WQ0016247_Residual Annual Report 2018_20190315

INITIAL REVIEW
Reviewer Williams, Kendall
Project Number* WQ0016247
SUBMITTAL DATED: 2/27/2019
Project Contact Information
Rease provide information on the person to be contacted by MB Staff regarding electronic submittal, confirmation of receipt, and other issues.
......................................................................................................................................................................................................................................................................................................................................................................................................
Name * Lisa Finnerty
Email Address*
[e-mail]
Project Information
Application Type* r
New
r
Renewal
r
Annual Report
Permit Type * r
Wastewater Irrigation
r
Other Wastewater
•
Closed -Loop Recycle
r
Single -Family Residence
Wastewater Irrigation
Is a paper copy of the application being submitted?*
r Yes r Nor N/A
Permit Number* WQ0016247
Phone Number*
443-489-9086
Permittee * Synagro Central LLC - Western Piedmont
Facility Name * Facilities listed in comments section
r Modification (Major or Minor)
• Additional Information
r Other
• High -Rate Infiltration
r Reclaimed Water
r Residuals
r Other
Please provide comments/notes on your current submittal below.
Facilities included in this report are:
Columbus WWTF
Granite Falls WWTP and Granite Falls WTP
Stanly County WWTP
Statesville Third Creek WWTP, Statesville Fourth Creek
Please attach all information required or requested for this submittal to be review here.

Application Form Engineering Rans, Specifications, Calculations, Etc.)
Synagro Central LLC Class B 2018 Annual
58.48M6
Report.pdf
upload only 1 RDF docurrent. NLltiple documents must be combined into one RDF file.
For new and modification permit applications, the paper copy is required to be submitted to the
Division_ Be advised, applicahans will not be considered complete until both the paper and electronic
applications have been received. The paper copy shall include the folio -ging:
• Application Form
• All relevant attachments (talcs, soils report, specs, etc_)
• 1 full-size engineumg plan set
• 2 11-17" engineering plan sets
• 1 extra set of specifications (in addition to the set of specifications provided in the
• Fee (if required)
This shall be mailed to the following address=
By US. Postal Service:
Division o2772ter Resources- Non -Discharge Branch
1617 hail Ser. -ice Center Raleigh INC 27699-1617
Sv Courier'Speeia. Deli-: ery:
Division o- iVater R e5ources- Non -Discharge Branch
A- Nathaniel Thornburg- 9th Floor, Office 4942W
512 N. Salisbury St. Raleigh, NC 27604
For questions or problems contact Tessa Monday at 919.707.3660 or TessaManday(i�ncderu.gatir Of
Sonia Graves at 919.7073657 or Sona. aves(a,ncdenr_9ov_
*V By checking this box I am acknowledging that I have read the above statement and agree
to send these documents as required to one of the address given above.
Signature
Submission Date 2/27/2019

435 Williams Court, Suite 100
Baltimore, MD 21220
www.synagro.com
FEBRUARY 273 2019
NCDEQ
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: 2018 Annual Report for Permit No. WQ0016247
Dear NCDEQ:
Synagro is submitting one copy and one electronic copy of the above referenced report as
required by Synagro Central, LLC's land application of Class B residuals permit. Residuals
from the City of Statesville, Town of Columbus, Town of Granite Falls, and Stanly County
Utilities were applied in 2018.
If you, have any questions of need additional information, please do not hesitate to contact Nate
Roth ataa6-403-4324.
Sincerely,
a
Derrick Shivar
Environmental Compliance Manager
Enclosures
cc: Nate Roth -Synagro
YOUR PARTNER FORA CLEANER, GREENERWORLD

2018 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION IN NC
STATESVILLE, NC
STATESVILLE, NC FOURTH CREEK CAKE
MONTH/YEAR
January 2018
June 2018
July 2018
YEARLY TOTAL
AMOUNT
UNIT
860.00
Y
412.00
Y
1,214.00
Y
2,486.00 Y
STATESVILLE, NC THIRD CREEK CAKE
MONTH/YEAR
January 2018
June 2018
YEARLY TOTAL
AMOUNT UNIT
560.00 Y
1,412.00 Y
1.972.00 Y
DRY METRIC
DRY TONS UNIT TONS
101.98 D 92.50
46.04 D 41.77
135.38 D 122.77
283.40 D 257.04
DRY METRIC
DRY TONS UNIT TONS
65.85 D 59.72
154.59 D 140.22
220.44 D 199.94
2/2/2019

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Waypoi nt.. 7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 18-060-9206
Client Project Description: Statesville 4th Creek
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
58889
Statesville
4th
Creek
Solids
02/28/2018
08:15
03/01/2018
58889
Statesville
4th
Creek
Solids
02/28/2018
08:15
03/01/2018
7471A
WiN
WTN: Waypoint Analytical -TN, Memphis, TN, Certifcation: #1354
Page 1 of 4

Report Number: 18-Ofi0-9206
Account Number: 46493
Send To: Synagro Cenral LLCI Statesville
Mary Brewer
284 Boger Road
Mocksville, NC 27028
Lab Number : 58689
Sample Id: Statesville 4th Creek
Waypoint_®
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-94010 Fax [phone]
www.waypolmanalydcal.cum
Project: Statesville 4th Creek
REPORT OF ANALYSIS Date Sampled:2/281201808:15:00
Date Received: 03/01/201800:00
Date Reported: 05/29/2018
Total Solids"
All values are on a dry weight basis except as noted by asterisk. Detecti
13.15
131500
100.0
JM
03/01/201815:00
SM -2540G
Moisture"
86.84
100.0
JM
03/01/201815:00
SM -2540G
Total Kjeldahl Nitrogen
6.42
64200
50.0
JM
03/02/2018
08:30
SMA500-NH3C-TKN
Phosphorus
2.64
26400
100
SMC
03106/201814:45
60101)
Potassium
0.52
5150
100
SMC
03/07/201814:16
6010D
Sulfur
0,75.
7480
100
SMC
03/06/201814:45
6010D
Calcium
1.07
10700
100
SMC
03/06/201814:45
6010D
Magnesium
0.39
3870
100
SMC
03/06/201814:45
6010D
Sodium
0.09
946
100
SMC
03/06/2018
14:45
60100
Iron
17200
100
SMC
03/06/201814:45
6010D
Aluminum
17000
100
SMC
03/06/201814:45
6010D
Manganese
1670
5.00
SMC
03/06/201814:45
6010D
Copper
237
5.00
SMC
03/06/201814:45
6010D
Zinc
539
5.00
SMC
03/06/201814:45
6010D
Ammonia Nitrogen
0.49
4940
50.0
JM
03/02/201808:30
SM-4500-NH3C
Organic
5.93
59260
50.0
03/02/201808:30
CALCULATION
Nitrate+Nitrite-N
34.8
2.49
MMT
03/06/201811:52
4500NO3F-2011
on limit on all N series is on a wet basis.
Ourrepods and lelfers are for the. exclusive and conAdenlial use of our rlienls, and near not be reproducer) in whole or pad, nor may any iekrrnce he made
IQ the aarle the frontal, or the company In any advertisingnews release_ or olhert uhllo announwmenYs without obtaining ourpdarwdllan auMorizallair
Pauric McGroary
Agronomist
Page 2 of 4

Report Number. 18-969-9206
Account Number. 46493
Sentl To: Synagm Central LLC/ Statesville
Mary Brewer
284 Boger Road
Mocksville, NC 27028
Lab Number: 58889
Sample Id : Statesville 4th Creek
Waypoint_®
ANALYTICAL
7fi21 Whitepine ftaadr Richmond, VA 23237
an 804-743-94010 Fax [phone]
www.waypolntanalytical.com
Project :Statesville 4N Creek
REPORT OF ANALYSIS Date sampled:2/28/261898:15:99
Date. Race ivad: 03/01/2018 00:00
Date Reported: 05/29/2018
Cadmium
2.09
Chromium
27.4
Nickel
21.3
Total Lead
18.4
Arsenic
3:50
Total Mercury
0.737
Selenium
<5,00
pH'
6.5
Molybdenum
8.75
Comments:
6010D
NC CERT#257
SMC
SULFURAND ORGANIC
NITROGEN NOT FOR COMPLIANCE PURPOSES.
2.00
SMC
03/06/201814:45
fi019D
5.00
SMC
03/06/201814:45
6919D
5:00
SMC
03/06/201814:45
6010D
5.00
SMC
03/06/201814:45
6010D
3.00
SMC
03/07/201814:16
6010D
0.0133
KKM
03/06/201814:04
7471A
5.00
SMC
03/07/201814:16
5010D
1.0
JM
03/02/201808:30
9045D
5.00
SMC
03/06/201814:45
6010D
All values ara on a dry weight hasis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Ourrepods and lef(ars are for the exMusive and avnlldoMial use of oarcllenfs, and may not be reprodvcodln whMe or Pat, nor tray any referencabe made
Iv pie wpM. Iha results, vrlha cgmpeny In any adveNslag. news relaase. vrpfherpublfp annvunoemenfs wkhwf obt�inlnb our prior uriillen apfM1vdzalivn,
Page 3 of 4
Pauric MCGroary
Agronomist

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Sodium Absorption Ratio Calculation (SAR)
Product Code
Product Name
Sample Date
Report Range
Ratio
2084-01-CAK-NC
STATESVILLE,
NC
FOURTH
CREEK
CAKE
2/28/2018
3/112018-4/30/2018
0.7203
Na mg/I = (Na mg/kg x %Solids) - 100 = (946 x 13.1500) + 100 = 124.399
Ca mg/I = (Ca mg/kg x %Solids) = 100 = (10700 x 13.1500) + 100 = 1407.05
Mg mg/I = (mg mg/kg x %Solids) + 100 = (3870 x 13.1500) - 100 = 508.905
Na meq = Na mg/I = Molec.Wgt.Na = 124.399 + 23 = 5.40865
Ca meq = Ca mgll + Molec.WgLCa = 1407.05 + 20 = 70.3525
Mg meq = Mg mg/I + Molec.Wgt.Mg = 508.905 + 12 = 42.4087
SAR = Na meq _ SgrRoot[0.5 x (Ca meq + Mg meq)] = 5.40865 + SgrRoot[0.5(70.3525+82.4087)] = 0.720318
Printed: 2/2/2019
Page 1 18:56

Wa oint `
Y -ANALYTICAL
5/23/2018
Synagro Central LLC/ Statesville
Mary Brewer
284 Boger Road
Mocksville, NC, 27028
Ref: Analytical Testing
Report Number: 18-135-0208
Project Description: Statesvile 4th Creek
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www,waypointa nalyttca Isom
Dear Mary Brewer:
Waypoint Analytical Virginia, Inc. received samples) on 5/15/2018 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were pertormed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
pm°w"'i
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of sold analysis.
Arizona AZ0629 New Jersey VA011 Pennsylvania 68-03109 Virginia 4fi0014
Florida E971087 North Carolina 257 South Carolina 93007
Jl
Page 1 of 9

Wa oint ��
Y -ANALYTICAL
Client: Synagro Central LLC/ Statesville
Project: Statesvile 4th Creek
Lab Report Number: 18-135-0208
pate: 5/23/2018
7621 Whitepine Road, Richmond, VA 23237
Main 804-743.9401 °Fax [phone]
www.waypolnta nalyttcal. com
CASE NARRATIVE
Nitrate +Nitrite Nitrogen Method SM-4500NO3F
Sample fi0698
Analyte: NO3+NO2-N
OC Batch No: E64084
The MS/MSD recoveries are considered insignificant due to the level of analyte present in the parent sample
relative to the spike level .RPD is based on the MS/MSD results and should be evaluated as laboratory
duplicates.
Metals Analysis Method SW-6010CM
Sample 60697
Analyte: AI
QC Batch No: L382487
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interterence is suspected.
QC Batch No: L382642
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interterence is suspected.
Analyte: As
QC Batch No: L382487
MS/MSD Recovery failed, PDS confirmed matrix interference
QC Batch No: L382642
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MOL. Post Digestion Spike within
method limits. No matrix interference is suspected.
Analyte: Ca
QC Batch No: L382487
MS/MSD Recovery failed,
DT confirmed matrix interterence
QC Batch No: L382642
MS/MSD Recovery failed,
DT confirmed matrix interterence
Analyte: Cd
QC Batch No: L382487
MS/MSD Recovery failed,
DT confirmed matrix interterence
Analyte: Cr
OC Batch No: L382487
MS/MSD Recovery failed,
DT confirmed matrix interference
Analyte: Cu
QC Batch No: L382487
Page 2 of 9

Waypoint�
ANALYTICAL
MS/MSD Recovery failed, DT confirmed matrix interterence
Analyte: Fe
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed matrix interference
7621 Whitepine Road, Richmond, VA 23237
Main 804-743.9401 °Fax [phone]
www.waypolnta nalyti ca I. com
QC Batch No: L382642
MS and/or MSD spike recovery failed. Analyte
concentration >25X the MQL. Dilution test within method limits.
No matrix interference is suspected.
Analyte: K
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed
matrix
interference
QC Batch No: L382642
MS/MSD Recovery failed, DT confirmed
matrix
interference
Analyte: Mg
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed
matrix
interference
QC Batch No: L382642
MS/MSD Recovery failed, DT confirmed
matrix
interference
Analyte: Mn
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed
matrix
interference
Analyte: Mo
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed
matrix
interference
Analyte: Na
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed
matrix
interference
QC Batch No: L382642
MS and/or MSD spike recovery failed. Analyte
concentration >25X the MQL. Dilution test exceeded method
limits. Matrix interference is suspected.
Analyte: Ni
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed
matrix
interterence
Analyte: P
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed
matrix
interference
QC Batch No: L382642
MS and/or MSD spike recovery failed. Analyte
concentration >25X the MQL. Dilution test within method limits.
No matrix interference is suspected.
Analyte: Pb
Page 3 of 9

Wa oint.®
Y ANALYTICAL
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed matrix interference
Analyte: S
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed matrix interference
QC Batch No: L382642
MS/MSD Recovery failed, DT confirmed matrix interference
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypo i nta nal yti ca I. co m
Analyte: Se
QC Batch No: L382487
MS/MSD Recovery failed, PDS confirmed matrix interference
QC Batch No: L382642
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within
method limits. No matrix interference is suspected.
Analyte: Zn
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed matrix interference
QC Batch No: L382642
MS/MSD Recovery failed, DT confirmed matrix interference
Solids Total Mercury Analysis - CVAA Method SW -7471 B
Sample 60698
Analyte: Hg
QC Batch No: E64133
MS/MSD Recovery failed, PDS confirmed matrix interference
Page 4 of 9

Waypoint.., 7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 18-135-0205
Client Project Description: Statesvile 4th Creek
Lab No Client Sample ID
Matrix Date Collected Date Received Method Lab ID
60701
Statesville
4th
Creek
Solids
05/10/2018
14:00
05/15/2018
60701
Statesville
4th
Creek
Solids
05/10/2018
14:00
OS/i5/2018
WTN: Waypoint Analytical -TN, Memphis, TN, Certifcation: #1354
Page 5 of 9
6010C WTN

Report Number: 18-135-0208
Account Number: 46493
Send To: Synagro Central LLC/ Statesville
Mary Brewer
284 Boger Road
Mocksville, NC 27028
Lab Number : 60701
Sample Id : Statesville 4th Creek
Waypoint_®
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 a Fax [phone]
www.waypointanalytical.com
Project: Statesvile 4th Creek
REPORT OF ANALYSIS Date Sampled: 5/10/201814:00:00
Date Received: 06/15/2018 00:00
Date Reported: 05/23/2018
Total Solids'
All values are on a dry
13.27
132700
100.0
R D
05/15/2018 15:00
SM -2540G
Moisture
86.72
100.0
R 0
05/15/2018 15:00
SM -2540G
Total Kjeldahl Nitrogen
5.70
57000
50.0
JM
05/16/2018 08:30
SM-4500-NH3C-TKN
Phosphorus
2.66
26500
50.0
KKM
05/21/201821:02
6010C
Potassium
0.81
8100
500
KKM
05/21/201821:07
6010C
Sulfur
0.61
6140
5.00
KKM
05/19/201806:54
6010C
Calcium
0.81
8060
5.00
KKM
05/19/201806:54
6010C
Magnesium
0.32
3180
5.00
KKM
05/19/2018 06:54
6010C
Sodium
0.07
655
25.0
KKM
05/19/2018 06:54
6010C
Iron
17000
50.0
KKM
05/21/201821:02
6010C
Aluminum
20200
50.0
KKM
05/21/201821:02
6010C
Manganese
1600
5.00
KKM
05/21/201821:02
6010C
Copper
220
0.250
KKM
05/19201806:54
6010C
Zinc
461
0.500
KKM
05/19/201806:54
6010C
Ammonia Nitrogen
0.81
8060
50.0.
JM
05/16/2018.08:20
SM-4500-NH3C
Organic
4.89
48940
50.0
05/16/201808:20
CALCULATION
Nitrate+Nitrite-N
<2.37
2.37
MMT
05/17/201809:47
45001\103F-2011
weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our reports and lectors are for the exnlusivaand wnfiden6al ueo of real and may not be rapmduaetlln whole organ nor may any rereroncro 69 matle
to the work, the results, or rhe Company in any advedlslny. news release, or other publlc anntivncemenls wdhout0tedheing ourpdor vrrillen aNhorizallon.
Pauric MCGroary
Agronomist
Page 6 of 9

Report Number: 18-135-0208
Account Number: 46493
Send To: Synagro Central LLC/ Statesville
Mary Brewer
284 Boger Road
Mocksville , NC 27028
Lab Numher : 60701
Sample Id : Statesville 4th Creek
VNaypoint_
ANALYTICAL
7621 Whitepine Roadr Richmond, VA 23237
Main 804-743-94010 Fax [phone]
www,waypointa nalytica l.com
Project : Statesvile 4th Creek
REPORT OF ANALYSIS Date sampled: s/10/zo161a:9o:09
Date Received: 05115/2018 00:00
Date Reported: 05/23/2018
Cadmium
1.75
Chromium
20.8
Nickel
16.9
Total Lead
14.7
Arsenic
3.86
Total Mercury
0.585
Selenium
2.58
pH `
6.9
Molybdenum
7.81
Comments:
KKM
NC CERT#257
06:54
SULFUR AND ORGANIC NITROGEN
NOT FOR COMPLIANCE PURPOSES.
0.100
KKM
05/19/2018
06:54
6010C
0.250
KKM
05/19/201806:54
6010C
0.250
KKM
05/19/201806:54
6010C
0.300
KKM
05/19/2018
06:54
6010C
1.00
KKM
05/19/2018
06:54
6010C
0.400
SMC
05/21/201814:40
SW -74718
0.500
KKM
05/19/201806:54
6010C
1.0
JM
05/16/2018
08:20
9045D
0.250
KKM
05/19/2018
06:54
6010C
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our reVorls antl leifem are for fhe exclusive and confidenflal usv of ourclients, and may not be reproduced in whole or part, nor may
any rererenco be made
to Na wbrk Iha resul(s, or the xompany In any advedislnp. news release. orohrerpubllc annoaucemenls without obtelning ourpdor wrltlen eufM1orlTadon
Page 7 of 9
Pauric McGroary
Agronomist

`���Vl
Waypoint.. ��
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypoi nta na lytics I. com
Cooler Receipt Form
Customer Number: 46493
Customer Name: Synagro Central LLC/ Statesville
Report Number; 18-135-0208
Shipping Method
Fed Ex a US Postal � Lab 0 Other : �—
UPS � Client 0 Courier Thermometer ID: �—
Shipping container/cooler uncompromised? � Yes � No
Number of coolers received
Custody seals intact on shipping container/cooler? � Yes (� No � Not Required
Custody seals intact on sample bottles? � Yes Q No � Not Required
Chain of Custody (COC) present? � Yes � No
COC agrees with sample label(s)? � Yes � No
COC properly completed � Yes � No
Samples in proper containers? � Yes � No
Sample containers intact? � Yes � No
Sufficient sample volume for indicated test(s)? � Yes � Nc
All samples received within holding time? � Yes � No
Cooler temperature in compliance? � Yes � No
Cooler/Samples arrived at the laboratory on ice. � Yes � No
Samples were considered acceptable as cooling
process had begun.
Water -Sample containers properly preserved � Yes 0 No � N/A
Water- VOAvials free of headspace � Yes 0 No � N/A
Trip Blanks received with VOAs � Yes � No � N/A
Soil VOA method 5035 –compliance criteria met � Yes � No � N/A
High concentration container (48 hr) � Low concentration Encore samplers (48 hr)
� High concentration pre -weighed (methanol -14 d) � Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? � Yes � No
Comments:
Signature: Brandi Watson Date &Time: 5/15/2018 13:47:02
Page 8 of 9

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Sodium Absorption Ratio Calculation (SAR)
Product Code
Product Name
Sample Date
Report Range
Ratio
2084-01-CAK-NC
STATESVILLE,
NC
FOURTH
CREEK
CAKE
5/10/2018
5/1/2018-6/30/2018
0.5676
Na mg/I = (Na mg/kg x %Solids) _ 100 = (655 x 13.2700) = 100 = 86.9185
Ca mg/I = (Ca mg/kg x %Solids) :100 = (8060 x 13.2700) - 100 = 1069.56
Mg mg/I = (mg mg/kg x %Solids) _ t 00 = (3180 x 13.2700) + 100 = 421.986
Na meq = Na mg/I : Molec.Wgt.Na = 86.9185 + 23 = 3.77907
Ca meq = Ca mg/I : Molec.Wgt.Ca = 1069.56 = 20 = 53.4781
Mg meq = Mg mg/i * Molec.Wgt.Mg = 421.986 + 12 = 35.1655
SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 3.77907 _ SgrRoot[0.5(53.4781+35.1655)] = 0.567644
Printed: 2/2/2019
Page 1 18:56

Wa Y-oint®
ANALYTICAL
Synagro Central LLC/ Statesv lle
Mary Brewer
284 Boger Road
Mocksville, NC, 27028
Ref: Analytical Testing
Report Number: 18-184-0204
Project Description: Statesville 4th Creek
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 a Fax [phone]
www.waypointanalyuca Isom
Dear Mary Brewer:
Waypoint Analytical Virginia, Inc. received sample(s) on 7/3/2018 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were pertormed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are eequired to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are report
ed on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of tfie charges paid for performance of said analysis.
Arizona AZ0629 New Jersey VA011 Pennsylvania 68-03109 Virginia 460014
Florida E871087 Nort
h Carolina 257 South Carolina 93007
:.
Page 1 of 8

Wa oint.®
Y ANALYTICAL
Client: Synagro Central LLC/ Statesville
Project: Statesville 4th Creek
Lab Report Number: 18-184-0204
Date: 7/11/2018
7621 Whitepine Road, Richmond, VA 23237
Main 804-743.9401 °Pax 804.271-6446
www.waypo iota nalytica Isom
CASE NARRATIVE
TKN (Titration) Method SM-4500-NH3C-TKN
Analyte: TKN
OC Batch No: E64890
Analyte was flagged for 0 % recovery in the LCS and/or LCSD due to the result being below the MQL. The actual
result was
XXJ which calculates to a recovery of XX%.
Analyte was flagged for 0 % recovery in the LCS and/or LCSD .The actual result was
0.870 which calculates to a recovery of 85 % .
QC Batch No: E64890
The MS/MSD recoveries are considered insignificant due to the level of analyte present in the parent sample
relative to the spike level .RPD is based on the MS/MSD results and should be evaluated as laboratory
duplicates.
Nitrate +Nitrite Nitrogen Method SM-4500NO3F
Sample 61491
Analyte: NO3+NO2-N
QC Batch No: E64942
The MS/MSD recoveries are considered insignificant due to the level of analyte present in the parent sample
relative to the spike level .RPD is based on the MS/MSD results and should be evaluated as laboratory
duplicates.
Metals Analysis Method SW -6010C
Sample 61489
Analyte: AI
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration >25X the MOL. Dilution test within method limits.
No matrix interterence is suspected.
Analyte: As
OC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within
method limits. No matrix interterence is suspected.
Analyte: Fe
QC Batch No: L389809
MS and/or MSD spike recovery failed. Analyte concentration >25X the MOL. Dilution test within method limits.
No matrix interterence is suspected.
Analyte: K
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration >25X the MOL. Dilution test within method limits.
No matrix interterence is suspected.
Page 2 of 8

Wa oint
Y ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypointanalytica l.com
Analyte: Mg
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interference is suspected.
Analyte: Mn
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interference is suspected.
Analyte: Mo
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within
method limits. No matrix interference is suspected.
Analyte: Pb
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within
method limits. No matrix interference is suspected.
Analyte: Se
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within
method limits. No matrix interference is suspected.
Solids Total Mercury Analysis - CVAA Method SW -7471 B
Sample 61491
Analyte: Hg
QC Batch No: E64928
MS/MSD Recovery failed, PDS confirmed matrix interference
Page 3 of 8

W�` /MO' �� 7621 Whitepine Road, Richmond, VA 23237
YN Main 804-743-9401 °Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 18-184-0204
Client Project Description: Statesville 4th Creek
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
61495
Statesville
4th
Creek
Solids
07/02/2018
08:35
07/03/2018
61495
Statesville
4th
Creek
Solids
07/02/2018
08:35
07/03/2018
6010D
WiN
WiN: Waypoint Analytical - TN, Memphis, TN, Certifcation: #1354
Page 4 oP 8

Report Number: 18-184-0204
Account Number. 46493 Waypoi nt.. 7621 Whitepine Road, Richmond, VA 23237
Main 804-743-94010 Fax [phone]
ANALYTICAL www.waypomwnalytial.com
Send To: Synagm Central LLC/ Statesville Project : Statesville 4th Creek
Mary Brewer
284 Boger Road
Mocksville, NC 27028
Total Soilds'
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
f) -6-
13.24
REPORT OF ANALYSIS Date Sampled:
7/2/2018 08:35:00
Lab Number:
61495
Date Received:
07/03/2018 00:00
Sample Id :
Statesville 4th Creek
Date Reported:
07/11/2018
Total Soilds'
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
f) -6-
13.24
132400
100.0
JM
07103/201815:30
SM -2540G
Moisture"
86.75
100.0
JM
07/03/201815:30
SM -2540G
Total Kjeldahl Nitrogen
6.24
62400
50.0
R D
07/05/2018 09:00
SM4500-NH3C-TKN
Phosphorus
2.86
28600
50.0
KKM
07/10/201801:23
6010D
Potassium
0.62
6200
50.0
JTR
07/10/201801:23
601 OD
Sulfur
0.78
7830
50.0
KKM
07/10/201801:23
6010D
Calcium
1.23
12300
50.0
KKM
07/10/2018 01:23
6010D
Magnesium
0.44
4360
50.0
KKM
07/10/201801:23
60100
Sodium
0.09
865
250
JTR
07110/201801:23
60100
Iran
20400
50.0
KKM
07/10/201801:23
601 OD
Aluminum
23800
50.0
KKM
07/10/201801:23
6010D
Manganese
1090
5.00
KKM
07/10/2018 01:23
6010D
Copper
259
2.50
KKM
07/10/2018 01:23
6010D
Zinc
591
5.00
KKM
07/10/201801:23
6010D
Ammonia Nitrogen
1.06
10600
50.0
RD
07/05/201809:00
SMA500-NH3C
Organic
5.18
51800
50.0
07/05/201809:00
CALCULATION
Nitrate+Nitrite-N
22.6
2.30
MMT
07/09/201811:22
4500NO3F-2011
mp
ourrtVortsaM,e,iors are for the exclusive and congtlenM1alus®o,ou,.c;mnrv. warmly not he reproduced An whole or Part, rermay any reference be made
to to workthe forints, or the company on any advert sln0, news releaseor otherpublto noncancerous without marrh log our poor whllen aaboacetion.
Pauric McGroary
Agronomist
Page 5 of 8

Report Number: 18-184-0204
Account Number: 46493
Sena To: Synagro Central LLC/ Statesville
Mary Brewer
284 Boger Road
Mocksvllle, NC 27028
Lah Number : 61495
Sample Id : Statesville 4th Creek
Waypoint.®
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-94010 Fax [phone]
www.waypointanalydcal.com
Project :Statesville 4th Creek
REPORT OF ANALYSIS Date
Dace Receivcei�ed:7/2/201808:3500
ea: 07/03/261e 60:00
Date Reported: 07/11/2018
Cadmium
2.26
Chromium
30.0
Nickel
25.8
Lead
20.6
Arsenic
<5.00
Mercury
0.762
Selenium
<5.00
FH*
8.4
Molybdenum
9.00
Comments:
6010D
NC CERT#257
SMC
SULFUR AND ORGANIC NITROGEN
NOT FOR COMPLIANCE PURPOSES.
1.00
KKM
07/10/201801:?3
60100
2.50
KKM
07/10/201801:23
fi010D
2.50
KKM
07/10/2018 01:23
6010D
3.00
KKM
07/101201801:23
6010D
5.00
KKM
07/11/201801:32
6010D
0.400
SMC
07106/201814:20
SW -74718
5.00
KKM
07111/201801:32
6010D
i.0
R D
07/05/2018 09:00
90450
2.50
KKM
07/10/2018 01:23
6010D
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
labors are m.me ecwslve and nonmomlal use „r,,,rr mlence, and may nm be reaoannae lnwnola or pan, nor may
oarrnpo�r: ann
enY,premnnR as mane
Iv the work, Ne results, yr IFe awnRanY In anyativerllaing. news releaee, or oNerpubllc annewpemen(s wl(M1vuf o6tvining eurpevr wA((an au(M1vrtmtlon.
Page 6 of 8
Pauric McGroary
Agronomist

Waypoint_�
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypointanalyHca I. com
Cooler Receipt Form
Customer Number: 46493
Customer Name: Synagro Central LLC/ Statesville
Report Number: 18-184-0204
Shipping Method
0 Fed Ex � US Postal (� Lab t� Other : �—
UPS � Client � Courier Thermometer ID: �—
Shipping container/cooler uncompromised? ®Yes � No
Number of coolers received ��- 1
Custody seals intact on shipping container/cooler? (� Yes � No � Not Required
Custody seals intact on sample bottles? � Yes � No � Not Required
Chain of Custody (COC) present? � Yes � No
COC agrees with sample label(s)? � Yes !� No
COC properly completed � Yes � No
Samples in proper containers? � Yes � No
Sample containers intact? � Yes � No
Sufficient sample volume for indicated test(s)? � Yes � No
All samples received within holding time? � Yes � No
Cooler temperature in compliance? � Yes � No
Cooler/Samples arrived at the laboratory on ice. � Yes !� No
Samples were considered acceptable as cooling
process had begun.
Water -Sample containers properly preserved � Yes � No � N/A
Water - VOAvials free of headspace 0 Yes � No � N/A
Trip Blanks received with VOAs � Yes � No � N/A
Soil VOA method 5035 –compliance criteria met � Yes � No � N/A
� High concentration container (48 hr) � Low concentration Encore samplers (48 hr)
� High concentration pre -weighed (methanol -14 d) � Low concyre-weighed vials (Sod Bis -14 d)
Special precautions or instructions included? � Yes � No
Comments:
Signature: Brandi Watson Date &Time: 7/03/2018 13:40:45
Page 7 of 8

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Sodium Absorption Ratio Calculation (SAR)
Product Code
Product Name
Sample Date
Report Range
Ratio
2084-01-CAK-NC
STATESVILLE, NC FOURTH CREEK CAKE
7/2/2018
7/1/2018-8/31/2018
0.6187
Na mg/i = (Na mg/kg x %Solids) + 100 = (865 x 13.2400) = 100 = 114.526
Ca mg/I = (Ca mg/kg x %Solids) = 100 = (12300 x 13.2400) - 100 = 1628.52
Mg mg/I = (mg mg/kg x %Solids) - 100 = (4360 x 13.2400) + 100 = 577.264
Na meq = Na mg/I + Molec.Wgt.Na = 114.526 + 23 = 4.97939
Ca meq = Ca mg/I + MolecWgLCa = 1628.52 - 20 = 81.426
Mg meq = Mg mg/I + Molec.Wgt.Mg = 577.264 + 12 = 48.1053
SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 4.97939 + SgrRoot[0.5(81.426+46.1053)] = 0.618734
Printed: 2/2/2019
Page 1 18:56

Wa oint.®
Y ANALYTICAL
ff/�:7PIIyC:
Synagro Central LLC/ Statesville
Mary Brewer
284 Boger Road
Mocksville, NC, 27028
Ref: Analytical Testing
Report Number: 18-305-0204
Project Description: Statesville 4th Creek
7621 Whitepine Road, Richmond, VA 23237
Main 804-743.9401 °Fax [phone]
www.way pointe nalytica Isom
Dear Mary Brewer:
Waypoint Analytical Virginia, Inc. received samples) on 11/1/2018 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures pertormed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were pertormed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Arizona AZO6Z9 New Jersey VA011 Pennsylvania 68-03109 Virginia 460014
Florida E871087 North Carolina 257 South Carolina 93007
t
Page 1 of 8

Waypoi nt..� 7621 Whitepine Road, Richmond, VA 23237
Main 804-743.9401 °Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 18-305-0204
Client Project Description: Statesville 4th Creek
Lab No Client Sample ID
Matrix Date Collected Date Received Method Lab ID
63377
Statesville
4th
Creek
Solids
10/31/2018
10:15
WiN
11/01/2018
63377
Statesville
4th
Creek
Solids
10/31/2018
10:Y5
11/01/2016
63377
Statesville
4th
Creek
Solids
10/31/2018
10:15
11/01/2018
63377
Statesville
4th
Creek
Solids
10/31/2018
10:15
11/01/2018
63377
Statesville
4th
Creek
Solids
10/31/2018
10:15
11/OiJ2018
63377
Statesville
4th
Creek
Solids
10/31/2019
10:15
11/01/2018
63377
Statesville
4th
Creek
Solids
10/31/2018
10:15
11/01/2018
63377
Statesville
4th
Creek
Solids
10/31/2018
10:15
11/01/2018
WiN: Waypoint Analytical -TN, Memphis, TN, Certification: #1354
Page 2 of 6
SM�600-NH3C
WTN
9045D
WiN
4500NO3F 2011
WiN
6010D
WiN
SW -7471B
W1N
SM-4500-NH3C TKN
WiN
SM -2540G
WiN

Report Number. 18-305-0204
Account Number: 46493a 7621 Whitepme Road, Richmond, VA 23237
Waypoi hyT Main 804-743-94010 FaK 804-271-6446
ANALYTICAL www.waypolnwnalytical.com
Send To: Synagm Central LLC/ Statesville Project : Statesville 4th Creek
Mary Brewer
284 Boger Road
Mocksville, NC 27028
REPORT OF ANALYSIS Date Sampled: 10/31/201810:15:00
Lab Number: 63377 Date Received: 11/01/2018 00:00
Sample Id : Statesville 4th Creek Date Reported: 11/09/2018
RESULT RESULT QUANTITATION LIMIT ANALYSIS
PARAMETER (%) (mbdkq) (pmlm*) ANALYST DATETIME METHOD
Total Solids13.40 134000 100.0 CJR 11/06/201815:22 SM -2540G
Moisture' 86.60 100.0 CJR 11/06/201815:22 SM-254OG
Total Kjeldahl Nitrogen 5.49 54900 250 CLP 11/08/201814:00 SM-4500-NH3C-TKN
Phosphorus 2.42 24200 50.0 BKN 11/07/201820:27 6010D
Potassium 0.35 3530 50.0 BKN 11/07/20182027 6010D
Sulfur 0.67 6700 50.0 BKN 11/07/201820:27 6010D
Calcium 0.67 6690 250 BKN 11/07/201820:27 6010D
Magnesium 0.26 2560 50.0 BKN 11/07/201820:27 6010D
Sodium 0.06 600 250 BKN 11/07/201820:27 6010D
Iron 21800 50.0 BKN 11/07/201820:27 6010D
Aluminum 29000 50.0 BKN 11/07/201820:27 6010D
Manganese 739 5.00 BKN 11/07/201820:27 6010D
Copper 245 2.50 BKN 11/07/201820:27 6010D
Zinc 602 5.00 BKN 11/07/201820:27 60100
Ammonia Nitrogen 0.13 1340 100 ZBD 11/06/201813:00 SM-4500-NH3C
Organic N 5.36 53560 250 11/06/2018 13:00 CALCULATION
Nitrate+Nitrite-N <4.78 4.78 ZBD 11/07/201811:07 4500NO3F-2011
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
B -Analyte detected in blank H - Beyond Holding Time P4« 1"� GPANy
rrevon: ararercers arepo,me exerroree and conrdemrarose of Our ouer,m..and mer eor ne venrodrreeam wnmeraven. earmavanv rere,an�na mace PaOric McGroary
ro me vrox. nre mswre, orthe . eomvanv ra any ndremerng.eew: rereeae.ovother public a�eeeneenreeis wunow onrarerr,y our prior written epunodz
arme. Agronomist
Page 3 of 6

Report Number: 18-305-0204
Account Number: 46493
Send To: Synagrc Central LLCI Statesvllle
Mary Brewer
284 Boger Road
Mocksville, NC 27028
Lah Number: 63377
Sample Id : Statesville 4th Creek
Chromium
Nickel
Lead
Arsenic
Mercury
Selenium
pH*
Molybdenum
Comments:
Waypoint_®
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-94010 Fax [phone]
www.waypointanalydcal.com
Project :Statesvllle 4th Creek
REPORTOFANALYSIS OateSampled:10/31/201810:15:00
Date Received: 11/01/2018 00:00
Data Reported; 11/09/2018
2.17
1.00
BKN
11/07/201820:27
60101)
38.2
2.50
BKN
11/07/201820:27
60101)
27.4
2.50
BKN
11/07/201820:27
6010D
23.3
3.00
BKN
11/07/201820:27
60101)
<5.00
5.00
BKN
11/07/201820:27
6010D
0.572
0.0157
KKM
11/06/201812:38
SW -74718
<5.00
5.00
BKN
11/07/201820:27
6010D
5.6
SAJ
11/07/201807:28
9045D
8.19
2.50
BKN
11/07/201820:27
6010D
All
Our repodsond lepers ere /or Ik,vexeluslve and cnnfidendel useurvurvllenis. entl may no[ba reproduced In whold erped, rrormayary rererenee he made
values are on a dry weight basis except as noted by asterisk.
Detection limit on all N series is
on a wet basis.
B -Analyte
detected in blank H -Beyond Holding Time
Ip IAe Work. the results,m (he company in any advedisln9. news,elease.'or'vfllerputilic announcemenlsWilhoul otilaining ourprior wdffen avlhorizaiien.
Page 4 of 6
Pauric McGroary
Agronomist

Waypoint,.®
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax 804-271-fi446
www.way points n alyHca Isom
Cooler Receipt Form
Customer Number: 46493
Customer Name: Synagro Central LLCI Statesville
Report Number: 18-305-0204
Shipping Method
Fed Ex � US Postal (� Lab (� Other
UPS � Client � Courier Thermometer ID:
Shipping container/cooler uncompromised? � Yes � No
Number of coolers received
Custody seals intact on shipping container/cooler? � Yes � No � Not Required
Custody seals intact on sample bottles? � Yes � No � Not Required
Chain of Custody (COC) present? � Yes � No
COC agrees with sample label(s)? � Yes � No
COC praperlycompleted � Yes � Na
Samples in proper containers? � Yes � No
Sample containers intact? � Yes. � No
Sufficient sample volume for indicated test(s)? � Yes � No
All samples received within holding time? � Yes � No
Ccoler temperature in compliance? � Yes � No
Cooler/Samples arrived at the laboratory on ice. � Yes � No
Samples were considered acceptable as cooling
process had begun.
Water -Sample containers properly preserved � Yes � No � N/A
Water - VOAvials free of headspace � Yes � No � N/A
Trip Blanks received with VOAs � Yes � No � N/A
Soil VOA method 5035 —compliance criteria met � Yes � No � N/A
High concentration container (48 hr) � Low concentration Encore samplers (48 hr)
� High concentration pre -weighed (methanol -14 d) � Low cone pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? � Yes � No
Comments:
Signature: Brandi Watson Date&Time: 11/01/201813:58:10
Page 5 of 6

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Sodium Absorption Ratio Calculation (SAR)
Product Code
Product Name
Sample Date
Report Range
Ratio
2084-01-CAK-NC
STATESVILLE,
NC
FOURTH
CREEK
CAKE
10/31/2018
/ / - 1 1
0.5770
Na mg/I = (Na mg/kg x %Solids) - 100 = (600 x 13.4000) = 100 = 80.4
Ca mg/i = (Ca mg/kg x %Solids) _ 100 = (6690 x 13.4000) - 100 = 896.46
Mg mg/I = (mg mg/kg x %Solids) _ 100 = (2560 x 13.4000) + 100 = 343.04
Na meq = Na mg/I = Molec.Wgt.Na = 80.4 - 23 = 3.49565
Ca meq = Ca mg/I + MolecWgt.Ca = 896.46 = 20 = 44.823
Mg meq = Mg mg/I + Molec.Wgt.Mg = 343.04 _ 12 = 28.5867
SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 3.49565 : SgrRoot[0.5(44.823+28.5867)] = 0.576988
Printed: 2/2!2019
Page 1 18:56

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W�� /NOI �� 7621 Whitepine Road, Richmond, VA 23237
Y N Main 804-743-9401 °Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 18-060-9205
Client Project Description: Statesville 3rd Creek
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
58888
Statesville
3rd
creek
Solids
02/28/2018
08:00
03/01/2018
59888
Statesville
3rd
creek
Solids
02/28/2018
08:00
03/01/2018
7471A
WiN
WTN: Waypoint Analytical -TN, Memphis, TN, Certification: #1354
Page 1 of 4

Report Numher: 18-060-9205
Account Number: 46493
Send To: Synagro Central LLC/ Statesville
Mary Brewer
284 Boger Road
Mocksville, NC 27028
Lap Numher : 58888
Sample Id : Statesville 3rd creek
Waypoint.
ANALYTICAL
7621 Whitepine Read, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypoimanalytical.com
Project: Statesville 3rd Creek
REPORT OFANALYSIS Dace samples: 2/za/2o16 oa:oo:oo
Date Received: 03/01/2018 00:00
Date Reported: 05/29/2018
Total solids *
All values are on a dry weight basis except as
13.63
136300
100.0
JM
03/01/201815:00
SM -2540G
Moisture*
86.36
100.0
JM
03/01/201815:00
SM -2540G
Total Kjeldahl Nitrogen
5.14
51400
50.0
JM
03/02/2018
08:30
SM-4500-NH3C-TKN
Phosphorus
1.92
19200
100
SMC
03/06/201814:41
6010D
Potassium
0.39
3880
100
SMC
03/07/201814:12
6010D
Sulfur
0.89
8850
100
SMC
03/06/201814:41
6010D
Calcium
1.56
15600
100
SMC
03/06/201814:41
6010D
Magnesium
0.37
3720
100
SMC
03/06/201814:41
6010D
Sodium
0.12
1190
100
SMC
03/06/201814:41
6010D
Iron
16200
100
SMC
03/06/201814:41
6010D
Aluminum
11700
100
SMC
03/06/201814:41
6010D
Manganese
508
5.00
SMC
03/06/201814:41
6010D
Copper
279
5.00
SMC
03/06/201814:41
6010D
Zinc
938
5:00
5MC
03/06/201814:41
6010D
Ammonia Nitrogen
0.35
3450
50.0
JM
03/02/201808:30
SM-4500-NH3C
Organic N
4.79
47950
50.0
03/02/2018
08:30
CALCULATION
Nitrate+Nitrite-N
201
2.26
MMT
03/06/201811:51
4500NO3F-2011
noted by asterisk. Detection limit on all N series is on a wet basis.
Pte«
One'iepons and letters are lo,the exclusive and confidential use of vurrlienh, and mayno(be reproduced in whole or pad, nor may any reloaded be made
fettle work, the nesulfs, or the company in any adva tfunD. news release, or other pandit ammuncements wifM1oN obtalninD ourpdor mil(an aufhanefidn,
Pauric McGroary
Agronomist
Page 2 of 4

Report Number: 18-060-9205
Account Number: 46493
Send To: Synagro Cential LLC/ Statesville
Mary Brewer
284 Boger Road
Mocksvllle, NO 27028
Lab Numher : 58688
Sample Id : Statesville 3rd creek
Waypoint.®
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Maln 804-743-94010 Fax [phone]
www,waypointanalytical.com
Project:
Statesville 3rd Creek
REPORT OFANALYSIS Date Sampled: z/z6/zo1696:o9:06
Date Received: 03/01/2018 00:00
Date Reported: 05/29/2018
Cadmium
10.7
Chromium
97.0
Nickel
39.8
Total Lead
66.9
Arsenic
<3.00
Total Mercury
0.271
Selenium
<5.00
pH °
7.5
Molybdenum
16.0
Comments:
6010D
NC CERT#257
SMC
SULFUR AND ORGANIC NITROGEN
NOT FOR COMPLIANCE PURPOSES.
2.00
SMC
03/06/201814:41
60100
5.00
SMC
03/06/201814:41
60100
5.00
SMC
03/06/201814:41
6010D
5.00
SMC
03/06/201814:41
6010D
3.00
SMC
03/07/201814:12
60100
0.0133
KKM
03/06/201814:03
7471A
5.00
SMC
03/07/201814:12
601 OD
1:0
JM
03/02/201808:30
9045D
5.00
SMC
03/06/201814:41
6010D
All values are. on a dry weight basis except as noted by asterisk. Detection limit on all N series Is on a wet hasis.
clutch; are Imrlhmexcluaivm and confidential use orour clients, and nraynnl be re
pmtluced In whale mrpa,[, ndrmay airy 2hrencabe made
to the wok. the results, or tM1a rornpany in any adveNsing. newy�xlease, or pnrerpublla annorrnsanrents wMdut mbtalnln§ ourprimr wnnen aullrarTeetlon.
Page 3 of 4
Pauric McGroary
Agronomist

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Sodium Absorption Ratio Calculation (SAR)
Product Code
Product Name
Sample Date
Report Range
Ratio
2084-02-CAK-NC
STATESVILLE,
NC
THIRD
CREEK
CAKE
2/28/2018
3/1120184/30/2018
0.8182
Na mg/I = (Na mg/kg x %Solids) = 100 = (1190 x 13.6300) + 100 = 162.197
Ca mg/I = (Ca mg/kg x %Solids) _ 100 = (15600 x 13.6300) + 100 = 2126.28
Mg mg/I = (mg mg/kg x % Salids) _ 100 = (3720 x 13.6300) _ 100 = 507.036
Na meq = Na mg/I = Molec.Wgt.Na = 162.197 - 23 = 7.05204
Ca meq = Ca mg/I + Molec.Wgt.Ca = 2126.28 = 20 = 106.314
Mg meq = Mg mg/I + Molec.Wgt.Mg = 507.036 + 12 = 42.253
SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 7.05204 : SgrRoot[0.5(106.314+42.253)] = 0.818218
Printed: 2!2/2019
Page 1 18:56

�� �:
Waypoint_`�-- -��`y
ANALYTICAL
5/23/2018
Synagro Central LLC/ Statesville
Mary Brewer
284 Boger Road
Mocksville, NC, 27028
Ref: Analytical Testing
Report Number: 18-135-0207
Project Description: Statesville 3rd Creek
7621 Whitepine Road, Richmond, VA 23237
Main R04-743-9401 °Fax ItD4-271-6446
www.waypointanalytica I.co m
Dear Mary Brewer:
Waypoint Analytical Virginia, Inc. received samples) on 5/15/2018 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures pertormed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
P N` �
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Arizona AZ06Z9 New Jersey VA011 Pennsylvania 68-03109 Virginia 460014
Florida E871087 North Carolina 257 South Carolina 93007
,`
Page 1 of 9

Wa oint_�
Y ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804743-9401 °Fax [phone]
www.way p olnta nalyti ca Lcom
Client: Synagro Central LLC/ Statesville CASE NARRATIVE
Project: Statesville 3rd Creek
Lab Report Number: 18-135-0207
Date: 5/23/2018
Nitrate +Nitrite Nitrogen Method SM-4500NO3F
Sample 60698
Analyte: NO3+NO2-N
QC Batch No: E64084
The MS/MSD recoveries are considered insignificant due to the level of analyte present in the parent sample
relative to the spike level .RPD is based on the MS/MSD results and should be evaluated as laboratory
duplicates.
Metals Analysis Method SW -601 OCM
Sample 60697
Analyte: AI
OC Batch No: L382487
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interterence is suspected.
QC Batch No: L382642
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interterence is suspected.
Analyte: As
QC Batch No: L382487
MS/MSD Recovery failed, PDS confirmed matrix interterence
QG Batch No: L382642
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike v�ithin
method limits. No matrix interterence is suspected.
Analyte: Ca
ClC Batch No: L382487
MS/MSD Recovery failed,
DT confirmed matdx interterence
QC Batch No: L382642
MS/MSD Recovery failed,
DT confirmed matrix interference
Analyte: Cd
QC Batch No: L382487
MS/MSD Recovery failed,
DT confirmed matrix interference
Analyte: Cr
QC Batch Na: L382487
MS/MSD Recovery failed,
DT confirmed matrix interference
Analyte: Cu
QC Batch No: L382487
Page 2 of 9

Wa point�®
Y -ANALYTICAL
MS/MSD Recovery failed, DT confirmed matrix interference
Analyte: Fe
QG Batch No: L382487
MS/MSD Recovery failed, DT confirmed matrix interterence
7621 Whitepine Road, Richmond, VA 23237
Main 804-743.9401 ° Faz 804-271-6446
www.waypo into na lydca Isom
QC Batch No: L382642
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interference is suspected.
Analyte: K
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed matrix interference
QC Batch No: L382642
MS/MSD Recovery failed, DT confirmed matrix interference
Analyte: Mg
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed matrix interference
QC Batch No: L382642
MS/MSD Recovery failed, DT confirmed matrix interference
Analyte: Mn
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed matrix interference
Analyte: Mo
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed matrix interference
Analyte: Na
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed matrix interterence
QC Batch No: L382642
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test exceeded method
limits. Matrix interference is suspected.
Analyte: Ni
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed matrix interference
Analyte: P
QC Batoh No: L382487
MS/MSD Recovery failed., DT confirmed matrix interference
QC Batch No: L382642
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interference is suspected.
Analyte: Pb
Page 3 of 9

Wa oint_®
Y ANALYTICAL
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed matrix interterence
Analyte: S
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed matrix interference
QC Batch No: L382642
MS/MSD Recovery failed, DT confirmed matrix interference
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
Analyte: Se
QG Batch No: L382487
MS/MSD Recovery failed, PDS confirmed matrix interterence
www.wayp of nta nalyti ca l.com
QC Batch No: L3$2642
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within
method limits. No matrix interference is suspected.
Analyte: Zn
QC Batch No: L382487
MS/MSD Recovery failed, DT confirmed matrix interference
QC Batch No: L382642
MS/MSD Recovery failed, DT confirmed matrix interference
Solids Total Mercury Analysis - CVAA Method SW -74716
Sample 60698
Analyte: Hg
QC Batch No: E64133
MS/MSD Recovery failed, PDS confirmed matrix interference
Page 4 of 9

Waypoi nt . 7621 Whitepine Road, Richmond, VA 23237
Main 804-743-94D1 °Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 18-135-0207
Client Project Description: Statesville 3rd Creek
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
60700
Statesville
3rd
Creek
Solids
05/10/2018
14:15
05/15/2018
60700
Statesville
3rd
Creek
Solids
05/10/2018
14:
i5
05/15/2018
6010C
WTN
WiN: Waypoint Analytical - TN, Memphis, TN, Certifcation: #1354
Page 5 of 9

Report Number. 18-135-0207
Account Number: 46493 s 7621 Whitepine Road, Richmond, VA 23237
WMa yp®I h Main 804743-9401 ° Fax [phone]
ANALYTICAL www.waypclntanalydcal.com
Send To: Synagm Central LLC/ Statesville Project: Statesville 3rd Creek
Mary Brewer
284 Boger Road
Moeksville, NC 27028
Total Solids * 13.00 130000 100.0 R D 05/15/201815:00 SM-254UG
Moisture * 86.99 100:0 R D OSI15I2018 15:00 SM -2540G
Total Kjeldahl Nitrogen 5.30 53000 50.0 JM 05/16/2018 08:30 SM-0500-NH3C-TKN
Phosphorus 2.65 26500 50.0 KKM 05/21/201820:52 6010C
Potassium 0.86 8570 500 KKM 05/21/201820:57 6010C
Sulfur 0.61 6090 5.00 KKM 05/19/201 B 06:49 6010C
Calcium 0.82 8240 SAO KKM 05/19/201806:49 6010C
Magnesium 0.35 3520 5.00 KKM 05/19/2018 06:49 6010C
Sodium 0.08 753 25.0 KKM 05/19/201806:49 6010C
Iron 16400 50.0 KKM 05/21/201820:52 6010C
Aluminum 19300 50.0 KKM 05/21/201820:52 6010C
Manganese 1380 5.00 KKM 05/21/201820:52 6010C
Copper 206 0.250 KKM 05/19/201806:49 6010C
Zinc 446 0.500 KKM 05/19/201606:49 6010C
Ammonia Nitrogen 0.58 5760 50.0 JM 05/16/2018 08:20 SMA500-NH3C
Organic N 4.72 47240 50.0 05/16/2018 08:20 CALCULATION
Nitrate+Nitrite-N 226 2.45 MMT 05/17/201809:46 4500NO3F-2011
All values are on a dry weight basis except as noted by asterisk. Detection limit an all N seder is on a wet basis.
Ovrrepor}a antllaHors are for the tentative and nonlibenfiel uae of are clients, and nraynpr be rapmbuced in wlrolo orpari, normay any rabsence be rrratle
to the calk. fier results, or th company In any adverdauer, news releaseor'other public announcenrenls vlehoul pbtelnlnp our prior hintlen aulhorl a Ion.
Pauric McGroary
Agronomist
Page 6 of 9
REPORT OF ANALYSIS Date Sampled:5/10/201814:15:00
Lab Number:
60700
Date Received:
05/15/2018 00:00
Sample Id:
Statesville 3rd Creek
Date Reported:
05/23/2018
Total Solids * 13.00 130000 100.0 R D 05/15/201815:00 SM-254UG
Moisture * 86.99 100:0 R D OSI15I2018 15:00 SM -2540G
Total Kjeldahl Nitrogen 5.30 53000 50.0 JM 05/16/2018 08:30 SM-0500-NH3C-TKN
Phosphorus 2.65 26500 50.0 KKM 05/21/201820:52 6010C
Potassium 0.86 8570 500 KKM 05/21/201820:57 6010C
Sulfur 0.61 6090 5.00 KKM 05/19/201 B 06:49 6010C
Calcium 0.82 8240 SAO KKM 05/19/201806:49 6010C
Magnesium 0.35 3520 5.00 KKM 05/19/2018 06:49 6010C
Sodium 0.08 753 25.0 KKM 05/19/201806:49 6010C
Iron 16400 50.0 KKM 05/21/201820:52 6010C
Aluminum 19300 50.0 KKM 05/21/201820:52 6010C
Manganese 1380 5.00 KKM 05/21/201820:52 6010C
Copper 206 0.250 KKM 05/19/201806:49 6010C
Zinc 446 0.500 KKM 05/19/201606:49 6010C
Ammonia Nitrogen 0.58 5760 50.0 JM 05/16/2018 08:20 SMA500-NH3C
Organic N 4.72 47240 50.0 05/16/2018 08:20 CALCULATION
Nitrate+Nitrite-N 226 2.45 MMT 05/17/201809:46 4500NO3F-2011
All values are on a dry weight basis except as noted by asterisk. Detection limit an all N seder is on a wet basis.
Ovrrepor}a antllaHors are for the tentative and nonlibenfiel uae of are clients, and nraynpr be rapmbuced in wlrolo orpari, normay any rabsence be rrratle
to the calk. fier results, or th company In any adverdauer, news releaseor'other public announcenrenls vlehoul pbtelnlnp our prior hintlen aulhorl a Ion.
Pauric McGroary
Agronomist
Page 6 of 9

Report Numher: 18-135-0207
Account Number: 46493
Send To: Synagro Central LLC/ Statesville
Mary Brewer
284 Boger Road
Mocksville, NO 27028
Lab Number: 60700
Sample Id : Statesville 3rd Creek
VVaypoint..®
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalydcal.com
Project :Statesville 3rd Creek
REPORT OF ANALYSIS Date Sampled: 5/10/201814:16:00
Date Received: 05/15/201 8 0 0:00
Date Reported: 05/23/2018
Cadmium
1.77
Chromium
20.1
Nickel
16.6
Total Lead
14.4
Arsenio
3.99
Total Mercury
0.497
Selenium
2.90
pH'
6.6
Molybdenum
7.26
Comments:
6010C
NO CERT#257
SMC
SULFURAND ORGANIC NITROGEN
NOT FOR COMPLIANCE PURPOSES.
0.100
KKM
05/19/2018 06:49
6010C
0.250
KKM
05/19/201806:49
6010C
0.250
KKM
05/19/201806:49
6010C
9.300
KKM
05/19/201806:49
6010C
1,00
KKM
05/19/201806:49
6010C
0.400
SMC
05/21/201814:37
SW -7471B
0.500
KKM
05/19/2018 06:49
6010C
1.0
JM
0 511 6/2 01 8 08:20
9045D
0.250
KKM
05/19/201806:49
6010C
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our reporissnd tellers ore tar fhe exclusiveantl confitlenfial use olwrcllarrta, and may not be reprotlucetlin whale orpart, bar may
any roforenea be made
b Iha wodr. the results, orthe mmpany many advertising, news rsleose: orolhe/Fu61ic annpuncamenh witM1ouf obfalniny ourphor written au(horlrarton.
Page T of 9
Pauric McGroary
Agronomist

Waypointm®
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypointa nalyHcal. com
Cooler Receipt Form
Customer Number: 46493
Customer Name: Synagro Central LLC/ Statesville
Report Number: 18-135-0267
Shipping Method
Q Fed Ex � US Postal � Lab � Other : �—
UPS 0 Client � Courier Thermometer ID:
Shipping container/cooler uncompromised? � Yes � No
Number of coolers received � 1
Custody seals intact on shipping container/cooler? � Yes � No � Not Required
Custody seals intact on sample. bottles? 0 Yes � No � Not Required
Chain of Custody (COC) present? � Yes � No
COC agrees with sample label(s)? � Yes � No
COC properly completed � Yes �} No
Samples in proper containers? � Yes � No
Sample containers intact? � Yes (� No
Sufficient sample volume for indicated test(s)7 � Yes � No
All samples received within holding time? � Yes � No
Cooler temperature in compliance? � Yes � No
Cooler/Samples arrived at the laboratory on ice. � Yes � No
Samples were considered acceptable as cooling
process had begun.
Water -Sample containers properly preserved � Yes � No � N/A
Water - VOAvials free of headspace � Yes. � No � N/A
Trip Blanks received with VOAs O Yes � No � N/A
Soil VOA method 5035 –compliance criteria met � Yes � No � N/A
� High concentration container (48 hr) � Low concentration Encore samplers (48 hr)
� High concentration pre -weighed (methanol -14 d) � Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes � No
Comments:
Signature: Brandi Watson Date &Time: 5/15/2018 13:44:52

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Sodium Absorption Ratio Calculation (SAR)
Product Code
Product Name
Sample Date
Report Range
Ratio
2084-02-CAK-NC
STATESVILLE,
NC
THIRD
CREEK
CAKE
5/10/2018
5/1/2018-6/30/2018
0.6286
Na mg/I = (Na mg/kg x %Solids) + 100 = (753 x 13.0000) + 100 = 97.89
Ca mg/I = (Ca mg/kg x %Solids) + 100 = (8240 x 13.0000) = 100 = 1071.2
Mg mg/I = (mg mg/kg x %Solids) = 100 = (3520 x 13.0000) _ 100 = 457.6
Na meq = Na mg/I = Molec.Wgt.Na = 97.89 _ 23 = 4.25609
Ca meq = Ca mg/I + Molec.Wgt.Ca = 1071.2 : 20 = 53.56
Mg meq = Mg mg/I + Molec.Wgt.Mg = 457.6 _ 12 = 38.1333
SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 4.25609 = SgrRoot[0.5(53.56+38.1333)] = 0.628574
Printed: 2!2/2019
Page 1 18:56

Waypoint.
ANALYTICAL
7/11 /2018
Synagro Central LLC/ Statesville
Mary Brewer
284 Boger Road
Mocksville, NC, 27028
Ref: Analytical Testing
Report Number: 18-184-0203
Project Description: Statesville 3rd Creek
7621 Whitepine Road, Richmond, VA 23237
Main 804-743.9401 °Fax [phone]
www.way pointana lytics I. com
Dear Mary Brewer:
Waypoint Analytical Virginia, Inc. received samples) on 7/3/2018 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were pertormed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise Indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time. for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
pa°car
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Arizona AZ0629 New Jersey VA011 Pennsylvania 68-03109 Virginia 460014
Florida E871087 North Carolina 257 South Carolina 93007
�•_
Page 1 of 8

• !�'�°r
Waypoint � .
ANALYTICAL
Client: Synagro Central LLC/ Statesville
Project: Statesville 3rd Creek
Lab Report Number: 18-184-0203
Date: 7111 /2018
7621 Whttepine Road, Richmond, VA 23237
Main 804.743-9401 °Fax [phone]
www.waypol ntana lytical.com
CASE NARRATIVE
TKN (Titration) Method SM-4500-NH3C-TKN
Analyte: TKN
QC Batch No: E64890
Analyte was flagged for 0 % recovery in the LCS and/or LCSD due to the result being below the MQL. The actual
result was
XXJ which calculates to a recovery of XX%.
Analyte was flagged for 0 % recovery in the LCS and/or LCSD .The actual result was
0.870 which calculates to a recovery of 85%.
OC Batch No: E64890
The MS/MSD recoveries are considered insignificant due to the level of analyte present in the parent sample
relative to the spike level .RPD is based on the MS/MSD results and should be evaluated as laboratory
duplicates.
Nitrate +Nitrite Nitrogen Method SM-4500NO3F
Sample 61491
Analyte: NO3+NO2-N
ClC Batch No: E64942
The MS/MSD recoveries are considered insignificant due to the level of analyte present in the parent sample
relative to the spike level .RPD is based on the MS/MSD results and should be evaluated as laboratory
duplicates..
Metals Analysis Method SW -6010C
Sample 61489
Analyte: AI
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration >25X the MOL. Dilution test within method limits.
No matrix interference is suspected.
Analyte: As
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within
method limits. No matrix interterence is suspected.
Analyte: Fe
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration >25X the MOL. Dilution test within method limits.
No matrix interference is suspected.
Analyte: K
OC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interterence is suspected.

Wa oint
Y -ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main Soo -743-9401 °Fax [phone]
www.waypointanalytica l.com
Analyte: Mg
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interference is suspected.
Analyte: Mn
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interference is suspected.
Analyte: Mo
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within
method limits. No matrix interference is suspected.
Analyte: Pb
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within
method limits. No matrix interference is suspected.
Analyte: Se
C1C Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within
method limits. No matrix interference is suspected.
Solids Total Mercury Analysis - CVAA Method SW -74716
Sample 61491
Analyte: Hg
QC Batch No: E64928
MS/MSD Recovery failed, PDS confirmed matrix interference
Page 3 of 8

Waypoi nt.., 7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 18-154-0203
Client Project Description: Statesville 3rd Creek
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
61494
Statesville
3rd
Creek
Solids
07/02/2018
08:30
07/03/2018
61494
Statesville
3rd
Creek
Solids
07/02/2018
08:30
07/03/2018
6010D
WTN
WiN: Waypoint Analytical - TN, Memphis, TN, Certifcation: #1354
Page 4 of B

Report Numher: 18-184-0203
Account Number: 46493
Send To: Synagro Central LLC/ Statesville
Mary Brewer
284 Boger Road
Mocksvllle. NO 27028
Lab Number; 61494
Sample Id : Statesville 3rd Creek
Waypoint-®
ANALYTICAL
7621 Whitepine Road, flichmond, VA 23237
Main 804-743-94010 Fax [phone]
www.waypointanaWNca Lcom
Project:5[atesville 3rd Creek
REPORT OF ANALYSIS Date Sampled:?/2/201808:30:00
Date Received: 07/03/2018 00:00
Dale Reported: 07/11/2018
Total Solids `
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
mp APA
15.23
152300
100.0
JM
0 710 3/2 01 8 15:30
SM -2540G
Moisture
84.76
100.0
JM
07/03/201815;30
SM -2540G
Total Kjeldahl Nitrogen
5.60
56000
50.0
RD
07/05/2018 09:00
SM-4500-NH3C-TKN
Phosphorus
2.36
23600
50.0
KKM
07/10/201801:18
6010D
Potassium
0.48
4820
50.0
JTR
07/10/2018 01:18
6010D
Sulfur
0.98
9800
50.0
KKM
07/10/2018 01:18
6010D
Calcium
3.13
31300
50.0
KKM
07/10/2018 01:18
6010D
Magnesium
0.34
3440
50.0
KKM
07/10/201 B 01:18
6010D
Sodium
0.11
1120
250
JTR
07/10/201801:18
6010D
Iron
19800
50.0
KKM
07/10/201801:18
6010D
Aluminum
15100
50.0
KKM
07/10/201801:18
6010D
Manganese
949
5.00
KKM
07/10/201801:18
6010D
Copper
320
2.50
KKM
07/10/2018 01:18
6010D
Zinc
994
5.00
KKM
07/10/201801:18
6010D
Ammonia Nitrogen
1.40
14000
50.0
R 0
07/05/2018 09:00
SM-4500-NH3C
Organic
4.20
42000
50.0
07/05/201809:00
CALCULATION
Mtrale+Nitrite-N
301
2.38
MMT
07/09/201811:22
4500NO3F-2011
a'mports and letters ere ror We emluslw are wnitlenllol usoolour ellenls, and may nal be repmducadln whole orpen, nor rnayany l»rarenoe be made
Pte« N�
to the workthe results, or the company In anyadvenlsirhp, news release. or other public wonourbeweale wllhoutoblalnin9 ourprlor wdffen euthorirellon.
Paurlc McGroary
Agronomist
Page 5 of 8

Report Number; 18-184-0203
Account Number: 46493
Send To; Synagro Central LLC/ Statesville
Mary Brewer
284 Boger Road
Mocksville, NO 27028
Lab Number:
61494
Chromium
88.0
Sample Id :
Statesville
3rd
Creek
Waypomt,.
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743,9401 a Fax [phone]
www,waypointanaiydcal.com
Project: Statesville 3rd Creek
REPORTOFANALYSIS Date Sampled: 7/2/202018:30:00
Date Received: 07/03/2018 OOAO
Date Reported: 07/11/2018
Cadmium
10.2
Chromium
88.0
Nickel
38.9
Lead
58.5
Arsenic
<5.00
Mercury
0.420
Selenium
<5.00
pH'
8.6
Molybdenum
16.8
Comments:
6010D
NC CERT4257
KKM
SULFUR AND ORGANIC
NITROGEN NOT FOR COMPLIANCE PURPOSES.
1.00
KKM
07/10/2018 01:18
6010D
2.50
KKM
07/1012018 01:18
6010D
2.50
KKM
07/10/2018 01:18
6010D
3.00
KKM
07/10/201801:18
6010D
5.00
KKM
07/11/201801:16
6010D
0.400
SMC
07/06/201814:18
SW -74718
5.00
KKM
07/11/201801:16
6010D
1.0
R D
07/05/2018 09A0
9045D
2.50
KKM
07/10/2018 01:18
6010D
All values anon a dry weight basis except as noted by asterisk. Detection Ilmit on all N series is on a wet basis.
labors are he me exandra ami annneamlal ass nron; nGama, and may not be rnpmdnoae n, whole or pail, nor may any rerrenae be
and
maga
Ou`^rep oM1s eesulte,orlM1e compenyfn any edverilslnBneweisleasa. orotnerpuWfe announwmenis whM1ouloMefnln9 oLrp�or written eulhorliaWn.
Page 6 of 8
Pauric McGroary
Agronomist

Waypoint..®
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax 804-271-fi446
www.waypointa n alyHca I. com
Cooler Receipt Form
Customer Number: 46493
Customer Name: Synagro Central LLC/ Statesville
Report Number: 18-184-0203
Shipping Method
0 Fed Ex � US Postal a Lab (� Other : �—
UPS � Client � Courier Thermometer ID:
Shipping container/cooler uncompromised? � Yes 0 No
Number of coolers received I '
Custody seals intact on shipping container/cooler? � Yes � No � Not Required
Custody seals intact on sample bottles? � Yes � No � Not Required
Chain of Custody (COC) present? � Yes 0 No
COC agrees with sample label(s)? � Yes 0 No
COC properly completed � Yes � No
Samples in proper containers? � Yes � No
Sample containers intact? � Yes Q No
Sufficient sample volume for indicated test(s)? � Yes � No
All samples received within holding time? � Yes � No
Cooler temperature in compliance? � Yes � No
Cooler/Samples arrived at the laboratory on ice. � Yes a No
Samples were consideretl acceptable as cooling
process had begun.
Water -Sample containers properly preserved � Yes � No � N/A
Water -VOA vials free of headspace � Yes � No � N/A
Trip Blanks received with VOAs � Yes � No � N/A
Soil VOA method 5035 –compliance criteria met � Yes � No � N/A
� High concentration container (48 hr) � Low concentration Encore samplers (48 hr)
� High concentration pre -weighed (methanol -14 d) � Low concyre-weighed vials (Sod Bis -14 d)
Special precautions or instructions included? (� Yes � No
Comments:
Signature: Brandi Watson Date &Time: 7/03/2018 13:38:33
Page 7 of 8

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Sodium Absorption Ratio Calculation (SAR)
Product Code
Product Name
Sample Date
Report Range
Ratio
2084-02-CAK-NC
STATESVILLE,
NC
THIRD
CREEK CAKE
7/2/2018
1 / - 1 /
0.6246
Na mg/I = (Na mg/kg z %Solids) + 100 = (1120 x 15.2300) + 100 = 170.576
Ca mg/I = (Ca mg/kg x %Solids) = 100 = (31300 x 15.2300) + 100 = 4766.99
Mg mg/I = (mg mg/kg x %Solids) - 100 = (3440 x 15.2300) = 100 = 523.912
Na meq = Na mg/I = Molec.Wgt.Na = 170.576 + 23 = 7.41635
Ca meq = Ca mg/I + Molec.WgLCa = 4766.99 + 20 = 238.349
Mg meq = Mg mg/I + Molec.Wgt.Mg = 523.912 + 12 = 43.6593
SAR = Na meq _ SgrRoot[0.5 x (Ca meq + Mg meq)] = 7.41635 _ SgrRoot[0.5(238.349+43.6593)] = 0.624559
Printed: 2/2/2019
Page 1 18:57

Wa Dint �
Y -ANALYTICAL
11/9/2018
Synagro Central LLC/ Statesville.
Mary Brewer
284 Boger Road
Mocksville, NC, 27028
Ref: Analytical Testing
Report Number: 18-305-0203
Project Description: Statesville 3rd Creek
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypointa n aly6ca Isom
Dear Mary Brewer:
Waypoint Analytical Virginia, Inc. received samples) on 11/1/2018 for the analyses presented in the following
report.
The above referenced projedt has been analyzed per your instructions. The analyses were pertormed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were pertormed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any Feld parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise intlicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
p a�cewr
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Arizona AZ0629 New Jersey VA011 Pennsylvania 68-03109 Virginia 460014
Florida E871087 North Carolina 257 South Carolina 93007
'+_
Page 1 of 6

Wa O' �� ^® 7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
Y ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 18-305-0203
Client Project Description: Statesville 3rd Creek
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
63376
Statesville
3rd
Creek
Solids
10/31/2018
10:00
11/01/2018
63376
Statesville
3rd
Creek
Solids
10/31/2018
10:00
11/01/2018
SM-4500-NH3C
WiN
63376
Statesville
3rd
Creek
Solids
10/3Y/2018
10:00
11/Ol/2018
9046D
WiN
63376
Statesville
3rd
Creek
Solids
10/31/2018
10:00
11/01/2018
4600NO3F-2011
WiN
63376
Statesville
3rd
Creek
Solids
10/31/2018
10:00
11/01/2018
6030D
WTN
63376
Statesville
3rd
Creek
Solids
10/31/2018
10:00
11/01/2018
SW -74718
WFN
63376
Statesville
3rd
Creek
Solids
10/31/2018
10:00
11/01/2018
SM-4500-NH3C-TKN
WFN
63376
Statesville
3rd
Creek
Solids
10/31/2018
10:00
11/01/7018
SM -25406
WTN
WTN: Waypoint Analytical - TN, Memphis, TN, Certification: #1354
Page `L of G

Report Number: 18-305-0203
Account Number: 46493
Send Tc: Synagro Central LLC/ Statesville
Mary Brewer
2B4 Boger Road
Mocksvllle, NC 27028
Lab Number
: 63376
Sample Id :
Statesville
3rd
Creek
Waypoint.®
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-94010 Fax [phone]
tvvniv,witypointanalytical.com
Project :Statesville 3rd Creek
REPORT OF ANALYSIS Date Sampled: l0/31/201810:00:00
Date Received: 11/01/2018 00:00
Date Reported: 11/09/2018
Total Solids" 17.40 174000 100.0 CJR 11/06/201815:22 SM -2540G
Moisture82.60 100.0 CJR 11/06/2018 15:22 SM -2540G
Total Kjeldahl Nitrogen 4.72 47200 250 CLP 11/08/2018 14:00 SM-4500-NH3C-TKN
Phosphorus 1.80 18000 50.0 BKN 11107/201820:22 6010D
Potassium 0.30 2980 50.0 BKN 11/07/201820:22 6010D
Sulfur 0.84 8420 50.0 BKN 11/07/201820:22 6010D
Calcium 1.24 12400 250 BKN 11/07/201820:22 6010D
Magnesium 0.28 2770 50.0 BKN 11/07/201820:22 6010D
Sodium 0.09 875 250 BKN 11/07/2018 20:22 6010D
Iron 22400 50.0 BKN 11/07/201820:22 6010D
Aluminum 15300 50.0 BKN 11107/201820:22 6010D
Manganese 683 5.00 BKN 11107/201820:22 6010D
Copper 338 2.50 BKN 11/07/201 B 20:22 6010D
Zinc 1040 5.00 BKN 11107/201820:22 6010D
Ammonia Nitrogen <0.01 <100 100 ZBD 11/06/201813:00 SM-4500-NH3C
Organic N 4.72 47200 250 11106/201813:00 CALCULATION
Nitrate+Nibite-N 174 4.24 ZBD 11/07/201811:07 4500NO3F-2011
All values are on a dryweight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. rnny1 �1
B -Analyte detected in blank H - Beyond Holding Time 1 G1t��° 1"p GP.ONy
rrapena and letters are for the a,nlasroe and ennedanral n:e oroar auanla, and may not be rep,od„aedm wnde organ, nor may any reference be made Paurlc McCreary
tothe wvd,. Ilie,esulis, or torten Ina
nyadveNalnp. newslalaase,or olherpubllc announcements without obta'ning ovrprior written a,nhorizatlon. Agfenefnl5t
Page
of 6

Report Number. 18-305-0203
Account Number. 46493
Sentl To: Synagro Central LLCI Statesville
Mary Brewer
284 Boger Road
Mocksville, INC 27028
Lab Numher : 63376
Sample Id : Statesville 3rd Creek
Cadmium
Chromium
Nickel
Lead
Arsenic
Mercury
Selenium
pH
Molybdenum
Comments:
waypo01
int.%7
ANALYTICAL
7621 Whitepine Road, Richmondr VA 23237
Main 804-743-9401 0 Fax [phone]
www,waypointanalytical.com
Project: Statesville 3rd Creek
REPORT OFANALYSIS Date
Sampled:
10/31/201810:00:00
11/07/Z01820:22
6010D
Date
Received:
11/01/2018
00:00
6010D
Date
Reported:
11/09/2018
11/07/201820:22
6010D
9.67
1.00
BKN
11/07/Z01820:22
6010D
101
2.50
BKN
11/07!201820:22
6010D
39.6
2.50
BKN
11/07/201820:22
6010D
79.2
3.00
BKN
11/07/201820:22
6010D
<5.00
5.00
BKN
11/07/201820:22
6010D
0.292
0.0151
KKM
11/06/201812:37
SW -7471B
<5.00
5.00
BKN
11/07/201820:22
6010D
3.6
SAJ
11/07/2018 07:28
9045D
20.3
2.50
BKN
11/07/201820:22
6010D
All
r reporle erW letters are for tl,e emlusive antl oon4denffalo(our allenfe, end may not be reprodunetlln whole orped, rarmay any m(ere
values are on a dry weight basis except as noted by asterisk.
Detection limit on all N series is on
a wet basis.
B -Analyte
detected in blank H -Beyond Holding 7lme
nCe be made
to the work. fire results, orlhe company in any ativeNsln9. neva rslease. orpfherpuhlic arrnouncamenl9 w4haui obtaining ourprior written authorization.
Page 4 of 6
I rata m° G�NX
Pauric McGroary
Agronomist

Waypoint..®
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Faz 804-271-6446
www.waypointa nalyti ca Lcom
Cooler Receipt Form
Customer Number: 46493
Customer Name: Synagro Central LLC/ Statesville
Report Number: 18-305.0203
Shipping Method
Fed Ex � US Postal � Lab � Other : ��
UPS � Client � Courier Thermometer ID:
Shipping container/cooler uncompromised? � Yes � No
Number of coolers received
Custody seals intact on shipping container/cooler? � Yes 0 No � Not Required
Custody seals intact on sample bottles? 0 Yes � No � Nof Required
Chain of Custody (COC) present? � Yes � No
COC agrees with sample label(s)? � Yes � No
COC properly completed � Yes (� No
Samples in proper containers? � Yes 0 No
Sample containers intact? � Yes � No
Sufficient sample volume for indicated test(s)? � Yes � No
All samples received within holding time? � Yes Q No
Cooler temperature in compliance? � Yes � No
Cooler/Samples arrived at the laboratory on ice. � Yes � No
Samples were considered acceptable as coaling
process had begun.
Water- Sample containers properly preserved � Yes 0 No � N/A
Water- VOAvials free of headspace � Yes � No � N/A
Trip Blanks received with VOAs � Yes � No � N/A
Soil VOA method 5035 —compliance criteria met � Yes � No � N/A
High concentration container (48 hr) � Low concentration Encore samples (48 hr)
� High concentration pre -weighed (methanol -14 d) � Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? � Yes � No
Comments:
Signature: randi Watson Date &Time: 11/01/2018 13:55:55
Page 5 of 6

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Sodium Absorption Ratio Calculation (SAR)
Product Code
Product Name
Sample Date
Report
Range
Ratio
2084-02-CAK-NC
STATESVILLE,
NC
THIRD
CREEK
CAKE
10/31/2018
1 1 - 1
/
0.7694
Na mg/I = (Na mg/kg x %Solids) + 100 = (875 x 17.4000) = 100 = 152.25
Ca mg/I = (Ca mg/kg x %Solids) + 100 = (12400 x 17.4000) + 100 = 2157.6
Mg mg/I = (mg mg/kg z %Solids) + 100 = (2770 x 17.4000) + 100 = 481.98
Na meq = Na mg/I _ Molec.Wgt.Na = 152.25 + 23 = 6.61957
Ca meq = Ca mg/I _ Molec.Wgt.Ca = 2157.6 + 20 = 107.88
Mg meq = Mg mg/I _ Molec.Wgt.Mg = 481.98 + 12 = 40.165
SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 6.61957 + SgrRoot[0.5(107.88+40.165)] = 0.769392
Printed: 2/2/2019
Page 1 18:57

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Statesville, NC Total Dry Tons. Applied (Annual): 23.52:
Permit #: W00016247 Cation Exchange Capacity (non 503 only):
Operator: Danny Millsaps Owner: Arlene Millsaps Predominant Soil Series: Pacolet
Acres Used: 15.1 Acres Permitted: 15.1 Site #: NC AL 00013 Field #: AL 00013 OOOlA
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
1/4/17
2
3
4
5
6
7
8
9
10
11
12
Solids
13.96
a
s
10
11
12
Arsenic
3.34
Cadmium
13.2
H
Copper
327
Chromi
141
�
Lead
84.6
Mercury
0.4
m
Molyb-
denum
19.4
Nickel
53.3
��
Selenium
6.87
0.000
0.000
0.000
0.000
0.000
Zinc
1020
0.000
0.000
0.000
0.000
0.000
0.010
Total
Phos-
horns
16300
0.000
0.000
0.000
0.000
0.000
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3-
a
5
6
7
a
s
10
11
12
H
DT/Ac./
�
App.
m
Event
1.56
��
Arsenic
0.010
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.010
Cadmium
0.041
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.041
Copper
1.018
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.018
Chromi
0.439
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.439
Lead
0.263
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.263
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.060
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.060
denum
Nic]<el
0.166
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.166
Selenium
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.021
Zinc
3.176
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.176
Total
Phos-
50.758
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
50.758
horns
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualiSed personnel properly gathered and evaluated the information submitted.
I am aware that there are signiScant penalties for submitting false information, including the possibility of Tnes and
imprisonment for knowing violations".
Signature of Land Applier
Z Z l � l
Date
DENR FORM MFLSF (12/2D06)

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ANNUAL METALS F1ELD LOADING SUMMARX FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Statesville, NC Total Dry Tons Applied (Annual): 40.59
WQ0016247 Cation Exchange Capacity (non 503 only):
Dennis Phillips Owner: Dennis Phillips Predominant Soil Series: Appling
11.1 Acres Permitted: 11.1 Site #: NC IR 00020 Field #: IIi 00020 0001
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
7/2/18
2
3
4
5
5
7
8
9
10
11
12
Solids
13.24
8
9
10
11
12
Arsenic
5
Cadmium
2.26
y
Copper
259
Chromi
30
�
Lead
20.6
Mercury
0.762
Molyb-
denum
9
Nickel
25.8
��
Selenium
5
0.000
0.000
0.000
0.000
0.000
Zinc
591
0.000
0.000
0.000
0.000
0.000
0.037
Total
Phos-
horus
2$600
0.000
0.000
0.000
0.000
0.000
0.000
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
y
DT/Ac./
�
APP•
Event
3.66
��
Arsenic
0.037
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.037
Cadmium
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.017
Copper
1.894
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.894
Chromi
0.219
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.219
Lead
0.151
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.151
Mercury
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
Molyb-
0.066
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.066
denum
Nickel
0.189
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.189
Selenium
0.037
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.037
Zinc
4.323
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4.323
Total
Phos-
209.180
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
209.180
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of Snes and
imprisonment for Dowing violations".
Signature of Land Applier
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DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Statesville, NC Total Dry Tons Applied (Annual):
WQ0016247 Cation Exchange Capacity (non 503 only):
Dennis Phillips Owner: Dennis Phillips Predominant Soil Series:
11.5 Acres Permitted: 11.5 Site #: NC IR 00020 Field #: IR 00020 0002
38.58
Cecil
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
7/2/18
2
3
4
5
6
7
8
9
10
11
12
°f Solids
13.24
8
9
10
11
12
Arsenic
5
Cadmium
2.26
y
Copper
259
Chromi
30
�
Lead
20.6
Mercury
0.762
Molyb-
denum
9
Nickel
25.8
Selenium
5
0.000
0.000
0.000
0.000
0.000
Zinc
591
0.000
0.000
0.000
0.000
0.000
0.034
Total
Phos-
horns
28600
0.000
0.000
0.000
0.000
0.000
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
y
DT/AC./
�
App.
Event
3.35
Arsenic
0.034
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.034
Cadmium
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
Copper
1.737
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.737
Chromi
0.201
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.201
Lead
0.138
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.138
Mercury
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Molyb-
0.060
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.060
denum
Nickel
0.173
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.173
Selenium
0.034
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.034
Zinc
3.954
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.964
Total
Phos-
191.849
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.00p
0.000
0.000
191.849
horns
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing vioLitions".
1
Signature of Land Applier
Z Z1 �
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DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING 5iJNIMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to he submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Statesville, NC Total Dry Tons Applied (Annual):
WQ0016247 Cation Exchange Capacity (non 503 only):
Dennis Phillips Owner: Dennis Phillips Predominant Soil Series:
10.4 Acres Permitted:. 10.4 Site #: NC IR 00020 Field #: IR 00020 0003
32.78
Cecil
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
7/2/18
2
3
4
5
6
7
8
9
10
11
12
Solids
13.24
8
9
10
11
12
Arsenic
5
Cadmium
2.26
H
Copper
259
Chromi
30
�
Lead
20.6
Mercury
0.762
w
Molyb-
enum
9
Nickel
25.8
��
Selenium
5
0.000
0.000
0.000
0.000
0.000
Zinc
591
0.000
0.000
0.000
0.000
0.000
0.032
Total
Phos-
horns
28600
0.000
0.000
0.000
0.000
0.000
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
TOtal
1
2
3
4
5
6
7
8
9
10
11
12
H
DT/Ac./
�
App
w
Event
3.15
��
Arsenic
0.032
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.032
Cadmium
0.014
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
Copper
1.633
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.633
Chromi
0.189
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.189
Lead
0.130
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.130
Mercury
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Molyb-
0.057
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.057
denum
Nickel
0.163
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.163
Selenium
0.032
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.032
Zinc
3.727
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.727
Total
Phos-
180.352
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
180.352
horns
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
i
Signature of Lan Applier
Z Zl
Da e
DENR FORM MFLSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Statesville, NC Total Dry Tons Applied (Annual): 18.97
Permit #: WQ0016247
Operator: Detmis Phillips Owner:
Acres Used: 15 Acres Permitted:
Cation Exchange Capacity (non 503 only):
Dennis Phillips Predominant Soil Series: Helena
15 Site #: NC IR 00020 Field #: ]R 00020 0006
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #�:
Sample or
Com-
posite
Date
1
10/4/17
2
3
4
5
6
7
8
9
10
11
12
Solids
14.08
8
9
10
11
12
Arsenic
3.13
Cadmium
2
H
Copper
242
Chromi
35.1
°
Lead
18.9
Mercury
0.601
w
Molyb-
denum
9.9
Nickel
19.5
��
Selenium
3
0.000
0.000
0.000
0.000
0.000
Zinc
307
0.000
0.000
0.000
0:000
0.000
0.008
Total
Phos-
horns
23600
0.000
0.000
0.000
0.000
0.000
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
H
DT/Ac./
°
App.
w
Event
1.27
��
Arsenic
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0:000
0.000
0.008
Cadmium
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Copper
0.612
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.612
Chromium
0.089
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.089
Lead
0.048
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.048
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.025
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
denum
Nickel
0.049
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.049
Selenium
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Zinc
0.777
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.777
Total
Phos-
59.708
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
59.708
horns
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that. qualified personnel properly gathered and evaluated the information submitted.
I am aware that there. are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
<� �-�
Signature of Land Applier
Z.. Z_ � � 5
Dat
DENR FORM MFLSF (12/2006)

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ANN [JAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annnal Report
Facility Name: Statesville, NC Total Dry Tons Applied (Annual): 42.33
Permit #: WQ0016247 Cation Exchange Capacity (non 503 only):
Operator: Dennis Phillips Owner: Dennis Phillips Predominant Soil Series: Helena
Acres Used: 15.2 Acres Permitted; 15.2 Site #: NC IR 00020 Field #: IIt 00020 0007
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
1/4/17
2
3
4
5
6
7
8
9
10
11
12
Solids
13.96
8
9
10
11
12
Arsenic
3.34
Cadmium
13.2
H
Copper
327
Chromi
141
�
Lead
84.6
Mercury
0.4
y
Molyb-
denum
19.4
Nickel
53.3
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Selenium
6.87
0.000
0.000
0.000
0.000
0.000
Zinc
1020
0.000
0.000
0.000
0.000
0.000
0.019
Total
Phos-
horns
16300
0.000
0.000
0.000
0.000
0.000
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
H
DT/Ac./
�
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Event
2.79
��
Arsenic
0.019
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Cadmium
0.074
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.074
Copper
1.821
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.821
Chromi
0.785
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.785
Lead
0.471
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.471
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.108
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.108
denum
Nickel
0.297
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.297
Selenium
0.038
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.038
Zinc
5.681
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.681
Total
Phos-
90.791
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
90.791
horns
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of Fines and
imprisonment for knowing violations".
_/`-- z z t
Signature of Lan plier Dat
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Statesville, NC Total Dry Tons Applied (Annual): 47.43
Permit #: W00016247 Cation Exchange Capacity (non 503 only):
Operator: Dennis Phillips Owner: Dennis Phillips Predominant 5oi15eries: Appling
Acres Used: 10.3 Acres Permitted: 10.3 Site #: NC IR 00020 Field #: II2 00020 0008
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg,. %Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
10/4/17
2
3
4
5
6
7
8
9
10
11
12
Solids
14.08
8
9
10
11
12
Arsenic
3.13
Cadmium
2
H
Copper
242
Chromi
35.1
�
Lead
18.9
Mercury
0.601
°'
Molyb-
denum
9.9
Nickel
19.5
��
Selenium
5
0.000
0.000
0.000
0.000
0.000
Zinc
307
0.000
0.000
0.000
0.000
0.000
0.029
Total
Phos-
horus
23600
0.000
0.000
0.000
0.000
0.000
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
H
DT/Ac./
�
App
°'
Event
4.61
��
Arsenic
0.029
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.029
Cadmium
0.018
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.018
Copper
2.229
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.229
Chromi
0.323
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.323
Lead
0.174
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.174
Mercury
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
Molyb-
0.091
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.091
denum
Nickel
0.180
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.180
Selenium
0.046
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.046
Zinc
2.827
0.000
0.000
0.000
0.000
0.000
0:000
0.000
0.000
0.000
0.000
0.000
2.827
Total
Phos-
217.356
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
217.356
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed. to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Lan lier
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DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this. form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Statesville, NC Total Dry Tons Applied (Annual):
WQ0016247 Cation Exchange Capacity (non 503 only):
Dennis Phillips Owner: Dennis Philhps Predominant Soil Series:
11.4 Acres Permitted: 11.4 Site #: NC IR 00020 Field #: IR 00020 0009
35.58
Cecil
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
10/4/17
2
3
4
5
6
7
8
9
10
11
12
Solids
14.08
8
9
10
11
12
Arsenic
3.13
Cadmium
2
H
Copper
242
Chromi
35.1
�
Lead
18.9
Mercury
0.601
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denum
9.9
Nickel
19.5
��
Selenium
5
0.000
0.000
0.000
0.000
0.000
Zinc
307
0.000
0.000
0.000
0.000
0.000
0.020
Total
Phos-
horns
23600
0.000
0.000
0.000
0.000
0.000
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
H
DT/AC./
�
App.
w
Event
3.12
��
Arsenic
0.020
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.020
Cadmium
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.012
Copper
1.510
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.510
Chromi
0.219
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.219
Lead
0.118
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.118
Mercury
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Molyb-
0.062
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.062
denum
Nickel
0.122
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.122
Selenium
0.031
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.031
Zinc
1.916
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.916
Total
Phos-
147.264
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
147.264
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
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(7ENR FORM MFLSF (12/2006)

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ANN -[JAL METALS FIELD LOADING SiJMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Statesville, NC Total Dry Tons Applied (Annual):
WQ0016247 Cation Exchange Capacity (non 593 only):
Sammy Deal Owner: Sammy &Jane Deal Predominant Soil Series:
35.2 Acres Permitted: 35.2 Site #: NC IR 00035 Field #: IR 00035 0003
115.57
Pacolet
Residual Analysis Data (Heavy Metals and Tatal Phosphorus use mglkg, %Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
5/10/18
2
5/f0/IS
3
7/2/18
4
5
6
7
8
9
10
11
12
Solids
13.27
13
13.24
9
10
11
12
Arsenic
3.86
3.99
5
Cadmium
1.75
1.77
2.26
H
Copper
220
206
259
Chromi
20.8
20.1
30
Lead
14.7
14.4
20.6
Mercury
0.585
0.497
0.762
,�,
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Molyb-
denum
7 81
7.26
9
0.09
Nickel
16.9
16.6
25.8
Selenium
2.58
2.9
5
0.001
0.000
0.000
0.000
Zinc
461
446
591
0.000
0.000
0.000
0.000
0.026
Total
Phos-
horus
26500
26550
28600
0.000
0.000
0.000
0.000
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
TOtal
1
2
3
4
5
6
7
8
9
10
11
12
H
DT/Ac./
APP•
,�,
y
Event
0.15
3.04
0.09
Arsenic
0.001
0.024
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Cadmium
0.001
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.012
Copper
0.067
1.253
0.046
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.366
Chromi
0.006
0.122
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.134
Lead
0.004
0.088
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.096
Mercury
0.000
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Molyb-
0.002
0.044
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.048
denum
Nickel
0.005
0.101
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.111
Selenium
0.001
0.018
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Zinc
0.140
2.713
0.105
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.959
Total
Phos-
8.056
161.530
5.091
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
174.677
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there. are significant penalties for submitting false information., including the possibility of fines and
imprisonment for larowing violations".
�i
Signature of Lan Applier
Z � ��
D e
DENR FORM MFLSF (12/2006)

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\2:2;27;22�

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this
form to the corresponding Field
Loading Summary Form to be submitted in Annual
Report
Facility Name:
Statesville, NC
Total Dry Tons Applied (Annual):
108.50
Permit #:
W00016247
Cation Exchange Capacity (non 503 only):
11
Operator:
Sammy Deal Owner:
Sammy &Jane Deal Predominant Soil Series:
Pacolet
Acres Used:
35:2 Acres Permitted:
35.2 Site #: NC IR 00035 Field #:
IR 00035 0004
Residual Analysis
Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
5/10/18
2
5/10/18
3
7/2/18
4
5
6
7
8
9
10
11
12
Solids
13.27
13
13.24
9
10
11
12
Arsenic
3.86
3.99
5
Cadmium
1.75
1.77
2.26
c
Copper
220
206
254
Chromi
20.8
20.1
30
Lead
14.7
14.4
20.6
Mercury
0.585
0.497
0.762
w
Molyb-
denum
7 81
7.26
9
0.58
Nickel
16.9
16.6
25.8
Selenium
2.58
2.9
5
0.006
0.000
0.000
0.000
Zinc
461
446
591
0.000
0.000
0.000
0.000
0.025
Total
Phos-
horus
26500
26550
28600
0.003
0.000
0.000
0.000
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
c
DT/Ac./
App,
w
Event
1.16
1.35
0.58
Arsenic
0.009
0.011
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
Cadmium
0.004
0.005
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
Copper
0.509
0.556
0.298
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.363
Chromiu
0.048
0.054
0.035
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.137
Lead
0.034
0.039
0.024
0..000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.097
Mercury
0.001
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Molyb-
0.018
0.020
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.048
denum
Nickel
0.039
0.045
0.030
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.114
Selenium
0.006
0.008
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.020
Zinc
1.066
1.204
0.681
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.951
Total
Phos-
61.268
71..685
32.947
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
165.900
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2- z l t
Signatureo dApplier Date
DENR FORM MFLSF (12/2006)

SUMMIT Summit Environmental Technologies, Inc.
TI3310 Win St.
MVIReNMENTALTECHNO LOUIE S, WE; Cuyahoga Falls, Ohio 44223
Analytical Lahoraiovtas TEL: [phone] FAX: [phone]
Website: http.lAviviv.settek.coni
March 15, 2018
Erik Bruce
Synagro
284 Boger Rd.
Mocksville, NC 27028
TEL: [phone]
FAX: [phone]
RE: Statesville
Dear Erik Bruce: Order No.: 18030033
Surnmit Environmental Technologies, Inc. received 1 sample(s) on 3/1/2018 for the
analyses presented in the following report.
There were no problems with the analytical events associated with this report unless noted
in the Case Narrative.
Quality control data is within laboratory defined or method specified acceptance limits
except where noted.
If you have any questions regarding these tests results, please feel free to call the
laboratory.
'y&A=VZ APFARAr
Jennifer Woolf
Project Manager
3310 Win St.
Cuyahoga Falls; Ohio 44223
Arkansas 86-0735, California 07256CA, Colorado, Connecticut Pir-0108, Delaware, Flouda NELAC 687688, Georgia E%7688, Idaho OH00923, Illinois
200061, Indiana C -OH -13, Kansas E-10347, KenWcky (Underground Storage. Tank
) 3, Kenh�cky 90146, Lowsiana 04061, Maryland 339, Minnesota
409711, New Hampshne 2996, New Iersey OH006, New York 11777, Norfh Carolina 39705 and 631, Noah Dakota R-201, Oklahoma 9940, Oregon
O112O0001, Rhode Island LA000317, South Carolina 92016001, Texas T104704466 -I1-5, Utah OH009232011-1, Virginia VELAP 9456, Washington
C891
Page 1 of 28

SUMMITsa,nni,Envi,on,nentalTechnologies, Inc.ffJ Case Narrative
3310 Win St.
rNVIRONNIENTAL TECi1NOLOGIES,INC- Cuyahoga Falls, Ohio 44213 WO#: 18030033
Arlatyiical Lahoraloner, TEL: [phone] FAX: [phone]
Website: hao:/hv, iv.senek.com Date: 3/15/2018
CLIENT: Synagro
Project: Statesville
WorkOrder Narrative:
18030033 � This report in its entirety consists of the following documents: Cover Letter, Case Narrative,
Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody,
Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit
Environmental Technologies, Inc., Work Order Number assigned to this report.
Summit Environmental Technologies, Inc.,. holds the accreditations/certifications listed at the bottom of
the cover letter that may or may not pertain to this report. State Certificates and Scopes of Accreditation
are attached as applicable. Results provided in this report for any parameter not listed on the Scope of
Accreditation should be considered "not certified."
The information contained in this analytical report is the sole property of Summit Environmental
Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of
Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results
contained in this report are only representative of the samples received. Conditions can vary at different
times and at different sampling conditions. Summit Environmental Technologies, Inc, is not responsible
for use or interpretation of the data included herein.
All results for Solid Samples
are reported on
an
"as received" or
"wet weight" basis unless indicated as
"dry weight" using the "-dry"
designation on
the
reporting units.
with this report are
This report is
believed
to meet all of the requirements of the
accrediting agency,
where applicable.
Any
comments or
problems
with the analytical events associated
with this report are
noted below.
Analytical Sequence Sample Notes:
18030033-OOla tclp-svoc-cpest(8081b): LCS recovery biased high; associated sample results are N.D.
18030033-OOIA SVOC-BNA_TCLP(8270d): CCV exhibited high recovery for Pentachlorophenol and
Pyridine. Associated samples are ND for Pentachlorophenol and Pyridine.
18030033-OOIA MTL-TCLP-7(6010D): Silver failed the CCV high, but because the sample was
nondetect for silver it can be accepted.
Analytical Sequence QC Notes:
CCV 7359 20 ug/L tclp-voc-mstr_tclp(8260): The VOC CCV (Batch R812$6) exhibited high recovery
for Vinyl chloride; Associated samples are ND for Vinyl chloride.
Original
Page 2 of 28

sural' Summit EmdronmenralTechnol1OWinrr Qualifiers and Acronyms
3310 Win 5
FNVIRONNENTALIECNNOLOGIES, INC. Cuyahoga Falls Ohio 4422 WO#: 18030033
ArWyficaf Leboratorles TEL: [phone] FAX' (330) 253-446
Website: httn:/hlnmvsetlek.ca Date: 3/15/2018
These commonly used Qualifiers and Acronyms may or may not be present in this report
Qualifiers
U
The compound was analyzed for but was not detected.
J
The reported value is greater than the Method Detection Limit but less than the Reporting Limit.
A
The hold time for sample preparation and/or analysis was exceeded.
D
The result is reported firm a dilution.
E
The result exceeded the linear range of the calibration or is estimated due to interference.
MC
The result is below the Minimum Compound Limit.
*
The result exceeds the Regulatory Limit or Maximum Contamination Limit.
m
Manual integration was used to determine the area response.
d
Manual integration in which peak was deleted
N
The result is presumptive basedon a Mass Spectral library search assuming a 1:1 response.
P
The second column confirmation exceeded 25% difference.
C
The result has been confirmed by GUMS.
X
The result was not confirmed when GC/MS Analysis was performed.
B/MB+
The analyte was detected in the associated blank.
G
The ICB or CCB contained reportable amounts of analyte.
QC-/+
The CCV recovery failed low (-) or high (+).
R/QDR
The RPD was outside of accepted recovery limits.
QL-/+
The LCS or LCSD recovery failed low (-) or high (+).
QLR
The LCS/LCSD RPD was outside of accepted recovery limits.
QM-/+
The MS or MSD recovery failed low (-) or high (+).
QMR
The MS/MSD RPD was outside of accepted recovery limits.
QV-/+
The ICV recovery failed low (-) or high (+),
S
The spike result was outside of accepted recovery limits.
Z
Deviation;. A deviation from the method was performed; Please refer to the Case Narrative for
additional information
Acronyms
ND
Not Detected RL Reporting Limit
QC
Quality Control MDL Method. Detection Limit
MB
Method Blank LOD Level of Detection
LCS
Laboratory Control Sample LOQ Level of Quantitation
LCSD
Laboratory Control Sample Duplicate PQL Practical Quantitation Limit
QCS
Quality Control Sample CRQL Contract Required Quantitation Limit
DUP
Duplicate PL Permit Limit
MS
Matrix Spike RegLvl Regulatory Limit
MSD
Matrix Spike Duplicate MCL Maximum Contamination Limit
RPD
Relative Percent Different MinCL Minimum Compound Limit
ICV
Initial Calibration Verification RA Reanalysis
ICB
Initial Calibration Blank RE Reextraction
CCV
Continuing Calibration Verification TIC Tentatively Identified Compound
CCB
Continuing Calibration Blank RT Retention Time
RLC
Reporting Limit Check CF Calibration Factor
DF
Dilution Factor RF Response Factor
This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting.
Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear inthis
list or for additional information regarding the use of these Qualifiers on reported data.
Original
Page 3 of 28

NU 'T. Summit Environmental Technologies, Inc. Workorder
EM 3310 Win St.
MVIRONMENTAL TEOHNOLOOI-cS, INC Cuyahoga Falls, Ohio 44223 Sample Summary
AnsfyHcal LahpratorlPa TEL: [phone] FAX [phone] WO#: 18030033
Website: hay..1APvvw.seHekcom 15 -Mar -I8
CLIENT: Synagro
Project: Statesville
Lab SampleID Client Sample ID Tag No Date Collected Date Received Matrix
18030033-001 4th Creek W WTP 2/28/2018 8:15:00 AM 3/1/2018 10:20:00 AM Sludge
Page 4 of 28

SUMMIT s„nm,;l� „menlalzeennavp 310Winnc. DATES REPORT
Win Si.
ENVIIONh1ENT11. TEC41401,00IEB, INC- C,ricdmga Falls, Ohio 44223
WOil: 18030033
AnaIVOcal Laboraltudea TEL: [phone] FAX: [phone]
wehxlle: ha,//v enakeo 15 -Mar -18
Client: Synagro
Project: Ststesville
Sample ED Client Sample Collection Date Mnfrix TesLTiams Leachate Dnfc Prep Date Analysis Date
18030033-OOIA 4th Creek WWTP 2/ 2880188:15:00 AM Sludge rpfitabiliry of Solids (SW -846: 1030)
3/2/2018 1:45:00 PM
pH(SW9045D)
Reactive Cyanide (9014/7.3.3.2) -Solid
Reserve Sulfide (9034)%/3.42
TCLP Hmbiddes Analysis (SW 1311/83/1/2018 6:00:00 PM
TCL? Mercury Analysis (SW 1311/]4 i3/1/2018 6,00:00 PM
TCLP Metals Analysis (SW1311/60103/l/2018 6 00:00 PM
TCLP Pesticides Analysis (SWI 311/8( 3/1/2018 6:00:00 PM
TCLP Semi -Volatiles Analysis 3/1/20186: 00:00 PM
(SW1311/8270)
TCLP VolaidesAmlysis
3/1/20186:0O:OOPM 31212010319:00
3/14/2018 8:00:00
PM
3/]/201812:15:00
PM
31!/2018 12:15:00
PM
31712018 2 3 0:00 PM
3/121201810:32.00
PM
3/5/2018 1150:00 AM.
3/5/2018 5:25:00
PM
3/2/2018 9:05:00 AM
3/6/2018 7:34:50
PM
3/5/20187:00:00 AMM
3/6120182:01:00
PM
3/5/20188.00:00 A
3/6/20189: 08:
00 PM
PM
Original
Page 5 of 28

M1 umml� Stmimir Envirompento/TeClvpol10 es,Win
StAnalytical Report
. Anal
3370 Wn St. J
nNVIR0Nh1ENTALTECAN0L0G1E5,;Nq. Cuyahoga Falls, Ohio 44223 (basereport)
Analytical LaboratDras TEL; [phone] FAX. [phone] WO#: 18030033
Website: han71Rvww.setlek.con' Date Reported: 3/15/2018
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 2/28/20188:15:00 AM
Lab ID: 18030033-OOIA
Project: Statesville
Client Sample ID 4th Creek W W TP
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW7470A SW7470A Analyst: EAM
TCLP MERCURY ANALYSIS (SW1311/7470)
TCLP Mercury ND 0.00500 mg/L 1 3/5/2018 5:25:00 PM
TCLP METALS, VOC, BNA, PEST, HERBSOLID SW6010D SW3010A Analyst: KMS
TCLP METALS ANALYSIS (SW131116010)
TCLP Arsenic(As) ND 0.500 mg/L 1 3/6/2018 7:34:50 PM
TCLP Barium(Ba) ND 5.00 mg/L 1 3/6/2018 7:34:50 PM
TCLP Cadmium(Cd) ND 0.100 mg/L 1 3/6/2018 7:34:50 PM
TCLP Chromium(Cr) ND 0.200 mg/L 1 3/6/2018 7:34:50 PM
TCLP Lead(Pb) ND 0.500 mg/L 1 3/6/2018 7:34:50 PM
TCLP Selenium(Se) ND 0.0500 mg/L 1 3/6/2018 7:34:50 PM
TCLP Silver(Ag) ND 0.500 QC+ mg/L 1 3/6/2018 7:34:50 PM
NOTES:
Silver failed the CCV high, but because the sample was nondetect for silver it can be accepted.
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270D SW3510C Analyst: BJH
TCLP SEMI -VOLATILES ANALYSIS (SW1311/8270)
1,4 -Dichlorobenzene ND 0.0800 mg/L 2 316/20189:08:00 PM
2,4,5 -Trichlorophenol ND 0.200 mg/L 2 3/6/2018 9:08:00 PM
2,4,6 -Trichlorophenol ND 0.200 mg/L 2 3/6/2018 9:08:00 PM
2,4-Dinitrotoluene ND 0.0400 mg/L 2 3/6/2018 9:08:00 PM
o -Cresol ND 0.200 mg/L 2 3/6/2018 9:08:00 PM
m/p-Cresol(s) 0.509 0.200 mg/L 2 3/6/2018 9:08:00 PM
Cresols, Total ND 4.00 mg/L 2 3/6/20189:08:00 PM
Hexachloro-1,3-butadiene ND 0.0160 mg/L 2 3/6120189:08:00 PM
Hexachlorobenzene ND 0.0400 mg/L 2 3/6/20189:08:00 PM
Hexachloroethane ND 0.0800 mg/L 2 3/6/20189:08:00 PM
Nitrobenzene ND 0.0800 mg/L 2 3/6/2018 9:08:00 PM
Pentachlorophenol NO 0.200 QC+ mg/L 2 3/6/2018 9:08:00 PM
Pyridine ND 0.200 QC+ mg/L 2 3/6/2018 9:08:00 PM
Surr: 2-Fluorophenol 38.6 10-109 %Rec 2 3/6/2018 9:08:00 PM
Surr: Phenol -d6 17.8 10-109 %Rec 2 3/6/2018 9:08:00 PM
Sum Nitrobenzene -d5 61.6 19-120 %Rec 2 3/6/2018 9:08:00 PM
QuaOfiers: �
Value exceeds Maximum Contaminant Level.
H
Aolding limes for preparation or analysis exceeded
MC
E Value above quantitation range
Value is below Minimum Compound Limit.
ND Not Detected
P Second colunm confirmation exceeds
R RPD outside accepted recovery limits
M Manual Integration used to determine area response
N Tentatively identified compounds
O RSD is greater than RSDbmit
PL Permit Limit Original
RL Reporting Detection Limit
Page 6 of 28

5u moff Summit Environmental Technologies, Inc. Analytical Report
ffl 3310 Win St.
r4vilIONhtENTAL 1fCHNOLOWE5, 1NC. Cuyahoga Falls, Ohio 44223 (base report)
Analytical taboraror/e.5 TEL: [phone] F,4X: [phone] WO#: 18030033
Website: htto:/Avivw.settek.com Date Reported: 3/15/2018
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 2/28/2018 8:15:00 AM
Lab ID: 18030033-001A
Project: Statesville
Client Sample ID 4th Creek W WTP
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270D SW3610C Analyst: BJH
TCLP SEMI -VOLATILES ANALYSIS (SW1311/8270)
Surr: 2,4,6-Ttibromophenol 38.6 10-120 %Rec 2 3/6/2018 9:08:00 PM
Surr: 2-Fluorobiphenyl 59.2 22-117 %Rec 2 3/6/20189:08:00 PM
Surr: p-Terphenyl-dl4 67.7 34-116 %Rec 2 3/6/2018 9:08:00 PM
NOTES:
CCV exhibited high recovery for Pentachlorophenol and Pyridine. Associated samples are ND for Pentachlorophenol and Pyridine.
TCLP METALS, VOC, BNA, PEST, HERB -SOLID. SW8081 SW3610C Analyst: JBN
TCLP PESTICIDES ANALYSIS (SW131118081)
Chlordane, total ND 0.0200 mg/L 2 3/6/2018 2:01:00 PM
Toxaphene NO 0.0400 mg/L 2 3/6/20182:01:00 PM
Endrin ND 0.00200 QL+ mg/L 2 316/20182:01:00 PM
gamma -BHC ND 0.00200 QL+ mg/L 2 316/20182:01:00 PM
Heptachlor NO 0.00200 QL+ mg/L 2 3/6/2018 2:01:00 PM
Heptachlor epoxide ND 0.00200 QL+ mg/L 2 3/6/20182:01:00 PM
Methoxychlor ND 0.00200 QL+ mg/L 2 3/6/20182:01:00 PM
Surr. TCMX 75.2 10-119 %Rec 2 3/6/2018 2:01:00 PM
Surr: DCB 63.9 10-119 %Rec 2 3/6/2018 2:01:00 PM
NOTES:
LCS recovery biased high; associated sample results are N.D.
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8151A SW8151A Analyst: JBN
TCLP HERBICIDES ANALYSIS (SW131118151)
2,4-D ND 1.00 mg/L 1 3/12/2018 10:32:00 PM
2,415 -TP ND 0.500 d mg/L 1 3/12/2018 10:32:00 PM
Surr: DCAA 88.7 20-140 %Rec 1 3/12/201810:32:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260B SW1311M Analyst: CTB
TCLP VOLATILES ANALYSIS
1,1-Dichloroethene ND 0.0500 mg/L 10 312/20183:19:00 PM
1,2-Dichloroethane ND 0.0500 mg/L 10 3/2/2018 3:19:00 PM
MEK 1.08 0.250 mg/L 10 3/2/2018 3:19:00 PM
Benzene ND 0.0500 mg/L 10 3/2/2018 3:19:00 PM
Qualifiers: * Value exceeds Maximum Contaminant Level. E Value above quandtation range
H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response
MC Value is below Minimum Compound Limit N Tentatively identified compounds
ND Not Detected 0 RSD is greater than RSDlimit
P Second column confirmation exceeds PL Pennit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 7 of 28

R1 U M'T SummitEnviranmental Technologies,iSt.
33100Win St.
friVIRONMENTAL IECHNOLOOiES, INC Cuyahoga Falls, Ohio 44223.
4natydpirl LatichatOdas TEL: [phone] PLY., [phone]
Website: httd:/Apuiv.seaek.cons
Analytical Report
(base report)
WO#: 18030033
Date Reported: 3/15/2018
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 2/28/20189:15:00 AM
Lab ID: 18030033-OOIA
Project: Statesville
Client Sample ID 4th Creek W WTP
Analyses Result RL Qnal Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERBSOLID
SW8260B
SW1311M Analyst:
CTB
TCLP VOLATILES ANALYSIS
Carbon tetrachloride ND
0.0500
mg/L
10
3/2/2018 3:19:00
PM
Chlorobenzene ND
0.0500
mg/L
10
3/2/2018 3:19:00
PM
Chloroform ND
0.0500
mg/L
10
3/2/2018 3:19:00
PM
Tetrachloroethene ND
0.0500
mg/L
10
3/2/2018 3:19:00
PM
Trichloroethene ND
0.0500
mg/L
10
3/2/2018 3:19:00
PM
Vinyl chloride ND
0.0200
QC+ mg/L
10
3/2/2018 3:19:00
PM
Surr: 4-Bromofluorobenzene 112
70-130
%Rec
10
312/20183:19:00
PM
Surr: Dibromofluoromethane 98.7
70-130
%Rec
10
3/2/2018 3:19:00
PM
Surr: Toluene -d8 101
70-130
%Rec
10
3/2/2018 3:19:00
PM
NOTES:
The VOC CCV (Batch 881286) exhibited high recovery far Vinyl
chloride;
Associated samples are
ND for Vinyl
chloride,
RCI -SOLID -Wt IGNITABILITY1030
SW9014
Analyst:
MS
REACTIVE CYANIDE (901417.3.3.2) -SOLID
Cyanide, Reactive ND
0.500
mg/Kg
1
3/7/2018 12:15:00 PM
RCI -SOLID -W/ IGNITABILITY1030
SW1030
Analyst:
AJT
IGNITABILITY OF SOLIDS (SW -846: 1030)
Ignitability non-flammable
1
3/2/20181:45:00
PM
RCI -SOLID -W/ IGNITABILITY1030
SW9045D
Analyst:
CXS
PH (SW9045D)
pH 5.8
s.u.@19.9°C
1
3/14/2018 8:00:00 PM
RCI -SOLID -W/ IGNITABILITY1030
SW9034
Analyst:
MS
REACTIVE SULFIDE (9034)17.3.4.2
Sulfide, Reactive ND
25.0
mg/Kg
1
3/7/2018 12:15:00 PM
Qualifiers: Value exceeds Maximum Containment Level.
E Value above quantitation range
H Holding times for preparation or analysis exceeded
M Manual Integration used to determine area response
MC Value is below Minimum Compound Limit.
N Tentatively identified compounds
ND Not Detected
O RSD is greater
than RSDlimit
P Second column confirmation exceeds
PL Permit Limit
Original
R RPD outside accepted recovery limits
RL Reporting Detection Limit
Page 8 of 28

SUMMIT
Summit Environmental Technologies, Inc. AeereditationProgram
ffl3310 Win St. Analytes Report
rNVIRONMENTAL IECHNOLOGiEg, INC. Cuyahoga Falls, Ohio 44223 y Y
ArratyNcal Lfiboralohen TEL [phone] FAX [phone] WO#: 18030033
Website: htta.1Avwiv.settek.com 15-Mar-18
Client: Synagro State: NW
Project: Statesville Program Name: NC—WW—SCM
Sample TD Matrix
Test Name
Analyte
Status
18030033-OOIA Sludge
Ignitability of Solids (SW -846: 1030)
Ignitability
A
Sludge
PH(SW9045D)
Hydrogen fon (pH)
A
Sludge
Reactive Cyanide (9014/7.3.3.2) -Solid
Cyanide, Reactive
U
Sludge
Reactive Suffide.(9034)/7.3.4.2.
Sulfide, Reactive
U
Sludge
TCLP Herbicides Analysis (SW1311/8151)
2,4,5-71P
A
Sludge
TCLP Herbicides Analysis (SWI 311/8151)
2,4-1)
A
Sludge
TCLP Herbicides Analysis (SW1311/815 1)
DCAA
A
Sludge
TCLP Mercury Analysis(SW1311/7470)
Mercury
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Arsenic
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Barium
A
Sludge
TCLP Metals Analysis(SW131.1/60I0)
Cadmium
A
Sludge
TCLP Metals Analysis (SWI311/6010)
Chromium
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Lead
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Selenium
A
Sludge
TCLP Metals Analysis (SW 1311/6010)
Silver
A
Sludge
TCLP Pesticides Analysis (SWI 311/808 1)
2,2',3,3',4,4',5,5',6,6'-
A
Decachlorobiphenyl
Sludge
TCLP Pesticides Analysis(SWI31l/8081)
Chlordane, total
A
Sludge
TCLP Pesticides Analysis (SWI 311/8081)
Endrin
A
Sludge
TCLP Pesticides Analysis (SW 1311/8081)
gamma -BHC
A
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
Heptachlor
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Heptachlorepoxide
A
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
Methoxychlor
A
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
Tetrachloro-m-xylene
A
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
Toxaphene.
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
1,4 -Dichlorobenzene.
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
2,4,5 -Trichlorophenol
A
Sludge
TCLP Semi -Volatiles Analysis (SW1311/8270)
2,4,6-Tribromophenol
A
Sludge
TCLP Semi -Volatiles Analysis (SW 1311/8270)
2,4,6 -Trichlorophenol
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
2,4-Dininotoluene
A
Sludge
TCLP Semi -Volatiles Analysis (SW 1311/8270)
2-Fluorobiphenyl
A
Sludge
TCLP Semi -Volatiles Analysis (SWI 311/8270)
2-Fluorophenol
A
NC_WW_SCM A Accredited NC_WW_SCM U Uiravailable.
Version #3.
Page 9 of 28

SUMMIT
Summit EmtronmemoT hnoogre, nc. Accreditation Program
pr 3310 win St. Analytes Report
MVIRONhIENIAL IECHUOLOGIES, TNC Cuyahoga Falls, Ohio 44223 y Y
drrafy(mal (aboraWies TEL: [phone] FIX: [phone] WO#: 18030033
Website: htp.,11i seir.settek.com 15 -Mar -18
Client: Synagro. State: NW
Project: Statesville Program Name: NC—WW—SCM
Sample ID Matrix
Test Name
Analyte
Status
18030033-OOIA Sludge
TCLP Semi -Volatiles Analysis
(SWI 311/8270)
2-Methylphenol
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
3,4-Methylphenol
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
Cresols, Total
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
Hexachlorobenzene
A
Sludge
TCLP Semi -Volatiles Analysis
(SW1311/8270)
Hexachlorobutadiene
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
Hexachloroethane
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
Nitrobenzene
A
Sludge
TCLP Semi -Volatiles Analysis
(SW 1311/8270)
Nitrobenzene -d5
A
Sludge
TCLP Semi -Volatiles Analysis
(SW1311/8270)
Pentachlorophenol
A
Sludge
TCLP Semi -Volatiles Analysis
(SWI 311/8270)
Phenol -d6
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
p-Terphenyl-dl4
A
Sludge
TCLP Semi -Volatiles Analysis
(SW 1311/8270)
Pyridine
A
Sludge
TCLP Volatiles Analysis
1,1-Dichloroethene
A
Sludge
TCLP Volatiles Analysis
1,2-Dichloroethane
A
Sludge
TCLP Volatiles Analysis
2-Butanone
A
Sludge
TCLP Volatiles Analysis
4-13romofluorobenzene
A
Sludge
TCLP Volatiles Analysis
Benzene.
A
Sludge
TCLP Volatiles Analysis
Carbon tetrachloride
A
Sludge
TCLP Volatiles Analysis
Chlorobenzene
A
Sludge
TCLP Volatiles Analysis
Chloroform
A
Sludge
TCLP Volatiles Analysis
Dibromofluoromethane
A
Sludge
TCLP Volatiles Analysis
Tetrachloroethene
A
Sludge
TCLP Volatiles Analysis
Toluene -d8
A
Sludge
TCLP Volatiles Analysis
Trichloroethene
A
Sludge
TCLP Volatiles Analysis
Vinyl chloride
A
NC_WW_SCM A Accredited NC_WW_SCM U Unavailable
Version #3
Page 10 of 28

SUMMIT 3337010Wb''°'°'"`ErnA.a,naenalTealmIft,hro Qc su nx�xEroRT
in Sr.
EWHONtIFNTNL MHNOWGIE6, iNe_ Cuyahoga Falls, Ohio 44223
Allalptical tatiOrMorloa TEL: [phone] FAX: [phone] WOH: 18030033
Website: help./Auwn enekco IS-Mrtr-78
Client: Synagro
Project: Statesville B6teLID: 31107
Sample ID MB -37107 SampType: MBLK TeslGode: tclp.
1,1-0ichlaroethene
ND
0.0500
1,2-0iohloroethane
ND
0.0500
MEK
ND
0.250
Benzene
ND
0.0500
Carbon tetrachloride
voc-mstr Units: mg/L
Prep Date: 3/1/2018
RunNo: 87266
Client lD:
PBS
Batch ID:
31107
TestNo:
SW82608 SW7311M
Analysis Date: 3/2/2018
SegNo: 1439966
Analyte
ND
0.0500
Result
PQL
SPKvalue SPKRef Val
%RFC LowLlmil Highl-imit RPDRef Val
%RPD RPDLimit Qual
1,1-0ichlaroethene
ND
0.0500
1,2-0iohloroethane
ND
0.0500
MEK
ND
0.250
Benzene
ND
0.0500
Carbon tetrachloride
ND
0.0500
Chlorobenzene
ND
0.0500
Chloroform
ND
0.0500
Tetrachloroelhene
ND
0.0500
Trichloroethene
ND
0.0500
Vinyl chloride
ND
0.0200
Sur: 4-Bmmmucrobenzene
560
Surr: Dlbmmofluoromethane
489
Suh: Toluene -d6
504
500.0
112
70
130
500.0
97.8
70
130
500.0
101
70
130
QC+
1,1-0ichloroethene
0.199
0.0500
39.9
Sample ID
18030033-001aM5
SampType:
MS
TestCode:
tclp-voc-mstr Units: mglL
Prep Date:
RunNo: 61266
Client ID:
4th Creek He
Batch ID:
31107
TestNo:
SW0260B SW1311M
Analysis Date: 3/2/2018
SegNo: 1440508
Analyte
Result
PQL
SPK value SPK Ref Val
%REC LowL]mit Highl-imlt RPDRef Val
%RPD RPDLimit Qua]
1,1-0ichloroethene
0.199
0.0500
39.9
0.200
0
99.3
39.9
ion limits
ND NotDetected
PG Pernmufflit
Iso
757
227
155
E Value above quantitative range
M
Manual Integration
used to determine
0 RSD isgree[er tfien RSDlimit
R RPD outside accepted recovery limits
0ligitial
Page 11 of 28

MIT srra�n,r1 .,aro manialTeam3317INia0Win e, QC SUMMARY REPORT
33Sl.
ENVIRONMENTAL 76CHNOWGIyb, INC Cnyahogal"alls, Ohio 44223
WON: 18030033
4rwylleal6ntroralarles Tom: (330) 2534211 TAA [phone]
JEebole: Im settekcoar M -Afar -78
Client: Synagro
Project: Statesville Batell 31107
Sample l0 18030033-001aMS SampType: MS TeslGade: tclp-voc-matt Units: mg/L Pre
Carbon tetrachloride O.tT/ 0.0500 0.200 0 88.7 40.8 162
Chlorobenzene 0208. 0.0500 0200
0.791
0.0500
0.200
D
95.3
39.9
160
Bample ID
18030033-001aMSD
.
0
104
35.7
p Date:
RunNo:
81286
Cllent[H
4th Creek WWTP
Batch ID:
31107
TestNo:
SW8260B
SW1311M
Analysis Date: 312/2018
SegNo:
1440808
Analyte
88,2
10
Result
PHIL
SPKvalue
SPKRef Val
%REG LowLlmit HighLimlt RPDRef Val
%RPD RPDLimit oust
1,1-Dichloreethene
Page 12 of 28
0.791
0.0500
0.200
D
95.3
39.9
160
Bample ID
18030033-001aMSD
.
0
104
35.7
168
Chloroform
0.210
0.0500
0.200
0
105
18.3
199
Tetrachlomethene
0.176
0.0500
0.200
0
88,2
10
261
Trichloroethene
0.207
0.0500
0.200
0
104
23.8
175
Vinyl chloride
0.231
0.0200
0.200
0
116
10
165 QC+
Surr: 4-Brcmofluorobenzene
558
88.5
500.0
162
112
84.6
130
Surr: Dibiomofluoromethane
508
500.0
0
102
71.4
127
Burr: Toluene -c8
508
Chloroform
500.0
0.0500
102
74.6
127
1,1-Dichloreethene
Page 12 of 28
0.791
0.0500
0.200
D
95.3
39.9
160
Bample ID
18030033-001aMSD
SampType:
MSD
TeslCotle:
tclp-voc-matt Units: mg/L
Prep Date:
RunNo:
81286
ClientlD:
4th CreekWWTP
Batch lH
31107
TestNo:
SWO260B
SW1311M
Analysis Date: 3/2/2018
SegNo:
1440509
Analyte
16.6
227
Result
PQL
SPK value
SPK Ref Val
%REG LowLimit HighLlmit RPD Ref Val
%RPD RPDLimit Qual
1,1-Dichloreethene
Page 12 of 28
0.791
0.0500
0.200
D
95.3
39.9
160
0.799 4.71
25
1,2-0Ichloroethane
0.193
0.0500
0.200
0
96.7
42.5
157
0.197 2.00
25
MEK
2.08
0.250
1.00
1.06
99.5
16.6
227
2.06 0.967
25
Benzene
0213
0.0500
0.200
0
106
38.1
155
0.226 5.57
25
Carbon tetrachloride
0.177
0.0500
0.200
0
88.5
40.8
162
0.177 0.226
25
Chlorobenzene
0,207
0.0500
0.200
0
103
35.7
168
0.208 0.867
25
Chloroform
0.199
0.0500
0.200
0
99.4
183
199
0.210 5.48
25
Tetrachlomethene
0.176
0.0500
0.200
0
87.8
10
261
0.176 0.455
25
Qualifiers. *
Value naeods Maximum Contaminant Level.
B
Analyte detected in the associated Method Blank
E
Value above quartitationrange
H
Holding times for preparation or analysis exceeded
I
Analyte detected below qui dtaiion limits
M
Manual Integration used to determine
Ongmal
MC
Valve is below Minimum Compound limit.
ND
Not Detected
O
RSD i s greater than RSDlimit
P
Second column confirmation exceeds
PL
Perm Limit
R
RPD oucide accepted recovery limits

®SUMIVII7 s, ;rDn„hannema t. 33lQ bahr3310fisn St. S(., QC SUMMARY REPORT
ENVIRONIAeNTAL n(NOWDLOn1ES, INC CvyahaKa Falls, Ohio 44223
prydlylf4`el Labornlarles WO#: 18030033
7M: [phone] FAX,. (330) 2534 89
Wehshe: hrm:/Mmpw.senekcom l5-MnrvlB
Client: Synagro
Project: Statesville BatchID: 31107
Sample ID 18030033-001aMSD SampType: MSD TestCode: tclp-voc-msM Units: mg;L Prep Data.
Trichloroethene
0.194 0.0500
0.200
0 97.0
23.8
175 0.207
6.48
25
Vinyl chloride
0.213 0.0200
0.200
0 106
10
165 0.231
RunNo: 81286
GlientlD:
4th Greek WWTP
Batch ID:
31107
TestNo:
SW82600 SW1311M
Malysis Date: 3IV2018
SegNo: 1440609
Analyte
491
500.0
Result
PDL
SPKvalue SPK Rat Val
%REG LowUmit Highl-imit RPDRef Val
%RPD RPDLImit Dual
Trichloroethene
0.194 0.0500
0.200
0 97.0
23.8
175 0.207
6.48
25
Vinyl chloride
0.213 0.0200
0.200
0 106
10
165 0.231
8.28
25 DC+
Sun: 4Bromofluombenzene
560
500,0
112
84.6
130
0
25
Sum. Dibanneflucrom ethane
491
500.0
98.2
71.4
127
0
25
Sun: TolueneAS
517
500.0
103
74.6
127
0
25
Qunlifiers: '
Valueexceeds Maximum Contaminan[Level.
B
Analyte detected in the associated Method Bleak
D
Value above 4uantltn8on range
H
Holding times for prepamdon or analysis exceeded
1
AnalNe detected below quantihtion limits
M
Manual Integration used to detemdne Original
MC
Value is below Minimum Compound Limit
ND
Not Detected
O
ASD is6 aterthan RSDlimit
P
Second column confirmation excels
PL
PermiWaniit
R
RPD outside accepted recovery limits
Page 13 of 28

SUMMIT s�a"'tE rano, ,tat 3310 §e#13310 WinhID.Sl. Qc suivnvraRYx�roxT
.
ENVIRONMENTAL TECHNOLOGIES, INC CiewhogaFalls, Ohio 44223
WQ#: 18030073
Ahalyfleel tabbrataNrs TLL:(330) 2534211 TAX..[phone]
Website: bNa lAmmr..sellekeom IS-Mtr18
Client: Synags
Project: Statesville 1latchDl: 31129
Sample lD 18030036-007ams SampType: ms TestCode: tclpsvoecpe Units: mg/L Prep Date: 3I5/2018
Endrin
0.0134
0.00200
0.0100
0
134
20
157
gamma -BHC
0.0123
0.00200
0.0100
0
123
22
137
RunNo: 81440
Client ID:
BatchQC
Batch ID:
31129
TestNo:
SW8G81
SW3510C
Analysis Date: 316/2018
SegNo: 1444091
Analyte
0
127
Result
PQL
SPKvalue
SPK Ref Val
%REC LowLlmit HighLimit RPD Ref Val
%RPD RPDHmll Qual
Sample lD 18030036-007amsd SampType: mad TeslCotle: tclp-svaecpe Units: mg/-
0.0134
0.00200
0.0100
0
134
20
157
gamma -BHC
0.0123
0.00200
0.0100
0
123
22
137
Heptachlor
0.0112
0.00200
0.0100
0
112
24
121
Heptachlorepoxlde
0.0127
000200
0.0100
0
127
27
152
Methoxychlor
0.0150
0.00200
0.0100
0
158
10
199
Surr. TCMX
16.3
11.9.
20.00
Methoxychlor
81.3
10
119
Surr. DCB
12.8
10
20.00
0.0158
64,2
10
119
Endrin
0.0120
0.00200
0.0100
0
120
20
157
0.0134
10.8
30
gamma -BHC
0.0107
0.00200
Prep Date: 316/2078
RunNo: 81440
Client to:
BatchQC
Batch ID:
31129
TestNo:
SW8081 SW3510C
Analysis Date: 3/8/2018
SegNo: 1444092
Analyte
0.0100
0
Result
PQL
SPKvalue SPKRef Val
%REC Lowl-imil HighUmit RPDRef Val
%RPD RPDLlmit Qual
0.0120
0.00200
0.0100
0
120
20
157
0.0134
10.8
30
gamma -BHC
0.0107
0.00200
0.0100
0
107
22
137
0.0123
14.4
30
Heptachlor
0.00992
000200
0.0100
0
99.2
24
121
0.0112
12.1
30
Heptachlor epoxide
0.0113
0.00200
0.0100
0
113
27
152
0.0127
11.9.
30
Methoxychlor
0.0143
0.00200
0.0100
0
143
10
199
0.0158
976
30.
Surr: TCMX
13.9
20.00
69.6
10
119
0
Surr: DCB
13.5
20.00
67.6
10
119
0
Qnnlifiers; t
Onglhal
Value exceeds Ma�iimum Contaminantlevel.
B
Analyte detected in !fie associated Method Blank
L
Value above quanSMtion Hobe
H
Holdinglimes forprepamtion or analysis exceeded
f
Analyte detected below quantitation limits
M
Manual in[ega8on uscl to determine
MC
Valueis below Minimum Compound Limit
�
Nat Detected
O
RSD is greater [ban RSDlimit
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits
Page 14 of 28

®�UMMI'r S ,nil n, oar ,,alTeln3310 win QO �UMMARYREPORT
vn n Sc5
ENVIRONMENTAL TECHNOLOt11E9, INC Cnyahaga Falls, Ohio 44223 WON: 18030033
Altalyl?"J laborebrles yl:'l,: [phone] FAX. [phone]
website: hrm:/hcaw.settekconr 15 -Mar -78
Client: Synagro
Project: Statesville BatchID: 31129
Sample ID mb-
Chlordane, Ictal NO 01
56.7
0100
Toxaphene
NB
0.0200
Endrin
NB
0.0010D
gamma -BHC
31129
SampType:
mblk
TeslCode:
tclp-snot-epa
Units: mglL
Prep Date: 3/5/2010
RunNo: 81440
CllentlD:
PBS
Batch ID:
31129
TestNo:
SWB081
SW3510C
Analysis Date: 3/6/2018
SegNo: 1446923
Analyte
Result
PQL
SPKvalue
SPKRaf Val
%REG Lowl-imit HlghLimlt RPDRef Val
%RPD RPD1-m18 Qual
20.00
56.7
0100
Toxaphene
NB
0.0200
Endrin
NB
0.0010D
gamma -BHC
NO
0.00100
Heptachlor
NO
0.00100
Heptachlor epoxide
NO
0.00100
Methoxychlor
NO
0.00100
Surr. TCMX
11.3
SW8081
Surr. DCB
12.6
SegNo: 1446924
20.00
56.7
10
119
20.00
62.6
10
119
Endrin
0
0.0178 0.00100
S
Sample ID
Its -31129
SampType:
Its
TeslCode:
tcip-svoc-cpe
Units: mglL
Prep Date: 3/5/2018
RunNo: 81440
Client ID:
LOSS
Batch ID:
31129
TestNo:
SW8081
SW3510C
Analysis Dale: 3/8/2018
SegNo: 1446924
Analyte
Result
PQL
SPK value
SPK Ref Val
%REG LowUndt HighLimlt RPD Ref Val
%RPD RPDLimit Qual
Endrin
0
0.0178 0.00100
S
0.0100
0
178
S
Permit Limit
20
157
S
Page 15 of 28

® SUMM17 y ai,ca,iro,,,»e„mlTeh»o/og;ea,me Qc s1�MMaRyREPoxT
33/0 a'in Sl.
ENVIRONMENTAL TECHNOLOGIES, INC Cn)whoga Falls, ONu 44223
411alpflGel lnbArsfortrs %F.L: (330) 2534211 FAX: [phone] WO#: 18030033
Webeire: hop 1AvoY errek aor I5 -.Mar -18
Client: Synagro
Project: Statesville 13atchlD: 31138
Sample ID
TCLP Mercury
18021390-001AMS
SampType:
MS
TestCode:
HG_TCLP(74 Units mglL
Prep Date: 3/5/2018
RunNo: 81362
Client lD:
MB -31138
SampType:
MBLK
TestCotle:
HG_TCLP(74 Units: mglL
Prep Dale: 3/5/2010
RunNo: 81362
Client ID:
PBS
Batch ID:
31138
TestNo:
SW7470A SW7470A
Analysis Date: 3/5/2018
SegNo: 1442191
Analyte
Result
PCL
SPKvalue SPKRef Val
%REC LowLimit HighLimit RPDRef Val
%RPD RPDLimit Qual
NO 0.00200
Sample l0 LCS31138 SampType: LCS TestCotle: HG TCLPlT4 Units: mg/L Prep Date: 315/2818 RunNo: 81
.P Mercury
18021390-001AMS
SampType:
MS
TestCode:
HG_TCLP(74 Units mglL
Prep Date: 3/5/2018
RunNo: 81362
Client lD:
Ba[chQC
Hatch ID:
31138
TestNo:
SW7470A SW7470A
Analysis Date: 3/5/2018
362
Client ID:
LCSS
Batch ID:
31138
TestNo:
SW7470A M7470A
Analysis Date: 315/2818
Seel 1442193
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLimit HighLimit RPDRef Val
%RPD RPDLimit Qual
0.00408 0.00200 0.00400 0 102 BO 120
Sample ID
.P Mercury
18021390-001AMS
SampType:
MS
TestCode:
HG_TCLP(74 Units mglL
Prep Date: 3/5/2018
RunNo: 81362
Client lD:
Ba[chQC
Hatch ID:
31138
TestNo:
SW7470A SW7470A
Analysis Date: 3/5/2018
SegNo: 1442195
Analyte
BatchQD
Batch ID:
Result
PQL
SPKvalue SPK Ref VaI
%REC LowLimit HighLimit RPD Ref Val
%RPD RPDLImit Qual
0.00441 0.00200 0,00400 0.0000700 108 75 125
Sample ID 18021399-001AMS0 SampType: MSO TestCotle: HG TCLPi]4 Unita: mg/L Prep
TCLP Mercury
pate: 3/5/2818
RunNo: 81362
Client lD:
BatchQD
Batch ID:
31138
TesWo:
SW7470A SW]4]OA
Analysis Date: 3/5/2878
SegNo: 1442196
Analyte
Result
PQL
SPKvalue SPK Ref Val
%REG LowLimit HighLimit RPD Ref Val
%RPD RPDLimit Coal
0.00437 0.00200 0.00400 0.0000700 108 75 125 0.00441 0.911 20
Qua crs: * Value exceeds Maximum Contaminant Level. H Malyte detecmd in the essociamd Medrad Hlank G ea canebquantitaiiov use
H Holdingtima for preparation or analysis exceeded J Armlyfe detected below quantitation limits M Manual Jn[egation used or determine
Original
MC Value is belowMinimum Compound Limit ND No[Detected O RSD is wester [flan RSDlimi[
P Second column confirmation exceeds PL Permit Limit R 12PD outside accepted recovery limits
Page 16 of 28

®SUMMi7 Bann,,;tnn• mn» talr 3310Iyirr s331O r, QC SIIMMARY REPORT
Sl.1.
EN1gRONMEMAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223
WO#: 18030033
Ahalylleal Leberslarles TEL: [phone] PAX. [phone]
Web®1e:1 ry.lAu nKsetakcm IS-Mm18
Client: Synagro
Project: Statesville BBtchID: 31138
Sample ID 1802139M
Quulifiere: Value ceeds Maxim mConlaminant Level. fl Mely[e detected in the associated Metfiod Blank E Value above qun ange
H Holding Ames forprepamtion or analysis exceeded 1 Analy[e detected below quantilalion limits M Manual in[egmd nosed to determine
MC Values be1mvMinimum Com ound Limit. ND Not Detected 0 RSD is greater 2fian liSDOIII Original
P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits
Page 17 of 28
01AM50
SampTypa:
MSO
TeslCode:
HG_TCLP(74 Units: mglL
Prep Dale: 3/5/2018
RunNo: 81362
Client to
BatchQC
Batch ID:
31138
TestNo:
SW7470A SW7470A
Analysis Date: 3/5/2018
SegNo: 1442196
Analyte
Result
PQL
SPKvalue SPKRd Val
%REC LowUmit HighLlmil RPDRef Val
%RPD RPDLimit Qual
Quulifiere: Value ceeds Maxim mConlaminant Level. fl Mely[e detected in the associated Metfiod Blank E Value above qun ange
H Holding Ames forprepamtion or analysis exceeded 1 Analy[e detected below quantilalion limits M Manual in[egmd nosed to determine
MC Values be1mvMinimum Com ound Limit. ND Not Detected 0 RSD is greater 2fian liSDOIII Original
P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits
Page 17 of 28

SUMMIt X„ararh�r mra a,al ph,3310MooSI. QC SUMMARY REPORT
33/0 !i'in 11.
ENVIRONMENTAL TECHNOLOGIES, Mat Cgyalansa Falls, Ohio 44223 WOR: 18030033
Arralpt real tsbOratarhep 7A1,: (330) 2534211 FAX: [phone]
Website: hno:/.fmmr.senek.com IS -Mar -I8
Client: Synagro
Project: Statesville BatchIl 31196
2,4D
Sample lD Ics-
ND
1.00
0
0
2,4,5 -TP
ND
0.500
0
Sample ID
mb-31198
SampType:
mblk
TestCode:
tclp-svooher
Units: mglL
Prep Date: 3f//2D78
RunNo: 81649
CllealD:
PBS
Balch ID:
31196
TestNo:
SW8151A
SW8151A
Analysis Date: 311212010
SegNo: 1453716
Analyte
Result
PQL
SPK value
SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
2,4D
Sample lD Ics-
ND
1.00
0
0
2,4,5 -TP
ND
0.500
0
0
Burr: DCAA
480
500.0
TestCode:
96.0 20 140
2,4-0
Sample ID 18030036AOtams SampType: ms TestCode; tclp-svoc-her 11Nls: mglL Pre
ND
100
0.500
0
81.5
62.6
125
2,4,5 -TP
ND
31196
SampType:
Ics
TestCode:
tclp-svoc-her
Units: mglL
Prep Date: 3f7/2018
RunNo: 81648
Client ID:
LCSS
Batch ID:
31196
TestNo:
SW81S7A
SW8151A
Analysis Date: 3/1212018
SegNo: 1453717
Analyte
Result
PQL
SPKvalue
SPKRef Val
%REC Lowl-nn0 [llghl-knit RPDRef Val
%RPD RPDLimit Qual
2,4-0
Sample ID 18030036AOtams SampType: ms TestCode; tclp-svoc-her 11Nls: mglL Pre
ND
100
0.500
0
81.5
62.6
125
2,4,5 -TP
ND
0.500
0.500
0
63.0
52.5
126
Sol DCAA
483
Client ID:
500.0
Batch ID:
96.5
20
140
2,4D ND 1.00 0.500 0 7
Value exceeds Maximum Contaminant Level.
B
Avaly[edetected iv Ike as cieted Method Blavk
B
9.0
37
105
2,4,5 -TP
ND
0.500
0.500
0
81.0
38
106
p Date: 317/2018
RunNa: 87649
Client ID:
BatchOC
Batch ID:
31196
TestNo:
SW8161A
SWB751A
Analysis Dale: 3/1212018
SegNo: 1453719
Analyte
Result
PQL
SPKvalue
SPKRef Val
%REC LmyUrrit HighLlmlt RPDRef Val
%RPD RPDLimit Qua]
QrrnliBera. ' E Value above quantitation range
M Manual Ntegatiov used to determine
Original
O ASD is ereeterOrav RSDlimit
R RPD outside accepted recovery limits
Page 18 of 28
Value exceeds Maximum Contaminant Level.
B
Avaly[edetected iv Ike as cieted Method Blavk
B
9.0
37
105
2,4,5 -TP
ND
0.500
0.500
0
81.0
38
106
Burr: DCAA
472
500.0
94.4
20
140
QrrnliBera. ' E Value above quantitation range
M Manual Ntegatiov used to determine
Original
O ASD is ereeterOrav RSDlimit
R RPD outside accepted recovery limits
Page 18 of 28
Value exceeds Maximum Contaminant Level.
B
Avaly[edetected iv Ike as cieted Method Blavk
B
Boldine times for preparation or analysis exceeded
I
Malyre detected belmv quantitation limits
MC
Value is 6elowMinimum Compound limit.
ND
Nat Detected
P
Second column confirmation exceeds
PL
Permit Limit

®Su1VIM17 331n !a 3310 Win
Se QC SUMMARY REPORT
Si.
ENVIRONMENTAL TCHNOLOOIEB, INC Cuyahoga Falls, Ohio 44223
4NalylJCa! Lnbdnleryq ZEL: WO#: 18030033
(330) 2534211 FAX.. [phone]
Website: hry-/h n swlekcan, IS-Mnr78
Client: Synagro
Project: Statesville BatchID: 31196
2,4-D ND 100 0.500 0 85.7 37 105 0 0 30
2,4,5 -TP ND 0.500 0.500 0 88.4 38 106
Value ceNs Maxmum Contaminant Level.
B
AnalNe deteGed in the associated Method Blank
E
Vnlue above quanlitadon range
H
Holding limes for preparadon or analysis exceeded
Sample ID
16030036-00lamsd
SampType:
msd
TestCotle:
tclp-svoc-her Units: mglL
Prep Dale: 317/2018
RunNo: 61649
Client ID:
BatchQC
Batch ID:
31188
TestNo:
SW8151A SW8151A
Analysis Dale: 3/12/2018
Seattle: 1453720
Analyte
500.0
Result
PQL
SPKvalue SPKRef Val
%REG LowLimil Highi-imit RPDRef Val
%RPD RPDLimit Qual
Qualifiers: •
Value ceNs Maxmum Contaminant Level.
B
AnalNe deteGed in the associated Method Blank
E
Vnlue above quanlitadon range
H
Holding limes for preparadon or analysis exceeded
]
Analyte defected below quantitation limits
M
Manual lvte6radms used to determine Origil'Ial
MC
Value �s 5elow Mivirnum Compound Limit.
ND
No[Detected
0
ASD is 6reeterthnn RSDlimit
P
0
0
30
Surr. DCM
502
500.0
100
20
140
0
Qualifiers: •
Value ceNs Maxmum Contaminant Level.
B
AnalNe deteGed in the associated Method Blank
E
Vnlue above quanlitadon range
H
Holding limes for preparadon or analysis exceeded
]
Analyte defected below quantitation limits
M
Manual lvte6radms used to determine Origil'Ial
MC
Value �s 5elow Mivirnum Compound Limit.
ND
No[Detected
0
ASD is 6reeterthnn RSDlimit
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits
Page 19 of 28

®S&JMMIt snna,;,�„4r0anearurTed,n310Win QC SUMMARY REPORT
3gJ0 Wh, 31.
EHVrIRONNENTAl TECHNOLOGIES, INC Ca3mhogaFalls, Ohio 44223 Woih 18030033
Amalyllest Laboratories TEL:(330) 253A211 F".(330) 2534489
Website: boo /6vinctyeneek com 15-MRr4il
Client: Spill
Project: Statesville Bateh16: R81272
Sample ID LCS.R6127
Ignitabillty 7.96
7.240 0 110 70 130
B
Analyte deteaed in the associated Metbod Hlavk
E
Value above quantitation mnge
H Iioldin9 times for preparation or analysis exceeded
I
Analyte detected below quantitation limits
Sample ID
2
SampType:
LCB
TestCode:
Ignilability_S Units:
Prep Date:
RgnNo: 61272
Client to
LCSS
Batch ID:
R81272
TestNo:
SW7030
Analysis Date: 3/2/2078
Beebe: 1439605
Analyte
Result
PQL
SPK value SPK Ref Val
%REC LowLimlt HighLimit RPD Ref Val
%RPD RPDLimit Qual
Ignitabillty 7.96
7.240 0 110 70 130
Ignitabllity
norHlammable
0 0 20
B
Analyte deteaed in the associated Metbod Hlavk
E
Value above quantitation mnge
H Iioldin9 times for preparation or analysis exceeded
I
Analyte detected below quantitation limits
Sample ID
18027223-001ADUP
SampType:
CUP
TestCode:
Ignitability_S Units:
Prep Date:
RunNo: 87272
ClienllD:
BatchQC
Batch ID:
R81272
TestNo:
SWIC30
Analysis Date: 31212018
SegNo: 1439607
Analyte
Result
PQL
SPKvalue SPKRef Val
%REG LoNrUmlt Hight -oft RPDRef Val
%RPD RPDLimit Qua]
Ignitabllity
norHlammable
0 0 20
rbillty
non -Flammable
B
Analyte deteaed in the associated Metbod Hlavk
E
Value above quantitation mnge
H Iioldin9 times for preparation or analysis exceeded
I
Analyte detected below quantitation limits
Sample ID
1B02122B-001ADUP
SampType:
DUP
TestCode:
Ignitability_S Unlls:
Prep Date:
RunNo: 81272
Client to
BatchQC
Batch ID:
R81272
TestNo:
SW1030
Analysis Date: 31D2018
SegNo: 1439609
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLimit HighUnnil RPDRef Val
%RPD RPDLimit Qual
rbillty
non -Flammable
rbility
non-flammable
0 0 20
QnnliRere: ` Value exceedx Maximum Conmmiaant level.
B
Analyte deteaed in the associated Metbod Hlavk
E
Value above quantitation mnge
H Iioldin9 times for preparation or analysis exceeded
I
Analyte detected below quantitation limits
Sample l0
18030033-001ADUP
SampType:
DUP
TestCode:
lgnitability_S Units:
Prep Dale:
RunNo: 81272
Client ID:
4th Creek WWTP
Batch ID:
R81272
TestNo:
SW7630
Analysis Date: 31212018
eq o: 1439611
Analyte
Result
PQL
SPK value SPK Ref Val
%FEC Lowl-lmlt HlghUmit RPD Ref Val
%RPD RPDLimit Qual
rbility
non-flammable
0 0 20
QnnliRere: ` Value exceedx Maximum Conmmiaant level.
B
Analyte deteaed in the associated Metbod Hlavk
E
Value above quantitation mnge
H Iioldin9 times for preparation or analysis exceeded
I
Analyte detected below quantitation limits
M
Manual ]nlegadon used to detemine
Original
MC Valueis below Minimum Compound Limit
ND
Not Detected
0
R3Duereeterihen RSDlimit
P Second column condonation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits
Page 20 of 28

®SUMMIfi'S,aaS;.Frro-nrareneal7ecbnalogesbrc' QC SUMMARY REPORT
3310 W'rr S(.
VINONMENTAL T6CHNOW01% INC Ceryahog Fells, Ohio 44223
WON: 18030433
4nalyllcal Labomakw ca ZT'L: [phone] FAX: [phone]
Website: hno /h um seNekcor IS-MnrvlB
Client: Synagro
Project: Statesville Batch1l): 881272
Sample l0 18030033.081ADUP BampType: DUP TestCode: Ignitability_S Units: Prep Date: RunNc: 8127
Ignitability
Value exceeds Maximum CovfaruinentLevel.
H
Anely[e detected in the azsociated Method➢IeNr
E
Value shove quantitation range
H
liotding times for preparation or analysis exceeded
ample ID
18838836-O01ADUP
SampType:
DDP
TestCode:
IgnRablllty_S Units:
Prep Date:
2
Client ID:
41h Creek WWTP
Hatch ID:
R81272
TestNo:
SWIM
Analysis Date: 3/2/2018
SegNo: 1439611
Analyte
Result
PQL
SPKvalue SPK Ref Val
%REC l owLimll Highl-imit RPD Ref Val
%RPD RPDUmlt oust
Ignitability
Value exceeds Maximum CovfaruinentLevel.
H
Anely[e detected in the azsociated Method➢IeNr
E
Value shove quantitation range
H
liotding times for preparation or analysis exceeded
ample ID
18838836-O01ADUP
SampType:
DDP
TestCode:
IgnRablllty_S Units:
Prep Date:
RunNo: 812]2
ant ID:
BatchQC
Batch ID:
881272
TestNo:
SW1030
Analysis Date: 3/2/2018
SegNo: 1439611
ialyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLant Highl-imit RPDRef Val
%RPD RPDLimit Qual
nonflammable
O U 20
Sample ID 18030038A01AOUP SampType: DUP Tes[Cotle: Ignitability_S Units: Prep Date: RunNo: 8127
Ignitability
non-flammable
0 0 20
Qunlifiers: '
Original
Page 21 of 28
Value exceeds Maximum CovfaruinentLevel.
H
Anely[e detected in the azsociated Method➢IeNr
E
Value shove quantitation range
H
liotding times for preparation or analysis exceeded
J
Analyte detected below quantitation limits
M
Manual lntegredon usedto determine
MC
Value is below Minimum Compouvd Li an
ND
2
Client ID:
BatchQC
Batch to:
R81272
TestNo:
SW1030
Analysis Date: 3/2/2018
SegNo: 1439615
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LoseLimll Highl-imit RPDRef Val
%RPD RPDUmIt Qual
Ignitability
non-flammable
0 0 20
Qunlifiers: '
Original
Page 21 of 28
Value exceeds Maximum CovfaruinentLevel.
H
Anely[e detected in the azsociated Method➢IeNr
E
Value shove quantitation range
H
liotding times for preparation or analysis exceeded
J
Analyte detected below quantitation limits
M
Manual lntegredon usedto determine
MC
Value is below Minimum Compouvd Li an
ND
Not Detected
O
RBD is greater Phan RSDlimit
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits

®SuMMIt Rrm,r„t�,;,aa,r,ena,Tee»amge QC SUMMARY REPORT
3310 Wia Sf. S(.
ENVIPONMFNT0.I. TECHNOLOGIES, INC Cryohaga Falls, Ohio 44223 We#: 18030033
4ryalyflcel LxbUYabrles 7Xl,:(330)25342]]FAX.[phone]
Wsbsite: htro'/Mo re set,ekemn IS-MnrvIR
Client: Synagro
Project: Statesville RatchR): R81476
Sample ID MB-RB1476 SampType: MBLK TestCode: Cyanlde,Rea Units: mg/L Prep Date:
Cyanide,
10.0 0.500
10.00 0.1330 98.8 81.3
118
9.975 0.400 5
Sample ID
LCS-R81476
SampType:
LCS
TeslCode:
Cyanide,Rea Units: mg/L
RunNo: 81476
ClientlD:
PBW
Batch to
R81476
TestNo:
SW9014
Analysis Dale: 31712018
SegNe: 1445165
Analyte
Value is below Minimum Compound Limit
ND
Result
PQL
SPKvalue SPKRef Val
%REG LowLimil High limit RPDRef Vel
%RPD RPDLimit Qual
Reactive ND 0.500
Sample to
nide, Reactive 982 0.500 10.00 0 982 85 115
Cyanide, Reactive 9.98 0.500 10.00 0.1330 98.4 81
10.0 0.500
10.00 0.1330 98.8 81.3
118
9.975 0.400 5
Sample ID
LCS-R81476
SampType:
LCS
TeslCode:
Cyanide,Rea Units: mg/L
Prep Date:
RunNo: 81476
Client ID:
LCSW
Batch ID:
R81476
TestNo:
SW9014
Analysis Date: 3/712018
SegNo: 1445167
Analyte
Value is below Minimum Compound Limit
ND
Result
PQL
SPKvalue SPKRef Val
%REG Lowl-imit HighLimit RPDRef Val
%RPD RPDLimit Qua]
PL
PermitLimit
12
"D outside accepted recovery limits
nide, Reactive 982 0.500 10.00 0 982 85 115
Cyanide, Reactive 9.98 0.500 10.00 0.1330 98.4 81
10.0 0.500
10.00 0.1330 98.8 81.3
118
9.975 0.400 5
Sample ID
18030243�001AMS
SampType:
MS
TeslCode:
Cyanide,Rea Units: mglL
Prep Date:
RunNo: 81476
Client to
BatchQG
Batch ID:
R81476
TestNo:
SW9014
Analysis Date: 3/7,2018
SegNo: 1445171
Analyte
Value is below Minimum Compound Limit
ND
Result
PQL
SPKvalue SPKRef Val
%DREG LowLimit HlghLimit RPDRef Val
%RPD RPDLimit Qual
3 118
Sample l0 18030243-001AMSD SampType; MSD TestCotle: Cyanide,Rea Units: mglL Prep Dale: RunNo: 81476
Client ID: BatchQC Batch ID: R81476 TestNo: SW9014 Analysis Date: 3/7/2018 Se No:
Cyanide,
10.0 0.500
10.00 0.1330 98.8 81.3
118
9.975 0.400 5
Qualifiers: •
Value exceeda Maximum CantntLevel.
B
Analy[edetected in [he associated Method Blavk
E
Value above quantitation range
H
Holding times for preparation or analysis
I
Analyte detected below quandtatanlimits
M
1445172
Analyte
Value is below Minimum Compound Limit
ND
Result
PQL
SPKvalua SPKRef Val
%REG Lowl-imit HighLimit RPDRef Val
%RPD RPDLimit Qual
Reactive
Page 22 of
10.0 0.500
10.00 0.1330 98.8 81.3
118
9.975 0.400 5
Qualifiers: •
Value exceeda Maximum CantntLevel.
B
Analy[edetected in [he associated Method Blavk
E
Value above quantitation range
H
Holding times for preparation or analysis
I
Analyte detected below quandtatanlimits
M
Manual Integration used to determine Original
MC
Value is below Minimum Compound Limit
ND
Not Detected
O
RM) is greater than RSDSmit
P
Second column confirmation exceeds
PL
PermitLimit
12
"D outside accepted recovery limits
28

mlTra]m310W Sf. QC SUMMARYREPOBT
3310 Win SI.
ENNNONNENTAL TECHNOLOOI=.6, INC Cuyahoga Falls, Oh;o 44223 WOR: 18030033
Analyrflnal r aborelorfr» TEL: [phone] FAX: [phone]
Webole: Ino efokcnm 75-Marv18
Client: Synagro
Project: Statesville BatchID: R81476
Sample ID 18030243-001AMSD SampType: MSD TestCotle: Cyanide Rea
Quatifierx. " Vatue eels Mamm mCon antLevel.
H Holdingtimes forprepara0on omanalyeis rzcecded
MC Value is belowMinimum Compound Lind t.
P Second column confirmation exceeds
➢ Analy[e detested in the assaciared Method Blank E Value above quantitation range
S Analyte detected below quentitafron limits M Manual integration usedto detenninc Original
ND Not Detected O RSD is greeter then RSDlimit
PL Permit Limit R RPD outside accepted recovety limits
Page 23 of 28
RunNo: 81476
Units: mg1L
Prep Dale:
Client ID:
BatchQC
Batch ID:
R81476
TeslNo:
SW9014
Analysis Dale: 317/2018
SegNo: 1445172
Analyte
Result
PQL
SPKvalua SPKRef Val
%REG Lowl-imlt HiOhl-imlt RPDRef Val
°%RPD RPDLimit Qual
Quatifierx. " Vatue eels Mamm mCon antLevel.
H Holdingtimes forprepara0on omanalyeis rzcecded
MC Value is belowMinimum Compound Lind t.
P Second column confirmation exceeds
➢ Analy[e detested in the assaciared Method Blank E Value above quantitation range
S Analyte detected below quentitafron limits M Manual integration usedto detenninc Original
ND Not Detected O RSD is greeter then RSDlimit
PL Permit Limit R RPD outside accepted recovety limits
Page 23 of 28

SuMMfn s aa,usmam 3310fU W,eNrnlreen„,ae. QC SUMMARY REPORT
ln S'I.
ENVIRONMENTALTECHR01.000S, INC Onnshoga Fabc,, Ohio 4422
Am lyfleal LntMraforles WOk: 18030033
1GL:(330)25342ff FAX.'[phone]
Websile: huo'/Ajwmsedekco ZSMnr-18
Client: Synagro
Project Statesville BatchID: R81487
Sample lD MB -R81487 SampType: MBLK TestCode: Sulfide, React Units: mglL Pre
tle, Reactive
ND 25.0
de, Reactive 4650 25.0 4800 0 97.1 8
Value cads Maximum Contaminant level.
H
Mal}rce detected in the associated MetM1od Hlank
H
Holding times for prepemtion or analysis exceeded
1
Maly[ede[ected below quantitation limits
Sample lD
LCS-R81487
SampType:
LCS
TestCode:
Sulfltle,React Units: mglL
p Date:
RunNo: 81487
Cliento.
PBW
Balch ID:
R81487
Teeple:
SW9034
Analysis Date: 3/7/2018
SegNo: 1445410
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLimil HighLimit RPDRef Val
%RPD RPDLimit Qual
tle, Reactive
ND 25.0
de, Reactive 4650 25.0 4800 0 97.1 8
Value cads Maximum Contaminant level.
H
Mal}rce detected in the associated MetM1od Hlank
H
Holding times for prepemtion or analysis exceeded
1
Maly[ede[ected below quantitation limits
Sample lD
LCS-R81487
SampType:
LCS
TestCode:
Sulfltle,React Units: mglL
Prep Oate:
RunNo: 81487
Cll r -I
LCSW
Batch ID:
R81487
TestNo:
SW9034
Analysis Date: 3/7/2018
SegNo: 1445411
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLimit HighLimit RPDRef Val
%RPD RPDLimit Qual
5 115
Bample ID 180302430
Sulfide, Reactive 47
Value cads Maximum Contaminant level.
H
Mal}rce detected in the associated MetM1od Hlank
H
Holding times for prepemtion or analysis exceeded
1
Maly[ede[ected below quantitation limits
MG
01AM5
SampType:
MS
TestCode:
SUlflde,React Units: mg/L
Prep Date:
RunNo: 8148]
Client ID:
BatchQC
Batch to:
R81487
TestNo:
SW9034
Analysis Date: 3/7/2018
SegNo: 1445413
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLimll HighLimit RPDRef Val
%RPD RPDLimit Qual
20 25.0 4800 D 96.3 75 125
Sample lD 18030243-007AM50 SampType: MSD TestCode: Sulflde,React Units: mglL Prep Data
Sulfide,
Value cads Maximum Contaminant level.
H
Mal}rce detected in the associated MetM1od Hlank
H
Holding times for prepemtion or analysis exceeded
1
Maly[ede[ected below quantitation limits
MG
Value is beton Minimum Compound LimiC
ND
No[Delected
P
Second column confirmation exceeds
RunNo: 81487
COent ID:
BatchQC
Batch ID:
R81487
Textile:
SW9034
Analysis Date: 317/2018
Sea a. 1445414
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC Lowl-imit HighLimit RPDRef Val
%RPD RPDLimit Qual
Reactive 4710 25.0 4800 0 96.1 75 125 4720 0.212 30
Qualifiers: ' E Vaiueabove guava range
M Mavual lnte9ration rlsed to determine
Original
0 RSD is greaterthan RSDlimit
R RPD outside accepted recoveryliseas
Page 24 of 28
Value cads Maximum Contaminant level.
H
Mal}rce detected in the associated MetM1od Hlank
H
Holding times for prepemtion or analysis exceeded
1
Maly[ede[ected below quantitation limits
MG
Value is beton Minimum Compound LimiC
ND
No[Delected
P
Second column confirmation exceeds
PL
Permit Limit

®�UMMIt 3310/0Iff1'om„�falTahn.hSc Qc st»vrnraR poxT
ia S'!.
ENVIRONMENTAL TECHNOLOGIES, INC Cayaleva Falls, Ohio 44223
WOIi: 180$0033
Ahalclfcal Lobdrstaries 1F1: (330) 2534211 FAX: [phone]
Webs/he: hryy./Avg ouakvap IS -Mur -Z8
Client: Synagrn
Project: Statesville BatchED: 881487
Sample ID 18030243.001AMSD SampType: MSO TeslCotle: Sulfide React Units: mglL Prep Date: RunNo: 81
Qunliliere: � Value exceeds Maximum Conlamivant Level. H Mely[e detected in the azsoeiated Method Hlank E Valueabove quanvtation range
H Holding times for preparation or analysis exceeded I AnalNe de[ected below quantitation limits M Manual ln[egation used to determine
MC Velue isbetowMinimum Compound Li mit ND Not Detected 0 RBD is greater than RSDliIn OHglnal
P Second column confirmation exceeds PL Penait Limit K RPD outside accepted reeuveryburits
Page 25 of 28
487
Client ID:
BatchQC
Batch ID:
R81487
Tes No:
SW9034
Analysis Date: 317/2018
Satan: 1445414
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLimit HighLimit RPDRef Val
%RPD RPDLimit oust
Qunliliere: � Value exceeds Maximum Conlamivant Level. H Mely[e detected in the azsoeiated Method Hlank E Valueabove quanvtation range
H Holding times for preparation or analysis exceeded I AnalNe de[ected below quantitation limits M Manual ln[egation used to determine
MC Velue isbetowMinimum Compound Li mit ND Not Detected 0 RBD is greater than RSDliIn OHglnal
P Second column confirmation exceeds PL Penait Limit K RPD outside accepted reeuveryburits
Page 25 of 28

®SuNiNur sraa,;rF„r;.a»areararzehneagea,nre. QC SUMMARY REPORT
3310 Win SI.
ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223
ArtalyflCal Ln4Gfn19fiCs LEL: [phone] FAX: [phone] WDX: 18030033
Websue: atec eAmmv,seeckgoc 75- rv18
Client: Syri
Project: Statesville BatCLID: R81742
Sample ID LCS-R81742 SampType: LCS TestCode: pH_S(9045D) Units: s.u,@19.8°C Prep Date:
PH
Vnlue ezcceds Mexemum Cootaminent Level.
B
Analyte detected in the associated Method Hank
E
Value above quantitation range
H
Holdingfimes£or preparation or analysis exceeded
Sample l0
18030038-001ADUP
SampType:
CUP
TeslCatle;
pH_S(9045D) Units: s.u.@21.0°C
RunNo: 81742
RunNo: 81742
Client ID:
LCSS
Batch ID:
R81742
TestNo:
SW9045D
Analyte
Analysis Date: 311412018
SegNo: 1456032
Analyte
PQL
SPKvalue SPKRef Val %REC
Result
PQL
SPK value SPK Ref Val
%REG
LowUmit Highi-mit RPD Ref Val
%RPD RPDLimit Qual
7.0
7.0 0 99.7 90 110
PH
Vnlue ezcceds Mexemum Cootaminent Level.
B
Analyte detected in the associated Method Hank
E
Value above quantitation range
H
Holdingfimes£or preparation or analysis exceeded
Sample l0
18030038-001ADUP
SampType:
CUP
TeslCatle;
pH_S(9045D) Units: s.u.@21.0°C
RunNo: 81742
Prep Dale:
RunNo: 81742
ClientlD:
BetchQC
Batch ID:
881742
TestNo:
SW9045D
Analyte
Analysts Date: 311412018
SegNo: 1456036
Analyte
PQL
SPKvalue SPKRef Val %REC
Result
PQL
SPK value SPK Raf Val
%REC
LowLimit HighUrnit RPD Ref Val
%RPD RPDLimit Qual
5.3 5.3 0.6 10
Sample ID LCS-881742 SampType: DUE
PH
Vnlue ezcceds Mexemum Cootaminent Level.
B
Analyte detected in the associated Method Hank
E
Value above quantitation range
H
Holdingfimes£or preparation or analysis exceeded
I
hnalytede[ected below quantitation limits
TestCode:
pH S(9045D) Units: s.u.@19.8°C
Prep Dale:
RunNo: 81742
Client ID:
BatchQC
Batch ID:
R81742
TestNo:
SW9045D
Analysis Date: 311412018
SegNo: 1456053
Analyte
O
RSD is greater than RSDlimit
Result
PQL
SPKvalue SPKRef Val %REC
Lowl.mk Hight -lot RPDRef Val
%RPD RPDLImit Qual
7.0
zo o tot so tto 7.0 os to
Q9etifiera: *
Vnlue ezcceds Mexemum Cootaminent Level.
B
Analyte detected in the associated Method Hank
E
Value above quantitation range
H
Holdingfimes£or preparation or analysis exceeded
I
hnalytede[ected below quantitation limits
M
Mmual ]otegration usedmdcteanine
Ongtnal
MC
Value is belowMnimum Compound Limit
ND
Not Dateoted
O
RSD is greater than RSDlimit
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside acceptedrecovery limits
Page 26 of 28

® g33110OWin Vin Sheet y Emironn ental 1�cnnologies Inc Anal sis Re uest/Chain of Custody
y
Cuyahoga Falls, Ohio 44223 Tel: [phone] Fan: 330.253.4489 lbr Sumoun Environmental 'hclmologies, lna use only
Pace_af_
Company eme (eau P.mq
5 1O
Jttt Name
�CSVI`�t
,,$y
y
ti
i
9p
y6>l�iVillBW0l�9
lee
�{ iS'r
A-kd uc
Climt Phots Na 3
0Plg
Formal to
umt Pns o. ❑
Poo
Client EmailQuom
5 n.
CamGaon
ERIC— 7J N
No
Sampled by �ina4<
Cheek if Ohio YAP aomplee!❑
..
swoPteidaaunauwn
°,', t:
N Ww Tim
z8
ris
0
1
JL
State of Sample Origin: Wi
U� cafu(tfe,
Check if FOR COMPLIANCE
I 126458
II 8'..oly
Bayumted By:°PPf°`�
— e�,n ka m.a
Whhc and yenmrPa�„Boa,a.�mp"r.mp,�a,ae,.�n .�aa<a�,����eNarP�<a.
Page 27 of 28

SUMMIT
SummitEm�ironmenfal Technologies, Inc.
PM 3310 Win St. r,,
"WIRONNIENTALTECHINCLOGIES,TNC. CnyahogaFalls, Ohio 44223 Sample Log -In Check List
Ana.yticof Leharaiuries TEL: [phone] FAX: [phone]
Website: hup:/hvwiv.seitekcom
Client Name: SYN -NC -27028 Work Order Number: 18030033 RcptNo: 1
Logged by: Nick Cleer 3/1/2018 10:20:00 AM
Completed By: Antonio Betscakos 3111201811:37:38 AM
Reviewed By: Jennifer Woolf 311/2018 4:49:47 PM
Chain of Cusfodv
1, Is Chain of Custody complete? Yes W No ❑ Not Present ❑
2, How was the sample delivered? UPS
Login
3. Coolers are present? Yes No ❑ NA ❑
4. Shipping container/cooler in good condi8on7 Yes � No ❑
Custody seals intact on shipping container/cooler? Yes ❑ No. ❑ Not Present ❑r
No. Seal Date: Signed By:
5. Was an attempt made to cool the samples? Yes W No ❑ NA ❑
6. Were all samples received at a temperature of >0° C to 6.0°C Yes W No ❑ NA ❑
7.
Samples) in proper container(s)?
Yes
❑�
No
❑
Signed By
6,
Sufficient sample volume for indicated test(s)?
Yes
W
No
❑
9,
Are samples (except VOA and ONG) properly preserved?
Yes
W
No
❑
10.
Was preservative added to bottles?
Yes
❑
No
❑
NA W
NA
11.
Is the headspace in the VOA vials less than 114 inch or 6 mm?
Yes
❑
No
❑
No VOA Vials W
12,
Were any sample containers received broken?
Yes
❑
No
W
13.
Does paperwork match bottle labels?
Yes
W
No
❑
(Note discrepancies on chain of custody)
14.
Are matrices correctly identified on Chain of Custody?
Yes
W
No
❑
15.
Is it clear what analyses were requested?
Yes
W
No
❑
16.
Were all holding times able to be met?
Yes
W
No
❑
(If no, notify customer for authorization.)
Special Handling (if applicable)
17.
Was client notified of all discrepancies with this order?
Yes
❑
No
❑
NA W
Person Notified: Date
By Whom: Via: ❑ etiail ❑ Phone ❑ Fax ❑ In Person
Regarding:
Client Instructions:
1g. Additional remarks:
Cooler Information
Cooler No
Temp °C
Condition
Seal Intact
Seal No
Seal Date
Signed By
1
4.4
Good
Not Present
Page 28 of 28

TISUMM111
ENVIRONMENTAL TECHNOLOGIES, INC
Analytical Laboraiprlea
March 15, 2018
Erik Bruce
Synagro
284 Boger Rd.
Mocksville, NC 27028
TEL: [phone]
FAX: [phone]
Smrrnvit Emdronmenta7 Technologies, Arc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
TEL [phone] FAX: [phone]
Website: htto://ii�iviv.settek.coni
RE: Statesville
Dear Erik Bruce: Order No.: 18030036
Summit Environmental Technologies, hie. received 1 sample(s) on 3/1/2018 for the
analyses presented in the following report
.
There were no problems with the analytical events associated with this report unless noted
in the Case Narrative.
Quality control data is within laboratory defined or method specified acceptance limits
except where noted.
If you have any questions regarding these tests results, please feel free to call the
laboratory.
Sincerely,
loo�
Jennifer Woolf
Project Man
ager
3310 Win St.
Cuyahoga Falls, Ohio 44223
Arkansas 88-0735, CaEfomia.07256CA, Colorado, ConnecticutPH-0108, Delaware., Florida NELAC E87688, Georgia E87688, Idaho OH00923, Plinois
200061, Indiana CA11
-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Louisiana 04061, Maryland 339, Minnesota
409771, New Hampsh¢e 2996, New Sersey OH006, New York 11777, North Camlim 39705 and 631, North Dakota R-201, Oklahoma 9940, Oregon
OH2O0001, Rhode Island LA000317, Saudi Carolina 92016001, Texas T104704466-11-5, Utah OH009232011-t, Virginia VELAP 9456, Washington
C991
Page 1 of 28

unit Environmental Technologies, ln.
SUMMIT 331010Win SG Case Narrative
FNVIRONMENIAL HCHNOLOGIES, INC. Cuyahoga Falls, Ohio 44223 WO#: 18030036
hnalytwal Labaraow,Yea TEL: [phone] FAX: [phone]
Website: han.Ilivivup.settek.com Date: 3/15/2018
CLIENT: Synagro
Project: Statesville
WorkOrder Narrative:
18030036: This report in its entirety consists of the following documents: Cover Letter, Case Narrative,
Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody,
Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit
Environmental Technologies, Inc., Work Order Number assigned to this report.
Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of
the cover letter that may or may not pertain to this report. State Certificates and Scopes of Accreditation
are attached as applicable. Results provided in this report for any parameter not listed on the Scope of
Accreditation should be considered "not certified."
The information contained in this analytical report is the sole property of Summit Environmental
Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of
Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results
contained in this report are only representative of the samples received. Conditions can vary at different
times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible
for use or interpretation of the data included herein.
All results for Solid Samples
are reported
on an
"as received" or "wet weight" basis unless indicated as
"dry weight" using the "-dry"
designation
on the
reporting units.
This report is
believed
to meet all of the requirements of the
accrediting agency,
where applicable.
Any
comments or
problems
with the analytical events associated
with this report are
noted below.
Analytical Sequence Sample Notes:
18030036-OOla tclp-svoc-cpest(8081b): LCS recovery biased high; associated sample results are N.D.
18030036-OOIA SVOC-BNA_TCLP(8270d): CCV exhibited high recovery for Pentachlorophenol and
Pyridine. Associated samples are ND for Pentachlorophenol and Pyridine.
18030036-001A MTL-TCLP-7(60101)): Silver failed the CCV high, but because the sample was
nondetect for silver it can be accepted.
Analytical Sequence QC Notes:
CCV 7359 20 ug/L tclp-voc-mstr_tclp(8260): The VOC CCV (Batch R81286) exhibited high recovery
for Vinyl chloride; Associated samples are ND for Vinyl chloride.
Original
Page 2 of 28

SU'NI- Summit Environmental Technologies, In Qualifiers and Acronyms
MI3310 Wine
FNVIRONMENTdL I£tnNOLbaIES,INC Cuyahoga Falls, Ohio 4422 WO#: 18030036
Analytical Labpkatvrle9 TEL: [phone] FAX. [phone]
Websile: hno:/hmvwseffek.co. Date: 3/15/2018
These commonly used Qualifiers and Acronyms may ormay not be present in this report
QnaBFiers
U
This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers
The compound was analyzed forbut was not detected.
J
The reported value is greater than the Method Detection Limit but less than the Reporting Limit
I
The hold time for sample preparation and/or analysis was exceeded.
D
The result is reported from a dilution.
E
The result exceeded the linear range of the calibration or is estimated due to interference.
MC
The result is below the Minimum Compound Limit.
*
The result exceeds the Regulatory Limit or Maximum Contamination Limit.
m
Manual integration was used to determine the area response.
d
Manual integration in which peak was deleted
N
The result is presumptive based on a Mass Spectral library search assuming a 1:1 response.
P
The second column confirmation exceeded 25% difference.
C
The result has been confirmed by GC/MS.
X
The result was not confirmed when GUMS Analysis was performed.
B/MB+
The analyte was detected in the associated blank.
G
The ICB or CCB contained reportable amounts of analyte.
QC-/+
The CCV recovery failed low (-) or high (+).
R/QDR
The RPD was outside of accepted recovery limits.
QL-/+
The LCS or LCSD recovery failed low (-) or high (+),
QLR
The LCS/LCSD RPD was outside of accepted recovery limits.
QM-/+
The MS or MSD recovery failed low (-) or high (+).
QMR
The MS/MSD RPD was outside of accepted recovery limits.
QV-/+
The ICV recovery failed low (-) or high (+).
S
The spike result was outside of accepted recovery limits.
Z
Deviation; A deviation from the method was performed; Please refer to the Case Narrative for
additional information
Acronyms
ND
Not Detected RL Reporting Limit
QC
Quality Control MDL Method Detection Limit
MB
Method Blank LOD Level of Detection
LCS
Laboratory Control Sample LOQ Level of Quantitation
LCSD
Laboratory Control Sample Duplicate PQL Practical Quantitation Limit
QCS
Quality Control Sample CRQL Contract Required Quanfitation Limit
DUP
Duplicate PL Permit Limit
MS
Matrix Spike RegLvl Regulatory Limit
MSD
Matrix Spike Duplicate MCL Maximum Contamination Limit
RPD
Relative Percent Different MmCL Minimum Compound Limit
ICV
Initial Calibration Verification RA Reanalysis
ICB
Initial Calibration Blank RE Reextractio t
CCV
Continuing Calibration Verification TIC. Tentatively Identified Compound
CCB
Continuing. Calibration Blank RT Retention Time
RLC
Reporting Limit Cheek CF Calibration Factor
DF
Dilution Factor RF Response Factor
and Acronyms for reporting.
Please refer to the Analytical Nates in the Case Narrative for any Qualifiers or Acronyms that do not appear in this
list or for additional information regarding the use of these Qualifiers on reported data.
Original
Page 3 of 28

R] 0SUIA1617
"WIRONMENTAL TECltNOLOcieS, INQ
Anallyteral Labm'arot7e5
CLIENT: Synagro
Project: Statesville
Summit Environmental Technologies, Inc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FIX: [phone]
Website: hua'/hviviv.settekcom
Workorder
Sample Summary
WO#: 18030036
T 5 -Mar -I S
Lxb SamplelD
Client Sample ID
Tag No
Date Collected
Dafe Received
Matrix
18030036-001
3rd Creek W WTP
2/28/2018 8:00:00
AM
3/1/2018 10:20:00
AM
Sludge
Page 4 of 28

SUMMIT smmr;ICmmm,m ,,n,T hnal3310 Re10WinorSt. DATES REPORT
Sl.
ENNIRONIAENTAL TECNNOWOIES, INC, Cvyahatia Fal A,, Oh;o 4.1223
WHO: 18030036
Arse/Meal Lff"rstndee TEL: [phone] FAX. [phone]
McA.sile: hnn'fheure:.senek.com I5-Mrar4li
Client: Synagro
Project•. Statesville
Sample ED Client SampleID Collection Date Mntria Test Name
Len.Fnte Dnte
Prep Date
Analysis Dale
18030036-OOIA 3rd Creek WWTP 2/28/20186x00:00 AM Sludge Ignilability of Solids (SW -M6:1030)
3/2/20181-45:00
PM
PH (SW9045D)
3/14/2018 8:00
00 PM
Reactive Cyanide (9014/7.3.3.2) -Solid
3/8/2018 4:06:00
PM
Reactive Sulfide (9034)/7.3.4.2
3/8/2018 4:06:00
PM
TCLP Herbicides Analysis (SWI 311/83/120186: 00: 00 PM
3/7/2018.2: 30:
00 PM
3/12/20188: 29:
00 PM
TCLP Mercury Analyst a(SWI 311f1473/1/20186:00X0 PM
3/5/2018 I1: 50: 00 AM
3/5/20185:27x00
PM
TCLP Metals Analysis (SW1311/60103/1/20186:90:OO PM
3/2/20189: 05:
00 AM
3/6/20187:3908
PM
TCLP Pesticides Analysis(SW13 I IM(3/12(1186:00:00 PM
3/5/20167: 00.00
AM
3/6/2018133:00
PM
TCLP Semi -Volatiles Analysis 3/1/2018 6:00:00 PM
3/5/2018 8 00:00
AM
3/6/2018 9:42:00
PM
(SW131118270)
TCLP Volatiles Analysis
3/1/20186: 00:
00 PM
3/2/20186:39:00
PM
Original
Page 5 of 28

summinSamnur&n,irnametalTechnologies, Inc. 3310 Win St. Analytical Report
FNVIR6NMENTALTECHNCLOOIES, iNC Cuyahoga Falls, Ohio 44223 (basereport)
Analyriral taboradrrJes TEL: [phone] FAX: [phone] WO#: 18030036
Website: htw /Rvrvrvserrekcom Date Reported: 3/15/2018
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 2/28/20188:00:00 AM
Lab ID: 18030036-OOIA
Project: Statesville
Client Sample ID 3rd Creek W WTP
Analyses
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
Result
RL Qual
Units
DF
Date Analyzed
TCLP METALS, VOC, BNA,
PEST, HERB -SOLID
SW7470A
SW7470A Analyst:
EAM
TCLP MERCURY ANALYSIS (SW131117470)
1,4 -Dichlorobenzene
ND
0.0800
mg/L
TCLP Mercury
ND
0.00200
mg/L
1
3/5/2018 5:27:00
PM
TCLP METALS, VOC, BNA,
PEST, HERB -SOLID
2
SW6010D
SW301OA
Analyst:
KMS
TCLP METALS ANALYSIS (SW1311/6010)
NO
0.200
mg/L
2
316/20189:42:00
TCLP Arsenlc(As)
ND
0.500
mg/L
1
3/6/2018 7:39:08
PM
TCLP Barium(Ba)
ND
5.00
mg/L
1
3/6/2018 7:39:08
PM
TCLP Cadmium(Cd)
ND
0.100
mg/L
1
3/6/2018 7:39:08
PM
TCLP Chromium(Cr)
ND
0.200
mg/L
1
3/6/2018 7:39:08
PM
TCLP Lead(Pla)
ND
0.500
mg/L
1
3/6/2018 7:39:08
PM
TCLP Selenium(Se)
ND
0.0500
mg/L
1
3/6/2018 7:39:08
PM
TCLP Silver(Ag)
ND
0.500 QC+
mg/L
1
3/6/2018 7:39:08
PM
NOTES:
mg/L
2
3/6/2018
9:42:00
PM
Silver failed the CCV high, but
because the sample was
nondetect for silver it can
be accepted.
2
3/6/2018
9:42:00
Qualifiers: �
Value exceeds Maximum Contaminant Level.
SW8270D
SW3510C Analyst:
BJH
TCLP SEMI -VOLATILES ANALYSIS (SW1311/8270)
1,4 -Dichlorobenzene
ND
0.0800
mg/L
2
3/6/2018
9:42:00
PM
2,4,5 -Trichlorophenol
ND
0.200
mg/L
2
3/6/20189:42:00
PM
2,4,6 -Trichlorophenol
NO
0.200
mg/L
2
316/20189:42:00
PM
2,4-Dinitrotoluene
ND
0.0400
mg/L
2
3/6/20189:42:00
PM
o -Cresol
ND
0.200
mg/L
2
3/6/2018
9:42D0
PM
m/p-Cresols)
0.272
0.200
mg/L
2
3/6/2018
9:42:00
PM
Cresols, Total
ND
4.00
mg/L
2
3/6/2018
9:42:00
PM
Hexachloro-1,3-butadiene
ND
.0.0160
mg/L
2
3/6/2018
9:42:00
PM
Hexachlorobenzene
ND
0.0400
mg/L
2
3/6/2018
9:42:00
PM
Hexachlomethane
ND
0.0800
mg/L
2
3/6/2018
9:42:00
PM
Nitrobenzene
ND
0.0800
mg/L
2
316/2018.9:42:00
PM
Pentachlorophenol
ND
0.200
QC+ mg/L
2
316/20189:42:00
PM
Pyridine
NO
0.200
QC+ mg/L
2
3/6/2018
9:42:00
PM
Surr: 2-Fluorophenol
40.4
10-109
( Rec
2
3/6/2018
9:42:00
PM
Surr: Phenol -d6
18.3
10-109
% Rec
2
3/6/2018
9:42:00
PM
Surr; Nitrobenzene -d5
67.0
19-120
% Rec
2
3/6/2018
9:42:00
PM
Qualifiers: �
Value exceeds Maximum Contaminant Level.
H
Holding times for preparation or analysis exceeded
MC
E Value above quantitation range
Value is below Minimum Compound Limit.
ND Not Detected
P Second column confirmation exceeds
R RPD outside accepted recovery limits
M Manual Integration used to determine area response
N Tentatively identified compounds
O RSD is greater than RSDlimit
PL Permit Limit Original
RI. Reporting Detection Limit
Page 6 of 28

�� ��� Sanaa;tEnv;ronnienfalTee in3310WinSt. Analytical Report
ffJ 33]0 Win St.
rN1nRONNIENTAL TECHNOLOGIES, INc Cuyahoga Falls, Ohio 44223 (base report)
Analytical Laboralooec TEL.: [phone]// FAX: [phone] WO#: 18030036
Website: Into //wwwsenek.com Date Reported: 3/15/2018
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 2/28/20188:00:00 AM
Lab ID: 18030036-OOIA
Project: Statesville
Client Sample ID 3rd Creek WWTP
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP SEMI -VOLATILES ANALYSIS (SW131118270)
SW8270D SW3510C Analyst: BJH
Surr. 2,4,6-Tribromophenol 39.9
10 - 120
%Rec
2 3/6/2018 9:42:00
PM
Surr. 2-Fluorobiphenyl 63.8
22-117
%Rec
2 3/6120189:42:00
PM
Surr: p-Terphenyl-d14 71.1
34-116
%Rec
2 316/20189:42:00
PM
NOTES:
CCV exhibited high recovery for Pentachlorophenol and Pyridine.
Associated
samples are ND for
Pentachlorophenol and Pyridine.
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8081
SW351OC Analyst:
JBN
TCLP PESTICIDES ANALYSIS (SW131118081)
Chlordane, total NO
0.0200
mg/L
2 3/6/2018 1:33:00
PM
Toxaphene ND
0.0400
mg/L
2 3/6/2018 1:33:00
PM
Endrin ND
0.00200
QL+
mg/L
2 3/6/2018 1:33:00
PM
gamma -BHC ND
0.00200
QL+
mg/L
2 3/6/2018 1:33:00
PM
Heptachlor ND
0.00200
QL+
mg/L
2 3/6/20181:33:00
PM
Heptachlor epoxide NO
0.00200
QL+
mg/L
2 3/6/20181:33:00
PM
Methoxychlor NO
0.00200
QL+
mg/L
2 3/6/2018 1:33:00
PM
Burr: TCMX 59.4
10-119
%Rec
2 3/6/2018 1:33:00
PM
Burr: DCB 46.5
10-119
%Rec
2 3/6/2018 1:33:00
PM
NOTES:
LCS recovery biased high; associated sample results are N.D.
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8151A
SW8151A Analyst:
JBN
TCLP HERBICIDES ANALYSIS (SW1311/8151)
214-D NO
1.00
mg/L
1 3/12/2018 8:29:00
PM
21475 -TP ND
0.500
d
mg/L
1 3/12/2018 8:29:00 PM
Surr,. DCAA 92.5
20-140
%Rec
1 3/12/2018 8:29:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8260B
SW1311M Analyst:
CTB
TCLP VOLATILES ANALYSIS
1,1-Dichloroethene NO
0.0500
mg/L
10 312/20186:39:00
PM
1,2-Dichloroethane NO
0.0500
mg/L
10 3/2/2018 6:39:00
PM
MEN 2.76
0.250
mg/L
10 3/2/2018 6:39:00
PM
Benzene ND
0.0500
mg/L
10 3/2/2018 6:39:00
PM
Qualifiers: * Value exceeds Maximum Contaminant Level.
E Value above quantitation
range
H Holding times for preparation or analysis exceeded
M Manual Integration used to determine area response
MC Value is below Minimum Compound Limit.
N Tentatively identified compounds
NO Not Detected
O RSD is greater
than RSDlimit
P Second column confirmation exceeds
PL Permit Limit
Original
R RPD outside accepted recovery limits
RL Reporting Detection Limit
Page 7 of 28

UM 1 01 Summit Environmental Technologies, Inc. Analytical Report
3310 Win St.
FrkVIRDNhIEN'rALIECkNOLOGIE5,INC. Cuyahoga Falls, Ohio 44223 (base report)
Analytical Leborelurum TEL: [phone] FAX: [phone] WO#: 18030036
Website; hup.,1Avwlv.settek.com Date Reported: 3/15/2018
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 2/28/20188:00:00 AM
Lab ID: 18030036-OOIA
Project: Statesville
Client Sample ID 3rd Creek W W TP
Analyses
Result RL Qual Uuits DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP VOLATILES ANALYSIS
SW8260B SW1311M Analyst: CTB
Carbon tetrachloride ND
0.0500
mg/L
10
3/2/2018 6:39:00
PM
Chlorobenzene ND
0.0500
mg/L
10
3/2/20186:39:00
PM
Chloroform ND
0.0500
mg/L
10
3/2/20186:39:00
PM
Tetrachlomethene ND
0.0500
mg/L
10
3/2/2018 6:39:00
PM
Trichloroethene ND
0.0500
mg/L
10
3/2/2018 6:39:00
PM
Vinyl chloride ND
0.0200
QC+ mg/L
10
3/2/2018 6:39:00
PM
Surr: 4-Bromofluorobenzene 109
70-130
%Rec
10
3/2/2018 6:39:00
PM
Surr: Dibromotluoromethane 91.6
70-130
%Rec
10
3/2/2018 6:39:00
PM
Surr: Toluene -d8 102
70-130
%Rec
10
3/2/20186:39:00
PM
NOTES:
The VOC CCV (Batch R81286) exhibited high recovery for Vinyl
chloride;
Associated samples are
ND for Vinyl
chloride.
RCI -SOLID -W/ IGNITABILITY1030
SW9014
Analyst:
MS
REACTIVE CYANIDE (9014/7.3.3.2) -SOLID
Cyanide, Reactive ND
0.500
mg/Kg
1
3/8/2018 4:06:00
PM
RCI-SOLID-W/IGNITABILITY1030
SW1030
Analyst:
AJT
IGNITABILITY OF SOLIDS (SW -846:1030)
Ignitability non-flammable
1
3/2/2018 1:45:00
PM
RCI -SOLID -W/ IGNITABILITY1030
SW9045D
Analyst:
CXS
PH (SW9045D)
pH 6.4
s.u.@19.7°C
1
3/14/2018 8:00:00 PM
RCI -SOLID -W/ IGNITABILITY1030
SW9034
Analyst:
MS
REACTIVE SULFIDE (9034)/7.3.4.2
Sulfide, Reactive ND
25.0
mg/Kg
1
3/8/2018 4:06:00
PM
Qualifiers: * Value exceeds Maximum Contaminant Level.
E Value above quantitation
range
H Holding times for preparation or analysis exceeded
M Manual Integration used to determine area response
MC Value is below Minimum Compound Limit.
N Tentatively identified compounds
ND Not Detected
0 RSD is greater
than RSDlimit
P Second column confmnation exceeds
PL Permit Limit
Original
R RPD outside accepted recovery limits
RL Reporting Detection Limit

ITSU 10�� Summit Environmental Technologies, Inc. Accreditation Program
3310 Win St. Analytes Report
rNVIRONMENI'AL 1PO3SNOLOGI-c S,�NC Cuyahoga Falls, Ohio 44223 J P
ArralyNcnl t-nhnratWh9a TEL: [phone] FAX. [phone] WO#: 18030036
Website: hua //wulio.settekeom 15 -Mar -18
Client: Synagro State: NW
Project: Statesville Program Name: NC WWSCM
Sample ID Matrix Test Name Analyte Status
18030036-OOIA Sludge
Igtdfability of Solids (SW -846:1030)
Ignitabllity
A
Sludge
pH (SW9045D)
Hydrogen Ion (pH)
A
Sludge
Reactive Cyanide (9014/7.3.3.2) -Solid
Cyanide, Reactive
U
Sludge
Reactive Sulfide (9034)/7.3.42
Sulfide, Reactive
U
Sludge
TCLP Herbicides Analysis (SWI 311/8151)
27425 -TP
A
Sludge
TCLP Herbicides Analysis(SW1311/8151)
234-D
A
Sludge
TCLP Herbicides Analysis (SWI 311/8151)
DCAA
A
Sludge
TCLP Mercury Analysis(SW1311/7470)
Mercury
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Arsenic
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Barium
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Cadmium
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Chromium
A
Sludge
TCLP Metals Analysis (SW 1311/6010)
Lead
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Selenium
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Silver
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
2,2',3,3',4,4',5,5',6,6'-
A
Decachlorobiphenyl
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
Chlordane, total
A
Sludge
TCLP Pesticides Analysis (SWI 311/8081)
Endrin
A
Sludge
TCLP Pesticides Analysis(SWI 311/8081)
gamma -BHC
A
Sludge
TCLP Pesticides Analysis (SW 1311/8081)
I-lepmchlor
A
Sludge
TCLP Pesticides Analysis (SW1 311/808 1)
Heptachlor epoxide
A
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
Methoxycldor
A
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
Tetrachloro-m-xylene
A
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
Toxaphene
A
Sludge
TCLP Senrallolatiles Analysis (SW1311/8270)
1,4-Dichlorobenzeno
A
Sludge
TCLP Semi -Volatiles Analysis (SW1311/8270)
2,4,5 -Trichlorophenol
A
Sludge
TCLP Semi -Volatiles Analysis (SW1311/8270)
2,4,6-Ttibromophenoi
A
Sludge
TCLP Semi -Volatiles Analysis (SW1311/8270)
2,4,6 -Trichlorophenol
A
Sludge
TCLP Semi -Volatiles Analysis (SW1311/8270)
2,4-Dinitrotoluene
A
Sludge
TCLP Semi -Volatiles Analysis (SW1311/8270)
2-Fluorobiphenyl
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
2-Fluoropbenol
A
Key
Key
NC WW SCM A Accredited
NC WW SCM U Unavailable
Version #2
Page 9 of 28

summit Environmental Technologies, Inc. Accreditation Program
N U ' T
3310 Win st. Analytes Report
r WIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223
.Analytical Laboratarles TEL: [phone] FAX. [phone] WO#: 18030036
Website: htto:/hvivm.settek.com 15 -Mar -18
Client: Synagro. State: NW
Project: Statesville Program Name: NC WW_SCM
Sample ID Matrix Test Name Analyte Status
18030036-001A Sludge TCLP Semi -Volatiles Analysis(SW1311/8270) 2-Methylpbenol A
Sludge TCLP Semi -Volatiles Analysis(SW1311/8270) 3,4-Methylphenol A
Sludge TCLP Semi -Volatiles Analysis (SW 1311/8270) Cresols, Total A
Sludge TCLP Semi -Volatiles Analysis (SW1311/8270) Hexachlorobenzene A
Sludge TCLP Semi -Volatiles Analysis (SW l31 t/8270) Hexachlorobutadiene A
Sludge TCLP Semi -Volatiles Analysis (SW 1311/8270) Hexachloroethane A
Sludge TCLP Semi -Volatiles Analysis(SW1311/8270) Nitrobenzene A
Sludge TCLP Semi -Volatiles Analysis(SW1311/8270) Nitrobenzene -d5 A
Sludge TCLP Serni-Volatiles Analysis(SW1311/8270) Pentachlorophenol A
Sludge TCLP Seini-Volatiles Analysis(SW1311/8270) Phenol -d6 A
Sludge TCLP Semi -Volatiles Analysis(SW1311/8270) p-Terphenyl-d14 A
Sludge TCLP Semi -Volatiles Analysis(SW1311/8270) Pyridine A
Sludge TCLP Volatiles Analysis 1,1-Dichloroethene A
Sludge TCLP Volatiles Analysis 1,2-DieWoroethane A
Sludge TCLP Volatiles Analysis 2-Butanone A
Sludge TCLP Volatiles Analysis 4-Bromofluorobenzene A
Sludge TCLP Volatiles Analysis Benzene A
Sludge TCLP Volatiles Analysis Carbon tetrachloride A
Sludge TCLP Volatiles Analysis Chlorobcnzeuc A
Sludge TCLP Volatiles Analysis Chloroform A
Sludge TCLP Volatiles Analysis Dibromofluoromethane A
Sludge TCLP Volatiles Analysis Tetrachloroethene A
Sludge TCLP Volatiles Analysis Toluene -d8 A
Sludge TCLP Volatiles Analysis Trichloroethene A
Sludge TCLP Volatiles Analysis Vinyl chloride A
NC_WW_SCM A Accredited NC_WW_SCM U Uuavailable
Version #2
Page 10 of 28

S:)MMIi sten;ra 33J0ia,a„aalTaeln3310sOm. QC SUMMARY REPORT
Piri 3l.
fNVIPbN14FNTgL TECBNOLDnIE6, tNr C'uyahaga Falls, 01do 44223
Atyalyllcel LgSnnitllles ZEL: [phone] FAX. [phone] WQ (8030036
Website: hero !/� n senekca 75-Mrrt-IS
Client: Synagro
Project: Statesville BatchlD: 31107
Sample ID
10
ND
0.0500
1,2-Dichloroethane
ND
0.0500
MEEK
ND
0.250
MB -17107
SampType:
MBLK
TeslCoda:
tclp-voc-msU Units: mglL
Prep Date: 3/1/2018
RunNo: 61266
Client IM
PBS
Batch ID:
31107
TestNo:
SW8260B SWIMIM
Analysis Date: 3/212016
Sari 1439966
Analyte
ND
0.0500
Result
PQL
SPKvalue SPKRef Val
%REC LowLlmit Highl.imil RPDRef Val
%RPD RPDLimit Qual
1-Oichlaroethene
ND
0.0500
1,2-Dichloroethane
ND
0.0500
MEEK
ND
0.250
Benzene
ND
0.0500
Carbon tetrachloride
ND
0.0500
Chlorobenrene
ND
0.0500
Chloroform
ND
0.0500
Temachlaroetherne
ND
0.0500
Trichloroethene
ND
0.0500
Vinyl chloride
ND
0.0200
Surr: 4-Bromofluorobenzene
%0
SPKvalue SPK Ref Val
Sun: Dibromofluoromethane
489
RPDUmft Qual
Surr Toluene48
504
500.0
112
70
130
500.0
97.8
70
130
500.0
101
70
130
QC+
1,1-0ichloroelhene
0.199'
0.0500
39.9
Sample lD
18030033-0OtaMS
SampType:
MS
TestCode:
fclpvoc-mstr Units: mg/L
Prep Date:
RunNo:
81288
Client ID-
BatchOC
Balch ID:
31107
TestNo:
SW82605 SW1311M
Analysis Dale: 3/212018
eq o:
1440508
Analyte
Result
PQL
SPKvalue SPK Ref Val
%REC Lowl-imit HiBhLimit RPDRef Val
%RPD
RPDUmft Qual
1,1-0ichloroelhene
0.199'
0.0500
39.9
0.200
D
99.3
39.9
e detected below quenamtion limits
M] Not Detected
PL Permit Limit
160
157
227
155
E Value above quantita0on range
M Manual lntegratim used to determine
O RSD is greeter than RBDllmit
R RPD omside accepted recovery limits
Original
Page 11 of 28

SVMM17 s.,»,nr;rr,..o-or»enfnrrhna310w in St. QC SUMMARY REPORT
33x9 win sr.
ENVINCNIAENTAI.TECHNOLOOz&, MC Cuyahoga Falls, Ohio 44223
Ahalyflcal LebOraforlcr 7E/,: WQR: 18030036
[phone] FAX.. [phone]
Webs;re: hun./Acmmr.senek.dom 15-MarvlR
Client: Synagro
Project: Statesville Batchll): 31107
Sample ID 10030033-001
Carbon tetrachloride 0.177 0.0500 0.200 0 88.7 40.8 162
Chi arob enzene 0208. 0.0500 0200
Sample lD
aMS
SampType:
MS
TeslCode:
tclp-voc-msM Units: mg/L
Prep Dale:
RunNo: 61266
Client ID:
BatchQC
Batch ID:
31107
TeslNo:
SW8260B SW1311M
Analysis Date: 3IV2018
SegNo: 1440506
Analyte
0:176
0.0500
Result
PQL
SPKvalue SPKRefVal
%REC LowUrnit HighLimit RPDRef Val
%RPD RPDLhnil Qual
1,1-Dienloroetrrene 0n91 0.0500
Sample lD
73030033-001aMSD
SampType:
.
0
104
35.7
168
Chloroform
0.210
0.0500
0.200
0
105
18.3
199
Tetrachloroethane.
0:176
0.0500
0.200
0
88.2
10
261
Trichloroethene
0.207
0.0500
0.200
0
104
23.8
175
Vinyl chloride.
0.231
0.0200
0.200
0
116
10
165 QC+
Sum 4-Bromofluorobenzens
558
500.0
112
84.6
130
Surr. Dlbromofluoromalhane
508
500.0
102
71.4
127
Sum Toluene -d8
508
500.0
102
74.6
127
1,1-Dienloroetrrene 0n91 0.0500
Sample lD
73030033-001aMSD
SampType:
MSD
Tes(Cetle:
tclp-vac-mstr Units: mglL
Prep Date:
RunNo: 81286
Client ID:
Batch=
Batch ID:
31107
TestNo:
SW8260B SW1311M
Analysis Date: 3/2/2018
SegNo: 1440509
Analyte
Result
PQL
SPK value SPK Ref Val
%REC LowUrnit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1,2-Oichloroethane 0.193 0,0500
MEK 2.08 0.250
Benzene 0.213 0.0500
Carbon tetrachloride 0.177 0.0500
Chlorobenzene 0.207 0.0500
Chloroform 0.199 00500
TetracNomethene 0.176 0.0500lifi
Quaers: ' Value exceeds Maximum Contaminant Level.
H Holding times for preparation or analysis exceeded
MC Value is belowMrrimum Compound Limit.
P Second column confirmation exceeds
0.200 0 95.3 39.9
0.200 o 96.7 42.5
1.00 1.08 99.5 16.6
0200 0 106 38.1
0.200 0 885 40.8
0.200 0 103 357
0.200 0 99.4 18.3
0.200 0 87,8 10
8 Maly[edetected indie associated Method Blank
M
! elyfe detected below quantitati
on limits
ND Not Detected
PL Permit Limit
760 0.199 4.11 25
157 0.197 2.00 25
227 2.06 0.967 25
755 0.225 5.57 25
162 0.177 0.226 25
168 0.208 0.867 25
199 0.210 5.48 25
261 0.176 0.455 25
E Valueabove quan
fim0on range
M Manual Integration used to determine
O RBD isb eater than RSDlimit
R RPD outside accepted recovery limits
Original
Page 12 of 28
0.200 0 95.3 39.9
0.200 o 96.7 42.5
1.00 1.08 99.5 16.6
0200 0 106 38.1
0.200 0 885 40.8
0.200 0 103 357
0.200 0 99.4 18.3
0.200 0 87,8 10
8 Maly[edetected indie associated Method Blank
M
! elyfe detected below quantitati
on limits
ND Not Detected
PL Permit Limit
760 0.199 4.11 25
157 0.197 2.00 25
227 2.06 0.967 25
755 0.225 5.57 25
162 0.177 0.226 25
168 0.208 0.867 25
199 0.210 5.48 25
261 0.176 0.455 25
E Valueabove quan
fim0on range
M Manual Integration used to determine
O RBD isb eater than RSDlimit
R RPD outside accepted recovery limits
Original
Page 12 of 28
on limits
ND Not Detected
PL Permit Limit
760 0.199 4.11 25
157 0.197 2.00 25
227 2.06 0.967 25
755 0.225 5.57 25
162 0.177 0.226 25
168 0.208 0.867 25
199 0.210 5.48 25
261 0.176 0.455 25
E Valueabove quan
fim0on range
M Manual Integration used to determine
O RBD isb eater than RSDlimit
R RPD outside accepted recovery limits
Original
Page 12 of 28
fim0on range
M Manual Integration used to determine
O RBD isb eater than RSDlimit
R RPD outside accepted recovery limits
Original
Page 12 of 28

�i S%mm"E 117 sn„m1„amvmnanal alm310W.ha. QC SUMMARYItEPORT
99 II 1I 3310 Tym 1'I.
ENVIRONMENTAL TECRNOLO ISS INC Cuyahoga Fallx, Ohio 44223
Ahaly0"I tnboraloNes TEL.' [phone] FAX... [phone] V✓O#: 18030030
Websile: hm.1h, senekea 15-MprvI8
Client: Synagro
Project: Statesville BatchID: 31107
Sample l0 18030033-001aMSD SampType: MSD TeslCotle: tclp.voc-mstr
Trichloroethene 0.194 0.0500 0.200 0 97.0 23.8 175 0.207 6.48 25
Vinyl chloride 0.213 0.0200 0200
Value ce ds Maxim mContaminantievel.
H
Melyte detected in Ore ass eted Method Blenb
H
Holding times [orpreparedon or analysis exceeded
I
Mely[e detected below quendtadon limits
MC
Valueu below Mini mum Compound Li mit
.
0 106
10
Units: mgiL
Prep Dale:
RunNo: 81286
MentlD:
BatchQC
Batch ID:
31107
Testida
SW8260B SW13111A
Moysis Date: 3/2/2018
SegNo: 1440509
Analyte
491
500.0
Result
PQL
SPKvalue SPKRef Val
%REC LowUmil Highl-imlt RPD Ref Val
%RPD RPDLimh Qual
Qualifiers: t E Vnlue above quandtation range
M Manusl lntegredon used to determine
Original
D tiSD is area torthan RSDlimit
R RPD outside accepted recovery limits
Value ce ds Maxim mContaminantievel.
H
Melyte detected in Ore ass eted Method Blenb
H
Holding times [orpreparedon or analysis exceeded
I
Mely[e detected below quendtadon limits
MC
Valueu below Mini mum Compound Li mit
.
0 106
10
165 0.231
8.28
25 QC+
Sun: 4-Bromofluorobenzene
560
500.0
112
84.6
130
0
25
Surr Dlbromolluorom ethane
491
500.0
98.2
71.4
127
0
25
Sun r Toluen"B
517
500.0
103
74.6
127
0
25
Qualifiers: t E Vnlue above quandtation range
M Manusl lntegredon used to determine
Original
D tiSD is area torthan RSDlimit
R RPD outside accepted recovery limits
Value ce ds Maxim mContaminantievel.
H
Melyte detected in Ore ass eted Method Blenb
H
Holding times [orpreparedon or analysis exceeded
I
Mely[e detected below quendtadon limits
MC
Valueu below Mini mum Compound Li mit
lufl
Not Detected
P
Second column confirmation exceeds
PL
Permit Limit
Page 13 of 28

® S14110IMMt0 rraaherno-aaarerrral ahaamgre.inQC SIIMNIARYREPORT
33/0 kVhr Sf 5'l.
ENVIBONIsENTA4 TECHNOL001_3, INC Oryahoga Palls, Ohio 44223
Attalyllea14a4gMarle€ WO#: 19030036
TKE.(330) 2534211 P(330) 253-4489
AX:
weasue: / rm /Muer ..rehelrmor 15 -Mar -18
Client: Synagro
Project: Statesville BatehlD: 31129
Semple lD 18030036-001ams SampType: ms TestCode: tclpsvoecpe Units: mg/l.
Endrin 0.0134 0.00200 0.0100 0 134
0.0120 0.00200
0.0100 D 120
20
157
20
157
gamma -BHC
0.0123
0.00200
0.0100
0
123
Prep Date: 315/2076
RunNo: 61440
Client to
3rd Creek WWTP
Batch ID:
31129
TestNo:
SW8081 SW3510C
Analysis Date: 3/6/2016
Sachs: 1444091
Analyte
0.0127
0,00200
Result
PQL
SPKvalue SPKRef Val
%REC LowUnnit HighLimit RPDRef Val
%RPD RPDLimit Qual
Methoxychlor
0.0158
0,00200
0.0100
0
155
10
199
Sample ID 18030036-001
0.0120 0.00200
0.0100 D 120
20
157
20
157
gamma -BHC
0.0123
0.00200
0.0100
0
123
22
137
Heptachlor
0.0112
0.00200
0.0100
0
112
24
121
Heptachlor epoxide
0.0127
0,00200
00100
0
127
27
152
Methoxychlor
0.0158
0,00200
0.0100
0
155
10
199
Sum. TCMX
16.3
20.00 69.6
20.00
119
81.3
10
119
Sur. DCB
12.8
2000 67.6
20.00
119
64.2
10
119
Endrin
0.0120 0.00200
0.0100 D 120
20
157
0.0134 10.8
30
gamma -BHC
amstl
SampType:
mstl
TestCede:
tclpswc-cpe Units: mglL
Prep Date: 3/5/2018
RunNo: 81440
ClientlD:
3rd Creek WWTP
Balch ID:
31129
TestNo:
SW8081 SW3510C
Analysis Date: 3/6/2018
SegNo: 1444092
Analyte
0.0113 0.00200
0.0100 0 113
Result
PHIL
SPKvalue SPKRef Val
%REC Lowl-imlt HighLimit RPDRef Val
%RPD RPDLImit Qual
0.0143 0.00200
0.0100 0 143
10
199
0.0158 9.76
30
Surr: TCMX
Endrin
0.0120 0.00200
0.0100 D 120
20
157
0.0134 10.8
30
gamma -BHC
0.0107 0.00200
0.0100 0 107
22
137
0.0123 14.4
30
Heptachlor
0.00992 0.00200
0.0100 0 99.2
24
121
0.0112 12.1
30
Heptachlor epoxide
0.0113 0.00200
0.0100 0 113
27
152
0.0127 11.9
30
Methoxychlor
0.0143 0.00200
0.0100 0 143
10
199
0.0158 9.76
30
Surr: TCMX
13.9
20.00 69.6
10
119
0
Surr. DCB
13.5
2000 67.6
10
119
0
Qualifiers:
a
Valueeseands Maximum Contaminant Level.
B Analy[edecated in the associated Method Blank
E
Value above quantitation range
H
Holding times for preparation or analysis exceeded
S Analyte detected below quantitation limits
M
Manual integration usd to determine
Original
MC
Value is below MNmum Until, mit
ND Not Detected
O
RSD is greater than RSDlimit
P
Second columns confirmation exceeds
PL Permit Limit
R
STT outside accepted recovery limits
Page 14 of 28

® SUMMIT N„mn„rn�a,merralT 33/04fin „ologleSt. QC SUMMARY REPORT
inSl.
ENVIaONNIENTALTECBNOLOOIES, INC Cuyahoga Falls, Ohio 44223 µr08: 18030036
Anal yf tsf Ladbarelarlrr /'tJ.: (330) 253-82]/FAX: [phone]
Website: ryJrpJh �i� evekconr IS-M4rvIR
Client: SynagTo
Project: Statesville BatChTD: 31129
Sample ID mb31129 SampType; mblk TestCotle: tclp-svoc-cps Units' mg/L Prep Date: 315/2098 Rumba:
Chlordane, total NO
0.0100
Toxaphene
ND
0.0200
Endrin
No
0.00100
gamma -BHC
ND
0.00100
Heptachlor
ND
0.00100
Heptachlor epoxltle
ND
81440
Client ID:
PBS
Batch ID:
31129
TesWo:
SW8081
SW3510C
Analysis Date: 3/6/2098
SegNo: 1446923
Analyte
0.0160
0.00100
Result
PQL
SPKvalue
SPKRef Val
%REC Lowl-mit HighHmit RPDRef Val
%RPD RPDLimit Qual
Sample ID Ica -31129
0.0100
Toxaphene
ND
0.0200
Endrin
No
0.00100
gamma -BHC
ND
0.00100
Heptachlor
ND
0.00100
Heptachlor epoxltle
ND
0.00100
Methoxychlor
No
0.00100
Sum TCMX
11.3
20.00 56.7 10 119
Sun: DCB
12.6
20.00 62.6 10 119
Endrin 0.0178 0.00900 0.0100 0 178 20 157 S
gamma -BHC 0.01
Sam pTYpe:
Ics
TestCotle:
tclp-svoc-cpe
Units; mglL
Prep Date: 3/5/2076
RunNo: 81440
Client ID:
LCSS
Batch ID:
31129
Tes1No:
SW8081
SW3510C
Analysis Date: 3/6/2018
SegNo: 1446924
Analyte
0.0160
0.00100
Result
PQL
SPKvalue
SPKRef Val
%REC LowLimit Hlghl-imil RPDRef Val
%RPD RPDUmlt Qual
Page 15 of 28
59
0.00100
0.0100 0 159
22
737
5
Heptachlor
0.0151
000100
0.0100 0 151
24
121
S
Heptachlor epoxide
0.0160
0.00100
0.0100 0 160
27
152
S
Methoxychlor
0.0202
0.00100
0.0100 0 202
10
199
S
Sun: TCMX
20.5
20.00 103
10
119
Sun: DCB
19.2
20.00 96.1
10
119
Qualifters.
t
Value exceeds Maximum Comaminant Level.
B Amlyte detected in the associated Method Blank
E
Value above quantitation range
H
Holding times for prepam0on or analysis exceeded
I Analyte detected below quantitation limits
M
Manuel Imegradon used to detemtine
Original
MC
Value is below Minimum Compound Limit
NO Not Detected
0
RSDissreaterthaRSDlimit
n
P
Second column confirmation exceeds
PL Permit Limit
K
RPD outside accepted recovery limits

SUMMIN crat„m trhnn,,,emalreelmalogieenm. QCSi7MMARYREP0RT
3310 wr» sr.
ENVInON14ENTAL TECNNOLOOt=_6, INC Cuyahoga Falls, Ohla 44223
Artafyllcellaborvfertry
[phone] FkK(330) 253-4489 WOM: 18030030
Websiie: hrrtsl4wmi.seaekcarn 15 -Mar -18
Client: Synagro
Project: Statesville Batch ID: 31138
Sample ID MB -37138 SampType: MBLK TeslCode: HG_TCLP(74 Units: mglL Prep Date: 315/2018 Rumble:
P Mercury
NO O.OD200
P Mercury
Sample to
LG531138
SampType:
LCS
TeslCode:
HG_TCLP(]4 Units: mglL
Prep Date: 316/2018
ROnNo: 81362
Client to:
61362
Client ID:
PBS
Balch ID:
31138
TestNo:
SW7470A SW7470A
Analysis Date: 3/5/2018
SegNo:
1442191
Analyte
PQL
SPKvalue SPK Ref Val
Result
PHIL
SPKvalue SPKRaf Val
%REC LowLlmil HlghL!mit RPDRef Val
%RPD RPDLimit Dual
P Mercury
NO O.OD200
P Mercury
Sample to
LG531138
SampType:
LCS
TeslCode:
HG_TCLP(]4 Units: mglL
Prep Date: 316/2018
ROnNo: 81362
Client to:
LCSS
Batch ID:
31138
TestNo:
SW7470A SW7470A
Analysis Date: 31512018
Seattle: 1442193
Analyte
Result
PQL
SPKvalue SPK Ref Val
%REC Lowl-nil HighLimit RPD Ref Val
%RPD RPDLImit Qual
0.00408 0.00200 0.00400 0 102 00 120
-P Mercury
Sample ID
18021390-OOtAMS
SampType:
MS
TeslCode:
HG_TCLP(74 Units: mg/L
Prep Data: 3/5/2018
RunNo: 81362
Client ID:
BatchQC
Batch ID:
31138
TestNo:
SW7470A SW7470A
Analysis Date: 315/2018
SegNo: 1442195
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLimit HighLimit RPDRef Val
%RPD RPDLimit Qual
0.00441 0.00200 0.00400 0.0000700 108 75 125
Sample ID
TCLP Mercury
18021390-001AMSD
SampType:
MSD
TeslCode:
HG_TCLP(74 Units: mglL
Prep Dale: 3/5/2018
RunNo: 81362
Client ID:
BatchQC
Batch ID:
31138
TestNo:
SW7470A SW7470A
Analysis Dale: 3/5/2018
eq 0: 7442796
Analyte
Result
PQL
SPKvalue SPK Ref Val
%REC Lowl-imit HighLimit RPDRef Val
%RPD RPDLimit Dual
0.00437 0.00200 0.00400 0.0000700 100 75 125 0.00441 0.911 20
Quaers: � Valueezceeds lvfavmnm Contaminant Levei. H Maly[e detected in8m associated Method Hlank E Value above queutitafion mage
H Holding times for preparation or analysis exceeded 1 Anal}le detested below quanfiVnion limits M Ma¢nel lntegmtion used to determine
MC Value is tielowMinimum Compouvd limit. ND Not Detected O RSD is We
than RSDlimit Original
P Second column confirmafion exceeds PL Permit Limit K RPD outside accepted mcoverylirits
Page 16 of 28

®l02"MI7 saarmlt h rnmenlGlTeahr331OFmSI.
kVIHONMEWAL
QC SUMMARY REPORT
TCCHNOLOOIES, INC Cuyahoga Falls,, Ohio 44223 WOh: 18030036
ArnalyticallebWaferles MI: [phone] FAX..-[phone]
WoWte: hO,1Aga enekcom 15-Man18
Client: Synagno -
Project: Statesville BatchID: 31138
Sample ID 18021390401AMSD SampType: MSD TestCode: HG_TCLPl74 Units;
Qualif rs: ' Vnlue exce ds Maximum Contaminant Level. B Maly[e detected inthe associated Method Hlank E Value above quantitation range
H Holding timesfor preparation or analysis exceeded I Analy[e dnected below quantitation limits M Manuat lntegraVon used fo determine
MC Valueis belowMinimum Compeund Limi[. ND No[Delected O RSD is grenterthan RSDlimi[ Original
P Second column conflrmation exceeds PL Permit Limit R RPDoInzideacceptedrecoverylimus
Page 17 of 28
mglL
Prep Date: 3/5/2018
RunNo:
87392
Client ID:
BatchQC
Batch ID:
31138
TestNo:
SW7470A
SW7470A
Analysis Date: 3/5/2018
SegNo:
1442196
Analyte
Result
PQL
SPK value SPK Ref Val
%RBC Lowl-mat Highl-imit RPD Ref Val
%RPD RPDLimit Qual
Qualif rs: ' Vnlue exce ds Maximum Contaminant Level. B Maly[e detected inthe associated Method Hlank E Value above quantitation range
H Holding timesfor preparation or analysis exceeded I Analy[e dnected below quantitation limits M Manuat lntegraVon used fo determine
MC Valueis belowMinimum Compeund Limi[. ND No[Delected O RSD is grenterthan RSDlimi[ Original
P Second column conflrmation exceeds PL Permit Limit R RPDoInzideacceptedrecoverylimus
Page 17 of 28

�/ �'UMMI� �"nm;l�r��.o,e„N,ralzaehaamrnea,hl�. QC SUMMARYR�+PORT
1 I 1 3310 Win SI.
ENVISONI9ENTAL TECHNOLOGIES, INC. Cuyahoga Falls, Ohio 44223 µ/07k: 18030036
Aryalp-float l aberattar m 7Ni.: (330) 2534211 FAX.' (330) 2534489
/e bade:) NPYAVIP arellek.com IS -Mar -18
Client: Synagro
Project: Statesville Batl 31196
2,4-D
Sample ID hes-31196 SampType; Ics TestCode: tclp�s
ND
1.00
0
0
2,4,5 -TP
ND
0.500
0
Sample ID
tab -31198
SampType:
mblk
TestCode:
tclpswc-her Units: mglL
Prep Date: 317/2018
RunNo:
81649
ClientlD:
PBS
Balch ID:
31196
TestNo:
SW8151A SW8151A
Analysis Dale: 3/1212018
SegNo:
1453716
Maybe
H
Result
PQL
SPKvalue SPKRef Val
%REG LowLimit HighLimit RPDRef Val
%RPD
RPDLimlt Goal
2,4-D
Sample ID hes-31196 SampType; Ics TestCode: tclp�s
ND
1.00
0
0
2,4,5 -TP
ND
0.500
0
0
Surf. DCAA
480
500.0
83.0
96.0 20 140
244-D ND 1.00 0:500 0 81.5 62.6 125
2,43
5 -TP
ND
0.500
0.500
0
83.0
vacher
Units: mglL
Prep Dale: 3/7/2016
RunNo: 81649
Client ID:
LCSS
Batch ID:
31196
TestNo:
SW8151A
SW8151A
Analysis Date: 31ID2018
SegNo: 1453717
Analyte
H
Result
PQL
SPKvalue
SPK Ref Val
%REC LowUmit Hight.imlt RPD Ref Val
%RPD RPDLimlt oust
Sample ID 18030036401
5 -TP
ND
0.500
0.500
0
83.0
52.5
128
Surr: DCAA
483
Client ID
500.0
Batch ID:
96.5
20
140
2,40 NO 1.00 0.500 0 790 37 105
2,415 -TP NO
0.500
ams
SampType:
ms
TestCode:
tclp-svoc-her
Units: mglL
Prep Date: 317/2018
RunNo: 81649
Client ID
and Creek WWTP
Batch ID:
31196
TestNo:
SW8151A
SW8151A
Analysis Date: 3/1212018
SegNo: 1453719
Analyte
H
Result
PQL
SPKvalue
SPKRef Val
°%REC LowLimit HighLimit RPDRef Val
%RPD RPDLimlt Qual
Page 18
0.500
0500 0 81.0 30
10G
un; DCAA
472
500.0 94.4 20
140
Qualifiers:
Qualifiers:
•
Value exceeds Maximum Contaminant Level.
B
Analyte detected in the associated Medical Blank
11
Value above quantitation range
H
Holding Mmes for preparation or analysis exceeded
I
Malyte detected below quantitation limas
M
Manual lntegamon used to determine
Original
MC
Value is below Minimum Compound Limit
ND
Not Detected
O
RSDismeaterthm RSDiimit
P
Second column continuation exceeds
PL
Permit Limit
R
RPD outside acceptedrecovery limits
of 28

Sunln"MY s»ntatnE »„e„tat em:nms;esh QCSi7MMARYREPORT
33fU Rein Sl.
ENVIRONMENTAL TECIINCLOGI=_S, iHC Cuyahoga Falls, Ohio 44223
Anafytiaal Lnbarsforfrs WON: 18030036
ZEL: [phone] FAX. [phone]
Wehsile: hun:Muuruo.senekcom 15 -Mao -18
Client: 8ynagro
Project: Statesville BatchID: 31196
Sample ID 18030036-001amstl SampType: mstl TestCode: [clpsvoc-her Units: mg/L Prep Date: 317
204-D NO 1.00 0.500 0 05.7 37 105 0 0. 30
2,4,5 -TP NO 0.500 0.500 0 88.4 36 106
Valueexceeda Maximum Contaminant Level.
H
Malyte detected in the associered Metfiod Blank
E
Value above qumtita0oa range
H
Holding times for preparation or analysis exceeded
1
Mel}rte detected below quantitation limits
M
Manual lntegarion used to determine Original
MC
Value is below Minimum Compound Limit
ND
No[Detected
/2018
RunNo: 81649
Client ID:
3rd Creek WWTP
Batch ID:
31196
TestNo:
SW8151A
SW8151A
Malysis Date: W1212018
BegNe: 1453720
Malyte
20
140
Result
PQL
SPK value
SPK Ref Val
%REG Lowl-mit HighLlmit RPD Rat Val
%RPD RPDLimit Qual
Qualifiers: *
Valueexceeda Maximum Contaminant Level.
H
Malyte detected in the associered Metfiod Blank
E
Value above qumtita0oa range
H
Holding times for preparation or analysis exceeded
1
Mel}rte detected below quantitation limits
M
Manual lntegarion used to determine Original
MC
Value is below Minimum Compound Limit
ND
No[Detected
O
RSD is greater than RSDlimit
P
0
0
30
Surr DGM
502
500.0
too
20
140
0
Qualifiers: *
Valueexceeda Maximum Contaminant Level.
H
Malyte detected in the associered Metfiod Blank
E
Value above qumtita0oa range
H
Holding times for preparation or analysis exceeded
1
Mel}rte detected below quantitation limits
M
Manual lntegarion used to determine Original
MC
Value is below Minimum Compound Limit
ND
No[Detected
O
RSD is greater than RSDlimit
P
Second coluumcon&rmatienexceeds
PL
Permit Limit
R
RPD outside accepted recovery limits
Page 19 of 28

®SUMMIT 3331010Wsonm;;Enr;ra,m:eaal�eh„fil hm.
iu S(.
ENVIRONMENTAL TECHNOLOOIEB, INC Cuyahoga Falls, Ohio 44223
ArIWyNeel4aboTaiorles TEL.. [phone] RAX: [phone]
Webece: hr�i senekcem
Clietit: Synagro
Project: Statesville
QC Si7MMARY REPORT
wok: 18030036
15 -Mar -18
Batch1l): R81272
ability 7.96 7.240 0 110 70 130
Sample ID 18021223-001ADUP SampType: DUP TeslCotle: Ignitability
Sample ID
LCS-R87272
SampType;
LCS
TeslCotle:
Ignitablllty_S Units:
Prep Dale:
RunNo: 81272
Client ID:
LCSS
Batch ID:
R81272
TestND:
SW1030
Analysis Dale: 3/212018
SegNo: 1439605
Analyte
No: 1439611
Result
PQL
SPKvalue SPKRef Val
%REG LmLimit HighLimit RPDRef Vel
%RPD RPDLimit Qual
ability 7.96 7.240 0 110 70 130
Sample ID 18021223-001ADUP SampType: DUP TeslCotle: Ignitability
ability
non-flammable.
0 0 20
Sample ID
18021228-0DIADUP
Samptype:
DUP
TestCoda:
_S Units:
Prep Date:
RunNo: 612]2
Client ID:
BatchQC
Batch lD:
R81272
TestNo:
SW1030
Analysis Date: 3/2/2618
SegNo: 1439607
Analyte
No: 1439611
Result
PQL
SPKvalue SPKRef Val
%RFC LowUnnit HighLimit RPDRef Val
%RPD RPDLimit Qual
ability
non-flammable.
0 0 20
Ignilahillly non-flammable 0 0 20
Sample ID 180311033-001ADUP SampType: DUP TeslCotle: Ignitability_S Units: Prep Dale: RunNo: 81272
Client ID: Eaton= Batch ID: R81272 at o: SW1030 Analysis Date: 3/2/2018 Seg
Sample ID
18021228-0DIADUP
Samptype:
DUP
TestCoda:
Ignitability_5 Units:
Prep Date:
RunNO: 81272
Clieni
BakI
Batch ID:
R81272
TestNo:
SW1030
Analysis Date: 31
Santis: 1439609
Analyte
No: 1439611
Result
PQL
SPKvalue SPKRef Val
%REG Lowl-int HighLimit RPDRef Val
%RPD RPDLimit Qual
Ignilahillly non-flammable 0 0 20
Sample ID 180311033-001ADUP SampType: DUP TeslCotle: Ignitability_S Units: Prep Dale: RunNo: 81272
Client ID: Eaton= Batch ID: R81272 at o: SW1030 Analysis Date: 3/2/2018 Seg
Ignitability non-flammable 0 0 20
Qualifiers: ` Value exceeds Maximum Contaminant level. B Melyle defected in the azsaciatN Metfiod Blnnk E Value above quantitation rause
H Holding times for preparation or analysis exceeded S Analyte detected belowquandlation limits
M
Manual lntepFation usN to defersnine
Original
MC no is below Mini mum compost nd[unit.
ND
Not Detecte
sgreaterthan RSDlion
P Second column conB:mation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits
No: 1439611
Analyte
Page 20 of 28
Result
PQL
SPKvalue
SPKRef Val
%REG Lowl-imil HighLimit RPDRef Val
%RPD RPDLImit Owl
Ignitability non-flammable 0 0 20
Qualifiers: ` Value exceeds Maximum Contaminant level. B Melyle defected in the azsaciatN Metfiod Blnnk E Value above quantitation rause
H Holding times for preparation or analysis exceeded S Analyte detected belowquandlation limits
M
Manual lntepFation usN to defersnine
Original
MC no is below Mini mum compost nd[unit.
ND
Not Detecte
sgreaterthan RSDlion
P Second column conB:mation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits
Page 20 of 28

® VMM�� si„m„rrcmrrb,a„emar m33)0 3310 t. QC SUMMARY REPORT
{Vin S/.
ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 WON: 18030036
Analley al Lobe rstovlea 1EL.[phone] FAX' (330) 253-489
Website: ltta'//:inc sevek.coni 15-Mar-18
Client: Synagro
Project: Statesville BatellID: R81272
Sample lD 16030033-001ADUP SampType: DUP TestCade: lgnitability_3 Units: Prep Date: RunNo: 8127
lability
non-flammable
0 0 20
Value eeds Maximum Contaminantlevcl.
B
Analyte detected in the as dated McOmd Hlank
E
4alue above quantitation range
li
Holding times for prepemtioa or analysis excelled
Sample ID
18030036-007ADUP
SampType:
DUP
TestCotle:
Ignitability_S Units:
Prep Dale:
2
Client ID:
BatchQC
Balch ID:
R81272
TestNo:
SW1030
Analysis Dale: 3/2/2018
SegNo: 1439611
Analyte
Result
PQL
SPKvalue SPKRefVal
%RLC LowLimit HighLimit RPDRef Val
%RPD RPDLimit Dual
lability
non-flammable
0 0 20
Value eeds Maximum Contaminantlevcl.
B
Analyte detected in the as dated McOmd Hlank
E
4alue above quantitation range
li
Holding times for prepemtioa or analysis excelled
Sample ID
18030036-007ADUP
SampType:
DUP
TestCotle:
Ignitability_S Units:
Prep Dale:
RunNo: 81272
ClientlD:
3rd CreekWWTP
batch ID:
R81272
TestNo:
SWI030
Analysis Dale. 3/2/2018
SegNo: 1439613
Analyte
Result
PQL
SPKvalue SPKRefVal
%REG LowLimit HighLimit RPDRef Val
%RPD RPDLImit Qual
lability
non-flammable
0 0 20
nitablllty
non-flammable
0 0 20
Qualifiers. *
Original
Page 21 of 28
Value eeds Maximum Contaminantlevcl.
B
Analyte detected in the as dated McOmd Hlank
E
4alue above quantitation range
li
Holding times for prepemtioa or analysis excelled
Sample ID
18030038-001ADUP
SampType;
DUP
TesfCode:
Ignifability_5 Units:
Prep Dale:
RunNo: 81272
Client ID:
BatchQC
Balch ID:
R81272
TestNo:
SW1030
Analysis Date: 3/2/2018
SegNo: 1439616
Analyte
Result
PQL
SPKvalue SPKRefVal
%REC LcwHmll HighLimit RPD Ref Val
%RPD RPDLimit Qual
nitablllty
non-flammable
0 0 20
Qualifiers. *
Original
Page 21 of 28
Value eeds Maximum Contaminantlevcl.
B
Analyte detected in the as dated McOmd Hlank
E
4alue above quantitation range
li
Holding times for prepemtioa or analysis excelled
]
Analyte detected below quanvireaon limits
M
Manual integration used to deteimina
MC
Value is below Minimum Compound Limit
ND
Not Detected
0
RSD is greaterthen RSDlimit
P
Second column conf rmatioh exceeds
PL
Permit Limit
A
RPD outside accepted moteverylimits

®SUMMIT ' fF,n4ra,nnen,alTeannoog(eghQC SUMMARY REPORT
3310 Wb, So I.
hWINOWENrALTECHNOLO01E6, INC Culmhaya Falls, Ohio 44223
Aaaiyllcal Lnbor8laorn TEL: [phone] FAX.[phone] k'O#; 18030036
Website: h to:/Aaum,.setrekcrnn 15 -Mar -18
Client: Synagro
Project: Statesville BatcM: 881628
nitle, Reactive
NO 0.500
RunNo: 81628
nple lD
MB -881628
SampType:
MBLK
TestCode:
Cyanide,Rea Units: mg/L
Prep Date:
RunNo: 81629
int ID:
PBW
Batch ID:
R81628
TestNo:
SW9014
Analysis Date: W812018
Serbs: 1462949
alvia
Result
Result
PQL
SPKvalu6 SPKRef Val
%REC LowLlmit HighLimit RPDRef Val
%RPD RPDLhnit Qua
nitle, Reactive
NO 0.500
side, Reactive 10.1 0.5D0 10.00 0 101 85 115
IeID 18030390-
RunNo: 81628
nple ID
LCS-881628
SampType:
LCS
TestCotle:
Cyanitle,Rea Units: mglL
Prep Date:
int ID:
LCSW
Batch ID:
R81628
TestNo:
SW9014
Analysis Date: 318/2918
SegNo: 1452950
tivia
style
Result
PQL
SPKvalue SPK Ref Val
%REC LowLtmit HighLimit RPD Ref Val
%RPD RPDLimit Qua'.
side, Reactive 10.1 0.5D0 10.00 0 101 85 115
IeID 18030390-
title, Reactive 10.1 0.500 10.00 0 101 81.3 118
nple.ID
001AMS
SampType:
MS
TestCode:
Cyanlde,Rea Units: mglL
Prep Dale:
RunNo: 81628
,nt ID:
BatchQC
Batch ID:
R81628
TestNo:
SW9014
Analysis Date: 3/8/2018
SegNo: 1452954
style
Result
PQL
SPKvalue SPKRef Val
%REC LOWLImII HighLimit RPDRef Val
%RPD RPDLimit Qua
title, Reactive 10.1 0.500 10.00 0 101 81.3 118
Cyanide, Reactive 9.87 0.500 10.00 0 98.7 81.3 118 10.13 2.57 5 W
Qualifiers: ' Value exceeds Maximum Contaminant Level. H Avely[e detected in the associated McNod an E Valueebwe qua an8e
H Holding times for prepamtionor analysis exceeded J Analyte detected below quantitation limits M Manuel rnregation used to determu,e
MC Value is below Minimum Com ou dLimit IJD NotDelecfed O RS➢is greater than RSDlimit Original
y
P Second column continuation exceeds PL Permit Limit R RPD outside accepted recovery limits
Page 22 of 28
nple.ID
1803x390-001AMSQ
SampType:
MSO
TestCode:
Cyanide,Rea Units: mglL
Prep Date:
RunNo: 81628
:nt ID:
BatchQC
Batch ID:
R81628
TestNo:
SW9014
Analysis Date: 318/2018
SegNo: 1452955
11yte
Result
PQL
SPKvalue SPK Ref Val
%REC LowUnut HighLlmit RPD Ref Val
%RPD RPDLimit Qua
Cyanide, Reactive 9.87 0.500 10.00 0 98.7 81.3 118 10.13 2.57 5 W
Qualifiers: ' Value exceeds Maximum Contaminant Level. H Avely[e detected in the associated McNod an E Valueebwe qua an8e
H Holding times for prepamtionor analysis exceeded J Analyte detected below quantitation limits M Manuel rnregation used to determu,e
MC Value is below Minimum Com ou dLimit IJD NotDelecfed O RS➢is greater than RSDlimit Original
y
P Second column continuation exceeds PL Permit Limit R RPD outside accepted recovery limits
Page 22 of 28

® SUMM17 sa»„ h m »»le»lase,»lees e,, . QC SUMMARY REPORT
331011'i»S.Sf.
NVIRONIhENTAL TECIINOLAOIE9, INC Ctryohoga Falls, Ohio 44223
AnalyNeal La4orritimX.
i TE4(330)25342]1 FA(330)253-4489 WO#18030036
:
Website: helm mensehekm» IS-Mnr-l8
Client: Synagco
Project: Statesville BatehID: 581628
Sample l0 18839390-O01AMSD SampType: MSD TestCotle: Cyanide,Rea Units: mglL Prep Date; Punta:
Quvtifiere: * Value exceeds Maximum Conteminadt Level. B Analyte detected in the associated Method Blank E Value above quentitetion renKe
H HoldinKlimes for preparation or analysis exceeded ) AnalNe detected below quantitation limits M Mmual lntegation used to determine Original
MC Value is bel ow Minimum Compound Limit. ND Not Detected 0 RSD is Kreaterthan RSDlimi[
P Seemed column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits
Page 23 of 28
81628
Client ID:
BatchQC
Batch ID:
R81628
Testsio:
SW9014
Analysis Date: 3/8/2018
SegNo: 1452955
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLimit HighLimit RPDRef Val
%RPD RPDLpdt Qual
Quvtifiere: * Value exceeds Maximum Conteminadt Level. B Analyte detected in the associated Method Blank E Value above quentitetion renKe
H HoldinKlimes for preparation or analysis exceeded ) AnalNe detected below quantitation limits M Mmual lntegation used to determine Original
MC Value is bel ow Minimum Compound Limit. ND Not Detected 0 RSD is Kreaterthan RSDlimi[
P Seemed column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits
Page 23 of 28

S%pa"N"M 0 5nnmusmo-mlmm,rar 34]0 5ha310Win SI-
ENVI80NM6Nigl.TeC15NOL00iE9,INe CuryalrogaFahs Ohio 44223 WOq: 18030036
4,ralrllcal Lnbontorles TTL:(3tQ) 2534211 FA. [phone]
Wehvis: Mm.11"Pw..,ertekeom 15 -Mar -18
Client:
Synagro
Project:
Statesville
BatellD:
R81630
Is,
Sample ID
Sample ID
MB -R81630
SampType:
MBLK
TestCode:
Sulfide, React Units: mg/L
Prep Dale:
RunNo: 81830
Client ID:
PBW
Balch to:
R81630
TestNo:
SW9034
Analysis Dale: 3/8/2018
SegNo. 1453002
Analyte
PQL SPKvalue SPKRef Val
%REG LowLimil HighLimit RPDRef Val
Result
PQL
SPKvalue SPK Ref Val
%REG Lowl-lmit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Reactive
NO 25.0
le,
Sample ID
LCB -881630
SampType:
LCS
TestCode: SUlfide,React Dnits: mg/L
Prep Date:
RwNo: 81630
Client ID:
LCSW
Batch ID:
R81630
TestNo: SW9034
Analysis Date: 318/2018
SegNo: 1453003
Analyte
Analysis Date: 3/8/2016
SegNo: 1453005
Result
PQL SPKvalue SPKRef Val
%REG LowLimil HighLimit RPDRef Val
%RPD RPDLimit Qual
Reactive 4460 25.0 4600 0 92.9 05 115
Sample to 18630396.661AM$ SampTYPe: MS TestCode: Sulfide, React Units: mglL Prep
Sulfide, Reactive 4310 25.0 48
Sample ID
18030390.001AMS0
SampType:
MSD
TestCode:
Sulfide,React Units: mg/L
Date:
RunNo: 81630
Client to:
BatchQC
Batch to:
R81630
TestNo:
SW9034
Analysis Date: 3/8/2016
SegNo: 1453005
Analyte
Result
PQL
SPKvalue SPKRef Val
°!DREG LowLimit HighLimit RPDRef Val
%RPD RPDLimit Qual
03 0 H9.8 75 725
V
Sulfide, Reactive 4370 25.0 4000 0 91.0 75 125 4310 1,38 30
Sample ID
18030390.001AMS0
SampType:
MSD
TestCode:
Sulfide,React Units: mg/L
Prep Date:
RunNo: 81630
GlientlD:
BatchQC
Batch lD:
R81630
TestNo:
SW9034
Analysis Date: 31512018
eq cc 1453006
Analyte
Result
PQL
SPKvalue SPK Ref Val
%REG LowUnilt HighLimit RPD Ref Val
%RPD RPDLimit Qual
W
Qualifiers: • Value ezoeeds Maximum Contaminant level. H Analyte detected in tfie azsociate d Method Blank E Value above quanfitation range
H Holding times forpreparalion or analysisexceeded J Analyte detected below quanfitafion limits M Manuel lntega0on used Mdetermine
MC Value is be] Minim 11 Compeund Limit: N➢ No[Dctectcd O RBD is greaser dmn RSDSmit Original
P
Second column confirmation exceeds
PL
Permit Limit
K
RPD outside accepted recovery limits
Page 24 of 28

El
%'MMMT 33/OnSt.
s,m ,rcE,naronn,mna r n,w glQC SUMMARY REPORT
WMm S(.
ENWRONbtENTAL TECHNOLOGIES, ,NC C,0'ahoga Falls, Onio 44223
Ahalylloal LabCram leg M: [phone] FAD [phone] k'a1: 18030036
Websile: haylMov.sellskewn ZS-M{n-ZB
Client: Synagro
Project: Statesville BatchED: R81630
Sample ID
Qualifiers: ' Value exceeds Maximum Coataminantlevel. B Analytedetected in the associated Method Blank E Value above qua�4itation range
H Holding timesfoc preparation or eualysisexce dad T Malyte detected below quantitation limits M Mmusl lntep{etion used to determine Original
MC Value is below Minimum Compound Li mit. ND Not Detected O R9D isgre#erthan RBDlimit
P Second column condonation exceeds PL Permit Limit R RPD outside accepted recovery limits
Page 25 of 28
18030390-001AMS0
SampType:
MSO
TeslCode:
Sulfide, React Units: mglL
Prep Date:
RunNo: 87630
Client to
BatchQC
Balch ID:
R81630
TestNo:
SW9034
Analysis Date: 3/8/2018
SegNo: 1453006
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC Lowl-imit Highl-imit RPDRef Val
%RPD RPDLImit Qual
Qualifiers: ' Value exceeds Maximum Coataminantlevel. B Analytedetected in the associated Method Blank E Value above qua�4itation range
H Holding timesfoc preparation or eualysisexce dad T Malyte detected below quantitation limits M Mmusl lntep{etion used to determine Original
MC Value is below Minimum Compound Li mit. ND Not Detected O R9D isgre#erthan RBDlimit
P Second column condonation exceeds PL Permit Limit R RPD outside accepted recovery limits
Page 25 of 28

u1V1i1V11't sm»n,rE,nnrann,�la r=chnaagie°✓tiQC SUMMARY REPORT
3310 Win St.t.
ENVIRONnIZINTALTECHROLOGIT511, INC CshahagaPalls, Ohio 44223 WOS: 18030036
Attal ypeal Lp60tafoflu M: (330) 2334'211 FAX. [phone]
Websllc; Lim✓Arwv.eeuekcom ]5-Mnr-78
Client 6ynagro
Project: Statesville 1latchED: R81742
Sample ID LCS-R81742 BampType: LCS TestCode: pH 5(90450) Units:
PH
Value exceeds Maximum Contaminantlevel.
H
Analy[e detected in the associated Method Hlank
B
Value above qumotaeon reu8e
fl
Holding times forprepamfion or analysis excee6ed
J
Analyte detected below quantitation limits
M
Manual Integration used to determine
s.w@19.8°C
Prep Date:
RunNo: 61742
Client to
LCSS
Batch ID:
R81742
TestNo:
SW9045D
Analysis Date: 3/14/2018
SegNo: 1456032
Analyte
Analysis Date: 3/1412018
SegNo: 1456036
Result
PQL
SPKvalue SPKRef Vel %REQ
LowLimil Highl-imit RPDRef Val
°%RPD RPDLimil Qual
7.0 7.0 0 99.7 90 110
Sample ID 18030038-001AOUP SampType: CUP TestCode: pH_S(90450) Units: s.u.@21.09C Pre
pH 5.3 5.3 0.6 10
Sample lD LCS-R81742 SampType: OUP TeslCotle: pH_S(9045p) Units: s,u.@79.8°C Prep Dale: RunNo: 817
Value exceeds Maximum Contaminantlevel.
H
Analy[e detected in the associated Method Hlank
B
Value above qumotaeon reu8e
fl
Holding times forprepamfion or analysis excee6ed
J
Analyte detected below quantitation limits
M
Manual Integration used to determine
Original
MC
42
p pate:
RunNo: 81]42
ClienllD:
BatchQC
Batch ID:
R81742
TeslNO:
SW9045D
Analyte
Analysis Date: 3/1412018
SegNo: 1456036
Analyte
PQL
SPKvalue SPKRef Val °%REC
Result
PQL
SPKvalue SPKRef Val
%REC
LowLlmit HlghLimit RPDRef Val
%RPD RPDLImit oust
pH 5.3 5.3 0.6 10
Sample lD LCS-R81742 SampType: OUP TeslCotle: pH_S(9045p) Units: s,u.@79.8°C Prep Dale: RunNo: 817
pH 7.0
7:0 0 101 so 110 zo os m
QualViers: *
Value exceeds Maximum Contaminantlevel.
H
Analy[e detected in the associated Method Hlank
B
Value above qumotaeon reu8e
fl
Holding times forprepamfion or analysis excee6ed
J
Analyte detected below quantitation limits
M
Manual Integration used to determine
Original
MC
42
Client I0:
SatchQC
Batch ID:
RB1742
Tsetse-
SWO045D
Analysis Date: 3/14/2018
SegNo: 1456055
Analyte
R
RPD outside accepted recovery Bunts
Result
PQL
SPKvalue SPKRef Val °%REC
LowLimit Highl-imlt RPDRef Val
%RPD RPOIJmit Qual
pH 7.0
7:0 0 101 so 110 zo os m
QualViers: *
Value exceeds Maximum Contaminantlevel.
H
Analy[e detected in the associated Method Hlank
B
Value above qumotaeon reu8e
fl
Holding times forprepamfion or analysis excee6ed
J
Analyte detected below quantitation limits
M
Manual Integration used to determine
Original
MC
Value is bel ow Minimum Compound Limit
ND
Not Detected
O
RSD is gresterthan RSDlimit
P
Second column confiscation exceeds
PL
Permit Limit
R
RPD outside accepted recovery Bunts
Page 26 of 28

summit Environmental Tecnnologies Inc
310 Win Slreel Analysis Request/Chain of Custody
3
Cuyahoga Falls, Ohio 44223 Tel: [phone] Fac: 330.253.4489 For Summit Environmental lceMdogics, Inc, use onlyProject None
Campupv Name (Plenve/—Of-- Stir
V'C3
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IN N, INN
°mN"tY
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ProjectIN
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11
INNNPip
cvmcpnnt>rN° 336 Zo3 %kl
R`P°"`°
tot No.
POOr.
Cham Entail
Quote No.
conuct Per17�
Sampled by
Cheek If Ohio VAPeempla J
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Whisked
)Cs4 Ofdi
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✓
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Ice
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"W hyt
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UPS tov�G'(1CC IaRmMPIDce JLn—
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�.�1 YnikaulmepWRsty iMP G
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client Naha the pink page. nw 121908 -
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@neh uealedB Must he spiel
Beg By:
- by 10 inotier
Went no tielbw pages route lownpanY Stolen w Ne lebonmry. the
Page 27 of 28

summ'y SvmmitEnvironmental.Technologies, bac.
ff13310 Win SG
rNVIRONMENTAL rECHNOLOGlcs, INC- Cuyahoga Falls, Ohio 44223 Sample Log -In Check List
Analytical Lahorarorles TEL: [phone] FAX: [phone]
Wehsile: h1tP7113vuay.se11ek.com
Client Name: SYN -NC -27028 Work Order Number: 18030036 RcptNo: 1
Logged by: Nick Clear 3/112018 10:20:00 AM -
Completed By: Antonio Betscakos 3/112018 11:45:09 AMy� Y
Reviewed By: Jennifer Woolf 3/112018 4:51:10 PM r•�'
Chain of Custody
1. Is Chain of Custody complete? Yes V No ❑ Not Present ❑
2. How was the sample delivered? UPS
Log In
Samples) in proper container(s)?
Yes
❑�
3. Coolers are present?
Yes ❑1
No ❑
NA ❑
4. Shipping container/cooler in good condition? Yes 0 No ❑
Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present ❑6
No. Seal Date: Signed By:
5. Was an attempt made to cool the samples? Yes © No ❑ NA ❑
6, Were all samples received at a temperature of >0° C to 6.0°C Yes 0 No ❑ NA ❑
7,
Samples) in proper container(s)?
Yes
❑�
No
❑
Sl nod By
8.
Sufficient sample volume for indicated test(s)?
Yes
©
No
❑
g,
Are samples (except VOA and ONG) properly preserved?
Yes
©
No
❑
10.
Was preservative added to bottles?
Yes
❑
No
❑
NA 0
NA
11.
Is the headspace in the VOA vials less than 1/4 inch or 6 mm?
Yes
❑
No
❑
No VOA Vials ❑�
12.
Were any sample containers received broken?
Yes
❑
No
❑1
13.
Does paperwork match bottle labels?
Yes
❑J
No
❑
(Note discrepancies on chain of custody)
14.
Are matrices correctly identified on Chain of Custody?
Yes
❑W
No
❑
15.
Is It clear what analyses were requested?
Yes
©
No
❑
16.
Were all holding times able to be met?
Yes
©
No
❑
(If no, notify customer for authorization.)
Special Handling (If applicable)
17,
Was client notified of all discrepancies with this order?
Yes
❑
No
❑
NA W
Person Notified: Date '
By Whom: - --- Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person
Regarding:
Client Instructions:
1$. Additional remarks:
Cooler Information
Cooler No
Temp °C
Condition
Seal Intact
Seal No
Seal Date
Sl nod By
1
4.4
Good
Not Present
Page 28 of 28

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Statesville Fourth Creek WWTP WQ Permit Number: WQ 0016247
W WTP Name: Statesville Fourth Creek W WTP NPDES Number: NC 0031836
Monitoring Period: From 01/01/18 To 12/31/18
Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) -Please indicate level achieved and alternative performed:
711
ALt 1/A (time/temp) Alt. 2/B (Alk Treatment) Alt. 3/C (Prior Testing)
Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PPRP)
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost Heat Drying Heat Treatment Thermophilic
Beta Ray Gamma Ray Pasteurization
Class B:
Alt. (1) Fecal Density X Alt (2) Process to Significantly Reduce Pathogens
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Air Drying Composting Aerobic Digestion
Anaerobic Digestion
fan rdiva
hir to altwrn afivw nwrfnrm w,i !('lace d nr ('lace Rl rnm nlrtw thr fnlinwina mnnitnrina data•
Parameter
Allowable Level in Sludge
Pathogen Density
No. of
Frequency
Sample
Analytical
(Spec. 02 uptalce) X
Option/Alt. 5
Option/Alt. 6
Excee-
of
Type
Technique
(Drying— Stable)
(Drying—Unstable) _
Minimum Geo. Mean Maximum Units
dences
Analysis
(Injection)
Fecal
2x10 to the 61h
NTN
12000
15422
17143
MPN/g
0
Annual
Grab
Sm9221ce
Coliform
power per gram
.2006
of total solids
CFU
CFU/g
1000 MPN per gram of
MPN/g
total solids (dry weight)
Salmonella
3 MPN per 4 grams total
bacteria (in
solids (dry weight)
lieu of fecal
coliform)
Vector Attraction Redaction (40 CFR 503.33/15A NCAC 02T.1107) -Please indicate option/alternative performed:
Option/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/ALt 4
(VS
CERTIFICATION STATEMENT (please check the appropriate statement)
reduction)
(40 -day bench)
(30 -day bench)
(Spec. 02 uptalce) X
Option/Alt. 5
Option/Alt. 6
Option/Alt. 7
Option/Alt. 8
(14 -Day Aerobic)
(Alk Stabilization)
(Drying— Stable)
(Drying—Unstable) _
Option/Alt 9
Option/Alt. 10
(Injection)
(Incorporation)
No vector attraction reduction
alternatives were performed
"I certi
fy, under penalty of law, that fire pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector atfiaction
X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32115A NCAC 02T.11On and the vector attraction
reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an
explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction mid supervision in accordance with the system designed to ensure that qualified
sonnet properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have
n raft. 1 am,Aware that there are signikant penalties for false certification including fine and imprisonment."
Name�nd�Ti10 (type or print) _ bp �j
/ Land Applier Name and Title (if applicable) (type or print)
of Preparer* llalk Signature of Lan
d Applier (if applicable) Date
*Proparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26)

Analytical Results
Synagro
284 Boger Rd.
Mocksville, NC 27028
Receive Date: 0411 2 /2 0 1 8
Reported: 04/13/2018
For: 4th Creek
Comments: Geometric Mean 15,422 MPN/g
Sample Number
Parameter
Sample ID
Result
Unit
180412-19-01
Fecal Coliforms
4-1
13873
MPN/g
180412-19-01
Percent Solids
4-1
17,3
%
180412-19-02
Fecal Coliforms
4-2
16783
MPN/g
180412-19-02
Percent Solids
4-2
14.3
%
180412-19-03
Fecal Coliforms
4-3
16667
MPN/g
180412-19-03
Percent Solids
4-3
14.4
%
180412-19-04
Fecal Coliforms
4-4
15484
MPN/g
180412-19-04
Percent Solids
4-4
15.5
WC
180412-19-05
Fecal Coliforms
4-5
12000
MPN/g
180412-19-05
Percent Solids
4-5
20
%
180412-19-06
Fecal Coliforms
4-6
17143
MPN/g
180412-19-06
Percent Solids
4-6
14
%
180412-19-07
Fecal Coliforms
4-7
16783
MPN/g
180412-19-07
Percent Solids
4-7
14.3
%
Respectfully submitted,
Dena Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
Method
Analyzed
Analyst
SM92210E-2006
64/12/2618
WC
40B-1 99704/12/2018
WC
SM92210E-2006
04/1212018
WC
sMzs40B-1997
04/12/2018
WC
sMs2210E-2006
04/12/2018
WC
sM2s409-1997
04/12/2018
WC
SM92210E-2005
64/12/2618
WC
SM2540B-1997
04/1212018
WC
sM9z210E-2006
04/12/2018
WC
sMzs408-1997
04/12/2018
WC
sMs2210E-2006
04/12/2018
WC
sMzs406-1997
04/12/2018
WC
ICE -2.006
04/12/2018
WC
40B 199704/12/2018
WC
PO Box 228 •Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180412-19-02 Temp on Arrival; 3.2
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180412-19-03 Temp on Arrival: 3.2
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180412-19-04 Temp on Arrival: 3.2
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180412-19=05 Temp on Arrival: 3.2
Parameter Schedule: Percent Solids
Received an Ice
Pd Box 228 •Statesville, NC 28687 • 704/872/4697
Page 2 of 4
Condition
of
Receipt
Sample Number 180412-19-01
Temp on Arrival:
3.2
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180412-19-02 Temp on Arrival; 3.2
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180412-19-03 Temp on Arrival: 3.2
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180412-19-04 Temp on Arrival: 3.2
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180412-19=05 Temp on Arrival: 3.2
Parameter Schedule: Percent Solids
Received an Ice
Pd Box 228 •Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180412-19-06 Temp on Arrival: 3.2
Parameter Schedulo: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180412-19-07 Temp on Arrival: 3.2
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 •Statesville, NC 28687 • 704/872/4697
Page 3 of 4

maa
!:
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Time
(minutes)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name
Biosolids Permit Number
Date
Digester Temperature
Sampling Date/Time
Sampled By
Analysis Date/Time
Analyzed By
Sample Volume
Total Solids
Beginning Temperature
End Temperature
Dissolved Oxygen Level
(ma/Il
Fourth Creek WWTP
1/2/2018
13.9
1/2/18 1:22 PM
LC
1/2/18 1:31 PM
BJ
300 milliliters
1.54
13.9
14
9.73
9.77
9.69
9.53
9.49
9.4
9.55
9.57
9.49
9.44
9.39
9.3
9.27
9.18
9.09
9.01
Slope:
Intercept:
Correlation Coefficient:
Oxygen Uptake Rate:
Ambient Specific Oxygen Uptake Rate:
Average Temperature:
Temperature Correction Factor:
0.0
9.8
0.9
Dry Solids
degrees Celsius
degrees Celsius
2.59 mg Oxygen/hr
0.56 mg Oxygen/g/hr
14 degrees Celsius
1.500730352
Temperature Corrected Specific Oxygen Uptake Rate: 0.84 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

Time
(minutes)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name
Biosolids Permit Number
Date
Digester Temperature
Sampling Date/Time
Sampled By
Analysis Date/Time
Analyzed By
Sample Volume
Total Solids
Beginning Temperature
End Temperature
Dissolved Oxygen Level
(mail)
9.42
9.39
9.33
9.3
9.2
9.14
9.07
8.99
8.97
8.88
8.78
8.69
8.6
8.53
8.47
8.38
Slope:
Intercept:
Correlation Coefficient:
Oxygen Uptake Rate:
Ambient Specific Oxygen Uptake Rate:
Average Temperature:
Temperature Correction Factor:
Fourth Creek WWTP
1/3/2018
16.7
1/3/18 1:05 PM
LC
1/3/18 1:13 PM
aOO
milliliters
Dry Solids
degrees Celsius
degrees Celsius
4.29 mg Oxygen/hr
0.82 mg Oxygen/g/hr
17 degrees Celsius
1.225043
Temperature Corrected Specific Oxygen Uptake Rate: 1.01 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

Time
(minutes)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name
Biosolids Permit Number
Date
Digester Temperature
Sampling Date/Time
Sampled By
Analysis Date[Time
Analyzed By
Sample Volume
Total Solids
Beginning Temperature
End Temperature
Dissolved Oxygen Level
Ima/ll
7.41
7.42
7.37
7.36
7.33
7.28
7.13
7.11
7.01
6.91
9.75
6.81
6.55
6.47
6.63
6.48
Slope:
Intercept:
Correlation Coefficient:
Oxygen Uptake Rate:
Ambient Specific Oxygen Uptake Rate:
Average Temperature:
Temperature Correction Factor:
Fourth Creek WWTP
1/1218
16
1/12/18 12:55 PM
LC
1/12/18 1:05 PM
BJ
300 milliliters
1.76
16.3
16.9
0.0
7.6
0.3
Dry Solids
degrees Celsius
degrees Celsius
2.95 mg Oxygen/hr
0.56 mg Oxygen/g/hr
17 degrees Celsius
1.225043
Temperature Corrected Specific Oxygen Uptake Rate: 0.68 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

Time
(minutes)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name
Biosolids Permit Number
Date
Digester Temperature
Sampling Date/Time
Sampled By
Analysis Date/Time
Analyzed By
Sample Volume
Total Solids
Beginning Temperature
End Temperature
Dissolved Oxygen Level
(mail)
Fourth Creek WWTP
1/17/2018
11.7
1/17/18 10:58 AM
LC
1/17/18 11:09 AM
aOO
9.83
9.94
10.09
10.16
10.21
10.22
10.21
10.14
10
9.83
9.75
9.9
9.82
9.78
9.82
9.79
Slope:
Intercept:
Correlation Coefficient:
Oxygen Uptake Rate:
Ambient Specific Oxygen Uptake Rate:
Average Temperature:
Temperature Correction Factor:
0.0
10.1
0.6
milliliters
°fo Dry Solids
degrees Celsius
degrees Celsius
1.27 mg Oxygen/hr
0.25 mg Oxygen/g/hr
12 degrees Celsius
1.71818618
Temperature Corrected Specific Oxygen Uptake Rate: 0.43 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

Time
(minutes)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name
Biosolids Permit Number
Date
Digester Temperature
Sampling Date/Time
Sampled By
Analysis Date/Time
Analyzed By
Sample Volume
Total Solids
Beginning Temperature
End Temperature
Dissolved Oxygen Level
!ma/11
9.47
9.67
9.87
10.02
10.12
10.11
10.13
10.13
10.15
10.16
10.21
10.08
10
9.86
9.58
9.46
Slope:
Intercept:
Correlation Coefficient:
Oxygen Uptake Rate:
Ambient Specific Oxygen Uptake Rate:
Average Temperature:
Temperature Correction Factor:
Fourth Creek WWTP
1/18/2018
9.8
1/18/18 10:40 AM
LC
1/18/18 10:47 AM
2 BJ
300
1,84 YO
10.2
11
0.0
10.0
0.0
milliliters
Dry Solids
leg Celsius
leg Celsius
0.11 mg Oxygen/hr
0.02 mg Oxygen/g/hr
11 degrees Celsius
1.838459212
Temperature Corrected Specific Oxygen Uptake Rate: 0.04 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

Time
(minutes)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name
Biosolids Permit Number
Date
Digester Temperature
Sampling Date/Time
Sampled By
Analysis Date/Time
Analyzed By
Sample Volume
Total Solids
Beginning Temperature
End Temperature
Dissolved Oxygen Level
(ma/11
Fourth Creek WWTP
1/18/2018
10.4
1/19/18 10:27 AM
LC
1/19118 10:39 AM
M
7.42
7.39
7.36
7.37
7.38
7.39
7.4
7.39
7:42
7.37
7.3
7.34
7.26
7.24
7.25
7.21
Slope:
Intercept:
Correlation Coefficient:
Oxygen Uptake Rate:
Ambient Specific Oxygen Uptake Rate:
Average Temperature:
Temperature Correction Factor:
0.0
7.4
0.8
milliliters
Dry Solids
degrees Celsius
degrees Celsius
0.71 mg Oxygen/hr
0.13 mg Oxygen/g/hr
12 degrees Celsius
1.71818618
Temperature Corrected Specific Oxygen Uptake Rate: 0.23 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility
Name:
City of Statesville
WQ Permit Number:
WQ 0016247
Sample
Analytical
W WTP
Name:
Statesville Third Creek W WTP
NPDES Number: NC
0020591
Type
Monitoring Period: From 01/01/18 To 12/31/2018
Pathogen Reduction (40 CFR 503.32115A NCAC 02T.1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. 1/A (time/temp) Alt. 2/B (Alk Treatment) Alt. 3/C (Prior Testing)
Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PPRP)
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost Heat Drying Heat Treatment Thermophilic
Beta Ray Gamma Ray Pasteurization
Class B:
Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Air Drying Composting Aerobic Digestion
Anaerobic Digestion
If applicable to alternative performed Class A or Class Eq complete the following monitorin data:
Parameter All
Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) -Please indicate option/alternative performed:
Option/Alt. 1
(VS reduction)
Option/Alt. 5
(14 -Day Aerobic)
Option/Alt. 9
(Injection)
ption/Alt.
(40 -day bench)
O 2
Option/Alt. 6
(Alk Stabilization)
Option/Alt. 10
(Incorporation)
CERTIFICATION STATEMENT (please check the appropriate etaYement)
"I cert
t
(30 -day bench)
Option/Al3
Option/Ah. 7
(Drying — Stable)
No vector attraction reducti
(Spec.
Option/Alt. 4
02 uptake) X
Option/Alt. 8
(Drying—Unstable)
on alternatives were performed
ify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector ath'action
X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an
explanation why you have not met one or both of the requirements.)
This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction
" reduction requirements have
e t. I a awar�that there m'o si ificant penalties For false certification including fine and imprisonment.
Pr ar Na n� Ti e (type or print) Q� Land Applier Name and Title (if applicable) (type or print)
Signatuof Preparer* D a ! Signature of Land Applier(if applicable) Date
*Preparer is defined in 40 CFR Part
503.9(x) and 15A NCAC 2T.1102 (26)
owable Level in Sludge
Pathogen Density
No. of
Frequency
Sample
Analytical
Excee-
of
Type
Technique
Minimum Geo. Mean Maximum Units
dentes
Analysis
Fecal
2xlOtothe 614
MPN
16000
17319
20870
MPN/g
0
Annual
Grab
SM9221C
Coliform
power per gram
E-2006
of total solids
CPU/g
CFU
1000 MPN per gram of
MPN/g
total solids (dry weight)
Salmonella
3 MPN per 4 grams total
bacteria (in
solids (dry weight)
lieu of fecal
coliform)
Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) -Please indicate option/alternative performed:
Option/Alt. 1
(VS reduction)
Option/Alt. 5
(14 -Day Aerobic)
Option/Alt. 9
(Injection)
ption/Alt.
(40 -day bench)
O 2
Option/Alt. 6
(Alk Stabilization)
Option/Alt. 10
(Incorporation)
CERTIFICATION STATEMENT (please check the appropriate etaYement)
"I cert
t
(30 -day bench)
Option/Al3
Option/Ah. 7
(Drying — Stable)
No vector attraction reducti
(Spec.
Option/Alt. 4
02 uptake) X
Option/Alt. 8
(Drying—Unstable)
on alternatives were performed
ify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector ath'action
X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an
explanation why you have not met one or both of the requirements.)
This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction
" reduction requirements have
e t. I a awar�that there m'o si ificant penalties For false certification including fine and imprisonment.
Pr ar Na n� Ti e (type or print) Q� Land Applier Name and Title (if applicable) (type or print)
Signatuof Preparer* D a ! Signature of Land Applier(if applicable) Date
*Preparer is defined in 40 CFR Part
503.9(x) and 15A NCAC 2T.1102 (26)

Analytical Results
Synagro
284 Boger Rd.
Mocksville, NC 27028
Receive Date: 04/1212018
Reported: 04/13/2018
For: 3rd Creek
Comments: Geometric Mean 17,319 MPN/g
Sample Number
Parameter
Sample ID
Result
Unit
Method
Analyzed
Analyst
180412-18-01
Fecal Coliforms
3-1
20870
MPN/g
sm922mea006
04/12/2018
WC
180412-18-01 _
Percent Solids
3-1
11.5
/
SM2540e-1997
04/12/2018
WC
180412-18-02
Fecal Coliforms
3-2
17143
MPN/g
SM9221cE-2oos
04/12/2018
WC
180412-18-02
Percent Solids
3-2
14
q
SM2540s-1997
04/12/2018
WC
180412-18-03
Fecal Coliforms
3-3
17021
MPN/g
SM92210E-200s
0411 212 01 8
WC
180412-18-03
Percent Solids
3-3
14.1
/
6M2540B-few
04/12/2018
WC
180412-18-04
Fecal Coliforms
3-4
16552
MPNlg
SM9221ce-2oo6
04/12/2018
WC
180412-18-04
Percent Solids
3-4
14.5
%
sWWB-1892
04/12/2018
WC
180412-18-05
Fecal Coliforms
3-5
16000
MPN/g
SM9221cE-2006
04/1212018
WC
180412-18-05
Percent Solids
3-5
15
%
SM25406-1997
04/12/2018
WC
180412-18-06
Fecal Coliforms
3.6
17391
MPN/g
SM9221ce-2906
04/12/2018
WC
180412-18-06
Percent Solids
3-6
13.8
%
SM254o6-1997
04/12/2018
WC
180412-18-07
Fecal Coliforms
3-7
16667
MPN/g
SM92210E-2008
04/12/2018
WC
180412-18-07
Percent Solids
3-7
14.4
/
SM2540B-0997
04/12/2018
WC
Respectfully submitted,
Dena Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 •Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 180412-18-01 Temp on Arrival: 3.2
ParameterSchedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on lce
Chemicals in containers, lab
Sample Number 180412-18-02 Temp on Arrival 32
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180412-18-03 Temp on Arrival: 3.2
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180412-18-04 Temp on Arrival: 3.2
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180412-18=05 Temp on Arrival: 3.2
Parameter Schedule: Percent Solids
Received on Ice
PO Box 228 •Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180412-18-06 Temp on Arrival: 3.2
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 180412-18-07 Temp on Arrival: 3.2
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 •Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Time
(minutes)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name
Biosolids Permit Number
Date
Digester Temperature
Sampling Date/Time
Sampled By
Analysis Date/Time
Analyzed By
Sample Volume
Total Solids
Beginning Temperature
End Temperature
Dissolved Oxygen Level
Ima/Il
9.42
9.39
9.35
9.33
9.3
9.26
9.22
9.18
9.16
9.13
9.1
9.07
9.03
8.97
8.94
8.9
Slope:
Intercept:
Correlation Coefficient:
Oxygen Uptake Rate:
Ambient Specific Oxygen Uptake Rate:
Average Temperature:
Temperature Correction Factor:
Third Creek WWTP
WQ0016247
1/10/2018
10.6
1/10/18 13:42
SA
1/10/18 13:58
aOO
milliliters
'/o Dry Solids
leg Celsius
leg Celsius
2.05 mg OxygeNhr
0.43 mg Oxygen/g/hr
11 degrees Celsius
1.838459212
Temperature Corrected Specific Oxygen Uptake Rate: 0.79 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes,
The Calculation and the Spreadsheet execute automatically.

Time
(minutes)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name:
Biosolids Permit Number:
Date:
Digester Temperature:
Sampling Date/Time:
Sampled By:
Analysis Date/Time:
Analyzed By,
Sample Volume.
Total Solids:
Beginning Temperature,
End Temperature.
Dissolved Oxygen Level
(ma/l)
9.22
9.17
9.14
9.12
9.09
9.07
9.05
9.01
8.98
8.95
8.93
8.91
8.88
8.84
8.81
8.78
Slope:
Intercept:
Correlation Coefficient:
Oxygen Uptake Rate:
Ambient Specific Oxygen Uptake Rate:
Average Temperature:
Temperature Correction Factor:
Third Creek WWTP
WQ0016247
1/11/2018
10.8
1/11/18 8:34
SA
1/11/18 8:42
SA
300
1.6
11.3
11.8
]milliliters
Dry Solids
degrees Celsius
deg Celsius
1.68 mg Oxygen/hr
0.35 mg Oxygen/g/hr
12 degrees Celsius
1.71818618
Temperature Corrected Specific Oxygen Uptake Rate: 0.60 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

Time
(minutes)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name:
Biosolids Permit Number:
Date:
Digester Temperature:
Sampling Date/Time:
Sampled By,
Analysis Date/Tima
Analyzed By,
Sample Volume,
Total Solids:
Beginning Temperature
End Temperature
Dissolved Oxygen Level
(mail)
8.44
8.41
8.38
8.36
8.33
8.29
8.26
8.24
8.21
8.18
8.15
8.13
8.09
8.07
8.03
8
Slope:
Intercept:
Correlation Coefficient:
Oxygen Uptake Rate:
Ambient Specific Oxygen Uptake Rate:
Average Temperature:
Temperature Correction Factor:
Third Creek WWTP
WQ0016247
1/12/2018
11.9
1/12/18 11:56
SA
1/12/18 12:05
aOO
milliliters
Dry Solids
legrees Celsius
Jag Celsius
1.74 mg Oxygen/hr
0.36 mg Oxygen/g/hr
13 degrees Celsius
1.605781476
Temperature Corrected Specific Oxygen Uptake Rate: 0.58 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

Time
(minutes)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name,
Biosolids Permit Number
Data
Digester Temperature,
Sampling Date/Time.
Sampled By
Analysis Date/Time
Analyzed By
Sample Volume
Total Solids:
Beginning Temperature
End Temperature
Dissolved Oxygen Level
(MCl/1)
11.29
11.26
11.22
11.18
11.13
11.1
11.06
11.04
10.99
10.97
10.94
10.91
10.88
10.86
10.82
10.79
Slope:
Intercept:
Correlation Coefficient:
Oxygen Uptake Rate:
Ambient Specific Oxygen Uptake Rate:
Average Temperature:
Temperature Correction Factor:
Third Creek WWTP
WQ0016247
1[19/2018
10.8
1/19/18 12:12
SA
1/19/18 12:20
SA
300 milliliters
1.6
11.2
12.7
Dry Solids
degrees Celsius
degrees Celsius
1.99 mg Oxygen/hr
0.41 mg Oxygen/g/hr
12 degrees Celsius
1.71818618
Temperature Corrected Specific Oxygen Uptake Rate: 0.71 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes,
The Calculation and the Spreadsheet execute automatically.

Time
(minutes)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name:
Biosolids Permit Number:
Date:
Digester Temperature:
Sampling Date/Time:
Sampled By.
Analysis Date/Time,
Analyzed By,
Sample Volume.
Total Solids:
Beginning Temperature
End Temperature
Dissolved Oxygen Level
(mall)
10.97
10.94
10.91
10.88
10.86
10.83
10.8
10.76
10.73
10.71
10.67
10.64
10.61
10.57
10.53
10.49
Slope:
Intercept:
Correlation Coefficient:
Oxygen Uptake Rate:
Ambient Specific Oxygen Uptake Rate:
Average Temperature:
Temperature Correction Factor:
Third Creek WWTP
WQ0016247
1/2212018
11.1
1/22/18 10:10
SA
1/22/18 10:19
SA
300
1.6
11.3
12.1
milliliters
'/o Dry Solids
leg Celsius
leg Celsius
1.88 mg Oxygen/hr
0.39 mg Oxygen/g/hr
12 degrees Celsius
1.71818618
Temperature Corrected Specific Oxygen Uptake Rate: 0.67 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes,
The Calculation and the Spreadsheet execute automatically.

Time
(minutes)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name
Biosolids Permit Number
Date
Digester Temperature
Sampling Date/Time
Sampled By
Analysis Date/Time
Analyzed By
Sample Volume
Total Solids:
Beginning Temperature
End Temperature
Dissolved Oxygen Level
(ma/11
9.73
9.69
9.65
9,63
9.59
9.55
9.52
9.5
9.49
9.43
9.4
9.37
9.34
9.32
9.28
9.25
Slope:
Intercept:
Correlation Coefficient:
Oxygen Uptake Rate:
Ambient Specific Oxygen Uptake Rate:
Average Temperature:
Temperature Correction Factor:
Third Creek WWTP
WQ0016247
1/23/2018
10.8
1/23/18 8:11
SA
1/23/18 8:19
SA
300 milliliters
1,6
11.1
12.3
Dry Solids
degrees Celsius
degrees Celsius
1.88 mg Oxygen/hr
0.39 mg Oxygen/g/hr
12 degrees Celsius
1,71818618
Temperature Corrected Specific Oxygen Uptake Rate: 0.67 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

Time
(minutes)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name
Biosolids Permit Number
Date
Digester Temperature
Sampling Date/Time
Sampled By
Analysis Date/Time
Analyzed By
Sample Volume
Total Solids;
Beginning Temperature
End Temperature
Dissolved Oxygen Level
(ma/l)
10.97
10.94
10.92
10.89
10.87
10.83
10.8
10.78
10.75
10.73
10.7
10.68
10.63
10.59
10.57
10.53
Slope:
Intercept:
Correlation Coefficient:
Oxygen Uptake Rate:
Ambient Specific Oxygen Uptake Rate:
Average Temperature:
Temperature Correction Factor:
Third Creek WWTP
WQ0016247
1/24/2018
10.7
1/24/18 7:40
SA
1/24/18 7:48
SA
300
1.6
10.9
11.5
milliliters
Dry Solids
degrees Celsius
degrees Celsius
1.73 mg Oxygen/hr
0.36 mg Oxygen/g/hr
11 degrees Celsius
1.838459212
Temperature Corrected Specific Oxygen Uptake Rate: 0.66 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet
execute automatically.

Agricultural Lime Application Log
Year: 2018
Project: Statesville
Field
(state -county -site -field)
Soil
pH
(from
Lime Requirement
soil analysis)
1Tons/Acre
Applied(CCE Eq.)
Date Applied
AL
-13-1A
6.3
O.OT/Ac.
IR -20-1
6.0
O.OT/Ac.
IR -20-2
6.1
O.OT/Ac.
IR -20-3
5.8
OAT/Ac.
IR -20-6
6.3
O.OT/Ac.
IR -20-7
6.9
O.OT/Ac.
IR -20-8
6.7
O.OT/Ac.
IR -20-9
7.2
O.OT/Ac.
IR -35-3
6.2
O.OT/Ac.
IR -35-4
6.5
O.OT/Ac.
*Lime will be applied when conditions improve.

Page 1 of 1
Report Number: 19-016-0581
Account Number: 46488 Waypoint..
7621
SenTo: SYNAGRO CENTRAL LLC/SALISBURY ANALYTICAL
Mary Bre ^Everyacre...Everyyear. ,M
284 BOGER RD
MOCKSVILLE NC 27028
SOIL ANALYSIS REPORT
Dale Received: 01/16/2019 Date Ot Analvsis: 01/17/2019 Date OF Report: 01/17/2019
d
Whltepine Road, Richmond, VA 23237
Main 804-743-94010 Fax [phone]
www.waypointanalytiol.com
Grower: Danny Mfllsaps AL -13
Analytical MetM1otl(s): McM1lish3 SMP BURer pH Loss On Bnieon Weler pH
NC=North Carolina Fert
ility Index Value
Values on this report represent the plant available nultlenb in the Explanation ofsymhcls:^h(pemen[), ppm (parts per million), IbsIA Thin export Iles to samplals)i�lea. samples ere relsineaa
sal. Rating after each value: VL Low), L(Low), M(Medlum), (pounds per acre), mslcm(millFmhos per cenlimeler), meo/ipog mewmumolfMrty nays anarlaauas.
(Vera
y by.
I VH (Very High}ENR
HF.C.-
OM
WN
ENR
Phosphorus
Potassium
Magnesium
Calcium
Sodium
pH
Acidity
C,E.0
Sample l0
Field ID
Lab
Number
%
Soil
M3
K
Mg
Ca
Na
Soil
Buffer
H
Rate
Class
lbs/A
ppm Rale
ppm Rate
ppm Rate
ppm Rate
m Rate
m Rate
ppm Rate
PH
Index
meg/100g
meq/100g
AL -13-1A
22519
3.6
109
471,
229 VH
249 H
1094 M
18 VL
6.3
1.0
9.2
M
MIN
NC=39
NC -117
Percent
Base Saturation
Nitrate
Sulfur
Zinc
Manganese
Iron
Copper
Bomn
Soluble salts
Sample ID
K
Mg
Ca
Na
H
NO3
S
Zn
Mn
Fe
Cu
B
as
Field ID
/
%
ppm Rate
ppm Rate
ppm Rate
ppm Rate
ppm Rate
ppm Rale
ppm Rale
ms/cm Rale
AL -13-1A
6.4
22.6
59.5
0.9.
10.9
10 L
3A M
69 VH
183 VH
1.8 H
0.4 L
NC=21
NC=65.0
NC=
NC.=90.0
-Eslimafetl Nllmgen Release. ( Illimslcmx IND igogrems). Conversions: ppmx2=lbalA, Soluble Pnl retl
C.E.C.-talion Exchange Capactty. Salh mslcmx640=ppm, as preps by: WaypoimMayti=al Virginia, Inc.
Pauric McGroary

NCDA$CS Agronomic Division Phone: [phone]
Website: v .ncagr.gov/agronomi/
Report No.
FY19-SL003546
o uwa6 Predictive
Client:
Dennis Phillips
Advisor:
EBruce
201 Barry Oak Rd
Synagro
Soil Report
Mehlich-3
Extraction
Statesville, NO 28625
284 Boger Rd
Mocksville, NO 27028
Sampled County: Iredell
Links to Helpful Information
Sampled:
Not Provided
Received:
08/31/2018
Farm: IR -20
Completed;
09/11/2018
Client ID: 259693
Advisor ID: 475821
Sample ID: 20-01
Recommendations;
Lime
Nutrients(lb/acre)
More
Crop
(tons/acre)
N P2O5
K2O Mg
S
Mn
Zn
Cu B
Information
Lime History;
1 - FescuelOGrass/Tim,
M 0.0
120-200 70
60 0
0
0
0
0 0
Note: 12
2 _
0.0
Test Results [units - WN in g/crr2; CEC and Na in
meq1100 cm3; Nos -N In mg/dol:
Soil Class:
Mineral
HM% WN CEC BS% Ac pH
P-1 K-1
Ca% Mg%
S -I Mn -I Mn -All
Mn-Al2
Zn -1
Zn -AI
Cu -I Na ESP
SS -1 NO3-N
0.41 1.03 8.2 83 1.4 6.0
27 40
58 23
40 518 328
134
134
73 0.1 1
Sample ID; 20-02
Recommendations:
Lime
Nutrients(iblacre)
More
Crop
(tons/acre)
N P2O5
K2O Mg
S
Mn
Zn
Cu B
Information
Lime History:
1-Fescue/OGressrrim,
M 0.0
120-200 0
0 0
0
0
0
0 0
Note: 12
2 _
0,0
Test Results [units -WN In g/cm3; CEC and Na in
meg1100 cm3; NO3-N in mg/dn77:
Soil Class:
Mineral
HM% WN CEC BS! Ac pH
P-1 K-1
Ca% Mg%
S-1 Mn -1 Mn -All
Mn-Al2
Zed
Zn -AI
Cu -I Na ESP
SS -1 NO3-N
0.36 1.05 10.1 83 1.7 6.1
299 99
62 16
55 597 374
606
606
314 0.1 1
Sample ID: 20-03
Recommendations:
Lime
Nutrients(Vacre)
More
Crop
(tons/acre)
N P2O5
K2O Mg
S
Mn
Zn
Cu B
Information
Lime History;
1- Fescue/OGfass/Tlm, M 0.4
120-200 0
80 0
0
0
0
0 0
Note: 12
2 _
0.0
Test Results [units -WN in g/cm; CEC and Na in
meq/100 cm3; NO3-N In mg/dr?]:
Soil Class:
Mineral
HM% WN CEC BS% Ac pH
P-1 K-1
Ca% Mg%
all Mnd Mn -All
Mn-Al2
Zn -I
Zn -AI
Cu -I Na ESP
SS -1 NO3-N
0.41 1.04 8.6 80 1.7 5.8
294 31
61 18
52 335 218
637
637
401 0.1 1
IIIIIr North Carolina
I T Fund
Reprogramming of the laboratory -information -management system that makes this report possible is
being funded through a Brent from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard
environmental quality.
- Steve Troxier, Commissioner ofAgriculture

NCDASCS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronoml/
Report No. FY19-SL003546
Dennis Phillips
Page 2 of 2
Understanding the Soil Report: explanation of measurements, abbreviations and units
Recommendations
Report Abbreviations
Lime
Ac
exchangeable acidity
If testing finds that soil pH is too low for the crop(s) indicated, a time recommendation will be given in units of either
B
boron
ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting.
BS %
% CEC occupied by basic cations
For no-till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (5016/1000 sq ft) at oni
Ca%
% CEC occupied by calcium
time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate
CEC
cation. exchange capacity
is applied. If MG is recommended and lime is needed, use dolomitric lime.
cu-1
copper index
ESP
exchangeable sodium percent
Fertilizer
HM%
percent humic matter
Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of
K-I
potassium index
Ib/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies
K20
potash
for the crop being grown, not on soil test results. K-I and P-1 values are based on test results and should be> 50. If they
Mg %
% CEC occupied by magnesium
are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is
MIN
mineral soil class
an excellent source; 175 to 250 Ib per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-I levels appear
Mn
manganese
Mn-All
Mn-availability index for crop 1
only on reports for greenhouse soil of problem Samples.
Mn-Al2
Mn-availability index for crop
Mn-I
manganese index
Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z
WO
mineral-organic soil class
notations appear on the soil report, refer to $Note: Secondary Nutrients and Micrunutnenfs. In general, homeowners do not
N
nitrogen
need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit
Na
sodium
nmgr.gov/agronami/pubs.htm.
M03-N
nitrate nitrogen
ORG
organic soil class
Recommendations forsmall areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find
pH
current soil pH
the exact fertilizer grade recommended on the report, visit www.ncacr..gov/agmnomi/obpart4.hfmlMs'ind information that
P-1
phosphorus index
may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer.
P2Os
phosphate
84
sulfur index
Test Results
SS-1
soluble salt index
WN
weight per volume
Zn-AI
zinc availability index
The first seven values [soil class, HM%, WN, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The
Zn-I
zinc index
remaining 16 [P-1, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS-1, Na, ESP, SS-1, NO3-N (not mutinel
available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncaaraovv/aaronomi/uvrst.htm

NCDA8;CS Agronomic Division Phone: [phone]
Website: w .ncagr.gov/ngronomi/
Report No. FY18-SL035644
Predictive
Client:
Dennis Phillips
Advisor:
E Bruce
201 Barry Oak Rd
Synagro
Soil Report
Mehlich-3
Extraction
Statesville, NC 28625
284 Boger Rd
s`
Mocksvllle, NC 27028
s
Sampled County :I recall
mim. Links to Helpful Information
Sampled:
01/13/2016
Received:
05/18/2018
Farm: 1R-20
Completed:
05/23/2018
Client ID: 259693
Advisor ID: 475821
Sample ID: 20-06
Recommendations:
Lime
Nutrients (Ib/acre)
More
Crop
(tons/acre)
N P205
K20 Mg S
Mn
Zn
Cu B
Information
Lime History:
1-Fescue/OGrass/Tim,
M 0.0
120-200 0
0 0 0
0
0
0 0
Note: 12
2-
Test Results [units - W/V in g/c0; CEC and Na in
meq/100 cm3; NO3-N in mg/dm3]:
Soil Class:
Mineral
HM% WIV CEC BS% Ac pH
P-I K4
Ca% Mg%
S4 Mn-I Mn-All Mn-Al2
Zn-I
Zn-AI
Cu4 Na ESP
SS-1 NO3-N
0.32 0.88 15.5 89 1.6 6.3
599 135
69 16
69358 228
1238
1238
452 0.3 2
SampcID: 20-D7
Recommendations:
Lime
Nutrients
More
Crop
(tonslacre)
N P205
K20 Mg S
Mn
Zn
Gu B
Information
Lime History;
1-Fescue/OGrass/rim,
M 0.0
120-200 0
0 0 0
pH$
0
0 0
Note: 12 Note:
2-
Test Results [units -WN In gle0; CEC and Na In
meg1100 cros; NOa-N In mg/dm3]:
Soil Class:
Mineral
HM% WN CEG BS% Ac pH
P-1 K4
Ga% Mg%
S-1 Mn-I Mn-All Mn-Al2
Zn-I
Zn-AI
Cu4 Na ESP
SS-1 NO3-N
0.22 0.99 13.8 95 0.6 6.9
442 153
79 11
57 753 455
816
816
569 0.2 1
Sample ID: 20-08
Recommendations:
Lime
Nutrients (Ib/acre)
More
Crop
(tonslacre)
N P205
K20 Mg S
Mn
Zn
Cu B
Information
Lime History:
1-Fescue/OGrasslfim,
M 0.0
120-200 0
0 0 0
pH$
0
0 0
Note: 12 Nola: $
2-
Test Results [units - WN in glcm3; CEC and Na in
meq/100 cm3; NO3-N in mg/dm?]:
Soil Class:
Mineral
HM% WN CEC BS% Ac PH
P-I K-1
CaY Mg%
S-I Mn-I Mn-All MmAl2
Zn-1
Zn-AI
Cu-I Na ESP
SS-I NO3-N
0.27 0.88 16.9 94 1.1 6.7
341 107
78 12
56 483 297
759
759
594 0.2 1
North
Irk
TOba<co�Trusl Fund Commission
Reprogramming of the labcratory-information-management system that makes this report possible is
being funded through a grant from the Nodh Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner otAgriculture

NCDA&CS Agronomic Division Phone: [phone]
Webslts: v .ncagr.gov/agronomil
ReportNo. FY18-SL035644
Dennis Phillips
Page 2 of 3
Sample ID: 20-09
Recommendations: Lime
Nutrients(lb/acre)
More
Crop (tons/acre)
N P205
K20
Mg
S
Mn Zn
Cu B
Information
Lime History:
1 -Fescue/OGrasslrim, M 0.0
120-200 0
40
0
0
pH$ 0
0 0
Note: 12 Nae: $
2-
Test Results [units-WN in glee; CEG and Na In meq/100 ce; Ws-N
In mg/dO]:
Soil Class:
Mineral
HM% WN CEC BS% Ac pH P-1 K-I
Ca% Mg% S-1
Mn-I
Mn-All
Mn-Al2
Zn4 Zn-AI
Cu4 Na ESP SS-1 NOs-N
0.22 0.95 21.8 98 0.4 7.2 410 53
87 10 83
364
217
751 751
624 0.2 1

NCDA&CS Agronomic Division Phone: [phone] Website: wwwncagr.gov/agronoml/
Report No. FYIS-SLO36644
Dennis Phillips
Page 3 of 3
Understanding the Soil Report: explanation of measurements, abbreviations and units
Recommendations
Report Abbreviations
Lime
Ac
exchangeable acidity
If testing finds that sail pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either
B
baron
ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 6 inches of soil several months before planting.
BS %
% CEC occupied by basic cations
For no-till or established plantings where this is not possible, apply no more than 1 to 1.5 tontacre (50 lb/1000 sq ft) at on
ca%
% CEC occupied by caldum
time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate
CEC
cation exchange rapacity
is applied. If MG is recommended and lime is needed, use dolomitric lime.
cu-I
copper index
ESP
exchangeable sodium percent
Fertilizer
HM%
percent humic matter
Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of
K-1
potassium index
Ib/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies
K20
potash
for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be> 50. If they
Mg %
% CEC occupied by magnesium
are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is
MIN
mineral soil class
an excellent source; 175 to 250 b per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear
Mn
manganese
Mn-AI2
Mn-availability infor crop 1
only on reports. for greenhouse soil or problem samples.
Mn-Al2
ex for crop
Mn-availability index
Mn-I
manganese index
Fanners and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z
M-0
mineral-organic soil class
notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients In general, homeowners do not
N
nitrogen
need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit
Na
sodium
ncagr.govlagronomi/pubs.him.
NO3-N
nitrate nitrogen
ORG
organic soil class
Recommendations for small areas, such as home lawns/gardens, are listed in units of licit 000 sq ft. If you cannot find
pH
current soil pH
the exact fertilizer grade recommended on the report, visit www.ncaar..aov/aaronomi/oboart4.htn?g ind information that
P4
phosphorus index
may help you choose a comparable alternate. For more information, read AHomeowner's Guide to Fertilizer.
PzOs
phosphate
S-1
sulfur index
Test Results
SS-1
soluble salt index
WN
weight per volume
Zn-AI
zinc availability index
The first seven values [soil class, HM%, WN, CEC, BS%, Ac and pH] describe the soil and its degree Of acidity. The
index
remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-Al 1, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-1, SS-I, Na, ESP, SS-I, NO3-N (not routinet
Zn-I
zinc
available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncaaroov/aoronomiNvrsthtm

NCDA&CS Agronomic Division Phone: [phone]
Website: w .ncagr.gov/agronomi/
Report No.
FY18-SL037945
Predictive
Client:
Sammy Deal
Advisor:
E Bruce
449 Fan Jay Rd
Synagra
Soil Report
Mehlich-3
Extraction
Statesville, NC 28625
284 Boger Rd
Mocksville, NC 2702B
Sampled County : Iredell
Links to Helpful Information
mn. '
Sampled:
06/20/2018
Received:
06/28/2018
Farm: IR -35
Completed:
07/09/2018
Client to: 478015
Advisor to: 475021
Sample ID: 35-03
Recommendations:
Lime
Nutrients (lb/acre)
More
Crop
(tons/acre)
N P205
K20 Mg S
Mn
Zn
Cu in
Information
Lime History:
1-Fescue/OGrass/1im,
M 0.0
720-200 0
0 0 0
0
0
0
Note: 12
2-
Test Results [units -WN in g/cmS; CEC and Na in
meq/100 cm3; NO3-N in mg/dms]:
Soil Class:
Mineral
HM% WN CEC BS% Ac pH
P-1 K4
Ca% Mg%
S4 Mn -I Mn-AI7 Mn-AI2
Zn -1
Zn -AI
Cu -1 Na ESP
SS -I NOS -N
0.92 1.09 12.1 86 1.7 6.2
196 100
55 27
47 232 154
394
394
195 0.2 2
Sample ID: 35-04
Recommendations:
Lime
Nutrients (Ib/acre)
More
Crop
(tons/acre)
N P205
K20 Mg S
Mn
Zn
Cu B
Information
Lime History:
1-Fescue/OGrasslTim,M
0.0
120-200 0
60 0 0
0
0
00
Note: 12
TestResults [units -WN In g/cart; CEG and Na In
meg1100 cmP; NO3-N In mg/tlm]:
Sail Class:
Mineral
HM% WN GEC BS% Ac pH
P-1 K-1
Ca% Mg%
S-1 Mn -I Mn -All Mn-Al2
Zn -I
Zn -AI
Cu -I Na ESP
SS -1 NO3-N
0.56 1.04 10.6 92 0.9 6.5
96 38
63 27
41 411 256
742
742
101 0.2 2
` North Carolina
ToLa<c Trull Fund Commission
Reprogramming of lhelaboratory-information-management system that makes this report possihle is
heing funtled through a grant from the Nodh Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutdents and safeguard environmental quality.
- Steve Tmxler, Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagnilovlagronomi/
Report No, FYI BSL037945
Sammy Deal
Page 2 of 2
Understanding the Soil Report: explanation of measurements, abbreviations and units
Recommendations
Report Abbreviations
Lime
Ac
exchangeable acidity
If testing finds that soil pH is too low for thecrop(s) indicated, a lime recommendation will be given in units of either
8
boron
ton/acre or 16/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting.
BS%
% CEC occupied by basic cations
For no-till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (501b/1000 sq ft) at on
Ca%
% CEC occupied by calcium
time, even If the report recommends more. You can apply the rest in similar increments every six months until the full rate
CEC
cation exchange capacity
is applied. If MG is recommended and lime is needed, use dolomitric lime.
Cu4
copper index
ESP
exchangeable sodium percent
Fertilizer
HM%
percent humic matter
Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of
K-I
potassium index
Ib/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies
K20
potash
for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they
Mg %
%CEC occupied by magnesium
are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is
MIN
mineral soil class
an excellent source; 175 to 250 Ib per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear
Mn
manganese
only on reports for greenhouse soil or problem samples.
Mn-All
Mn-availability index for crop 1
Mn-A I2
Mn-availability index for crop
M
manganese index
Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z
M-0
mineral-organic soil class
notations appear on the Soil report, refer to $Note: Secondary Nutrients and Micronutrients In general, homeowners do not
N
nitrogen
need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit
Na
sodium
nmgr.gov/agranoml`/pubs.htm.
NO3-N
nitrate nitrogen
ORG
organic soil class
Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find
pH
current soil pH
the exact fertilizer grade recommended on the report, visit ncaocoov/aamnomi/obpart4.hrmMfdnd information that
P-1
phosphorus index
may help you choose a comparable alternate. For more information, read AHomeowner's Guide to Fertilizer.
P20s
phosphate
S4
sulfur index
Test Results
SS-1
soluble salt index
WN
weight per volume
The first seven values [soil class, HM%, WN, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The
Zn-AI
zinc availability index
Zn4
zinc index
remaining 16 (P-I, K-1, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS-1, Na, ESP, SS-I, NO3-N (not noutmell
available)] indicate levels of plant nutrients or other fertility measurement. Visit ~ ncaor.dov/a aronomi/uvrst.htm

SECTION 3

2018 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION IN NC
STANLY COUNTY UTIL., NC (FKA OAKBOR
STANLY COUNTY UTIL., NC WEST STANLY WWTP AEROB DIG LIQUID
DRY METRIC
MONTH/YEAR AMOUNT UNIT DRY TONS UNIT TONS
June 2018 272,800.00 G 14.46 D 13.11
July 2018 409,200.00 G 21.66 D 19.65
YEARLY TOTAL 6822000.00 G 36.12 D 32.76
2/2/2019

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Product Code
Product Name
SamPle Date
Report Range
Ratio
2170 -01 -LIQ -NC
STANLY COUNTY UTIL., NC WEST STANLY
WWTP AEROB DIG LIQUID
2/7/2018
1/1/2018-12/31/2018
0.4901
Na mg/I = (Na mg/kg x %Solids) + 100 = (2980 x 1.2700) + 100 = 37.846
Ca mg/I = (Ca mg/kg x %Solids) + 100 = (13500 x 1.2700) + 100 = 171.45
Mg mg/I = (mg mg/kg x %Solids) _ 100 = (13200 x 1.2700) - 100 = 167.64
Na meq = Na mg/I + Molec.Wgt.Na = 37.846 + 23 = 1.64548
Ca meq = Ca mg/I + Molec.Wgt.Ca = 171.45 + 20 = 8.5725
Mg meq = Mg mg/I _ Molec.Wgt.Mg = 167.64 + 12 = 13.97
SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 1.64548 + SgrRoot[0.5(8.5725+13.97)] = 0.490124
Printed: 2/4/2019
Page 1 13:44

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uu : ul y _ l _+. l� _ I .. � .
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Stanly County Utilities, NC Total Dry Tons Applied (Annual):
WQ0016247 Cation Exchange Capacity (non 503 only):
Robert Ridenhour Owner: Robert Ridenhour Predominant Soil Series:
31.19
Badin
19.1 Acres Permitted: 19.1 Site. #: NC ST 00003 Field #: ST 00003 0001
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids. use Raw Percent. #):
Sample or
Com-
posite
Date
1
2/7/18
2
3
4
5
6
7
8
9
10
11
12
%Solids
1.27
8
9
10
11
12
Arsenic
5.45
Cadmium
2
y
Copper
168
Chromi
51.2
�
Lead
17
Mercury
0.779
Molyb-
denum
14.1
Nickel
18.5
Selenium
5
0.000
0.000
0.000
0.000
0.000
Zinc
629
0.000
0.000
0.000
0.000
0.000
0.018
Total
Phos-
horns
15700
0.000
0.000
0.000
0.000
0.000
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
y
DT/AC./
�
App.
Event
1.63
Arsenic
0.018
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.018
Cadmium
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Copper
0.549
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.549
Chromi
0.167
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.167
Lead
0.056
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.056
Mercury
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Molyb-
0.046
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.046
denum
Nickel
0.060
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.060
Selenium
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
Zinc
2.056
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.056
Total
Phos-
51.308
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
51.308
horns
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that. there are significant penalties for submitting false information, including the possibility of fines and
imprisonme or knowing violations".
2 �� ��
Signat e of d Ap ter Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Stanly County Utilities, NC Total Dry Tons Applied (Annual):
WQ0016247 Cation Exchange Capacity (non 503 only):
Robert Ridenhaur Owner: Robert Ridenhour Predominant Soil Serieso-
18,1 Acres Permitted: 18.1 Site #: NC ST 00003 Field #:
4.93
Budin
5T 00003 0007
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
2/7/18
2
3
4
5
6
7
8
9
10
11
12
%Solids
1.27
9
10
11
12
DT/Ac./
Arsenic
5.45
Cadmium
2
M
App;
Copper
168
Chromi
51.2
m
Event
0.27
Lead
17
Mercury
0.779
Arsenic
0.003
0.000
Molyb-
denum
14.1
0.000
0.000
0.000
0.000
0.000
0.000
Nickel
18.5
0.000
0.000
0.003
Cadmium
0.001
0.000
0.000
Selenium
5
0.000
0.000
0.000
0.000
0.000
Zinc
629
0.000
0.000
0.001
Copper
0.091
0.000
0.000
Total
Phos-
horus
15700
0.000
0.000
0.000
0.000
0.000
0.000
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
M
App;
m
Event
0.27
Arsenic
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Cadmium
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Copper
0.091
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.091
Chromium
0.028
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.028
Lead
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.009
Mercury
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Molyb-
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.008
denum
Nickel
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
Selenium
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0:000
0.000
0.003
Zinc
0.342
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.342
Total
Phos-
8.541
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
8.541
horus
"I certify, under penalty of law, that. this document was prepared under my direction or supervision in accordance
with a system designed to assure that. qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
� /3
Signatu of and Applier Date
DENR FORM MFLSF (12/2006)

summint
ENVIRONMENTAL TECHNOLOGIES, INC
Anaiyffr-a? LoharwprieF
March 07, 2018
Adam Brigman
Synagro, NC 28134
12701 Lancaster Hwy
Pineville, NC 28134
TEL: [phone]
Summit Environmental Technologies, Inc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
TEL [phone] FAX: [phone]
Website: htto /hvl nv settek eom
FAX: [phone]
M: West Stanley 50-2170
Dear Adam Brigman: Order No.: 18020441
Summit Environmental Technologies, Inc. received 1 sample(s) on 2/8/2018 for the
analyses presented in the following report
.
There were no problems with the analytical events associated with this report unless noted
in the Case Narrative,
Quality control data is within laboratory defined or method specified acceptance limits
except where noted.
If you have any questions regarding these tests results, please feel. free to call the
laboratory.
Sincerely; �"f
r
Jennifer Woolf
Project Manager
3310 Win St.
Cuyahoga Falls, Ohio 44223
Arkansas 88-0735, California
07256CA, ColoYadq Connecticut PH -0708, Delaware, Florida NELAC E87688, Georgia E876$8, Idaho OH00923, Illinois
200061, Indiana(] -0H-13, Kansas E-10347, Kevtucky (Underground Storage Tauk) 3, KenNcky 90146, Lowsiana 04061, Maryland 339, Mimresota
409711, New Hampshire 2996, New Jersey OHOOfi, New York 11777, North Caroliha39705 a,id 631, North Dakcta R-201, Oklahoma 9940, Oregon
OH2O0001, Rhode Island LA000317, South Carolina 92016001, Texas 7104704466-11-5, Utah OH009232011-1, Virginia VELAP 9456, Washington
C891
Page 1 of 25

YOU MM I T sumnot Environmental Te hno og,e , Inc. Case Narrative
3310 Win SL
fNVIR0NF4SNTRL TECHNOLOGIES, INC. Cuyahoga Falls, Ohio 44223 WO#: 18020441
Analytical Laboratories TEL: [phone] FAX. [phone]
Website: h1W.,1Ao,awseaekcom Date: 3/7/2018
CLIENT: Synagro, NC 28134
Project: West Stanley 50-2170
WorkOrder Narrative:
18020441: This report in its entirety consists of the following documents: Cover Letter, Case Narrative,
Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody,
Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit
Environmental Technologies, h1c, Work Order Number assigned to this report.
Summit Environmental Technologies, Inc, holds. the accreditations/certifications listed at the bottom of
the cover letter that may or may not pertain to this report. State Certificates and Scopes of Accreditation
are attached as applicable. Results provided in this report for any parameter not listed on the Scope of
Accreditation should be considered "not certified."
The information contained in this analytical report is the sole property of Summit Environmental
Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of
Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results
contained in this report are only representative of the samples received. Conditions can vary at different
times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible
for use or interpretation of the data included herein.
All results for Solid Samples
are reported on
an
"as received" or "wet weight" basis unless indicated as
"dry weight" using the "-dry"
designation on
the
reporting units.
This report is
believed
to meet all of the requirements of the
accrediting agency,
where applicable. Any
comments or
problems
with the analytical events associated
with this report are
noted below.
Analytical Sequence Sample Notes:
18020441-OOlatclp-voc-mstr_tclp(8260); Sample extracted in methanol:
18020441-001a tclp-voc-mstr_tclp(8260): VOC Reporting Limit elevated due to sample being treated
as waste dilution due to matrix.
Original
Page 2 of 25

UMMINt Summit Environmental Technologies, In Qualifiers and Acronyms
R1 S 3310 Wln 5
FNVIRONIAENTALTECHNOLOOIES, INC Cuyahoga Falls, Ohio 442; wO#: 18020441
.hnalvtiral Lahoratvrles TEL: [phone] FAX: [phone]
Website: htm.#imviv.settekeo Date: 3/7/2018
These commonly used Qualifiers and Acronyms may or may not fie present in this report
Qualitiers
U
This fist of Qualifiers and Acronyms refl
The compound was analyzed for but was not detected.
J
The reported value is greater than the Method Detection Limit but less than the Reporting Limit.
IT
The hold time for sample preparation and/or analysis was exceeded.
D
The result is reported from a dilution.
E
The result exceeded the linear range of the calibration or is estimated due to interference.
MC
The result is below the Minimum Compound Limit.
The result exceeds the Regulatory Limit or Maximum Contamination Limit.
m
Manual integration was used to determine the area response.
d
Manual integration in which peak was deleted
N
The result is presumptive based on a Mass Spectral library search assuming a 1:1 response.
P
The second column confirmation exceeded 25v/ difference.
C
The result has been confirmed by GC/MS.
X
The result was not confirmed when GC/MS Analysis was performed.
B/MB+
The analyte was detected in the associated blank.
C
The ICB or CCB contained reportable amountsof analyte.
QC-/+
The CCV recovery failed low (-) or high (+).
R/QDR
The RPD was outside of accepted recovery limits.
QL-/+
The LCS or LCSD recovery failed low (-) or high (+),
QLR
The LCS/LCSD RPD was outside of accepted recovery limits.
QM-/+
The MS or MSD recovery failed low (-) or high (+).
QMR
The MS/MSD RPD was outside of accepted recovery limits.
QV-/+
The ICV recovery failed low O or high (+),
S
The spike result was outside of accepted recovery limits.
Z
Deviation; A deviation from the method was performed; Please refer to the Case Narrative for
additional information
Acronyms
ND
Not Detected RL Reporting Limit
QC
Quality Control MDL Method Detection Limit
MB
Method Blank LOD Level of Detection
LCS
Laboratory Control Sample LOQ Level of Quantitation
LCSD
Laboratory Control Sample Duplicate PQL Practical Quantitation Limit
QCS
Quality Control Sample CRQL Contract Required Quamitation Limit
)UP
Duplicate PL Permit Limit
MS
Matrix Spike RegLvl Regulatory Limit
MSD
Matrix Spike Duplicate MCL Maximum Contamination Limit
RPD
Relative Percent Different MhrCL Minimum Compound Limit
ICV
Initial Calibration Verification RA Reanalysis
ICB
Initial Calibration Blank RE Reextraction
CCV
Continuing Calibration Verification TIC Tentatively Identified Compound
CCB
Continuing Calibration Blank RT Retention Time
RLC
Reporting Limit Check CF Calibration Factor
DF
Dilution Factor RF Response Factor
ects the most commonly utilized Qualifiers and Acronyms for reporting.
Please refer to the Analytical Notes in the Case Narrative for any Qua BFiers or Acronyms that do not appear in this
list or for additional information regarding the use of these Qualifiers on reported data.
Original
Page 3 of 25

UMM111 SummitER1 mdronmentalTechn3310 Win Stolo0WinSt. WOrkor(ler
.
ENVIRONMENTAL TECHNOLOGIES, WC Cuyahoga Falls, Ohio 44223 Sample Summary
Analytical Laboratories TEG: [phone] FAX: [phone] WO#: 18020441
Website: hay.1llviviv.settek.com 07 -Mar -18
CLIENT: Synagro, NC 28134
Project; West Stanley 50-2170
Lab SamplelD Client Sample ID Tag No Date Collected Date Received Matrix
18020441-001 West Stanley TCLP 2/7/20189:00:00 AM 2/8/2018 10:15:00 AM Sludge
Page 4 of 25

R1 SV MIV s nnitEn,i,nnn,entorTeehnorWir t. Analytical Report
331010Win St.
rNVIRONMENTAL TECHNOLOGIES, mtc Cmnrhoga Falls, Ohio 44223 (base report)
Arralyfrraf Laharararles TEL: [phone] E4X. [phone] Woll: 18020441
Website: hgp.Iliviviv settek.com Date Reported: 3/7/2018
CLIENT: Synagro, NC 28134 Tag Number:
Matrix: SLUDGE Collection Date: 2/7/2018 9:00:00 AM
Lab ID: 18020441-OOIA
Project: West Stanley 50-2170
Client Sample ID West Stanley TCLP
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW7470A SW7470A Analyst: EAM
TCLP MERCURY ANALYSIS (SWI 31117470)
TCLP Mercury ND 0.00500 mg/L 1 2/21/2018 3:33:00 PM
TCLP METALS, VOC, BNA, PEST, HERBSOLID SW6010D Analyst: KMS
TCLP METALS ANALYSIS (SW131116010)
TCLP Arsenic(As) ND 0.500 mg/L 1 2/21/2018 8:26:26 PM
TCLP Barium(Ba) ND 5.00 mg/L 1 2/21/2018 8:26:26 PM
TCLP Cadmium(Cd) ND 0.100 mg/L 1 2/21/2018 8:26:26 PM
TCLP Chromium(Cr) ND 0.200 mg/L 1 2/21/2018 8:26:26 PM
TCLP Lead(Pb) ND 0.500 mg/L 1 2/21/2018 8:26:26 PM
TCLP Selenium(Se) ND 0.0500 mg/L 1 2/21/2018 8:26:26 PM
TCLP Silver(Ag) ND 0.500 mg/L 1 2/21/2018 8:26:26 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270D SW351OC Analyst: BJH
TCLP SEMI -VOLATILES ANALYSIS (SW1311/8270)
1,4 -Dichlorobenzene ND 0.0800 mg/L 2 2122/2018 5:21:00 PM
2,4,5 -Trichlorophenol ND 0.200 mg/L 2 2/22/2018 5:21:00 PM
2,4,6 -Trichlorophenol ND 0.200 mg/L 2 2/22/2018 5:21:00 PM
2,4-Dinitrotoluene ND 0.0400 mg/L 2 2/22/2018 5:21:00 PM
o -Cresol ND 0.200 mg/L 2 2/22/2018 5:21:00 PM
m/p-Crescl(s) ND 0.200 mg/L 2 2/22/2018 5:21:00 PM
Cresols, Total ND 4.00 mg/L 2 2/22/2018 5:21:00 PM
Hexachloro-1,3-butadiene ND 0.0160 mg/L 2 2/22/2018 5:21:00 PM
Hexachlorobenzene ND 0.0400 mg/L 2 2/22/2018 5:21:00 PM
Hexachloroethane ND 0.0800 mg/L 2 2/22/2018 5:21:00 PM
Nitrobenzene ND 0.0800 mg/L 2 2/22/2018 5:21:00 PM
Pentachlorophenol ND 0.200 mg/L 2 2/22/2018 5:21:00 PM
Pyridine ND 0.200 mg/L 2 2/22/2018 5:21:00 PM
Surr: 2-Fluorophenol 38.0 10- 109 %Rec 2 2/22/2018 5:21:00 PM
Surr: Phenol -d6 35.9 10-109 % Rec 2 2/22/2018 5:21:00 PM
Surr: Nitrobenzene -d5 62.1 19-120 % Rec 2 2/22/2018 5:21:00 PM
Surr: 2,4,6-Tribromophenol 33.9 10-120 % Rec 2 2/22/2018 5:21:00 PM
Surr: 2-Fluorobiphenyl 71.4 22-117 % Rec 2 2/2212018 5:21:00 PM
Qualifiers: * Value exceeds Maximum Contaminant Level. E Value above quantitation range
H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response
MC Value is below Minimum Compound Limit. N Tentatively identified compounds
ND Not Detected O RSD is greater than RSDlimit
P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 6 of 25

NUMMIT RI337010Win SSt, snnn,itEnvhonn,enla,TechnorWAnalyticalReport
St,
rNVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 (base report)
Ara(ytiraP Laharsrodes TEL: [phone] FAX: [phone] Wok 18020441
Website: hap.11ivmlv.settek.coni Date Reported: 3/7/2018
CLIENT: Synagro, NC 28134 Tag Number:
Matrix: SLUDGE Collection Date: 2/7/2018 9:00:00 AM
Lab ID: 18020441-OOIA
Project: West Stanley 50-2170
Client Sample ID West Stanley TCLP
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270D SW3510C Analyst: BJH
TCLP SEMI -VOLATILES ANALYSIS (SW131118270)
Surr: p-Terphenyl-dl4 78.4 34-116 %Rec 2 2/22/2018 5:21:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8081 SW3510C Analyst: JBN
TCLP PESTICIDES ANALYSIS (SW131118081)
Chlordane, total ND 0.0200 mg/L 2 2/22/2018 5:11:00 PM
Toxaphene ND 0.0400 mg/L 2 2/22/20185:11:00 PM
Endrin ND 0.00200 mg/L 2 2/22120185:11:00 PM
gamma -BHC ND 0.00200 mg/L 2 2/22/2018 5:11:00 PM
Heptachlor ND 0.00200 mg/L 2 2/22/2018 5:11:00 PM
Heptachlor epoxide ND 0.00200 mg/L 2 2/2212018 5:11:00 PM
Methoxychlor ND 0.00200 mg/L 2 2/22/2018 5:11:00 PM
Surr: TCMX 90.1 10-119 %Rec 2 2/22/2018 5:11:00 PM
Sun': DCB 58.8 10-119 %Rec 2 2/22/2018 5:11:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8151A SW8151A Analyst: JBN
TCLP HERBICIDES ANALYSIS (SW131118151)
2,4-D ND 1.00 mg/L 1 2/28/2018 3:38:00 AM
2,4;5 -TP ND 0.500 d mg/L 1 2/28/2018 3:38:00 AM
Surr: DCAA 102 20 - 140 %Rec 1 2/28/2018 3:38:00 AM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260B SW1311M Analyst: CTB
TCLP VOLATILES ANALYSIS
1,1-Dichloroethene ND 500 mg/L 1000 2121/20184:11:00 PM
1,2-Dichloroethane No 5.00 mg/L 1000 2/21/20184:11:00 PM
MEK No 25.0 mg/L 1000 2/21/20184:11:00 PM
Benzene No 5.00 mg/L 1000 2/21/2018 4:11:00 PM
Carbon tetrachloride No 5.00 mg/L 1000 2/21/2018 4:11:00 PM
Chlorobenzene ND 5.00 mg/L 1000 2/21/20184:11:00 PM
Chloroform ND 5.00 mg/L 1000 2/21/20184:11:00 PM
Tetrachloroethene ND 5.00 mg/L 1000 2/21/20184:11:00 PM
Trichloroethene ND 5.00 mg/L 1000 2/21/20184:11:00 PM
Vinyl chloride ND 2.00 mg/L 1000 2/21/2018 4:11:00 PM
Qualifiers: * Value exceeds Maxunum Contaminant Level. E Value above quantitation range
H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response
MC Value is below Minimum Compound Limit, N Tentatively identified compounds
ND Not Detected O RSD is greater than RSDlimit
P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 7 of 25

91 uMMI�3310 Win 9t, SummitEntironn:enralTechno(10WAnalytical Report
St,
rt4VIRON14ENTALIECNBJOLOO1ES,iNC Cuyahoga Falls, Ohio. 44223 (base report)
Analytical Laboratories TEL: [phone] FAX. [phone] WO#: 18020441
Website: htro.//mlriv .settekcom Date Reported: 3/7/2018
CLIENT: Synagro, NC 28134 Tag Number:
Matrix: SLUDGE Collection Date: 2/7/2018 9:00:00 AM
Lab ID: 18020441-OOIA
Project: West Stanley 50-2170
Client Sample ID West Stanley TCLP
Analyses
Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
Value exceeds Maximum Contaminant Level.
SW82606
SW1311M Analyst: CTB
TCLIP VOLATILES ANALYSIS
Value is below Minimum Compound Limit.
ND
Not Detected
P
Surr: 4-Bromofluorobenzene
82.0
70-130
%Rec
1000 2/21/2018 4:11:00 PM
Surr: Dibromofluoromethane
101
70-130
%Rec
1000 2/21/2018 4:11:00 PM
Surr: Toluene -d8
84.8
70-130
%Rec
1000 2/21/2018 4:11:00 PM
NOTES:
Sample treated as waste dilution due to matrix.
RCI -SOLID -W/ IGNITABILITY1030
SW9014
Analyst: MS
REACTIVE CYANIDE (9014/7.3.3.2) -SOLID
Cyanide, Reactive
ND
0.500
mg/Kg
1 2/20/2018 5:14:00 PM
RCI-SOLID-W/IGNITABILITY1030
SWI030
Analyst: AJT
IGNITABILITY OF SOLIDS (SW -846:1030)
Ignitability non-flammable
1 2/14/2018 2:00:00 PM
RCI-SOLID-WlIGNITABILITY1030
SW9045D
Analyst: CXS
PH (SW9045D)
pH
6.4
smu @20.0°C
1 2/22/2018 6:50:00 PM
RCI -SOLID -W/ IGNITABILITY1030
SW9034
Analyst: MS
REACTIVE SULFIDE (9034)17.3.4.2
Sulfide, Reactive
ND
25.0
mg/Kg
1 2/20/20185:14:00 PM
Qualifiers: �
Value exceeds Maximum Contaminant Level.
H
Holding times for prepararion or analysis exceeded
MC
Value is below Minimum Compound Limit.
ND
Not Detected
P
Second column conF matim exceeds
R
RPD outside accepted recovery limits
E Value above quantitation range
M Mazmal Integration used to determine area response
N Tentatively identified compounds
O RSD is greater than RSDliinit
PL permit Limit Original
RL Reporting Detection Limit
Page 8 of 25

SUMMIT
UIT Summit Environmental Technologies, Inc. Accreditation Program
FI3310 Win St. Analytes Report
rNVIRONMENTAL IECNNOLOOJES, INC Crryahoga Falls, Ohio 44223
Anattytical Laboratot'Fes TEL: [phone] FAX.. [phone] WO#: 18020441
Website: hno://mvw.seaekeore
07 -Mar -18
Client: Synagro, NC 28134 State: NW
Project: West Stanley 50-2170 Program Name: NC -WW -SCM
SampleID Matrix
Test Name
Analyte
Status
18020441-OOIA Sludge
Ignitability of Solids (SW -846: 1030)
Igoitability
A
Sludge
pH (SW9045D)
Hydrogen Ion (pH)
A
Sludge
Reactive Cyanide (9014/7.3.3 2}Solid
Cyanide, Reactive
U
Sludge
Reactive Sulfide (9034)/7.3.4.2
Sulfide, Reactive
U
Sludge
TCLP Herbicides Analysis (SWI 311/8151)
254,5 -TP
A
Sludge
TCLP Herbicides Analysis (SWI 311/8151)
2,4-D
A
Sludge
TCLP Herbicides Analysis (SW1311/81 51)
DCAA
A
Sludge
TCLP Mercury Analysis(SW1311/7470)
Mercury
A
Sludge
TCLP Metals Analysis (SW 1311/6010)
Arsenic
A
Sludge
TCLP Metals Analysis (SW 1311/6010)
Barium
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Cadmium
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Chromium
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Lead
A
Sludge
TCLP Metals Analysis (SW 1311/6010)
Selenium
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Silver
A
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
2,2',3,3',4,4',5,5',6,6'-
A
Decachlorobiphenyl
Sludge
TCLP Pesticides Analysis (SWI 311/808 1)
Chlordane, total
A
Sludge
TCLP Pesticides Analysis (SWI 311/8081)
Endrin
A
Sludge
TCLP Pesticides Analysis (SW13 11/808 1)
gamma -BHC
A
Sludge
TCLP Pesticides Analysis (SW 1311/8081)
I-Ieptachlor
A
Sludge
TCLP Pesticides Analysis (SWI 311/8081)
Heptachlor epoxide
A
Sludge
TCLP Pesticides Analysis .(SWI 311/8081)
Methoxychlor
A
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
Tetrachloro-m-xylene
A
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
Toxaphene
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
1,4 -Dichlorobenzene
A
Sludge
TCLP Semi -Volatiles Analysis(SW13ll/8270)
2,4,5 -Trichlorophenol
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
2,4,6-Tribrcnrophenol
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
2,4,6 -Trichlorophenol
A
Sludge
TCLPSerin-VolatilesAnalysis(SW1311/8270)
2,4Dinitrotoluene
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
2-Fiuorobiphenyl
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
2-Fluoiophenol
A
NC WW SCM A Accredited NC_WW_SCM U Unavailable
Version #2
Page 9 of 25

U 'T Sumnartc„viromneatalTechnologies, Inc. Accreditation Program
prS3310 Win St. Analytes Report
FrWRON6IENTAL TECHNOLOClaSr INC Cuyahoga Falls, Ohio 44223 y P
Arra(yacal Laboratories TEL: [phone] FAX: [phone] WO#: 18020441
Website: hap://viviv.setrek.cam- 07-Mar-I8
Client:
Sample ID
Synagro, NC
28134
Status
State:
NW
Project:
West Stanley
50-2170
Program
Name:
NC -WW -SCM
Matrix
Test Name
Analyte
Status
18020441-001A Sludge
TCLP Semi-Volatites Analysis(SW1311/8270)
2-Methylphenol
A
Sludge
TCLP Semi -Volatiles Analysis
(SW 1311/8270)
3,4-Methylphenol
A
Sludge
TCLP Semi -Volatiles Analysis(SW13ll/8270)
Cresols, Total
A
Sludge
TCLP Semi -Volatiles Analysis
(SW1311/8270)
Hexachlorobenzene
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
Hexachlorobutadiene
A
Sludge
TCLP Semi -Volatiles Analysis
(SWI 311/8270)
Hexachloroethane
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
Nitrobenzene
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
Nitrobenzene -d5
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
Pentachlorophenol
A
Sludge
TCLP Semi -Volatiles Analysis(SWI311/8270)
Phenol -d6
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
p-Terphenyl-d14
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
Pyridine
A
Sludge
TCLP Volatiles Analysis
1,1-Dichloroethene
A
Sludge
TCLP Volatiles Analysis
1,2-Dichloroethme
A
Sludge
TCLP Volatiles Analysis
2-Butanone
A
Sludge
TCLP Volatiles Analysis
4-Bromofluorobenzene
A
Sludge
TCLP Volatiles Analysis
Benzene
A
Sludge
TCLP Volatiles Analysis
Carbon tetrachloride
A
Sludge
TCLP Volatiles Analysis
Chlorobenzene
A
Sludge
TCLP Volatiles Analysis
Chloroform
A
Sludge
TCLP Volatiles Analysis
Dibromofluoromethane
A
Sludge
TCLP Volatiles Analysis
Tehachloroethene
A
Sludge
TCLP Volatiles Analysis
Toluene -d8
A
Sludge
TCLP Volatiles Analysis
Trichloroethene
A
Sludge
TCLP Volatiles Analysis
Vinyl chloride
A
NC. WW SCM A Accredited NC_WW_SCM U Unavailable
Version #2
Page 10 of 25

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SUMMIT SunnnitEm,ironnaenral Technologies, St.
3370 Win St.
ENVIRONMENTAL TECHNOLOGIES, INC, Cuyahoga Falls, Ohio 44223 Sample Log -in Check List
Analyfical Laboratorles TEL: [phone] FAX: [phone]
Website: htto:/hvwir.senek.coni
Client Name: SYN -NC -28134
Logged by; Lori Douglas
Completed By: Christopher Livengood
Reviewed By: Jennifer Woolf
Chain of Custody
1, Is Chain of Custody complete?
2. How was the sample delivered?
Lop In
3, Coolers are present?
Work Order Number: 18020441
2/8/2018 10:15:00 AM
2/9/2018 1:12:46 PM
2119/2018 1:0.8:08 PM
4, Shipping container/cooler in good condition?
Custody seals intact on shipping container/cooler?
No. Seal Date:
5, Was an attempt made to cool the samples?
6. Were all samples received at a temperature of >0° C to 6.0°C
7. Samples) in proper container(s)?
g. Sufficient sample volume for indicated test(s)?
g. Are samples (except VOA and ONG) properly preserved?
10- Was preservative added to bottles?
1 � , Is the headspace in the VOA vials less than 1/4 inch or 6 mm?
12, Were any sample containers received broken?
13. Does paperwork match bottle labels?
(Note discrepancies on chain of custody)
14. Are matrices correctly identified on Chain of Custody?
15. Is it clear what analyses were requested?
16. Were all holding times able to be met?
(If no, notify customer for authorization.)
Special Handling (if applicable)
17, Was client notified of all discrepancies with this order?
Yes
d❑
UPS
❑
Yes
❑�
Yes
0
Yes
❑
Signed By:
Yes
0
Yes
Yes
Yes❑
Yes
❑d
Yes
❑
Yes
❑
Yes
❑
Yes
❑�
Yes❑
2.4
Yes❑
Yes❑
Yes ❑
RcptNo: 1
No ❑ Not Present ❑
No ❑
NA ❑
Not Present 0
NA ❑
NA ❑
NA ❑�/
NA
No VOA Vials W
Person Notified: Date '
By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person
Regarding:
Client Instructions
16, Additional remarks:
Cooler Information
Cooler No To
Page 25 of 25
°C
Condition Seallntact
Seal No
Seal Date
Signed By
1
2.4
Page 25 of 25

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility
Name:
West
Stanly
WWTP
WQ Permit Number:
W00016247
X (Spec. 02 uptal<e)
Option/Alt. 5
Option/Alt. 6
Excee-
WWTP
Name:
West
Stanly
WWTP
NPDES Number:
NCO043532
Analysis
Monitoring Period: From 01/01/2018 To 12/31/2018
Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. 1/A (time/temp) Alt 2B (Alk Treatment) Alt. 3/C (Prior Testing)
Alt. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt 6 (Equivalent to PFRP)
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost Heat Drying Heat Treatment Thermophilic
Beta Ray Gamma Ray Pasteurization
Class B:
Alt (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Air Drying Composting Aerobic Digestion
Anaerobic Digestion
Tf nnnlirahle to alternative nerfnrmed !Class A or Clnss Rl romnlete the following monitoring data:
Parameter Allowable Levet in Sludge
Vector Attraction Redaction (40 CFR 503.33/15A NCAC 02T.1107) -Please indicate option/alternative performed
Option/Alt. 1
Option/Alt. 2
Pathogen Density
No. of
Frequency
Sample
Analytical
X (Spec. 02 uptal<e)
Option/Alt. 5
Option/Alt. 6
Excee-
of
Type
Technique
(Drying — Stable)
(Drying—Unstable)
Minimum Geo. Mean Maximum Units
dentes
Analysis
(Injection)
Fecal
2x10 to the 6O'
MPN
Coliform
power per gram
MPN/g
Grab
SM9221 C
of total solids
CPU
7005000
878,970
2,0009000
CFU/g
I
Annually
Grab
SM9222D
1000 MPN per gram of
total solids (dry weight)
Salmonella
3 MPN per 4 grams total
bacteria (in
solids (dry weight)
lieu of fecal
coliform
Vector Attraction Redaction (40 CFR 503.33/15A NCAC 02T.1107) -Please indicate option/alternative performed
Option/Alt. 1
Option/Alt. 2
Option/Alt. 3
Option/Att 4
(VS reduction)
(40 -day bench)
(30 -day bench)
X (Spec. 02 uptal<e)
Option/Alt. 5
Option/Alt. 6
Option/Alt. 7
Option/Alt. 8
(14 -Day Aerobic)
(Alk Stabilization)
(Drying — Stable)
(Drying—Unstable)
Option/Alt. 9
Option/Alt. 10
(Injection)
(Incorporation)
No vector attraction
reduction alternatives were performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify,
"This determination has been made corder my direction and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate the information used to determine that the pathogen and vector att
under penalty of law, that the pathogen requirements
in 40
CFR 503.32/15A NCAC 02T.1106 and the vector attraction
X reduction
requirement in 40 CFR 503.33/15A NCAC 02T.1107
have
been met"
"I certify,
under penalty of law, that the pathogen requirements
in 40
CFR 503,32115A NCAC 021.1106 and the vector attraction
reduction
requirement in 40 CFR 503.33/15A
NCAC 02T.1107
have
not been met," (Please note if you check this statement attach an
explanation why you have not met one or both of the requirements.)
Tommv Gibbons Plant ORC
Preparer Name and Title (Type or print)
ignature of Pre At* Date
Land Applier Name and Title (if applicable) (Type or print)
r2�
Signature of Land Applier (if applicable)
*Prepazer is defined in 40 CFR Part 503.9(r) and ISA NCAC 2T.1102 (26)
Date
raction reduction requirements have
been met. I am awaze that there are
significant penalties for
false certification including fine
and imprisonment "
Tommv Gibbons Plant ORC
Preparer Name and Title (Type or print)
ignature of Pre At* Date
Land Applier Name and Title (if applicable) (Type or print)
r2�
Signature of Land Applier (if applicable)
*Prepazer is defined in 40 CFR Part 503.9(r) and ISA NCAC 2T.1102 (26)
Date

:�i
Ism
LAaOnATOPIE$ INC.
Synagro
Adam Brigman
12701 Lancaster Hwy.
Pineville, NO 28134
NC Certification No, 402
FU11-Service Analytical& NC Drinking Water Cert No. 37735
Environmental Solutions SC Certification No. 99012
Project: 2018 Production
Project No.: West Stanley
Lab Submittal Date: 02/07/2018
Prism Work Order: 8020130
This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample
Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed
according to the referenced methods.
Data qualifiers are
flagged
individually on each
sample.
A key
reference for the data qualifiers appears at the end of Phis case
narrative.
Narrative N®tes:
This report contains a total of 4 pages.
Please call if you have any questions relating to this analytical report.
Respectfully,
PRISM LABORATORIES, INC.
Cara C. Rusmisell
Project Manager
Data Qualifiers Key Reference
ed By Cara C. Rusmisell
Review
Project Manager
BRL Below Reporting Limit
MDL Method Detection Limit
RPD Relative Percent Difference
Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and
reporting limit indicated with a J.
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 -Charlotte, NC 28224-O543
Phone: [phone]fi4-Toll Free Number: f -8 0 01529 -6 3 6 4 -Fax: [phone]

VR
e4 xc Env seance al Bol Analytical s
t _ueo�,raA �ei.oamemei sewe ons
02/09%2018
Prism Work Order: 8020130
Client Sample ID
Lab Sample ID
Matrix
Date Sampled
Date Received
West Stanley 1
8020130-01
Solid
02/07/18
02/07/18
West Stanley 2
8020130-02
Solid
02/07/18
02/07/18
West Stanley 3
8020130-03
Solid
02/07/18
02/07/18
West Stanley
8020130-04
Solid
02/07/18
02/07/18
West Stanley 5
8020130-05
Solid
02/07/18
02/07/18
West Stanley
8020130-06
Solid
02/07/18
02/07/18
West Stanley
8020130-07
Solid
02/07/18
02/07/18
Samples were received in good condition at 2.7 degrees C unless otherwise noted.
This report should not be reproduced, except In Its entirety, wilheut the written consent of Prism Laboratories, Inc.
449 Spring6rool< Road - P.O. Box 246543 - Chario[te, NC 2822A-0543
Phone: [phone] -Toll Free Number: 1-8601529-6364 -Far.: 7041525AS06

SC Certification No. 99012
NC Drinking Water Cert. No. 37735
Client Name: Synagro
Sample Date/Time Collected:
Sample DatePTime Submitted:
Full-Servioe Analytical &
Environmental Solutions
449 Springbrook Rd.
P.O. Box 240543
Charlotte, NC 28224-0543
Phone: [phone]
Fax: [phone]
Project Name: West Stanley
2-6-18 08:40 Project ID: West Stanley
2-7-18 11:36 COC Group: 8020130
Prism Sample ID: 8020130
Note: All results are reported on adry
Geometric
Mean:
878970 A
cfulg
Jill
Reporting
Limit:
878970
.��
1111 •
1111
•1
/ :
.:C
r '_. ' '
1-1.1111 •-�
111111
1
11
�r=r_�':
r r r r.
�
__,_�. � ,
1111 •
: 1111
___
_ .�.
.
r
�
..
:'.'.. ' ' •
11111-• �.
1111 lY
• i
.
:r. r_ r r
�_
_. --
• 1111 �
�
• 1111
. ____..__
.'. _.w._ w_
1:
_
'
r
,: �.
Prism Sample ID: 8020130
Note: All results are reported on adry
Geometric
Mean:
878970 A
cfulg
Reporting
Limit:
878970
-weight basis.
A: The result is less than the report
ing limit. At the request of 4he client, the value reported equals the value of the reporting
Data Reviewed By: u a.!(�,N?iLi.i� '� e; Project Manager: C. Rusmisell
Review Date: 2-9-18 Approval
Date: 2-9-18
This report
should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

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PLLR
CCU RATE -RELIABLE
LABORATORIES INC
WWW, PA RLA BS.CO\I
REPORT OF ANALYSES
Attn: ADAM BRIGMAN
SYNAGRO
12701 LANCASTER HWY
PINEVILLE, NC 28134 -
PROJECT NAME: FEB 18
DATE: 03/21/18
SAMPLE NUMBER-
13U5b2
SAMPLE ID- WEST STANLEY
SAMPLE MATRIX
50
DATE SAMPLED-
02/07/18
TIME SAMPLED -10855
DATE RECEIVED-
02/07/18
SAMPLER- A8
RECEIVED BY-
DJ
TIME RECEIVED-
1200
DELIVERED BY- AB
TYPE SAMPLE-
Grab
Page 1 of 1
ANALYSIS
ANALYSIS METHOD DATE TIME BY RESULT UNITS
30 DAY BENCH SCALE TEST VAR 02/07/18 1420 RE ATTACHED
LABORATORY DIRECTOR
P.O. Bus 411483 • Chmiouc, NC 28241-1453
Phune: (7041 i88-8}}3 • I'a.e: (7(14) i85 -S33;

PJA R
PROLABORATORSESI INC
WWW.PARLABS.COM
30 Day Bench Scale Extended Aeration Test
Percent Volatile Solids Reduction
SYNAGRO
WEST STANLEY
130562
02107118
03107118
Start: End:
TS ()
0.1381
0.1413
TS %
t28%
t30%
VS
0.1044
0.1042
VS %
75.60%
73.74%
y Mass Fraction of Volatile Solids in Liquid Sludge
0.0096866
0.0096076
x Mass Fraction of Fixed Solids in Liquid Sludge
0.0031268
0.0034207
FSVR Mass Balance
0.79%
FSVR (Van Kleeck)
0.81%
FSVR (Mass Balance
<15%
YES
FSVR (Van Kleeck) <15 %
YES
P.0.13ue 4L LJN3 � Charlotte, NC 2N24]-IiN7
Phone: (7Ui) iNS-N333 � Far: (7U -V) .iNN-N3:5

PhR
PROMPT, ACCURATE k RELIABLE
LABORATORIES) INC
W W W.PARLASS.COM
Collected
D.O.
Crucible
Tare Wt (g)
Sample Wt +
Tare Wt (g)
Liquid Sludge W
(g)
Oven Temp °C
Date/Time In
DatelTime Out
Dried Sample W
+ Tare Wt (g)
Dried Sludge Wt (g
Fixed Solids Wt (g,
Furnace Temp °C
Date/Time In
Date/Time Out
Burned Sample
Wt + Tare Wt (g
Volatile Solids Wt (g
TS%
VS%
30 Day Bench Scale Extended Aeration Test
VAR Col on 3. Percent Volatile Solids Reduction
As Received
Day 0
Day 7
Day 14
Day 21
Day 28
nOlnntlR
n9N AllR
n212111R
02128119
03107/11
YI Mass Fraction of VolaWe eolitls In
Yb Mass Fra�unn m vmarle souas m ❑e
Fraction of Fixed Solids in Liquid (Fee
xb Mass Fraction of Fixed Soda in Liquid
TS
VS
Volatile Fraction In: 0.59063
e.o. an> 411483 e chutunc, NC zszat
rl,tlne: Goal sxa-s3sa. rax: (zua) saaesas
`[I
4.80
5.12
4.96
6.13
5.93
X1
X1
X12
X30
X16
X1
21.6890
21.6890
19.3073
32.4203
22.6917
21.6863
32.4668
32.4668
30.2447
43.1857
33.4960
32.5319 1
10.7778 1
10.7778
10.9374
10.7654
10.8043
10.8456
106
106
105
106
106
106
02/07/18 14:20
02/07/18 14:20
02/14/18 09:15
02/21/18 08:40
02/28/18 10:00
03/07/18 09:15
02/08/18 13:00
02/08/18 13:00
02/15/18 10:00
02/22/18 09:15
03/01/18 10:15
03/08/18 09:00
21.8271
21.8271
19.4479
32.5594
22.8342
21.8276
0.1381
0.1381
0.1406
0.1391
0.1425
0.1413
.21.6890
0.0337
0.0346
0.0344
0.0367
0.0371
550
550
550
550
550
02/08/18 15:40
02/15/18 14100
02/22/18 13:50
03101/18 15:00
03/08/18 121,:50
02/08/18 16:50
02/15118 15:05
02/22/18 16:00
03/01/18 16:10
03/08!18 1
:10
21.7227
19.3419
32.4547
22.7284
21.7234
0,1044
0.1060
0.1047
0.1058
0.1042
1.28%
1.28%
1.29%
1.29%-
1.32%
1.30%
75.60%
75.39%
75.27%
74.25%.
73.74%,
YI Mass Fraction of VolaWe eolitls In
Yb Mass Fra�unn m vmarle souas m ❑e
Fraction of Fixed Solids in Liquid (Fee
xb Mass Fraction of Fixed Soda in Liquid
TS
VS
Volatile Fraction In: 0.59063
e.o. an> 411483 e chutunc, NC zszat
rl,tlne: Goal sxa-s3sa. rax: (zua) saaesas
`[I

PAR
LABORATORIES, INC.
www.pariabs.com
Shipping:
2217 Graham Park Drive
Charlotte, NC 28273
CHAIN OF CUSTODY
PAR Laboratories, Inc
Phone[phone]
Fax [phone]
Mailing:
PO Box 411483
Charlotte, NC 28241-1483
It I8 essenllal that all information be recortled on this Chain of Custody document for acceptance 6y PAR Laboratories, Inc. and the Nodh
Company Name (billing)
Comments/ Special Instructions
Clarifier Effluent provided in the event that
SYNAGRO CENTRAL
Set Up
Date/Time
Address
the sample needs to be reduced to below
12701 LANCASTER HWY
2% solids.
City, State a zip code
PINEVILLE INC 28134
Point of Contact Et. Telephone Number
ADAM BRIGMAN 704-650-4341
Sample
Taken By:
PRINTEp NAME
4
ARE SAMPLES FOR STATE or EPA REPORTING? YES I/ NO
*Sample Type: DW WW c/ GWMW HW Solt Other
Sample Temp at time of sampling: ° C Sample Temp upon receipt: ° C
'"Field Preserved: Yes No Teflon Liner/Zero Headspace: Yes No n/a
Residual Chlorine checked at time of sampling (Y/N): Dechlorination Necessary (Y/N):
Cllent Sample I.D.
(Sample Location !Number)
Relinquished
7� or e
Comp
Grab
Preserv.
Set Up
Date/Time
Collection
Datelrlme
nalyses
Requested
Welt Staple 30 n«
v
TcE
2 35
30 nrq( l7
Relinquished
Received by:
Datelrime
C=Composite G=Grab DW=Drinking Water WW=Wastewater GWMW=Groundwater Monitoring Well HW=Hazardous
Waste

Agricultural Lime Application Log
Year: 2018
Project: West Stanley 50-2170
#lime has been ordered but not spread
Field Grower Soil I
Lime Require Tons/Acr Date Total
(state -county -site -field) 057H
from soil anal sis A lied A lied Acres
NC -ST -03-01 Robert Ridenhour6.0
0.0 0.0 0 19.1
NC
-ST -03-07 Robert Ridenhour=11
0.8 1.0 ® 18.1
#lime has been ordered but not spread

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2018 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION IN NC
COLUMBUS, NC
COLUMBUS, NC WWTF AEROBICALLY DIGESTED LIQUID
DRY METRIC
MONTHNEAR AMOUNT UNIT DRYTONS UNIT TONS
July 2018 210,800.00 G 24.35 D 22.09
YEARLY TOTAL 210,800.00 G 24.35 D 22.09
zizizois

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Waypoint.
ANALYTICAL
8/9/2018
Synagro SW LLC/ Columbus MS
C Simmons- 56-2994
501 Woodall Road
Decatur, AL, 35601
Ref: Analytical Testing
Report Number: 18-208-0206
Project Description: Columbus WWTP
7621 Whitepine Road, Richmond, VA 23237
Main 804-743.9401 °Fax [phone]
www.waypointa nalytica I. com
Dear CSimmons- 56-2994:
Waypoint Analytical Virginia, Inc. received samples) on 7/27/2018 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were pertormed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures pertormed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were pertormed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required tc be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
A
Sincerely,
P..N a° cr�r
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses pertormed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Arizona AZ0629 New Jersey VA031 Pennsylvania 68-03109 Virginia 460014
Florida E871087 North Carolina 257 South Carolina 93007
Y +a
Page 1 of 7

Waypoint.
ANALYTICAL
Client: Synagro SW LLC/ Columbus MS
Project: Columbus WWTP
Lab Report Number: 18-208-0206
Date: 8/9/2018
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypointanalytica Lmm
CASE NARRATIVE
Nitrate +Nitrite Nitrogen Method 4500NO3F-2011
Sample 62007 (Columbus WWTP)
Analyte: NO3+NO2-N
OC Batch No: E65376/E65341
The MS/MSD recoveries are considered insignificant due to the level of analyte present in the parent sample
relative to the spike level .RPD is based on the MS/MSD results and should be evaluated as laboratory
duplicates.
Solids Total Mercury Analysis - CVAA Method SW -74716
Analyte: Hg
OC Batch No: E65368/E65351
MS/MSD Recovery failed, PDS confirmed matrix interference
Page 2 of 7

Waypoi nt . 7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
ANALYTICAL www,waypointanalytical.com
Sample Summary Table
Report Number: 18-208-0206
Client Project Description: Columbus WWTP
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
62007
Columbus
WWiP
Solids
07/24/2018
11:00
07/27/2018
62007
Columbus
WWiP
Solids
07/24/2018
11:00
07/27/2018
6010D
WiN
WTN: Waypoint Analytical -TN, Memphis, TN, Certifcation: #1354
Page 3 of 7

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Waypoint
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypointa nalytf ca I.co m
Cooler Receipt Form
Customer Number: 90024
Customer Name: Synagro SW LLC/ Columbus MS
Report Number: 18-208-0206
Shipping Method
0 Fed Ex � US Postal � Lab � Other
UPS � Client � Courier Thermometer ID:
Shipping container/cooler uncompromised? � Yes � No
Number of coolers received �� 1
Custody seals intact on shipping container/cooler? � Yes � No � Not Required
Custody seals intact on sample bottles? � Yes � No � Not Required
Chain of Custody (COC) present? � Yes � No
COC agrees with sample label(s)? � Yes � No
COC properly completed � Yes � No
Samples in proper containers? � Yes � No
Sample containers intact? � Yes Q No
Sufficient sample volume for indicated test(s)? � Yes � No
All samples received within holding time? � Yes � No
Cooler temperature in compliance? � Yes � No
Cooler/Samples arrived at the laboratory on ice. � Yes � No
Samples were considered acceptable as cooling
process had begun.
Water -Sample containers properly preserved � Yes � No � WA
Water -VOA vials free of headspace � Yes 0 No � N/A
Trip Blanks received with VOAs � Yes � No � N/A
Soil VOA method 5035 —compliance. criteria met 0 Yes � No � N/A
High concentration container (48 hr) � Low concentration Encore samplers (48 hr)
� High concentration pre -weighed (methanol -14 d) � Low cont pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? � Yes � No
Comments:
Signature: Brandi Watson Date &Time: 07/27/2018 13:51:22
Page 6 of 7

Sodium Absorption Ratio Calculation (SAR)
Product Code
Product Name
Sample Date
Report Range
Ratio
2143-01-AEDLIQ-NC
COLUMBUS, NC WWTF AEROBICALLY
7/24/2018
1/1/2018-12/31/2018
0.2128
DIGESTED LIQUID
Na mg/I = (Na mglkg x %Solids) + 100 = (1430 x 2.7700) :100 = 39.611
Ca mg/I = (Ca mg/kg x %Solids) :100 = (88600 x 2.7700) + 100 = 2454.22
Mg mg/I = (mg mg/kg x %Solids) _ 100 = (3590 x 2.7700) + 100 = 99.443
Na meq = Na mg/I + Molec.Wgt.Na = 39.611 + 23 = 1.72222
Ca meq = Ca mg/I + Molec.Wgt.Ca = 2454.22 + 20 = 122.711
Mg meq = Mg mg/I + Molec.Wgt.Mg = 99.443 _ 12 = 8.28692
SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 1.72222 + SgrRoot[0.5(122.711+8.28692)] = 0.2128
Printed: 2!2/2019
Page 1 19:10

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Columbus, NC Total Dry Tons Applied (Annual): 18.62
Permit #: W00016247 Cation Exchange Capacity (non 503 only):
Operator: Danny &Ethan Edwards Owner: Danny &Ethan Edwards Predominant Soil Series: CEB2
Acres Used: 10.6 Acres Permitted: 10.6 Site #: NC PO 00007 Field #: PO 00007 0001
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #):
Sample or
Com-
posite
Data
1
7/24/18
2
3
4
5
6.
7
8
9
10
11
12
%Solids
2.77
8
9
10
11
12
Arsenic
5
Cadmium
1.39
Copper
592
Chromium
47.8
�
Lead
33.7
Mercury
0.557
°'
Molyb-
denum
6.01
Nickel
20.9
Selenium
5
0.000
0.000
0.000
0.000
0.000
Zinc
982
0.000
0.000
0.000
0.000
0.000
0.018
Total
Phos-
horns
15200
0.000
0.000
0.000
0.000
0.000
0.000
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
�
App
°'
Event
1.76
Arsenic
0.018
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.018
Cadmium
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Copper
2.080
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.080
Chromi
0.168
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.168
Lead
0.118
0.000
0.000
0.000
0:000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.118
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.021
denum
Nickel
0.073
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.073
Selenium
0.018
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.018
Zinc
3.451
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.451
Total
Phos-
53.413
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
53.413
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
L_� NW Imo. Z �
Signature d Applier Da e
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING Si1MMARY FORM*
Attach this form
to the corresponding Field
Loading
Summary Form to be
submitted in Annual
Report
Facility Name:
Columbus, NC
8
Tota] Dry Tons
Applied (Annual):
5.73
Permit #: W00016247
Operator: Danny &Ethan Edwards Owner:
Acres Used: 7.7 Acres Permitted:
Cation Exchange Capacity (non 503 only):
Danny &Ethan Edwards Predominant Soil Series:
7.7 Site #: NC PO 00007 Field #:
Pacolet
PO 00007 0002
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
7/24/18
2
3
4
5
6
7
8
9
10
11
12
%Solids
2.77
8
9
10
11
12
Arsenic
5
Cadmium
1.39
�
Copper
592
Chromi
47.8
0
Lead
33.7
Mercury
0.557
w
Molyb-
denum
6.01
Nicke]
20.9
Selenium
5
0.000
0.000
0.000
0.000
0.000
Zinc
982
0.000
0.000
0.000
0.000
0.000
0.007
Total
Phos-
horns
15200
0.000
0.000
0.000
0.000
0.000
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
�
DT/Ac./
0
App.
w
Event
0.74
Arsenic
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Cadmium
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Copper
0.881
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.881
Chromi
0.071
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.071
Lead
0.050
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.050
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.009
denum
Nickel
0.031
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.031
Selenium
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Zinc
1.461
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.461
Total
Phos-
22.618
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
22.618
horns
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
z. Z l
Dat
DENR FORM MFLSF (12/2006)

TISUMM111-
rMeIRONMENTAL
AnatyBeal Laharatw es
March 06, 2018
Erik Bruce
Synagro
284 Boger Rd.
Mocksville, NC 27028
TEL: ('336) 998-7150
FAX: [phone]
RE: Columbus WWTP
Dear Erik Bruce:
Summit Erndronnrental7kchnclogies, lna
3310 Win St.
CuTahoga Fulls, Ohio 44223
TEL [phone] FAX: [phone]
Wehsite: http://ivivtrseuck.com
Order Na.: 18021228
Summit Environmental Technologies, Inc. received 1 samples) on 2/23/2018 for the
analyses presented in the following report.
There were no problems with the analytical events associated with this report unless noted
in the Case Narrative.
Quality control data is within laboratory defined or method specified acceptance limits
except where noted.
If you have any questions regarding these tests results, please feel free to call the
laboratory.
Sincerely,
Jennifer Woolf
g
Project Manaer
3310 W n St.
Cuyahoga Falls, Ohio 44223
Arkansae.88-0735, California 0725GCA, Colored
Connecticut PH -0108, Delaware, Florida NELAC 687688, Georgia E87688, Idaho OH00923, lllinois
200061, Indicia C -OH -13, Kansas &10347, Kentucky (Undergrowd Storage Tank) 3, Kentucky 90146, Lowsiava 04061, Maryland 339, Minnesota
409711, New Hampshire 2996, New Jersey GH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Oklahoma 9940, Oregon
OH2O0001, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-11-51 Utah OH009232011-1, Virginia VELAP 9456, Washington
C891
Page 1 of 24

SUMMIT SumnntEnvironmental Technologies, Inc.ffiCase Narrative
3310 Win St.
�rNWRONAIENTAL TECHNOLOGIES, INC- Cuyahoga Falls, Ohio 44223 WO#: 18021228
Analytical tahoretone9 TEL: [phone] FAX: [phone]
Wehsite: huy.*1A ww.settek.com Date: 3/6/2018
CLIENT: Synagro
Project: Columbus WWTP
WorkOrder Narrative:
18021228: This report in its entirety consists of the following documents: Cover Letter, Case Narrative,
Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody,
Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit
Environmental Technologies, Inc., Work Order Number assigned to this report.
Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of
the cover letter that may or may not pertain to this report. State Certificates and Scopes of Accreditation
are attached as applicable. Results provided in this report for any parameter not listed on the Scope of
Accreditation should be considered "not certified."
The information contained in this analytical report is the sole property of Summit Environmental
Technologies, hie, and that of the customer. It cannot be reproduced in any form without the consent of
Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results
contained in this report are only representative of the samples received. Conditions can vary at different
times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible
for use or interpretation of the data included herein.
All results for Solid Samples
are reported
on an
"as received" or
"wet weight" basis unless indicated as
"dry weight" using the "-dry"
designation
on the
reporting units.
noted below.
This report is
believed
to meet all of the requirements. of the
accrediting agency,
where applicable. Any
comments or
problems
with the analytical events associated
with this report are
noted below.
Analytical Sequence QC Notes:
ccv 7359 20ppb tclp-voc-mstr_tclp(8260): This CCV rerun exhibited high recovery for Vinyl Chloride.
All TCLP samples were nondetect for Vinyl Chloride. The CCV meets all other criteria.
Original
Page 2 of 24

SU'NI- Sununit Environmental Technologies, In Qualifiers and Acronyms
ffI3310 Win
DIVIRONMENTAL IECHNGLOnI=S, INC. Cuyahoga Falls, Ohio 4422 wG#: 18021228
Arrafyticaf Laborafurles TEL.: [phone] FLY: (330) 253-446
Website: haw1luiviv.settek.co. Date: 3/6/2018
These commonly used Qualifiers and Acronyms may or may not be present in this report
QualiSers
U
This list of Qualifiers and Acronyms refl
The compound was analyzed for but was not detected.
J
The reported value is greater than the Method Detection Limit but less than the Reporting Limit.
I
The hold time for sample preparation and/or analysis was exceeded.
D
The result is reported from a dilution.
E
The result exceeded the linear range of the calibration or is estimated due to interference.
MC
The result is below the Minimum Compound Limit.
*
The result exceeds the Regulatory Limit or Maximum Contamination Limit.
m
Manual integration was used to determine the area response.
d
Manual integration in which peak was deleted
N
The result is presumptive based on aMass Spectral library search assuming a 1:1 response.
P
The second column confirmation exceeded 25% difference.
C
The result has been confirmed by GC/MS.
X
The result was not confirmed when GUMS Analysis was performed.
B/MB+
The analyte was detected in the associated blank.
G
The ICB or CCB contained reportable amounts of analyte.
QC-/+
The CCV recovery failed low(-) or high (+).
VQDR
The RPD was outside of accepted recovery limits.
QL-/+
The LCS or LCSD recovery failed low (-) or high (+),
QLR
The LCS/LCSD RPD was outside of accepted recovery limits.
QM-/+
The MS or MSD recovery failed low (-) or high (+),
QMR
The MS/MSD RPD was outside of accepted recovery limits.
QV-/+
The ICV recovery failed low (-) or high (+).
5
The spike result was outside of accepted recovery limits.
Z
Deviation; A deviation from the method was performed; Please refer to the Case Narrative for
additional information
Acronyms
ND
Not Detected RL Reporting Limit
QC
Quality Control MDL Method Detection Limit
MB
Method Blank LOD Level of Detection
LCS
Laboratory Control Sample LOQ Level of Quantitation
LCSD
Laboratory Control Sample Duplicate PQL Practical Quantitation Limit
QCS
Quality Control Sample CRQL Contract Required Quantitation Limit
DLP
Duplicate PL Permit Limit
M9
Matrix Spike RegLvl Regulatory Limit
MSD
Matrix Spike Duplicate MCL Maximum Contamination Limit
RPD
Relative Percent Different MiaCL Minimum Compound Limit
ICV
Initial Calibration Verification RA Reanalysis
ICB
Initial Calibration Blank RC Reextraction
CCV
Continuing Calibration Verification TIC Tentatively Identified Compound
CCB
Continuing Calibration Blank RT Retention'rime
RLC
Reporting Limit Check CF Calibration Factor
DF
Dilution Factor RF Response Factor
ects the most commonly utilized Qualifiers and Acronyms for reporting.
Please refer to the Analytical Notes in the CaseNarrative for any Qualifiers or Acronyms that do not appear in this
list or for additional information regarding the use of these Qualifiers on reported data.
Original
Page 3 of 24

5 U 1 01. Summit Envbromnental Technologies, Inc. Workorder
3310 Win St.
rNVIRONPAEN'NAL TECHNOLOGIES, Inc. Cuyahoga Falls, Ohio 44223 Sample Summary
Anaf yHaai tabaarooes TEL: [phone] FAX: [phone] Woll: 18021228
Website: low :/hmviv.settekcom
06 -Mar -18
CLIENT: Synagro
Project: Columbus WWTP
Lab SampleID Client Sample ID Tag No Date Collected Date Received Matrix
1 802 122 8-001 Columbus W WTP 2/16/2018 10:00:00 AM 2/23/2018 10:15:00 AM Sludge
Page 4 of 24

S1Tsnm,;lA,,,ro,me,wlran,3310WiSt. DATES REPORT
■ 3310 Ilrin'SI.
ENVINONIAENTAI- TECHN01-00159, INC- Cuyahoga Falls', Ohio a{_23 WO#: 18021228
Analykeal LnbAYalorles TEL: [phone] FAX: [phone]
Website: 11 ''nv�i ve0ekca, 06-M610144
Client: Synagro
Project: Columbus WWTP
Sample Client Sample 1D Collection Date Matrix TestName
Leacbete Dale
Prep Dah
Analysis Date
18021228-OOIA Columbus WWTP 2/16201810:00x00 AM Sludge Ignitability of Solids (SW -846:1030)
3/2/20181: 45:00 PM
pH (SW9045D)
3/5/2018 2:33:00 PM
Reactive Cyanide (9014/T33.2) -Solid
2/26/2018 5.02:00 PM
Reactive Sulfide (9034)/1.3.4.2
2/26/2018 5:02.00 PM
TCLP Herbicides Analysis Cato 1311/82/24/20184:00:00 PM
2/26/201811x45:00 A
3/1/2018.2:4100 AM
TCLP Mercury Analysis (SW1311/74'=4/20184'00.00 PM
2/27/201810:55:ODA
2/27/20182: 54:00 PM
TCLP Metals Analysis(SW 13 I lodHO 2/24/20184:00:00 PM
M6/2018
2/27/2018 5:11:17 PM
TCLP Pesticides Analysis (SW1311/8(2/24/20184:00:00 PM
2/26/201811: 00 CO A
2/28/20187: 35: 09 PM
TCLP Semi -Volatiles Analysis 2/24/20184:00: 00 PM
2/26/20187: 00: 00 AM
2/27/2018 10900 AM
(SW1311/8270)
TCLPVoleliles Analysis
2J24/2018 4: 00: 00 PM
1/25/20183 i9: 00 PM
O�ginal
Page 5 of 24

NUMMITSummit Environmental Technologies, Inc.FI3310 Win St. Analytical Report
fNVIRONMENIX IPCHNOLOGIE4, INQ Cuyahoga Falls, Ohio 44223 (base report)
Anatyfirat Laharerorlen TEL: [phone] FIX: [phone] WO#: 18021228
Website: htm:/Avww.seuek.coin Date Reported: 3/6/2018
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 2/16/2018 10:00:00 AM
Lab ID: 18021228-OOIA
Project: Columbus WWTP
Client Sample ID Columbus WWTP
Analyses Result RL Qual Units DE Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW7470A SW7470A Analyst: EAM
TCLP MERCURYANALYSIS (SWIM1/7470)
TCLP Mercury NO 0.00200 mg/L 1 2/27/2018 2:54:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW6010D SW3010A Analyst: KMS
TCLP METALS ANALYSIS (SW131116010)
TCLP Arsenic(As) ND 0.500 mg/L 1 2/27/2018 5:11:17 PM
TCLP Barium(Ba) ND 5.00 mg/L 1 2/27/2018 5:11:17 PM
TCLP Cadmium(Cil) ND 0.100 mg/L 1 2/2712018.5:11:17 PM
TCLP Chromium(Cr) NO 0.200 mg/L 1 2/27/2018 5:11:17 PM
TCLP Lead(Pb) NO 0.500 mg/L 1 2/27/2018 5:11:17 PM
TCLP Selenium(Se) NO 0.0500 mg/L 1 2/27/2018 5:11:17 PM
TCLP Silver(Ag) NO 0.500 mg/L 1 2/27/20185:11:17 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW0270D SW351OC Analyst: BJH
TCLP SEMI -VOLATILES ANALYSIS (SW131118270)
1,4 -Dichlorobenzene ND 0.0800 mg/L 2 2/27/20181:09:00 AM
2,4,5 -Trichlorophenol ND 0.200 mg/L 2 2/27120181:09:00 AM
2,4,6 -Trichlorophenol ND 0.200 mg/L 2 2/27/2018 1:09:00 AM
2,4-Dinitrotoluene NO 0.0400 mg/L 2 2/27/2018 1:09:00 AM
o -Cresol NO 0.200 mg/L 2 2/27/2018 1:09:00 AM
m/p-Cresol(s) NO 0.200 mg/L 2 2/27120181:09:00 AM
Cresols, Total ND 4.00 mg/L 2 2/27120181:09:00 AM
Hexachloro-1,3-butadiene NO 0.0160 mg/L 2 2/27/20181: 09:00 AM
Hexachlorobenzene NO 0.0400 mg/L 2 2/27/20181:09x00 AM
Hexachloroethane NO 0.0800 mg/L 2 2/27/2018 1:09:00 AM
Nitrobenzene NO 0.0800 mg/L 2 2/27/20181:09:00 AM
Pentachlorophenol NO 0.200 mg/L 2 2/27/20181:09:00 AM
Pyridine NO 0.200 mg/L 2 2/27120181:09:00 AM
Surr: 2-Fluorophenol 40.5 10-109 %Rec 2 2/27/2018 1:09:00 AM
Surr: Phenol -d6 19.1 10-109 %Rec 2 2/27/2018 1:09:00 AM
Surr. Nitrobenzene -d5 68.2 19-120 %Rec 2 2/27/2018 1:09:00 AM
Surr: 2,4,6-Tribromophenol 38.6 10-120 %Rec 2 2/27/2018 1:09:00 AM
Surr: 2-Fluorobiphenyl 63.3 22-117 %Rec 2 2/27/2018 1:09:00 AM
Qualifiers: * Value exceeds Maximum Contaminant Level. E Value above quantitation range
H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response
MC Value is below Mimmum Compound Limit. N Tentatively identified compounds
ND Not Detected O RSD is greater than RSDlimit
P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 6 of 24

sutomlZ san,mitEnvironmental TechnnlW. Analytical Report
331010Wi Stn Sl.
rNVIRONMEN'rAl. 7£CHNOLOOIES,,NC_ Cuyahoga Falls, Ohio 44223 (base. report)
Anafytical Labaaiw9es TEL: [phone] FAX. [phone] WO#: 18021228
W bsile: htta:/hu,umsettek.com Date Reported: 3/6/2018
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 2/16/2018 10:00:00 AM
Lab ID: 18021228-OOIA
Project: Columbus WWTP
Client Sample ID Columbus W WTP
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270D SW351OC Analyst: BJH
TCLP SEMI -VOLATILES ANALYSIS (SW131118270)
Surr: p-Terphenyl-d14 75.2 34-116 %Rec 2 2/27/2018 1:09:00 AM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8081 SW3510C Analyst: JBN
TCLP PESTICIDES ANALYSIS (SW1311/8081)
Chlordane, total ND 0.0100 mg/L 1 2/28/20187:35:00 PM
Toxaphene ND 0.0200 mg/L 1 2/28/20187:35:00 PM
Endrin ND 0.00100 mg/L 1 2/28/20187:35:00 PM
gamma -BHC ND 0.00100 mg/L 1 2/28/2018 7:35:00 PM
Heptachlor ND 0.00100 mg/L 1 2/28/2018 7:35:00 PM
Heptachlor epoxide ND 0.00100 mg/L 1 2/28/2018 7:35:00 PM
Methoxychlor ND 0.00100 mg/L 1 2/28/2018 7:35:00 PM
Surr: TCMX 102 10-119 %Rec 1 2/28/2018 7:35:00 PM
Surr: DCB 71.8 10-119 %Rec 1 2/28/20187:35:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8151A SW8151A Analyst: JBN
TCLP HERBICIDES ANALYSIS (SW131118151)
214-D ND 1.00 mg/L 1 3/1/20182:41:00 AM
27415 -TP ND 0.500 d mg/L 1 311/20182:41:00 AM
Surr: DCAA 84.4 20-140 %Rec 1 3/1/2018 2:41:00 AM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260B SW1311M Analyst: CTB
TCLP VOLATILES ANALYSIS
1,1-Dichloroethene ND 0.0500 mg/L 10 2/26/2018 3:39:00 PM
1,2-Dichloroethane ND 0.0500 mg/L 10 2/26/2018 3:39:00 PM
MEK ND 0.250 mg/L 10 2/26/2018 3:39:00 PM
Benzene ND 0.0500 mg/L 10 .2126/2018 3:39:00 PM
Carbon tetrachloride ND 0.0500 mg/L 10 2/26/2018 3:39:00 PM
Chlorobenzene ND 0.0500 mg/L 10 2/26/20183:39:00 PM
Chloroform ND 0.0500 mg/L 10 2/26/20183:39:00 PM
Tetrachloroethene ND 0.0500 mg/L 10 2/26/2018 3:39:00 PM
Trichloroethene ND 0.0500 mg/L 10 2/26/2018 3:39:00 PM
Vinyl chloride ND 0.0200 QC+ mg/L 10 2/26/2018 3:39:00 PM
Qualifiers: * Value exceeds Maximum Contaminant Level. B Value above quantitation range
H Holding times for preparation or analysis exceeded M Manual Integration used to
Page 7 of 24
determine area response
MC
Value is below Minimum Compom,d Limit
N
Tenmtively identified compounds
ND
Not Detected
O
RSD is greater than RSDbmit
P
Second column confirmation exceeds
PL
Permit Limit Original
R
RPD outside accepted recovery limits
RL
Reporting Detection Limit
Page 7 of 24

NUMM'T Summit Environmental Technologies, Inc.
FI3310 Win St.
FrWIRONMENTAL IEC14NOLOOIESF INC Cuyahoga Falls; Ohio 44223
Analytical Laboralooes TEL: [phone] FAX: [phone]
Website: htm:/Avrviv.seltek.aom
Analytical Report
(base report)
WO#: 15021228
Date Reported: 3/6/2018
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 2/16/201810:00:00 AM
Lab ID: 18021228-OOIA
Project: Columbus WWTP
Client Sample ID Columbus W WTP
Analyses Result RL Qual Units DF Date. Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
Value exceeds Maximum Contaminant Level.
SW8260B
SW1311M Analyst: CTB
TCLP VOLATILES ANALYSIS
Valne is below Minhnum Cmnpound Limit.
ND
Not Detected
P
Second column confirmation exceeds
Sum. 4-Bromofluorobenzene
92.2
70 - 130
% Rec
10
2/26/2018 3:39:00 PM
Surr: Dibromofluoromethane
102
70-130
%Rec
10
2/26/2018 3:39:00 PM
Surr: Toluene -d8
98.5
70-130
% Rec
10
2/26/2018 3:39:00 PM
RCI -SOLID -W/ IGNITABILITY1030
SW9014
Analyst: MS
REACTIVE CYANIDE (901417.3.3.2) -SOLID
Cyanide, Reactive
ND
0.500
mg/Kg
1
2/26/2018 5:02:00 PM
RCI -SOLID -WI IGNITABILITY1030
SW1030
Analyst: AJT
IGNITABILITY OF SOLIDS (SW -846:1030)
Ignitability non-flammable
1
3/2/2018 1:45:00 PM
RCI -SOLID -W/ IGNITABILITY1030
SW90450
Analyst: DHC
PH (SW9045D)
pH
6.9
s.u.@19.9C
1
3/5/2018 2:33:00 PM
RCI -SOLID -W/ IGNITABILITY1030
SW9034
Analyst: MS
REACTIVE SULFIDE (9034)17.3.4.2
Sulfide, Reactive
ND
25.0
mg/Kg
1
2/26/2018 5:02:00 PM
Qualifiers: *
Value exceeds Maximum Contaminant Level.
H
Holding times for prepazation or analysis exceeded
MC
Valne is below Minhnum Cmnpound Limit.
ND
Not Detected
P
Second column confirmation exceeds
R
RPD outside accepted recovery limits
E Value above quantitation range
M Manual Integration used to determine area response
N Tentatively identified compounds
O RSD is greater than RSDlimit
PL Permit Limit Origin)
RL Reporting Detection Limit
Page 8 of 24

U 'T Summit Environmental Technologies, Inc. Accreditation Program
HIS3310 win si. Analytes Report
rNVIRONh1ENYAL 1ECHNOLOGI Es, INC Cuyahoga Falls, Ohio 44213 Y
Anafvtcal LaboraroRes TEL: [phone] FAX: [phone] WO#: 18021228
Website: htty.Iliviviv.settek.com 06Mar-18
Client: Synagro State: NW
Project: Columbus WWTP Program Name: NC—WW—SCM
Sample H) Matrix
Test Name
Analyte
Status
18021228-OOIA Sludge
Ignitablity of Solids (SW -846:1030)
Ignitability
A
Sludge
pH(SW9045D)
Hydrogen Ion Hill)
A
Sludge.
Reactive Cyanide (9014/7.3.3.2) -Solid
Cyanide, Reactive
U
Sludge
Reactive Sulfide (9034)/7.3.4.2
Sulfide, Reactive
U
Sludge
TCLP Herbicides Analysis (SW1311/8151)
23435 -TP
A
Sludge
TCLP Herbicides Analysis (SW1311/8151)
234-D
A
Sludge
TCLP Herbicides Analysis(SW1311/8151)
DCAA
A
Sludge
TCLP Mercury Analysis(SW131in470)
Mercury
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Arsenic
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Barium
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Cadmium
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Chromium
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Lead
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Selenium
A
Sludge
TCLP Metals Analysis(SW1311/6019)
Silver
A
Sludge
TCLP Pesticides Analysis(SW1311/8081)
2,2',3,3',4,4',5,5',6,6'-
A
Decachlorobiphenyl
Sludge
TCLP Pesticides Analysis (SWI 311/8081)
Chlordane, total
A
Sludge
TCLP Pesticides Analysis (SWI 311/8061)
Endrin
A
Sludge
TCLP Pesticides Analysis (SWI 311/8081)
gamma -BHC
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Heptachlor
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Heptachlor epoxide
A
Sludge
TCLP Pesticides Analysis(SW1311/8081)
Methoxychlor
A
Sludge
TCLP Pesticides Analysis (SWI 311/8081)
Totrachloro-m-xylene
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Toxaphene
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
1,4 -Dichlorobenzene
A
Sludge
TCLP Somi-Volatiles Analysis (SW1311/8270)
2;4,5 -Trichlorophenol
A
Sludge
TCLP Semi -Volatiles Analysis (SWI311/8270)
2,4,6-Tribromophenol
A
Sludge
TCLP Semi -Volatiles Analysis (SW13I1/8270)
2,4,6 -Trichlorophenol
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
2,4Dinitrotoluene
A
Sludge
TCLP Send -Volatiles Analysis(SW1311/8270)
2-Fluorobiphenyl
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
2-Fluorophenol
A
Key
Key
NC—WW—SCM A Accredited
NC_WW_SCM U. Unavailable
Version #2
Page 9 of 24

' summit Environmental Technologies, Inc. Accreditation Program
SUMM3310 Win St. Analytes Report
t�NVIRONhIENTAL I'cCHNO LOC IES, INC Cuyahoga Falls, Ohio 44223 Y P
Analytical LaboratorIas TEL: [phone] FAX [phone] WO#: 18021228
Website: http://ivlviv.settekcom 06-Mat-18
Client: Synagro State: NW
Project: Columbus WWTP Program Name: NC_WW_SCM
Sample ED Matrix
Test Name
Analyte
Status
18021228-OOIA Sludge
TCLP Semi -Volatiles Analysis
(SW1311/8270)
2-Methylphenol
A
Sludge
TCLP Semi -Volatiles Analysis
(SWI 3 l 1/8270)
3,4-Methylphenol
A
Sludge
TCLP Semi -Volatiles Analysis
(SW1311/8270)
Cresols, Total
A
Sludge
TCLP Semi -Volatiles Analysis
(SW1311/8270)
Hexachlorobenzene
A
Sludge
TCLP Semi -Volatiles Analysis
(SW1311/8270)
Hexachlorobutadiene
A
Sludge
TCLP Semi -Volatiles Analysis
(SW1311/8270)
Hexachloroethane
A
Sludge
TCLP Semi -Volatiles Analysis
(SWI 311/8270)
Nitrobenzene
A
Sludge
TCLP Semi -Volatiles Analysis
(SW1311/8270)
Nitrobenzene -d5
A
Sludge
TCLP Semi -Volatiles Analysis
(SW1311/8270)
Pentachlorophenol
A
Sludge
TCLP Semi -Volatiles Analysis
(SW1311/8270)
Phenol -d6
A
Sludge
TCLP Semi -Volatiles Analysis
(SW1311/8270)
p-Terphcnyl-d14
A
Sludge
TCLP Semi -Volatiles Analysis
(SW1311/8270)
Pyridine
A
Sludge
TCLP Volatiles Analysis
1,1-Dichloroethene
A
Sludge
TCLP Volatiles Analysis
1,2-Dichloroethane.
A
Sludge
TCLP Volatiles Analysis
2-Butanone
A
Sludge
TCLP Volatiles Analysis
4-Bromofluorobtazene
A
Sludge
TCLP Volatiles Analysis
Benzene
A
Sludge
TCLP Volatiles Analysis
Carbon tetrachloride
A
Sludge
TCLP Volatiles Analysis
Chlorobenzene
A
Sludge
TCLP Volatiles Analysis
Chloroform
A
Sludge
TCLP Volatiles Analysis
Dibromofluoromethane
A
Sludge
TCLP Volatiles Analysis
Tetrachloroethene
A
Sludge
TCLP Volatiles Analysis
Toluene -d8
A
Sludge
TCLP Volatiles Analysis
Trichlomethene
A
Sludge
TCLP Volatiles Analysis
Vinyl chloride
A
NC_WW_SCM A Accredited NC_WV'_SCM U Unavailable
Version #2
Page 10 of 24

SUMMItsnnpwEni. 310
peprar,�naI,e. QC SUMMARY REPORT
3310 Win Sl.
ENVIRONMENTAL TECHNOLOGIES, INC 0bralsam Folls. Ohio 44223
Anal yNbal I.pbblbbVles W04; 18021228
TEL: [phone] FAX.[phone]
{Ceb.v0e: hnP.1mv n sebekam 06 -Mar -18
Client: Synagro
Project: Columbus W WTP B8tchED: 31022
Sample l0 MB -37022 SampType: MBLK TestCode: tclp.voc-mstr Units: mglL Prep Dale: 2/241
1,1-Dichloraethene
ND
0.0500
1,2-Dichloreethane
ND
0.0500
MILK
ND
0.250
Benzene
No
0.0500
Carbon tetrachloride
ND
2078
RunNo: 81096
Client ID:
PBS
Batch ID:
31022
TeslNo:
SW82608 SW1311M
Analysis Dale: 2126/2018
Segr4o: 1434157
Anil
ND
0.0500
Result
PQL
SPKvalue SPKRef Val
%REG Low[Limit HighUrnit RPDRef Val
%RPD RPDLimil Qua]
1,1-Dichloraethene
ND
0.0500
1,2-Dichloreethane
ND
0.0500
MILK
ND
0.250
Benzene
No
0.0500
Carbon tetrachloride
ND
0.0500
Chlorobenzene
No
0.0500
Chloroform
ND
0.0500
Tetrachloroethane
ND
0.0500
Trichloroethene
ND
0.0500
Vinyl chloride
ND
0.0200
Sun: 4-Bromoflucrobenzene
465
Sun: Dilummofluoromethane
494'
Surc ToluenedS
4813
500.0
92.9
70
130
500.0
98.7
70
130
500.0
97.1
70
130
Qualifiers: '
Value exceeds Maximum Contaminant level.
H
Malyte detected in the associated Method Blauk
H
Holding rimes for prepay ranalysis. exceeded
]
Maly[edetected below quantitation limits
MC
Value is below MinimumtCompoue limit.
ND
No[Detected
P
Second column confirmation exceeds
PL
PermitLimit
E Value abovequan0tavon range
M Manual lntegmdon used to determine
O RSD is grceterthan RSDlimit
R RPD outside accepted recovery limits
OCt
Original
Page 11 of 24

®Su1VIM10 s n,r nom smrm 33310 a1011181.
QC SUMMARY REPORT
SI.
kVINONeFNTALTFCHNNL0OlE3, INC GryahogaTalls, Ohio 44223 WOO: 18021228
Abudi lcel LabonlaHea 7YL: [phone] FAX: [phone]
Website: &m /.i negekcnm 06-Mar-18
Client: Synagro
Project: Columbus W WTP BatchED: 31038
Sample to 78021228-001ams SampType: ms TeslCode: tclpevoc-
Entlnn 0.00643 0.00100 0.0100 0 64.3 20 157
gamma -BHC 0.00617
0.00643 21.7
30
0.00100
0.0100
0
cpe Units: mglL
Prep Date: 2126/2078
RunNo: 81219
Client ID:
Columbus MTP
Batch ID:
31038
TestNo:
SW8081 SW3510C
Analysis Date: V2812018
SegNo: 1437649
Analyte
0.00648
0.00100
Result
PQL
SPKValue. SPKRef Val
%REC LowLimit Hight-imit RPDRaf Val
%RPD RPDLImit Qual
Sample lD 78021228-0
0.00643 21.7
30
0.00100
0.0100
0
61.7
22
137
Heptachlor
0.00640
0.00100
0.0100
0
64.0
24
121
Heptachlor epoxide
0.00648
0.00100
0.0100
0
64.8
27
152
Methoxychlor
0.00766
0.00100
0.0100
0
766
10
199.
Sur. TCMX
12.9
0.00766 17.2
20.00
Sur. TCMX
64.6
10
119
Sur. DCB
9.76
119
20.00
46.6
10
119
Endrin 0.00000 0.00100 0:0100 0 80.0 20 157
0.00643 21.7
30
gamma -BHC
0lamsd
SampType:
mad
TeslCode:
tclp-swot-cpe
Units: melt
Prep Date: 2/28/2018
RunNo: 87279
Ghent to
Columbus WWTP
Batch ID:
31038
TestNo:
SW8081
SW3510C
Analysis Date: 2/28/2018
Beebe: 1437650
Analyte
0.00795 0.00100
00100 0
Result
PQL
SPKvalue
SPK Ref Val
%REC LowLimll Highl-I nit RPD Ref Val
%RPD RPDLImIt Qual
Page 12 of
0.00643 21.7
30
gamma -BHC
0.00734 0.00100
0.0100 0
73.4
22
137
0.00617 17.2
30
Heptachlor
0.00764 0.00100
0.0100 0
76A
24
121
0.00640 17.7
30
Heptachlor epoxide
0.00795 0.00100
00100 0
79.5
27
152
0.00648 20.4
30
Methoxychlor
0.00910 COMM
0.0100 0
910
10
199
0.00766 17.2
30
Sur. TCMX
14.6
20.00
73.0
10
119
0
Sur. DCB
11.5
20.00
57.7
10
119
0
Qualifiers:
"
ValweexcessisMaximunnCommumnantLevel.
B Analyte detected in the associated Method Blank
E
Value above quantitation range
H
Holding times For preparation or analysis exceeded
J Analyte detected below quantitation limits
M
Manual integration used to determine
Original
MC
Value is below Minimum Compound Limit.
ND Not Detected
O
MDisgreaterflum RSDlimit
P
Second column confirmation exceeds
PL PermitUrrit
R
RPD outside accepted recovery limits
24

SuMMN7 33/100wWinin »,re,r,Nlrcn»o>c. QC SUMMARY REPORT
51.
ENVIRtlNMENTAL TEGNNOLn01ES, INC Cuyahoga F'alh, 01do 44223
Aaalyllbe/ lrboraloAes TEL: WO0: 19021228
[phone] F4X: [phone]
Wehs;re: htm./n seaekcn 06 -Mar -18
Client: Synagro
Project: Columbus WWTP BatchlD: 31055
P Mercury
Sample lD
MB -31055
SampType:
MBLK
TeslCode:
HG_TCLP(74 Units: PPM
Prep Date: 2/27/2018
RunNo: 81127
ClientlD:
PBS
Balch U:
31055
TastNo:
SW7470A SW7470A
Analysis Date: 2/27/2018
SegNm 1435144
Analyte
SW7470A
SW7470A
Result
PQL
SPKvalue SPKRef Val
%REG Lowl-imit HighLimit RPDRef Val
%RPD RPDLimit Qual
ND 000200
P Mercury
Sample ID
LC531055
SampType:
LCS
TeslCode:
HG_TCLP(74 Units: PPM
Prep Dale: 212]12018
RunNo: 81127
Client ID:
LCSS
Batch ID:
31055
TestNo:
SW7470A SW7470A
Analysis Date: 2/27/2018
SegNo: 1435146
Analyte
SW7470A
SW7470A
Result
PQL
SPKvalue SPKRef Val
%REG Lowl-imit HlghLlmil RPDRef Val
%RPD RPDLimit Qual
0.00419 0.00200 0.00400 0 105 80 120
Sample l0 78027791-002AM5 SampType: MS TestCotle: HG_TCLP(74 Units: PPM Prep Dale: 2127
.P Mercury
12018
RunNo: 61127
Client to
/2018
RunNo:
87727
Client ID:
BatchQC
Batch ID:
31055
TestNo:
SW7470A
SW7470A
Analysis Date: 2/27/2018
SegNo:
1435155
Analyte
%RPD RPDLlmit Qual
Result
PQL
SPKvalue SPKRef Val
%REC LoWLimll HighLimit RPDRef Val
%RPD RPDLimit Qual
0.00428 0.00200 0.00400 0 107 75 125
Sample lD 16021197A02AMSD SampType: MBD TestCotle: HG TCLP(74 Units: PPM Prep Date: 2127
TCLP Mercury
12018
RunNo: 61127
Client to
BatchQC
Balch ID:
31055
TestNo:
SW7470A SW7470A
Analysis Date: 2/27/2018
SegNo: 1435156
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC Lowl-imit HighLimit RPDRef Val
%RPD RPDLlmit Qual
0.00434 0.00200 0.00400 0 108 75 125 0.00428 1.39 20
Qualifiers: * Vafuc zceeds Maximum Cone ant Level, H Analyte detected in the associated McNM Hlank E Value above quantiw0on range
H Haldin9times forprepam5on oraanalysis exceeded ) Analyte detectedbelow quantitation limits M Manual Integration used mdctermine
MC Value is below Minimum Camp need
Limit ND Not Detected O RSD is �eN
ateren RSDlimi[ Original
P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits
Page 13 of 24

S U10"M17 SNalmill n,r oa re,rlal abe m 333/0JOW. r e. QC SUMMARY REPORT
in SI.
ENVIHONME.NTa4TEL11NOLONI_9, INC Crryahuga Falls. Ohia 44223
Artatylleal SaborafoYlea 7FZ: (3310) 253-8211 FAX. [phone] WON: 18021228
Wchnie: Irud/M serrek co 06-M 18
Cli®t: Synagro
Project: Columbus WWTP Batchlo: 31055
Sample ID 18021191-002AMSD SampType: MSO TestCode: HCa_TCLP(74 Units: PPM Prep Date: 2/271
Qualifiers: *
Valne exceedsMaximnm Contaminant Level.
B
Maly[ede[ected in the associated Method Hlank
8
Value above quavtita0on range
H
Holdingtimes £orprepamM1on or analysis exceeded
J
Maly[e detected below quanN+ation limits
M
Manual Integration used to determine Original
MC
Value is below Minimum Compouvd limit
2018
RunNo: 61127
Client ID:
BalehQQ
Balch ID:
81055
TeStNo:
SW7470A SW7470A
Analysis Date: 2/27/2018
SegNm 1435156
Analyte
Result
PQL
SPKvalue SPKRefVal
%REG LowLlmlt Hight -mit RPDRefVal
%RPD RPDLimit Dual
Qualifiers: *
Valne exceedsMaximnm Contaminant Level.
B
Maly[ede[ected in the associated Method Hlank
8
Value above quavtita0on range
H
Holdingtimes £orprepamM1on or analysis exceeded
J
Maly[e detected below quanN+ation limits
M
Manual Integration used to determine Original
MC
Value is below Minimum Compouvd limit
ND
Not Detected
O
RS➢is greater than RSDlimi[
P
Second column cov5smaaon exceeds
n
Permit Limit
R
RPD outside accepted recovery limits
Page 14 of 24

® �%IPMMt� awn rm„ 3310 Win
St.
ENIIRONNIENTAL TECHNOLOGIES,
QC SUIVIMARYREPORT
INC CuahogaTalls, One 44223 WQU: 18021228
4haly(lcal LnbOMlnlins 7E!_-[phone] Fq.(330) 2534499
Wabsee: 06 -Mn -18
Client: Synagre
Project: Columbus W WTP BatCLID: R81098
Sample lD MB-Ra1999 SampType: MBLK TeslCotle: SulOde, React Units:
Sulfide, Reactive
Sample ID
LCS-R81098
SampType:
LCS
TeslCode:
mglL
Prep Date:
RunNo: 81098
Client ID:
PEW
Batch ID:
R81098
TestNo:
SW9034
Analysis Date: 2/2612016
SegNo: 1434279
Analyte
Value is below lvliriimum Compound Limit.
ND
Result
PQL
SPKvalue SPKRef Val
%REC LowLlmit HighLlmit RPDRef Val
°%RPD RPDLimit Qual
ND 25.0
Sulfide,
Sample ID
LCS-R81098
SampType:
LCS
TeslCode:
Sulfide,Raact Units: mglL
Prep Date:
RunNo: 81098
Client IM
LCSW
Batch to:
881098
TestNo:
SW9034
Analysis Date: 2/26/2018
SegNo: 1434280
Analyte
Value is below lvliriimum Compound Limit.
ND
Result
PQL
SPKvalue SPKRef Val
%REG LowLimit HighHmil RPDRef Val
%RPD RPDLimit Qual
Reactive 4720 25.0 4800 0 98.3 85 115
Sample ID 18021084-001AM5 SampType: MB TeslCode: SUlfide,React Units: mg/L Prep Dat
Sulfide,
Sample ID
18021064-001AMSD
SampType:
MSO
TeslCotle:
Sulfide,React Units: mg/L
e:
RunNo: 81098
Client ID:
BafchQC
Batch ID:
R81098
Teethe:
SW9034
AnalysisDate: 2126/2018
SegNo: 1434282
Analyte
Value is below lvliriimum Compound Limit.
ND
Result
PQL
SPKvalue SPKRef Val
%REC LowLimit Highl-imlt RPDRef Val
%RPD RPDLimit Qual
Reactive 4760 25.0 4800 0 992 75 125
Sulfide, Reactive 4710 25.0 4600 0 98.1 75 125 4760 1.06
Sample ID
18021064-001AMSD
SampType:
MSO
TeslCotle:
Sulfide,React Units: mg/L
Prep Dale:
RunNo: 81098
Client ID:
Bati
Batch ID:
R81098
TestNo:
SW9034
Analysis Date: 2126/2018
SegNa: 1434283
Analyte
Value is below lvliriimum Compound Limit.
ND
Result
PQL
SPK value SPK Ref Val
%REC LowLimit Hight-imit RPD Ref Val
%RPD RPDLimlt Qual
30 HW
Qualifiers: •
Value exceeds Maxi mum ContWeuse tl.evel.
H
Analyte delected in the associated Method➢lack
E
Value above. quavdtation range
H
Holding times for preparation or analysis exceeded
I
Analyte detected below quantitation limits
M
Manual lntepmtion used to determine
MC
Value is below lvliriimum Compound Limit.
ND
Not Detected
O
RSDisgreaterthan RSDlimit
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery findts
Original
Page 15 of 24

®SUMMIt s, mnrv„ aa» vol ba 3310Will
QC SUMMARYREPdRT
3310 WSl.
ENVIRONMENTAL TECHNOLOOIE6, INC CuyaJ,oga Falls, Ohio 44223 WOB: 18821228
Anal yVvEl La60ralarfes TEL: [phone] FAX: [phone]
We6she: P no'/Gmi • serc shoe 06-Mar48
Client: Synagro
Project: Columbus WWTP BetchlD: R81098
Sample ID 18021084-001AMS0 SampType: MSD TeslCotle: SUlflde,React Units:
Qualigers: ` Value exceeds Maximum Covtaminantl,eveL B Malyte detected in the associated Method Blank E Valueabove quamitaiion anye
H Holdingvmes for prepemdon or analysis exceeded J Analyte detectedbelow quendlntion limits M Manuel integration used to detem,ine
MC Value is bel ow Mnimum GOmpound Ii mit. ND Not Detected O R6D is greeter tban lLSDlimi[ Original
P Secondcvlunmeonfrmatiovexceeds PL PermitUmn R "D outside accepted recovery limits
Page 16 of 24
mglL
Prep Date:
RunNo: 81098
Client ID:
BatchQG
Batch ID:
1181098
Tes No:
SW9034
Analysis Date: 2126/2018
SegNo: 1434283
Analyte
Result
PQL
SPKvalua SPK.Ref Val
%REG Lowl-imit Highl-imlt RPDRef Val
%RPD RPDLimlt Qual
Qualigers: ` Value exceeds Maximum Covtaminantl,eveL B Malyte detected in the associated Method Blank E Valueabove quamitaiion anye
H Holdingvmes for prepemdon or analysis exceeded J Analyte detectedbelow quendlntion limits M Manuel integration used to detem,ine
MC Value is bel ow Mnimum GOmpound Ii mit. ND Not Detected O R6D is greeter tban lLSDlimi[ Original
P Secondcvlunmeonfrmatiovexceeds PL PermitUmn R "D outside accepted recovery limits
Page 16 of 24

® E3►UMM17 m0onSt
3wnr srs,aaasi,P,ma,m,znmlTeahnalQC SUMMARY REPORT
.
NVI9n NMENTAL TECHNOLOGIES, INC Cayahaga Falls, Ohio 44123
Aner]VUcal Laboratorlep TEL: [phone] FAX: [phone] WO#: 18021228
Weeaile: hsoY4an seaekco 06 -Mar -18
Client: Synagro
Project: ColumbusWWTP BatchlD: R81179
Sample lD MB.
snide, Reactive
NO 0.500
Cyanide,
}I
Holding[imes for preparation or analysis ezceeded
Sample ID
R81179
SampType:
MBLK
TestCotle:
Cyanide,Rea Units: mg/L
Prep Date:
RunNo; 81179
Client ID:
PEW
Batch ID:
R81179
TestNo:
SW9014
Analysis Date: 2/26/2018
SegNo: 1436294
Analyte
Result
PQL
SPKvalue SPKR&Va[
%REC LowLimil HighLimil RPDRef Val
%RPD RPDLimil Quad
snide, Reactive
NO 0.500
Cyanide,
}I
Holding[imes for preparation or analysis ezceeded
Sample ID
1,CS-881179
SampType:
LCS
TestCotle:
Cyanide,Rea Units: mglL
Prep Date:
RunNo: 81179
Client ID:
LCSW
Balch ID:
R81179
TestNo:
SW9014
Analysis Date: 2/2612018
SegNo: 1436296
Analyte
Result
PQL
SPK value SPK Ref Val
%REC LowLdmit HlghLimit RPD Ref Val
%RPD RPDUmit Qua[
Reactive 10.1 0.500 10.00 0 101 85 115
Sample ID 18021084-001AM5 SampType: MS TestCotle: Cyanitle,Rea Units: milli. Pre
Cyanide, Reactive 9.80 0.500 10.00 0 98.0 81.3 118
NOTES:
}I
Holding[imes for preparation or analysis ezceeded
I
Analyte detected below quantimtion limits
M
Manuel rnteP{atiw used to determine
MC
no is bel ow Minimum Compound Limit.
p Date:
RunNo: 81179
Client ID:
BatchQC
Batch ID:
881179
TestNo:
SW9014
Analysis Date: V2612018
SegNo: 1436299
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLlmit HighLim[t RPDRef Val
%RPD RPDUrmt Quad
W
Sample was received not meeting proper temperature requirements.
Sample ID 76027064-OOtAMSD SampType: MSD TestCotle: Gyanide,Rea Units: mglL Pre
Qualifiers: ` Value exceeds Maximum Contaminantsevel. B Analyte detxted in the associated Method Blank E Value above quantifaGon mage
}I
Holding[imes for preparation or analysis ezceeded
I
Analyte detected below quantimtion limits
M
Manuel rnteP{atiw used to determine
MC
no is bel ow Minimum Compound Limit.
p Date:
RunNo: 81179
Client ID:
BalchQC
Batch ID:
R81179
TestNo:
SW9014
Analysis Date: 2/26/2018
SegNo: 1436300
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LowUmit Highl-imit RPDRef Val
%RPD RPDLimil Qual
Original
Page 17 of 24
}I
Holding[imes for preparation or analysis ezceeded
I
Analyte detected below quantimtion limits
M
Manuel rnteP{atiw used to determine
MC
no is bel ow Minimum Compound Limit.
ND
Not Detected
O
RSD is Greater than RSDlimit
P
Second column confirmation exceeds
PL
Patrol
A
RPD cumide accepted reeovery limits

SUMM17 ' 331O �n,,rra,a,e„ta,TeaWin .
3310 nSiS(.
ENVINONIAENTAL TECHNOLOGIES, INC CayalrogaFalts. Ohio 44223
AlWytical LagOrblP1ler
TEL: [phone] FA. (330) 2534489
Website: Lino Loniosesek.cion
Clienh. Synagro
Project: Columbus WWTP
QC SUMMARY REPORT
WO#: 18021228
06-Marv18
BatchlD: R81179
Cyanide, Reactive 9.85 0.500 10.00 0 98.5 81.3 11B 9.796 0.590 5 W
NOTES:
Sample was received not meefing proper temperature requirements.
Qualifiers: '
Page 18
Value exceeds Maumum Conuminent Level
H
Maly[edetedted intheassociered McNod Hlar�k
H
Value above quantitaiiw range
H
Hdding times forptepamtionor analysis xceeded
Sample ID
1802108d-001AM5O
SampType:
M50
TestCode:
Cyanlde,Rea Unils: mg/L
Prep Date:
RunNo: 81779
CllaC ID:
BatChOC
Batch ID:
R81179
TestNm
SW9014
Analysis Date: 2126/2018
SegNo: 1436300
Analyte
Second column confirmation exceeds
PL
Result
PCL
SPKvalue SPKRef Val
AREC LowLlmit HlghLimit RPDRefVal
%RPD RPDLimit Qua[
Cyanide, Reactive 9.85 0.500 10.00 0 98.5 81.3 11B 9.796 0.590 5 W
NOTES:
Sample was received not meefing proper temperature requirements.
Qualifiers: '
Page 18
Value exceeds Maumum Conuminent Level
H
Maly[edetedted intheassociered McNod Hlar�k
H
Value above quantitaiiw range
H
Hdding times forptepamtionor analysis xceeded
S
Analyte delated below quanfitation limits
M
Manual integration used to determine
OrigiGal
MC
Veluc is below Nu'vimum Compound limit.
ND
Nat Detected
0
RSD is greater than RSDlimi[
P
Second column confirmation exceeds
PL
Peunit Limit
K
RPD outside accepted recovery limits
of 24

® S1IAMMIi saWnFn,;ra»» rte rent331OWMS1. QC SUMMARY REPORT
3vo W,'»sr.
FNWRONh16NTAL TECHNOLOGIES, IRC Cuyahoga Fags, Ohio 44223
Aryelykeal Lubnrsfartes TEL: [phone] FAX.' [phone] WO#18021228
:
Webs,le: Lien..11www..eellotemn 06-M r48
Client: Synagro
Project: Colwnbus WWTP Retchll): R81272
Sample ID LCS-R87272 SampType: LCS TestCode: Ignitebility_5 Units:
Ignitability
a
Analyte detected iv Bre associated Method Black
E
Valve above. quantitation Hoge
H Holding times for prepamtiov or analysis
1
Analyte detected below quantitation limits
Sample ID
78021228OOtADUP
SampType:
DUP
TestCode:
_S Units:
Prep Dale:
RunNo: 81272
Client ID:
LCSS
Batch ID:
R81272
TestNo:
SW1030
Analysis Dale: 3/2r2016
SegNo: 1439605
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLimit HighLimll RPDRef Val
%RPD RPDLimit Qua]
7.96
7.240 0 710 70 180
Sample lD 18021223A01ADUP SampType: DUP TestCode: Ignitablllty
Ignitability
non-flammable
0 0 20
Ignitabilit
a
Analyte detected iv Bre associated Method Black
E
Valve above. quantitation Hoge
H Holding times for prepamtiov or analysis
1
Analyte detected below quantitation limits
Sample ID
78021228OOtADUP
SampType:
DUP
TestCode:
_S Units:
Prep Date:
RunNo: 61272
ClientlD:
BatchQG
Batch ID:
881272
TestNo:
SW1030
Analysis Date: 31W2018
SegNo: 1439607
Analyte
Result
PQL
SPKvalue SPK Ref Val
%REC LowLimft HighLimit RPD Ref Val
%RPD RPDUmit Qual
Ignitability
non-flammable
0 0 20
Ignitabilit
a
Analyte detected iv Bre associated Method Black
E
Valve above. quantitation Hoge
H Holding times for prepamtiov or analysis
1
Analyte detected below quantitation limits
Sample ID
78021228OOtADUP
SampType:
DUP
TestCode:
Ignitability_S Units:
Prep Date:
RunNo: 81272
Client ID
Columbus WWTP
Batch ID:
R81272
TestNo:
SW1030
Analysis Date: 3£2/2018
SegNo: 1439609
Analyte
Result
PQL
SPKvalue SPK Ref Val
%REC LowL]mit HighLimit RPD Ref Val
%RPD RPDLimit Qua[
y
non-flammable
0 0 20
ability
non-flammable
0 o zo
Qualifiers: * Valve exceeds Maximum Contaminant Level.
a
Analyte detected iv Bre associated Method Black
E
Valve above. quantitation Hoge
H Holding times for prepamtiov or analysis
1
Analyte detected below quantitation limits
Sample l0
18030033A01ADUP
SampType:
DUP
TestCode:
IgnitablllTy_S Units:
Prep Date:
RunNo: 81272
ClientlD:
BatchQC
Batch lD:
881272
TestNo:
SW1030
Analysts Date: 3/2J2076
SegNo: 1439611
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLimlt HighLimit RPDRMVal
%RPD RPDUmi/ Qual
ability
non-flammable
0 o zo
Qualifiers: * Valve exceeds Maximum Contaminant Level.
a
Analyte detected iv Bre associated Method Black
E
Valve above. quantitation Hoge
H Holding times for prepamtiov or analysis
1
Analyte detected below quantitation limits
M
Manual integmdon used to determine
Original
MC Value is below Minimum Compouvd Limit
ND
Not Detected
0
RSD is greater than ASDlimit
P Sewed column con5mration exceeds
Pi.
Permit Limit
R
RPD outside accepted recovery limits
Page 19 of 24

S U MM 17 s, onnren,a, Iech,rolag;es,1
33107yin S(.
MISONMEWAL 160HNOLOOIE9, INC C✓Xahoga Falle', Ohio 44223
AhedyNast (ab6rg1crles TEL: [phone] FAX[phone]
Weha;(e: lnro://nloesettek.coni
Client: Synagro
Project: Columbus WWTP
QC SUMMARY REPORT
WO#: 18021228
66-d1ar48
No: R81272
lability
Value. eeds Maz,m mContaminant Level.
H
Analyte detected in the associated McWod Blavk
B
Value above. quantitetien mngd
H
Sample l0
76030033-001ADUP
SampType:
DUP
TestCotle: lgnitabilitq_S Units:
Prep Date:
RunNc: 81272
Client ID:
BatchQC
Batch ID:
RI 1272
TestNo: SW1030
Analysis Date: 302018
Beside: 1439611
Analyte
Analysis Date: 3/212018
SegNo: 1439613
Result
PQL SPKvalue SPKRef Val
%REG LowLimit HighLimit RPDRef Val
%RPD RPDLimit Qual
lability
Value. eeds Maz,m mContaminant Level.
H
Analyte detected in the associated McWod Blavk
B
Value above. quantitetien mngd
H
Holding times for preparation or analysis exce dad
Sample IQ
18030036001ADUP
SampType:
pUP
TeatCode: Ignitability_S
Units:
Prep Dale:
RunNo: 81272
Client ID:
BatchQG
Batch ID:
R81272
TestNo: SW7030
SW1030
Analysis Date: 3/212018
SegNo: 1439613
Analyte
Result
PQL SPKvalue
SPKRef Val
%REG LowLimit HighLimit RPDRef Val
%RPD RPDLimit Qual
non-flammable
0 0 20
nitabifily
non-flammable
0 0 20
Quntifiers: '
Original
Page 20 of 24
Value. eeds Maz,m mContaminant Level.
H
Analyte detected in the associated McWod Blavk
B
Value above. quantitetien mngd
H
Holding times for preparation or analysis exce dad
Sample to
18030038-OOtADUP
SampType:
DUP
TeslCode:
lgnitability_S Unl(s:
Prep Date:
RunNo: 87272
Client ID:
BatchQC
Batch ID:
R81272
TestNo:
SW1030
Analysis Date: 312/2018
SegNo: 1439615
Analyte
Result
PQL
SPKvalue SPK Ref Val
%REC LowLimit HighLimit RPD Ref Val
%RPD RPDLimit oust
nitabifily
non-flammable
0 0 20
Quntifiers: '
Original
Page 20 of 24
Value. eeds Maz,m mContaminant Level.
H
Analyte detected in the associated McWod Blavk
B
Value above. quantitetien mngd
H
Holding times for preparation or analysis exce dad
J
Avely[e det¢td below guantimtion limits
M
Manuel integation used to determine
MC
Value is below NRsdmum Compound limit.
ND
Not Detected
O
RSD is greater tban lLSDlimit
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits

SU1V11U110 snn nr Nrm,,�nalram33101finS Qr �j]MNjAj2YREPORT
3310Ii�i/�Sl.
ENVIRONMENTAL TECHNOLOOIESt INC C/ryahoga Falls, Ohio 44223 WOO: 18021228
AnalyNeal Latlaralarlea l'Nl.: [phone] FiL , (330) 2534489
Wedsae: ] lro //�m�m• seHekcam 06-Mbr-IS
Client: Synagro
Project: Columbus WWTP BatchED: R81332
Sample ID 18021339�002ADUP SampType: CUP TestCatle: pH_5(
pH
7.0
Qvnliflera: ` Value exceeds Maximum Canmminan[laud.
13 Holdingtimes for prepemtiov or analysis excelled
MC Vnlue is below Minimum Compound Limit.
P Second column confirmation exceeds
70 0 10
]3
Malyte detected in the associated Method Hlank
E
Value above quantitation mvge
T
Analyte detected below quantila0on limits
M
Manual lntegmrien used to dektmine
o[iginal
ND
Not Detected
O
RSDis greaterthao RSDlimil
PL
Permit Limit
90450) Units: s.u.@19.3C
RPD outside accepted recovery limits
Prep Date:
RunNo: 87332
Client ID:
BatchQC
Batch ID:
881332
TestNo:
SW9045D
Analysis Date: 3/5/2018
SegNc: 1441276
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC
Lowl-imlt Hight-imit RPDRef Val
%RPD RPDLimit Qual
pH
7.0
Qvnliflera: ` Value exceeds Maximum Canmminan[laud.
13 Holdingtimes for prepemtiov or analysis excelled
MC Vnlue is below Minimum Compound Limit.
P Second column confirmation exceeds
70 0 10
]3
Malyte detected in the associated Method Hlank
E
Value above quantitation mvge
T
Analyte detected below quantila0on limits
M
Manual lntegmrien used to dektmine
o[iginal
ND
Not Detected
O
RSDis greaterthao RSDlimil
PL
Permit Limit
R
RPD outside accepted recovery limits
Page 21 of 24

®SUMM17 3310 A'Wnht Sl. 81. QC SUMMARY REPORT
e1NIRONME11TAL TECHNOLOOIES, INC Cuoahoga Falls, Ohio 44223
ARalPileel LnSarsforie. WON: 18021228
TEL: [phone] FAX.. [phone]
A'ebshe: h,1»./ri• selrrkaon O6 -DT rvIR
Client: Synagro
Project: ColumbuSWWTP BatchID: R81332
Sample ID LCS-R81332 SampType: LEGS TestCode: pH_NPW(450 Units; s,u.@
pH 7.0 7.0 0 101 98.6 101.4
Sample lD 78021341.001ADUP SampType; pUP TestCode: pH NPW(450 Units: s.u.@19.8C Pre
PH
Valve exceeds Mezimum Conteminen[Level.
e
Malyte deiacted in the associated Method Hlank
L
Vxlue above quantl[ation range
11
Holding times forpreparetlon or analysis exceeded
1
Auelyte detected below quantitation limits
M
Manual integration used [n detemdne
MC
20.2C
Prep Dale:
RunNo: 81332
Client ID:
LCSW
Batch ID;
R81332
TastNo:
5W9045D
Analysis Date: 315/2018
SegNo: 1441108
Analyte
Result
PQL
SPKvalue SPKRef Val %REG
Lowl-imit HighLimit RPDRef Val
%RPD RPDLimlt Qual
pH 7.0 7.0 0 101 98.6 101.4
Sample lD 78021341.001ADUP SampType; pUP TestCode: pH NPW(450 Units: s.u.@19.8C Pre
PH
Valve exceeds Mezimum Conteminen[Level.
e
Malyte deiacted in the associated Method Hlank
L
Vxlue above quantl[ation range
11
Holding times forpreparetlon or analysis exceeded
1
Auelyte detected below quantitation limits
M
Manual integration used [n detemdne
MC
Value is bel ow Mini mum Compound liin
p Data:
RunNo: 81332
ClientlD:
BatchQC
Batch l0:
R81332
TestNo:
SW9045D
Analysis Date: 3/5/2018
SegNo: 1441110
Analyte
Result
PQL
SPKvalue SPK Ref Val %REG
LowLlmit HighLlmil RPD Ref Val
%RPD RPDLimlt Qual
12.7
12.7 04 5
Qualifiers: T
Original
Page 22 of 24
Valve exceeds Mezimum Conteminen[Level.
e
Malyte deiacted in the associated Method Hlank
L
Vxlue above quantl[ation range
11
Holding times forpreparetlon or analysis exceeded
1
Auelyte detected below quantitation limits
M
Manual integration used [n detemdne
MC
Value is bel ow Mini mum Compound liin
T8J
No[Delected
O
RSD is grcaterthen RSDlimi[
P
Second column confinnationexceeds
PL
Pemtit Limit
A
"D outside accepted recovery limits

®Summit Environmental 'I>rchno►ogles, Ina Analysis Request/Chain of Custody
3310 Win Stwet Ws Summit Environmental Technologies, Inc use only
Cuyahoga Falls, Ohio 44223 1& 330.253.8211 Fax: [phone] Pvge_of_. ser --No
27oz$
sempeldenWlalbn
Nm�cnmmnms:
OVy I t-�-
N13
Stets of Sample Origin:_.,��
(� Check if FOR COMPLIANCE
126x57
ag of 1
Page 23 of 24

Summit Environmental Technologies, Inc.
ff1summiliff 3310 Win St.
rNVIRONMEN7AL 1EC8NOLCIGIES, INC Cuyahoga Falls, Ohio 44223 Sample LI Check. List
ArtalyRCaf Laboratories TEL: [phone] FAX, [phone]
Website: hup71Avww.settek.com
Client Name: SYN-NC-27028 Work Order Number: 18021228 RcptNo: 1
Logged by: Christopher Livengood 2/23/2018 10:15:00 AM (f/
Completed By: Christopher Livengood 212 312 01 8 1:02:11 PM 64;
Reviewed By: Jennifer Woolf 3/1/2018 3:12:07 PM rjq�77
Chain of Cusfodv
Sample(s) in proper container(s)?
Yes
0
No
1. Were seals Intact?
Yes
W
No ❑
Not Present ❑
2, Is Chain of Custody complete?
Yes
❑V
No ❑
Not Present ❑
3, How was the sample delivered?
UPS
❑
No
❑
Loq In
10.
Was preservative added to bottles?
Yes
❑
4, Coolers are present?
Yes
9
No ❑
NA ❑
5. Was an attempt made to cool the samples? Yes � No ❑ NA ❑
6, Were all samples received at a temperature of >D° C to 6.0°C Yes � No ❑ NA ❑
�,
Sample(s) in proper container(s)?
Yes
0
No
❑
$,
Sufficient sample volume for indicated test(s)?
Yes
0
No
❑
9,
Are samples (except VOA and ONG) properly preserved?
Yes
❑
No
❑
10.
Was preservative added to bottles?
Yes
❑
No
❑
NA W
NA
11.
Is the headspace in the VOA vials less than 1/4 inch or 6 mm?
Yes
❑
No
❑
No VOA Vials
12.
Were any sample containers received broken?
Yes
❑
No
0
13.
Does paperwork match bottle labels?
Yes
No
❑
(Note discrepancies on chain of custody)
14,
Are matrices correctly identified on Chain of Custody?
Yes
❑V
No
❑
15.
Is it clear what analyses were requested?
Yes
0
No
❑
16.
Were all holding times able to be met?
Yes
No
❑
(If no, notify customer for authorization.)
Special Handling (if applicable)
17,
Was client notified of all discrepancies with this order?
Yes
❑
No
❑
NA ❑1
Person Notified: I Date
By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person
Regarding:
Client Instructions:
1$, Additional remarks:
Cooler Information
Cooler No Tem °C Condition Seal Intact Seal No Seal Date Si ned B
Page I of I
Page 24 of 24

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Columbus NC WQ Permit Number: WQ 0016247
WWTP Name: Columbus WWTP NPDES Number: NC 0021369
Monitoring Period: From 01/01/18 To 12/31/2018
Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. 1/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing)
Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens _ Alt. 6 (Equivalent to PFRP)
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost Heat Drying Heat Treatment Thermophilic
Beta Ray Gamma Ray Pasteurization
Class B:
Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens x
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization X Air Drying Composting Aerobic Digestion
Anaerobic Digestion
If applicable to alternative performed Class A or Class B) complete the followhim monitorin data:
Parameter
Vector Att
Allowable Level in Sludge
Pathogen Density
No. of
Frequency
Sample
Analytical
Excee-
of
Type
Technique
Minimum Geo. Mean Maximum Units
dentes
Analysis
Fecal
2x10to the 66
MPN
MPN/g
Coliform
power per gram
of total solids
CFU
CFU/g
1000 MPN per gram of
MPN/g
total solids (dry weight)
Salmonella
3 MPN per 4 grams total
bacteria (in
solids (dry weight)
lieuof fecal
coliform)
raction Reduction (40 CFR 503.33/15A NCAC 02T.1107) -Please indicate option/alternativepeiformed:
Otion/Alt. 1
(VSpreduction)
(40 -day bench)
Option/Alt. 5
(14 -Day Aerobic)
Option/Alt. 9
(Injection)
Option/Alt. 2
Option/Alt. 6
(Alk Stabili
zation) x
Option/Alt. 10
(Incorporation)
STATEMENT (please check the appropriate statement)
"I certify, under penalty of taw, that t pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vecCor attraoCion
X reduction requirement m 40 CFR 503.33/15A NCAC 02T.1107 have became
O/Alt. 3
(30 -day ption bench) (Spec.
Option/Alt. 7
(Drying — Stable)
Option/Alt. 4
02 uptake)
Option/Alt. 8
(Drying—Unstable)
No vector attraction reduction alternatives were performed
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note i£ you check this statement attach an
explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate the information used to determine that the pathogen and vector att
raction reduction requirements have
been met, I am aware that there are significant penalties for false certification including fine and imprisonment "
Todd Larson, Regional Director
Preparer N e nd Title ( type print) Land Applier Name and Title (if applicable) (type or print)
e of
Prever* at Signature of Land Applier (if applicable) Data
*Preparer is defined in 40 CFR Part
.503.9(r) and ISA NCAC 2T.1102 (26)

I UvvN Ut CULUMBUS WWTP
VECTOR ATTRACTION REDUCTION
OPTION 6- 503 REGS,
24 HOUR TEST OF ADDITION OF ALKALINE MATERIAL FOR LAND APPLIED SLUDGE
TEST:
INITIALpH fZ;f3 TIMEIuO•) TEMP 23 DATE?/2}/tJ
PH @ 2 HOURS (Z. 3f y TIME ZK4 TEMP Z' DATE?�x3�
p H@ 22 HOURS 2.1 TIME1T3.s TEMP Z-3 DATEj2'
30% LIME SLURRY PRODUCT
GAtLOWOF ALKALINE MATERIAL ADDED
SIGNATURE ✓ldl��y DATE be
Temp°C
Conation Factor
X10
Plus 0.45
39
Plus 0.42
38
Plus 0.39
37
Plus 036
36
Plus 0.33
35
Plus 0.30
3A
Plus 0.27
33
Plus 0.24
32
Plus vi
31
Plus 0.13
3G
Plus 0.15
29 I
Plus 0.12
28
Plus 0.09
27
.Plus 0.06
26
Plus 0.03
25
0.00
24
Minus0.03
23
Minus 0.06
22
Minus 0.09
2I
I Minus O.t2
. 20
Minus 0.35
19
Minus 0.18
IS
Minus 0.21
17
Minus 0.24
tb
Minus 0.27
15
Ndinus 0.30
l4
Minus 033
13
Minus 036
12
Minus 0.39
It
Minus 0,42
10.'
Minus 0.45

Agricultural Lime Application Log
Year: 2018
Project:
Columbus
Field
(state -county -site -field)
Soil 11
pH 11
(from
Lime Requirement
soil analysis)
ons ere
Applied(CCE Eq.)
Date Applied
PO -07-01
6.9
O.OT/Ac.
PO -07-02
6.6
O.OT/Ac.
O.OT/Ac.
O.OT/Ac.
O.OT/Ac.
"Lime will be applied when conditions improve.

NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomi/
Report No. FY19-SL003525
Predictive
µFTX
Client:
Ethan Edwards
Advisor:
E Bruce
5
160 Floyd Blackwell Rd
Synagro
Soil Report
Mehlich-3
Extraction
Tryon, NC 28782
284 Boger Rd
S
Mocksville, NC 27028
5,
Sampled County: Polk
Links to Helpful Information
Sampled:
08/28/2018
Received:
08/30/2018
Farm: PO -07
Completed;
09/10/2018
ClientlD:474750
Advisor ID: 475821
Sample ID: 07-01
Recommendations:
Lime
Nutrients (Ib/acre)-1More
Crop
(tons/acre)
N P2O
K20 Mg S
Mn
Zn
CuInformation
Lime History:
1 -Fescue/OGrassFrim,
M 0.0
120-200 120
120 0 20
pH$
0
0
Note: 12 Note: S
2-
0.0
Test Results [units - WN in g/cm3; CEC and Na in
meq/100 cm3; NO3-N In mg[dm]:
Soil Class:
Mineral
HM% WN CEC BS% Ac pH
P-1 K-1
Ca% Mg%
S-1 Mn -I Mn -All Mn-Al2
Zn4
Zn -AI
Cu -I Na ESP
SS -1 NO3-N
0.36 1.15 7.4 92 0.6 6.9
10 13.
66 26
22 295 180
40
40
59 0.1 1
Sample ID: 07-02
Recommendations:
Lime
Nutrients(Ib/acre)More
Crop
(tons/acre)
N P2O5
K2O Mg 5
Mn
Zn
Cu B.
Information
Lime History:
1 -Fescue/OGrass/tim,
M 0.0
120-200 90
110 0 0
pH$
0
0 0
Note: 12 Note: $
2-
0.0
Test Results [units.- WN In g/crrr; CEC and Na in
meq/100 cm3; 114O3-14 in mg/d0]:
Soil Class:
Mineral
HM/ WN CEC BS% Ac pH
P -I K -I
Ca% Mg%
S4 Mn -I Mn -All Mn-Al2
Znd
Zn -AI
Cu -I Na ESP
SS -1 1403-14
0.51 1.16 7.8 90 0.8 6.6
22 15
64 24
29 241 152
140
140
43 0.1 1
IIIIIr North-
Tial Fund
Reprogramming of the lahoratory-information-management system that makes this repprt possible is
being funded through a grant from the North Carolina Tobacco Tmst Fund Commission.
Thank you for using agronomic serv
ices to manage nutrients and safeguard environmental quality.
- Steve Tmzler, Commissioner ofAgnculture

NCDABCS Agronomic Division Phone: [phone] Website: www.ncagingov/agronomi/
Report No. FY19-SL1303525
Ethan Edwards
Page 2 of 2
Understanding the Soil Report: explanation of measurements, abbreviations and units
Recommendations
Report Abbreviations
Lime
Ac
exchangeable acidity
If testing finds that soil pH Is too low for the crop(s) indicated, a lime recommendation will be given in units of either
a
baron
ton/acre or W1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting.
BS %
% CEC occupied by basic cations
For no-till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at on
ca%
% CEC occupied by calcium
time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate
CEC
cation exchange capacity
is applied. If MG is recommended and lime Is needed, use dolomitric lime.
Cu.]
copper index
ESP
exchangeable sodium percent
Fertilizer
HM%
percent humic matter
Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of
K-1
potassium index
Ib/acre unless othenvise specified). Recommendations for N (and sometimes for B) are based on research/field studies
K20
potash
for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be> 50. If they
Mg %
% CEC occupied by magnesium
are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is
MIN
mineral soil class
an excellent source; 175 to 250 Ib per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear
Mn
manganese
only on reports for greenhouse soil or problem samples.
Mn-A1
Mn-availability index for crop 1
Mn-AI2
2
Mn-availability index for crop 2
Mn4
manganese index
Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z
M-O
mineral-organic soil class
notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients In general, homeowners do not
N
nitrogen
need to be concerned about micronutrients. Various crap notes also address lime fertilizer needs; visit
Na
sodium
nmgr.gov/agronomi/pubs,htm,
NOs-N
nitrate nitrogen
ORG
organic soil Gass
Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find
pH
current sail pH
the exact fertilizer grade recommended on the report, visit wunv.ncaqrqov1aqronomi1obpart4.hfmlWaind information that
P•I
phosphorus Index
may help you choose a comparable alternate. For more information, read AHomeowner's Guide to Fertilizer.
PZOs
phosphate
S-1
sulfur index
Test Results
SS-1
soluble salt index
WN
weight per volume
The first seven values [soil class, HM%, WN, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The
Zn-AI
zinc availability index
Znd
zinc index
remaining 16 [P-11 K-1, Ca%, Mg%, Mn-I, Mn-A11, Mn-Al2, Zn-I, Zn-AI, Cu4, S-I, SS-I, Na, ESP,. SS-I, NO3-N (not routmell
available)] indicate levels of plant nutrients or other fertility measurement. Visit v wncaoraov/e oronomi/uvrst.htm

SECTION 5

2018 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION IN NC
GRANITE FALLS, NC
GRANITE FALLS, NC WWTP LIME STABILIZED LIQUID
MONTH/YEAR
June 2018
YEARLY TOTAL
GRANITE FALLS, NC WTP LIQUID
MONTH/YEAR
June 2018
YEARLY TOTAL
AMOUNT UNIT
80,600.00 G
80,600.00 G
AMOUNT UNIT
1481800.00 G
1483800.00 G
DRY TONS UNIT
12.03 D
12.03 D
DRY TONS UNIT
17.87 D
17.87 D
DRY METRIC
TONS
10.91
10.91
DRY METRIC
TONS
16.21
16.21
2/2/2019

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Waypoint.
ANALYTICAL
7/12/2018
Synagro Central LLC/ Technical
Mary Brewer
284 Boger Road
Mocksville, NC, 27028
Ref: Analytical Testing
Report Number: 18-184-0201
Project Description: Granite Falls WTP
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypolnta nalyti ca L com
Dear Mary Brewer:
Waypoint Analytical Virginia, Inc. received samples) on 7/3/2018 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Sub -contracted testing is noted do the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were pertormed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Arizona AZOfi29 New Jersey VA011 Pennsylvania 68-03109 Virginia 460014
flarida E871087 North Carolina 257 South Carolina 93007
J +�
Page 1 of 8

Wa oint �
Y ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypo rota nal yti ca Isom
Client: Synagro Central LLC/ Technical CASE NARRATIVE
Project: Granite Falls WTP
Lab. Report Number: 18-1 $4-0201
Date: 7/11 /2018
TKN (Titration) Method SM-4500-NH3C-TKN
Analyte: TKN
QC Batch No: E64890
Analyte was flagged for 0 % recovery in the LCS and/or LCSD due to the result. being below the MQL. The actual
result was
XXJ which calculates to a recovery of XX°/ .
Analyte was flagged for 0 % recovery in the LCS and/or LCSD .The actual result was
0.870 which calculates to a recovery of 85%.
QC Batch No: E64890
The MS/MSD recoveries are considered insignificant due to the level of analyte present in the parent sample
relative to the spike level .RPD is based on the MS/MSD results and should be evaluated as laboratory
duplicates.
Nitrate +Nitrite Nitrogen Method SM-4500NO3F
Sample 61491
Analyte: NO3+NO2-N
QC Batch No: E64942
The MS/MSD recoveries are considered insignificant due to the level of analyte present in the parent sample
relative to the spike level .RPD is based on the MS/MSD results and should be evaluated as laboratory
duplicates.
Metals Analysis Method SW -6010C
Sample 61489
Analyte: AI
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interterence is suspected.
.Analyte: As
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within
method limits. No matrix interference is suspected.
Analyte: Fe
QC Batch No: L389609
MS and/or MSD spike recovery Palled. Analyte concentration >25X the MQL. Dilution test within method limits.
Nc matrix interterence is suspected.
Analyte: K
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interterence is suspected.
Page 2 of 8

Waypointry
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www,waypointa n alytica I.co m
Analyte: Mg
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interference is suspected.
Analyte: Mn
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interference is suspected.
Analyte: Mo
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike v✓ithin
method. limits. No matrix interterence is suspected.
Analyte: Pb
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within
method limits. No matrix interference is suspected.
Analyte: Se
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within
method limits. No matrix interterence is suspected.
Solids Total Mercury Analysis - CVAA Method SW -7471 B
Sample 61491
Analyte: Hg
ClC Batch No: E64928
MS/MSD Recovery failed, PDS confirmed matrix interterence
Page 3 of 8

Waypoint.., 7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 18-184-0201
Client Project Description: Granite Falls WTP
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
61492
Granite
Falls
WTP
Solids
06/28/2018
10:30
07/03/2018
61492
Granite
Falls
WTP
Solids
06/28/2018
10:30
07/03/2018
6010D
WiN
WiN: Waypoint Analytical - TN, Memphis, TN, Certifcation: #1354
Page 4 of 8

Report Number: 18-184-0201
Account Number: 46622
Send To: Synagro Central LLC/ Technical
Mary Brewer
284 Boger Road
Mocksvlile. NC 27028
Lab Number : 61492
Sample Id : Granite Falls WTP
Waypoint_
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-94010 Fax [phone]m
www.waypolmanalytical.co
Project: Granite Falls WTP
REPORT OFANALYSIS Date Sampled: 6/28/201810:30:00
Date Received: 07/03/2016 00:00
Date Reported: 07/12/2018
Total Solids * 2.88 28800 100.0 JM 07/03/201815:30 SM -2540G
Moisture* 97.11 100.0 JM 07/03/201815:30 SM -2540G
Total Kjeldahl Nitrogen 1.97 19700 50.0 RD 07/05/2018 09:00 SM-4500-NH3C-TKN
Phosphorus 0.20 2000 50.0 KKM 07/10/2018 01:08 6010D
Potassium 0.14 1420. 50.0 JTR 07/10/201801:08 6010D
Sulfur 0.37 3700 50.0 KKM 07/10/201801:08 6010D
Calcium 0.14 1420 50.0 KKM 07/10/201801:08 6010D
Magnesium 0.17 1690. 50.0 KKM 07/10/201801:08 6010D
Sodium <0.03 <250 250 JTR 07/10/201801:08 6010D
Iron 37200 50.0 KKM 07/10/201801:08 601 OD
Aluminum 126000 500 BKN 07/11/201811:30 6010D
Manganese 1780 5.00 KKM 07/10/2018 01:08 6010D
Copper 56.7 2.50 KKM 07/10/2018 01:08 6010D
Zinc 81A 5.00 KKM 07/10/201801:08 6010D
Ammonia Nitrogen 0.28 2770 50.0 R D 07/05/2016 09:00 SM-4500-NH3C
Organic 1.69 16930 50.0 07/05/201809:00 CALCULATION
Nitrate+Nitrile-N <2.44 2.44 MMT 07/09/201811:20 4500NO3F-2011
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our rep ads and fettersaexclusive and confidential use 01 our closes. and may hot be reproduced In whale orpad, nor ntayany re(arenoa be made
to the aunts the results or the the
In any advielpir p. naves releaseor ether public ann selcembnl3 without obtaining oprimse written authorization,
Pauric McCreary
Agronomist
Page 5 of 8

Report Numher: 18-184-0201
Account Number: 46622
Send To: Synagro Central LLC/Technical
Mary Brewer
284 Boger Road
Mocksville, NC 27028
Lab Number: 61492
Sample Id : Granite Falls WTP
Cadmium
Chromium
Nickel
Lead
Arsenic
Mercury
Selenium
pH'
Molybdenum
Comments:
Waypoint_®
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-94010 Fax [phone]
www,waypointanalytical.com
Project : Granite Falls WTP
REPORT OF ANALYSIS Date Sampled: 6/28/2018 10:30:00
Date Received: 07/03/2018 00:00
Date Reported: 07/12/2018
<1.00
1.00
KKM
07/10/201601:08
60100
49.9
2.50
KKM
07/10/2018 01:08
fi010D
19.5
2.50
KKM
07/10/2018 01:00
6010D
23.6
3.00
KKM
07/10/2018 01:08
6010D
7.45
5.00
KKM
07/11/201800:50
60100
<0.400
0.400
SMC
07/06/201814:13
SW -74710
<5.00
5.00
KKM
07/10/201801:08
6010D
6.3
1.0
R D
07/05/2018 09:00
9045D
<2.50
2.50
KKM
07/10/201801:08
6010D
All values are on a dry weight hasis except as noted by asterisk. Detection limit on all N series Is on a wet basis.
letters are forth vxclusrw and cvnpdenlfel use vlvur clients, and may not be reFlrvduretlln whole orpart, normay any refere
Dur repode and
nce be made
fo IM1e rvorlt. file results, vYlhe tympany In any etived(.sing. ne�rslaleasa. arufherpublio announcements without vblelning vurprlvr wrlllen eulM1vnrellort
Page 6 of 8
Pauric McGroary
Agronomist

Waypoint..®
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Faz 804-271-6446
www.waypo I nta nalytfcal.co m
Cooler Receipt Form
Customer Number: 46622
Customer Name: Synagro Central LLC/ Technical
Report Number: 18-184-0201
Shipping Method
0 Fed Ex � US Postal � Lab � Other
UPS 0 Client � Courier Thermometer ID:
Shipping container/cooler uncompromised? � Yes � No
Number of coolers received r 1'
Custody seals intact on shipping container/cooler? � Yes � No � Not Required
Custody seals intact on sample bottles? � Yes � No � Not Required
Chain of Custody (COC) present? � Yes � No
COC agrees with sample label(s)? � Yes � No
COC properly completed � Yes � No
Samples in proper containers? � Yes � No
Sample containers intact? � Yes (J No
Sufficient sample volume for indicated test(s)? � Yes (J No
All samples received within holding time? � Yes � No
Cooler temperature in compliance? � Yes � No
Cooler/Samples arrived at the laboratory on ice. � Yes Q No
Samples were considered acceptable as cooling
process had begun.
Water -Sample containers properly preserved � Yes � No � N/A
Water -VOA vials free of headspace � Yes � Nc � N/A
Trip Blanks received with VOAs � Yes 0 No � N/A
Soil VOA method 5035 —compliance criteria met � Yes � No � N/A
High concentration container (48 hr) � Low concentration Encore samplers (48 hr)
� High concentration pre -weighed (methanol -14 d) � Low concpre-weighed vials (Sod Bis -14 d)
Special precautions or instructions included? � Yes � No
Comments:
Signature: Brandi Watson Date &Time: 7/03/2018 13:36:17
Page 7 of 8

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Sodium Absorption Ratio Calculation (SAR)
Product Code
Product Name
Sample Date
Report Range
Ratio
2209-02-WPL-NC
GRANITE FALLS,
NC
WTP
LIQUID
6/28/2018
6/1/2018-12131/2018
0.1792
Na mg/I = (Na mg/kg x %Solids) + 100 = (250 x 2.8800) = 100 = 7.2
Ca mg/I = (Ca mg/kg x %Solids) - 100 = (1420 x 2.8800) _ 100 = 40.896
Mg mg/I = (mg mg/kg x %Solids) + 100 = (1690 x 2.8800) + 100 = 48.672
Na meq = Na mg/I - Molec.Wgt.Na = 7.2 = 23 = 0.313043
Ca meq = Ca mg/I + Molec.WgLCa = 40.896 + 20 = 2.0448
Mg meq = Mg mg/I +Molec.Wgt.Mg = 48.672 - 12 = 4.056
SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 0.313043 + SgrRoot[0.5(2.0448+4.056)] = 0.179236
Printed: 2/2/2019
Page 1 19:11

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eJ

Wa oint
Y -ANALYTICAL
7/11 /2018
Synagro Central LLC/ Technical
Mary Brewer
284 Boger Road
Macksville, NC, 27028
Ref: Analytical Testing
Report Number: 18-184-0202
Project Description: Granite Falls WWTP
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypointa nalyti ca I. com
Dear Mary Brewer:
Waypcint Analytical Virginia, Inc. received samples) on 7/3/2018 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines establishetl by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise. indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you. have any questions or need additional information.
Sincerely,
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Arizona AZ0629 New Jersey VA011 Pennsylvania 68-03109 Virginia 460014
Florida E871087 North Carolina 257 South Carolina 93007
��
Page 1 of 8

(`'�`�'
• �
Waypoint_
ANALYTICAL
Client: Synagro Central LLC/ Technical
Project: Granite Falls WWTP
Lab Report Number: 18-184-0202
Date: 7/11 /2018
7621 Whltepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypointa na lyti ca I. com
CASE NARRATIVE
TKN (Titration) MethodSM-4500-NH3C-TKN
Analyte: TKN
QC Batch No: E64890
Analyte was flagged for 0 % recovery in the LCS and/or LCSD due to the result being below the MQL. The actual
result was
XXJ which calculates to a recovery of XX % .
Analyte was flagged for 0 % recovery in the LCS and/or LCSD .The actual result was
0.870 which calculates to a recovery of 85 % .
OC Batch No: E64890
The MS/MSD recoveries are considered insignificant due to the level of analyte present in the parent sample
relative to the spike level .RPD is based on the MS/MSD results and should be evaluated as laboratory
duplicates.
Nitrate +Nitrite Nitrogen Method SM-4500NO3F
Sample 61491
Analyte: NO8+NO2-N
OC Batch No: E64942
The MS/MSD recoveries are considered insignificant due to the level of analyte present in the parent sample
relative to the spike level .RPD is based on the MS/MSD results and should be evaluated as laboratory
duplicates.
Metals Analysis Method SW -6010C
Sample 61489
Analyte: AI
C1G Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration >25X the MOL. Dilution test within method limits.
No matrix interterence is suspected.
Analyte: As
OC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Past Digestion Splke within
method limits. No matrix interference is suspected.
Analyte: Fe
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interference is suspected.
Analyte: I<
OC Batch No: L389fi09
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interference is suspected.
Page 2 of 8

Wa oint�
Y ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.way po intanalytica I.co m
Analyte: Mg
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits.
No matrix interference is suspected.
Analyte: Mn
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. pilution test within method limits.
No matrix interterence is suspected.
Analyte: Mo
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within
method limits. No matrix interference is suspected.
Analyte: Pb
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within
method limits. No matrix interference is suspected.
Analyte: Se
QC Batch No: L389609
MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within
method limits. No matrix interterence is suspected.
Solids Total Mercury Analysis - CVAA Method SW -74716
Sample 6.1491
Analyte: Hg
QC Batch No: E64928
MS/MSD Recovery failed, PDS confirmed matrix interference
Page 3 of 8

Waypoi nt.. 7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 18-184-0202
Client Project Description: Granite Falls W WTP
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
61493
Granite
Falls
WWTP
Solids
06/28/2018
10:00
07/03/2018
61493
Granite
Falls
WWiP
Solids
06/28/2018
10:00
07/03/2018
6010D
WFN
WiN: Waypoint Analytical -TN, Memphis, TN, Certifcation: #1354
Page 4 of 8

Report Number: 18-184-0202
Account Number: 46622
Send To: Synagro Central LLC/Technical
Mary Brewer
284 Boger Road
Mocksvllle, NO 27028
Lab Number: 61493
Sample Id: Granite Falls WWTP
Waypoint.®
ANALYTICAL
7621 Whi[epine Road, Richmond, VA 23237
Main 804-743-9401 a Fax [phone]
www.waypointanaiytfcal.com
Project :Granite Falls W WTP
REPORT OFANALYSIS Date Sampled: 6128/2 01 8 1 0:00:00
Date ceivetl: 07/03/2018 00;00
Date Reported: 07/11/2018
Total Solids"
All values are on a dry weight basis except as noted 6y asterisk. Detection limit on all Nsenes is on a wet basis.
3.58
35800
100.0
JM
07/03/201815:30
SM -2540G
Moisture `
96.41
100.0
JM
07/03/2018 15:30
SM -2540G
Total Kjeldahl Nitrogen
3.70
37000
50.0
R D
07/05/2018 09:00
SM-4500-NH3C-TKN
Phosphorus
1.35
13500
50.0
KKM
07/10/201801:13
601 OD
Potassium
0.22
2190
50.0
JTR
07/10/201801:13
6010D
Sulfur
0.85
8540
50.0
KKM
07/10/201801:13
6010D
Calcium
12.40
124000
500
KKM
07/11/201801:01
6010D
Magnesium
0.37
3730
50.0
KKM
07/10/201801:13
6010D
Sodium
0.10
959
250
JTR
07/10/2018 01:13
6010D
Iron
15900
50.0
KKM
07/10/201801:13
6010D
Aluminum
25600
50.0
KKM
07/10/2018 01:13
6010D
Manganese
160
5.00
KKM
07/10/201801:13
6010D
Copper
124
2.50
KKM
07/10/201801:13
6010D
Zinc
267
5.00
KKM
07/10/201801:13
6010D
Ammonia Nitrogen
0.36
3620
50.0
R D
07/05/2018 09:00
SMA500-NH3C
Organic N
3.34
33380
50.0
07/05/2018 09:00
CALCULATION
Nitrate+Nitrite-N
3370
24.6
MMT
07/09/201811:21
4500NO3F-2011
Pte« mp
Our and letters are for the excNslveand confidential use olour clionls, and may not be reproduced in whole or reel. nor may any re/eance be made
to the updo the results. or Ore company in any advedlsing. news? climate. at olherpubllp ammai mints without obtelmng our prior wrlller, aulhodea Rm
Pauric McGroary
Agronomist
Page 5 of 8

Report Number: 18-184-0202
Account Number: 46622
Send To: Synagro. Central LLC/ Technical
Mary Brewer
284 Boger Road
Mocksville. NO 27028
Lah Numher: 61493
Sample Id : Granite Falls W WTP
Waypoint.
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 904-743-94010 Fax [phone]
www.waypointanaiyticai.com
Project: Granite Falls W WTP
REPORT OF ANALYSIS Date Sampled: 6/28/201810:00:00
Data Rsee ivetl: 07/03/2018 00:00
Date Reported: 07/11/2018
Cadmium
<1.00
Chromium
28.8
Nickel
11.3
Lead
33.8
Arsenic
<5.00
Mercury
2.39
Selenium
<5.00
pH '
11.9
Calcium Carbonate Equivalent
26.30 263000
Molybdenum
3.73
Comments:
KKM
NO CERT#257
CCE, SULFUR AND ORGANIC NITROGEN
NOT FOR COMPLIANCE PURPOSES.
1.00
KKM
07/10/2018 01:13
6010D
2.50
KKM
07110/201801:13
6010D
2.50
KKM
07/10/201801:13
6010D
3.00
KKM
07/10/201801:13
6010D
5.00
KKM
07/11/201800:56
6010D
0.400
SMC
07/06/201814:16
SW -74718
5.00
KKM
07/11/201800:56
6010D
1-0
R D
07/05/2018 09:00
9045D
2500
R D
07/05/2018 12:00
AOAC 955.01
2.50
KKM
07/10/201801:13
6010D
All values are on a dry weight hasis except as noted by asterisk. Detection limit on all N series is on a wet basis.
rrepods and leflera am for the eaGuslve end conlldonlial use orourollenta, an maynor be repmduoedln whale orVeri, nor Way any
mlemnce he metle
bathe worlr. the lesulte, or the tympany In any adyenlaing news releaae,aro[herpubllo annourrcemenfs wRhoul obinlnl g ourRdor wdden auMorFiedon.
Page 6 of 8
Pauric McCreary
Agronomist

Waypoint.®
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypof nta nalyti ca I. com
Cooler Receipt Form
Customer Number: 46622
Customer Name: Synagro Central LLC/ Technical
Report Number: 18-184-0202
Shipping Method
Fed Ex � US Postal � Lab � Other : �—
D UPS � Client � Courier Thermometer ID: �—
Shipping container/cooler uncompromised? � Yes � No
Number of coolers received I '
Custody seals intact on shipping container/cooler? � Yes � No � Not Required
Custody seals intact on sample bottles? � Yes � No � Not Required
Chain of Custody (COC) present? � Yes 0 No
COC agrees with sample label(s)? � Yes � No
COC properly completed � Yes � No
Samples in proper containers? � Yes � No
Sample containers intact? � Yes (J No
Sufficient sample volume for indicated test(s)? � Yes � No
All samples received within holding time? � Yes (J No
Cooler temperature in compliance? � Yes � No
Cooler/Samples arrived at the laboratory on Ice. � Yes � No
Samples were considered acceptable as cooling
process had begun.
Water - Sample containers properly preserved � Yes Q No � N/A
Water- VOAvials free of headspace 0 Yes � No � N/A
Trip Blanks received with VOAs � Yes � No � N/A
Sail VOA method 5035 –compliance criteria met � Yes � No � N/A
� High concentration container (48 hr) � Low concentration Encore samplers (48 hr)
High concentration pre -weighed (methanol -14 d) � Low concyre-weighed vials (Sod Bis -14 d)
Special precautions or instructions included? � Yes � No
Comments:
Signature: Brandi Watson Date &Time: 7/03/2018 13:37:20
Page 7 of 8

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Page 8 of 8
r�

Sodium Absorption Ratio Calculation (SAR)
Product Code
Product Name
Sample Date
Report Range
Ratio
2209-01-LSLIQ-NC
GRANITE FALLS, NC WWTP LIME
6/28/2018
6/1/2018-12131/2018
0.1383
STABILIZED LIQUID
Na mg/I = (Na mg/kg x %Solids) :100 = (959 x 3.5800) + 100 = 34.3322
Ca mg/I = (Ca mg/kg x %Solids) + 100 = (124000 x 3.5800) = 100 = 4439.2
Mg mg/I = (mg mg/kg x %Solids) = 100 = (3730 x 3.5800) - 100 = 133.534
Na meq = Na mg/I : Molec.Wgt.Na = 34.3322 + 23 = 1.4927
Ca meq = Ca mg/I + Molec. Wgt.Ca = 4439.2 + 20 = 221.96
Mg meq = Mg mg/I + Molec.Wgt.Mg = 133.534 _ 12 = 11.1278
SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 1.4927 + SgrRoot[0.5(221.96+11.1278)] = 0.13827
Printed: 2/2/2019
Page 1 19:10

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Granite Falls, NC Total Dry Tons Applied (Annual): 12.03
Permit #: W00016247 Cation Exchange Capacity (non 503 only):
Operator: Shane Wilson Owner: John Hayes Predominant Soil Series: Fairview
Acres Used: 8 Acres Permitted: 13.3 Site #: NC CD 00002 Field #: CD 00002 0001
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
6/28/18
2
3
4
5
6
7
8
9
10
11
12
%Solids
3.58
8
9
10
11
12
Arsenic
5
Cadmium
1
y
Copper
124
Chromi
28.8
�
rt
Lead
33.8
Mercury
2.39
W
Molyb-
denum
3.73
Nickel
11.3
��
Selenium
5
0.000
0.000
0.000
0.000
0.000
Zinc
267
0.000
0.000
0.000
0.000
0.000
0.015
Total
Phos-
horus
13.500
0.000
0.000
0.000
0.000
0.000
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
y
DT/Aa/
�
rt
App.
W
Event
1.50
��
Arsenic
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
Cadmium
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Copper
0.373
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.373
Chromi
0.087
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.087
Lead
0.102
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.102
Mercury
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0:000
0.007
Molyb-
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
denum
Nickel
0.034
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.034
Selenium
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
Zinc
0.803
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.803
Total
Phos-
40.608
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
40.608
horns
°I certify,. under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of%mt pplier
�-1
Dat..
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Granite Falls,. NC Total Dry Tans Applied (Annual): 17.87
Permit #: WQ0016247
Operator: Shane Wilson Owner:
Acres Used: 6.4 Acres Permitted:
Cation Exchange Capacity (non 503 only):
Jennie Wilson Predominant Soil Series:
6.4 Site #: NC CD 00002 Field #:
Fairview
CD 00002 0004
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
6/28/18
2
3
4
5
6
7
8
9
10
11
12
Solids
2.88
8
9
10
11
12
Arsenic
7.45
Cadmium
1
c
Copper
56.7
Chromi
49.9
Lead
23.6
Mercury
0.4
w
MoIyb-
denum
2 5
Nickel
19.5
��
Selenium
5
0.000
0.000
0.000
0.000
0.000
Zinc
81.4
0.000
0.000
0.000
0.000
0.000
0.042
Total
Phos-
horns
2000
0.000
0.000
0.000
0.000
0.000
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
c
DT/Ac./
App.
w
Event
2.79
��
Arsenic
0.042
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.042
Cadmium
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
Copper
0.317
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.317
Chromiu
0.279
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.279
Lead
0.132
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.132
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0..000
0.000
0.000
0.002
Molyb-
0.014
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
denum
Nickel
0.109
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.109
Selenium
0.028
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.028
Zinc
0.455
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.455
Total
Phos-
11.168
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
11.168
horns
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of £nes and
imprisonment for knowing violations".
Signature of Land ier
Z- � l �
Dat
DENR FORM MFLSF (12/2006)

TCLP data is not included in the 2018 Annual Report for Granite Falls WTP.
A TCLP sample was taken in 2016 and is only required to be taken once per permit cycle.

TjSul"Mil
FUVIRONA1ENTAL FECHNOLODIES, ftp
A,rratyHcat Laboratoi'OP5
March 155 2018
Erik Bruce
Synagro
284 Boger Rd.
Mocksville, NC 27028
TEL: [phone]
FAX: [phone]
RE: Granite Falls
Stmmvit Environmental Technologies, Inc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX:: [phone]
Website: hitu.Iliviow.settek.com
Dear Erik Bruce: Order No.: 18030038
Summit Environmental Technologies, Inc. received 1 sample(s) on 3/1/2018 for the
analyses presented in the following report.
There were no problems with the analytical events associated with this report
unless noted
in the Case Narrative.
Quality control data is within laboratory defined or method specified acceptance limits
except where noted.
If you have any questions regarding these tests results, please feel free to call the
laboratory.
Sincerely,
Jennifer Woolf
Project Manager
3310 Win St,
Cuyahoga Fall
s, Ohio 44223
Arkansas 88-0735, California 07256
CA, Colomdq ConneoticutPH-0108, Delawaze, floada NPLAC 087688, Georgia E87688, Ideho OH00923, Illinois
200061, Indiana C -OH -13, Kansas E-10347, KcnNcky (Undergromd Storege Tank) 3, Kentucky 90146, Louisiana 0406], Marylmrd 339, Minnesota
409711, New Hampshire 2996, New Iersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Oklahoma 9940, Oregon
OH2O0001, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-11-5, Utah OH009232011-1, Virginia VELAP 9456, Washington
0891
Page 1 of 28

NUMMIT S„"""`Environmental Te""oInc. Case Narrative
33/010Win St.
rNVIRONh1ENTRL IEGMNOLOGIEs, NG. Cuyahoga Falls, Ohio 44223 WO#: 18030038
Analytical tabcrBw0 es TEL: [phone] FAX. [phone]
Website: InaclAvmm.setrekcom Date: 3/15/2018
CLIENT: Synagro
Project: Granite Falls
WorkOrder Narrative:
18030038: This report in its entirety consists of the following documents: Cover Letter, Case Narrative.,
Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody,
Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit
Environmental Technologies, Inc, Work Order Number assigned to this report.
Summit Environmental Technologies, Inc, holds the accreditations/certifications listed at the bottom of
the cover letter that may or may not pertain to this report. State Certificates and Scopes of Accreditation
are attached as applicable. Results provided in this report for any parameter not listed on the Scope of
Accreditation should be considered "not certified."
The information contained in this analytical report is the sole property of Summit Environmental
Technologies, hie. and that of the customer. It cannot be reproduced in any form without the consent of
Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results
contained in this report are only representative of the samples received. Conditions can vary at different
times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible
for use or interpretation of the data included herein.
All results for Solid Samples
are reported
on
an
"as received" or
"wet weight" basis unless indicated as
"dry weight" using the "-dry"
designation
on
the
reporting units.
This report is
believed
to meet all of the requirements of the
accrediting agency,
where applicable. Any
comments or
problems
with the analytical events associated
with this report are
noted. below.
Analytical Sequence Sample Notes:
18030038-OOIa tclp-svoc-cpest(8081b): LCS recovery biased high; associated sample results are N.D.
18030038-OOIA MTL-TCLP-7(60101)): Silver failed the CCV high, but because the sample was
nondetect for silver it can be accepted.
Analytical Sequence QC Notes:
CCV 7359 20 ug/L tclp-voc-mstr_tclp(8260): The VOC CCV (Batch R81286) exhibited high recovery
for Vinyl chloride; Associated samples are ND for Vinyl chloride.
18030038-OOIAMS SVOC-BNA_TCLP(8270): MS exhibited high recovery for Pentachlorophenol;
Parent sample is ND for Pentachlorophenol.
Original
Page 2 of 28

SUMMIT SmmmitEn„ironmentalYeehnolWi St. Case Narrative
331010Win Sr.
Rd19RONh1EWAL IE"NOLOOIas, INC- Cuyahoga Falls, Ohio 44223 w0#: 18030038
ArraFyGoal Laboratos W9 TEL: [phone] FAX: [phone]
Website: htm://v,nvsettekcom Date: 3/15/2018
CLIENT: Synagro
Project: Granite Falls
18030038-OOIAMS SVOC-BNA_TCLP(8270): Spike recovery indicates matrix interference. The
method is in control as indicated by the laboratory control sample (LCS).
18030038-OOIAMSD SVOC-BNA_TCLP(8270): High RPD due to suspected sample inhomogeneity.
18030038-OOIAMSD SVOC-BNA_TCLP(8270): MSD exhibited low recovery for Surrogate: Phenol -
d6 due to matrix effect.
Original
Page 3 of 28

Summit Environmental Technologies, In Qualifiers and Acronyms
P1 SUMMINt 3310 Win 5
"WIRONlAEWAL a EC14NOLOQ1'c S, iNC Cuyahoga Falls, Ohio 442, WO#: 18030038
Analytical taboratorles TEL: [phone] FAX: [phone]
Website: hum:Nuviv.settek.co. Date: 3/15/2018
These commonly used Qualifiers and Acronyms may or may not be present in this report
Qualifiers
U
The compound was analyzed for but was not detected.
J
The reported value is greater than the Method Detection Limit but less than the Reporting Limit.
I
The hold time for sample preparation and/or analysis was exceeded.
D
The result is reported from a dilution.
E
The result exceeded the linear range of the calibration or is estimated due to interference.
MC
The result is below the Minimum Compound Limit.
The result exceeds the Regulatory Limit or Maximum Contamination Limit.
m
Manual integration was used to determine the area response.
d
Manual integration in which peak was deleted
N
The result is presumptive based on a Mass Spectral librarysearch assuming a 1:1 response.
P
The second column confirmation exceeded 25% difference.
C.
The result has been confirmed by GUMS.
R
The result was not confirmed when GUMS Analysis was. performed.
B/MB+
The analyte was detected in the associated blank.
G
The ICB or CCD contained reportable amounts of analyte.
QC-/+
The CCV recovery failed low (-) or high (+).
R/QDR
The RPD was outside of accepted recovery limits.
QL-/+
The LCS or LCSD recovery failed low (-) or high (+).
QLR
The LCS/LCSD RPD was outside of accepted recovery limits.
QM-/+
The MS or MSD recovery failed low (-) or high (+).
QMR
The MS/MSD RPD was outside of accepted recovery limits.
QV-/+
The ICV recovery failed low (-) or high (+),
S
The spike result was outside of accepted recovery limits.
Z
Deviation; A deviation from the method was performed; Please refer to the Case Narrative for
additional information
Acronyms
ND
Not Detected RL Reporting Limit
QC.
Quality Control MDL Method Detection Limit
MB
Method Blank LOD Level of Detection
LCS
Laboratory Control Sample LOQ Level of Quantitation
LCSD
Laboratory Control Sample Duplicate PQL Practical Quantitation Limit
QC5
Quality Control Sample CRQL Contract Required Quantitation Limit
DUP
Duplicate PL Permit Limit
MS
Matrix Spike RegLvl Regulatory Limit
MSD
Matrix Spike Duplicate MCL Maximum Contamination Limit
RPD
Relative Percent Different MinCL Minimum Compound Limit
ICV
Initial Calibration Verification RA Reanalysis
ICB
Initial Calibration Blank RE Reextraction
CCV
Continuing Calibration Verification TIC Tentatively Identified Compound
CCB
Continuing Calibration Blank RT Retention Time
RLC
Reporting Limit Check CF Calibration Factor
DF
Dilution Factor RF Response Factor
This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting.
Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this
list or for additional information regarding the use of these Qualifiers on reported data.
Original
Page 4 of 28

5U 'T Summit Environmental Technologies, Inc. Workorder
3310 Win St.
FINVIRONAIEMWAL TECtMOLd�Mfes, INC Cuyahoga Falls, Ohio 44223 Sample Summary
Anafytfral Laborntones TEL: [phone] FAX: [phone] WQ#: 18030038
Webstre: ham://vwv.sertekcom I5 -Mar -18
CLIENT: Synagro
Project: Granite Falls
Lab SampleID Client Sample u) Tag No Date Collected Date Received Matrix
18030038-001 Ganite Falls W WTP 2/27/2018 2:00:00 AM 3/1/2018 10:20:00 AM Sludge
Page 5 of 28

VM�1T �'nm,ttFnv omnealglT:ha3)ag01 3310 t' DATES REPORT
0'ia 0'l.
ENVIRONMENTAL TECHNOLOGIES, INC. Cuyahoga Falls, Ohio 44223
AnalyUeal LabOfalorle.4 WLNl: 180311038
TPJ,:[phone] FAXj330) 253-489
Webs/ue: Judo/Avarav seHek. m 15-M,48
Client: Synagro
Project: Granite Falls
Sample Clieotsample ID Collection Date Matra Test Name Leachate Date Prep Date Analysis Date
18030038-001A Gani
te FallsWWTP 2/2]/20182:09:00 AM Sludge Ipyitability of Solids (Sul -846:1030)
3/2/20161:45:00
PM
pH (SW9045D)
3/14/20189 00:09
PM
Reactive Cyanide (9014/73 3.2) -Solid
3/8/2018 4:06:00
PM
Reactive Sulfide (9034)/7 3A.2
3/8/2018 4:06:00
PM
TCU Herbicides Analysis (SWI 311/83/1/20186:00:00 PM
3/]/2018230:00
PM
3/12/201811:1300PM
TCU Mercury Analysis (SW 1311/]413/1/20186:00:00 PM
3/5/201811:
50: 00 AM
3/5/20185: 34:
00 PM
TCLP Metals Analysis (SW1311/60103/020186:00:00 PM
3/2/20189:
05: 00 AM
3/6/2018 7 43
39 PM
TCLP pesticides Analysis(SW1311/8/3/1/208 6-00x00 PM
3/5/2018]:
00: 00 AM
3/6/2018229:
00 PM
TCLP Seng -Volatiles Analysis 3/1/20186:00: 00 PM
3/5/20188:
00: 00 AM
3/5/20186: 54:
00 PM
(SW1311/8270)
TCLPVolatiles Armlysis
3/1/20186:
00.00 PM
3/2/2018]: 13:
00 PM
Original
Page 6 of 28

Summit Environmental Technologies, Inc.
RINUMMIT
33/0 Win St. Analytical Report
rrWRONM1ENTAL I£CHHOLOG: Es, iNC Cuyahoga Falls, Ohio 44223 (basereport)
Analytical Laboratories TEL: [phone] FAX [phone] WO#: 18030038
Website: pita lAvwiv.senekeom Date Reported: 3/15/2018
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 2/27/20182:00:00 AM
Lab ED: 18030038-OOIA
Project: Granite Falls
Client Sample ID Granite Falls W WTP
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB-SOLID SW7470A SW7470A Analyst: EAM
TCLP MERCURY ANALYSIS (SW1311/7470)
TCLP Mercury ND 0.00500 mg/L 1 3/5/2018 5:34:00 PM
TCLP METALS, VOC, BNA, PEST, HERB-SOLID SW6010D SW3010A Analyst KMS
TCLP METALS ANALYSIS (SW1311/6010)
TCLP Arsenic(As) ND 0.500 mg/L 1 3/6/2018 7:43:39 PM
TCLP Badum(Ba) NO 5.00 mg/L 1 3/6/2018 7:43:39 PM
TCLP Cadmium(Cd) ND 0.100 mg/L 1 3/6/2018 7:43:39 PM
TCLP Chromium(Cr) ND 0:200 mglL 1 3/6/2018 7:43:39 PM
TCLP Lead(Pb) ND 0.500 mg/L 1 3/6/2018 7:43:39 PM
TCLP Selenium(Se) ND 0.0500 mg/L 1 3/6/2018 7:43:39 PM
TCLP Silver(Ag) NO 0.500 QC+ mg/L 1 3/6/2018 7:43:39 PM
NOTES:
Silver failed the CCV high, but because the sample turas nondetect for silver it can be accepted.
TCLP METALS, VOC, BNA, PEST, HERB-SOLID SW8270D SW351OC Analyst: BJH
TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270)
1,4-Dichlorobenzene NO 0.0800 mg/L 2 315/20186:54:00 PM
2,4,5-Trichlorophenol NO 0.200 mg/L 2 315/20186:54:00 PM
2,4,6-Trichlorophenol ND 0.200 mg/L 2 3/5120186:54:00 PM
2,4-Dinitrotoluene NO 0.0400 mg/L 2 3/5120186:54:00 PM
o-Cresol ND 0.200 mg/L 2 3/5/20186:54:00 PM
m/p-Cresol(s) ND 0.200 mg/L 2 3/5/20186:54:00 PM
Cresols, Total ND 4.00 mg/L 2 3/5/2018 6:54:00 PM
Hexachloro-1,3-butadiene NO 0.0160 mg/L 2 315/20186:54:00 PM
Hexachlorobenzene NO 0.0400 mglL 2 3/5/2018 6:54:00 PM
Hexachloroethane ND 0.0800 mglL 2 3/5/2018 6:54:00 PM
Nitrobenzene ND 0.0800 mglL 2 3/5/20186:54:00 PM
Pentachlorophenol ND 0.200 QC+ mg/L 2 3/512018:6:54:00 PM
Pyridine ND 0.200 QC+ mg/L 2 3/5/20186:54:00 PM
Surr: 2-Fluorophenol 42.9 10-109 %Rec 2 3/5/2018 6:54:00 PM
Surr: Phenol-d6 18.9 10-109 %Rec 2 3/5/2018 6:54:00 PM
Surr. Nitrobenzene-d5 70.9 19-120 %Rec 2 3/5/2018 6:54:00 PM
Qualifiers: * Value exceeds Maximum Contaminant Level. E Value abovequantitation range
H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response
MC Value is below Minimum Compound Limit, N Tentatively identified compounds
ND Not Detected O RSD is greater than RSDlimit
P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 7 of 28

N U MM 1 7 Sunartlm
f Em�ironenral Technologies, Inc.
3310 Win Sr.
nNYIRONhIEMfALTECONOLOGIES, INC Cuyahoga Falls, Ohio 44223
AnedVficaf LaborBlories TEL: [phone] FAX: [phone]
Website.: huy.lApunp.serreircom
Analytical Report
(base report)
WO#: 18030038
D ate. Reported: 3/15/2018
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 2/27/20182:00:00 AM
Lab ID: 18030038-OOIA
Project: Granite Falls
Client Sample ID Granite Falls W WTP
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP SEMI -VOLATILES ANALYSIS (SW1311/8270)
Surr: 2,4,6-Tribromophenol 45.1 10-120
Surr: 2-Fluorobiphenyl 66.0 22-117
Surr: p-Terphenyl-tl14 84.0 34-116
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP PESTICIDES ANALYSIS (SW1311I6081)
Chlordane, total No
SW8270D SW3510C Analyst: BJH
%Rec
Toxaphene
ND
Endrin
No
gamma -BHC
No
Heptachlor
ND
Heptachlor epoxide
ND
Methoxychlor
ND
Surr: TCMX
85.7
Surr: DCB
64.7
NOTES:
2
LCS recovery biased
high; associated sample results are N.D.
SW8270D SW3510C Analyst: BJH
%Rec
2
3/5/2018 6:54:00
2
3/6/20182:29:00
PM
%Rec
2
3/5/2018 6:54:00
ND
mg/L
PM
%Rec
2
3/5/2018 6:54:00
PM
0.00200
PM
SW8081 SW3510C Analyst: JBN
0.0200
ND
mg/L
2
3/6/20182:29:00
1.18
Benzene
PM
0.0400
ND
mg/L
2
3/6/2018 2:29:00
PM
0.00200
QL+
mg/L
2
3/6/2018 2:29:00
PM
0.00200
QL+
mg/L
2
3/6/2018 2:29:00
PM
0.00200
QL+
mg/L
2
3/6/2018 2:29:00
PM
0.00200
QL+
mg/L
2
3/6/2018 2:29:00
PM
0.00200
QL+
mg/L
2
3/6/2018 2:29:00
PM
10 - 119
%Rec
2
3/6/2018 2:29:00
PM
10 -119
%Rec
2
3/6/2018 2:29:00
PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP HERBICIDES ANALYSIS (SW1317/8751)
214-D ND 1.00
2,4,5 -TP ND 0.500 d
Surr: DCAA 85.2 20-140
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP VOLATILES ANALYSIS
1,1-Dichlaroethene
ND
1,2-Dichloroethane
ND
MEK
1.18
Benzene
ND
Carbon tetrachloride
ND
Chlorobenzene
ND
SW8151A SW8151A Analyst: JBN
mg/L 1 3/12/2018 11:13:00 PM
mg/L 1 3/12/2018 11:13:00 PM
%Rec 1 3/12/2018 11:13:00 PM
SW8260B SW1311M Analyst: CTB
0.0500
Value exceeds Maximum Contaminant Levol.
mg/L
10
3/2/2018 7:13:00
Value is below Minimum Compound Limit.
ND
PM
0.0500
Second column confirmation exceeds
mg/L
10
3/2/2018 7:13:00
PM
0.250
mg/L
10
3/2/2018 7:13:00
PM
0.0500
mg/L
10
3/2/2018 7:13:00
PM
0.0500
mg/L
10
3/2/2018 7:13:00
PM
0.0500
mg/L
10
3/2/2018 7:13:00
PM
Qualifiers: ' E Value above quantitation range
M Manual Integration used to determine area response
Value exceeds Maximum Contaminant Levol.
H
Holding times for preparation or analysis exceeded
MC
Value is below Minimum Compound Limit.
ND
Not Detected
P
Second column confirmation exceeds
R
RPD outside accepted recovery limits
N Tentatively identified compounds
O RSD is greater than RSDlimit
PL Permit Limit Original
RL Reporting Detection Limit
Page 8 of 28

s V � i Su anitEnvironmental Technologies, Inc. Analytical Report
3310 117in St.
FrWRON6IENTALUCkNOLOCies, INC. Cuyahoga Falls, Ohio 44223 (base report)
An3fyNoaf Laborarorlas TEL: [phone] FAX: [phone] WO#: 18030038
Websue: hno:/hviviv.settek.com Date Reported: 3/15/2018
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 2/27/2018 2:00:00 AM
Lab ID: 18030038-OOIA
Project: Granite Falls
Client Sample ID Granite Falls W WTP
Analyses
Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8260B
SW1311M Analyst:
CTB
TCLP VOLATILES ANALYSIS
Chloroform
ND
0.0500
mg/L
10
3/2/2018 7:13:00
PM
Tetrachlomethene
ND
0.0500
mg/L
10
3/2/2018 7:13:00
PM
Trichloroethene
ND
0.0500
mg/L
10
3/2/20187:13:00
PM
Vinyl chloride
ND
0.0200
QC+ mg/L
10
3/2/2018 7:13:00
PM
Surr: 4-Bromofluorobenzene
111
70-130
%Rec
10
3/2/2018 7:13:00
PM
Surr: Dibromofluoromethme
94.9
70-130
%Rec
10
3/2/2018 7:13:00
PM
Surr: Toluene -d8
103
70-130
%Rec
10
3/2/2018 7:13:00
PM
NOTES:
The VOC CCV (Batch R81286) exhibited high recovery for Vinyl chloride;
Associated samples are
ND for Vinyl
chloride.
RCI -SOLID -W/ IGNITABILITY1030
SW9014
Analyst:
MS
REACTIVE CYANIDE (901417.3.3.2) -SOLID
Cyanide, Reactive
ND
0.500
mg/Kg
1
3/8/2018 4:06:00
PM
RCI -SOLID -W/ IGNITABILITY1030
SWI 030
Analyst:
AJT
IGNITABILITY OF SOLIDS (SW -846:1030)
Ignitability
non-flammable
1
3/2/2018 1:45:00
PM
RC1 -SOLID -W/ IGNITABILITY1030
SW9045D
Analyst:
CXS
PH (SW9045D)
pH
5.3
s.u.@21.0°C
1
3/14/2018 8:00:00 PM
RCI -SOLID -W/ IGNITABILITY1030
SW9034
Analyst:
MS
REACTIVE SULFIDE (9034)/7.3.4.2
Sulfide, Reactive
ND
25.0
mg/Kg
1
3/8/2018 4:06:00
PM
Qualifiers: * Value exceeds Maximum Confaminamit Level.
H Holding times far preparation or analysis exceeded
MC Value is belew Minimum Compound Limit.
ND Not Detected
P Second column confirmation exceeds
R RPD outside accepted recovery limits
E Value abovequantitation range
M Manual Lrtegration used to determine area response
N Tentatively identified compounds
O RSD is greater than RSDlimit
PL Permit Limit Original
RL Reporting Detection Limit
Page 9 of 28

S U ' 01 Summit Environmental Technologies, Inc. Accreditation Program
3310 win sr. Analytes Report
FNVIRONMENTALTBCMNOLAGIES,. INC. Cuyahoga Falls, Ohio 44223 Y P
Analytical Labcuatrr)es TEL: [phone] FAX: [phone] WO#: 18030038
Website: hau:lAnviv.settek.com
15 -Mar -18
Client: Synagro State: NW
Project: Granite Falls Program Name: NC_WW_SCM
Sample
Matrix
Test Name
Analyte
Status
18030038-OOIA
Sludge
Ignitability of Solids (SW -846: 1030)
Ignitability
A
Sludge
pH(SW9045D)
Hydrogen Ion (PH)
A
Sludge
Reactive Cyanide (9014/7.3.3.2) -Solid
Cyanide, Reactive
U
Sludge
Reactive Sulfide (9034)/7.3:4.2
Sulfide, Reactive
U
Sludge
TCLP Herbicides Analysis (SW131 1/8151)
274,5 -TP
A
Sludge
TCLP Herbicides Analysis(SW1311/8151)
2,4-D
A
Sludge
TCLP Herbicides Analysis (SW1311/8151)
DCAA
A
Sludge
TCLP Mercury Analysis(SW1311/7470)
Mercury
A
Sludge
TCLP Metals Analysis (SW1 311/6010)
Arsenic
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Barimn
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Cadmium
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Chromium
A
Sludge
TCLPMetals Analysis(SW1311/6010)
Lead
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Selenium
A
Sludge
TCLP Metals Analysis(SW1311/6010)
Silver
A
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
252',3,3',434'.,535,6,6'-
A
Decachlorobiphenyl
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
Chlordane, total
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Endrin
A
Sludge
TCLP Pesticides Analysis .(SW1311/8081)
gamma -BHC
A
Sludge
TCLP Pesticides Analysis (SWI 311/8081)
Heptachlor
A
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
Heptachlor epoxide
A
Sludge
TCLP Pesticides Analysis (SW1311/808 1)
Methoxychlor
A
Sludge
TCLP Pesticides Analysis (SWI 311/8081)
Tetrachloro-m-xylene
A
Sludge
TCLP Pesticides Analysis (SWI 311/8081)
Toxaphene
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
1,4 -Dichlorobenzene
A
Sludge
TCLP Semi -Volatiles Analysis (SW1311/8270)
2,4,5 -Trichlorophenol
A
Sludge
TCLP Semi -Volatiles Analysis (SWI 311/9270)
2,4,6-Triblomophenol
A
Sludge
TCLP Semi -Volatiles Analysis (SW1311/8270)
2,4,6 -Trichlorophenol
A
Sludge
TCLP Semi -Volatiles Analysis (SW1311/8270)
2,4-Dinitrotoluene
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
2-Fluorobiphenyl
A
Sludge
TCLP Semi -Volatiles Analysis (SW 1311/8270)
2-Fluorophenol
A
Key
Key
NC—WW—SCM
A Accredited
NC_WW_SCM U Unavailable
Version #2
Page 10 of 28

SUMMIT
SummitEnvironnienlalTechnologies, Inc. Accreditation Program
3310 Win St. Analytes Report
rNVIA.ON MENTALTECHlNOLO©IES, INC Cuyahoga Falls, Ohio 44223 J C
Anafyfical Laboratollea TEL: [phone] FAX [phone] WO#: 18030038
Website: htto:lAnviv.settek.eoni 15 -Mar -18
Client: Synagro State: NW
Project: Granite Falls Program Name: NC—WW—SCM
Sample lD Matrix
Sludge TCLP Volati
Test Name
Analyte
Statue
18030038-OOIA Sludge
TCLP Semi -Volatiles Analysis(SWI311/8270)
1,2-Dichloroethane
2-Methylphenol
A
Sludge
TCLP Semi -Volatiles Analysis
(SWI 311/8270)
3,4-Methylphenol
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
Sludge
Cresols, Total
A
Sludge
TCLP Semi -Volatiles Analysis
(SW 1311/8270)
Hexachlorobenzene
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
Chlorobenzene
Hexachlorobutadiene
A
Sludge
TCLP Semi -Volatiles Analysis.(SW1311/8270)
A
Hexachloroethane
A
Sludge
TCLP Semi -Volatiles Analysis
(SWI 311/8270)
Nitrobenzene
A
Sludge
TCLP Semi -Volatiles Analysis(SW1311/8270)
TCLP Volatiles Analysis
Nitrobenzene -d5
A
Sludge
TCLP Semi Volatiles Analysis
(SW1311/8270)
Pentachlorophenol
A
Sludge
TCLP Semi -Volatiles Analysis
(SW1311/8270)
Phenol -d6
A
Sludge
TCLP Semi -Volatiles Analysis
(SW131118270)
p-Terphenyl-d14
A
Sludge
TCLP Semi -Volatiles Analysis
(SWI 311/8270)
Pyridine
A
Page 11 of 28
les Analysis
l,l-Dichloroethene.
A
Sludge
TCLP Volatiles Analysis
1,2-Dichloroethane
A
Sludge
TCLP Volatiles Analysis
2-Butahone
A
Sludge
TCLP Volatiles Analysis
4-Bromofluorobenzene
A
Sludge
TCLP Volatiles Analysis
Benzene
A
Sludge
TCLP Volatiles Analysis
Carbon tetrachloride
A
Sludge
TCLP Volatiles Analysis
Chlorobenzene
A
Sludge
TCLP Volatiles Analysis
Chloroform
A
Sludge
TCLP Volatiles Analysis
Dibromotluoromethane
A
Sludge
TCLP Volatiles Analysis
Tetrachloreethene
A
Sludge
TCLP Volatiles Analysis
Toluene -d8
A
Sludge
TCLP Volatiles Analysis
Trichloroethene
A
Sludge
TCLP Volatiles Analysis
Vinyl chloride
A
Key
Key
NC—WW—SCM A Accredited
NC_WW_SCM U Unavailable
Version #2
Page 11 of 28

® SuMMI't sraam;ren,haaa,ea,a;reen„310fYinSI. QC SUMMARY REPORT
3310 Wfi SI.
ENVISONrdENTAL TECSNOLaOIFS, INC CeOahoga Falls, Ohio 44223
Analytical Laboralariea T[iL: (330) 2534211 FAX: [phone] WON: 18030038
O'eAdle: hilt) lAewn..renek.com IS -Marl R
Client: Synago
Project: Granite Falls BatchB): 31107
Sample lD M13�31107 SampType: MBLK TestCode: Iclp-vocrostr Unlls: milli.
1,1-Dichloroelhene NB 0.0500
1,2-Dichloroethane NO
112
70
130
500.0
0.0500
MEK
NO
0.250
Benzene
ND
0.0500
Carbon tetrachloride
ND
Prep Date: 3/1/2018
RunNo: 81286
Client ID:
PBS
Batch ID:
31107
TestNo:
SW8260B SW1311M
Analysis Date: 3IV2018
Sense: 1439966
Analyte
NB
0.0500
Result
PQL
SPKvalue SPKRef Val
%REC LowLimit HighLimit RPDRef Val
%RPD RPDLimit Qual
500.0
112
70
130
500.0
0.0500
MEK
NO
0.250
Benzene
ND
0.0500
Carbon tetrachloride
ND
0.0500
Chlorobenzene
NO
0.0500
Chloroform
ND
0.0500
Tobachloreethene
ND
0.0500
Trichloroether»
NB
0.0500
Vinyl chloride
ND
0.0200
Surr: 4-BmmoBuorobenzene
560
Surr. Dibromofluomm ethane
489
Surr: Toluene -dB
504
500.0
112
70
130
500.0
97:3
70
130
500.0
101
70
130
QC+
1,1-Oichlamethene 0.199 0.0500 0.200 0 99.3 39:9 160
1,2-0ichloro
or analysis exceeded
Sample ID
t8030033001aMS
SampType:
MS
TeslCode:
tclp-voc-mstr Units: mglL
Prep Date:
RunNo: 81286
Client ID:
Ba1chQC
Batch ID:
31107
TestNo:
SW8260B SW1311M
Analysis Date: 3/2/2018
SegNo: 1440508
Analyte
0.225
0.0500
Result
PQL
SPK value SPK Ref Val
%REC LowLimlt HighLimit RPDRef Vel
%RPD RPDLImit Coal
Qualifiers: ' Value exceeds Maximum Contaminant Level, B Malytedetec[ed in elle assodated Method Bleak E Value above quantitation mage
H Holding times for preparation
or analysis exceeded
ethane
0,197
0.0500
0.200
0
986
42.5
157
MEK
2.06
0.250
100
1.08
97:5
76.6
227
Benzene
0.225
0.0500
0.200
0
113
38.1
155
Page 12 of 28
or analysis exceeded
1
Mature detected below quantitation limits
M
Manual lntagmtion used to determine
Ongutal
MC
Value is belowArdimum Compound limit
ND
Not Detected
O
RSD is},neaterthan RSDliTo
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits
Page 12 of 28

®SUM"E"Mi 3310 s„nr„,Em,o-a»mearalTeahn310War S(.
InVIPONMENTAL TECkN I-Orl s3, INC Oaaf rgalralls, Ohio 44M WO#: 18030038
AhalyOoul Laboratories TEL: [phone] FAX: [phone]
Webstte: haahopusu.sseakcansLS-M 78
Client: Synagro
Project: Granite Falls BatchlD: 31107
Sample lD 18030033-001aM5 SampType: MS TestCode: tclp-voc-mstr Units: mg/-
Carbon teUactJaride 0.177 00500 0.200 0 88.7 40.8 162
Chlorobenzene 0208. 0.0500 0200
.
0
104
Prep Dale:
RunNo: 81286
Client ID:
BatchQC
Batch ID:
31107
TestNo:
SW8260B SW1311M
Analysis Date: 3/2/2018
Sense: 1440508
Analyte
0.176
0.0500
Result
PQL
SPK value SPK Ref Val
%REG LowLlmit Highl-imit RPD Ref Val
%RPD RPDLimit Qual
Sample ID 18030033-001aMSD SampType: MSD TestCode: tclp.
.
0
104
35.7
166
Chloroform
0.210
0.0500
0.200
0
105
18.3
199
Telrac iloroethene
0.176
0.0500
0.200
0
86.2
10
261
Trichloroethene
0.207
0.0500
0.200
0
104
23.8
175
Vinyl chloride
0.231
0.0200
0.200
0
116
10
165 QC+
Sun: 4-Bromoflucrobenzene
558
88.5
500.0
162
112
84.6
130
Surr. Dibromofluommathane
508
500.0
0
102
71.4
127
Surr: TolueneCe
508
Chloroform
500.0
BMW
102
74.6
127
1,1-Oichloroethene 0.191 0.0500 0.200 0 95.3 39.9 160 0.199 4.11 25
1;2-Dichloroethane 0.193 0.0500 0.200 0 96.7
voc-msir Units: mglL
Prep Dale'.
RunNo: 81286
Client ID:
BatChQC
Batch to:
31107
TestNo:
SW8260B SW1311M
Analysis Date: 3/2/2019
SegNo: 1440809
Analyte
1.00
Result
PQL
SPKvalue SPKRef Val
%REC Lowl-imit Hlghl-imil RPDR&Val
%RPD RPDLimit oust
Page 13 of 28
42.5
157
0.197 2.00
25
MEK
2.08
0.250
1.00
1.08
99.5
166
227
2.06 0.967
25
Benzene
0.213
0.0500
0.200
0
106
38.1
155
0.225 5.57
25
Carbon tetrachloride.
0.177
0.0500
0:200
0
88.5
40.6
162
0.177 0.226
25
Chlorobenzene
0.207
0.0500
0.200
0
103
35.7
168
0.208 0.867
25
Chloroform
0.199
BMW
0.200
0
99.4
18.3
199
0,210 5.48
25
Tetrachlorcethene
0.176
0.0500
0.200
0
87.8
10
261
0.176 0.455
25
Qualifiers: '
Value exceeds Maximum Contaminant Level.
B
Andytedetected in the associated Medrad Blank
E
Valueabwequantitationrange
H
Holding times for preparation or analysis exceeded
I
Analyte detected below quantitation It mils
M
Manual integration used to determine
Ongival
MC
Value is belowMinimum Compound Limit.
ND
Not Detected
O
RSDisgreaterthan ASDlimit
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits
Page 13 of 28

SuMMI0 „ nEroo-nme„rat knhnadsgegbm. QC SUMMARY REPORT
3310 WM Sr.
ENVIRONMENTAL TECHNOLOGIES, INC CaOoahoga Falls, Ohio 44223
AtralyNGgl GxbOraforfta WON: 18030038
711: (330) 2534211 F9 . [phone].
Webslre: Li,o /Aviviv.sellek eo ZS-MrirvLB
Client: Synago
Project: Granite Falls BatchID: 31107
Sample ID 1
Trichloroethene 0:194 0.0500 0.200 0 97.0 23.6 175 0,207 6.48 25
Vinyl chloride 0.213 0.0200 0200
Value ezceede Maximum Contaminant Level.
H
Analyte detected in the associated Method Hlank
E
Value above quantimtien range
H
Holding times t'orpreparation or analysis exceeded
!
8030033.001aMSD
SampType:
MSD
TestCode:
tclp-voc-mstr Units: mglL
Prep Date:
RunNo: 81286
Client ID:
BatchCC
Batch ID:
31107
TestNo:
SW8260B SW1311M
Analysis Date: 312J2018
SegNo: 1440509
Analyte
491
500.0
Result
POL
SPKvalue SPKRef Val
%REC Lowl-imit Highl-mut RPDRer Val
%RPD RPDLImit Dual
Qmdifiers:
Value ezceede Maximum Contaminant Level.
H
Analyte detected in the associated Method Hlank
E
Value above quantimtien range
H
Holding times t'orpreparation or analysis exceeded
!
Analyte deteckd belmv quantitatlon limits
.
D 106
10
165 0.231
6.28
25 QC+
Sum: 4-Bronofluorobenzene
560
500.0
112
04.6
130
0
25
Sun: Dibromotluoiomelhane
491
500.0
98.2
71.4
127
0
25
Surr. TclueneCS
517
500.0
103
74.6
127
0
25
Qmdifiers:
Value ezceede Maximum Contaminant Level.
H
Analyte detected in the associated Method Hlank
E
Value above quantimtien range
H
Holding times t'orpreparation or analysis exceeded
!
Analyte deteckd belmv quantitatlon limits
M
Manual lntetrzation used to determine
Original
MC
Val no i3 bel ow Mnimum Compound limit
ND
No[Detected
O
RSD is Beater Utan RSDlimit
P
Second column confirmation nceeds
PL
Permit Limit
R
RPD outside accepted recovery limits
Page 14 of 28

®S%DMMIT_ sun„nsn..no»n,anmr 331100Wit] 471,
ia.Sl.
ENVIHON615WALTEONNOt0OIE5, INC CayahagaFalls, Ohio 44223
AhalyriCel GabDYelarles Wit: 18030038
lFJ,:(330) 2534211 FAX.(330) 2�3-4489
Brabant: st„elcoom ]5-Marv18
Client: Synagro
Project: Granite Falls BatcLB): 31129
Sample ID 18030036-001ams SampType: ms TestCotle: temp-svoc-cpe Units: mglL Prep Data: 3/5/2018
Endrin 0.0134 0.00200 0.0100 0 134 20 157
BHC00123
10.8
30
gamma -BHC
00123
0.00200
0.0100
0
123
22
137
RunNo: 61440
ClientlD:
BatchQC
Batch ID:
31129
TestNo:
SW8081
SW3510C
Analysis Date: 3/6/2018
SegNo: 1444091
Analyte
0
127
Result
PQL
SPK value
SPK Ref Val
%REC LoseLimit HighUrnit RPD Raf Vel
%RPD RPDUmlt Qual
Sample ID 18030038-001amsd SampType: mad TestCotle: temp-svoecpe Units:
10.8
30
gamma -BHC
00123
0.00200
0.0100
0
123
22
137
Heptachlor
0.0112
0.00200
0.0100
0
112
24
121
Heptachlor epoxide
0.0127
0.00200
0.0100
0
127
27
152
Methoxychlor
God 58
0.00200
0.0100
0
158
10
199
Surr: TCMX
16.3
20.00 69.6
20.00
119
B13
10
119
Surr: DCB
12.9
20.00 67.6
20.00
119
64.2
10
119
Endrin 0.0120 0.00200 0.0100 0 120 20 157 0.0134
10.8
30
gamma -BHC
0.0107 0.00200
0.0100 0 107
22
mg/L
Prep Date: 3/5/2018
RunNo: 81440
Client ID:
BatchQC
Batch ID:
31129
Teethe :
SW8081 SW3510C
Analysis Date: 3/612018
SegNo: 1444092
Analyte
0.0113 0.00200
0.0100 0 113
Result
PQL
SPKvaluec SPKRef Val
%REC LowUmlt Highl-imit RPDRef Val
%RPD RPDUmil Qual
Page 15 of
10.8
30
gamma -BHC
0.0107 0.00200
0.0100 0 107
22
137
0.0123 14.4
30
Heptachlor
0.00992 0.00200
0.0100 0 99.2
24
121
0.0112 12.1
30
Heptachlor epoxide
0.0113 0.00200
0.0100 0 113
27
152
0.0127 11.9
30
Methoxychlor
0.0143 0.00200
0.0100 0 143
10
199
0.0158 9.76
30
Surr: TCMX
13.9
20.00 69.6
10
119
0
Sum DCB
13.5
20.00 67.6
10
119
0
Qualifiers:
'
Value exceeds Maximum Contamimntleve1.
B Analytedetected in the associated Method Blank
E
Value above quantitation range
H
Holding times for preparation or analysis exceeded
I Analyte detected below quantitation limits
M
Manuel integration used to determine
Original
MC
Value is below Minimum Compound Limit.
ND Not Detected
O
RSD is greater than RSDlimi[
P
Second column confirmation exceeds
PL Permit Limit
R
RPD outside accepted recovery limits
28

SU2"M17 33310 S»»,�n.,,n,m,e,,,alreh»,la<, QC SUMMARY REPORT
1004Win 5r.
ENVISONMENTAu TECUNOL( IE$INC Cuyahoga Falls, Ohio 44123
WOtF: 18030038
Ana/ytiod taberefoary TEL: [phone] FAX: [phone]
Webshe.'h,ro/A.um reaeknan 15 r -l8
Client: Synagro
Project: Granite Falls Batcli 31129
Sample to
Chlordane, total
Sample ID Ics31129 SampType: Ise Tes[Code: tclpsvoc-cpe Units:
ND
0.0700
Toxaphene
ND
0.0200
Endan
ND
0.00100
gamma$HC
mb31129
SampType:
mblk
TestCotle:
tclpsvoc-cpe Units: mglL
Prep Dale: 3/5/2018
RunNo:
81440
nt ID:
PBS
Balch ID:
31129
TestNo:
SWBD81 SW3510C
Analysis Dale: 3/6/2018
SegNo;
1446923
lyte
L
152
Result
PQL
SPKvalue SPKRef Val
%REC LowLimit HighLimit RPDRef Val
%RPD RPDUrn It Qual
Chlordane, total
Sample ID Ics31129 SampType: Ise Tes[Code: tclpsvoc-cpe Units:
ND
0.0700
Toxaphene
ND
0.0200
Endan
ND
0.00100
gamma$HC
ND
0.0010D
Heptachlor
ND
0.00100
Heptachlor epoxide
ND
0.00100
Methoxychlor
ND
0.00100
Surr TCMX
11.3
20.00 56.7 10 119
Surr. DCB
12.6
20.00 62.8 10 119
Endrin
0.0178 0.00100
0.0100 0 178
20
157
S
gamma -BHC
0.0159 0.00100
0.0100 0 159
22
137
mglL
Prep Dale: 315!2018
RunNo: 87440
ClienllD:
LCSS
Balch ID:
31129
TestNo:
SW8081
SW3610C
Analysis Date: 3/6/2018
SegNo: 1446924
Analyte
152
Result
PQL
SPKvalue
SPKRef Val
°AREC LowUmit HighLimlt RPDRef Val
%RPD RPDUmit Quad
Endrin
0.0178 0.00100
0.0100 0 178
20
157
S
gamma -BHC
0.0159 0.00100
0.0100 0 159
22
137
5
Heptachlor
0.0151 0.00100
0.0100 0 151
24
121
S
Heptachlor epoxide
D.0160 0.00100
0.0100 0 160
27
152
S
Methoxychlor
0.0202 0.0010D
0.0100 0 202
10
199
S
Sun: TCMX
20.5
20.00 103
10
119
Sum DCB
19,2
20.00 96.1
10
119
Qualifiers:
'
Value exceeds Maximum Contaminant Level.
B Analyte detected in the associate.] Method Blank
E
Value above quantitaticn range
H
Holdinglimes for proportion m analysis excelled
J Analyte detected below quantitation limits
M
Manuel integration used as determine
Original
MC
Value is belowtvinarra mCompound Limit
ND Not Detected
O
RSD is greater than l unit
P
Second column confirmation exceeds
PL Permit Limit
R
RPD outside accepted recovery limits
Page 16 of 28

SVMMt0 snlnnilEroomlaatar cmmlages,hm' QC SIIMMARYREP(?RT
3310 Win.Sl.
enVlRQN61ENTAL HICHNOLOOIE6, INC GryahogaPalls, Ohio 44223 WO#: 18030038
®
4naly0eal Laboratories Y=L [phone] F".(330) 2534489
Website: hrm'/Aymnv seuekeonr 15 -Mar -18
Client: Synago
Project: Grauite Falls BBtchED: 31138
Sample lD MB -31736 SampType: MBLK TestCode: HG TCLP(74 Units: mg/L PrepDae:
P Mercury
0.00437 0.00200
0.00400 0.0000700 108 75
125
0.00441 0.911 20
Sample lD
LCS�37138
SampType:
LCS
TestCotle:
HG_TCLP(74 Units: mg/L
3/5/2018
RunNo: 87362
Clientl0:
PBS
Batch to:
31138
TestNo:
SW7470A SW7470A
Analysis Date: 3/512018
Seri 1442191
Analyte
SW7470A
SW7470A
Result
PQL
SPKvalue SPKRef Val
%REC Lowl-imlt Highl-lmit RPDR&Val
%RPD RPDLimit Qual
NO 0.00200
TCLP Mercury 0.00408 0.00200 O.W400 0 102 BO 1
0.00437 0.00200
0.00400 0.0000700 108 75
125
0.00441 0.911 20
Sample lD
LCS�37138
SampType:
LCS
TestCotle:
HG_TCLP(74 Units: mg/L
Pmp Dale: 316/2018
RunNo: 81362
Client ID:
LCSS
Batch ID:
31138
Teethe:
SW7470A SW7470A
Analysis Date: 3/512018
SegNo: 1442193
Analyle
SW7470A
SW7470A
Result
PQL
SPK value SPK Ref Val
%REC LowLimlt HlghLimll RPD Ref Val
%RPD RPDLimit Qual
20
Sample lD 18021390�001AMS SampType: MS TestCode; HG_TCLP(74 Units: mglL Pre
TCLP Mercury
0.00437 0.00200
0.00400 0.0000700 108 75
125
0.00441 0.911 20
Sample ID
18021390-001AMSD
SampType:
MSD
p Dale: 3/5/2018
RunNo: 61382
Client to
BatollQC
Batch ID:
31138
TestNo:
SW7470A SW7470A
Analysis Date: 3/5/2018
SegNo: 1442195
Analyte
SW7470A
SW7470A
Result
PQL
SPK value SPK Ref Val
%REC LowLimil Highl-imft RPD Ref Val
%RPD RPDLimit oust
0.00441 0.00200 0.00400 0.0000700 108 75 125
TCLP Mercury
0.00437 0.00200
0.00400 0.0000700 108 75
125
0.00441 0.911 20
Sample ID
18021390-001AMSD
SampType:
MSD
TestCotle:
HG_TCLP(74
Units: mglL
Prep Dale: 3/5/2015
RunNo:
81362
Client 10:
BatchQC
Batch ID:
31138
TeI
SW7470A
SW7470A
Analysis Dale: 3/5/2018
eq o:
1442196
Analyte
Second column confirmation exceeds
PL Permit Limit
Result
PQL
SPKvalue SPKRef Val
%REC LowLimil Highi-imil RPDRef Vel
%RPD RPDLimit Qual
Page 17 of 28
0.00437 0.00200
0.00400 0.0000700 108 75
125
0.00441 0.911 20
Qualifiers: •
Valueexceeds Maxi mum Contaminant Level
B Analyte detected in the associated McNod Blank
R
Value above quantitation range
H
Holding times for prepamtion or analysis exceeded
I Analyte detected below quantitation limits
M
Manual Lntegrationusedtodelemline
Original
MC
Valueisbelow Minimum Compound Limit.
ND Not Dekcted
O
RSD is greater than RSDlimil
P
Second column confirmation exceeds
PL Permit Limit
R
RPD outside accepted recovery limits
Page 17 of 28

SIJMMI7 3vo w5,mnuFnna,menla/iecnnoh,a QC SUMMARY REPORT
0Whiin sl.
ENVIPONMENTRL TECHNOLOoiES, INC Cuyahoga Falls, Ohio 44223
Ahalyllcal Labamtarfes WOH: 18030038
TCL:(330) 253421/ FAY. [phone]
Website: hmnYM,wop.sCllek,epnl 15-A1nr-18
Client: Synagro
Project: Granite Falls Thatc11ID: 31138
Sample ID 18027390-o01AMSD SampType: MSD TestCode: HIS
Qnaliflcrs: ' Value exceeds Mewnum Contam(nant Level. E Malyte detected in the associated Methotl HlaNc E Value above quandtatimn anger
H Holdingtimes for preperadon or analysis exceeded 1 Mnl}le detected below quantitation limits M Manual Integration used to determine Original
MC Valueis below Mirtir�mm Compoundlimit. ND Not Detected O RSD is6 aterthan RSDiimi[
P Second column confirmation exceeds PL Permit Limit R RPD outside acceptedrecovery limits
Page 18 of 28
TCLP(74 Units: mglL
Prep Date: 3/5/2078
RunNo: 81362
ClientlD:
Batch=
Batch ID:
31138
TestNo:
SW747DA SW7470A
Analysis Date: 3/5/2018
SegNo: 1442196
Analyte
Result
PQL
SPKvalue SPKRef Val
%REG LowLimlt Highlimit RPDRef Val
%RPD RPDLimit Qual
Qnaliflcrs: ' Value exceeds Mewnum Contam(nant Level. E Malyte detected in the associated Methotl HlaNc E Value above quandtatimn anger
H Holdingtimes for preperadon or analysis exceeded 1 Mnl}le detected below quantitation limits M Manual Integration used to determine Original
MC Valueis below Mirtir�mm Compoundlimit. ND Not Detected O RSD is6 aterthan RSDiimi[
P Second column confirmation exceeds PL Permit Limit R RPD outside acceptedrecovery limits
Page 18 of 28

SUMM1� 5,mm,;r ,henrneraalTecfiaolagea,hm.
3310 w'„ sr.
ENr19CN18ENTaL TECHNOLOOIE9, INC C,Orahoga Falls, Ohio 44223
AnalyNeal tab(IMpO fol TF✓,:(330) 2534217 FAX.- [phone]
Website: Mro.//, eaek ca
Client: Synagro
Project: Granite Falls
QC SUMMARY REPORT
WQ#: 18030038
15-Marv18
Ba[ch1D: 31196
2,4-D NO
ND
1.00
0
0
2,4,5 -TP
NO
0.500
0
Sample ID
mb�31196
SampType:
mblk
TeslCotle:
tclp-sveaher
Units: mg/L
Prep Date: 3/7/2618
RunNo: 87649
Client to
PBS
Batch ID:
31196
Tes0No:
SWS161A
SWO151A
Analysis Date: 3/1212018
SegNo: 1453716
Analyte
SegNe:
1453717
Result
PQL
SPKvalue
SPK Ref Val
%REC LowUmil HighLimit RPD Ref Val
%RPD RPDLImit Qual
Sample ID Ica -3119G SampType: Ica
ND
1.00
0
0
2,4,5 -TP
NO
0.500
0
0
Surr: DOM
480
500.0
96.0 20 140
21
ND
1.00
0.500
0
81.5
62.6
125
2,4,5 -TP
ND
0.500
0.500
0
TestCode:
tclp-svoc-het
Units: mglL
Prep Date: 317/2078
RunNo:
87649
Cfientl0:
LOSS
Batch ID:
31196
TeslNo:
SW8151A
SW8151A
Analysis Date: 3/12/2018
SegNe:
1453717
Analyte
PQL
SPKvalue
Result
PQL
SPKvalue
SPKRef Val
%REC LowLimit HighLimit RPDRef Val
%RPD RPDLimit Qual
4-D
Sample ID 18030036-00tams SampType: ms TestCode: tclp-svoc-her Units:
ND
1.00
0.500
0
81.5
62.6
125
2,4,5 -TP
ND
0.500
0.500
0
83.0
52.5
126
Burn DOM
483
Client ID:
500.0
Batch ID:
96.5
20
140
2,44)
Sum DCAA
ND 1.00 0.500 0 79:0 37 105
2,4,5 -TP
Value exceedsMaximum Cortteviineni Level
H
Maly[e detected in Nre associated Method BleNc
H
Holdingtimes for preparation or analysis exce dad
1
ND
0.500
0.500
0
81.0
38
106
472
mg/L
Prep Dale: 3/7/2018
RunNo: 81649
Client ID:
BatchQC
Batch ID:
31196
To o:
SW6151A
SW8151A
Analysis Date: 311212018
eq o: 1453719
Analyte
Result
PQL
SPKvalue
SPKRef Val
%REC LowUnnit HighLimit RPDRef Val
%RPD RPDLimit Qua]
2,44)
Sum DCAA
ND 1.00 0.500 0 79:0 37 105
2,4,5 -TP
QuelJiers: • L• Value above quantitation mn6e
M Manual integration usd to dete,mine
pdginal
0 RSD is greatertban RSDlimit
R APD outside accepted recoverylimits
Page 19 of 28
Value exceedsMaximum Cortteviineni Level
H
Maly[e detected in Nre associated Method BleNc
H
Holdingtimes for preparation or analysis exce dad
1
ND
0.500
0.500
0
81.0
38
106
472
Permit Limit
500.0
94.4
20
140
QuelJiers: • L• Value above quantitation mn6e
M Manual integration usd to dete,mine
pdginal
0 RSD is greatertban RSDlimit
R APD outside accepted recoverylimits
Page 19 of 28
Value exceedsMaximum Cortteviineni Level
H
Maly[e detected in Nre associated Method BleNc
H
Holdingtimes for preparation or analysis exce dad
1
Maly[e defected belowquantiRtion limits
MC
Value is below Minimum Compoundiimit.
ND
No[Detected
P
Second column confirmation excels
PL
Permit Limit

SUMM17_ Baan,hEim;ra„aealal 3310
er,es,he. QC SUMMARY REPORT
sato w,n sr.
ENVIRONMENTAL TCBNOLOOIE9, INC CyalioKa Falls,, Ol»o 44223
WO#; 18030038
Awly"tal tobannorles TEL [phone] FAX.- [phone]
Website: him lAveAw.sevekemn ZS-rllirrvZR
Client: Synagro
Project: Granite Falls BateLID: 31196
Sample AD 78030036-0
22
ND
1D0
0.500
0
85.7
37
105
D
07amsd
SampType:
msd
TeslCotle;
tclp�wc•her Units: mglL
Prep Date: 317/2018
RunNo: 81649
Client ID:
BatchDC
Batch ID:
31196
TestNo.
SW8151A SW8151A
Analysis Date: 3/12/2018
SegNo: 1453720
Analyte
500.0
PL
Result
PDL
SPKvalue SPK Ref Val
%RED LowLimit Highl-ilnit RPD Ref Val
%RPD RPDLanit Dual
4-D
ND
1D0
0.500
0
85.7
37
105
D
0
30
2,4,5 -TP
ND
0.500
0.500
0
88.4
38
106
0.
0
30
Surr. DCM
502
P
500.0
PL
100
20
140
0
QaaliOers: '
Value exceeds Maximum Cwtamivavt Level.
B
Malyle. detected iv the associated Method Hlavk
E
Value above quantiladov mvge
H
Holdingtimes for prepernrion oranelysis exceeded
I
Mel}rte detected below quendtaaon liudts
M
Manuel lntegetibn used to deteemiue
Original
MG
Value is below Minimum Compound Limit
ND
Not Detected
O
RSD is greater than RSDlimi[
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits
Page 20 of 28

SUMMI 0
s 3310 a:»,tEmhm:,»w,talfhnh:wm;a SQC SUMMARY REPORT
331a t. s.
ENVIII(MMUNTALTECHNOLOOIE9, INC C,ryahoya Fahs Ohio 44223
Rryalylfcal Labaratofles TFL: [phone] FAX.. [phone] W O#: 18030078
Ifeletice: htm.14ww.sertekrnm 15 -Mar -18
Client: Synagro
Project: Granite Falls Batch1l): R81272
Ignitabilily 7.96 7.240 0 110 70 130
Sample 10 18021223.001ADUP SampType: DUP TeslCode: Ignitablllty_S Units: Prep Date:
Ignifabllity nor -fl
Sample ID
LCS-R81272
SampType:
LCS
TestCotle;
Ignitability_S Units:
Prep Dale:
RunNo: 81272
Client ID:
LCSS
Batch ID:
R81272
TestNo:
SW1030
Analysis Date: 312/2018
SegNo: 1439605
Analyte
SegNo:
1439611
Result
PQL
SPKvalue SPKRef Val
%REG Lowi-imit HighLimit RPDRef Val
%RPD RPDLimit Qual
Ignitabilily 7.96 7.240 0 110 70 130
Sample 10 18021223.001ADUP SampType: DUP TeslCode: Ignitablllty_S Units: Prep Date:
Ignifabllity nor -fl
Sample ID
18030033-0OtADUP
SampType:
DUP
_S Units:
Ruallo: 81272
Client ID:
BatchQC
Batch ID;
R81272
Tactile:
SW7030
Analysis Date: 3/2/2018
SegNo: 1439607
Analyte
SegNo:
1439611
Result
PQL
SPKvalue SPKRef Val
%RECLowUmit HighLimit RPDRef Val
%RPD RPDLimil Qual
ammable D 0 20
Sample l0 18021228-001ADUP SampType: DUP TeslCode: lgnitability
ability
non-flammable
0 0 20
Sample ID
18030033-0OtADUP
SampType:
DUP
_S Units:
Prep Dale:
RunNo: 81272
Client ID:
Ba1chQC
Batch ID:
R81272
TestNo:
SW1030
Analysis Date: 3/2/2018
SegNo: 1439609
Analyte
SegNo:
1439611
Result
PQL
SPKvalue SPK Ref Val
%REC Lowt-imit HighLimit RPD Ref Val
%RPD RPDLImit oust
ability
non-flammable
0 0 20
Ignitabilily non-flammable 0 0 20
Qualifiers: * Value exceeds Maximum Conlamiban[Level: H Acolyte detected in the associated Method Black E Value above quandtationrange
H Holding times for Preparation or analysis exceeded 1 Malyte det¢ted below quamitadonli:uits M Manual integration
used to determine
MC Value is below Minimum Compound Limit. ND No[Dekcted O RSD is Breaterthan RSDlimi[ Original
P Second column confirmation exceeds PL Permit Llmit R RPDoutsideacceptedrecoverylimits
Page 21 of 28
Sample ID
18030033-0OtADUP
SampType:
DUP
TeslCode:
Ignitabllity_S Units:
Prep Dale:
RunNo:
81272
ClienllD:
BatchQC
Batch ID:
R812M
TestNo:
SW1030
Analysis Date: 3122018
SegNo:
1439611
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLimit HighLimit RPDRef Val
%RPD
RPDLimlt Qual
Ignitabilily non-flammable 0 0 20
Qualifiers: * Value exceeds Maximum Conlamiban[Level: H Acolyte detected in the associated Method Black E Value above quandtationrange
H Holding times for Preparation or analysis exceeded 1 Malyte det¢ted below quamitadonli:uits M Manual integration
used to determine
MC Value is below Minimum Compound Limit. ND No[Dekcted O RSD is Breaterthan RSDlimi[ Original
P Second column confirmation exceeds PL Permit Llmit R RPDoutsideacceptedrecoverylimits
Page 21 of 28

®SUMM17 33/0WlVia /Technalag;wSI, Sl.
ENVIRONMENTAL WCHNOLOOIES, INC Gryahoga Falls, Ohio 44223
ARelytlbell,abbYaln/(es TEL: [phone] FAX.[phone]
Wehshm hap.lAnnay.seln.f.com
CBeot: Synago
Project: Groote Falls
QC SUMMARY REPORT
WO#: 18030038
15-Mnrv18
Batchto: 881272
Sample l0
18W0036-001ADUP
SampType:
DUP
Tes(Code:
Ignitability_S Units:
Prep Date:
RunNo: 812]2
Sample ID
18030033401ADUP
SampTypa:
OUP
TestCode:
Ignitabilily_S Units;
Prep Dale:
RunNo: 87272
Client ID:
Ba1chDC
Batch to:
881272
TestNo:
SW1030
Analysis Dale: 3/2/2018
SegNo: 1439611
Analyte
Result
PQL
SPKvalue SPKRef Val
%RLC LowLimil HighLimit RPDRefVal
%RPD RPDLimit Dual
Sample l0
18W0036-001ADUP
SampType:
DUP
Tes(Code:
Ignitability_S Units:
Prep Date:
RunNo: 812]2
Client ID:
BatchDC
Batch ID:
R81272
TestNo:
SW1030
Analysis Date: 3/2/2818
SegNa: 1438613
Analyte
Granite Fails WWTP
Batch ID:
Result
PDL
SPK value SPK Ref Val
%REG LowLimit HighLimit RPD Ref Val
%RPD RPDLimit Dual
Ignitability non-flammable 0 0 20
Samplell) 18030038-90
Ignilabilily norvflammable
0 0 20
Qualifiers: "
OTiginal
Page 22 of 28
Value exceeds Maximum Contaminant Level
a
Analyte detected in the associated Method Blank
L
Valuc above quantitation conga
H
lioldmgtimes for preparation or avelysis exceeded
1
1ADDP
SempType:
DUP
TestCotle:
Ignitabllily_S Units:
Prep Date:
RunNo: 87272
Client ID:
Granite Fails WWTP
Batch ID:
R81272
TestNo:
SW1030
Analysis Date: 3/212018
SegNo: 1439615
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLimil HighLimit RPDRef Val
%RPD RPDLimit Dual
Ignilabilily norvflammable
0 0 20
Qualifiers: "
OTiginal
Page 22 of 28
Value exceeds Maximum Contaminant Level
a
Analyte detected in the associated Method Blank
L
Valuc above quantitation conga
H
lioldmgtimes for preparation or avelysis exceeded
1
Analyte detected below quantitarien limits
M
Manval integradon used to dete,mine
MC
Vxlue is below Minimum Compound Limit.
ND
No[Dekcted
0
RSD is greater Nan LtBDlimit
P
Second column con8,malion exceeds
PL
Petmil Limit
X
RPD outside accepted recovery limits

❑,aaahh,Brmmer,nlTechrom0Will1. QC SUMMARY REPORT
UMM17 31CW4271.
23
ENVIRONMENTAL LabLahmseq L06196, INC 38211 FAX. Tls,Ohdo 5-4489 WORN 18939038
AhaJyllCel LpbOY�+lul7r.. TEL f330J 2538211FbY.'(330)253-{J8Y
Website: boo uAnn,,.renek oor IS-Mrrv78
Client: Synagro
Project: Granite Falls BatchID: R81628
Cyanide, Reactive
ND 0.590
times for preparation or analysis exceeded
!
MalNe detected below quantitation limits
Sample ID
MB-R8162B
SampType:
MBLK
TestCode:
Cyanitle,Rea Units; mglL
Prep Date:
RunNo: 87628
CfentlD:
PBW
Batch ID:
R81628
TestNo:
SW9014
Analysis Date: 3/8/2018
Seri 1452949
Analyte
Result
PQL
SPKvalue SPKRef Val
%REG LowUmil HighLimil RPDRef Val
%RPDRPDLimit Qual
Cyanide, Reactive
ND 0.590
Cyanide, Reactive 10.1 0.500 10.00 0 101 88 115
times for preparation or analysis exceeded
!
MalNe detected below quantitation limits
Sample lD
LCS�R81628
SampType:
LCS
TestCode:
Cyanide,Rea Units: mglL
Prep Date:
RunNo: 81628
Client ID:
LCSW
Balch ID:
R81628
TestNo:
SW9014
Analysis Date: 3/8/2018
SegNo: 1452950
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLimit HighLimil RPDRef Val
%RPD RPDLimit Qua]
Cyanide, Reactive 10.1 0.500 10.00 0 101 88 115
Title, Reactive 10.1 0.500 10.00 0 101 81.3 118
Sample ID 1893939a-001AM50 SampType; MSD TestCode: Cyanide,Rea Units:
Cyanide, Reactive
times for preparation or analysis exceeded
!
MalNe detected below quantitation limits
Sample lD
18030390-001AM5
SampType:
MB
TestCode:
Cyanlde,Rea Units: mglL
Prep Date:
RunNo: 81628
Client ID:
BatchQC
Batch ID:
R81628
TestNo:
SW9014
Analysis Date: 31812018
SegNo: 1452954
Analyte
Result
PQL
SPKvalue SPKRef Vel
%REC LowLimit HighLimil RPDRef Val
%RPD RPDLimit Qual
Title, Reactive 10.1 0.500 10.00 0 101 81.3 118
Sample ID 1893939a-001AM50 SampType; MSD TestCode: Cyanide,Rea Units:
Cyanide, Reactive
times for preparation or analysis exceeded
!
MalNe detected below quantitation limits
MC
Value is below Minimum Compound Li mit
NU
Not Detected
P
mg/L
Prep Date:
RunNo: 81628
Client ID:
BatchQC
Balch lD:
R81628
TesWo:
SW9014
Analysis Data: 3/8/2018
eq no 7462955
Analyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLimit HighLlmit RPDRef Val
%RPD RPDLIrmt Qual
987 0.500 10.00 0 98.7 81.3 118 10.13 2.57 5 W
Quaers: � Value eeds Maumum Contaminant level. B Analyte detected in Ore associated Method Hle�dc E Value above quan an8e
H Holding
M Manual ]ntcgration used to detemline
Original
O RSD is Breaterthan RSDlimit
R RPD outside accepted recovery limits
Page 23 of 28
times for preparation or analysis exceeded
!
MalNe detected below quantitation limits
MC
Value is below Minimum Compound Li mit
NU
Not Detected
P
Second column confirmation exceeds
PL
Permit Limit

WPuMMI'r3310W,b,e. Qc su1VIMARyREPoxT
33I0IYn, SY.
ENVIRONMENTAL TEC14HOLOOISSr INC Cuyohogel Fulld, Ohio 44223
Arcalynuvl LahavalaNes TEL: [phone] FAX.. [phone] WOH: 18030038
hlebsiie: hno:/hnvw.seitekcom ZS-Mrn-18
Client•. Synagro
Project: Granite Falls Batchli): R81628
Sample ID 18030390-001AMSD SampType: MSD TesiCode: Cyanide Rea
Qualifiers: ` Value exceeds Maximum Contaminant Level H Acolyte detected in the associated Method Blank E Value above quantitatipn range
H Holdivg times for prepamtiov or malysis exceeded 1 Malyte detected below guenritation limits M Manual lntegadon used to detemsine
MC Value is below Minimum Compound Limit ND No[Delected O RSD is geeterthenASDlimil Original
P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits
Page 24 of 28
Units: mg/L
Prep Date:
RunNo; 81828
Client ID:
BatchQC
Batch ID:
R81628
TestNo:
SW9014
Analysis Dale: 3/8/2018
SegNo: 1452955
Acolyte
Result
PQL
SPKvalue SPKRef Val
%REC LowLimit Highl-imit RPDRef Val
%RPD RPDLimit Qual
Qualifiers: ` Value exceeds Maximum Contaminant Level H Acolyte detected in the associated Method Blank E Value above quantitatipn range
H Holdivg times for prepamtiov or malysis exceeded 1 Malyte detected below guenritation limits M Manual lntegadon used to detemsine
MC Value is below Minimum Compound Limit ND No[Delected O RSD is geeterthenASDlimil Original
P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits
Page 24 of 28

SUMMIT snn,nrilhail,irn,n„,,nl yeehn 3331010WWire.
in Sl.
ENVIRON61ENTAL TECHNCLOOISS, INC Cvrymhoga Palls, Ohio44223
ARalyllrel lnboralorlr. TCL: [phone] FAX [phone]
Website: huvJAmern..eenek.voet
Client: Synagro
Project: Granite Falls
QC SUMMARY REPORT
WON: 18030038
15-Mnr-I8
BatcLID: R81630
Sulfide,
Semple lD
MB -R87639
SampType:
MBLK
TeslCode:
SUIBtle,React Units; mglL
Prep Dale:
RunNo: 81630
Client to
PBW
Batch to
R81630
TestNo:
SW9034
Analysis Dale: 3/8/2018
SegNo: 1453002
Analyte
Result
PQL
SPKvalue SPKRef Val
%REG LowUmit HlghLimlt RPDRaf Val
%RPD RPDLImfl Qual
ReacOve
ND 25.0
Sulfide,
Sample ID
LCS-R81830
SampType:
LC3
TeslCode:
Sulfide,React Units: mg/L
Prep Date:
RunNo: 87630
Client ID:
LCSW
Batch ID:
R91630
TestNo:
SW9034
Analysis Date: 3/8/2078
SegNo: 1453003
Analyte
Result
PQL
SPKvalue SPK Ref Val
%REG LowLimil HighLimit RPD Ref Val
%RPD RPDLimit oust
Reactive 4400 25.0 4800 0 92.9 85 115
SURide, Reactive 4310 25.0 4800 0 89.8 75 125
Sample ID
78030390-001AMS
SampType:
MS
TeslCotle:
Sulfde,React Units: mglL
Prep Dale:
RunNo: 816J0
Client ID:
BatchQC
Batch ID:
R81630
TestNo:
SW9034
Analysis Dale: 3/6/2018
SegNo: 1453005
Analyte
Result
PQL
SPKvalue SPKRef Val
%REG LowUmlt Hight-imat RPDRef Val
%RPD RPDLImit Qual
SURide, Reactive 4310 25.0 4800 0 89.8 75 125
SUHde, Reactive 4370 25.0 4800 0 91.0 75 125 4310 1.36 30 W
Qualifiers: ” Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range
13 Holding times for preparation or analysis exceeded 1 Malyte detected below queuvta5ov limits M Manuel lnmgretiov used to determine
Sample to
18030390-001AMSD
SampType:
MSD
TeslCode:
SUIFlda,React Units: mg/L
Prep Dale:
RunNo: 87630
Client 10:
eatchQC
Batch ID:
R81630
TestNo:
SW9034
Analysis pate: 3/8/2018
SegNo: 7453006
Analyte
Result
PQL
SPKvalue SPKRef Val
%REG Lowl-mit HighLimit RPDRef Val
%RPD RPDLlnut Qual
SUHde, Reactive 4370 25.0 4800 0 91.0 75 125 4310 1.36 30 W
Qualifiers: ” Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range
13 Holding times for preparation or analysis exceeded 1 Malyte detected below queuvta5ov limits M Manuel lnmgretiov used to determine
Original
MC Valve is below Mlvimum Compcund Limit.
ND
Not Detected
O
RSD is grestertM1av RSDlimi[.
P Second column confirmation exceeds
PL
Permit Limit
R
RPD nannies accepted recovery limits
Page 25 of 28

®SIJMMIt s,w„it ram»w,talTeaPo 3310 in St.
33m w...5+.
fNVIHOMMEWAL TECHNOLOGIES, INC CuyahojaFalls, Olaro 44223
ANaly0ce14flbdrslotJes TGL:(330)25}8211x/.[phone]
Website: hrro:fmm�v.seHekeonr
Client Synagro
Project: Granite Falls
QC SUMMARY REPORT
BateM1ID: R81630
WOk: ]8030038
15-Alnr-18
QuaBriere: '
Vrvlue exceeds Maximum Contaminant Level.
B
Analyte detected in the associated Mefhad Hlank
E
Valua above quantitadon range
H
Holding[imes for preparation or analysis exceeded
Sample lD
18090390-001AMSD
SampType:
MSD
TestCode:
SUlflde,React Unils: mglL
Prep Date:
RunNo: 81630
Clien ID:
Batch=
Batch to:
R81630
TestNc:
SW9034
Analysis Date: 3/8/2018
Senile: 1453006
Analyte
Second column confirmation exceeds
PL
Result
PQL
SPK value SPK Ref Val
%RFC Lowl-imit HlghLimit RPD Ref Val
%RPD RPDLimit Qual
QuaBriere: '
Vrvlue exceeds Maximum Contaminant Level.
B
Analyte detected in the associated Mefhad Hlank
E
Valua above quantitadon range
H
Holding[imes for preparation or analysis exceeded
J
Analyte detected below quandlalion limits
M
Manuel Integration used to deteemine
Original
MC
Value is below Minimum Compound limit
ND
No[Detected
O
RSD is greater than RSDlimit
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits
Page 26 of 28

1110%off"m®0 Sumnril ErnNarnrren(al Techrrolo8±es,hsc.
3310 Wirr 8l.
ENVIRnnN.mNTAI. MCNnOLOnI99, INC Ciryahoga Falls, 01dio44223
Anafy6cail Laddfalerlrs TEL: [phone] FAX: (330) 253-a 89
Website: him iii reakoo
Client: Synagro
Project: Granite Falls
QC SUMMARY REPORT
WOQ#: 18030038
IS -MOF -18
RatchED: R81742
Sample ID
PH
LCS-881742
SampType:
LES
TeslCode:
pH_S(90450( Units: s.u.�79.8°C
Prep Date:
RunNo: 81742
Client ID:
LCSS
Batch to
R81742
TestNo:
SW90ZD
Analysis Date: 3/14/2018
SeciNo: 1456032
Analyte
RunNo: 81742
Client lD:
Result
PQL
SPK value SPK Ref Val %REC
LowLlmil HighLimlt RPD Ref Val
%RPD RPDUmlt Qual
7.0
7.0 D 99.7 90 710
pH 5.3 5.3 0
H
Analyte detected in the associated Methal Hlank
E
Value above quantitation range
H Holding dmes forpreparadon or analysis exceeded
3
Malyle detected below quandmdon limits
M
Sample ID
18030038-001ADUP
SampType:
pUP
Tes(Cotle:
pH_SI9045D) Units: s.u.@21.0°C
RunNo: 81742
Prep Date:
RunNo: 81742
Client lD:
Granite Falls WWTP
Batch ID:
R81742
TestNo:
SW9045D
Analyte
Analysis Dale: 3/142018
SegNo: 1466036
Analyte
PQL
SPKvalue SPKRef Val %REC
Result
PQL
SPKvalue SPKRef Val
%REC
LowLimil HlghUmit RPDRef Val
%RPD RPDLimil Qual
.6 10
Sample ID LGS-881742 SampType: DUP TestCode; pH_5(9045D( Units: s.u.@
pH 7.0
7.0 0 101 9D 170 7.0 0.9 10
qunlifiers: • Value exce ds Maximum Contaminant Level.
H
Analyte detected in the associated Methal Hlank
E
Value above quantitation range
H Holding dmes forpreparadon or analysis exceeded
3
Malyle detected below quandmdon limits
M
Manual lmtegmdon used to determine
�Ilgln8l
MC Velue is bclowMinimum Compound Limit.
ND
Not Detected
19.8°C
Prep Date:
RunNo: 81742
Client to
BatchQC
Batch ID:
881742
TestNo:
SW90l5D
Analysis Date: 3114/2018
SegNo: 1458953
Analyte
Result
PQL
SPKvalue SPKRef Val %REC
LowUmit HighLimlt RPDRef Val
%RPD RPDLimil Qual
pH 7.0
7.0 0 101 9D 170 7.0 0.9 10
qunlifiers: • Value exce ds Maximum Contaminant Level.
H
Analyte detected in the associated Methal Hlank
E
Value above quantitation range
H Holding dmes forpreparadon or analysis exceeded
3
Malyle detected below quandmdon limits
M
Manual lmtegmdon used to determine
�Ilgln8l
MC Velue is bclowMinimum Compound Limit.
ND
Not Detected
O
RSD isb eaterthan RSDlimi[
P Second column coniinnation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits
Page 27 of 28

Sin111nit Environmental Technologies, Inc q
3310 Win Street Analysis•s Re uest/Chain of Custody
CuYahaga Falls, Ohio 44223 Tel: [phone] Fax; 330.253.4489 Far Sumindt enrlroumwial'Achnologim mn use only
Nam4 (Please Print)
Page 28 of 28
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Page 28 of 28

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Town of Granite Falls WQ Permit Number: WQ 0016247
W WTP Name: Granite Falls. W WTP NPDES Number: NC 0021890
Monitoring Period: From 01/01/18 To 12/31/2018
Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) -Please indicate level achieved and alternative performed:
Class A:
Alt. 1/A (time/temp)
Alt. 4/D (No Prior Test)
Alt. 2B (Alk Treatment) AIY. 3/C (Friar Testing)
It. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP)
If applicable to alternative performed (Class A only) indicate "Procese to Further Reduce Pathogens'":
Compost Beat Drying Heat Treatment Thermophilic.
Beta Ray Gamma Ray Pasteurization
Class B:
Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens X
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization X Air Drying Composting Aerobic Digestion
Anaerobic Digestion
TF annliwahlw 4n a14w.nativa nw.Fnrm w.l /('lace D nr
!`lace Rl wnm nlwfw 4hw fnnnwinn mnni4nrinn `Ia4a•
Parameter
Vector Att
Allowable Leve] in Sludge
Pathogen Density
No. of
Frequency
Sample
Analytical
Excee-
of
Type
Technique
Minimum Geo. Mean Maximum Units
dances
Analysis
Fecal
2x10 to the 6"
MPN
MPN/g
Coliform
power per gram
of total solids
CFU
CFU/g
1000 MPN per gram of
MPN/g
total solids (dry weight)
Salmonella
3 MPN per 4 grams total
bacteria (in
solids (dry weight)
lieu of fecal
coliform)
raction Reduction (40 CFR 503.33/15A NCAC 02T.1107)
Please indicate option/alternative performed:
Option/Alt. I Option/Alt. 2
(VS reduction) (40 -day bench)
Option/Alt. 5 Option/Alt, 6
(14 -Day Aerobic) (Allo Stabilization) X
Option/Alt. 9 Option/Alt. 10
(Injection) (Incorporation)
Option/Alt. 3 Option/Alt. 4
(30 -day bench) (Spec. 02 uptake)
Option/Alt. 7 Option/Alt. 8
(Drying—Stable) (Drying—Unstable)
No vector attraction reduction alternatives
CERTIFICATION STATEMENT (please check the appropriate statement)
were performed
"I certify, under penalty of law, that the pathogen requirements in 40 GFR 503.32/15A NCAC 02T.1106 and the vector attraction
X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
reduction requirement in 40 CFR 503.33/15A NCAC 02T, 1107 have not been met." (Please note if you check this statement attach an
explanation why you have not met one or both of the requirements,)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate the information used to determine that thepathogen and vector attraction reduction requirements have
been met. I am aware that there are significant penalties for false certification including fine and imprisonment."
Todd Larson Operations
Director
Prep d itle �tyyo.cr-pflht)
zl 14
at
Land Applier Name and Title (if applicable) (type or print)
,Z
SigneofPreparer
Signature of Land Applier (if applicable)
*Preparer is defined in 40 CFR Part 5039(r) and 15A NCAC 2T.1102 (26)
Date

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Date of Initial &2 hr:
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sample&plItest
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Agricultural Lime Application Log
Year: 2018
Project: Granite Falls
Field
(state -county -site -field)
Soil
pH
(from
Lime Requirement
soil analysis)
ITons/Acre
Applied E Eq.)
Date Applied
CD
-02-01
7.1
O.OT/Ac.
CD -02-04
7.0
O.OT/Ac.
O.OT/Ac.
O.OT/Ac.
O.OT/Ac.
*Lime will be applied when conditions improve.

NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomi/
Report No. FY79-SL003534
ovro Predictive
Client: Shane Wilson Advisor:
E Bruce
a
4649 Sawwills School Rd
Synagro
;
Soil Report Mehlieh-3
Extraction Granite Falls, NC 28630
284 Boger Rd
Mocksville, NC 27028
Sampled County: Caldwell
�. Links to Helpful Information Sampled:
06/20/2018
Received:
08/31/2018
Farm: CD -02 Completed:
09/14/2018 Client ID: 474751
Advisor ID: 475821
Agronomist's Comments:
ATTENTION: This report was flagged with a "C" and/or "Z" to alert you
that copper and/orzinc have accumulated in the soil and are approaching
a level that could be detrimental to crop
production. The C and Z symbols are printed on your report for soil lest
Zn and Cu index levels of 2000 or more for agronomic crops; for peanuts
with zinc, the level is 250. This note is
designed to be a "trig9er'that allows enough time to either reduce the
rate of application orfind another field for application of biosolids and/orwaste water. The CTL (critical toxic level) for
Cu and Zn Is set at a 3000 index; for peanuts with zinc, the level is 500.
Maintaining a pH of 6.0 or higher may reduce potential for toxicity, especially for Zn. These levels are used by
DENR as a benchmarkio determine when application of waste products
should be slapped. The CTL for copper and zincwas setio prevent levels from accumulating to the point where
they becometoxicto crops qmwn on a field.
Sample ID: 02-01
Recommendations: Lime
Nutrients(Ib/acre)
More
Crop (tons/acre)
N P2O5 K2O Mg S Mn Zn
Cu B
Information
Lime History:
1 . Fescue/OGrassfrim, M 0.0
120-200 0 10 0 0 pH$ 0
0 0
Nate' 12 Note: $
21 0.0
Test Results [units - WN in g/cm3; CEC and Na in meq/100 cm3; NOs-N in mg/dm3]: Soil Class: Mineral
HM% WN CEC BS% Ac pH P-1 K-1
Ca% Me% Sri Mn -I Mn -All Mn-Al2 Zn4 Zn -AI
Cu4 Na ESP SS -I NO3-N
0.36 0.89 19.4 98 0.5 7.1 437 71
77 19 47 81 48 860 860
1858 0.1 1
Sample 10: 02-04
Recommendations: Lime
Nutrients (Ib/acre)
More
Crop (torts/acre)
N P2O5 K20 Mg S Mn Zn
Cu B
Information
Lime History;
1 -Fescue/OGrass/rlm� M 0.0
120-200 0 30 0 0 pH$ 0
0 0
Note: 12 Note: $
Test Results [units - WN In g/cm3; CEC and Na In meq/100 cm3; NO3-N in mg/do): Sol Class: Mineral
HM% WN CEC SS% Ac pH P-1 K -I
Ca% Mg% S -I Mod Mn -All Mn-AI2 Zn -I Zn -AI
Cu -1 Na ESP SS -I NO3-N
0.46 1.05 14.6 95 0.7 7.0 172 59
69 24 40 203 124 740 740
3575 0:1 1
North
Tofiacco Trust Fund Commission
Reprogramming of iha laboratory-informaticn-management system that makes this report possible is
being funded through a grant from theNorth Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic serv
ices to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner ofAgnculture

NCDA&CS Agronomic Division Phone: [phone] Website: v .ncagr.gov/ngronami/
Report No. FY19-SL003534
Shane Wilson
Page 2 of 2
Understanding the Soil Report: explanation of measurements, abbreviations and units
Recommendations
Report Abbreviations
Lime
Ac
exchangeable acidity
If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either
B
boron
ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to B inches of soil several months before planting.
3S%
% CEG occupied by basic cations
For no-till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 fall 000 sq ft) at ora
Ca%
% CEC occupied by calcium
time, even if the report recommends more. You can apply the rest in similar increments every six months. until the full rate
CEC
cation exchange capacity
is applied. If MG is recommended and lime is needed, use dolomitric lime.
Ca-I
copper index
ESP
exchangeable sodium percent
Fertilizer
HM%
percent humic matter
Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of
K-I
potassium index
Ib/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on researchifeld studies
K20
potash
for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they
Mg %
% CEC occupied by magnesium
are not, follow the fertilizer recommendations given. If Mg is needed and no lime Is recommended, 0-0-22 (11.5% Mg) is
MIN
mineral sail class
an excellent source; 175 to 2501b per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-I levels appear
Mn
manganese
Mn-AI2
Mn-availability index for crop 1
only on reports for greenhouse soil or problem Samples.
Mn-Al2
Mn-availability index for crop 2
Mn-I
manganese index
Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $p H, C or Z
M-0
mineral-organic soil class
notations appear on the soil report, refer to $Note Secondary Nutrients and Micronutrients. In general, homeowners do not
N
nitrogen
need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit
Na
sodium
ncagrgov/agronomi/pubs.htm.
NOs-N
nitrate nitrogen
ORG
organic soil class
Recommendations for small areas, such as home lawns/gardens, are listed in units of fall 000 sq ft. If you cannot find
pH
current soil pH
the exact fertilizer grade recommended on the report, visit ncaoroov/aoronomLoboart4.hh2gMnd information that
P4
phosphorus index
may help you choose a comparable alternate. For more information, read AHomeowners Guide to Fertilizer.
P205
phosphate
S4
sulfur index
Test Results
as-[
soluble salt index
WN
weight per volume
Zn-AI
zinc availability index
The first seven values [soil class, HIM%, WN, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The
Zn-I
zinc index
remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-A11, Mn-AI21 Zn-I, Zn-AI, Cu-I, S-I, SS-I, Na, ESP, SS-I, NO3-N (not routine)
available)] indicate levels of plant nutrients or other fertility measurement. Visit ~.ncaaroov/aamnomiNyrst.htm