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HomeMy WebLinkAboutIsoconcentration Maps with CCR DataL } L J44 .I ROXBO ND COOLING WATER INTAKE BASIN O PLANT va-'I� GYPSUM -SRAGE TO AREA 2-101D� ABMW-5D ND ND CCR-100D . �. ND LCID LANDFILL . INDUSTRIAL LANDFILL -. 0 �I � - s • r _ _ _ J DUNNAWAYRD kjw CW-3 e ♦ f `. ,� ND e � `.y ,, ,. • ND 5W-4 ND VW-15D? lii.Il SFMDR9 ND ' r., R, MW-18D,�k • _ ND ^Imp .• °� e g4 ' e. t"I'l It/ i 41 GRAPHIC SCALE 0 362.5 725 1,450 2,175 2,900 synTerra Feet 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE DUKE I m,COM E N E RGY DRAWN BY:, ROBERTS DATE: 02/19/2018 EADY CHOJECT CK D BYNAGC.EERRDY. LEGEND 10TOTAL ANTIMONY CONCENTRATION (fag/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR IMAC CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY STREAM NOTES: THE INTERIM MAXIMUM ALLOWABLE CONCENTRATION (IMAC) FOR ANTIMONY IS 1 Ng/L. PROVISIONAL BACKGROUND THRESHOLD VALUE IS SET AT REPORTING LIMIT OF 1 Ng/L. DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. NS = NOT SAMPLED VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALIFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL. DATA WITH HIGH TURBIDITY (>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD83/2011). FIGURE 11-1 ISOCONCENTRATION MAP ANTIMONY IN TRANSITION ZONE GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA " lift " • I • RO 1 ' ♦ • ND " •, ; , f W-2BR GPMW-3BR MW 2$, D �a'1BR ` .. N `♦• i '+ ND MW-3B�R-,DSBR GPMLEGEND t cc IL ' Np D 10TOTAL ANTIMONY CONCENTRATION (fag/L) ♦ .�+ I _. •• MW-29BR .. • ��' �,. •' 7 -" '-` = - - - -''' - - - - , : GPMW-1BR ,.r _ ND CCR-112BR-BG ND NOT DETECTED ABOVE REPORTING LIMIT ♦ ♦r �� CCR-102BR oY ND MW-22BR CCR-106BR • NS ND NOT SAMPLED ��♦ •� y CCRNDOOBR t ND CCR-103BR r •GMW-10 Np ND MW-30BR e ND ND CW-1 +ty I RO-16 HIGHEST CONCENTRATION AREA CONTOUR ♦ �..� CCR-101 BR I _ ` ND t ND • ND ` CCR-202BR ND GMW-11 CCR'107BR IMAC CONTOUR -` • .� ,�'' ND CCR-104BR ND MW-1BR ND ® RO-1012 INTERMEDIATE CONTOUR ♦ BMW 6BR MW-11BR ABMW-7BR R-203BR ND ND ND ND ND CCR-108BR •-,., += ND%, "'- r.w. ABMW-7BRL CCR-109BR ND . ND APPROX. BACKGROUND CONTOUR y�. MW-5BR ABMW-4BR ND MW-23BRR MW-20BRL CCR-204BR ND ND ti ND RO2014-RAW ND '- CVV2D ND ® ND Np RO-1005 BACKGROUND MONITORING WELL ABMW-6BR MW-9BR ND INDUSTRIAL LANDFILL ND DOWNGRADIENT MONITORING WELL - ,... - ND Lr+ r. ND CCR-110BR ' • _ RO-1017 . I N LCID LANDFILL GMW-7 —. - ND ND MW-24BR RO 4 - - + ND � SIDEGRADIENT MONITORING WELL ABMW-3BRL ABM -3BCCR 200BR R,l ND ND RO-1015 UPGRADIENT MONITORING WELL CCR-111BR - CCR-205BR ND N MW-2BR } + a' p ND ND ND ABMW-1BR ND sl., l - GMW-8 MW-25BR MW-8BR r GMW-9 -.. ° ND `'' Ro-1o11 ..: WATER SUPPLY WELL ND :`� ND CCR-201BR r+ ND ;w a ND M N1pBR d+. ND LAN DFILLAREA MW-12BR ND it + ffs i a+ ND CCR-207BR �♦ FCC-206BR %- ,� yn RO-13 `�.. ND ND y�, F ri RO-7 '' ND ASH BASIN WASTE BOUNDARY • .� •. s ,.''�-�: MW-13BR'.-.,' ND ASH BASIN COMPLIANCE BOUNDARY v MW-33BR CCR-208BR ABMW-2BR A el ND '_ ND e° — - `) e.. • • ND ND ND y MW-16BR - ' - - RO-1016 RO-1013 DUKE ENERGY ROXBORO SITE �• ` - r . - CCR-212BR V ND -DNNAwaYRo MW-19BRL RO.B RO-1010 �� ND ND 7 �. ::. -:_, - ND ND ND ��� �..�... BOUNDARY ♦ • hAW-7BR CCR-209BR N�. _ 4®M10BR '�"-/�.. RO-1018 # �• STREAM ' • ND ND CCRND13BR +#�. FRO-2 •� - ti s RO-15 MW-32BR ND ND ♦„ ND • �' ND NOTES: �� CCft-210BR CCR-214BR . ' / Lr RO-3 •'1 - THE INTERIM MAXIMUM ALLOWABLE CONCENTRATION (IMAC) FOR ANTIMONY IS 1 Ng/L. �•� r� ND CCR-211BR ND CCR-215BR ND F R0-12 1� ND CVV-3D ND RO-11 • ND PROVISIONAL BACKGROUND THRESHOLD VALUE IS SET AT REPORTING LIMIT OF 1 Ng/L. • • f `� , ND CCR B-216BR ND RO-1010A DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. / G-1 BRLR L'♦ 214 ND MW-26BR� +F-•;,�,,, ND NS = NOT SAMPLED • �• �, CCR-217BR ND `�',^."•. • e • " MW-31BR Np • ' VALUE CONSIDERED AN ANOMALY b• RO-10-1 ND r - CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE B BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. ND MW-4BR R020�6-RAW DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION BG-1 BR ND PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. 1.07 R02040-RND srgrFH�rSND • MW 1 R��7 CCR-218BR �� �� RO-1024 RO-10255 DATA FOINCLU R QUALIFIER ABDEFINITIONS. RESULTS. REFER TO ANALYTICAL DATA TABLE 3FM0 ND i' ND � `� . r - ND 9 g CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE R02040-RAW �Rp • - RESULTS FOR EACH WELL DATA WITH HIGH TURBIDITY (>10 NTU) OR RESULTS THAT ND MW-18BR� • • r Y INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO RO-1004 ° _ _ ND I RO-1000 JULY 2017. RO-10-2 d - ND •� `I ND _ ND ♦e - R02031-RAW - • RO-1026 PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. ND I� e • O-1001 AERAL WAS COLLECTED ON JUNE 13, 2016. R 9 +n. -z •= • : - F NORTH CAROLINA STATE PLANE •, _, DRAWING HAS BEEN SET WITH A PROJECTION O COORDINATE SYSTEM FIPS 3200 (NAD83/2011). RO-1003 s RO-1027 ND ND FIGURE 11-2 GRAPHIC SCALE 0 362.5 725 1,450 2,175 2,900 ISOCONCENTRATION MAP _ - synTerra Feet ANTIMONY IN BEDROCK GROUNDWATER GREENVILE,SOUTH CAROLI A29601 ROXBORO STEAM ELECTRIC PLANT DUKE PHONE864-421-9999 wwws nterracor .cor, DUKE ENERGY PROGRESS LLC r ENERGY DRAWN BY 1. ROBERTS DATE:02/20/2018 EADY SEMORA, NORTH CAROLINA a ♦° _ R oonno- CPROJECT HECKED BYNC EADY 0 i ♦ f ■ . Sygr�H`yY s� ♦ -•.� • L• - GPMW-3D ♦ • • � 153Q • GPMW-2D - ND GPMW-1D 981 GPMW-7S MW-22D 1590 m, 458 es 2420 --- - + _ r D ggMW-5D . s- MW-6D ND 2580 ND CCR-101 CW-2 MW-5D - 252 CW-5 NMD 747 CCR-100D CC R-203D N D 3gg LCID L `rr CCR-202D 2890 ,lion o '` 70Q INDUSTRIAL LANDFILL LEGEND 10TOTAL BORON CONCENTRATION (fag/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR NORTH CAROLINA2L CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL ¢' DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY —4- STREAM 4 ■ J NOTES: ' .. THE NORTH CAROLINA 2L FOR BORON IS 700 Ng/L. CW-3: PROVISIONAL BACKGROUND THRESHOLD VALUE IS SET AT REPORTING LIMIT OF 50 Ng/L. NO DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. NS = NOT SAMPLED VALUE CONSIDERED AN ANOMALY • .. CW-4 _ _ ,�... t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE ND - BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. • • •" DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. ` _ ♦ /.:,y. - PdW-15D /■■ • • - DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES SFMOR4 ND + + • • FOR QUALIFIER DEFINITIONS. RD ` MUM1I-18D 1 .♦ - y CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELLDATAWITH HIGH TURBIDITY(>10 NTU) OR RESULTS THAT ♦ ND • • ■�� -„ INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM i_ - • _ + ■ - DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO ■ �:- JULY2017. '��'.♦a. '- t.� PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. ■ ' ar,■ �. AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. ♦ • — AERAL WAS COLLECTED ON JUNE 13, 2016. - DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE ■�� ♦ COORDINATE SYSTEM FIPS 3200 (NAD83/2011). a ■ I ■ ■ wk, GRAPHIC SCALE HIC FIGURE 11-3 0 375 750 2,250 3,000 - ISOCONCENTRATION MAP • �, Feet BORON IN TRANSITION ZONE GROUNDWATER `* synTerra 148RIVERTREET.SUITE220 S _ GREENVILLE, SOUTH CAROLINA 29601 ROXBORO STEAM ELECTRIC PLANT �' DUKE PHONE864-42 -9999 DUKE ENERGY PROGRESS LLC �' ENERGY www.s nterracor .com err.co DRAWNBY:1.ROBERTS DATE:03/15/2015 PROJECT MANAGER: C. EADY � SEMORA, NORTH CAROLINA ,4 ► CHECKED BY: C. EADY . . ' PROGRESS ­n �an�F�nTn,a � ., �n Q.—I--- �l KA—,a a 1IKITI .m i 7R_20�4BR� R 2870 C' MW-9BR� - '- ND I CCR-205BR - MW-8BR _ 3280 pp, I . i I ND GPMW-1BR 1420 CCR-102BR MW-22BR ND 558 GMW-10 92 ~ •CCR-101BR l - - ND R-201BR - ' C -103BR N D 40 CCR-104BR :6B3R MW-11BR 6710 AB D ND MW-5BR Q� CCR-100BR ABMW-7 ND ND 1430 • ABM W-6BR ND ABMV N M1. LCID LANDFILL , I ' . 1 ' I � GPMW-3BR �� •♦/ 294 l00000• - ND MW-3BR _ .- 3000 MW-141 • MW-28BR � ND + CCR-105BR 570 CCR-106BR 1080 ND MW-27 MW-1BR ' -. CCR-112BR-BG ND �oII . MW-30BR ND - CW-1 ND RO-16 ND ® ND GMW-11 CCR-10813R AW-7BRL 3380 13000 93 RO-1012 3R CCR-107BR MW-23BRR ; ND ND USTRIA 3860 .tt t CCR-109BR MW-20BRL FRO-1005 -494 ' ND 4BR ND • �- •MW-24BR �+i FRO-11117 ND RO-1015 CCR-110BR ND RO-4 ND GMW-7 CCR-111 BR MW-3BR � MW-2BR .1340 22500 2930 '.MW-17BR ND RO-7 4650 ND _ ' ND 1 , NO RO-1011 L RO-13 NO BR CCR-200BR G48 08 ♦'�00 ♦. -j ND ND - MW-25BR R02014-RAW - r' MW-12BR } GMW-9 ' CCR-206BR ND CCR-207BR , ND ND 23400 • -: ♦♦ RO-1018 9160 MW-13BR M BR� CCR-208BR ABMW-2BR ♦ - ♦ .I ND.A ND qUI � 52900 ND ♦ 'kMW-16BR 01 UNNAWgygp MW-19BRL ♦, ND RO-8 �o MW-7BR CCR-209BR CCR-2121 D ♦ ND RO-11 Np-1010 ND ND ND 4360 p _ MW-32BR� /�� CCR-213BR � BOND • J ` - - • FRO-15 ND ND y�.,r.'.' L ND CCR-214BR RO-3 RO-1010A Rp_i CCR-210BR ND ND ND 6.1 2540 CCR-211BR w ♦ +� ,� CR-216BR { t • 2150 CW-3D � C ND ♦ ND .'� MW-26BR • BG-1 BRLR CCR-215BR ♦ CCR-217BR 3 ♦ y'� ^ ND ♦� +♦ 374?firSi MW'-3`1BR�,Y { •'.�-�. ' -+ RO- 1025BG-2BR W-4BR CCR.218BR D NO nn D N BG-1BR R02056-RARO-10-1 ND NO NO RO-1004 rt NO -1024 MW-15BRNDRAW R02040 71 F NO SFND ► ��'.� ,•J. ��i�. .4 -�� -'mil R02040-RAW NO RO-10-2 • i ♦ ' MW-18BR� ND • % ND • ♦t ♦ '• R02031-RAW RO-1000 a 1• - �� l RO-1001 w ♦�' ON '. RO-1026 RO-1027 �' ND ND ND •� GRAPHIC SCALE 0 375 750 1,500 2,250 t Feet 148 RIVER STREET- SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 ldF f*w- DUKE ENERGY IRO-1016 NO LEGEND 10TOTAL BORON CONCENTRATION (pg/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR NORTH CAROLINA 2L CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL O WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY —••—••- ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE ��- BOUNDARY STREAM NOTES: THE NORTH CAROLINA 2L FOR BORON IS 700 Ng/L. PROVISIONAL BACKGROUND THRESHOLD VALUE IS SET AT REPORTING LIMIT OF 50 Ng/L. s DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. NS = NOT SAMPLED 3,000 DRAWN BY: J. ROBERTS DATE: 03/15/2018 PROJECT MANAGER: C. EADY CHECKED BY: C. EADY VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALIFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL. DATA WITH HIGH TURBIDITY (>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83/2011). FIGURE 11-4 ISOCONCENTRATION MAP BORON IN BEDROCK GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA w- NEWS ,r- ♦� e ' %/ V X1 • P � Vn• ♦ i + > s m .. .00. •r� I N r ■ I i • t • GPMW-3D '� ■ '; _9 ■ COOLING WATER INTAKE BASIN STGYPSUM GPMW-1 D ORAGE .. ._ . ■ 0.03 ROXBORO PLANT ■ ■ ■ ® MW-22D . LCID LANDFILL L61D - _.. ' GMW-6 ■ ND INDUSTRIAL LANDFILL 0.527 ,. MW-111 GMW-6 2.28 1.75 ■ M11D CW-2 „ MN- W- 2.55 i 112 ND CCR 100D ■ ND GM-6 `tl ■ ABMW-5D W ND I 9t ND ND F203D {:, CCR-202D _ ■ f ii ND sa • • L"u. • MW-15D Se41OR4 RD 1, 3.5 M W-1 E _ 8.35 mom nk 1 ■.:yS-. ■ t; ■ _ 1 lip �+■ .I DUKE ENERGY GRAPHIC SCALE 0 325 650 1,300 1,950 2,600 Feet 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 DRAWN BY: J. ROBERTS DATE: 03/15/2018 PROJECT MANAGER: C. EADY CHECKED BY: C. EADY LEGEND OTOTAL CHROMIUM CONCENTRATION (fag/L) ND TOTAL CHROMIUM NOT DETECTED ABOVE REPORTING LIMIT OCHROMIUM (VI) CONCENTRATION (fag/L) CHROMIUM (VI) NOT DETECTED ABOVE REPORTING LIMIT HIGHEST CONCENTRATION AREA CONTOUR NORTH CAROLINA2L CONTOUR INTERMEDIATE CONTOUR CHROMIUM CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL WATER SUPPLY WELL LANDFILL AREA ASH BASIN BOUNDARY —••—••■ ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY THE NORTH CAROLINA 2L FOR CHROMIUM IS 10 Ng/L. TRANSITION ZONE BACKGROUND THRESHOLD VALUE FOR TOTAL CHROMIUM IS 26 Ng/L AND HEXAVALENT (VI) CHROMIUM IS 7 Ng/L. DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED NS = NOT SAMPLED VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALIFIER DEFINITIONS CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL DATA WITH HIGH TURBIDITY (>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83/2011). FIGURE 11-5 ISOCONCENTRATION MAP CHROMIUM AND CHROMIUM (VI) IN TRANSITION ZONE GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA iJ- ROXBORO PLANT M` MW-9BRNJ 1 ND CCR-2 NC n 7CR-202BR CCR-204BR ND ND CCR-203BR CCR-205BR ND 1.04 APKMA ND ND CCR-101 BR ND Me ■ I ■ GPMW-3BR MND ° ° - MW-14BR �� • RO-1 • ND • • ND MW-28BR GPMW-2BIR �' 2.08 ■■ ND MW-3BR r ND �♦ MW-27BR i i CCR-106BR ND MW-29BR INTAKEbAlINND ND I CR N1D05R CCR-103BR MW-1�:• MW-30BR R04BND ND R 264C ■ i CCR-1N12DBR-BG 1.35 :CR-102BR _ CW-1 ° ■ RO-16 ND � ■ 1.4 ND ABM Wp-7BR ,�. GMW-11 ND CCR-108BR - BM-7BRL CCRNp07BR ND MW BRR ND W ■ - ND CCR-109BR MW -11 B-R ND ND ABMW-413 - 10 ■ - MW-20BRL ND �� CCR-200BR INDUSTRIAL LANDFILL ND MW 24BR MW-17BR 4W-3BR LCID LANDFILL CCR-214BR ND 7 CCR-215BR ND GMW-7 CCR-110BR' ND i ND ND ND 1tfj,.: �• r R2O7-4 R.O-.13 CR-111BR 1.3 ND Ok RGM 4.1.5 GM-9 - ♦ - 47 •� • ND � �.-• ND _ ♦ M NDBR f«Q`• •-• ter. MW-13BR � R.� y9 • � • • ■ ND ♦f g • . DUNNAWAY RD • - "� g 16BR MW,19BRL D i : - MW-10BR ND■ ■ , IRO-11 .._ . ND 1 1.7 -RO-15 RO-2 RO- .,.._. 1.3 ND RO-3 ND ..R0-12. _ .. ND ND ,. ■ MW♦ m 0.57 57 • •.%ON ■ MW-18BR • i ND 00 ■ /fj/jam■•� ■ j. _ 4!. DUKE ENERGY r . GRAPHIC SCALE 0 325 650 1,300 1,950 2,600 Feet 148 RIVER STREET, SUITE 220 GREENVILLE SOUTH CAROLINA 29601 PHON E 864-421-9999 DRAWN BY: J. ROBERTS DATE: 03/15/2018 PROJECT MANAGER: C. EADY CHECKED BY: C. EADY LEGEND 10T0TAL CHROMIUM CONCENTRATION (fag/L) ND TOTAL CHROMIUM NOT DETECTED ABOVE REPORTING LIMIT OCHROMIUM (VI) CONCENTRATION (fag/L) CHROMIUM (VI) NOT DETECTED ABOVE REPORTING LIMIT HIGHEST CONCENTRATION AREA CONTOUR NORTH CAR0LINA2L CONTOUR INTERMEDIATE CONTOUR CHROMIUM CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL ® SIDEGRADIENT MONITORING WELL • UPGRADIENT MONITORING WELL O WATER SUPPLY WELL LANDFILL AREA ASH BASIN BOUNDARY —••—••■ ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY THE NORTH CAROLINA 2L FOR CHROMIUM IS 10 Ng/L. BACKGROUND THRESHOLD VALUE FOR TOTAL CHROMIUM IS 4 Ng/L AND HEXAVALENT (VI) CHROMIUM IS 2 Ng/L. DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. CCR WELLSARE NOT SAMPLED FOR HEXAVALENT CHROMIUM NS = NOT SAMPLED VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL. DATA WITH HIGH TURBIDITY (>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD83/2011). FIGURE 11-6 ISOCONCENTRATION MAP CHROMIUM AND CHROMIUM (VI) IN BEDROCK GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA 1. 'GPMW-1S G 99.69 . CCR-101D ~ MW-6D 321 ABM ° MW-SD ND CW-2 ND ND " - CWD-5 CCR-100D ND CCF' 03D '- LCID LANDFILL 14.7 CCR-202D . a ND i r_. L: SST AS~ EAB EXTENSION IMPOUNDMENT r r f ♦♦ ," N D Cj 'b• 3G-1 ND CW4 MW-15D . - - i� D SFgyO�� ND R, • _ ND s a �• • g • It/ ♦ �/, • Ik ^�.._ 41 4" • GRAPHIC SCALE 0 362.5 725 1,450 2,175 2,900 symTen-a Feet 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 ,,Lft�www.s DUKE ENERGY nterracor .com DRAWN BY J. ROBERTS EADY DATE 02/26/2018 C HOC ED BYNC EADY LEGEND 10TOTAL COBALT CONCENTRATION (fag/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR IMAC CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY _10- STREAM NOTES: THE INTERIM MAXIMUM ALLOWABLE CONCENTRATION (IMAC) FOR COBALT IS 1 Ng/L. PROVISIONAL BACKGROUND THRESHOLD VALUE IS SET AT REPORTING LIMIT OF 1 Ng/L DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED NS = NOT SAMPLED VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB QUALIFIED RESULTS REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALIFIER DEFINITIONS CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL DATAWITH HIGH TURBIDITY(>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83/2011). FIGURE 11-7 ISOCONCENTRATION MAP COBALT IN TRANSITION ZONE GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA �■, t' ♦- a\ ♦1 • s .. IN OF ■ • �•. CCR-202BR ♦ • ND ■ �♦ CCR-201BR CCR-203BR 16.7 ■ ■ COOLINGWATE. INTAKE BASIN ■ 'd KBORO PLANT `�y GYPSUM r' `STORAGEAREA Ilmolplunin. 6�rsr tJ i i 5.4 CW-2D MW-5BR CCR-204BR ND 2.45 1.02 MW-9BR ND 'ABMW-3BRL ABMW CCR-205BR ND 128 MW-8BR ND ABMW-1BR ND ND MW-126R I. ABMW-7BR I ND II ND ABMW 7BRL I-11BR ND CCR-109B ND e. ND i i I 1 V-3BR • 1.86 MW-14BR MW-288R 2.25 ' ND J CCR-105BR ■♦ ND MW-29BR ND BR CCR-106BR ■ ■ CCR-112BR-BG ND MW-30BR ND CW 1 1.56 ND CCR-107BRr�_M 3 ND CCR-108B R Ro-1012 ND � ND �� MW-23BRR ABMW-6BR ABMW-4BR ND MW-20BRL I NDO-1005 ND . � 1.68 _ .,... ND ■ CCR-110BR ■ Ro-Jon LCID LANDFILL 30.6 ND GMW-7 '(� RO-4 M2.92R ND CRND11BR M ND BR I • ND �F'M CCR-200BR G ND 8� GMW-9 MT'2513 MW�-17BR ND ND nln •. ^�� Ro-7 1.38 CCR-207BR �yy ♦ ♦� 33.9 , � ■ • �_ CCR-206BR v< '�` MW-33BR - CCRR ABMW-2BR f.,,, .• ND t ND `) 34.5 - MW-16BR ♦^ 'C ♦ - 1 �h :. EE 212B R ND ♦ ♦ ♦ - MW-7BR CCR 209BR ND - - •`. 1 ND 15.6 CCR-213BR ♦ M7-32BR n'27 ND MW-106R V _ • '�rC_C CCR-214BR 19.9 1 CCND CCR-215BR �•� �, f` R ND - • 1.15 CCR-216BR • •� CW-3D ND MW-26BR •, BBRLR ND CCR-217BR ND G-1 ♦�� ` < �� ND ND .. •` - - j °'n. ,.. ,0B%2BR �'•MND BR MW-4BRR02040-RAWBG-1 BRNDo.e2ND CCR-218BR y RO-10-1 ND a• ND h'Yy.� MW-158R R02040-RRD ND . 0.66 Ro-10-2 Ro-looa MW-18BR N ND ♦ _ ND ♦• - FRO-1003 *: ♦ ND i` • s� ■ ■ 011 ♦ RO-1016 � R020 ND ' RO10 Qo ND- RO-1010 h RO-1018 N D RO-15 ND ' RO-12 _ ■ ND �- • RO-1010A ND ND ND RO-1025 ND ♦ 14-RAW q , 13 •�, 2.74 ♦♦ MW-19BRL - ■ �� � RO-1024 ♦ ND - RO-1000 AW ND ND RO-1026 • -- RO-1001 ND ■ ND J C RO-1027 ♦ ND ■ DUKE ' ENERGY t PROGRESS GRAPHIC SCALE 0 362.5 725 1,450 2,175 2,900 Feet 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHON E 864-421-9999 DRAWN BY: J. ROBERTS DATE: 03/15/2018 PROJECT MANAGER: C. EADY CHECKED BY: C. EADY LEGEND 10TOTAL COBALT CONCENTRATION (pg/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR IMAC CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY —•• ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY STREAM NOTES: THE INTERIM MAXIMUM ALLOWABLE CONCENTRATION (IMAC) FOR COBALT IS 1 Ng/L PROVISIONAL BACKGROUND THRESHOLD VALUE IS 6.4 Ng/L. DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED NS = NOT SAMPLED VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALIFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL. DATAWITH HIGH TURBIDITY(>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83/2011). FIGURE 11-8 ISOCONCENTRATION MAP COBALT IN BEDROCK GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA Hyco • • •`1`i GPMW-2D,-��. µ 74100 GPMW e4 825 GPMW-ID _ GPMW-IS ,v 16 65 ., �i� I MW 22D ' 42 ABM 3020000 GMW-6 CCR-101 D 32 MW-6D NS 13 MW-5D 95 CCR-100D INDUSTRIAL LANDFILL C 3-2 C N-D Ns CCR-203D CCR-202D LCID LANDFI NS NS r __•Nm..4 f. aytia.Sl • a ,� L • !\ ■POO ly ■ `� • 1313-1 y 11 CW 4 202 Srgre MW-15D L 16 tr" a MW-18D • 163 ■ 41 LEGEND 1 ]TOTAL IRON CONCENTRATION (pg/L) ND NOT DETECTED ABOVE REPORTING LIMIT HIGHEST CONCENTRATION AREA CONTOUR NORTH CAROLINA2L CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY —■■—■■, ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY —4- STREAM ■ " •��- • .J-<` NOTES: ±�„'� • THE NORTH CAROLINA 2L FOR IRON IS 300 pg/L. 1 PROVISIONAL BACKGROUND THRESHOLD VALUE IS 1,173 Ng/L. I- - DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. NS = NOT SAMPLED ■ �� ' VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. - DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION _ .., PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES �■ �� _ FOR QUALFIER DEFINITIONS. `- • CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE •�■ • RESULTS FOR EACH WELLDATA WITH HIGH TURBIDITY(>10 NTU) OR RESULTS THAT ■ ■ ♦ INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. •� PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE ZCOORDINATE SYSTEM FIPS 3200 (NAD83/2011). I GRAPHIC SCALE FIGURE 11-9 0 362.5 725 1,450 2,175 2,900 ISOCONCENTRATION MAP Feet IRON IN TRANSITION ZONE GROUNDWATER 148RIVER STREET, SUITE 220 synTerra GREENVILLE, SOUTH CAROLINA 29601 PHONE864-421-9999 www. nterracor .com ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC at,DUKE ENERGY SEMORA, NORTH CAROLINA DRAWN BY: J ROBERTS DATE:03/15/2018 PROJECT MANAGER: C. EADY CHECKED BY: C. EADY I ; CCR-102BR CCR-101 BR NS CCR-100BR NS CCR-202BR NS CCR-201 BR MW-6BR CCR-203BR NS 419 NS MW-SBR CW-2D t CCR-204BR 72S ND NS MW-9BR 274 -_ CCR-205BR NS ABMW-3BRL MW-8BR 822 ABMW-3BR 5540 2360 MW-12BR ABMW-1B r°♦ 3300 168 CCRNS7BR ` `■ CCR-206BR ■ • ■-�� MW-33BR CCR 208BR NS ABMW-2 750 ..+ ` 32 CCR-212E MW-76R CCR-209BR NS NS CCR-2131 136 MW-32BR NS A ■1 180 CCR-214BR ` CCR-210BR NS NS CCR-211 BR NS ,� ' C W-3 • ■ • BG-1 BRLR 269 46 ■ MW-31 BR 108 ■■�■�_ BG-2BR ■ ■ �� RO-10-1 116 MW-4BR 290 SrgrF gG-1 BR 117 p 113 R02040-RAW 55.4 R02040'RAW - sFMDR MW-1SBR CCR-218B NS 269 -- - RO-10-2 806 ` / ND RO-100565 V ■ ■ -� rr7: •.� ND +• MW-3BR I Ri �r GPMW-3BR 4S MW-14BR 1230 f , � ■ ■ � . ND MW-28BR GPMW-2BR 79 GPMW-1BR CCR-105BR 194 z NS MW-29BR ._ MW-27BR 43 CCR-103BR MW-22BR 104 . CCR-106BR CCR-112BR-!G6 'i NS 1400 NS MW-30BR I NS GM $-10 CW-1 1260 ■ 162 ■ RO-16 CCR-107BR ND CCR-104BR GMW-11 NS 62 NS ABM68-7BR ABMW-7BRL MW-1B CCR-108BR ' R0-1 112 243 172 NS MW-23BRR I 232 MW-11 BR 388 INDUSTRIAL LANDFILL 24 CCR-109BR MW-20BRL FRO-1005 ABMW-6BR NS 169 ND 129 = BMW-4BR s a' ` I RO-101 CCR-110BR 7 9400 r JJ MW-24BR - ND LCID LANDFILL NS . , ND ,■ PROa =•RO-1011 MW 2BR ■ 24500 GMW-7 CCR-111 BR MW-17BR 97 9 RO-1015 12 GMW-8 NS 332 L + 576 F. CCR-200BR . 85 GMW-9 RO-7 RO-13 NS - 23 MW-25BR 53.8 ND ■ ■ _ • I 1340 .: • . � �. - R02014-RAW RO-1013 1400 ■ e MW-13BR 3R w 493 MW-16BR NNAWAY RD � 46 DUMW-19BRL � 4520 RO-11 RO-1010 RO-1016 R ND MW-10BR RO-2 ND '� Np ■ ND RO-15 RO-1D018 ND ;CR-215BR RO-8 •RO-03 ND RO-12 NS ND 1100 CR-216BR RO-1010A NS 80 MW-26BR CCR-217BR 1280 NS RO-1025 61.4 RO-1024 ND LEGEND OTOTAL IRON CONCENTRATION (fag/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR NORTH CAROLINA2L CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL ® SIDEGRADIENT MONITORING WELL • UPGRADIENT MONITORING WELL O WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY —••—••■ ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY STREAM NOTES: THE NORTH CAROLINA 2L FOR IRON IS 300 Ng/L. PROVISIONAL BACKGROUND THRESHOLD VALUE IS 4,227 Ng/L DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED NS = NOT SAMPLED VALUE CONSIDERED AN ANOMALY 1 CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL. DATAWITH HIGH TURBIDITY(>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. MW-1813R PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. 1200 AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. RO-1000 AERAL WAS COLLECTED ON JUNE 13, 2016. ND R02031-RAW DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE • 54 COORDINATE SYSTEM FIPS 3200 (NAD83/2011). I- ° ♦ %�RO-1001 RO-1026 �FRO__10_03_e RO-1027 DN 17 - synTerra 'DUKE ENERGY PROGRESS GRAPHIC SCALE 0 320 640 1,280 1,920 2,560 Feet 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHON E 864-421-9999 DRAWN BY: J. ROBERTS DATE: 03/15/2018 PROJECT MANAGER: C. EADY CHECKED BY: C. EADY FIGURE 11-10 ISOCONCENTRATION MAP IRON IN BEDROCK GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA .1/ GPMW-3D GPMW-2D 1730 -. 5670 55 I i . GPMW-IS' 3960 ABMW-51) 2160 • 5990 .F-MW6D.- FCC- 00 DD GN ND rNS ND MW-5D - INDUSTRIAL LANDFILL CW 2 22 CW 5 DOD ND ND CCR-203D CCR-202D -� NS LCID LANDFILL ■ NS r f ♦ � ,� 7 r ♦ ND ` NDWAS EXTENSION hAW-95D 1� D 3FM0�9 ND ■ r MW-18D • _ 196 i. '♦rr, i g . ► v +F • �/, , GRAPHIC SCALE 0 362.5 725 1,450 2,175 2,900 synTerra Feet 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE DUKE r m,COM E N E RGY DRAWN BY: 1. ROBERTS DATE: 02/19/2018 ANAGY EADY CHOJECT CKED C.EERRDY. LEGEND OTOTAL MANGANESE CONCENTRATION (fag/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR NORTH CAROLINA 2L CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE ��•�••� BOUNDARY STREAM NOTES: THE NORTH CAROLINA 2L FOR MANGANESE IS 50 Ng/L. PROVISIONAL BACKGROUND THRESHOLD VALUE IS 405 Ng/L DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED NS = NOT SAMPLED VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALIFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL. DATA WITH HIGH TURBIDITY (>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD83/2011). FIGURE 11-11 ISOCONCENTRATION MAP MANGANESE IN TRANSITION ZONE GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA J 611 1 ♦ I ,— a.' ♦ \ ♦ • -i'. r GPMW-2BR eo2s _ -3BR _ 1 ♦ 19 MW-14BR - MW--102BR M 2030 R1636R 291 END 7 LEG r`.- f CCR-1osBR 10TOTAL MANGANESE CONCENTRATION (pg/L) Ns All �,. ♦�Nk, GPMW-1BR w Ns M--29BR ND NOT DETECTED ABOVE REPORTING LIMIT 176 ^MW-27BR,k,CCR-106BR 'G �'� ",, '-J`� ♦ Pr.h+ CCRNS1BR CCR-103BR 241 n. NS CCR-112BR-BG NS NOT SAMPLED Ns -GMW-10 "Af MW-3oBR CCR-100BR 1110 RO-1s HIGHEST CONCENTRATION AREA CONTOUR ♦ `�..� ND 100 .. 1 ose NORTH CAROLINA 2L CONTOUR a GMW-11 MW-1BR CCR-107BR CCR 201BR 'c M 84BR ABMW-7BR ND sso Ns INTERMEDIATE CONTOUR -,• 531 CCR-104BR :e'.CCR-108BR ,.MW-23BRR Ro-1o12 NS NS '"MW-5BR- MW-11BR Ns NS 68 . s.6 --APPROX. BACKGROUND CONTOUR CCR-203BR CW-2D 376 a 52 ABMW-7BRLLAHDFILL .' ( .. - MW-20BRL ND O ,� 6 I RO-loos BACKGROUND MONITORING WELL NS I ' 71 CCR-109BR 345 0.78 MW098BR t �,+?,, 1 ABMW-6BR BMW-4BR NS `., Ro-1on DOWNGRADIENT MONITORING WELL 930 2420 CCR-110BR MW-24BR, �J -- 10 CCR-204BR FILL Ns ND • Ro-1011 •.. SIDEGRADIENT MONITORING WELL CCR-205BRNS ABMW-3BRL ABMW-3BR M 590R GMW-7 '` 144 1s 13900 ND CCR-111BR ! MW-17BR I 1aa UPGRADIENT MONITORING WELL NS ABMW$1BR CCR-200BR. { GMW-8 �s 285 RO-1o1s MW-8BR NS 75 r �` Ro-7 RO-13 s.z ,�. WATER SUPPLY WELL 795 MW-12BR sss '{. I,' _ _ G ND 9 �s886R /� " • s.4 3.7 -� ". .. LANDFILL AREA • 1050 CCR-207BR ` R02014-RAW RO-1013 ASH BASIN WASTE BOUNDARY ,• � � ' " .� CCR-206BR Ns ♦ ss.7 se v e NS f MW-13BR ASH BASIN COMPLIANCE BOUNDARY w _ CCR-208BR.: ABMW-2BR OW-33BR �,� -2 1W- i MW_1gBR 189 Ro-1o10 e RO 131� ^'■ - DUKE ENERGY ROXBORO SITE IN ���` sr:.- •- CCR-212BR 69 MW-19BRL '92 �� BOUNDARY i I CCR 209BR Ns MW-10BR - 1040 Ro-1o1e , I ♦� M 128 NS CCR-213BR �• 352 1.s ' ' 4.1 STREAM `+� • 128 Ro2,• ♦ MW-326R Ns V ` ND r Ro-is �.. 95 CCR-214BR 0.62 NOTES: CCR-210BR NS RO-3 1.6 RO-12 THE NORTH CAROLINA 2L FOR MANGANESE IS 50 Ng/L. NS CCR-211 BR CCR-215BR ND qgq �. NS NS PROVISIONAL BACKGROUIND THRESHOLD VALUE IS 1198 Ng/L. f `• CCR-216BR RO-100.8: DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. W-3D NS e ' BG-1 BRLR � 24 CCR17BR -2l~;,. - 564 NS = NOT SAMPLED 252 MW-31BR NS 0-1022 _ ' VALUE CONSIDERED AN ANOMALY `• -. r R BG-2BR 534 �',�. , . RO-10-1 167 `"• MW-4BR .. _. _ 1 CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS R02056-RAW t DUE GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION J + 1100 -. s..+ BG-16R 35 10.2 „ - - !•- -- PATTERNS, NS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. R02040-R 9W ., Srgr�H 390 R CCR-218BR ♦� DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE I&1 /yps MW�15BR NS .. RO-1024 NOTES FOR QUALIFIER DEFINITIONS. ND JMi f R02040-RAW.. SFa,Q " CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE 1900 R9Rp ~I , ! RESULTS FOR EACH WELL. DATA WITH HIGH TURBIDITY (>10 NTU) OR RESULTS THAT RO-10-2' " MW-186R I . .1 INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM ND . Js RO-1004 _ • 937 ��� 'v DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO .1 121 a - - JULY 2017. L ;7. RO-10-2 I� - RO-1000 5, - ,,- ND I 4 RO-10-2 I ee . i"� R02031-RAW PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. 369 - 12.9 - ,. - RO ' AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. I e ��-1 RO-1001 RO-112 6 AERIAL WAS COLLECTED ON JUNE 13, 2016. e ♦ 12.4 DRAWING HAS BEEN SET ITH A PROJECTIONF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM F PS3 00 (NAD83/201 1 66.6 . - 3.8 I e e e GRAPHIC SCALE 0 362.5 725 1,450 2,175 2,900 FIGURE 11-12 Feet ISOCONCENTRATION MAP e - WnTerra MANGANESE IN BEDROCK GROUNDWATER GREENVILE,SOUTH CAROLINA 29601 ROXBORO STEAM ELECTRIC PLANT DUKE -421-9999 DUKE ENERGY PROGRESS LLC '/'1' www- nterracor -com e ENERGY .11-N MANAGER-C. DY DATE:02/21/2018 SEMORA, NORTH CAROLINA '�" ,� CHECKED BY: C. EADY LAKE =1 �T"`�.. � �=r �''4 GPMW-2D ♦ ;: I GPMW-1D ND , _ . 4•.e,_ :4 GPMW-IS 2.44 HEATED WATER ♦ �GMW 6 � 1 CCR-101D ND _ MW-6D::. IL 3.5 ND t - CW-5 MW-SD BMW -SD ND IAW INDUSTRIAL LANDFILL CW-2 - 618 • . } I ND CCR-100D 2.^36 - CCR-203D ND CCR-202D ND LCID LANDFILL I`'y IN jw CVN NI BG-1 ND L r W, - ` ,. "� �� �. a ': . IFuo._� 1 VIP 41 I♦ v Cs y .y I 1 GRAPHIC SCALE 0 362.5 725 1,450 2,175 2,900 synTerra Feet 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 DUKE "err cor"DRAWN 4 E N E RGY BY: 1, ROBERTS DATE: 02/22/2018 ANAGY EADY CHOJECT CKED C.EERRDY. LEGEND 10TOTAL MOLYBDENUM CONCENTRATION (fag/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR NORTH CAROLINA 2L CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY —••n ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY STREAM NOTES: NO NORTH CAR 0LINA 2L OR INTERIM MAXIMUM ALLOWABLE CONCENTRATION ESTABLISHED FOR MOLYBDENUM. PROVISIONAL BACKGROUND THRESHOLD VALUE IS 4.17 Ng/L. DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. NS = NOT SAMPLED ' VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALIFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL. DATA WITH HIGH TURBIDITY (>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERIAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD83/2011). FIGURE 11-13 ISOCONCENTRATION MAP MOLYBDENUM IN TRANSITION ZONE GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC y .N + l ♦ ■ ` ♦_ ♦ ♦ 8.86 ,�♦ + ♦S - -- - - , - _ CCR-102BR �� 1_ '��♦�� 2.99 1 ND .� �. 'CCR-101BR ;� CCR-103BRS GIAW 7.31 ND ♦+ = ♦ ♦ CCR-100BR 3' 1 ♦ ■ -�MUM4.36 ` ♦ •• � MW-6BR ABMW-7BR ■ I , CCR-201BR 3.36 , ■ _ CCR-202BR 1.22 1.66 1.75 CW-2D MW-56R MW-11BR CCR-203BR ND 1.23 1.43 6.3 ABMW-6BR MW-9BR 2.11 A 1.68 CCR-204BR LCID LANDFILL GMW-7; 1.37 ABMW-3BR MW-2BR ND ' CCR-205BR ABMW-3BRL ND ND ND 2.06 MW-8BR CCR-.78 ABMW-1 BR -,:v 1.78 2.57 2.48 ` w FM-12BR _♦' - 1.49 CCR-207BR ■ _ ■' �� CCR-206BRZ 2.47 v `. ■ 1.16 eCCR-208BR ABMW-2BR 11.4 • ♦ + +� MW-7BR CCR50 ♦ y 65.. ♦`■ • 1.51 ♦ MW-32BR ' ! _ 4.66 CCR-210BR 25.6 ■ + ` BG-1BRLR ■ + RO-10-1 71.1 ♦�� ` . ND `■ - ` BG-2BR ■ ' � ' ' 4.36 R02040-RA 3 614" �Si R02040-RAW RO-1004 ND RO-10-2 ND 16, 140 10.7 CCR-212BR'''.- 1 ND CCR-213BR4Al, �1.25 ! - CCR-214BR 1.87 [:O I I MW-3BR Y. 0-1 '00000 ND ■ MW-3BR MW-286R MW.42BR `• GPM+IV-2BR ND 9.82 ND ■ CCR-105BR 2.05 MW-29BR 1.82 _ MW-27BR 1.78 CCR-106BR ■ CCR-112I3R-BG -10 1.81 I 8.91 g CW-1 MW-30BR ND 6.11 ■ RO-16 MNpBR CCR-107BR � ND GMW-11 ND MW-23BRR CCR-104BR 117 CCR-1086R 3.pg ■ Ro-1012 1.2 193 - ND ABMW-7BRL.2g LANDFILL i W1.28 Ro-loos 79 CCR-109BR I ND BMW-4BR ND R02014-RAVV Ro-10_17 ND 4.29 CCR-110BR nMW-24BR 1790 S 4.93 '� Ro-a Ro-1o11 CCR-111BR ND ND 2.77 MW-17BR I_. Ro-1o1s GMW-8 7 RO-13 ND GMW-9 RO-7 ■Q'y ND 3.22 _ ND MW-25BR- 1.49 ■101�4 .�.. ♦♦ RO-6 ► MW-13BR :' i 1.51 �, Roe e Ro-1o1e i< - //�� 074 0.75 16UNNAWA,Rp" - - y MW-19BRL "Ro-1o10' �" MW-10BR 7.37 RO-11 ND 91 41 14.1 _ RO-1 4.42 CCR-216BR ...I CW-313 1.41 MW-26BR - t 3.84 CCR-217BR - 8.49* 3.35 Ro-1 MW-31BR ND '.'�., - 1.26 �- R02056-RAW ` 3-1BR MW-4BR ND 4.79 p, 7.71 MW-15BR CCR-218BR �. �� RO-1024 ND SFM0R9 6.05 ♦ 3.14 •�■ `.. /.. a0 ' • ■ • _ _ 4.32 - •� +' - RO-1000 ND R02031-RAW ♦' • ND RO-1026 RO-1001 ND ♦ -�♦♦�!♦ l ND C RO-1027 41 RO-1003 ♦ ' I I ■ synTerra _ DUKE ' Nk,�' ENERGY i°a*.monnocco GRAPHIC SCALE 0 362.5 725 1,450 2,175 Feet 148 RIVER STREET- SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 2,900 DRAWN BY: J. ROBERTS DATE: 03/15/2018 PROJECT MANAGER: C. EADY CHECKED BY: C. EADY LEGEND 10T0TAL MOLYBDENUM CONCENTRATION (pg/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR NORTH CAR0LINA2L CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL "< DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY -•• ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY _40STREAM NOTES NO NORTH CAROLINA 2L OR INTERIM MAXIMUM ALLOWABLE CONCENTRATION ESTABLISHED FOR MOLYBDENUM. PROVISIONAL BACKGROU IN THRESHOLD VALUE IS 35.2 Ng/L. DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. NS = NOT SAMPLED VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELLDATAWITH HIGH TURBIDITY(>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83/2011). FIGURE 11-14 ISOCONCENTRATION MAP MOLYBDENUM IN BEDROCK GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA L } L J 1 I .I � V e +�, +IN ♦ . 1 Y♦ � 1 1 � � 16. 1. =1 1 1 GPMW-2D 6.7 `a GPMW-: 6.1 ? 6 .7 7I11'; GPMW-1S ° MW-22D 6.3 5.4 HEATED WA 40 GMW-6 e CCR-101D 6.6 M .6.9 ABMW-5D — 65 7.5 — MW-sD 1 INDUSTRIAL LANDFILL 6.9 ofCCR-100D - CW-2 �° 7.1 Y CW 5 CCR-203D �� s'$ LCID LANDFILL ■ CC 5-302D,, V-1 6.6 IFuo._� 1 MW-18D ♦1 � v r • I� a � � I 1 144 i 1 161p synTerra ?DUKE ENERGY 41 GRAPHIC SCALE 0 362.5 725 1,450 2,175 Feet 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 wwwsv "erracom.com 2,900 DRAWN BY: J. ROBERTS DATE: 02/19/2018 PROJECT MANAGER: C. EADY CHECKED BY: C. EADY LEGEND OTOTAL pH CONCENTRATION (fag/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR NORTH CAROLINA 2L CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY STREAM NOTES: THE NORTH CAROLINA 2L RANGE FOR pH IS 6.5 TO 8.5 S.U. PROVISIONAL BACKGROUND THRESHOLD VALUE IS 6.3-7.6 S.U. DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. NS = NOT SAMPLED VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALIFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL. DATA WITH HIGH TURBIDITY (>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD83/2011). FIGURE 11-15 ISOCONCENTRATION MAP pH IN TRANSITION ZONE GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA 1 LEGEND 10TOTAL pH CONCENTRATION (pg/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR NORTH CAROLINA 2L CONTOUR INTERMEDIATE CONTOUR GGR6.4 ABMW-3BRL BMW 3BR 66 *--•-6.7 •- - MW-17BR'� _j I I: u (e UPGRADIENT MONITORING WELL 6.4 7.2 55 CCR200BRI- � +. GMW-8 7.3 Ro-1o1s Mw-aBR ss GMw-s WATER SUPPLY WELL 7.3 ,.,� ABMW-1BR , ;. 69 �g-xc 1�� 6.2 MW-25BR RO-7 v'� 5s - 7 ri.", 7,1 " s.1e rr LANDFILL AREA MW-12BR Y,( I ♦ 7.2 ccR-zmeR •-,""'� ° F RO-1016 Ro_1o13 ASH BASIN WASTE BOUNDARY 6.3 ; 5.8 CCR6206BR CCR-208BR ABMW-2BMW-136Ro-11 - R •`* `� ASH BASIN COMPLIANCE BOUNDARY � R a `,r• ♦ . M -� 6.1 7• ;M 7 + INA - 7.2 6.2 MW-19BRL s.a 10 Ro-1o61.4e i , DUKE ENERGY ROXBORO SITE CCR-212BR BOUNDARY ♦♦ • �, MW-7BR MW 3.;CCR-209BR w 5.9 - 74 �� STREAM .-. - • 7.3 6.5 CCR-213BR MW-10BR RO-2 _ . s.s 2BR l 6.6 / 7 6.63 r r; RO-15 7 r 7.6 - -_ - NOTES: CCR-214BR _ ' - RO-3 R012 CCR--210BR 7.1 CCR-215BR 6.3 6 -8 •-' • 6 82 THE NORTH CAROLINA 2L RANGE FOR pH IS 6.5 TO 8.5 S.U. 6.5 r ` CCR-211BR 6.9 RO 1010A PROVISIONAL BACKGROUND THRESHOLD VALUE IS 6.8-8.3 S.U. 6.3 CCR6266BR ry�gly 266R 65 DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. C .5 7.5 7.3 NS = NOT SAMPLED _�, ? _ . • ` BG-1BRLR CCR-217BR Ro-1o2s ♦ ` 8.2 6.8 'VALUE CONSIDERED AN ANOMALY MW-31BR .. , ;... 1' Al , ` � BG 2BR 7 � ?CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE .' �° �` _ - BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. • � . � ♦y RO 10-1 � ` �� �• � R02056-RAW 7.1 7.5 BG-16R MW-4BR i. 62 DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION ! _ s 9 7,g • •� - '• - - --, PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. R02040-RAW SrgrP ,a. r DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE 6.2 Hlyps MW7.3 BR CCR-218BR - _ .. �� RO-1026 _ NOTES FOR QUALIFIER DEFINITIONS. RO-10-2 • CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE • q,, 6.65 RO-1004 �� ' W 18 • ., - RESULTS FOR EACH WELL. DATA WITH HIGH TURBIDITYA(>10 NTU) OR RESULTS THAT r 6 2 M BR. •� t INDICATE GROUT CONTAMINATION OF THE WELL PH>9 HAVE BEEN REMOVED FROM �. rpy ' , i • - r -• _ ��,.. _ 7.9 - .-.t - COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO e °,. •� I RO-FRO'._. - - JJULY 2017. a R02031-RAW 5.1 6 . PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. RO-1001-'�'"�`° - AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. L i RO-1026 °-' , � . . � ♦ f/r' �- 6.3 57 AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE C r RO-1027 COORDINATE SYSTEM FIPS 3200 (NAD83/2011). 7.3 ' r R0-1003 .` � I _ GRAPHIC SCALE 0 362.5 725 1,450 2,175 2,900 FIGURE 11-16 _ Feet ISOCONCENTRATION MAP ' synTerra 148RIVER STREET, SUITE 220 pH IN BEDROCK GROUNDWATER GREENVILLE- SOUTH CAROLINA 29601 ROXBORO STEAM ELECTRIC PLANT ¢9 a j' DUKE PHONE864-421-acor DUKE ENERGY PROGRESS, LLC a.. • www.nterr.com com ENERGY PROJECT ROJECTM J MANAGER- DATE 02/21/2018 SEMORA, NORTH CAROLINA PROJECT MANAGER: C. EADY ^ ^ ^ ^ ^ .... CHECKED BY: C" EADY • IN ♦ 1 • LAKE =1 GPMW-2D ND - r GPMW-1D I 'I 3.88 - - - i GPMW-1S - - 4„k,- ND MW-22D I "016' HEATED WATER ® 92.9 _ GMW-8 72.9 1 MNDD� CCN1D01D ®ABMW-5D ND �k MW-5D INDUSTRIAL LANDFILL I •- CCR-100D # CW-2 ND CW-5 ND ND ND CCR-203D LCID LANDFILL ■ - f - �J ND CCR-2021DD I`y N I , a OUNNAWAYRD r f ♦+ ,�INS IND MW-15D� - .-.. 1� D 3F4fp�9 ND + MW-18DQ� • _ ND r • ,s � � I 1 g 1 F f 4 I 16. v 1 .µ^ 1 � GRAPHIC SCALE 0 362.5 725 1,450 2,175 2,900 synTerra Feet 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 DUKE r E N E RGY DRAWN BY: 1. ROBERTS DATE: 02/19/2018 ANAGY EADY CHOJECT CKED C.EERRDY. LEGEND 10TOTAL SELENIUM CONCENTRATION (fag/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR NORTH CAROLINA 2L CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY STREAM NOTES: THE NORTH CAROLINA 2L FOR SELENIUM IS 20 Ng/L. PROVISIONAL BACKGROUND THRESHOLD VALUE IS 1.78 (Ng/L) DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED INS = NOT SAMPLED VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALIFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL. DATA WITH HIGH TURBIDITY (>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD83/2011). FIGURE 11-17 ISOCONCENTRATION MAP SELENIUM IN TRANSITION ZONE GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA YW J• • `- ,,� , ' ♦, 1 . GPMW-3BR • N - .rr000 --�- RO-1 - - MW-3BR �;�a" �■ a r 3.3 MW-14BR MW-22BR 00 MW-28BR ND ND GPMW-2BR ND ♦♦ 1.25 _ CCR-1056R � • GPMW-16R 10.5 �MW-29BR :RN02BRD1.22 MW-27BR ND R-101BR CCR-103BR ND CCR-106BR ■ CCR-112BR-BG ND ' 1.48 _ GMW-10 ND I ND MW-30BR :-100BR ND r�. CW-1 ND ■ Ro-1s ND MW-1BIR 1.77 ND .9W-6BR CCR-104BR 307 CCR-107BR ' wrt-�ui❑rt O - ABMW-7BR 34.3 ND CCR-202BR ND 4q ND ND GMW-11 - MW-23BRR ■ Ro-1o12 ' BMW-7BRL 108 CCR-108BR ■ ND ND CW-2D MW-5BR ■ fMW-11BR- ND 12.2 ND . CCR-203BR ND ND g ND LLANDFILL - MW-20BRL I RO-i005 , ND _v�', . ABMW-4BR CCR-109BR ND ND - ABMW-6BR Np ND FT- NDBR ND 2 CCR-110BR . MW-24BR Ro2o1a-RAW RO-1 R LCID LANDFILL ND '22.1 GMW-7 MW-17BR ND Ro-a RO-1011 CCR-205BR ABM-3BRL ,ABMW-3BR MW-2BR 8.36 CR-111BR ND ND NO I ND ND ND ND 111 MW-25BR I Ro-1o1s MW-8BR CCR-200BR GMW-8 ND � r RO-13 ND r ND ABMW-1BR ND ND GND_g Ro-D ems`' ND •_-- . • .' -_. s.. , , - .. ... ,.. MW-12BR ND as '`'- i ♦� . ♦ ` ,, . • ND CCR-207BR • 22 S RO-1013 - ` - - .;L CCR-206BR - ND FRO-1 Np ND _ ■ - 7 ND id• �♦ - CCR-208BR ABMW-2BR MW-13BR - ... MW-33BR •. ND ND ND MW-16BR / Ro-1o10 Ro-1o1s ' •% % ♦.. ♦ , ` ND ND DONNAWAYRD MW-19BRL �� ' 1 • - �� M-7BR CCR-209BR CCRND2BR W W M-10BR ND I KO-11 NO NO M ND + ND - ND NO MW-32BR CCR-213BR - RO 2 ND ND �� . � � RO 15 J CCR-214BR CCR-210BR - �* ♦ �•`♦ ' ND CCR215BR ND . �i` '� �• CCR-211B ND _ r I BG-16RLR ND CCR-216BR ♦ ` 3.99 CW-3D 1.16 - ♦ ND - � ♦ ` BG-2BR � ND ND ND ■.-- ?� TMTRM BG-1BR� A^ M NND DBR l j, SrgrP • r R02040-RAW H�rsi MW-15BR CCR-218BR 1.3 ND ND RO-10-2MDR9Rp • • - ^ NO IRO-1004 / � ■_ - •ter FRO-10031 ND ND r ND ■ ■ '•s ND RO-3 RO-8 ND ND RO-12 NO RO-1010A BR 726ND S ■ _000- - ND ♦ ■ 718BR 1, LEGEND 10T0TAL SELENIUM CONCENTRATION (pg/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR NORTH CAR0LINA2L CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL "< DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY —4- STREAM NOTES: THE NORTH CAROLINA 2L FOR SELENIUM IS 20 Ng/L. PROVISIONAL BACKGROUND THRESHOLD VALUE IS 1 Ng/L DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED NS = NOT SAMPLED ' VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL. DATAWITH HIGH TURBIDITY(>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. ND RO-1000 - m {•. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. ffi ND RO-1001 _ AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERIAL WAS COLLECTED ON JUNE 13, 2016. - ♦ RO-1026 �"- RO-1027 � -' ND '. .s: � DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE - NO -" COORDINATE SYSTEM FIPS 3200 (NAD83/2011). ■ I ■ _ ■ GRAPHIC SCALE FIGURE 11-18 ■ - 0 362.5 725 1,450 2,175 2,900 ISOCONCENTRATION MAP I.. synTerra Feet SELENIUM IN BEDROCK GROUNDWATER 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 ROXBORO STEAM ELECTRIC PLANT DUKE PHON E 864-421-9999 www.synterracorp.com DUKE ENERGY PROGRESS LLC r DRAWN BY J.ROBERTS DATE:03/15/2018 PROJECT MANAGER: C. EADY ` 4m� ENERGY SEMORA, NORTH CAROLINA CHECKED BY: C. EADY f � 1 �GPMW-2D GPMW-lD �.GPMW-3D -_� 1470 - a� 1680 1: a VC Es. i LED" HEATED WATER iiiiiiiiiiiiiiiiiiiiiiii�DISCHARGE -, 189 NS ABMW-51) MW-5D 419 INDUSTRIAL LAP CW2 379 �CCR-100D - 367 NS CW-5 306 CCR 203D LCID LANDFILL NS CCR-202D �.- NS ti11� � v 1 IN �♦ -� J CW-3 '. r f `. ♦ ,� 205 1 � 448 `s I - rs� MW-1: �Mi,t, sFya� 239 ¢ W s • �' N, ♦ �4 OUNNAWAYR MW-18D ♦ _ 665 AL a L , ♦,N/, `► �:r -.v A k» oy l ll%-1 ILA �' DUKE 3 ENERGY 41 GRAPHIC SCALE 0 362.5 725 1,450 2,175 2,900 Feet 148 RIVER STREET- SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 www.svnterracorD.com DRAWN BY: J. ROBERTS DATE: 02/19/2018 PROJECT MANAGER: C. EADY CHECKED BY: C. EADY LEGEND OTOTAL STRONTIUM CONCENTRATION (pg/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR NORTH CAROLINA 2L CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY —••n ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY STREAM NOTES: NO NORTH CAR0LINA2L OR INTERIM MAXIMUM ALLOWABLE CONCENTRATION ESTABLISHED FOR STRONTIUM. PROVISIONAL BACKGROUND THRESHOLD VALUE IS 760 Ng/L. DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. NS = NOT SAMPLED VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALIFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL. DATA WITH HIGH TURBIDITY (>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD83/2011). FIGURE 11-19 ISOCONCENTRATION MAP STRONTIUM IN TRANSITION ZONE GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA mb l WIN/ ` ♦_ J ♦\i�■� ♦ '�/ RO-1' ♦ 390 MW-22BR ■ ` ♦ 574 GPMW-2BR �• • ♦. ti � h 1300 ♦ 1 i .0"%it■ CCR-102BR GPMW-0.00 1BR - INS ` V r ,'CCR-103BR-' GMW-10 � s ♦ ♦ 1 NS INS 127 416\ ffi ♦ �� '. - CCR-100BR - (33 ♦ CCR-104BR ♦■ CCR 201 BR MW-56BR, ,ABMW-7BR INS GM1 ♦ CCR-202BR NS 236 M INS F CW 2D MW-SBR MW-11BR' ABMW-7BRL CCR-203BR ° 327 319 .I 189 734 L l ABMW-6BR _ MW-9BR ' 208 190 165 CCR-204BR LCIOLANDFILL •GMW-7 - NS 589 CCR-205BR BMW-3BRL ABMW-3BR MW-2BR' INS818 1860 607 ' CCR-200BR GMW-8 MW-8BR ABMW-1BR INS 1060 222 f i 178 MW-12BR 11 I I GPMW-3BR • 0000 / MW-3131R • • _ • 1390 MW-14BR MW-28BR 164 278 CCR-105BR NS MW-29BR FMW-27BR 147 253 CCR-106BR NS � ` ` CCR-112BR-BG ' MW-30BR - INS I 367 288 ■ RO-16 1 BR 121 �. 08 CCR-107BR V-11 INS G. I 2 CCR-108BR MW-23BRR RO-1012 10s INS170 MW-20BRL CR-109BR 184 --- Ro-ioos NS _ 163 - ' R02014-RAW pro ��nQo 274 - an-11117 INS R-11113 Myy_17 INS 892 w 223 86 _♦• ■ ■ 1CCR-206BR CCRNS7BR INS `• ♦ MW-33BR _ CCR-208BR 590 INSABMW-2BR MW-16BR MW-13BR 568 _ 424 ��♦ • � fl � : . - ', ♦ � 172 DUNNAWAYk0 ^7 CCR-212BR '�-_Y; - MW-19BRL ♦ • CCR-209BR ,... Ro-1 ♦♦ y - MW-7BR -2 INS - - ' MW-10BR 228 23s •`■ • 132 CCR-213BR • • MW-32BR jil INS'(. ! ■ 1y ■ � 602 CCR-214BR R p2 � Ro-e �•� ♦ •� CCR-210BR INS CCR-215BR Ro_3 255 lift INS INS 80 &n/ CW-3D CCR-216BR 1 BG-16RLR � • � 271 � INS- MW-26BR • • ♦♦ 819 ITC-217BR 261 - • MW-31BR ♦�� ` ♦ BG-2BR 316 NS •` ■ ■ ` • 268 MW-4BR i ■ ■ �_ _ - Ro-10-1 BG-16R` - 272 t_ R020`. 179 ` .& Ro2oao-R6 grFy s' MW-159R CCR-218BIR 't �• �� • 136 INS 277 144 RO-1004 + _ _.MW-18BR • •�`� ■ ♦ y 176 jiii- 1.:r 1 R02031-RAW 167 11 �rt RO-1001 - ■ •�♦♦ 26 119 R010.7 1 , • RO-1118 FRO- 0003 . 118 • 101 i`l ■ll^v - x I ■ 'y r ND 2so RO- 268 i MW-256R Q 1860 -1010A RO-1010 180 135 ■ RO-1025 139 RAW 40 68.4 0-1024 93.3 DUKE ENERGY 41 LEGEND 10T0TAL STRONTIUM CONCENTRATION QIg/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR NORTH CAR0LINA2L CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR IIIIIIII BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL ® SIDEGRADIENT MONITORING WELL ® UPGRADIENT MONITORING WELL WATER SUPPLY WELL " LANDFILL AREA SASH BASIN WASTE BOUNDARY —••—••■ ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE ���■ BOUNDARY STREAM NOTES NO NORTH CAROLINA 2L OR INTERIM MAXIMUM ALLOWABLE CONCENTRATION ESTABLISHED FOR STRONTIUM. PROVISIONAL BACKGROUND THRESHOLD VALUE IS 232 Ng/L. DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. INS = NOT SAMPLED ' VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALIFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL. DATAWITH HIGH TURBIDITY(>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE fy COORDINATE SYSTEM FIPS 3200 (NAD83/2011). GRAPHIC SCALE 0 362.5 725 1,450 2,175 2,900 Feet 148 RIVER STREET- SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 DRAWN BY: J. ROBERTS DATE: 03/15/2018 PROJECT MANAGER: C. EADY CHECKED BY: C. EADY FIGURE 11-20 ISOCONCENTRATION MAP STRONTIUM IN BEDROCK GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA . 1 a - l i GPMW-2D 430 ♦ � ♦ ♦ T GPMW-3D GPMW-IS ♦ - 1200 �J. 1100 r•' - LEGEND OTOTAL SULFATE CONCENTRATION (mg/L) I {j ="~ • ., GPMW-1D •- _ 1100 ' - I- ND NOT DETECTED ABOVE REPORTING LIMIT {t � • NS NOT SAMPLED GMW-6 MW-22D sso � HIGHEST CONCENTRATION AREA CONTOUR • ccR-101D ,�g� - NORTH CAROLINA 2L CONTOUR 5.3 Mw-sD aemw-sD INTERMEDIATE CONTOUR 37 MW-5D aoo 2.4 '-APPROX. BACKGROUND CONTOUR CCR-100D INDUSTRIAL LANDFILL cw-z 25 ® EXTENSION � BACKGROUND MONITORING WELL 80 ,CW5 �_ ` - DOWNGRADIENT MONITORING WELL 250 CCR-203D LCID LANDFILL i 270 Zyp t SIDEGRADIENT MONITORING WELL CCR-202D +, - , rI. I UPGRADIENT MONITORING WELL WATER SUPPLY WELL WESTASH '00 - �� ` LANDFILL AREA ASH BASIN WASTE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE �••�••- BOUNDARY _10- STREAM .•► . - - J . - - - NOTES: ^ L F. r • THE NORTH CAROLINA 2L FOR SULFATE IS 250 mg/L. cw-3 - - - - - - PROVISIONAL BACKGROUND THRESHOLD VALUE IS 37 mg/L. 35 I DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. Y& - NS =NOT SAMPLED J *VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE CW-4 BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. 37 DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. MW-15D . DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES +ry 28 - FOR QUALFIER DEFINITIONS. • CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE MW-18D '�'y RESULTS FOR EACH WELL. DATAWITH HIGH TURBIDITY(>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM - _ 32 - . - DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. I �/►^ `♦ PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. ♦J �� I _ AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. �♦ ri, �� - AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH PROJECTION OF NORTH CAROLINA STATE PLANE FI rI, ` COORDINATE SYSTEM PS 3200 (NAD83/2011). 0 362.5 725 GRA1,4500 SCA 2,175 2,900 FIGURE 11-21 Feet ISOCONCENTRATION MAP I symTeaa 148 RIVER STREET, SUITE 220 SULFATE IN TRANSITION ZONE GROUNDWATER ,i GREENVILLE, SOUTH CAROLINA 29601 ROXBORO STEAM ELECTRIC PLANT DUKE —"s r 64-421-9999 DUKE ENERGY PROGRESS LLC www.s nterracor .com � . ENERGY DRAWN BY:1.ROBERTS DATE:02/26/2018 SEMORA, NORTH CAROLINA PROJECT MANAGER: C. EADY „✓ CHECKED BY: C. EADY I 900 CC2470 MW-9BR CCR-204BR 21 210 r% .40 RO-1 i�' 440 - GPMW-2BR 51 MW-3BR 1000 - 1400 MW-14BR MW-22BR ■ ■ ■ r • MW-28BR 13 ' 410 42 CCR-105BR �i • _ - 400 MW-29BR .:. ,. CCR-102BR GPMW-1BR 19 360 1000 MW-27BR ?'8 . -106BR210 CCR CCR-1101 BRCCR-103BRGMW-10 440 Iqm W30BR HEA—CR-130 64C -. .. MW-1 '■■ CCR-201 BR 380 75 CCR-107BR MW-6BR CCR-104BR 3700 14M1 1 1W10-0 130 WW,"44\ ABM --- AB MW-6R ABMW-48B17 LCID 7 58 LANDFILL CCR--820056R h� ABMW-3BRL ABMW-3BR M 47 e1K GMW0-7 ti 500 2700 MW-8BR CCR-2003R GMW-8 25 'yr, ABMW-1 BR 45 580 zo � MW-12BR n - - 28 CCR-207BR CC R 06BR1. 410 4G0 I ccrc-�uslsrc MW-23BRR ■ 1300 23 ■ LANDFILL _ MW-20BRL CCR-109BR 10 I 330 CCR-110BR. . • R02014-R 1300 CCR-111BR ' 510 MW-24BR • 68 ■ RO-4 7 - MW-17BR L _ - '25 180 MW-33BR CCR-208BR ABMW-2BR MW32 71 1000 110 MW-16BR -1 J" ` CCR-212BR 25 DUNNAWAYRD MW-7BR� CCR-209BRfje 39 MW-106R 23 Y 26 CCR-213BR 40 rh MW-326�ftCCR-21 49 - 41(CCR-214BRCCR-2106RR 62 CCR-215BR 10 54 ■ w BG-1BRLR N3 JEER -216BR ah MWA BRL 1.4 RO-11 RO-1010 31.1 8.2 FRO-2 _/ N�� . r RO-15 *47,1 RO-3 RO-8 j71 29.2ROCW-47 .- / . 390 O 32 MW-26BR IV '� MW-31BR 49 RO-1025 30 3.7 MW-46R 34 _ R02056-RAW 1. ♦ * 4 MW-15BR CCR-218BR ■ o RO-1024 43 31.3 YI SFM"14 27 - ♦ `s Rp � - . MW-18BR �� .. 5.8 R02031 ■ _ • RO-1000 ■ 3.9 -RAW ` rFRO-71003, ♦ •_ 25 •` L DUKE ENERGY 8.4 1 dr GRAPHIC SCALE 0 375 750 1,500 2,250 3,000 Feet 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 www.s "e"... D.com DRAWN BY: J. ROBERTS DATE: 03/15/2018 PROJECT MANAGER: C. EADY CHECKED BY: C. EADY ice", I I-s LEGEND 10T0TAL SULFATE CONCENTRATION (mg/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR NORTH CAR0LINA2L CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY —■■—■■ ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY —4- STREAM NOTES: THE NORTH CAROLINA 2L FOR SULFATE IS 250 mg/L. PROVISIONAL BACKGROUND THRESHOLD VALUE IS 73.5 mg/L. DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. NS = NOT SAMPLED VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL. DATAWITH HIGH TURBIDITY(>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERIAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83/2011). FIGURE 11-22 ISOCONCENTRATION MAP SULFATE IN BEDROCK GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA J z s'f b WIN � � •• a .�JGPMW-3DCOOLING WATER - GPMW-2D 1900 -- __ I, 1800 " I ' -! GPMW-1S _r MW-22D _ CCR-101D 1700 1500 1 390 - CW-5 - 6 MW-6D GMW- 490 - MW- 250 MW-51D ABMW-5D 1200 CW-2 ` 700 -.., CCR-100D 280 INDUSTRIAL LANDFILL 440 460 CCR-203D LCID LANDFILL- ` — 760 a - - POO' ly . - •♦ Cyy_340 , • �� �- ``♦ a& �' SrArFHlyys ♦ ` t %._ j!-.ti .._. G a PONDS R TOR MW-18D • _1 750 ■ , • 'ter - • 41 1' ■ a GRAPHIC SCALE 0 362.5 725 1,450 2,175 2,900 Feet synTerra 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864421 DUKE VENERGY www.s nterracor o.com .com ROBERTS DRAWN BY J. EADY DATE 03/15/2018 CHOC ED BYNC EADY LEGEND 1 ]TOTAL DISSOLVED SOLIDS CONCENTRATION (mg/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR NORTH CAROLINA2L CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY —■■—■• ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY —4- STREAM NOTES: THE NORTH CAROLINA 2L FOR TOTAL DISSOLVED SOLIDS IS 500 mg/L. PROVISIONAL BACKGROUND THRESHOLD VALUE IS 540 mg/L. DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. NS = NOT SAMPLED ' VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL. DATAWITH HIGH TURBIDITY(>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83/2011). FIGURE 11-23 ISOCONCENTRATION MAP TOTAL DISSOLVED SOLIDS IN TRANSITION ZONE GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC ■ J n - . `.. -.GPMW-3BR •• ' ♦� i r 780 O • . `.'�. GPMW-2BR L �MW-3BR2000 • a. 2200 MW-14BR + g MW-22BR� ■ ' - 360 f' - 1 � .. MW-28BR • ♦p. • ` CCR-105BR /± • /� ' s ii. GPMW-1BR 580 MW-29BR LEGEND • ' �►• ♦ • -� ♦ CCR-102BR 300 ♦ l ■ '• • " • ;' 850 1700 MW-27BR ■ _ 10TOTAL DISSOLVED SOLIDS CONCENTRATION (mg/L) ■♦ `V ✓ f � �-' � , �" I l 550 CCR-106BR CCR-112BR-BG .• (s CCR-101BR CCR-103BR GMW-10 . 770 1 430 1200 180 I 170 ND NOT DETECTED ABOVE REPORTING LIMIT CW-1 MW-30BR CCR-100BR ®420 480 RO-16 NS NOT SAMPLED f ■ - 460 MW80 R CCR-107BR ND HIGHEST CONCENTRATION AREA CONTOUR -• CCR-201BR MW'6BR CCR-104BR 470 CCR-202BR 5500 250 ABMW-7BR ,C GMW-11 ■ NORTH CAROLINA2L CONTOUR _ 1900 RO-1012 i 440 900 CCR-108BR 2400 CW-2D MW-5BR MW-11BR ABMW-7BRL 1900 MW-23BRR I 116 INTERMEDIATE CONTOUR CCR-2036R 440 560 340 570 L CCR-109BR 280 • FRO-1005 APPROX. BACKGROUND CONTOUR 790 qg ZWp4BR 870 MW250 RL , 129 R0-1017 � BACKGROUND MONITORING WELL MW-9BR ABMW-6BR MUM CCR-204BR 220 340 CCR-110BR _ 224 2000 LCID LANDFILL 1800 MW-24BR R0201a RAW / — DOWNGRADIENT MONITORING WELL F 300 �!'' 241 + _FRO-1011 cnnwa Ro 4 G 15z SIDEGRADIENT MONITORING WELL CCR-205BR -A CCR-111BR 2200 ABMW-3BRL BMW-3BR 820 1100 267 RO-1015 920 4200 MW-17BR- L _ Ro-13 160 UPGRADIENT MONITORING WELL MW-8BR MW-2BR GMW-8 410 138 ABMW-1BR CCR-200BR 570 1600 ® GMW-9 • 370 ® 390 160 MW-25BR Roa o, • � ■ • WATER SUPPLY WELL c MW-12BR 340 - 590 .♦� • . �° �� _ • • LANDFILL AREA 420 -` RO-101 CCR-207BR 3 CCR-2o6BR / 160 ASH BASIN WASTE BOUNDARY 4500 ■ ■�•� • e° •�. 3400 ' MW-136R. RO-1016 •• ASH BASIN COMPLIANCE BOUNDARY _ CCR-208BR ABMW-2BR 420 5 117 DUKE ENERGY ROXBORO SITE • MW-33BR ♦, �� ■ 430 7300 480 MW-16BR RO-1018"�"' BOUNDARY 290 DUNNAWAYRD MW-19BRL CCR-212BR 209 ' •� MW-7BR CCR-209BR 150 MW-10BR 460 RO-11 RO1010 -411-- STREAM • 250 B40 330 326 206 CCR-213BR RO-2 ■i ✓• MW-32BR 640 383 ■ ■ RO-15 NOTES: t` ■ ♦ 620 ^•® 456 THE NORTH CAROLINA 2L FOR TOTAL DISSOLVED SOLIDS IS 500 mg/L. CCR-214BR RO-3 CC 481pOBR CC 4001 BR 440 CCRso 6BR 410 R366 RO-12 _ PROVISIONAL BACKGROUND THRESHOLD VALUE IS 530 mg/L. ��♦ • - 463 DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. •• BG-1 BRLR CW-3D RO 101332 ■ NS=NOT SAMPLED 340 �', ♦ 1100 310 MW-26BR ♦ 'VALUE CONSIDERED AN ANOMALY ■ • CCR-217BR 500 ` -- 1 CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE ��•, i� � ♦ ■ BG-2BR MW31 BR 260 - RO-1025 BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. • ` 390 191 DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION `■ ■ ♦ �' 320 • ��1�07. PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. RO-1 4 R0DATAMAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES ♦ BG-1BR • MW-4BR644310 • 27p - FOR QUALIFIER DEFINITIONS qr `• • ' CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE R02040-RAW Fy CCR-218BR ■ �� • R0-1024 RESULTS FOR EACH WELL DATAWITH HIGH TURBIDITY(>10 NTU) OR RESULTS THAT 891 �1'S) MW-15BR ♦ INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM 3 s 350 200 171 DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO F ` - JULY 2017. 369 q RID • = RO-1004 ' - MW-18BR • PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS 284 RO-1000 " AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. ■ R02031-RAW - 150 AERIAL WAS COLLECTED ON JUNE 13, 2016. *. S' • 165.*.. - DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE ■" ;t RO-1026 COORDINATE SYSTEM FIPS 3200 (NAD83/2011). e RO 1001 152 " '". - ■ ♦ ♦ 179 "� MO-1027 205 RO-1003 199 / f' ■ �- -, GRAPHICSCALE FIGURE 11-24 ■ 0 320 640 1,280 1,920 2,560 ISOCONCENTRATION MAP Feet TOTAL DISSOLVED SOLIDS IN BEDROCK synTerra 148 RIVER STREET, SUITE 220 GROUNDWATER GREENVILLE, SOUTH CAROLINA 29601 'I DUKE =r,',64-421-9999 ROXBORO STEAM ELECTRIC PLANT YVRA nY-- J.RO ROBERTS DATE:03/15/2018 DRAWNBY--N DUKE ENERGY PROGRESS LLC ENERGY GER-C_S PROJECT MANAGER: C. EADY SEMORA NORTH CAROLINA � - PROGRESS CHECKED BY: C. EADY P:\Duke Enerav Pro ress.1026\00 GIS BASE DATA\Roxboro\Ma Docs\CSA Supplement 2\ISOCON MAPS\TDS BED ccr.mxd V � IN ,�• Jr1 a1. HYCO O -01 0444 - H�' s� �-�.,•� --ram . ..� 31 ' ♦ �1 CCR-101 D NS ABMW-O5D 1I ND "IRI CCR-100D NS CW-OS 0.00029 LCID LANDFILL D. GPMW-03D D2D - - � 0.000132 � ii�iHL�i 1S MW-22D � 0.000962 - f - 1 I 1 0.00235 INDUSTRIAL LANDFILL , - DUNNAWAYRD v n DUKE ENERGY LEGEND 10T0TAL URANIUM CONCENTRATION (pg/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR NORTH CAROLINA 2L CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL WATER SUPPLY WELL LANDFILL AREA —ASH BASIN WASTE BOUNDARY —••—••- ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY STREAM NOTES: THE NORTH CAROLINA 2L FOR TOTAL URANIUM IS 0.03 Ng/L. PROVISIONAL BACKGROUND THRESHOLD VALUE IS 0.005 Ng/L DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED NS = NOT SAMPLED ' VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALIFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELLDATAWITH HIGH TURBIDITY(>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. ' DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD83/2011). GRAPHIC SCALE 0 362.5 725 1,450 2,175 2,900 Feet 148 RIVER STREET- SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 DRAWN BY. J. ROBERTS DATE: 02/26/2018 PROJECT MANAGER: C. EADY CHECKED BY. C. EADY FIGURE 11-25 ISOCONCENTRATION MAP TOTAL URANIUM IN TRANSITION ZONE ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA CCR-20 NS CCR-203BF NS '4.f l MW-9BR ♦ i 14BR 0.000218 � f N20513 8BR )40� CCR-206BR n NS NS .. FT NS NS N. r 7 . • GPMW-2BR GPMW-313R .+ •� - / 0.00465 RO-1 0.000998 ' Ns MW-3BR ND MW-22BR � - - 0.00236 0.00279 �' CCR-105BR f NS MW-29BR GPMW-1BR '. 0.00185 �- 0.00342 MW-27BR' ' CCR-106BR CCR-103BR .}� 0.00285 NS I CCR-112BR-BG NS CW-1 jkfMW-30BR NS 0.000155 0.00357 Ro-1s MW-11311 CCR-107BR Ns • CCR-104BR 0.00541 NS NS N - I---- '-I ♦ 0'ABAW-7BGMW-11 C` C.'R -108BR •% �W 10.00112 NS ♦- .MW-23BRR 0-2MW-5BR -ABW 0.0025814-WD .003ND 0.000317 CCR9BR- , MW-20BRL � ` MW-6BR ABMW-4BR NS I 0.00035 4 • 0.000648 0.000491 CCR-110BR - \�? LCID LANDFILL - NS } t- - MW-24BR . �J ' v 1 MW-2,CR-111BR 0.000983 ,BMW-3BRL BMW-3BR 0.000279 GMW-7 M 0526 NS 0.0002 0.00089 0.00181 002 -a I RO-13 .GMW 0.0194 GMW-9 -8 Ns ABMW-1BR - CCR-200BR - �♦ L ♦ RO-7 -,� ' Ns• NS 0.0001 MW-2 0.0000712 5BIR 0.00206 ' - --� A CCR-207BR ;��}-k.. ♦♦ ,`�'R NS ♦ MW-13BR r. e v _ MW-33BR CCR-208BR ABMW-2BR !� 0.0001 MW-11BRL 6. ♦ ` 0.00108 ,} NS 0.000633 0.0001 �s� �., 7 C • �� DUNNAWAYRD ♦ + iii • P. - " CCR-212BR - ♦�+� ♦ f ♦ CCR-209BR NS MW-10BR l m ' NS CCR-213BR ! �, 0.0,308 ` R02 R 8 NO-11 FRO-15 ♦ MW-32BR Ng ?f,'.. .1 NS NS., Ns _ � 0.00126 i+ a rhjCCR-214BR ♦' o-sos Ro-12 �+ r•� CCR-210BR Ng CCR-215BR'. I NS 1 NS • CCR-211 BR �>: CCR-216BR f • __ 1 ♦ NS BG-1BRLR f : CW-3D NS �,� I'� MW-26BR - ♦ • 0.0385 0.000807 ' CCR-217BR ) ; 0 ' 0.004 • \� f` ♦ ` BG-02BR O� 0 002 3W-31R `, NS - - ♦' • ND - . + r`•3r BG-01 BR ` MW-04BR+ 0.000871 �' 0.000952 ' }. �• H�rsi MW-15BR CCR-218BR RO -iNs SFMD�0.000482 ' j NSYI r a MW-18BR 10.000231 7 A '-�•, rsc♦' • • SCALE ,tipGRAPHIC 0 362.5 725 1,450 2,175 2,900 Feet nTerra 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PWHOWNEBe4�o1-9om9 DUKE DRAWN BY 1 ROBERTS DATE 02/22/2015 E N E RGY C.EADY CPROJECT ED BYNAGC. ER LEGEND 10TOTAL URANIUM CONCENTRATION (pg/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR NORTH CAROLINA 2L CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL 0 WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY -••- ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY STREAM NOTES: THE NORTH CAROLINA 2L FOR TOTAL URANIUM IS 0.03 Ng/L. PROVISIONAL BACKGROUND THRESHOLD VALUE IS 0.003 Ng/L. DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. NS = NOT SAMPLED *VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALIFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL. DATA WITH HIGH TURBIDITY (>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83/2011). FIGURE 11-26 ISOCONCENTRATION MAP TOTAL URANIUM IN BEDROCK GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA V � IN ,�• �`+ 1 • J1. '' ` 1 - u ■ 1 PMW-3D 1.81 ■ 4.39 ♦ - 101 D JS � ABMW-sD #� o.sss ` ■ �CCR-100D INDUSTRIAL LANDFILL I NS -1 - EXTENSION IMPOUNDMENT LCID LANDFILL _ - _ Ind SFya,tqftl Ar*'Aoff � GPMW-2 � ` NNAWAYRD MWA8D ♦ _ 0.983 1 1 . LEGEND 10TOTAL VANADIUM CONCENTRATION (pg/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR IMAC CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL WATER SUPPLY WELL LANDFILL AREA SASH BASIN WASTE BOUNDARY —••—••- ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY STREAM NOTES: THE INTERIM MAXIMUM ALLOWABLE CONCENTRATION (IMAC) FOR VANADIUM IS 0.3 Ng/L PROVISIONAL BACKGROUND THRESHOLD VALUE IS 30.2 Ng/L. DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED NS = NOT SAMPLED ' VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALIFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL. DATA WITH HIGH TURBIDITY (>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. ' DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83/2011). SCALE ,tipGRAPHIC 0 362.5 725 1,450 2,175 2,900 Feet nTerra 148 RIVER STREET- SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PH/OWN E Se4 C201-9 099 DUKE DRAWN BY 1 ROBERTSDATE 02/19/2015 ENERGY C. EADY CPROJECT ED BYNAGC. ER FIGURE 11-27 ISOCONCENTRATION MAP VANADIUM IN TRANSITION ZONE GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA i •r-r/ • ' .1M ..1001 t� ■ �r• 'V-IDR .' 2.26 4rFy • +I�rrIII sFyDRgRD ERO-1004 ND COOLING WATER CCR-104BR 1 14.5 NS GMW-11 5.57 ABMW-7BR 0.496 L LANDFILL MW-16BRt 2.93 r DUNNAWAY RD MW-10BRt 2.9 i it • • I MW-18E rr_` ND ■ i ♦ I �.vr♦ RO-1003 ii 1.6 ■ ■ ■ ■ I /-3BR • 8 •i 3BR 5.3 IW-14BR MW-28BR ND f 2.01 . r t-105BR J NS MW-29BR r !7BR 1.24 I 03 CCR-112BR-BG NS CW-1 MW-30BR 21.4 0.3 RO-16 :5.5 =�N RO-1012 MW-23BRR I 1.12 ■ RO-1005 MW-20BRL ■ 6.1 0.318 r RO-1 R02014-RAW 5.1 5.1 � MW-24BR4- ■ 1.9 1 RO-1011 ND■ MW5-17BR A' 1 - 1.38 RO-1015 0.373 L RO-13 3.5 0.433 RO-11 10.6 RO-2 ND ■ RO-i03 RO8 ND 4.5 , r• .err. w •.■ • RO-1000 J5 0.6 DUKE ENERGY 5.9 pi■�_. RO-1013 3.8 -•_- RO-1016 5.5 RO-1018 4�S 4.1 6 GRAPHIC SCALE 0 320 640 1,280 1, 920 Feet 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 www.sv "errac.rc.com 2,560 DRAWN BY. J. ROBERTS DATE: 03/15/2018 PROJECT MANAGER: C. EADY CHECKED BY. C. EADY LEGEND 10TOTAL VANADIUM CONCENTRATION (pg/L) ND NOT DETECTED ABOVE REPORTING LIMIT NS NOT SAMPLED HIGHEST CONCENTRATION AREA CONTOUR IMAC CONTOUR INTERMEDIATE CONTOUR APPROX. BACKGROUND CONTOUR BACKGROUND MONITORING WELL DOWNGRADIENT MONITORING WELL SIDEGRADIENT MONITORING WELL UPGRADIENT MONITORING WELL O WATER SUPPLY WELL LANDFILL AREA ASH BASIN WASTE BOUNDARY -••-••■ ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY ROXBORO SITE BOUNDARY STREAM NOTES: THE INTERIM MAXIMUM ALLOWABLE CONCENTRATION (IMAC) FOR VANADIUM IS 0.3 Ng/L. PROVISIONAL BACKGROUND THRESHOLD VALUE IS 2.49 Ng/L. DASHED ISOCONCENTRATION CONTOURS WHERE INFERRED. NS = NOT SAMPLED VALUE CONSIDERED AN ANOMALY t CONCENTRATION GREATER THAN CURRENT SITE SPECIFIC BTV BUT WITHIN THE BACKGROUND CONCENTRATION RANGE FOR SIMILAR PIEDMONT GEOLOGIC SETTINGS. DUE TO GROUNDWATER FLOW DIRECTION AND OTHER CONSTITUENT MIGRATION PATTERNS, CONCENTRATION DOES NOT SUGGEST IMPACT FROM THE ASH BASIN. DATA MAY INCLUDE LAB -QUALIFIED RESULTS. REFER TO ANALYTICAL DATA TABLE NOTES FOR QUALFIER DEFINITIONS. CONCENTRATIONS REPORTED ON FIGURE REPRESENT MOST RECENT VALID SAMPLE RESULTS FOR EACH WELL. DATAWITH HIGH TURBIDITY(>10 NTU) OR RESULTS THAT INDICATE GROUT CONTAMINATION OF THE WELL (PH>9) HAVE BEEN REMOVED FROM DATASET. COLLECTION DATES DEPICTED ON FIGURE RANGE FROM MARCH 2O15 TO JULY 2017. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. AERIAL PHOTOGRAPHY OBTAINED FROM GOOGLE EARTH PRO ON SEPTEMBER 27, 2017. AERAL WAS COLLECTED ON JUNE 13, 2016. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83/2011). FIGURE 11-28 ISOCONCENTRATION MAP VANADIUM IN BEDROCK GROUNDWATER ROXBORO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC SEMORA, NORTH CAROLINA