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WQ0004609_Residual Annual Report 2018_20190314
INITIAL REVIEW Reviewer Williams, Kendall Project Number* WQ0004609 SUBMITTAL DATED: 2/26/2019 Project Contact Information Rease provide inforrration on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other issues. ...................................................................................................................................................................................................................................................................................................................................................................................................... Name * Lisa Finnerty Email Address* Ifinnerty@synagro.com Project Information Application Type* r New r Renewal r Annual Report Permit Type * r Wastewater Irrigation r Other Wastewater • Closed -Loop Recycle r Single -Family Residence Wastewater Irrigation Is a paper copy of the application being submitted?* r Yes r Nor N/A Permit Number* WQ0004609 Permittee * Facility Name * Wayne Farms Wayne Farms Phone Number* 4434899086 r Modification (Major or Minor) • Additional Information r Other • High -Rate Infiltration r Reclaimed Water r Residuals r Other Please provide comments/notes on your current submittal below. Please attach all information required or requested for this submittal to be review here. Application Form Engineering Rans, Specifications, Calculations, Etc.) Wayne Farms NC 2018 Annual Report.pdf 12AMB Upload only 1 RDF docurrent. NLltiple documents must be corrbined into one RDF file. For nein and modif cation permit applications, the paper copy is required to be submitted to the Di, risiom Be advised, applications will not be considered complete until both the paper and electronic applications. have been received_ The paper copy shall include the follm ging: • Application Farm • All relevant attachments (talcs, soils report, specs, etc_) • 1 full-size engineering plan set • 2 11-17" engineering plan sets • 1 extras set of specifications (in addition to the set of specifications Provided in the attachments) • Fee (if required) This shall be mailed to the following address: By US_ Postal Service- Di,vision of Water Resources- Non -Discharge Branch 1617 Mail Service Center Raleigh NC 27699-1617 By Courier, -Special Delivery: Division of Water Resources- Non -Discharge Branch Nathaniel Thornburg- 9th Floor, Office #942M 512 N_ Salisbury St_ Raleigh, NC 27644 For questions or problems contact Tessa Monday at 919.7073660 or Tessa_X%nday(dncdem_gov or Sonia Graves at 919.707.3657 or Sonia Graves(dpcdenr.gov. *140 By checking this box I am acknowledging that I have read the above statement and agree to send these documents as required to one of the address given above. Signature Submission Date 2/26/2019 435 Williams Court, Suite 100 Baltimore, N'ID 21220 Nv<v-,u syn Agro. com FEBRUARY 26, 2019 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2018 Annual Report for Permit No. WQ0004609 Dear NCDEQ: SYNA,GRO Synagro is submitting one copy and one electronic copy of the above referenced report on behalf of the Wayne Farms, L.L.C.-Dobson, NC. If you have any questions or need additional information, please do not hesitate to contact Paul Nordin at (336) 386-8151 or Erik Bruce at (336) 703-8681. Sincerely, Derrick Shivar Environmental Compliance Manager Enclosures cc: Paul Nordin, Wayne Farms, L.L.C.-Dobson Erik Bruce, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD WAYNE FARMS, L.L.C. , NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0004609 2018 ANNUAL REPORT Wayne Farms, L.L.C. - Dobson, NC Residuals Land Application Program 2018 Annual Report TABLE OF CONTENTS 1. Certification Form &Annual Operations Summary 2. Annual Residual Sampling Summary Forms and SAR Calculation Pages 3. Annual Land Application Field Summary Forms 4. TCLP Analysis 5. Control of Possible Nuisance Conditions 6. Soil pH &Lime Application Records 7. Soil Analyses SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: W00004609 County Sorry Year 2018 FaciliTy Name (as shown on permit) W avne Farms NPDES No. NC0006548 Land Application Operator Synazro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip Part A, and Part B and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: 23 Total number of fields utilized for land application during the year: 4 Total amount of dry tons applied during the year for all application sites: 119.70 Total number of acres utilized for land application during the year: 62_30 Part B —Annual Compliance Statement: Facility was compliant during calendar year 2018 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water QualityX YES. NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. I. Only residuals approved for this permit were: applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and Gine was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15ANCAC 02T .1105(a) or the Pollutant Loading Rates in 15ANCAC 02T. 1105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15ANCAC 02T. I 111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediation. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: 'I certify, under penalty of law,. that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, ding the possibility of fines and imprisonment for knowing violations." �T �a 69/7 ComplexMan aQer eurattee Name and Title (type or print) Signature P Date Signature of Preparer* Date Signa e and Appl Date (if different from Permittee) (if different from emrittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15ANCAC 02T.1 102 (26) DENR FORM ACF (12/2006) 2018 ANNUAL OPERATIONS SUMMARY = LAND APPLICATION IN NC WAYNE FARMS, L.L.C., NC WAYNE FARMS LLC, NC FOOD PROCESSING LIQUID Mulm 1 ri EAR AMOUNT UNIT DRY TONS UNIT TONS April 2018 341,000.00 G 59.86 D 54.31 May 2018 5452600.00 G 59.84 D 54.25 YEARLY TOTAL 886,600.00 G 119.70 D 108.56 1!28/2079 SECTION 2 0 w L_ 0 O a m E E N 9 U N N O C N 73 m (p G � ro c (D C.0 Q O m N N O Ed N � (0 O 0. 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Zr 5;I//);3£4;a;t + ®®G -G- ik � !} /\/// / /// r /#7\) B7) }2\ §.2 §) !;, ®- 2, 44| ;3S :& IL.. .. .. ) < |r• \$7� . � �(�. \\\\\\C4 \ §WRy2§#\9 k « \ =:§\§22\ � a z _ ICK �j k LU $ \\ � « o •§//)\) \� \ \\ \ - { dm \ j \ { \_ Ld / ;` [{}\ d\ f «« \ E «!/+ ;§ . y_ � E ! > m § a 7 : ;` zr _2\#;) K)#)j �) 0 ) n u 12 12 02ELu \t C7 � Z � J a �LLI a 0 cn Cc W LLZ oQ xe z O U Z I � O T (� oa y (L m dl z IL U U) O O n ami Z w � O C O L a LL N U Q) W C7 � Z � J a �LLI a 0 cn Cc W LLZ oQ xe z O U Z I � O J W oa y (L m dl Z IL U U O n ami c w � O C L a LL C7 � Z � J a �LLI a 0 cn Cc W LLZ oQ xe z O U Z W O ow W oa y (L m dl g IL U U O n ami c V � N W N W o¢ W N ¢ Fw V < w 0) O Q :5 w U� 3 ¢ a � � 0 C7 � Z � J a �LLI a 0 cn Cc W LLZ oQ xe z O U Z W O as W oa y0 m dl g �p W m g W oa m dl g �a U U 0 a fJ N m a U N ] N � E � E N � o j �Q 0 `o ua 0 0 L � a E c ? maNi O C .: m m � � U Y U N U)N 0 Q N Cf) a � o U) m 0a o" m m n � n ami N 0a � N m N N N N 00 7 N Q O Q C � U� 3 r � � 0 U m V x aa N N F P 0 a fJ N m a U N ] N � E � E N � o j �Q 0 `o ua 0 0 L � a E c ? maNi O C .: m m � � U Y U N U)N 0 Q N Cf) a � o U) m 0a o" m n U n > 0a � aai m aai N N N 00 7 N O C G U� r � � 0 a fJ N m a U N ] N � E � E N � o j �Q 0 `o ua 0 0 L � a E c ? maNi O C .: m m � � U Y U N U)N 0 Q N Cf) a � o U) 0a o" z U 0a N N Pa 00 7 N O U� m Q U m x aa N a N W � � x Q W N Ul aca a a J Q a Z a a 'z a U a U a O �a O Z �a 2 Z J a J U w J a� Y 3 Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2061-01-FPLIQ-NC WAYNE FARMS LLC, NC FOOD PROCESSING 4/18/2018 4/1/2018.4/30/2018 0.6079 LIQUID Na mg/I = (Na mg/kg x %Solids) _ 100 = (3810 x 4.2100) _ 100 = 160.401 Ca mg/I = (Ca mg/kg x %Solids) :100 = (111000 x 4.2100) :100 = 4673.1 Mg mg/I = (mg mg/kg x %Solids) :100 = (8420 x 4.2100) :100 = 354.482 Na meq = Na mg/I - Molec.Wgt.Na = 160.401 = 23 = 6.97396 Ca meq = Ca mg/I + Molec.WgLCa = 4673.1 - 20 = 233.655 Mg meq = Mg mg/I = Molec.Wgt.Mg = 354.482 + 12 = 29.5402 SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 6.97396 + SgrRoot[0.5(233.655+29.5402)] = 0.607932 Printed: 2/11/2019 Page 1 09:01 Waypoint ANALYTICAL 5/23/2018 Synagro Central LLC/ Wayne Farm Mary Brewer 284 Boger Road Mocksville, NC, 27028 Ref: Analytical Testing Report Number: 18-135-0205 Project Description: Wayne Farms 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 °Fax 804-271-6446 www.waypointana lyti ca I. com Dear Mary Brewer: Waypoint Analytical Virginia, Inc. received samples) on 5/15/2018 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with.guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except fn full and relates only to the samples included in this report, Please do not hesitate to contact me or client services if ycu have any questions or need additional information. Sincerely, Pauric McGroary Agronomist Laboratory's liability in any claim relating tb analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Arizona AZ0629 New Jersey VA011 Pennsylvania 68-03109 Virginia 460014 Florida E873087 North Carolina 257 South Carolina 93007 x Page 1 of 9 �� • • =►G Client: Syhagro Central LLC/ Wayne Farm Project: Wayne Farms Lab Report Number: 18-135-0205 Date: 5/23/2018 7621 Whltepine Road, Richmond, VA 23237 Mein 804-743-9401 °Fax 804-271-6446 www.waypointana lyti ca Isom CASE NARRATIVE Nitrate+ Nitrite Nitrogen Method SM-4500NO3F Sample 80898 (Wayne Farms) Analyte: NO3+NO2-N QC Batch No: E84084/E84082 The MS/MSD recoveries are considered insignificant due to the level of analyte present in the parent sample relative to the spike level .RPD is based on the MS/MSD results and should be evaluated as laboratory duplicates. Metals Analysis Method SW-6010CM Sample 80897 Analyte: AI OC Batch No: L382487 MS and/or MSD spike recovery failed. Analyte concentration >25X the MOL. Dilution test within method limits. No matrix interterence is suspected. OC Batch No: L382842 MS and/or MSD spike recovery failed. Analyte concentration >25X the MOL. Dilution test within method limits. No matrix interterence is suspected. Analyte: As OC Batch No: L382487 MS/MSD Recovery failed, PDS confirmed matrix interference OC Batch No: L382842 MS and/or MSD spike recovery failed. Analyte concentration K 25X the MOL. Post Digestion Spike within method limits. No matrix interference is suspected. Analyte: Ca OC Batch No: L382487 MS/MSD Recovery failed, DT confirmed matrix interterence OC Batch No: L382842 MS/MSD Recovery failed, DT confirmed matrix interterence Analyte: Cd OC Batch No: L382487 MS/MSD Recovery failed, DT confirmed matrix interference Analyte: Cr OC Batch No: L382487 MS/MSD Recovery failed, DT confirmed matrix interference Analyte: Cu OC Batch No: L382487 Page 2 of 9 Wa ointrv® Y -ANALYTICAL MS/MSD Recovery failed, DT confimted matrix interference Analyte: Fe QC Batch No: L382487 MS/MSD Recovery failed, DT confirmed matrix interterence 7621 Whi[epine Road, Richmond, VA 23237 Main 804-743-4401 °Fax 804-271-6446 www.waypointa na lytical. com QC Batch No: L382842 MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits. No matrix interference is suspected. Analyte: K QC Batch No: L382487 MS/MSD Recovery failed, DT confirmed matrix interterence QC Batch No: L382642 MS/MSD Recovery failed, DT confirmed matrix interterence QC Batch Na: L382833 MS and/or MSD spike recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within method limits. No matrix interference is suspected. Analyte: Mg QC Batch No: L382487 MS/MSD Recovery failed, DT confirmed matrix interference QC Batch No: L382642 MS/MSD Recovery failed, DT confirmed matrix interference Analyte: Mn QC Batch No: L382487 MS/MSD Recovery failed, DT confirmed matrix interference Analyte: Mo QC Batch No: L382487 MS/MSD Recovery failed, DT confirmed matrix interterence Analyte: Na QC Batch No: L382487 MS/MSD Recovery failed, DT confirmed matrix interference QC Batch No: L382642 MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test exceeded method limits. Matrix interterence is suspected. Analyte: Ni QC Batch No: L382487 MS/MSD Recovery failed, DT confirmed matrix interference Analyte: P QC Batch No: L382487 MS/MSD Recovery failed, DT confrmed matrix interference Page 3 of 9 Waypoint ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743.9401 °Fax 804-271-6446 www.waypointa n alytica I. com QC Batch No: L382642 MS and/or MSD spike recovery failed. Analyte concentration >25X the MQL. Dilution test within method limits. No matrix interference is suspected. Analyte: Pb QC Batch No: L382487 MS/MSD Recovery failed, DT confirmed matrix interference Analyte: S QC Batch No: L382487 MS/MSD Recovery failed, DT confirmed matrix interference QC Batch No: L382842 MS/MSD Recovery failed, DT confirmed matrix interterence Analyte: Se QC Batch No: L382487 MS/MSD Recovery failed, PDS confirmed matrix interference QC Batch No: L382642 MS and/or MSD spike. recovery failed. Analyte concentration < 25X the MQL. Post Digestion Spike within method limits. No matrix interference is suspected. Analyte: Zn QC Batch No: L382487 MS/MSD Recovery failed, DT confirmed matrix interference QC Batch No: L382642 MS/MSD Recovery failed, DT confirmed matrix interference Solids Total Mercury Analysis - CVAA Method SW -7471 B Sample 60698 (Wayne Farms) Analyte: Hg QC Batch No: E64133/E64121 MS/MSD Recovery failed, PDS confirmed matrix interference Page 4 of 9 Wa oint.® Y ANALYTICAL Report Number: 18-135-0205 Client Project Description: Wayne Farms 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 °Fax 804-271-6446 ww w.wa y p o i n to n a l yti c a I. co m Sample Summary Table Lab Na Client Sample ID Matrix Date Collected Date Received Method Lab ID 60698 Wayne Farms Solids 05/09/2018 09:00 OS/15/2018 60698 Wayne Farms Solids 05/09/2018 09:00 05/15/2018 6010C WTN WTN: Waypoint Analytical - TN, Memphis, TN, Certifcation: #1354 Page 5 of 9 " E z \ §{ ; 2a[ R§& �--2oReee§eReee/}2 E}) \\\\QQQ§(§§§{Q)S( - ° ¥7!\ ,Sm .. .. .. k§!__,�,_,_,:„ !2 \\0 ==,memes6666666 66 6i ,>! �)IS §\\\\\\\\\\)\ � co ®~-§SQ©/Q2y«Qy22R \ 22§§§§§§§§§f§7 \ Cl) W 7 a �\ § ==, x � .�\ clow Lli � \ (\co 7/ _ !) f2§0 a z �S _)f$!,®=:�\p22;#« ;/\//7fklarq §�§ }§\ � §) „ _\\}\< (� q\ !, �0 0 .. .. .. $k- __= z k!! r:eem,o,e, •± �© �a E \� /j\.=\\\\\\\\\\ r ~33333333= / x§§§§)§77§ $ WA % - � � \ LL 7 g L ___-ci__ » � { - .�/ \ / \ / w ,_ / - � \ ® `^ � \\ j § _ - \ .- ) ° LLI ){t /{ \ i) #!§§ \ !* !§ rr . £t,j{/2 K]!Q\ + /) ® (w \\ ° k\) }{ Waypoint ANALYTICAL 7621 Whrtepine Road, Richmond, VA 23237 Main 804-743-9401 °Fax 804-271-6446 www.waypointa nalyti ca I. com Cooler Receipt Form Customer Number: 46499 Customer Name: Synagro Central LLC/ Wayne Farm Report Number: 18-135-0205 Shipping Method Q Fed Ex Q US Postal Q Lab Q Other: UPS Q Client Q Courier Thermometer ID: Shipping container/cooler uncompromised? � Yes Q No Number of coolers received � 1 Custody seals intact on shipping container/cooler? Q Yes Q No � Not Required Custody seals intact on sample bottles? Q Yes Q No � Not Required Chain of Custody (COC) present? t♦ Yes Q No COC agrees with sample label(s)? � Yes Q No COC properly completed � Yes Q No Samples in proper containers? � Yes Q No Sample containers intact? � Yes Q Nc Sufficient sample volume for indicated test(s)? � Yes Q No All samples received within holding time? � Yes Q No Cooler temperature in compliance? � Yes � No Cooler/Samples arrived at the laboratory on ice. Q Yes � No Samples were considered acceptable as cooling process had begun. Water -Sample containers properly preserved � Yes Q No Q N/A Water -VOA vials free of headspace Q Yes Q No � N/A Trip Blanks received with VOAs Q Yes Q No � N/A Soil VOA method 5035 —compliance criteria met (J Yes Q No � N/A � High concentration container (48 hr) � Low concentration Encore samplers (48 hr) � High concentration pre -weighed (methanol -14 d) � Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? Q Yes � No Comments: Signature: Brandi Watson Date &Time: 05/15/2018 13:38:10 Page 8 of 9 y i b U y Q � N ,�u 40 y � U o L U N O +'C-� Q � U7 'C ��, a wt.. � � � �° 3/ f J W w v Q r Z .-. U '� w C O � a OW =a � y D ❑� O � xW �i � �w a W O � � ~ a ma a 1i Z oa � Z 0 U J w a n; �~ Y W w v � w Q "� u 00 0 a H a .o n ami m m m m .� ,� ,� Q Q � 1 `� 0 Eh E E H v E= T F= i= o m m m O� O Z d �aQ Z O y0 m y � Y W w v � w Q "� u 00 0 a H a .o n ami m m m m .� ,� ,� Q Q � 1 `� 0 Eh E E H v E= T F= i= o m m m O� O W N Z O m y � �q Uy Y W w v � w Q "� u 00 0 a H a .o n ami m m m m .� ,� ,� Q Q � 1 `� 0 Eh E E H v E= T F= i= o m m m O� O m� Page 9 of 9 v a 7 m `a G E F U) z 0 F U^ � ._✓U H z J Q d w � a w N Z O m W U o d N t '� �O L N .� N ._ o� o - G U� C � D_ m� Page 9 of 9 v a 7 m `a G E F U) z 0 F U^ � ._✓U H z J Q d w � a w c N N `m a U N C m m E� � E �N � G o E n. v¢ � c 0 `o E N p O (/� a E O1 N O � z� m E v � � �U (tl w N C/J � � 'o o. � J h � 'O O mo om �� Z O U o d N '� �O O 7 � U� \ U m d x a N °� w � _ W � y y Q } Q:n Z a Q Z � ' U V c m� O z 0 z x N� J J w as e 3 u�- c N N `m a U N C m m E� � E �N � G o E n. v¢ � c 0 `o E N p O (/� a E O1 N O � z� m E v � � �U (tl w N C/J � � 'o o. � J h � 'O O mo om �� Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2061-01-FPLIQ-NC WAYNE FARMS LLC, NC FOOD PROCESSING 5/9/2018 5/1/2018.6/30/2018 0.2395 LIQUID Na mg/I = (Na mg/kg x %Solids) + 100 = (1700 x 2.6300) + 100 = 44.71 Ca mg/I = (Ca mg/kg x %Solids) + 100 = (87000 x 2.6300) + 100 = 2288.1 Mg mg/I = (mg mg/kg x %Solids) + 100 = (7940 x 2.6300) = 100 = 208.822 Na meq = Na mg/I + Molec. Wgt.Na = 44.71 : 23 = 1.94391 Ca meq = Ca mg/I + Molec.Wgt.Ca = 2288.1 = 20 = 114.405 Mg meq = Mg mg/I = Molec.Wgt.Mg = 208.822 _ 12 = 17.4018 SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 1.94391 = SgrRoot[0.5(114.405+17.4018)] = 0.239454 Printed: 2/11/2019 Page 1 09:02 SECTION 3 k P Q a R O O Q N A U k Q R O O N U h h N 0 0 ch zdg z NN R 0 x b q 5 o V U 0.A. N cV U P4 R 0. 0 q b o O a 6 z'�❑ 6R q z qq� 0. a a R R z U U F � G F vi � 77 � O C 6 U '« 7 C b �a 79 N N N ❑ _ v Sa`w o d Z Q o Q ti U Q � W W � o � Q H W o ti d N vNi 00 � 03 N � �o k R N N N ch z 0 x b q 5 o V U 0.A. � U P4 U b o O a 6 z'�❑ 6R q qq� 0. a a U U � G F vi � 77 O 6 U k N ch oa b q 5 o c U � P4 O a z'�❑ 6R q qq� 0. a k ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Wayne Farms, LLC, NC Total Dry Tons Applied (Annual): 14:96 Permit #: W00004609 Cafion Exchange Capacity (won 503 only): 12 Operator: Acres Used: Walter Johnson Owner: Walter Johnson Predominant Soil Series: ✓Voolwine-Fairview 9.9 Acres Permitted: 9.9 Site #: NC SU 00013 Field #: SU 00013 0005 Residual Analysis Data (I3eavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #gip Sample. OT Com- posite Date 1 5/9/18 2 3 4 5 6 7 S 9 10 11 12 Solids 2.63 8 9 10 11 12 Arsenic 1.79 Cadmium 0.327 y Copper 220 Chromi 11.3 C Lead 4:5 Mercury 0.4 �' Molyb- denum 6.34 Nickel 10.5 Selenium 3.14 0.000 0.000 0.000 0.000 0.000 Zinc 536 0.000 0.000 0.000 0.000 0.000 0.005 Total Phos- horus 13300 0.000 0.000 0.000 0.000 0.000 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 10 11 12 y DTIAC./ C App �' Event 1.51 Arsenic 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Cadmium 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Copper 0.665 0.000 0.000 0:000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.665 Chromi 0.034 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.034 Lead 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Molyb- 0.019 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.019 denum Nickel 0.032 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.032 Selenium 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.009 Zinc 1.620 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.620 Total Phos- 40.193 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 40.193 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". �v _ � ^� Signature of Lan pplier Z Z1 Dat DENR FORM MFLSF (12/2006) N a m ti a a kn N� a N m ti a kn N� N O O 0 0 0 0 N z U x N � o U w a W A a C R Q 4 a U E Q R N cJ N cV N z� � U a ti C C � O � v N N C ao oaoo >YH N N N N V v F F m o N 4 0 QI Q F N d' •.T N N N [V � U C7 c7 � c7 c7 c7 O V' O N b M N ti Q 4 4 v. h r" Q N a kn N� N 0 N z U x N � o U w a W A a C R Q 4 a U E Q R ti � U a ti C � O � N kn U N � o U a W A a C R 4 a U E Q R N ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be snbmitted in Annnal Report Facility Name: Wayne Farms, LLC, NC Total Dry Tons Applied (Annual): 62..84 Permit #: W00004609 Operator: Walter Johnson Owner: Acres Used: 30.4 Acres Permitted: Cation Exchange Capacity (non 503 only): Walter Johnson 30.4 Site #: Predominant Soil Series: NC SU 00013 Field #: Braddock 5U 00013 0006 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #): Sample or Com- posite Date 1 5/9/18 2 4/18/18 3 4 5 6 7 8 9 10 11 12 Solids 2.63 4.21 9 10 11 12 Arsenic 1.79 3 Cadmium 0.327 2 H Copper 220 325 Chromi 11.3 18.1 M Lead 4.5 5.46 Mercury 0.4 0.4 °' Molyb- denum 6.34 5.6 1.04 Nickel 10.5 14.5 Selenium 3.14 5 0.006 0.000 0.000 0.000 0.000 Zinc 536 813 0.000 0.000 0.000 0.000 0.010 Total Phos- horns 13300 12500 0.004 0.000 0.000 0.000 0.000 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 10 11 12 H DT/Ac./ M App °' Event 1.03 1.04 Arsenic 0.004 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Cadmium 0.001 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Copper 0.452 0.675 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.127 Chromi 0.023 0.038 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.061 Lead 0.009 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.021 Mercury 0.001 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- 0.013 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.025 denum Nickel 0.022 0.030 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.052 Selenium 0.006 0.010 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.017 Zinc 1.102 1.688 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.790 Total Phos- 27.345 25.950 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 53.295 horns "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". L Zt Signature of Lan pplier Dat DENR FORM MFLSF (12/2006) m a O a d a U o a Q 4 w ci V doH N A O O d a U o a Q 4 w ci V doH N O �33 U o Q R' z w Q R a O oF D a Q 4 Q ci N N O z 00 Q co R o 5'. o x o U N N � U oF D a Q 4 Q N N O z 00 co U 5'. o x R G N N � U 0. E� U n R R R a J] N N N N z� v U n A � = E U C z m ti .v a n a v a i C ' o Q'y V V V V V 0 0 0 0 0 h nUq ANw o0 F o e a N N z 0 5'. o x R N N � U U U a v U n A � = E U Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Wayne Farms, LLC, NC Total Dry Tons Applied (Annual): 33.19 Permit #: W00004609 Cation Exchange Capacity (non 503 only): Operator: Walter Johnson Owner: Walter Johnson Predominant Soil Series: Clifford Acres Used: 18.5 Acres Permitted: 18.5 Site #: NC SU 00013 Field #: SU 00013 0007 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #): Sample or Com- posite Date 1 5/9/18 2 4/18/18 3 4 5 6 7 8 9 10 11 12 Solids 2.63 4.21 9 10 11 12 Arsenic 1.79 3 Cadmium 0.327 2 c Copper 220 325 Chromi 11.3 18.1 �' Lead 4.5 5.46 1.06 Mercury 0.4 0.4 Molyb- denum 6.34 5.6 0.006 0.000 0.000 0.000 0.000 Nickel 10.5 14.5 0.000 0.000 0.000 0.000 0:009 Selenium 3.14 5 0.004 0.000 0.000 0.000 0.000 Zinc 536 813 0.000 0.000 0.000 0.000 0.005 Total Phos- horns 13300 12500 0.689 0.000 0.000 0.000 0.000 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 S 9 10 11 12 DT/Ac./ c App �' Event 0.74 1.06 Arsenic 0.003 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0:009 Cadmium 0.000 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Copper 0.323 0.689 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.012 Chromi 0.017 0.038 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.055 Lead 0.007 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 Mercury 0.001 0.00] 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Molyb- 0.009 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.021 denum Nickel 0.015 0.031 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.046 Selenium 0.005 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.015 Zinc 0.788 1.724 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.511 Total Phos- 19.551 26.500 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 46.051 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z1 \ Signature of an Applier Dat DENR FORM MFLSF (12/2006) `J i U a a z U � 4 U a a c w kj o F a 0. Z �33 a U z U � 4 U a a c w kj o F 0. 0. Z �33 N N 0 0 O U w w 4wo 4 U a o o o 0. 0. Z N N O U w w U N U x � F y r�i 3 � U A z � � W u � wU v O vwFi a 4 � o N 0. 0. 0 N N V U w U N U x N r�i C A U a fi U v a U � N N z� a � n "Inc IIIM � ca c d E d�z oe U� o. 0. A a � a F � a � U � C « � o a+ Qo$ � no v v o Sao z o 0 o � w w � � 3 as caF4 o V R a > 0 0 o V 4 ~ C7 C7 CJ `7, H 3 o oIn a a � v v d' Ca 4 � o N 0 N N z N U x N r�i C A U a fi U a U b c U a � n "Inc IIIM � ca U� A a � a F � a � U N U N r�i C U fi a c a � n na � ca ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding, Field Loading Summary Form to be submitted in Annual Report Facility Name: Wayne Farms, LLC, NC Total Dry Tons Applied (Annual): Permit #: W00004609 Cation Exchange Capacity (non 503 only): Operator: Walter Johnson Owner: Walter Johnson Predominant Soil Series: Acres Used: 3.5 Acres Permitted: 3.5 Site #: NG SU 00013 Field #: 8.7I Clifford SU 00013 0008 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #): Sample or Com- posite Date 1 4/18/18 2 3 4 5 6 7 8 9 10 11 12 Solids 4.21 8 9 10 11 12 Arsenic 3 Cadmium 2 c Copper 325 Chromi 18.1 Lead 5.46 Mercury 0.4 iil Molyb- denum 5.6 Nickel 14.5 Selenium 5 0.000 0.000 0.000 0.000 0.000 Zinc 813 0.000 0.000 0.000 0.000 0.000 0.015 Total Phos- horus 12500 0.000 0.000 0.000 0.000 0.000 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 10 11 12 c DT/Ac./ App iil Event. 2.49 Arsenic 0.015 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.015 Cadmium 0.010 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Copper 1.617 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.617 Chromiu 0.090 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.090 Lead 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- 0.028 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.028 denum Nickel 0.072 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.072 Selenium 0.025 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.025 Zinc 4.045 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4.045 Total Phos- 62.200 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 62.200 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of £rues and imprisonment for knowing violations". �_ Signature of Land Applier Z, 1.,1 D to DENR FORM MFLSF (12/2006) SECTION 4 SUMMIT Sunvnil Environmental Technologies, Inc. TI3310 win St. FNIVIRONMENTAL IECHNOLMES, INC Cuyahoga Falls, Ohio 44223 Ana?VHcai LahoraloNeS TEL: (330) 253-8211 FAX: (330) 253-4489 Website: htty.lAvivm.settek.eom March 22, 2016 Nate Roth Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Wayne Farms Dear Nate Roth: Order No.: 16030471 Summit Environmental Technologies, Inc, received 1 samples) on 3/8/2016 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data. is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Bachar Najm Project Manager 3310 Win St, Cuyahoga Falls, Ohio 44223 Alabama 41600, Arkansas 68-0735, California 07256CA, Coloredv, Connecticut PH -0105, De]aware, Florida NELAC E87688, Georgia E87688'and 943, IAaho OH00923, Illin ois 200061 and Reg.S, Indiana C -OH -13, Kansas P.-10347, KenNcky (Undergromd Storage Tank) 3, KenNcky 90146, Loiusiana 04061 and LAI2004, Maine 2012015, Maryland 339, Massachusetts M-OPH923, Minnesota 409711, Movtava CERT0099, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, Ohio Drinking Water 4170, Ohio VAP CL0052, Oklahoma 9940, Oregon OH2O0001, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-11-5, Region 8 8TMS-L, USDAIAPHIS P330-11-00244, Utah OH00923201I-1., Vcannot VT -87688, Virginia 00440 and 1581, Washington C891, West Virginia 248 aid 9957C and E87688, Wisconsin 399013010 Page 1 of 25 SUMMIT Su°,mm it Environmental Technologies, Gtc.ffl 3310 Win St. Case Narrative MIRONMENTAL 1ECtlt10LQG:E51 iNC. Cuyahoga Falls, Ohio 44223 WO#: 16030471 AnafV0ca/ Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: h1tp:1Avunv.se11ek.com Date: 3/22/2016 CLIENT: Synagro Project: Wayne Farms This report in its entirety consists of the documents listed below. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Paginated Report including Cover Letter, Case Narrative, Analytical Results, Applicable Quality Control Summary Reports, and copies of the Chain of Custody Documents are supplied with this sample set. Concentrations reported with a J -Flag in the Qualifier Field are values below the Limit of Quantitation (LOQ) but greater than the established Method Detection Limit (MDL). Method numbers, unless specified as SM (Standard Methods) or ASTM, are EPA methods. Estimated uncertainty values are available upon request: Analysis performed by DBM, VRM, or SFG were performed at Summit Labs 2704 Eatonton Highway Haddock, GA 31033 All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. The information contained in this analytical report is the sole propert y of Summit Environmental Technologies, Inc.. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. This report is believed to meet all of the requirements of NELAC or the accrediting /certifying agency. Any comments or problems with the analytical events associated with this report are noted below. Analytical Comments for svoc-BNA_TCLP(8270), Sample 1603047 1 -00 lAMSD, Batch ID 19319 : The TCLP SVOC MS and MSD (Batch 19319) exhibited high RPD for Pyridine; The MS and MSD Original Page 2 of 25 SUMMIT saaaa;rEnvironmental TeahaoioWin t. Case Narrative 33100win sr. rNVIHONNIENTAL 1ECHNOLOOIES, INC.- Cuyahoga Fal/s, Ohio 44223 WO#: 16030471 Analytical Labowarles TEL: (330) 253-8211 FAX: (330) 253-1489 Website: huxlAvm,v.settekeom Date: 3/22/2016 CLIENT: Synagro Project: Wayne Farms exhibited recoveries within Acceptance Limits. Analytical Comments for svoc-BNA_TCLP(8270), Sample 16030471-OOIAMSD, Batch ID 19319: The TCLP SVOC MS and MSD (Batch 19319) exhibited high RPD for Pyridine; The MS and MSD exhibited recoveries within Acceptance Limits. Analytical Comments for TCLP-SVOC-Herb_S(8321), Sample LCSD-R51212, Batch ID R51212: The TCLP Herbicides LCSD (Batch 51212) exhibited marginally high recovery for 2,4-D; All samples were ND. Original Page 3 of25 U 'T Sunnnit Environmental Technologies, In Qualifiers and Acronyms IS3310 Win 8 MIRONPAENTAL TECHNOLOGIES, INC Calwhogo Falls, Ohio 442; AVO#: 16030471 _ AnaPytiraf Labwalurles TEL: (330) 253-8211 FAX. (330) 25344b Website: hawlA+viv.settek.eo Date: 3/2212016 These commonly used Qualifiers and Acronyms may or may not be present ht this report Quali£ers U The compound was analyzedfor but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. A The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. * The. result exceeds the Regulatory Limit or Maximum Contamination Limit. m Manual integration was used to determine the area response. N The result is presumptive based on aMass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GUMS. X The result was not confirmed when GUMS Analysis was performed. B/MB+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low (-) or high (+), R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low (-) or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low (-) or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. QV -I+ The ICV recovery failed low (-) or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for RE additional information Acronyms ND This Bst of Qualifi Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different WoCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICD Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively) Identified Compound CCB Continuing Calibration Blank RT Retention Time RLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor ers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Original Page 4 of 25 TS�� � � Summit Environmental Technologies, Inc. U33/0 win St. MVIRONMENTAL IECtINGLOGIES, INC. Cuyahoga Falls, Ohio 44223 Analytical tahprafonas TEL: (330) 253-8211 FAX: (330) 253-4489 Website: haw1ltinw.settek.eom Workorder Sample Summary WO#: 16030471 22-Mnr-16 CLIENT: Synagro Project: Wayne Farms Lab SampleID Client Sample ID Tag No Date Collected Date Received Matrix 16030471-001 Wayne Fames 3/7/2016 10:00:00 AM 3/8/2016 10:10:00 AM Sludge Page 5 of 25 SUAV11111AT sumunit Environmental Technomgies,e.ffJ Analytical Report 3310 Win St. FN\9RONh1ENTAL IECHNOLOGlest iNC_ Cuyahoga Falls, Ohio 44223 (base report) Analytical Labaratorles TEL: (330) 253-8211 FAX: (330) 253-4489 Wo#: 16030471 Website: htto://www.settek.co'" Date Reported: 3/22/2016 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 3/7/201610:00:00 AM Lab ID: 16030471-OOIA Project: Wayne Farms Client Sample ID Wayne Farms Analyses Result RL Qual Units DF Date Analyzed RCI SW9045D Analyst: DHC PH (SW9045D) pH 12.4 s.u.@21.00 1 3/1.512016 12:20:00 PM Qualifiers. Valnc exceeds Maximum Contwvnwt Level. E Velne above gneatitaeien rwge H holding times. Porprepmation or walysis exceeded M Manuel lntegmtion usedro determine area renponse MC Value is below Minimum Compnwd Limit N Tentatively identified compowds ND Not Detected al the Repormmg Limit O RSD is greater than RSDlimit P Second column companion exceeds PL Permit Limit Original R RPD outside accepted recovery limits lit Reporting Detection Limit U Maarten with Calcval<NUS, .r Analyte detected below quanfitation limits Page 6 o 25 Summ6Em7ronmental Technologies, Inc. S U MM 1 N 3310 Win St. fNVIRONMENTAL 7ECHNOLOCIES, tNe Cuyahoga Falls, Ohio 44223 AnatyNcal Laboratories TEL: (330) 253-8211 FAX. (330) 253-4489 Website: hrtv.,Ngvw.settek.com WO#: 16030471 Date Reported: 3/22/2016 Company: Synagro Address: 284 Boger Rd. Mocksville NC 27028 VOC by GC/MS Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Received: 3/8/2016 DF RegLvl Run Analyst Wayne Farms 001 3/7/2016 1,1-Dichloroethene 0.100 ND mg/L Project#: Wayne Farms 1 0.700 3/16/2016 MES Wayne Farms 001 TCLP Metals Analysis (6010) 0.100 ND mg/L Sludge EPA 8260 B 1 Client ID# Lab ID# Collected Analyte Rep Lou Result Units Matrix Method DF RegLvl Run Analyst Wayne Farms 001 3/7/2016 TCLP Arsenic(As) 0.500 ND mg/L Sludge EPA 6010C 1 5.00 3/15/2016 WK Wayne Farms 001 3/7/2016 TCLP Banum(Ba) 5.00 ND mg/L Sludge EPA 6010 C. 1 100 3/15/2016 WK Wayne Farms 001 3/7/2016 TCLP Cadmium(Cd) 0.100 ND mg/L Sludge EPA 6010 C 1 1.00 3/15/2016 WK Wayne Farms 001 3/7/2016 TCLP Chromium(Cr) 0.200 ND mg/L Sludge EPA 6010 C 1 5.00 3/15/2016 WK Wayne Farms 001 3/7/2016 TCLP Lead(Pb) 0.500 ND mg/L Sludge EPA 6010 C 1 5.00 3/15/2016 WK Wayne Farms 001 3/7/2016 TCLP Selenium(Se) 0.500 ND mg/L Sludge EPA 6010 C 1 1.00 3/15/2016 WK Wayne Farms 001 3/7/2016 TCLP Silver(Ag) 0.500 ND mg/L Sludge EPA 6010 C 1 5.00 3/15/2016 WK 0.200 3/16/2016 MES TCLP Mercury Analysis (1311/7470) Client ID# Lab ID# Collected Analyte Rep Unit Result Units Matrix Method DF RegLvl Run Analyst Wayne Farms 001 3/7/2016 TCLP Mercury 0.00200 ND mg/L Sludge EPA 7470 A 1 0.200 3/15/2016 ALJ SVOC SW -846: 8081-TCLP Pesticides Client ID# Lab ID# Collected Analyte Rep Lint Result Units Matrix Method DF RegLvl Run Analyst Wayne Farms 001 3/7/2016 Chlordane, total 0.0250 ND mg/L Sludge EPA 8081 B 1 0.0300 3/17/2016 JBN Wayne Farms 001 3/7/2016 Toxaphene 0.0500 ND mg/L Sludge EPA 8081 B 1 0.500 3/17/2016 JBN Wayne Farms 001 3/7/2016 Endrin 0.00250 ND mg/L Sludge EPA 80818 1 0.0200 3/17/2016 JBN Wayne Farms 001 3/7/2016 gamma -BHC 0.00250 ND mg/L Sludge EPA 80818 1 0.400 3/17/2016 JBN Wayne Farms 001 3/7/2016 Heptachlor 0.00250 ND mg/L Sludge EPA 80818 1 0.00800 3/17/2016 JBN Wayne Farms 001 3/7/2016 Heptachlor epoxide 0.00250 ND mg/L Sludge EPA 8081B 1 0.00800 3/17/2016 JBN Wayne Farms 001 3/7/2016 Methoxychlor 0.00250 ND mg/L Sludge EPA 8081 B 1 10.0 3/17/2016 JBN VOC by GC/MS Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Wayne Farms 001 3/7/2016 1,1-Dichloroethene 0.100 ND mg/L Sludge EPA 8260 B 1 0.700 3/16/2016 MES Wayne Farms 001 3/7/2016 1,2-Dichloroethane 0.100 ND mg/L Sludge EPA 8260 B 1 0.500 3/16/2016 MES Wayne Farms 001 3/7/2016 MEK 2.00 ND mg/L Sludge EPA 8260 B 1 200 3/16/2016 MES Wayne Farms 001 3/7/2016 Benzene 0.100 ND mg/L Sludge EPA 8260 B 1 0.500 3/16/2016 MES Wayne Farms 001 3/7/2016 Carbon tetrachloride 0.100 ND mg/L Sludge EPA 8260 B 1 0.500 3/16/2016 MES Wayne Farms 001 3/7/2016 Chlorobenzene 0.100 ND mg/L Sludge EPA 8260 B 1 100 3/16/2016 MES Wayne Farms 001 3/7/2016 Chloroform 0.100 ND mg/L Sludge EPA 8260 B 1 6.00 3/16/2016 MES Wayne Farms 001 3/7/2016 Tetrachlaroethene 0.100 ND mg/L Sludge EPA 8260 B 1 0.700 3/16/2016 MES Wayne Farms 001 3/7/2016 Trichloroethene 0.100 ND mg/L Sludge EPA 8260 B 1 0.500 3/16/2016 MES Wayne Farms 001 3/7/2016 Vinyl chloride 0.200 ND mg/L Sludge EPA 8260 B 1 0.200 3/16/2016 MES Page 7 of 25 ���. Summit Env/ronmenfal Technologies, Inc. WO#: 16030471 MM 3310 Win St FTWIRONMENTAL I ECHNOLOGIEs, INC Cuyahoga Falls, Ohio 44223 Date Reported: 3/22/2016 Analytical Labcoatunes TEL: (330) 253-8211 FAX: (330) 253-4489 Company: Synagro Website: htto://wmw.settekcon Address: 284 Boger Rd. Mocksville NC 27028 Received: 3/8/2016 Project#: Wayne Farms SVOC 8270 TCLP BNA List Client H)# Lab ID# Collected Analyte. Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Wayne Farms 001 3/7/2016 1,4 -Dichlorobenzene 0.200 NO mg/L Sludge EPA 8270 C 2 7.50 3/16/2016 CxA Wayne Farms 001 3/7/2016 2,4,5 -Trichlorophenol 0.500 NO mg/L Sludge EPA 8270 C 2 400 3/16/2016 CxA Wayne Farms 001 3/7/2016 2,4,6 -Trichlorophenol 0.500 NO mg/L Sludge EPA 8270 C 2 2.00 3/16/2016 CxA Wayne Farms 001 3/7/2016 2,4-Dinitrotoluene 0.200 NO mg/L Sludge EPA 8270 C 2 0.130 3/16/2016 CxA Wayne Farms 001 3/7/2016 Cresols, Total 10.0 NO mg/L Sludge EPA 8270 C 2 200 3/16/2016 CxA. Wayne Farms 001 3/7/2016 Hexachloro-1,3- 0.200 NO mg/L Sludge EPA 8270 C 2 0.500 3/16/2016 CxA butadiene Wayne Farms 001 3/7/2016 Hexachlorobenzene 0.200 NO mghL Sludge EPA 8270 C 2 0.130 3/16/2016 CxA Wayne Farms 001 3/7/2016 Hexachloroethane 0.200 NO mg/L Sludge EPA 8270 C 2 3.00 3/16/2016 CxA Wayne Farms 001 3[7/2016 Nitrobenzene 0.200 NO mg/L Sludge EPA 8270 C 2 2.00 3/16/2016 CxA Wayne Farms 001 3/7/2016 Pentachlorophenol 0.500 NO mg/L Sludge EPA 8270 C 2 100 3/16/2016 CxA Wayne Farms 001 3/7/2016 Pyridine 0.500 NO mg/L Sludge EPA 8270 C 2 5.00 3/16/2016 CxA 5VOC SW -846:8321 Herbicides-TCLP Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Wayne Farms 001 3/7/2016 294-D 5.00 NO mg/L Sludge EPA 8321A 1 10.0 3/18/2016 BJH Wayne Farms 001 3/7/2016 21415 -TP 0.500 NO mg/L Sludge EPA 8321 A 1 1.00 3/18/2016 BJH Page 8 of 25 NUMMITSummit Environmental Technologies, Inc.ffJ 3310 Win St. Analytical Report FrlirlRO N h1 EMI' AL! ECHMO LOG I E S, 1NG. Cuyahoga Falls, Ohio 44223 (consolidated) Analytical Laborisionee TEL: (330) 253-8211 FAX., (330) 253-4489 WO#: 16030471 Wehsite: hito://wiviv.settekeom Date Reported: 3/22/2016 CLIENT: Synagro Collection Date: 3/7/2016 10:00:00 AM Project: Wayne Farms Lab ID: 16030471-001 Matrix: SLUDGE Client Sample ID Wayne Farms Analyses Result RL Qnal Units DF Date Analyzed RCI Folding times forpreparation or analysisexcelled SW1010 Manual inteKmtion used to determine area response Analyst: TAH FLASHPOINT DETERMINATION (1010) Valne is below Minimum CompnwdLimit. N Tentarively identified compowds Flashpoint(140nF) >140 OF 1 3/9/20169:52:00 AM RCI Second column collimation exceeds SW9014 Permit Linul Analyst: MS REACTIVE CYANIDE (9014/7.3.3.2) RPD outside accepted recovery limits RL Reporting Detection Limit Cyanide, Reactive ND 0.500 mg/Kg 1 3/11/2016 2:33:00 PM RCI SW9034 Analyst: MS REACTIVE SULFIDE (9034) Sulfide, Reactive ND 25.0 mg/Kg 1 3/11/2016 2:33:00 PM Qllauiler5. Valuc exceeds Maximum Contaminant Level. E Value above quanM1feM1on range F Folding times forpreparation or analysisexcelled M Manual inteKmtion used to determine area response MC Valne is below Minimum CompnwdLimit. 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U 3 a .1 K a E r��� uJ r r r W P N N N o N y m lo[J L c � o C a � 0 r o 0 � 0 n o E m 0 0 o 0 0 0 N Q � 3 z E IL V N W O P.' 3 .1 � N N zp E m a z a q U Q K a E r��� uJ r r r W P N N d ryNry N N N n w C o D N N t 0 N iE co --E V E O E C O N O o A v �- N Cl N U :2 =_= d d N N o N h o lo[J o� o o C 0 0 r o 0 0 0 0 o 0 0 0 0 o 0 N d ryNry N N N n w C o D N N t 0 N iE co --E V E O E C O N O o A v �- N Cl N U :2 =_= d d v � m Z C 0 Z r o 0 o 0 0 0 0 o 0 0 0 0 N d ryNry N N N n w C o D N N t 0 N iE co --E V E O E C O N O o A v �- N Cl N U :2 =_= d d v � C 0 v A o � v � 3 z > a °d W O P.' v � C � 3 z .1 zp z a O M M M M m M M M M M M o r co m L6 q O O o o.0 0 0 0 0 � r � d 0 N � V W N N b � o N � o W i� r OMi h W OOi N (^O V O O o o.0 0 0 0 0 N N O O C N N L y N — OL N L N O Q O _ _ N O O 0 N VF7 � r � d 0 N � V W N N O O C N N L y N — OL N L N O Q O _ _ N O O 0 N VF7 � r N O � N � N N b � o N � o u a O a 0 0 0 O O O N N O O C N N L y N — OL N L N O Q O _ _ N O O 0 N VF7 � r N ❑ � N � ❑ b � o oQ � o u a a T N N O O C N N L y N — OL N L N O Q O _ _ N O O 0 N VF7 :J 8 w b � o oQ � o u a a T o � Q pQ, :J w � o u a a T o � b :J % a T � � 7 x � a :J � 5% \\\ )! § \\\ ){ 46 (`)[ !$i ))[) \� ( / \\ \ w0 )\Q \}\ »!mm �\\ \\\\ \\ 3324 § \\\ ){ 46 (`)[ !$i ))[) \� }\){ \\ \ w0 )\Q \}\ »!mm \\\\ § \\\ ){ (`)[ !$i ))[) \� }\){ § \\\ ){ (`)[ !$i ))[) }\){ \\ \ § # \\\ ){ (`)[ !$i ))[) }\){ )\Q \}\ »!mm # ){ !$i \k\ )\Q \}\ \\\\ \\ 3324 \ )\Q )� \\ /\\§ )\\) \ � B ■ b ) )! }\� ) }\� )) /\ «y! \� ) ) \\\ \ }))\ \{\ \)»! 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V M � 0 N N o �- o� W Omi � Omi m W O r 0 0 0 0 0 0 0 o a 0 0 0 0 0 o a o N O o 0 0 0 0 0 0 0 O N 0 0 0 0 0 0 0 m m m m r M N N Z O Z O M V N M V Z M V � M V M � 0 N 0 �- o� W Omi � Omi m W O r 0 0 0 0 0 0 0 o a 0 0 0 0 0 o a o N O o 0 0 0 0 0 0 0 O N 0 0 0 0 0 0 0 N N N N N N N m N r o rn o w m 0 0 0 0 0 m m� m m r M N N Z O Z O M V N M V Z r O O o 0 0 L 0 o 0 o 0 0 0 0 o N N N N N N N m N r o rn o w m 0 0 0 0 0 m m� m m r M N N Z O O O M V N M V M r O O o 0 0 L 0 0 0 0 `m m o a c E - - o W " O Y H a `o `o r >. .= N W E .. m U U U F- F - .- N N N N N N N m N r o rn o w m 0 0 0 0 0 m m� m m r M N N Z O O O M V N M N r o rn o w m 0 0 0 0 0 m m� m m r M N N Z O O O M V N M V M r O o ' � ' c " rn m m� m m r M N N Z O O O M V N M V M r rn m m� m m r M N N Z O O O M V N M V M r 0 L rLU € c m U U U VY N pq O Q N QI 0 r m a co 0 N N Z O O O N N _ 0 L rLU € c m U U U VY N pq O Q N QI 0 00 0 00 0 0 N N Z O O O N N _ O O o 0 0 L 0 0 0 0 L rLU € c m U U U VY N pq O Q N QI m O m N .- v N N Z O O O N N _ O O o 0 0 0 L rLU € c m U U U VY N pq O Q N QI m ❑ m N .- v N N Z N _ O O o 0 0 0 L rLU € c m U U U VY N pq O Q N QI N N N _ L - 0 W W " N pq O Q N QI Oq 9 aLT L5 E g b o a m � � W v � S C C C 3 S � c 0 w � W W " @ 2 � ci \\ ] )! ci \\ ] 3\ } / &2 )) 46 !47 B2� \� § \ \;\ }\\( �f 7: E E; \\\\ ci \\ j 3\ } / &2 )) 46 !47 \� § \ \;\ }\\( �f 7: E E; \\\\ 00 \\� �}\ cy 2 ( E \\\\ \\!) ci \\ 3\ } / &2 )) 46 !47 \� \;\ }\\( �f 7: E E; \\\\ 00 \\� cy 2 ( ; \\ 3\ / &2 )) !47 \� }); }\\( �f 7: E E; \\\\ \\� ;>_* 2 ( E \\\\ \\!) \/ \ ; \\ 3\ / ; )) !47 }); }\\( 7: E; \\\\ \\� ;>_* ; )) !47 }); rf{ \\\\ \\� E \\\\ \\!) ff}/ 7f2: ■ \\\\ E \\\\ \\\\ ■ 0 ,a � N pok� p M Uo w z � F N TTTI yy0 r � tt U s�� y r 7,2 �y .� �' &lbmuluo� �o aagomN N @ ti E � 110=0 `P1u6F7=7'P11o3=g :zulull[ F a qwD allsodao0 X a e � o ❑ 5' >r � ❑ o S •� u Q N ,�, �.-�• cJ a A 8 c N CE PL� ME U R V V UyU V, Mv. 1a Summit Environmental "technologies, Inc. Cooler Receipt Form 5 Initials of person Inspecting cooler and samples: CsL Client: IO Order Number:_. *sr.-r`DTI. '!off dX77, Data Received: -AL t. Time Received: 10y0Date coolar(s) opened and samples Inspected: Number of Coolers/Boxas: N/A Shipper.trr urJy UPS OHL Airborne USPostal Walk-in Pickup Other:`_ Packaging: Peanuts 8 ble/�'�l Paper Foam None Other. Tape on cooler/box: W N N/A Custody Seals intact yy/.".� NIA GO-Cnastic /r7 IN WA Ice Blue Ice / absent / melted WA Sample Temperature IR Gun #t 045 2g CF �'0 °C ' NIA Radiniogiral Tesfing instrumentsedalp 127 y N WA (sae page 2 for scan results) Use 1 sheet per sample for Radiological Testlng. If samRadiological S mmadiefely. ple Is HOT, the Rafety Officer must be notifiedi C-OQC filled out properly, N N/A Samples in separate bags �}' N NIA Sample containers Intact• L/Y/ N N/A 'If no, list broker samolefsk Sample labels) complete (10, tlale, etc.) (y� N N/A Labal(s) agree with C-0-C/y17�/. N NIA, Correct containersused �Y N NIA Sufficient sample received Y N WA Samples received within holding time t1% N Bubbles absent from 40 mL Asia" y N " Samples with bubbles c6mm are axaptabia. Indicate bubble size if >6mm, Wee client contacted about samples y N W111 client send new samples y N Logged in Page 1 of 2 SECTION 5 Wayne Farms Land Application Program Permit #WQ0004609 Calender Year 2.018 Animal processing wastewater residuals were land applied in one event in the year 2018. The biosolids were sampled at the time of the land application events for nutrient and metal data. The biosolids land applied in 2018 had sufficient lime added to raise the pH of the uniform mixture to a pH of 10 for thirty minutes prior to being surface land applied. This was performed to control possible nuisance conditions (see Section II, Item 7 in permit #WQ0004609). op ;sa}gd�a[drues TT III T Q xd�.r la,ues �q; � p b 6 a ":o tAIV w fn � a¢iy;sa;gd in /aw[; a[dmvg U s[xy[ur;ad[e¢e G1 gdwza[dumg N t -d N tA a Cl IV G � G p Fy asa; Hd sg a}dmes ano91�ZJ° a�eQ }wT;d /mawV aidmes s;ep;¢;75dtaua gdwaatdweg k3 N b � [mow t5 � G iJ1 FGGG9 F A+ ,, Isa}Rd v aldwes `Q ;.Iq Z 0 JUITI(II3o n7uq x TTT 7p aw,y )sal ad aldmag sluplul.7s,fluuu "r �d �, aaldwug L1 w IV Com} �•. �� amy asal gd I 11 /awg atdmus -L -L -Li s1eANlls6teae �d gaaldwug N IV a VI w a. IND) gd V oldmus :znoy ryZ jo aluQ amp;sa}pd /hill aldmug steylul asfleue .9 Ed � aaldmug � N C � x SECTION 6 Agricultural Lime Application Log Year: 2018 Project: Wayne Farms Field (state -county -site -field) Soil pH (from Lime Requirement soil analysis) TonslAcre Applied(CCE Eq.) Date Applied SU -13-5 5.4 0.9T/Ac. SU -13-6 6.5 0.OT/Ac. SU -13-7 6.6 O.OT/Ac. SU -13-8 5.6 0.8T/ac O.OT/Ac. O.OT/Ac. *Lime applied in product SECTION 7 U) f 0m 2Ea fz \ CO § : : 0m 2Ea |w )z \ ® § s;, {7 \ ) , ix Z ° Lu U) $ )®° ) = N f § &_ N \ 2 3 7 2 3 7 2 3§ ` ° i i ) _ ®o £_ {\{ / 2 - o ! o ! - 232 2: : ( \ \ \ § - U) 4q6= zi a} a: CL (k \)2 ! { ®® : f E <Z § \ ) ) \ \ : J ; ; « 2 - ; 7 3 2 �\ _ ()\ E C3 E,2 } § z w- : }\0 z z § & 3 ( & t / t & - - - o § § ! $ fL a ) m E ) ; § # 2 \ # \ i / [ | @ $ $ } , ! . , . . , t = $ 12 >/ 00 u� ( ( ( 8 0 j e 2 o o o ¥ # ¥ L �: }aRI § /« _~■w§a !�w§2 §■a `\\\ § \ \) \§m\} k§>)} N (O h O J IrL O ra a M O C7 pl FIII O a` QN O m m Gl UU x v Q p m m � D a w O u1 m U U n ao O U N U ..T m �' X W U O1 E ' N "00 N va CL N U W z E U s 2 x E 'yN . a Y LN U `i E p) E .o m O o U m? � � N U U 20 axi GXi N E U 0 N Nm m m E E r III,N 45 C c c S 2 2 2 N U w C IE d O l C E`a c O 2 2 'cO z rpn z O OO m 'c Z Z y U= .N mo (7 O a w wv �Om Cd C Ln - "O' -XOp d 0 w 0 (L 0 E O- N aOl NN 3 N 3 X c U N N 5 U c <_ N N C a) T m M a CO m E O N m mo w w= C s o6rna ami Nc `p c� moLG Y ;n = m p o L Iau7 aM ? O m pO .0 w A > N Q. C a C 0 'C-.. > .m O N m w O a L 'm0 a U) = L O Q� C a N Q O. E w .N $ C Z > _ O CO O N L 0- O E N m mE o 0 $ paa c �v os E vwcf0i m c a • C N p m a c AC Y ` � ¢ a.lc6 w > 14 >°> L GO E E O` d Zd C O C mo0 N U °1 (D Um) rE CO m O C N C p? - G m C .L.+ C m m U O O p QQ td E L •.L. C m U O w m m CU) N E C m _T N O m O- E _U N U=> (a �a3 Mn a uro EE E �' oaa` m mm e a U a i o 0 — a E Tb m a c m w m � o m a c c m o m o w = Q E 3 m U m m o a T m G O c` N C p C o a E E (D C 0 `m ) m 'mo 3 'm O c m m C m N m N (v m m N m z (D E m- - m Gl E �w aiwa G) O mz > C _ m p m o QN E �r oO N 7 U C NaC aU 0 m a E AQE m A>m QQc MW Ac N Oa CG C Om m Ex E o m °E UY `m w— m 0 0 W m O)a > Lo (-o° No o E 0 C E ^m. O N m p O m w m E O 0 m C L O C L w Y O_ U p C 'm0 m a V o- C O a .m-. C N aa o no s E c`m m y c ` o 5 a 3 3 m p m a— ° c c w a o 0 r a CD x 0 cc u mam E a i p cn m 1. `0 m Eac m umi m c nC E a CL NE ` _O U $ E o m d pP. -m oU0 ON0 N LLa d E N E � (D O O � OO Ya O N ca I Y N m m= O .o O U O L C r.. O o C7 'Lm" .G > N m _ o. m�� rn v a �� .wmo,m�.mp o m o 'p a I acpam o P3 >co Q c C O_ C m a— C a C m C w T N ,C C O C m c O O m m m m m m O m 01" v o :° E E w> a) E u, c o E c.2 a - y c d m 4 c " � N w 'R W a U m C a U U C N f9 _0 0( N >. m Gwmi 2 `a GI m m T U E a c m E E w m 2 c c m o G°1 m m m y C z 7 � J= LL '- h LL K m m 0 LL c c x w E H N