4:24 PM JR Aluminum, Total SW846 601OC 5040 39.6 mg/kg 5/23/2018 10:27 AM JR Percent Moisture SW846 3540 36.2 0.1 wt% 5/21/2018 2:23 PM ML Acid Digestion (Solids) EPA 200.2 YES 5/21/2018 9:20 AM JR Selenium, Total EPA 7010 / 6010C <0.989 0,989 mg/kg 5/23/2018 4:24 PM JR PCB SW846 8082A BRL mg/kg 5/25/2018 3:42 PM UH Mercury, Total SW846 7470A <0.029 0.029 mg/kg 5/30/2018 12:45 PM CG Nkkel, Total SW846 6010C 11.0 0.989 mg/kg 5/21/2018 3.44 PM JR A N I M A L WASTE ANALYS IS R E P O R T Agricultural Service Laboratory LAB No. 71003 Clemson University TURNER, SHERRY ACCOUNT COMRLBR PO BOX 219 DATE 08/03/2018 CHERAW SC 29520 STOLSON@CHERAW.COM SAMPLE NO. 07181850 MANURE: OTHER STORAGE: COVERED -----------------RESULTS REPORTED ON AN AS -SAMPLED BASIS---------------------- lbs/ton Ammonium Nitrogen 0.00 % 0.00 Organic Nitrogen 0.67 % 13.39 Nitrate Nitrogen --------------------------------------------------------------- 89.00 ppm 0.18 INCORPORATED AVAILABLE NITROGEN ESTIMATE 8.32 SURFACE AVAILABLE --------------------------------------------------------------- NITROGEN ESTIMATE 8.32 Phosphorus as P205 0.43 % 8.55 Potassium as K20 0.16 % 3.15 Calcium 24.56 % 491.18 Magnesium 0.16 % 3.11 Sulfur 0.17 % 3.36 Zinc 183.60 ppm 0.37 Copper 26.14 ppm 0.05 Manganese 42.94 ppm 0.09 Sodium 237.75 ppm 0.48 Moisture 37.76 % Calcium Carbonate Equivalency 49.07 % 981.37 ------------------------------------------------------------------------------ INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - 80% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be incorporated into the soil within hours of application. Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. Available nitrogen calculations are estimates and if nitrate-N was not re- quested the amount of available nitrogen may be slightly more than reported. Also, the actual amount may be more or less than the estimate depending on the composition of the manure, soil type, and environmental conditions. All of the potash in the animal waste should be plant available in the first year of application. Although not all of the phosphorous is available in the first year, its availability should be comparable to that in commercial fertilizers. The rate of animal waste to apply for crop production is dependent on the nutrient content of the waste, method of application and incorporation, soil test, crop to be grown, and previous manure applications. In most cases, the plant available nitrogen content of the waste is used to determine the rate of % moisture % solids lbs. solids/ton lbs. solids/500 tons 37.76 62.24 1244.8 622400 % ppm lbs/ton % ppm lbs/ton as -sampled as -sampled as -sampled d ton d ton dry Ammonium Nitrogen 0 0 0 0 0 0 Organic Nitrogen 0.6695 6695 13.39 1.075675 10756.75 21.5135 Nitrate Nitrogen 0.008900 89 0.178 0.014299 142.9949 0.28599 Incorporated Available Nitrogen Estimate 0.416 4160 8.32 0.66838 6683.805 13.36761 Surface Available Nitrogen Estimate 0.416 4160 8.32 0.66838 6683.805 13.36761 Phosphorus as P2O5 0.4275 4275 8.55 0.686857 6868.573 13.73715 Potassium as K2O 0.1575 1575 3.15 0.253053 2530.527 5.061054 Calcium 24.559 245590 491.18 39,45855 394585.5 789.171 Magnesium 0.1555 1555 3.11 0.249839 2498.393 4.996787 Sulfur 0.168 1680 3.36 0.269923 2699.229 5.398458 Zinc 0.01836 183.6 0.3672 0.029499 294.9871 0.589974 Copper 0.002614 26.14 0.05228 0.0042 41.99871 0.083997 Manganese 0.004294 42.94 0.08588 0.006899 68.991 0.137982 Sodium 0.023775 237.75 0.4755 0.038199 381.9891 0.763978 Calcium Carbonate Equivalency 49.0685 490685 981.37 78.83756 788375.6 1576.751 July 2018 CHERAW ALKALINE BIOSOLIDS SOIL AMENDMENT CHEMICAL CHARACTERISTICS AND LAND APPLICATION RATES BIOSOLIDS SAMPLE DATE: September 19, 2018 METALS Biosolids Metal Content, ppm Maximum Allowable Metal Content, ppm Maximum Maximum Allowable Application App. Rate, Rate, #/Acre/Yr. DT/Acre/Yr. Maximum Application Rate, WT/Acre/Yr. Arsenic, Total 0.94 ' 41.00 1.80 675.67 962.49 Cadmium, Total 0.94 ' 39.00 1.70 638.13 909.02 Chromium, Total 35.52 1200.00 134.00 1324.02 1886.07 Copper, Total 26.78 1500.00 67.00 878.04 1250.76 Lead, Total 1.38 300.00 13.00 3303.00 4705.13 Mercury, Total 0.02 17.00 0.75 12179.13 17349.19 Molybdenum, Total 3.74 " 18.00 0.80 75.07 106.94 Nickel, Total 12.69 420.00 18.70 517.36 736.98 Selenium, Total 0.94 ' 36.00 4.50 1689.17 2406.22 PCB BRL 1.60 * Actual metal content less than amount indicated Biosolids Biosolids Maximum Maximum Nutrient Nutrient Crop/Soil Application Application Content, Content, Requirement, Rate, Rate, ppm % #/Acre" DT/Acre/Yr. WT/Acre/Yr. Ammonium Nitrogen 200.00 0.02 Organic Nitrogen 10115.00 1.01 Incorporated Available Nitrogen 6330.00 0.63 120.00 6.65 9.48 Surface Available Nitrogen 6270.00 0.63 120.00 6.72 9.57 Phosphorus as P2O5 6430.00 0.64 80.00 4.37 6.22 Potassium as K2O 3045.00 0.30 50.00 5.76 8.21 Calcium, Total 182305.00 18.23 Calcium as CaO 255227.00 25.52 Calcium as CaCO3 (CCE) 4230.00 0.42 2000.00 165.96 236.41 Magnesium, Total 1685.00 0.17 Manganese 55.00 0.01 Sodium 530.00 0.05 Percent Moisture 29.80 These are typical values and must be adjusted based upon specific site conditions DT is Dry Tons of Biosolids. WT is Wet Tons of Biosolids. CERTIFICATION: This biosolid product has been produced by the Town of Cheraw s Wastewater Treatment Plant by a treatment process that pasteurized plant residual solids using high temperature and lime (calcium oxide). The Town of Cheraw certifies that this biosolid complies with the Environmental Protection Agency regulations 40 CFR Part 503 for a "Class A" product and has a metal and nutrient content as presented above. DIRECTIONS FOR USE: This biosolid is intneded to be used as a soil amendment. The biosolid land application rate shall not exceed the most restrictive Maximum Application Rate as indicated in the table above. The application rate for nitrogen, phosphorus, potassium, and calcium is dependent upon the crop grown and site soil characteristics. The user should contact the Clemson Extension Service (843-623-2134) and/or the Soil Conservation Service (843-623-2187) for assistance in determining the proper application rate for each crop and site. In no case shall the land application rate exceed the agronomic rate for the crop grown. User should also refer to the Clemson Extension Service Circular #476 titled 'Lime and Fertilizer Recommendations.' THIS PRODUCT IS HIGHLY ALKALINE AND SHOULD BE HANDLED ACCORDINGLY. AVOID PROLONGED CONTACT WITH THE SKIN. AVOID CONTACT WITH THE EYES. THE TOWN OF CHERAW IS NOT RESPONSIBLE FOR IMPROPER USE OR HANDLING OF THIS BIOSOLID PRODUCT. Mr. Ricky D. Ingram, Public Utility Director P. 0. Box 219; Cheraw, SC 29520 Telephone: 843-537-8440 FAX: 843-537-8442 PRODUCT USER NAME: ADDRESS: LOCATION OF USE: QUANTITY RECEIVED: Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Receipt Date: 20-Sep-18 Client #: 168 Report Date: 04-Oct-18 Sample Date: 20-Sep-18;r 4 SDG #: SDG-127338 Approved By: Van Ward Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst LSID-281005 9-19-18-040-BIOSOLIDS Acid Digestion (Solids) YES EPA 200.2 9/21/2018 9:30 JR Selenium, Total <0.995 0.995 mg/kg EPA 7010 / 6010D 9/24/2018 12:52 AE Percent Moisture 28.6 0.1 wt% SW846 3540 9/20/2018 16:30 NIL Aluminum, Total 6420 19.9 mg/kg SW846 6010D 9/25/2018 17:01 JR Arsenic, Total <0.995 0.995 mg/kg SW846 601OD 9/24/2018 12:52 AE Cadmium, Total <0.995 0.995 mg/kg SW846 6010D 9/24/2018 12:56 JR Chromium, Total 37.8 0.995 mg/kg SW846 6010D 9/24/2018 12:56 JR Copper, Total 28.5 0.995 mg/kg SW846 6010D 9/24/2018 12:56 JR Lead, Total 1.47 0.995 mg/kg SW846 601OD 9/24/2018 12:56 JR Molybdenum, Total <3.98 3.98 mg/kg SW846 6010D 9/25/2018 16:36 JR Nickel, Total 13.5 0.995 mg/kg SW846 6010D 9/24/2018 12:56 JR Mercury, Total <0.023 0.023 mg/kg SW846 7470A 9/26/2018 12:30 CG PCB BRL mg/kg SW846 8082A S11A 9/27/2018 19:20 UH LSID-281006 9-19-18-001INF Biochemical Oxygen Demand <100 2 mg/L SM 5210B SDF 9/20/2018 10:50 AE LSID-281007 9-19-18-002 EFF Biochemical Oxygen Demand <2.0 2 mg/L SM 5210B 9/20/2018 10:50 AE Page 1 ACCESS AnsALYnCAL, INC. ANALYTICAL REPORT CLIENT Davis & Brown P.O. Box 15038 Quinby SC 29506 ATTENTION Scott Fields PROJECT ID 281005 LABORATORY REPORT NUMBER 1809K85 DATE October 04, 2018 Primary Data Review By Secondary Data Review By Ashley Amick Chris Pafford Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCNI Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 4 In V' S & BROWN 124 W. McIver Road PH: 843-665-6746 PAGE # OF DAVIS CJ Pi +13 BROWN Y 9 �Y Florence, SC 29501 FAX: 843-656-2206 REGULATORY: YES NO HAIN OF CUSTODY RECORDTURNAROUND TIME —STANDARD RUSH Pz CLIENT. i �' ;�5'(�')/'�y�h 1 a V s J —"" SAMPLEAN,ALYSIS REQUESTED < Q < o G USE CODES TO INDICTATE IF SANIPLE WAS FILTERED OR PRESERVED: A = HNOs S= HCL D= H=SGa F=FILTRATION C = NAOH E = NA,S,O� G = ZINCACETATE Preservative a UZ a a.a. W Z F p 4 i� f I ADDRESS: P,ROGRAMAREA: D=DRINKINGWATER G=GROUNDWATER S:SOLID SL=SLUDGE W c WASTEWATER O=OTHER PLEASE PRINT LEGIBLY SHADED AREAS FOR LAB USE ONLY PHONE: FAX SAMPLE.ID_ DATE TIME INITIAL NOTES 1.A8 {0 0015 nyt,{� l ��"1tU y& 1 t Fill In the Number I of Containers forEACH Test j I I I SAMPLER SIGNATURE { FLOW INFO ICE YES NO PACK RECElP7 TEMP: C Relin by Data: Time: Re„nquished by Date: Time: Relinquished by: Date: Time: R Date: Time: Received by Date: Tme: R Commen'.s: t f ISSUED: NOVEMBER 2012 Page 2 of 4 Analytical Environmental Services, Inc Date: 4-Oct-18 Client: Davis & Brown Client Sample ID: 281005 Project Name: 281005 Collection Date: 9/20/2018 8:20:00 AM Lab ID: 1809K85-001 Matrix: Solid Analyses Result Reporting Qual Limit Units BatchlD uuut►on Factor Date Analyzed Analyst POLYCHLORINATED BIPHENYLS SW8082A (SW3550C) Aroclor 1016 BRL 46 ug/Kg-dry 267792 1 09/27/2018 19:20 UH Aroclor 1221 BRL 46 ug/Kg-dry 267792 1 09/27/2018 19:20 UH Aroclor 1232 BRL 46 ug/Kg-dry 267792 1 09/27/2018 19:20 UH Aroclor 1242 BRL 46 ug/Kg-dry 267792 1 09/27/2018 19:20 UH Aroclor 1248 BRL 46 ug/Kg-dry 267792 1 09/27/2018 19:20 UH Aroclor 1254 BRL 46 ug/Kg-dry 267792 1 09/27/2018 19:20 UH Aroclor 1260 BRL 46 ug/Kg-dry 267792 1 09/27/2018 19:20 UH Surr: Decachlorobiphenyl 58.7 45.6-131 /oREC 267792 1 09/27/2018 19:20 UH Surr: Tetrachloro-m-xylene 76.9 47.1-130 %REC 267792 1 09/27/2018 19:20 UH PERCENT MOISTURE D2216 Percent Moisture 28.0 0 wt% R381376 1 10/02/2018 17:00 CG Qualifiers: • Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N knalyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value ! Estimated value detected below Reporting Limit Page 3 of 4 XVIRONNIT-Tdt. AES S@RVtCP>4, WC. 1. Client Name: Access Analytical, Inc. 2. Carrier: Fed Ex ❑• UPS ❑ USPS❑ Client❑ Courier❑ Othei 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. SAMPLE/COOLER RECEIPT CHECKLIST AES Work Order Number: 18091<85 Vec N. N/C rl-ilc Shipping container/cooler received in good condition? ® damaged ❑ leaking r 1 other❑ Custody seals present on shipping container? G' Custody seals intact on shipping container? Temperature blanks present? Cooler temperature(s) within limits of 0-6°C? (See item 13 and 14 for temperature recordings.) ® ® Coaling initiated for recently collected samples / ice present ❑ Chain of Custody (CDC) present? • Chain of Custody signed, dated, and timed when relinquished and received? • Sampler name and/or signature on COC? o Were all samples received within holding time? • TAT marked on the COC? • If no TAT indicated, proceeded with standard TAT per Terms & Conditions. U 13. Cooler 1 Temperature -9.6 14. Cooler 5 Temperature 15. Comments: 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. °C Cooler 2 Temperature °C Cooler 3 Temperature °C Cooler 4 Temperature °C °C Cooler 6 Temperature °C Cooler 7 Temperature °C Cooler 8 Temperature °C I certify that I have completed sections 1-15 (dated initials). Aff 9/25/18 Vaa run N/C rl-ik r,......,e..�� Were sample containers intact upon receipt? • Custody seals present on sample containers? Custody seals intact on sample containers? v Do sample container labels match the COC. ®° ® ® incomplete info ❑ illegible ❑ no label ❑ other ❑ Are analyses requested indicated on the COC? • Were all of the samples listed on the COC received? ®° ® ® samples received but not listed on CDC ❑ samples listed on CDC not received ❑ Was the sample collection date/time noted? • Did we receive sufficient sample volume for indicated analyses? ' Were samples received in appropriate containers? Were VOA samples received without headspace (< 1/4" bubble)? Were trip blanks submitted? listed on CDC ❑ not listed on CDC ❑ 27. Comments: This section only applies to samples where pH can be I certify that I have completed sections 16-27 (dated initials). AP 9/25/18 checked at Sample Receipt. Yes No N/A Details Comments ' 28. Have containers needing chemical preserv 29. Containers meet preserv 30. lWas Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & GreasefrPH. I certify that I have completed sections 28-30 (dated initials 1 Checklist 6.9.17 Rev >..,_., Lacked. a. f AP 9/25/18 Page 4 of 4 ation been checked? ation guidelines? pH adjusted at Sample Receipt? " m DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S 1 South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratory Clemson University S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S11 South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016; 99006001 Note: S11A indicates AES Laboratory (98016); S11G indicates GCAL Laboratory (73006); S 11 P indicates Pace Analytical (96042001); S 11 TS indicates Test America Savannah (98001) S11TP indicates Test America Pittsburg89014 S 12 AASHTO R18 Certified S 13 South Carolina Lab Certification Number: 96012 S 14 South Carolina Lab Certification Number: 89002 S 16 South Carolina Lab Certification Number: 84004 S 17 South Carolina Lab Certification Number: 96037001 S 18 South Carolina Lab Certification Number: 95005 S 19 South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S26 North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 S29 South Carolina Lab Certification Number: 32566 S30 Galbraith Laboratories, Inc. Knoxville TN S31 South Carolina Lab Certification Number: 32576 Revision 08118 Da1aqua1(SubLabs)p2.wpd 124 W. Road PH: 643-665-6746 ®A V i S & BROWN Floren eoSCr 9501 FAX: 843-656- 208 k1q b2 f # _ OF REGULATORY: NO CH,4IAl .oF .CUSTODY -'RECORD TURNAROUND TIME: _PT _STANDARD' RUSH _PZ CLIENT: �— !, �. •�; ^. r%Cl U—) SAMPLE ANALYSIS REQUESTED o a USE CODES TO INOICTATE IF SAMPLE WAS FILTERED OR PRESERVED: A=HNO3 S-HCL 0=H1SO, F-FILTRATION C=NAOH E=NAiSsq G=LNCACETATE Pre'setyetiiie""' -;::6;> :::`1!_!- rP:') ':t'": "' `.' : -. '" ^ s=.j':i •-'"" (..aa ^::::::: "' ` ,..... `"'"' "' " ; .;:...: •-'. "•-' ' "" �f`. ''.. ` " :..f r o a Z z Z U 0 J r ,� ADDRESS: PROGRAM AREA: D = DRINKING WATER G=GROUNDWATER S=SOLID SL-SLUDGE W=WASTEWATER O=OTHER PLEASE PRINT LEGIBLY PHONE: FAX: SAMPLE ID - DATE TIME INITIAL NOTES LAB 10 - - _ - Fill JJ,,�� �rF [.., _ ....:.gig. G ...i..::. oo . SAMPLER SIGNATURE li�J1%L•r/!'--' FLOW INFO I ICE YE NO PACK RECEIPT TEMP: -Do Retiltqu� ed by: _. /y� cXlkr— Date: ,may Time: ` ` Received Cd-r_Uf�A' lie" (70at lv Timel: J-_5� �, `;n 7�5 Rel' fished by /} Date: �� T,� :, ed 6y / D(ralt : Tune: -P9.� -wits Iur ReGnqulshed Cy: Date: Tlme: Received by: Date: Time: Comments: ISSUED: 'NDV A N I M A L WASTE ANALYSI S R E P O R T Agricultural Service Laboratory LAB No. 91186 Clemson University TURNER, SHERRY PO BOX 219 CHERAW SC29520 ACCOUNT COMRLBR DATE 10/05/2018 STOLSON@CHERAW.COM SAMPLE NO. 091918 MANURE: OTHER STORAGE: COVERED -----------------RESULTS REPORTED ON AN AS -SAMPLED BASIS---------------------- lbs/ton Ammonium Nitrogen 0.02 % 0.40 Organic Nitrogen 1.01 % 20.23 Nitrate Nitrogen --------------------------------------------------------------- 61.77 ppm 0.12 INCORPORATED AVAILABLE NITROGEN ESTIMATE 12.66 SURFACE AVAILABLE --------------------------------------------------------------- NITROGEN ESTIMATE 12.54 Phosphorus as P2O5 0.64 % 12.86 Potassium as K2O 0.30 % 6.09 Calcium 18.23 % 364.61 Magnesium 0.17 % 3.37 Sulfur 0.25 % 4.91 Zinc 246.39 ppm 0.49 Copper 44.93 ppm 0.09 Manganese 56.86 ppm 0.11 Sodium 528.59 ppm 1.06 Moisture 29.80 % Calcium Carbonate Equivalency 0.42 % 8.46 ------------------------------------------------------------------------------ INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - 80% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be incorporated into the soil within hours of application. Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. Available nitrogen calculations are estimates and if nitrate-N was not re- quested the amount of available nitrogen may be slightly more than reported. Also, the actual amount may be more or less than the estimate depending on the composition of the manure, soil type, and environmental conditions. All of the potash in the animal waste should be plant available in the first year of application. Although not all of the phosphorous is available in the first year, its availability should be comparable to that in commercial fertilizers. The rate of animal waste to apply for crop production is dependent on the nutrient content of the waste, method of application and incorporation, soil test, crop to be grown, and previous manure applications. In most cases, the plant available nitrogen content of the waste is used to determine the rate of % moisture % solids lbs. solids/ton lbs. solids/500 tons 29.8 70.2 1404 702000 % ppm lbs/ton % ppm lbs/ton as -sampled as -sampled as -sampled dry ton dry ton dry Ammonium Nitrogen 0.02 200 0.4 0.02849 284.9003 0.569801 Organic Nitrogen 1.0115 10115 20.23 1.440883 14408.83 28.81766 Nitrate Nitrogen 0.006177 61.77 0.12354 0.008799 87.99145 0.175983 Incorporated Available Nitrogen Estimate 0.633 6330 12.66 0.901709 9017.094 18.03419 Surface Available Nitrogen Estimate 0.627 6270 12.54 0.893162 8931.624 17.86325 Phosphorus as P2O5 0.643 6430 12.86 0.915954 9159.544 18.31909 Potassium as K2O 0.3045 3045 6.09 0.433761 4337.607 8.675214 Calcium 18.2305 182305 364.61 25.96937 259693.7 519.3875 Magnesium 0.1685 1685 3.37 0.240028 2400.285 4.80057 Sulfur 0.2455 2455 4.91 0.349715 3497.151 6.994302 Zinc 0.024639 246.39 0.49278 0.035098 350.9829 0.701966 Copper 0.004493 44.93 0.08986 0.0064 64.00285 0.128006 Manganese 0.005686 56.86 0.11372 0.0081 80.99715 0.161994 Sodium 0.052859 528.59 1.05718 0.075298 752.9772 1.505954 Calcium Carbonate Equivalency 0.423 4230 8.46 0.602564 6025.641 12.05128 September 2018 CHERAW ALKALINE BIOSOLIDS SOIL AMENDMENT CHEMICAL CHARACTERISTICS AND LAND APPLICATION RATES BIOSOLIDS SAMPLE DATE: November 20, 2018 METALS Biosolids Metal Content, ppm Maximum Allowable Metal Content, ppm Maximum Maximum Allowable Application App. Rate, Rate, #/Acre/Yr. DT/Acre/Yr. Maximum Application Rate, WT/Acre/Yr. Arsenic, Total 0.92 ' 41.00 1.80 673.44 979.26 Cadmium, Total 0.92 ' 39.00 1.70 636.02 924.86 Chromium, Total 53.89 1200.00 134.00 855.01 1243.29 Copper, Total 28.51 1500.00 67.00 807.99 1174.91 Lead, Total 0.92 ' 300.00 13.00 4863.71 7072.44 Mercury, Total 0.02 ' 17.00 0.75 10436.12 15175.40 Molybdenum, Total 3.68 18.00 0.80 74.79 108.75 Nickel, Total 13.78 420.00 18.70 466.58 678.46 Selenium, Total 0.92 ' 36.00 4.50 1683.59 2448.15 PCB BRL 1.60 ' Actual metal content less than amount indicated Biosolids Biosolids Nutrient Nutrient Content, Content, ppm % Crop/Soil Requirement, #/Acre" Maximum Application Rate, DT/Acre/Yr. Maximum Application Rate, WT/Acre/Yr. Ammonium Nitrogen 200.00 0.02 Organic Nitrogen 8010.00 0.80 Incorporated Available Nitrogen 5020.00 0.50 120.00 8.22 11.95 Surface Available Nitrogen 4960.00 0.50 120.00 8.32 12.10 Phosphorus as P205 6140.00 0.61 80.00 4.48 6.51 Potassium as K20 2320.00 0.23 50.00 7.41 10.78 Calcium, Total 194335.00 19.43 Calcium as CaO 272069.00 27.21 Calcium as CaCO3 (CCE) 3295.00 0.33 2000.00 208.71 303.49 Magnesium, Total 1720.00 0.17 Manganese 60.00 0.01 Sodium 385.00 0.04 Percent Moisture 31.23 " These are typical values and must be adjusted based upon specific site conditions DT is Dry Tons of Biosolids. WT is Wet Tons of Biosolids. CERTIFICATION: This biosolid product has been produced by the Town of Cheraw's Wastewater Treatment Plant by a treatment process that pasteurized plant residual solids using high temperature and lime (calcium oxide). The Town of Cheraw certifies that this biosolid complies with the Environmental Protection Agency regulations 40 CFR Part 503 for a "Class A" product and has a metal and nutrient content as presented above. DIRECTIONS FOR USE: This biosolid is intneded to be used as a soil amendment. The biosolid land application rate shall not exceed the most restrictive Maximum Application Rate as indicated in the table above. The application rate for nitrogen, phosphorus, potassium, and calcium is dependent upon the crop grown and site soil characteristics. The user should contact the Clemson Extension Service (843-623-2134) and/or the Soil Conservation Service (843-623-2187) for assistance in determining the proper application rate for each crop and site. In no case shall the land application rate exceed the agronomic rate for the crop grown. User should also refer to the Clemson Extension Service Circular #476 titled "Lime and Fertilizer Recommendations." THIS PRODUCT IS HIGHLY ALKALINE AND SHOULD BE HANDLED ACCORDINGLY. AVOID PROLONGED CONTACT WITH THE SKIN. AVOID CONTACT WITH THE EYES. THE TOWN OF CHERAW IS NOT RESPONSIBLE FOR IMPROPER USE OR HANDLING OF THIS BIOSOLID PRODUCT. Mr. Ricky D. Ingram, Public Utility Director P. O. Box 219; Cheraw, SC 29520 Telephone: 843-537-8440 FAX: 843-537-8442 PRODUCT USER NAME: ADDRESS: - - -- - - LOCATION OF USE: QUANTITY RECEIVED: RECEIVED BY: Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Receipt Date: 20-Nov-18 Client #: 168 Report Date: 07-Dec-18 Sample Date: 20-Nov-18 approved By:i SDG #: SDG-128353 Van Ward Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst LSID-283360 11-19-18-001 INF Biochemical Oxygen Demand 217 2 mg/L SM 5210B 11/20/2018 12:46 JW LSID-283361 11-19-18-002 EFF Biochemical Oxygen Demand 6.3 2 mg/L SM 5210B 11/20/2018 12:46 JW LSID-283362 11-20-18-0500 BIO SOLIDS Acid Digestion (Solids) YES EPA 200.2 11/27/2018 9:30 JR Selenium, Total <0.967 0.967 mg/kg EPA 7010 / 601 OD 12/6/2018 11:14 JR Percent Moisture 29.4 0.1 Wt% SW8463540 11/21/2018 8:52 ML Aluminum, Total 3310 38.7 mg/kg SW846 6010D 11/28/2018 9:11 JR Arsenic, Total <0.967 0.967 mg/kg SW846 6010D 12/6/2018 11:14 JR Cadmium, Total <0.967 0.967 mg/kg SW846 6010D 11/27/2018 14:35 JR Chromium, Total 56.7 0.967 mg/kg SW846 6010D 11/27/2018 14:35 JR Copper, Total 30.0 0.967 mg/kg SW846 6010D 11/27/2018 14:35 JR Lead, Total <0.967 0.967 mg/kg SW846 6010D 11/27/2018 14:35 JR Molybdenum, Total <3.87 3.87 mg/kg SW846 6010D 11/27/2018 17:01 JR Nickel, Total 14.5 0.967 mg/kg SW846 6010D 11/27/2018 14:35 JR Mercury, Total <0.026 0.026 mg/kg SW846 7470A 11/29/2018 13:00 CG PCB BRL mg/kg SW846 8082A S11A/D 11/27/2018 17:14 UH Page 1 Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Client #: 168 Sample Date: 20-Nov-18 SDG #: SDG-128353 Parameter Reporting Result Limit Unit South Carolina Certification Number: 21117 Receipt Date: 20-Nov-18 ReportDate: 07-Dec-18 Approved By: Van Ward Lab Director Method Flag Date Time Analyst LSID-283363 11-20-18-FIN Total Organic Carbon 2.4 0.5 mg/L SM 531 OB-2011 12/3/2018 13:10 SF L S ID-283364 11-20-18- RA W Total Organic Carbon 6.3 0.5 mg/L SM 5310B-2011 12/3/2018 13:10 SF Page 2 ANALYTICAL, INC. CLIENT Davis & Brown P.O. Box 15038 Quinby SC 29506 ATTENTION Scott Fields PROJECT ID 283362 LABORATORY REPORT NUMBER 1811K30 DATE November 29, 2018 Primary Data Review By Secondary Data Review By Ashley Amick Chris Pafford Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 4 e BROWN,s124W.MclverRoad PH: 843-606.6746 PAGE # _ OFDAVIS & _ Florence, SC 29601 FAX: 843-656-2208 " REGULATORY: YES NO g� ' l S/ Y CHAIN OF CUSTODY RECORD TURNAROUND11ME: _P1 _STANDARD RUSH P2 CUE FF11 SAMPLE ANWSIS REQUESTED a < o USE CODES TO INDICTATE IF SAMPLE WAS FILTERED OR PRESERVED: A= HNO, B = HCL O = HBO, F = FILTRATION C = NACH E = NA:SzO� G = ZINCACETATE Pre ervativo ro c - E rj a U.` a C u 2 O tL I- It �-• ! II 1 I ADDRESS: PROGRAMAREA: D=DRINKING WATER G = GROUNDWATER 5 =SOLID SL =SLUDGE SY=WASTEWATER C=OTHER PLEASE PRINT LEGIBLY SHADED AREAS FOR LAB USE ONLY PHONE: FAX: SAMPLE ID DATE TIME INITIAL NOTES LAB ID l 1 L Fill In the Number of Containers for EACH Test I SAMPLER SIGNATURE 1 FLOWINFO !CE^- ICE ES no PACK RECEIPT�—j TEMP: ' :L.�o C Wo y: pp ,Date:/ r Time: e 4ti-- �C.L (11 Zs (r (C-C Revel dby, , ,t Date: Time: ^} Relinquished by Date: Time: Received'oy Date: Time: Relinquished by: Date: Time: Received by: Date: Time; Commerl9; ISSUED: NOVEMBER 2012 Page`2 of 4 Analytical Environmental Services, Inc Date: 29-Nov-18 Client: Davis & Brown Client Sample ID: 283362 Project Name: 283362 Collection Date: 11/20/2018 10:40:00 AM Lab ID: 1811K30-001 Matrix: Soil Analyses 'Result Reporting Qual Limit Units BatchlD Dilution Factor Date Analyzed Analyst POLYCHLORINATED BIPHENYLS SW8082A (SW3550C) Aroclor 1016 BRL 49 ug/Kg-dry 270691 1 11/27/2018 17:14 UH Aroclor 1221 BRL 49 ugiKo dry 270691 1 11/27/2018 17:14 UH Aroclor 1232 BRL 49 ugiKo dry 270691 1 11/27/2018 17:14 UH Aroclor 1242 BRL 49 ug/Ko dry 270691 1 11/27/2018 1i:14 UH Aroclor 1248 BRL 49 ug/Kg-dry 270691 1 11/27/2018 17:14 UH Aroclor 1254 BRL 49 ug/Kg-dry 270691 1 11/27/2018 17:14 UH Aroclor 1260 BRL 49 ugiK; dry 270691 1 11/27/2018 17:14 UH Surr: Decachlorobiphenyl 39.3 45.7-140 S %REC 270691 1 11/27/2018 17:14 UH Surr: Tetrachloro-m-xylene 35.7 45.3-126 S %uREC 270691 1 11/27/2018 17:14 UH PERCENT MOISTURE D2216 Percent Moisture 31.7 0 wt% R385541 1 11/28/2018 15:15 JW Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr Sze case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 3 of 4 IANAwnc tt. FM-MONMEA fAI. AES SEavim,rue. 1. client Name: Access Analytical, Inc. 2. Carrier: FedEx C UPS C USPSn Client[- Courier[] Othei 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. SAMPLE/COOLER RECEIPT CHECKLIST AES Work Order Number: 1811K30 rrt-r.. . r, Shipping container/cooler received in good condition? • damaged ',_] leaking _ other_ Custody seals present on shipping container? • Custody seals intact on shipping container? • Temperature blanks present? • Cooler temperature(s) within limits of OAVC? [See item 13 and 14 for temperature recordings.] Q © © Cooling initiated for recently collected samples / ice present Chain of Custody (CDC) present? Chain of Custody signed, dated, and timed when relinquished and received? • Sampler name and/or signature on CDC? • Were all samples received within holding time? • TAT marked on the COC? • If no TAT indicated, proceeded with standard TAT per Terms & Conditions. 13. Cooler 1 Temperature 3.7 14. Cooler 5 Temperature 15. Comments: 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. oC Cooler 2 Temperature oC Cooler 3 Temperature oC Cooler 4 Temperature °C oC Cooler 6 Temperature °C Cooler 7 Temperature oC Cooler 8 Temperature °C I certify that I have completed sections 1-15 (dated Initials). MH 11/21/18 romm•nts Were sample containers intact upon receipt? • Custody seals present on sample containers? Custody seals intact on sample containers? • Do sample container labels match the COC? 0 © O incomplete info L illegible �] no label other Are analyses requested indicated on the COC? • Were all of the samples listed on the COC received? Q Q ® samples received but not listed on COC L] samples listed on COC not received ❑ Was the sample collection date/time noted? • Did we receive sufficient sample volume for indicated analyses? • Were samples received in appropriate containers? • Were VOA samples received without headspace (< 1/4" bubble)? I I Were trip blanks submitted? listed an COC _ not listed on CDC ❑ 27. Comments: This section only applies to samples where pH can be I certify that I have completed sections 16-27 (dated initials). checked at Sample Receipt. Yes No N/A Details Comments 28. Containers meet preservation 29. 30. Was pH adjusted at Sample Receipt01 ' Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & Grease/TPH. I certify that I have completed sections 28-30 (dated Initials). Checklist 6.9.17 Rev 2 L n Imd, AB 11/21/18 guidelines? AB 11/21/18 Page 4 of 4 DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by a data qualifier or a flag next to the result. This table summarizes the possible Data Qualifiers that may be associated with this report. A BOD result showed toxic tendencies. B The BOD data is suspect due to a failed quality control check (GGA). C The BOD data is suspect due to a failed quality control check (Blanks). D Results are reported on a dry weight basis. H Sample was analyzed beyond the accepted holding time J Estimated value. Presence of the compound was confirmed but less than the reported detection limit. L Results based on colony counts outside the acceptable range. The ideal range for the fecal coliform test is 20 - 60 colonies. MS Sample matrix spike percent recovery was outside the accepted range. O Sampled, but analysis lost or not performed P Sample was not properly preserved upon receipt. G LCS or MS exceeds the control limits. S Sample was analyzed by another SC certified Lab. SC Seed Correction outside the accepted range of 0.60 - 1.4 mg/L. (BOD) Seed Correction outside the accepted range of 0.60 - 1.4 mg/L (CBOD) SD Results reported are derived from suspect data. SS BOD results derived from supersaturated D.O. values. Sample(s) were aerated per the supersaturation procedure in Standard Methods 5210B SDF Sample Dilutions did not meet the requirement of DO depletion of at least 2.0 mg/L, or the sample dilutions did not meet the requirement ofDO residual of at least 1.0 mg/L. Davis & Brown is reporting these results as valid data. T Storage Condition: Temperature above 60 C due to power outage. V Analyte detected in the associated method blank. Note: the value in the blank shall not be subtracted from the sample result. Revision 04/17 WSF Dataqual.wpd DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S 1 I South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratory Clemson University S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S 11 South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016; 99006001 Note: Sl lA indicates AES Laboratory (98016); Sl1G indicates GCAL Laboratory (73006); S 11 P indicates Pace Analytical (96042001); S 11 TS indicates Test America Savannah (98001) S11TP indicates Test America Pittsburg89014 S 12 AASHTO R18 Certified S 13 South Carolina Lab Certification Number: 96012 S 14 South Carolina Lab Certification Number: 89002 S 16 South Carolina Lab Certification Number: 84004 S 17 South Carolina Lab Certification Number: 96037001 S 18 South Carolina Lab Certification Number: 95005 S 19 South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S26 North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 S29 South Carolina Lab Certification Number: 32566 S30 Galbraith Laboratories, Inc. Knoxville TN S31 South Carolina Lab Certification Number: 32576 Revision 08/l8 DaIaqual (SubLabs)p2 ,%pd t3 br I S & ]BROWN 124 W. MCtver Road PH: 843.663.6746 PAGE # OF _ Fforen¢r_°, SC 29501 FAX: 843-656-2208 m o :35 5 REGULATORY: `fES fdO A , Of Ct�l,�TODJ' RECORD TuaraARouuc TIME: Pl _P2 STANDAP.D RUSH CUEMT: S,A,IMPLE ANALYSIS REQUESTED USE CDOES TO Ir"ClO P,, TE:F SAH'PLE WAS Pra,<.er.•;��i✓a '��y�y FILTSREDQRPRESERIICG: A=HNO,t B=HCL O=H'so' F- FILTRATION �% ADDRESS: ' ez C = NAOH E = NA^S,O✓ G = 24NCACETATE — Z FRGGF;I:.i„ac, : ❑ = DRINKING WATER c Vi c G=GROUNDWATER S'=SOLID SL=SLUDGE W=WASTEWATER O=D'THER _ 0 PLEASE PRINT LEGIBLY PHorae: FAX: fi p`�- �' -Z j a. a. SA%IPLE ID DATE TMIC iM1T`:AL NGTES LA$1f? '"Itt-fre,ihaNum6erofCan;ainers`EoucACH.Tcst � A � C t.` t j i� I I v� ..:. " . (....`,,,1tt�t Drs'r C�. f ! {I fi art, i�`t�� Gi tr isr..t.•-� �`.` { pr^° jj ))"° e _ f,_r 1. ✓/5 �^s.,, �J.,. [Jy, L+ (,,,,I :_L -I a 1 I ' fi I SAMPLER SIGNATURE FLOWINFO ` ^� ICE f YES) NO PACK Ll�} • - is+NP: I� 1 oC P .lirgwshed Gy: Dale: t y�i Rehrauisheri by Datu: '1 i+r.e: Rahngwshud by: Ga;e: Time; �Y: t'' s`) Ode. t�-7mry�:/ Receiver, pY Oate: i+me: pwC ved Y: Daw 111 L mnen:s; % I _J CHERAW, TOWN OF 20-Nov-18 SDG # SDG-127338 PRELIMINARY Note: Some or all results may not be finalized. Lab Smp ID Analysis Analysis Sample Point Parameter Name Result MDL Units Date Time Analyst 9-19-18-040-B IOSO L IDS LSID-281005 Acid Digestion (Solids) YES 9/21/2018 9:30 AM JR LSID-281005 Aluminum, Total 6420 19.9 mg/kg 9/25/2018 5:01 PM JR LSID-281005 Arsenic, Total <0.995 0.995 mg/kg 9/24/2018 12:52 PM AE LSID-281005 Cadmium, Total <0.995 0.995 mg/kg 9/24/2018 12:56 PM JR LSID-281005 Chromium, Total 37.8 0.995 mg/kg 9/24/2018 12:56 PM JR LSID-281005 Copper, Total 28.5 0.995 mg/kg 9/24/2018 12:56 PM JR LSID-281005 Lead, Total 1.47 0.995 mg/kg 9/24/2018 12:56 PM JR LSID-281005 Mercury, Total <0.023 0.023 mg/kg 9/26/2019 12:30 PM CG LSID-281005 Molybdenum, Total <3.98 3.98 mg/kg 9/25/2018 4:36 PM JR LSID-281005 Nickel, Total 13.5 0.995 mg/kg 9/24/2018 12:56 PM JR LSID-281005 PCB BRL mg/kg 9/27/2018 7:20 PM UH LSID-281005 Percent Moisture 28.6 0.1 wt% 9/20/2018 4:30 PM ML LSID-281005 Selenium, Total <0.995 0.995 mg/kg 9/24/2018 12:52 PM AE 9-19-18-001 INF LSID-281006 Biochemical Oxygen Deman <100 2 mg/L 9/20/2018 10:50 AM AE 9-19-18-002 EFF LSID-281007 Biochemical Oxygen Deman <2.0 2 mg/L 9/20/2018 10:50 AM AE A N I M A L WASTE ANALYS IS R E P O R T Agricultural Service Laboratory LAB No. 111401 Clemson University TURNER, SHERRY PO BOX 219 CHERAW SC29520 ACCOUNT COMRLBR DATE 12/07/2018 STOLSON@CHERAW.COM SAMPLE NO. 11201850 MANURE: OTHER STORAGE: COVERED -----------------RESULTS REPORTED ON AN AS -SAMPLED BASIS---------------------- lbs/ton Ammonium Nitrogen 0.02 % 0.40 Organic Nitrogen 0.80 % 16.02 Nitrate Nitrogen --------------------------------------------------------------- 34.38 ppm 0.07 INCORPORATED AVAILABLE NITROGEN ESTIMATE 10.04 SURFACE AVAILABLE --------------------------------------------------------------- NITROGEN ESTIMATE 9.92 Phosphorus as P205 0.61 % 12.28 Potassium as K20 0.23 % 4.64 Calcium 19.43 % 388.67 Magnesium 0.17 % 3.44 Sulfur 0.20 % 3.99 Zinc 212.49 ppm 0.42 Copper 45.39 ppm 0.09 Manganese 61.20 ppm 0.12 Sodium 385.10 ppm 0.77 Moisture 31.23 % Calcium Carbonate Equivalency 0.33 % 6.59 ------------------------------------------------------------------------------ INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - 80% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be incorporated into the soil within hours of application. Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. Available nitrogen calculations are estimates and if nitrate-N was not re- quested the amount of available nitrogen may be slightly more than reported. Also, the actual amount may be more or less than the estimate depending on the composition of the manure, soil type, and environmental conditions. All of the potash in the animal waste should be plant available in the first year of application. Although not all of the phosphorous is available in the first year, its availability should be comparable to that in commercial fertilizers. The rate of animal waste to apply for crop production is dependent on the nutrient content of the waste, method of application and incorporation, soil test, crop to be grown, and previous manure applications. In most cases, the plant available nitrogen content of the waste is used to determine the rate of • moisture • solids lbs. solids/ton lbs. solids/500 tons 31.23 68.77 1375.4 687700 % ppm lbs/ton % ppm lbs/ton as -sampled as -sampled as -sampled dry ton dry ton dry Ammonium Nitrogen 0.02 200 0.4 0.029082 290.8245 0.581649 Organic Nitrogen 0.801 8010 16.02 1.164752 11647.52 23.29504 Nitrate Nitrogen 0.003438 34.38 0.06876 0.004999 49.99273 0.099985 Incorporated Available Nitrogen Estimate 0.502 5020 10.04 0.729969 7299.695 14.59939 Surface Available Nitrogen Estimate 0.496 4960 9.92 0.721245 7212.447 14.42489 Phosphorus as P2O5 0.614 6140 12.28 0.892831 8928.312 17.85662 Potassium as K2O 0.232 2320 4.64 0.337356 3373.564 6.747128 Calcium 19.4335 194335 388.67 28.25869 282586.9 565.1738 Magnesium 0.172 1720 3.44 0.250109 2501.091 5.002181 Sulfur 0.1995 1995 3.99 0.290097 2900.974 5.801949 Zinc 0.021249 212.49 0.42498 0.030899 308.9865 0.617973 Copper 0.004539 45.39 0.09078 0.0066 66.00262 0.132005 Manganese 0.00612 61.2 0.1224 0.008899 88.99229 0.177985 Sodium 0.03851 385.1 0.7702 0.055998 559.9826 1.119965 Calcium Carbonate Equivalency 0.3295 3295 6.59 0.479133 4791.333 9.582667 IklkwTa 074WI IF-11 Pasteurization vessel operates on a constant speed with an in/out time duration of 30 minutes. DATE 2 HOUR pH 24 HOUR pH MINIMUM TEMP IN MINIMUM TEMP OUT 01 /12/2018 11.98 12.08 157 173 01 /13/2018 12.16 12.18 157 170 01 /14/2018 12.49 12.38 160 171 01 /20/2018 12.16 12.24 158 164 01 /21 /2018 12.12 12.10 157 162 01 /23/2018 12.01 12.05 163 164 01 /24/2018 12.14 12.13 159 163 01 /25/2018 12.14 12.00 160 165 01 /26/2018 12.18 12.28 158 156 01 /27/2018 12.22 12.24 158 159 01 /29/2018 12.11 12.12 163 163 01 /30/2018 12.21 12.02 158 160 - 01 /31 /2018 12.19 12.31 146 158 02/01 /2018 12.11 12.11 156 159 02/02/2018 12.13 12.12 157 168 02/05/2018 12.21 12.24 157 156 02/06/2018 12.10 12.13 144 159 02/08/2018 12.14 12.09 156 175 A1V1r UAL rA 111VI-ThIN A1VL V MI UK AI 1 KAl:11UIN Kh1)UU'l'lU1V k'UKM Facility Name: Town of Cheraw Permit Number: WQ0014248 WWTP Name: Town of Cheraw wwTP NPDES Number: SCO020249 Monitoring Period: From 01 /01 /18 To 12/31 /18 Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed: Class A: Alternative 1 ❑ Alternative 2 ❑ Alternative 3 ❑ Alternative 40 1 Alternative 5 ® Alternative 6 ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑T Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray ❑ Gamma Ray ❑ Pasteurization Class B: Alternative 1 ❑ Alternative 2 ❑ Alternative 3 ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ I Air Drying ❑ Composting ❑ Aerobic Digestion ❑ Anaerobic Digestion[] If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter tAilliwdulc Level in Pathogen Density g y Number o Excee- den s Frequency of Analysis Sample Type Analytical Tech-nique inimu Geo. Mean aximu Units Fecal Coliform 2 x 10 to the 6th power MPN per gram of total solids or 2 x 10 to the 6th power CFU per gram of 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed: Option 1 ❑ Option 2 ❑ Option 3 ❑ Option 4 ❑ Option 5 ❑ Option 6 ® Option 7 ❑ Option 8 ❑ Option 9 ❑ Option 10 ❑ No vector attraction reduction options were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) ® "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Sherry Turner/Operator of Record Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print) Signatur of Preparer Date Signature of Land Applier (if applicable) Date Author Daryl D. Merritt DENR FORM RF (7/2002) Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Client #: 168 Sample Date: 18-Jan-18 SDG #: SDG-123418 Lab Sample ID: LSID-272436 Sample ID: 1-18-18-500 South Carolina Certification Number: 21117 Receipt Date: 18-Jan-18 Report Date: 06-Feb-18 Approved By: Van Ward Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst Fecal Coliform <305 305 MPN/gm SM 9221 A.3/92 Percent Solids 65.5 0.1 Wt% SW846 3540 Page 6 1/18/2018 13:45 LM 1/24/2018 10:00 ML 124 W. McIver Road PH: 843-666-6746 PAGE # _� OF DAVIS & BROWN Florence, SC 29501 FAX: 843-656-2208 k t$ � CHAIN OF CUSTODY RECORD �UND TIME. �±N STANDARD RUSH REGULATORY: YES NO — ^pZ CLIENT: SAMPLE ANALYSIS REOUESTED USE CODE'S TO INDICTATE IF SAMPLE WAS Preservative E FILTERED OR PRESERVED: A - HNO� w B = HCL D - H2S0, F = FILTRATION C = NAOH E = NA2S203 G = ZiNCACETATE ADDRESS: PROGRAMAREA: D-DRINKING WATER otv I E F q G = GROUNDWATER S - SOLID SL = SLUDGE a O Lu Q W= WASTEWATER O=OTHER PLEASE PRINT LEGIBLY a L) 0 u Q PHONE: FAX: a. � I- �"- U1 o a SAMPLE ID DATE TIME INITIAL NOTES LAB 10 7:r Fill in the Number of Containers for EACH Test A 1 Fc �1S -Ib-Ilt 015D S t, r 7- 9- sod 1330 a G I f 2'+2A35 a'--,o0 OT(d as 61 f SAMPLER SIGNATURE FLOW INFO ICE. ICE YES NO PACK RECEIPT TEMP: o n / (_ ��? —• C LUnquishad 'by: Data: Ti Relinquis d by Dale: Tlrtta: Relinquished by: Dete: Time: _r Receiv Date: Ti e: e d by Dee: Time: ��r� $ JVZ Received by: Dale: Time: Comments: 155ut:Lj: nvvcmaen ;&u]1 FECAL COLIFORM FOR MID-ZV1CIP_AL BIOSOLIDS A-1 Medium Double Strength Single Strength 10-' dilution / 10 nil sample 10-1 dilution! 1.0 nil sample Single Strength Single Strength 10-2 dilution / 1.0 nil sample 10-2 dilution / 0.1 nil sample I Date/Time Test Set -Up: 7 -1 k _ Date/ Time Test Read: - $ 1 Time Placed in Incubator: 1 3 0 Incubator Temp: Time Transferred to Water Bath: V.710,S Water Bath Temp: -io Operator C>Z' 1'0-- Media Lot # C' 3 - % Solids : �p , `�Sample # a MPN Fecal Coliform — 10 x MPN Index / 100 nil per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results; -indicates negative results osos Collection: Date —1�-� $ Time � 33O 0 01, BilidP r� FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium. Double Strength 10` dilution / 10 ml sample Single Strength I W dilution / 1.0 ml sample Single Strength 10_2 dilution ! 1.0 ml sample Single Strength 10-2 dilution / 0.1 ml sample r Date/Time Test Set -Up: a-a1'1 g } 500 Time Placed in Incubator: ) 500 Time Transferred to Water Bath: ) Wb Operator %Solids (:e,q 010 Date/ Time Test Read: - - 568, Incubator Temp: 3 5. ID Water Bath Temp: Media Lot # -11 c? 3to Sample # Q'oq i-) 8-500 iVIPN Fecal Coliform = W x WN Index / 100 ml = (� per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date 9.169) i Time 14q D Op. Ar 0 0 FECAL COLIFOR_M FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength 10-dilution / 10 ml sample Single Strength 10"' dilution / 1.0 ml sample Single Strength Single Strength 10-2 dilution / 1.0 ml sample 10-2 dilution / 0.1 nil sample Date/Time Test Set -Up: 3 21-1 g� 1� 1 a� Date/ Time Test Read-- Dw�t -1 4 113-7 Time Placed in Incubator: Incubator Temp: ?,S, D C- Time Transferred to Water Bath: Water Bath Temp: q y_ {a C— Operator Media Lot # `i 19 % Solids 5. Sample # 3 - X-12--SDO �iPN Fecal Coliform = 10 x MPN Index / 100 ml — per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date I Time f D 3 9 Op. Q , ti 4p+f -0 FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength 10-' dilution / 10 ml sample Single Strength 10' dilution / 1.0 ml sample Single Strength 10"2 dilution / 1.0 ml sample Single Strength 10'2 dilution / 0.1 ml sample r i1 Date/Time Test Set -Up: 4p-(Y-tY S3 G� Date/ Time Test Read: L(- I q - I k' Time Placed in Incubator: Incubator Temp: L4 4, (00 Time Transferred to Water Bath: I K3 1� Water Bath Temp: Operator SCv_ Media Lot # : % Solids Sample # : MPN Fecal Coliform = 10 x NTN Index / 100 ml = . per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date q—fi—f b Time /.r-v o Op. St�— TiffM P out -; o CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE FORMULA: % Total Solids = (A - B) x 100 C-B Where: A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample # : Weight of dried residue + dish: Duplicate weight of dried residue + dish: Weight of empty dish Weight of wet sample + dish : % Total Solids = 11 11 FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength Single Strength 10' dilution / 10 ml sample 10-1 dilution / 1.0 ml sample Single Strength Single Strength 10-'- dilution / 1.0 ml sample 10'2 dilution / 0.1 ml sample r-. Date/Time Test Set -Up: = - �, Q Date/ Time Test Read:- - j -I- I I 10 `S Time Placed in Incubator: 1 1 Incubator Temp: ss K o Time Transferred to Water Bath: � � � � Water Bath Temp: q , (o C_ Operator Media Lot # % Solids Sample # _ - I Ce-j ,�--O� Oy MPN Fecal C©liform = 10 x MPN Index / 100 ml = per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date ( k Time Op. a _� _ FORMULA: Where: CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE % Total Solids (A-B)xl00 C-B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample # : S:�f (P " ( a--Ot4c)o Weight of dried residue + dish: Duplicate weight of dried residue + dish: Weight of empty dish Weight of wet sample + dish % Total Solids = �(o • 0 a�o51� FECAL COLIFORNI FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength 10'1 dilution / 10 ml- sample Single Strength 10'1 dilution / 1.0 ml sample Single Strength Single Strength 10''- dilution / 1.0 ml sample 10''- dilution / 0.1 ml sample Date/Time Test Set-Up:%0-1 131� Date/ Time Test Read:' ,2I-1 Time Placed in incubator: ' [ Incubator Temp: 35.3 C Time Transferred to Water Bath: Water Bath Temp: Operator : �; , Media Lot # : D i Cho &I OCpl 5Zp % Solids (p 55 Sample # : (p -oZO-I - 0`i✓(7C� MPN Fecal Coliform = 10 x NUN Index / 100 ml = per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results r :. Biosolids Collection: Date -ab -I Time Op, S CALCULATION FOR TOTAL SOLIDS N BIOSOLIDS SAi�il.'LE FC3RMnA: % Total Solids = (A - B) x 100 C-B Where: A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample# : Weight of dried residue + dish: ag Duplicate weight of dried residue + dish: Weight of empty dish o�' � , 3 Weight of wet sainple + dish % Total Solids FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength Single Strength 10-' dilution / 10 ml sample 10-1 dilution / 1.0 ml sample Single Strength Single Strength 10-' dilution / 1.0 ml sample 10-2 dilution / 0.1 ml sample Date/Time Test Set -Up: Date/ Time Test Read: -(�(' 24 loco Time Placed in Incubator: Incubator Temp: 2 C- Time Transferred to Water Bath: 1355 Water Bath Temp: { p Operator Media Lot # 5 (-P % Solids : �6 0/ 0 Sample # MPN Fecal Coliform = 10 x MPN Index / 100 ml = per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date '-1 rI �'-j Time 101 D 0 Op. Q I CALCULATION FOR TOTAL SOLIDS INT BIOSOLIDS SAMPLE ` FORMULA: % Total Solids = (A - B) x 100 C-B Where: A = Weight of dried. residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample # : 00 Weight of dried residue + dish: l a I Duplicate weight of dried residue + dish: Weight of empty dish f �' Weight of wet sample + dish �D % Total Solids = F FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength 10' dilution / 10 rnl sample Single Strength 10"1 dilution / 1.0 ml sample r- Single Strength 10-'- dilution / 1.0 ml sample Single Strength 10'- dilution / 0.1 ml sample- Date/Time Test Set -Up j 5-1 ---)- 0 _�_ Time Placed in incubator: 4_L� (aO� Time Transferred to Water Bath:' a,Operator % Solids (n s?0 Date/ Time Test Read: S -141 l__;� U Incubator Temp: 3�5 Water Bath Temp: 4 5 Media Lot # : % � c- o '�-) O o Tr Sample# R'�.5-19�-ogoo MPN Fecal Coliform = 10 x MPN Index / 100 ml = per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results D OT iosolids Collection: Date C5 B' � 5'� g Time.- -- Op. CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE % Total Solids = (A - B) x 100 C-B Where: A = Weight of dried residue +,dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample Weight of dried `residue + dish: Duplicate weight of dried residue + dish: Weight of empty dish Weight of wet sample -+-dish % TotalSolids FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength 10' dilution / 10 ml sample Single Strength 10' dilution / 1.0 ml sample Single Strength 10' dilution / 1.0 ml sample Single Strength 10"' dilution / 0.1 ml sample Date/Time Test Set -Up: Time Placed in Incubator: Date/ Time Test Read: 9 a0,1 Incubator Temp: 3 i Time Transferred to Water Bath: ) 30O-1 Water Bath Temp: 4 �j q oc— Operator :0,&2._ % Solids (p� ��0 Media Lot # Sample # MPN Fecal Coliform = 10 x MPN Index / 100 ml = per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results 00 Biosolids Collection: Date q--(91-I �_ Time D� D Op. a FORMULA: Where: CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE % Total Solids (A-B)x 100 C-B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample#: 9')9')%-014&L) Weight of dried residue + dish: Duplicate weight of dried residue + dish: Weight of empty dish Weight of wet sample + dish : % Total Solids = s " o 11J 11 US I G) FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength 10-1 dilution / 10 ml sample Single Strength 10-' dilution / 1.0 ml sample Single Strength Single Strength 10''- dilution / 1.0 ml sample 10'2 dilution / 0.1 ml sample Date/Time Test Set -Up: Time Placed in Incubator: a� Time Transferred to Water Bath: 1230 Operator % Solids �p p Date/ Time Test Read: I 0-I �--j 2�1 qD a. Incubator Temp:.3� Water Bath Temp: 5 Media Lot # : Sample # MPN Fecal Coliform = 10 x MPN Index'/ 100 ml = per Gram'Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results f Biosolids Coll 0� ection: Date �� � � � � � � � Time Op. A S k gc ��:3y,S°c_ FORMULA: Where: CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE % Total Solids (A-B)xl00 C-B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample # : 11 C) —11 A 1� — U SDD Weight of dried residue + dish: Duplicate weight of dried residue + dish: Weight of empty dish Weight of wet sample + dish : % Total Solids = G,� aT3--k3.,a!::> 3 a8 rI L (, On FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength 10-1 dilution / 10 ml sample Single Strength 10''- dilution / 1.0 ml sample Single Strength 10' dilution / 1.0 ml sample Single Strength 10'2 dilution / 0.1 ml sample Date/Time Test Set -Up: Date/ Time Test Read: ((-z(- (8 (o�-g Time Placed in Incubator: 1 i �'� Incubator Temp: 9 Time Transferred to Water Bath: N ) 7 Water Bath Temp: L) Operator S� Media Lot # % Solids Sample # OS-00 MPN Fecal Coliform = 10 x MPN Index / 100 ml = per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date ( ( - Zn (9 Time ,rAf 35,`f oc @ 1 '7 A5 .44f : * V CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE FORMULA: % Total Solids = (A - B) x 100 C-B There: A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample # : Weight of dried residue + dish: Duplicate weight of dried residue + dish: Weight of empty dish Weight of wet sample + dish % Total Solids = FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength 10` dilution / 10 ml sample Single Strength 10"1 dilution / 1.0 ml sample Single Strength:' 10` dilution / 1.0 ml sample Single Strength 10'- dilution / :0.1 ml sample Date/Time Test Set -Up: taA9-1S, OqqU Time Placed in Incubator: 09 p Time Transferred to Water Bath: A a 3 Operator vl % Solids t Date/ Time Test Read: -ao-I �� 0 R-0 Incubator Temp: 3 s-.1), Water Bath Temp: Media Lot # Sample# MPN Fecal Coliform = 10 x MPN Index / 100 ml = per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results y 1z. Biosolids Collection: Date Q-I9-1 2� Time,_D9 DD Op. FORMULA: Where: CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAWLE % Total Solids = (A - B) x 100 C-B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample # : � 2 q - � � - D 5,D0 Weight of dried residue + dish: Duplicate weight of dried residue + dish: Weight of empty dish Weight of wet sample + dish J/ % Total Solids = -1 1 1 % l O 35 -, b9 �s5 35,Olial.. a- b (.0 s-q