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HomeMy WebLinkAboutNCS000329_Monitoring Reports_20140228February 28, 2014 Attn: Central Files V cEN N.C. Division of Water Quality MpR 0 6 2G14 1617 Mail Service Center jr-[RALFILES Raleigh, NC 27699-1617 )\NQIBOG Central Files: ATIaivac P.O. Box 5030 2020 Ashcraft Avenue Monroe, NC 28111-5030 Phone: (704) 289-4511 Fax: (704)290-5194 Email: joe.hinkle(&atimetals.com Attached, please find stormwater monitoring data for Permit No NCS000329. The originals and one copy are included. The monitoring data is for the following monitoring schedule. Monitoring Period Sample Number I Start End Year 4 — Period 2 8 1 Se tember 1, 2013 Februa 28, 2014 Analytical monitoring includes: • Outfall #01 (B), commingled stormwater • Outfall #02 (B), non -commingled stormwater • Outfall #03 (B), non -commingled stormwater • Non Contact Cooling Water #1 - #8 If you have any questions or need additional information, please contact me at 704-289-4511. Thank you. Sincerely, e Hinkle Environmental Manager ATI Plant MonitoringStormwater Report, Sample Date: Sample Location: Person Collecting Samples: Laboratory Performing Analysis: Analytical Techniques andMethods: Results of Sample Analysis: Sample Time: Starmwater Discharge Outf all #Ol (Commingled) Drainage Area = 2,915,470sq. ft. = 69 acres % Impervious = 34% ' f k'6d Parameter Results (mg/1) Benchmark Values (mg/1) BOD 1316 30 COD 120 TS S 100 Cadmium 0.001 Chromium, total recoverable 1 Copper, total recoverable 0.007 Nickel, total recoverable 0.26 Zinc, total recoverable E 0.067 Oil and Grease A 20 Temp (effluent) ge / (deg C) n/a Temp (downstream) (deg C) n/a Tomp (upstream) (deg C) it/a Total Residual Chlorine 0.017 pH (std units) 6-9 (std units) Q)torm Date: Storm Duration: (Hrs.) Inches of Rainfall: Duration of time preceding rain event exceeding .1": "1 J (Hrs.) Estimated Flow Calculation: Q=CIA Q(Total) = Q(Pervious Area) + Q(Impervious Area) Q(tot., cfs) = (A x inches rain/12 inches/ft. x 69 acres x .66) + .9 x inches rain/12inches/f1. x 69 x .34) Q(Total, cfs)=1.5180 x — 6.50 0} (Inches of rain) + 1.7595 x (, 501 (Inches of rain) �. 1,337 - cfs Allvac - Bakers Plant Stonnwater Monitoring Re ort Fonn =p Cample Date: Sample Location: Person Collecting Samples: Laboratory Performing Analysis: Analytical Techniques and Methods - Results of Sample Analysis: Sample Time: 3."',3 1 All? Stormwater Discharge Outfall #02 (Non -Commingled) Drainage Area = 212,952sq.. ft. = 4.9 acres % Impervious = 12% n 14111, /V �ile a- 40 CFR.Pxt j 3 Parameter Results (mg/1) Benchmark Values (mg/1) BOD 30 COD 120 TSS 100 Cadmium 0.001 Chromium, total recoverable Q. q I Copper, total recoverable 0.007 Nickel, total recoverable 6, 633,�' 0.26 Zinc, total recoverable 641 001 0.067 pH (std units) 6-9 (std units) Qtorm Date: 117N Storm Duration: (Hrs.) Inches of Rainfall: ; il Duration of time preceding rain event exceeding 0.1 ": -J& — (Hrs.) Estimated Flow Calculation: Q = CIA Q(Total) = Q(Pervious Area) + Q(Irnpervious Area) Q(tot., cfs) = (A x inches rain/12 inches/ft. x 4.9 acres x.88) +.9 x inches rain/12inches/ft. x 4.9 x.12) Q(Total,cf§)=0.l437x_ J),-50 (Inches of rain) + 0.0441 x —L.56 (Inches of rain —cfs W "'ATI AllvaJ r Allvac - Bakers Plant Stormwater Monitorin Report Form . Ild C,ample Date:-. Sample Location: Person Collecting Samples: Laboratory Performing Analysis: Analytical Techniques and Methods: Results of Sample Analysis: Qample Time: Stormwater Discharge Outfall #03 (Non -Commingled) Drainage Area = 336,580sq. ft. = 7.8 acres % Impervious = 15% 110s32In Xawdoa 4 /1 4,cr MA/4 I U911WIMM Parameter Results (mg/1) Benchmark Values (mg/1) BOD 69 30 COD 120 TSS fs 100 Cadmium 0.001 Chromium, total recoverable I Copper, total recoverable 0.007 Nickel, total recoverable 0t 0.26 Zinc, total recoverable 6,363 0.067 pH 9 (std units) 6-9 (std units) Storm Date: - -V-P/ Storm Duration: Mi (Hrs.) Inches of Rainfall: 0,0, Duration of time preceding rain event exceeding 0.1": _� �Y(Hrs.) Estimated Flow Calculation: Q = CIA Q(Total) = Q(Pervious Area) + Q(Itnpervious Area) Q(tot., cfs) = (A x inches rain/1 2 inches/ft. x 7.8 acres x .85) +.9 x inches rain/1 2inches/ft. x 7.8 x .15) Q(Total, cfs) = 0.2210 x (Inches of rain) + 0.0878 x _-6, (Inches of rain) 15#4 cfs (IQ cl 04. IZS �p > r- -0 (A 0 14 M � CD to ft C> ON �A 1 c O c O d O m A "f W y v� O o d � 9 0oCD r.i w M C. i m y o O" CA d m a O O�4 A C J ((n W �: 0 o cn H O �.• ° O y M p t= �mto ab n \. a, . O. M ram., fD ^'r M_ •�, y �Ay VI ram+. v�i C rye.4 i�i rD ld M ffb y w ry GM C >v 'U o r.r 0 00 0 y b cm A �* ego AsIs d tr eo K fD A l9 A 10 in a Pell O � � O Orly s m CL � CD ;CPa dodM• �• � CD (CD O O i�+ e� C Q\ •U J. rt l O fb C C � ArA J � p " >n A aAIE QuaUtative Monitoring Report For guidance on filling out this form, please visit.' httu://h2o.car.state.nc.us/su/Forms Documents.htmOmiscforms Permit No.: &C Facility Name: County: Inspector: DaEe of luspection: Time of Inspection: lri 11 l or Certificate of Coverage No.: NIC IGI �r 47 r4 _ r�A Y®P� W la ®o Total Event Precipitation (inches): a . —) Was this a Representative Storm Event? (See information below) ,lees ❑ No Please check your permit to verify if Qualitative Monitoring must be performed during a representative storm event (requirements vary). A "Representative Storm Event" is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has I occurred. A single storm event may contain up to 10 consecutive hours of no z)reciDitation. i By this signat0a, I certify that this report is accurate and complete to the best of my knowledge: 11 (Signature of 1. Out€all Deser Vutfalf NO. . Receiving Stream: Describe the industrial Structure ( -pe, ditch, etc.) 3 s t I Uj q t� that occur within the outfall drainage area: 2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: #f -- b rp et) A_ 3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak - chlorine odor, etc.): 110 ti C_ Page I of 2 5wU-242—I 22608 4. Clarity: Choose the number which best describes the clarity of the discharge, where I is clear and 5 is very cloudy: 1 20 3 4 5 5. Flouting Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids- I ( 3 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and.5 is extremely muddy: I 3 4 5 7. Is there any foam in the stormwater discharge? Yes (N)o 8. Is there an oil sheen in the stormwater discharge? Yes 9. Is there evidence of erosion or deposition at the outfall? Yes No 10. Other Obvious Indicators of Stormwater pollution: List and describe Mote: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 SWU-242-112608 aAT o L Qualitative Monitoring Report .For guidance on filling out this form, please visit.- http://h2o.enr.state.nc.us/su/Forms Documents.htmfmiscforms Pe snit No.: N/Ck_ Facility Name: -' County: Inspector: M s Date of Inspection: Tinge, of Inspection: Total Event Precipitation (inches): s ' er of Coverage No.: NICIGI / l l l l l Was this a Representative Storm Event? (See information below) es ❑ No Please check yourpermit to verify if Qualitative Monitoring must be performed daring a representative storm event (requirements vary). A "Representative Storm Event" is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has i occurred. A single storm event may contain up to 10 consecutive hours of no Drecigitation. i By this signapre, I certify that this report is accurate and complete to the best of my knowledge: A (Signature of Permi*4 or 1. Outfall Description: Outfah No. iJ ol,)- Receiving Stream: AkV Describe the industrial actlTlcb ditch, etc.) 1 1 /� iye' that occur within the outfall drainage area: 2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: k+ b(r) ; 3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak - chlorine odor, etc.): Page I of 2 S VVU-242-112608 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 3 4 5 5. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: 1 3 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: 4 5 7. Is there any foam in the stormwater discharge? Yes F. Is there an oil sheen in the stormwater discharge? Yes l�lo 9. Is there evidence of erosion or deposition at the outfall? Yes o 10. Other Obvious .Indicators of Stormwater Pollution: List and describe Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 SWU-242-112608 I. 5TATIE For guidance on filling out this form, please visit: http:/A3,2o.enr.state.ne.us/su/Forms Documeats.htm-Pmiscfarms Permit No.: N/C/,. Facility Name: Z County: ailr Inspector: lom Date, of l'nspectiorr Time, of Inspection: / °F Certificate of Coverage No.: NIC/G/T/ Total Event Precipitation (inches): No. Was this a Representative Storm Event? (See information below) 2ry.s ❑ No Please check your permit to verify if Qualitative Monitoring roust be performed during a representative storm event (requirements vary). A "Representative Storm Event" is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has i occutred. A single storm event may contain up to 10 consecutive hours of no urecinitation. By this sigpture, I certify tat this report is accurate and complete to the best of my knowledge: (Signature of Permi'teb, or 1. Outfall Description: Outfall No. 5 LJ6, P.e-% �� ceiving Stream: d.li^y Describe the industrial_ actiditi /)--1.)6 i _JL .- ti Structure (pipe, ditch, etc.) F ,C_rV ,- _ _ iv ur within the outfall drainage area: 0 (a_ � c 2. Color: Describe the color of the di s harge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: 4 LA U 3. Gdor: Describe any distinct odors that the discharge may have (i.e., smeIls strongly of oii ,we chlorine odor, etc.): VI 0 A C Page I of 2 SWU-242-I I2608 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 2 3 4 5 5. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: 1 3 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids a.1Yd 5 is c;:awnely uluddy: 1 2 3 4 5 7. Is there any foam in the stormwater discharge? Yes No f. 8. Is there an oil sheen in the stormwater discharge? Yes No 9. Is there evidence of erosion or deposition at the outfall? Yes DO 10. Other Obvious Indicators of Stormwater Pollution: List and describe Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposi on may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 SWU-242-112600 aceAnalytical www.pacelabs.c= February 11, 2014 Mr. Joe Hinkle Allvac RE: Project: BAKER STORMWATER SW01 Pace Project No.: 92188821 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Dear Mr. Hinkle: Enclosed are the analytical results for sample(s) received by the laboratory on February 05, 2014. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, a� n Wad Frin Waters enn.watersLpacelabs.com Project Manager Enclosures cc: Mr. Preston Baucom, Allvac Mr. Tommy Long, Allvac REPORT OF LABORATORY ANALYSIS This report shall not be rermduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 14 aceAnaiXical www.pacelabs.com CERTIFICATIONS Project: BAKER STORMWATER SW01 Pace Project No.: 92188821 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Florida/NELAP Certification #: E87627 North Carolina Drinking Water Certification #: 37706 Kentucky UST Certification #: 84 North Carolina Field Services Certification #: 5342 West Virginia Certification #: 357 North Carolina Wastewater Certification #: 12 Virginia/VELAP Certification #: 460221 South Carolina Certification #: 99006001 Asheville Certification IDs 2225 Riverside Dr., Asheville, NC 28804 North Carolina Wastewater Certification #: 40 Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001 Massachusetts Certification #- M-NC030 West Virginia Certification #• 356 North Carolina Drinking Wator Cortiflcation #- 377,12 Vlrginln/VCL AI' Cortifcation #, 460422/2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 14 (�Iacmnalytical" wm..pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: BAKER STORMWATER SW01 92188821 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92188821001 BAKERS STORMWATER SW01 GRAB EPA 1664E CLW 1 PASI-C EPA200.7 SH1 5 PASI-A SM 2540D WRC 1 PASI-A SM 4500-CI G AES2 1 PASI-A SM 5210B DAS 1 PASI-A SM 5.2201) EWS I PAS[ A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 14 aceAnalj4ical www.pacelabs.com ANALYTICAL RESULTS Project: BAKER STORMWATER SW01 Pace Project No.: 92188821 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: BAKERS STORMWATER Lab ID: 92188821001 Collected: 02/04/14 14:58 Received: 02/05/14 17:00 Matrix: Water SW01 GRAB Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[ HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mg/L 5.0 1 02/06/14 08:45 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Cadmium ND ug/L 1.0 1 02/06/14 08:60 02/11/14 11:52 7440 43 9 Chrorrilum ND ug/L 6.0 1 02/06/ 14 08:b0 02/09/14 16:52 1440-41-3 Copper •18.5 ug/L b.0 1 02/06/14 08:50 02/09/14 16:52 /440-50-8 Nickel ND ug/L 5.0 1 02/06/14 08:50 02/09/14 16:52 7440-02-0 Zinc 25.0 ug/L 10.0 1 02/06/14 08:50 02/09/14 16:52 7440-66-6 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 8.2 mg/L 5.0 1 02/10/14 16:13 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G Chlorine, Total Residual 0.068 mg/L 0.024 1 02/06/14 09:32 7782-50-5 H3 5210E BOD, 5 day Analytical Method: SM 5210B BOD, 5 day 3.0 mg/L 2.0 1 02/07/14 07:09 02/11/14 09:25 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 33.0 mg/L 25.0 1 02/07/14 13:30 Date: 02/11/2014 05:27 PM REPORT OF LABORATORY ANALYSIS This report ehall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 14 aceAnalytical ww.pacelabs.c= QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: BAKER STORMWATER SW01 Pace Project No.: 92188821 QC Batch: GCSV/16595 Analysis Method: EPA 1664E QC Batch Method: EPA 1664E Analysis Description: 1664 HEM, Oil and Grease Associated Lab Samples: 92188821001 METHOD BLANK: 1133931 Matrix: Water Associated Lab Samples: 92188821001 Blank Reporting Parameter Units Result Limit Anuly�c:d Qualiriei8 Oil and Grease mg/L ND 5.0 02/06/14 08,39 LABORATORY CONTROL SAMPLE: 1133932 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Oil and Grease mg/L 40 37.6 94 78-114 MATRIX SPIKE SAMPLE: 1133933 92188301001 Spike MS MS % Rec Parameter Units Result Cone. Result % Rec Limits Qualifiers Oil and Grease mg/L ND 41.7 40.4 88 78-114 REPORT OF LABORATORY ANALYSIS This report shall not be reprodueed, exeept in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 14 aceAnalytical www.pacelabs.corn Project: BAKER STORMWATER SW01 Pace Project No.: 92188821 QC Batch: MPRP/15194 QC Batch Method: EPA 200.7 Associated Lab Samples: 92188821001 METHOD BLANK: 1133916 Associated Lab Samples: 92188821001 Parameter Units Cadmium tig/t Chromium ug/t Copper ug/L Nickel ug/L Zinc ug/L QUALITY CONTROL DATA Analysis Method: EPA200.7 Analysis Description: 200.7 MET Matrix: Water Blank Result Reporting Limit Analyzed NC) 10 02/11/1411-25 ND 50 02/09/14 16-15 ND 5.0 02/09/1416:15 ND 5.0 02/09/1416:15 ND 10.0 02/09/1416:15 Qualifiers LABORATORY CONTROL SAMPLE: 1133917 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Cadmium ug/L 500 516 103 85-115 Chromium ug/L 500 494 99 85-115 Copper ug/L 500 522 104 85-115 Nickel ug/L 500 504 101 85-115 Zinc ug/L 500 489 98 85-115 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1133918 1133919 MS MSD 92188808001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua] Cadmium ug/L ND 500 500 487 480 97 96 70-130 1 Chromium ug/L ND 500 500 480 486 95 96 70-130 1 Copper ug/L 114 500 500 640 640 105 105 70-130 0 Nickel ug/L 7 9 500 500 480 488 94 96 70-130 2 Zinc ug/L 303 500 500 776 784 95 96 70-130 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1133920 1133921 MS MSD 92188777001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Cadmium ug/L ND 500 500 516 514 103 103 70-130 1 Chromium ug/L 0.53J 500 500 496 488 99 98 70-130 2 Copper ug/L 5.1 500 500 535 532 106 105 70-130 1 Nickel ug/L ND 500 500 506 495 101 99 70-130 2 Zinc ug/L 195 500 500 693 670 100 95 70-130 3 Date: 02/11/2014 05:27 PM REPORT OF LABORATORY ANALYSIS This repurL shall not be repruduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 14 acmnalytical www.pwdabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: BAKER STORMWATER SW01 Pace Project No.: 92188821 QC Batch: WET/29471 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92188821001 METHOD BLANK: 1136199 Matrix: Water Associated Lab Samples: 92188821001 Blank Reporting Parameter Units Result 1-hrill AiialyLed Qualifiers dotal Suspended Solids mg/L ND 2 5 02/10/14 16-08 LABORATORY CONTROL SAMPLE: 1136200 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 248 99 80-120 SAMPLE DUPLICATE: 1136201 92188644001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 6.9 6.7 3 SAMPLE DUPLICATE: 1136202 92188815001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 44.3 45.3 2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 14 4 acmnalXical www.pacelabs.com Project: BAKER STORMWATER SW01 Pace Project No.: 92188821 QC Batch: WET/29440 QC Batch Method: SM 4500-CI G Associated Lab Samples: 92188821001 METHOD BLANK: 1134928 Associated Lab Samples: 92188821001 Parameter Units Chlorine, Total Residual mg/t QUALITY CONTROL DATA Analysis Method: SM 4500-CI G Analysis Description: 4500CL G Chlorine, Total Residual IIITiFla =YMPMt i Dlank Reporting Result Limit Analyzed Qualifiers ND 0 024 02/06114 09-32 SAMPLE DUPLICATE: 1134929 92188325001 Dup Parameter Units Result Result RPD Qualifiers Chlorine, Total Residual mg/L 0.033 0.034 3 REPORT OF LABORATORY ANALYSIS This repurt shall nut be reproduced, except In Full, Date: 02/11/2014 05:27 PM without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 14 aceAnalyticai® wwwpacelabs.com QUALITY CONTROL DATA Project: BAKER STORMWATER SW01 Pace Project No.: 92188821 QC Batch: WET/29408 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 92188821001 METHOD BLANK: 1133903 Associated Lab Samples: 92188821001 Parameter Units B01), 5 day mg/1 LABORATORY CONTROL SAMPLE: 1133904 Parameter Units BOD, 5 day mg/L Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Matrix: Water Blank Reporting Result Llinil Analyzed Qualifers ND 2 0 02/11 /14 0975 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 198 173 87 84.5-115.4 SAMPLE DUPLICATE: 1133905 92188706001 Dup Parameter Units Result Result RPD BOD, 5 day mg/L 378 339 11 REPORT OF LABORATORY ANALYSIS This repurt shall nut lie reproduced, except in full, Date: 02/11 /2014 05:27 PM without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 9 of 14 aceAnalytical www.pacefabs.= Project: BAKER STORMWATER SW01 Pace Project No.: 92188821 QC Batch: WETA/17985 QC Batch Method: SM 5220D Associated Lab Samples: 92188821001 METHOD BLANK: 1134191 Associated Lab Samples: 92188821001 Parameter Units Chomical Oxygon Domand mg/1 QUALITY CONTROL DATA Analysis Method: SM 5220D Analysis Description: 5220D COD Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers NE) 25 0 02/07/14 13-30 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1134192 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg/L 750 736 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1134193 1134194 MS MSD 92188/13001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Conc. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg/L 461 750 750 1050 1060 79 80 75-125 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1134195 1134196 MS MSD 92188710001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua[ Chemical Oxygen Demand mg/L 2220 3000 3000 5100 5180 96 99 75-125 2 REPORT OF LABORATORY ANALYSIS I his report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 14 acmnalXical wwwpacelabs.com QUALIFIERS Project: BAKER STORMWATER SW01 Pace Project No.: 92188821 DEFINITIONS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-Adjusted Method Detection Limit. PRL - Pace Reporting Limit. RL Roporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PAST -A Pace Analytical Services -Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS H3 Sample was received or analysis requested beyond the recognized method holding time. REPORT OF LABORATORY ANALYSIS I his report shall not be reproduced, except in full, Date: 02/11 /2014 05:27 PM without the written consent of Pace Analytical Services, Inc.. Page 11 of 14 Pace Analytical Services, Inc. Analytical ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 as QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: BAKER STORMWATER SW01 92188821 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92188821001 BAKERS STORMWATER SW01 EPA 1664B GCSW16595 GRAB 92188821001 BAKERS STORMWATER SW01 EPA 200.7 MPRP/15194 EPA 200.7 ICP/13792 GRAB 92188821001 BAKERS STORMWATER SW01 SM 2540D WET/29471 GRAB 99188891001 BAKE-R8 8IORMWAIEPo SW01 5M 000 Cl G WET/20440 GRAB 92188821001 BAKERS STORMWATER SW01 SM 5210B WET/29408 SM 5210B WET/29437 GRAB 92188821001 BAKERS STORMWATER SW01 SM 5220D WETA/17985 GRAB Date: 02/11/2014 05:27 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 14 p�CeArla/vfica! Sample Condition Upon Recei Document Number: F-CHR-CS-03-rev.13 Page 1 of 2 Issuing Authority: Pace Huntersville Quality Office Client Name: k&Np' Co Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑] /Commerciae Pace Other Custody Seal on Cooler/Box Present: ❑ yes � no Seals intact: ❑ yes ❑ no Optional Proj. Due Date: Proj. Name: Packing Material: ❑ Bubble Wrap ❑ Bubble Bags ❑ None n Other Thermometer Used: IR Gun T1102 T1 01 Type of Ice: a Blue None El,->�Ples on ice, cooling process has begun Tamn rnrrartinn Fnrtnr T1102• Nn CnrrPrtinn T1301: Nn CnrrPrtion Corrected Cooler Temp.: -- C Temp should be above freezing to 6°C Biological Tissue is Frozen: Yes No N/A Comments: Date R nn n examining Initial f p rso Chain of Custody Present: Yes ONO ❑NIA 1. Chain (if Custody Filled Out. 2 Yea ONO ❑N/A 2. Chain of Custody Rolinquishod 4. Sampler Name & Signature on COC: Samples Arrived within Hold Time: ❑ s ONO ❑ s ONO ❑NIA ❑NIA 5. Short Hold Time Analysis (<72hr): ❑Yes RNo ❑N/A 6. Rush Turn Around Time Requested: ❑Yes ONO ❑N/A 7. Sufficient Volume: Yes ❑No ❑N/A 8. Correct Containers Used: -Pace Containers Used: ONO (7ys []No El NIA nN/A 9. Containers Intact: 16Y9 ONO ❑N/A 10. Filtered volume received for Dissolved tests ONO ❑N/A 11. Sample Labels match COC: -Includes date/time/ID/Analysis Matrix: es ONO ❑N/A 12. All containers needing preservation have been checked. All containers needing preservation are found to be in compliance with EPA recommendation. exceptions: VOA, coliform, TOC, O&G, Wl-DRO (water) Yes ONO es El No ❑Yes ❑No ❑NIA ❑N/A 13. Siainhlu, 0ioc.ked for dschlorinatiow Fl es CINo t iNIA 14_ 15. Headspace in VOA Vials >6mm : ❑Yes ONO/ ❑N/A Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): ❑Yes ONO ❑Yes ONO 71A ON/A 16. Client Notification/ Resolution: Field Data Required? Y / N Person Contacted: Date/Time: Comments/ Resolution: SCURF Review: (' 'L) Date: O� m SRF Review:L Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le out of hold, incorrect preservative, out of temp, incorrect containers) WOit:92388821 1111111111111111111111 92188821 Page 13 of 14 ITEM # v 3 0 A CD C 14 3 .� 3 n o cu C) O a CJD n 0 v) yo � p Y 1 D i� m a)m y+` -. s h O m Z v m x r z 02 U, N J © 0- S. O O O (wD Np lN4 i Z Z m 1 7 r j m r 3 m O o n G� � -y � ...1r ..5� MATRIX CODE (see valid codas to IaH) i Z 0 Z P R 3 o J �a i(+ SAMPLE TYPE (G=GRAB C=COMP) S ti 3 m > mG m ya o 3 0 O m N v A � z ,T m m i a 3 C a n C eZi R' m m Z �� " "j^' ...` ` m i 90 O �' ,321 D > r 1 m ., } b m ^` SAMPLE TEMP AT COLLECTION ? A m •...J ,� " '— .... — # OF CONTAINERS d " A n 0 a i E 1 m o ' o Unpreserved H2SO4 u a HNO3 m s i HCI m NaOH 0 Na2S203 y Gs Methanol e Other 03 � j Analysis Test j Y/ N i 3 m C CG m r N A T -n 1 m �J 1 A Z t-, At A bm An D 0 c z z -0C EQ p Ten in °C Residual Chlorine (YIN) 1 m A Received on Ice (Y7N) D - mr m Custody m 0 'U 0 o Sealed Cooler O 0 (YIN) Z Z .nm. C m W N Samples Intact m D (Y/N) O m O A 0 m n D m _ o Z C0 ' �Q a ii H n N C �Q 00 0 � 1 m > z = D 2) io < m m 0 I ID ;0 N c M m oN o 0 rs � v3 K rr 14 of 14 acmnalytical www.pacWabs.c= February 11, 2014 Mr. Joe Hinkle Allvac RE: Project: Bakers Stormwater SW02 Pace Project No.: 92188809 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Dear Mr. Hinkle: Enclosed are the analytical results for sample(s) received by the laboratory on February 05, 2014. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Erin Waters erin.waters(§pacelabs.com Project Manager Enclosures cc: Mr. Preston Baucom, Allvac Mr. Tommy Long, Allvac REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 12 aceAnalytical wmpacelabs.com Project: Bakers Stormwater SW02 Pace Project No.: 92188809 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Asheville Certification IDs 2225 Riverside Dr., Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not he reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 12 aceAnalytical www.pacelabs.corn SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: Bakers Stormwater SW02 92188809 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92188809001 Bakers Stormwater SW02 EPA 200.7 SH1 5 PASI-A SM 2540D WRC 1 PASI-A SM 5210B DAS 1 PASI-A SM 5220D EWS 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not Le repruduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 12 aceAnalytical" wmpacelabs.cem ANALYTICAL RESULTS Project: Bakers Stormwater SW02 Pace Project No.: 92188809 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Bakers Stormwater SW02 Parameters Lab ID: 92188809001 Collected: 02/04/14 15:31 Results Units Report Limit DF Received: 02/05/14 17:00 Matrix: Water Prepared Analyzed CAS No. Qual 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Cadmium ND ug/L 1.0 1 02/06/14 08:50 02/11/14 11:44 7440-43-9 Chromium 40.9 ug/L 5.0 1 02/06/14 08:50 02/09/14 16:40 7440-47-3 Copper 245 ug/L 5.0 1 02/06/14 08:50 02/09/14 16:40 7440-50-8 Nickel 33.2 ug/L 5.0 1 02/06/14 08:50 02/09/14 16:40 7440-02-0 Zinc 283 ug/L 10.0 1 02/06/14 08:50 02/09/14 16:40 7440-66-6 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 122 mg/L 8.3 1 02/10/14 16:12 5210B BOD, 5 day Analytical Method: SM 5210B BOD, 5 day 2.3 mg/L 2.0 1 02/07/14 07:09 02/11/14 09:25 5220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 28.0 mg/L 25.0 1 02/07/14 13:30 Date: 02/11/2014 05:28 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 12 aceAnalytical vlmpecelabs.00m QUALITY CONTROL DATA Project: Bakers Stormwater SW02 Pace Project No.: 92188809 QC Batch: MPRP/15194 Analysis Method: EPA200.7 QC Batch Method: EPA200.7 Analysis Description: 200.7 MET Associated Lab Samples: 92188809001 METHOD BLANK: 1133916 Associated Lab Samples: 92188809001 Parameter Units (1admiLlm Chromium Copper Nickel Zinc u0/t ug/L ug/L ug/L ug/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 10 02111/1411-25 ND 6.0 02/0911416:16 ND 5.0 02/0911416:15 ND 5.0 02/0911416:15 ND 10.0 02/0911416:15 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1133917 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Cadmium ug/L 500 516 103 85-115 Chromium ug/L 500 494 99 85-115 Copper ug/L 500 522 104 85-115 Nickel ug/L 500 504 101 85-115 Zinc ug/L 500 489 98 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1133918 1133919 MS MSD 92188808001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qua[ Cadmium ug/L ND 500 500 487 480 97 96 70-130 1 Chromium ug/L ND 500 500 480 486 95 96 70-130 1 Copper ug/L 114 500 500 640 640 105 105 70-130 0 Nickel ug/L 7 9 600 600 480 488 04 06 70.130 2 Zinc ug/L 303 500 500 776 784 95 96 70-130 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1133920 1133921 MS MSD 92188777001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Conc. Result Result % Rec % Rec Limits RPD Qual Cadmium ug/L ND 500 500 516 514 103 103 70-130 1 Chromium ug/L 0.53J 500 500 496 488 99 98 70-130 2 Copper ug/L 5.1 500 500 535 532 106 105 70-130 1 Nickel ug/L ND 500 500 506 495 101 99 70-130 2 Zinc ug/L 195 500 500 693 670 100 95 70-130 3 Date: 02/11/2014 05:28 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 12 (�Iacmnalyticalo www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Bakers Stormwater SW02 Pace Project No.: 92188809 QC Batch: WET/29471 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92188809001 METHOD BLANK: 1136199 Matrix: Water Associated Lab Samples: 92188809001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/t NI) 2 5 02/10/14 16:08 LABORATORY CONTROL SAMPLE: 1136200 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 248 99 80-120 SAMPLE DUPLICATE: 1136201 92188644001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 6.9 6.7 3 SAMPLE DUPLICATE: 1136202 92188815001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 44.3 45.3 2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 02/11 /2014 05:28 PM without the written consent of Pace Analytical Services, Inc.. Page 6 of 12 aceAnalj cal www.pacelabs.com Project: Bakers Stormwater SW02 Pace Project No.: 92188809 QC Balch: WET/29408 QC Batch Method: SM 5210B Associated Lab Samples: 92188809001 METHOD BLANK: 1133903 Associated Lab Samples: 92188809001 Parameter Units ROn, 5 day m©/t QUALITY CONTROL DATA Analysis Method: SM 52106 Analysis Description: 5210B BOD, 5 day Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers NI) 2 0 02/11/14 09,2E Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1133904 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day mg/L 198 173 87 84.5-115.4 SAMPLE DUPLICATE: 1133905 92188706001 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 378 339 11 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/11 /2014 05:28 PM without the written consent of Pace Analytical Services, Inc.. Page 7 of 12 aceAnalytical vlm.pacelabs.com Project: Bakers Stormwater SW02 Pace Project No.: 92188809 QC Batch: WETA/17985 QC Batch Method: SM 5220D Associated Lab Samples: 92188809001 METHOD BLANK: 1134191 Associated Lab Samples: 92188809001 Parameter Units Chemical Oxygen Demand m0/L QUALITY CONTROL DATA Analysis Method: SM 5220D Analysis Description: 5220D COD Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 25 0 02/07/14 11 30 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1134192 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg/L 750 736 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1134193 1134194 MS MSD 92188713001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua[ Chemical Oxygen Demand mg/L 461 750 750 1050 1060 79 80 75-125 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1134195 1134196 MS MSD 92188710001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua] Chemical Oxygen Demand mg/L 2220 3000 3000 5100 5180 96 99 75-125 2 Date: 02/11/2014 05:28 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 12 leAnalytical www.pacelabs.com QUALIFIERS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Bakers Stormwater SW02 Pace Project No.: 92188809 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PRL- Pace Reporting Limit. RL- Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270listed snalyte) decomposes toAzobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/11 /2014 05:28 PM without the written consent of Pace Analytical Services, Inc.. Page 9 of 12 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: Bakers Stormwater SW02 92188809 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92188809001 Bakers Stormwater SW02 EPA 200.7 MPRP/15194 EPA 200.7 ICP/13792 92188809001 Bakers Stormwater SW02 SM 2540D WET/29471 92188809001 Bakers Stormwater SW02 SM 5210B WET129408 SM 5210B WET/29437 92188809001 Bakers Stormwater SW02 SM 5220D WETA/17985 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/11/2014 05:28 PM without the written consent of Pace Analytical Services, Inc.. Page 10 of 12 ��P1CeAnalfrfiral Sample Condition Upon Recei Document Number: F-CHR-CS-03-rev.13 Page 1 of Issuing Authority: Pace Huntersville Quality Office Client Name: �Aa_c , Courier: ❑ Fed Ex ❑ UPS❑ LISPS❑ Client❑ Comm cial❑ Pace Other Custody Seal on Cooler/Box Present: ❑ yes -I:n no Seals intact: ❑ yes ❑ no Packing Material: ❑ Bubble Wrap ❑ Bubble Bags F1' None ❑ Other Optional Proj. Due Date: Proj. Name: Thermometer Used: IR Gun T1102 T 30 Type of Ice:W Blue None El Samples on ice, cooling process has begun Temn Cnrrertinn Fartnr T1102: No Correction T13a1 No Correction J Corrected Cooler Temp.: k -C Temp should be above freezing to T Biological Tissue is Frozen: Yes No N/A Comments: Dateanq Initials of p son examining Chain of Custody Present: Yes ❑No ❑N/A 1. Chain of Custody Filled Out: 2 es ❑No ❑N/A 2. Chain of Custody Relinquished: o o NTA- 3— Sampler Name & Signature on COC: Yes ❑No ❑N/A 4. 5. Samples Arrived within Hold Time: es ON. El N/A Short Hold Time Analysis (<72hr): gWs ON. El N/A 6, Rush Turn Around Time Requested: ❑Yes 6No ❑NIA 7. Sufficient Volume: es ❑No ❑NIA 8, Correct Containers Used: -Pace Containers Used: YY�es ❑No 1dYe ❑No ❑NIA ❑N/A 9. Containers Intact: Yes ❑No N/A 10. Filtered volume received for Dissolved tests ❑Yes ❑No ❑N/A 11. Sample Labels match COC: -Includes date/time/ID/Analysis Matrix: ❑Yes ❑No ❑NIA 12, All containers needing preservation have been checked. All containers needing preservation are found to be in compliance with EPA recommendation. exceptions: VOA, coliform,TOG, 0&G, WI-DRO (water) 514s f YSPs 77 '' Oyes ❑No ❑No ❑No ❑NIA ❑N/A 13. Carriplou c liocl(W for duc:hluiinution. FlYra nNo CINIA 14. Headspace in VOA Vials (>6mm): Yes ❑Nod❑N/A 15, 16. Trip Blank Present: LJYes ❑No Trip Blank Custody Seals Present ❑Yes ❑No Pace Trip Blank Lot # (if purchased): f M ❑N/A Client Notification/ Resolution: Field Data Required? Y / N Person Contacted: Date/Time: Comments/ Resolution: �" ^�--�,• inr,ol hares SCURF Review: Date: i SRF Review: i Q40Date: a S) WO# : 921888109 Note: Whenever there is a discrepancy affecting North Carolina compliance IIIIIIIIIIIIIIIIIIIIII samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, )2188809 incorrect containers) Page 11 of 12 ITEM #cn o m 3 (� 75 55 i C G m CO) o OA Y 3 c0 O f 1 d z i 3 n 0 Wol x � O 3 c _m z Q m O m m o y P. 6* 018 � 0 D3 a A N N x n = D ' © m N M L c m i9 u o n o am 3 3 D O 1 U W 0. y MATRIX CODE (seo valid codes to left) c ° o m S j� SAMPLE TYPF (G=GRAB C=COMP) c o m m r v -ni m r ch T m P m m ii O rn z X M A z --1i z m ., o m _ i m �� !, �. m �o m 3 z 8 ° o r:, A A m r 1 m a ;,y SAMPLE TEMP AT COLLECTION 6 t # OF CONTAINERS �r��M n o =`o } 3 m v a n v W. W p g' o ' h v .O. % Unpreserved `r� H2SO4 �k HNO3 HCl m o. r 2 {' > NaOH v Na2S203 m y (� 9 Methanol m Other Q �`• jAnalysis Test j Y/ N j { o m S M _ C ,z M N• D m y o n�i 0 � 0_ C s 'T y O m 7 m Co0 • - a q y� 1 m 1 D A A D O z p 2 n Z m 1D Temp in °C Residual Chlorine (YIN) y Received on y � Ice (Y/N) r N N Custody Sealed Cooler m n0 ' � 1 O A °, z O m \, Q Samples Intact m D (Y/N) Cr m b � � Pa 12 of 12 aceAnalytical —pacelabs.ow February 11, 2014 Mr. Joe Hinkle Allvac RE: Project: Bakers Stormwater SW03 Pace Project No.: 92188808 IonnIVA iMMMIn, 3r4 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on February 05, 2014. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, 0, - -) M Erin Waters erin.waters@pacelabs.com Project Manager Enclosures cc: Mr. Preston Baucom, Allvac Mr. Tommy Long, Allvac pCCRF4 REPORT OF LABORATORY ANALYSIS This repurl shall not be reproduced, except in Full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 12 aceAnalytical www.pacelabs.com CERTIFICATIONS Project: Bakers Stormwater SW03 Pace Project No.: 92188808 Asheville Certification IDs 2225 Riverside Dr., Asheville, NC 28804 North Carolina Wastewater Certification #: 40 Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001 Massachusetts Certification #: M-NC030 West Virginia Certification #: 356 North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 12 lacmnalyticalo www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: Bakers Stormwater SW03 92188808 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92188808001 Bakers Stormwater SW03 EPA 200.7 SH1 5 PASI-A SM 2540D WRC 1 PASI-A SM 5210B DAS 1 PASI-A SM 5220D EWS 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 12 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Bakers Stormwater SW03 Pace Project No.: 92188808 Sample: Bakers Stormwater SW03 Lab ID: 92188808001 Collected: 02/04/14 15:40 Received: 02/05/14 17:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Cadmium ND ug/L 1.0 1 02/06/14 08:50 02/11/14 11:32 7440-43-9 Chromium ND ug/L 5.0 1 02/06/14 08:50 02/09/14 16:31 7440-47-3 Copper 114 ug/L 5.0 1 02/06/14 08:50 02/09/14 16:31 7440-50-8 Nickel 7.9 ug/L 5.0 1 02/06/14 08:50 02/09/14 16:31 7440-02-0 Zinc 303 ug/L 10.0 1 02/06/14 08:b0 02/09/14 16:31 1440-66-6 2540D total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 16.3 mg/L 2.5 1 02/10/14 16:11 5210B BOD, 5 day Analytical Method: SM 5210B BOD, 5 day 5.8 mg/L 2.0 1 02/06/14 14:48 02/11/14 12:30 L2 6220D COD Analytical Method: SM 5220D Chemical Oxygen Demand 107 mg/L 25.0 1 02/07/14 13:30 REPORT OF LABORATORY ANALYSIS This repurt shall nut be reproduced, except in ruil, Date: 02/11/2014 04:47 PM without the written consent of Pace Analytical Services, Inc.. Page 4 of 12 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: Bakers Stormwater SW03 Pace Project No.: 92188808 QC Batch: MPRP/15194 Analysis Method: EPA 200.7 QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET Associated Lab Samples: 92188808001 METHOD BLANK: 1133916 Matrix: Water Associated Lab Samples: 92188808001 Blank Reporting Parameter Units Result Limit Analyzed Cadmium ug/L, ND 10 02/111141125 Chromium ug/L ND 5.0 02/0911416-15 Copper ug/L ND 5.0 02/09/1416:15 Nickel ug/L ND 5.0 02/09/1416:15 Zinc ug/L ND 10.0 02/09/1416:15 Qualtflers LABORATORY CONTROL SAMPLE: 1133917 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Cadmium ug/L 500 516 103 85-115 Chromium ug/L 500 494 99 85-115 Copper ug/L 500 522 104 85-115 Nickel ug/L 500 504 101 85-115 Zinc ug/L 500 489 98 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1133918 MS 92188808001 Spike Parameter Units Result Cone. Cadmium ug/L ND 500 Chromium ug/L ND 500 Copper ug/L 114 500 Nickel u0/t 7.9 500 Zinc ug/L 303 500 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1133920 MS 92188777001 Spike Parameter Units Result Cone. Cadmium ug/L ND 500 Chromium ug/L 0.53J 500 Copper ug/L 5.1 500 Nickel ug/L ND 500 Zinc ug/L 195 500 Date: 02/11/2014 04:47 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers 1133919 MSD Spike MS MSD MS MSD % Rec Cone. Result Result % Rec % Rec Limits RPD 500 487 480 97 96 70-130 1 500 480 486 95 96 70-130 1 500 640 640 105 105 70-130 0 500 480 488 94 96 70-130 2 500 776 784 95 96 70-130 1 1133921 MSD Spike MS MSD MS MSD % Rec Cone. Result Result % Rec % Rec Limits RPD 500 516 514 103 103 70-130 1 500 496 488 99 98 70-130 2 500 535 532 106 105 70-130 1 500 506 495 101 99 70-130 2 500 693 670 100 95 70-130 3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, without the written consent of Pace Analytical Services, Inc.. Qual Qual Page 5 of 12 acmnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Bakers Stormwater SW03 Pace Project No.: 92188808 QC Batch: WET/29471 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92188808001 METHOD BLANK: 1136199 Matrix: Water Associated Lab Samples: 92188808001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers "total Suspended Solids mg/t ND 2 6 02/10/14 16-08 LABORATORY CONTROL SAMPLE: 1136200 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 248 99 80-120 SAMPLE DUPLICATE: 1136201 92188644001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 6.9 6.7 3 SAMPLE DUPLICATE: 1136202 92188815001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 44.3 45.3 2 Date: 02/11/2014 04:47 PM REPORT OF LABORATORY ANALYSIS This report Shall not be reproduced, except in Full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 12 acmnalytical wwvw.pacelabs.com QUALITY CONTROL DATA Project: Bakers Stormwater SW03 Pace Project No.: 92188808 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: WET/29418 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 92188808001 METHOD BLANK: 1134290 Matrix: Water Associated Lab Samples: 92188808001 Blank Reporting Parameter Units Result Llmlt Analyzed Quallflers DOD, 5 day mg/1 ND 2 0 02/11/14 12,30 LABORATORY CONTROL SAMPLE: 1134291 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day mg/L 198 148 75 84.5-115.4 LO SAMPLE DUPLICATE: 1134292 92188808001 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 5.8 5.8 1 Date: 02/11/2014 04:47 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 12 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: Bakers Stormwater SW03 Pace Project No.: 92188808 QC Batch: WETA/17985 Analysis Method: SM 5220D QC Batch Method: SM 5220D Analysis Description: 5220D COD Associated Lab Samples: 92188808001 METHOD BLANK: 1134191 Associated Lab Samples: 92188808001 Parameter Units Chemical Oxygen Demand mg/t LABORATORY CONTROL SAMPLE: 1134192 Parameter Units Chemical Oxygen Demand mg/L Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Matrix: Water Blank Reporting Result Llrnit Analyzed Qualifiers ND 25 0 02/07/14 13-30 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 750 736 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1134193 1134194 MS MSD 92188713001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg/L 461 750 750 1050 1060 79 80 75-125 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1134195 1134196 MS MSD 92188710001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qua] Chemical Oxygen Demand mg/L 2220 3000 3000 5100 5180 96 99 75-125 2 Date: 02/11/2014 04:47 PM REPORT OF LABORATORY ANALYSIS This report shall nut be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 12 acleAnalytical www.pacelabs.com QUALIFIERS Project: Bakers Stormwater SW03 Pace Project No.: 92188808 DEFINITIONS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-Adjusted Method Detection Limit. PRL - Pace Reporting L imit RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services -Asheville ANALYTE QUALIFIERS LO Analyte recovery in the laboratory control sample (LCS) was outside QC limits. L2 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated samples may be biased low REPORT OF LABORATORY ANALYSIS This repurL shall nut be repruduced, except in Full, Date: 02/11 /2014 04:47 PM without the written consent of Pace Analytical Services, Inc.. Page 9 of 12 acmnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: Bakers Stormwater SW03 92188808 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92188808001 Bakers Stormwater SW03 EPA 200.7 MPRP/15194 EPA 200.7 ICP/13792 92188808001 Bakers Stormwater SW03 SM 2540D WET/29471 92188808001 Bakers Stormwater SW03 SM 5210B WET/29418 SM 5210B WET/29420 92188808001 Bakers Stormwater SW03 SM 5220D WETA/17985 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/11/2014 04:47 PM without the written consent of Pace Analytical Services, Inc.. Page 10 of 12 0' aceAnalytical Sample Condition Upon Recei Document Number: F-CHR-CS-03-rev.13 Client Name: Wu Page 1 of 2 Issuing Authority: Pace Huntersville Quality Office Courier: ❑ Fed Ex ❑ UPS[] USPS❑ Client❑ Commercial Pace Other Custody Seal on Cooler/Box Present: ❑ yes D no Seals intact: ❑ yes ❑ no Optional Proj. Due Date: Proj. Name: Packing Material: ❑ Bubble Wrap ❑ Bubble Bags E] None ❑ Other Thermometer Used: IR Gun T1102 T1 1 Type of Ice: Blue None �amples on ice, cooling process has begun Temp Correction Factor T1102: o Correction T1301: No Correction Corrected Cooler Temp.: C Temp should be above freezing to 6°C Biological Tissue is Frozen: Yes No N/A g Comments: Date and Initials of pe son examining content -- Chain of Custody Present: Yes ❑No ❑N/A 1, Chain of Custody Filled Out: Zyes ❑No ❑N/A 2. Chain of Custody Relinquished: Yes [`INo —PRIA 3. Sampler Name & Si naturo on COC: ,6Yas ❑No ❑N/A 4. Samples Arrived within Hold Time: Y s ❑No ❑N/A 5. Short Hold Time Analysis (<72hr): Yes ❑No El N/A 6. Rush Turn Around Time Requested: []Yes 2fNo ❑N/A 7. Sufficient Volume: es ❑No ❑N/A g, Correct Containers Used: -Pace Containers Used: EXes / es El No ❑No ❑N/A El N/A 9. Containers Intact: Yes 11 No ❑N/A 10. Filtered volume received for Dissolved tests ❑Yes ❑No 41A 11. Sample Labels match COC: -Includes date/time/ID/Analysis Matrix: ❑ W ❑No ❑NIA 12, All containers needing preservation have been checked. All containers needing preservation are found to be in compliance with EPA recommendation. exceptions: VOA, coliform, TOC, O&G, WI-DRO (water) ❑ s �s Yes ❑No ❑No El No El N/A ❑NIA 13. Samples checked for dechlorination: ❑Y ❑No ❑N/A 14. Headspace in VOA Vials (>6mm): bYes ❑No N/A 15. Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): Clues ❑Yes F1No ❑No ,i ETN/A ❑N/A 16. Client Notification/ Resolution: Field Data Required? Y / N Person Contacted: Date/Time: Comments/ Resolution: SCURF Review: , Date: 2 S Plana lahal harp SRF Review: Date: i WO# : 9218880g Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR IIIIII IIIIIII II III III Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) _ 92188808 Page 11 of 12 0 V ITEM # a c> z rn o !> N qm m oD OE50 0 r m x z ° s C m _ m \ 3 a y h i? ON 2F0 Co �$,p o v )JJ 0 a ."Tl .'11 V) U (7 m z 1 O'1>*Ow, Q m'^ R 1NA'Orr �� z z m o 4 -mf ( v z 3 3 m O P W MATRIX CODE (see valid cafes to left) c z s, �-�. SAMPLE TYPE (G=GRAB C=COMP) �` 1� S 3 a _ W m m 0 9 m oo N O M . ~ In ' N v A A z z z n p z rr m 0 c m m o is 0 m m z o t v y $m N N N 1 m D m 3 3; :i r m A m "Q a.q SAMPLE TEMP AT COLLECTION ri # OF CONTAINERS n m d D R O o Y v C 3 m vvmp , o. m 'g ; m y y P'.n. Unpreserved } HZSO, " * o z 0 HNO3 m , m o n z, HCI 2 y a NaOH m Na2S203 y C 3 Methanol ` m Other jAnalysis Test j Y/ N j ks m { 71, gyp 1 �\ T X- M ._.._. :'A1 Q n D e, G, m O Vi 0 C z C T. m a a - C)1 m m _ ` -t m o co O I D ti c� -q to a C z J. m A Q O m 'V W x �] O D Z Z Temp in "C Residual Chlorine (Y/N) D m �•-+� Received on Ice (Y/N) N D 3 r m � "p Custody Sealed Cooler (Y/N) Z o z C M m Z .jam z N t� Samples Intact y y (Y/N) Cr m Q � j n T. D _ Z 0 c ' a n �• n m C m � D C) 0 0 c ` m D z = z D 0) 12 of 12 m acmnalytical www.pacelabs.cm January 22, 2014 Mr. Joe Hinkle Allvac Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 RE: Project: Bakers Non Contact Cooling Pace Project No.: 92186793 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Dear Mr. Hinkle: Enclosed are the analytical results for sample(s) received by the laboratory on January 16, 2014. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, r, , J M Erin Wators erin.waters@pacelabs.com Project Manager Enclosures cc: Mr. Preston Baucom, Allvac Mr. Tommy Long, Allvac REPORT OF LABORATORY ANALYSIS This resort shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 18 Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceAnalytica! ® 205 East Meadow Road - Suite A 2225 Riverside Dr. Eden, NC 27288 Asheville, NC 28804 www.pacelabs.com (336)623-8921 (828)254-7176 CERTIFICATIONS Project: Bakers Non Contact Cooling Pace Project No.: 92186793 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Asheville Certification IDs 2225 Riverside Dr., Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 Norlli Carolinaa DOildng Water Cerlifluallun ✓#. 3// 12 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 West Virginia Certification #: 357 VirginiaNFL AP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #6: 356 VlrginlaNEUVP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 18 Iacmnalyfica( Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc. 205 East Meadow de Dr. 128804 Suite 9800Hunte Eden, NC 272 8 Asheville, NC sville, NC28078 www.pacelabs.com (� (336)623-8921 (828)254-7176 (704)875-9092 SAMPLE ANALYTE COUNT Project: Bakers Non Contact Cooling Pace Project No.: 92186793 Analytea Lab ID Sample ID Method Analysts Reported Laboratory 92186793001 Bakers Non Contact #1 EPA 1664B CLW 1 PASI-C SM 4500-CI G AES2 1 PASI-A 92186793002 Bakers Non Contact #2 EPA 1664B CLW 1 PASI-C SM 4500-CI G AES2 1 PASI-A 92186793003 Bakers Non Contact #3 EPA 1664B CLW 1 PASI-C b'M 4500-(;I G AES2 I WASI-A 92186793004 Bakers Non Contact #4 EPA 1664E CLW 1 PASI-C SM 4500-CI G AES2 1 PASI-A 92186793005 Bakers Non Contact #5 EPA 1664B CLW 1 PASI-C SM 4500-CI G AES2 1 PASI-A 92186793006 Bakers Non Contact #6 EPA 1664B CLW 1 PASI-C SM 4500-CI G AES2 1 PASI-A 92186793007 Bakers Non Contact #7 EPA 1664E CLW 1 PASI-C SM 4500-CI G AES2 1 PASI-A 92186793008 Bakers Non Contact #8 EPA 1664B CLW 1 PASI-C SM 4500-CI G AES2 1 PASI-A REPORT OF LABORATORY ANALYSIS T1,66 report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 18 lacieAnalyticale www.pecelabs.com Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Bakers Non Contact Cooling Pace Project No.: 92186793 Sample: Bakers Non Contact #1 Lab ID: 92186793001 Collected: 01/15/14 09:50 Received: 01/16/14 16:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mg/L 5.0 1 01/21/14 14:06 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G Chlorine, Total Residual 0.57 mg/L 0.024 1 01/21/14 13:56 7782-50-5 H3 REPORT OF LABORATORY ANALYSIS This repurL shall nut be reproduced, except in full, Date: 01/22/2014 01:54 PM without the written consent of Pace Analytical Services, Inc.. Page 4 of 18 Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceAnalytical 205 East Meadow Road - Suite A 2225 Riverside Dr. Eden, NC 27288 Asheville, NC 28804 www.pacelabs.com (336)623-8921 (828)254-7176 ANALYTICAL RESULTS Project: Bakers Non Contact Cooling Pace Project No.: 92186793 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Bakers Non Contact #2 Lab ID: 92186793002 Collected: 01/15/14 10:10 Received: 01/16/14 16:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua] HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mg/L 5.0 1 01/21/14 14:07 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G Chlorine, Total Residual 0.15 mg/L 0.024 1 01/21/14 14:09 7782-50-5 H3 Date: 01/22/2014 01:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 18 Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceAnalytical ® 205 East Meadow Road - Suite A 2225 Riverside Dr. Eden, NC 27288 Asheville, NC 28804 www.pacelabs.com (336)623-8921 (828)254-7176 ANALYTICAL RESULTS Project: Bakers Non Contact Cooling Pace Project No.: 92186793 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Bakers Non Contact #3 Lab ID: 92186793003 Collected: 01/15/14 10:20 Received: 01/16/14 16:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua] HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mg/L 5.0 1 01/21/14 14:07 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G Chlorine, Total Residual 0.14 mg/L 0.024 1 01/21/14 14:22 7782-50-5 H3 Date: 01/22/2014 01:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 18 Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceAnalytical ® 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078 wvnvpacelabs.com (336)623-8921 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: Bakers Non Contact Cooling Pace Project No.: 92186793 Sample: Bakers Non Contact #4 Lab ID: 92186793004 Collected: 01/15/14 10:35 Received: 01/16/14 16:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664E Oil and Grease 52.7 mg/L 5.0 1 01/21/14 14:08 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G Chlorine, Total Residual 0.50 ing/L 0.024 1 01/21/14 14:56 7782-50-5 H3 Date: 01/22/2014 01:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 18 Pace Analytical Services, Inc. Pace Analytical Services, Inc. w Road - Suite A 2225 Riverside Dr. acmnalytical ® 205 East MeadoEden, NC 27288 Asheville, NC 28804 www.pacelabs.com (336)623-8921 (828)254-7176 ANALYTICAL RESULTS Project: Bakers Non Contact Cooling Pace Project No.: 92186793 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Bakers Non Contact #5 Lab ID: 92186793005 Collected: 01/15/14 10:50 Received: 01/16/14 16:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664E Oil and Grease ND mg/L 5.0 1 01/21/14 14:08 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G Chlorine, Total Residual 0.064 mg/L 0.024 1 01/21/14 15:05 7782-50-5 H3 Date: 01/22/2014 01:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 18 Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceAnalXiml ® 205 East MeadoEden, NC 27288 Asheville, Riverside NC www.pacelabs.com (336)623-8921 (828)254-7176 ANALYTICAL RESULTS Project: Bakers Non Contact Cooling Pace Project No.: 92186793 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Bakers Non Contact #6 Lab ID: 92186793006 Collected: 01/15/14 11:05 Received: 01/16/14 16:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664E Oil and Grease ND mg/L 5.0 1 01/21/14 14:08 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G Chlorine, Total Residual 0.042 mg/L 0.024 1 01/21/14 15:18 7782-50-5 H3 Date: 01/22/2014 01:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 18 Pace Analytical Services, Inc. Pace Analytical Services, Inc. acmnalytical ® 205 East MeadowRoad Riverside NC 272 8 AshevilleNC 28804 www.pacelabs.com (336)623-8921 (828)254-7176 ANALYTICAL RESULTS Project: Bakers Non Contact Cooling Pace Project No.: 92186793 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Bakers Non Contact #7 Lab ID: 92186793007 Collected: 01/15/14 11:20 Received: 01/16/14 16:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664E Oil and Grease ND mg/L 5.0 1 01/21/14 14:09 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G Chlorine, Total Residual 0.42 mg/L 0.024 1 01/21/14 15:45 7782-50-5 H3 Date: 01/22/2014 01:54 PM REPORT OF LABORATORY ANALYSIS This repurl shall nut be repruduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 18 Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc. ® ace 205 East MeadowRoad de Dr. )NC Suite 100 9800Hunte 272 8 AshevilleNCr28804 svlle, NC 28078 www.pacelabs.com (336)623-8921 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: Bakers Non Contact Cooling Pace Project No.: 92186793 Sample: Bakers Non Contact #8 Lab ID: 92186793008 Collected: 01/15/14 11:40 Received: 01/16/14 16:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease 5.2 mg/L 5.0 1 01/21/14 14:09 4500CL G Chlorine, Residual Analytical Method: SM 4500-CI G Chlorine, Total Residual 0.28 mg/L 0.024 1 01/21/14 15:49 7782-50-5 H3 Date: 01/22/2014 01:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 18 Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc. de Dr. ,�acieAnalyticale 205 East Meadow Road - Suite A 2225 RiversEden, NC 27288 Asheville, NC 128 04 9800Hunte sv lle, NC128078 www.pacelabs.com (336)623-8921 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project: Bakers Non Contact Cooling Pace Project No.: 92186793 QC Batch: GCSV/16474 Analysis Method: EPA 1664E QC Batch Method: EPA 1664E Analysis Description: 1664 HEM, Oil and Grease Associated Lab Samples: 92186793001, 92186793002, 92186793003, 92186793004, 92186793005, 92186793006, 92186793007, 92186793008 METHOD BLANK: 1124651 Matrix: Water Associated Lab Samples: 92186793001, 92186793002, 92186793003, 92186793004, 92186793005, 92186793006, 92186793007, 92186793008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Oil and Grease rng/L ND 5.0 01/21/14 14:04 LABORATORY CONTROL SAMPLE: 1124652 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Oil and Grease mg/L 40 33.8 84 78-114 MATRIX SPIKE SAMPLE: 1124653 92186786002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Oil and Grease mg/L ND 40 36.9 92 78-114 Date: 01/22/2014 01:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 18 Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc. de Dr. Suite aceAnaljftal ® 205 East Meadow 128804 9800Hunte Eden, NC 272 8 Asheville, NC sv le, NC28078 wmpacelabs.com (336)623-8921 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project: Bakers Non Contact Cooling Pace Project No.: 92186793 QC Batch: WET/29188 Analysis Method: SM 4500-CI G QC Batch Method: SM 4500-CI G Analysis Description: 4500CL G Chlorine, Total Residual Associated Lab Samples: 92186793001, 92186793002, 92186793003, 92186793004, 92186793005, 92186793006, 92186793007, 92186793008 METHOD BLANK: 1125476 Matrix: Water Associated Lab Samples: 92186793001, 92186793002, 92186793003, 92186793004, 92186793005, 92186793006, 92186793007, 92186793008 Blank Reporting Parameter Units Result Limit Analyzed Uualifiers Chlorine, Total Residual mg/1- ND 0.024 01/21/14 13:50 SAMPLE DUPLICATE: 1125477 92186793001 Dup Parameter Units Result Result RPD Qualifiers Chlorine, Total Residual mg/L 0.57 0.57 0 Date: 01/22/2014 01:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, exoept in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 18 Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceAnalXical ® 205 East MeadoEden, 128804 9800Hunte NC 27288 Asheville, NC sv Ile, NC128078 www.pacelabs.com (336)623-8921 (828)254-7176 (704)875-9092 QUALIFIERS Project: Bakers Non Contact Cooling Pace Project No.: 92186793 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-Adjusted Method Detection Limit. PRL - Pace Reporting Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unfounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PAST -A Pace Analytical Services - Asheville PAST-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS H3 Sample was received or analysis requested beyond the recognized method holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, Date: 01/22/2014 01:54 PM without the written consent of Pace Analytical Services, Inc.. Page 14 of 18 Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceAnalytical ® 205 East MeadowRoad NC 272 8 Asheville) Riverside NC www.pacelabs.com (336)623-8921 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Bakers Non Contact Cooling Pace Project No.: 92186793 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92186793001 Bakers Non Contact #1 EPA 1664B GCSV/16474 92186793002 Bakers Non Contact #2 EPA 1664B GCSV/16474 92186793003 Bakers Non Contact #3 EPA 1664B GCSV/16474 92186793004 Bakers Non Contact #4 EPA 1664B GCSV/16474 92186793006 Bakers Non Contact #6 EPA 1664B GCSV/16474 92186793006 Bakers Nun Contact #6 EPA 1664B GCSV/16474 92186793007 Bakers Non Contact #7 EPA 1664E GCSV/16474 92186193008 Bakers Non Contact #0 EPA I664B GUSV/ 164/4 92186793001 Bakers Non Contact #1 SM 4500-CI G WET/29188 92186793002 Bakers Non Contact #2 SM 4500-CI G WET/29188 92186793003 Bakers Non Contact #3 SM 4500-CI G WET/29188 92186793004 Bakers Non Contact #4 SM 4500-CI G WET/29188 92186793005 Bakers Non Contact #5 SM 4500-CI G WET/29188 92186793006 Bakers Non Contact #6 SM 4500-CI G WET/29188 92186793007 Bakers Non Contact #7 SM 4500-CI G WET/29188 92186793008 Bakers Non Contact #8 SM 4500-CI G WET/29188 Date: 01/22/2014 01:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch Page 15 of 18 Uocument Name: �r' cr ArlalytJcaf Sample Condition Upon Recei Document Number: F-CHR-CS-03-rev.13 uocument muvibeu. Ljutx i iuGi l u, w l o Page 1 of 2 Issuing Authority: Pace Huntersville Quality Office Client Name: Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ ClientEl Commercifilll-� Pace Other Custody Seal on Cooler/Box Present: Elyes 2 no Seals intact: ❑ yes ❑ no Optional Proj. Due Date: Proj. Name: Packing Material: ❑ Bubble Wrap ❑ ,,Bubble Bags ❑ None ❑ Other .{ Thermometer Used: IR Gun T1102 *130 Type of Ice: Je9f Blue None LJ Samples on ice, cooling process has begun Temn Correction Factor T1102: fro Correction T13'No Correction Corrected Cooler Temp.: C — Biological Tissue is Frozen: Yes No N/A Date and In' ialls ofp s contents:-4 -'-i-'�a n�examining Temp should be above freezing to 6°C Comments: Chain of Custody Present: es ONO ❑NIA 1. Chain of Custody Filled Out: es ONO ❑N/A 2. Chain of Custody Relinquished: l Yes171a- nTrrA 3— ---- — Sampler Name & Signature on COG: -eyes ❑No ❑N/A 4. 5. Samples Arrived within Hold Time: Z Yes ONO ❑N/A Short Hold Time Analysis (<72hr): ❑Yes LTNo ❑N/A 6. Rush Turn Around Time Requested: ❑Yes [,],No ❑N/A 7. Sufficient Volume: Pl(e-, El No ❑N/A 8. Correct Containers Used: ZYes ONO ❑NIA g. -Pace Containers Used: 9es ONO ❑N/A Containers Intact: Yes ONO ❑N/A 10. Filtered volume received for Dissolved tests ❑Yes ONO [I N/A 11. Sample Labels match COC: ❑�❑No ❑N/A 12, -Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. []Yes ONO El N/A 13. All containers needing preservation are found to be in ❑Yes ONO / ❑ ylA compliance with EPA recommendation. / exceptions: VOA, coliform, TOC, O&G, WI-DRO (water) ❑Yes ONO Eutriplob uhtiakod lk�r doolilorinutitnt nyoot nNo N/A 14_ Headspace in VOA Vials (>6mm): ❑Yes ONO OLNtk 15. 16. Trip Blank Present: LJYes LJNo ❑rf/A Trip Blank Custody Seals Present ❑Yes ONO ❑N/A Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Field Data Required? Y / N Person Contacted: Comments/ Resolution: Date/Time: SCURF Review: 1 Date: 111101ALI SRF Review: Yv Date: j 7 /` Note: Whenever there i discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) Place label here WOii: 92186793 II21II�I7d93IY Page 16 of 18 J- r-] ITEM # ;0. -,o M > 0 3 1 C il it, 5 'n > z > M 7:1 k r 0 0 3 0 an z M zi X0 L 1 a 00 0 -V 'o I -U 0 0 0 > 0 0 mN ;U N K0 r r z z a 0 m3 E7— —A MATRIX CODE (see valid codes to left) z z 0 I' j Q" ISAMPLE TYPE (G=GRAB C=COMP) M 1P > 1 m 8 7 .0 9 'U 0 0 r- M m 0z Z 0 z m > X 0 ITI C z M > m z r. 0 M M 2, 0 0 > > G) V- kb m ra m Im a ;U SAMPLE TEMP AT COLLECTION M 0 # OF CON IAINFRS I>- Unpreserved H2SO4 z 3 P I HNO, ii? z HCI 00 CD X- NaOH ca Na2S203 G) > 0 Methanol o Other 6 <- < 'n JAnalysis Test I re- e -s e.- YIN 1>1 o m r Qv d (D 2: z 'L, i ITI Ile re—,t -i > < 0. C: 0z, U C =7 m -n D-) M 0 K8,JA, I e- A to r = , :3 5 n 0 e— rL > M G) �11ITI 0 0 z 0 Temp in 'C iiJdd < Residual Chlorine (YIN) In Received on 1>0 Ice (Y/N) 0 " I �)� 'U Custody Sealed Cooler 0 m 0 z .0 0 0 (YIN) 2 0 z 0 5 G) r Samples Intact (YIN);U Im I ZZI 7 of 18 C 455 ITEM# W -0 an 00 0 Z, 30 2 > U) > 0 c: (h U z > > -1 rn M lo ri 0 0 'D c: 1> m C an z + 4- 0 *0 4 x x Ce 0 *0 0 -U > COX 0 ;U ra MATRIX (see valid codes to left) 0 EL LA -U Ua A z SAMPLE TYPE (G=GRAB C=COMP) a A EP (11 r� 3: 0 1>1 tJ 1ON 0 m .V M X I 0 M 7 z ;U Z > z 0 iz 0 —al 1 3 , T 0 4 Z, M 0 ;U m z 2 0 an > m '0 > > > D, V,3 9, 0 m Z A m Im M 'A a ;a• SAMPLE TEMP AT COLLECTION 1 -0 g: -0 # OF CONTAINERS M .0 > C) 09 L, m 'a U Unpreserved 0 'W H,SO, z a 0 HNO3 T D 3 HCI co 1 C7,) NaOH > 0 Na2S203 Q 'U H Methanol Other M <71 IOU lAnalysis Test I YINJ < (A) R D R, -n 61 0 m — ;U CD Re!5 �,Ako,\ Wt,, �',e_ > (D rk. > M o Q b ID cn -a r— m n Cz 0 M (D > M n Az M FD -,) > C: z 0 so Temp in 0 Residual Chlorine (YIN) M Received on Ice (Y/N) > al 0 0 ­11 Custody Cooler SealeYiN) 0 (D• w (- z 0 z V) 0d z ra G) Samples Intact jc�c m (YiN) O 0 0 X :F z 0 -n 0 C 8 of 18