NCS000592_HISTORICAL WITH APPLICATION_20171002

-STURIGIINATER"DIVISION-CODING SHEET-"--
PERMIT NO.
DOC TYPE
❑FINAL PERMIT
❑ MONITORING INFO
APPLICATION
11 COMPLIANCE
❑ OTHER
DOC DATE
❑ ��-I 1 D
YYYYMMDD

Permit Dumber NCS000592
Program Category
NPDES SW
Permit Type
Stormwater Discharge, Individual
Primary Reviewer
robert.patterson
Coastal SWRule
Central Files: APS _ SWP ✓
10J2J2017
Permit Tracking Slip
Status
Project Type
Active
New Project
Version
Permit Classification
1.00
Individual
Permit Contact Affiliation
RECIZI ED
Permitted Flow
OCT 03 2017
Facility
CENTRAL FILES
Facility Name
Major/Minor
Region
Culpeper Of Roanoke Rapids
Minor
Raleigh
Location Address
County
2262 W 10th St
Halifax
Roanoke Rapids
Owner
NC 27870
Facility Contact Affiliation
Billy Rodgers
2262 W 10th St
Ronok Rpd Afs NC - 27870
Owner Name Owner Type
Culpeper of Roanoke Rapids Non-Govemment
Owner Affiliation
Billy Rodgers
2262 W 10th St
Dates/Events Ronok Rpd Afs NC 27870
Scheduled
Orig Issue App Received Draft Initiated Issuance Public Notice Issue Effective Expiration
10/2/2017 6/5/2017 7/12/2017 8/15/2017 10/2/2017 10/212017 9/30/2022
Regulated Activities Requested /Received Events
Wood treatment w w Region comments on draft requested 7/13117
Region comments on draft received 7131/17
Outfal l 001
Waterbody Name Streamindex Number Current Class Subbasln
Chockoyotte Creek 23-29 C 03-02-08
Outfal I 002
Waterbody Name Streamindex Number Current Class Subbasln
Chockoyotte Creek 23-29 C 03-02-08

AFFIDAVIT OF PUBLICATION RANDY GILBERT
being first duly sworn,
STATE OF NORTH CAROLINA deposes and says: That (he) (she) is the Agent to the
COUNTY OF HALIFAX Publisher of THE DAILY HERALD newspaper printed and
published five days a week in the County of Halifax, State
of North Carolina, and of general circulation in the city of
P--NCDIV'OFENERGY, Roanoke Rapids, County of Halifax, State of North Carolina
MINERAL AND LAND � and elsewhere, and thehereto attached:
RESOURCES"``
INTENT To; ISSUE A.
ST©RMWATER DISCHARGE PUBLIC NOTICE TO
PERMIT ISSUE STORM
''Pubiic'comment'or.`objectibn to DISCHARGE PERMIT
"tW'draft permit(s) 'is- invited. CULPEPER
i'Subhiit written comments -;to
DEMILR; at the address -below.
All- ;rents xeceivea. Dior -to was printed and published correctly in the regular and entire
5epternber 15,.. 2017 will be
Considered in the 'final detertrii- issue of said THE DAILY HERALD for 1 issues, that.the first
7-n'ation' regarding pefriiits"issi! 15th AUGUST 17
ance'.and permit provisions: was made on the day ofAUGUST
Application: Cuipep�e�r„of �Ro 15th
! ,, Rapids, �'s2 west ,off and the last publication was made on the day of
Roanoke-' Rapids;' -'NC'
27878`° has applied for an AUGUST 20 17 that said publication
1,NPDES: permit ito, discharge
m p
storrnwater froan• industrial
facility at the above address in was made on each of the following dates, to wit:
Halifax County. The facility
bis'Aarges to .. Chockoyotte 0 8 / 15 / 17 [�
':'�C€eekgin the Roanoke River
ryStormwater Program Contact:
q&c
Rotiert'Patterson
(919),807-6369
Robert.Fatterson@ncdenngov Request of
NCDEQ/DEMLR �r�RpQU9(f�
coPY.of the;draft:,permit, Paly He/fj
NGS000592; is, available. at:W
htw'ov/atoutivi-•ionsienergyln onallMe; sourcesle_ventsr: Adtional A
dL:
,DEMLR,Stormwate€ Program
512 N. Salisbury Street.
1612 Mad Service Center
k Ratel9h.-.rNC 2Z699-1612
�� ? ?FM
',tAugiistE15�20t7fY(�ssU3 � j
ffi togR F: bof'3
r
BY
Subscribed sworn to before me this
20
17
r
Notary Signatu
0
�. tit
15th , T .IUGitI
CO
Notary Public in and for the County of Y Halifax, tat f h ling
M Commission Expires: V.4 (ofInlsstcn jXPIfes °ay" ° bar

Energy, Mineral
and Land Resources
ENVIRONMENTAL QUALITY
July 31, 2017
Mr. Billy Rodgers
Culpeper of Roanoke Rapids
2262 West 10'h Street
Roanoke Rapids, NC 27870
Dear Mr. Rodgers:
ROY COOPER
Govenror
MICHAEL S. REGAN
Secrekrn
TRACY DAVIS
Director
Subject: Draft NPDES Stormwater Permit
Permit No. NCS000592
Culpeper of Roanoke Rapids
Halifax County
Enclosed with this letter is a copy of the draft stormwater permit for your facility. Please review the
draft very carefully to ensure a thorough understanding of the conditions and requirements it contains.
The draft permit contains the following significant items:
i. Benchmarks are included for the following parameters: BOD, COD, Arsenic, Chromium,
Copper, TSS, and pH. Stormwater benchmarks are not permit limits but are guidelines for
implementing the Stormwater Pollution Prevention Plan (SPPP). A benchmark exceedance is
NOT a permit violation; however, the permittee must respond to exceedances as directed in the
Tiers.
2. You are required to collect analytical and qualitative monitoring samples during a "measureable
storm event" as defined in Part H, Section B.
3. Vehicle maintenance monitoring parameters are included. "Non -Polar Oil & Grease" by Method
1664 (SGT-HEM) is included. This requirement appears in all individual stormwater permits;
however, it only applies to facilities that perform vehicle maintenance activities (VMA) on -site.
If the facility begins vehicle maintenance during the permit cycle, the requirements shall apply.
Also, pH monitoring is not required for discharges only associated with VMA.
4. Requirements for the Stormwater Pollution Prevention Plan have been updated in Part II, Section
A.
Please submit any comments to me no later than thirty (30) days following your receipt of the draft.
Comments should be sent to the address listed on the front page of this letter. If no adverse
comments are received from the public or from you, this permit will likely be issued in about two
months.
If you have any questions or comments concerning this draft permit, contact me at [phone] or
[e-mail]
State of North Carolina I Fmiromnental Quality I Faergy, Mineral and Land Resmuces
1612 Mail Service Center 1 512 North Salisbury Street I Raleigh, NC 27699-1612
919 707 9200 T

Mr. Rodgers
NCS000592,2017
Page 2 of 2
cc: Raleigh Regional Office
Stormwater Program
Attachments
Sincerely,
Robert D. Patterson, PE
Environmental Engineer
Stormwater Program
State of Nw& C=I= I Em im=mW QuiWj Enemy. M-W wdLsnd
16121M Sft*e Curter 1 5121 IlhS&bdmyStmet 1 diakith, wX 27699.1612
919 707 9200 T

NCS000592
9
STATE OF NORTH CAROLINA
n
DEPARTMENT OF ENVIRONMENTAL QUALITY
DIVISION OF ENERGY, MINERAL, AND LAND RESOURCES
C
o
x
r
PERMIT 4
ar"a
o'
co
TO DISCHARGE STORMWATER UNDER THE
'
_
o
C)
MONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM10
In compliance with the provisions of North Carol { ` General Statute 143-215.1, other
lawful standards and regulations promulgated and adopted by,the North Carolina
Environmental Management Commission, and the,Federal Water Pollution Control Act, as
amended,
Culpeper oftRoano a Rapids, LLC
is hereby authorized to discharge stormwater from a facility located at
Culpeper of Roanoke Rapids
,2262 West 10th Street
Roanoke Rapids, NC
Halifax County
to receiving waters designated as Chockoyotte Creek, a class C stream in the Roanoke River
Basin, in accordance with the discharge limitations, monitoring requirements, and other
conditions set forth in Parts I,1I, II1, and IV hereof.
Note: Draft Permit Dates are Approximate
This permit shall become effective [November 1, 2017].
This permit and the authorization to discharge shall expire at midnight on [October 31,
2022].
Signed this day [December 20, 2017].
for Tracy E. Davis, P.E., CPM, Director
Division of Energy, Mineral and Land Resources
By the Authority of the Environmental Management Commission

Permit No. NCS000592
PART-10
Section A:
Section B:
Section C:
PART II
Section A:
Section B:
Section C:
Section D:
Section E:
TABLE OF CONTENTS
INTRODUCTION
Individual Permit Coverage
Permitted Activities
Location Map
MONITORING, CONTROLS, AND LIMITATI01
DISCHARGES
Stormwater Pollution Prevention Up-
s
D
Analytical Monitoring Requii17el
rem�en ,
l/
Qualitative Monitoring Requirements
R PERMITTED
On -Site Vehicle�Mante ante Monitoring Requirements
Special Condid. ns
PART III STANDARD CONDITIONS FOR NPDES STORMWATER INDIVIDUAL PERMITS
Section A: Compliance and Liability
1.
Compliance Schedule
2.
Duty to Comply
3.
Duty to Mitigate
4.
Civil and Criminal Liability
5.
Oil and Hazardous Substance Liability
6.
Property Rights
7.
Severability
8.
Duty to Provide Information
9.
Penalties for Tampering
10.
Penalties for Falsification of Reports
11.
Onshore or Offshore Construction
12.
Duty to Reapply
i

Permit No. NC5000592
Section B: General Conditions
1.
Permit Expiration
2.
Transfers
3.
Signatory Requirements
4.
Permit Modification, Revocation•and Reissuance, or Termination
S.
Permit Actions
6.
Annual Administering and Compliance Monitoring Fee
Requirements
f'
Section C: Operation
p
1.
and Maintenance of Pollution Controls
Operation �`
Proper and Maintenance
2.
Need to Halt or Reduce No0 Defense
3.
Bypassing of Stormwat�er Cont o� acilities
Yp g ,�
Section D: Monitoring and Records
1.
2.
Representativ ,Sampli ng
Recor iiig- Results
3.
Flow Measurements
A
4.
Testv?rocedures
give
5.
Repesen Outfall
6.
Re ords'Retention
7.
Inspection and Entry
Section E: Reporting
Requirements
1.
Discharge Monitoring Reports
2.
Submitting Reports
3.
Availability of Reports
4.
Non-Stormwater Discharges
5.
Planned Changes
6.
Anticipated Noncompliance
7.
Spills
8.
Bypass
9.
Twenty-four Hour Reporting
10.
Other Noncompliance
11.
Other Information
PART IV DEFINITIONS
M

Permit No. NCS000592
PART I INTRODUCTION
SECTION A: INDIVIDUAL PERMIT COVERAGE
During the period beginning on the effective date of the permit and lasting until expiration,
the permittee is authorized to discharge stormwater associated with industrial activity.
Such discharges shall be controlled, limited and monitored as specified in this permit.
If industrial materials and activities are not exposed to precipitation or runoff as described
in 40 CFR §122.26(g), the facility may qualify for a No Exposure Exclusion from NPDES
stormwater discharge permit requirements. Any owner�or operator wishing to obtain a No
Exposure Exclusion must submit a No Exposure Cer-tificatid"t Notice of Intent (NOI) form to
17
the Division; must receive approval by the Division; must�r�ntain no exposure conditions
unless authorized to discharge under a valid NPDES-aormwater permit; and must recertify
the No Exposure Exclusion annually. 1nN\"
SECTION B: PERMITTED ACTIVITIES
Until this permit expires or is ifiodiflid•'or revoked, the permittee is.authorized to discharge
stormwater to the surface waters of N-6fth,Carolina or separate storm sewer system that
1.)—\ \.
has been adequately treated and.managed,in accordance with the terms and conditions of
this permit. All stormwater discha ges shall be in accordance with the conditions of this
permit.
Any other point source discharge to surface waters of the state is prohibited unless it is an
allowable non-stormwater discharge or is covered by another permit, authorization, or
approval. The stormwater discharges allowed by this permit shall not cause or contribute
to violations of Water Quality Standards.
This permit does not relieve the permittee from responsibility for compliance with any
other applicable federal, state, or local law, rule, standard, ordinance, order, judgment, or
decree.
Part I Page 1 of 2

Permit No. NCS000592
PART II MONITORING, CONTROLS, AND LIMITATIONS FOR
PERMITTED DISCHARGES
SECTION A: STORMWATER POLLUTION PREVENTION PLAN
The permittee shall develop and implement a Stormwater Pollution Prevention Plan
(SPPP). The SPPP shall be maintained on site unless exempted from this requirement by
the Division. The SPPP is public information in accordance with Part I11, Standard
Conditions, Section E, paragraph 3 of this permit. The SPPP shall include, at a minimum,
the following items:
1. Site Overview. The Site Overview shall provide a description of the physical facility
and the potential pollutant sources that may belexpe wed, o co �ribute to
1-1
contamination of stormwater discharges. The Site,Qveiview-shall contain the following:
(a) A general location map (USGS quadrangle:fmap\dr appropriately drafted equivalent
map), showing the facility's location in relation to transportation routes and surface
waters; the name of the receiving waters to.whidthe stormwater outfalls
discharge, or if the discharge is to a'muriicipal separate storm sewer system, the
name of the municipality and the(tftiniate4�eceiving waters; and accurate latitude
and longitude of the poinrs.ofstormwater discharge associated with industrial
activity. The general location,map (or alternatively the site map) shall identify
whether any receiving/waters arefmpaired (on the state's 303(d) list of impaired
waters) or if the site is`located in a watershed for which a TMDL has been
established, and wliat the parameters of concern are.
(b) A narrative descripkion of storage practices, loading and unloading activities,
outdoor process areas, dust or particulate generating or control processes, and
waste disposal practices. A narrative description of the potential pollutants that
could be expected to be present in the stormwater discharge from each outfall.
(c) A site map drawn at a scale sufficient to clearly depict: the site property boundary;
the stormwater discharge outfalls; all on -site and adjacent surface waters and
wetlands; industrial activity areas (including storage of materials, disposal areas,
process areas, loading and unloading areas, and haul roads); site topography and
finished grade; all drainage features and structures; drainage area boundaries and
total contributing area for each outfall; direction of flow in each drainage area;
industrial activities occurring in each drainage area; buildings; stormwater Best
Management Practices (BMPs); and impervious surfaces. The site map must
indicate the percentage of each drainage area that is impervious, and the site map
must include a graphic scale indication and north arrow.
(d) A list of significant spills or leaks of pollutants during the previous three (3) years
and any corrective actions taken to mitigate spill impacts.
Part 11 Page 1 of 14

Permit No. NCS000592
(e) Certification that the stormwater outfalls have been evaluated for the presence of
non-stormwater discharges. The permittee shall re -certify annually that the
stormwater outfalls have been evaluated for the presence of non-stormwater
discharges. The certification statement will be signed in accordance with the
requirements found in Part III, Standard Conditions, Section B, Paragraph 3.
2. Stormwater Management Strategy. The Stormwater Management Strategy shall
contain a narrative description of the materials management practices employed which
control or minimize the stormwater exposure of significant materials, including
structural and nonstructural measures. The Stormwater Management Strategy, at a
minimum, shall incorporate the following:
(a) Feasibility Study. A review of the technical and
the methods of operations and/or storage practi
of materials and processes to rainfall and run-on
permittee shall prevent exposure of all storage a
and manufacturing or fueling operations. mare
not practical, this review shall document.the fea,
run-on away from areas of potential contaminati
•onomic feasibility of changing
s to eliminate or reduce exposure
bw\Wherever practical, the
as material handling operations,
where elimination of exposure is
dity of diverting the stormwater
(b) Secondary Containment Requiremen"ttss afid Records. Secondary containment is
required for: bulk storage of lid materials: storage in any amount of Section 313
of Title ll[ of the SuperfunAm`endments and Reauthorization Act (SARA) water
ri ri chemicals; and storagei:n any amount of hazardous substances, in order to
prevent leaks and spills from contaminating stormwater runoff. A table or summary
of all such tanks and�stored materials and their associated secondary containment
areas shall be maintained..,If'the secondary containment devices are connected to
stormwater conveyance�systems, the connection shall be controlled by manually
activated valves or other similar devices (which shall be secured closed with a
locking mechanism). Any stormwater that accumulates in the containment area
shall be at a minimum visually observed for color, foam, outfall staining, visible
sheens and dry weather flow, prior to release of the accumulated stormwater.
Accumulated stormwater shall be released if found to be uncontaminated by any
material. Records documenting the individual making the observation, the
description of the accumulated stormwater, and the date and time of the release
shall be kept for a period of five (5) years. For facilities subject to a federal oil Spill
Prevention, Control, and Countermeasure Plan (SPCC), any portion of the SPCC Plan
fully compliant with the requirements of this permit may be used to demonstrate
compliance with this permit. The Division may allow exceptions to secondary
containment requirements for mobile refuelers, as with the exemption provided by
amendments to federal SPCC regulations, as long as appropriate spill containment
and/or diversionary structures or equipment is used to prevent discharge to surface
waters. Exceptions do not apply to refuelers or other mobile tankage used primarily
as bulk liquid material storage in a fixed location in place of stationary containers.
(c) BMP Summary. A listing of site structural and non-structural Best Management
Practices (BMPs) shall be provided. The installation and implementation of BMPs
Part 11 Page 2 of 14

Permit No. NCS000592
shall be based on the assessment of the potential for sources to contribute
significant quantities of pollutants to stormwater discharges and on data collected
through monitoring of stormwater discharges. The BMP Summary shall include a
written record of the specific rationale for installation and implementation of the
selected site BMPs. The BMP Summary shall be reviewed and updated annually.
3. Spill Prevention and Response Procedures. The Spill Prevention and Response
Procedures (SPRP) shall incorporate an assessment of potential pollutant sources based
on a materials inventory of the facility. Facility personnel responsible for implementing
the SPRP shall be identified in a written list incorporated into the SPRP and signed and
dated by each individual acknowledging their responsibilities for the plan. A
responsible person shall be on -site at all times during facility operations that have
increased potential to contaminate stormwater runoff through spills or exposure of
materials associated with the facility operations ATh SPRP must be site stormwater
specific. Therefore, an oil Spill Prevention Conerol aniKb ntermeasure plan (SPCC)
may be a component of the SPRP, but may not be•sufffici nt.to completely address the
stormwater aspects of the SPRP. The commonelements of the SPCC with the SPRP may
be incorporated by reference into the SPRP.
si X /
4. Preventative Maintenance and Goodklousekeeping Program. A preventative
maintenance and good housekeeping progr`amAall be developed and implemented.
The program shall address �a7lstormwateLcontral systems [if applicable], stormwater
discharge outfalls, all on -site and adjacent surface waters and wetlands, industrial
activity areas (including material storage areas, material handling areas, disposal areas,
process areas, loading andunloadingareas, and haul roads), all drainage features and
structures, and existing�structural�BMPs. The program shall establish schedules of
inspections, maintenance and4ii/ousekeeping activities of stormwater control systems,
as well as facility equipment; facility areas, and facility systems that present a potential
for stormwater exposure or stormwater pollution where not already addressed under
another element of the SPPP. Inspection of material handling areas and regular
cleaning schedules of these areas shall be incorporated into the program. Timely
compliance with the established schedules for inspections, maintenance, and
housekeeping shall be recorded and maintained in the SPPP.
S. Facility Inspections. Inspections of the facility and all stormwater systems shall occur
as part of the Preventative Maintenance and Good Housekeeping Program at a
minimum on a semi-annual schedule, once during the first half of the year (January to
June), and once during the second half [July to December), with at least 60 days
separating inspection dates (unless performed more frequently than semi-annually).
These facility inspections are different from, and in addition to, the stormwater
discharge characteristic monitoring at the outfalls required in Part I1 B, C, and D of this
permit.
6. Employee Training. Training programs shall be developed and training provided at a
minimum on an annual basis for facility personnel with responsibilities for: spill
response and cleanup, preventative maintenance activities, and for any of the facility's
operations that have the potential to contaminate stormwater runoff. The facility
Part 11 Page 3 of 14

Permit No. NCS000592
personnel responsible for implementing the training shall be identified, and their
annual training shall be documented by the signature of each employee trained.
7. Responsible Party. The SPPP shall identify a specific position or positions responsible
for the overall coordination, development, implementation, and revision of the SPPP.
Responsibilities for all components of the SPPP shall be documented and position
assignments provided.
8. SPPP Amendment and Annual Update. The permittee shall amend the SPPP
whenever there is a change in design, construction, operation, site drainage,
maintenance, or configuration of the physical features which may have a significant
effect on the potential for the discharge of pollutants to surface waters. All aspects of
the SPPP shall be reviewed and updated on an annua basis. The annual update
shall include:
(a) an updated list of significant spills or,leaks of pollutants for the previous three
(3) years, or the notation that no spills.have occurred (element of the Site
Overview);
(b) a written re -certification that the §tonormwater outfalls have been evaluated far
the presence of non-stormwater discharges (element of the Site Overview);
(c) a documented re-evaluation of the effectiveness of the on -site stormwater
BMPs (BMP Summary eleirient�of the Stormwater Management Strategy).
(d) a review and comparison ofsample analytical data to benchmark values (if
applicable) over the.past.yearincluding a discussion about Tiered Response
status. The permittee shall use the Division's Annual Summary Data
Monitoring Report (DMR) form, available from the Stormwater Permitting
Program's web'site,(See'Monitoring Forms' here:
mineral- land -permits/ stormwater-permits/npdes-industria l-sw).
The Director may notify the permittee when the SPPP does not meet one or more of the
minimum requirements of the permit. Within 30 days of such notice, the permittee
shall submit a time schedule to the Director for modifying the SPPP to meet minimum
requirements. The permittee shall provide certification in writing (in accordance with
Part III, Standard Conditions, Section B, Paragraph 3) to the Director that the changes
have been made.
9. SPPP Implementation. The permittee shall implement the Stormwater Pollution
Prevention Plan and all appropriate BMPs consistent with the provisions of this permit,
in order to control contaminants entering surface waters via stormwater.
Implementation of the SPPP shall include documentation of all monitoring,
measurements, inspections, maintenance activities, and training provided to
employees, including the log of the sampling data and of actions taken to implement
BMPs associated with the industrial activities, including vehicle maintenance activities.
Such documentation shall be kept on -site for a period of five (5) years and made
available to the Director or the Director's authorized representative immediately upon
request.
Part II Page 4 of 14

Permit No. NCS000592
SECTION B: ANALYTICAL MONITORING REQUIREMENTS
Analytical monitoring of stormwater discharges shall be performed as specified in Table 1.
All analytical monitoring shall be performed during a measureable storm event at each
stormwater discharge outfall (SDO). Only SDOs discharging stormwater associated with
industrial activity must be sampled (See Definitions).
A measurable storm event is a storm event that results in an actual discharge from the
permitted site outfall. The previous measurable storm event must have been at least 72 hours
prior. The 72-hour storm interval does not apply if the permittee is able to document that a
shorter interval is representative for local storm events during the sampling period, and the
permittee obtains approval from the local DEMLR Regional Engineer. See D�'rnitions.
Table 1. Analytical Monitoring Re uirement�s &
Parameter
Discharge
-
Measurement
Sample
Sample
_Code
- _
Characteristics >
Units
Fre uen
T eZ
Location3
310
Biochemical Oxygen Demand
n
,
i-annual
Grab
SDO
mgti,.
340
Chemical Oxygen Demand
semi-annual
Grab
SDO
�
.L
COD � .,.
, �
1002
Arsenic, Total Re ov abl \;:\
> m L
semi-annual
Grab
I SDO
1034
Chromium, Totall J
Grab
SDO
mg/L
semi-annual
Recoverable
1119
f
Copper, TotahR` ecove/r�able
m Lsemi-annual
Grab
SDO
530
Total Suspended Solids (TSS)
m L
semi-annual
Grab
SDO
400
pH
standard
semi-annual
Grab
SDO
46529
Total Rainfall¢
inches
semi-annual
Rain
-
Gauge
Footnotes:
1 Measurement Frequency: Twice per year (unless other provisions of this permit prompt monthly
sampling) during a measureable storm event, until either another permit is issued for this facility or until
this permit is revoked or rescinded. If the facility is monitoring monthly because of Tier Two or Three
response actions under the previous permit, the facility shall continue a monthly monitoring and
reporting schedule in Tier Two or Tier Three status until relieved by the provisions of this permit or
the Division.
2 Grab samples shall be collected within the first 30 minutes of discharge. When physical separation between
outfalls prevents collecting all samples within the first 30 minutes, sampling shall begin within the first 30
minutes, and shall continue until completed.
3 Sample Location: Samples shall be collected at each stormwater discharge outfall (SDO) unless
representative outfall status (ROS) has been granted. A copy of the Division's letter granting ROS shall be
kept on site.
4 For each sampled measureable storm event, the total precipitation for the entire event must be recorded.
An on -site rain gauge is required. Where isolated sites are unmanned for extended periods of time, a local
rain gauge reading may be substituted for an on -site reading.
Part 11 Page 5 of 14

Permit No. NCS000592
The permittee shall complete the analytical samplings in accordance with the schedule
specified below in Table 2, unless adverse weather conditions prevent sample collection
(see Adverse Weather in Definitions). Sampling is not required outside of the facility's
normal operating hours. A minimum of 60 days must separate Period 1 and Period 2
sample dates, unless monthly monitoring has been instituted under a "Tier Two"
response. Inability to sample because of adverse weather conditions must be documented
in the SPPP and recorded on the DMR. The permittee must report the results from each
sample taken within the monitoring period (see Part 111, Section E). However, for purposes
of benchmark comparison and Tiered response actions, the permittee shall use the
analytical results from the first sample with valid results thin the monitoring period.
Table 2. Monitorin Schedule
Monitoring periodl.z
Sample Number
Start
End
Year 1- Period 1
1
Jan`uary�l, 2018
June 30, 2018
Year 1-Period 2
2
Z7 July�1,,2018
December 31, 2018
Year 2 - Period 1
3
Manua yi 1, 2019
June 30, 2019
Year 2 - Period 2
4 f
// ,July 1, 2019
December 31, 2019
Year 3 - Period 1
5 /�
`;January 1, 2020
June 30, 2020
Year 3 - Period 2
"6,
July 1, 2020
December 31, 2020
Year 4 - Period 1
7,
January 1, 2021
June 30, 2021
Year 4 - Period 2
8 )i\%
July 1, 2021
December 31, 2021
Year 5 - Period 1
9,/%
January 1, 2022
June 30, 2022
Year 5 - Period 2
�j1b
July 1, 2022
October 31, 2022
Footnotes:
1 Maintain semi-annual monitoring until either another permit is issued for this facility or until this
permit is revoked or rescinded. The permittee must submit an application for renewal of coverage
before the submittal deadline (180 days before expiration) to be considered for renewed coverage
under the permit. The permittee must continue analytical monitoring throughout the permit
renewal process, even if a renewal permit is not issued until after expiration of this permit.
2 If no discharge occurs during the sampling period, the permittee must submit a monitoring report
indicating "No Flow" or "No Discharge" within 30 days of the end of the sampling period.
Failure to monitor semi-annually per permit terms may result in the Division requiring
monthly monitoring for all parameters for a specified time period. "No discharge" from an
outfall during a monitoring period does not constitute failure to monitor, as long as it is
properly recorded and reported.
The permittee shall compare monitoring results to the benchmark values in Table 3.
Exceedances of benchmark values require the permittee to increase monitoring, increase
management actions, increase record keeping, and/or install stormwater Best Management
Practices (BMPs) in a tiered program. See below the descriptions of Tier One, Tier Two, and
Tier Three response actions below. In the event that the Division releases the permittee from
continued monthly monitoring and reporting under Tier Two or Tier Three, the Division's
Part 11 Page 6 of 14

Permit No. NCS000592
release letter may remain in effect through subsequent reissuance of this permit, unless the
release letter provides for other conditions or duration.
Table 3. Benchmark Values for Analytical Monitoring
Discharge Characteristics
Units
Benchmark
Biochemical Oxygen Demand (BOD)
mg/L
30
Chemical Oxygen Demand (COD)
mg/L
120
Arsenic, Total Recoverable
mg/L
0.34
Chromium, Total Recoverable
mg/L AL,
0.905
Copper, Total Recoverable
mg �
6 0.010
Total Suspended Solids (TSS)
mg/�€�''
NOV 100
pH
stanclar`
6-9
The benchmark values in Table 3 are gi
implementation of the permittee's SPPP
is not a permit violation; however, fa
N IV
permit is a violation of permit conditiioonn
rs but should be used as guidelines for
nce of a stormwater benchmark value
d to the exceedance as outlined in this
Part 11 Page 7 of 14

Permit No. NCS000592
Tier One =
If: The first valid sampling results are above a benchmark value, or outside of the benchmark range, for any
parameter at any outfall;
Then: The permittee shall:
1. Conduct a stormwater management inspection of the facility within two weeks of receiving sampling
results.
2. Identify and evaluate possible causes of the benchmark value exceedance.
3. Identify potential, and select the specific feasible: source controls, operational controls, or physical
improvements to reduce concentrations of the parameters of concern, and/or to bring concentrations
within the benchmark range.
4. Implement the selected feasible actions within two months of the inspection.
5. Record each instance of a Tier One response in the SPPP. Include the date and value of the benchmark
exceedence, the inspection date, the personnel conducting the inspection, the selected actions, and the
date the selected actions were implemented.
6. Note: Benchmark exceedances for a different parameter se rate] trigger a tiered response.
Tier Two
If: The first valid sampling results from two consecutive mo44E�,�tg�ring periods (omitting periods with no
discharge) are above the benchmark values, or outside-ofathe`tienchmark range, for any specific parameter at
a specific discharge outfall;
Then: The permittee shall:
1. Repeat all the required actions outlined above in Tier. One.
2. Immediately institute monthly monitoring an&.r rtmg for all parameters. The permittee shall conduct
monthly monitoring at every outfall whece,a sampling result exceeded the benchmark value for two
consecutive samples. Monthly (anaIkQcatjfid qualitative) monitoring shall continue until three
consecutive sample results areAelow_th benchmark values or within benchmark range.
3. If no discharge occurs during�the sampling period, the permittee is required to submit a monthly
monitoring report indicating "No Floto comply with reporting requirements.
4. Alternatively, in lieu of ste s 2 ,..an the permittee may, after two consecutive exceedances, exercise the
PP Y
option of contacting the DEM1R'Regional Engineer as provided below in Tier Three. The Regional
Engineer may direct the response actions on the part of the permittee as provided in Tier Three,
including reduced or additional sampling parameters or frequency.
S. Maintain a record of the Tier Two response in the SPPP.
6. Continue Tier Two response obligations throughout the permit renewal process.
Tier Three
If: The valid sampling results required for the permit monitoring periods exceed the benchmark value, or
are outside the benchmark range, for any specific parameter at any specific outfall on four occasions, the
permittee shall notify the DEMLR Regional Engineer in writing within 30 days of receipt of the fourth
anal ical results;
Then: The Division may but is not limited to:
• require that the permittee revise, increase, or decrease the monitoring and reporting frequency for
some or all of the parameters herein;
• require sampling of additional or substitute parameters;
• require the permittee to install structural stormwater controls;
• require the permittee to implement other stormwater control measures;
• require the permittee to perform upstream and downstream monitoring to characterize impacts on
receiving waters; or
• require the permittee implement site modifications to qualify for a No Exposure Exclusion;
• require the permittee to continue Tier Three obligations through the permit renewal process.
Part 11 Page 8 of 14

Permit No. NCSO0O592
SECTION C: QUALITATIVE MONITORING REQUIREMENTS
The purpose of qualitative monitoring is to evaluate the effectiveness of the Stormwater
Pollution Prevention Plan (SPPP) and identify new potential sources of stormwater
pollution. Qualitative monitoring of stormwater outfalls must be performed during a
measurable storm event
Qualitative monitoring requires a visual inspection of each stormwater outfall regardless of
representative outfall status. Qualitative monitoring shall be performed semi-annually as
specified in Table 4, and during required analytical monitoring events (unless the permittee
is required to perform further qualitative monitoring per the Qualitative Monitoring
Response, below). Inability to monitor because of adverse weather conditions must be
documented in the SPPP and recorded on the Qualitative Monitoring Report form (see
Adverse Weather in Definitions). Only SDOs discharging stormwater associated with
industrial activity must be monitored (See Definitions)..
In the event an atypical condition is noted at a storinN
shall document the suspected cause of the condition a
the discovery. This documentation will be maintainec
Table 4. Qualitative
discharge outfall, the permittee
iy actions taken in response to
i the SPPP.
Discharge Characteristics
Frequencyl
Monitoring
Location2
Color
semi-annual
SDO
Odor
semi-annual
SDO
Clarity
semi-annual
SDO
Floating Solids
semi-annual
SDO
Suspended Solids
semi-annual
SDO
Foam
semi-annual
SDO
Oil Sheen
semi-annual
SDO
Erosion or deposition at the outfall
semi-annual
SDO
Other obvious indicators
of stormwater pollution
semi-annual
SDO
Footnote
1 Monitoring Frequency. Twice per year during a measureable storm event unless other provisions of this
permit prompt monthly monitoring. See Table 2 for schedule of monitoring periods through the end of
this permitting cycle. The permittee must continue qualitative monitoring throughout the permit renewal
process until a new permit is issued.
2 Monitoring Location: Qualitative monitoring shall be performed at each stormwater discharge outfall
(SDO) regardless of representative outfall status.
Part II Page 9 of 14

Permit No. NCS000592
A minimum of 60 days must separate monitoring dates, unless additional sampling has
been instituted as part of other analytical monitoring requirements in this permit.
If the permittee's qualitative monitoring indicates that existing stormwater BMPs are
ineffective, or that significant stormwater contamination is present, the permittee shall
investigate potential causes, evaluate the feasibility of corrective actions, and implement
those corrective actions within 60 days, per the Qualitative Monitoring Response, below.
A written record of the permittee's investigation, evaluation, and response actions shall be
kept in the Stormwater Pollution Prevention Plan.
ualitative Nidnit6ting Response
Qualitative monitoring is for the purposes of evaluatini SPPP effectiveness, identifying new potential
sources of stormwater pollution, and prompting Pe permttt&-!s.response to pollution. If the
permittee repeatedly fails to respond effectively "to orrecti•oblems identified by qualitative
monitoring, or if the discharge causes or contributes .a water quality standard violation, the
Division may but is not limited to:''
• require that the permittee revise, incre sedecrease the monitoring frequency for some
or all parameters (analytical or qualitative'}
• require the permittee to install structu� stormwater controls;
Er
• require the permittee to,implement other stormwater control measures;
• require the permittee ta:perfo upstream and downstream monitoring to characterize
impacts on receiving waters, o.rE.
• require the permittee .imp trite modifications to qualify for a No Exposure Exclusion.
SECTION D: ON -SITE VEHICLE MAINTENANCE MONITORING REQUIREMENTS
Facilities that have any vehicle maintenance activity occurring on-site'which uses more
than 55 galIons of new motor oil per month when averaged over the calendar year
shall perform analytical monitoring as specified below in Table S. All analytical
monitoring shall be performed during a measureable storm event at all stormwater
discharge outfalls (00s) that discharge stormwater runoff from vehicle maintenance areas,
and in accordance with the schedule presented in Table 2 (Section B).
Part II Page 10 of M

Permit No. NCS000592
Table 5. Analytical Monitoring Requirements for On -Site Vehicle Maintenance
Discharge Characteristics
Units
Measurement
Frequencyl
Sample
Type2
Sample
Location3
Non -Polar Oil & Grease by
EPA Method1664SGT-HEM
mg/L
semi-annual
Grab
SDO
Total Suspended Solids
m L
semi-annual
Grab
SDO
Total Rainfall4
inches
semi-annual
Rain gauge
New Motor Oil Usage
I gallons/month
1 semi-annual
I Estimate
I-
Footnotes:
1 Measurement Frequency: Twice per year during a measureable storm event (unless other provisions of
the permit prompt monthly sampling), until either another permit is issued for this facility or until this
permit is revoked or rescinded. See Table 2 for schedule o monitolng periods through the end of this
permitting cycle. If the facility is monitoring monthly because' 4eW Three response actions
under the previous permit, the facility shall continue a monthly mo�mfton.47
ng and reporting schedule in
r"-,. �- : -
Tier Two or Tier Three status until relieved by the provisions of this"permit or the Division.
2 Grab samples shall be collected within the first 30 minutess ofd s� charge. When physical separation
N.: '
between outfalls prevents collecting all samples withimthe..firstY30%minutes, sampling shall be begun within
the first 30 minutes, and shall continue until complete �v
3 Sample Location: Samples shall be collected at ach sto` ter discharge outfall (SDO) that discharges
stormwater runoff from area where vehicle aintenant activities occur, unless representative outfall
status (ROS) has been granted. A ppp�y of th'es�ette ng nting ROS shall be kept on site.
4 For each sampled measureable storm evetftthe total precipitation must be recorded. An on -site rain
gauge is required. Where isolated sites are unmanned for extended periods of time, a local rain gauge may
be substituted for an on -site reading
Failure to monitor semi -annually -per permit terms may result in the Division requiring
monthly monitoring for al1T'parameters for a specified time period, as provided in Part II
Section B.
Monitoring results shall be compared to the benchmark values in Table 6. The benchmark
values in Table 6 are not permit limits but should be used as guidelines for the permittee's
Stormwater Pollution Prevention Plan (SPPP). Exceedances of benchmark values require
the permiee to increase monitoring, increase management actions, increase record
keeping, and/or install stormwater Best Management Practices (BMPs), as provided in Part
II Section B.
Table 6. Benchmark Values for Vehicle Maintenance Analytical Monitoring
Discharge Characteristics
Units
Benchmark
Non -Polar Oil & Grease by
EPA Method1664 (SGT-HEM)
mg/L
15
Total Suspended Solids
mg/L
100
TSS (HQW, ORW, Tr, and PNA)
mg/L
50
Part 11 Page 11 of 14

Permit No. NCS000592
SECTION E: SPECIAL CONDITIONS
A (1.) ELECTRONIC REPORTING OF MONITORING REPORTS [G.S.143-215.1(b)]
Federal regulations require electronic submittal of all discharge monitoring reports
(DMRs) and program reports. The final NPDES Electronic Reporting Rule was adopted and
became effective on December 21, 2015.
NOTE: This special condition supplements or supersedes the following sections within
Part III of this permit (Standard Conditions for NPDES Permits):
1.
• Section B. (3.)
Signatory Requirements
• Section D. (6.)
Records Retention
• Section E. (1.)
Discharge Monitoring R(
• Section E. (2.)
Submitting Reports
a-u
Effective December 21, 2016 or when
to accept NPDES stormwater permit mi
discharge monitoring data electronic -all
Monitoring Report [eDMR)��nternet apt
when eDMR is ready to accept stormwi
y;s;electronic reporting system is able
iata, the permittee shall report
e NC DWR's Electronic Discharge
NC DEMLR will notify permittees
monitoring data.
Monitoring results obtained during,the previous month(s) shall be summarized for each
month and submitted electronicily using eDMR. The eDMR system allows permitted
facilities to enter monitoring -data and submit DMRs electronically using the internet.
Until such time that the state's eDMR application is compliant with EPA's Cross -Media
Electronic Reporting Regulation (CROMERR), permittees will be required to submit all
discharge monitoring data to the state electronically using eDMR and also will be
required to complete the eDMR submission by printing, signing, and submitting one
signed original and a copy of the computer printed eDMR to the following address:
NC Dept. of Environmental Quality
DWR Central Files
512 N. Salisbury St.
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
If a permittee is unable to use the eDMR system due to a demonstrated hardship or due
to the facility being physically located in an area where less than 10 percent of the
households have broadband access, then a temporary waiver from the NPDES
electronic reporting requirements may be granted and discharge monitoring data may
be submitted on paper DMR forms or alternative forms approved by the Director.
Duplicate signed copies shall be submitted to the mailing address above. See "How to
Request a Waiver from Electronic Reporting" section below.
Part 11 Page 12 of 14

Permit No. NCS000592
Regardless of the submission method, the first DMR is due no later than 30 days from
the date the facility receives the sampling results from the laboratory.
2. How to Request a Waiver from Electronic ftorting
The permittee may seek a temporary electronic reporting waiver from the Division. To
obtain an electronic reporting waiver, a permittee must first submit an electronic
reporting waiver request to the Division. Requests for temporary electronic reporting
waivers must be submitted in writing to the Division for written approval at least sixty
(60) days prior to the date the facility would be required under this permit to begin
submitting monitoring data and reports. The duration of a temporary waiver shall not
exceed 5 years and shall thereupon expire. At such time, monitoring data and reports
shall be submitted electronically to the Division unles§,the permittee re -applies for and
is granted a new temporary electronic reporting waiver by the Division. Approved
electronic reporting waivers are not trans ferra''v1�Only,p rmit-tees with an approved
reporting waiver request may submit monitoring data and -reports on paper to the
Division for the period that the approved reporting waiver request is effective.
Information on eDMR and the application"for'a�temporary electronic reporting waiver
are found on the following web page: 7/ r
3. Sienatory Reo ement?/1NmD-D1e-mL
B. (3.) (d)l
All eDMRs submitted tol,th�e.p�er�mrt issuing authority shall be signed by a person
described in Part I11, Section B. (1)(a) or by a duly authorized representative of that
person as described in Part II[, Section B. (1)(b). A person, and not a position, must be
delegated signatory authority for eDMR reporting purposes.
For eDMR submissions, the person signing and submitting the DMR must obtain an
eDMR user account and login credentials to access the eDMR system. For more
information on North Carolina's eDMR system, registering for eDMR and obtaining an
eDMR user account, please visit the following web page:
b.ttp:de .nc. gov.1about.ldivisions water -resources jedmr
Certification. Any person submitting an electronic DMR using the state's eDMR system
shall make the following certification [40 CFR 122.22]. NO OTHER STATEMENTS OF
CERTIFICATION WILL BE ACCEPTED:
7 certify, under penalty of law, that this document and all attachments were prepared
under my direction or supervision in accordance with a system designed to assure that
qualified personnel properlygather and evaluate the information submitted. Based on my
inquiry of the person or persons who manage the system, or those per sons directly
Part 11 Page 13 of 14

Permit No. NCS000592
responsible forgathering the information, the information submitted is, to the best of my
knowledge and belief, true, accurate, and complete. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations."
4. Records Retention_[Supplements Section D. (6.]1
The permittee shall retain records of all Discharge Monitoring Reports, including eDMR
submissions. These records or copies shall be maintained for a period of at least 3
years from the date of the report. This period may be extended by request of the
Director at any time [40 CFR 122.41].
Part 11 Page 14 of 14

Permit No. NCS000592
PART III STANDARD CONDITIONS FOR NPDES STORMWATER INDIVIDUAL PERMITS
SECTION A: COMPLIANCE AND LIABILITY
Compliance Schedule
The permittee shall comply with Limitations and Controls specified for stormwater discharges in
accordance with the following schedule:
Existing Facilities already operating but applying for permit coverage for the first time: The
Stormwater Pollution Prevention Plan shall be developed and implemented within 12 months of the
effective date of the initial permit and updated thereafter on an annual basis. Secondary
containment, as specified in Part 11, Section A, Paragraph 2(b) of this permit, shall be accomplished
within 12 months of the effective date of the initial permit issuance.
New Facilities applying for coverage for the first time: 7`he`Stormwater Pollution Prevention Plan
shall be developed and implemented prior to the be nninof discharges from the operation of the
industrial activity and be updated thereafter on an arinuahbas►s Secondary containment, as specified
in Part 1I, Section A, Paragraph 2(b) of this permit shall I�e accompll"shed prior to -the beginning of
stormwater discharges from the operation of the industpial'activity.
Existing facilities previously permitted
limitations, and controls contained in this
shall become effective immediately upon
Pollution Prevention Plan for this permit
months of the effective datef this 6"it
containment, as specified in Part Il; Sectio
prior to the beginning of storrmwater disci
Gappirfig.f6f renewal: All requirements, conditions,
nnii except new SPPP elements in this permit renewal)
ince ofAis permit. New elements of the Stormwater
wal-sfall be developed and implemented within 6
[-updated thereafter on an annual basis. Secondary
Paragraph 2(b) of this permit shall be accomplished
es from the operation of the industrial activity.
Duty to Coml& f� "
The permittee must comply withal conditions of this permit. Any permit noncompliance constitutes
a violation of the Clean Water Act(CWA) and is grounds for enforcement action; for permit
termination, revocation and reissuance, or modification; or denial of a permit upon renewal
application [40 CFR 122.41].
a. The permittee shall comply with standards or prohibitions established under section 307(a) of
the CWA for toxic pollutants within the time provided in the regulations that establish these
standards or prohibitions, even if the permit has not yet been modified to incorporate the
requirement [40 CFR 122.41].
b. The CWA provides that any person who violates section[s] 301, 302, 306, 307, 308, 318 or 405 of
the Act, or any permit condition or limitation implementing any such sections in a permit issued
under section 402, or any requirement imposed in a pretreatment program approved under
sections 402(a)(3) or 402(b)(8) of the Act, is subject to a civil penalty not to exceed $51,570 per
day for each violation [33 USC 1319(d) and 40 CFR 122.41(a)(2)].
c. The CWA provides that any person who negligently violates sections 301, 302, 306, 307, 308,
318, or 405 of the Act, or any condition or limitation implementing any of such sections in a
permit issued under section 402 of the Act, or any requirement imposed in a pretreatment
program approved under section 402(a)(3) or 402(b)(8) of the Act, is subject to criminal
penalties of $2,500 to $25,000 per day of violation, or imprisonment of not more than 1 year, or
both. In the case of a second or subsequent conviction for a negligent violation, a person shall be
subject to criminal penalties of not more than $50,000 per day of violation, or by imprisonment
of not more than 2 years, or both [33 USC 1319(c)(1) and 40 CFR 122.41(a)(2)].
Part III Page 1 of 9

Permit No. NCS000592
d. Any person who knowingly violates such sections, or such conditions or limitations is subject to
criminal penalties of $5,000 to $50,000 per day of violation, or imprisonment for not more than 3
years, or both. In the case of a second or subsequent conviction for a knowing violation, a person
shall be subject to criminal penalties of not more than $100,000 per day of violation, or
imprisonment of not more than 6 years, or both [33 USC 1319(c)(2) and 40 CFR 122.41(a)(2)].
e. Any person who knowingly violates section 301, 302, 303, 306, 307, 308,318 or 405 of the Act,
or any permit condition or limitation implementing any of such sections in a permit issued under
section 402 of the Act, and who knows at that time that he thereby places another person in
imminent danger of death or serious bodily injury, shall, upon conviction, be subject to a fine of
not more than $250,000 or imprisonment of not more than 15 years, or both. In the case of a
second or subsequent conviction for a knowing endangerment violation, a person shall be
subject to a fine of not more than $500,000 or by imprisonment of not more than 30 years, or
both. An organization, as defined in section 309(c)(3)(B)(iii)�of the CWA, shall, upon conviction
of violating the imminent danger provision, be subject to a4 a of not more than $1,000,000 and
can be fined up to $2,000,000 for second or subs6uentca victionst{40 CFR 122.41(a)(2)].
f. Under state law, a civil penalty of not more thari $25;000 per violation may be assessed against
any person who violates or fails to act in accordance with the terms, conditions, or requirements
of a permit [North Carolina General Statutes §-143- 2 U ].
g. Any person may be assessed an adn
301, 302, 306, 307, 308, 318 or 405
implementing any of such sections i
Administrative Dena lties�for_Class V
maximum amount of anyC
violations are not to excee,
with the maximum amoun
and 40 CFR 122.41(gJ 3)].
ffattiVie penalty by the Administrator for violating section
ti�ct, or, any permit condition or limitation
iermit-issued under section 402 of this Act.
Ehions are not to exceed $20,628 per violation, with the
yassessed not to exceed $51,570. Penalties for Class II
day for each day during which the violation continues,
II penalty not to exceed $257,848 [33 USC 1319(g)(2)
3. Duty to Mitigate 1__�
The permittee shall taklFreasonable steps to minimize or prevent any discharge in violation of this
permit which has a reasonable likelihood of adversely affecting human health or the environment [40
CFR 122.41(d)].
4. Civil and Criminal Liability
Except as provided in Part 111, Section C of this permit regarding bypassing of stormwater control
facilities, nothing in this permit shall be construed to relieve the permittee from any responsibilities,
liabilities, or penalties for noncompliance pursuant to NCGS 143-215.3,143-215.6, or Section 309 of the
Federal Act, 33 USC 1319. Furthermore, the permittee is responsible for consequential damages,
such as fish kills, even though the responsibility for effective Compliance may be temporarily
suspended.
5. Oil and H az rdous Substance Liability
Nothing in this permit shall be construed to preclude the institution of any legal action or relieve the
permittee from any responsibilities, liabilities, or penalties to which the permittee is or may be
subject to under NCGS 143-215.75 et seq. or Section 311 of the Federal Act, 33 USC 1321.
6. Property Rights
The issuance of this permit does not convey any property rights in either real or personal property,
or any exclusive privileges, nor does it authorize any injury to private property or any invasion of
personal rights, nor any infringement of federal, state or local laws or regulations [40 CFR 122.41(g)].
Part III Page 2 of 9

Permit No. NCS000592
7. SeyCrability
The provisions of this permit are severable, and if any provision of this permit, or the application of
any provision of this permit to any circumstances, is held invalid, the application of such provision to
other circumstances, and the remainder of this permit, shall not be affected thereby [NCGS 1508-231.
8. Duty to Provide Information
The permittee shall furnish to the Permit issuing Authority, within a reasonable time, any
information which the Permit Issuing Authority may request to determine whether cause exists for
modifying, revoking and reissuing, or terminating the permit issued pursuant to this permit or to
determine compliance with this permit The permittee shall also furnish to the Permit Issuing
Authority upon request, copies of records required to be kept by this permit [40 CFR 122.41(h)].
9. Penalties for Jampering
The Clean Water Act provides that any person who falsifies, tampers with, or knowingly renders
inaccurate, any monitoring device or method required to be maintained under this permit shall, upon
conviction, be punished by a fine of not more than $10,000 per_violation, or by imprisonment for not
more than two years per violation, or by both. If a conviction of a,persowis for a violation committed
I.r f/ NIZ .'p:_-1 lV
after a first conviction of such person under this paAa rqh, punishment is a fine of not more than
$20,000 per day of violation, or by imprisonment of� m\re than=4 years, or both [40 CFR 122.411.
10. Penalties for Falsification of Reports /�
The Clean Water Act provides that any person4L lkaibwi`gly makes any false statement,
representation, or certification in any record/or olrher document submitted or required to be
maintained under this permit, including mo niting�� ports or reports of compliance or
noncompliance shall, upon c nviction;.be pun shedby a fine of not more than $10,000 per violation,
or by imprisonment for notjmore thdn two years'per violation, or by both [40 CFR 122.41].
11.
This permit does not authosrike or apprdve the construction of any onshore or offshore physical
structures or facilities orflhe undertaking of any work in any navigable waters.
12. Duty to Reapply
If the permittee wishes to•coli an activity regulated by this permit after the expiration date of
this permit, the permittee must apply for and obtain a new permit [40 CFR 122.41(b)].
SECTION B: GENERAL CONDITIONS
1. Permit Expiration
The permittee is not authorized to discharge after the expiration date. In order to receive automatic
authorization to discharge beyond the expiration date, the permittee shall submit forms and fees as
are required by the agency authorized to issue permits no later than 180 days prior to the
expiration date, unless permission for a later date has been granted by the Director. (The Director
shall not grant permission for applications to be submitted later than the expiration date of the
existing permit) [40 CFR 122.21(d)]. Any permittee that has not requested renewal at least 180 days
prior to expiration, or any permittee that does not have a permit after the expiration and has not
requested renewal at least 180 days prior to expiration, will be subjected to enforcement procedures
as provided in NCGS §143-215.36 and 33 USC 1251 et seq.
Part ill Page 3 of 9

Permit No. NCS000592
2. Transfers
This permit is not transferable to any person without prior written notice to and approval from the
Director in accordance with 40 CFR 122.61. The Director may condition approval in accordance with
NCGS 143-215.1, in particular NCGS 143-215.1(b)(4)b.2., and may require modification or revocation
and reissuance of the permit, or a minor modification, to identify the new permittee and incorporate
such other requirements as may be necessary under the CWA [40 CFR 122.41(1)(3), 122.611 or state
statute. The Permittee is required to notify the Division in writing in the event the permitted
facility is sold or closed.
Sign: atory ReauiremCnts
All applications, reports, or information submitted to the Permitting Issuing Authority shall be signed
and certified [40 CFR 122.41(k)].
a. All permit applications shall be signed as follows:
(1) For a corporation: by a responsible corporate officer. Fofthe purpose of this Section, a
responsible corporate officer means: (a) a president, secretary, treasurer or vice president
of the corporation in charge of a principal busin'essNfunction.��
, or ny other person who
f/
performs similar policy or decision makingKnctions foi;the'rorporation, or (b) the manager
of one or more manufacturing, production, or operating facilities, provided, the manager is
authorized to make management decisionsywhichgovern the operation of the regulated
g` p �
facility including having the explicit or implicit d'uty.of making major capital investment
recommendations, and initiating and.directing•other comprehensive measures to assure
long term environmental compliance with�envizonmental laws and regulations; the manager
can ensure that the necessary sy�ins'ai e established or actions taken to gather complete
and accurate information forper mit application requirements; and where authority to sign
documents has been assigned or`delegated to the manager in accordance with corporate
procedures. `\�
(2) For a partnership or sole. proprietor%%%ship: by a general partner or the proprietor,
respectively; or
(3) For a municipality, state, federal, or other public agency: by either a principal executive
officer or ranking elected,official [40 CFR 122.221.
b. All reports required by the permit and other information requested by the Permit Issuing
Authority shall be signed by a person described in paragraph a. above or by a duly authorized
representative of that person. A person is a duly authorized representative only if:
(1) The authorization is made in writing by a person described above;
(2) The authorization specified either an individual or a position having responsibility for the
overall operation of the regulated facility or activity, such as the position of plant manager,
operator of a well or well field, superintendent, a position of equivalent responsibility, or an
individual or position having overall responsibility for environmental matters for the company.
(A duly authorized representative may thus be either a named individual or any individual
occupying a named position.); and
(3) The written authorization is submitted to the Permit Issuing Authority [40 CFR 122.22].
c. Changes to authorization: If an authorization under paragraph (b) of this section is no longer
accurate because a different individual or position has responsibility for the overall operation of
the facility, a new authorization satisfying the requirements of paragraph (b) of this section must
be submitted to the Director prior to or together with any reports, information, or applications to
be signed by an authorized representative [40 CFR 122.22].
Part III Page 4 of 9

Permit No. NCS000592
d. Certification. Any person signing a document under paragraphs a. or b. of this section, or
submitting an electronic report (e.g., eDMR), shall make the following certification [40 CFR
122.221. NO OTHER STATEMENTS OF CERTIFICATION WILL BE ACCEPTED:
"I certrtfy, under penalty of law, that this document and all attachments were prepared under my
direction orsupervision in accordance with a system designed to assure that qualified personnel
properlygather and evaluate the information submitted. Based on my inquiry of the person or
persons who manage the system, or those persons directly responsible forgathering the
information, the information submitted is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties far submitting false information,
including the possibility offrnesand imprisonmentfor knowing violations."
4. Permit Modification. Revocation and-Mssuance. or Termination
The issuance of this permit does not prohibit the Permit Issuing Authority from reopening and
modifying the permit, revoking and reissuing the permit, or terminating the permit as allowed by the
laws, rules, and regulations contained in Title 40, Code of Federal,Regulations, Parts 122 and 123;
Title 15A of the North Carolina Administrative Code, S{tbchiq ter 2H .0100; and North Carolina
General Statute 143-215.1 et al.i
6.
Permit Actions
The permit may be modified, revoked and
planned changes or anticipated noncompl
122.41(f)].
The permittee must pay the
after being billed by the Div]
NCAC 2H .0105(b)(2) may c
SECTION C: OPERATION AND
N
_11.,
!rminated for cause. The notification of
s)t�y'aany permit condition [40 CFR
andJrripliance monitoring fee within 30 (thirty) days
\pay the fee in timely manner in accordance with 15A
�n to initiate action to revoke the permit.
OF POLLUTION CONTROLS
The permittee shall at all times properly operate and maintain all facilities and systems of treatment
and control (and related appurtenances) which are installed or used by the permittee to achieve
compliance with the conditions of this permit. Proper operation and maintenance also includes
adequate laboratory controls and appropriate quality assurance procedures. This provision requires
the operation of back-up or auxiliary facilities or similar systems which are installed by a permittee
only when the operation is necessary to achieve compliance with the conditions of this permit [40
CFR 122.41(e)].
2. Need to Halt or Reduce Not a Def&nse
It shall not be a defense for a permittee in an enforcement action that it would have been necessary
to halt or reduce the permitted activity in order to maintain compliance with the condition of this
permit [40 CFR 122.41(c)].
3. Bypassing of StormwatCr Control FaCiliess
Bypass is prohibited and the Director may take enforcement action against a permittee for bypass
unless:
a. Bypass was unavoidable to prevent loss of life, personal injury or severe property damage; and
b. There were no feasible alternatives to the bypass, such as the use of auxiliary control facilities,
retention of stormwater, or maintenance during normal periods of equipment downtime or dry
weather. This condition is not satisfied if adequate backup controls should have been installed in
the exercise of reasonable engineering judgment to prevent a bypass which occurred during
normal periods of equipment downtime or preventive maintenance; and
Part III Page 5 of 9

Permit No. NCS000592
c. The permittee submitted notices as required under, Part III, Section E of this permit
If the Director determines that it will meet the three conditions listed above, the Director may
approve an anticipated bypass after considering its adverse effects.
SECTION D: MONITORING AND RECORDS
e es
Samples collected and measurements taken, as required herein, shall be characteristic of the volume
and nature of the permitted discharge. Analytical sampling shall be performed during a measureable
storm event Samples shall be taken on a day and time that is characteristic of the discharge. All
samples shall be taken before the discharge joins or is diluted by any other waste stream, body of
water, or substance. Monitoring points as specified in this permit shall not be changed without
notification to and approval of the Permit Issuing Authority [40 CFR 122.410)].
2, Recording Results /�
For each measurement or sample taken pursuant to the regmrement f this permit, the permittee
shall record the following information [40 CFR 122.41]
A_
a. The date, exact place, and time of sampling or measurements;
b. The individual(s) who performed the sampling m asu ements;
C. The date(s) analyses were performed;
d. The individuals) who performed the aan/al ses;
e. The analytical techniques -or methods used; and
f. The results of such analvse\s \ \ ��
3. Flow Measurements
Where required, appropriate flow measurement devices and methods consistent with accepted
scientific practices shall; a selected and used to ensure the accuracy and reliability of measurements
of the volume of monitgred'discharges.
4. Test Procedures
Test procedures for the analysis of pollutants shall conform to the EMC regulations published
pursuant to NCGS 143-215.63 et seq, the Water and Air Quality Reporting Acts, and to regulations
published pursuant to Section 304(g), 33 USC 1314, of the Federal Water Pollution Control Act, as
Amended, and Regulation 40 CFR 136.
To meet the intent of the monitoring required by this permit, all test procedures must produce
minimum detection and reporting levels and all data generated must be reported down to the
minimum detection or lower reporting level of the procedure. If no approved methods are
determined capable of achieving minimum detection and reporting levels below permit discharge
requirements, then the most sensitive (method with the lowest possible detection and reporting
level) approved method must be used.
5. Representative Outfall
If a facility has multiple discharge locations with substantially identical stormwater discharges that
are required to be sampled, the permittee may petition the Director for representative outfall status.
If it is established that the stormwater discharges are substantially identical and the permittee is
granted representative outfall status, then sampling requirements may be performed at a reduced
number of outfalls.
Part III Page 6 of 9

Permit No. NCS000592
6. Records Retention
Visual monitoring shall be documented and records maintained at the facility along with the
Stormwater Pollution Prevention Plan. Copies of analytical monitoring results shall also be
maintained on -site. The permittee shall retain records of all monitoring information, including
o all calibration and maintenance records,
o all original strip chart recordings for continuous monitoring instrumentation,
o copies of all reports required by this permit, including Discharge Monitoring Reports
(DMRs),
o copies of all data used to complete the application for this permit
These records or copies shall be maintained for a period of at least 5 years from the date of the
sample, measurement, report or application. This period may be extended by request of the Director
at any time [40 CFR 122.41].
7. InspCcti9n gnd
The permittee shall allow the Director, or an authorizedrepresentative (including an authorized
contractor acting as a representative of the Director)] or iri the case of facility which discharges
through a municipal separate storm sewer system, an authorized representative of a -municipal
operator or the separate storm sewer system receiving.the,discharge, upon the presentation of
11
credentials and other documents as may be required by la�to:
a. Enter upon the permittee's premises wher" "e�r / lated facility or activity is located or conducted,
or where records must be kept under the conditions of this permit;
b. Have access to and copy, at reasonable times, any records that must be kept under the conditions
of this permit;
c. Inspect at reasonable times any.facilities;,equipment (including monitoring and control
equipment), practices, or operations regulated or required under this permit; and
NI
d. Sample or monitor at reasonable times, for the purposes of assuring permit compliance or as
otherwise authorized,by the Clean Water Act, any substances or parameters at any location [40
CFR 122.41(i)]. / \ 1/�
SECTION E: REPORTING REQUIREMENTS
Samples analyzed in accordance with the terms of this permit shall be submitted to the Division on
Discharge Monitoring Report (DMR) forms provided by the Director or submitted electronically to
the appropriate authority using an approved electronic DMR reporting system (e.g., eDMR). DMR
forms are available on the Division's website (hUp://deg.nc.gQv/about/divisions/energy-mineral-
land-resources/energv-mineral-land-Dermits/stormwalu--Ilermits/nudes-industrial-swl.
Regardless of the submission method (paper or electronic), submittals shall be delivered to the
Division or appropriate authority no later than 30 days from the date the Facility receives the
sampling results from the laboratory.
When no discharge has occurred from the facility during the report period, the permittee is required
to submit a discharge monitoring report, within 30 days of the end of the specified sampling period,
giving all required information and indicating "NO FLOW" as per NCAC T15A 0213.0506.
if the permittee monitors any pollutant more frequently than required by this permit using test
procedures approved under 40 CFR Part 136 and at a sampling location specified in this permit or
other appropriate instrument governing the discharge, the results of such monitoring shall be
included in the data submitted on the DMR [40 CFR §122.41(1)].
Part III Page 7 of 9

Permit No. NCS00OS92
The permittee shall record the required qualitative monitoring observations on the SDO Qualitative
Monitoring Report form provided by the Division and shall retain the completed forms on site.
Qualitative monitoring results should not be submitted to the Division, except upon the Division's
specific requirement to do so. Qualitative Monitoring Report forms are available at the website
above.
2.. Submitting Deports
Two signed copies of Discharge Monitoring Reports (DMRs) shall be submitted to:
NC Dept of Environmental Quality
DWR Central Files
S12 N. Salisbury St
1617 Mail Service Center
Raleigh, NC 27699-1617
3. Availability of Reports
Except for data determined to be confidential under NCG541 3�215:3{a�) or Section 308 of the
Federal Act, 33 USC 1318, all reports prepared in accordance with -the terms of this permit shall be
available for public inspection at the offices of the I�Asioin".NAs required by the Act, analytical data
shall not be considered confidential. Knowingly
aking any false statement on any such report may
result in the imposition of criminal penalties as-proviXded forin NCGS 143-215.6E or in Section 309 of
the Federal Act
4. Non-StQrmwatCr Discharges
If the storm event monitored inlaccordance with -this permit coincides with a non-stormwater
discharge, the permittee shall�separately-monitor all parameters as required under all other
applicable discharge permits and.provide,this information with the stormwater discharge
monitoring report �� 1
5. Planned Changes f
The permittee shall give noticeld the Director as soon as possible of any planned changes at the
permitted facility which could significantly alter the nature or quantity of pollutants discharged [40
CFR 122.41(1)]. This notification requirement includes pollutants which are not specifically listed in
the permit or subject to notification requirements under 40 CFR Part 122.42 (a).
6. Anticipated Noncompliance
The permittee shall give advance notice to the Director of any planned changes at the permitted
facility which may result in noncompliance with the permit [40 CFR 122.41(1)(2)].
7. Snills
The permittee shall report to the local DEMLR Regional Office, within 24 hours, all significant spills
as defined in Part IV of this permit Additionally, the permittee shall report spills including: any oil
spill of 2S gallons or more, any spill regardless of amount that causes a sheen on surface waters, any
oil spill regardless of amount occurring within 100 feet of surface waters, and any oil spill less than
2S gallons that cannot be cleaned up within 24 hours.
8.Bypass
Notice [40 CFR 122.41(m)(3)]:
a. Anticipated bypass. If the permittee knows in advance of the need for a bypass, it shall submit
prior notice, if possible at least ten days before the date of the bypass; including an evaluation of
the anticipated quality and effect of the bypass.
b. Unanticipated bypass. The permittee shall submit notice within 24 hours of becoming aware of
an unanticipated bypass.
Part III Page 8 of 9

Permit No. NC5000592
9. Twenty-four Hour Reporting
a. The permittee shall report to the central office or the appropriate regional office any
noncompliance which may endanger health or the environment Any information shall be
provided orally within 24 hours from the time the permittee became aware of the circumstances.
A written submission shall also be provided within 5 days of the time the permittee becomes
aware of the circumstances.
10.
The written submission shall contain a description of the noncompliance, and its causes; the
period of noncompliance, including exact dates and times, and if the noncompliance has not
been corrected, the anticipated time compliance is expected to continue; and steps taken or
planned to reduce, eliminate, and prevent reoccurrence of the noncompliance [40 CFR
122.41(1)(6)].
b. The Director may waive the written report on a case-by-casebasis for reports under this section
if the oral report has been received within 24 hours.
c. Occurrences outside normal business hour in
Response personnel at [phone], (800)
Other Noncompliance
The permittee shall report all instances of
the time monitoring reports are submittec
pQed%to the Division's Emergency
or (9191 733-3300.
;not reported under 24 hour reporting at
1(I)(7)).
11. Other Information
Where the Permittee becom a are -hat it failed to submit any relevant facts in a permit
application, or submitted incorrect information_in a permit application or in any report to the
Director, it shall promptly sulmit-such,facts or information [40 CFR 122,41(1)(8)].
Part III Page 9 of 9

W
NCSOOOS92
PART IV DEFINITIONS
1. Act
See Clean Water Act
2. Adverse Weather
Adverse conditions are those that are dangerous or create inaccessibility for personnel, such as local
flooding, high winds, or electrical storms, or situations that otherwise make sampling impractical.
When adverse weather conditions prevent the collection of samples during the sample period, the
permittee must take a substitute sample or perform a visual assessment during the next qualifying
storm event Documentation of an adverse event (with date, time and written narrative) and the
rationale must be included with SPPP records. Adverse weaathe does not exempt the permittee from
having to file a monitoring report in accordance with the sampling schedule. Adverse events and
failures to monitor must also be explained and repotted on -.the eelevant�DMR.
3. Allowable Non-Stormwater Discharges
This permit regulates stormwater discharges. Howe
allowed in the stormwater conveyance system incluc
a. All other discharges that are authorized by a -nor
b. Uncontaminated groundwater, foundation dram
chemicals, springs, discharges of uncontaminate
flushings, water from footing drainsflows-from
c. Discharges resulting from fire -fighting or -fire -fig
4.
-stormwater discharges which shall be
EPstoririwater NPDES permit
s, air conditioner condensate without added
d potable water, waterline and fire hydrant
riparian habitats and wetlands.
hting training, or emergency shower or eye
wash as a result of use in,the event or an emergency.
Measures or practices used to reduce'the amount of pollution entering surface waters. BMPs may
take the form of a process, activity; or physical structure. More information on BMPs can be found at:
S. Baass
A bypass is the known diversion of stormwater from any portion of a stormwater control facility
including the collection system, which is not a designed or established operating mode for the facility.
6. Bulk Storage of Liquid products
Liquid raw materials, intermediate products, manufactured products, waste materials, or by-
products with a single above ground storage container having a capacity of greater than 660 gallons
or with multiple above ground storage containers located in close proximity to each other having a
total combined storage capacity of greater than 1,320 gallons.
7. Certificate of Coverage
The Certificate of Coverage (COC) is the cover sheet which accompanies a General Permit upon
issuance and lists the facility name, location, receiving stream, river basin, effective date of coverage
under any General Permit and is signed by the Director.
S. Clean Water Act
The Federal Water Pollution Control Act, also known as the Clean Water Act (CWA), as amended, 33
USC 1251, et seq.
9. Division or DEMLR
The Division of Energy, Mineral, and Land Resources, Department of Environmental Quality.
10. Director
The Director of the Division of Energy, Mineral, and Land Resources, the permit issuing authority.
Part IV Page 1 of 4

Permit No. NCS000592
11, Env �
The North Carolina Environmental Management Commission.
12. �a p1C
An individual sample collected instantaneously. Grab samples that will be analyzed (quantitatively
or qualitatively) must be taken within the first 30 minutes of discharge.
13. a oSUbstance
Any substance designated under 40 CFR Part 116 pursuant to Section 311 of the Clean Water Act
14. Landfill
A disposal facility or part of a disposal facility where waste is placed in or on land and which is not a
land treatment facility, a surface impoundment, an injection well, a hazardous waste long-term
storage facility or a surface storage facility. , /1
15. Measureable Storm Event
A storm event that results in an actual discharge frc
measurable storm event must have been at least 72
apply if the permittee is able to document that a sh`
events during the sampling period, and obtains app
copies of this information and a written request ietl
Office. After authorization by the DEMLR Regi nA
site in the permittee's SPPP. 15(11
16.
A stormwater collection
town.
�rriiifted•site outfall. The previous
r ior. The 72-hour storm interval may not
Orval is representative for local storm
ir�t�>the local DEMLR Regional Office. Two
be sent to the local DEMLR Regional
written approval letter must be kept on
area of local self-government such as a city or
17. No Exposure
A condition of no exposure means -that all industrial materials and activities are protected by a storm
resistant shelter or acceptable -storage containers to prevent exposure to rain, snow, snowmelt, or
runoff. Industrial materikls-or activities include, but are not limited to, material handling equipment
or activities, industrial machinery, raw materials, intermediate products, by-products, final products,
or waste products [40 CFR 122.26 (b)(14)]. DEMLR may grant a No Exposure Exclusion from NPDES
Stormwater Permitting requirements only if a facility complies with the terms and conditions
described in 40 CFR §122.26(g).
18. Notice of Intent
The state application form which, when submitted to the Division, officially indicates the facility's
notice of intent to seek coverage under a General Permit.
19. Pe[nit Issuing Authority
The Director of the Division of Energy, Mineral, and Land Resources (see "Director" above).
20. Permittee
The owner or operator issued this permit.
21. Point Source Discharge of Stormwater
Any discernible, confined and discrete conveyance including, but not specifically limited to, any pipe,
ditch, channel, tunnel, conduit, well, or discrete fissure from which stormwater is or may be
discharged to waters of the state.
Part IV Page 2 of 4 Pages

Permit No. NCS000592
22. Representative Outfall Status
When it is established that the discharge of stormwater runoff from a single outfall is representative of the
discharges at multiple outfalls, the Division may grant representative outfall status. Representative outfall
status allows the permittee to perform analytical monitoring at a reduced number of outfalls.
23. Secondar-y Containment
Spill containment for the contents of the single largest tank within the containment structure plus
sufficient freeboard to contain the 25-year, 24-hour storm event.
24. Section 313 Water Priority Chemical
A chemical or chemical category which:
a. Is listed in 40 CFR 372.65 pursuant to Section 313 of Title III of the Superfund Amendments and
Reauthorization Act (SARA) of 1986, also titled the Emergency Planning and Community Right -
to -Know Act of 1986;
b. Is present at or above threshold levels at a facility subject to SARA title III, Section 313 reporting
requirements; and
c. Meets at least one of the following criteria: n
i. Is listed in appendix D of 40 CFR part 122 on Table 114organic priority pollutants), Table
III {certain metals, cyanides, and phenols) or Ta\ IV (certain toxic pollutants and
hazardous substances);
ii. Is listed as a hazardous substance pursuant to won 311(b)(2)(A) of the CWA at 40 CFR
116.4;or
iii. Is a pollutant for which EPA has publishedacute or chronic water quality criteria.
25. Severe Proper Damage
Substantial physical damage to property, damage to the control facilities which causes them to
become inoperable, or substantial'and'per�manent loss of natural resources which can reasonably be
expected to occur in the absence,of.a bypass Severe property damage does not mean economic loss
caused by delays in production. '� _.
26. SigniftiInt Materials/ ` /�
Includes, but is not limited fo:•raw materials; fuels; materials such as solvents, detergents, and plastic
pellets; finished materials -such as metallic products; raw materials used in food processing or
production; hazardous substances designated under section 101(14) of CERCLA; any chemical the,
facility is required to report pursuant to section 313 of Title III of SARA; fertilizers; pesticides; and
waste products such as ashes, slag and sludge that have the potential to be released with stormwater
discharges.
27. Significant Spills
Includes, but is not limited to: releases of oil or hazardous substances in excess of reportable
quantities under section 311 of the Clean Water Act (Ref: 40 CFR 110.3and 40 CFR 117.3) or section
102 of CERCLA (Ref 40 CFR 302.4).
28. Stormwater Discharge Outfall (SDO)
The point of departure of Stormwater from a discernible, confined, or discrete conveyance, including
but not limited to, storm sewer pipes, drainage ditches, channels, spillways, or channelized collection
areas, from which stormwater flows directly or indirectly into waters of the State of North Carolina.
29. Stormwater Runoff
The flow of water which results from precipitation and which occurs immediately following rainfall
or as a result of snowmelt.
Part IV Page 3 of 4 Pages

Permit No. NCS000592
A , a I
30.Stormwater-Assoriated with Industrial Actift
The discharge from any point source which is used for collecting and conveying stormwater and
which is directly related to manufacturing, processing or raw material storage areas at an industrial
,site. Facilities considered to be engaged in "industrial activities" include those activities defined in
40 CFR 122.26(b)(14). The term does not include discharges from facilities or activities excluded
from the NPDES program.
31. Stormwater Pollution Prevention Plan
A comprehensive site -specific plan which details measures and practices to reduce stormwater
pollution and is based on an evaluation of the pollution potential of the site.
32. Total Maximum Daily Load (TMDL)
TMDLs are written plans for attaining and maintaining water quality standards, in all seasons, for a
specific water body and pollutant A list of approved TMDLs for the state of North Carolina can be
found at http://dQQ,nc•gQv/about/divisions/water-rmurces/plafininE/modeling-
assessmentltmdls. U
33. Toxic Pollutant
Any pollutant listed as toxic under Section 307(a)(I),6f the Clean Water Act
34. Vehicle Maintenance Activity
Vehicle rehabilitation, mechanical repairs, painting, fuefuli_ng; lubrication, vehicle cleaning operations,
or airport deicing operations. J/ �/ "),_/
35. Visible Sedimentation 17
Solid particulate matter, boti^nineral and organic, that has been or is being transported by water,
air, gravity, or ice from its site -of origin which can be seen with the unaided eye.
36.
The maximum 24-hour pTecipitatlon`e'vent expected to be equaled or exceeded, on the average, once
in 25 years.
Part IV Page 4 of 4 Pages

Energy, Mineral
and Land Resources
ENVIRONMENTAL QUALITY
RFrFIVED
JUL31 2011
DENR-LAND QUALITY
STORMWATER PERMITTING
ROY COOPER
Goremor
MICHAEL S. REGAN
SecremnT
TRACY DAVIS
Director
STAFF REVIEW AND EVALUATION
NPDES Stormwater Permit o
Regional Office: Raleigh 010
Owner/Company:
Facility Name:
NPDES Permit Number:
Expiration Date:
Facility Location:
Type of Activity:
SIC Code or Description:
Receiving Stream(s):
River Basin:
Stream Classification:
Proposed Permit
Requirements:
Culpeper of Roanoke Rapids, LLC O
Culpeper of Roanoke Rapids
NCS000592
N/A - New Permit
2262 West 10th St., Roanoke Rapids, NC (Halifax Co.)
Wood preserving
2491
Chockoyotte Creek
Roanoke River Basin, Sub -basin 03010107
C
See attached draft permit.
Response Requested by (Date): August 14, 2017
Central Office Staff Contact: Robert Patterson, [phone]
Central Office Review Summary:
1. General Info.: New operation & owner at an existing facility; currently being
reconstructed. Two existing stormwater detention basins are the only 2 SDO's (see site
drainage map in application).
2. Industrial Activities: Pressure treating various wood products with copper -based
solution (CCA). Treating solutions kept in AST's under roof. Wood storage both inside
& outside. Diesel fuel storage under roof & mobile units. Used oil products.
3. Receiving Waters: Receiving stream is not impaired. There is a TMDL for dissolved
State of North Carolina I Environmental Quality I Energy. Mineral and Land Resources
1612 Mail Service Center 1 512 North Salisbury Street I Raleigh, NC 27699-1612
919 707 9200 T
z
la

NCS000592
Page 2 of 3
oxygen for the Roanoke Rivbr''tnainstem, but not the receiving stream.
4. Threatened n Endangered S ecies: Coppery Emerald / Somatochlora georgiana - a
dragonfly/damselfly
5. Analytical and/or ggalitative m6nitorinid' uring-this past permit cycle: None - new
- operation
6. Rationale for monitoring parameters: Potential stormwater pollutants used and stored
on -site include 1) wood treatment chemicals [acids with very low pH < 1, copper
chromium arsenic (CCA)]; 2) diesel fuel; and 3) mold inhibitors [chlorothalonil].
Parameters in this draft permit are consistent with permits issued to similar wood
treatment facilities in NC.
s. 7. Permit Fmility. and Owner Contactsupdates:
® Confirmed contact information with permittee and updated BIMS if necessary.
Obtained e-mail addresses for each contact and updated BIMS.
Recommendations:
Based on the documents reviewed, the application information submitted on May 26 and
June 5, 2017 is sufficient to issue an Individual NPDES Stormwater Permit.
Central Office recommends reissuance of this permit with monitoring listed in the attached
draft permit. The proposed draft permit reflects the most recent individual stormwater
permit template and boiler plate language, incorporating revisions that are similar to the
industrial general permits recently issued.
Prepared by (Signature) ' ( Date 9 r 3 �y
Stormwater Permitting Supervisor c<_Date l3/'
for Mike Randall (acting)
Concurrence by Regional Office t k,09-�_ Date 1
4
RO DEMLR Supervisor w Y Date 0 _7 Zo r 7
StacecfNaa&Cuu6m I Fx%===WQuafiryjEnaU,NinealandLvARewames
1612 llU Seniee Curter j 512 NorihSah6wy$tmet j Rater, M 27699.1612
919 707 9200 T

NCS000592
Page 3 of 3
Regional Office Staff Comments (attach additional pages as necessary.
'P 6-+- - -
_
cal d ,6s�" /I N
i � c�
I cu,
OL
A(so, ,
,��, j ",lam � � °
State of � Groiim I EmiromnmW Quality] EnuU Mne al andi.:ad Rmases
1612NUSenice Ceattr 1 512 LTovb SdW=y5treet i Rak*6,1C 27G99.1612
919 707 9200 T

Patterson, Robert D
From: Strawbridge, Ray
Sent: Monday, June 12, 2017 4:20 PM
To: [e-mail]; Hunneke, William F; Burke, Don
Cc: Deaver, Melodi; Pope, Antoine R; Patterson, Robert D
Subject: NCR000169292, CULPEPER OF ROANOKE RAPIDS, LLC. Please use the original ID# for
the site: NCD101734598
ATTENTION: DO NOT USE RECENTLY ISSUED ID# NCR000169292 for Culpeper of Roanoke Rapids
It has come to our attention that Culpeper is located at the former Georgia-Pacific Treating site in Roanoke
Rapids identified in the EPA RCRAInfo database as ID# NCD101734598. The new number was issued in error.
Invoice #HW74241 was created as SQG and thus far has not been paid. FIMU will nullify the new ID#
NCR000169292 and mark the recent "initial notification" as a subsequent under the old Georgia-Pacific ID#.
hope this is clear to everyone. I spoke to Robert Patterson in Storm Water and he said correcting the ID#
would not be a problem. Robert, please insert NCD101734598 as the correct EPA ID#.
Ray Strawbridge
Business Officer/Supervisor
Financial & Information Mgmt. Unit
Hazardous Waste Section
Division of Waste Management
919-707-8231 office
[e-mail]
Postal Address:
Hazardous Waste Section
NC Div of Waste Mgmt
1646 Mail Service Center
Raleigh, NC 27699-1646
Physical Address:
217 W Jones St
Raleigh, NC 27603
Fc. ^Nothing Compares_,%.,
Email correspondence to and from this address is subject to the
North Carolina Public Records Law and may be disclosed to third parties.

RECEIVED
JUN 0 2 2017
LAND QUALITY SECTION
Culpeper of Roanoke Rapids
2262 West 10"' Street
Roanoke Rapids, NC 27870
June 1, 2017
Section Manager, Toby Vincent
NCDEQ/DEMLR Stormwater Permitting Program
512 N. Salisbury St./ V' Floor
1612 MSC Raleigh, NC 27699-1612
Mr Vincent,
CULPEPER
WOOD PRESERVERS
I am sending -this letter as a one time notification that our plant located in Roanoke Rapids intends to
claim the waste water exclusion from RCRA jurisdiction that was published in the May 26, 1998 Federal
Register. It is our understanding that NC has adopted the waste water exclusion: therefore, as of the
date of this letter, we will be operating under this exclusion.
Additionally, this letter is to certify that we have read the applicable regulation establishing an exclusion
for the wood preserving waste waters and spent wood preserving solutions and understand it requires
us to comply at all times with the conditions set out in the regulation.
If there are any questions or comments, please advise.
Regards,
Billy Rodgers
Facility Manager
252-308-8474
culpeperwoodcom
HEADQUARTERS
FREDERICKSBURGti VA
SHELBYVILLE, IN
COLUMBIA, SC
FEDERALSSURG, MD
15487 Braggy Comer {toad
10299 Tidewater Tral
701 Mausoleum Road
208 Flint Lake Road
2000 Industrial Park Road
PO Banc 1148
Fredericksburg. VA 22408
PO Box 260
PO Sae 23950
PO Box 298
Culpeper, VA 22701
TF: [phone]
Shelbyville, IN 46176
00(umbia, SC 29224
Federalsburg, MD 21632
TR [phone]
LOCAL [phone]
TF: [phone]
TP [phone]
TF: [phone]
LOCAL [phone]
FAX: [phone]
LOCAL: [phone]
LOCAL (803) 788-5om
LOCAL [phone]
FAX: [phone]
FAX: [phone]
FAX: (803) 78&1782
FAX: [phone]

Patterson, Robert D
From: Patterson, Robert D
Sent: Friday, May 26, 2017 2:48 PM
To:'[e-mail]'
Subject: Application fee
Billy — As we discussed on the phone today, we received your application, but it was missing the application fee. The fee
for new individual permits is $860; made payable to NCDEQ. Please place all 3 lines of the address below on the
envelope.
Thanks and have a good Memorial Day weekend!
Robert D. Patterson, P.E.
Environmental Engineer
919-807-6369 1 Robert. Patterson 0ncdenr.gov
httns://dea.nc.gov/about/divisions/energv-mineral-la nd-resources/stormwater
NCDEQ I DEMLR I Stormwater Permitting Program
512 N. Salisbury St. 19t' Floor
1612 MSC I Raleigh, NC 27699-1612
Email correspondence to and from this address is subject to the North Carolina Public Records Low and may be disclosed to third parties.

,gyp tiyl
May 25, 2017
Robert Patterson
Storm water Programming
1612 Mail Service Center
Raleigh, NC 27699-1612
Mr. Patterson,
21A&A
CULPEPER
WOOD PRESERVERS
RECEIVED
MAY 2 6 2017
LAND QUALITY SECTION
Culpeper Wood is opening a treating facility on a previously permitted site. We hope to be processing
by September 1, 2017. The site address is 2262 W. 10th Street, Roanoke Rapids, NC and was previously
permitted to Georgia-Pacific.
Any assistance you could provide in expediting our permits would be greatly appreciated.
Thanks for your consideration,
Sincerely,
Q)Q� 245-��
Billy Rodgers
Facility Manager
Culpeper of Roanoke Rapids
252-308-8474
cuipeperwood.Com
HEADQL AMRS
15487 Braggs Comer Road
PO Bm( 1140
Cuipepar, VA 22701
TF: (am) 817-6215
LOCAL [phone]
FAX: (540) 82" 162
FREDERICKSBURG, VA
10299 Tidewater Trail
Fredericksburg, VA 22408
TF. [phone]
LOCAL: [phone]
FAX: [phone]
SHELBYVILLE, IN
701 Mausoleum Road
PO Box 260
SheibydIa, IN 46176
IF: [phone]
LOCAL: [phone]
FAX. [phone]
COLUMBIA, SC
208 FTmt Lake Road
PO Bar 23958
Cokrmbia, SC 29224
TR (Boa) 347-5033
LOCAL- (8w) 788,5033
FAX: (wa) 78&1782
FEDERALSBURG, MD
2000 industrial Park Read
PO Boa 29B
Federalsburg. MD 21632
TF: [phone]
LOCAL, [phone]
FAX: [phone]

JLPEPER WOOD OF ROANOKE RAPIDS, INC".
.O. BOX 1148 CULPEPER, VA 22101-6148
NCDEQ/DEMLR/STORMWAT 12864 Check# 000009 Date 6/01/17
Zeference# Inv/Date Description Gross Amt Discount Net�Amt
PERMITS 5/26/17 PERMITS/EPA 860.00 .00 86.0.'00
I�C �,o 0 0 5-q;9-'
Totals --�
D �@ bg
. D .
JUN d a '201V
860.00 .00 860.00

Please phi or type is the unshaded areas or*.
Dd 5q 2--
r4m v1 Annrrmwi CMM u. 'Aunjwma
FORM
lf.S. ENVIRONMENTAL Pt20i EI.D.-
�E
-- - ----
NUI+IBER
TnnAn non 7A 6
1
ems► GENExa�,. MF IV1/
GENERAL
(Road darTwAucdarrs"6ranearmrixy)
.1��$�6�z�+ D
1
= 9 Y b
LABQ ITEMS GENS AL WSTRUCTIONS
= fl a termed label her than peavide4 &Tx it in ft
e d Spew. Review the 'edohnf 111 caheW. If any of it
L EPA LO NU MBEit 3 ' is k=ff C% aosn dWOU h It and weer mo =1 dame in the
appropriate 01n am helm. Also. i'any of ft Idmed dame
'NQClAL1TY SE m• a ale rra d an roar >mae m.
_ tea("'°
IIL : FACtUTY NAME .. PLEASE PLACE LA9EL W TIilS 3P for ahadd eppeall. II in the
thleass povtds props
r his ammo)ladaw. It ft 1" 1. mn1 1, and meat Diu
V .:FA(YLTTY MAILJNG _ need not oompleee meIYLS !. M. V. ald N fwCare Mevvhi>s
<.A moot 8s coapieptd reymdSsy. Co Oft d tt = if no MW
her been prodded. Refer to Dn WOft. is derWW ft.
VL LOCAT1OtN " - dwalpdolls and for ale tape! � ita molds vAdd O
_FACIifTY date h aAWKftd.
II. POLLtrrANF CHARACTERISTICS
01STRUCTION5: Canpiete A ftmo J lbdebmmine wimmUm You need to subndt any permit application fixms tD the EPA If you answer yes" to any quesUM you mast
sir. 11 this form and the supplra mobi form Hslad In the pererdmis fabowing the question. Mark 7f' In the box In the thud cohmm if the supplemadal farm is afladred. if
you amm 're to each question, you need not sh . I any of these b"ne_ You map Stow ,rw 11yoeor actw* is eetchhded from Pall see Section C Gift
inalsuctiars. Sea also. Section D of do instructions for ti I inems of boldfaced torus,
ak'x
mWkW
res
No
Fom
�
SPECM QUESTIONS
AnrACHED
SPECK QUESTIONSres
A TrACKED
A IS Cis iaclMy a puW* anted I all ea worlrs whidh
reacts in a dbedrage to waters cf the U.S.? (FORM 2A)
X
B. Does or will this facDly (e0w eadsft or jempos"
hhchrde a eonoeSdratsd ar>s boom aperatforh or
aquatic aeI a production fmdlllt► which reahbs In a
M
A
tldbchwgolGw11
q
a
21
0 of the tlt&? (FORM RM 26)
C. is Cds a bally which amerdiy mem In dlsdrarghha M
watore of the US. other than those daerrl in A or 8
x
D. Is this a Pmpaaed faciMy (other Man Moore dnwfi od in A-
era above) wlddh WID rest I In a dbdt Wp to waeas of
X
above? (FORM 2C)
tin WIL? TOTt11A 2D)
n
a
as
a
a
a
E. Does or wil Clio facWy beat, Stara, or dispose of
hasardous vast m? (FORA! 3)
X
F. DD you or wits you infect at Oft facRy irvd�bciai or
mhmir�l eMantt beidw the lowermost strahnn
carrWit" witldn am quef6er fade of to weft bare,
undeVou nd sources of 4fini water? (FORM 4)
a
a
sv
st
$
a
g
G. Do you or wdi you inject at Cis *xft any txoducad water
K Do you or wie you Wed at am teddy &dds for qx=W
ar otther fluids wlddh am Ismod M the surface, in
connection will conventional oil or retreat gas production,
X
processes such as rrbft of sulhu by Cho Fhmc h process.
solution rnhrdrg of ndrhaa}s. In situ Cornbusflon of to sm
b"d Voids used for enhammd recov Sty of oil or rnatrua
foal, or recovery of geWmanal WOW? (FORM 4)
yes, a inject fhdds for storage of pquld lydrotarbons?
(FORM 4)
av
w
«
a
s
a
I. Is dds facOty a proposed I aoumo whldn Is arm
J. Is this faclly a I F noedohm, ml source wlt d Is
of f 28 induNtW celepmm load in fire hubucdou and
�
NOT one of ft28 tndhatrta! listed In ft
cefsporso
lh
wdh w8i pobrrtf mlfy ernit 100 tans per year of any air
1 11ruafhana and whidh VA pub mfi* ertui 250 tors per
polttnt mgddod under the Clean Air Act and may stied
)mar of any air polluWnt ed under MeCleanAir Act
O
fl
O
M
tl
or be IDCabed in an atted u t aQar�f � S)
1reguulel
a Wy
d nW a� w or be tided In an atYYpe[i[ am?
5)
M. NAME OF FAGAITY
slapCUL O ROANO RAP I
IZIC
v''"'=
N. FACILITY COINFACT
A. NAME s rinE UasCffi-A die) B. PHONE (nee code &
Z
R O D G E R S I L L Y F A C I L I A N A G E R( 5) 3 8-8 7
u
s e « tr « n es
V. FAf;tLTY MAMM ADDRESS
A. STRUT OR P.O. t3DX
32 2 62 WES 1 STREET
-
1a M d
B, CITY cITY OR TOM
c. STATE D. ztP CODE
fey
4ROANOKE RAPIDS
C
28
VI. FACILITY LOCATION
A STREET. ROUTE NO OR OTHER SPECIFIC 1001 ER ` -�� ' s ''' fi a , + i
5 2 2 6 2 W E S 10 T H S T R E
so
6 WUNTY NfIhr1E-
r
H A L I F A X
40
C. CITY OR TOWN D. sTATEF
E. aP CODE I
F. COUMN CODE {ijbrrrwel
`= :' :
SRO
A N O K E RAP I D S
2 8 0
L iZ.
-:
u
s n a
v
EPA Farm 3510.1(8-W)
CONTINUE ON REVERSE
.��4�a�
Sg�o
gin. 0 7

CONTnitIFn FMU THE FROW
VIL SIC CODES is mrferof
A- FIRST
9. SECOND
y
C. THIRD
D. FOURTH
GSa�Ji1
(�►fi'1
T
b
w
T
�
VM. OPERATOR WORAIADON
A NAME
B.Is the nmrle listed 61 Iterrr
C U. L P E E R O F R O A N O K E R A P I
D S VIA-�► the ow�nerl
1a
S
o YES NO
w %
s
C. STATUS OF OPERATOR ffM9w liner b y d w amw w bin "Odber,' }
D.FEDERAL PHONE min node ua
gayrr M=PUBLIC(odiwdmTJedwwlar�s)
ATE
p
�
(252) 30$—$474
O S OTHER {spaifyJ
P = PRIVATE
E. STREET OR P.O. BOX
=A j lr
2 2 6 2 1 0 A S T R
F. CITY ORTOWN
G. STATE H. ZIP CODE
IDL INDIAN LAND
Is the hCft heated m Wan lords?
B
R O A N O K E R A P I D S
NC
7870
1k
O YES ® NO
m
40141
X. EXISTING ENVIRONMENTAL PERLM
A NPDES m iY
D. PSD
T
e2r72Tfj&qmces x"
C T
1
NA
r _
-
9 N
9 P
w w n w
s=
w w
n w »
B. IIIC Fhridr
E OTHER
T
1
A
C
T
I
r
}
9
a
u
9
in
i
pa
w
Is
Tr
b
C. RCRA limier
E OTHER
C
T
1
C T t
�qpf r}
M��J
9
R
9
n
w
via a
w w w s
XL AAAP
ANarh to Oft app8eation a topoWapfrlc nap of The area mdenMig to of lest One nine beyord property boundmiea. The rrmp must show the oufflm d the fixft. the
bca8orr aR 8acfi ai iZs e7f18" and proposed irreelaa and cbdrarge sbueMms, each of Its hazm does waste treahrrent, atNaM or dispose! facdkk a. and each we0 where A
injects &*b undo Wvm& tndude aN smtgL rivers, and other atrrfaoe water bodies in the map area. See bv*udiorrs for pregse rm**ement s.
W NATURE OF afWW
Wood preserving plant which uses various products and pressure treats them to yield a rood product that resist
ldew, rot and insect attack,
MIL CERTIFICATION jsm k*Mxdarrs}
f cerWy under penehy of law slat I have pwma mNy. axa n&W and am f nWar wftb ft bdammUon submtbd in Nds pppLcdbn and aff ammtemrrts end Mai based an my
kxp*y of Norse persona krAmmM W resP4rA�ibte ibr aI I I S Me kxbnjaf m carda1had br the appEcaffm ! be b w that do lj*onreflorr true, —ma, tad cmp bta. l
am swam Mat amm am somftem pnn�aNfm IhrsrMratd hg false 6dhmraWm bx*jcMV Me pommy of floe and lrtpdmoranent
F f
�'RS E'lEfi' 1* MANAGER
EL SIGNATURE
C DATE SIGNED
05/24/2017
COMAOSIM FOR OFFICIAL USE ONLY
EPA Form 3510.1(8-60)

,� pmwEPA
EPA a) Number (copy trot Vern i oTFaRECEIVEDm 1) NCR000169292 Fam Appvtod ONS No 2040MM
_ .... _ _Apprwat ectnes 531.62
US. E Pr ime ��y "'- r 4 v Lull
Wassrhrglon, M 20M
Application for Permit to Discharge Storm Water
Associated with
Papmvm RoducthmPA* ftiadce
PUbft MPortbrg Braden for Skits appar»ttarh is estbrmted to average Z&O hours Per app6®tiah. Idrmrdbhp llme for reviewft itntnudiam saardft e3dism>8 dam sources.
gathwhv and fn8ft*ing the date needed, and corrhpletar9 and Fevk w ft the cD%C6 n of li f -IMSM Send COINIM ragdrdmp the burden es&m ts, any other aspect
of Oft aaGectton of Wdarrnatloo, or suggsaorm for iwrovtrg fits tbrsa. brdxng suggestions wlids may frovase or reduce fits burden lix ChW, bdorr aft Polley
Brand►. Pb1,= U.S. ErmiromwU Protection Aipwmy. 1200 Pennsyl=U Avorme, NW. WhsidroMn. DC 20M a Dhectm. Qttioe of bfomm5m and Reghdetory
Affab% Oft& of Mmmip meat and Budges: Washiroon, DC 2[ M&
� O%dMI Location
I Far each otdd Oat ttre letltrrde and kmaW a of tis location to the nemest 15 samrdo and the rmme of the . scei►drra water
A. Outid Number
ABSO
B. bide
C. Lagitrrda
D- Reoeivfrg Water
)
001
36.00
2 - - 001
49.17
'77.()DI
41.001
23.12
Chockoyotte Creek
002
36.0101
27.00
55.32
77.00
41.001
14.55
Chockoyotte Greek
L lmpvv@Inm tS
A. Are you now requhed by a" Federal. State. or focal autharily to meet any beplmnwftbon schedule for the car>*uWon, uppradhhg or operation of y r
t uabnente4ulpmerd or or anydhar onvironmerstal programs which may affect the Ap sm desatbed in flits application? This hrhiudes. but is not lhrhPoed
to.pm.. corn On 4 admbshawa or erdmmernerd cedersadmaim compillarmeschoduieletrme. adpulatiorm cam ordem and grmrt or kart cmxM ons.
4. Rnai
1. kkoldlicdlon ofCardM=, 2-ABectod Outfaf Cangt6mhce Dale
Aphem. m-1 Ebm mprhber scurry of disdrmge 3. BrW Desa"m d Projed a req. b. pmj.
B: You may achch additiorsal streets dssaibBhg artyeddttiortal water pdkdim (a ofiererrvm--wdat Projects whild may afted vmw dimchgs) you now have order
way or which you Plan. bxkata whether each program is now under way of piarhrhed, and badkate your acthal or planrmd schedules for corms rur4om
HL SEte D Map
Attach a site map ahawbg topography (or ardica ft titer outline oldrahvegs areas served by the outfaQs(s) onsred in On a ppka*m Ira topographic map Is camvalahle)
depicting the fecft iruArdbtg each of ds bl loa and drsdhmga strudraes; fie drainage area of each storm walar oettat Pared ereas cord 819swulblithedrokoge
he
area Df each storm wafer Dolts% each laroMm Past a prwm areas used for ahldoer storaga Df disipmel of materials. each ahcisd shupurAl control thwarter
fareduce pol5dais bh slam waist none. rrrataritl, bedbg wd access areas areas where pesdddm hwbkkles, soil cormMonms and farMem are appiiad; each of
tis hmmrdm a ornate tra'dff d. storage or d urat (kKko rg cads area not mgLdmd to have a RCRA Pmrnit which is seed fa acaanc*ftq herdoes waste
tcdo 40 CM 262.34k each well whme &d&ftmftbcftwe hadergmushd ' , I fis amd other surface war bodies whiidh racetved starer water ftCtmrgm
from tthe tadny.
EPA Form 3510.2E (1e2) Page 1 of 3 CahSnn an Pape 2

Conntrnred from the Fred
. Narratlw Description of PogutmM Sources
A. For sech mud, prodda an astlrnets d the ame Cffxk4a w s) d teyedous surleaes Ow1uOrg Pa+md erase and trrdrag rods) drahted to the arwd an as11 1 d the bfel surbw arse
&Mrmd by the oulhdl.
Ordfd
I wnbs
Area of Wpmriue Sm Um
Tdd Am Orahed
fPreMrb Nov
C dal
Wrmtbe
Amu of h.Wo ous smkoe
rstt�
TaW Arm prairled
�rwloia unrttrl
-ACRW
002 4.850
ACRES
B. Rvride a rrerettve dear n oftig ffirp IrrmCe►fei4 that are c unw* or in lie past three ye re have been treated, stared or disposed in a mum er to Wow exposure
to storm water, ..md d' not Grit, skni a, or dkgxm tr pas! and preaerrt m marre01 P I Pracgoes erpbyed to minoronted by dtase me6eriets with
storm water nnwfu mataeriafs bat5ng and acDm areasand ft bcaft% marwer, and fregtretcy in which pesticides, tectides, sail cmdMones, and ferLiaem are
This is a facility being constructed on a prey ors y owned facility -
Future activities.,
Pressure treat various wood products with a cooper -based treating solution.
Inside above ground contained tank storage of the rood treating solutions.
Inside and Ootaide storage of wood.
Operation of diesel fueled mobile equipment and inside fuel storage.
Management of used oil products.
Proper and constant management of stormrater runoff,
C. For each otdfa4 Prorlde the btF don end a deKdpGon d shucbjrW and nonshmend crab measures to reduce po&dmrft in atom water nnwff. and a
4 , 4 is of tie treatment the am., water receives, bxhx rrg the sdvxhde and type of rtnktenmwe for and beetrnend measures and the uftbude dial
of any sood oriLAd wwbn od w Bter by db&wge.
outm
Ud Codes tam
Nurnber
Treabrwd
Table 2F-1
001 a 002 Detention ponds, berms, storage of materials in buildings. employee training and basic good
usekeeping.
V. NonstorrrfMrater Discharges
A. l cetity raider penally of taw hat the ouffaWs) core ed by this applicefim here been tested or evakmW fix the presence of nonsborrmeater dtedamVes, and that 80
nonskwnymatw dbctmnged * m these otdfa0(s) om lderddle 'in miller an acrrtpwWft Farm 20 or Fnem 2E applbow for the otdbll.
Name and Mid Me ftw arp&*
Sigrwd
Billy Rodgers Facility Manager
05/24/2017
8. MmIde a desor"w of ft method used, the deb of wINWhig, wide* orals drainage paints that were dracity obsevad a test.
A visual review of the property was made and no non-stormwater sources were located-
VL $1Sf7ffk={t i.0da or Spas
Provide aodstnrg 6rtorrrtation re9wdh the tdsbry of aig W - leaks or spdis of tmdc or hazardous polukuds at the facRy in the last ttuee yom. hxkmmng the
apmWftni ie date and taratierr of the spit arm*, aed gob" and amnmt of tnafsi relemered_
None ,this is a facility that was under previous ownership being reconstructed.
EPA Form 3510,2F (1-G2) Page 2 of 3 Cordl m on Page 3

EPA 1D Number (oapy frmh !lain 1 of Fam 1)
Continued froin Page 2 NCn000169292
L Discharge lrftnnMon
A, B, C. 6 D: See enskuctiara before p ooeedng. Complete one sat of Tables for each oulfall. Ammme the cuCaB nimber in the space pmvkiad.
Table Vll-A. VU-9. VlW am kmlu ad an separate WmAss numbers VS-1 and VS-2
E Po6erl13a1 degas not covered by aratiym — is any lack polluter& fisted m table 2F-2, 2F3, or 2F4, a substance or a componerd of a subiderme wlddr you
marenthr use or rrmrtuftiehue as an b4or radian or 6rral product or byproduct?
Fe Yes (Bet aff a m h paw baba) ❑ No (go to Section JX)
Recall that we stated this facility is under construction and will be new with no analytical data.
Materials list that will be used at our facility:
Mold inhibitor- attached SDS
MP-200A concentrate- attached SDS
CCA concentrate- attached SDS
Diesel fuel- attached SDS
WL Bi *n& ai T03dc y Teeft Dam
Do you have any latowledge or reason to believe That any biology test foram or duto c t wdcity has been made an any of yarn dbscharges or an a mow*g water in
relat m to dfscharga wf hen the last 3 years?
I_I Yes (EW al ach pow below) �✓ No (go W SeW. vg
DL Pr*vbad Analysis IMcnrradon
Were any of the analyses reported in tram %M performed by a contract laboratory or conatdling firm?
❑ Yes (W fire creme, aa' ,am and baAsp win rrrmrber of, and potk4ards
No (go to section X)
arsalYl+ed by, each such bboratory orrom below!
A. Nana
B. Address
C. Area Coda d. Pharra No.
D. Polaufmds Ar4dyxed
Environment 1, Inc hire once
P.0_ Box 7085 Greenville,NC 27835-7085
252-756-6208
processing begins
I cei y raider parraCy of taw tfat this doeaune d and ate aMw hmenfs were p►oparsd render my dreetlan or mpervkOm in accordance wfib a ayslem deslphed b assure
VWquaffibdposo prapt* Lund evacuate pro ihbmmt n subutfftad Based on my kVuiry of H* person orpwsons who nraHa system or those pehsons
*vcw rerA "w(bb for gaftft tiro kftmaum the b* mrebion =*nlffed 4, to go bast of cry tmowledge and beW,, ftme acstaaie, and aamphle. I am aware 6W
there era a oerrt panatlies khrsr,brnitHerg fhMse ida►metiryh i>rmrg the possirSW of8ne and br*wbomnent ibrknowbV WuAdko q
A. Nerna a OMM TWe (Type Or Plfrd)
S. Area Code and Phone No.
Billy Rodgers Facility Manager
[phone]
EPA Form 3510-2F (1-62) Pegs 3 d 3

EPA ID Number (oaipy fr M n m 1 of Fora! 1) Form Approved. OMB No. 2040-0086
Approval expires 631-82
VII. Discharge infomlation {Continued fimm page 3 of Form 2F)
Pert A — You Woven provide the rest of at least ate analysts for pollutant in this table. Complete one fable for each ouNall. Sae irhsb uctions for addldonal detallL
Mmd utm Values Average Values
tat") Number
P09utard Gray Sample Cxffi Sample of
and Taken Otrrfrg Taken During Storm
CAS Number FhU 20 Fb-WeVded First 20 Fb-Welgftted l"cvettta
id ) hbudes composite Nkma a Campus Sampled sotmxs of Pol Mania
O9 and Grease WA
f3lologioaf oxygen
Demand
Chi oxygen
Demand (COD)
Total Srrsperpded
uofids (T8S
Total Ifrogen
Total Phosphorus
Of iifotl3rxmt Matdrnum AAitittuahh Ma>arruuh
PW 13 — List each pollutant that is 9m0 to an enlretd guideline wtdc h the tac�ty is erhijed to a any pollu artt listed in the tars NPM perni't for its prooesa
rra' M ; I N (it the tarty is opav*V tinder an a>dsthg WOES perrrtitJ Complete one table for each auflall. See the Inshm*ons for adffl*w l daUft and
ktaxknxaa Values Average Vahree
rraBuda Number
Po9tatani �Swriple Grab Samoa o
aw Talon n Storm.
tAS Number First 20 Flo-Welgided Past 20 P--Weigtmed Everds
fg+ ) Minutes Car% -Ste IGMAM Ciompostte SampledSources of Pam
EPA Farm 3510 2F (1412) Page Vil-1 conftwe on PAYS ee

Co+>bntimd from the Front
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REFERENCE:
USGS 7.5—MIN TOPOGRAPHIC
QUADRANGLE ROANOKE RAPIDS, SCALE — FEET
NORTH CAROLINA, DATED 2016.
0 2000
APPROVED DIRK 05/23/2017 KU Resources, Inc.
CHECKED DRK 05/23/2017 22 South Linden Street
DRAWN RAM 05/19/2017 Duquesne, PA 15110
CAD FILE NO. 17046AD03 412.469,9331
412.469.9336 fax
PROJECT NO. CWP.17046.ESA www.kuresources.com
W.
k-
SITE TOPOGRAPHIC MAP
CULPEPER WOOD PRESERVERS
2262 WEST 10th STREET
ROANOKE RAPIDS
HALIFAX COUNTY, NORTH CAROLINA
PREPARED FOR
CULPEPER WOOD PRESERVERS
CULPEPER, VIRGINIA
1s CI

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ui CONCRETE FLOOR` SLAB C&G
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•
REFERENCES: I. IMAGE IMAGE BY GOGGLE EARTH DATED 11-15-2015.
2. STORM WATER MANAGEMENT PLAN BY BURR k ASSOCIATES, P. A_ .`
OF ROANOKE RAPIDS, NORTH CAROLINA, DATED 10-14-99. PREPARED BY: PREPARED FOR: PROJECT: DRAWING TITLE:
SCALE — FEET Ru Resources, Inc.
22 South Linden Street CULPEPER WOOD PRESERVERS ROANOKE RAPIDS SITE
Duquesne, PA 15110 15487 BRAGGS CORNER ROAD 2262 WEST 1Oth STREET
REVISION DATE DESCRIPTION 0 60 120 412.469.9331 P.O. BOX 1148 ROANOKE RAPIDS SITE DRAINAGE MAP
412.469.9336 fax HALIFAX COUNTY, NORTH CAROLINA
CHECKED BY DRK 05 24 2017 APPROVED BY DRK 05 24 2017 www.kuresources.com CULPEPER, VIRGINIA 22701
I

KOPPERS
1. Identification
Product identifier
Other means of Identification
SDS number
Recommended use
Recommended restrictions
SAFETY DATA SHEET
SN RTU
307-KPC
Corrosion inhibitor additive for use at wood treatment plants.
None known.
Manufacturer/Importer/Supplier/Distributor information
Company name Koppers Performance Chemicals Inc.
Address 1016 Everee Inn Rd., Griffin, GA 30224
Telephone number
Contact person
Emergency phone number
E-mail
770-233-4200
Regulatory Manager, KPC Inc.
CHEMTREC:
[e-mail]
2. Hazard(s) Identification
Physical hazards Not classified.
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Serious eye damage/eye irritation
Hazardous to the aquatic environment,
acute hazard
Not classified.
< I
Warning
1-800-424-9300
Category 2A
Category 2
Causes serious eye irritation. Toxic to aquatic life.
Wear eye protectiontface protection. Wash thoroughly after handling. Avoid release to the
environment.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Store away from incompatible materials.
Dispose of contentsicontainer in accordance with Ioca//regional/nationallintemational regulations.
None known.
3. Compositionfinformation on ingredients
Mixtures
Chemical name CAS number %
Water 7732-18-5 a 95
Sodium Nitrite 7632-00-0 1-5
Colorant Proprietary < 1
Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume. The specific chemical identity and/or exact percentage of component(s)
have been withheld as a trade secret. This product may also contain <1 % of mold inhibitors.
SN_RTU SDS US
Page 1 of 6

4. First -aid measures
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
physician if symptoms develop or persist.
Skin contact
Remove contaminated clothes and rinse skin thoroughly with water. Get medical attention if
irritation develops or persists.
Eye contact
Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open
eyelids wide apart. Get medical attention if irritation develops or persists.
Ingestion
Rinse mouth thoroughly with water. Do not induce vomiting without advice from medical
personnel. If vomiting naturally occurs, keep head low (lean forward) so that stomach content
doesn't get into the lungs. Get medical attention if any discomfort continues.
Most important
This material may produce methemoglobin which, in sufficient concentration, causes cyanosis, a
symptomsieffects, acute and
blue -gray discoloration of the skin and lips caused by a reduced ability of the blood to carry
delayed
oxygen. Headaches, dizziness and nausea. Contact may cause eye irritation with redness,
tearing, pain, and/or blurred vision.
Indication of immediate
Treat symptomatically. Danger of methaemoglobin formation after ingestion.
medical attention and special
Treatment: Treat according to symptoms (decontamination, vital functions), treat with toluonium
treatment needed
chloride to reverse methaemoglobinanaemia.
General information
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
5. Fire -fighting measures
Suitable extinguishing media
Use fire -extinguishing media appropriate for surrounding materials.
Unsuitable extinguishing
Dry chemical. Carbon dioxide (CO2).
media
Specific hazards arising from
By heating and fire, toxic vapors/gases may be formed.
the chemical
Special protective equipment
Selection of respiratory protection for firefighting: follow the general fire precautions indicated in
and precautions for
the workplace. Self-contained breathing apparatus and full protective clothing must be wom in
firefighters
case of fire.
Firefighting
Use standard firefighting procedures and consider the hazards of other involved materials. Cool
equipmentlinstructions
containers exposed to heat with water spray and remove container, if no risk is involved.
Specific methods
Use water spray to cool unopened containers.
General fire hazards
Combustible materials may catch fire more easily after being wet with sodium nitrite and dried.
Product intensifies combustion of other materials.
6. Accidental release measures
Personal precautions,
Ensure adequate ventilation. Avoid inhalation of mist and contact with skin and eyes. Keep
protective equipment and
unnecessary personnel away. Do not touch damaged containers or spilled material unless
emergency procedures
wearing appropriate protective clothing. Wear appropriate personal protective equipment (See
Section 8).
Methods and materials for
Should not be released into the environment, For waste disposal, see Section 13 of the SDS.
containment and cleaning up
Large Spills: Dike far ahead of spill for later disposal. Absorb or cover with dry earth, sand or other
non-combustible material and transfer to containers.
Small Spills: After removal flush contaminated area thoroughly with water.
Never return spills to original containers for re -use.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not contaminate water. Reporting of
releases to appropriate regulatory agencies may be required.
7. Handling and storage
Precautions for safe handling
Use only with adequate ventilation. Avoid inhalation of mist and contact with skin and eyes. Do not
breathe dust from dried product. Keep away from clothing and other combustible materials. Wash
thoroughly after handling. Wear appropriate personal protective equipment. Observe good
industrial hygiene practices. Avoid release to the environment.
Conditions for safe storage,
Keep container tightly dosed in a dry and well -ventilated place. Do not store with acids,
including any incompatibilities
ammonium salts, cyanides, amines or reducing agents.
8. Exposure controls/personal protection
Occupational exposure limits
No exposure limits noted for ingredient(s).
Biological limit values
No biological exposure limits noted for the ingredient(s).
SN_RTU SDS US
Page 2 of 6

Appropriate engineering
Good general ventilation should be provided to minimize contact with vapors, or dust from
controls
dried -down product. Eye wash facilities and emergency shower must be available when handling
this product.
Individual protection measures, such as personal protective equipment
Eye/face protection
Chemical goggles and face shield are recommended.
Skin protection
Hand protection
Wear protective gloves. Be aware that the liquid may penetrate the gloves. Frequent change is
advisable. Suitable gloves can be recommended by the glove supplier.
Other
Wear appropriate chemical resistant clothing.
Respiratory protection
Not necessary under normal conditions. In case of insufficient ventilation wear suitable respiratory
equipment. Use a NIOSHIMSHA approved air purifying respirator as needed to control exposure.
Consult with respirator manufacturer to determine respirator selection, use, and limitations. Use
positive pressure, air -supplied respirator for uncontrolled releases or when air purifying respirator
limitations may be exceeded. Fallow respirator protection program requirements (OSHA 1910.134
and ANSI Z88.2) for all respirator use.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene
Always observe good personal hygiene measures, such as washing after handling the material
considerations
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9. Physical and Chemical Properties
Appearance
Physical state Liquid.
Form
Color
Odor
Odor threshold
PH
Melting poinWreezing point
Initial boiling point and boiling
range
Flash Point
Evaporation rate
Flammability (solid, gas)
Clear liquid.
Pink.
No odor.
Not available.
7.8 — 8.8
32 T (0 °C) (Approximate)
212 T (100 'C) (Approximate)
Non-combustible.
Not determined.
Not applicable.
Upperllower flammability or explosive limits
Flammability limit - lower Not applicable.
Flammability limit - upper (%) Not applicable.
Explosive limit — lower (%)
Explosive limit - upper (%)
Vapor pressure
Vapor density
Specific gravity
Solubllity(les)
Solubility (water)
Partition coefficient (n-
octanollwater)
Auto -Ignition temperature
Decomposition temperature
Viscosity
Other Information
Bulk density
Not applicable.
Not applicable.
Not determined.
Not determined.
1.03 (1-120 = 1) (Approximate)
Soluble in water.
No data available.
Not applicable.
Not available.
Not determined.
8.6 lb/gal (Approximate)
SN RTU
SDS US
Page 3 of 6

10. Stability and reactivity
Reactivity
The product is stable and non -reactive under normal conditions of use, storage and transport.
Chemical stability
Material is stable under normal conditions. Unstable with heat after dry down.
Possibility of hazardous
Will not occur.
reactions
Conditions to avoid
High temperatures. Incompatible materials.
Incompatible materials
Acids. Ammonium salts. Amines. Activated carbon. Cyanides. Reducing agents. May react with
secondary or tertiary amines to form nitrosamines. (Certain nitrosamines are cancer -suspect
agents.)
Hazardous decomposition
Decomposes with heat. Decomposition temperature is 490"C (914'F) after dry down and will
products
produce oxygen and toxic nitrogen.
11. Toxicological information
Information on likely routes of
exposure
Inhalation
Vapor may be irritant to nose, throat and respiratory tract.
Skin contact
May cause skin irritation.
Eye contact
Causes serious eye irritation.
Ingestion Harmful if swallowed. If ingested it may cause the formation of methaemoglobin. Ingestion may
cause gastrointestinal irritation, nausea, vomiting and diarrhea. Hypotension (low blood
pressure).
Symptoms related to the This material may produce methemoglobin which, in sufficient concentration, causes cyanosis, a
physical, chemical and blue -gray discoloration of the skin and lips caused by a reduced ability of the blood to cant'
toxicological characteristics oxygen. Headaches, dizziness and nausea. Contact may cause eye irritation with redness,
tearing, pain, and/or blurred vision. Rash.
Information on toxicological effects
Acute toxicity Not expected to be acutely toxic.
Components Species Test Results
Sodium nitrite (CAS 7632-00-0)
Inhalation
LC50 Rat 1.45 mg/L. 4 hours
Oral
LD50 Rat 120 mglkg
Skin corrosionlirritation Based on available data, the classification criteria are not met.
Serious eye damageleye Causes serious eye irritation.
Irritation
Respiratory or skin sensitization
Respiratory sensitization Based on available data, the classification criteria are not met.
Skin sensitization Based on available data, the classification criteria are not met.
Germ cell mutagenicity No data available.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity No data available.
Specific target organ toxicity - Based on available data, the classification criteria are not met
single exposure
Specific target organ toxicity - Based on available data, the classification criteria are not met.
repeated exposure
Aspiration hazard Not classified.
Chronic effects None known.
SN_RTU SDS U5
Page 4 of 6

Further information This material may produce methemoglobin which, in sufficient concentration, causes cyanosis, a
blue -gray discoloration of the skin and lips caused by a reduced ability of the blood to carry
oxygen. Sodium nitrite can also react with certain amines forming compounds which may cause
cancer, mutations, or other toxicity. These compounds, known as nitrosamines, can be formed in
acidic environments such as that found in stomach. Since many medications and chemicals
contain an amine group, simultaneous exposure to nitrites should be avoided.
12. Ecological information
Ecotoxicity
Components
Very toxic to aquatic life.
_ §J?�cles _ _ Test Results
Sodium nitrite (CAS 7632-00-0)
Aquatic
Crusacea
EC50 Greasyback shrimp (Metapenaeus ensis) 16.14 - 26.61 mg/l, 48 hours
Fish
LC50 Rainbow trout (Oncorhynchus mykiss) 0.15 - 0.25 mg/I, 95 hours
Persistence and degradability
The product oontains inorganic compounds which are not biodegradable.
Bioaccumulative potential
Bioaccumulation is not expected.
Mobility in soil
This product is water soluble and may disperse in soil.
Mobility in general
The product is soluble in water.
Other adverse effects
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions Dispose in accordance with applicable federal, state, and local regulations. Do not discharge into
drains, water courses or onto the ground.
Local disposal regulations
Hazardous waste code
Waste from residues 1 unused
products
Contaminated packaging
14. Transport information
DOT
IATA
IMDG
Transport in bulk according
to Annex 11 of MARPOL 73f78
and the IBC Code
15. Regulatory information
Dispose of in accordance with local regulations.
The Waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose in accordance with all applicable regulations. Do not discharge into drains, water
courses or onto the ground.
Since emptied containers may retain product residue, follow label warnings even after container
is emptied.
Not regulated as dangerous goods.
Not regulated as dangerous goods.
Not regulated as dangerous goods.
Not applicable.
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 107, Subpt. D)
Sodium nitrite (CAS 7632-00-0) 1.0 % One -Time Export Notification only.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Sodium nitrite (CAS 7632-00-0)
LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories
Hazard categories
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SN_RTU SDS US
Page 5 of 6

SARA 302 Extremely hazardous substance Not listed.
SARA 3111312 Hazardous chemical Yes
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
Sodium nitrite 7632-00-0 4 T
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Clean Water Act (CWA) Section 112(r) (40 CFR 68.130) Hazardous substance
Safe Drinking Water Act (SDWA) Not regulated.
US state regulations
US. Massachusetts RTK - Substance List
Sodium nitrite (CAS 7632-00-0)
US. New Jersey Worker and Community Right to -Know Act
Sodium nitrite (CAS 7632-00-0)
US. Pennsylvania Worker and Community Right -to -Know Law
Sodium nitrite (CAS 7632-00-0)
US. Rhode Island RTK
Sodium nitrite (CAS 7632-00-0)
US. California Proposition 65
Not regulated.
Not regulated.
Califomia Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any
chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
On inventory (yes/no)'
Yes
'A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A 'No' indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the
governing country(s).
16. Other information, including date of preparation or last revision
Issue date 15-May-2015
Revision date 9-Dec2015
Version # 03
Further information HMIS® is a registered trade and service mark of the NPCA.
C - Safety Glasses, Gloves, Apron
HMIS® ratings Health: 2
Flammability: 0
Physical hazard: 0
Personal protection: C
NFPA ratings
i
Disclaimer Koppers Performance Chemicals Inc. cannot anticipate all conditions under which this
information and its product, or the products of other manufacturers in combination with its
product, may be used. It is the user's responsibility to ensure safe conditions for handling,
storage and disposal of the product, and to assume liability for loss, injury, damage or expense
due to improper use. The information in the sheet was written based on the best knowledge and
experience currently available.
SN—RTU SDS US
Page 6of6

KOPPERS
1. Identification
Product identifier
Other means of identification
SDS number
EPA Reg No
Recommended use
Recommended restrictions
SAFETY DATA SHEET
K-33 (60%) Wood Preservative
73-KPC
3008-34
Preservative concentrate used for pressure treatment of wood.
None known.
ManufacturerllmporterlSuppiier/Distributor information
Company Name
Address
Telephone number
Contact person
Emergency Telephone
Number
E-mail
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Koppers Performance Chemicals Inc.
1016 Everee Inn Rd., Griffin, GA 30224
770-233-4200
Regulatory Manager, KPC Inc.
CHEMTREC 1-800-424-9300
[e-mail]
Not classified.
Acute toxicity, oral
Acute toxicity, dermal
Acute toxicity, inhalation
Skin corrosionfirritation
Serious eye damageleye irritation
Sensitization, respiratory
Sensitization, skin
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
Specific target organ toxicity, repeated
exposure
Category 3
Category 3
Category 3
Category 1A
Category 1
Category 1
Category 1
Category 1 B
Category 1 A
Category 2
Category 1 (Respiratory system)
Hazardous to the aquatic environment, acute Category 1
hazard
Hazardous to the aquatic environment, Category 1
long-term hazard
Not classified.
r
Toxic 0 swallowed. Toxic in contact with skin. Toxic if inhaled. Causes severe skin bums and eye
damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an
allergic skin reaction. May cause genetic defects. May cause cancer. Suspected of damaging
fertility. Causes damage to organs (Respiratory system) through prolonged or repeated exposure.
Very toxic to aquatic life with long lasting effects.
K-33 (60%) Wood Preservative SDS US
924255 Version #: 03 Revision date: 05-June-2015 Issue date: 25-April-2015 1 19

Precautionary statement
Prevention
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink
or smoke when using this product. Use only outdoors or in a well -ventilated area. Contaminated
work clothing must not be allowed out of the workplace. Avoid release to the environment. Wear
protective gloveslprotective clothing/eye protection/face protection. In case of inadequate
ventilation wear respiratory protection.
Response
If swallowed: Immediately call a poison center/doctor. If swallowed: Rinse mouth. Do NOT induce
vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with
waterlshower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in
eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. Immediately call a poison center/doctor. If skin irritation or rash occurs:
Get medical advice/attention. Take off immediately all contaminated clothing and wash it before
reuse. Collect spillage.
Storage
Store in a well -ventilated place. Keep container tightly closed. Store locked up.
Disposal
Dispose of contentstcontainer in accordance with locallregionallnadonailintemationai regulations.
Hazard(s) not otherwise
None known.
classified (HNOC)
3. Composition/information
on ingredients
Mixtures
Chemical name
CAS number °%
Water
7732-18-5 39.6
Chromic Acid
1333-82-0 29.9
Arsenic Acid (expressed as
7778-3%4 20
As205)
Cupric Oxide
1317-39-1 10.5
Composition comments
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
4. First -aid measures
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or
artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance.
Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device. Cali a POISON CENTER or doctor/physician.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Call a physician
or poison control center immediately. Chemical bums must be treated by a physician. Wash
contaminated clothing before reuse.
Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Call a physician or poison control center immediately.
Ingestion
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use
mouth-to-mouth method if victim ingested the substance. induce artificial respiration with the aid of
a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Most important
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
symptoms/effects, acute and
include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
delayed
blindness could result Difficulty in breathing. Causes digestive tract bums. Prolonged exposure
may cause chronic effects.
Indication of immediate
Provide general supportive measures and treat symptomatically. Chemical bums: Flush with water
medical attention and special
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
treatment needed
ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under
observation. Symptoms may be delayed.
General information
Take off immediately all contaminated clothing. If exposed or concerned: get medical
attention/advice. If you feel unwell, seek medical advice (show the label where possible). Ensure
that medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing
before reuse.
5. Fire -fighting measures
Suitable extinguishing media
Water spray, fog or mist. Carbon Dioxide.
K-33 (60%) Wood Preservative
SOS us
924255 Version #: 03 Revision date: 05- tune-2015 Issue date: 25-April-2015 2/9

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed. Closed containers may rupture violently if
the chemical heated. Contact with combustible material may cause fire.
Special protective equipment Self-contained breathing apparatus and foil protective clothing must be wom in case of fire.
and precautions for firefighters
Fire fighting Move containers from fire area if you can do so without risk.
equipmentlinstructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions,
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
protective equipment and
appropriate protective equipment and clothing during dean -up. Do not breathe mist or vapor. Do
emergency procedures
not touch damaged containers or spilled material unless wearing appropriate protective clothing.
Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of.the SDS.
Methods and materials for
Should not be released into the environment.
containment and cleaning up
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth
and place into containers. Prevent product from entering drains. Following product recovery, flush
area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re -use. For waste disposal, see section 13 of the SDS.
Environmental precautions
Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Do not
contaminate water. Avoid discharge into drains, water courses or onto the ground. Inform
appropriate managerial or supervisory personnel of all environmental releases.
7. Handling and storage
Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Avoid
prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Pregnant or
breastfeeding women must not handle this product. Should be handled in dosed systems, if
possible. Use only outdoors or in a well -ventilated area. Wear appropriate personal protective
equipment. Wash hands thoroughly after handling. Avoid release to the environment. Wash
contaminated clothing before reuse. Observe good industrial hygiene practices.
Conditions for safe storage, Store locked up. Store in original tightly dosed container. Store in a well -ventilated place. Store
including any incompatibilities away from incompatible materials (see Section 10 of the SDS).
B. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Components
Type
Chromic Acid (CAS TWA
1333-82-0)
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Type
Chromic Acid (CAS PEL
1333-82-0)
US. OSHA Table Z-2 (29 CFR 1910.1000)
Value
0.005 mg1m3
Value
1 mglm3
Components Type Value
Chromic Acid (CAS Ceiling 0.1 mglm3
1333-82-0)
K-33 (60%) Wood Preservative SDS US
924255 Version #: 03 Revision date: 05-June-2015 Issue date: 25-April-2015 319

US. ACGIH Threshold Limit Values
Components Type Value
Arsenic Acid (expressed as TWA 0.01 mg/m3
As205) (GAS 7778-39-4)
Chromic Arad (CAS TWA 0.05 mg/m3
1333-82-0)
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value Form
Arsenic Acid (expressed as Ceiling 0.002 mg/m3
As2O5) (CAS 7778-39-4)
Chromic Acid (CAS TWA 0.001 mg/m3
1333-82-0)
Cupric Oxide (CAS TWA 1 mg/m3 Dust and mist.
1317-39-1)
Biological limit values
ACGIH Biological Exposure Indices
Components Value Determinant Specimen Sampling Time
Arsenic Acid (expressed as 35 pgA
As205) (CAS 7778-39-4)
Chromic Acid (CAS 25 pgA
1333-82-0)
10 pgA
Inorganic Urine
arsenic, plus
methylated
metabolites, as
As
Total chromium Urine
Total chromium Urine
- For sampling details, please see the source document.
Appropriate engineering Good general ventilation (typically 10 air changes per flour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
General ventilation normally adequate. Eye wash facilities and emergency shower must be
available when handling this product.
Individual protection measures, such as personal protective equipment
Eyelface protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Wear appropriate chemical resistant gloves.
Other
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
Respiratory protection
Chemical respirator with specific cartridge and full facepiece providing protection against the
compound of concern.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
considerations
as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash
work clothing and protective equipment to remove contaminants. Contaminated work clothing
should not be allowed out of the workplace.
9. Physical and chemical properties
Appearance
Physical state
Liquid.
Form
Liquid.
Color
Dark red -orange.
Odor
Odorless.
Odor threshold
Not available.
pH
< 1
Melting pointlfreezing point
Not available.
Initial boiling point and boiling
> 212 °F (> 100 °C).
range
Flash point
Not available.
K-33 (60%) Wood Preservative
SDS US
924265 Version #: 03 Revision date: 05-June-2015 Issue date: 25-April-2015 4/9

Evaporation rate
Not available.
Flammability (solid, gas)
Not available.
Upperflower flammability or explosive limits
Flammability limit - lower
Not available.
(%)
Flammability limit - upper
Not available.
M
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
Not available.
Vapor density
Not available.
Relative density
1.83 (Water = 1)
Solubility(ies)
Solubility (water)
Not available.
Partition coefficient
Not available.
(n-octanol/water)
Auto -Ignition temperature
Not available.
Decomposition temperature
Not available.
Vlscosity
Not available.
Other information
Percent volatile
40 % vhr (Water)
Pounds per gallon
15.3
10. Stability and reactivity
Reactivity Reacts violently with strong alkaline substances. This product may react with reducing agents.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Do not mix with other chemicals. Contact with incompatible materials.
Incompatible materials Strong bases. Reducing agents. Aluminum. Zinc. Combustible material.
Hazardous decomposition Metallic oxides.
products
11. Toxicological information
Information on likely routes of exposure
Inhalation
Toxic if inhaled. May cause damage to organs through prolonged or repeated exposure by
inhalation, May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Skin contact
Toxic in contact with skin. Causes severe skin bums. May cause an allergic skin reaction.
Eye contact
Causes serious eye damage.
Ingestion
Toxic if swallowed. Causes digestive tract bums.
Symptoms related to the
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
physical, chemical and
include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
toxicological characteristics
blindness could result. Difficulty in breathing. Causes digestive tract bums. .
Information on toxicological effects
Acute toxicity
Toxic if inhaled. Toxic in contact with eyes and skin. Toxic if swallowed. May cause an allergic
skin reaction.
Components
Species Test Results
Cupric Oxide (CAS 1317-39-1)
Acute
Dermal
LD50
Rat > 2000 mg/kg, 24 hours
Inhalation
LC50
Rat 2.92 mg/l, 4 hours
K-33 (60%) Wood Preservative
SDS US
924255 Version #: 03 Revision date: 05 June-2015 Issue date: 25-April-2015 5/9

Components Species Test Results
Oral
LD50 Rat 0.47 glkg
Estimates for product may be based on additional component data not shown.
Skin corrosionfirritation
Serious eye damage/eye
Irritation
Respiratory or skin sensitisation
Causes severe skin bums.
Causes serious eye damage.
Respiratory sensitization May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Skin sensitization May cause an allergic skin reaction.
Germ cell mutagenicity May cause genetic defects.
Carcinogenicity May cause cancer.
[ARC Monographs. Overall Evaluation of Carcinogenicity
Arsenic Acid (expressed as As205) (CAS 7778-39-4)
1 Carcinogenic to humans.
Chromic Acid (CAS 1333-82-0)
1 Carcinogenic to humans.
NTP Report on Carcinogens
Arsenic Acid (expressed as As205) (CAS 7778-39-4)
Known To Be Human Carcinogen.
Chromic Acid (CAS 1333-82-0)
Known To Be Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Arsenic Acid (expressed as As205) (CAS 7778-39-4)
Cancer
Chromic Acid (CAS 1333-82-0)
Cancer
Reproductive toxicity Suspected of damaging fertility.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Causes damage to organs (Respiratory system) through prolonged or repeated exposure.
repeated exposure
Aspiration hazard Not an aspiration hazard.
Chronic effects Causes damage to organs through prolonged or repeated exposure. Prolonged inhalation may be
harmful. Prolonged exposure may cause chronic effects.
12. Ecological information
Ecotoxicity
Very toxic to aquatic life with long lasting effects. Because of the low pH of this product, it would be
expected to produce significant ecotoxicity upon exposure to aquatic organisms and aquatic
systems.
Persistence and degradab€lity
No data is available on the degradability of this product.
Bioaccumulative potential
No data available.
Mobility In soil
This product is water soluble and may disperse in soil.
Other adverse effects
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow
this material to drain into sewerstwater supplies. Do not contaminate ponds, waterways or ditches
with chemical or used container. Dispose of cantentslcontainer in accordance with
locallregionaUnationalfintemational regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code D002: Waste Corrosive material [pH <=2 or=>12.5, or corrosive to steel]
D004: Waste Arsenic
D007: Waste Chromium
US RCRA Hazardous Waste P List: Reference
Arsenic Acid (expressed as As205) (CAS 7778-39-4) Polo
Waste from residues 1 unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
K-33 (60%) Wood Preservative SDS us
924255 Version #: 03 Revision date: 05-Iune-2015 Issue date: 25-April-2015 619

Contaminated packaging
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard classes)
Class
Subsidiary risk
Label(s)
Packing group
Environmental hazards
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
UN2922
Corrosive liquids, toxic, n.o.s. (Arsenic Acid, Chromic Acid) ( RQ = 1 LB)
8
6.1
8, 6.1
II
Marine pollutant
No
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions
B3, I132, T7, TP2
Packaging exceptions
154
Packaging non bulk
202
Packaging bulk
243
IATA
UN number
UN2922
UN proper shipping name
Corrosive liquid, toxic, n.o.s. (Arsenic Acid, Chromic Acid)
Transport hazard class(es)
Class
B
Subsidiary risk
6.1
Label(s)
8, 6.1
Packing group
II
Environmental hazards
No
ERG Code
8P
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IMOG
UN number
UN2922
UN proper shipping name
CORROSIVE LIQUID, TOXIC, N.O.S. (Arsenic Acid, Chromic Acid)
Transport hazard class(es)
Class
8
Subsidiary risk
6.1
Label(s)
8, 6.1
Packing group
II
Environmental hazards
Marine pollutant No
EmS F A, S-B
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Transport In bulk according to Not applicable.
Annex II of MARPOL 73178 and
the IBC Code
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200,
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Chromic Acid (CAS 1333--82-0)
0.1 % Annual Export Notification required.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Arsenic Acid (expressed as As205) (CAS 7778-39-4)
Cancer
Chromic Acid (CAS 1333-82-0)
Cancer
Arsenic Acid (expressed as As205) (CAS 7778-394)
Liver
Chromic Acid (CAS 1333-82-0)
Eye irritation
Arsenic Acid (expressed as As205) (CAS 7778-39.4)
Skin
Chromic Acid (CAS 1333-82-0)
Skin sensitization
Arsenic Acid (expressed as As205) (CAS 7778-39-4)
Respiratory irritation
K-33 (60%) Wood Preservative SDS US
924255 Version #: 03 Revision date: 05-June-2015 Issue date: 25-April-2015 719

Nervous system
Acute toxicity
CERCLA Hazardous Substance List (40 CFR 302.4)
Arsenic Acid (expressed as As2O5) (CAS 7778-39-4) LISTED
Cupric Oxide (CAS 1317-39-1) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 3111312 Hazardous No
chemical
SARA 313 (TRI reporting)
Chemical name
CAS number % by wt.
Chromic Acid 1333-82-0 29.9
Arsenic Acid (expressed as As2O5) 7778-39-4 20
Cupric Oxide 1317-39-1 10.5
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Arsenic Acid (expressed as As2O5) (CAS 7778-39-4)
Chromic Acid (CAS 1333-82-0)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Arsenic Acid (expressed as As2O5) (CAS 7778-394)
US. New Jersey Worker and Community Rightto-Know Act
Arsenic Acid (expressed as As2O5) (CAS 7778-39.4)
Chromic Acid (CAS 1333-82-0)
Cupric Oxide (CAS 1317-39-1)
US. Pennsylvania Worker and Community Right -to -Know Law
Arsenic Acid (expressed as As2O5) (CAS 7778-39-4)
Chromic Acid (CAS 1333-82-0)
US. Rhode Island RTK
Arsenic Acid (expressed as As2O5) (CAS 7778-39-4)
Cupric Oxide (CAS 1317-39-1)
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other
reproductive harm.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT}: Listed substance
Arsenic Acid (expressed as As2O5) (CAS 7778-39-4)
Chromic Acid (CAS 1333-82-0)
International Inventories
Country(s) or region Inventory name On inventory (yeslno)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non -Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINGS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
K-33 (60%) Wood Preservative SIDS US
924255 Version #: 03 Revision date: 05-June-2015 Issue date: 25-April-2015 8/9

Country(s) or region Inventory name On inventory (yes/no)'
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
'A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16.Other information, including date of preparation or last revision
Issue date
25-April-2015
Revision date
05-June-2015
Version #
03
Further information
HMISO is a registered trade and service mark of the NPCA-
B - Safety Glasses, Gloves
HMISO ratings
Health: 2
Flammability: 0
Physical hazard: 1
Personal protection: B
NFPA ratings
1
ox
Disclaimer Koppers Performance Chemicals Inc. cannot anticipate all conditions under which this information
and its product, or the products of other manufacturers in combination with its product, may be
used. It is the user's responsibility to ensure safe conditions for handling, storage and disposal of
the product, and to assume liability for loss, injury, damage or expense due to improper use. The
information in the sheet was written based on the best knowledge and experience currently
available.
K-33 (60%) Wood Preservative SDS US
924255 Version #: 03 Revision date: 05-June-2015 Issue date: 26-April-2015 9/9

KOPPERS
1. Identification
Product identifier
Other means of identification
SDS number
Product code
Recommended use
Recommended restrictions
SAFETY DATA SHEET
CleanWood Micro
273-KPC
EPA Reg. No. 72304-1-3008
Mold Inhibitor Additive for use at wood treatment plants.
None known.
Manufacturer/Importer/Supplier/Distributor information
Company Name
Koppers Performance Chemicals Inc.
Address
1016 Everee Inn Rd., Griffin, GA 30224
Telephone number
770-233-4200
Contact person
Regulatory Manager, KPC Inc.
Emergency Telephone
CHEMTREC 1-800-424-9300
Number
E-mail
[e-mail]
2. Hazard(s) identification
Physical hazards
Not classified.
Health hazards
Serious eye damageleye irritation Category 1
Sensitization, skin Category i
Carcinogenicity Category 2
Environmental hazards Specific target organ toxicity, single exposure Category 3 respiratory tract irritation
Hazardous to the aquatic environment, acute Category 1
hazard
OSHA defined hazards Hazardous to the aquatic environment, Category 2
long-term hazard
Label elements Not classified.
•
Signal word Danger
Hazard statement Causes serious eye damage. May cause an allergic skin reaction. Suspected of causing cancer.
May cause respiratory irritation. Very toxic to aquatic life with long lasting effects.
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Wear protective gloves/proiective dothingleye protectiontface protection.
Contaminated work clothing must not be allowed out of the workplace. Do not breathe dust or
mist. Use only outdoors or in a well -ventilated area. Avoid release to the environment.
Response If exposed or concerned: Get medical advice/attention. If on skin: Wash with plenty of soap and
water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing
before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. If inhaled: Remove person to fresh air and keep
comfortable for breathing. Collect spillage.
Storage Store in a well -ventilated place. Keep container tightly dosed. Store locked up.
Disposal Dispose of contents/container in accordance with kxal/regional/nationaUntemational regulations.
CteanWood Micro SDS US
117

Hazard(s) not otherwise
None known.
classified (HNOC)
3. Composition/information on ingredients
Mixtures
Chemical name
CAS number %
Water
7732-18-5 45-55
Chlorothalonil
1897-45-6 35-45
Propylene glycol
57-55-6 <5
Composition comments
All concentrations are in percent by weight unless ingredient is a gas_ Gas concentrations are in
percent by volume. The specific chemical identity and/or exact percentage of component(s) have
been withheld as a trade secret.
4. First -aid measures
Inhalation
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention.
Skin contact
Remove contaminated clothes and rinse skin thoroughly with water for at least 15 minutes. Call a
POISON CENTER or doctorlphysician.
Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove any contact lenses
and open eyelids wide apart. Get medical attention immediately. Continue to rinse.
Ingestion
Have affected person sip a glass of water if able to swallow. Do not induce vomiting unless told
by a poison control center or doctor_ Do not give anything by mouth to an unconscious person.
Most important
Headaches, dimness and nausea. Can cause blurred vision, redness, pain and eye damage.
symptoms/effects, acute and
Sensitization. Burning sensation in mouth.
delayed
Indication of immediate
Treat symptomatically.
medical attention and special
treatment needed
General information
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
S. Fire -fighting measures
Suitable extinguishing media Use carbon dioxide, foam, dry chemical or water.
Unsuitable extinguishing None known.
media
Specific hazards arising from By heating and fire, toxic vapors/gases may be formed.
the chemical
Special protective equipment Selection of respiratory protection for firefighting: follow the general fire precautions indicated in
and precautions for firefighters the workplace. Self-contained breathing apparatus and full protective clothing must be worn in
case of fire.
Fire fighting
Use standard firefighting procedures and consider the hazards of other involved materials. Cool
equipment/instructions
containers exposed to heat with water spray and remove container, if no risk is involved.
6. Accidental release measures
Personal precautions,
Avoid breathing vapors. Avoid skin and eye contact. Wear appropriate personal protective
protective equipment and
equipment (See Section 8).
emergency procedures
Methods and materials for
Should not be released into the environment For waste disposal, see Section 13 of the SDS.
containment and cleaning up
If possible, stop flow of product Contain and/or absorb spill with inert material, then place in
suitable container. Dispose of waste in accordance with local, state and federal regulations.
Environmental precautions
Prevent entry to sewers and public waters. Reporting of releases to appropriate regulatory
agencies may be required.
CleanWood Micro SDS US
217

7. Handling and storage
Precautions for safe handling Avoid contact with eyes, skin and clothing. Do not eat, drink or smoke when using this product.
Do not breathe dust from dried product. Wash thoroughly after handling. Wear appropriate
personal protective equipment Observe good industrial hygiene practices. Avoid release to the
environment.
Conditions for safe storage, Keep container tightly dosed in a dry, cool, and well -ventilated place.
Including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
Chemical name OSHA PEL ACGIH TLV Other Source
Propylene glycol Not established Not established 10 mglm3 TWA A1HA
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
wash facilities and emergency shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eyelface protection
Chemical goggles and face shield are recommended.
Skin protection
Hand protection
Wear impervious gloves to minimize skin contact. Frequent change is advisable.
Other
Wear appropriate chemical resistant clothing.
Respiratory protection
Not necessary under nominal conditions. In case of insufficient ventilation wear suitable respiratory
equipment. Use a NIOSHIMSHA approved air purifying respirator as needed to control exposure.
Consult with respirator manufacturer to determine respirator selection, use, and limitations. Use
positive pressure, air -supplied respirator for uncontrolled releases or when air purifying respirator
limitations may be exceeded. Follow respirator protection program requirements (OSHA
1910.134 and ANSI Z88.2) for all respirator use.
Thermal hazards Wear appropriate thermal protective doWng, when necessary.
General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Observe any medical surveillance requirements.
9. Physical and chemical properties
Appearance
Physical state
Liquid.
Form
Liquid.
Color
Medium beige.
Odor
Slight
Odor threshold
Not available.
PH
8-8
Melting pointlfreezing point
23 -F (-5 -C)
Initial boiling point and boiling
212 °F (100 °C)
range
Flash point
Not flammable.
Evaporation rate
Not determined.
Flammability (solid, gas)
Not applicable.
Upperllower flammability or explosive limits
Flammability limit - lower
Not available.
M
Flammability limit - upper Not available.
N
Explosive limit - lower (96) Not available.
Explosive limit - upper [96} Not available.
Vapor pressure 5.72 x 10-7 torn @ 25 °C
CleanWood Micro SDS US
317

Vapor density 1.1929 glml @ 20 °C
Relative density Not available.
Solubiltty(les)
Solubility (water)
Dispersible in water.
Partition coefficient
No data available.
(n-octanolfwater)
Auto -ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity
738.1 centistokes @ 25°C
Other Information
Bulk density
10.3 lb/gal (Approximate)
10. Stability and reactivity
Reactivity
The product is non reactive under normal conditions of use, storage and transport.
Chemical stability
Material is stable under normal conditions.
Possibility of hazardous
Will not occur.
reactions
Conditions to avoid
High temperatures. Incompatible materials.
Incompatible materials
None known.
Hazardous decomposition
Thermal decomposition can produce hydrogen chloride gas and nitrogen oxides.
products
11. Toxicological information
Information on likely routes of exposure
Inhalation Fatal if inhaled. Vapors and mist may irritate throat and respiratory system and cause coughing.
Skin contact May cause skin irritation. May cause an allergic skin reaction.
Eye contact Causes serious eye damage.
Ingestion May be harmful if swallowed. Ingestion may cause gastrointestinal imitation, nausea, vomiting and
diarrhea. Hypotension (low blood pressure).
Symptoms related to the Vapors may irritate throat and respiratory system and cause coughing. Headaches, dizziness and
physical, chemical and nausea. Can cause blurred vision, redness, pain and eye damage. Sensitization. Burning
toxicological characteristics sensation in mouth_
Information on toxicological effects
Acute toxicity
Components
Chlorothalonil (CAS 1897-45-6)
Acute
Dermal
LD50
Inhalation
LC50
Oral
LD50
Skin corroslon/lrritation
Serious eye damage/eye
Irritation
Respiratory or stein sensitization
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity
National Toxicity Program
Fatal if inhaled.
Species
Test Results
Rabbit > 2000 mg/kg
Rat 0.13 mg/l, 1 Hour
Rat 4100 mg/kg
Based on available data, the classification criteria are not met.
Causes serious eye damage.
Based on available data, the classification criteria are not met.
May cause an allergic skin reaction.
No data available.
Suspected of causing cancer.
Reasonably anticipated to be a human carcinogen.
CleanWood Micro SDS US
4/7

IARC Monographs. Overall Evaluation of Carcinogenicity
Chlorothalonil (CAS 1897-45-6) 2B Possibly carcinogenic to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity No data available.
Specific target organ toxicity - May cause respiratory irritation.
single exposure
Specific target organ toxicity - Based on available data, the classification criteria are not met.
repeated exposure
Aspiration hazard Not classified.
Chronic effects None known.
12. Ecological information
Ecotoxicity Very toxic to aquatic life with long lasting effects.
Components Species Test Results
Chlorothalonil (CAS 189745.6)
Aquatic
Crustaoea EC50 Water flea (Daphnia magna) 0.0342 - 0.143 mgll, 48 hours
Fish LC50 Rainbow trout,donaldson trout 0.012 mg/l, 96 hours
(Oncorhynchus mykiss)
Persistence and degradability The product contains inorganic compounds which are not biodegradable.
Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating. Log Pow = 2.9
(at 22 -C).
Mobility in soil Expected to have low mobility in soil.
Mobility in general Product is miscible with water and is expected to disperse in the soil.
Other adverse effects No other adverse environmental effects e.. ozone depletion,
( g pl photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions Dispose in accordance with applicable federal, state, and local regulations. Do not discharge into
Local disposal regulations
Hazardous waste code
Waste from residues 1 unused
products
Contaminated packaging
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Environmental hazards
Marine pollutant
IATA
UN number
drains, water courses or onto the ground.
Dispose of in accordance with local regulations.
The Waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose in accordance with all applicable regulations. Do not discharge into drains, water courses
or onto the ground.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
UN3082
Environmentally hazardous substances, liquid, n.o.s. (Chlorothalonil)
9
9
III
No
UN3082
UN proper shipping name Environmentally hazardous substances, liquid, n.o.s. (Chlorothalonil)
CleanWood Micro
SAS US
5r7

Transport hazard class(es)
Class 9
Subsidiary risk -
Label(s) 9
Packing group III
Environmental hazards Yes
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IMDG
UN number
UN3082
UN proper shipping name
Environmentally hazardous substances, liquid, N.O.S. (Chlorothalonil)
Transport hazard class(es)
Class
9
Subsidiary risk
-
Label(s)
9
Packing group
IIl
Environmental hazards
Marine pollutant
Yes
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Transport in bulk according to The material is not covered under Appendix I of the IMSBC Code.
Annex 11 of MARPOL 73178 and
the IBC Code
15. Regulatory information
US federal regulations This product is a 'Hazardous Chemicar as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, SubpL D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
BENZENE, HEXACHLORO- (CAS 118-74-1) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
Chlorothalonil 1897-45-6 3545
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
BENZENE, HEXACHLORO- (CAS 118-74-1)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Clean Water Act (CWA)
Section 112(r) (40 CFR
68.130)
Safe Drinking Water Act
(SDWA)
Hazardous substance
Not regulated.
CleanWood Micro SOS US
925732 Version P. 01 Revision date: - Issue date: 20-March-2015 6/7

US state regulations
US. Massachusetts RTK - Substance List
Chlorothalonil (CAS 1897-45-6)
US. New Jersey Worker and Community Right4o-Know Act
Chlorothalonil (CAS 1897-45-6)
US. Pennsylvania Worker and Community Right -to -Know Law
Chlorothalonil (CAS 1897-45-6)
US. Rhode Island RTK
Chlorothalonil (CAS 1897-45-6)
US. California Proposition 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Chlorothalonil (CAS 1897-45-6)
International Inventories
Country(s) or region Inventory name On Inventory (yes/no)"
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory No
'A 'Yes' indicates this product complies with the inventory requirements administered by the governing country(s).
A'No' indicates that one nr more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
1.6. Other information, including date of preparation or last revision
Issue date 20-March-2015
Revision date 22-June-2015
Version # 03
Further Information HMIS® is a registered trade and service mark of the NPCA.
D - Face Shield, Gloves, Apron
HMISV ratings Health: 3"
Flammability: 0
Physical hazard: 0
Personal protection: D
NFPA ratings
i
41 0
Disclaimer Koppers Performance Chemicals Inc. cannot anticipate all conditions under which this information
and its product, or the products of other manufacturers in combination with its product, may be
used. It is the users responsibility to ensure safe conditions for handling, storage and disposal of
the product, and to assume liability for loss, injury, damage or expense due to improper use. The
information in the sheet was written based on the best knowledge and experience currently
available.
CleanWood Micro SIDS US
717

SAFETY DATA SHEET
KOPPERS=
1. Identification
Product identifier
MP200-,A
Other means of identification
SDS number
258-KPC
EPA Reg. No.
3008-101
Recommended use
Preservative Concentrate Component used for the pressure treatment of wood.
Recommended restrictions
None known.
Manufacturer/imparter/Supplier/Distributor information
Company Name
Koppers Performance Chemicals Inc.
Address
1016 Everee Inn Rd., Griffin, GA 30224
Telephone number
770-233-4200
Contact person
Regulatory Manager, KPC Inc.
Emergency Telephone
CHEMTREC 1-800-424-9300
Number
E-mail
[e-mail]
2. Hazard(s) identification
Physical hazards Not classified.
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Serious eye damage/eye irritation Category 28
Hazardous to the aquatic environment, Category 1
long-term hazard
Not classified.
Warning
Causes eye irritation. Very toxic to aquatic life with long lasting effects.
Wear eyetface protection. Wash thoroughly after handling. Avoid release to the environment.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advicelattention. Collect
spillage.
Store away from incompatible materials.
Dispose of contents/container in accordance with IocaVregionallnationairintemational regulations.
None known.
3. Composition/information on ingredients
Mixtures
Chemical name
CAS number
%
Copper carbonate"
12069-69-1
3D-60
Water
7732-18-5
25-30
Dispersent,
Mixture
6-9
Tebuconazole
107534-96-3
1-2
MP200-A SDs U5
926215 Version #: 01 Revision date: - Issue date: 21-April-2015 117

57.6% as Copper Carbonate Copper oxide equivalent 41.70% Copper Metallic Equivalent 33.31 %
Composition comments
Ail concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume. Product contains either sodium benzoate or calcium nitrite at <1 %. It will not
contain both ingredients. Components not listed are either non -hazardous or are below reportable
limits.
4. First -aid measures
Inhalation
Move to fresh air. If breathing is difficult, remove to fresh air and keep at rest in a position
comfortable for breathing. Symptoms of toxicity may occur after several hours, therefore, medical
observation of breathing may be necessary.
Skin contact
Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact
Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses.
If eye irritation persists: Get medical advice/attention,
Ingestion
Rinse mouth with water and afterwards drink plenty of water. Get medical attention if symptoms
occur.
Most important
Symptoms may include coughing, difficulty breathing and shortness of breath. Symptoms include
symptoms/effects, acute and
itching, burning, redness, and tearing of eyes. Symptoms may include capillary damage,
delayed
headache, cold sweat, weak pulse, kidney and liver damage, central nervous excitation followed
by depression, jaundice, convulsions, blood effects, paralysis and coma. Death could occur from
shock or renal failure. May cause gastrointestinal disturbances.
Indication of Immediate
Treat symptomatically.
medical attention and special
treatment needed
General Information
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
5. Fire fighting measures
Suitable extinguishing media Use extinguishing agent suitable for type of surrounding fire.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting Move containers from fire area if you can do so without risk.
equipmentlinstructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
6. Accidental release measures
Personal precautions,
Ensure adequate ventilation. Avoid inhalation of mist and contact with skin and eyes. Keep
protective equipment and
unnecessary personnel away. Do not touch damaged containers or spilled material unless wearing
emergency procedures
appropriate protective clothing. Wear appropriate personal protective equipment (See Section 8).
Methods and materials for
Should not be released into the environment. Stay upwind. Keep out of low areas. For waste
containment and cleaning up
disposal, see Section 13 of the SDS.
Large Spills: Dike far ahead of spill for later disposal. Absorb or cover with dry earth, sand or other
non-combustible material and transfer to containers.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). After removal flush contaminated
area thoroughly with water.
Never return spills in original containers for re -use.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Reporting of
releases to appropriate regulatory agencies may be required.
7. Handling and storage
Precautions for safe handling Use only with adequate ventilation. Avoid inhalation of vapors/mist and contact with skin and eyes.
Wash thoroughly after handling. Wear appropriate personal protective equipment. Observe good
industrial hygiene practices. Avoid release to the environment.
Conditions for safe storage, Keep container tightly dosed in a dry and well -ventilated place. Store away from incompatible
including any Incompatibilities materials (see Section 10 of the SDS).
MP200-A SDS US
926215 Version #: 01 Revision date: - Issue date: 21-April-2015 21 7

8. Exposure controlslpersonal protection
Occupational exposure limits
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value Form
Copper carbonate' (CAS TWA 1 mg/m3 Dust and mist.
12069-69-1)
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Good general ventilation should be provided to minimize contact with vapors, or dust from
controls dried -down product Provide easy access to water supply and eye wash facilities.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear approved safety goggles.
Skin protection
Hand protection
Wear protective gloves. Be aware that the liquid may penetrate the gloves. Frequent change is
advisable. Suitable gloves can be recommended by the glove supplier.
Other
Wear appropriate chemical resistant clothing.
Respiratory protection
In case of insufficient ventilation wear suitable respiratory equipment. Use a NIOSH/MSHA
approved air purifying respirator as needed to control exposure. Consult with respirator
manufacturer to determine respirator selection, use, and limitations. Use positive pressure,
air -supplied respirator for uncontrolled releases or when air purifying respirator limitations may be
exceeded. Follow respirator protection program requirements (OSHA 1910.134 and ANSI Z88.2)
for all respirator use.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene
Always observe good personal hygiene measures, such as washing after handling the material
considerations
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Observe any medical surveillance requirements.
9. Physical and chemical properties
Appearance
Physical state
Liquid.
Form
Liquid.
Color
Blue green.
Odor
Latex.
Odor threshold
Not available.
pH
8.99
Melting point1freezing point
Not determined.
Initial boiling point and boiling
Not determined.
range
Flash point
Not determined.
Evaporation rate
Not determined.
Flammability (solid, gas)
Not applicable.
Upperilower flammability or explosive limits
Flammability limit - lower
Not available.
(%)
Flammability limit - upper
Not available.
(%)
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
Vapor density
Relative density
Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanol/water)
Not determined.
Not determined.
1.8 (H2O=1) (Approximate)
Soluble in water.
Not available.
MP200-A SDS US
926215 Version M 01 Revision date: - Issue date: 21-April-2015 3/7

Auto -ignition temperature
Decomposition temperature
viscosity
Other information
Bulk density
Density
Percent volatile
10. Stability and reactivity
Not available.
Not available,
Not available.
15 lb/gal
1.80 (Approximate)
Not determined.
Reactivity The product is stable and non -reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Avoid contact with incompatible materials.
Incompatible materials Sodium hypobromite. Acetylene. Hydrazine. Nitromethane. Strong acids. Reducing agents.
Hazardous decomposition Thermal decomposition or combustion may produce: CO, CO2, oxides of nitrogen and other
products potentially toxic gases.
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause respiratory irritation. Inhalation of fumes may cause a ilu4ike illness called metal fume
fever.
Skin contact Prolonged skin contact may cause temporary irritation.
Eye contact Causes eye irritation.
Ingestion Copper poisoning can result in hemolytic anemia and kidney, liver and spleen damage.
Symptoms related to the Symptoms may include coughing, difficulty breathing and shortness of breath. Symptoms include
physical, chemical and itching, burning, redness, and tearing of eyes. Symptoms may include capillary damage,
toxicological characteristics headache, cold sweat, weak pulse, kidney and liver damage, central nervous excitation followed
by depression, jaundice, convulsions, blood effects, paralysis and coma. Death could occur from
shock or renal failure. May cause gastrointestinal disturbances.
Information on toxicological effects
Acute toxicity
Not expected to be acutely toxic.
Product
Species
Test Results
MP200-A (CAS Mixture)
Acute
Dermal
LD50
Rat
> 2000 mglkg
Inhalation
LC50
Rat
> 2.05 mgll
Oral
LD50
Rat
> 2000 mg/kg
Components
Species
Test Results
Tebuconazole (CAS 107534-96-3)
Acute
Dermal
LD50
Rat
> 5000 mg/kg
Inhalation
LC50 Rat > 2.07 mg/I
Oral
LD50 Rat 1750 mglkg
Skin corrosion/irritation Skin irritation test (rabbit): Not a skin irritant.
Serious eye damage/eye Causes eye irritation.
irritation Eye irritation test (rabbit): Mildly irritating to the eye.
MP200-A SDS US
926215 Version #: 01 Revision date: - Issue date: 21 -April-201 5 4/7

Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization Skin sensitization (Guinea pig): Not a skin sensitizer.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1 % are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity Not classified.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not an aspiration hazard.
Chronic effects Prolonged skin contact may cause dermatitis.
12. Ecological information
Ecotoxicity Very toxic to aquatic life with long lasting effects.
Components Species Test Results
Copper carbonate' (CAS 12069-69-1)
EC50 Balanus balanoides 350 - 480 pgll, 48 hours
Persistence and degradability The product contains inorganic compounds for which biodegradability is not applicable.
Bloaccumulative potential No data available.
Mobility in soil This product is water soluble and may disperse in soil.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions Dispose in accordance with applicable federal, state, and local regulations. Do not discharge into
drains, water courses or onto the ground.
Local disposal regulations Dispose of in accordance with local regulations.
Hazardous waste code The Waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose in accordance with all applicable regulations. Do not discharge into drains, water courses
products or onto the ground.
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
UN number UN3082
UN proper shipping name Environmentally hazardous substance, liquid, n.o.s. (Tebuconazole, copper carbonate)
Transport hazard class(es)
Class 9
Subsidiary risk -
Label(s) 9
Packing group III
Environmental hazards Yes
ERG Code 9L
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IMDG
UN number UN3082
UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Tebuconazole, copper
carbonate)
MP200-A
926215 Version #: 01 Revision date: - Issue date: 21-April-2015
SDS US
517

Transport hazard class(es)
Class
9
Subsidiary risk
-
Label(s)
9
Packing group
III
Environmental hazards
Marine pollutant
Yes
EmS
F-A, S-F
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Transport in bulk according to
Not applicable.
Annex 11 of MARPOL 73178 and
the IBC Code
15. Regulatory information
US federal regulations This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302-4)
Copper carbonate (CAS 12069-69-1) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
SARA 313 (TRI reporting)
Chemical name CAS number % by wL
Copper carbonate' 12069-69-1 30-60
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Not regulated.
US. New Jersey Worker and Community Right -to -Know Act
Copper carbonate' (CAS 12069-69-1)
US. Pennsylvania Worker and Community Right -to -Know Law
Not listed.
US. Rhode Island RTK
Copper carbonate' (CAS 12069-69-1)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
MP200-A SOS US
926215 Version #: 01 Revision date: - Issue date: 21 -April-201 5 617

International Inventories
Country(s) or region Inventory name On inventory (yeslno)`
United States 1£ Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
'A 'Yes' indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
rountry(s).
16.Other information, including date of preparation or last revision
Issue date
21-April-2015
Revision date
-
Version #
01
Further information
HMIS® is a registered trade and service mark of the NPCA.
G - Safety Glasses, Gloves, Vapor Respirator
HMIS® ratings
Health: 1
Flammability: 0
Physical hazard: 0
Personal protection: G
NFPA ratings
r
0
Disclaimer Koppers Performance Chemicals Inc. cannot anticipate all conditions under which this information
and its product, or the products of other manufacturers in combination with its product, may be
used. It is the user's responsibility to ensure safe conditions for handling, storage and disposal of
the product, and to assume liability for loss, injury, damage or expense due to improper use. The
information in the sheet was written based on the best knowledge and experience currently
available.
MP200-A SDS us
926215 Version #: 01 Revision date: - Issue date: 21-April-2015 7/7

HE55
Safety Data Sheet
Material Name: Diesel Fuel, All Types SDS No. 9909
us OHS
Synonyms: Ultra Low Sulfur Diesel; Low Sulfur Diesel; No. 2 Diesel; Motor Vehicle Diesel Fuel; Non
Road Diesel Fuel; LocomotivelMarine Diesel Fuel
* * * Section 1 - Product and Company Identification
Manufacturer Information
Hess Corporation
1 Hess Plaza
Woodbridge, NJ 07095-Ml
Phone: [phone] Corporate EHS
Emergency # 800-424-9300 CHEMTREC
www.hess.com (Environment, Health, Safety Intemet Website)
* * * Section 2 - Hazards Identification
GHS Classification:
Flammable Liquids - Category 3
Skin Corrosionllmtation — Category 2
Germ Cell Mutageniaty — Category 2
Carcinogenicity - Category 2
Specific Target Organ Toxicity (Single Exposure) - Category 3 (respiratory irritation, narcosis)
Aspiration Hazard — Category 1
Hazardous to the Aquatic Environment, Acute Hazard — Category 3
GHS LABEL ELEMENTS
Symbol(s)
<*><
Signal Word
DANGER
Hazard Statements
Flammable liquid and vapor.
Causes skin irritation.
Suspected of causing genetic defects.
Suspected of causing cancer.
May cause respiratory irritation.
May cause drowsiness or dizziness.
May be fatal if swallowed and enter; airways.
Harmful to aquatic life.
Precautionary Statements
Prevention
Keep away from heattsparks/open flamesthot surfaces. No smoking
Keep container tightly closed.
Ground/bond container and receiving equipment.
Page 1 of 10 Revision Date 8130/12

Safety Data Sheet
Material Name: Diesel Fuel, All Types SDS No. 9909
Use explosion -proof electrical/ventilatingAightinglequipment.
Use only non -sparking tools.
Take precautionary measures against static discharge.
Wear protective gtoves/protecctive clothing/eye protection/face protection.
Wash hands and forearms thoroughly after handling.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Avoid breathing fume/mistivapours/spray.
Response
In case of fire: Use water spray, fog or foam to extinguish.
IF ON SKIN (or hair): Wash with plenty of soap and water. Remove/Take off immediately all contaminated
clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention-
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you
feel unwell.
If swallowed: Immediately call a poison center or doctor. Do NOT induce vomiting.
IF exposed or concerned: Get medical advice/attention.
Storage
Store in a well -ventilated place. Keep cool.
Keep container tightly dosed.
Store locked up.
Disposal
Dispose of contents/container in accordance with locaVregionallnationaUntemabonal regulations.
E: * * * Section 3 - Composition 1 information on ingredients * * * ::1
CAS #
Component
Percent
68476-34-6
Fuels, diesel, no. 2
100
91-20-3
Naphthalene
<0.1
A complex mbdure of hydrocarbons with carbon numbers in the range C9 and higher.
* * * Section 4 - First Aid Measures * * *
First Aid: Eyes
In case of contact with eyes, immediately flush with dean, low-pressure water for at least 15 min. Hold eyelids
open to ensure adequate flushing. Seek medical attention.
First Aid: Skin
Remove contaminated clothing. Wash contaminated areas thoroughly with soap and water or with waterless hand
cleanser. Obtain medical attention if irritation or redness develops. Thermal bums require immediate medical
attention depending on the severity and the area of the body burned.
First Aid: Ingestion
DO NOT INDUCE VOMITING. Do not give liquids. Obtain immediate medical attention. If spontaneous vomiting
occurs, lean victim forward to reduce the risk of aspiration. Monitor for breathing difficulties. Small amounts of
material which enter the mouth should be rinsed out until the taste is dissipated.
Page 2 of 10 Revision Date 8/30/12

Safety Data Sheet
Material Name: Diesel Fuel, All Types
First Aid: Inhalation
SDS No. 9909
Remove person to fresh air. If person is not breathing, provide artificial respiration_ If necessary, provide
additional oxygen once breathing is restored if trained to do so. Seek medical attention immediately.
I * * * Section 5 - Fire Fighting Measures * * * I
General Fire Hazards
See Section 9 for Flammability Properties.
Vapors may be ignited rapidly when exposed to heat, spark, open flame or other source of ignition. When mixed
with air and exposed to an ignition source, flammable vapors can bum in the open or explode in confined spaces.
Being heavier than air, vapors may travel long distances to an ignition source and flash back. Runoff to sewer
may cause fire or explosion hazard.
Hazardous Combustion Products
Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke).
Extinguishing Media
SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, CO2, water spray, fire fighting foam, and
other gaseous agents_
LARGE FIRES: Water spray, fog or fire fighting foam. Water may be ineffective for fighting the fire, but may be
used to cool fire -exposed containers_
Unsuitable Extinguishing Media
None
Fire Fighting Equipment/instructions
Small fires in the incipient (beginning) stage may typically be extinguished using handheld portable fire
extinguishers and other fire fighting equipment Firefighting activities that may result in potential exposure to high
heat, smoke or toxic by-products of combustion should require NIOSHIMSHA- approved pressure -demand self-
contained breathing apparatus with full facepiece and full protective clothing. Isolate area around container
involved in fire. Cool tanks, shells, and containers exposed to fire and excessive heat with water. For massive
fires the use of unmanned hose holders or monitor nozzles may be advantageous to further minimize personnel
exposure. Major fires may require withdrawal, allowing the tank to bum. Large storage tank fires typically require
specially trained personnel and equipment to extinguish the fire, often including the need for properly applied fire
fighting foam.
* * * Section S - Accidental Release Measures
Recovery and Neutralization
Carefully contain and stop the source of the spill, if safe to do so.
Materials and Methods for Clean -Up
Take up with sand or other oil absorbing materials. Carefully shovel, scoop or sweep up into a waste container for
reclamation or disposal. Caution, flammable vapors may accumulate in closed containers.
Emergency Measures
Evacuate nonessential personnel and remove or secure all ignition sources. Consider wind direction; stay upwind
and uphill, if possible. Evaluate the direction of product travel, diking, sewer;, etc. to confirm spill areas. Spills
may infiltrate subsurface soil and groundwater, professional assistance may be necessary to determine the extent
of subsurface impact.
Page 3 of 10 Revision Date 8/30/12

Safety Data Sheet
Material Name: Diesel Fuel, All Types SDS No. 9909
Personal Precautions and Protective Equipment
Response and clean-up crews must be property trained and must utilize proper protective equipment (see Section
8).
Environmental Precautions
Protect bodies of water by diking, absorbents, or absorbent boom, if possible. Do not flush down sewer or
drainage systems, unless system is designed and permitted to handle such material. The use of fire fighting foam
may be useful in certain situations to reduce vapors. The proper use of water spray may effectively disperse
product vapors or the liquid itself, preventing contact with ignition sources or areas/equipment that require
protection.
Prevention of Secondary Hazards
None
* * * Section 7 - Handling and Storage
Handling Procedures
Handle as a combustible liquid. Keep away from heat, sparks, excessive temperatures and open flame! No
smoking or open flame in storage, use or handling areas. Bond and ground containers during product transfer to
reduce the possibility of static -initiated fire or explosion.
Special slow load procedures for "switch loading" must be followed to avoid the static ignition hazard that can
exist when higher flash point material (such as fuel oil) is loaded into tanks previously containing low flash point
products (such as this product) - see API Publication 2003, "Protection Against Ignitions Arising Out Of Static,
Lightning and Stray Currents."
Storage Procedures
Keep away from flame, sparks, excessive temperatures and open flame. Use approved vented containers. Keep
containers dosed and clearly labeled. Empty product containers or vessels may contain explosive vapors. Do not
pressurize, cut, heat, weld or expose such containers to sources of ignition.
Store in a well -ventilated area. This storage area should comply with NFPA 30 "Flammable and Combustible
Liquid Code". Avoid storage near incompatible materials. The cleaning of tanks previously containing this product
should follow API Recommended Practice (RP) 2013 "Cleaning Mobile Tanks In Flammable and Combustible
Liquid Service" and API RP 2015 "Cleaning Petroleum Storage Tanks."
Incompatibilities
Keep away from strong oxidizers.
I * * * Section 8 - Exposure Controls I Personal Protection * * *- I
Component Exposure Limits
Fuels, diesel, no. 2 (68476-34-6)
ACGIH. 100 mg/m3 TWA (inhalable fraction and vapor, as total hydrocarbons, listed under Diesel fuel)
Skin - potential significant contribution to overall exposure by the cutaneous route (listed under
Diesel fuel)
Page 4 of 10 Revision Date 8/30/12

Safety Data Sheet
Material Name: Diesel Fuel, All Types SOS No. 9909
Naphthalene (91-20-3)
ACGIH: 10 ppm TWA
15 ppm STEL
Skin - potential significant contribution to overall exposure by the cutaneous route
OSHA: 10 ppm TWA; 50 mglm3 TWA
NIOSH: 10 ppm TWA; 50 mglm3 TWA
15 ppm STEL; 75 mglm3 STEL
Engineering Measures
Use adequate ventilation to keep vapor concentrations of this product below occupational exposure and
flammability limits, particularly in confined spaces.
Personal Protective Equipment: Respiratory
A NIOSHIMSHA-approved air -purifying respirator with organic vapor cartridges or canister may be permissible
under certain circumstances where airborne concentrations are or may be expected to exceed exposure limits or
for odor or irritation. Protection provided by air -purifying respirators is limited.
Use a positive pressure, air -supplied respirator if there is a potential for uncontrolled release, exposure levels are
not known, in oxygen -deficient atmospheres, or any other circumstance where an air -purifying respirator may not
provide adequate protection.
Personal Protective Equipment: Hands
Gloves constructed of nitrile, neoprene, or PVC are recommended.
Personal Protective Equipment: Eyes
Safety glasses or goggles are recommended where there is a possibility of splashing or spraying.
Personal Protective Equipment: Skin and Body
Chemical protective clothing such as of E.I. DuPont TyChem®, Saranex® or equivalent recommended based on
degree of exposure. Note: The resistance of specific material may vary from product to product as well as with
degree of exposure. Consult manufacturer specifications for further information.
I * * * Section 9 - Physical & Chemical Properties * * * I
Appearance:
Physical State:
Vapor Pressure:
Boiling Point.
Solubility (H20):
Evaporation Rate:
Percent Volatile:
Flash Point:
Upper Flammability Limit
(UFL):
Burning Rate:
Clear, straw -yellow.
Liquid
0.009 psia @ 70 °F (21 °C)
320 to 690 T (160 to 366 -C)
Negligible
Slow, varies with conditions
100%
>125 -F (>52 °C) minimum
7.5
Odor.
pH:
Vapor Density:
Melting Point:
Specific Gravity:
VOc:
OctanoUN20 Coeff.:
Mild, petroleum distillate odor
NO
>1.0
NO
0.W-0.876 @ 60-F (16-C)
NO
NO
Flash Point Method: PMCC
Lower Flammability Limit 0.6
(LFL):
Auto Ignition: 494°F (257°C)
* * * Section 10 - Chemical Stability & Reactivity Information
Chemical Stability
This is a stable material.
Hazardous Reaction Potential
Will not occur.
Page 5 of 10
Revision Date 8/30/12

Safety Data Sheet
Material Name: Diesel Fuel, All Types
Conditions to Avoid
Avoid high temperatures, open flames, sparks, welding, smoking and other ignition sources.
Incompatible Products
Keep away from strong oxidizers.
Hazardous Decomposition Products
Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke).
SDS No. 9909
I * * * Section I I - Toxicological Information * * * I
Acute Toxicity
A: General Product Information
Harmful if swallowed.
B: Component Analysis - I-D5011-050
Naphthalene (91 20-3)
Inhalation LC50 Rat >340 mg/m3 1 h; Oral LD50 Rat 490 mglkg; Dermal LD50 Rat >2500 mg/kg; Dermal LD50
Rabbit >20 g/kg
Potential Health Effects: Skin Corrosion Property/Stimulativeness
Practically non -toxic if absorbed following acute (single) exposure. May cause skin irritation with prolonged or
repeated contact. Liquid may be absorbed through the skin in toxic amounts if large areas of skin are repeatedly
exposed.
Potential Health Effects: Eye Critical Damage/ Stimulativeness
Contact with eyes may cause mild irritation.
Potential Health Effects; Ingestion
Ingestion may cause gastrointestinal disturbances, including irritation, nausea, vomiting and diarrhea, and central
nervous system (brain) effects similar to alcohol intoxication. In severe cases, tremors, convulsions, loss of
consciousness, coma, respiratory arrest, and death may occur.
Potential Health Effects: Inhalation
Excessive exposure may cause irritations to the nose, throat, lungs and respiratory tract. Central nervous system
(brain) effects may include headache, dizziness, loss of balance and coordination, unconsciousness, coma,
respiratory failure, and death.
WARNING: the burning of any hydrocarbon as a fuel in an area without adequate ventilation may result in
hazardous levels of combustion products, including carbon monoxide, and inadequate oxygen levels, which may
cause unconsciousness, suffocation, and death.
Respiratory Organs Sensitization/Skin Sensitization
This product is not reported to have any skin sensitization effects.
Generative Cell Mutagenicity
This material has been positive in a mutagenicity study.
Carcinogenicity
A: General Product Information
Suspected of causing cancer.
Page 6 of 10
Revision Date 8130/12

Safety Data Sheet
Material Name: Diesel Fuel, All Types
SDS No. 9909
Studies have shown that similar products produce skin tumors in laboratory animals following repeated
applications without washing or removal. The significance of this finding to human exposure has not been
determined. Other studies with active skin carcinogens have shown that washing the animal's skin with soap and
water between applications reduced tumor formation. .
B: Component Carcinogenicity
Fuels, diesel, no. 2 (68476-34-6)
ACGIH: A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans (listed under Diesel
fuel)
Naphthalene (91-20-3)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
NTP: Reasonably Anticipated To Be A Human Carcinogen (Possible Select Carcinogen)
IARC: Monograph 82 [2002] (Group 2B (possibly carcinogenic to humans))
Reproductive Toxicity
This product is not reported to have any reproductive toxicity effects.
Specified Target Organ General Toxicity: Single Exposure
This product is not reported to have any specific target organ general toxicity single exposure effects.
Specified Target Organ General Toxicity: Repeated Exposure
This product is not reported to have any specific target organ general toxicity repeat exposure effects.
Aspiration Respiratory Organs Hazard
The major health threat of ingestion occurs from the danger of aspiration (breathing) of liquid drops into the lungs,
particularly from vomiting. Aspiration may result in chemical pneumonia (fluid in the lungs), severe lung damage,
respiratory failure and even death.
I * * * Section 12 - Ecological Information * * * I
Ecotoxicity
A: General Product Information
Keep out of sewers, drainage areas and waterways. Report spills and releases, as applicable, under Federal and
State regulations.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Fuels, diesel, no. 2 (68476-34-6)
Test & Species Conditions
96 Hr LC50 Pimephales promelas 35 mg/L [flow -
through]
Naphthalene (91-20-3)
Test & Species
Conditions
96 Hr LC50 Pimephales promelas
5.74-6.44 mg1L
[flow -through]
96 Hr LC50 Oncorhynchus mykiss
1_6 mg/L [flow -
through]
96 Hr LC50 Oncorhynchus mykiss
0.91-2.82 mg/L
[static]
96 Hr LC50 Pimephales promelas
1.99 mg/L [static]
Page 7 of 10 Revision Date 8/30112

Safety Data Sheet
Material Name: Diesel Fuel, All Types SIDS No. 9909
96 Hr LC50 Lepomis macrochirus 31.0265 mg/L
[static]
72 Hr EC50 Skeletonema costatum
0.4 mg1L
48 Hr LC50 Daphnia magna
2.16 mg1L
48 Hr EC50 Daphnia magna
1.96 mg/L [Flow
through]
48 Hr EC50 Daphnia magna
1.09 - 3.4 mg/L
[Static]
Persistence/Degradability
No information available.
Bioaccumulation
No information available.
Mobility in Soil
No information available.
* * * Section 13 - Disposal Considerations
Waste Disposal Instructions
See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations.
Disposal of Contaminated Containers or Packaging
Dispose of contents/container in accordance with IocaVregionaVnationaVintemational regulations.
[ * * * Section 14 - Transportation Information * * * I
DOT Information
Shipping Name: Diesel Fuel
NA #: 1993 Hazard Class: 3 Packing Group: III
Placard:
* * * Section 15 - Regulatory Information
Regulatory Information
Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302
(40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Naphthalene (91 20-3)
CERCLA: 100 Ib final RQ; 45.4 kg final RQ
SARA Section 311/312 — Hazard Classes
Acute Health Chronic Health Fire Sudden Release of Pressure Reactive
X X X — —
Page 8 of 10 Revision Date 8/30/12

Safety Data Sheet
Material Name: Diesel Fuel, All Types
SDS No. 9909
SARA SECTION 313 - SUPPLIER NOTIFICATION
This product may contain fisted chemicals below the de minimis levels which therefore are not subject to the
supplier notification requirements of Section 313 of the Emergency Planning and Community Right- To -Know Act
(EPCRA) of 1986 and of 40 CFR 372. If you may be required to report releases of chemicals listed in 40 CFR
372.28, you may contact Hess Corporate Safety if you require additional information regarding this product.
State Regulations
Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component
CAS
CA
MA
MN
NJ
PA
RI
Fuels, diesel, no. 2
68476-34-6
No
No
I No
Yes
I No
No
Naphthalene
91-20-3
Yes
Yes
Yes
Yes
Yes
No
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of
1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
Component Analysis - WHMIS IDL
No components are listed in the WHMIS IDL.
Additional Regulatory Information
Component Analysis - Inventory
Component
CAS #
TSCA
CAN
EEC
Fuels, diesel, no. 2
68476-34-6
Yes
DSL
EINECS
Naphthalene
91-20-3
Yes
DSL
EINECS
* * * Section 16 - Other Information * *
NFPA® Hazard Rating Health 1
Fire 2
Reactivity 0 p'
HMIS® Hazard Rating Health 1 * Slight
Fire 2 Moderate
Physical 0 Minimal
'Chronic
Page 9 of 10
Revision Date 8/30/12

Safety Data Sheet
Material Name: Diesel Fuel, All Types SDS No. 9909
Key/Legend
ACGIH = American Conference of Govemmental Industrial Hygienists; ADG = Australian Code for the Transport
of Dangerous Goods by Road and Rail; ADRIRID = European Agreement of Dangerous Goods by Road/Rail; AS
= Standards Australia; DFG = Deutsche Forschungsgemeinschaft; DOT = Department of Transportation; DSL =
Domestic Substances List; EEC = European Economic Community; EINECS = European Inventory of Existing
Commercial Chemical Substances; EI_INCS = European List of Notified Chemical Substances; EU = European
Union; HMIS = Hazardous Materials Identification System; IARC = International Agency for Research on Cancer;
IMO = International Maritime Organization; IATA = International Air Transport Association; MAK = Maximum
Concentration Value in the Workplace; NDSL = Non -Domestic Substances List; NFPA = National Fire Protection
Association; NOHSC = National Occupational Health & Safety Commission; NTP = National Toxicology Program;
STEL = Short-term Exposure Limit; TDG = Transportation of Dangerous Goods; TLV = Threshold Limit Value;
TSCA = Toxic Substances Control Act; TWA = Time Weighted Average
Literature References
None
Other Information
Information presented herein has been compiled from sources considered to be dependable, and is accurate and
reliable to the best of our knowledge and belief, but is not guaranteed to be so. Since conditions of use are
beyond our control, we make no warranties, expressed or implied, except those that may be contained in our
written contract of sale or acknowledgment. '
Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if
reasonable safety procedures are not adhered to as stipulated in the data sheet Additionally, vendor assumes no
responsibility for injury to vendee or third persons proximately caused by abnormal use of the material, even if
reasonable safety procedures are followed_ Furthermore, vendee assumes the risk in their use of the material.
Page 10 of 10
End of Sheet
Revision Date 8/30/12