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HomeMy WebLinkAboutWQ0008008_Residual Annual Report 2018_20190314INITIAL REVIEW Reviewer Williams, Kendall Project Number* WQ0008008 SUBMITTAL DATED: 3/1/2019 Project Contact Information Rease provide inforrration on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other issues. ...................................................................................................................................................................................................................................................................................................................................................................................................... Name * Drew Matthews Email Address* dmatthews@soilplus.net Project Information Application Type* r New r Renewal r Annual Report Permit Type * r Wastewater Irrigation r Other Wastewater • Closed -Loop Recycle r Single -Family Residence Wastewater Irrigation Is a paper copy of the application being submitted?* r Yes r Nor N/A Permit Number* WQ0008008 Permittee * Pasquotank County Facility Name * Pasquotank County Regional WTF Phone Number* 2528839301 r Modification (Major or Minor) • Additional Information r Other • High -Rate Infiltration r Reclaimed Water r Residuals r Other Please provide comments/notes on your current submittal below. Please attach all information required or requested for this submittal to be review here. Application Form Engineering Rans, Specifications, Calculations, Etc.) 2018 Pasquotank Annual Report.pdf 6MB Wload only 1 RDF docurrent. NLltiple documents must be corrbined into one RDF file. For nein and modif cation permit applications, the paper copy is required to be submitted to the Di, risiom Be advised, applications will not be considered complete until both the paper and electronic applications. have been received_ The paper copy shall include the follm ging: • Application Farm • All relevant attachments (talcs, soils report, specs, etc_) • 1 full-size engineering plan set • 2 11-17" engineering plan sets • 1 extras set of specifications (in addition to the set of specifications Provided in the attachments) • Fee (if required) This shall be mailed to the following address: By US_ Postal Service- Di,vision of Water Resources- Non -Discharge Branch 1617 Mail Service Center Raleigh NC 27699-1617 By Courier, -Special Delivery: Division of Water Resources- Non -Discharge Branch Nathaniel Thornburg- 9th Floor, Office #942M 512 N_ Salisbury St_ Raleigh, NC 27644 For questions or problems contact Tessa Monday at 919.7073660 or Tessa_X%nday(dncdem_gov or Sonia Graves at 919.707.3657 or Sonia Graves(dpcdenr.gov. *140 By checking this box I am acknowledging that I have read the above statement and agree to send these documents as required to one of the address given above. Signature Submission Date 3/1/2019 PASQUOTANK COUNTY WATER TREATMENT FACILITY 2018 ANNUAL LAND APPLICATION OF RESIDUAL BIO -SOLIDS REPORT CLASS B PROGRAM Submitted by: Soil Plus PO Box 1396 Oxford, NC 27565 February 21, 2019 SOIL PLUS SOIL PLUS February 21, 2019 NCDEQ-DWR Information Processing Unit 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Re: 2018 LAND APPLICATION ANNUAL REPORT Pasquotank County Water Treatment Facility "Class B" Program NC Permit No.: WQ0008008 Soil Plus Project No. 200701.A10 Information Processing Unit: Soil Plus, LLC (Soil Plus) is submitting all monitoring and reporting requirements as specified in the above referenced permit for the Pasquotank County Water Treatment Facility on behalf of Atlantic OBX, Inc. Soil Plus compiled this report using data gathered during the compliance year. This data includes (1) certification form, (2) residual sampling, (3) field loading calculations, and (4) standard soil fertility nutrient analysis. The Pasquotank County Water Treatment Facility conducted application events on permitted fields in Pasquotank County during 2018. A total of 138.50 Dry Tons or 299,500 gallons of permitted residuals were land applied to permitted fields. If there is any further information required or questions regarding this annual report please do not hesitate to contact me or the Pasquotank County Water Treatment Facility (252- 335-2240) for further assistance. Respectfully, Drew Matthews, Soil Plus David Smithson, Pasquotank County Water J. Bryan Smith, Atlantic OBX, Inc. PO Box 1396 Oxford, NC 27565 (252) 883-9301 dmatthews @s oilplus. net www.soilplus.net Pasquotank County Water Treatment Facility Annual Land Application of Residual Bio -Solids Report Elizabeth City, NC ANNUAL LAND APPLICATION CERTIFICATION FORM Field Loading & Source Summary ANNUAL RESIDUAL SAMPLING SUMMARY FORM Annual Analytical Data FIELD LOADING SUMMARY FORM SOIL SAMPLES N/A Pasquotank County WTP 2018 Class B Annual Report WQ Permit# WQ0008008 Annual Certification Form Source Summary Field Loading Summary ANNUAL LAND APPLICATION CERTIFICATION FORM PermitNumber FacilityName Land Application Operator County Phone Number WQ0008008 Pasquotank County Regional Water Treatment lac. Year: 2018 Atlantic OBX, Inc. Pasquotank (252) 335-2240 Land application of residuals as allowed by the permit occurred during the past calendar year? If No, skip Part A, and Part Yes No B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the ❑1 F-.1 residuals were handled. Part A - Residuals Application Summary: Total number of application fields in the permit: 24 Total number of fields utilized for land application during the year: 6 Total amount of dry tons applied during the year for all application sites: 138.50 Total number of acres utilizes for land application during the year: 13.59 Part B - Annual Compiance Statement: Facility was compliant during calendar year with all conditions of the land application permit? Yes No Including but not limited to items 1-13 below) issued by the Division of Water Quality V FJ If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6 3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached 6.The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T 7. All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Parr 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior autthorization was received from the Division of Water Quality 10. No contravention of Ground Water Quality Standards occurred ata monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C - Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, trite, accurate, and complete. I am aware that there are significant penalties for submitting false informati ,including the o 'bility of fines and imprisonment for knowing violations." David Smithson, Water Superintendent , Permittee Name and Title (type or print): Signature of Permittee 2-22-19 Signature of Preparer* Date Signature of Land Applier Date (if different from Permittee) (if different from Permittee) * Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T. 1 102 (26) Thursday, February 21, 2019 Source Summary Report WWTP VolumeApph� Pasquotank County Regional Water 299,500 138.50 Treatment Fac. Total 299,500 138.50 Thursday, February 21, 2019 Page 1 of 1 a N .�y o � � �I N '7 Ln Ln Ln Ln Ln Ln U R+ 4 4-4 N cyd cm m m O U e C C � 0 0 0 000 0 0 r. 00 00 00 00 00 a. U r v z c� 0 0 0 0 0 0 0 U V U U U V U Ci U G� M .-r O M Vr G\ O N N N p N Cl) .-r N � O � Fa U ti � � w w C� C� 0 0 0 0 0 0 o U H A oco o r o r c o iri O H O A O O O O OLr) O M 06 � N M O G4 � in N vNj 000 .-. M .--i N c-+ N .d G O r N M w Pasquotank County WTP 2018 Class B Annual Report WQ Permit# WQ0008008 Residual Sampling Summary Form Pasquotank County WTP Field Loading Calculations 2018 Analytical ) \ § [ \ a ) ) / §! ƒ S m \ - \ ® » } _ a; g §] § ) 5 u f 2 f 2 m @ f 0o« # 2 'ng f z 4 i f 2 2 ±< 2$ f k o k $ f z 2 o k )) 2 Z» 2« f z f f + 2 z Z/$ f*± z k I 2< i$ k f k» e J . f \ Id ba ) � | ) § e | k~� / | \ _ ) i l ) ) & \ R ( ! u § \ ; z \ \ 6 , ) \ g ƒcw ) | ) 7 ® 5 Q / A` AGMAN FIELD LOADING ESTIMATES Facility Pasquotank County Regional Water Sampling Date 2/6/2018 % Solids 11.09 Mineralization Rate 0 Gallons per DT 2,162.38 PH 8.1 Sodium Absorpotion 0.53 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply Ratio NITROGEN APPLICATION TKN (mg/Kg) 2,563 lbs./1,000 gal 2.37 Ammonia Nitrogen (mg/Kg) 55.39 lbs./1,000 gal 0.05 Nitrate -Nitrite (mg/Kg) 15.83 lbs./1,000 gal 0.01 PLANT AVAILABLE NITROGEN SURFACE APPLIED PAN (mg/Kg) 44 lbs./1,000 gal 0.04 PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED PAN (mg/Kg) 71 lbs./1,000 gal 0.07 Volatization Rate= 0.5 Surface Application 1.0 Injection/Incorporation EPA METAL LIMITS Class A Ceiling Class B Ceiling Limits (mg/Kg) Limits (mg/Kg) 41 75 39 85 1,500 4,300 300 840 17 57 420 420 100 100 2,800 7,500 1 st Year 2nd Year 3rd Year 4th Year 5th Year HEAVY METAL CONCENTRATION NUTRIENT APPLICATION Potassium lbs./1,000 gal 0.42 Phosphorus lbs./1,000 gal 5.76 Calcium lbs./1,000 gal 38.72 Magnesium lbs./1,000 gal 2.60 Manganese lbs./1,000 gal Sulfur lbs./1,000 gal Molybdenum lbs./1,000 gal 0.00 HEAVY METAL LOADING Arsenic (mg/Kg) 2.50 Arsenic lbs./1,000 gal 0.00 Cadmium (mg/Kg) 0.50 Cadmium lbs./1,000 gal 0.00 Copper (mg/Kg) 16.00 Copper lbs./1,000 gal 0.01 Lead (mg/Kg) 7.90 Lead lbs./1,000 gal 0.01 Mercury (mg/Kg) 0.03 Mercury lbs./1,000 gal 0.00 Nickel (mg/Kg) 5.00 Nickel lbs./1,000 gal 0.00 Selenium (mg/Kg) 5.00 Selenium lbs./1,000 gal 0.00 Zinc (mg/Kg) 29.00 Zinc lbs./1,000 gal 0.03 RESIDUAL NITROGEN CALCULATION 2,519 Total 44 0.09 Total 71 0.14 Equations I st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx 2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2) 3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4) 4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8) 5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16) Surface Application Injection/Incorporation Application Remaining Remaining Organic Organic PAN PAN Nitrogen PAN PAN Nitrogen TKN (mg/kg) (lbs/DT) (M9 Y_-) TKN (mg/kg) (lbs/DT) (mg/Kg) 2,563 44 0.09 2,519 2,563 71 0.14 2,492 2,519 0 0.00 2,519 2,492 0 0.00 2,492 2,519 0 0.00 2,519 2,492 0 0.00 2,492 2,519 0 0.00 2,519 2,492 0 0.00 2,492 2,519 0 0.00 2,519 2,492 0 0.00 2,492 Total 44 0.09 Total 71 0.14 Equations I st Yr. PAN (mg/Kg)=(MR x (TKN-NH3))+(VR x NH3)+NOx 2nd Yr PAN (mg/Kg)= 2nd Yr. TKN x (MR/2) 3rd Yr PAN (mg/Kg)= 3rd Yr. TKN x (MR/4) 4th Yr PAN (mg/Kg)= 4th Yr. TKN x (MR/8) 5th Yr PAN (mg/Kg)= 5th Yr. TKN x (MR/16) P.O. BOX 7085, 114 OAKMONT DRIVE GREENVILLE, N.C. 27835-7085 PASQUOTANK CO. WATER (SLUDGE) MR. RONNY JENNINGS P.O. BOX 2245 ELIZABETH CITY ,NC 27906 Water Plant Analysis Method PARAMETERS Sludge Date Analyst Code PH (not to be used for reporting) 8.1 02/06/18 JTH 4500HB-11 Aluminum, (dry wt. basis), mg/kg 6201 02/26/18 LFJ EPA200.7 Arsenic (dry wt. basis), mg/kg <2.5 02/26/18 MTM 3113B-04 Calcium (dry wt. basis), mg/kg 41867 02/26/18 LFJ EPA200.7 Cadmium (dry wt. basis), mg/kg <0.5 02/26/18 MTM 3113B-04 Copper (dry wt. basis), mg/kg 16 02/26/18 LFJ EPA200.7 Chromium, T.(dry wt. basis),mg/kg 11 02/26/18 LFJ EPA200.7 Lead (dry weight basis), mg/kg 7.9 02/23/18 MTM 3113B-04 Magnesium (dry wt. basis), mg/kg 2815 02/26/18 LFJ EPA200.7 Mercury (dry wt. basis), mg/kg 0.03 02/27/18 MTM EPA7471B Nickel (dry wt. basis), mg/kg 5 02/26/18 LFJ EPA200.7 Potassium (dry wt. basis), mg/kg 458 02/26/18 LFJ EPA200.7 Selenium (dry wt. basis), mg/kg <5.0 02/22/18 MTM 3113B-04 Sodium (dry wt. basis), mg/kg <1250 02/26/18 LFJ EPA200.7 Zinc (dry wt. basis), mg/kg 29 02/26/18 LFJ EPA200.7 Total Solids, % 11.09 02/07/18 MAR 2540G-11 TKN (dry wt.), mg/kg c 2563 02/22/18 CML 351.2 R2-93 Ammonia Nitrogen (dry wt.),mg/kg c 55.39 03/06/18 MF 350.1 R2-93 Phosphorus, T. (dry wt.), mg/kg c 6230 02/22/18 DTL 365.4-74 Nitrate -Nitrite (dry wt.), mg/kg c 15.83 03/01/18 DTL 353.2 R2-93 Plant Available Nitrogen, mg/kg 1046 03/09/18 SEJ Molybdenum (dry wt. basis), mg/kg <5.0 02/26/18 LFJ EPA200.7 Drinking Water ID: 37715 Wastewater ID: 10 PHONE (252) 756-6208 FAX (252) 756-0633 ID#: 149 DATE COLLECTED: 02/06/18 DATE REPORTED : 03/09/18 REVIEWED BY: c Uncertified data. DWR does not offer non -aqueous certification for this analytical procedure. t r u O H U Oa z U Q M M O 1.6 IrlP N Q N 1. O Q U 'O Y1 U in ®z �^ k Xo *5 a N P�1 o a aUi j O 3 C-' 0 5 w _: U ~ O Zo U Q z O U 0 W a. U) n Im 0 z o W la- J LU UUO Q U 2 Z u_ z LLF o w CD [aIL w 0 w w O ¢ z S S W 2-1 U Q m U U O w CL � " S1S31/Sd3 I NgVHVd G7 d sa;x� d'I�,L C7 d �al�i d'Ia,L 0 Q sapl;)IgaaH d'131 d CD C7 d sapPiPad drool C7 d IOAS/IOA d'131 AIAISO.I.IOa � a d flIIIg�IA�I C� O w H U ~ p Lu 5 It'd 0 a d a;I�aIH-a;�a�IN v a tod w d -Omw U!UOM V a Q NXZ o = a d sp?IoS I'mol % A41 smIaw a d (CIUO 'OJUD Hd SHDNIVIN00 30 It w N0110311001V > z oo'3�1f1m3dNR 01103700 V I N6w ❑l u' 3NI OIH0lH101 3 C-' 0 5 w _: U ~ O Zo U Q z O U 0 W a. U) n z LU 0 r LU m 0 LU w C) Im o LU z } O z LU �{ � LU Q Z w � LU J p Q d CD vw z m 3 Q � O z C� O w H U ~ p Lu 5 0 0 00 [-O Uc�%� v o (�—{i 11 Eli o = � � U) w Qp d V 3 CL U co d W z LU 0 r LU m 0 LU w C) i l The results set forth herein are provided by SGS North America Inc. Hardcopy 2° Automated Report Technical Report for Environment 1, Inc Pasquotank Co Water; Elizabeth City, NC 149 SGS Job Number: FA51719 Sampling Date: 02/06/18 Report to: Environment 1, Inc PO Box 7085 Greenville, NC 27835 dwoolard@environmentlinc.com ATTN: Deedee Woolard Total number of pages in report: V. Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001) DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177), AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WV This report shall not be reproduced, except in its entirety, without the written approval of SGS. Test results relate only to samples analyzed. SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: 407-425-6700 • fax: 407-425-0707 SGS is the s le authority for authorizing edits or modifications to this document.ar�� Unauthoriz d modification of this report is strictly prohibited. Review st i and terms at: http://www.sgs.com/eu/terms-and-conditions 4 of 14 FA51719 If. - Test results contained within this data package meet the requirements Caitlin Brice, M.S. General Manager of the National Environmental Laboratory Accreditation Program and/or state specific certification programs as applicable. Client Service contact: Sue Bell 407-425-6700 Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001) DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177), AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WV This report shall not be reproduced, except in its entirety, without the written approval of SGS. Test results relate only to samples analyzed. SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: 407-425-6700 • fax: 407-425-0707 SGS is the s le authority for authorizing edits or modifications to this document.ar�� Unauthoriz d modification of this report is strictly prohibited. Review st i and terms at: http://www.sgs.com/eu/terms-and-conditions 4 of 14 FA51719 S TabRe of Contents -i- on1: Sample Summary................................................................................................... on2: Summary of Hits.................................................................................................... orn3: Sample Restafts........................................................................................................ 1: FA51719-1: WATER PLANT SLUDGE...................................................................... on4: Misc. Forms............................................................................................................ 1: Chain of Custody........................................................................................................... Sections: 3 4 5 12 13 01,$) 2of14 FA51719 SGS North America Inc. Sample Summary Environment 1, Inc Job No: FA51719 Pasquotank Co Water; Elizabeth City, NC Project No: 149 !ample Collected Matrix Client dumber Date Time By Received Code Type Sample ID FA51719-1 02/06/18 08:30 MH 02/10/18 SO Sludge WATER PLANT SLUDGE Soil samples reported on a dry weight basis unless otherwise indicated on result page. C ((� 3of14 FA51719 Summary of Hits Job Number: FA51719 Account: Environment 1, Inc Project: Pasquotank Co Water; Elizabeth City, NC Collected: 02/06/18 Lab Sample ID Client Sample ID Analyte Result/ Qual RL MDL Units Method FA51719-1 WATER PLANT SLUDGE Corrosivity as pH 8.4 su SW846 CHAP? Ignitability (Flashpoint) a > 200 Deg. F SW846 1010 Benzene Tetrachloroethylene 0.0032 J 0.0791 0.010 0.0031 mg/I SW846 8260B 0.010 0.0022 mg/I SW846 8260B (a) Not ignitable. Page I of 1 1, 4 of 14 FA51719 Or�andc, FL Sample Results Report of Analysis 3; :K -R) 5 al 14 (a Is FA51719 SGS North America Inc. Report of Analysis Client Sample ID: WATER PLANT SLUDGE Lab Sample ID: FA51719-1 Date Sampled: 02/06/18 Matrix: SO - Sludge Date Received: 02/10/18 Method: SW846 8260B SW846 1311 Percent Solids: 11.2 Project: Pasquotank Co Water; Elizabeth City, NC Page 1 of 1 ) File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 M0101533.D 10 02/26/18 14:19 WV 02/13/18 13:30 OP68746 VM4372 Run #2 Purge Volume Run #1 5.0 ml Run #2 VOA TCLP List MDL Units Q 0.0031 CAS No. Compound Result HW# MCL RL 71-43-2 Benzene 0.0032 D018 0.50 0.010 78-93-3 2-Butanone (MEK) ND D035 200 0.050 56-23-5 Carbon Tetrachloride ND D019 0.50 0.010 108-90-7 Chlorobenzene ND D021 100 0.010 67-66-3 Chloroform ND D022 6.0 0.010 106-46-7 1,4 -Dichlorobenzene ND D027 7.5 0.010 107-06-2 1,2-Dichloroethane ND D028 0.50 0.010 75-35-4 1,1-Dichloroethylene ND D029 0.70 0.010 127-18-4 Tetrachloroethylene 0.0791 D039 0.70 0.010 79-01-6 Trichloroethylene ND D040 0.50 0.010 75-01-4 Vinyl Chloride ND D043 0.20 0.010 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 1868-53-7 Dibromofluoromethane 99% 83-118% 17060-07-0 1, 2-Dichloroethane-D4 101% 79-125% 2037-26-5 Toluene -D8 101% 85-112% 460-00-4 4-Bromofluorobenzene 99% 83-118% TCLP Leachate method SW846 1311 MDL Units Q 0.0031 mg/l J 0.020 mg/l 0.0036 mg/l 0.0020 mg/l 0.0030 mg/l 0.0026 mg/1 0.0031 mg/l 0.0032 mg/l 0.0022 mg/l 0.0035 mg/l 0.0041 mg/l ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value MCL = Maximum Contamination Level (40 CFR 261 7/1/11) B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound gent `�i 6of14 FA51719 SGS North America Inc. Report of Analysis Page 1 of 1 ` Client Sample ID: WATER PLANT SLUDGE Lab Sample ID: FA51719-1D ate Sampled: 02/06/18 Matrix: SO - Sludge Date Received: 02/10/18 Method: SW846 8270D SW846 3510C Percent Solids: 11.2 Project: Pasquotank Co Water; Elizabeth City, NC File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 9I000297.1) 1 02/23/18 17:03 NJ 02/23/18 13:00 OP68890 S9I13 Run #2 Initial Volume Final Volume .un #1 100 ml 1.0 ml .un #2 ABN TCLP List TCLP Leachate method SW846 1311 CAS No. Compound Result HW# MCL RL MDL Units Q 95-48-7 2-Methylphenol ND D023 200 0.050 0.0056 mg/l 118-79-6 3&4-Methylphenol ND D024 200 0.050 0.0098 mg/1 87-86-5 Pentachlorophenola ND D037 100 0.25 0.050 mg/1 95-95-4 2,4,5 -Trichlorophenol ND D041 400 0.050 0.0074 mg/1 88-06-2 2,4,6 -Trichlorophenol ND D042 2.0 0.050 0.0075 mg/l 106-46-7 1,4 -Dichlorobenzene ND D027 7.5 0.050 0.0050 mg/l 121-14-2 2,4-Dinitrotoluene ND D030 0.13 0.050 0.0081 mg/l 118-74-1 Hexachlorobenzene ND D032 0.13 0.050 0.0069 mg/l 87-68-3 Hexachlorobutadiene ND D033 0.50 0.050 0.0050 mg/1 67-72-1 Hexachloroethane ND D034 3.0 0.050 0.016 mg/l 98-95-3 Nitrobenzene ND D036 2.0 0.050 0.0093 mg/l 110-86-1 Pyridine ND D038 5.0 0.10 0.020 mg/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 367-12-4 2-Fluorophenol 17% 14-67% 4165-62-2 Phenol -d5 10% 10-50% 118-79-6 2,4,6-Tribromophenol 87% 33-118% 4165-60-0 Nitrobenzene -d5 67% 42-108% 321-60-8 2-Fluorobiphenyl 72% 40-106% 1718-51-0 Terphenyl-dl4 49% 39-121% (a) Associated CCV outside of control limits high, sample was ND ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value MCL = Maximum Contamination Level (40 CFR 261 7/1/11) B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 7of14 FA51719 SGS North America Inc. Report of Analysis Client Sample ID: WATER PLANT SLUDGE Lab Sample ID: FA51719-1 Date Sampled: 02/06/18 Matrix: SO - Sludge Date Received: 02/10/18 Method: SW846 8151A SW846 3510C Percent Solids: 11.2 Project: Pasquotank Co Water; Elizabeth City, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 CC057314.1) 1 02/21/18 14:47 EM 02/20/18 15:00 OP68843 GCC1252 Run #2 Initial Volume Final Volume Run #1 10.0 ml 5.0 ml Run #2 Herbicide TCLP Leachate File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 CC057314.1) 1 02/21/18 14:47 EM 02/20/18 15:00 OP68843 GCC1252 Run #2 Initial Volume Final Volume Run #1 10.0 ml 5.0 ml Run #2 Herbicide TCLP Leachate TCLP Leachate method SW846 1311 CAS No. Compound Result HW# MCL RL MDL Units Q 94-75-7 2,4-D ND D016 10 0.050 0.017 mg/1 93-72-1 2,4,5 -TP (Silvex) ND D017 1.0 0.0050 0.0013 mg/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 19719-28-9 2,4-DCAA 81% 39-135% ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value MCL = Maximum Contamination Level (40 CFR 2617/1/11) B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound e�8of14 FA51719 SGS North America Inc. Report of Analysis Client Sample ID: WATER PLANT SLUDGE Lab Sample ID: FA51719-1 Date Sampled: 02/06/18 Matrix: SO - Sludge Date Received: 02/10/18 Method: SW846 8081B SW846 3510C Percent Solids: 11.2 Project: Pasquotank Co Water; Elizabeth City, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 KK88078.D 1 02/21/18 12:59 KL 02/20/18 14:00 OP68842 GKK2806 Run #2 Initial Volume Final Volume Run #1 100 ml 5.0 ml Run #2 Pesticide TCLP Leachate TCLP Leachate method SW846 1311 CAS No. Compound Result HW# MCL RL MDL Units Q 58-89-9 gamma -BHC (Lindane) ND D013 0.40 0.00010 0.000022 mg/1 12789-03-6 Chlordane ND D020 0.030 0.0010 0.00038 mg/1 72-20-8 Endrin ND D012 0.020 0.00020 0.000021 mg/1 76-44-8 Heptachlor ND D031 0.0080 0.00010 0.000026 mg/1 1024-57-3 Heptachlor epoxide ND D031 0.0080 0.00010 0.000020 mg/1 72-43-5 Methoxychlor ND D014 10 0.00020 0.000050 mg/1 8001-35-2 Toxaphene ND D015 0.50 0.0050 0.0021 mg/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 877-09-8 Tetrachloro-m-xylene 108% 42-127% 2051-24-3 Decachlorobiphenyl 58% 27-127% ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value MCL = Maximum Contamination Level (40 CFR 2617/1/11) B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 9of14 FA51719 SGS North America Inc. Report of Analysis Page 1 of 1 Client Sample ID: WATER PLANT SLUDGE Lab Sample ID: FA51719-1 Date Sampled: 02/06/18 Matrix: SO - Sludge Date Received: 02/10/18 Project: Pasquotank Co Water; Elizabeth City, NC Percent Solids: 11.2 Metals Analysis, TCLP Leachate SW846 1311 Analyte Result HW# MCL RL Units DF Prep Analyzed By Method Prep Method Arsenic Barium <0.10 D004 5.0 0.10 mg/1 1 02/14/18 02/15/18 LM SW846 6010D 1 SW846 3010A 3 Cadmium < 2.0 < 0.050 D005 D006 100 1.0 2.0 mg/1 1 02/14/18 02/15/18 LM SW846 6010D 1 SW846 3010A 3 Chromium < 0.10 D007 5.0 0.050 0.10 mg/I mg/I 1 1 02/14/18 02/14/18 02/15/18 LM SW846 6010D 1 SW846 3010A 3 Lead < 0.050 D008 5.0 0.050 mg/I 1 02/14/18 02/15/18 02/15/18 LM LM SW846 6010D 1 SW846 6010D 1 SW846 3010A 3 SW846 3010A 3 Mercury < 0.0050 D009 0.20 0.0050 mg/l 1 02/20/18 02/20/18 LM SW846 7470A 2 SW846 7470A 4 Selenium a < 0.50 DO10 1.0 0.50 mg/1 5 02/14/18 02/15/18 LM SW846 6010D 1 SW846 3010A 3 Silver < 0.10 D011 5.0 0.10 mg/l 1 02/14/18 02/15/18 LM SW846 6010D 1 SW846 3010A 3 (1) Instrument QC Batch: MA14687 (2) Instrument QC Batch: MA14696 (3) Prep QC Batch: MP33339 (4) Prep QC Batch: MP33368 (a) Elevated reporting limit(s) due to matrix interference. RL = Reporting Limit MCL = Maximum Contamination Level (40 CFR 2617/1/11) 10 of 14 FA51719 SGS North America Inc. Report of Analysis Client Sample ID: WATER PLANT SLUDGE Lab Sample ID: FA51719-1 Date Sampled: 02/06/18 Matrix: SO - Sludge Date Received: 02/10/18 Percent Solids: 11.2 Project: Pasquotank Co Water; Elizabeth City, NC General Chemistry vK SW846 CHAP? 02/21/18 17:15 Analyte Result RL Units DF Corrosivity as pH 8.4 su 1 Cyanide Reactivity < 13 13 mg/kg 1 Ignitability (Flashpoint) a > 200 Deg. F 1 Solids, Percent 11.2 % 1 Sulfide Reactivity < 450 450 mg/kg 1 (a) Not ignitable. RL = Reporting Limit Page 1 of 1 Analyzed By Method 02/13/18 14:10 vK SW846 CHAP? 02/21/18 17:15 KH SW846 CHAP7 02/24/1810:30 BW SW846 1010 02/12/18 13:06 Jc SM19 2540G 02/19/18 18:00 BW SW846 CHAP? (M 11 of 14 FA51719 i I 04ando, FL j Section 4 Misc. Forms Custody Documents and Other Forms Includes the following where applicable: o Chain of Custody 12 o114 SMM FA61719 J� PQ FORM #6 PLEASE READ Instructions for co e Sampler must place a "C" for composite sample or a "G" for eting this fo on the reverse side. Q 3(J Grab sample in the blocks above for each parameter requested.M_ 0 342346 FA51 %19: Chain ®f Custody Page I ®f 2 13 of 14 FA51719 U11AIN UI+' CUSTODY RECORD P.O. Box 70 5,114 Oakmont Dr. Greenville, C27858 Page 1 of 1 environmen linc.com DISINFECTION Phone (252) 756-6208 • Fax (252) 756-0633 CHLORINE NEUTRAUZEDATCOLLECIION CHLORINE CLIENT.49 Week:9 uv pHCHECK (LAB) 'ASQUOTANK CO. WATER (SLUDGE) NONEp p p p p p p p CANTAINERTYPE, P/G TR RONNY GS P P G G G G G 1. O. BOX 22A 5 CHEMICAL :LIZABETH CITYNC27906 A A A A A A A A A A A A A A A PRESERVATION z E A -NONE D -NADH t52)330,400 0:j U ' P y :2 b B-HNO, E -HCL C -H,80, F-ZINCACETATE/NAOH COLLECTION a a a G-NATHIOSULFATE SAMPLE LOCATION DATE TIME 00a dg,E8�>9 10rig RIVER . e CLASSIFICATION: U WASTEWATER(NIMES) nJ DRINMWATER I�► DWWW SOUDWASTESECTION CHAIN OF CUSTODY (SEAL) MAINTAINED DURING SyIPMENT/DELIVERY ' N SAMPLES COLLECTED BY: (Please Print) SAMPLES RECENED M LABAT (/ °C NO HE (SAMPLER) DATFlRME REC BY(SIG. DATE/TIME COMMEMS: -6-1$ 1,10AIK %b iz., REL E BY(S ) DATE/1IME zAd/ RECE BY(SI . DATE/RME ' n a1911s la:ao REUNOUI ( DATEMME RECEIVED (SIG.) DATE/TIME ,t r G k FORM #6 PLEASE READ Instructions for co e Sampler must place a "C" for composite sample or a "G" for eting this fo on the reverse side. Q 3(J Grab sample in the blocks above for each parameter requested.M_ 0 342346 FA51 %19: Chain ®f Custody Page I ®f 2 13 of 14 FA51719 SGS Sample Receipt Summary Date / Tit ob Number. FA51719 Client: ENV. 1 ne Received: 2/10/2018 9:30:00 AM Delivery Method: D: IR 1; Therm CF: 0.4; Project: PASQUOTANK CO. FED EX Airblll #'s: 1001893351360003281100420040462988 # of Coolers: 1 WATER Therm Cooler Temps (Raw Measured) °C: Cooler 1: (4.4); Cc oler Temps (Corrected) °C: Cooler 1: (4.8); 1. Custo Y or N ly Seals Present © ❑ Samole Information 1. Sample labels present on bottles Y or ® N N/A 2. Custo ly Seals Intact ® ❑ 'feria 2. Samples preserved property © ❑ ❑ 3. Temp achieved © ❑ 3. Sufficient volume/containers recvd for analysis: ® ❑ 4. Cooler temp verification IS Gun 4. Condition of sample Intact 5. Coote media Ice !Baal 5. Sample recvd within HT © ❑ 6. Dates/rimes/IDs on COC match Sample Label ® ❑ Y or N N/A 7. VOCs have headspace ❑ ❑ 1. Trip B El present / cooler ❑ © 8. Bottles received for unspecified tests ❑ 21 2. Trip Blank listed on COC ❑ ❑ © 9. Compositing instructions dear ❑ ❑ W or S N/A 10. Voa Soil Kits/Jars received past 48hrs7 ❑ ❑ 3. Type TB Received ❑ ❑ ® 11. % Solids Jar received? ❑ ❑ 12. Residual Chlorine Present? ❑ ❑ 10 Number of Encores: 25 -Gram 5 -Gram Number of 5035 Field Kits: Number of Lab Filtered Metals: Test S1 rip Lot #s: pH 0-3 230315 pH 10.12 219813A Other: (Specify) Residual Chlorine Test Strip Lot #: Comment smoRw. D Technician: SHAYLAP Date: 2/10/2018 9:30:00 AM Rev. Date44117 Reviewer. SP Date: 2/10/2018 FA51719: Chagas of Custody Page 2 of 2 14 of 14 �`y FA61719 Pasquotank County WTP 2018 Class B Annual Report WQ Permit# WQ0008008 Land Al2plication Field Summary Form C v A cV O 0 U V ° U LL O m Pups N O U R+ '. m � V R o C0 0 �" O p ski ti C M N M Y � V' A (� N U Q � Z v q 0 N G GO N O O N o - N 9 R C, N'o NO � N G\ L O O O V w CQ CO r— r- r a V aV. O Rr �i O a O cq rcq O Q O U N � v 0 0 0 0 Y o 0 0 r Q C � O O vA b O n N M MW y a O N 7 O O r N O U A •�•� •y0 00 N i � d c V A � v 'o A v u r- M N M b o V H o 0 0 r p c cn �^ 0 0 o "I - Cd Cd U 0 0 0 CD o 16 m m U 00 C, . o +7 O O O m wo cd y x m � y •° � b v o V � V " m M A 0 Ocq a o H P4 u R°1 v A cV O 0 O P N fJ U U N O HUP.0 U P" '. o" C) 0 O� 0 V o M GC ul M � [� N V Q .Ni c v a O N O O N O pp .0 a0 O O O W v w a o o F v m 00 a V b O M Ca o U Cl o O o Q o O O v� � G v � o 0 0 .o ro N u 00 o cva ra O O O N O N O U M ~O V O `V o O a U A ° F. vvo A vC, °. 0 H V 0 0 0 c � a C, o o M c O M M L ro C A ro It O O O O O O M v U o o 0 0 ' Cl m o 0 0 �J 6 O O O M o 00 .� v v oN v t o U M A Cq o No A O r O P N fJ U U N O HUP.0 U P" '. ° co 0 00 0 V o M GC ul M � V rT« � ^ F-1 [� N V Q w � aijy 0 M O M O t— oo N o o o 6 °2 0 c, oo v U w O 41 Z O O O M a V O O 00 Ca O O O U o N w O O o r v � G v � o 0 0 0 .o ro "t 00 q ? v ra O N O M O r N O U m A oo0 0 00 O A � H Q vCq A v N v No oo � 0 � V 0 0 0 C, o o v7 C'� A o O O M L ro V ro It o O O Dd o o ° m o o vCqv o m A CqM U o H 0.0�i V Rv No A O r O P N fJ U U N O HUP.0 U P" '. o" C) 0 C, 0 V o M GC ul M � .� rT« A [� N V w � aijy 0 C,o C, u1 C. M 00 G\ 00 G1 N O O O N o 0 o a0 v U w O 41 a V y N O N b O O N O N O A o U Cl o O o Q o O O v � G � 0 0 .o cq It 00 ID q ? v ra r O O O N O r N O U m A o AF N N V cq `V o O U A � i m o A v 00 7 N oo 0 0 0 In c H0 U a C, v7 O V A ro It O O O O O O M A. 0 0. 10 m o o O 00 o .� v v m cqM v U No A O r O P N fJ U U N O HUP.0 U P" '. o" C) 0 C, 0 V zz o M GC ul M � V � ^ F-1 [� N V Q .Ni c v a O Vr o o,o M O C0 G, N O O N N C, 4 N C� O V M C\ M °J o o 0 o c, a0 v N U w O 41 .O. a V y1 O V V b O O N O O N O Ca o U � o o O o w o O o v � G � 0 0 p, o CS v ra O O co O NCq O r N O U Q [� ON , V c o N O A � v v O A v CT 7 M M O M 0 H V 0 0 0 � o � v7 � c O N M L ro ro � O O O O O O M V v v o 00 .� v vCqv o U m CqM No A O r O P N fJ U U N O HUP.0 U P" '. o" C) 0 C, 0 V o M GC ul M � V rT« � ^ F-1 [� N V .Ni c v a 0 N N oo u1 O c. M N r G\ 00 G1 N O O O N o o 11' 0 r o a0 v U w O GO 07 � O � r a V y O O Cl b O O N O N O Ca o U Cl O O o � w o 0 0 v � G v � o 0 0 c3 `° 7 ? v ra .N. O O O N O r N O U m r C� O A E N c, , iA-! V N O A � o H Q v w q v v n 0 0 0 0 � � V C, v7 L ro v A ro It O O O O O O M Dd o Ln ° o r r- m Lf) o CD 0 �J O O O M �a v 00 o .� v v m A cqM v U o No A O Pasquotank County WTP 2018 Class B Annual Report WQ Permit# WQ0008008 Soil Samples LOQ)O O O U)i Wa O = O = \ fn N C/)C U W Z WLU o a o O CD r OO Z Z O R M M E N N O O O Z Z ) Z — y U) fA W co a O O iz O m M M � E N N O O O Z Z z — �� N a fA W N = OO Z Z O m M M E N N O O O Z Z z (nO U) a fA N Z CT O m 0 0 m 0 0 m 0 0 O O CO C14 a- 0 . N m W p O z M R z M ca z M — o o o O a' L O w O > Coo Coo C o 0 > a Q - C M - C - C N 0 o Q N o o Q N o o Q C V C N 00 C O LO N N N cc tB co mY L L L p a s N a s N 000 a s N oO U M= j CD or (6 N U to O U to N U to T CN a (6 m CV (6 m N (6 t6 N N V Q CN V Q co Z .T. 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