WQ0037094_Residual Annual Report 2018_20190313

INITIAL REVIEW
Reviewer Williams, Kendall
Project Number* WQ0037094
SUBMITTAL DATED: 3/5/2019
Project Contact Information
Hease provide inforrration on the person to be contacted by MB Staff regarding electronic submittal, confirmation of receipt, and other issues.
......................................................................................................................................................................................................................................................................................................................................................................................................
Name * Rob Willcox
Email Address*
rob@Wllco)Tnabesoil.com
Project Information
Application Type* r
New
r
Renewal
r
Annual Report
Permit Type * r
Wastewater Irrigation
r
Other Wastewater
•
Closed -Loop Recycle
r
Single -Family Residence
Wastewater Irrigation
Is a paper copy of the application being submitted?*
r Yes r Nor N/A
Permit Number* WQ0037094
Permittee * Michael Brooks
Facility Name * Howard Fertilizer Company, Inc.
Phone Number*
336-339-9128
r Modification (Major or Minor)
• Additional Information
r Other
• High -Rate Infiltration
r Reclaimed Water
r Residuals
r Other
Please provide comments/notes on your current submittal below.
Please attach all information required or requested for this submittal to be review here.
Application Form Engineering Hans, Specifications, Calculations, Etc.)
Howard Fertilizer - 2018 ANNUAL REPORT
3.02MB
WQ0037094. pdf
Upoad only 1 HDF document. NLltiple docurrents must be combined into one H7F file.

For nein and modif cation permit applications, the paper copy is required to be submitted to the
Di, risiom Be advised, applications will not be considered complete until both the paper and electronic
applications. have been received_ The paper copy shall include the follm ging:
• Application Farm
• All relevant attachments (talcs, soils report, specs, etc_)
• 1 full-size engineering plan set
• 2 11-17" engineering plan sets
• 1 extras set of specifications (in addition to the set of specifications Provided in the
attachments)
• Fee (if required)
This shall be mailed to the following address:
By US_ Postal Service-
Di,vision of Water Resources- Non -Discharge Branch
1617 Mail Service Center Raleigh NC 27699-1617
By Courier, -Special Delivery:
Division of Water Resources- Non -Discharge Branch
Nathaniel Thornburg- 9th Floor, Office #942M
512 N_ Salisbury St_ Raleigh, NC 27644
For questions or problems contact Tessa Monday at 919.7073660 or Tessa_X%nday(dncdem_gov or
Sonia Graves at 919.707.3657 or Sonia Graves(dpcdenr.gov.
*140 By checking this box I am acknowledging that I have read the above statement and agree
to send these documents as required to one of the address given above.
Signature
Submission Date 3/5/2019

2018 ANNUAL REPORT
HOWARD FERTILIZER COMPANY, INC.
DISTRIBUTION OF CLASS A MUNICIPAL
WASTEWATER TREATMENT PLANT RESIDUALS
NON -DISCHARGE PERMIT #WQ0037094
Prepared For:
Howard Fertilizer Company, Inc.
8306 South Orange Avenue
Orlando, Florida 32809
Compiled By:
Willcox & Mabe Soil Solutions, PLLC
7231B Summerfield Road
Summerfield, North Carolina 27358
February 2019

March 1, 2019
willcoX&'l abe
SOIL SOLUTIONS
N.C. Department of Environmental Quality
Division of Water Resources — Non -Discharge Branch
512 N. Salisbury Street, 0 Floor, Office # 942WN
Raleigh, North Carolina 27604
Attention: Non -Discharge Branch
Reference: 2018 ANNUAL REPORT
Howard Fertilizer Company, Inc.
Non -Discharge Permit No. WQ0037094
WMSS Project No. 15-07, Phase: 05
Willcox & Mabe Soil Solutions, PLLC (WMSS) is submitting all monitoring and reporting
requirements as specified in the above referenced permit for Howard Fertilizer Company,
Inc. (Howard Fertilizer) on behalf of Howard Fertilizer. WMSS compiled this report using
data provided by Howard Fertilizer. This data includes: 1) Class A Annual Distribution of
Marketing / Surface Disposal Certification and Summary Form, 2) Annual Residual
Sampling Summary Form, 3) Annual Pathogen and Vector Attraction Reduction Form
(503), and 4) Analytical Data.
Howard Fertilizer distributed 131.1 Total Dry Tons of blended fertilizer (69.7 Tons) and
South Cross Bayou WRF pellets (100.4 Tons) in North Carolina under Permit No.
WQ0037094 during the 2018 calendar year.
If there is any further information required or questions regarding this distribution program
please do not hesitate to contact Mr. Michael Brooks, Corporate Compliance Officer (407)
466-2960 for further assistance.
Sincerely,
Willcox & Mabe Soil Solutions, PLLC
Rob Willcox, L.S.S.
Soil Scientist
Enclosure(s)
cc: Howard Fertilizer Company, Inc.
Shared\WMSS Projects\2015\15-07 Howard Fertilizer\Phase 05 - 2018 Annual Report\2018 ANNUAL REPORT.doc
Willcox & Mabe Soil Solutions, PLLC / 7231 B Summerfield Road / Summerfield, INC 27358 / Rob 336.339.9128 or
Martin 336.312.1396 / www.willcoxmabesoil.com

TABLE OF CONTENTS
SECTION NO. TITLE
Class A Distribution and Marketing / Surface Disposal
Certification Summary Form
Form DMSDF
II Annual Residual Sampling Summary Form
Form RSSF
III Annual Pathogen and Vector Attraction Reduction Form
(503 Rules)
Form PVRF 503
IV Lab Sheets
Analytical Data

Class A Distribution and Marketing / Surface Disposal Certification
Summary Form
FORM DMSDF

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
WQ PERMIT #: W00037094 FACILITY NAME: Howard Fertilizer Company, Inc. / Soulh Crass fia oa WRF Pelletizing Facility
PHONE: [phone] COUNTY: Statewide OPERATOR: N/A
FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C)
❑p Distribution and Marketing (complete Parts A, B, and C)
VC- ray,. 1,—; lit.- i i�- A •I th.. «t n 1—dnr --9 Vnc 01 No t -I ---b� if No .kin n irk :1. R. C and re. riifv form below
* If more space is required, attach additional inrormation sheets (FORM DM SDI; (aupp)): Total Number of Form DMSDF (Supp)I
Part C:
Facility was compliant during the past calendar year with all conditions of the land application permit El Yes
(including but not limited to items 1-3 below) issued by the Division of Water Resources: ❑ No —► If No, Explain in Narritive
1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached.
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Resources.
3. No contravention of Ground Water Quality Standards occurred at a monitoring well.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
aigindeofPermiltee 1 t]de � Signature ofPreparer** Date
(if different from Permittee)
**Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T, 1102 (26)
DENR FORM DMSDF (12/2006)
Part A*:
Part B*:
Month
Sources(s) (include NPDES # if
applicable)
Volume dry tons
AendmenU
mResidual In
Bulkin * A ent
Product Out
Recipient Information
Name(s) Volume (dry tons) Intended use(s)
January
South Cross Bayou WRF Pelletizing Facility
697
100.4
T37-1-7
Class A Residuals utilized 131 1 Fertilizer
February
(Fertilizer)
(Pellets)
(Blended Product)
for Distribution durinr 2018
March
April
Ma
June
Jul
August
September
October
November
December
Total from FORM DMSDF (su)
0
0
0
0
'Totals:
Annual (dry tons :
69.7
100.4
131.1
131.1
Amend mcnl s used: I
Bulking A enl(s) used'
* If more space is required, attach additional inrormation sheets (FORM DM SDI; (aupp)): Total Number of Form DMSDF (Supp)I
Part C:
Facility was compliant during the past calendar year with all conditions of the land application permit El Yes
(including but not limited to items 1-3 below) issued by the Division of Water Resources: ❑ No —► If No, Explain in Narritive
1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached.
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Resources.
3. No contravention of Ground Water Quality Standards occurred at a monitoring well.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
aigindeofPermiltee 1 t]de � Signature ofPreparer** Date
(if different from Permittee)
**Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T, 1102 (26)
DENR FORM DMSDF (12/2006)

Annual Residual Sampling Summary Form
FORM RSSF

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: WQ0037094
Facility Name: Howard Fertilizer Company, Inc. (Permittee)
Residual Source WQ # or N/A - Florida Permit
NPDES #:
WWTP Name: South Cross Bayou WRF Pelletizing Facility
Residual Analysis Data
Laboratory: 1) Pace Analytical
2)
3)
4)
5)
Parameter
(mg/kg)
Ceiling
Cone.
Limit
Sala ie or Composite [)ale
12/4/18
Percent Solids (%)
NA
91.5
Arsenic
75
6.6
Cadmium
85
1.3
Copper
4,300
601
Chromium
NA
38.0
Lead
840
16.6
Mercury
57
0.38
Molybdenum
75
12.7
Nickel
420
25.8
Selenium
100
4.9
Zinc
7,500
696
Total Phosphorus i
NA
40.800
TKN
NA
51,100
Ammonia -Nitrogen
NA
1,320
Nitrate and Nitrite
NA
2,6
° For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false intftwmati�pn, in ding lie possibility of fines and imprisonment for knowing violations."
* Permitte (I loward Fertilizer)
Signature ofPreparer * 1, (] le
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1 102 (26)
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number:
WQ0037094
Facility Name: Howard Fertilizer Company, Inc. (Permittee)
Residual Source N/A - Florida Permit
NPDES # or WQ#:
WWTP Name: South Cross Bayou WRF Pelletizing Facility
Residual Analvsis Data
Laboratory: 1) Pace Analytical
2)
3)
4)
5)
Parameter
Sample or Composite Date
------------
------------
------------
------------
------------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties forsubm�false mfor nation, including the possibility of fines and imprisonment for knowing violations."
* Permitte [Iloward Feriilirx:r) /l
Signature of Preparer * D' 'c
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T. 1102 (26)
DENR FORM RSSF - B (12/2006)

Annual Pathogen and Vector Attraction Reduction Form - (503 Rules)
FORM PVRF 503

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (503 Rules)
Facility Name: Howard Fertilzer Company, Inc. (Permittee) WQ Permit Number: WQ0037094
WWTP Name: South Cross Bayou WRF Pelletizing Facility NPDES Number:
Monitoring Period: From 1/1/2018 To 12/31/2018
Pathogen Reduction f40 CFR 503.32] - Please indicate level achieved and alternative nerformed:
Class A: Alternative 1 ❑ Alternative 2 07= Alternative 3 ❑
Alternative 4 ❑ Alternative 5 El I Alternative 6 ❑
If applicable to alternative performed Class A only) indicate "Process to Further Reduce Pathogens":
(Tompost 111 Heat Drying El Heat Treatment ❑ Thermophilic ❑
Beta Ray 01 Gamma Ray ❑ Pasteurization ❑
Class B: I Alternative 1 ❑ Alternative 2 ❑
11'applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens"':
Liiilu Stabilization ❑ Air Dl'vina❑ Cam 05t111 r ❑ JAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
um er of
Excee-
Frequency
of Analysis
Sample
Type
na ytica
Tech -
Minimum
Geo. Mean
MaximumUnits
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
1000 mpn per gram
of total solid (dry
weieht)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
vector Attraction KeduCtion (4U L kH bU,i.3.3) - Please inaicate option performed:
Alt.l (VS reduction) ❑ Alt. 2 (40 -day bench) ❑ Alt. 3 (30 -day bench) El Wt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14 -Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ JAIt. 8 (Drying - Unstable) l]
Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) ❑ No vector attraction reduction alternatives were perforined ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
El "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an exulanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
N/A N/A
Preparer Name and Title (type or print)
N/A
Signature of Preparer*
Date
Land Applier Name and Title (if applicable)(type or print)
N/A
Signature of Land Applier (if applicable) Date
*Prepare'r is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 503 (12/2006)

Lab Sheets
ANALYTICAL DATA

HOWARD FERTILIZER
CLASS A
BIOSOLIDS ANALYSIS
Residual Type: Wastewater Treatment Plant
Date Sampled: December 4, 2018
South Cross Bayou WRF Permit No. WQ0037094
Mineralization Rate 0.30 91.50 % Solids
oas prr
Parameter
%
Mg/Kg Dry Weight
(% x 10,000)
Pounds/Dry Ton
(Mg/Kg x 0.002) N
Nitrogen (TKN)
5.110
51,100.000
102.200
Phosphorus
4.080
40,800.000
81.600
Potassium
0.499
4,990.000
9.980
PAN (injected)*
1.626
16,256.600
32.513
PAN (surface)*
1.560
15,596.600
31.193
Ammonia Nitrogen
0.132
1,320.000
2.640
Calcium
3.520
35,200.000
70.400
Calcium Carbonate Eq.
---
---
---
Magnesium
---
8,120.000
16.240
Sodium
---
1,590.000
3.180
Sulfur
---
---
---
Nitrate N / Nitrite N
---
2.600
0.005
Barium
---
---
---
Chloride
---
---
Iron
---
---
---
Aluminum
---
0.000
Arsenic
---
6.600
0.013
Cadmium
---
1.300
0.003
Chromium
---
38.000
0.076
Copper
---
601.000
1.202
Lead
---
16.600
0.033
Mercury
---
0.380
0.001
Molybdenum
---
12.700
0.025
Nickel
---
25.800
0.052
Selenium
---
4.900 1
0.010
Zinc
---
696.000 1
1.392
Pace Analytical 35434546
*Determination of Plant Available Nitrogen (PAN):
Injected Application:
(Mineralization Rate)(TKN-Ammonia N) + Ammonia N + Nitrate N + Nitrite N = % PAN
Surface Application:
(Mineralization Rate)(TKN-Ammonia N) + (0.5)(Ammonia N) + Nitrate N + Nitrite N = % PAN
Note: Constituents N.D. (Not Detected) or < detection limits are listed as detection limits
for calculation purposes.
SAR
1.89
Ceiling Concen.
(Mg/Kg)
75
85
4,300
840
57
75
420
100
7,500

aceAnalytical
—pacelabs.com
December 18, 2018
William Reyes
Synagro
RE: Project: Pinellas County Pelletizer
Pace Project No.: 35434546
Dear William Reyes:
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on December 04, 2018.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Cameron Meynardie
[e-mail]
[phone]
Project Manager
Enclosures
cc: Robert Ervin, Synagro
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 20

acmnalytical
www.pacelabs.com
Project: Pinellas County Pelletizer
Pace Project No.: 35434546
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH -0216
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
CERTIFICATIONS
Nebraska Certification: NE -OS -28-14
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 2 of 20

aceAnalytical
—pacelabsxom
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
SAMPLE SUMMARY
Project: Pinellas County Pelletizer
Pace Project No.: 35434546
Lab ID Sample ID Matrix Date Collected Date Received
35434546001 Pellet Solid 12/04/1812:30 12/04/1812:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 20

aceAnalytical
—pacelabs.com
SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project:
Pace Project No.:
Pinellas County Pelletizer
35434546
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
35434546001
Pellet
EPA 6010
LEC, SC1
18
PASI-O
EPA 7471
AMS
1
PASI-O
ASTM D2974-87
NMP
1
PASI-O
SM 2540G
SAI
1
PASI-O
SM 2540G
SA1
1
PASI-O
EPA 9045
AMP
1
PASI-O
ASTM D5057
JDW
1
PASI-O
TKN-NH3 Calculation
AEM
1
PASI-O
EPA 350.1
JWH
1
PASI-O
EPA 351.2
JWH
1
PASI-O
EPA 353.2
AMP
2
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 20

aceAnalytical
-pacelabs.com
ANALYTICAL RESULTS
Project: Pinellas County Pelletizer
Pace Project No.: 35434546
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Sample: Pellet Lab ID: 35434546001 Collected: 12/04/18 12:30 Received: 12/04/18 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
6010 MET ICP
Arsenic
Boron
Cadmium
Calcium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Phosphorus
Potassium
Selenium
Sodium
Sulfur
Zinc
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
2540G Total Solids
Total Solids
254OG Total Volatile Solids
Total Volatile Solids
9045 pH Soil
pH at 25 Degrees C
Specific Gravity/Bulk Density
Specific Gravity
Total Organic Nitrogen Soil
Total Organic Nitrogen
350.1 Ammonia
Nitrogen, Ammonia
Date: 12/18/2018 03:50 PM
Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
Analytical Method: EPA 6010 Preparation Method: EPA 3050
6.6
mg/kg
1.8
0.89
1
12/06/18 12:13
12/07/18 09:51
7440-38-2
73.7
mg/kg
8.9
4.5
1
12/06/18 12:13
12/07/18 09:51
7440-42-8
1.3
mg/kg
0.18
0.089
1
12/06/18 12:13
12/07/18 09:51
7440-43-9
35200
mg/kg
1780
890
20
12/06/1812:13
12/07/1815:41
7440-70-2
38.0
mg/kg
0.89
0.45
1
12/06/18 12:13
12/07/18 09:51
7440-47-3
601
mg/kg
17.8
8.9
20
12/06/1812:13
12/07/1815:41
7440-50-8
8020
mg/kg
142
71.2
20
12/06/1812:13
12/07/1815:41
7439-89-6
16.6
mg/kg
1.8
0.89
1
12/06/18 12:13
12/07/18 09:51
7439-92-1
8120
mg/kg
89.0
44.5
1
12/06/18 12:13
12/07/18 09:51
7439-95-4
216
mg/kg
17.8
8.9
20
12/06/1812:13
12/07/1815:41
7439-96-5
12.7
mg/kg
1.8
0.89
1
12/06/18 12:13
12/07/18 09:51
7439-98-7
25.8
mg/kg
0.89
0.45
1
12/06/18 12:13
12/07/18 09:51
7440-02-0
40800
mg/kg
35600
17800
200
12/06/1812:13
12/07/1816:31
7723-14-0
4990
mg/kg
178
89.0
1
12/06/18 12:13
12/07/18 09:51
7440-09-7
4.9
mg/kg
2.7
1.3
1
12/06/18 12:13
12/07/18 09:51
7782-49-2
1590
mg/kg
178
89.0
1
12/06/18 12:13
12/07/18 09:51
7440-23-5
11700
mg/kg
3560
1780
20
12/06/1812:13
12/07/1815:41
696
mg/kg
3.6
1.8
1
12/06/18 12:13
12/07/18 09:51
7440-66-6
Analytical
Method: EPA 7471 Preparation Method: EPA 7471
0.38
mg/kg
0.052
0.026
1
12/11/1811:05
12/11/1818:35
7439-97-6
Analytical
Method: ASTM D2974-87
7.0
%
0.10
0.10
1
12/10/18 09:55
Analytical
Method: SM 2540G
91.5
%
0.0010
0.0010
1
12/07/18 08:41
Analytical
Method: SM 254OG
71.1
%
0.0010
0.0010
1
12/07/18 08:41
Analytical
Method: EPA 9045
6.8
Std. Units
0.10
0.10
1
12/12/18 16:32
Analytical
Method: ASTM D5057
0.670
1
12/05/18 20:25
Analytical
Method: TKN-NH3 Calculation
49800
mg/kg
21.5
21.5
1
12/18/1812:30
Analytical
Method: EPA
350.1 Preparation Method:
EPA 350.1
1320
mg/kg
13.7
4.5
15
12/13/1812:00
12/13/1814:15
7664-41-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
ON
M6
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ANALYTICAL RESULTS
Project: Pinellas County Pelletizer
Pace Project No.: 35434546
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Sample: Pellet
Lab ID: 35434546001 Collected: 12/04/18 12:30 Received: 12/04/18 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Preparation Method: EPA 351.2
Nitrogen, Kjeldahl, Total
51100 mg/kg 1220 611 15 12/08/18 14:52 12/10/18 16:04 7727-37-9
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Preparation Method: EPA 353.2
Nitrogen, NO2 plus NO3
2.6 mg/kg 0.54 0.27 1 12/05/18 14:15 12/05/18 17:53
Nitrogen, Nitrate
1.6 mg/kg 0.54 0.27 1 12/05/18 14:15 12/05/18 17:53 14797-55-8
Date: 12/18/2018 03:50 PM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35434546
QC Batch: 499512
Analysis Method: EPA 7471
QC Batch Method: EPA 7471
Analysis Description: 7471 Mercury
Associated Lab Samples: 35434546001
METHOD BLANK: 2701076
Matrix: Solid
Associated Lab Samples: 35434546001
Blank Reporting
Parameter Units
Result Limit MDL
Analyzed
Qualifiers
Mercury mg/kg
0.0049 U 0.0099 0.0049
12/11/1815:04
LABORATORY CONTROL SAMPLE: 2701077
Spike LCS LCS
% Rec
Parameter Units
Conc. Result % Rec
Limits Qualifiers
Mercury mg/kg
0.095 0.10 106
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2701078 2701079
MS MSD
35432985001
Spike Spike MS MSD
MS MSD
% Rec Max
Parameter Units Result
Conc. Conc. Result Result
% Rec % Rec
Limits RPD RPD Qual
Mercury mg/kg 1.3
13 11.3 13.7 12.0
97 92
80-120 13 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Pinellas County Pelletizer
Pace Project No.: 35434546
QC Batch: 499000 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 35434546001
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
METHOD BLANK: 2697894
Associated Lab Samples: 35434546001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
MDL
Analyzed Qualifiers
Arsenic
mg/kg
0.23 U
0.46
0.23
12/07/1815:14
Boron
mg/kg
1.1 U
2.3
1.1
12/07/18 09:00
Cadmium
mg/kg
0.023 U
0.046
0.023
12/07/1815:14
Calcium
mg/kg
11.5 U
22.9
11.5
12/07/1815:14
Chromium
mg/kg
0.11 U
0.23
0.11
12/07/1815:14
Copper
mg/kg
0.11 U
0.23
0.11
12/07/1815:14
Iron
mg/kg
0.92 U
1.8
0.92
12/07/1815:14
Lead
mg/kg
0.23 U
0.46
0.23
12/07/1815:14
Magnesium
mg/kg
11.5 U
22.9
11.5
12/07/1815:14
Manganese
mg/kg
0.11 U
0.23
0.11
12/07/1815:14
Molybdenum
mg/kg
0.23 U
0.46
0.23
12/07/1815:14
Nickel
mg/kg
0.11 U
0.23
0.11
12/07/1815:14
Phosphorus
mg/kg
22.9 U
45.8
22.9
12/07/1815:14
Potassium
mg/kg
22.9 U
45.8
22.9
12/07/1815:14
Selenium
mg/kg
0.34 U
0.69
0.34
12/07/1815:14
Sodium
mg/kg
22.9 U
45.8
22.9
12/07/1815:14
Sulfur
mg/kg
22.9 U
45.8
22.9
12/07/1815:14
Zinc
mg/kg
0.46 U
0.92
0.46
12/07/1815:14
LABORATORY CONTROL SAMPLE:
Parameter
2697895
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Arsenic
mg/kg
15.1
13.5
90
80-120
Boron
mg/kg
151
150
99
80-120
Cadmium
mg/kg
1.5
1.4
95
80-120
Calcium
mg/kg
753
736
98
80-120
Chromium
mg/kg
15.1
14.8
99
80-120
Copper
mg/kg
15.1
14.3
95
80-120
Iron
mg/kg
151
146
97
80-120
Lead
mg/kg
15.1
14.6
97
80-120
Magnesium
mg/kg
753
729
97
80-120
Manganese
mg/kg
15.1
14.3
95
80-120
Molybdenum
mg/kg
15.1
14.8
98
80-120
Nickel
mg/kg
15.1
15.0
100
80-120
Phosphorus
mg/kg
15.1
30.1 U
97
80-120
Potassium
mg/kg
753
703
93
80-120
Selenium
mg/kg
15.1
13.1
87
80-120
Sodium
mg/kg
753
701
93
80-120
Sulfur
mg/kg
151
134
89
80-120
Zinc
mg/kg
75.3
68.3
91
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project:
Pace Project No.:
Pinellas County Pelletizer
35434546
MATRIX SPIKE &
MATRIX SPIKE DUPLICATE:
2697896
2697897
MS
MSD
35432985001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Arsenic
mg/kg
43.0 U
2110
2040
1850
1830
87
89
75-125
1
20
Boron
mg/kg
215 U
21100
20400
20700
20400
98
100
75-125
1
20
Cadmium
mg/kg
4.3 U
208
208
199
196
94
96
75-125
2
20
Calcium
mg/kg
25500
105000
102000
131000
125000
100
97
75-125
4
20
Chromium
mg/kg
21.5 U
2110
2040
2040
2020
96
98
75-125
1
20
Copper
mg/kg
314
2110
2040
2310
2260
95
96
75-125
2
20
Iron
mg/kg
2660
21100
20400
23300
22200
98
96
75-125
5
20
Lead
mg/kg
43.0 U
2110
2040
2020
1990
96
97
75-125
2
20
Magnesium
mg/kg
8350
105000
102000
111000
106000
98
96
75-125
5
20
Manganese
mg/kg
52.7
2110
2040
2050
2000
95
95
75-125
3
20
Molybdenum
mg/kg
43.0 U
2110
2040
2040
2000
97
98
75-125
2
20
Nickel
mg/kg
21.5 U
2110
2040
2090
2070
99
101
75-125
1
20
Phosphorus
mg/kg
28300
2110
2040
31800
31200
166
144
75-125
2
20 J(M1)
Potassium
mg/kg
9990
105000
102000
107000
103000
93
92
75-125
4
20
Selenium
mg/kg
64.5 U
2110
2040
1780
1740
84
85
75-125
2
20
Sodium
mg/kg
5370 1
105000
102000
110000
104000
100
97
75-125
5
20
Sulfur
mg/kg
9230
21100
20400
28000
27200
89
88
75-125
3
20
Zinc
mg/kg
446
10500
10200
9830
9650
89
90
75-125
2
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/18/2018 03:50 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35434546
QC Batch: 499847
Analysis Method:
ASTM D2974-87
QC Batch Method: ASTM D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Associated Lab Samples: 35434546001
SAMPLE DUPLICATE: 2702771
35433923011
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
32.6
34.2 5
5
SAMPLE DUPLICATE: 2702772
35433923045
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
19.2
17.6 9
5 J(D6)
SAMPLE DUPLICATE: 2702773
35434564002
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
67.4
69.5 3
5
SAMPLE DUPLICATE: 2702774
35435556002
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
0.99
0.80 21
5 J(D6)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Pinellas County Pelletizer
Pace Project No.: 35434546
QC Batch: 499325 Analysis Method: SM 2540G
QC Batch Method: SM 2540G Analysis Description: 2540G Total Solids
Associated Lab Samples: 35434546001
SAMPLE DUPLICATE: 2699951
Parameter
Total Solids
SAMPLE DUPLICATE: 2699952
Parameter
Total Solids
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
35435098001 Dup Max
Units Result Result RPD RPD Qualifiers
% 2.9 2.9 0 5
35435351001 Dup Max
Units Result Result RPD RPD Qualifiers
% 3.0 3.0 1 5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35434546
QC Batch: 499323
Analysis Method: SM 2540G
QC Batch Method: SM 2540G
Analysis Description: 2540G Total Volatile Solids
Associated Lab Samples: 35434546001
METHOD BLANK: 2699942
Matrix:
Solid
Associated Lab Samples: 35434546001
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Total Volatile Solids
%
0.0010 U
0.0010 0.0010
12/07/18 08:36
SAMPLE DUPLICATE: 2699943
35435098001
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Total Volatile Solids
%
62.0
64.1 3
5
SAMPLE DUPLICATE: 2699944
35435351001
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Total Volatile Solids
%
63.1
62.2 1
5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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QUALITY CONTROL DATA
Project: Pinellas County Pelletizer
Pace Project No.: 35434546
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
QC Batch: 498760 Analysis Method: ASTM D5057
QC Batch Method: ASTM D5057 Analysis Description: Spec. Gravity/Bulk Density,ASTM D5057
Associated Lab Samples: 35434546001
SAMPLE DUPLICATE: 2696270
Parameter
Specific Gravity
35434546001 Dup
Units Result Result
0.670 0.670
Max
RPD RPD Qualifiers
0 N2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35434546
QC Batch: 500924
Analysis Method:
EPA 350.1
QC Batch Method: EPA 350.1
Analysis Description:
350.1 Ammonia
Associated Lab Samples: 35434546001
METHOD BLANK: 2708280
Matrix: Solid
Associated Lab Samples: 35434546001
Blank Reporting
Parameter
Units
Result Limit
MDL
Analyzed
Qualifiers
Nitrogen, Ammonia
mg/kg
0.28 U 0.85 0.28
12/13/18 13:40
LABORATORY CONTROL SAMPLE:
2708281
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/kg
10.1 9.9
98
80-120
MATRIX SPIKE SAMPLE:
2708283
35434546001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/kg
1320 10.9
1380
544
80-120 M6
SAMPLE DUPLICATE: 2708282
35434546001 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Nitrogen, Ammonia
mg/kg
1320 1340 2
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35434546
QC Batch: 499337
Analysis Method:
EPA 351.2
QC Batch Method: EPA 351.2
Analysis Description:
351.2 TKN
Associated Lab Samples: 35434546001
METHOD BLANK: 2700021
Matrix: Solid
Associated Lab Samples: 35434546001
Blank Reporting
Parameter
Units
Result Limit
MDL
Analyzed
Qualifiers
Nitrogen, Kjeldahl, Total
mg/kg
10.4 U 20.9
10.4
12/10/18 13:33
LABORATORY CONTROL SAMPLE:
2700022
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits Qualifiers
Nitrogen, Kjeldahl, Total
mg/kg
858 793
92
90-110
MATRIX SPIKE SAMPLE:
2700024
35434706001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Nitrogen, Kjeldahl, Total
mg/kg
5.8 % (w/w) 3030
59000
19
90-110 M6
SAMPLE DUPLICATE: 2700023
35434706001 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Nitrogen, Kjeldahl, Total
mg/kg
5.8 % (w/w) 52900 10
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35434546
QC Batch: 498759
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite
Associated Lab Samples: 35434546001
METHOD BLANK: 2696265
Matrix: Solid
Associated Lab Samples: 35434546001
Blank Reporting
Parameter
Units
Result Limit MDL
Analyzed
Qualifiers
Nitrogen, Nitrate
mg/kg
0.25 U 0.50 0.25
12/05/18 17:45
Nitrogen, NO2 plus NO3
mg/kg
0.25 U 0.50 0.25
12/05/18 17:45
LABORATORY CONTROL SAMPLE:
2696266
Spike LCS LCS % Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Nitrogen, NO2 plus NO3
mg/kg
20 21.1 105
90-110
MATRIX SPIKE SAMPLE:
2696268
35433995001 Spike MS
MS
% Rec
Parameter
Units
Result Conc. Result
% Rec
Limits Qualifiers
Nitrogen, NO2 plus NO3
mg/kg
1.6 1 85.6 36.7
41
80-120 J(M1)
SAMPLE DUPLICATE: 2696267
35433995001 Dup
Max
Parameter
Units
Result Result RPD
RPD
Qualifiers
Nitrogen, Nitrate
mg/kg
1.6 1 1.1 1
20
Nitrogen, NO2 plus NO3
mg/kg
1.6 1 1.1 1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services, LLC
ceAnalX cal ® 110 South Bayview Blvd.
Oldsmar, FL 34677
www.pacelabs.com [phone]
QUALIFIERS
Project: Pinellas County Pelletizer
Pace Project No.: 35434546
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
IW_1.101Ica] Nl*I
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.
U Compound was analyzed for but not detected.
J(D6) Estimated Value. The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory
control limits.
J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS)
recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
N2 The lab does not hold NELAC/TNI accreditation for this parameter.
Q Sample held beyond the accepted holding time. Analysis initiated more than 15 minutes after sample collection.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project:
Pace Project No.:
Pinellas County Pelletizer
35434546
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
35434546001
Pellet
EPA 3050
499000
EPA 6010
499179
35434546001
Pellet
EPA 7471
499512
EPA 7471
500272
35434546001
Pellet
ASTM D2974-87
499847
35434546001
Pellet
SM 254OG
499325
35434546001
Pellet
SM 2540G
499323
35434546001
Pellet
EPA 9045
500705
35434546001
Pellet
ASTM D5057
498760
35434546001
Pellet
TKN-NH3 Calculation
502177
35434546001
Pellet
EPA 350.1
500924
EPA 350.1
501094
35434546001
Pellet
EPA 351.2
499337
EPA 351.2
499902
35434546001
Pellet
EPA 353.2
498759
EPA 353.2
498802
Date: 12/18/2018 03:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 20

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Sample Condition •• •Form (SCUR)
Project # WO# : 35434541" Date and Initials of person:
—ExannProject Manager: PM: CEM Due Date Label: abel: in co�rtents: (f�VL_
Label:
Client: CLIENT: 37-SYNAGRO Deliver:
pH:
Thermometer Used: T-202 Date: `1.2-r. `•- t t Time: Initials:
State of Origin:
lJocument Name.
Document Revsed:
IA7dLeArmlytic r
n u,K
Sample Condition Upon Receipt Farm
May 30, 2018
ocument o..
F -FL -C-007 rev. 13
Issuing u onty'
Pace Florida Quality Office
Sample Condition •• •Form (SCUR)
Project # WO# : 35434541" Date and Initials of person:
—ExannProject Manager: PM: CEM Due Date Label: abel: in co�rtents: (f�VL_
Label:
Client: CLIENT: 37-SYNAGRO Deliver:
pH:
Thermometer Used: T-202 Date: `1.2-r. `•- t t Time: Initials:
State of Origin:
FL
❑ For WV projects, all containers verified to s °C
Cooler #1 Temp.°A-�-
(Visual)
0.0 (Correction Factor) --1 _ (Actual)]
Samples on ice, cooling process has begun
Cooler #2 Temp.°C
(Visual)
(Correction Factor) (Actual)
❑ Samples on ice, cooling process has begun
Cooler #3 Temp.°C
(Visual)
(Correction Factor) (Actual)
❑ Samples on ice, cooling process has begun
Cooler #4 Temp.'C
(Visual)
(Correction Factor) (Actual)
❑ Samples on ice, cooling process has begun
Cooler #5 Tomp.'C
(Visual)
(Correction Factor) (Actual)
❑ Samples on ice, cooling process has begun
Cooler #6 Temp.°C
(Visual)
(Correction Factor) (Actual)
❑ Samples on ice, cooling process has begun
Containers Intact
s
❑ No ❑N/A
Courier, ❑ Fed Ex
❑ UPS
❑USPS Client ❑ Commercial ❑ Pace
❑ Other
Shipping Method: ❑ First Overnight
❑ Priority Overnight ❑ Standard Overnight ❑ Ground
❑ International Priority
❑ Other
Headspace in VOA Vials? (>6mm):
Trip Blank Present:
❑Yes
❑Yes
❑ No/A
❑ No N/A
Billing: ❑ Recipient
❑
Sender ❑ Third Party ❑ Credit Card ❑
Unknown
Tracking #
Custody Seal on Cooler/Box Present: [--]Yes �]No
Packing Material: []BubbleWrap ❑ Bubble Bagls VNIone
Samples shorted to lab (If Yes, complete) Shorted Date:
Seals intact: ❑ Yes ❑ No Ice:, Wet Blue Dry None
❑ Other
CnmManfr•
Shorted Time: Qty:
Chain of Custody Present
Yes
❑ No El N/A
Chain of Custody Filled Out
es
❑ No 11 N/A
Relinquished Signature & Sampler Name COC
es
❑ No ❑N/A
Samples Arrived within Hold Time
Yes
❑ No ❑N/A
Rush TAT requested on COC
❑Yes
o ❑N/A
Sufficient Volume
Yes
❑ No ❑N/A
Correct Containers Used
Y s
Q No ❑NIA
Containers Intact
s
❑ No ❑N/A
Sample Labels match COG (sample IDs & date/lime of
collection)
Yes
❑ No ❑NIA
All containers needing acid/base preservation have been
checked, ❑Yes
All Containers needing preservation are found to be in
compliance with EPA recommendaficn: ❑Yes
Exceptions VOA, Coliform, TOC, O&G, Carbamates
❑ NoIA
ElNo NY`` /A
Preservation Information:
preservative:
Lot #/Trace #:
Date: Time:
Initials,
Headspace in VOA Vials? (>6mm):
Trip Blank Present:
❑Yes
❑Yes
❑ No/A
❑ No N/A
U
Client Notification/ Resolution:
Person Contacted:
Comments/ Resolution (use back for additional comments):
DatefTime:
Project Manager Review: Date: Page 20 of 20

TestAmerica °
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
TestAmerica Laboratories, Inc.
TestAmerica Tampa
6712 Benjamin Road
Suite 100
Tampa, FL 33634
Tel: [phone]
TestAmerica Job ID: 660-85548-1
Client Project/Site: TCLP Biosolids SCB amd WED
roi
Synagro Technologies, Inc.
5900 74th St. N.
St. Petersburg, Florida 33709
Attn: Mr. William Reyes
Authorized for release by. -
212612018
y:2/26/2018 10:09:56 AM
Haukur Gudnason, Project Manager II
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited
parameters, exceptions are noted in this report. This report may not be reproduced except in full,
and with written approval from the laboratory. For questions please contact the Project Manager
at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.

Client: Synagro Technologies, Inc.
Project/Site: TCLP Biosolids SCB amd WED
Table of Contents
TestAmerica Job ID: 660-85548-1
CoverPage ..............................................
1
Table of Contents .........................................
2
Sample Summary .........................................
3
Case Narrative ...........................................
4
Definitions/Glossary.......................................
5
Detection Summary ........................................
6
Client Sample Results ......................................
7
QC Sample Results ........................................
13
QC Association Summary ...................................
22
Lab Chronicle ............................................
25
Method Summary .........................................
27
Certification Summary ......................................
28
Chain of Custody ..........................................
29
Receipt Checklists .........................................
30
TestAmerica Tampa
Page 2 of 30 2/26/2018

Sample Summary
Client: Synagro Technologies, Inc. TestAmerica Job ID: 660-85548-1
Project/Site: TCLP Biosolids SCB amd WED
Lab Sample ID Client Sample ID Matrix Collected Received
660-85548-1 SCB-CAKE-2-18 Solid 02/14/1807:30 02/14/1810:10
660-85548-2 WED -CAKE -2-18 Solid 02/14/18 09:28 02/14/18 10:10
TestAmerica Tampa
Page 3 of 30 2/26/2018

Client: Synagro Technologies, Inc. Case Narrative TestAmerica Job ID: 660-85548-1
Project/Site: TCLP Biosolids SCB amd WED
Job ID: 660-85548-1
Laboratory: TestAmerica Tampa
Narrative
Receipt
The samples were received on 2/14/2018 10:10 AM; the samples arrived in good condition, properly preserved and, where required, on
ice. The temperature of the cooler at receipt was 10.3° C.
GUMS VOA
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
GUMS Semi VOA
Method 8270D: The following samples required a dilution due to the nature of the sample matrix: WED -CAKE -2-18 (660-85548-2) and
(660 -85548 -B -2-G DU). Because of this dilution, the surrogate spike concentration in the sample was reduced to a level where the
recovery calculation does not provide useful information.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
GC Semi VOA
Method 8082: The following samples were diluted due to the nature of the sample matrix: SCB-CAKE-2-18 (660-85548-1) and
WED -CAKE -2-18 (660-85548-2). Elevated reporting limits (RL) are provided. F
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Metals
Method 7470A: The matrix spike / matrix spike duplicate (MS/MSD) recoveries and precision for batch 193075 were outside control limits.
Sample matrix interference and/or non -homogeneity are suspected because the associated laboratory control sample(LCS) recovery was
within acceptance limits.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Organic Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
TestAmerica Tampa
Page 4 of 30 2/26/2018

Definitions/Glossary
Client: Synagro Technologies, Inc.
Project/Site: TCLP Biosolids SCB amd WED
Qualifiers
GC/MS VOA
TestAmerica Job ID: 660-85548-1
Qualifier Qualifier Description
U Indicates that the compound was analyzed for but not detected.
GUMS Semi VOA
Qualifier Qualifier Description
U Indicates that the compound was analyzed for but not detected.
D1 Surrogate or matrix spike recoveries were not obtained because the extract was diluted for analysis
GC Semi VOA
Qualifier Qualifier Description
U Indicates that the compound was analyzed for but not detected.
Metals
Qualifier Qualifier Description
U Indicates that the compound was analyzed for but not detected.
J3 Estimated value; value may not be accurate. Spike recovery or RPD outside of criteria.
I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.
Glossary
Abbreviation
a
%R
CFL
CNF
DER
Dil Fac
DL
DL, RA, RE, IN
DLC
EDL
LOD
LOQ
MDA
MDC
MDL
ML
NC
ND
PQL
QC
RER
RL
RPD
TEF
TEQ
These commonly used abbreviations may or may not be present in this report.
Listed under the "D" column to designate that the result is reported on a dry weight basis
Percent Recovery
Contains Free Liquid
Contains No Free Liquid
Duplicate Error Ratio (normalized absolute difference)
Dilution Factor
Detection Limit (DoD/DOE)
Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample
Decision Level Concentration (Radiochemistry)
Estimated Detection Limit (Dioxin)
Limit of Detection (DoD/DOE)
Limit of Quantitation (DoD/DOE)
Minimum Detectable Activity (Radiochemistry)
Minimum Detectable Concentration (Radiochemistry)
Method Detection Limit
Minimum Level (Dioxin)
Not Calculated
Not Detected at the reporting limit (or MDL or EDL if shown)
Practical Quantitation Limit
Quality Control
Relative Error Ratio (Radiochemistry)
Reporting Limit or Requested Limit (Radiochemistry)
Relative Percent Difference, a measure of the relative difference between two points
Toxicity Equivalent Factor (Dioxin)
Toxicity Equivalent Quotient (Dioxin)
TestAmerica Tampa
Page 5 of 30 2/26/2018

Detection Summary
Client: Synagro Technologies, Inc.
Project/Site: TCLP Biosolids SCB amd WED
TestAmerica Job ID: 660-85548-1
Client Sample ID: SCB-CAKE-2-18
Lab Sample ID: 660-85548-1
1 No Detections.
Client Sample ID: WED -CAKE -2-18
Lab Sample ID: 660-85548-2
Analyte Result Qualifier
PQL
MDL Unit
Dil Fac D Method Prep Type
2-Butanone (MEK) 190
100
32 ug/L
10 82608 TCLP
3 & 4 Methylphenol - DL 2500
190
40 ug/L
20 8270D TCLP
Barium 0.034 1
0.50
0.030 mg/L
1 60108 TCLP
F
F
F
This Detection Summary does not include radiochemical test results.
TestAmerica Tampa
Page 6 of 30
2/26/2018

Client Sample Results
Client: Synagro Technologies, Inc.
Result
Qualifier
PQL
MDL
Unit
TestAmerica Job ID: 660-85548-1
Project/Site: TCLP Biosolids SCB amd WED
Dil Fac
3 & 4 Methylphenol
2.0
U
9.6
2.0
Client Sample ID: SCB-CAKE-2-18
02/22/18 08:01
02/22/18 14:10
1
2-Methylphenol
Lab Sample ID: 660-85548-1
Date Collected: 02/14/18 07:30
9.6
2.1
ug/L
02/22/18 08:01
02/22/18 14:10
Matrix:
Solid
Date Received: 02/14/18 10:10
U
9.6
2.5
ug/L
02/22/18 08:01
02/22/18 14:10
1
F
Method: 8260B - Volatile Organic Compounds (GC/MS) - TCLP
3.4
U
14
3.4
Analyte
Result
Qualifier
PQL
MDL
Unit
D Prepared Analyzed
Dil Fac
Benzene
2.5
U
10
2.5
ug/L
02/22/1814:26
10
Carbon tetrachloride
2.3
U
10
2.3
ug/L
02/22/18 14:26
10
Chlorobenzene
2.7
U
10
2.7
ug/L
02/22/1814:26
10
Chloroform
2.9
U
10
2.9
ug/L
02/22/1814:26
10
1,4 -Dichlorobenzene
2.2
U
10
2.2
ug/L
02/22/1814:26
10
1,2-Dichloroethane
3.1
U
10
3.1
ug/L
02/22/1814:26
10
1,1-Dichloroethene
2.6
U
10
2.6
ug/L
02/22/1814:26
10
2-Butanone (MEK)
32
U
100
32
ug/L
02/22/18 14:26
10
Trichloroethene
6.1
U
20
6.1
ug/L
02/22/1814:26
10
Tetrachloroethene
5.0
U
20
5.0
ug/L
02/22/1814:26
10
Vinyl chloride
2.6
U
10
2.6
ug/L
02/22/18 14:26
10
Surrogate
%Recovery
Qualifier
Limits
02/22118 08:01
02/22118 14:10
Prepared Analyzed
Dil Fac
4-Bromofluorobenzene
102
39-130
70-130
02/22118 08:01
021221181
10
Dibromofluoromethane
103
70-130
02/22/18 14:26
10
Toluene -d8 (Surr)
103
70-130
02/22/18 14:26
10
Method: 8270D - Semivolatile Organic Compounds (GC/MS) - TCLP
Analyte
Result
Qualifier
PQL
MDL
Unit
D Prepared
Analyzed
Dil Fac
3 & 4 Methylphenol
2.0
U
9.6
2.0
ug/L
02/22/18 08:01
02/22/18 14:10
1
2-Methylphenol
2.1
U
9.6
2.1
ug/L
02/22/18 08:01
02/22/18 14:10
1
1,4 -Dichlorobenzene
2.5
U
9.6
2.5
ug/L
02/22/18 08:01
02/22/18 14:10
1
2,4-Dinitrotoluene
3.4
U
14
3.4
ug/L
02/22/18 08:01
02/22/18 14:10
1
Hexachlorobenzene
1.2
U
3.8
1.2
ug/L
02/22/18 08:01
02/22/18 14:10
1
Hexachlorobutadiene
4.1
U
14
4.1
ug/L
02/22/18 08:01
02/22/18 14:10
1
Nitrobenzene
1.2
U
9.6
1.2
ug/L
02/22/18 08:01
02/22/18 14:10
1
Pentachlorophenol
6.1
U
19
6.1
ug/L
02/22/18 08:01
02/22/18 14:10
1
Pyridine
3.0
U
48
3.0
ug/L
02/22/18 08:01
02/22/18 14:10
1
2,4,6 -Trichlorophenol
2.3
U
9.6
2.3
ug/L
02/22/18 08:01
02/22/18 14:10
1
Surrogate
%Recovery
Qualifier
Limits
Prepared
Analyzed
Dil Fac
2,4,6-Tribromophenol (Surr)
85
31-141
02/22/18 08:01
02/22/18 14:10
1
2-Fluorophenol (Surr)
63
25-130
02/22/18 08:01
02/22/18 14:10
1
Phenol -d5 (Surr)
54
25-130
02/22/18 08:01
02/22/18 14:10
1
2-Fluorobiphenyl
82
38-130
02/22118 08:01
02/22118 14:10
1
Nitrobenzene -d5 (Surr)
87
39-130
02/22118 08:01
02/22118 14:10
1
Terphenyl-d14 (Surr)
78
10-143
02/22118 08:01
02/22118 14:10
1
Method: 6010B - Metals (ICP) - TCLP
Analyte
Result
Qualifier
PQL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Silver
0.050
U
0.50
0.050
mg/L
02/21/18 14:00
02/22/18 06:56
1
Arsenic
0.12
U
1.0
0.12
mg/L
02/21/18 14:00
02/22/18 06:56
1
Barium
0.030
U
0.50
0.030
mg/L
02/21/18 14:00
02/22/18 06:56
1
Cadmium
0.018
U
0.50
0.018
mg/L
02/21/18 14:00
02/22/18 06:56
1
Chromium
0.050
U
1.0
0.050
mg/L
02/21/18 14:00
02/22/18 06:56
1
Lead
0.040
U
1.0
0.040
mg/L
02/21/18 14:00
02/22/18 06:56
1
Selenium
0.15
U
0.50
0.15
mg/L
02/21/18 14:00
02/22/18 06:56
1
TestAmerica Tampa
Page 7 of 30 2/26/2018

Client Sample Results
Client: Synagro Technologies, Inc. TestAmerica Job ID: 660-85548-1
Project/Site: TCLP Biosolids SCB amd WED
Client Sample ID: SCB-CAKE-2-18 Lab Sample ID: 660-85548-1
Date Collected: 02/14/18 07:30 Matrix: Solid
Date Received: 02/14/18 10:10
Method: 7470A - Mercury (CVAA) - TCLP
Analyte Result Qualifier PQL MDL Unit D Prepared Analyzed Dil Fac
Mercury 0.00050 U 0.00070 0.00050 mg/L 02/21/1813:00 02/21/1816:26 1
TestAmerica Tampa
Page 8 of 30 2/26/2018

Client Sample Results
Client: Synagro Technologies, Inc.
TestAmerica Job ID: 660-85548-1
Project/Site: TCLP Biosolids SCB amd WED
Client Sample ID: SCB-CAKE-2-18
Lab Sample ID: 660-85548-1
Date Collected: 02/14/18 07:30
Matrix: Solid
Date Received: 02/14/18 10:10
Percent Solids: 19.2
Method: 8082 - Polychlorinated Biphenyls (PCBs) by Gas Chromatography
Analyte
Result
Qualifier
PQL
MDL
Unit
D
Prepared
Analyzed Dil Fac
PCB -1016
240
U
1000
240
ug/Kg
0
02/21/1811:06
02/22/1812:07 1
PCB -1221
510
U
1500
510
ug/Kg
02/21/1811:06
02/22/1812:07 1
PCB -1232
270
U
1000
270
ug/Kg
02/21/1811:06
02/22/1812:07 1
PCB -1242
430
U
1300
430
ug/Kg
02/21/1811:06
02/22/1812:07 1
PCB -1248
300
U
1000
300
ug/Kg
02/21/1811:06
02/22/1812:07 1
PCB -1254
150
U
500
150
ug/Kg
02/21/1811:06
02/22/1812:07 1
PCB -1260
230
U
680
230
ug/Kg
02/21/1811:06
02/22/1812:07 1
Surrogate
%Recovery
Qualifier
Limits
Prepared
Analyzed DY Fac
DCB Decachlorobiphenyl
60
30-150
02/21/18 11:06
02/22/18 12:07 1
Tetrachloro-m-xylene
99
30-150
02/21/18 11:06
02/22/18 12:07 1
TestAmerica Tampa
Page 9 of 30 2/26/2018

Client Sample Results
Client: Synagro Technologies, Inc.
Result
Qualifier
PQL
MDL
Unit
TestAmerica Job ID: 660-85548-1
Project/Site: TCLP Biosolids SCB amd WED
Dil Fac
2-Methylphenol
2.1
U
9.6
2.1
Client Sample ID: WED -CAKE
-2-18
02/22/18 14:58
1
1,4 -Dichlorobenzene
2.5
Lab Sample ID: 660-85548-2
Date Collected: 02/14/18 09:28
2.5
ug/L
02/22/18 08:01
02/22/18 14:58
1
Matrix:
Solid
Date Received: 02/14/18 10:10
14
3.4
ug/L
02/22/18 08:01
02/22/18 14:58
1
Hexachlorobenzene
F
Method: 8260B - Volatile Organic Compounds (GC/MS) - TCLP
U
3.8
1.2
ug/L
Analyte
Result
Qualifier
PQL
MDL
Unit
D Prepared Analyzed
Dil Fac
Benzene
2.5
U
10
2.5
ug/L
02/22/1815:48
10
Carbon tetrachloride
2.3
U
10
2.3
ug/L
02/22/18 15:48
10
Chlorobenzene
2.7
U
10
2.7
ug/L
02/22/1815:48
10
Chloroform
2.9
U
10
2.9
ug/L
02/22/1815:48
10
1,4 -Dichlorobenzene
2.2
U
10
2.2
ug/L
02/22/1815:48
10
1,2-Dichloroethane
3.1
U
10
3.1
ug/L
02/22/1815:48
10
1,1-Dichloroethene
2.6
U
10
2.6
ug/L
02/22/1815:48
10
2-Butanone (MEK)
190
2-Fluorophenol (Surr)
100
32
ug/L
02/22/18 15:48
10
Trichloroethene
6.1
U
20
6.1
ug/L
02/22/1815:48
10
Tetrachloroethene
5.0
U
20
5.0
ug/L
02/22/1815:48
10
Vinyl chloride
2.6
U
10
2.6
ug/L
02/22/18 15:48
10
Surrogate
%Recovery
Qualifier
Limits
02/22/18 14:58
1
Prepared Analyzed
Dil Fac
4-Bromofluorobenzene
103
70-130
02/22/18 08:01
02/22/18 14:58
021221181
10
Dibromofluoromethane
103
(GC/MS) - TCLP
70-130
02/22/18 15:48
10
Toluene -d8 (Surr)
105
Qualifier
70-130
MDL
Unit
02/22/18 15:48
10
Method: 8270D - Semivolatile Organic Compounds (GC/MS) - TCLP
Analyte
Result
Qualifier
PQL
MDL
Unit
D Prepared
Analyzed
Dil Fac
2-Methylphenol
2.1
U
9.6
2.1
ug/L
02/22/18 08:01
02/22/18 14:58
1
1,4 -Dichlorobenzene
2.5
U
9.6
2.5
ug/L
02/22/18 08:01
02/22/18 14:58
1
2,4-Dinitrotoluene
3.4
U
14
3.4
ug/L
02/22/18 08:01
02/22/18 14:58
1
Hexachlorobenzene
1.2
U
3.8
1.2
ug/L
02/22/18 08:01
02/22/18 14:58
1
Hexachlorobutadiene
4.1
U
14
4.1
ug/L
02/22/18 08:01
02/22/18 14:58
1
Nitrobenzene
1.2
U
9.6
1.2
ug/L
02/22/18 08:01
02/22/18 14:58
1
Pentachlorophenol
6.1
U
19
6.1
ug/L
02/22/18 08:01
02/22/18 14:58
1
Pyridine
3.0
U
48
3.0
ug/L
02/22/18 08:01
02/22/18 14:58
1
2,4,6 -Trichlorophenol
2.3
U
9.6
2.3
ug/L
02/22/18 08:01
02/22/18 14:58
1
Surrogate
%Recovery
Qualifier
Limits
Prepared
Analyzed
Dil Fac
2,4,6-Tribromophenol (Surr)
87
31-141
02/22/18 08:01
02/22/18 14:58
1
2-Fluorophenol (Surr)
68
25-130
02/22/18 08:01
02/22/18 14:58
1
Phenol -d5 (Surr)
55
25-130
02/22/18 08:01
02/22/18 14:58
1
2-Fluorobiphenyl
62
38-130
02/22/18 08:01
02/22/18 14:58
1
Nitrobenzene -d5 (Surr)
59
39-130
02/22/18 08:01
02/22/18 14:58
1
Terphenyl-d14 (Surr)
67
10-143
02/22/18 08:01
02/22/18 14:58
1
Method: 8270D - Semivolatile
Organic Compounds
(GC/MS) - TCLP
- DL
Analyte
Result
Qualifier
PQL
MDL
Unit
D Prepared
Analyzed
Dil Fac
3 & 4 Methylphenol
2500
190
40
ug/L
02/22/18 08:01
02/22/18 16:53
20
Surrogate
%Recovery
Qualifier
Limits
Prepared
Analyzed
Dil Fac
2,4,6-Tribromophenol (Surr)
0
D1
31-141
02/22/18 08:01
02/22/18 16:53
20
2-Fluorophenol (Surr)
0
DI
25-130
02/22/18 08:01
02/22/18 16:53
20
Phenol -d5 (Surr)
0
DI
25-130
02/22/18 08:01
02/22/18 16:53
20
2-Fluorobiphenyl
0
D1
38-130
02/22/18 08:01
02/22/18 16:53
20
Nitrobenzene -d5 (Surr)
0
D1
39-130
02/22/18 08:01
02/22/18 16:53
20
Terphenyl-d 14 (Surr)
0
D1
10-143
02/22/18 08:01
02/22/18 16:53
20
TestAmerica Tampa
Page 10 of 30 2/26/2018

Client Sample Results
Client: Synagro Technologies, Inc.
TestAmerica Job ID: 660-85548-1
Project/Site: TCLP Biosolids SCB amd WED
Client Sample ID: WED -CAKE -2-18
Lab Sample ID: 660-85548-2
Date Collected: 02/14/18 09:28
Matrix: Solid
Date Received: 02/14/18 10:10
Method: 6010B - Metals (ICP) - TCLP
Analyte Result
Qualifier
PQL
MDL
Unit
D Prepared
Analyzed Dil Fac
Silver 0.050
U
0.50
0.050
mg/L
02/21/18 14:00
02/22/18 07:09 1
Arsenic 0.12
U
1.0
0.12
mg/L
02/21/18 14:00
02/22/18 07:09 1
Barium 0.034
1
0.50
0.030
mg/L
02/21/18 14:00
02/22/18 07:09 1
Cadmium 0.018
U
0.50
0.018
mg/L
02/21/18 14:00
02/22/18 07:09 1
Chromium 0.050
U
1.0
0.050
mg/L
02/21/18 14:00
02/22/18 07:09 1
Lead 0.040
U
1.0
0.040
mg/L
02/21/18 14:00
02/22/18 07:09 1
Selenium 0.15
U
0.50
0.15
mg/L
02/21/18 14:00
02/22/18 07:09 1
Method: 7470A - Mercury (CVAA) - TCLP
Analyte Result
Qualifier
PQL
MDL
Unit
D Prepared
Analyzed Dil Fac
Mercury ObOO50
U
ObOM
ObOM
mg/L
02/21/1813:00
02/21/1816:32 1
TestAmerica Tampa
Page 11 of 30 2/26/2018

Client Sample Results
Client: Synagro Technologies, Inc.
TestAmerica Job ID: 660-85548-1
Project/Site: TCLP Biosolids SCB amd WED
Client Sample ID: WED -CAKE
-2-18
Lab Sample ID: 660-85548-2
Date Collected: 02/14/18 09:28
Matrix: Solid
Date Received: 02/14/18 10:10
Percent Solids: 15.9
Method: 8082 - Polychlorinated Biphenyls (PCBs) by Gas Chromatography
Analyte
Result
Qualifier
PQL
MDL
Unit
D
Prepared
Analyzed Dil Fac
PCB -1016
300
U
1200
300
ug/Kg
*
02/21/1811:06
02/22/1812:21 1
PCB -1221
620
U
1800
620
ug/Kg
02/21/1811:06
02/22/1812:21 1
PCB -1232
330
U
1200
330
ug/Kg
02/21/1811:06
02/22/1812:21 1
PCB -1242
520
U
1600
520
ug/Kg
02/21/1811:06
02/22/1812:21 1
PCB -1248
370
U
1200
370
ug/Kg
02/21/1811:06
02/22/1812:21 1
PCB -1254
180
U
610
180
ug/Kg
02/21/1811:06
02/22/1812:21 1
PCB -1260
280
U
830
280
ug/Kg
02/21/1811:06
02/22/1812:21 1
Surrogate
%Recovery
Qualifier
Limits
Prepared
Analyzed Dil Fac
DCB Decachlorobiphenyl
97
30-150
02/21/18 11:06
02/22/18 12:21 1
Tetrachloro-m-xylene
114
30-150
02/21/18 11:06
02/22/18 12:21 1
TestAmerica Tampa
Page 12 of 30 2/26/2018

QC Sample Results
Client: Synagro Technologies, Inc.
TestAmerica Job ID: 660-85548-1
Project/Site: TCLP Biosolids SCB amd WED
Method: 8260B - Volatile Organic Compounds
(GC/MS)
Lab Sample ID: MB 660-193118/6
Client Sample
ID: Method Blank
Matrix: Solid
Prep Type: Total/NA
Analysis Batch: 193118
MB
MB
Analyte
Result
Qualifier
PQL
MDL
Unit
D Prepared
Analyzed Dil Fac
Benzene
0.25
U
1.0
0.25
ug/L
02/22/1813:50 1
Carbon tetrachloride
0.23
U
1.0
0.23
ug/L
02/22/18 13:50 1
Chlorobenzene
0.27
U
1.0
0.27
ug/L
02/22/1813:50 1
Chloroform
0.29
U
1.0
0.29
ug/L
02/22/1813:50 1
1,4 -Dichlorobenzene
0.22
U
1.0
0.22
ug/L
02/22/1813:50 1 •
1,2-Dichloroethane
0.31
U
1.0
0.31
ug/L
02/22/1813:50 1
1,1-Dichloroethene
0.26
U
1.0
0.26
ug/L
02/22/1813:50 1
2-Butanone (MEK)
3.2
U
10
3.2
ug/L
02/22/18 13:50 1
Trichloroethene
0.61
U
2.0
0.61
ug/L
02/22/1813:50 1
Tetrachloroethene
0.50
U
2.0
0.50
ug/L
02/22/1813:50 1
Vinyl chloride
0.26
U
1.0
0.26
ug/L
02/22/18 13:50 1
MB
MB
Surrogate %Recovery
Qualifier
Limits
Prepared
Analyzed Dil Fac
4-Bromofluorobenzene
102
70-130
02/22/18 13:50 1
Dibromofluoromethane
106
70-130
02/22/18 13:50 1
Toluene -d8 (Surr)
103
70-130
02/22/18 13:50 1
Lab Sample ID: LCS 660-193118/4
Client
Sample ID:
Lab Control Sample
Matrix: Solid
Prep Type: Total/NA
Analysis Batch: 193118
Spike
LCS
LCS
%Rec.
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits
Benzene
10.0
9.23
ug/L
92
69-131
Carbon tetrachloride
10.0
9.50
ug/L
95
62-124
Chlorobenzene
10.0
9.79
ug/L
98
68-128
Chloroform
10.0
9.79
ug/L
98
77-117
1,4 -Dichlorobenzene
10.0
9.36
ug/L
94
69-133
1,2-Dichloroethane
10.0
9.57
ug/L
96
65-125
1,1-Dichloroethene
10.0
8.85
ug/L
89
62-133
2-Butanone (MEK)
100
104
ug/L
104
65-129
Trichloroethene
10.0
9.53
ug/L
95
68-128
Tetrachloroethene
10.0
9.65
ug/L
97
65-125
Vinyl chloride
10.0
8.82
ug/L
88
59-136
LCS LCS
Surrogate %Recovery Qualifier
Limits
4-Bromofluorobenzene
98
70-130
Dibromofluoromethane
104
70-130
Toluene -d8 (Surr)
100
70-130
Lab Sample ID: LB 660-193135/1-A
Client Sample
ID: Method Blank
Matrix: Solid
Prep Type: TCLP
Analysis Batch: 193118
LB
LB
Analyte
Result
Qualifier
PQL
MDL
Unit
D Prepared
Analyzed Dil Fac
Benzene
2.5
U
10
2.5
ug/L
02/22/1814:08 10
Carbon tetrachloride
2.3
U
10
2.3
ug/L
02/22/18 14:08 10
Chlorobenzene
2.7
U
10
2.7
ug/L
02/22/1814:08 10
TestAmerica Tampa
Page 13 of 30 2/26/2018

QC Sample Results
Client: Synagro Technologies, Inc.
TestAmerica Job ID: 660-85548-1
Project/Site: TCLP Biosolids SCB
amd WED
Method: 82608 - Volatile Organic Compounds
(GC/MS) (Continued)
Lab Sample ID: LB 660-193135/1-A
Client Sample
ID: Method
Blank
Matrix: Solid
Prep Type:
TCLP
Analysis Batch: 193118
LB LB
Analyte
Result Qualifier
PQL
MDL Unit
D Prepared
Analyzed
Dil Fac
Chloroform
2.9 U
10
2.9 ug/L
02/22/1814:08
10
1,4 -Dichlorobenzene
2.2 U
10
2.2 ug/L
02/22/1814:08
10
1,2-Dichloroethane
3.1 U
10
3.1 ug/L
02/22/1814:08
10
1,1-Dichloroethene
2.6 U
10
2.6 ug/L
02/22/1814:08
10
2-Butanone (MEK)
32 U
100
32 ug/L
02/22/18 14:08
10
Trichloroethene
6.1 U
20
6.1 ug/L
02/22/1814:08
10
Tetrachloroethene
5.0 U
20
5.0 ug/L
02/22/1814:08
10
Vinyl chloride
2.6 U
10
2.6 ug/L
02/22/18 14:08
10
LB LB
Surrogate
%Recovery Qualifier
Limits
Prepared
Analyzed
Dil Fac
4-Bromofluorobenzene
99
70-130
02/22/18 14:08
10
Dibromofluoromethane
101
70-130
02/22/18 14:08
10
Toluene -d8 (Surr)
101
70-130
02/22/18 14:08
10
Lab Sample ID: 660-85548-2 MS
Client Sample ID: WED -CAKE -2-18
Matrix: Solid
Prep Type:
TCLP
Analysis Batch: 193118
Sample
Sample
Spike
MS
MS
%Rec.
Analyte
Result
Qualifier
Added
Result
Qualifier
Unit
D %Rec
Limits
Benzene
2.5
U
100
95.9
ug/L
96
69-131
Carbon tetrachloride
2.3
U
100
93.9
ug/L
94
62-124
Chlorobenzene
2.7
U
100
96.6
ug/L
97
68-128
Chloroform
2.9
U
100
97.0
ug/L
97
77-117
1,4 -Dichlorobenzene
2.2
U
100
96.4
ug/L
96
69-133
1,2-Dichloroethane
3.1
U
100
100
ug/L
100
65-125
1,1-Dichloroethene
2.6
U
100
88.5
ug/L
89
62-133
2-Butanone (MEK)
190
1000
1320
ug/L
113
65-129
Trichloroethene
6.1
U
100
95.0
ug/L
95
68-128
Tetrachloroethene
5.0
U
100
93.0
ug/L
93
65-125
Vinyl chloride
2.6
U
100
85.3
ug/L
85
59-136
MS
MS
Surrogate %Recovery
Qualifier
Limits
4-Bromofluorobenzene
99
70-130
Dibromofluoromethane
104
70-130
Toluene -d8 (Surr)
106
70-130
Lab Sample ID: 660-85548-2 MSD
Client Sample ID: WED -CAKE -2-18
Matrix: Solid
Prep Type:
TCLP
Analysis Batch: 193118
Sample
Sample
Spike
MSD
MSD
%Rec.
RPD
Analyte
Result
Qualifier
Added
Result
Qualifier
Unit
D %Rec
Limits RPD
Limit
Benzene
2.5
U
100
95.0
ug/!-
95
69-131 1
30
Carbon tetrachloride
2.3
U
100
94.1
ug/L
94
62-124 0
30
Chlorobenzene
2.7
U
100
94.2
ug/L
94
68-128 3
30
Chloroform
2.9
U
100
99.1
ug/L
99
77-117 2
30
1,4 -Dichlorobenzene
2.2
U
100
96.3
ug/L
96
69-133 0
30
1,2-Dichloroethane
3.1
U
100
93.8
ug/L
94
65-125 7
30
1,1-Dichloroethene
2.6
U
100
88.2
ug/L
88
62-133 0
30
TestAmerica Tampa
Page 14 of 30 2/26/2018

QC Sample Results
Client: Synagro Technologies, Inc.
Project/Site: TCLP Biosolids SCB amd WED
TestAmerica Job ID: 660-85548-1
Method: 82608 - Volatile Organic Compounds (GC/MS) (Continued)
MB MB
Lab Sample ID: 660-85548-2 MSD
Surrogate %Recovery
Qualifier
Limits
Client Sample
ID: WED -CAKE -2-18
Matrix: Solid
Analyzed Dil Fac
2,4,6-Tribromophenol (Surr)
63
31-141
02/22/18 08:01
Prep Type: TCLP
Analysis Batch: 193118
51
25-130
02/22/18 08:01
02/22/18 12:59 1
Phenol -d5 (Surr)
43
Sample
Sample
Spike
02/22/18 08:01
MSD MSD
2-Fluorobiphenyl
69
38-130
%Rec. RPD
Analyte Result
Qualifier
Added
Nitrobenzene -d5 (Surr)
Result Qualifier
39-130
Unit
D %Rec
Limits RPD Limit
2-Butanone (MEK) 190
Terphenyl-d14 (Surr)
1000
10-143
1280
ug/L
109
65-129 3 30
Trichloroethene 6.1
U
100
Client Sample ID:
96.8
Matrix: Solid
ug/L
97
68-128 2 30
Tetrachloroethene 5.0
U
100
Analysis Batch: 193097
88.5
ug/L
88
65-125 5 30
Vinyl chloride 2.6
U
100
Spike
87.6
ug/L
88
59-136 3 30
MSD
MSD
Result Qualifier
Unit
D %Rec
Limits
3 & 4 Methylphenol
100
Surrogate %Recovery
Qualifier
Limits
32 -112
2-Methylphenol
100
69.5
ug/L
4-Bromofluorobenzene IN
31-110
70-130
100
65.0
ug/L
65
23-110
Dibromofluoromethane 101
70-130
82.7
ug/L
83
46-130
Hexachlorobenzene
Toluene -d8 (Surr) 102
81.8
70-130
82
43-119
Hexachlorobutadiene
100
69.5
Method: 8270D - Semivolatile Organic Compounds
(GC/MS)
22-110
FLab Sample ID: MB 660-193093/1-A
Client Sample ID: Method Blank
Matrix: Solid
Prep Type: Total/NA
Analysis Batch: 193097
Prep Batch: 193093
MB MB
Analyte Result Qualifier
PQL
MDL
Unit
D Prepared
Analyzed Dil Fac
3 & 4 Methylphenol
2.1 U
10
2.1
ug/L
02/22/18 08:01
02/22/18 12:59 1
2-Methylphenol
2.2 U
10
2.2
ug/L
02/22/18 08:01
02/22/18 12:59 1
1,4 -Dichlorobenzene
2.6 U
10
2.6
ug/L
02/22/18 08:01
02/22/18 12:59 1
2,4-Dinitrotoluene
3.6 U
15
3.6
ug/L
02/22/18 08:01
02/22/18 12:59 1
Hexachlorobenzene
1.3 U
4.0
1.3
ug/L
02/22/18 08:01
02/22/18 12:59 1
Hexachlorobutadiene
4.3 U
15
4.3
ug/L
02/22/18 08:01
02/22/18 12:59 1
Nitrobenzene
1.2 U
10
1.2
ug/L
02/22/18 08:01
02/22/18 12:59 1
Pentachlorophenol
6.3 U
20
6.3
ug/L
02/22/18 08:01
02/22/18 12:59 1
Pyridine
3.1 U
50
3.1
ug/L
02/22/18 08:01
02/22/18 12:59 1
2,4,6 -Trichlorophenol
2.4 U
10
2.4
ug/L
02/22/18 08:01
02/22/18 12:59 1
TestAmerica Tampa
Page 15 of 30 2/26/2018
0
MB MB
Surrogate %Recovery
Qualifier
Limits
Prepared
Analyzed Dil Fac
2,4,6-Tribromophenol (Surr)
63
31-141
02/22/18 08:01
02/22/18 12:59 1
2-Fluorophenol (Surr)
51
25-130
02/22/18 08:01
02/22/18 12:59 1
Phenol -d5 (Surr)
43
25-130
02/22/18 08:01
02/22/18 12:59 1
2-Fluorobiphenyl
69
38-130
02/22/18 08:01
02/22/18 12:59 1
Nitrobenzene -d5 (Surr)
72
39-130
02/22/18 08:01
02/22/18 12:59 1
Terphenyl-d14 (Surr)
68
10-143
02/22/18 08:01
02/22/18 12:59 1
Lab Sample ID: LCS 660-193093/2-A
Client Sample ID:
Lab Control Sample
Matrix: Solid
Prep Type: Total/NA
Analysis Batch: 193097
Prep Batch: 193093
Spike
LCS LCS
%Rec.
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
3 & 4 Methylphenol
100
68.2
ug/L
68
32 -112
2-Methylphenol
100
69.5
ug/L
70
31-110
1,4 -Dichlorobenzene
100
65.0
ug/L
65
23-110
2,4-Dinitrotoluene
100
82.7
ug/L
83
46-130
Hexachlorobenzene
100
81.8
ug/L
82
43-119
Hexachlorobutadiene
100
69.5
ug/L
70
22-110
TestAmerica Tampa
Page 15 of 30 2/26/2018
0

QC Sample Results
Client: Synagro Technologies, Inc. TestAmerica Job ID: 660-85548-1
Project/Site: TCLP Biosolids SCB amd WED
Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued)
Lab Sample ID: LCS 660-193093/2-A
Matrix: Solid
Analysis Batch: 193097
Analyte
Nitrobenzene
Pentachlorophenol
Pyridine
2,4,6 -Trichlorophenol
Surrogate
LCS LCS
%Recovery Qualifier
2,4,6-Tribromophenol (Surr)
82
2-Fluorophenol (Surr)
58
Phenol -d5 (Surr)
49
2-Fluorobiphenyl
72
Nitrobenzene -d5 (Surr)
76
Terphenyl-d14 (Surr)
75
Spike
Added
100
200
200
100
Limits
31-141
25-130
25-130
38-130
39-130
10-143
0
Lab Sample ID: LB 660-193058/1-B
Client Sample ID: Lab Control Sample
Prep Type: Total/NA
Client Sample ID: Method Blank
Prep Batch: 193093
LCS LCS
%Rec.
Result Qualifier
Unit
D %Rec
Limits
79.0
ug/L
79
27-113
190
ug/L
95
33-138
113
ug/L
56
10-110
82.0
ug/L
82
38-119
0
Lab Sample ID: LB 660-193058/1-B
Client Sample ID: Method Blank
Matrix: Solid
Prep Type: TCLP
Analysis Batch: 193097
Prep Batch: 193093
LB
LB
Analyte
Result
Qualifier
PQL
MDL
Unit
D Prepared
Analyzed Dil Fac
3 & 4 Methylphenol
2.0
U
9.6
2.0
ug/L
02/22/18 08:01
02/22/18 13:46 1
2-Methylphenol
2.1
U
9.6
2.1
ug/L
02/22/18 08:01
02/22/18 13:46 1
1,4 -Dichlorobenzene
2.5
U
9.6
2.5
ug/L
02/22/18 08:01
02/22/18 13:46 1
2,4-Dinitrotoluene
3.4
U
14
3.4
ug/L
02/22/18 08:01
02/22/18 13:46 1
Hexachlorobenzene
1.2
U
3.8
1.2
ug/L
02/22/18 08:01
02/22/18 13:46 1
Hexachlorobutadiene
4.1
U
14
4.1
ug/L
02/22/18 08:01
02/22/18 13:46 1
Nitrobenzene
1.2
U
9.6
1.2
ug/L
02/22/18 08:01
02/22/18 13:46 1
Pentachlorophenol
6.1
U
19
6.1
ug/L
02/22/18 08:01
02/22/18 13:46 1
Pyridine
3.0
U
48
3.0
ug/L
02/22/18 08:01
02/22/18 13:46 1
2,4,6 -Trichlorophenol
2.3
U
9.6
2.3
ug/L
02/22/18 08:01
02/22/18 13:46 1
LB
LB
Surrogate
%Recovery
Qualifier
Limits
Prepared
Analyzed Dil Fac
2,4,6-Tribromophenol (Surr)
51
31-141
02/22/18 08:01
02/22/18 13:46 1
2-Fluorophenol (Surr)
43
25-130
02/22/18 08:01
02/22/18 13:46 1
Phenol -d5 (Surr)
40
25-130
02/22/18 08:01
02/22/18 13:46 1
2-Fluorobiphenyl
63
38-130
02/22/18 08:01
02/22/18 13:46 1
Nitrobenzene -d5 (Surr)
66
39-130
02/22/18 08:01
02/22/18 13:46 1
Terphenyl-d14 (Surr)
67
10-143
02/22/18 08:01
02/22/18 13:46 1
Lab Sample ID: 660-85548-1 MS
Client Sample
ID: SCB-CAKE-2-18
Matrix: Solid
Prep Type: TCLP
Analysis Batch: 193097
Prep Batch: 193093
Sample
Sample
Spike
MS
MS
%Rec.
Analyte
Result
Qualifier
Added
Result
Qualifier
Unit
D %Rec
Limits
3 & 4 Methylphenol
2.0
U
96.2
50.0
ug/L
52
32-112
2-Methylphenol
2.1
U
96.2
52.0
ug/L
54
31-110
1,4 -Dichlorobenzene
2.5
U
96.2
46.2
ug/L
48
23-110
2,4-Dinitrotoluene
3.4
U
96.2
67.1
ug/L
70
46-130
Hexachlorobenzene
1.2
U
96.2
62.8
ug/L
65
43-119
Hexachlorobutadiene
4.1
U
96.2
52.0
ug/L
54
22-110
Page 16 of 30
TestAmerica Tampa
2/26/2018

QC Sample Results
Client: Synagro Technologies, Inc. TestAmerica Job ID: 660-85548-1
Project/Site: TCLP Biosolids SCB amd WED
Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued)
Lab Sample ID: 660-85548-1 MS
MS MS
%Recovery Qualifier
Limits
2,4,6-Tribromophenol (Surr)
87
Matrix: Solid
2-Fluorophenol (Surr)
55
25-130
Phenol -d5 (Surr)
Analysis Batch: 193097
25-130
2-Fluorobiphenyl
69
38-130
Sample
Sample
Spike
MS MS
78
Analyte Result
Qualifier
Added
Result Qualifier
Unit
Nitrobenzene 1.2
U
96.2
59.1
ug/L
Pentachlorophenol 6.1
U
192
154
ug/L
Pyridine 3.0
U
192
66.6
ug/L
2,4,6 -Trichlorophenol 2.3
U
96.2
64.6
ug/L
Surrogate
MS MS
%Recovery Qualifier
Limits
2,4,6-Tribromophenol (Surr)
87
31-141
2-Fluorophenol (Surr)
55
25-130
Phenol -d5 (Surr)
49
25-130
2-Fluorobiphenyl
69
38-130
Nitrobenzene -d5 (Surr)
74
39-130
Terphenyl-d14 (Surr)
78
10-143
Lab Sample ID: 660-85548-2 DU
Matrix: Solid
Analysis Batch: 193097
Analyte
Sample
Result
Sample
Qualifier
33-138
DU
Result
DU
Qualifier
Unit
2-Methylphenol
2.1
U
2.1
U
ug/L
1,4 -Dichlorobenzene
2.5
U
2.5
U
ug/L
2,4-Dinitrotoluene
3.4
U
3.4
U
ug/L
Hexachlorobenzene
1.2
U
1.2
U
ug/L
Hexachlorobutadiene
4.1
U
4.1
U
ug/L
Nitrobenzene
1.2
U
1.2
U
ug/L
Pentachlorophenol
6.1
U
6.1
U
ug/L
Pyridine
3.0
U
3.0
U
ug/L
2,4,6 -Trichlorophenol
2.3
U
2.3
U
ug/L
DU
DU
Surrogate
%Recovery
Qualifier
Limits
2,4,6-Tribromophenol (Surr)
90
31-141
2-Fluorophenol (Surr)
70
25-130
Phenol -d5 (Surr)
53
25-130
2-Fluorobiphenyl
64
38-130
Nitrobenzene -d5 (Surr)
60
39-130
Terphenyl-d14 (Surr)
71
10-143
Method: 8270D - Semivolatile Organic Compounds (GC/MS) - DL
Client Sample ID: SCB-CAKE-2-18
Prep Type: TCLP
Prep Batch: 193093
%Rec.
D %Rec Limits
61
27-113
80
33-138
35
10-110
67
38-119
Client Sample ID: WED -CAKE -2-18
Prep Type: TCLP
Prep Batch: 193093
RPD
D RPD Limit
NC 35
NC 35
NC 35
NC 35
NC 35
NC 35
NC 35
NC 35
NC 35
Lab Sample ID: 660-85548-2 DU Client Sample ID: WED -CAKE -2-18
Matrix: Solid Prep Type: TCLP
Analysis Batch: 193097 Prep Batch: 193093
Sample Sample DU DU RPD
Analyte Result Qualifier Result Qualifier Unit D RPD Limit
3 & 4 Methylphenol - DL 2500 2590 ug/L 5 35
TestAmerica Tampa
Page 17 of 30 2/26/2018
0

QC Sample Results
Client: Synagro Technologies, Inc.
Project/Site: TCLP Biosolids SCB amd WED
TestAmerica Job ID: 660-85548-1
Method: 8270D - Semivolatile Organic Compounds (GC/MS) - DL (Continued)
Lab Sample ID: 660-85548-2 DU
Matrix: Solid
Analysis Batch: 193097
Surrogate
2,4,6-Tribromophenol (Surr) -
DL
2-Fluorophenol (Surr) - DL
Phenol -d5 (Surr) - DL
2-Fluorobiphenyl - DL
Nitrobenzene -d5 (Surr) - DL
Terphenyl-d14 (Surr) - DL
DU DU
MB
Result
%Recovery Qualifier
Limits
0 D1
31-141
0 D1
25-130
0 D1
25-130
0 D1
38-130
0 D1
39-130
0 D1
10-143
Client Sample ID: WED -CAKE -2-18
Prep Type: TCLP
Prep Batch: 193093
Method: 8082 - Polychlorinated Biphenyls (PCBs) by Gas Chromatography
Lab Sample ID: MB 660-193056/1-A
Matrix: Solid
Analysis Batch: 193091
Client Sample ID: Method Blank
Prep Type: Total/NA
Prep Batch: 193056
0
Analyte
MB
Result
MB
Qualifier
PQL
MDL
Unit
D Prepared
Analyzed
Dil Fac
PCB -1016
16
U
67
16
ug/Kg
02/21/1811:06
02/22/1810:02
1
PCB -1221
34
U
100
34
ug/Kg
02/21/1811:06
02/22/1810:02
1
PCB -1232
18
U
67
18
ug/Kg
02/21/1811:06
02/22/1810:02
1
PCB -1242
28
U
86
28
ug/Kg
02/21/1811:06
02/22/1810:02
1
PCB -1248
20
U
67
20
ug/Kg
02/21/1811:06
02/22/1810:02
1
PCB -1254
9.6
U
33
9.6
ug/Kg
02/21/1811:06
02/22/1810:02
1
PCB -1260
15
U
45
15
ug/Kg
02/21/1811:06
02/22/1810:02
1
MB MB
Surrogate %Recovery Qualifier Limits
DCB Decachlorobiphenyl 92 30-150
Tetrachloro-m-xylene 97 30-150
Lab Sample ID: LCS 660-193056/2-A
Matrix: Solid
Analysis Batch: 193091
Analyte
PCB -1016
PCB -1260
LCS LCS
Surrogate %Recovery Qualifier
DCB Decachlorobiphenyl 91
Tetrachloro-m-xylene 103
Lab Sample ID: LCSD 660-193056/3-A
Matrix: Solid
Analysis Batch: 193091
Analyte
PCB -1016
PCB -1260
Spike
LCS LCS
Added
Result Qualifier
334
270
334
293
Limits
30-150
30-150
Prepared Analyzed Dil Fac
02/21/1811:06 02/2211810:02 1
02/21/1811:06 02/2211810:02 1
Client Sample ID: Lab Control Sample
Prep Type: Total/NA
Prep Batch: 193056
%Rec.
Unit D %Rec Limits
ug/Kg 81 35-130
ug/Kg 88 45-137
Client Sample ID: Lab Control Sample Dup
Prep Type: Total/NA
Prep Batch: 193056
Spike LCSD LCSD %Rec. RPD
Added Result Qualifier Unit D %Rec Limits RPD Limit
333 281 ug/Kg 84 35-130 4 50
333 305 ug/Kg 91 45-137 4 50
TestAmerica Tampa
Page 18 of 30 2/26/2018

QC Sample Results
Client: Synagro Technologies, Inc.
Project/Site: TCLP Biosolids SCB amd WED
TestAmerica Job ID: 660-85548-1
Method: 8082 - Polychlorinated Biphenyls (PCBs) by Gas Chromatography (Continued)
Lab Sample ID: LCSD 660-193056/3-A
Matrix: Solid
Analysis Batch: 193091
LCSD LCSD
Surrogate %Recovery Qualifier Limits
DCB Decachlorobiphenyl 97 30-150
Tetrachloro-m-xylene 110 30-150
Lab Sample ID: 660-85548-1 MS
Matrix: Solid
Analysis Batch: 193091
Sample
Sample
Spike
MS MS
Analyte Result
Qualifier
Added
Result Qualifier
PCB -1016 240
U
5030
5620
PCB -1260 230
U
5030
4140
Client Sample ID: Lab Control Sample Dup
Prep Type: Total/NA
Prep Batch: 193056
Client Sample ID: SCB-CAKE-2-18
Prep Type: Total/NA •
Prep Batch: 193056
%Rec.
Unit D %Rec Limits
ug/Kg 112 35-130
ug/Kg 82 45-137
MS MS
Surrogate %Recovery Qualifier
DCB Decachlorobiphenyl 54
Tetrachloro-m-xylene 44
Limits
30-150
30-150
Method: 6010B - Metals (ICP)
Lab Sample ID: LCS 660-193074/2-A
Client Sample ID:
Lab Control Sample
Matrix: Solid
Prep Type: Total/NA
Analysis Batch: 193089
Prep Batch: 193074
Spike
LCS LCS
%Rec.
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
Silver
5.00
3.93
mg
79
75 -125
Arsenic
5.00
3.96
mg/L
79
75-125
Barium
5.00
3.79
mg/L
76
75-125
Cadmium
5.00
3.90
mg/L
78
75-125
Chromium
5.00
3.93
mg/L
79
75-125
Lead
5.00
3.85
mg/L
77
75-125
Selenium
5.00
4.03
mg/L
81
75-125
Lab Sample ID: LB 660-193057/1-C
Client Sample ID: Method Blank
Matrix: Solid
Prep Type: TCLP
Analysis Batch: 193089
Prep Batch: 193074
LB
LB
Analyte Result
Qualifier
PQL
MDL
Unit
D Prepared
Analyzed Dil Fac
Silver 0.050
U
0.50
0.050
mg/L
02/21/18 14:00
02/22/18 06:47 1
Arsenic 0.12
U
1.0
0.12
mg/L
02/21/18 14:00
02/22/18 06:47 1
Barium 0.030
U
0.50
0.030
mg/L
02/21/18 14:00
02/22/18 06:47 1
Cadmium 0.018
U
0.50
0.018
mg/L
02/21/18 14:00
02/22/18 06:47 1
Chromium 0.050
U
1.0
0.050
mg/L
02/21/18 14:00
02/22/18 06:47 1
Lead 0.040
U
1.0
0.040
mg/L
02/21/18 14:00
02/22/18 06:47 1
Selenium 0.15
U
0.50
0.15
mg/L
02/21/18 14:00
02/22/18 06:47 1
TestAmerica Tampa
Page 19 of 30 2/26/2018

QC Sample Results
Client: Synagro Technologies, Inc.
Project/Site: TCLP Biosolids SCB amd WED
TestAmerica Job ID: 660-85548-1
Method: 60108 - Metals (ICP) (Continued)
Lab Sample ID: 660-85548-1 MS
Client Sample
ID: SCB-CAKE-2-18
Matrix: Solid
Prep Type: TCLP
Analysis Batch: 193089
Prep Batch: 193074
Sample
Sample
Spike
MS
MS
%Rec.
Analyte Result
Qualifier
Added
Result
Qualifier
Unit
D %Rec
Limits
Silver 0.050
U
5.00
4.74
mg/L
95
75-125
Arsenic 0.12
U
5.00
4.69
mg/L
94
75-125
Barium 0.030
U
5.00
4.55
mg/L
91
75-125
Cadmium 0.018
U
5.00
4.63
mg/L
93
75-125
Chromium 0.050
U
5.00
4.65
mg/L
93
75-125
Lead 0.040
U
5.00
4.52
mg/L
90
75-125
Selenium 0.15
U
5.00
4.73
mg/L
95
75-125
Lab Sample ID: 660-85548-1 MSD
Client Sample
ID: SCB-CAKE-2-18
Matrix: Solid
Prep Type: TCLP
Analysis Batch: 193089
Prep Batch: 193074
Sample
Sample
Spike
MSD
MSD
%Rec. RPD
Analyte Result
Qualifier
Added
Result
Qualifier
Unit
D %Rec
Limits RPD Limit
Silver 0.050
U
5.00
4.99
mg/L
100
75-125 5 20
Arsenic 0.12
U
5.00
5.04
mg/L
101
75-125 7 20
Barium 0.030
U
5.00
4.87
mg/L
97
75-125 7 20
Cadmium 0.018
U
5.00
4.92
mg/L
98
75-125 6 20
Chromium 0.050
U
5.00
4.97
mg/L
99
75-125 7 20
Lead 0.040
U
5.00
4.79
mg/L
96
75-125 6 20
Selenium 0.15
U
5.00
5.08
mg/L
102
75-125 7 20
Method: 7470A - Mercury (CVAA)
Lab Sample ID: LCS 660-193069/14-A Client Sample ID: Lab Control Sample
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 193075 Prep Batch: 193069
Spike LCS LCS %Rec.
Analyte Added Result Qualifier Unit D %Rec Limits
Mercury 0.00140 0.00137 mg/L 98 80-120
Lab Sample ID: LB 660-193057/1-B Client Sample ID: Method Blank
Matrix: Solid Prep Type: TCLP
Analysis Batch: 193075 Prep Batch: 193069
LB LB
Analyte Result Qualifier PQL MDL Unit D Prepared Analyzed Dil Fac
Mercury 0.00050 U 0.00070 0.00050 mg/L 02/21/1813:00 02/21/1816:21 1
Lab Sample ID: 660-85548-1 MS Client Sample ID: SCB-CAKE-2-18
Matrix: Solid Prep Type: TCLP
Analysis Batch: 193075 Prep Batch: 193069
Sample Sample Spike MS MS %Rec.
Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits
Mercury 0.00050 U 0.00140 0.00125 mg/L 90 80-120
TestAmerica Tampa
Page 20 of 30 2/26/2018

QC Sample Results
Client: Synagro Technologies, Inc.
Project/Site: TCLP Biosolids SCB amd WED
Method: 7470A - Mercury (CVAA) (Continued)
TestAmerica Job ID: 660-85548-1
Lab Sample ID: 660-85548-1 MSD Client Sample ID: SCB-CAKE-2-18
Matrix: Solid Prep Type: TCLP
Analysis Batch: 193075 Prep Batch: 193069
Sample Sample Spike MSD MSD %Rec. RPD
Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit
Mercury 0.00050 U 0.00140 0.00110 J3 mg/L 79 60-120 13 20
0
TestAmerica Tampa
Page 21 of 30 2/26/2018

QC Association Summary C
Client: Synagro Technologies, Inc. TestAmerica Job ID: 660-85548-1
Project/Site: TCLP Biosolids SCB amd WED
GC/MS VOA
Analysis Batch: 193118
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
660-85548-1
SCB-CAKE-2-18
TCLP
Solid
8260B
193135
WED -CAKE -2-18
660-85548-2
WED -CAKE -2-18
TCLP
Solid
8260B
193135
1311
LB 660-193135/1-A
Method Blank
TCLP
Solid
8260B
193135
MB 660-193118/6
Method Blank
Total/NA
Solid
8260B
WED -CAKE -2-18
LCS 660-193118/4
Lab Control Sample
Total/NA
Solid
8260B
Method Blank
660-85548-2 MS
WED -CAKE -2-18
TCLP
Solid
8260B
SCB-CAKE-2-18
660-85548-2 MSD
WED -CAKE -2-18
TCLP
Solid
8260B
WED -CAKE -2-18
Leach Batch: 193135
Lab Sample ID
660-85548-1
660-85548-2
LB 660-193135/1-A
GC/MS Semi VOA
Client Sample ID
Prep Type
Matrix
Method Prep Batch
SCB-CAKE-2-18
TCLP
Solid
1311
WED -CAKE -2-18
TCLP
Solid
1311
Method Blank
TCLP
Solid
1311
GC/MS Semi VOA
Leach Batch: 193058
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch C
660-85548-1
SCB-CAKE-2-18
TCLP
Solid
1311
660-85548-2
WED -CAKE -2-18
TCLP
Solid
1311
660-85548-2 - DL
WED -CAKE -2-18
TCLP
Solid
1311
LB 660-193058/1-B
Method Blank
TCLP
Solid
1311
660-85548-1 MS
SCB-CAKE-2-18
TCLP
Solid
1311
660-85548-2 DU
WED -CAKE -2-18
TCLP
Solid
1311
660-85548-2 DU - DL
WED -CAKE -2-18
TCLP
Solid
1311
Prep Batch: 193093
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
660-85548-1
SCB-CAKE-2-18
TCLP
Solid
3510C
193058
660-85548-2
WED -CAKE -2-18
TCLP
Solid
3510C
193058
660-85548-2 - DL
WED -CAKE -2-18
TCLP
Solid
3510C
193058
LB 660-193058/1-B
Method Blank
TCLP
Solid
3510C
193058
MB 660-193093/1-A
Method Blank
Total/NA
Solid
3510C
LCS 660-193093/2-A
Lab Control Sample
Total/NA
Solid
3510C
660-85548-1 MS
SCB-CAKE-2-18
TCLP
Solid
3510C
193058
660-85548-2 DU - DL
WED -CAKE -2-18
TCLP
Solid
3510C
193058
L660-85548-2 DU
WED -CAKE -2-18
TCLP
Solid
3510C
193058
Analysis Batch: 193097
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
660-85548-1
SCB-CAKE-2-18
TCLP
Solid
8270D
193093
660-85548-2
WED -CAKE -2-18
TCLP
Solid
8270D
193093
660-85548-2 - DL
WED -CAKE -2-18
TCLP
Solid
8270D
193093
LB 660-193058/1-B
Method Blank
TCLP
Solid
8270D
193093
MB 660-193093/1-A
Method Blank
Total/NA
Solid
8270D
193093
LCS 660-193093/2-A
Lab Control Sample
Total/NA
Solid
8270D
193093
660-85548-1 MS
SCB-CAKE-2-18
TCLP
Solid
8270D
193093
660-85548-2 DU
WED -CAKE -2-18
TCLP
Solid
8270D
193093
660-85548-2 DU - DL
WED -CAKE -2-18
TCLP
Solid
8270D
193093
TestAmerica Tampa
Page 22 of 30 2/26/2018

QC Association Summary C
Client: Synagro Technologies, Inc. TestAmerica Job ID: 660-85548-1
Project/Site: TCLP Biosolids SCB amd WED
GC Semi VOA
Prep Batch: 193056
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method Prep Batch
660-85548-1
SCB-CAKE-2-18
Total/NA
Solid
3546
660-85548-2
WED -CAKE -2-18
Total/NA
Solid
3546
MB 660-193056/1-A
Method Blank
Total/NA
Solid
3546
LCS 660-193056/2-A
Lab Control Sample
Total/NA
Solid
3546
LCSD 660-193056/3-A
Lab Control Sample Dup
Total/NA
Solid
3546
660-85548-1 MS
SCB-CAKE-2-18
Total/NA
Solid
3546
Analysis Batch: 193091
Lab Sample ID
660-85548-1
660-85548-2
MB 660-193056/1-A
LCS 660-193056/2-A
LCSD 660-193056/3-A
660-85548-1 MS
Metals
Leach Batch: 193057
Lab Sample ID
660-85548-1
660-85548-2
LB 660-193057/1-B
LB 660-193057/1-C
660-85548-1 MS
660-85548-1 MSD
Prep Batch: 193069
Lab Sample ID
660-85548-1
660-85548-2
LB 660-193057/1-B
LCS 660-193069/14-A
660-85548-1 MS
660-85548-1 MSD
Prep Batch: 193074
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
SCB-CAKE-2-18
Total/NA
Solid
8082
•
193056
WED -CAKE -2-18
Total/NA
Solid
8082
193056
Method Blank
Total/NA
Solid
8082
193056
Lab Control Sample
Total/NA
Solid
8082
193056
Lab Control Sample Dup
Total/NA
Solid
8082
193056
SCB-CAKE-2-18
Total/NA
Solid
8082
193056
Client Sample ID
Prep Type
Matrix
Method
SCB-CAKE-2-18
TCLP
Solid
1311
WED -CAKE -2-18
TCLP
Solid
1311
Method Blank
TCLP
Solid
1311
Method Blank
TCLP
Solid
1311
SCB-CAKE-2-18
TCLP
Solid
1311
SCB-CAKE-2-18
TCLP
Solid
1311
Client Sample ID
Prep Type
Matrix
Method
SCB-CAKE-2-18
TCLP
Solid
7470A
WED -CAKE -2-18
TCLP
Solid
7470A
Method Blank
TCLP
Solid
7470A
Lab Control Sample
Total/NA
Solid
7470A
SCB-CAKE-2-18
TCLP
Solid
7470A
SCB-CAKE-2-18
TCLP
Solid
7470A
Prep Batch
Prep Batch
193057
193057
193057
193057
193057
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
660-85548-1
SCB-CAKE-2-18
TCLP
Solid
3010A
193057
660-85548-2
WED -CAKE -2-18
TCLP
Solid
3010A
193057
LB 660-193057/1-C
Method Blank
TCLP
Solid
3010A
193057
LCS 660-193074/2-A
Lab Control Sample
Total/NA
Solid
3010A
660-85548-1 MS
SCB-CAKE-2-18
TCLP
Solid
3010A
193057
660-85548-1 MSD
SCB-CAKE-2-18
TCLP
Solid
3010A
193057
Analysis Batch: 193075
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
660-85548-1
SCB-CAKE-2-18
TCLP
Solid
7470A
193069
660-85548-2
WED -CAKE -2-18
TCLP
Solid
7470A
193069
LB 660-193057/1-B
Method Blank
TCLP
Solid
7470A
193069
TestAmerica Tampa
Page 23 of 30 2/26/2018

QC Association Summary
Client: Synagro Technologies, Inc.
TestAmerica Job ID: 660-85548-1
Project/Site: TCLP Biosolids SCB amd WED
Metals (Continued)
Analysis Batch: 193075 (Continued)
Lab Sample ID Client Sample ID
Prep Type
Matrix
Method
Prep Batch
LCS 660-193069/14-A Lab Control Sample
Total/NA
Solid
7470A
193069
660-85548-1 MS SCB-CAKE-2-18
TCLP
Solid
7470A
193069
660-85548-1 MSD SCB-CAKE-2-18
TCLP
Solid
7470A
193069
Analysis Batch: 193089
Lab Sample ID Client Sample ID
Prep Type
Matrix
Method
Prep Batch
660-85548-1 SCB-CAKE-2-18
TCLP
Solid
6010B
193074
660-85548-2 WED -CAKE -2-18
TCLP
Solid
6010B
193074
LB 660-193057/1-C Method Blank
TCLP
Solid
6010B
193074
LCS 660-193074/2-A Lab Control Sample
Total/NA
Solid
6010B
•
193074
660-85548-1 MS SCB-CAKE-2-18
TCLP
Solid
6010B
193074
L660-85548-1 MSD SCB-CAKE-2-18
TCLP
Solid
6010B
193074
General Chemistry
Analysis Batch: 192847
FLab Sample ID Client Sample ID
Prep Type
Matrix
Method
Prep Batch
660-85548-2 WED -CAKE -2-18
Total/NA
Solid
Moisture
Analysis Batch: 192943
Lab Sample ID Client Sample ID
Prep Type
Matrix
Method
Prep Batch
660-85548-1 SCB-CAKE-2-18
Total/NA
Solid
Moisture
TestAmerica Tampa
Page 24 of 30 2/26/2018

Lab Chronicle
Client: Synagro Technologies, Inc.
Project/Site: TCLP Biosolids SCB amd WED
TestAmerica Job ID: 660-85548-1
Client Sample ID: SCB-CAKE-2-18
Lab Sample ID: 660-85548-1
Date Collected: 02/14/18 07:30
Matrix: Solid
Date Received: 02/14/18 10:10
Batch Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type Method
Run Factor
Amount
Amount
Number
or Analyzed
Analyst
Lab
TCLP Leach 1311
25.01 g
500 mL
193135
02/21/18 20:00
TGP
TAL TAM
TCLP Analysis 8260B
10
5 mL
5 mL
193118
02/22/18 14:26
TGP
TAL TAM
TCLP Leach 1311
100.03 g
2000 mL
193058
02/20/18 20:30
GH1
TAL TAM
TCLP Prep 3510C
260 mL
1 mL
193093
02/22/18 08:01
BKM
TAL TAM
TCLP Analysis 8270D
1
193097
02/22/18 14:10
MWJ
TAL TAM
TCLP Leach 1311
100.03 g
2000 mL
193057
02/20/18 19:30
GH1
TAL TAM
TCLP Prep 3010A
10 mL
50 mL
193074
02/21/18 14:00
GH1
TAL TAM
TCLP Analysis 6010B
1
193089
02/22/18 06:56
GAF
TAL TAM
TCLP Leach 1311
100.03 g
2000 mL
193057
02/20/18 19:30
GH1
TAL TAM
TCLP Prep 7470A
25 mL
35 mL
193069
02/21/18 13:00
GH1
TAL TAM
TCLP Analysis 7470A
1
193075
02/21/18 16:26
GH1
TAL TAM
Total/NA Analysis Moisture
1
192943
02/19/18 08:37
AJG
TAL TAM
Client Sample ID: SCB-CAKE-2-18
Lab Sample
ID: 660-85548-1
Date Collected: 02/14/18 07:30
Matrix: Solid
Date Received: 02/14/18 10:10
Percent
Solids:
19.2
Batch Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type Method
Run Factor
Amount
Amount
Number
or Analyzed
Analyst
Lab
Total/NA Prep 3546
5.18 g
10 mL
193056
02/21/18 11:06
EM
TAL TAM
Total/NA Analysis 8082
1
193091
02/22/18 12:07
MDS
TAL TAM
Client Sample ID: WED -CAKE -2-18
Lab Sample
ID: 660-85548-2
Date Collected: 02/14/18 09:28
Matrix: Solid
Date Received: 02/14/18 10:10
Batch Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type Method
Run Factor
Amount
Amount
Number
or Analyzed
Analyst
Lab
TCLP Leach 1311
25.02 g
500 mL
193135
02/21/18 20:00
TGP
TAL TAM
TCLP Analysis 8260B
10
5 mL
5 mL
193118
02/22/18 15:48
TGP
TAL TAM
TCLP Leach 1311
100.00 g
2000 mL
193058
02/20/18 20:30
GH1
TAL TAM
TCLP Prep 3510C
260 mL
1 mL
193093
02/22/18 08:01
BKM
TAL TAM
TCLP Analysis 8270D
1
193097
02/22/18 14:58
MWJ
TAL TAM
TCLP Leach 1311
DL
100.00 g
2000 mL
193058
02/20/18 20:30
GH1
TAL TAM
TCLP Prep 3510C
DL
260 mL
1 mL
193093
02/22/18 08:01
BKM
TAL TAM
TCLP Analysis 8270D
DL 20
193097
02/22/18 16:53
MWJ
TAL TAM
TCLP Leach 1311
100.00 g
2000 mL
193057
02/20/18 19:30
GH1
TAL TAM
TCLP Prep 3010A
10 mL
50 mL
193074
02/21/18 14:00
GH1
TAL TAM
TCLP Analysis 6010B
1
193089
02/22/18 07:09
GAF
TAL TAM
TCLP Leach 1311
100.00 g
2000 mL
193057
02/20/18 19:30
GH1
TAL TAM
TCLP Prep 7470A
25 mL
35 mL
193069
02/21/18 13:00
GH1
TAL TAM
TCLP Analysis 7470A
1
193075
02/21/18 16:32
GH1
TAL TAM
Total/NA Analysis Moisture
1
192847
02/15/18 11:43
AJG
TAL TAM
TestAmerica Tampa
Page 25 of 30 2/26/2018

Lab Chronicle
Client: Synagro Technologies, Inc.
Project/Site: TCLP Biosolids SCB amd WED
Client Sample ID: WED -CAKE -2-18
Date Collected: 02/14/18 09:28
Date Received: 02/14/18 10:10
C
TestAmerica Job ID: 660-85548-1
Lab Sample ID: 660-85548-2
Matrix: Solid
Percent Solids: 15.9
Batch
Batch Dil Initial Final Batch
Prepared
Prep Type Type
Method Run Factor Amount Amount Number
or Analyzed Analyst Lab
Total/NA Prep
3546 5.13 g 1-0m L 193056
02/21/18 11:06 EM TAL TAM
Total/NA Analysis
8082 1 193091
02/22/18 12:21 MDS TAL TAM
Laboratory References:
TAL TAM = TestAmerica Tampa,
6712 Benjamin Road, Suite 100, Tampa, FL 33634, TEL [phone]
TestAmerica Tampa
Page 26 of 30 2/26/2018

Method Summary
Client: Synagro Technologies, Inc.
TestAmerica Job ID: 660-85548-1
Project/Site: TCLP Biosolids SCB amd WED
Method Method Description
Protocol
Laboratory
8260B Volatile Organic Compounds (GC/MS)
SW846
TAL TAM
8270D Semivolatile Organic Compounds (GC/MS)
SW846
TAL TAM
8082 Polychlorinated Biphenyls (PCBs) by Gas Chromatography
SW846
TAL TAM
6010B Metals (ICP)
SW846
TAL TAM
7470A Mercury (CVAA)
SW846
TAL TAM
Moisture Percent Moisture
EPA
TAL TAM
Protocol References:
EPA = US Environmental Protection Agency
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL TAM = TestAmerica Tampa, 6712 Benjamin Road, Suite 100, Tampa, FL 33634, TEL [phone]
TestAmerica Tampa
Page 27 of 30 2/26/2018

Accreditation/Certification Summary
Client: Synagro Technologies, Inc.
Project/Site: TCLP Biosolids SCB amd WED
Laboratory: TestAmerica Tampa
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
C
TestAmerica Job ID: 660-85548-1
Authority Program EPA Region Identification Number Expiration Date
Florida NELAP 4 E84282 06-30-18
The following analytes are included in this report, but accreditation/certification is not offered by the governing authority:
Analysis Method Prep Method Matrix Analyte
Moisture Solid Percent Moisture
Moisture Solid Percent Solids
TestAmerica Tampa
Page 28 of 30 2/26/2018

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2/26/2018
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Page 29 of 30
2/26/2018

Client: Synagro Technologies, Inc.
Login Number: 85548
List Number: 1
Creator: Southers, Kristin B
Question
Login Sample Receipt Checklist
Answer Comment
Radioactivity wasn't checked or is </= background as measured by a survey N/A
meter.
The cooler's custody seal, if present, is intact. True
Sample custody seals, if present, are intact. True
The cooler or samples do not appear to have been compromised or True
tampered with.
Samples were received on ice. True
Cooler Temperature is acceptable. True
Cooler Temperature is recorded.
True
COC is present.
True
COC is filled out in ink and legible.
True
COC is filled out with all pertinent information.
True
Is the Field Sampler's name present on COC?
True
There are no discrepancies between the containers received and the COC.
True
Samples are received within Holding Time (excluding tests with immediate
True
HTs)
Sample containers have legible labels.
True
Containers are not broken or leaking.
True
Sample collection date/times are provided.
True
Appropriate sample containers are used.
True
Sample bottles are completely filled.
True
Sample Preservation Verified.
True
There is sufficient vol. for all requested analyses, incl. any requested
True
MS/MSDs
Containers requiring zero headspace have no headspace or bubble is
N/A
<6mm (1/4").
Multiphasic samples are not present.
True
Samples do not require splitting or compositing.
True
Residual Chlorine Checked.
N/A
Job Number: 660-85548-1
List Source: TestAmerica Tampa
Received same day of collection; chilling process
has begun.
TestAmerica Tampa
Page 30 of 30 2/26/2018
7
m

"I certify, under penalty of law, that the information that will be used to determine compliance with the
Class A pathogen requirements in §503.32(x) and the vector attraction reduction requirement in
§503.33(b)(8) was prepared under my direction and supervision in accordance with the system designed
to ensure that qualified personnel properly gather and evaluate this information. I am aware that there
are significant penalties for false certification including the possibility of fine and imprisonment."
Project(s): South Cross Bayou WRF Pelletizing Facility
Reporting Period: December 2018
Name: Williames — lant M
Signature: 4�)JA I
Synagro
Date: 1 -Jan -2018
The Class A pathogen requirements were met through §503.32(x)(7). The Process to Further Reduce
Pathogens was Heat Drying (Appendix B, B.2.). The biosolids were dried by direct or indirect contact with
hot gases to reduce the moisture content to 10% or lower. The temperature of the biosolids particles
exceeded 80 degrees Celsius. Fecal coliform testing was performed and the density of fecal coliform in
the biosolids was <1000 MPN per gram of total solids (dry weight basis).
The vector attraction reduction requirement was met through §503.33(b)(8). The percent solids of the
bIOSOIIdS that contains unstabilized solids generated in a primary wastewater treatment process shall be
>90% based on the moisture content and total solids prior to mixing with other materials.
NTYPE 29: CA5 PR PELL PT VAR 90