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Home My WebLink AboutWQ0011413_Residual Annual Report 2018_20190315INITIAL REVIEW Reviewer Williams, Kendall Project Number* WQ0011413 SUBMITTAL DATED: 3/15/2019 Project Contact Information Rease provide inforrration on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other issues. ...................................................................................................................................................................................................................................................................................................................................................................................................... Name * Scott Smart Email Address* randolph.smart@ncdps.gov Project Information ...... ............................. Application Type* r New r Renewal r Annual Report Permit Type * r Wastewater Irrigation r Other Wastewater • Closed -Loop Recycle r Single -Family Residence Wastewater Irrigation Is a paper copy of the application being submitted?* r Yes r Nor N/A Permit Number* WQ0011413 Permittee * NC Department of Public Safety Facility Name * Odom Correctional Institute Phone Number* 919-324-1254 r Modification (Major or Minor) • Additional Information r Other • High -Rate Infiltration r Reclaimed Water r Residuals r Other Please provide comments/notes on your current submittal below. Two paper copies will be hand delivered today. Please attach all information required or requested for this submittal to be review here. Application Form Engineering Rans, Specifications, Calculations, Etc.) WQ0011413 2018 Annual Report (full package).pdf 4.38MB upload only 1 RDF docurrent. IVufiple documents rust be contained into one RDF file. For nein and modif cation permit applications, the paper copy is required to be submitted to the Di, risiom Be advised, applications will not be considered complete until both the paper and electronic applications. have been received_ The paper copy shall include the follm ging: • Application Farm • All relevant attachments (talcs, soils report, specs, etc_) • 1 full-size engineering plan set • 2 11-17" engineering plan sets • 1 extras set of specifications (in addition to the set of specifications Provided in the attachments) • Fee (if required) This shall be mailed to the following address: By US_ Postal Service- Di,vision of Water Resources- Non -Discharge Branch 1617 Mail Service Center Raleigh NC 27699-1617 By Courier, -Special Delivery: Division of Water Resources- Non -Discharge Branch Nathaniel Thornburg- 9th Floor, Office #942M 512 N_ Salisbury St_ Raleigh, NC 27644 For questions or problems contact Tessa Monday at 919.7073660 or Tessa_X%nday(dncdem_gov or Sonia Graves at 919.707.3657 or Sonia Graves(dpcdenr.gov. *140 By checking this box I am acknowledging that I have read the above statement and agree to send these documents as required to one of the address given above. Signature Submission Date 3/15/2019 NCDEQ Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699 Subject: 2018 Annual Biosolids Land Application Certification North Carolina Department of Public Safety — Odom Correctional Institution Permit #WQ0011413 Northampton County, N.C. Dear Madam or Sir, Enclosed for your review is the 2018 Annual Report for the monitoring and reporting of the Biosolids Land Application Program for the NCDPS Odom Correctional Institution as required by 40 CFR -503 Regulations. There were no changes this past year to the Land Application program at Odom C.I. We did most of our spraying late in the season. One issue which I must bring to your attention is that I have been unable to locate the soil tests performed for 2018. I have included the soil tests for 2017 and 2016. Should 2018's be located, I will amend this report. However, I do not anticipate such an event happening. I will be certain to conduct and maintain 2019's soil test records for our next year should I still be the responsible party during that season. Should you have any further question or comments, please contact me at geo.s.pittard@gmail.com or (252) 532-0664 Sincerely, �35�0011, Geoffrey S. Pittard Odom Correctional Institution ORC LA# 1003310 NCDPS- Odom Correctional Institution Northampton County, NC Residuals Land Application Program 2018 Annual Report Table of Contents 1. ACF —Annual Land Application Certification Form, I Annual Operations Summary, Facility and Operator -in -Responsible Charge (ORC) Contact on 2. RSSF — Annual Residual Sampling Fon-n, Residual Analysis 3. MFLSF — Annual Metals Loading Summary Form (by Zone) 4. FSF — Annual Land Application Field Summary Form (by Zone) 5. PVRT — Annual Pathogen and Vector Attraction Reduction Form (503 Rule), SOURS Test 6. Soil Analysis 7. TCLP Analysis 8. Copies of Lab Results ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit#: WQ0011413 County: Northampton Year: 2018 Facility Name (as shown on permit): North Carolina Department of Public Safety — Odom Correctional Ins. Land Application Operator: Geoffrey S Pittard Phone: 252-532-0664 Land application of residuals as allowed by the permit occurred during the past calendar year? Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A - Residuals Application Summary: Total number of application fields in the permitJ 3 Total number of fields utilized for land application during the ear: 1 Total amount of dry tons applied during the year for all application sites: 2.15 Total number of acres utilizes for land application during the year: 41.4 Part B - Annual Compiance Statement: Facility was compliant during calendar year 2018 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Resources. ❑ Yes 0 No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. See included Letter NOV and NOV Response. The NOV has been closed by DEO 's RRO. 1) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities). 7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Resources. 10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified in the permit. 12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application of residuals. Part C - Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Jeffrey T. OBriant, Director of Engineering Permittee Name and Title (type or print) or�5.nal r..i...,1W41 .?/►�q k"Moo cl� -M 510,0�� Sign r of ermittee Date SiKaiGre of Preparer* Date Signature of Land Applier Date (if different from Permittee) (if different from Permittee and Preparer) * Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (1212006) tl�tittt:i €ts�Sc.tlrCes I'll\ ti kill. 11.,: 11F.i1 t};t,!liFS September 5, 2018 CERTIFIED MAIL 7016 3564 0009 4428 5126 RETURN RECEIPT REQUESTED Mr. William Stovall, P.E. NC Department of Public Safety 4216 Mail Service Center Raleigh, NC 27699 ROY COOPER (!n ver lar MICHAEL S. REGAN -Sccl:•I:r:1• LINDA CU'LK-PPE.R Subject: NOTICE OF VIOLATION N0V-2018-IAC-4164 Odom Correctional Institution -Land Application of Class 13 Residuals Permit WQ00114I3 Northampton County Dear Mr. Stovall, _ Oil May 9, 2018, Rick Trone and Ray Milosh of the Raleigh Regional Office conducted a compliance evaluation inspection of the residuals management program located at the Odom Correctional Institution. The purpose of this inspection was to ensure compliance with the subject permit. During the inspection, the knowledge and cooperation of Julio Oms was helpful and appreciated. The Odom Correctional Institution is located at 485 Odom Prison Road in Jackson, North Carolina. Class B residuals are generated at au onsite class WIN -2 wastewater treatment plant that treats domestic wastewater. Residuals generated at the facility are approved to be applied to three sites known as Tracts A -C totaling 85.10 acres. The facility is permitted to apply a tnaxintum of 7.5 dry tons per year. This compliance evaluation inspection consisted of tile following: a Review of the permit; Review of tine ownerlfacility information; Review of the previous 3 annual reports Review of log books, i"spection lolls, land application event records, residual sampling., forms lab analytical results, pathogen and vector Wit"action reduction fortis, soil reports, TCLP analyses, etc., and; On-site inspection of the land apq)iication sites .L'rtlliYly CQ['i7t�3rC'3:,- €:::, t'idii �Ci �:45: l Viitil ! I.7 t:7'_'ii,':ti•::.1t: ;�ili,tFiiF� .ry. f �"i•IiY.�.'fi Jt 9--;vl..j�i 1 NOV-1018-PC-0164 Odom Correctional Institution Page 3 of 3 If you have questions or comments about the inspection, this report or the requirements to take corrective action, please contact Rick Trone at 919-7914257 orvin email at I�i.:i..t �7,tCCci't�cele e�r.0 Sincerely, Rick Bolich, L.G., Assistant Regional Supervisor Water Quality Regional Operations Section Raleigh Regional Office Attachments: Inspection Report cc: Nainesh Patel, P.E. via ilaines' WQOO11413 RRO Pile DWR WQROS Central Files DM��3 North Carolina Department of Public Safety Cenirai Engineering Roy Cooper, Governor Casaudra Skinner Hoekstra, Chief Deputy Secretary Erik A. Hooks, Secretary Douglas Holbrook, Chief Financial Officer Jeffrey O'Briant, Director September 17, 2018 Mr. Rick Bolich, L.G. Assistant Regional Supervisor DEQ/WQROS/RRO 1628 MSC Raleigh, NC 27699 In Re: NOV-2018-PC-0164 Odom Correctional Institution- Land Application of Class B Residuals Permit WQ0011413 Northampton County Dear Mr. Bolich, The Department of Public Safety (DPS) appreciates the opportunity to reply to the findings of your inspection on May 9, 2018. DPS has reviewed your notes from the site visit related to the use and condition of application tracts (A, B, and Q. At current time DPS is working with a consultant on a minor permit modification to install an access road across tract A. Included with this permit modification work is an internal evaluation to increase utilization of additional areas in the permitted tracts. DPS offers the following responses to the permit violation items identified in your letter: Condition 3 of Section M of the operating permit requires that the Raleigh Regional Office receive 24 hours' notice prior to any land application activity. Response: As identified in your inspection report, there has been unplanned staff changes at this location. Our certified operator, Geoffrey Pittard (# NC1003310) and maintenance supervisor for this facility have been reminded of this requirement. The Central Engineering (CE) department has been made aware that the notification protocol was followed with the recent application completed on September 12, 2018. Future notifications are planned to be sent via email for documentation and Incorporation into the site log book. This situation has prompted additional attention to improve DPS processes during staff turnover and changes. Included within these improvements, CE staff Is preparing a new hire/transfer of operator responsibility orientation to be signed off on by any newly designated ORC or back-up ORC. Included in this orientation will be a review of the permit and all permit conditions by the ORC and the ORC's supervisor. Condition 5 of Section f of the operating permit requires that the permittee designate and employ an ORC and back-up ORC. Response: At the time of the inspection, DPS was in negotiations to bring back Geoffrey Pittard to act as the ORC. Geoffrey departed his ORC MAIIdNG ADDRESS: 4216 Mail Service Center Raleigh, NC 27699-4216 www.ncdps.gov An Equal OAaanu * Employer OFFICE LOCATION: 2020 Yonkers Road Raleigh, NC 27604 Telephone: (919) 716-3400 Fax: (919) 716-3978 North Carolina Department of Public Safety Odom Correctional Institution Residual Solids Land Application (503) Northampton County Permit #WQ0011413 2018 Total Gallons of Biosolids Applied Month Loads Gallons January 0 0 February 0 0 March 0 0 April 0 0 May 0 0 June 0 0 July 0 0 August 8 12000 September 17 25500 October 1 1500 November 0 0 December 0 0 Total: 39000 North Carolina Department of Public Safety Odom Correctional Institution Residual Solids Land Application (503) Northampton County Permit #WQ0011413 Date Tract Zone Lot Loads 09/05/18 B 1 3 1 Total Zone 1 Loads: 1 Total Zone 2 Loads: 0 08/22/18 B 3 1 2 08/23/18 B 3 1 3 08/31/18 B 3 3 3 09/04/18 B 3 2 2 09/10/18 B 3 3 3 09/11/18 B 3 3 5 09/12/18 B 3 2 6 10/15/18 B 3 1 1 Total Zone 3 Loads: 25 Total Loads: 26 NCDPS- Odom Correctional Institution Residuals Land Application Program 2018 Annual Report Facilit Odom Correctional Institution 485 Odom Prison Rd. Jackson, NC 27845 (252) 534-5611 Permit Number: WQ0011413 Responsible -Official* Jeremy Phelps Facility Maintenance Supervisor NCDPS Odom Correctional Institution PO Box 36 485 Odom Prison Rd Jackson NC 27845 (252) 574-2351 ORC: Geoffrey S Pittard 7561 NC Highway 48 Roanoke Rapids, NC 27870 (252) 532-0664 LA License #1003310 Land A . licationR ort Prepared By: Geoffrey S Pittard A M O O d • u N N O I z zz �z a COO E, w I a U �� 0 AL � � o nn ci p I Qn 'fir Vii a Q LL I O 00 b o Cn "0 a U b�JOrA ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Odom Correctional Institution Total Dry Tons Applied (Annual): 0.08 ID--rmit #: WQ0011413 Cation Exchange Capacity (non 503 only): erator: Geoffrey S Pittard Owner: NC DPS Predominant Soil Series: Acres Used: 13.8 Acres Permitted: 41.4 Site #: Tract - B Field #: Zone 1 Residual Analdsis Data [Heavy Metals and Total Phosahorus use me/kis. % Solids use Raw Percent #1: Sample or Com- posite Date 9/5/18 gs (Calculated in lbs/acre): Total % Solids 1.32 H DT/Ac./ Arsenic 0.053 0 App. Cadmium 1.02 14 Event 0.08 Copper 222.7 Arsenic 0.000 0.000 0.000 0.000 0.000 Chromium 14.4 0.000 0.000 0.000 0.000 0.000 0.000 Cadmium 0.000 0.000 0:000 0.000 Lead 17.42 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Copper 0.036 0.000 0.000 Mercury 3.712 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.036 Chromiuni 0.002 0.000 Molyb- denum 18.2 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Lead 0.003 Nickel 3.106 0.000 0.000 0.000 0.000 j 0.000 0.000 0.000 0.000 0.000 0.003 Mercury Selenium 2.04 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.001 Zinc 770.46 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Total `'hos- porus 20450 Annual Heavy Metal Field Loa din gs (Calculated in lbs/acre): Total H DT/Ac./ 0 App. 14 Event 0.08 Arsenic 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cadmium 0.000 0.000 0:000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Copper 0.036 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.036 Chromiuni 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Lead 0.003 0.000 0.000 0.000 0.000 0.000 0.000 j 0.000 0.000 0.000 0.000 0.000 0.003 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.001 Molyb- 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 denum Nickel 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Selenium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Zinc 0.123 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.123 Total Phos- 3.272 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.272 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a sXstem designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am ire that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". 7 f Land A lien ate Siiature o pp ANNUAL METALS FIELYM G SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Odom Correctional Institution Total Dry Tons Applied (Annual): emit #: WQ0011413 Cation Exchange Capacity (non 503 only): Operator: Geoffrey S Pittard Owner: NC DPS Predominant Soil Series: Acres Used: 13.8 Acres Permitted: 41.4 Site #: Tract - B Field #: Zone 2 Residual Analvsis Data (Heavy Metals and Total Phosnhorus use mg/kg. % Solids use Raw Percent #): Sample or Com- posite Date 1 2 3 J 4j 5 6 7 j L 8 _2_J LJ II J 12 % Solids y DT/Ac./ 0 App. Arsenic � Event Arsenic 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cadmium 0.000 0.000 0.000 0.000 Cadmium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 Copper 0.000 1 0.000 0.000 0.000 0.000 0.000 Copper 0.000 0.000 0.000 0.000 0.000 0.000 Chromiun 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Mercury 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 Lead 0.000 Molyb- 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 denum Nickel 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Mercury 0.000 0.000 Selenium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Zinc 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Molyb- denum 0.000 0.000 0.000 Total Phos- 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 chorus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a Nickel information submitted. I am -.vare that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Selenium Signa urs of Land Applier ate Zinc Total hos- phorus Annual Heavy Metal Field Loadingls Calculated in lbs/acre : Total 1 2 3 4 5 6 7 y DT/Ac./ 0 App. � Event Arsenic 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Cadmium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 Copper 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Chromiun 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Mercury 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 Molyb- 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 denum Nickel 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Selenium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Zinc 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Total Phos- 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 chorus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a _item designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am -.vare that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signa urs of Land Applier ate ANNUAL METALS FIELll-LVJ&�G SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Odom Correctional Institution Total Dry Tons Applied (Annual): Z06g2 mit #: WQ0011413 Cation Exchange Capacity (non 503 only): Operator: Geoffrey S Pittard Owner: NC DPS Predominant Soil Series: Acres Used: 13.8 Acres Permitted: 41.4 Site #: Tract - B Field #: Zone 3 Residual Analvsis Data (Heavv Metals and Total Phosnhorus use mg/lig. % Solids use Raw Percent #): Sample or Com- posite Date 8/22/18 8/23/18 8/31/18 9/4/18 9/10/18 9/11/18 9/12/18 10/15/18 % Solids 1.32 1.32 1.32 1.32 1.32 1.32 1.32 1.32 App, Arsenic 0.053 1 0.053 0.053 0.053 1 0.053 0.053 0.053 0.053 0.41 0.04 0.50 Cadmium 1.02 1.02 1.02 1.02 1.02 1.02 1.02 1.02 0.000 0:000 0.000 Cadmium 0.000 0.001 0.001 0.000 Copper 222.7 222.7 222.7 222.7 222.7 222.7 222.7 222.7 0.111 0.183 0.016 0.220 0.000 Chromimi 14.4 14.4 14.4 14.4 14.4 14.4 14.4 14.4 0.000 0.000 0.000 0.058 Lead 17.42 17.42 17.42 17.42 17.42 17.42 17.42 17.42 Mercury 0.001 0.002 0.002 0.001 0.002 0.003 0.000 Mercury 3.712 3.712 3.712 3.712 3.712 3.712 3.712 3.712 0.018 0.000 0.000 0.000 0.000 Molyb- denum 18.2 18.2 18.2 18.2 18.2 18.2 18.2 18.2 0:013 Selenium0.001 0.001 0.001 0.001 0.001 0.002 Nickel 3.106 3.106 3.106 3.106 3.106 3.106 3.106 3.106 0.055 0.763 0.000 0.0000.000 Selenium 2.04 2.04 2.04 2.04 2.04 2.04 2.04 2.04 0.000 82.737 phorus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a Zinc 770.46 770.46 770.46 770.46 1 770.46 770.46 770.46 770.46 Total hos- horus 20450 20450 20450 20450 20450 20450 20450 20450 Annual Heavy Metal Field Loa din =s (Calculated in lbs/acre): Total y DT/Ac./ App, y Event 0.17 0.25 0.25 0.17 0.25 0.41 0.04 0.50 Arsenic 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0:000 0.000 Cadmium 0.000 0.001 0.001 0.000 0.001 0.001 0.000 0.001 0.000 0.000 0.000 0.000 0.004 Copper 0.073 0.110 0.111 0.076 0.111 0.183 0.016 0.220 0.000 0.000 0.000 0.000 0.901 'hromiun 0.005 0.007 0.007 0.005 0.007 0.012 0.001 0.014 0.000 0.000 0.000 0.000 0.058 Lead 0.006 0.009 0.009 0.006 0.009 0.014 0.001 0.017 0.000 0.000 0.000 0.000 0.070 Mercury 0.001 0.002 0.002 0.001 0.002 0.003 0.000 0004 0.000 0.000 0.000 0.000 0.015 Molyb- 0.006 0.009 0.009 0.006 0.009 0.015 0.001 0.018 0.000 0.000 0.000 0.000 0.074 de um Nickel 0.001 0.002 0.002 0.001 0.002 0.003 0.000 0.003 0.000 0.000 0.000 0.000 0:013 Selenium0.001 0.001 0.001 0.001 0.001 0.002 0.000 0.002 0.000 0.000 0.000 0.000 0.008 Zinc 0.254 0.381 0.385 0.262 0.385 0.632 0.055 0.763 0.000 0.0000.000 0.000 3.117 Total Phos- 6.749 10.102 10.225 6.953 10.225 16.769 1.468 20.246 0.000 0.000 0.000 0.000 82.737 phorus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a "stem designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". S`iyiati& of Land App lier Date F. 0 Ci0 z z N OPI U out � N O O O O Cl O O O O O O O 0 0 0 0 0 Cl Cl 0 0 0 0 O o z o 0 0 0 0 0 0 0 0 0 0 0 a V 0 0 0 0 0 0 0 0 0 0 0 0 Qa � 0 0 0 0 0 0 0 0 0 0 0 0 0 O O O N O O O O O O O O O O O O O U al Q b O N 00 U y Q 000000000000 � O oho w as U U � CUd U .o a, 0 � -O L � W CI- W)� A cn O w 4 y � W U Z O N 00 U y Q 000000000000 O O oho w as 0 0 � CUd �+ .o a, 0 -O L � z CI- W)� A cn "d O W CO O O M '—T ON al o °' Qi U -9 0 O a O ~ N w o G 0 IPOI Io t-. td 0 a o a 3 0 aHaa > q � b oUS�z U ts, A w 0 w Z a A � W A �y N 0 U ZE-'a � O a Z � j 0 W o U Q U W � A a o 0 o Z O o OO 0 0 O N 00 U y Q 000000000000 O O oho w a000000000000 0 0 � CUd �+ .o a, 0 -O L 000 CI- W)� °zj cn "d O CO O O M '—T ON al o °' Qi U -9 0 O a O ~ N w o G 0 IPOI Io t-. td 0 0 o > q oUS�z U ts, 0 0 0 �y N Z � j o N a O o OO 0 0 O 0 O 0 O 0 O 0 O 0 O 0o O d z Z Z o 0 0 0 0 0 0 0 0 o z U U O O O O O O O O O O d n, 0 0 0 0 0 C. 0 0 0 C. 01`6 O O O O O O O O O O O O OuO O O O O O O O O O O � m b •� Y z Z E Ammonia Nitrogen E Mineralization Rate*** Volatilization Rate** Application Method* ¢ d N N 'IvIyy � � yv1 rT U P, P, rte, c 0 LIJUOW 0 a 0 0 O O V1 00 a N o `n N 00 U y Q 000000000000 O O oho w a000000000000 0 0 0 �+ .o a, 0 -O L 000 CI- W)� °zj cn "d O CO O O M '—T ON al O\ c -9 0 O a O ~ N w o 0 0 IPOI Io 0 0 0 o > q oUS�z U ts, 0 0 0 LIJUOW 0 a 0 0 O O V1 00 a N o `n N PLO 00 N O O O oho w 0 0 0 �+ .o 00 0 000 CI- W)� °zj O O O M Cj ON O\ O a O ~ N o 0 0 IPOI Io 0 0 PLO 00 W]� M O �+ .o 00 0 000 O ON O\ O a O ~ N o 0 0 0 oUS�z P 0 0 o. O cNn 00 M �R" O O M ON N OO — N P4 C o o M U o 1 H i N A W U w a M�d �ZIZ J N r r r r r r r r O O O O O O O O 0 r r r • r �D �D �O �D lD �D �O �D O O O C13 z z LO z z z z z s. Pi cf�S PW P"� Q� o c y � cc:v� 'C po a � 0 0 r O o p � olZ N 4U-. O .5 Q O 00 00 00 - - 00 00 00 Aonia mm r rn CO w 4 v a.a a. as a. P, Pa P, PN, Nitrogen C G �n M v) M a q w M Mkn Mkn Mkn M MTOO Cpi O h M °ZZZZZZZZ0000 U o N N o z N N N Eo 0 U.. 0 0 o 0 0 0 O 110 U V �D �D M pC, 00 O 0 0 00 00 0o r.. O o0 00 � p N � v ¢, d' M �O d• 110 '4D O O O N O N O O O O 0 O O 0 O O 0 O i - R p d• �p �p .-� M N0 O O C. 0 0 0 0 C> Cj C> v) lerallzation` Rate*** I o 0 0 0 0 0 0 0 Volatilization I,,� I � 1 n I n I n I -n j 1n I kn 0 0 0 0 0 0 0 0 Rate** Application Method* 'a a � cloiololol0{0l0�0 CO O 0 w W CA v a^ N r r r r r r r r O O O O O O O O 0 r r r • r �D �D �O �D lD �D �O �D O O O C13 z z z z z z z z PW P"� Q� o c y � cc:v� 'C po a � 0 0 r O o p � olZ N 00 00 00 00 00 00 00 00 Aonia mm r rn 00 � W r r r n r r r Nitrogen C G �n M v) M m M w M w M Mkn Mkn Mkn M MTOO Cpi O h M U o N N N N N N Eo 0 U.. 0 0 0 0ID W) d O 110 V �D �D lerallzation` Rate*** I o 0 0 0 0 0 0 0 Volatilization I,,� I � 1 n I n I n I -n j 1n I kn 0 0 0 0 0 0 0 0 Rate** Application Method* 'a a � cloiololol0{0l0�0 CO O 0 w W CA v a^ N N N N N N N N -0 Is O O O O O O O O 0 r r r r r r 0 r r 0 0 C) O 0 O 0 O 0 O 0 O O O O C13 z z z z z z z z PW P"� Q� o c y � cc:v� 'C po a � 0 0 r O o r r m o0 o cin opo � � N W00 � U O\ I r N P Q N o0 0o N o0 O -0 Is O O O O O O O O 0 0 0 0 0 0 O 0 O 0 O 0 O 0 1-4 6 0 0 O � O O O M > PW P"� Q� o c y � cc:v� 'C po a � 0 0 r r r m o0 o cin opo � � N W00 =a N M O\ I r r/1 0 � 0 0 0 o0io W � o 0 r OC) O oC� 1-4 � O � O O O M PW o o c y � cc:v� 'C po a � 0 0 r O o p � olZ as CCS 0 .2 0 O 9 IL =a N M N M N M N M N M N M kn N ❑r OC) O 1-4 O O O PW o c y � cc:v� 'C po t- C r O o p � p N O z p. m 79 d• � M� r rn 00 � W ou�oI n �D — \ z oC 0 o oL a Cpi O h M U o � M U.. W) d O O V M pC, 00 o 0 0 00 00 0o r.. O o0 00 � p N � OO O M O O O as CCS 0 .2 0 O 9 IL =a N M N M N M N M N M N M N M N M c y � cc:v� 'C po p o 0 0 o p o r, z p. m M d• � M� r rn c° b � o oL a U o U.. 00 00 00 o0 00 00 0o r.. uo F r, _ p N `r' a as CCS 0 .2 0 O 9 IL ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (503 Rules) Facility Name: Odom Correctional WWTP Name: Odom Wastewater Treatment Facility d• From 1/1/2018 Momtoring Perio . Pathogen Reduction (40 CFR 503.32 Class A: Alternative 1 Alternative 4 If applicable to alternative performed (I I Heat Drving Beta Ray Class B: Gamma Alternative 1 If applicable to alternative Lime Stabilization If applicable to alternative pert Allowable Level Parameter in Sludge Fecal Coliform 2 x 10 to the MPN 6th power per gram of CFU total solids 1000 mpn per gram of total solid (dry Salmonella bacteria ` 3 MPN per 4 grams (in lieu of fecal I total solid (dry WQ Permit Number: NPDES Number: To 12/31/2016 WQ0011413 NCO027642 - Please indicate level achieved and alternativeperformed: Alternativ�5�� Alternative 3 AlternatiAlternative 6 A Tf!iPansteurizffation nl) indicate "Process to Further Reduce Pathogens": Thermophilic Alternative 2 (Class B only) indicate "Process to Significantly Reduce Pathogens Air Drying I Composting Aerobic Digestion ------------ ied (Class A or Class B) complete the following monitoring data: na ca um er o Frequency Sample Pathogen Density Excee- 9 y p Tech - of Analysis Type inimun Geo. Mean i�laximun Units SM9221C 20909 22466 26744 MPN 0 7/OPS G E-2006 colttorml I wc Vect77 ttraction Reduction 40 CFR 503.33} -Please indicate option performed: Alt. 4 (Spec. O uptake) Alt.l Alt. 2 (40 -day bench) Alt. 3 (30 -day bench)Alt. 8 (z Unstable) Alt. ic) Alt. 6 (Alk. Stabilization Alt 7 (Drying -Stable) (Drying - Alt. 9 (Injection) Alt. 10 (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have been "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the re uirements.) th "This determination has been made under my direction and ln accordance the informationlused to determine mine the system designed to ensure that qualified personnel property gatherand evaluate that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." r0r+ f ''' -' her Name and Title (if applicable)(type or print) Preparer ne and Title Ld (type or print) Land App I-V Date ate Signature of Land Applier (if applicable) Si attire of Preparer* g *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) nF_NR FORM PVRF 503(12/2006) Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level 5. 5. 5. 5. 5. 4 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: % Dry Solids degrees Celsius decrees Celsius 0.15 6.0 0.99 8.71 mg Oxygen/hr 0.66 mg Oxygen/hr/g 24 degrees Celsius 0.82 Temperature Corrected Specific Oxygen Uptake Rate: 0.5 mg Oxygen/hr/g Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Updated 10/23/2013 'E O In Lo N M r G: C O L a m O Q co Ce) � O 00 m a Ln o (0 O N CL .N N o _ �Lo O Z 76 zrC CD O _ N r.m N cn Z U O OLO E O O T Y L -,O Q G O Z Q! O O 0 as d U .- cn U m� Cc G N I O R O � O TU M U Cf) Q N N o m a� g N N "S T O U N N � a � G � O � C N N Q � co N 00 N o 0. M W A Z p In In 0 Oo 0C) af0 N CL c p tm T v O LO O LO m.LO� E � z L E zo E T zo °a c oO W ILL O = M OT C U T T C7 ? ? OO Gi O V Z YC14 Z Y `— 41 V O 0 0 col 00 co Z: d T d E r. E __ _ = o a L� E co U C Z C. v C Z d w O Occ O C l�4 C W = '6 IM cuI W °mV OM QE^W E U ECL o 0 aa UL - N � cm C CL �N d� U cT N T to 06 f] kadMY„'•ti�j A Eco d = r t0 d N J U) co w T E v G (� Z M Z Y m O r d CO cr E = N Z a L6 C t6 C1 U N UJ Q T C C a o c � w E CD @ m J U N �L p A '} Q 0 � � O fl. 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H 2 N N o m IA 0ca N N c N U E U •� X Z o 'c E Z N oc m 4c; m a: N E E c o 0 m 4- E c `� co U_ (6 m Z f6 f4 N E o) U 7 O O cc +�+ p E al O f0 C C N CIO O � `o O m 0 T c fp o t rn ~ c .E E rn 0 CL N w co N LIC O 0,0 N O o C4 `r O Z O O deo NO J C O J Z M Z = 0 w7 r T Q {0 U) 0 0 e z CL IA N W m O f0 r z O O _ U 7 O Q N N o C T N m a� c cS N N O U lyp N N U a c � 0 m Q � Z � g o CD Lo M 0 O r U) cD In O o _ o � C4 ~ �p O O O1 E M Z O C U tD O z M Z dro w c 0 co . c E c O S O N z C' 17 0 _ M m c U w o �l Lu Q o E E _c u 0 D cm N � U T N C � 3 W Ld + V N C J 3 IN 7 r�2 e (D Cl S w oo E °' r U) i =N C6 u6 i r 1 i o ss m n i U W � i V i rn 1 o yN o CD O � O �o N C W c �1 0 V t e E u ai E c v o a "� y ti ce : J N L E 3 0 O N_ 4 (D = 0 E Eti c fn .1 h S Lo CL In s i � a O n m CO U o W � i U r I T I 0 0 = o z M O z O o N O 10 T ` U 0 0 c Z a U) W N CL1 0 M Z p _ 7 O U 3 U co CO a M N O N a� c co LD � W INO N N U N y T_ c m Q � z tm � o g C ti �D T O N O ]C V1 n O O o N In a ry to N -8 O 117 V Z O = U o z z Y 0 opo E ! 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O LO "0 M'a 'a •�C = '0 = = lC Vcc 10 __ E 2 W Q N cC v W Q O CM N E W Q N E E c c W Q U fV E c U E c U E U Lr U r N W U r N m U r N o U �' N o C1 m m m m CSO _ = = W j W U o U of ti V w U U L1 U y L6 Cl) N = N FN =r N = y M r N 7 _ N u o N ,.y+ r` o N O r `- r w 7 r Q a0+ 7 N r r — N 7 N N_ d O. 2 LO O' Sr C7 E S Cp o(a d E S o d E= a+ o E S o U) 2w moc V / , d K z 0 z U) U) N W moo z z \ moo 3 CCD �0 o E , k_} N o o a% � N § � 2w moc V / , d K z 0 z U) U) N W moo z z \ moo 3 CCD - Q N o o a% N ƒ L � ) - k a 2 k N(0 ca B IN 04 to - & u «Q « f \ / ILU) U) \ �IMoo a i k Z�o0 \ 2 \ o q q \ f e e 2 U \ cn E 0C, koo CD IL IL 2q 7 CLOD \� 27/ I/ G z\\�7/\� ƒ J z a)- I f u o o o, ~ E $ \ \ m a CD ° 0 o G 2 CL co crE E E a I a m § n \ L z § k 2 2 0 % 2 V co W k g E 6 a\ k/ c aQ§ [OE / E 2 0 0 Q ®o a c') U 2 a o # m § � 0 \ n \ UR q ui � 6 2 , E N o ~ p $ - 2 \ k a l t D ¢ S E E \ s § $ l\ e ~1 LO LO LOM O h N Cb U- cu E T a) Q a) (D U) c d E 7 a1 0 c C m o. 0 Q N W t C c a1 8 _ to c 0 a Q 0 CL N x U) O C r N C E V O O n CL L a7 i6 U. E E O O C- o N �. X X U 0 U '0 "O a) y E X N cQ E '00 U a) a) N C a) 'Q 'Q G N 0 -0 C- U •-� c C a5 C C — a) CO O X p) _ E o 0 0 22 0 O U (� C L C C 'y t U N fa >> co N CO a) D7 x 0 U U a cam) L m U ac a)) .0 o o `� °U axi a a a E E 2 2 E E X N 0 � N �E •� C f6 m _0 C m U C ._ = O — C C U ,0 L C a) d> 0) 7 C N N S m C X a) C V1 C O U a Q N N 3 •IV •- U C N N Z a aO> a R M a '= OR .i A w e i — (1) c c amULuY22zzz0 C.aaUv)'SNN tm N O O O C) — L C) c += o C) 7 -0 li t C _r_lO > O N X 'Em E " N M o a 3 L - T U) a) NC N U � O O = a) 00 E E E o O O (D c c Eo_>Q 'u)E o� Q-2 o a) ca rte- aj X - m ° u0i Q C E C_ (0 a) C° v a) p to C C E L ,—N O o U) c a O U) (L) a) a o � }, Eo C LLL Q U E = a) E a a= a o 0 -t U U) (1) N � " N C) C N .�. OT a) <n� J- o o c O D m > m U pa) N Cl) = N C E C o E c0 J t- o LL N L N 'N a) 0 y Q 0 � -0 Lr) if C a) A r N i v a) a) U Q N (n aa) � oM (n N co CD N O p C - G - a ca c CL D w ° •C U C N O UI U U) N N m N ? 0 0 ° E T cn O a) 7 o E N C N o CrC o = 0 -0 N fA ? C N NZ tn-E Co 0a m a, ca C: N C ca tL: C N O` E m Y a) O o CrN+ .CD 0 E U) C m a) 0 Ea) o a) Z 3. O C NN -0 Q `0 = a m 0 CL_ CX E o 0U Ln V N O O N 3 d N C (Do = 0 C N Lo c w N cm o N o L c) D ° O . m N N w -cf C _N C_ = C Q E c a) a) L N E(D a) O UO U U +� C N T O U�' -� o fa (Ca O N O C O 0 U N = a) O Q o n C N a) � c C N 0r N_ d w W Q) o a) o .E g � a) O `0 ro ° w O c ID ;(b m O Z N (a O c 0. C U U O C_O 70 —Q,c S a ca O C > L U) O w `)` N U o ,� C—) tf o CL 0 CL (D E .0 L O 0 E E N .Q .0 oa) m u; aai � O t ° O E o ° Q O O C 0 O N O O m E a)I (0 O a) cci LL C c C 4=. O Co C C � U E O O 0 .� L- a C N c O t O o A a N r_ a) ca t E d N CD F � O H � C cE O ZLo c Co M Oro a) Z O 0) !� ~ '0 U w ac LU = Z O � CO > (D O C U a) = Q E CL c a) -0 N N Q E o CV co a i C ti - U a) U r 0Q ° 0 C O C o T a) C L cn o o)co cu a U o O 0 O U U a) a) Y a) _ o W CD � r •E cC ca E CO F- ca Analytical Results ACDOC-Odom Correctional Institution 485 Odom Prison Rd. Jackson, NC 27845 Receive Date: 08/21/2018 Reported: 02/20/2019 For: Comments: STATESVILLE ANALYTICAL Unit Method Analyzed Analyst Sample Number Parameter Sample ID Result _ as Note 08/28/2018 PACE 180821-34-01 TCLP See Attached Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 25 d I 0 It 2 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 25 3 CD m 3 m m pN fm0— @ m m L30 N (3D N m 3C. C7' ; ro cr O ro C, ro ro m m ro 3 4. " 3 C < a m m O c 0 0a � � 1 r 3 3 3 Cr o a a !� I1 IIS d I 0 It 2 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 25 3 CD m 3 m m 3 3 ; ( 3 3 ro m m ro O 0 0a d I 0 It 2 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 25 �-. �aceAnalytical / www.pecefebs.com Project: 180821-34-01 RUSH Pace Project No.: 92396778 Pennsylvania Certification IDs 1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601 ANAB DOD-ELAP Rad Accreditation M L2417 Alabama Certification M 41590 Arizona Certification #: AZ0734 Arkansas Certification California Certification #: 04222CA Colorado Certification M PAO1547 Connecticut Certification #: PH -0694 Delaware Certification EPA Region 4 DW Rad Florida/TNI Certification M E87683 Georgia Certification M C040 Guam Certification Hawaii Certification Idaho Certification Illinois Certification Indiana Certification Iowa Certification #: 391 Kansas/TNI Certification #: E-10358 Kentucky Certification M KY90133 KY WW Permit KY0098221 KY WW Permit KY0000221 Louisiana DHH/TNI Certification #: LA180012 Louisiana DEQIrNI Certification #: 4086 Maine Certification #: 2017020 Maryland Certification M 308 Massachusetts Certification #: M-PA1457 Michigan/PADEP Certification M 9991 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 LouisianalNELAP Certification # IA170028 North Carolina Drinking Water Certification M 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #. E87648 Massachusetts Certification M M-NC030 North Carolina Drinking Water Certification M 37712 CERTIFICATIONS Missouri Certification M 235 Montana Certification #: Cert0082 Nebraska Certification M NE -OS -29-14 Nevada Certification M PA014572018-1 New HampshireITNi Certification #: 297617 New Jersey/TNI Certification #: PA051 New Mexico Certification M PA01457 New York/TN l Certification M 10888 North Carolina Certification #: 42706 North Dakota Certification #: R-190 Ohio EPA Rad Approval: #41249 Oregon/TNI Certification M PA200002-010 PennsylvaniafrNl Certification M 65-00282 Puerto Rico Certification M PA01457 Rhode Island Certification M 65-00282 South Dakota Certification Tennessee Certification #: 02867 Texas/TNI Certification M T104704188-17-3 Utah/TNI Certification #: PA014572017-9 USDA Soil Permit#: P330-17-00091 Vermont Dept. of Health: ID# VT -0282 Virgin IslandlPADEP Certification VirginiaNELAP Certification M 9526 Washington Certification M C868 West Virginia DEP Certification M 143 West Virginia DHHR Certification #: 9964C Wisconsin Approve List for Rad Wyoming Certification #: 8TMS-L South Carolina Certification #: 99006001 Florida/NELAP Certification M E87627 Kentucky UST Certification M 84 VirginiaNELAP Certification M 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification M 99030001 VlrginiaNELAP Certification M 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 HuntersAile, NC 28078 (704)875-9092 Page 2 of 22 PO Box 228 • Statesville, NC 28687 e 704/872/4697 Page 5 of 25 .-.raceAnalytical www.pacelabs.com i SAMPLE ANALYTE COUNT Project: 180821.34-01 RUSH Pace Project No.: 92396778 Pace Analytical Services, LLC 9800 KlnceyAve. Suite 100 Huntersville, NC 28078 (7041875-9092 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92398778001 180821.34-01 EPA 8081B NU1 9 PASI-C EPA 6010D DS 7 PASI-A EPA 7470A RDT 1 PASI-A EPA 82700 Bpi 18 PASI-C EPA 8260B GAW 14 PAST -C EPA 1010A MOW 1 PAST -A EPA 9045D MDW 1 PASI-A EPA9014 PAS 1 PASI-PA SM450DS2F-00 PAS 1 PASI-PA 92396778002 180821-34.01 PCB EPA 8082A NU1 8 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 22 PO Box 228 • Statesville, NC 28687 e 704/872/4697 Page 6 of 25 aceAnalytical mmpecelabs.com s ANALYTICAL RESULTS Project: 180821-34-01 RUSH Pace Project No.: 92396778 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Hunlersville, NC 28078 (704)875.9092 Sample: 180821-34-01 Lab ID: 92396778001 Collected: 08121118 09:50 Received: 08122/18 10:55 Matrix: Solid Results reported on a "wet -weight" basis 10-110 1 08/24/18 14:42 08/28/18 12:55 877-09-8 S5 6010 MET ICP, TCLP Parameters Results Units Report Limit OF Prepared Analyzed CAS No. 8081 TCLP Pesticides RVE Analytical Method: EPA 8081 B Preparation Method: EPA 351 OC ND mg1L Leachate Method/Date: EPA 1311; 08/24118 07:59 Initial pH: ; Final pH: 5 gamma -BHC (Lindane) NO ug/L 0.50 1 08/24/18 14;42 08128118 12:55 58-89-9 Chlordane (Technical) NO ug/L 3.0 1 08/24118 14:42 08128/18 12:55 57-74-9 Endrin ND ug1L 0,50 1 0812411814:42 08/2811812:55 72.20-8 Heptachlor NO ug/L 0.50 1 08124/1814:42 08128/1812:55 76-44-8 Heptachlor epoxide NO ug/L 0.50 1 08/24/18 14:42 08/28/18 12:55 1024-57-3 Methoxychlor NO ug/L 1000 1 08124/1814:42 08128/1812:55 72-43-5 Toxaphene NO ug/L 3.0 1 08/24/1814:42 08128/1812:55 8001-35-2 Qual Surrogates Decachlorobiphenyl (S) 10 % 10-138 1 08124/18 14:42 08/28118 12:55 2051-24-3 Tetrachloro-m-xylene (S) 3 % 10-110 1 08/24/18 14:42 08/28/18 12:55 877-09-8 S5 6010 MET ICP, TCLP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Leachate Method/Date: EPA 1311; 08123118 16:30 Initial pH: 7.23; Final pH: 4.5 Arsenic ND mg1L 0.050 1 08124118 21:47 08/26118 16:44 7440-38-2 Barium ND mg/L 0.25 1 08/24/18 21:47 08/26/18 16:44 7440-39-3 Cadmium NO mg/L 0.0050 1 08/24/18 21:47 08/26/18 16:44 7440-43-9 Chromium NO mg/L 0.050 1 08/24/18 21:47 08/26/18 16:44 7440-47-3 Lead NO mg/L 0.025 1 08/24/18 21:47 08/26/18 16:44 7439-92-1 Selenium NO mg/L 0.10 1 08124118 21:47 08/26/18 16:44 778249-2 Silver NO mg/L 0.025 1 08/24/18 21:47 08126/18 16:44 7440-224 7470 Mercury, TCLP Analytical Method: EPA 7470A Preparation Method: EPA 7470A Leachate Method/Date: EPA 1311; 08123118 16:30 Initial pH: 7.23; Final pH: 4.5 Mercury NO mg1L 0.00020 1 08/24118 22:00 08/27/18 10:11 7439-97-6 8270 MSSV TCLP Sep Funnel Analytical Method: EPA 8270D Preparation Method: EPA 351 OC Leachate Method/Date: EPA 1311; 08/24/18 07:59 Initial pH: ; Final pH: 5 1,4 -Dichlorobenzene NO ug/L 50.0 1 08/24/1813:40 08127/1811:35 106-46-7 2,4-Dinitrotoluene NO uglL 50.0 1 08/2411813:40 08/2711811:35 121-14-2 Hexachloro-1,3-butadiene NO uglL 50.0 1 0812411813:40 0812711811:35 87-68-3 Hexachlorobenzene NO ug/L 50.0 1 08/2411813:40 08/2711811:35 118-74-1 Hexachioroethane NO ug/L 50.0 1 08/24/1813:40 0812711811:35 67-72-1 2-Methylphenol(o-Cresol) NO ug1L 50.0 1 08/24/1813:40 08/2711811:35 9548-7 3&4-Methylphenol(m&p Cresol) NO ug/L 50.0 1 08124118 13:40 08127/18 11:35 15831.104 NO ug/L 50.0 1 08/2411813AO 0812711811:35 98-95-3 Nitrobenzene NO ug1L 100 1 0812411813:40 0612711811:35 87-86.5 Pentachlorophenol NO ug1L 50.0 1 0812411813:40 08127/1811:35 110-86-1 Pyridine NO ug/L 50.0 1 08124/1813:40 0812711811:35 95.95-4 2,4,5 -Trichlorophenol NO uglL 50.0 1 08124/1813:40 0812711811:35 88-06-2 2,4,6 -Trichlorophenol Surrogates 24 % 12-102 1 08124118 13:40 08/27/18 11:35 4165-60-0 Nitrobenzene -d5 (S) % 13-107 1 08/24118 13:40 08/27118 11:35 321-60-8 2-Fluorobiphenyl (S) 21 34 % 21-132 1 08124118 13:40 08/27118 11:35 1718-51-0 Terphenyl-d14 (S) 6 % 10-110 1 08/24/18 13:40 08/27/18 11:35 13127-88-3 SO Phenol -d6 (S) % 10-110 1 08/24/18 13:40 08127118 11:35 367-12-4 2-Fluorophenol(S) 10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 0911812018 10:20 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 22 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 7 of 25 � ' ceAnalytical www.pecelabs.com 1 i Project: 180821-34-01 RUSH Pace Project No.: 92396778 Pace Analytical Services, LLC 9800 Klncey Ave. Suite 100 Huntersvllle, NC 28078 (704)875.9092 ANALYTICAL RESULTS sample: 180821-34.01 Lab ID: 92396778001 Collected: 08/21118 09:50 Received: 08122118 1055 Matrix: Solid Results reported on a "wet -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8270 MSSV TCLP Sep Funnel Analytical Method: EPA 8270D Preparation Method: EPA 351 OC Leachate MethodiDate: EPA 1311; 08124/18 07:59 Initial pH: ; Final pH: 5 Surrogates 2,4,6-Tribromaphenol(S) 8260 MSV TCLP Benzene 2-Bulanone (MEK) Carbon tetrachloride Chiorobenzene Chloroform 1,4 -Dichlorobenzene 1,2-Dichloroethane 11-Dichloroethene Tetrachloroethene Trichloroethens Vinyl chloride Surrogates 1,2-Dichioroethane-d4 (S) Toluene -d8 (S) 4-Bromofluorobenzene (S) 1010 Flashpolnt,Closed Cup Flashpoint 9045 pH Soil pH at 25 Degrees C 733C S Reactive Cyanide Cyanide, Reactive 7345 Reactive Sulfide Sulfide, Reactive Sample: 180821-34-01 PCB 45 % 27-108 1 08/2411813:40 08127/1811:35 118.79-6 Analytical Method: EPA 82606 Leachate Method/Date: EPA 1311; 08/23/18 15:52 NO ug/L 100 20 08/27/1810:25 71-43-2 NO ug1L 200 20 08/27/1810:25 78-93-3 NO ug/L 100 20 08127/1810:25 56-23-5 NO ug/L 100 20 08/2711810:25 108-90-7 NO ug/L 100 20 08127/1810:25 67-66-3 ND ug/L 100 20 08127/1810:25 106-46-7 NO uglL 100 20 08/27118 10:25 107-06-2 NO ug/L 100 20 08127/1810:25 75-35.4 NO ug/L 100 20 0812711810:25 127-18.4 NO ug1L 100 20 08/2711810:25 79-01-6 NO ug/L 100 20 08127/1810:25 75-014 97 % 70-130 20 08127/1810:25 17060-07.0 105 % 67-135 20 08127/18 10:25 2037-26.5 100 % 70-130 20 0812711810:25 460-00-4 Analytical Method: EPA 1010A > 200.0 deg F 70.0 1 08/23/18 20:17 Analytical Method: EPA 9045D 6.9 Std, Units 0.10 1 08/25118 00:32 Analytical Method: EPA 9014 Preparation Method: SW -846 7.3.3.2 NO mg/kg 0.99 1 08/23118 22:16 08124/18 00:03 Analytical Method: SM4500S2F-00 Preparation Method: SW -846 7.3.4.2 NO mglkg 9.9 1 0812311822:16 08/23/1822:19 Lab ID: 92396778002 Collected: 08121/1809:50 Received: 08122/1810:55 Matrix: Non Aqueous Liquid Results reported on a 'dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 8082 GCS PCB Analytical Method: EPA 8082A Preparation Method: EPA 3580 PCB -1016 (Aroclor 10 16) NO mg/kg 1.0 1 08/27/1806:51 08127118.18:35 12674-11-2 PCB -1221 (Aroclor 1221) NO mg/kg 1.0 1 08127/18 06:51 08/27/18 18:35 11104-28-2 PCB -1232 (Aroclor 1232) NO mg/kg 1.0 1 08127/18 06:51 08127118 18:35 11141-16-5 PCB -1242 (Aroclor 1242) NO mg/kg 1.0 1 08/27118 06:51 08/27118 18:35 53469-21-9 PCB -1248 (Aroclor 1246) NO mg/kg 1.0 1 08/27/18 06:51 08/27/18 18:35 12672-29-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 09/18/2018 10:20 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 22 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 8 of 25 ;aceAnal.1/tical o �� www.pecolobs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersvilie, NC 28078 (704)876-9092 Project: 180821-34-01 RUSH Pace Project No.: 92396778 Sample: 180821-34.01 PCB Lab ID: 92396778002 Collected: 08/21118 09:50 Received: 08122118 10:55 Matrix: Liiqu Lon iquid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8082 GCS PCB Analytical Method: EPA 8082A Preparation Method: EPA 3580 PCB -1254 (Aroclor 1254) ND mg/kg 1.0 1 08/27/18 06:51 08/27/18 18:35 11097-69-1 PCB -1260 (Aroclor 1260) ND mg/kg 1.0 1 08/2711806:51 08/27/18 18:35 11096-82-5 Surrogates Decachlorobiphenyl (S) 57 % 49-130 1 0812711806:51 08127118`18:35 2051-24-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 0911 8/201 8 10:20 AM without the written consent of Pace Analytical services, LLC. Page 6 of 22 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 9 of 25 aceAnalJ�/"�ical r_/ 07 waw.pecelabe.com Project: 180821-34-01 RUSH Pace Project No.: 92396778 OC Batch: 427086 QC Batch Method: EPA 7470A Associated Lab Samples: 92396778001 METHOD BLANK: 2357848 Associated Lab Samples: 92396778001 Parameter Units Mercury mg1L LABORATORY CONTROL SAMPLE: 2359921 Parameter Units Mercury mg/L Pace Analytical Services, LLC 9800 KlnceyAve. Suite 100 Huntersvllle, NC 28078 (704)875.9092 QUALITY CONTROL DATA Analysis Method: EPA 7470A Analysis Description: 7470 Mercury TCLP Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.00020 0812711810:06 Spike LCS LCS % Rae Cone. Result % Rae Limits Qualifiers ,0025 0.0024 94 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2359922 2359923 MS MSD 92396778001 Spike Spike MS MSD MS MSD % Rae Parameter Units Result Cone. Cone. Result Result % Rae % Rae Limits RPD Qual Mercury mg/L ND .0025 .0025 0.0022 0.0023 86 91 75-125 5 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 0911812018 10:20 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 22 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 10 of 25 aceAnalytical www.pacelabs.com i i QUALITY CONTROL DATA Project: 180821-34-01 RUSH Pace Project No.: 92396778 QC Batch: 427085 2359918 Units Analysis Method: EPA 601 OD QC Batch Method: EPA 3010A % Rec Limits Qualifiers Analysis Description: 6010 MET TCLP Associated Lab Samples: 92396778001 97 80-120 Barium mg/L METHOD BLANK: 2357848 2.4 Matrix: Water 80-120 Cadmium Associated Lab Samples: 92396778001 2.5 2.4 96 80-120 Chromium mg/L Blank Reporting 2.4 Parameter Units Result Limit Analyzed Qualifiers Arsenic mg/L NO 0.050 08/26/1816:37 Barium mg/L ND 0.25 08126/1816:37 Cadmium mg/L NO 0.0050 08/26/1816:37 Chromium mg/L NO 0.050 08126/1816:37 Lead mg/L NO 0.025 08/26/1816:37 Selenium mg/L NO 0.10 08/2611816:37 Silver mg/L NO 0.025 08/26/1816:37 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 2359918 Units Spike Conc. LCS Result LCS e% Rec % Rec Limits Qualifiers Arsenic mg/L 2.5 2.4 97 80-120 Barium mg/L 2.5 2.4 96 80-120 Cadmium mg/L 2.5 2.4 96 80-120 Chromium mg/L 2.5 2.4 98 80.120 Lead mg/L 2.5 2.3 91 80-120 Selenium mg/L 2.5 2.4 97 80-120 Silver mg/L 1.2 1.2 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2359919 2359920 MS MSD 92396778001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Conc. Result Result e% Rec e% Rec Limits RPD Qual Arsenic mg1L NO 2.5 2.5 2.4 2.4 96 96 75-125 0 Barium mg/L NO 2.5 2.5 2.5 2.5 99 99 75-125 0 Cadmium mg/L NO 2.5 2.5 2.4 2.4 96 97 75-125 1 Chromium mg/L NO 2.5 2.5 2.4 2.5 97 98 75-125 1 Lead mg/L ND 2.5 2.5 2.3 2.3 90 91 75-125 1 Selenium mg/L ND 2.5 2.5 2.4 2.4 96 97 75-125 1 Silver mg/L NO 1.2 1.2 1.2 1.2 99 100 75-125 0 Results presented on this page are In the units indicated by the "Units" column except where an allernete unit Is presented to the right of the faeall. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/18/2018 10:20 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 22 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 11 of 25 �r aceAnalytical' www.pacelaba.com Project: 180821.34-01 RUSH Pace Project No.: 92396778 QC Batch: 427249 Analyzed Qualifiers QC Batch Method: EPA 82608 5.0 Associated Lab Samples: 92396778001 ND METHOD BLANK: 2358126 08/27/18 09:51 Associated Lab Samples: 92396778001 5.0 Parameter Units 1,1-Dichloroethene ug/L 1,2-Dichloroethane ug/L 1,4 -Dichlorobenzene ug/L 2-Butanone (MEK) ug/L Benzene ug/L Carbon tetrachloride ug/L Chlorobenzene ug/L Chloroform ug/L Tetrachloroethene uglL Trichloroethene ug/L Vinyl chloride ug/L 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene -d8 (S) % QUALITY CONTROL DATA Analysis Method: EPA 82608 Analysis Description: 8260 MSV TCLP Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 5.0 08/27/18 09:51 ND 5.0 08/27/18 09:51 ND 5.0 08/27/18 09:51 ND 10.0 08/27/18 09:51 ND 5,0 08/27/18 09:51 ND 5.0 08127/18 09:51 ND 5.0 08/27/18 09:51 ND 5.0 08/27118 09:51 ND 5.0 08/27118 09:51 ND 5.0 08/27/18 09:51 ND 5.0 08/27/18 09:51 98 70-130 08/27/18 09:51 103 70-130 08127/18 09:51 103 67-135 08/27/18 09:51 Pace Analytical Services, LLC 9800 KlnceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2360405 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1-Dichloroethene T ug/L 50 50.5 101 66.135 1,2-Dichloroethane ug/L 50 44.8 90 67-128 1,4 -Dichlorobenzene ug/L 50 47.0 94 78-130 2-Butanone (MEK) ug/L 100 97.5 97 61.144 Benzene ug/L 50 50.6 101 80.125 Carbon tetrachloride ug/L 50 49.7 99 69-131 Chlorobenzene ug/L 50 46.5 93 81.122 Chloroform ug/L 50 47.6 95 73-127 Tetrachloroethene ug/L 50 45.4 91 78-122 Trichloroethene ug/L 50 53.2 106 78-122 Vinyl chloride ug/L 50 50.8 102 58-137 1,2"Dichloroethane-d4 (S) % 95 70-130 4-Bromofluorobenzene (S) % 96 70.130 Toluene -de (S) % 94 67-135 MATRIX SPIKE S MATRIX SPIKE DUPLICATE: 2360406 ~T 2360407 MS MSD 92396693001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD 1,1-Dichloroethene ug/L ND 20 20 21.5 22.2 107 111 70-150 3 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/181201 B 10:20 AM without the written consent of Pace Analytical Services, I.I.C. Page 9 of 22 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 12 of 25 W y ~� Pace Analytical Services, LLC b ® 9800 Klncey Ave. Suite 100 aceAnalxical Hunlersville, NC 28078 www.pacele6s.crom (704)875-9092 I QUALITY CONTROL DATA Project: 180821-34-01 RUSH Pace Project No.: 92396778 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2360406 2360407 MS MSD 92396693001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Roo % Rao Limits RPD Qual 1,2-Dichloroethane ug/L ND 20 20 18.2 19.2 91 96 70-150 6 1,4 -Dichlorobenzene ug/L ND 20 20 18.0 19.5 90 97 70-150 8 2-Butanone (MEK) ug/L 13.4 40 40 53.3 52.4 100 97 70-150 2 Benzene ug/L ND 20 20 20.5 21.4 103 107 70-150 4 Carbon tetrachloride ug1L ND 20 20 18.2 19.2 91 96 70-150 5 Chlorobenzene ug/L ND 20 20 17.7 19.4 88 97 70-150 9 Chloroform ug/L ND 20 20 19.3 19.8 97 99 70-150 3 Tetrachloroethene ug/L ND 20 20 18.3 19.6 91 98 70-150 7 Trichloroethene uglL ND 20 20 20.1 22.6 101 113 70-150 12 Vinyl chloride ug/L ND 20 20 20.4 21.2 102 106 70-150 4 1,2-Dichioroethane-d4 (S) e/ 101 89 70-130 4-Bromoiluorobenzene (S) % 97 96 70-130 Toluene -d8 (S) % 96 97 67-135 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 0911812018 10:20 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 22 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 13 of 25 1..`,,AJceAna1Xica1 / sww.pscelabscom r QUALITY CONTROL DATA Project: 180821-34-01 RUSH Pace Project No.: 92396778 QC Batch: 426981 2359353 Analysis Method: EPA 8081B OC Batch Method: EPA 3510C Analysis Description: 8081 TCLP Pesticides RV Associated Lab Samples: 92396778001 Spike LCS LCSD LCS METHOD BLANK: 2358854 % Rec Matrix: Water Units Conc. Associated Lab Samples: 92396778001 Result % Rec % Rec Limits Endrin ug/L Blank Reporting 0,89 Parameter Units Result Limit Analyzed Qualifiers Chlordane (Technical) ug/L ND 3.0 08/28118 12:17 Endrin ug/L ND 0.50 08/28/1812:17 gamma -BHC (lindane) ug/L ND 0.50 08/28/18 12:17 Heptachlor ug/L ND 0.50 0812811812:17 Heptachlor epoxide ug/L ND 0.50 08/28/1812:17 Methoxychlor Ug/L ND 1000 08128/1812:17 Toxaphene ug/L ND 3.0 08128/1812:17 Decachlorobiphenyl (S) % 63 10-138 08/28118 12:17 Tetrachloro-m-xylene (S) % 39 10-110 08/2611B 12:17 LABORATORY CONTROL SAMPLE & LCSD: 2359353 2359354 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result % Rec % Rec Limits Endrin ug/L 1.2 0,89 0.80 72 64 20.134 gamma -BHC (Lindane) ug/L 1.2 0.52 0.73 42 59 20-118 Heptachlor ug/L 1.2 0.52 0.69 41 55 20-142 Heptachlor epoxide ug/L 1.2 0.74 0.75 59 60 22-133 Methoxychlor ug/L 3.8 ND ND 100 85 44-150 Decachlorobiphenyl (S) % 76 65 10-138 Tetrachloro-m-xylene (S) % 24 46 10-110 Pace Analytical Services, LLC 9800 Klncey Ave, Sults 100 Huntersville, NC 28078 (704)876-9092 Max RPD RPD Qualifiers 11 30 33 30 R1 28 30 2 30 30 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/18/2018 10:20 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 22 PO Box 228 a Statesville, NC 28687 a 704/872/4697 Page 14 of 25 reAnalytical / www.pacelabs.com f Project: 180821.34-01 RUSH Pace Project No.: 92396778 QC Batch: 427214 QC Batch Method: EPA 3580 Associated Lab Samples: 92396778002 METHOD BLANK: 2360305 Associated Lab Samples: 92396778002 Parameter PCB -1016 (Aroclor 1016) PCB -1221 (Aroclor 1221) PCB -1232 (Aroclor 1232) PCB -1242 (Aroclor 1242) PCB -1248 (Aroclor 1248) PCB -1254 (Aroclor 1254) PCB -1260 (Aroclor 1260) Decachlorobiphenyl (S) Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA LABORATORY CONTROL SAMPLE & LCSD: 2360306 2360307 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result gra Rec % Rec Limits RPD RPD Qualifiers PCB -1016 (Aroclor 1016) mg/kg 10 8.2 8.9 82 89 50-148 8 30 PCB -1260 (Aroclor 1260) mg/kg 10 9.6 10.1 96 101 53-149 5 30 Decachlorobiphenyl (S) a/ 73 79 49-130 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Page 12 of 22 Date: 09/18/2018 10:20 AM without the written consent of Pace Analytical Services, LLC. PO Box 228 • Statesville, NC 28687 a 704/872/4697 Page 15 of 25 Analysis Method: EPA 8082A Analysis Description: 8082 GCS PCB Oil Matrix: Non Aqueous Liquid Blank Reporting Units Result Limit Analyzed Qualifiers mg/kg ND 1.0 08127/18 22:15 mg/kg ND 1.0 08/27/18 22:15 mglkg ND 1.0 08/27/18 22:15 mg/kg ND 1.0 08/27/18 22:15 mg/kg ND 1.0 08127/1822:15 mg/kg ND 1.0 08/27118 22:15 mg/kg ND 1.0 08/27/18 22:15 rya 81 49-130 08127/18 22:15 LABORATORY CONTROL SAMPLE & LCSD: 2360306 2360307 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result gra Rec % Rec Limits RPD RPD Qualifiers PCB -1016 (Aroclor 1016) mg/kg 10 8.2 8.9 82 89 50-148 8 30 PCB -1260 (Aroclor 1260) mg/kg 10 9.6 10.1 96 101 53-149 5 30 Decachlorobiphenyl (S) a/ 73 79 49-130 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Page 12 of 22 Date: 09/18/2018 10:20 AM without the written consent of Pace Analytical Services, LLC. PO Box 228 • Statesville, NC 28687 a 704/872/4697 Page 15 of 25 caAnalytical I` www.paoelah%com 1 Project: 180821-34-01 RUSH Pace Project No.: 92396778 QC Batch: 426983 QC Batch Method: EPA 3510C Associated Lab Samples: 92396778001 METHOD BLANK: 2358854 Associated Lab Samples: 92396778001 QUALITY CONTROL DATA Analysis Method: EPA 8270D Analysis Description: 8270D TCLP MSSV IwgUTA. —1-1 Qualifiers Pace Analytical Services, LLC 9800 KlnceyAve, Suite 100 Hunleraville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE & LCSD: 2359356 Blank Reporting Parameter Units Result Limit Analyzed 1,4 -Dichlorobenzene ug/L ND 50.0 08/2711811:06 2,4,5 -Trichlorophenol ug/L ND 50.0 08/2711811:06 2,4,6 -Trichlorophenol ug/L ND 50.0 08/2711811:06 2,4-Dinitrotoluene ug/L ND 50.0 08/2711811:06 2-Methylphenol(o-Cresol) ug/L ND 50.0 08/27/1811:06 3&4-Methylphenol(m&p Cresol) ug/L NO 50.0 08/27/18 11:06 Hexachloro-1,3-butadiene ug/L ND 50.0 08/27/1811:06 Hexachlorobenzene ug/L NO 50.0 08/27/1811:06 Hexachioroethane ug/L NO 50.0 0812711811:06 Nitrobenzene ug/L ND 50.0 0812711811:06 Pentachlorophenol ug/L ND 100 08/2711811:06 Pyridine ug/L NO 50.0 08/2711811:06 2,4,6-Tribromophenol (S) % 84 27-108 08/27118 11:06 2-Fluorobiphenyl(S) % 56 13-107 08/27118 11:06 2-Fluorophenol (S) % 27 10-110 08/27118 11:06 Nitrobenzene -d5 (S) % 59 12-102 08/27/18 11:06 Phenol -d6 (S) % 17 10-110 08/27/18 11:06 Terphenyl-dl4 (S) % 89 21-132 08/27/18 11:06 Qualifiers Pace Analytical Services, LLC 9800 KlnceyAve, Suite 100 Hunleraville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE & LCSD: 2359356 2359357 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 1,4-Dlchlorobenzene ug/L 600 302 320 60 64 10-110 6 30 2,4,5 -Trichlorophenol ug/L 500 378 389 76 78 39.108 3 30 2,4,6 -Trichlorophenol ug/L 500 390 396 78 79 40-104 2 30 2,4-Dinitrotoluene ug1L 500 427 435 85 87 42.109 2 30 2-Methylphenol(o-Cresol) ug1L 500 300 316 60 63 31-110 5 30 3&4-Methylphenol(m&p Cresol) ug/L 500 252 261 50 52 30-110 4 30 Hexachloro-1,3-butadiene ug/L 500 282 320 56 64 10-110 12 30 Hexachlorobenzene ug/L 500 383 403 77 81 39-121 5 30 Hexachloroethane ug1L 500 308 324 62 65 10-110 5 30 Nitrobenzene ug/L 500 375 397 75 79 32-101 6 30 Pentachlorophenol ug/L 1000 737 800 74 80 18-108 8 30 Pyridine ug/L 500 196 167 39 33 10-110 16 30 2,4,6-Tribromophenol(S) % B6 87 27-108 2-Fluorobiphenyl (S) % 75 74 13-107 2-Fluorophenol (S) % 37 37 10-110 Nitrobenzene-d5(S) % 80 81 12-102 Phenol-d6(S) % 25 27 10-110 Terphenyl-dl4(S) % 91 89 21-132 Results prevented on this page are In the unite Indicated by the "Units" column except where an alternate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shalt not be reproduced, except in full, Date: 09/1812018 10:20 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 22 PO Box 228 a Statesville, NC 28687 • 704/872/4697 Page 16 of 25 aceAnalytical www.pacelabs.com Project: 180821-34-01 RUSH Pace Project No.: 92396778 QC Batch: 426784 QC Batch Method: EPA 1010A Associated Lab Samples: 92396778001 SAMPLE DUPLICATE: 2358596 Parameter Flashpoint QUALITY CONTROL DATA Analysis Method: EPA 1010A Analysis Description: 1010 Flash Point, Closed Cup 92396307001 Dup Units Result Result RPD Qualifiers deg F > 200.0 > 200.0 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09118/2018 10:20 AM without the written consent of Pace Analytical Services, U.C. Page 14 of 22 PO Box 228 • Statesville, NC 28687 e 704/872/4697 Page 17 of 25 aceAnalylicale f -- www.pacelaba.com Project: 180821-34-01 RUSH Pace Project No.: 92396778 QC Batch: 427065 QC Batch Method: EPA 9045D Associated Lab Samples: 92396778001 SAMPLE DUPLICATE: 2359871 Parameter pH at 25 Degrees C SAMPLE DUPLICATE: 2359872 Parameter pH at 25 Degrees C Units Std. Units Units Sid. Units QUALITY CONTROL DATA Analysis Method: EPA 9045D Analysis Description: 9045 pH 92396330001 Cup Result Result 12.7 12.7 92396656004 Dup Result Result 5.3 5.1 RPD Qualifiers 0 E,H6 RPD Qualifiers 4 D6 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersvtlle, NC 28078 (704)87$-9092 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to tha right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 09/18/201810:20 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 22 PO Box 228 o Statesville, NC 28687 • 704/872/4697 Page 18 of 25 !�aceAnalXical whw.pacelahs.com Project: 180821-34-01 RUSH Pace Project No.: 92396778 QC Batch: 310744 QC Batch Method: SW -846 7.3.3.2 Associated Lab Samples: 92396778001 METHOD BLANK: 1517930 Associated Lab Samples: 92396778001 Parameter Cyanide, Reactive QUALITY CONTROL DATA Analysis Method: EPA 9014 Analysis Description: 733C Reactive Cyanide Matrix: Solid Blank Reporting Units Result Limit Analyzed Qualifiers mg/kg NO 1.0 08123/18 23:42 LABORATORY CONTROL SAMPLE: 1517931 Parameter Units Cyanide, Reactive mg/kg SAMPLE DUPLICATE: 1517932 Parameter Cyanide, Reactive Pace Analytical Services, LLC 9800 Klncey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 99.6 NO 0 — 0-8 40174340001 Units Result mg/kg X0.40 Dup Result RPD Qualifiers ND Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full. Dale: 0911B/2018 10:20 AM without the written consent of Pace Analytical Services, L.I.C. Page 16 of 22 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 19 of 25 P7ceAna1j/`j'ica1 www.peealsCs.com Project: 180821.34.01 RUSH Pace Project No.: 92396778 QC Batch: 310743 QC Batch Method: SW -846 7.3.4.2 Associated Lab Samples: 92396778001 QUALITY CONTROL DATA Analysis Method: SM4500S2F-00 Analysis Description: 734S Reactive Sulfide METHOD BLANK: 1517927 Matrix: Solid Associated Lab Samples: 92396778001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide, Reactive mg/kg ND 10 08123/18 22:19 LABORATORY CONTROL SAMPLE: Parameter 1517928 Units Sulfide, Reactive mg/kg SAMPLE DUPLICATE: 1517929 Parameter Units Sulfide, Reactive mg/kg Pace Analytical Services, LLC 9800KInceyAve. Suite 100 Huntersville, NC 28078 (704)876.9092 Spike LCS LCS % Rae Cone. Result % Rae Limits Qualifiers 199 43.8 22 0-52 — — 40174340001 Dup Result Result RPD Qualifiers X10 ND Results presented on this page are in the units Indicated by the "Unita" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 09/18/2018 10:20 AM without the written consent of Pace Analytical Services, I.I.C. Page 17 of 22 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 20 of 25 iaceAnalytical WW'Pacalabs.com i QUALIFIERS Project: 180821-34-01 RUSH Pace Project No.: 92396778 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot Pace Analytical Services, LLC 9800 Klncey Ave. Suite 100 Hunlereville, NC 28078 (704)875-9092 ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroelhylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte PASI-PA Pace Analytical Services - Greensburg ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits, E Analyte concentration exceeded the calibration range. The reported result is estimated. H6 Analysis initiated outside of the 15 minute EPA required holding time. R1 RPD value was outside control limits. so Surrogate recovery outside laboratory control limits. S5 Surrogate recovery outside control limits due to matrix interferences (not confirmed by re -analysis). Date: 0911812018 10:20 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 22 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 21 of 25 aceAnalXical www,Pscelaae can QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 9800 KlnceyAve. Suite 100 Huntersvllle, NC 28078 (704)875-9092 Project: Pace Project No.: Lab ID 180821-34-01 RUSH 92396778 Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92396778001 180821.34-01 EPA 3510C 426981 EPA 8081B 427433 92396778002 180821-34-01 PCB EPA 3580 427214 EPA 8082A 427326 92396778001 180821-34.01 EPA 3010A 427085 EPA 6010D 427090 92396778001 180821-34-01 EPA 7470A 427086 EPA 7470A 427183 92396778001 180821.34.01 EPA 3510C 426983 EPA 8270D 427261 92396778001 180821-34-01 EPA 8260B 427249 92396778001 180821.34-01 EPA 1010A 426784 92396778001 180821.34-01 EPA 9045D 427065 92396778001 180821-34.01 SW -8467.3.3.2 310744 EPA9014 310768 92396778001 180821-34-01 SW -846 7.3.4.2 310743 SM4500S2F-00 310767 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 09118/2018 10:20 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 22 PO Box 228 a Statesville, NC 28687 v 704/872/4697 Page 22 of 25 Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Client Name: t— Courier: []Fed Ex ❑UPS ❑USPS ❑ Commercial mp ce []Other:— Custody Seal Present? []Yes [INS' Seals Intact? ❑Yes HuntersvilliaA Raleigh❑ M ❑ echanicsville Project N: r Wo# ' 92396778 []Client IIIIIF II I I III 111 III III 92396778 []No Date/initials Person Examining Contents:'— Packing Material: ❑Bubble Wrap [-]Bubble Bags (Qtaone ❑ Other Biological Tissue Frozen? Thermometer ❑Yes []NO [9h/A IR Gun 10: 92TO44 Type of Ice: ti❑wet ❑Blue ❑None Cooler Temp ('C): Correction Factor: Add/Subtract (°C) -0,1 r Temp should be above Freezing to 6'C Cooler Temp Corrected ('C):❑samples out of temp criteria. Samples on ice, cooling process has begun USDA Regulated Soil (JOIN/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, 1—I— rlr.,_ Inr1„dhe Hawa6 and Puerto Rirol? MYes nNo Document Name: Document Revised: February 7, 2018 Sample Condition Upon Recelpt(SCUR) Page 1 of 2 Document No.: issuing Authority: 8conalytical" 1. F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Client Name: t— Courier: []Fed Ex ❑UPS ❑USPS ❑ Commercial mp ce []Other:— Custody Seal Present? []Yes [INS' Seals Intact? ❑Yes HuntersvilliaA Raleigh❑ M ❑ echanicsville Project N: r Wo# ' 92396778 []Client IIIIIF II I I III 111 III III 92396778 []No Date/initials Person Examining Contents:'— Packing Material: ❑Bubble Wrap [-]Bubble Bags (Qtaone ❑ Other Biological Tissue Frozen? Thermometer ❑Yes []NO [9h/A IR Gun 10: 92TO44 Type of Ice: ti❑wet ❑Blue ❑None Cooler Temp ('C): Correction Factor: Add/Subtract (°C) -0,1 r Temp should be above Freezing to 6'C Cooler Temp Corrected ('C):❑samples out of temp criteria. Samples on ice, cooling process has begun USDA Regulated Soil (JOIN/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, 1—I— rlr.,_ Inr1„dhe Hawa6 and Puerto Rirol? MYes nNo COMMENTS/SAMPLE DISCREPANCY Field Data Required? []Yes []No Lot t0 of s lit containers: CLIENT NOTIFICATION/RESOLUTION �i 1�..u 1 ' I l Person contacted: 6LDate/Time: Project Manager SCURF Review: I tJ Date: Project Manager SRF Review: Date: Page 20 of 22 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 23 of 25 Comm encs/Diserep a ncy: Chain of Custody Present? qdYes ❑No ❑NJA 1. Samples Arrived within Hold Time? OYes No NJA 2. Short Hold Time Analysis (<72 hr.)? ❑V s 4o ❑NJA 3. Rush Turn Around Time Requested? Yes Q No ❑N/A 4. Sufficient Volume? ',C-J,Yles ❑No ❑NJA S. Correct Containers Used? -Pace Containers Used? ta res M//es ❑No ❑Ne ❑NIA ❑NIA 6. Containers Intact? t Yes []NO ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes []NO -8N/A 8. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: _]Yes []NO ❑N/A 9. Heads ace in VOA Vials (>5-6mml? _[]Yes ❑No'A 10. Trip Blank Present? Trio Blank Custody Seals Present? []Yes [-]Yes ❑No ❑No .D[ IA •dNJA 11, COMMENTS/SAMPLE DISCREPANCY Field Data Required? []Yes []No Lot t0 of s lit containers: CLIENT NOTIFICATION/RESOLUTION �i 1�..u 1 ' I l Person contacted: 6LDate/Time: Project Manager SCURF Review: I tJ Date: Project Manager SRF Review: Date: Page 20 of 22 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 23 of 25 20Ali IAMI- Document Name: Sample Condition Upon Recelpt(SCURI Document Revised: February 7, 2018 Pa e 1 of 2 Document No.: P-CAR-CS-033•Rev,06 Issuing Authority: Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, 011 and Grease, DR0/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle Project #` WOW -1239677& 23961 7 . FM:. AMS Clue Dote: 08/27/18 CLIENT. 924tatesvi X pH Adjustment Log for Preserved Samples o > g4tR J E 0. > J E o ? J E a Z c a a V = i J J E E M a J E a b J E i ?3 t7 a 4 M ca E a Y l7 a d J OE t9 $ 'ri S 1�.7 2 J E ti £ a E o i. a b E O ¢ J E > a Z p a 9 E 7 y?L a J E O a Yf Y 0. Yf i y u J E ya�j y y J E Ap N P T z Jg ^F m c E p Q c c z a J O 4 6 i \ \\ z 3 A 5 6 7 8 1 9 10 11 a — 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot a Note: whenever there Is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le, Out of hold, incorrect preservative, out of temp, incorrect containers. Page 21 of 22 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 24 of 25 -age 22 of 22 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 25 of 25 N A ITEM N m $ n 'e 3 m r $ H n zEn L•. "• 6 O /� V '� N 3 n D n j.a to nO D s A ti C_ M � T . i m 1 I 3L zq•: I 1 r4�3C VNx � P n EI � n a " = z 3 O v m _ MATRIXCODE mewlm0.01tole111 m 3 z TYPE (G=GRAa C=GCI:P) g CSAMPLE d � 1 9 v ^ 10 t>o 3 n O v m O — Cn py D S m m n D z r• V m 9 9 SAMPLE TEMP AT COLLECTION z m # OF CONTAINERS EYa� C On < Unpreserved o _ H2SO4 z 3 5 HNO3 n HCl a ` _ NaOH Na2S203 ti v Methanol m Other 0 jAnalysis Test t YiNj i Fe Fe S o A v n A 0 e z i c y3 a m Q rte'. a C) D m Q t m a O C: z 9 < Tempm •C W I L o D IiA15E[I1131 ChICf nu (YIN) p Racelvetl Ice on (WN) W O O 4 CU81OCy .ater Scaled 0 O yl r�sl Z (YON) 1 m � rt -i Sempfea Inlect S :A7 -age 22 of 22 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 25 of 25 a rn aR 0 al 9 9 e Li age 22 of 22 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 26 of 25 N A ITEM N a O V! V �. 3 a = Iti n N -U .. H .L'I \ •' > y m ' M \ rC fi ° � c z v m m ` y�aFf •:Fix nn 1 S n n 9 3 (1` MATRIXCODE (son rea ccaes to len) a SAMPLE TYPE (G=GFIAS C=CGll,P) -m m p� o n ;; 21 -� 10 3 m '0 z z Z o m1 0 m o 4 0 _ 9 p Fn N SAMPLE TEMP AT COLLECT+ON A OF CONTAINERS m e o T $ a W; E <j Unpreserved ul ",SO, z 3 HNO3 � o HCI NaOH m r ° Na2S203 H m _ Melhanol m Other s lAnalysis Testa YINj — > om Z N to rD _ N �(1 r3y z C 1 (CA .0 CL D O s m 0� In z C` —1 � z 0 n j Temp in 'C W r Residual Chlorine (YIN) Pecalvetl an A Ica (YIN, _ \ y } I m n O O Cualotly Sealed ° ,$, = A a 0 r n [Ti Samples Iniac: (YIN) cr 1'r O a rn aR 0 al 9 9 e Li age 22 of 22 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 26 of 25 SVILLE Analytical Results ANALYTICAL NCDOC-Odom Correctional Institution 485 Odom Prison Rd. Jackson, NC 27845 Receive Date: 06/19/2018 Reported: 02/20/2019 For: Vector Tank Comments: Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 180619-23-01 Aluminum Sludge 6712.12 mg/kg SM 3111 D-2011 06/21/2018 MD 180619-23-01 Ammonia Nitrogen Sludge 1357.58 mg/kg SM4500NH3BE-1997 06/22/2018 MD 180619-23-01 Arsenic - Solid Sludge 0.053 mg/kg SM3113 B-2004 07/03/2018 MD 180619-23-01 Cadmium -Solid Sludge 1.02 mg/kg SM3111B-1999 07/03/2018 MD 180619-23-01 Calcium Sludge 16212.1 mg/kg SM3111B2011 06/21/2018 MD 180619-23-01 Chromium -Solid Sludge 14.4 mg/kg SM3113 B 07105/2018 MD 180619-23-01 Copper - Solid Sludge 222.7 mg/kg SM3111B-2011 07/05/2018 MD 180619-23-01 Magnesium Sludge 4590 mg/kg EPA2oo.7 06/21!2018 MD 180619-23-01 Mercury Solid Sludge 3.712 mg/kg SM3112B-2011 07/0512018 MD 180619-23-01 Molybdenum -Solid Sludge 18.2 mg/kg EPA200.7 06/21/2018 MD 180619-23-01 Nickel -Solid Sludge 3.106 mg/kg SM3113 B 07/03/2018 MD 180619-23-01 Nitrate/Nitrite - Sludge 14.1667 mg/kg SM4500F/A 0612112018 CL Solids Sludge g 242.7 mg/L Calculation 07/03/2018 CL 180619-23-01 PAN % SM25408-2011 06/20/2018 WC 180619-23-01 Percent Solids Sludge 1.32 Std. Units SM4500HB-2011 06/19/2018 MD 180619-23-01 pH a Sludge g 6.74 mg/kg g EPA200.7 06/29/2018 ENCO 180619-23-01 Potassium - Solid Sludge 1120 Calculation 07/03/2018 CL 180619-23-01 SAR Sludge 2.29 % mg/kg g SM3113B 06/21/2018 MD 180619-23-01 Selenium Solid Sludge 2.04 SM 3111 B 06/2112018 MD 180619-23-01 Sodium - Solid Sludge 100 mg/kg SM4500PE-2011 06/21/2018 CL 180619-23-01 T. Phosphorus Solid Sludge 20450 mg/kg SM4500Norg B-2011 06/21/2018 CL 180619-23-01 TKN Sludge 60327.3 mg/kg SM3111B-2011 06/21/2018 MD 180619-23-01 Zinc -Solid Sludge 770.455 mg/kg PO Box 228 a Statesville, NC 28687 0 704/872/4697 Page 1 of 13 Sample Number Parameter 180619-23-01 Lead -Solid Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 Sample ID Result Sludge 17.42 Unit Method Analyzed Analyst mg/kg SM3113B 06/21/2018 MD PO Box 228 a Statesville, NC 28687 • 704/872/4697 Page 2 of 13 Condition of Receipt f "zample Number 180619-23-01 Temp on Arrival: 2.9 pH on Arrival: <2 Parameter Schedule: Aluminum Nitric Acid Received on Ice Chemicals in containers, lab Chemicals in containers, lab Received on Ice pH on Arrival: <2 Parameter Schedule: Arsenic - Solid Nitric Acid Received on Ice Chemicals in containers, lab pH on Arrival: <2 Parameter Schedule: Cadmium Nitric Acid Received on Ice Chemicals in containers, lab pH on Arrival: <2 Parameter Schedule: Cadmium - Solid Nitric Acid Chemicals in containers, lab Received on Ice pH on Arrival: <2 Parameter Schedule: Chromium Nitric Acid Chemicals in containers, lab Received on Ice pH on Arrival: <2 Parameter Schedule: Chromium -Solid Nitric Acid Received on Ice Chemicals in containers, lab pH on Arrival: <2 Parameter Schedule: Copper Nitric Acid Received on Ice Chemicals in containers, lab pH on Arrival: <2 Parameter Schedule: Copper - Solid Nitric Acid Chemicals in containers, lab Received on Ice Parameter Schedule: Molybdenum - Solid pH on Arrival: <2 Nitric Acid Received on Ice Chemicals in containers, lab pH on Arrival: <2 Parameter Schedule: Nickel Nitric Acid Received on Ice Chemicals in containers, lab Parameter Schedule: Nickel - Solid pH on Arrival: <2 Chemicals in containers, lab Nitric Acid Received on Ice Parameter Schedule: Potassium pH on Arrival: <2 Nitric Acid Received on Ice Chemicals in containers, lab PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3Of13 pH on Arrival: <2 Parameter Schedule: Potassium - Solid Nitric Acid Chemicals in containers, lab Received on Ice pH on Arrival: <2 Parameter Schedule: Nitric Acid Received on Ice Chemicals in containers, lab pH on Arrival: <2 Parameter Schedule: Sodium Nitric Acid Received on Ice Chemicals in containers, lab pH on Arrival: <2 Parameter Schedule: Sodium - Solid Nitric Acid Received on Ice Chemicals in containers, lab pH on Arrival: <2 Parameter Schedule: Nitric Acid Received on Ice Chemicals in containers, lab pH on Arrival: <2 Parameter Schedule: Zinc - Solid Nitric Acid Received on Ice Chemicals in containers, lab pH on Arrival: <2 Parameter Schedule: Nitric Acid Received on Ice Chemicals in containers, lab pH on Arrival: <2 Parameter Schedule: Received on Ice Chemicals in containers, lab Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: pH Received on Ice pH on Arrival: <2 Parameter Schedule: Nitrate/Nitrite Sulfuric Acid Received on Ice Chemicals in containers, lab pH on Arrival: <2 Parameter Schedule: Nitrate/Nitrite - Solids Sulfuric Acid Chemicals in containers, lab Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 4 of 13 pH on Arrival: <2 Parameter Schedule: Phosphate, Total as P Sulfuric Acid Received on Ice Chemicals in containers, lab pH on Arrival: <2 pH on Arrival: <2 Parameter Schedule: TKN Sulfuric Acid Received on Ice Chemicals in containers, lab Parameter Schedule: Ammonia Nitrogen Sulfuric Acid Received on Ice Chemicals in containers, lab Parameter Schedule: Received on Ice Parameter Schedule: Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 5 of 13 b O m m m m m 3 m CL 0 a _°w a � 3 ] 3 3 3 3 3 fl v v v Ico m m m LLL I :I I PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 6 of 13 e� O Laboratori ENCes �, A .� ��"�# l"i� Vit', � � �" 102-A woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Friday, June 29, 2018 Statesville Analytical Holdings, LLC (ST032) Attn: Crystal Little PO Box 228 Statesville, NC 28687 RE: Laboratory Results for Project Number: 180619-23, Project Name/Desc: Misc. Subcontract ENCO Workorder(s): CB09598 Dear Crystal Little, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Friday, lune 22, 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager Enclosure(s) Page t of 7 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. p0 Box 228 o Statesville, NC 28687 e 704/872/4697 Page 7 of 13 Client ID: 180619-23.01 Parameter Preparation EPA 6010D EPA 30508 FINAL www.encolebs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Lab ID: CB09598-01 Sampled: 06/19/18 09:00 Received: 06/22/16 11:20 Hold Date/Time(sl Prep nate/Tlme(s) BOalvsis Date/Timefal 12/16/18 06/28/18 09:01 06/29/18 1401 This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 2 of 7 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 8 of 13 www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: 180619-73-01 Wb ID: 0609598.01 Aaalyt Results Fla.9 MDL P_46 Units Method Notes Potassium - Total 1120 89.7 560 mg/kg dry EPA 6010D FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 3 of 7 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 9 of 13 ANALYTICAL RESULTS Description: 180619-23-01 Lab Sample ID: C009598-01 Matrix: Sludge Sampled:06/19118 09:00 Project: Misc. Subcontract Sampled By: CLIENT Metals by EPA 6000/7000 Series Methods www.encolabs.com Received: 06/22/18 11:20 ~ Work Order: CB09598 % Solids: 4.46 Analyte rCAS Numbed Results E109 mom PE MPl M @stsh Method Analyzed ft NoMa Potassium [7440.09-71 1120 mg/kg dry 1 89.7 560 SF28013 EPA 6010D 06/29/18 14:01 JDH FINAL This report relates only to the sample as recelved by the laboratory, and may only be reproduced In full. Page 4 or 7 PO Box 228 a Statesville, NC 28687 • 704/872/4697 Page 10 of 13 page 5 of 7 This report relates only to the sample as received by the laboratory, and may only be reproduced In full. p0 Box 228 • Statesville, NC 28687 • 704/872/4697 Page 11 of 13 CEAmTT -f l www.encolobs.com QUALITY CONTROL DATA letals by EPA 600017000 Serles Methods -Quality Control Batch OF28013 - EPA 3050B Prepared: 06/2812018 09:01 Analyzed: 06/29/201813:58 Blank (SF28013-13M) Spike Source "/oREC RPD -AREC Limits RPD Limit Notes Result Flaq POL Units Level Result Analyte 4.00 U 25.0 mg/kg wet Potassium Prepared: 06/28/2018 09:01 Analyzed: 06/29/2018 14:03 LCS (BF28013-BSI) Spike Source %REC RPD %REC LlmRPD L161Lt Notes lts Result Flaq POL Units Level Result Analyte 425 25.0 mg/kg wet 505 84 BD -120 Potassium Prepared: 06/28/2018 09:01 Analyzed: 06/29/2018 14:05 Matrix Spike (8F28013 -MSI) source: C009598-01 Spike Source %REC RPD Notes Result Flaq POL Units revel Be3111L %REC Ualm RPD 61m16 Analyte 560 mg/kg dry 11200 1120 86 75.125 Potassium 10800 06/28/2018 09:01 Analyzed: 06/29/2018 14:08 Matrlx spike Dup (SF28013-MSDi] Prepared: Source: CB09598-01 Spike Source %REC RPD Notes Result Flag POL Units Level Result %REC Limits RPD WMR Analyte 560 mg/k9 dry 11100 1120 79 75-125 9 2 Potassium 9860 06/28/2018 09:01 Analyzed: 061291201814:10 Post Spike (SF28013-PSI) Prepared: source: C809598-01 Spike Source %REC RPD LWA Notes Result Flaq POL Units Level Result %REC 61m)is RPD Analyte 0.500 mg/L 10.0 0.996 99 80-120 Potassium 10.9 page 5 of 7 This report relates only to the sample as received by the laboratory, and may only be reproduced In full. p0 Box 228 • Statesville, NC 28687 • 704/872/4697 Page 11 of 13 eco www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. 7 The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL Is roughly equivalent to the practical quantitation limit (PQL) and Is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL, N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration Is reported. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full, Page 6 of 7 PO Box 228 • Statesville, NC 28687 e 704/872/4697 Page 12 of 13 E b a L° CLm y' O [ N .y r I '/ N O E o E O V i E F- a( Cn W F m _ F- 14 y J W L1 7 l I i , 1 y N W v r r O 3 °c O _ m LU X i A O to 1 II r zg Qw w I • I I � 1 m a� w� �� i LLA j I I ti .� r I T .q W c E Z c 2 p-� c U 1 E'i I I ¢ ¢ ¢ � u> 1 cc iufp� CT 1 �;,� E 1 � UI V tJ i. I O N� w.ry; C't iV] >1z9 I r u, o G4 .� U - I R. i I N 'p .--. . a a' m i �C ., n: .. V7 9a c V! v J g �E pa a �I 1 1 I 1 N LJ PO Box 228 a Statesville, NC 28687 • 704/872/4697 Page 13 of 13 MAN Analytical Results STATESVILLE ANALYTICAL f. NCDOC-Odom Correctional Institution 485 Odom Prison Rd. Jackson, NC 27845 Receive Date: 06/05/2018 Reported: 02/20/2019 For: Comments: Geometric Mean 22,466 MPN/g Sample Number Parameter Sample ID Result unit Method Analyzed Analyst 180605-47-01 Fecal Coliforms 1 20909 MPN/g SM92210E-2006 06/06/2018 WC 180605-47-01 Percent Solids 1 1.10 % SM254OB-2011. 06/06/2018 WC 180605-47-02 Fecal Coliforms 2 21101 MPN/g SM92210E-2006 06/06/2018 WC 180605-47-02 Percent Solids 2 1.09 % SM254OB-2011 06/06/2018 WC 180605-47-03 Fecal Coliforms 3 23958 MPN/g SM92210E-2006 06/06/2018 WC 180605-47-03 Percent Solids 3 0.96 % SM2540B-2011 06106/2018 WC 180605-47-04 Fecal Coliforms 4 21698 MPN/g SM92210E-2006 06/06/2018 WC 180605-47-04 Percent Solids 4 1.06 aha SM254OB-2011 06/06/2018 WC 180605-47-05 Fecal Coliforms 5 26744 MPN/g SM9227CE-2006 0610612018 WC 180605-47-05 Percent Solids 5 0.86 % SM254OB-2011 06/06/2018 WC 180605-47-06 Fecal Coliforms 6 21905 MPN/g SM92210E-2006 06/06/2018 WC 180605-47-06 Percent Solids 6 1.05 % SM254OB-2011 06/06/2018 WC 180605-47-07 Fecal Coliforms 7 21495 MPN/g SM92210E-2006 06/06/2018 WC 180605-47-07 Percent Solids 7 1.07 % SM254OB-2011 06/06/2018 WC Respectfully submitted, rUF -v�,/Ck.•.� r Fr �.�. r Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 180605-47-01 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 180605-47-02 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 180605-47-03 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 180605-47-04 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 180605-47-05 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 4 Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 180605-47-06 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 180605-47-07 Temp on Arrival: -3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 3 3 B 3 3 3 vl 7 OL CD N 4 f PO Box 228 * Statesville, NC 28687 v 704/872/4697 Page 4 of 4 (1) (D (D :3 07 CD CD Ck LO .0 0 co ra r4 3 a 3 3 B 3 3 3 vl 7 OL CD N 4 f PO Box 228 * Statesville, NC 28687 v 704/872/4697 Page 4 of 4 Analytical Results �T.ATESVILL� y ANALYTICAL NCDOC-Odom Correctional Institution r 485 Odom Prison Rd. Jackson, NC 27845 Receive Date: 06/05/2018 Reported: 02/20/2019 For: Digester Comments: Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 180605-48-01 Aluminum Digester 5953.27 mg/kg SM 3111 D-2011 06/19/2018 MD 180605-48-01 Ammonia Nitrogen Digester 3663.55 mg/kg SM4500NH3BE-1997 06/07/2018 MD 18060548-01 Arsenic - Solid Digester 0.4 mg/kg SM3113 B-2004 06/18/2018 MD 180605-48-01 Cadmium - Solid Digester 0.748 mg/kg SM3111B-1999 06/06/2018 MD 180605-48-01 Calcium Digester 9 23177.6 mg/kg SM3111B2011 06/19/2018 MD 180605-48-01 Chromium - Solid Digester 13.08 mg/kg SM3113 B 06/11/2018 MD 180605-48-01 Copper - Solid Digester 195.3 mg/kg SM3111B-2011 06/11/2018 MD 180605-48-01 Lead -Solid Digester 19.63 mg/kg SM3113B 06/21/2018 MD 180605-48-01 Magnesium Digester 3820 mg/kg EPA 200.7 06/21/2018 MD 180605-48-01 Mercury Solid Digester 0.364 mg/kg SM3112B-2011 06/12/2018 MD 180605-48-01 Molybdenum - Solid Digester 5.05 mg/kg EPA200.7 06/14/2018 MD 180605-48-01 Nickel - Solid Digester 10.19 mg/kg SM3113B 06/07/2018 MD 180605-48-01 Nitrate/Nitrite Digester <0.1 mg/L SM450OF-2011 06/07/2018 CL 180605-48-01 PAN Digester 9 226.6 mg/L Calculation 07/03/2018 CL 180605-48-01 Percent Solids Digester 1.07 % SM2540B-2011 06/06/2018 WC 180605-48-01 pH Digester 9 6.82 Std. Units SM4500HB-2011 06/05/2018 MD 180605-48-01 SAR Digester 1.52 Calculation 07/03/2018 CL 180605-48-01 Selenium Solid Digester 15.9 mg/kg SM3113B 06/18/2018 MD 180605-48-01 Sodium -Solid Digester 100 mg/kg SM 3111 B 06/21/2018 MD 180605-48-01 T. Phosphorus Solid Digester 14020 mg/kg SM450OPE-2011 06/06/2018 CL 180605-48-01 TKN Digester 9 68142.1 mg/kg SM4500Norg B-2011 06/13/2018 CL 180605-48-01 Zinc - Solid Digester 482.243 mg/kg SM3111B-2011 06/11/2018 MD PO Box 228 • Statesville, NC 28687 0 704/872/4697 Page 1 of 11 Sample Number Parameter Sample ID Result Unit Method 180605-48-01 Potassium - Solid Digester Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 5220 mg/kg EPA200.7 Analyzed Analy 06/12/201$ ENCO' PO Box 228 • Statesville, NC 28687 • 704/872/4697.,;:. Page 2 of 11 i 1 I -j -1 n -1 y 3 z • � a o 7D 77 7D 77 d G 3 m N W CD m fD m m 3 m m m m, M Q Cd C1 O (n I y' CL n CD a t0 N a t0 y a W =r'D I �I w� 6 a I a U) w cr 3 3 Su N 3 3 3 3 0 m fD ]CD it CD 6 e-_. 7 10 v n O a Q c: 'm 3 z • � a o xC N � d 1 N v ` O - m m m Cd C1 (n I y' O v ED n CD tO p 3 a I J• { 3 3 3 3 fD (D CD w r PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 11 - m m m Cd w (n I y' O v ED n CD tO p 3 a v I �I PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 11 ENCO Laborato 'Y ,rti,M_4�4.ucu �J�:",Ja..hA�s s,•.:s:rt,•q vxa-.r .. v'4 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Wednesday, June 13, 2018 Statesville Analytical Holdings, LLC (ST032) Attn: Crystal Little PO Box 228 Statesville, NC 28687 RE: Laboratory Results for Project Number: 180605-48, Project Name/Desc: Misc. Subcontract ENCO Workorder(s): CB08864 Dear Crystal Little, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Friday, June 8, 2018. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 1 or 7 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 4 of 11 Ce N www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client 10: 180605-48 Lab ID: CBOB864.01 Sampled: 06/05/18 09:15 Recelved: 06/08/18 10:30 Parameter Preparation Hold Date/Time( sl plan DatalTlm9w analysis DatafTime(sl EPA 6010D EPA 3005A 12/02/18 06/11/18 08:43 06/12/18 13:41 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 2 of 7 PO Box 228 • Statesville, NC 28687 0 704/872/4697 Page 5 of 11 �Ca www.encolabs.com SAMPLE DETECTION SUMMARY ClfentlD: 180605-48 Lab 1D: C608864-01 Analyte (Results fin MU ML 5 nHA Method Notes Potassium - Total 55600 0 750 2500 ug/L EPA 60 101) R-01 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full, Page 3 of 7 PO Box 228 a Statesville, NC 28687 • 704/872/4697 Page 6 of 11 CeNSGED -10 ANALYTICAL RESULTS Description: 180605-4B Lab Sample ID:CB08864-01 Received: 06/08/18 10:30 Matrix: Waste Water Sampled:06/05/18 09:15 Work Order: CB08864 Project: Misc. Subcontract Sampled By: Client Metals (total recoverable) by EPA 6000/7000 Series Methods Analyte rCAS Nemberl Results f10 Y111b Pf Hu ML AD= Metbad Analyzed Ay Kola Potassium [7440.09-71 55600 D ug/L 5 750 2500 6FI1010 EPA 6010D 06/12/18 13:41 JDH R -OS FINAL This report relates only to the sample as recel ed by the laboratory, and may only be reproduced In full. Page 4 of 7 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 7 of 11 C�- C GD www.encolabs.com FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full, Page 5 of 7 PO Box 228 a Statesville, NC 28687 • 704/872/4697 Page 8 of 11 QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch BF11010 - EPA 3005A Blank (BF31010-BLK1) Prepared: 06/11/2018 08:43 Analyzed: 06/12/2018 11:11 Spike Source %REC RPD Analvte Result Flag POL Units Level Result VAREC Lim RPD Limit Notes Potassium 150 U 500 ug/L LCS (81`11010 -BSS) Prepared: 06/11/2018 08:43 Analyzed: 06/12/2018 11:17 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Mmks RPD Limit Notes Potassium 9850 500 ug/L 10000 98 80-120 Matrix Spike (8F11010-MS1) Prepared: 06/11/2016 08:43 Analyzed: 06/12/2018 11:21 Source:C608804.01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result a/ REC Limits RPD 11R1Lt Notes Potassium 10900 500 ug/L 10000 1030 98 75-125 Matrix Spike Dup (81`33010-MSD1) Prepared: 06/11/2018 08:43 Analyzed: 06/12/2018 11:24 Source:CB08804.01 Spike Source %REC RPD .Analvte Result Flan POL Units Level Result %REC Limits RPD llmlt Notes Potassium 11000 500 ug/L 10000 1030 100 75-125 2 20 Post Spike (SF11010-PSS) Prepared: 06/11/2018 08:43 Analyzed: 06/12/2018 12:28 Source: C608804-01 Spike Source %REC RPD Analvte Result Flaq POL units Level Result %REC Limits RPD limit Notes Potassium 11.0 0.500 mg/L 10.0 1.03 99 80-120 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full, Page 5 of 7 PO Box 228 a Statesville, NC 28687 • 704/872/4697 Page 8 of 11 CC-== N C= -e www.encolabs.com FLAGS/NOTES AND DEFINITIONS 0 The analyte was detected in the associated method blank. D The sample was analyzed at dilution. ] The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitatlon Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. R-01 The Reporting Limit for this analyte has been raised to account for matrix interference. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 6 017 PO Box 228 • Statesville, NC 28687 e 704/872/4697 Page 9 of 11 .n u 0 a VA I U. ! zc o W 0 r m C1 H � 00 OulU 16 E 10 U Q I Ii U U O . N m v� N —� r b G a cc i I V I 1 A VA I U. ! zc o W 0 r m C1 H � 00 OulU Q2 U Q I Ii U U O . N m v� N N" q� V1 � ! d d m is U Q I Ii U t mr �' 01 —� r b G f � i I V I 1 g d Q IQ U i e i 4' Ir Q a` m t Y S U F PO Box 228 • Statesville, NC 28687 0 704/872/4697 Page 10 of 11 Sample Preservation Verification ENCO Cary Work Order: CB08864 Project: Misc. Subcontract Client: Statesville Analytical Holdings, LLC (ST032) Project#: 180605-48 Logged In: 08 -Jun -18 15:07 Logged By: Rachel Ann Yonisj� a �� Preservation Check Performed By: Date/Time: lD I � CB08864-01 .tint 7 � p �-. ir. _ Yp`. b F2equa. A 500mLP+HNO3 `2 r Rea ent Name ID 1 :;t 2 G.tSeCkeG I '; pH Adjust�,d r�0antrot IN/NA Y}1 NINAU Rea ent Name ID 3 4 0-3 Rea ent Name ID 5 6 pH Strip ID: PH Strips C7J0E20 page 1 of 1 C:lelmnt\Priimwnu_r- aacivaLwtwiic%ln.ipt PO Box 228 - Statesville, NC 28687 - 704/872/4697 Page 11 of 11