HomeMy WebLinkAboutNCS000351_OTHER_20100714STORIVIVIIATER-DIVISION-CODING-SHEET
PERMIT NO.
N(.,c, v�055 I
DOC TYPE
El FINAL PERMIT
❑ MONITORING INFO
❑ APPLICATION
❑ COMPLIANCE
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❑ a ni a 01 1 `1
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. Best Management Practices for Wood Ash Used as an Agricultural Soil Amendment Page 1 of 6
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0 From the 1700's tlu ough the early 1900's, wood was combusted in the United States to
produce ash for chemical extraction. The ash was mainly used to produce potash for
fertilizer and alkali for industry. As other potash production technologies became more
economical the value of wood ash as a raw material dropped. Recently, ash has been
considered a waste product instead of a resource as few industries have taken advantage of
the beneficial properties of the ash. Today, approximately three million tons of wood ash
are produced annually in the United States. While approximately 80% of all ash is land
applied in the Northeast United States, less than 10% is being land applied in the Southeast.
The other 90% of this wood ash is currently being landfilled. While several alternative uses
for wood ash have been developed, land application is one of the best methods for ash
utilization as nutrients taken from the land during harvest are recycled back to the land. In a
survey of more than 80 Southeastern paper mills, 60% of the responding mills reported an
interest in land application. Wood ash has the potential to be used as a lime substitute in
almost all Georgia's counties.
Wood ash is the inorganic and organic residue remaining after the combustion of wood
or unbleached wood fiber. The physical and chemical properties of wood ash vary
significantly depending on many factors. Hardwoods usually produce more ash than
softwoods and the bark and leaves generally produce more ash than the inner woody parts
of the tree. On the average, the burning of wood results in about 6-10% ashes. When ash is
produced in industrial combustion systems, the temperature of combustion, cleanliness of
the ftiel wood, the collection location, and the process can also have profound effects on the
nature of the ash material. Therefore, wood ash composition can be highly variable
depending on geographical location and industrial processes. This makes testing the ash
extremely important.
0 Ash is composed of many major and minor elements needed by the tree for plant
growth (Table 1). Since most of these elements are extracted from the soil and atmosphere
during the tree's growth cycle, they are elements that are corrunon in our enviromilent and
are also essential elements in the production of crops and forages. Calcium is the most
abundant element in wood ash and gives the ash properties that are similar to agricultural
lime. Ash is also a good source of potassium, phosphorus, magnesium, and aluminum. In
terms of commercial fertilizer, average wood ash would probably be about 0-1-3 (N-P-k).
In addition to these macronutrients, wood ash is also a good source of many micronutrients
that are needed in trace amounts for adequate plant growth. Wood ash contains few
elements that pose environmental problems. Heaw metal concentrations are typically low
and not in a highly extractable or available forin.
mhtml:file://C:IDocuments and SettingslCory_LarsenlDesktoplCoastal Carolina Clean Po... 4/28/2010
STORMWATER DISCHARGE MONITORING REPORT (DMR)
Please Mail Original and One Co .to Mailing Address Below
GENERAL PERMIT NO, NCGO20000
Part A: Facility Ltformation
Samples Collected in Calender Year: 2009 (all samples shall be reported within 30 days following monitoring period)
Certificate of Coverage No. NCG020175 County of Facility GUILFORD
Facility Name HICONE QUARRY Name of Laboratory PACE ANALYTICAL
Facility Contact DAVID THORNE Lab Certification q 12
Facility Contact Phone No. (336) 375-7584
Part B. Land Disturbance and Process Area Monitorine Reauirements
Cutfall' �'Receivij&Strearri:
No..
Naive
-Date
50050 A
00530
00076,
00545
Sample, '
"Collect`ed!
"Total
Flow
Total
Suspended
Soilds
"Turbidity
Settleable
Solids
mo/dd/ '.
MG
m .
NTUs
min
001
UT of Rocky Fork
Part C: Vehicle Maintenance Manflorine Reauirements
Outfail
No;,
Receiving,Streain
Name-
Date `
50050
.00556
00530
00400_.
:Sample
Collected
Total
Flow
Offhand
Grease
Total
Suspended
Solids
pH,
.
mo/dd/w
MG: .
_ m
m
unit
002
UT of Roc Fork
The stormwater sample for Mcone Quarry was inadvertately not collected. All monthly sampling was conducted as requited for 2009.
Para D: Storm Event Characteristics
Total Event Precipitation (inches)
Event Duration (hours)
Part E. Certo7cation
Total Event Precipitation (inches)
Event Duration (hours)
(if a separate storm event is sampled)
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting, false information,
Including the possibility of fines and imprisonment for knowing violation."
1126/l0
gna a of Permitee) (Date)
Part D, Mailing Address
Atin: Central Files, DENR, N.C. Division of Rater Quality, 1617 Mail Service Center, Raleigh, N.C. 27699-1617
SWU-243-012005
Best Management Practices for Wood Ash Used as an Agricultural Soil Amendment Page 2 of 6
0 Field and greenhouse research have confirmed the safety and practicality of recycling
wood ash on agricultural lands. It has shown that wood ash has a liming effect of between 8
and 90% of the total neutralizing power of lime and can increase plant growth up to 45%
over traditional limestone. The major constraints to land application of wood ash are
transportation costs, low fertilizer analysis, and handling constraints. With ever increasing
disposal costs, land application of wood ash will probably be the disposal method of choice
in the coming century resulting in savings for the industry, an opportunity for agriculture,
and conservation of our resources.
® Georgia's regulations concerning wood ash application are rather vague and difficult to
follow. Wood ash is specifically exempted from the Georgia Department of Agriculture's
fertilizer act and does not meet the specifications outlined in the regulations that govern
agricultural lime distribution. Depending on the interpretation, it could be registered under
the Soil Amendment Act, however, the Department of Agriculture has not registered it in
the past. To facilitate the distribution of wood ash, a recommended procedure for the land
application of wood ash has been established and approved by the Georgia Department of
Agriculture and Environmental Protection Division of the Georgia Department of Natural
Resources. Basically, these recommendations state that the wood ash supplier should meet
certain requirements that insure that the wood ash composition is safe for the environment.
To distribute wood ash to landowners, the supplier will likely require the landowner to
show that proper soil tests and analysis have been performed to calculate the optimum
application rate. In.addition, the supplier will probably maintain records on the distribution
of the wood ash and ask the landowner to sign a release form. The landowner is responsible
for obtaining soil test and calculating the appropriate application rate, however, these
services may be provided through the Extension Service or other qualified individuals.
0 Most of Georgia's soils are naturally infertile, acidic, and low in organic matter.
Therefore, continuous agriculture requires many soil additions to correct for these
deficiencies. The fact that additions such as nitrogen often lower the soil pH makes the
addition of neutralizing agents such as lime or wood ash a necessity on most Georgia soils.
Luring improves crop growth by decreasing the availability of certain metals below toxic
levels, providing Ca and Mg to crops, and improving P availability. While dolomitic and
some calcitic limes are the most common additions used in Georgia, wood ash has many of
the same effects as commercial lime. It also has the added benefit of being able to replace
many of the macro and micro nutrients removed during plant growth and harvesting.
Several studies have compared plant growth using both traditional limestone and wood ash
and most have concluded that ash gives better growth responses than limestone. While some
studies have reported detrimental effects at extremely high application rates. these responses
were explained by the drastic increases in soil pH beyond the plant's optimal level. As long
as the soil pH is maintained at the proper level, productivity will be enhanced by using
wood ash as a liming agent and soil amendment.
0 Planning for wood ash application requires several considerations. Before planting any
crop the soil's nutrient level and pH must be detenrined tluough proper soil testing.
Landowners should consult with their local Extension office or soil testing laboratory to
obtain a bulletin outlining the proper procedures for soil sampling and determining proper
liming. rates, however, several of the essentials are reviewed here. Samples should be taken
in the fall or winter. If fields contain variable soils, they should be divided into blocks with
similar characteristics and sampled individually. It is also important to obtain a
representative sample. This can be accomplished by mixing several cores from a variety of
mhtAnl:file://C:1Documents and SettingslCory_LarsenlDesktoplCoastal Carolina Clean Po... 4/28/2010
STORMWATER DISCHARGE MONITORING REPORT (DMR)
11 Please Mail Original and One Copy to Mailing Address Below
GENERAL PERMIT NO. NCG020000
Part A: Facility Information
Samples Collected in Calender Year: 2009 (all samples shall be reported within 30 days following monitoring period)
Certificate of Coverage No. NCO020039 County of Facility CALDWELL
Facility Name CALDWELL QUARRY Name of Laboratory PACE ANALYTICAL
FacMity Contact LARRY SHERRILL Lab Certification # 12
Facility Contact Phone No. (8M 754-3077
Part B: Land Disturbance and Process Area Monitoring Requirements
Date.
.50050
00530
00076
00545
'4� "r%3
Sample.
'total
Settleable
Outfall
Reaeiving,Stceam,
.Collected
Total .
: Suspended
'Turbidity
. Solids
�No: A
_ Narrse t
-Flow,
Soilds
L,>.
mo/d""MO
in
NTUs
m1/1
001
Millers Creek
08/27/08
Part C Vehicle Maintenance Monitoring Requirements
Outfall
No. ..
'.Receiving Stream
Name
Date
50050
00556
00530
00400
Sample
Collected
Total
Flow
Oil and
Grease
Total.
Suspended
Soilds
pH
mold
MG
m
m
.unit:
002
Millers Creek
The stormwater sample for Caldwell Quarry was inadvertately not collected. All quarterly sampling was conducted as required for 2009.
Part D: Storm Event Characteristics
Total Event Precipitation (inches)
Event Duration (hours)
Part E. Certification
Total Event Precipitation (inches)
Event. Duration (hours)
(if a separate storm event is sampled)
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the Information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for subomitting false Information,
Including the possibility of fines and imprisonment for knowing violation." f _ /J
Of
Part D; Mailing Address
Attn: Central Files, NC DENR, Division of Water Quality,1617 Mail Service Center, Raleigh, N.C. 27699-1617
1/26/10
(Date)
OF
. Best Management Practices for Wood Ash Used as an Agricultural Soil Amendment Page 3 of 6
locations within each sampling area. Not only will this enhance crop uniformity and
production, but could reduce the input expenses as well. Maintaining accurate records is an
important aspect of soil testing. A collection of past records can be used to identifi, the
buildup or decline of any chemical component in the soil profile so that changes in the
inputs can be made.
® Wood ash applications should be limited to a level that maintains the soil pH within the
optimum range for the intended crop growth. The liming ability of wood ash is usually
estimated using a laboratory measured parameter called the calcium carbonate equivalent
(CCE). The CCE tells you how well the wood ash will raise the soil pH compared to lime
(calcium carbonate). As with the nutrient composition of wood ash, the CCE of different
wood ash may vary considerably, however, most are within the range of 25 to 60%. With
proper soil tests and the lime equivalency of the wood ash, application rates for wood ash
can be calculated by dividing the recommended lime application rate by the lime
equivalency of the wood ash as shown:
Mood ash application rate In tonslacro a Recommandad Limlog Rats In tnnalocre
Percent limo equivalency (cc" 1 toO
m For example, if two tons of lime are needed per acre and the ash has a CCE of 50%,
then four tons of ash would be required. While this calculation is relatively easy to snake, it
is strongly recommended that producers allow the county extension agent or other qualified
individuals to calculate appropriate application rates. At times, fertilizer application rates
may also need to be reduced when liming with wood ash as the ash may contain significant
amounts of plant nutrients. Therefore; if additional fertilizer applications are being used,
they should be formulated to insure that the plant requirements for these elements are not
being exceeded, especially on crops that are known to be sensitive to particular nutrients
such as phosphorus and potassium.
0 During application of wood ash to the soil, special care should be taken to prevent the
ash from entering any surface or ground water. A distance of at least 50 feet should separate
the wood -ash from any farm ditches, wells, or other bodies of water. This distance should be
increased to 160 feet in highly erodible areas or areas without riparian stream side
vegetation or buffer zones. Karst areas in Georgia present unique conditions where surface
waters can rapidly reach the groundwater with little attenuation of pollutants. In these areas,
or within wellhead protection areas where local ordinances may impose additional
restrictions, application rates should be reduced or larger buffer zones should be used.
Wood ash should not be applied to areas with water standing on the soil surface. Care
should also be taken to avoid wood ash applications immediately preceding periods of
prolonged rainfall or when large storms are expected.
0 Wood ash should be land applied as soon as possible to avoid the need for on -site
storage. When conditions such as inclement weather do require on -site storage, wood ash
should be stored in a manner that prevents runoff particulate from entering surface or
ground water. Indoor storage is ideal-, however, when it must be stored outdoors it should be
placed on packed soil or pad surrounded by a small berm to prevent surface water from
entering or leaving the storage area. The storage area should also be located away from
wells, surface water, and animal watering areas and covered or shielded as much as possible
to prevent nuisance conditions if it were moved or disturbed during dry or windy weather.
mhtml:file: //C:1Docutnents and SettingslCory_LarsenlDesktoplCoastal Carolina Clean Po... 4/28/2010
STORMWATER DISCHARGE MONITORING REPORT (DMR)
Please Mail Original and One Cop
y to Mailing Address Below
GENERAL PERMIT NO. NCGO20000
Part A: Facility Information
Samples Collected in Calender Year: 2009 all samples shall be reported within 30 days following monitoring period)
Certificate of Coverage No. NCG020029 County of Facility ALAMANCE
Facility Name EAST ALAMANCE QUARRY Name of Laboratory PACE ANALYTICAL
Facility Contact TONY JENKINS Lab Certification # 12
Facility Contact Phone No. (336) 578-5420
Part R" fund Disturhance and Prncecc Area Mnnitnrinv Reauiremenis
'
^Qutfall,
No:
oReceming'Streamf
Naive ';
`Dates
" 50050 :
; :00530.
100076 ':.
00545
Sample
Collected
-
Total ;
Flow jli.
Total
'Suspended
Soilds
Tatbidity
Settleable-
'Solids'
_
:mo/d
MG
I 'MPA
NT'Us
MIA
001
Boyds Creek
08/27/08
0.480
30
30
ND
Part D: Storm Event Characteristics
Total Event Precipitation (inches) 6
Event Duration (hours) 8
Part E: Certi•rication
Part C: Vehicle Maintenance Monitoring Reauirements
Outfall.
No.
Receiving Stream;
Name
Date
'50050;
00556
00530
'00400_ .1
Sample_.
' Collected;
TU6
-Flow
Oil:am,
Gi me
Total:
tStispended
Solids
;pH
_
mo/dd/ •
. MG.
mgA
mrd,.
unit '..;
002
Bo ds Creek
06/17/09
0.480
ND
91
6.9
Total Event Precipitation (inches)
Event Duration (hours)
(if a separate storm event is sampled)
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision In accordance with a
system designed to assure that qualititd personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the Information, the information submitted is,.to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are signific nt penalties for submitting false information,
Including the possibility of flees and imprisonment for knowing violation." — &/,2. j -//,, J 1n6no
a e of Permitee) (Date)
Part D; Mailing Address
Attn: Central Files, DENR, N.C. Division of Water Quality,1617 Mail Service Center, Raleigh, N.C. 27699-1617
S WU-243-012005
'. Best Management Practices for Wood Ash Used as an Agricultural Soil Amendment Page 4 of-6
® One of the major obstacles to land spreading of wood ash is the undesirable handling
and spreading characteristics of ash. Most ash has a low density and small particle size and
consequently creates dust problems during transport and application. Wood ash should
always be covered during transport to prevent losses in route to the application sites. Studies
indicate that the handling characteristics of ash generally improve with increasing relative
humidity so attempts should be made to avoid spreading on extremely dry days. Moisture
can be added to improve the handling characteristics of ash, however, if too much moisture
is added the ash will cake and become difficult to spread uniformly. Ash can be spread with
conventional manure spreading or lime application equipment and is either top dressed or
incorporated. To get the maximum benefit, incorporate the wood ash throughout the root
zone whenever possible as the benefits only occur where the ash and soil are in contact. It is
also essential to calibrate the spreader to insure that the target application rate is met. Due to
the physical characteristics of ash. it is often difficult to obtain uniform application. but
calibration and knowledge of the application distribution of the spreader can help to
minimize non-unifornity.
0 The fall is generally the best time for wood ash application. Soil pH is generally lower
in the fall and applications at this time will allow the ash will have plenty of time to react
with the soil before rapid spring growth. Soils are also usually drier and more accessible in
the fall. Application at other times throughout the year is acceptable; however, ash should
not be applied immediately preceding planting or during early emergence as it could cause
short term concentrated alkaline conditions that could interfere with plant growth. Ash may
also absorb pesticides if it not given time to neutralize in the soil, so chemical applications
should be avoided for three to five days prior to or after wood ash application.
A Health considerations must be taken into account when dealing with ash to prevent
both particle inhalation and contact with the skin. Inhaling any small particle is dangerous
so masks should be worn during application or when dusty conditions warrant them. Ash is
an alkaline material with a pH ranging frorn 9-13. Therefore. this material could irritate the
skin. To prevent this, skin should be covered during application and transport and skin areas
exposed to ash should be washed and thoroughly rinsed with water immediately following
application. It is also important to remember that fresh ash can still retain hot coals which
are both a health risk and a fire hazard.
® In summary, wood ash application is similar to lime application. Both materials can
benefit crop productivity but wood ash has an added advantage of supplying additional
nutrients. Both materials are also alkaline and could cause crop damage if over applied or
misused. It is imperative that the land owners follow the prescribed application rates and
use conunion sense approaches to prevent accidents and avoid environmental contamination.
Table 1. Range in elemental composition of industrial
wood ash samples and ground limestone.
Element Wood Ash* 11 Limestone
Macroelements. Concentration in %
Calcium 15 (2.5-33) 31
Potassium 2.6 (0.1-1 3) 11 0.13
Aluminum 0 - ] E;
1 1.6 (0.5-3.2)
1 5
SPtl A&"WoK,k
(�lL �
mhtml:filea/C:1Documents and Setting 1Cory_ arsenlDesktoplCoastat Carolina Clean Po... 4/28/2010
STORMWATER DISCHARGE MONITORING REPORT (DMR)
Please Mail Original and One Copy to Mallinit Address Below
GENERAL PERMIT NO. NCG020000
Part A: Facility Information
Samples Collected in Calender Year: 2009 ,(all samples shall be reported witbin 30 days following monitoring period)
Certificate of Coverage No. NCG020114 County of Facility YADKIN
Facility Name YADKIN QUARRY Name of Laboratory PACE ANALYTICAL
Facility Contact DENNIS HELLARD Lab Certification q 12
Facility Contact Phone No. L336) 669-3253
Part B: band Disturbance and Process Area Monitoring Reauirements
Outfall;
No.
Receiving Stream
Name
:Date ,
. 50050
00530 i
` 00076' '
.• 00545
Sample; '
Collected,'
Total
Flow
Total
Suspended
'Soiids
'
Turbidity
Settleable
Solids
mo/dd/ ',
MG
m
NTUs
my]
001
UT of South Deep Creek
No Dischar e
Part D: Storm Event Characteristics
Total Event Precipitation (inches)
Event Duration (hours)
Part E. Cert0cation
Part C: Vehicle Maintenance MonitoringRequirements
Outfall
_No.
ReceivingStream
Name
Date
50050,
-.00556
00530
'00400
Sample
Collected.;
Total
Flow
Oil and
Grease
Total,
Suspended
Solids
pH
moldd/yr
MG
MWA
m
unit
002
UTof5outh Deep Creek
No Dischar e
Total Event Precipitation (inches)
Event Duration (hours)
(if a separate storm event is sampled)
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
Including the possibility of fines and imprisonment for knowing violation."
Part D; Mailing Address
Attu: Central Files, DENR, N.C. Division of Water Quality, 1617 Mail Service Center, Raleigh, N.C. 27699-1617
S WU-243-012005
. Best Management Practices for Wood Ash Used as an Agricultural Soil Amendment Page 5 of 6
Magnesium 3 z- 1.0 (0.1-2.5) 5.1
Iron 1-0 11
0.84 (0.2-2.1)
0.29
Phosphorus �.0 0.53 (0.1-1.4) 0.06
Manganese — 0.41 (0-1.3) 0.05
Sodium P6 s 0.19 (0-0.54) 0.07
Nitrogen 3o 10.15 (0.02-0.77) o.o l
Microclements I I Concentration in mg/kg
Arsenic 0.36 6 (3-10)
Boron 123 (i4-290)
Cadmium o •0ol 3 (0.2-26) 1 7
Chromium . 0 57 (7-368) 16.0
Copper p. o0 70 (37-207) 10
Lead 0.0; 65 (16-137)
55
Mercury 0,66 00 2 1.9 (0-5)
Molybdenum S)O 19 (0-123)
Nickel 0-2-611 20 (0-63)
20
Selenium 0 - b sb 0.9 (0-11)
Zinc 0.067 j 1 233 (35-1250) 113
Other Chemical Properties
CaCO� Equivalent 43% (22-92%) F-I 00%
pH ' 10.4 (9-13.5) 9,9
%Total solids 75 (31-100) 100
* Mean and (Range) taken from analysis of 37 ash samples
Mark Risse, Extension Engineering. 307 Hoke Smith Bldg., Athens 30602. 706-542-
2154
Glen Harris, Extension Agronomist, F.O. Box 1209, Tifton 31793. 912-386-3194
nilitinl:f le://C:1Docuinents and SettingslCory_LarsenlDesktoplCoastal Carolina Clean Po... 4/28/2010
STORMWATER DISCHARGE MONITORING REPORT (DMR)
Please Mail Original and One Copy to Mailing Address Below
GENERAL PERMIT NO. NCG020000
Pail A: Facility Information
Samples Collected in Calender Year: 2009 (aU samples shall be reported within 30 days following monitoring period)
Certificate of Coverage No. NCG020013 County of Facility RANDOLPH
Facility Name ASHEBORO QUARRY Name of Laboratory PACE ANALYTICAL
Facillity Contact DOYLE CARLISLE Lab Certification # 12
Facility Contact Phone No.
336 672-1501
Part B: Land Disturbance and Process Area Monitoring Requirements
1'I i
Date.,
. 50050 •
00530
00076
00545
yy�
Sample
Total
„
: Settleable
'30utfall ;
{Receiving Stream'
Collected •
'. Total
Suspended
Turbidity
' Solid's
Name
Flow
Sands
}
~
mo/d
M& `-.-me
NTUs
mlll"
001
UT of Back Ck
06/18/09
0,480
84
105
ND
Part D: Storm Event Characteristics
Total Event Precipitation (inches) 2
Event Duration (hours) 8
Part E: Certification
Parr C: Vehicle Maintenance Monitoring Requirements
Outfall
No.
Receiving Stream
Name ..
Date
50050
00556
00530
00400
Sample .
Collected
Total.
Flow
Oil and
Grease
-Total
Suspended-
Soilds
pH
mold
' MG '
iri
n1
unit
002
UT of Back Ck
06/16/09
0.480
ND
49
2.4
Total Event Precipitation (inches)
Event Duration (hours)
(if a separate storm event is sampled)
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted Is, to the best
of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
Including the possibility of fines and Imprisonment for knowing violation."
fart 0; Mailing Address
Attn: Central Files, NC DENR, Division of Water Quality, 1617 Mail Service Center, Raleigh, N.C. 27699-1617