NC0000337_AROHistoricGroundwaterDWRData_20190207

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box 27ee1-111141 EtO 101r. 27e11;.` tY1u T��-d063
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WELL CONSTRUCTION RECORD
Basin Code
Header Ent. GW-1.
DRILLING CONTRACTOR S&ME. Inc.
kj °
STATE WELL CONSTRUCTION a
DRILLER REGISTRATIOINUMBER 412
PERMIT NUMBER: 87-0012 WM-0032
1. WELL LOCATION: (Show sketch of the location below)
Nearest Town: Brevard
County: Transylvania
Cedar Mountain
Depth DRILLING LOG
(Road, Community, or Subdivision and Lot No.)
Frpm To Fo ati n Description
0 6' dozer
2. OWNER E. I. DuPont DeNumerous & Company. Inc.
Cut away by
ADDRESS P.O. Box 267 HtI.Y. 267 South
6" 416" Tan brown, sandy, clayey SILT
(Street or Route No.
4' 6" 121611 Brownish white, tan, sandy SII
Brevard NC 28712
City or Town State Zip Code
121611 161611 Cray. white, silty sand
3. DATE DRILLED 6-26-86 USE OF WELL. Monitoring
1616" 2216" Tannish, red, silty sand
4. TOTAL DEPTH 32' 6" CUTTINGS COLLECTED ® Yes ❑ No
22' 6" 32' 6" Reddish stray, white silty sand
5. DOES WELL REPLACE EXISTING WELL? ❑ Yes ® No
6. STATIC WATER LEVEL: 23' 11" FT. 0 above TOP OF CASING,
-- e
Q below
TOP OF CASING IS 2 ' 6n FT. ABOVE LAND SURFACE.
_
7. YIELD (gpm): METHOD OF TEST
8. WATER ZONES (depth):
9. CHLORINATION: Type Amount
10. CASING
Depth
0' 22`6"
From To Ft.
From To Ft.
From To Ft.
GROUT
Wall Thickness
Diameter or Weight/Ft. Material
2" sch 40 PVC
If additional space is needed use back of form.
LOCATION SKETCH
(Show direction and distance from at least two State Roads.
or other map reference points) RIVER
O
r
Depth Material Method I
From 1 ' 61 To 21' 6"Ft. lean grout Tremie pill e WELL q AERATION POLISHING DETENTION 300'
From To Ft. (Z*50' POND l POND POND
SCREEN:
Depth Diameter Slot Size Material
From 22' 6" To 32' 6" Ft. 2" in 0.0101n. PVC
From To Ft. In. in.
From To Ft inin. ;
13. GRAVEL PACK:
Depth Size Material � HWY.276
From 22' 6" To 32' 6" Ft Coarse Sand
From To Ft.
14.REMARKS: 1ft. bentonite seal above screen, concrete collar, lockainiz cap at surface.
1 00 HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15 NCAC 2C, WELL CONSTRUCTION
STANDARDS, AND THAT A COPY OF THIS RECORD HAS EN TO THE WELL OWNER.
S c—
SIGNATURE OF C CTOR OR AGENT DATE
GW-1 Revised 11/84 Submit original to Division of Environmental Management and copy to well owne

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biotite-injection gneiss, which is a. migmatite, is believed to have bee.
formed during Precambrian time by the selected melting of metamorphic rocs_
The selective melting results in the more mobile granitic parts being n.o
..tr.d
and forming layers, leaving the less fusible parts of the original metamorphic
rock between them.
The quartz-biotite.gneiss found in the biotite-injection gneiss unit is
composed chiefly of feldspar, quartz, biotite, and minor amounts of horn-
blende, magnetite, Pyrite, muscovite, and sphene. The granitic portion: of
the unit is composed chiefly of plagioclase feldspars, alkali feldspars,
quartz, and minor amounts of biotite, hornblende, muscovite, and magnetite.
The unit generally weathers into a light- to medium dark -red, clayey to
slightly sandy saprolite which closely resembles that of quartz-biotite
gneiss. This factor, in addition to the very gradational contacts, nial:es
mapping of this emit very difficult.
Hydrologic Oh, exacter .;.sties
The biotite-injection gneiss ur.i t p i�n remor.e areas of Transylvania
County, and, as a -result, very little hydrologic information is available.
However, in other areas of the mountains it is a very good
aquifer, provided the wells are located in draws or valleys(with a large
t� pw k1'4a
recharge area.��
�`«''i E4 r' i�„3
Brevard Belt
L
General Character and Buena
The Brevard Belt occupies a narrow northeast trending belt across the
center of Transylvania County and is bounded on both sides by fault zones.

Typical outcrops of the unit can be seen on secondary road 1321 just no.
of its intersection with U. S. Highway 64.
The Brevard Belt consists of Brevard schist, a medium dark -gray to
dark bluish --gray, fine-grained rock which may exhibit boudinage structure
(bulges on the surface of the rock as a result of concentrated layering of
muscovite). The belt also contains smaller amounts of quartzite, slate,
garnet --muscovite schist, quartz-biotite gneiss, marble and pyroclastics.
The Brevard schist is composed: of muscovite, quartz, biotite, metal
oxides, graphite, minor amounts of garnet, and augens of quartz and feldspar.
The Brevard Belt is believed to have been formed during Lower Cambrian
time by the metamorphism of a sedimentary sequence of rocks. Evidence for
this can be seen in the discontinuous lenses of marble parallel to relatively
continuous beds of quartzite. The belt generally weathers deeply into a
reddislh-bror�m clay.
Hydrologic Characteristics
1', e Bre -gard Belt `'s xtensl ely faulted and fractured along its boundaries
in the vicinity of the Brevard Fault Zone. This Crakes it a very good watx_-
' e��.�; aquifer, as can be noted by h ch-y7el& wells located in these areas.
It is also underlain in some areas by lenses of marble which could contain
solution cavities bes.*-Jrng large amounts of water. Large water supplies could
be developed in this unit
Hornblende Gneiss
General Character and Extent
The hornblende gneiss unit can be seen in the southeastern section of
Transylvania County, generally in the form of lens --shaped beds.

The hornblende gneiss is a dark --gray to grayish -black, fine-grained .
which weathers into a dark reddish -brown, clayey saprolite. It is be7..ievf,,AAl
to have been formed by the metamorphism of gabbro or diorite during preca.O,ar1an.
time. It is composed of hornblende, plagioclase feldspar, alkali feldspar,
quartz, and smaller amounts of biotite, muscovite, or garnet. Traces of
magnetite, ilmenite, pyrite, .or sphene may be present.
Hydrologic i
y r logic Characteristics
Very little information is available on the hydrologic characteristics of
the hornblende gneiss unit in Transylvania County. However, in other mountain
areas where more information is available, it seems to be highly fractured
and should supply adequate lister for large water users} witt�r/proper 'tell
location. -
i M1 fr Y 1.lu
F/mow f y f" E 8 ilFut1
Marble General Character and Fterm
Marble 4-S" in: Transylvania County in the fora of discontinuous beds in
the Breva,rd Belt with few outcrops being exposed dAZ2` to theAbeds generally
wy
valleys.
The marble is described by ,Conrad (1960) as being white and finely
crystalline, but may contain beds of light and dark -blue marble.
Hydrologic Characteristics
Characteristics
° t {
Al
z
Large supplies of water can. probably be developed in the marble because
' the solution cavities ban carry large quantities of water. However, the
b
location of marble beds is hard' to determine owing to the lack of outcrops,
f

and, therefore, a series of test wells would be needed to properly devel.o,
the marble:
Saprolite and Alluvium
General Character -and Extent
Saprolite overlies all the geologic units in Transylvania County except
the alluvial areas in the floodplains and locally whore bedrock is exposed.
The nature of the saprolite is dependent on the type of parent rock from which
It was formed. It is composed generally of clay on geologic units such as
hornblende gneiss and sandy clay on the Whiteside granite and Henderson gneiss.
Alluvial deposits, e along the French Broad River and other surface(
streams in Transylvania County. They are deposited when the saprolite is
transported by erosion to the floodplains. Most of the smaller particles
of clay and silt are carried away in suspension by surface water, leaving
deposits of sand, gravel, and cobbles on the valley floor. Varying atmounts
of clay And silt are also deposited.
The thickness of the saprolite 1-g--va?riabl67 (fig. 9) . The saprolite is
generally thicker on hills,or slopes and thinner in draws or valleys.
Figure 10 illustrates the relationship of saprolite thickness to topography.
The saprolite thickness or, hills is not plotted ° e to lack of data.
ok
_ thickness of the alluvium i.s- n-ot--ava44-al4e---car--th"i:s—prep-ort.
.r�✓Yt L/�...,�C-tl��--R-,�`i..y� .�. -s-'s1 t.:G 5,.'..,,r' .;.+'^r'. �.. i.. ,. '�.:a�'f "a' r4° _ � .r .S�. t'.1a a,�Q9a_,
bas-ed--on_ oth,er-gt-udies-,-- the alluvial. thArkxzess- r � T ay arria e t n ty ��ill.
bo.v�=ab3�-;u�l�"�1i"ke t�e._,.saprolite.
Hydrologic Characteristics
The saprolite; due -to its high clay and silt content, is generally only
suitable for the development of small water supplies by the use of bored or

dug water -table wells. Hov,ever, in alluvial deposits of sand and gravel
along the French Broad River, large supplies could probably be developed
by the use of collector or gravel -packed wells.
HYDRAULIC CHARACTER
AccordingNto records collected .y»rrart`Tf: Htural� an.dn
\, �
'r t , '
Economic `'R otxrees,�13 pumping tests-ve—b° vn made in Transylvania County.
are 4++tTs-t-r' in
table 2, and their locations are--s� . n *ev*= `y in figure I.
t y p{
of fi 1A d C-
T}�6-h h.,,,mariab i�batRe.en_Mthe-,t-ests is the result of a number of
factors, �x Eenrdert con-m-ire -g"ier- ter t�
4
x
M.�.made. These factors include (1) how. -many fractures -ha-_v tee t
penetrated by the well; (2) the different elevations of the various fracture
recharge areas in the saprolite; (3) the depth of the saprolite; (4) the
thickness of the water -table aquifer; and (3) the permeability of the R ,
1 �' ,may@. �' , `t-�o, `ti.:�,r9,,;Y,},�.- u�,v1r 'N„�'kr^'i-d.'t.�A t^'F� r.LSv
saproli>ne. 4 p
r G yts, " �e crvw 4_ wrR��ew-�ot�al 11�4 sl�k._
e all of these variables exist, it is the author's opinion that
.here is need for a .detailed aquifer study inthe mountainous areas of the
�.. State. This would consist of drilling artesian wells in carefully chosen
i
areas, boring water -table wells, and snaking pumping tests in order to deterraine
the location of the recharge areas. 0
, 4 y
. I
TATER-24
Natural Qualm
Groundwater contains many various types and concentrations of dissolved
minerals. These minerals are leached from the soil

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and rock through which the water percolates and, to a much lesser extent
from the atmosphere prior to entering the ground. As a result, the chemica
quality of groundwater is not uniform, but varies with the temperature and
composition of the soil and rock over and through which it passes and with
the pattern and rate of circulation of the water. Siact the circulation
period in the mountain region is relatively;bhort,; the dissolved mineral
content of groundwater is,generally very low.
The locations of weals from which :eater samples were collected for chemical
analysis are shown in figure 11. The results of these analyses are summarised
according to geologic UP -its in table 3.
The iron content of groundwater in Transylvania County is very low (fig. 12)
with only ;eery localized high concentrations generally associated with possible
mineralization along areas of the B evafc? Fault Zone. Figure 13 shows the
relationship of iron content in groundwatet-venvus rock type in three geologic
Units.
s _ the VV e s vex �ent� of groundwater in the
Ta1�'. i ��, w..-I.Lt.1�.ioli C.i d.12: `�.G'i`s+�1_ a:._mC.._ fir"
county is shown in figure 14. Most of the wells saizpled for chemical analysis
had soft water. The relationship of the total hardness of groundwater to the
geologic units is illustrated in figure 15.
Figure 1.6 shows the specific conductance of groundwater that -ems a�r the
county. The majority of the samples taken have a very low specific conductance,
indicating a low dissolved solid content. Figure 17 illustrates the relation-
ship between specific conductance and rock type.
The concentration of silica Wan -As in groundwater in the county is sho-wn
In figure 18. These concentrations are vary low and should not represent a:
problem for most domestic and industrial use. The relationship between silica
concentration in groundwater and rock type is shown in figure 19.
s
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Potential Pollution
Groundwater pollution in Transylvania County is rare except possibly
r
sanitary landfills, sludge disposal
lagoons, high -density septic tank areas, evaporation basins, etc. There
are a few �xss -ces w coliform bacteria ha* ti� in wells, but in
most cases this could probably be attributed to waste disposal systems being
located too close to the wel; or/,a thin saprolite which did not properly
filter the water or/,poor well construction.
As water percolates through the soil, it is filtered naturally by five
processes: (1) 'filtration; (2) adsorption; (3) biodegradation (4) death of
microorganisms due to excessive competition for nutrients and oxygen.,
antagonsiM, predation, Or simply detlention; and (5) dilution by dispersion- in
the grouneNwater system. The processes are very effective in, removing
suspended particles, bacteria, virsuses, many chemical pollutants, and
radiation. -ibis does not mean That r_y b�orrr>daat_€r is safe from polluti_c..r .�'
.,
c
the soil can only absorb a certain amount of pollution, and when the satu-
ration point is reached, the groundc,ater system- will be damaged for a. long
time because groundwater movement is slow. The quality of streams would
also be lowered because they are dependent on groundwater from springs for
most of the year.
A network of water -quality monitoring wells is being set -up-- aere�s�h9 -x._
state-, _.lt z11_..,con's st 4f..b line w 11 1�rca ed i t € ll�ate�i_.ar,ea _ to
monitor natural Changes in slater quality
"
et'k t n)" Y ,�.�
located,-ten -a s.,.:org potent i1 pollut-i-on tam-slZo of <,.i ffec ed
b .--- ",. . Figure 11 shows the location of water --quality monitoring well
in Transylvania County. A-tai pr s .......
tndeay t`o "r'ecord all ."potential groundwater pollution points'*`i�°" Alo°nth =�

WATER USE AND DEVELOPMENT
Current Use
Groundwater is being utilized in Transylvania County by many public
,sue-lhes-'and industries;jand for the domestic needs of a majority of
households in the county., Table 4'shows several of the current large public
and industrial groundwater users in the county. Their location is shown in
figure 20.
Potential Development
Although groundwater is used throughout Transylvania County for public,
industrial, and domestic supplies, only a fraction
of its potential. it is capa-ble of supplying large waters foes with an
irexpensite and high -quality source of water.
The amount of groundwater available in various areas in Transylvania
County, based ,on stream flow 70 percent of the time, has previously been
illustrated ixy figure 4. - Itow this figure, it can be seer: that large amounts
of groundwater are available in the county.As an example, the Catheys
Creek Basin above the gaging station has a drainage area of only 11.7 square
404-
1�.�. `'"' Miles, but could be expected to yield 14.5 million gallons per day if
properly developed. This basin represents only approximately three percent
of Transylvania County's 379 square miles. . - te- shows the location_ of
high. -yield wells constructed in Trmasylvania County, the location of the
hydrogeolcgic units roost favorable and least favorable for groundwater
development, and the location of potential high --yield well sites.
The most favorable areas (unit 1) shown in plYteZ'O"are very suitable for

Table 4. - Public and industrial groundwater use in Transylvania County.
Vlell Maximum. Daily
Location Owner Type of Use Yield in
Number I Gallons/Day
P89
s-1
U. S. Forestry Service
Q87
q-3
Transylvania Co. Board of Education
Q88
1-1
M. R. Hunter
Q88
n-3
U. S. Forestry Service
Q88
r-3
U. S. Forestry Service
i
Q89
m-1
U. S. Forestry Service
P87
d-1
Eagle Nest Camp
R87
r-1
E. I. DuPont Co.
R87
r-4
E. 1. DuPont Co.
R87
r-5
E. I. DuPont Co.
R87
s-2
E: I. DuPont Co.
R83
h--2
Knob Creek Subdivision
1'88
h-3
Knob Creek Subdivision
R88
h-4
Knob Creek Subdivision
318i
q---1
p.ock Brook Camp
R88
qP-2
Alfred J. Check
S88
e-1
Connestee Falls Development
S88
f-1
Connestee Falls Development
S88
g-1
Connestee Falls Developme-nt
S88
g--2
Connestee Falls Development
S88
g-3
Connestee Falls Development
S39
d-4
American Thread Company
S89
f_1
Transylvania Co. Board of Education
S89
f-2
Rosman. Water Association
S89
f-9
Transylvania Co. Board of Education
I
S90
j-1
Mitchell Bissell Company
!S90
4-2
Mitchell Bissell Company
S90
j-3
Mitchell Bissell Company
S90
w-1
Hemlock Hill Camp
�S91
b-1
Indian Lake Estates
Public
Public
Public
I
Public
Public
Public
Public
Industrial
Industrial
Industrial
Industrial
Public
Public
Public
Public
Public
Public
Public
Public
Public
Public
Industrial
Public
Public
Public
industrial
Industrial
Industrial
Public
Public
33,120
40,896
28,800
28,800
50,400
36,000
76,320
21,600
28,800
18,760
6,480
360,000
31,680
28,800
11,320
144,000
288,000
216,000
216,000
214,5.60
43,200
144,000
77.1760
57,600
28,800
67,680
43,200
15,840

Table 4. -,Public and industrial groundwater use in Transylvania County
(continued).
Well
Location
Number
Owner
Type of Use
Maximum Daily
Yield in
Gallons/Day
S91 b-2
Indian Lake Estates
Public
28,8001
S91 b-3
Indian Lake Estates
Public
8,640
S91 i-3
A. H. Cosby
Public
11,520
S91 i--4
Sher-Lor Corporation
Public
28,800
S91 r-1
S. N. Youngblood
Public
10,800
S91 r-2
S. N. Youngblood
Public
8,640
S91'x--1
White Water Pines Subdivision
Public
28,800
S92 u-1
I
I
I �
I
}
Camp Buc
1
Public

the development of high -yielding wells. These areas are extensively frac_,
and faulted., in many instances overlain by sand and gravel, and have large
fi, recharge areas which make them excellent -aquifers. Wells constructed in these
areas should be drilled to a` minimum depth of 500 feet to insure that as raar.
ay
fractures as possible, have been penetrated. The alluvium could possibly be
developed by the installation of collector -type or screened wells.
The areas shown as least favorable (unit 3) are generally not heaRr-i:7.-;
fractured and have smaller recharge areas. Moderate supplies of water cou'.d
be developed in this unit if wells were drilled in the larger draws.
The following is a list of location descriptions of the potential well
sites shown on «4_.
Site No.
1. Site is located about 1,300 feet southwest of Rosman just northwest
of a sharp bend on U. S. 178. The well should be approximately 200
feet northwest of U. S. 178 and approximately 300 feet soutrawes-. Of
the French Broad River,
2. Site is located in the general vicinity of the Rosman sewage treatment
plant. A high -yielding well is located at the plant.
3. Site is located nea.r.Rosran. The well should be located approximately
200 feet east of U. S. 178 and approximately 100 feet south of
secondary road 1107.
4. Site is located southeast of the intersection of secondary roads
1107 and 1131 and west of the Middle Fork French Broad River. The
well should be _located approximately 200 feet east of secondary
road 1131 and approximately 100 feet south of secondary road 1107.
5. Site is located east of Rosman in the French Broad Flood Plain. The

well should be located approximately 400 feet southeast of U. S. ,
and approximately 0.2 mile northeast of the intersection of U. S. 64'
and secondary road 1156.
6. Site is located in the French Broad Flood Plain, 2,000 feet northeast
of site h7o. 5 and is approximately 400 feet south of U. S. 64. A
high -yielding well is located approximately 3,000 feet northeast of
this well site at American Thread Company.
7. Site is located southwest of Calvert in the French Broad Flood Plain.
The well should be located approximately 100 feet west of secondary
road 1129 and approximately 300 feet 'north of the French Broad River.
8. Site is located northeast of Calvert. The well should be located
approximately 100 feet north of secondary road 1109 and approximately
100 feet east of Paxaon Creek vhieh crosses secondary road 1109 0.6
Haile northeast of the French Broad River bridge.
9. Site is located northeast of Calvert. The well should be located
approximately 100 feet north o.: secondary road 1.109 and approximately
5�CO feet west of the French Broad River bridlge.
10. Site is located north of Calvert. The well should be located approxi-
mately 100 feet southeast of secondary road 1128 and approximately
100 feet east of Cherryfield Creek which is 0.8 mile northeast of the
intersection of secondary roads 1128 and 1331.
11. Site is located southwest of Selica. The well should be located
approximately 200 feet east of secondary road 1128 and approximately
100 feet south of Patterson Creek which crosses secondary road 1128-
approximately 0.6 mile south of U. S. 64.
12. Site is located: north of Calvert The well should be located approxi-
mately 100 feet east of U. S. 64 and approximately 100 feet northeast
of Morgan Mill Greek which. crosses U. S. 64 0.2 mile south of the

intersection of U. S. 64 and secondary road 1331.
13. Site is located southeast of Selica. The well should be located
approximately 100 feet from the east side of secondary road 1110
and approximately 300 feet south of the intersection of secondary'
.roads 1110 and 1113.
14. Site is located south of Selica near Catheys Creek. The well should
be located approximately 100 feet southeast of U. S. 64 and approxi-
mately 100 feet southwest of Catheys Creek which crosses U. S. 64
south of Selica.
15. Site is located south of Brevard. The well should be located approxi--
mately 100 feet west of U. S. 276 and approximately 800 feet north of
the intersection of U. S. 64 and secondary road 1103.
16. Site is located south of Brevard. The well should be located approxi-
mately 100 feet west of U. S. 276 and approximately 900 feet south
of the intersections of U. S. 276 and secondary road 1.114.
17. Site is loca_¢ .yd south of Brevard. The well should be located
approximately 100 feet west of U. S. 276 and approximately 800
feet south of the intersection of �T. S. 276 and secondary road 1537.
18. Site is located south of Brevard. The well should be located
approximately 100 feet east of U. S. 276 and approximately 200 feet
north of the French Broad River.
19. Site is located southeast of Brevard. The well should be located
approximately 100 feet east of secondary road 1119 and approximately
900 feet southeast of secondary road 1118.
20. Site is located southeast of Brevard. The well should be located
approximately 100 feet southeast of secondary road 1118 and
approximately 1,400 feet southwest of the intersection of U. S. 64

and secondary road 1118. This would place the site approximately
100 feet southwest of an unnamed tributary to the French Broad
River.
21. Site is located between Nicholsen Creek and Norton Creek. The well
should be located approximately 100 feet east of secondary road 11.16
and approximately 100 feet south of Norton Creek which crosses
secondary road 1116 approximately 300 feet north of the intersection
of secondary roads 1116 and 1123.
22. Site is located southwest of Brevard. The well should be located
approximately 100 feet south of secondary road 1344 and directly
south of the intersection of secondary roads 1344 and 1348.
23. Site: is located east of Brevard. The well should be located approxi-
D�ately 00 feet east of secondary road 1546 and approximately 0.35
mile aortheast of tre intersection of secondary roads 1546 and 1544.
.24. S-to is located north of Brevard. The site is located approximately
100 A-Fee.t southeast of the Souci er-n Railway tracks between Ydngs
Creek. and Long Creek (Tinsley Creek).
25. Site is located north of Brevard. The well should he located approxi-
mately 500 feet west of secondary road 1353 and approximately 800
feet -north of the intersection of secondary roads 1353 and 1351.
High yield wells are located in this area.
26. Site is located northwest of Brevard. The site is located approxi-
mately 100 feet west of secondary road 1354 and approximately 0.55
mile nor,:hi,.rest of the intersection of secondary roads 1354 and 1353.
High yield vaells are located in this area
27. Site is located southeast of Pisgah Forest. The well should be

located approximately 700 feet south of secondary road 1533 and
approximately 400 feet southeast of the junction of the Davidson
River and the French Broad River.
28. Site is located southeast of Pisgah Forest The well should be
located approximately 100 feet south of secondary road 1533 and
approximately 300 feet east of the intersection of secondary
roads 1533 and 1504.
29. Site is located west of Penrose. The well should be located
approximately 100 feet south of U. S. 64 and approximately 100
feet east of Lyday Creek (Lydia Creek) which is approximately
0.5 mile west of Penrose School.
30. Site is located northwest of Penrose. The well should be located
appro- imiately 100 feet north of secondary -road 1506 and approxi-Mately
100 feet west of Lyday Creek (Lydia. Creek).
31. Site is located south of Penrose. The well should be located
approxI_in rely 100 feet west of secondary road. 1528 and approximately
100 feet south of the Southern Railway which crosses secondary roads
1528 0.24 mile: south of U. S. 64. A. high yield well is reported in
this area.
32. Site is located northeast of Pisgah Forest. The well should be
located approximately 100 feet southeast of N. C. 280 and approxi-
mately 1,300 feet southwest of the intersection: of N. C. 280 and
secondary road 1502 Nigh yield wells are in this area.
^.,

WhIl Construction
The most common type of well constructed in Transylvania County is the
61-inchIdrilled well. It is cased through the saprolite, and the casing is
seated into bedrock. The well is drilled deeper into the rock until water -
bearing fractures or faults are penetrated. These fractures or faults act as
a pipeline to carry and store water from the recharge area in the water -table _
aquifer to the artesian well.
Two other types of wells are also encountered in Transylvania County;
the bored and dug wells,,both of which are water -table wells constructed in
the saprolite. Both types of wells are essentially the same, the only differ-
ence being that the bored well is completed with power machinery and lined
with cement the while the dug well: is constructed by hand and may or may
not be lined with tile or rock.
an January 1, 1932i the North Carolina Well Construction Regulations and
Standar6s becamela T.:__ e laws were_ designed to insure proper well cAsti.uc-
tion and t o ,p _ta%-ect the grouundwatqr Yt.sour es. They se t1reqLIirepent sA the Mx
iiii� b �
asin "zael girt Ezs r . _ 4 `we zb __ cement to a depth of
26 feet, rr nimon d� �. of 100 feet from well §Aseptic tank, and
reqaAr_ he- we,11- t
DATA COLLECTION PROGRAM
Information on grounduuter is constantly being received in Transylvania
,...
{ t'kr#„tom
County and across the state.well construction
records supplied by drillers, the inventory of wells during well inspection,
t
the collection of water.samples from wells, data pumping tests on permit
<a1+

wells, and the collection of rock samples from wells.
A monitoring system for groundwater pollution is being set up across the
state to determine the amount and type of pollutants in groundwater. These
data will be of much help in evaluating waste disposal in the ground.
` w SUMMARY
4
Groundwater is available in Transylvania County through two different
'i:- but interconnected aquifer systems: the artesian and water -table aquifers.
a —
� ' dells in the artesian aquifer are completed in bedrock and receive their
water err fractures, faults, or joints intersected by ` drilling] Taese, ,
in turn, receive their recharge from the water table aquifer in the saprolatp..'`
oare the most cco aj �ly ,
x:�allt��^J�4x� u�"Tki�sia �.artefra wells t -r�.7L•, constructed type: of
wells in the area and can supply adequate water for large industrial and
public supplies. Wells constructed in the dater -table aquifer are either
bored or hand dug into the s aprolite or alluviums to a point below the at; r
table. They are: used primarily for domestic water supplies. However, large
supplies could possibly bE� developed in the alluvial areas through the use f `7
of collector type or gravel packed wells. � I
The aquifer systems in the county receive all recharge (�irec It from
f
precipitation, except perhaps locally around areas of heavy pumping where
nearby streams may contribute.
Groundwater is continuously bein&,discharged naturally into the surface
waters by springs. It has been estimated that the strew flow equaled or
exceeded seventy percent of the time is the natural groundwater discharge.
This amounts to approximately 470 m_gd being naturally discharged in
Transylvania. County.

Transylvania County is underlain by varying grades of metamorphic,
igneous, and sedimentary rocks. These are overlain by 0 to about 200
feet of various combinations of clay, silt, sand, and gravel. The sand
and gravel are more common in the alluvial areas in the flood plains.
All of the rock units appear to be highly fractured and faulted in
areas of draws and valleys. However, the most heavily fractured and
faulted areas are in the rock units adjacent to the Brevard Fault Zone
and along the French Broad Flood Plain inthe Henderson gneiss. Both of
these areas should be excellent locations for the construction of high
yield artesian wells.
The natural quality of groundwater in Transylvania. County is generally
excellent with a lour dissolved solids content, a low hardness, and low iron
content. Iron is generally the only mineral constituent that can cause
problems, but it is very localized in its occurrence and can be easily
removed frov, water by treatment.
Groundwater pollution is not a problem in Transylvania County at present,
butt with increased. developL�ent and subsurface .Taste disposal the threat
exists. The soil through Ghich water percolates ants as a natural filter,
reproving organic and chemical pollutants, but this natural filtering
capacity can be destroyed by subjecting the soils to long periods of heavy
pollution. At present, p5y polluted groundwater in the county is very
localized and is usually the result of improper well construction or a thin
soil. cover which does not properly filter percolating water.
Groundwater is being utilized throughout the county by industries,
businesses, and public or private crater supplies as a safe and economical
source of water. However, its true potential as a water supply has not been
even remotely realized when a naturaexcessJgroundwater discharge of 470 mgd

SELECTED REFERENCES
Conrad, Stephen G., 1960, Crystalline Limestone of the Piedmont and Mount-t-111
Regions of North Carolina: N. C. Department of Conservation and Develop
meat, Bull. No. 74, 56 p.
Duncan, Donald A., and Peace, Richard R., Jr., 1966, Ground --Water Resources
of Cleveland County, North Carolina: North Carolina Department of Water
Resources, Ground -Water Bull. No. 11, 65 p.
Floyd, Edwin o., and Peace, Richard R., 1974,An Appraisal of the Groundwater
Resources of the Upper Cape Fear River Basin, North Carolina: N. C.
Department of Natural and Economic Resources, Ground Water Bull.. No. 20,
21 p.
Goddard, G. C., Jr. 1963, Water Supply Characteristics of North Carolina'
Streams U. S. Geological Survey Water -Supply Paper 1761, 233 p.
Heath, Ralph C., and Trainer, Frank W., 1965, Introduction to Groundwater
Hydrology: New York, John Wiley and Sons, Inc., 284,p.
Hutchison, Dr._H. , Microbiological Aspects of Groundwater Pollution: The
Water_ R.esrarch Association.
. ohnson, Edward E., Inc., 1966, Ground T-?ater and 1--Tells: St. Paul, 440 p.
Mundorff, t$s J. , 1945, Progress Report or, r3round-Water in North Carolina:
N. C. Dept. of Conserv. and Devel., Bull. 47, 78 p.
Peace, R. R„ Jr. , ank.21 Link, Donald R. 1971. Geology and Cround—TNTat.-.r
Resources of Nortl1western North Carolina: rd. C. Department of Watcr
and Air Resources, Ground Water is'ull. No. 19., 135 p.
Stuckey, Jasper L., and Conrad, Stephen G., 1955, Explanatory Text for
Geologic Map of North Carolina: N. C. Departq:-.ent of Conservation and
Development, Bull. No. 71, 51 p.
Trapp, Henry, Jr., 1970 Geology and Ground -Water Resources of the Asheville
Area; North Carolina: N. C. Department of Water and Air Resources,
Bull. No. 16, 127 p.
Yorts, W. I.•., 1971, Low -Flow Measurements of North Carolina Streams: N. C.
Department of Water and Air Resources, 235 p.

Figu J Silica concentrations in groundwater in Transylvania County.
Cumulative frequency curves according to rock type and
silicain groundwater...... IH
..
Public axed industrial•o,' .......in.
Transylvania
ounty.................
TABLES
_ Page
Table 1. Record of water -level monitoring wells in Transylvania
County. .... .., ..
Pumping test data from wells in Transylvania County....
Ranges of chemical constituents in groundwater in Transylvania
County. ........ ,...•.... .. •. .•
1�, Public and industrial groundwater use in Transylvania Cotinty. ,

DATE SAMPLED
ALKALINITY, TO pH 4.5
ALKALINITY, TO pH 8.3
ALUMINUPI
ARSENIC
4 to
BARIUM
BERYLLIUM
BICARBONATE
CADMIUM
.� t'. OjJ
.L, Q. 00 f
00 /
CALCIUM
CARBONATE
CHLORIDE
CHROMIUM, TOTAL
0. 0,1
C 0.0,4 0
4, 0,70
COBALT
COD
p
COLIFORM, FECAL
COLIFORM, TOTAL
COPPER
0.013
4 0, 4 /0
.4
CYANIDE
DISSOLVED SOLIDS
e
% 7
�S
_
FLUORIDE
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< C). 1
.L 0, l
HARDNESS CaCo,
HARDNESS, NON -CARBONATE
IRON
.��
C7 • 3 3
T 7
LEAD
0. Os-
LITHIUM
Red Ink = Sample taken by facility

2

DATE SAMPLED
MBAS
MAGNESIUM
MANGANESE
o
MERCURY
NICKEL
NITROGEN, AMMONIA
Ot
0 �7
c2•
0,0i
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NITROGEN, LJELDAIIL
NITRATE & NITRITE
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PH
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PHOSPHORUS, TOTAL
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SELENIUM
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SODIUM
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7.5 7
COUNTY TkAA)s Yl- VA^J,
DATE SAMPLED
%IA-11
11-A3-11-A
ALKALINITY, TO pH 4.5
ALIaLINITY. TO pH 8.3
ALUMINUM
ARSENIC
o
BARIUM
BERYLLIUM
BICARBONATE
CADMIUM
.40-001
CALCIUM
CARBONATE
CHLORIDE
7
CHROMIUM, TOTAL
4 0. 0
COBALT
COD
COLIFORM, FECAL
COLIFORM, TOTAL
COPPER
CYANIDE
D . ISSOLVED SOLIDS
37
FLUORIDE
c)
HARDNESS CaCo.,
HARDNESS, NON -CARBONATE
IRON
o
LEAD
4 C7.0 -5
LITHIUM
C D SA -r,4 Ae IV dY

SO

DATE SAMPLED
% — 7— 7/
7 " .� 3- -7l
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I
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pH
PHENOLS
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PHOSPHORUS, TOTAL
POTASSIUM
SELENIUM
4
SILVER
G C% < C> l� _5'
Q e C�
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SODIUM
SPECIFIC CONDUCTANCE
SULFATE
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TOX
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STATIC WATER LEVEL
3 6-
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COU .
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SAAIPLEn
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ALKALINITY TO H
ALKALINITY, TO PH 8.3
ALUMINUM -
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44
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PHOSPHORUS, TOTAL �lJfO!
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ENVIRONMENTAL LABORATORIES
Mr. Roger Galloway
Page 2
Client Reference: Monitoring Wells
REPORT OF LABORATORY ANALYSIS
December 18, 1995
PACE Project Number: A51128�
PACE Sample Number:
93 0154069
93 0154077
93 0154085
Date Collected:
11/27/95
11/27/95
11/27/95
Date Received:
11/28/95
11/28/95
11/28/95
Client Sample ID:
Well-
River-
River-
R87s7
Bridle
Intake
Parameter
Units
MDL
Veil
Dike
INORGANIC ANALYSIS
INDIVIDUAL PARAMETERS
mg/L
0.005
ND
ND
ND
Arsenic
Barium
mg/L
0.10
ND
ND
ND
Biochemical Oxygen Demand, 05 Day
mg/L
2.0
ND
ND
ND
Cadmium
mg/L
0.001
ND
ND
ND
Chemical Oxygen Demand
mg/L
15
ND
ND
ND
Chloride
mg/L
1
1.5
ND
1.5
Chromium
mg/L
0.020
ND
ND
ND
Copper
mg/L
0.01
ND
ND
ND
Fluoride, Total Recoverable (Electrode)
mg/L
0.1
ND
ND
ND
Iron
mg/L
0.05
0.247
0.203
0.282
Lead
mg/L
0.005
ND
ND
ND
Manganese
mg/L
0.01
0.056
0.034
0.038
Mercury
mg/L
0.0002
0.0007
ND
ND
Nitrogen, Ammonia
mg/L
0.1
ND
ND
ND
Nitrogen, Nitrate in Wastewater
mg/L
0.1
ND
ND
ND
Phenol
mg/L
0.005
ND
ND
ND
Selenium
mg/L
0.005
ND
ND
ND
Silver
mg/L
0.010
ND
ND
ND
Solids, Total Dissolved
mg/L
1
25
34
36
Specific Conductivity
umhos/cm
10
16
15
16
Sulfate
mg/L
1
ND
ND
ND
Total Organic Carbon
mg/L
0.5
6.1
6.3
6.2
Zinc
mg/L
0.01
0.021
ND
ND
pH
Units
0.10
7.5
5.7
6.5
Samples exceeded hold time for pH analysis when rec'd by lab, results not
valid for permit monitoring.
D
JAN 1 0 W6
ft���� ! An Equal Opportunity Employer
Asheville, NC 28801
TEL:[phone]
FAX:[phone]

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J
ENVIRONMENTAL LABORATORIES
Mr. Roger Galloway
Page 7
Client Reference: EI Dupont
PACE Sample Number:
Date Collected:
Date Received:
Client Sample ID:
Parameter
ORGANIC ANALYSIS
r�
i
REPORT OF LABORATORY ANALYSIS
December 18, 1995
PACE Project Number:
A5112b.
93 0154069
11/27/95
11/30/95
Well
Units MDL R87s7 DATE ANALYZED
VOLATILE ORGANICS
Dichlorodifluoromethane ug/L 1.0 NO 12/07/95
Chloromethane ug/L 1.0 ND 12/07/95
Chloroethene (Vinyl chloride) ug/L 1.0 ND 12/07/95
Bromomethane ug/"L 1.0 ND 12/07/95
Chloroethane ug/L 1.0 ND 12/07/95
Trichlorofluoromethane ug/L 1.0 ND 12/07/95
1,1-Dichloroethene ug/L 1.0 ND 12/07/95
Dichloromethane ug/L 1.0 ND 12/07/95
trans-1,2-Dichloroethene ug/L 1.0 ND 12/07/95
1,1-Dichloroethane ug/L 1.0 ND 12/07/95
cis-1,2-Dichloroethene ug/L 1.0 ND 12/07/95
2,2-Dichloropropane ug/L 1.0 ND 12/07/95
Chloroform ug/L 1.0 ND 12/07/95
Bromochloromethane ug/L 1.0 ND 12/07/95
1,1,1-Trichloroethane ug/L 1.0 ND 12/07/95
1,1-Dichloro-l-propene ug/L 1.0 ND 12/07/95
Carbon tetrachloride ug/'L 1.0 ND 12/07/95
1,2-Dichloroethane ug/L 1.0 ND 12/07/95
1,1,2-Trichloroethene ug/L 1.0 ND 12/07/95
1,2-Dichloropropane ug/L 1.0 ND 12/07/95
Bromodichloromethane ug/L 1.0 ND 12/07/95
Dibromomethane ug/L 1.0 ND 12/07/95
cis-1,3-Dichloro-l-propene ug/L 1.0 ND 12/07/95
trans-1,3-Dichloro-l-propene ug/L 1.0 ND 12/07/95
1,1,2-Trichloroethane ug/L 1.0 ND 12/07/95
1,3-Dichloropropane ug/L 1.0 ND 12/07/95
Tetrachloroethene ug/L 1.0 ND 12/07/95
Dibromochloromethane ug/L 1.0 ND 12/07/95
1,1,1,2-Tetrachloroethane ug/L 1.0 ND 12/07/95
Bromoform ug/L 1.0 ND 12/07/95
1,1,2,2-Tetrachloroethane 1.0 ND 12/07/95
in 1-1-knao
54 Ravenscroft Drive uuVIV 11 1 U wavL../ An Equal Opportunity Employer
Asheville, NC 28801
TEL: [phone]
FAX: [phone] GCbUowatet Section

0

dw , I =I=. -
ENVIRONMENTAL LABORATORIES
Mr. Roger Galloway
Page 8
Client Reference: EI Dupont
REPORT OF LABORATORY ANALYSIS`
December 18, 1995
PACE Project Number: A5112b,
PACE Sample Number:
93 0154069
Date Collected:
11/27/95
Date Received:
11/30/95
Client Sample ID:
Parameter
Units
MDL
Well
R87s7
DATE ANALYZED
ORGANIC ANALYSIS
VOLATILE ORGANICS
1,2,3-Trichloropropane
ug/L
1.0
ND
12/07/95
Bromobenzene
ug/L
1.0
ND
12/07/95
2-Chlorotoluene
ug/L
1.0
ND
12/07/95
4-Chlorotoluene
ug/L
1.0
ND
12/07/95
1,3-Dichlorobenzene
ug/L
1.0
ND
12/07/95
1,4-Dichlorobenzene
ug/L
1.0
ND
12/07/95
1,2-Dichlorobenzene
ug/L
1.0
ND
12/07/95
1,2-Dibromo-3-chloropropane
ug/L
1.0
ND
12/07/95
1,2,4-Trichlorobenzene
ug/L
1.0
ND
12/07/95
Hexachlorobutadiene
ug/L
1.0
ND
12/07/95
1,2,3-Trichlorobenzene
ug/L
1.0
ND
12/07/95
Benzene
ug/L
1.0
ND
12/07/95
Toluene
ug/L
1.0
ND
12/07/95
Chlorobenzene
ug/L
1.0
ND
12/07/95
Ethylbenzene
ug/L
1.0
ND
12/07/95
Xylenes
ug/L
1.0
ND
12/07/95
Styrene
ug/L
1.0
ND
12/07/95
Isopropylbenzene
ug/L
1.0
ND
12/07/95
n-Propylbenzene
ug/L
1.0
ND
12/07/95
1,3,5-Trimethylbenzene
ug/L
1.0
ND
12/07/95
t-Butylbenzene
ug/L
1.0
ND
12/07/95
1,2,4-Trimethylbenzene
ug/L
1.0
ND
12/07/95
s-Butylbenzene
ug/L
1.0
ND
12/07/95
4-Isopropyltoluene
ug/L
1.0
ND
12/07/95
n-Butylbenzene
ug/L
1.0
ND
12/07/95
Naphthalene
ug/L
1.0
ND
12/07/95
54 Ravenscroft Drive An Equal Opportunity Employer
Asheville, NC 28801
TEL: [phone] wateir Section
FAX:[phone] K h onalO�Ce

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® REPORT OF LABORATORY ANALYST,
I N C O R P O R A T E D
THE ASSURANCE OF QUALITY
Mr. Roger Galloway
Page 7
Client Reference: DuPont
December 19, 1994
PACE Project Number: A41115512
PACE Sample Number:
93 0037283
Date Collected:
11/14/94
Date Received:
11/15/94
Client Sample ID:
Monitoring
Well
Parameter
Units
MDL
R87S7
ORGANIC ANALYSIS
VOLATILE ORGANICS
Chloromethane
ug/L
0.5
NO
Bromomethane
ug/L
0.5
NO
Dichlorodifluoromethane
ug/L
0.5
NO
Chloroethene (Vinyl chloride)
ug/L
0.5
NO
Chloroethane
ug/L
0.5
NO
1,1-Dichloroethene
ug/L
0.5
NO
Trichlorofluoromethane
ug/L
0.5
NO
Dichloromethane
ug/L
0.5
NO
trans-1,2-Dichloroethene
ug/L
0.5
NO
1,1-Dichloroethane
ug/L
0.5
NO
2,2-Dichloropropane
ug/L
0.5
NO
cis-1,2-Dichloroethene
ug/L
0.5
NO
Bromochloromethane
ug/L
0.5
ND
Chloroform
ug/L
0.5
NO
Dibromomethane
ug/L
0.5
NO
1,1,1-Trichloroethane
ug/L
0.5
NO
Carbon tetrachloride
ug/L
0.5
NO
1,2-Dichloroethane
ug/L
0.5
NO
1,1,2-Trichloroethene
ug/L
0.5
NO
1,1-Dichloro-l-propene
ug/L
0.5
NO
1,2-Dichloropropane
ug/L
0.5
NO
Bromodichloromethane
ug/L
0.5
NO
trans-1,3-Dichloro-l-propene
ug/L
0.5
NO
cis-1,3-Dichloro-l-propene
ug/L
0.5
NO
1,1,2-Trichloroethane
ug/L
0.5
NO
1,3-Dichloropropane
ug/L
0.5
NO
Tetrachloroethene
ug/L
0.5
NO
Dibromochloromethane
ug/L
0.5
NO
1,1,1,2-Tetrachloroethane
ug/L
0.5
NO
Bromoform
ug/L
0.5
NO
1,2,3-Trichloropropane
ug/L
0.5
NO
54 Ravenscroft Drive An Equal Opportunity Employer
Asheville, NC 28801
TEL:[phone]
FAX:[phone]

0 0

REPORT OF LABORATORY ANALYST,
THE ASSURANCE Of QUALITY
-` Mr. Roger Galloway December 19, 1994
Page 8 PACE Project Number: A411155,
Client Reference: DuPont
PACE Sample Number: 93 0037283
Date Collected: 11/14/94
Date Received: 11/15/94
Client Sample ID: Monitoring
Well
Parameter Units MDL R87S7
ORGANIC ANALYSIS
VOLATILE ORGANICS
1,1,2,2-Tetrachloroethane
ug/L
0.5
ND
Hexachlorobutadiene
ug/L
0.5
ND
Benzene
ug/L
0.5
ND
Toluene
ug/L
0.5
ND
Chlorobenzene
ug/L
0.5
ND
Ethylbenzene
ug/L
0.5
ND
Xylenes
ug/L
0.5
ND
Styrene
ug/L
0.5
ND
Isopropylbenzene
ug/L
0.5
ND
Bromobenzene
ug/L
0.5
ND
n-Propylbenzene
ug/L
0.5
ND
2-Chlorotoluene
ug/L
0.5
ND
4-Chlorotoluene
ug/L
0.5
NO
1,3,5-Trimethylbenzene
ug/L
0.5
ND
t-Butylbenzene
ug/L
0.5
ND
1,2,4-Trimethylbenzene
ug/L
0.5
ND
1,3-Dichiorobenzene
ug/L
0.5
ND
s-Butylbenzene
ug/L
0.5
ND
1,4-Dichlorobenzene
ug/L
0.5
NO
4-Isopropyltoluene
ug/L
0.5
ND
1,2-Dichlorobenzene
ug/L
0.5
ND
n-Butylbenzene
ug/L
0.5
ND
1,2,4-Trichlorobenzene
ug/L
0.5
ND
Naphthalene
ug/L
0.5
ND
1,2,3-Trichlorobenzene
ug/L
0.5
NO
54 Ravenscroft Drive An Equal Opportunity Employer
Asheville, NC 28801
TEL:[phone]
FAX:[phone]

x

iacee REPORT OF LABORATORY ANALYSIS.
6i r n R P r1
THE ASSURANCE OF QUALITY
E.I. DuPont de Nemours & Co., Inc.
P.O. Box 267
Staton Rd. Cedar Mtn.
Brevard, NC 28712
Attn: Mr. Roger Galloway
Client Reference: Monitoring Wells
PACE Sample Number:
Date Collected:
Date Received:
Client Sample ID:
Parameter
INORGANIC ANALYSIS
INDIVIDUAL PARAMETERS
Arsenic
Barium
Biochemical Oxygen Demand, 05 Day
Cadmium
Chemical Oxygen Demand
Chloride
Units
mg/L
mg/L
mg/L
mg/L
mg/L
Chromium mg/L
Copper mg/L
Fluoride, Total Recoverable (Electrode) mg/L
Iron mg/L
Lead mg/L
Manganese, mg/L
December 07, 1994
PACE Project Number: A411155.,
93 0037259 93 0037267 93 0037275
11/14/94 11/14/94 11/14/94
11/15/94 11/15/94 11/15/94
Monitoring Monitoring Monitoring
Well Well Well
MDL R87s3 R87s4 R87s5
(1) (1) (1)
0.005 ND ND ND
0.10 0.839 ND ND
2.0 3.3 ND 5.0
0.001 ND ND ND
5.0 24 12 43
1 6.4 8.0 11
0.020 NO ND ND
0.01 0.010 ND ND
0.1 ND ND ND
0.05 7.86 3.86 29.0
0.005 ND ND ND
0.01 0.974 5.14 17.6
mg/L
0.0002
0.0003
0.0002
0.0003
Mercury
Nitrogen, Ammonia
mg/L
0.1
-
5.8
ND
Nitrogen, Ammonia
mg/L
mg/L
1.0
0.1
52
0.17
0.22
ND
Nitrogen, Nitrate in Wastewater
mg/L
0.005
0.013
0.006
0.014
Phenol
mg/L
0.005
ND
ND
ND
Selenium
Silver
mg/L
0.010
1
ND
120
ND
140
ND
120
Solids, Total Dissolved
mg/L
umhos/cm
10
670
270
140
Specific Conductivity
mg/L
1
2.6
Sulfate
mg/L
2
-
-
9.2
Sulfate
mg/L
5
-
20
Sulfate
Total Organic Carbon
mg/L
mg/L
0.5
0.01
4.0
0.017
3.5
0.022
4.7
ND
Zinc
pH
Units
0.10
6.1
6.7
5.4
An Equal Opportunity Employer
54 Ravenscro(t Drive
Asheville, NC 28801
TEL:[phone]
FAX:[phone]

0

cee
Ad I oaR 0R A T E OREPORT OF LABORATORY ANALY&II
THE ASSURANCE OF QUALITY
Mr. Roger Galloway December 07, 1994
Page 2 PACE Project Number: A41115<:
Client Reference: Monitoring Wells
PACE Sample Number:
93 0037283
93 0037291
93 0037305
Date Collected:
11/14/94
11/14/94
11/14/94
Date Received:
11/15/94
11/15/94
11/15/94
Client Sample ID:
Monitoring
River-
River -
Well
Bridle
Intake
Parameter
Units MDL R87s7
Veil
Dike
— (1)
(1)
(1)
INORGANIC ANALYSIS
INDIVIDUAL PARAMETERS
Arsenic
mg/L
0.005
ND
ND
ND
Barium
mg/L
0.10
ND
ND
ND
Biochemical Oxygen Demand, 05 Day
mg/L
2.0
ND
ND
ND
Cadmium
mg/L
0.001
ND
ND
ND
Chemical Oxygen Demand
mg/L
5.0
3.5
5.6
7.7
Chloride
mg/L
1
3.6
ND
ND
Chromium
mg/L
0.020
ND
ND
ND
Copper
mg/L
0.01
ND
ND
ND
Fluoride, Total Recoverable (Electrode)
mg/L
0.1
ND
ND
ND
Iron
mg/L
0.05
0.393
0.280
0.396
Lead
mg/L
0.005
ND
ND
ND
Manganese
mg/L
0.01
0.168
0.045
0.054
Mercury
mg/L
0.0002
ND
0.0003
ND
Nitrogen, Ammonia
mg/L
0.1
ND
ND
ND
Nitrogen, Nitrate in Wastewater
mg/L
0.1
ND
ND
ND
Phenol
mg/L
0.005
ND
0.006
0.008
Selenium
mg/L
0.005
ND
ND
ND
Silver
mg/L
0.010
ND
ND
ND
Solids, Total Dissolved
mg/L
1
17
18
25
Specific Conductivity
umhos/cm
10
14
15
16
Sulfate
mg/L
1
ND
1.2
ND
Total Organic Carbon
mg/L
0.5
1.8
2.7
2.6
Zinc
mg/L
0.01
0.022
0.026
0.078
pH
Units
0.10
5.2
5.3
5.3
54 Ravenscroft Drive An Equal Opportunity Employer
Asheville, NC 28801
TEL:[phone]
FAX-704-252-4618

0

ce,
R A T E D
THE ASSURANCE OF QUALITY
Mr. Roger Galloway
Page 3
Client Reference: Monitoring Wells
IF' M1D
REPORT OF LABORATORY ANALYSIS'
These data have been reviewed and are approved for release.
ate, m.mIL
Barbara M. Miller
Supervisor, Inorganic Chemistry
J
Sherry L. Ratzlaff
Supervisor, Bioassay Department
December 07, 1994
PACE Project Number: A4111551e.
54 Ravenscroft Drive An Equal Opportunity Employer
Asheville, NC 28801
TEL:[phone]
FAX:[phone]

"'490'aceoc
REPORT OF LABORATORY ANALYST.:
THE ASSURANCE OF QUALITY
Mr. Roger Galloway FOOTNOTES December 07, 1994
Page 4 for pages 1 through 3 PACE Project Number: A411155,
Client Reference: Monitoring Wells
MDL Method Detection Limit
ND Not detected at or above the MDL.
(1) pH analysis exceeded hold time; Results not valid for NPDES Permit monitoring.
54 Ravenscroft Drive An Equal Opportunity Employer
Asheville, NC 28801
TEL:[phone]
FAX:[phone]

0

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A10 a N C O R P o R A T E CeSC'
REPORT OF LABORATORY ANALYST,
THE ASSURANCE OF QUALITY
Mr. Roger Galloway
Page 2
Client Reference: PB2555
PACE Sample Number:
Date Collected:
Date Received:
Client Sample ID:
Parameter
INORGANIC ANALYSIS
December 16, 1993
PACE Project Number: A31116,
93 0157572 93 0157580 93 0157599
11/15/93
11/15/93
11/15/93
11/16/93
11/16/93
11/16/93
Well
River
River
R87s7
Bridle
Intake
Units MDL
Veil
Dike
INDIVIDUAL PARAMETERS
Arsenic
mg/L-
0.001
ND
ND
ND
Barium
mg/L
0.10
0.40
ND
ND
Biochemical Oxygen Demand, 05 Day
mg/L
1.0
ND
ND
ND
Cadmium
mg/L
0.001
ND
ND
ND
Chemical Oxygen Demand
mg/L
5.0
9.8
ND
NO
Chloride
mg/L
1
ND
2.4
1.4
Chromium
mg/L
0.02
ND
ND
ND
Copper
mg/L
0.01
0.013
ND
ND
Fluoride, Total Recoverable (Electrode)
mg/L
0.1
ND
ND
ND
Iron
mg/L
0.05
2.5
0.33
0.56
Lead
mg/L
0.05
ND
ND
ND
Manganese
mg/L
0.01
0.46
ND
0.068
Mercury
mg/L
0.0002
ND
ND
ND
Nitrogen, Ammonia
mg/L
0.05
ND
ND
ND
Nitrogen, Nitrate
mg/L
1
ND
ND
ND
Phenol
mg/L
0.0060
0.014
ND
ND
Selenium
mg/L
0.001
ND
ND
ND
Silver
mg/L
0.01
ND
ND
ND
Solids, Total Dissolved
mg/L
1
48
30
40
Specific Conductivity
umhos/cm
1.0
24
19
20
Sulfate
mg/L
1
ND
ND
1.2
Total Organic Carbon
mg/L
0.50
1.1
2.3
2.5
Zinc
mg/L
0.01
ND
ND
ND
PH
Units
0.10
5.4
6.0
5.8
54 Ravenscroft Drive
Offices Serving: Minneapolis, Minnesota
Charlotte, North Carolina An Equal Opportunity Employer
Asheville, NC 28801
Tampa, Florida
Asheville, North Carolina
TEL: [phone]
Iowa City, Iowa
New York, New York
FAX: [phone]
San Francisco, California
Pittsburgh, Pennsylvania
Kansas City, Missouri
Denver, Colorado
Los Angeles, California

m
0

lq J
'04-a o® REPORT OF LABORATORY ANALYSIS
THE ASSURANCE OF QUALITY
Mr. Roger Galloway
Page 7
Client Reference: DuPont
December 17, 1993
PACE Project Number: A311169.
PACE Sample Number: 93 0157572
Date Collected: 11/15/93
Date Received: 11/17/93
Client Sample ID: Well
Parameter Units MDL R87s7 DATE ANALYZED
ORGANIC ANALYSIS
VOLATILE ORGANICS
Chloromethane
ug/L
0.5
ND
11/21/93
Bromomethane
ug/L
0.5
ND
11/21/93
Dichlorodifluoromethane
ug/L
0.5
ND
11/21/93
Chloroethene '(Vinyl chloride)
ug/L
0.5
ND
11/21/93
Chloroethane
ug/L
0.5
ND
11/21/93
1,1-Dichloroethene
ug/L
0.5
ND
11/21/93
Trichlorofluoromethane
ug/L
0.5
ND
11/21/93
Dichloromethane
ug/L
0.5
ND
11/21/93
trans-1,2-Dichloroethene
ug/L
0.5
ND
11/21/93
1,1-Dichloroethane
ug/L
0.5
ND
11/21/93
2,2-Dichloropropane
ug/L
0.5
ND
11/21/93
cis-1,2-Dichloroethene
ug/L
0.5
ND
11/21/93
Bromochloromethane
ug/L
0.5
ND
11/21/93
Chloroform
ug/L
0.5
ND
11/21/93
Dibromomethane
ug/L
0.5
ND
11/21/93
1,1,1-Trichloroethane
ug/L
0,5
ND
11/21/93
Carbon tetrachloride
ug/L
0.5
ND
11/21/93
1,2-Dichloroethane
ug/L
0.5
ND
11/21/93
1,1,2-Trichloroethene
ug/L
0.5
ND
11/21/93
1,1-Dichloro-1-propene
ug/L
0.5
ND
11/21/93
1,2-Dichloropropane
ug/L
0.5
ND
11/21/93
Bromodichloromethane
ug/L
0.5
ND
11/21/93
2-Chloroethoxyethane
ug/L
0.5
ND
11/21/93
trans-1,3-Dichloro-1-propene
ug/L
0.5
ND
11/21/93
cis-1,3-Dichloro-l-propene
ug/L
0.5
ND
11/21/93
1,1,2-Trichloroethane
ug/L
0.5
ND
11/21/93
1,3-Dichloropropane
ug/L
0.5
ND
11/21/93
Tetrachloroethene
ug/L
0.5
ND
11/21/93
Dibromochloromethane
ug/L
0.5
ND
11/21/93
1,1,1,2-Tetrachloroethane
ug/L
0.5
ND
11/21/93
Bromoform
ug/L
0.5
ND
11/21/93
54 Ravenscroft Drive
Offices Serving: Minneapolis, Minnesota
Charlotte, North Carolina An Equal Opportunity Employer
Asheville, NC 28801
Tampa, Florida
Asheville, North Carolina
TEL: [phone]
Iowa City, Iowa
New York, New York
FAX: [phone]
San Francisco, California
Pittsburgh, Pennsylvania
Kansas City, Missouri
Denver, Colorado
Los Angeles, California

0

0 R A T E 0® REPORT OF LABORATORY ANALYST,
THE ASSURANCE OF QUALITY
Mr. Roger Galloway
Page 8
Client -Reference: DuPont
December 17, 1993
PACE Project Number: A311165.
PACE Sample Number: 93 0157572
Date Collected: 11/15/93
Date Received: 11/17/93
Client Sample ID: Well
Parameter Units MDL R87s7 DATE ANALYZED
ORGANIC ANALYSIS
VOLATILE ORGANICS
1,2,3-Trichloropropane
ug/L
0.5
ND
11/21/93
1,1,2,2-Tetrachloroethane
ug/L
0.5
ND
11/21/93
Hexachlorobutadiene
ug/L
0.5
ND
11/21/93
Methyl-t-butyl ether
ug/L
0.5
ND
11/21/93
Benzene
ug/L
0.5
ND
11/21/93
Toluene
ug/L
0.5
ND
11/21/93
Chlorobenzene
ug/L
0.5
ND
11/21/93
Ethylbenzene
ug/L
0.5
ND
11/21/93
Xylenes
ug/L
0.5
ND
11/21/93
Styrene
ug/L
0.5
ND
11/21/93
Isopropylbenzene
ug/L
0.5
ND
11/21/93
Bromobenzene
ug/L
0.5
ND
11/21/93
n-Propylbenzene
ug/L
0.5
ND
1`1/21/93
2-Chlorotoluene
ug/L
0.5
ND
11/21/93
4-Chlorotoluene
ug/L
0.5
ND
11/21/93
1,3,5-Trimethylbenzene
ug/L
0.5
ND
11/21/93
t-Butylbenzene
ug/L
0.5
ND
11/21/93
1,2,4-Trimethylbenzene _
ug/L
0.5
ND
11/21/93
1,3-Dichlorobenzene
ug/L
0.5
ND
11/21/93
s-Butylbenzene
ug/L
0.5
ND
11/21/93
1,4-Dichlorobenzene
ug/L
0.5
ND
11/21/93
4-Isopropyltoluene
ug/L
0.5
ND
11/21/93
1,2-Dichlorobenzene
ug/L
0.5
ND
11/21/93
n-Butylbenzene
ug/L
0.5
ND
11/21/93
1,2,4-Trichlorobenzene
ug/L
0.5
ND
11/21/93
Naphthalene
ug/L
0.5
ND
11/21/93
1,2,3-Trichlorobenzene
ug/L
0.5
ND
11/21/93
54 Ravenscroft Drive
Offices Serving: Minneapolis, Minnesota
Charlotte, North Carolina An Equal Opportunity Employer
Asheville, NC 28801
Tampa, Florida
Asheville, North Carolina
TEL: [phone]
Iowa City, Iowa
New York, New York
FAX: [phone]
San Francisco, California
Pittsburgh, Pennsylvania
Kansas City, Missouri
Denver, Colorado
Los Angeles, California

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0

ARTMENT OF NATURAL �X)RCEs AND COMMUNITY DEVELopf 7JT
.�' ENVIRONMENTAL MANAC6 ` :�iT - GROUNDWATER t tCT10tV
`' FOR OFFiCt
j BOX 27687-RALEIGH,N.C. 27e11. PHONE (919) 733-aoa3
►��l7
Quad. No. I 1 7 s
Lat.3.5' / I a 8 Long. $�
Minor Basin
WELL CONSTRUCTION RECORD
Basin Code
Header Ent. GW-1 Ei,
DRILLING CONTRACTOR Westinghouse Environmental
DRILLER REGISTRATION NUMBER 412
STATE WELL CONST UCTIONy
PERMIT NUMBER: 7- a •
001 tA�%�I�-E���
1. WELL LOCATION: (Show sketch of the location below)
Nearest Town: Brevard, NC - Highway 64
County: Transylvania
Depth DRILLING LOG
(Road, Community, or Subdivision and Lot No.)
2. OWNER Dupont
From
ETA Formation Description
Top Soil
ADDRESS PO Box 267
4'f 10, Tan Sand with some silt
(Street or Route No.)
Brevard NC 28712
101 52.5 Partially Weathered Rock
City or Town State Backg7xi�ble
25.5' 36' Tan Moist Sand
3. DATE DRILLED 7/7/88 USE OF WELL Water Quality
4. TOTAL DEPTH 36.5 CUTTINGS COLLECTED ❑ Yes 0 No
NOTE: Log is from auger
5. DOES WELL REPLACE EXISTING WELL? ❑ Yes FK1 No
cuttings. No split
6. STATIC WATER LEVEL: -3 �� FT. O above TOP OF CASING,
Spoons were taken
O below
TOP OF CASING IS 2 FT. ABOVE LAND SURFACE.
7. YIELD (gpm): N/A METHOD OF TEST N/A
8. WATER ZONES (depth): 25.5
9. CHLORINATION: Type N/A Amount N/A
In CASING
n.`11
W
�1110
Wall Thickness
If additional s
via°-u'sel`
Depth
Diameter or Weight/Ft. Material
From 0.0
To
25.5 Ft.
211 Sch 40 PVC
LOCATION SKETCH
(Show direction and distance from at least two State Roads,
From
To
Ft.
or other map reference points)
From
To
Ft.
11. GROUT:
Depth
Material Method
From 0.0
To 25.5 Ft.
Grout/Bentonite- Tremy Pipe
y
From
To
Ft.
u
12. SCREEN:
Depth
Diameter Slot Size Material
From 25.5
To
35.5 Ft.
2" in. 0. 010 in. PVC
y
From
To
Ft.
in. in.
From
To
Ft.
in. in.4
13. GRAVEL PACK:
Yl
r.tL
Depth
Size_ Material
From 20.0
To
36.0 Ft.
Torpedo Sand
r. f�
From
To
Ft
i r
14. REMARKS:
d(1
C/
�/� C1itu/a�
qr
L•
�C?) 3
1f �► �
/
1 DO HEREBY CERTIFY THAT
THIS WELL WAS CONSTRUCTED IN ACCQRDANCE WITH 15 NCAC 2C, WELL CONSTRUE
STANDARDS,
AND THAT A COPY OF THIS RECOS BEEN PROVIDED TO THE WELL OWNER.,
(,W-1 0—i-4 t t 10A
51GNA�ClHF0F CONTRACTOR OR AGENT DATE
Cnhmit nri nin aJ to nivicinn of GnvirnnmcnMl �A�nonomnM �nrt nn n„ to u,cll

i _
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�,
•,
`\
`_...\
4 � :' Y � i.
',S
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r '
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0
s
.� 2120
„I j \ F'\--,?�
"
OnQ /
1G Cem `�' �
T
U
t �
woo � l
sta J�!n natee
,, B dry / � ,, ��� J -1l�- ��{ �'\� _ .,�i`� -�%- ' �� �•;'�.
1 '
8� dat V I i
x`��071
r
i� Y ;�IS�`�. �` ! J T i �0 �� i
` I
jw
,<e00
�A,
1�0 - , �--J I J;:_ ��� �� Q yip }• �� _- Chbr
I ao0o ( 1 ke �r fix, Zy` !v r
1
i

NOTE TO FILE
Agfa reported COD as 290 mg/1 on the 11/23/03 sample date for monitor well R87s7. ARO split
samples with the facility on this date and reported 20 mg/1 for the same parameter.
On 3/30/04, Gary Francies examined the bench sheet at Pace, Inc. for this sampling event and
did not note any lab errors in reporting this data.
Ann Rumbough

0 0

WELL NO.: R87s7
AGFA CORPORATION
l
COUNTY: TRANSYLVAN,,
DATE SAMPLED
ALKALINITY,TO pH 4.5
47-03
r/-1.2 -.0
ALKALINITY,TO pH 8.3
ALUMINUM
ARSENIC
BARIUM
BERYLLIUM
BICARBONATE
CADMIUM
CALCIUM
CARBONATE
CHLORIDE
CHROMIUM,TOTAL
COBALT
COD
130
COLIFORM, FECAL
COLIFORM, TOTAL
COPPER
CYANIDE
DISSOLVED SOLIDS
FLUORIDE
DNEaCo3
tHARDNE]SSE,NONGARB HJ���
IRON
LEAD
LITHIUM
MBAS
MAGNESIUM
MANGANESE
MERCURY
NICKEL
NITROGEN, AMMONIA
NITROGEN, KJELDAHL
NITRATE & NITRITE
0.03
0 n o 1
- a. e o
ORGANIC SCAN
ORTHOPHOSPHATE
pH
9�
5A. 9�7
S. 8
_ 44
PHENOLS
'o. o to u
0. 0 o
PHOSPHORUS, TOTAL
0.43
o• ao
POTASSIUM
SELENIUM
SILVER
r 0 00A
o.00.!5 tA
O-o®s
1o, ay.2a
v. 0v. "u
- o= 002-0
SODIUM
SPECIF. CONDUCTANCE
SULFATE
x
..Su
A
TOC (UNFILTERED)
X
TOX
TSS
voC
N
L2
ZINC
STATIC WATER LEVEL
30• %`
20,7
9. i
l
�
•' r
Red Ink=Sample taken by facility
4 IjSt4r-FtC REN"i' v./A'rER Go A+-5AMft6,
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DATE SAMPLED
ALKALINITY, TO pH 4.5
ALKALINITY, TO PH 8.3
ALUMINUM
ARSENIC
BARIUM
BERYLLIUM
BICARBONATE
CADMIUM
CALCIUM
CARBONATE
CHLORIDE
CHROMIUM, TOTAL
COBALT
COD
L f (,
Yy e
COLIFORM, FECAL
COLIFORM, TOTAL
COPPER
CYANIDE
DISSOLVED SOLIDS
3
f / o
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HARDNESS CaCo3
HARDNESS, NON CARB
IRON
LEAD
LITHIUM

0 0

COUNTY: -7-1,�,41vS yL V 41VII4
DATE SAMPLED
. co
1-2 7,
MBAS
MAGNESIUM
MANGANESE
MERCURY
NICKEL
NITROGEN, AMMONIA
0 , Q
NITROGEN, KJELDA14L
NITRATE & NITRITE
0,03
ORGANIC SCAN
FH
D
�. 6
PHENOLS
4°
. "%
PHOSPHORUS, TOTAL
0.06
POTASSIUM
SELENIUM
SILVER
o. vos
O cc;7
SODIUM
SPECIIa. CONDUCTANCE
SULFATE
TOC (UNFILTERED)
TOX
TSS
VOC
ZINC
STATIC WATER LEVEE,
j3o-ss-'j,3o--5--5'
Red lick = Sample taken by facility

0 0

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DATE SAMPLED4-gl /l-� q
q
ALKALINITY, TO pH 4.5
ALKALINITY, TO pH 8.3
ALUMINUM
ARSENIC
BARIUM
BERYLLIUM
BICARBONATE
CADMIUM
CALCIUM
CARBONATE
CHLORIDE
CHROMIUM, TOTAL
-
COBALT
COD
COLIFORM, FECAL
COLIFORM, TOTAL
COPPER
CYANIDE
DISSOLVED SOLIDS
FLUORIDE
HARDNESS CaCo3
HARDNESS, NON CARB
IRON
LEAD
LITHIUM
Red Ink = Sample taken by facility
-t WLLL O/zy

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WELL NO. 9 8 7 S % COUNTY: 72.4 Ivs x Vl-i N 1.4
DATE SAMPLED
MBAS
MAGNESIUM
MANGANESE
MERCURY
NICKEL
NITROGEN, AMMONIA
0 •
c �6.
NITROGEN, KJELDAHL
NITRATE & NITRITE
ORGANIC SCAN
PH
PHENOLS
PHOSPHORUS, TOTAL
POTASSIUM
SELENIUM
SILVER
SODIUM
SPECIF. CONDUCTANCE
SULFATE
TOC (UNFILTERED)
TOX
TSS
VOC
ZINC
STATIC WATER LEVEL
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DATE SAMPLED
ALKALINITY, TO pH 4.5
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ALUMINUM
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BARIUM
o _
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BICARBONATE
CADMIUM
4,
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CALCIUM
CARBONATE
CHLORIDE
CHROMIUM, TOTAL
4 (9-2
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Lab Sample No: 923533418
Client Sample ID:,R87S7
Parameters
Pace Analytical s,,
2225 Riv6.
Asheville, Nt._
Phone: 828.254..
Fax: [phone]c
Lab Project Number: 9254148
Client Project ID: MONITORING WELLS
Project Sample Number: 9254148-004 Date Collected: 11/12/03 12:50
Matrix: Water Date Received: 11/13/03 16:08
Results Units Report Limit Analyzed By CAS No. Qual RegLmt
Client Services
Nitrogen, Total Method:
Nitrogen 0.94 mg/l 0.20 11/26/03 UP 7727-37-9
Metals
Trace,lCP Metals
Prep/Method:
/ EPA 200.7
Si l-v 'r` `
NO
mg/l
D"ate Digested
11/14/03
Wet Chemistry
Total Dissolved Solids
Method: EPA
160.1
Total Dissolved Solids
NO
mg/l
Ammonia
Method: EPA
350.1
Nitrogen, Ammonia
NO
mg/l
Total Kjeldahl Nitrogen
Method: EPA
351.2
Nitrogen, Kjeldahl, Total
0.78
mg/l
Nitrogen, Nitrate/Nitrite
Method: EPA
353.2
Nitrate -Nitrite (as N)
0.16
mg/l
Nitrate as N
NO
mg/l
Phosphorus, Total
Method: EPA
365.2
Phosphorus
_0.400
mg/l
Sulfate,Automated Colorimetric
Method: EPA
375.4
Sulfate
NO
mg/l
Chemical Oxygen Demand
Method: EPA
410.4
Chemical Oxygen Demand
290
mg/l
Phenolics, Total Recoverable
Method: EPA
420.1
Phenolics, Total Recoverable
0.020
mg/l
Total Organic Carbon
Method: SM 5310B
Total Organic Carbon
NO
mg/l
Date: 11/26/03
0.0020 11/21/03 23:23 LBG 7440.22-4
11/14/03
20.
11/15/03
KHJ
0.10
11/14/03
LTH 7727-37-9
0.10
11/18/03
BKS
0.050
11/14/03
SHB 7727-37-9
0.050
11/14/03
SHB
0.100 11/15/03 WWB 7723-14-0
5.0 11/20/03 WWB
25. 11/19/03 BMF
0.0050 11/19/03 LTH
0.50 11/24/03
LTH 7440-44-0
REPORT OF LABORATORY ANALYSIS
Asheville Certification IN This report shall not be reproduced, except in full, _
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc.
NC Drinking Water 37712 N ACCpgO
SC Environmental 99030
F1 NEL AP FR764R
Page: 10 of 31
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FI N1E1 AD EA7627

0 0

Pace Analytical a.
2225 Rivo.
Asheville, N,
Phone., 828.254.,
Fax, 828.252.4L
Lab Project Number: 9254148
Client Project ID: MONITORING WELLS
Lab Sample No: 923533418 Project Sample Number: 9254148-004 Date Collected: 11/12/03 12:50
Client Sample ID: R87S7 Matrix: Water Date Received: 11/13/03 16:08
Parameters _ __
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
GC Volatiles
GC VOCs in Water
Method: SM
6230D
Benzene
NO
ug/l
0.50
11/21/03
00:24
STC
71-43-2
Bromobenzene,,,
NO
ug/1
0.50
11/21/03
00:24
STC
108-86-1
Bromochlortmethane
NO
ug/l
0.50
11/21/03
00:24
STC
74-97-5
Bromo'dichloromethane
NO
ug/l
0.50
11/21/03
00:24
STC
75-27-4
Br6moform
NO
ug/l
0.50
11/21/03
00:24
STC
75-25-2
s Bromomethane
NO
ug/l
0.50
11/21/03
00:24
STC
74.83-9
n-Butylbenzene
NO
ug/l
1.0
11/21/03
00:24
STC
104-51-8
sec-Butylbenzene
ND'
ug/1
0.50
11/21/03
00:24
STC
135-98-8
tert-Butylbenzene
NO
ug/l
0.50 _11/21/03
00:24
STC
98-06-6
Carbon tetrachloride
NO
ug/l
0.50
11/21/03
00:24
STC
56-23-5
Chlorobenzene
NO
ug/l
0.50
11/21/03
00:24
STC
108-90-7
Chloroethane-
NO
ug/l
0.50
11/21/03
00:24
STC
75-00-3
Chloroform
ND
ug/l
0.50
11/21/03
00:24
STC
67-66-3
Chloromethane
ND
ug/l
2.0
11/21/03
00:24
STC
74-87-3
2-Chlorotoluene
ND
ug/l
0.50
11/21/03
00:24
STC
95-49-8
4-Chlorotoluene
ND
ug/l
0.50
11/21/03
00:24
STC
106-43-4
1,2-Dibromo-3-chloropropane
NO
ug/l
2.0
11/21/03
00:24
STC
96-12-8
Dibromochloromethane
ND
ug/l
0.50
11/21/03
00:24
STC
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/l
0.50
11/21/03
00:24
STC
106-93-4
Dibromomethane
ND
ug/l
0.50
11/21/03
00:24
STC
74-95-3
1,2-Dichlorobenzene
NO
ug/l
1.0
11121/03
00:24
STC
95-50-1
1,3-Dichlorobenzene
ND
ug/l
1.0
11/21/03
00:24
STC
541-73-1
1,4-Dichlorobenzene
ND
ug/l
1.0.
11/21/03
00:24
STC
106-46-7
Dichlorodifluoromethane
ND
ug/l
0.50
11/21/03
00:24
STC
75-71-8
1,1-Dichloroethane
NO
ug/l
0.50
11/21/03
00:24
STC
75-34-3
1,2-Dichloroethane
NO
ug/1
0.50
11/21/03
00:24
STC
107-06-2
!,I-Dichloroethene
NO
ug/l
0.50
11/21/03
00:24
STC
75-35-4
cis-1,2-Dichloroethene
NO
ug/l
0.50
11/21/03
00:24
STC
156-59-2
trans-1,2-Dichloroethene
ND
ug/l
0.50
11/21/03
00:24
STC
156-60-5
1,2-Dichloropropane
ND
ug/l
0.50
11/21/03
00:24
STC
78-87-5
1,3-Dichloropropane
NO
ug/l
0.50
11/21/03
00:24
STC
142-28-9
2,2-Dichloropropane
NO
ug/l
0.50
11/21/03
00:24
STC
594-20-7
1,1-Dichloropropene
NO
ug/l
0.50
11/21/03
00:24
STC
563-58-6
cis-1,3-Dichloropropene
NO
ug/l
0.50
11/21/03
00:24
STC
10061-01-5
trans-1,3-Dichloropropene
NO
ug/l
0.50
11/21/03
00:24
STC
10061-02-6
Diisopropyl ether
NO
ug/l
0.50
11/21/03
00:24
STC
108.20-3
Ethylbenzene
NO
ug/l
0.50
11/21/03
00:24
STC
100-41-4
Date: 11/26/03
Page: 11 of 31
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs
This report shall not be reproduced, except in full,
Charlotte Certification IN
NC Wastewater
40
without the written consent of Pace Analytical Services, Inc.
NC Wastewater 12
NC Drinking Water
37712
N A �oqo
NC Drinking Water 37706
SC Environmental
99030
Sc 99006
FL NELAP
E87648
FL RIM AD EQza��
Q, �,

0

Lab Sample No: 923533418
Client Sample ID: R87S7
. Pace Analytical S,
2225 Rive,
Asheville, NL
Phone: 828.254:.
Fax: [phone]r,
Lab Project Number: 9254148
Client Project ID: MONITORING WELLS
Project Sample Number: 9254148-004 Date Collected: 11/12/03 12:50
Matrix: Water Date Received: 11/13/03 16:08
►rameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Hexachloro-1,3-butadiene-
ND
ug/l
2.0
11/21/03
00:24
STC
87-68-3
Isopropyl benzene (C-6mehe)
ND
ug/l
0.50
11/21/03
00:24
STC
98-82-8
p-Isopropyltoluene '
NO
ug/l
1.0
11/21/03
00:24
STC
99-87-6
Methylene chloride
ND
ug/l
2.0
11/21/03
00:24
STC
75-09-2
Methyl-tert butyl ether
ND
ug/l
0.50
11/21/03
00:24
STC
1634-04-4
Naphthalene
ND
ug/l
2.0
11/21/03
00:24
STC
91-20-3
n Prppylbenzene
ND
ug/l
0.50
11/21/03
00:24
STC
103-65-1
Siyrene
ND
ug/l
0.50
11/21/03
00:24
STC
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/l
0.50
11/21/03
00:24
STC
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/l
0.50
11/21/03
00:24
STC
79.34-5
Tetrachloroethene
ND
ug/l
0.50
11/21/03
00:24
STC
127-18-4
Toluene
ND
ug/l
0.50
11/21/03
00:24
STC
108-88-3
1,2,3-Trichlorobenzene
ND
ug/l
2.0
11/21/03
00:24
STC
87.61-6
1,2,4-Trichlorobenzene
NO
ug/l
2.0
11/21/03
00:24
STC
120-82-1
1,1,1-Trichloroethane
ND
ug/l
0.50
11/21/03
00:24
STC
71-55-6
1,1,2-Trichloroethane
ND
ug/l
0.50
11/21/03
00:24
STC
79.00-5
Trichloroethene
ND
ug/l
0.50
11/21/03
00:24
STC
79-01-6
Trichlorofluoromethane
ND
ug/l
0.50
11/21/03
00:24
STC
75-69-4
1,2,3-Trichloropropane
NO
ug/l
0.50
11/21/03
00:24
STC
96-18-4
1,2,4-Trimethylbenzene
ND
ug/l
0.50
11/21/03
00:24
STC
95-63-6
1,3,5-Trimethylbenzene
NO
ug/l
0.50
11/21/03
00:24
STC
108-67-8
Vinyl chloride
ND
ug/l
0.50
11/21/03
00:24
STC
75-01-4
m&p-Xylene
ND
ug/l
0.50
11/21/03
00:24
STC
o-Xylene
NO
ug/l
0.50
11/21/03
00:24
STC
95-47-6
1-Chloro-3-fluorobenzene (S)
128
%
11/21/03
00:24
STC
625-98-9
Date: 11/26/03
REPORT OF LABORATORY ANALYSIS
Page: 12 of 31
Asheville Certification IN
This report shall not be reproduced, except in full,
Charlotte Certification IDs
NC Wastewater
40
without the written consent of Pace Analytical Services, Inc.
NC Wastewater
12
NC Drinking Water
37712
�4"F
NC Drinking Water
37706
SC Environmental
99030
0
Sc
99006
FI NFI AP
E87648
1 ���'
FL NELAP
EQ7627

0 0

PARAMETER FOOTNOTES
Inorganic Wet_.Chemistry and Metals Analyses were performed at our Pace Asheville laboratory and Organic
testing was,,per',formed at our Pace Charlotte laboratory unless otherwise footnoted.
ND Not detecfed-gat or above adjusted reporting limit
NC Not Calculable
J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
urrogate
Date: 11/26/03
REPORT OF LABORATORY ANALYSIS
Page: 13 of 31
Asheville Certification IN This report shall not be reproduced, except in full, Charlotte Certification IN
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc. NC Wastewater 12
NC Drinking Water 37712 a ,N A��oRo9 NC Drinking Water 37706
SC Environmental 99030 �N t F Sc 99006
FL NEI AP ER7AAA 1 IPIe1��_ FI nfFl AP FR707

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Pace Analytical ,
laceAliafyt�caf® °
2225 Rive
Asheville, h.
`
Phone: 828.25s,
www.pacelabs.com -
Lab Project Number: 9334534
Fax: [phone],
Client Project ID: WELL ANALYSIS
Lab Sample No: 931407290
Client Sample ID: WELL R87S7
Bioassay
pH
pH
Metals
ICP Metals
Silver
_ Project Sample Number: 9334534-004 Date Collected: 11/20/02 13:25
Matrix: Water Date Received: 11/21/02 15:00
�r
r°
esults Units Report Limit Analyzed By CAS No. Qual Re Lmt
Method: EPA 150.1
6.10 units 11/26/02 KAS 1
evel Prep/Method: EPA 3010 / EPA 200.7
ND mg/l 0.0020 12/04/02 16:50 EWS 7440-22-4
Date D,gested 11/25/02 11/25/02
Chemistry
Total Dissolved Solids
Method:
EPA
160.1
Total Dissolved Solids
54.
mg/l
Ammonia
Method:
EPA
350.1
Nitrogen, Ammonia
ND
mg/l
Nitrogen, Nitrate plus Nitrite
Method:
EPA
353.3
Nitrogen, Nitrite
ND
mg/l
,'Nitrogen, Nitrate
NO
mg/l
Sulfate,Automated Colorimetric
Method:
EPA
375.2
---Sul fate- _ _-_ ---_ -_- _ ___
5-.2__
Chemical Oxygen Demand
Method:
EPA
410.4
Chemical Oxygen Demand
ND
mg/1
Phenolics, Total Recoverable
Method:
EPA
420.1
Phenolics, Total Recoverable
0.00920
mg/l
Total Organic Carbon
Method:
EPA
9060
Total Organic Carbon
11.
mg/l
Date: 12/12/02
10. 11/25/02 WCB
0.100 11/24/02 WWB 7727-37-9
0.10
12/06/02
ALA
0.10
12/06/02
ALA
5.-0------
12/07/-02 --_
__ALA_._---_____--- -_
50.
11/26/02 '
EWS
0.00500 12/07/02 ALA
0.50 12/12/02
WWB 7440-44-0
GROUNDWATER SECTION Page
ASHEVILLE REGIONAL OFFICE
4of5
Laboratory Certification IN REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
NC Wastewater 40 Ths report shad not be reproduced, except in full, TN Drinking Water 02980
i
NC Drinking Water 37712 SC Environmental 99030
without the written consent of Pace Analytical Services, Inc.
aW �� ca

0

.2 FROM:PACE ANALYTICAL
4 ,,
ls^zsvr�s�+9'i
Lab samplA No: 931407290
Client Sample ID: WELL R87S7
MAITA ID:6282524619
v 9800 Kinsey A.
NUnte OB
Mone: 704..
Far 70481.
Lab Project Ntrmber: 9238890
Client Project ID: Agfa/9334534
Project Sample Number: 9238890-004 Date Collected: 11/20/02 13:25
Matrix: Water Date Received: 11/21/02 15:00
Parameters
30wilts
Units ReRort Limit
DR
_Analyzed
By
C" xo_ Oual g�gjy�D
GC Volatiles
GC VOCs in Water
Method:
SH 6230D
Benzene
ND
ug/l
0.50
1.0
11/26/02
18:52
STC
71-43-2
Bromobenzane
ND
ug/1
0.50
1.0
11/26/02
18:52
STC
108-86-1
Bromochloromethaue
ND
ug/1
0.50
1.0
11/26/02
18:52
STC
74-97-5
Bromodicbloromethane
ND
ag/1
0.50
1.0
11/26/02
18:52
STC
75-27.4
Bromoform
ND
ug/1
0-50
1.0
11/26/02
18:52
STC
75-25-2
Bromomethane
ND
ug/l
0.50
1.0
11/26/02
18:52
STC
74-83-9
n-Butylbenzene
ND
ug/l
1.0
1.0
11/26/02
18:52
STC
104-51-8
sec-Butylbenzene
ND
ug/1
0.50
1.0
11/26/02
18:52
STC
135-99-8
tart-Butylbenzene
ND
ug/l
0.50
1.0
11/26/02
18:52
STC
98-06-6
Carbon tetrachloride
XD
ug/l
0.50
1.0
11/26/02
18:52
STC
56-23-5
Chlorobenzene
ND
ug/1
0.50
1.0
11/26/02
18:52
STC
108-90-7
Chloroethane
ND
ug/1
0.50
1.0
11I26/02
18:52
ETC
75-00-3
Chloroform
ND
ag/1
0.50
1.0
11/26/02
18.52
STC
67-66-3
Chloromethane
ND
ug/1
2.0
1.0
11/26/02-18:52
ETC
74-87-3
2-Chlorotoluena
ND
ug/l
0.50
1.0
12/26/02
18-52
STC
95-49-8
4-ChlorotolueaO
ND
ugil
0-50
1.0
11/26/02
18:52
STC
106-43.4
1,2-Dibromo-3-chloropropane
ND
ug/1
2.0
1.0
11/26/02
18:52
STC
96-12.8
Dibromochloromethane
ND
ug/l
0.50
1.0
11/26/02
18:52
STC
124-49-1
1,2-Dibromoeth3ne (EDB)
ND
ug/1
0.50
1.0
11/26/02
18:52
STC
106-93-4
Dibromomethane
ND
ug/1
0.50
1.0
11/26/02
18:52
STC
74-95-3
1,2-Dichlorobenzene
ND
ug/1
1.0
1.0
11/26/02
18:52
STC
95-50-1
1,3-Dichlorabenzene
ND
ug/l
2.0
1.0
11/26102
18:52
STC
541-73-1
1,4-Dichlorobenze11e
ND
ug/l
1.0
1.0
11/26/02
19:52
STC
106-46-7
Dichlorodifluoromethane
ND
ug/l
0.50
1.0
11/26/02
18:52
STC
75-71-8
1,1-Diehioroethane
ND
ng/1
0.50
1.0
11/26/02
18:52
STC
75-34.3
1,2-Dichloroethane
ND
ag/1
0.50
1.0
11/26/02
18:52
STC
107-06-2
1,1-Dichloroethene
ND
ag/1
0.50
1.0
11/26/02
16:52
STC
75-35-4
cis-1,2-Dichloroethens
ND
ug/l
0.50
1.0
11/26/02
1.8:52
STC
156-59-2
trans- l,2-Dichloroethene
ND
ag/l
0.50
1.0
11/26/02
18:52
STC
156-60-5
1,2-Dichloropropane
ND
ug/i
0.50
1.0
11/26/02
18:52
STC
78-87-5
1,3-Dichloropropane
ND
ug/1
0.50
1.0
11/26/02
18:52
STC
142-28-9
2,2-Dichloropropane
ND
ug/l
0.50
1.0
11/26/02
18:52
ETC
594-20-7
1,1-Dichloropropene
ND
ug/1
0.50
1.0
11/26/02
18.52
ETC
563-58-6
cis-1,3-Dichloropropene
ND
ug/1
0.50
1.0
11/26/02
18:52
STC
10061-01-5
trans-1,3-Diohloropropene
ND
ng/1
0.50
1.0
11/26/02
18:52
STC
10061-02-6
Diisopropyl ether
ND
ug/i
0.50
1.0
11/26/02
18:52
STC
lDS-20-3
Ethylbenzene
IM
ug/l
0.50
1.0
11/26/02
18:52
STC
100-41-4
Data: 12/03/U2
,rrtificeFon IDs
NC Wastewater 12
NC Drinking Wamr 37706
cr: aaW
REPORT OF LABORATORY ANA=
This reportsW not be repmdumd, axcept in lull.
wimom the written consent of Pace k aNficat Services, Inc
GROUND'v'VrJER S
;HEVILLE REQ
KY Drinking Water 90090
VA Drinking Water . 213
FL NEtAP 6876Z7

12 FROM=PACE ANALYTICAL
asszzssu�.��t'i
Lab Sample No: 931407290
Client Sample ID: WELL R8757
MAITA ID=B2B2524618
f 9800 Kinaey
NUn&sv,
Phone: b..
Fax.- 704.e.
Lab Project Number: 9238090
Client Project ID: Agfa/9334534
Project Sample Number: 92388SO-004 Date Collected: 11/20/02 13:25
Matrix: Water Date Received: 11/21/02 15:00
Parameters
Rexachloro-1,3-butadiene
Results
Units
RtRort Limit
Analyzed
gy
CAS 90, oual ReaLmt
WD
u9/1
2.0
_DF
1.0
11/26/02
18.52
STC
87-68-3
Isopropylbenzene (Cumene)
ND
ug/l
0.50
1-0
11/26/02
18:52
STC
98-82-8
p-Isopropyltoluene
ND
ug/1
1.0
1.0
11/26/02
18:52
STC
99-97-6
Methylene chloride
ND
ug/1
2.0
1.0
11/26/02
18:52
STC
75-09-2
Methyl-tert-butyl ether
ND
ug/l
0.50
1.0
11/26/02
19:52
STC
1634-04-4
Naphthalene
ND
ug/i
2.0
1.0
11/26/02
18:52
STC
91-20-3
n-Propylbenzene
ND
ug/l
0-50
1.0
11/26/02
18:52
STC
103-65-1
styrene
ND
ug/1
0.50
1.0.11/261D2
18:52
STC
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/1
0.50
1.0
11/26/02
18:52
STC
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/1
0.50
1.0
11/26/02
18:52
STC
79-34-5
Tetrachloroethene
ND
ug/l
0.50
1.0
11/26/02
18:52
STC
127-18-4
Toluene
ND
ug/1
0.50
1.0
11/26/02
18:52,STC
108-BB-3
1,2,3-Trichlorobenzene
ND
ug/l
2.0
1-0
11/26/02
18:52
STC
67-61-6
1,2,4-Trichlorobenzene
ND
ug/1
2.0
1.0
11/26/02
18:52
STC
120-82-1
1,1,1-Trichloroethane
ND
ug/1
0.50
1.0
11/26/02
18:52
STC
71-55-6
1,1,2-Trichloroethane
ND
ug/1
0.50
1.0
11/26/02
18:52
STC
79-DD-5
Trichloroethane
ND
u9/1
0.50
1.0
11/26/02
18:52
STC
79-01-6
Trichlorofluoromethane
ND
ug/1
0.50
1-0
11/26/02
18-52
STC
75-69-4
1, 2,3 -Trichloropropane,
ND
ug/1
0.50
1.0
11/26/02
18:52
STC
96-18-4
1,2,4-Trimethylbenzene
ND
ug/l
0.50
1.0
11/26/02
18.52
STC
95-63-6
1,3,5-Trimethylbenzene
ND
ug/l
0.50
1.0
11/26/02
18:52
STC
108-67-8
vinyl chloride
ND
ug/1
0.50
1.0
11/26/02
18:52
STC
75-01-4
m&p-%ylAne
ND
ug/l
0.50
1.0
11/26/02
18:52
STC
o-%ylene -
DID-
ug/1
'0.50
1.0
11/26/02
18.52
STC
95-47-6
1-Chloro-3-fluorobenzene (S)
110
1.0
11/26/02
18:52
STC
625-98-9
Date: 12/01/02
NC Wastowawr 12
NC Dtlnldng Water 37706
SC 99006
GROUNIMNIWER SECTION
ASHIFVILLE REGIONAL OFFICE
REPORT OF LABORATORY ANALYSIS KY Drnking water
111 s report span not to reprodvoat, exoW in full, VA Drinking Water 213
whtmt the written consent of Paco Analytical Services, Inc- FL NEW E87627
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i`iCD-E RfDSVQChemistryLaboratory
Sample Anomaly Report (SAR)
,C C) / Sample M:
Location: - {i , ►= i� (0-z,' p —M W5' County. 772G " s �4 1,)e., wj -k- Region:
.mple Type: L9u, e Y Priority::. C O c— Collector: �. i Vx i C'L
Date collected:]_/ 2 v / o L Date « ceived: .1 } / 2 / o Z Date analyzed: 1 / Z S /
Affected Parameter(s); w -
Analytical Area (check one):
❑ WCH C3. METALS
❑ VOA ❑ SVOA
❑ NUT MICRO
❑ PEST
The following anomalies occurred (check all that apply):
❑ Santplcs
❑ Quality Control
❑ Improper container used
❑ Instrument failure- no reportable results
❑ VOA vials tivith headspace
❑ Analyst error- no rcpo,-,_blc results
❑ Suifide samples with hcadspace
❑ Surrogates
❑ Samples not received, but listed on fieldshect
0 None added
❑ Samples received, but not listed on ficidshect
❑ Recovery outside acceptance limits
❑ Nlislabeled as to tests, preservatives, etc.
❑ Spike recovery
❑ Holding time expired
❑ None added
❑ Prior to receipt in'lab
❑ Recovery outside acceptance limits
❑ After receipt in lab
Failed to meet criteria for precision
❑ Insufficient quantity for analysis
❑ Intemal standards
❑ Sample exhibis gross non -homogeneity
❑ Blank contamination
❑ Sample not chemically preserved properly
0 QC data reported outside ofcontrols (i.e. QCS, I -CS)
❑ pH out of range (record pH):
❑ Incorrect procedure used
❑ Improper chemical
C SOP intentionally modified tivith QA and Branch Hcad
❑ Residual chlorine- present in sample
approval
❑ Color inicr(cm icc
❑ Invalid instrument calibration
❑ Heavy emulsion formed during extraction
❑ Efevatcd detection limits due to:
❑ Saniple bottle broken in lab - no reportable results
❑ Insufficient sample volume
1 Gtr-� Glt�•h^tn.�e, cr��... �ZS l,l j,�9-� C-� � �-� 1 tLJ �
0 Other (sp cify):
O-L"�Y t, Qt, C-Y +0yG�-1 'l0 a
ct1T ,c �4-t/J
ae1,0
l.o
4,
1 J v
Comments: 5.CJ.,,�
�c.Q� _ � �Lo-0 S. 2
V . `' a r)lt-ei)
5 {roci� Vv�-s 5
kid �.9c.v,
Corrective Action: /o�
❑ Samples were rejected by DWQ Lab. Authorized by: Date:
❑ Accepted and analyzed after notifying the collector or contact person and determining that another sample could not be secured.
❑ ,$�ample(s) on hold until:
tg/ Sample reported Nvth qualification. Data qualification code used:
❑ Other (explain):
Notification Required (circle one)?
Person Contacted:
L ad Chemist R Se initial):
0CHEIZ
# .TALS
Branch Head Review,( initial):
QA/QC Review (initial '
Q.OFumutL.banwey1SA t
Yes No
orm completed by:
I
c-i t— -
JAB
Date:
Date: [ 1 Zs /
❑ SVOA
Logged into database by (initial):
tor.10 t.a.
GROtJNDMTER SECTION
e ASHEVII_t_E KGIONIA'•_ O�'F?C-E I`

NC DENR/DWQ Chemistry Laboratory
Sample Anomaly Report (SAR) f
, (W, J Sample ID: 142 - 5
Location: ...�/1 County: .t, A Region: - �_
ample Type: W lite Priority: �r /�//1 �_ Collector: ✓C�i�.
Date collected: 02-/ Date received: ZZ / Date analyzed: __/��/ OZ
Affected Parameter(s):�
Analytical Area (check one):
e WCH ❑ METALS ❑ VOA
❑ NUT ❑ MICRO ❑ PEST
The following anomalies occurred (check all that apply): -
❑ Samples
❑ Improper container itscd
❑ VOA vials with licadspacc'
❑ Sulfidc samples with headspace
❑ Samples not received, but listed on tieldslteet
❑ Samples received, but not listed on fieldsheet
❑ Mislabeled as to tests, preservatives, etc.
❑ Holding time expired
Prior to receipt in lab
After receipt in lab
❑ Insufficient quantity for analvsis
❑ Sample exhibits gross non-homugcncity
❑ Sample not chemically preserved properly
❑ pl I out of range (record pI0:
❑ Improper chemical
❑ Residual chlorine present in sample
❑ Color interference
0 Heavy emulsion formed during extraction
D Sample bottle broken in lab - no reportable results
l<a Other (speci I'A- �D hJ'r D
c_A^ r- w
Comments:
Corrective Action:
❑ Quality Contro
❑ Instrument
ZI Analyst err,
❑ Surrogates _
❑ None added
❑ Recovery outside acceptance limits
❑ , Spike recovery
❑ None added
❑ Recovery outside acceptance limits
❑ Failed to meet criteria for precision
❑ Internal standards
❑ Blank contamination
❑ QC data reported outside of controls (i.e. QCS, LCS)
❑ Incorrect procedure used
❑ SOP intentionally modified with QA and Branch Head
approval
❑ Invalid instrument calibration
❑ Elevated detection limits due to:
❑ Insufficient sample volume
Cool"
LABORATORY SECTION!
ASHEVILLE REGIONAL OFFICE
❑ Samples were rejected by DWQ Lab. Authorized by: Date:
❑ Accepted and analyzed after noti Eying the collector or contact person and determining that another sample could not be secured.
❑ Sample(s) on hold until:
R—Sample reported with qualification. Data qualification code used:
❑ Other (explain):
Notification Required (circle one)?
Person Contacted:
L d Chemist Rev i � �n ial):
B10CHE\t—LL?-
0 NIETALS
Branch Heal Review (initial):
QA/QC Re%iew (initia
QATOnns`3abomtorySA R
Yes No
Date:
Form completed by: (/ • / "i7 Date: /� / l 7
❑ PEST
❑ VOA
Cl SVOA
Logged into database by (initial):
10/23/Oldbs

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Face Analytical m
www.pacelabs.com
Lab Sample No: 931057020
Client Sample ID: WELL R87S7
Parameters
Metals
ICP Metals, trace -led'
Silver
Date Diaested.01
Date: 12/17/01
Pace Analytica,,
54 Ravc.
Asheville,
Phone: 828.2.
Fax:828,254.
Lab Project Number: 9325207
Client Project ID: Wells/4500126184
gN F Project Sample Number: 9325207-004 Date Collected: 11/27/01 12:55
Matrix: Water Date Received: 11/28/01 12:15
F
Results Units Report Limit Analyzed CAS No. Ftnote Reg Limit
Prep/Method: EPA 3010 / EPA 200.7
ND mg/l 0.0020 12/05/01 16:01 TRW 7440-22-4
12/03/01
Page: 4
Laboratory Certification IDs REPORT OF LABORATORY ANALYSIS Laboratory Certification IN
NC Wastewater 40 This report shall not be reproduced, except in full, TN Drinking Water 02980
NC Drinking Water 37712 SC Environmental 99030
without the written consent of Pace Analytical Services, Inc.
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.

-_�Pace Analytical',
54 /f Gllr An -al ical ,, Ashen lle, ,
www.pacelabs.com Phone. 828.25..
DATE: 12/14/00 Fax:828.252.v
PAGE: 5
Pace Project Number: 9316795
Client Project ID Wells/4500119639
Pace Sample No: 93730364 Date Collected: 11/27/00 Matrix: Water
Client Sample ID: WELL R87S7 Date Received: 11/28/00
Parameters Results Units PRL Analyzed Analyst CAS# Footnotes
Bioassay
pH Method EPA 150.1 Prep Method: EPA 150.1
pH 6.6 _units 0 11/29/00 HLL 1
Metals
ICP Metals, trace -level Method: EPA 200.7Prep Method: EPA 3010
Silver NO mg/l 0.002 12/11/00 TRW 7440.22-4
Date Digested 12/06/00
Wet Chemistry
Total Dissolved Solids Method: EPA 160.1 Prep Method: EPA 160.1
Total Dissolved Solids 110 mg/1 10 12/01/00 JMS
Ammonia ' -Method: EPA 350.3 Prep Method: EPA 350.3
Nitrogen, Ammonia ND mg/l 0.1 12/08/00 JDA 7727-37-9
Nitrogen. Nitrate plus Nitrite Method: EPA 353.3 Prep Method: EPA 353.3
Nitrogen, Nitrate O.50 mg/l 0.1 12/07/00 JDA
Sulfate,Automated Colorimetric Method: EPA 375.2 Prep Method: EPA 375.2
Sulfate' 6.5 mg/l 5 12/07/00 JDA
Chemical Oxygen Demand Method: EPA 410.4 Prep Method: EPA 410.4
Chemical Oxygen Demand ND mg/l 50 12/05/00 AAB
Phenolics, Total Recoverable Method: EPA 420.1 Prep Method: EPA 420.1
Phenolics, Total Recoverable 0.0079 mg/l 0.005 12/06/00 JMS 108-95-2
Total Organic Carbon Method: EPA 9060 Prep Method: SM 5310C
Total Organic Carbon 5.0 mg/l 2 12/11/00 AAB 7440-44-0
Laboratory Certification IN REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
NC Wastewater 40 TN Drinking Water 02980
This report shall not be reproduced, except in full,
NC Drinking Water- 37712 SC Environmental 99030
without the written consent of Pace Analytical Services, Inc.

0

J Pace Analytica'r
iceAnal cal " AshevXc,
y
www.pacelabs.com Phone 828'_'
DATE: 12/14/00 Fax, 828.252
PAGE: 6
Pace Project Number: 9316795
Client Project ID: Wells/4500119639
PARAMETER FOOTNOTES
NO Not Detected
NC Not Calculable
PRL Pace Reporting Limit
Ell Analysis conducted in excess of EPA recommended holding time.
Laboratory Certification IN REPORT OF LABORATORY ANALYSIS Laboratory Certification IN
NC Wastewater 40 TN Drinking Water 02980
NC Drinking Water 37712 This report shall not be reproduced, except in full,
g SC Environmental 99030
without the written consent of Pace Analytical Services, Inc.

0 0

Pace Analytical,
9800Kincey r.Anal�inalM
Hunterville,
www.pacelabs.com
Phone. 704.6;.
Fax. 704,875.,
DATE: 12/13/00
PAGE: 7
Pace Project Number:
9218932
CLient Project ID:
Agfa-9316795
Pace Sample No: 93730364
Date
Collected:
11/27/00
Matrix: Water
- Ctient Sample ID: WELL R87S7
Date
Received::
11/28/00
Parameters
Resu{ts Units
PRL
App.
DF Analyzed
Analyst CAS# Footnotes
GC VoLa;iLes
GC VCCs in Water
Method: SM 6230D
Prep Method:
SM
6230D
DichlorodifLuoromethane
ND
ug/l
0.5
1.00
12/09/00
KST
75-71-5
Chtoromethane
ND
ug/L
0.5
1.00
12/09/00
KST
74.87-3
Vinyl Chloride
ND
ug/L
0.5
1.00
12/09/00
KST
75-01-4
Bromcmethane
ND
ug/1
0.5
1.00
12/09/00
KST
74-83-9
Chtoroethane
ND
ug/L
0.5
1.00
12/09/00
-KST
75-00-3
Trichloroftuoromethane
ND
ug/L
0.5
1.00
12/09/00
KST
75-69-4
1,1-Dichtoroethene
ND
ug/L
0.5
1.00
-12/09/00
KST
75-35-4
Methylene Chtoride
ND
ug/1
0.5
1.00
12/09/00
KST
75-09-2
trans-1,2-Dichloroethene
ND
ug/C
0.5
1.00
12/09/00
KST
156-60-5
1-,1-Dichloroethane
ND
ug/L
0.5'
1.00
12/09/00
KST
75-34-3
cis-1,2-Dichloroethene
ND
ug/L
0.5
1.00
12/09/00
KST
156-59-2
BromochLorome.thane
ND
ug/L
0.5
1.00
12/09/00
KST
74-97-5
Chloroform
ND
ug/1
0.5
1.00
12/09/00
KST
67-66-3
2,2-Dichloropropane
ND
ug/t
0.5
1.00
12/09/00
KST
-594-20-7
-1,2-Dichloroethane
ND
ug/L
0.5
1.00
12/09/00
KST
107-06-2
1,1,1-Trichloroethane
ND
ug/l-
0.5
1,00
12/09/00
KST
71-55-6
1,1-0ichloropropene
ND
ug/l-
0.5
1.00
12/09/00
KST
563-58-6
Carbon Tetrachloride
ND
ug/L
0.5
1.00
12/09/00
KST
56-23-5
Dib-cmomethane
ND
ug/L
0.5
1.00
12/09/00
KST
74-95-3
1,2-Dichloropropane
ND_
ug/L
0.5
1.00
12/09/00
KST
78-87-5
Trig^Loroethene
ND
ug/L r
0.5
1.00
12/09/00
KST
79-01-6
Brc;-cdichloromethane
ND
ug/L
0.5
1:00
12/09/00
KST
75-27-4
cis-1,3-Dichloropropene
ND
ug/t
0.5
1.00
12/09/00
KST
10061-01-5
tra7s-1,3-Dichtoroproper,e
ND
ug/L
0.5
1.00
12/09/00
KST
10061-02-6
-1,',2-Trichtoroethane'
No
ug/L_
0.5
1.00
12/09/00
KST
79-00-5
1,3-Dichtoropropane
ND
ug/L -
0.5
1.00
12/09/00
KST
142-28-9
Dibrcmochloromethane
ND
ug/L
0.5 '
1.00
12/09/00
KST_
124-48-1
1,2-Dibromoethane
ND
ug/t
0.5
1.00
12/09/00
KST
106-93-4
Tetrachioroethene
ND
ug/L
0.5
1.00
12/09/00
KST `
127-18-4
1,1,1,2-Tetrachtoroethane
ND
ug/L
0.5
1.00
12/09/00
KST
630-20-6
Ch'.o-obenzene
ND
ug/L
0.5
1.00
12/09/00
KST
108-90-7
8rc�-.c-Iorm
ND
ug/L
0.5
1.00
12/09/00
_KST'
75-25-2
1,1,2,2-Tetrachloroethane
ND'
ug/t
0.5
1.00
12/09/00
KST
79-34-5
1,2,3-Trichtoropropane
ND
ug/L
0.5
1.00
12/09/00
KST
96-18-4
Bromobenzene
ND
ug/L
0.5
1.00
12/09/00
KST
108-86-1
2-Chtorotoluene
ND
ug/l
0.5
1.00
12/09/00
KST'
95-49-8
Laboratory Certification INLaborato
REPORT OF
LABORATORY ANALYSIS
Certification IDS
water
NC Wastewater 12
KY Drinking 90090
NC 0- ^king Water 37706
This report shall
not
be reproduced, except in full,
TN UST List
Sc 99006
without the written
consent of Pace Analytical Services, Inc.
VA Drinking Water 213

�'
�J��
/�
�'

Pace Analytical,
M
9800 Kincey Ave,
aceAnalytical
Huntersville,.
www.pacelabs.com
Phone 704.8;,
I
Fax: 704.875..
DATE: 12/13/00
PAGE: 8
Pace Project Number:
9218932`
CLient Project
ID:
Agfa-9316795
Pace Sample No: 93730364
Date
CoLLected:
11/27/00
Matrix: Water
Client Sample ID: WELL R87S7
Date
Received:
11/28/00
Parameters
ResuLts
Units
PRL
App.
DF Analyzed
Analyst CAS# Footnotes
4-ChLorotoluene
ND
ug/L
0.5
------
1.00
--------
12/09/00
-----
KST
---------- ----------
106-43-4
1,3-DichLorobenzene
ND
ug/L
1
1.00
12/09/00
KST
541-73-1
1,4-Dichlorobenzene
ND
ug/L
1
1.00
12/09/00
KST
106-46-7
1,2-Dichlorobenzene
ND
ug/t`
1
1.00
12/09/00
KST
95-50-1
1,2-Dibromo-3-ChLoropropane
ND
ug/L
2
1.00
12/09/00
KST
96-12-8
1,2,4-Trichlorobenzene
ND
ug/L
2
1.00
12/09/00
KST
120-82-1
Hexachloro-1,3-butadiene
ND
ug/L
2
1.00
12/09/00
KST
87-68-3
1,2,3-Trichlorobenzene
ND
ug/L
2
1.00
12/09/00
KST
87-61-6
MethyL-tert-butyl Ether
ND
ug/l
0.5
1.00
12/09/00
KST
1634-04-4
Diisopropyl ether
ND
ug/L
0.5
1.00
12/09/00
KST
108-20-3
Benzene
ND
ug/L
0.5
1.00
12/09/00
KST
71-43-2
ToLuene
ND
ug/L
0.5
1.00
12/09/00
KST
108.88-3
Ethylbenzene
ND
ug/l
0.5
1.00
12/09/00
KST
100-41-4
mBp-XyLene
ND
ug/l
0.5
1.00
12/09/00
KST
7816-60-0
Styrene
ND
ug/L
0.5
1.00
12/09/00
KST
100-42-5
o-Xytene (1,2-Dimethylbenzene)
ND
ug/L
0.5
1.00
12/09/00
KST
95-47-6
Isopropytbenzene (Cumene)
ND
ug/L
0.5
1.00
12/09/00
KST
98-82-8
n-Propytbenzene
ND
ug/L
0.5
1.00
12/09/00
KST
103-65-1
1,3,5-Trimethylbenzene
ND
ug/L
0.5
1.00
12/09/00
KST
108-67-8
tert-Butylbenzene
ND
ug/l
0.5
1.00
12/09/00
KST
98-06-6
1,2,4-Trimethylbenzene
ND
ug/L
0.5
1.00
12/09/00
KST
95-63-6
sec-Butylbenzene
ND
ug/L
0.5
1.00
12/09/00
KST
135-98-8-
p-Isopropyltotuene
ND
ug/L
1
1.00
12/09/00
KST
99-87-6
n-Butylbenzene
ND
ug/L
1
1.00
12/09/00
KST
104-51-8
Naphthalene
ND
ug/l
2
1.00
12/09/00
,KST
91-20-3
1-Chloro-3-fluorobenzene (S)
95
%
1.00
12/09/00
KST
625-98-9
Laboratory Certification IDs
REPORT OF
LABORATORY
ANALYSIS
Laboratory Certification IN
NC Wastewater 12
KY Drinking Water 90090
NC Drinking Water 37706
This report
shall not be reproduced, except in full,
TN UST List
SC 99006
without
the written consent
of Pace Analytical
Services, Inc.
VA Drinking Water 213

. , . a. w ,.,.��- � .�,.� .. 4 �e �.�,��.�-. � . _.�. �.... ___ � ��, -��� ,_�,� �...-�.� a ��
�_ . �.�., mr..� �,., � ��.�,��

w
L`
Pace Analyticav,
rM
9800 Kincey Ave,
aceAnalytical
Huntersvillt;
' www.pacelabs.com
Phone. 704. b,,
Fax: 704.875:,
DATE: 12/13/00
PAGE: 9
Pace Project Number:
9218932
Client Project ID:;
Agfa-9316795
Pace Sample No: 93730372
Date
Collected:
11/27/00
Matrix: Water
Client sample ID: TRAVEL BLANK-AGFA
Date
Received:
11/28/00
Parameters
Results
Units
PRL
App.
DF Analyzed
Analyst
CAS# Footnotes
GC Volatiles
GC VOCs in Water
Method: SM 6230D
Prep Method: SM
6230D
Dichlorodifluoromethane
ND
ug/t
0.5
1.00
12/09/00
KST
75-71-8
Chloromethane
ND
ug/l
0.5
1.00
12/09/00
KST
74-87-3
Vinyl Chloride
ND
ug/l
0.5
1.00
12/09/00
KST
75-01-4
Bromomethane
ND
ug/l
0.5
1.00
12/09/00
KST
74-83-9
Chloroethane
ND
ug/l
0.5
1.00
12/09/00"
KST
75-00-3
Trichioroftuoromethane
ND
ug/l
0.5
1.00
12/09/00
KST
75-69-4
1,1-Dichloroethene
ND
ug/t
0.5
1.00
12/09/00
KST
75-35-4
Methylene Chloride
ND
ug/l
0.5
1.00
12/09/00
KST
75-09-2
trans-1,2-Dichloroethene -
ND
ug/t
0.5
1.00
12/09/00
KST
156-60-5
1,1-Dichloroethane
ND
ug/l
0.5
1.00
12/09/00
KST -
75-34-3
cis-1,2-Dichloroethene
ND
ug/l
0.5
1.00
12/09/00
KST
156-59-2
Bromochloromethane
ND
ug/l
0.5
1.00
12/09/00"
KST
74-97-5
- Chloroform
ND
ug/l
0.5
1.00
12/09/00
KST
67-66-3
2,2-Dichloropropane
ND
ug/t
0.5
1.00
12/09/00
KST :
594-20-7
1,2-Dichloroethane
ND
ug/l
0.5
1.00
12/09/00
KST
107-06-2
1,1,1-Trichloroethane
ND
ug/l
0.5
1.00
12/09/00
KST
71-55-6
1,1-Dichloropropene
ND
ug/l
0.5
-1.00
12/09/00
KST
563-58-6 '
Carbon Tetrachloride
ND
ug/L
0.5
1.00
12/09/00
KST
56-23-5
Dibromomethane
ND
ug/l
0.5
1.00
12/09/00
KST
74-95-3
1,2-Dichloropropane
ND
ug/t
0.5
1.00
12/09/00
KST
78-87-5
Trichtoroethene
ND
ug/l
0.5
1.00
12/09/00
KST
79-01-6
Bromodichtoromethane
ND
ug/t
0.5
1.00
12/09/00
KST
75-27-4
cis-1,3-Dichloropropene
ND
ug/l
0.5
1.00
12/09/00
KST
10061-01-5
trans-1,3-Dichloropropene
No
ug/t
0.5
1.00-
12/09/00
KST
10061-02-6
1,1,2-Trichloroethane
ND
ug/l
0.5
1.00
12/09/00
KST
79-00=5
1,3-Dichloropropane
ND
ug/L
0.5
1.00
12/09/00
KST
142-28-9
Dibromochloromethane
ND
ug/t
0.5
1.00
12/09/00
KST
124-48-1
1,2-Dibromoethane
ND
ug/l
0.5
1.00
12/09/00
KST
106-93.4
Tetrachloroethene
ND
ug/l
0.5
1.00
12/09/00
KST
127-18-4
1,1,1,2-Tetrachloroethane
ND
ug/l
0.5
1.00
12/09/00
KST
630-20-6
Chlorobenzene
ND
ug/l
0.5`
1.00
12/09/00
KST
108-90.7
Bromoform
ND
ug/l
0.5
1.00
12/09/00
KST
75-25-2
1,1,2,2-Tetrachloroethane
ND
ug/l
0.5
1.00
12/09/00
KST
79-34-5
1,2,3-Trichtoropropane
ND
ug/l
0.5
1.00
12/09/00
KST
96-18-4
Bromobenzene
ND
ug/l
0.5
1.00
12/09/00
KST
108-86-1
2-Chlorotoluene
_ND
ug/l
0.5
1.00
12/09/00
KST
95-49-8
Laboratory Certification IDs
REPORT OF
LABORATORY ANALYSIS
LaboratoryCertification IDs
NC Wastewater 12
KY Drinking ater 90090
NC Drinking Water 37706
This report shall
not be reproduced, except in full,
TN UST List
SC 99006
without the written
consent of Pace Analytical Services, Inc.
VA Drinking Water 213

0 0

Pace Analytical
ace
9800 Kincey Ave,,.
AnalXicah
Huntersviile .
www.pacelabs.com
Phone 704 8, .
Fax: 75.
DATE: 12/13/00
PAGE: 10
Pace Project Number:
9218932
Client Project ID:
Agfa-9316795
Pace Sample No: 93730372
Date
CoLlected:
11/27/00
Matrix: Water
CLient Sample ID: TRAVEL BLANK-AGFA
Date
Received:
11/28/00
Parameters
Results
Units
PRL
App.
Dr- Analyzed
Analyst CAS# Footnotes
4-ChLorotoluene
ND
ug/L
0.5
1.00
-------
12/09/00
-----
KST
---------- ----------
106-43-4
1,3-Dichtorobenzene
ND
ug/L
1
1.00
12/09/00
KST
541-73-1
1,4-Dichlorobenzene
ND
ug/L
1
1.00
12/09/00-
KST
106-46-7
1,2-Dichlorobenzene
ND
ug/l
1
1.00
12/09/00
KST
95-50-1
1,2-Dibromo-3-ChLoropropane
ND
ug/L
2
1.00
,12/09/00
KST
96-12-8
1,2,4-Trichlorobenzene
ND
_ug/l
2 -
1.00
12/09/00
KST
120-82-1
Hexachloro-1,3-butadiene
ND
ug/t
2
1.00
12/09/00
"KST
87-68-3
1,2,3-Trichlorobenzene
ND
ug/L
2
1.00
` 12/09/00
KST
87-61-6
Methyl-tert-butyl Ether
ND
ug/l
0.5
1.00
12/09/00
KST
1634-04-4
Diisopropyl ether
,ND
ug/l
0.5
1.00
12/09/00
KST
108-20-3
Benzene
ND
ug/L
0.5
1.00
12/09/00
KST
71-43-2
Toluene
ND
ug/L
0.5
1.00
12/09/00
KST
108-88-3
Ethylbenzene
ND
ug/t
0.5
1.00
12/09/00
KST
100-41-4
m&p-Xylene
ND
ug/l
0.5
1.00
12/09/00
KST
7816-60-0
Styrene
ND -
ug/l
0.5
1.00
12/09/00
KST
100-42-5
o-Xylene (1,2-Dimethylbenzene)
ND
ug/L
0.5
140
12/09/00
KST
95-47-6
Isopropylbenzene (Cumene)
ND
ug/l
0.5
1.00
12/09/00
KST
98-82-8
n-.Propylbenzene
ND
ug/l
6.5
1.00
12/09/00
KST
103-65-1
1,3,5-Trimethylbenzene
ND
ug/L
0.5
1.00
12/09/00
KST
108-67-8
tert-Butylbenzene
ND
ug/t
0.5
1.00
"12/09/00
KST
98-06-6
1,2,4-TrimethyLbenzene
ND
ug/L
0.5
1.00
12/09/00
KST
95-63-6
sec-Butylbenzene
ND
ug/L
0.5
1.00
12/09/00
KST
135-98-8
p-IsopropyLtotuene
ND
ug/l
1
1.00
12/09/00
KST
99-87-6
n-Butylbenzene
ND
ug/L
1
1.00
12/09/00
_KST
104-51-8
Naphthalene
ND
ug/L
2
1.00
12/09/00
KST
91-20-3
1-ChLoro-3-fLuorobenzene (S)
92
%
1.00
12/09/00
KST
625-98-9
Laboratory Certification los
REPORT OF LABORATORY ANALYSIS
Laboratory certification los
NC Wastewater 12
KY Drinking Water 90090
NC Drinking Water 37706
This report
shall not be reproduced:
except in full,
TN UST List
SC 99006
without
the written consent of Pace Analytical
Services, Inc.
VA Drinking Water 213

0 0

Pace Analytica,
9800 Kincey Avg
ace Analytical T M HuniersvillL,
www.pacelabs.com Phone 704,
Fax. 704, 876,
I
DATE: 12/13/00
PAGE: 11
Pace Project Number: 9218932
Client Project ID: Agfa-9316795
PARAMETER FOOTNOTES
ND Not Detected
NC Not calculable
PRL Pace ReportingLimit
(S) Surrogate
App. DF Applied Dilution Factor
Laboratory Certification IDs REPORT OF LABORATORY ANALYSIS Laboratory Certification 90
NC Wastewater 12 _ KY Drinking Water 90090
NC Drinking Water 37706 This report shall not be reproduced, except in full, TN UST List
SC 99006 without the written consent of Pace Analytical Services, Inc. VA Drinking Water 213

0

/
Pace Analytical .
rM
9800 Kincey Aver i�
/'+QAnalytical,-"
/�
�l�C.r An
/'+
alyti
al
Huntersv;lle."
www.pacelabs.com
Phone.' '04 31 ,
Fax. 70d.875..
QUALITY CONTROL DATA DATE:
12/13/00
PAGE:
12
AGFA Corporation
Pace Project Number: 9218932
P. 0. Box 1176
Client Project ID: Agfa-9316795
Brevard, NC 28712
Attn: Mr. Roger Galloway
QC Batch ID: 35561
OC Batch Method: SM 6230D
Analysis Method: SM 6230D
Analysis Description: GC VOCs in Water
Associated Pace Samples:
93730331
_93730349
93730356 93730364 93730372
METHOD BLANK:- 921365508
Associated Pace Samples:
93730331
-93730349
93730356 93730364 93730372
Method
Blank
Parameter
Units
Result
PRL Footnotes
Dichlorodifluoromethane
ug/l"
-NO
0.5
Chloromethane
ug/t
NO
0.5
Vinyl Chloride
ug/l
NO
0.5
Bromomethane
ug/l
NO
0.5
Chloroethane
ug/l
NO
0.5
Trichlorofluoromethane
ug/l
ND
0.5
1,1-Dichloroethene
ug/l
NO
0.5
Methylene Chloride
ug/l
NO
0.5
trans-1,2-Dichloroethene
ug/l
NO
0.5
1,1-Dichloroethane
ug/l
ND
0.5
cis-1,2-Dichloroethene
ug/l
NO
0.5
Bromochtoromethane
ug/t
ND
0.5
Chloroform
ug/t
NO
0.5
2,2-Dichloropropane
ug/l
NO
0.5
1,2-Dichloroethane
ug/l
ND
0.5
1,1,1-Trichloroethane
ug/l
ND
0.5
1,1-Dichloropropene
ug/l
NO
0.5'
Carbon Tetrachloride
ug/t
NO
0.5
Dibromomethane
ug/l-
NO
0.5
1,2-Dichloropropane
ug/t
NO
0.5
Trichloroethene
ug/l
ND
0.5 -
Bromodichloromethane
ug/t
ND
0.5
cis-1,3-Dichloropropene
ug/l
NO
0.5
trans-1,3-Dichloropropene
ug/t
NO
0.5
1,1,2-Trichloroethane
ug/l
ND
0.5
Laboratory Certification IDs
REPORT OF LABORATORY ANALYSIS
Laboratory Certification IN
NC Wastewater 12
KY Drinking Water 90090
NC Drinking Water 37706
This report
shall not be reproduced, except in full
TN LIST List
Sc 99006
without the written consent of Pace Analytical Services; Inc.
VA Drinking Water 213

K

`
f
Pac(epAna(lytica,
/al IVQ/TM
- /�
�%r
JUDO II�Hurt rs!
Hunters m
{A.VV / �I
www.pacelabs.com
Phcre 704.6„
I-
Fax 4.875 .
DUALITY CONTROL DATA
DATE: 12/13/00
PAGE: 13
Pace Project Number:
9218932
Client Project ID:
Agfa-9316795
METHOD BLANK: 921365508
Associated Pace Samples:
93730331
93730349
93730356 93730364 93730372
Method.
Blank
Parameter
Units
Result
PRL Footnotes
1,3-DichLoropropane -
ug/L
ND
0.5
DibromochLoromethane
ug/L
ND
0.5
1,2-Dibromoethane
ug/L
ND
0.5
Tetrachloroethene
ug/L
ND
0.5
1,1,1,2-Tetrachloroethane
ug/L
ND
0.5
Chlorobenzene
ug/L
ND
0.5
Bromoform
ug/L
ND
0.5
1,1,2,2-Tetrachloroethane
ug/L
ND
0.5
1,2,3-TrichLoropropane
ug/L
NO
0.5
Bromobenzene
ug/L
ND
0.5'
2-Chlorotoluene
ug/L
ND
0.5
4-Chlorotoluene
ug/L
ND
0.5
1,3-Dichlorobenzene
ug/L
NO
1
1,4-Dichlorobenzene
ug/L
NO
1
1,2-Dichlorobenzene
ug/t
ND
T
1,2-Dibromo-3-Chloropropane
ug/t
NO
2
1,2,4-TrichLorobenzene
ug/L
ND
2
Hexachloro-1,3-butadiene
ug/L
ND
2
1,2,3-Trichlorobenzene
ug/L
ND
2
Methyl-tert-butyL Ether
ug/l
ND
0.5
Diisopropyl ether
ug/L
NO
0.5
Benzene
ug/L
ND
0.5
Toluene
ug/L
ND
0.5
Ethylbenzene
ug/t
ND
0.5
m&p-Xylene
ug/t
ND
0.5
Styrene
ug/L
ND
0.5
o-Xylene (1,2-Dimethylbenzene)
ug/L
ND
0.5
Isopropylbenzene (Cumene)
ug/l
ND
0.5
n-Propytbenzene
ug/l
ND
0.5
1,3,5-Trimethylbenzene
ug/L :
ND
0.5
tert-Butylbenzene
ug/L
NO
0.5
1,2,4-Trimethylbenzene
ug/L
NO
_0.5
sec-Butylbenzene
ug/l
ND
0.5
p-IsopropyLtoluene
ug/L
ND
1 -
n-Butytbenzene
ug/L
ND
1
Naphthalene
ug/L
ND
2
1-Chloro-3-ftuorobenzene (S)
%
100
Laboratory Certification IDS
REPORT
OF LABORATORY ANALYSIS
i aborato Certification IDs
water
NC Wastewater 12
KY Drinking 90090
NC Drinking Water 37706
This report
shall not be reproduced, except in full,
TN UST List
Sc 99006
-without the written consent of Pace Analytical Services. Inc.
VA Drinking Water 213

Ho
H

u
Pace Analyficat
9800 .K, ncey Ave,,
Huntersville,
,_,.,,laceAnalytical�
www.pacelabs.com
Phone: 704 8,.
% I
Fax: 704.875.
DATE:
12/13/00
PAGE:
14
Pace Project Number: 9218932
Client Project ID: Agfa-9316795
QUALITY CONTROL DATA PARAMETER FOOTNOTES
Consistent with EPA guidelines unrounded concentrations are displayed and have been used to catcutate %
Rec and RPD values.
NO Not Detected
NC Not Calculable
PRL Pace Reporting limit
RPD Relative Percent Difference
(S) Surrogate
Laboratory Certification IDs REPORT �F LABORATORY ANALYSIS
Laboratory Certification IDs
NC Wastewater 12
KY Drinking Water 90090
NC Drinking Water 37706 This report shall not he reproduced, except in full,
TN UST List
Sc 99006 without the written consent of Pace Analytical Services, Inc.
VA Drinking Water 213

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DDK Environmental, Inc.
LABORATORY DIVISION
777 Phone: [phone]
506 Colwell Drive Fax: [phone]
Brevard, NC 28712
Certificate of Analysis
Project name: AGFA Monitoring Wells
Collection date: 2-May-00
Date received: 3-May-00
Results:
Sample identification: Well R87s3
Parameters
Method
Result
Ammonia, Nitrogen
EPA 350.3
104
Sample identification:
Well R87s4
Parameters
Method
Result
Ammonia, Nitrogen
EPA 350.3
7.7
Sample identification: Well R87s5
Parameters
Ammonia, Nitrogen
Sample identification: Well R87s7
Parameters
Ammonia, Nitrogen
NC
Method
EPA 350.3
Method
Result
<0.1
Result
Project number: 000503.516
Sample number: 2026
MDL Units Footnotes
2.0 mg/1
Sample number: 2027
MDL Units Footnotes
0.10 mg/1
Sample number: 2028
MDL Units Footnotes
0.10 mg/1
Sample number: 2029
MDL Units Footnotes
EPA 350.3 <0.1 0.10 mg/1
■
Water Certification Number: 37778 SC Certification tvumoer: Y7vwz
ECEIV

0 � 0

Pace Analytical S,,
Analytocal 54 hevenSG
Asheville, Nb.
Tel: [phone]
Fax: [phone],
DATE: 05/20/99
PAGE: 4
Pace Project Number: 935415
Client Project ID: Groundwater Monitoring
Pace Sample No: 93254217 Date Collected: 05/11/99 Matrix: Water
Client Sample ID: WELL R87S7 Date Received: 05/11/99
Parameters Results Units PRL Analyzed Analyst CAS# Footnotes
--------------------------------- ------------------- ------------------ ----- ---------- ----------
Wet Chemistry
Ammonia
Nitrogen, Ammonia
Method: EPA 350.3 Prep Method: EPA 350.3
0.81 mg/l 0.1 05/11/99 AAB 7727-37-9

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Pace Analytical S,
54 Ravensc,
Analytical Asheville, NC
Tel: 704-254-i'
Fax: [phone],
Sterling Diagnostic Imaging, Inc. June 02, 1998
P.O. Box 267 PACE Project Number: A80519513
Staton Rd. Cedar Mtn.
Brevard, NC 28712 NC Wastewater Lab Cert. #40
NC Drinkingwater Lab Cert'. #37712
SC lab Cert. #99030
Attn: Mr. Roger Galloway
Client Reference: Routine Samples 4500017649
PACE Sample Number: 93 0567940 93 0567959 93 0567967
Date Collected: 05/18/98 05/18/98 05/18/98
Date Received: 05/19/98 05/19/98 05/19/98
Client Sample ID: Well Well Well
Parameter Units PRL #R8753 #R8754 #R8755
r"-5165 73154 wg1S5
INORGANIC ANALYSIS
INDIVIDUAL PARAMETERS
Nitrogen, Ammonia mg/L 0.10 - 5.2 NO
Nitrogen, Ammonia mg/L 1.0 64 -
PACE Sample Number: 93 0567975`
Date Collected: 05/18/98
Date Received: 05/19/98
Client Sample ID: Well
Parameter Units PRL #R8757
R �5-7
INORGANIC ANALYSIS
INDIVIDUAL PARAMETERS
Nitrogen, Ammonia mg/L 0.10 NO
These data have been reviewed and are approved for release.
VL t 'W&L
Walter L. Miller
Operations Manager
Laboratory Certification IN Laboratory Certification IDS
NC Wastewater 40 REPORT OF LABORATORY ANALYSIS TN Drinking Water 02980
NC Drinking Water 37712 FL Environmental 96317
SC Environmental 99030 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inca

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Page 2
Client Reference: Monitoring Wells
PACE Sample Number:
Date Collected:
Date Received:
Client Sample ID:
Parameter
INORGANIC ANALYSIS
INDIVIDUAL PARAMETERS
Barium
Cadmium
Chromium
Copper
Iron
Nitrogen, Ammonia
Nitrogen, Nitrate in Wastewater
Specific Conductivity
Pace Analytical Se,
t 54 RavenscrL.
Asheville, NC
Tel: [phone]
Fax: [phone]
May 15, 1996
PACE Project Number: A6050751`i
93 0202993 93 0203000 93 0203027
05/06/96
05/07/96
05/07/96
05/07/96
05/07/96
05/07/96
Well #
Bridle
Intake
R87S7
Veil
Dike
Units MDL
River
River
mg/L
0.10
ND
ND
ND
mg/L
0.01
ND
0.020
ND
mg/L
0.020
ND
ND
ND
mg/L
0.01
ND
ND
ND
mg/L
0.05
0.178
0.233
0.245
mg/L
0.1
ND
ND
ND
mg/L
0.1
0.10
0.13
ND
umhos/cm
10
16
15
16
These data have been reviewed and are approved for release.
} ,
f 1%<<.w.
Barbara M. Mille
Supervisor, Inorganic Chemistry
5 -:z? le7G/
Sherry L. Ratzlaff
Supervisor, Bioassay Department
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.

r
'�

ENVW4N ENTAL MAI . 'tiiOIMOWATM SECTION rve� vrr�„
SOX 27667 - �'.. _ e —
N : �. ^iO�E tY193 735-601a
Lat. _,y,S // Ito Long. t,.
WELL CONSTRUCTION RECORD Mkw Basin
Baaln Cods
Header Ent. OW-1 E,
DRILLING CONTRACTOR S&ME, Inc.
DRILLER REGISTRATION NUMBER 412 STATE WELL CONSTRUCTION
PERMIT NUMBER: 87-0012-WM-0032
1. WELL LOCATION: (Show sketch of the location below)
Nearest Town: Brevard County: Transylvania
77777-77 Cedar Mountain -
(Road, Community, or Subdivision and Lot No.) Depth DRILLING LOG
2. OWNER E. I. DuPont DeNumours & Company, Inc. 0r" 1T6" Brown, layey, �an ptio
�y 9ILT _
ADDRESS P.O. Box 267 Hwy. 267 South 116" 2' Tan, brown, CLAY
Street or Route No. 2' 3' Tan clay
Brevard NC 8717 y (moist)
City or Town State Zip Code 31 4' 6" Gray, silty, SAND (wet)
3. DATE DRILLED 6/24/86 USE OF WELL.Monitoring 416" 6'611 Tan, SAND (wet)
4. TOTAL DEPTH 28811 —•
CUTTINGS COLLECTED ®Yes ❑ No AV" 12' White, tan silty SAND
S. DOES WELL REPLACE EXISTING WELL? ❑ Yes ®No 12' 1616" Gray. white silty SAND
6. STATIC WATER LEVEL: FT. 0 above TOP OF CASING, 16'6" 22'6" Tan, red, silty SAND
�� ® below 226" 28'6" Red, gray, white, silty SAND -
TOP OF CASING IS 1 1 FT. ABOVE LAND SURFACE.
7. YIELD (gpm): METHOD OF TEST
8. WATER ZONES (depth):
;" --_
9. CHLORINATION: Type Amount
10. CASING:
Wall Thickness If additional space is needed use back of form.
Depth Diameter or Weight/Ft. Material
From 0' To 19' Ft. 2" sch 40 PVC LOCATION SKETCH
(Show direction and distance from at least two State Roads,
From To Ft. or other map reference points)
From To Ft. _ _ RIVER
� - --••
11. GROUT: WELL-3
70
1' 6" Depth Material Method I ,
From To 18 Ft. -Lean grout Tremie Pipe
AERATION ` POLISHING DETENTION
To Ft. 300
From POND I POND
POND
12. SCREEN:
Depth Diameter Slot Size Material
From _ 19' To 29, Ft. 2 in. 0. 10 in. pyr
From To Ft. in in.—Z—����
From To Ft. in irL
13. GRAVEL PACK:
Depth Size Material
19, HWY.276 �
From 29 To Ft. Coarse Sand _
From To Ft. ,
14.REMARKS: 1 .7t. bentonite seal above
scree collar -
I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15 NCAC 2C. WELL CONSTRUCTION
STANDARDS, AND THAT A COPY OF THIS RECORD H B�CONT�RAC
O THE WELL OWNErR.
SIGNAT E OOR AGENTDATE
GW-1 Revised 11/84 Submit original to Division of Environmental Management and copy to well owner.

BE

NO.: R87s5
AGFA CORPORATION COUNTY: TRANSYLVAN,
ALKALINITY,TO pH 4.5
ALKA-INITY,TO pH 8.3
ALUMINUM
ARSENIC
BARIUM
BERYLLIUM
BICARBONATE
CADMIUM
CALCIUM
CARBONATE
CHLORIDE
CHROMIUM,TOTAL
COBALT
COD
4.6-0
s
COLIFORM, FECAL
COLIFORM, TOTAL
COPPER
CYANIDE
DISSOLVED SOLIDS
q 0
J V-0
FLUORIDE
HARDNESS CaCo3
HARDNESS, NON CARB
IRON
LEAD
LITHIUM
MBAS
MAGNESIUM
MANGANESE
MERCURY
NICKEL
NITROGEN, AMMONIA
0., 00
-Y, 7
3
NITROGEN, KJELDAHL
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rm li o. t-w1
NITRATE & NITRITE
0. 0,2 a
0'io
0. 0.7, L4
ORGANIC SCAN
ORTHOPHOSPHATE
pH
603
6,01
6 &
PHENOLS
-00,
1k
0,0 /tart
a - 0 i -4 /.
0,010"
0.0io
PHOSPHORUS, TOTAL
0 0.;L
POTASSIUM
SELENIUM
SILVER
0- 00,Z
0 - 006"q
U. 00 6:-t4
0Y44
J- 0- 00-2 0
SODIUM
SPECIF. CONDUCTANCE
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3 - -7
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I-C
/0-0
TOX
TSS
VOC
AID
ZINC
STATIC WATER LEVEL
-3"
3
a'
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Red lnk=Sample taken by facility
SAMPLC 01,5C4A.OEd- 19/0 A/07- 1%41-6-r iLMP. 134--CAe4SG7 OF O&FtAy
//v

0 0

DATE SAMPLED
ALKALINITY, TO pH 4.5
ALKALINITY, TO pH 8.3
ALUMINUM
ARSENIC
BARIUM
BERYLLIUM
BICARBONATE
CADMIUM
CALCIUM
CARBONATE
CHLORIDE
CHROMIUM, TOTAL
COBALT
COD
`T
COLIFORM, FECAL
COLIFORM, TOTAL
,
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a
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DISSOLVED SOLIDS
300
4
FLUORIDE
HARDNESS CaCo3
HARDNESS, NON CARB
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LEAD
LITHIUM

0 0

DATE SAMPLED
PESAMPc-o-
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MBAS
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6
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PHOSPHORUS, TOTAL
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0 0

WELL NO. /? 37 S COUNTY: l R /- IV .S y L- V14 IV I'4
DATE SAMPLED R _5ANR`'�
ALKALINITY, TO pH 4.5
ALKALINITY, TO pH 8.3
ALUMINUM
ARSENIC
BARIUM
BERYLLIUM
BICARBONATE
CADMIUM
CALCIUM
CARBONATE
CHLORIDE
CHROMIUM, TOTAL
COBALT
COD
33
COLIFORM, FECAL
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DISSOLVED SOLIDS
310
24-o
3& 0
D
FLUORIDE
HARDNESS CaCo3
HARDNESS, NON CARB
IRON
LEAD
LITHIUM
Red Ink = Sample taken by facility

n1w

WELL NO. R S S COUNTY:
- ace
L. vA n/i 14
DATE SAMPLED
//- i 7- U
7 -y
.5-.2
Red Ink = Sample taken by facility

AOL
w 0

COUNTY
DATE SAMPLED
/t e SAMP..
ALKALINITY, TO pH 4.5
ALKALINITY, TO pH 8.3
ALUMINUM
ARSENIC
BARIUM
IU . I i '7
BERYLLIUM
BICARBONATE
CADMIUM
, O %
d• 0
CALCIUM
CARBONATE
CHLORIDE
/3-
1 5-
CHROMIUM , TOTAL
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COD
�f
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6,
COLIFORM, FECAL
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0. O f
CYANIDE
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O
l©
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0 0
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COUNTY
DATE SAMPLED
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pH
3
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Pace Analytical ,
2225 Ric,
�n Q��lr+� �l� a
Asheville, n
lr /-1 l�
Phone:828.2b•.
www, pacelabs. com
Fax: 828.252. s.
Lab Project Number:
9254148
Client Project ID:
MONITORING WELLS
Lab Sample No: 923533400
Project Sample
Number: 9254148-003 Date Collected: 11/12/03 11:52
Client Sample ID: R87S5
Matrix: Water
Date Received: 11/13/03 16:08
Parameters Results
Units Report Limit
Analyzed By
CAS No. Qual Re Lmt
Client Services ,
Nitrogen, Total Method:
Nitrogen 11.
mg/l 0.20
11/26/03 UP
7727-37-9
Metals
Traceg,ICP�Metals Prep/Method:
/ EPA 200.7
Silver ND
mg/l 0.0020
11/21/03 23:18 LBG
7440-22-4
Date Digested 11/14/03
11/14/03
Wet Chemistry
Total Dissolved Solids
Method:
EPA
160.1
Total Dissolved Solids
340
mg/l
Ammonia
Method:
EPA
350.1
Nitrogen, Ammonia
1.3
mg/1
Total Kjeldahl Nitrogen
Method:
EPA
351.2
Nitrogen, Kjeldahl, Total
11.
mg/l
Nitrogen, Nitrate/Nitrite
Method:
EPA
353.2
Nitrate -Nitrite (as N)
0.12
mg/l
Nitrate as N
NO
mg/l
Phosphorus, Total
Method:
EPA
365.2
Phosphorus
ND
mg/l
Sulfate,Automated Colorimetric
Method:
EPA
375.4
Sulfate
5.0
mg/l
Chemical Oxygen Demand
Method:
EPA
410.4
Chemical Oxygen Demand
74.
mg/l
Phenolics, Total Recoverable
Method:
EPA
420.1
Phenolics, Total Recoverable
0.010
mg/l
Total Organic Carbon
Method:
SM 5310B
Total Organic Carbon
il.
mg/l
Date: 11/26/03
20. 11/15/03 KHJ
0.10 11/14/03 LTH 7727-37-9
0.10 11/18/03 BKS
0.050
11/14/03
SHB 7727-37-9
0.050
11/14/03
SHB
0.100
11/15/03
WWB 7723-14-0
5.0
11/20/03
WWB
25.
11/19/03
BMF
0.0050
11/19/03
LTH
0.50 11/24/03 LTH 7440-44-0
REPORT OF LABORATORY ANALYSIS
Page: 7 of 31
Asheville Certification IDs
This report shall not be reproduced, except in full,
Charlotte Certification IDs
NC Wastewater
40
without the written consent of Pace Analytical Services, Inc.
NC Wastewater
12
NC Drinking Water
37712
N A
NC Drinking Water
37706
SC Environmental
99030
so
F
Sc
99006
FLNELAP
E87648
`i1PI1&,t
:. ■ ■ viv�r.«
M PIELAP
E87627

0 0

aceAnalytical °
www.pacelabs.com
Lab Sample No: 923533400
Client Sample ID: R87S5
GC Volatiles
GC VOCs in Water
<,_- Benzene
oromethane
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene-
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Date: 11/26/03
(47�
Pace Analytical'.
2225 Riv,
Asheville, io
Phone: 628.25,,
Fax [phone],
Lab Project Number: 9254148
Client Project ID: MONITORING WELLS
Project Sample Number: 9254148-003 Date Collected: 11/12/03 11:52
Matrix: Water Date Received: 11/13/03 16:08
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Method: SM
6230D
0.76
ug/l
0.50
11/20/03
23:42
STC
71-43-2
ND
ug/l
0.50
11/20/03
23:42
STC
108-86-1
ND
ug/l
0.50
11/20/03
23:42
STC
74-97-5
NO
ug/l
0.50
11/20/03
23:42
STC
75-27-4
NO
ug/l
0.50
11/20/03
23:42
STC
75-25-2
ND
ug/l
0.50
11/20/03
23:42
STC
74-83-9
NO
ug/l
1.0
11/20/03
23:42
STC
104-51-8
ND'
ug/l
0.50
11/20/03
23:42
STC
135-98-8
NO
- ug/l
0.50
11/20/03
23:42
STC
98-06-6
NO
ug/l
0.50
11/20/03
23:42
STC
56-23-5
NO
ug/l
0.50
11/20/03
23:42
STC
108-90-7
NO
ug/l
0.50
11/20/03
23:42
STC
75-00-3
ND
ug/l
0.50
11/20/03
23:42
STC
67-66-3
NO
ug/l
2.0
11/20/03
23:42
STC
74-87-3
NO
ug/l
0.50
11/20/03
23:42
STC
95-49-8
NO
ug/l
0.50
11/20/03
23:42
STC
106-43-4
ND
ug/l
2.0
11/20/03
23:42
STC
96-12-8
NO
ug/l
0.50
11/20/03
23:42
STC
124-48-1
NO
ug/l
0.50
11/20/03
23:42
STC
106-93-4
ND
ug/l
0.50
11/20/03
23:42
STC
74-95-3
NO
ug/l
1.0
11/20/03
23:42
STC
95-50-1
NO
ug/l
1.0
11/20/03
23:42
STC
541-73-1
NO
ug/l
-1.0
11/20/03
23:42
STC
106-46-7
ND
ug/l
0.50
11/20/03
23:42
STC
75-71-8
ND
ug/l
0.50
11/20/03
23:42
STC
75-34-3
NO
ug/l
0.50
11/20/03
23:42
STC
107-06-2
NO
ug/l
0.50
11/20/03
23:42
STC
75-35-4
NO
ug/l
0.50
11/20/03
23:42
STC
156-59.2
ND
ug/l
0.50
11/20/03
23:42
STC
156-60-5
ND
ug/l
0.50
11/20/03
23:42
STC
78-87-5
NO
ug/l
0.50
11/20/03
23:42
STC
142-28.9
NO
ug/l
0.50
11/20/03
23:42
STC
594-20-7
NO
ug/l
0.50
11/20/03
23:42
STC
563.58-6
ND
ug/l
0.50
11/20/03
23:42
STC
10061-01-5
NO
ug/l
0.50
11/20/03
23:42
STC
10061-02-6
NO
ug/l
0.50
11/20/03
23:42
STC
108-20.3
ND
ug/l
0.50
11/20/03
23:42
STC
100-41-4
REPORT OF LABORATORY ANALYSIS
Page: 6 of 31
Asheville Certification IN
This report shall not be reproduced, except in full,
Charlotte Certification IN
NC Wastewater
40
without the written consent of Pace Analytical Services, Inc.
NC Wastewater
12
NC Drinking Water
37712
N A oq
NC Drinking Water
37706
SC Environmental
99030�
SC
99006
FL NEI AP
E87648
�' P�a�
R ain AD
C:Q7a)7

0 0

aceAnalytical
www.pacelabs.com
Lab Sample No: 923533400
Client Sample ID: R87S5
Parameters
Hexachloro-1,3-butadi:en
Isopropylbenzene (Cumbn
p-Isopropyltoluene
Methylene chT ride
Methyl tern=butyl ether
n Propvlbenzene
1,1,1,2,Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
1-Chloro-3-fluorobenzene (S)
Date: 11/26/03
(
Pace Analytical
2225 Rip,
Asheville, ib
Phone: 828.25s
Fax: [phone],
Lab Project Number: 9254148
Client Project ID: MONITORING WELLS
Project Sample Number: 9254148-003 Date Collected: 11/12/03 11:52
Matrix: Water Date Received: 11/13/03 16:08
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
ND
ug/l
2.0
11/20/03
23:42
STC
87-68-3
NO
ug/l
0.50
11/20/03
23:42
STC
98-82'8
NO
ug/l
1.0
11/20/03
23:42
STC
99-87-6
NO
ug/l
2.0
11/20/03
23:42
STC
75-09-2
ND
ug/l
0.50
11/20/03
23:42
STC
1634-04-4
NO
ug/l
2.0
11/20/03
23:42
STC
91-20-3
NO
ug/l
0.50
11/20/03
23:42
STC
103-65-1
ND
ug/l
0.50
11/20/03
23:42
STC
100-42-5
NO
ug/l
0.50
11/20/03
23:42
STC
630-20-6
ND
ug/l
0.50
11/20/03
23:42
STC
79-34-5
ND
ug/l
0.50
11/20/03
23:42
STC
127-18-4
ND
ug/l
0.50
11/20/03
23:42
STC
108-88-3
NO
ug/l
2.0
11/20/03
23:42
STC
87-61-6
NO
ug/l
2.0
11/20/03
23:42
STC
120-82-1
ND
ug/l
0.50
11/20/03
23:42
STC
71-55-6
NO
ug/l
0.50
11/20/03
23:42
STC
79-00-5
NO
ug/l
0.50
11/20/03
23:42
STC
79-01-6
ND
ug/l
0.50
11/20/03
23:42
STC
75-69-4
ND
ug/l
0.50
11/20/03
23:42
STC
96-18-4
ND
ug/l
0.50
11/20/03
23:42
STC
95-63-6
NO
ug/l
0.50
11/20/03
23:42
STC
108-67-8
NO
ug/l
0.50
11/20/03
23:42
STC
75-01-4
ND
ug/l
0.50
11/20/03
23:42
STC
NO
ug/l
0.50
11/20/03
23:42
STC
95-47 6
118
%
11/20/03
23:42
STC
625-98-9
Page: 9 of 31
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs
This report shall not be reproduced, except in full,
Charlotte Certification IN
NC Wastewater
40
without the written consent of Pace Analytical Services, Inc.
NC Wastewater 12
NC Drinking Water
37712
go
��` '�
NC Drinking Water 37706
SC Environmental
FL NELAP
99030
E87648
�F
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ace Analytical °
www.pacelabs.com
y
Pace Analytica,
2225 Fs.,
Asheville;
Phone: 828.2,
Lab Project Number:
9334534 a,,. 828.252.
Client Project ID:
WELL ANALYSIS
L.ab Sample No:
931407282 �:
Project Sample Number: 9334534.003
Date Collected: 11/20/02 12:45
ilientSample ID:
WELL R87S5��'
Matrix: Water
Date Received: 11/21/02 15:00
, y
Parameters
s
Units Report Limit Analyzed By
CAS No. Qual RegLmt
Bioassay
pH
Method: EPA
150.1
ph
6.30
units 11/26/02 KAS
1
P
Metals `
ICP Metals, trace level
Prep/Method:
EPA 3010
/ EPA 200.7
Silver
NO
mg/1
0.0020
12/04/02 16:47
EWS 7440 22 4
Date D!gested
11/25/02
11/25/02
L et "Chemi stry
Total Dissolved Solids
Method: EPA
160.1
Total Dissolved Solids
290
mg/l
10.
11/25/02
WCB
Ammonia
Method: EPA
350.1
Nitrogen, Ammonia
1.69
mg/l
0.100
11/24/02
WWB 7727-37-9
Nitrogen, Nitrate plus Nitrite
Method: EPA
353.3
Nitrogen, Nitrite
0.15
mg/1
0.10
12/06/02
ALA -
`Nitrogen, Nitrate
NO
mg/l
0.10
12/06/02
ALA
Sulfate,Automated Colorimetric
Method: EPA
375.2
--Sulfate----- —
-9.6
5-0—--12-/-07/-02-----
=--ALA---
- = - —
Chemical Oxygen Demand
Method: EPA
410.4
Chemical Oxygen Demand
ND
mg/1
50.
11/26/02
EWS
Phenolics, Total Recoverable
Method: EPA
420.1
Phenolics, Total Recoverable
0.0136
mg/l
0.00500
12/07/02
ALA
Total Organic Carbon
Method`. EPA
9060
Total Organic Carbon
10.
mg/l
0.50
12/12/02
WWB 7440-44-0
Date: 12/12/02
d
GROUNDWATER SECTION age: 3 of 5
ASHEVILLE REGIONAL OFFICE
Laboratory Certification IDs REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
NC Wastewater 40 This report shall not be reproduced, except in full, TN Drinking Water 02980
NC Drinking Water 37712 without the written consent of Pace Analytical Services, inc. SC Environmental 99030
e�

0

,=31 FROM:PACE ANALYTICAL MAITA ID:6262524816
9" Kincey n..
Phone 7fi�,
�s^rvrr��zxm Fez: TOG.b.
Lab Sample No: 931407232
Client Sample ID: WELL R8795
Lab Project Number: 9238890
Client Project IDt Agfa/9334534
Project Sample Number: 9238890-003 Date Collected: 11/29/02 12:45
matrix.: Water Date Received: 11/21/02 15:00
Aaramnt.ers Results IInilta Report limit _Dl? - Analyzed BY CAS No_ Qiial- $agl=,,
GC Polatile8
GC vocs in water Method. SH 6230D
Benzene ND ug/l 0-50 1.0 11/26/02 18.11 STC 71-43-2
Bromobenzene ND ugll 0.50 1.0 11/26/02 18tll STC 108-86-1
Bromochloro:nethane ND us/1 0.5o 1.0 11/26/02 18:11 STC 74-97-5
Bromodichloromethane ND ug/1 0.5o 1.0 11/26/02 18:11 STC 75-27-4
Bromoform ND ug/l 0.50 1.0 11/26/02 18:11 STC 75-25-2
Bromomethana ND ug/1 0.50 1.0 11/26/02 18:11 STC74-83-9
n-Butylbenzene ND ug/l 1.0 1.0 11/26/02 18:11 STC 104-51-8
sac-Butylbenz9ae ND ug/l 0.50 1.0 11/26/02 18:11 STC 135-98-8
tort-Butylbeasene ND ug/1 0.50 1.0 11/26/02 18:11 STC 98-06-6
Carbon tetrachloride ND ug/1 0.50 1.0 11/26/02 18:11 STC 56-23-5
Chlorobanaane ND ug/l 0.50 1.0 11/26/02 18:11 STC 108-90-7
Chloroethane ND ug/Z 0.50 1.0 11/26/02 18:11 STC 75-00-3
Chloroform ND ug/1 0.50 1.0 11/26/02 18:11 STC 67-66-3
chloromethane ND ug/l 2-0 1.0 11/26/02 18:11 STC 74-87-3
2-Chlorotoluene ND ug/1 0.50 1.0 11/26/02 18:11 STC 95-494
4-Chlorotoluene ND ug/1 0.50 1.0 11/26/02 18:11 STC 106-43-4
1,2-Dibromo-3-chlorcpropane ND ug/l 2.0 1.0 11/26/02 18:11 STC 96-12-8
Dibromochloromethane ND ug/l 0.50 1.0 11/26/02 18:11 STC 124-48-1
1,2-Dibromoethane (EDB) ND ug/l 0_50 1.0 11/26/02 18:11 STC 106-53-4
Dibromomethane ND ug/l 0.50 1.0 11/26/02 18:11 STC 74-95-3
-- 1-2-Dichlorobeazene- - ----- ND- - ug/1------- ---_I-._0__---------- S.D_11126/02_16_;11_STC----_-
1,3-Dichlorobenzene ND ug/1 1.0 11.0 11/26/02 18:11 STC 541-73-1
1,4-Dichlorobeuzene ND ug/1 1.0 1.0 11/26/02 18:11 STC 106-46-7
DichrTorodifluosomethan® ND ug/i 0.50 1.0 11/26/02 18:11 STC 75-71-8
1,1-Dichloroethane ND ugll 0.50 1.0 11/26/02 18:11 STC 75-34-3
1,2-Dichloroethane ND ug/l 0.50 1.0 11/26/02 18=11 STC 107-06-2
lei-Dichloroethene ND ug/1 0.5o 1.0 11/26/02 18:11 STC 75-35.4
cis-1,2-Dichloroethene ND ug/1 0.50 1.0 11/26/02 18:11 STC 156-59-2
trans-1,2-Dichloroethene ND ug/l 0.50 1.0 11/26/02 18:11 STC 156-60-5
1,2-Dichloropropene ND ug/1 0.50 1:0 11/26/02 18:11 STC 78-87-5
1,3-Dichl6ropropane ND ug/l 0.50 1.0 11/26/02 18:11 STC 142-28-9
2,2-Dichloropropane ND ug/l 0.50 1.0 11/26/02 18:11 STC 594-20-7
1,1-Dichloropropene ND ug/1 0.5o 1.0 11/26/02 18:11 STC 563-58-6
cis-1,3-Dichloropropene ND ug/1 0.50 1.0 11/26/02 18:11 STC 10061-01-5
trans-1,3-11ichloropropene ND ug/l 0.50 1.0 11/26/02 18:11 STC 10061-02-6
Diisopropyl ether ND ug/1 0.50 1.0 11/26/02 18-11 STC 108-20-3
gthyibenzeae ID uy^/1 0.50 1.0 11/26/02 18t11 STC 100-41-4
JE n r n(j E ease: s of as
D1nsti®: s�lcsloa tv `f
1.
GROUNDWATER SECTION
Wsm
ASi-IEVILLE REGION
i ahCerirficalIDS REPORT OF KY Drinking rinking WaW 90040
NO Wast9warer 12 12
NO DMking Waltr 37706 This report shall not be reproduced, except in full, VA Driniang Water 213
Cr oof= wwnnrrt tho wmm anent of Pace Atka cal Semi m Inc - R MR AR €87=

0 0

-31 FROM:PACE ANALYTICAL MAITA ID:828252461B
Lab Sample No: 931407282
Client Sample ID: WELL R87S5
98W Kinney,
Nast &
Phase, )�
far 704.E
Lab Project Number: 9238890
Client Project TD: Agfa/9334534
Project Sample Number: 9238890-003 Data Collected: 11/20/02 12:45
Matrix: Water Date Received: 11/21/02 15:DD
Parameters _
Rasults
Units Report Limit
.Dl_
Analyred
by
CAS No. Dual RegLmt
Haxachloro-1,3-butadiene
ND
ug/1
2.0
1.0
11/26/02
18:11
STC
87-69-3
Isopropylbenzene (Cumene)
ND
ug/1
0.50
1.0
11/26/02
18:11
STC
98-82-8
p-I3opropyltoluene
ND
ug/1
1.0
1.0
11/26/02
18:11
STC
99-87-6
Methylene chloride
ND
ug/l
2.0
1.0
11/26/02
18:11
STC
75-09-2
Methyl -tart -butyl ether
ND
ug/1
0.50
1-0
11/26/02
18:11
STC
1634-04-4
Naphthalene
ND
ug/l
2.0
1.0
11/26/02
18:11
STC
91-20-3
n-Propylbenzene
ND
ug/l
0.50
1.0
11/26/02
18:11
STC
103-65-1
Styrene
ND
ug/1
0.50
1.0
11/26/02
18:11
STC
1DO-42-5
1,1,1,2-Tetrachloroethane
ND
ug/1
9.50
1.0
11/26/02
18:11
sac
630-20-6
1,1,2,2-Tetrachloroothane
ND
ug/1
0.50
1.0
11/26/02
18:11
STC
79-34-5
Tetrachloroetheae
ND
ug/1
0.50
1-0
11/26/02
18:11
STC
127-18-4
Toluene
ND
ug/1
0.S0
1-0
11/26/02
18.11
STC
108-88-3
1,2,3-Trichlorobenzens
ND
ug/1
2.0
1-0
11/26/02
18:11
STC
87-61-6
1,2,4-Tzichlorobenzene
ND
ug/1
2.0
1.0
11/26/02
18:11
STC
120-82-1
1,1,1-Trichloroetha.ne"
ND
ug/l
0.50
1.0
11/26/02
18:11
STC
71-55-6
1,1,2-Trichloroethane
ND
ug/1
0.50
1.0
11/26/02
18:11
STC
79-OD-5
Trichloroethene
ND
ug/l
0.50
1.0
12/26/02
18:11
STC
79-01-6
Trichlorofluoromethan.e
ND
ng/1
0.50
1.0
11/26/02
18:11
STC
75-69-4
1,2,3-Trichloroprnpane
ND
ug/1
0.50
1.0
11/26/02
18:11
STC
96-18-4
1,2,4-Trimethylbenzene
ND
ng/1
E SD
1.0
11/26/02
18:11
STC
95-63-6
1,3,5-Trimathylbenzene
ND
ug/1
0.50
1.0
12/26/02
19:11
STC
108-67-8
Vinyl chloride
ND
ug/l
0.50
1.0
11/26/02
18:11
STC
75-01-4
m&p-%ylene
)M
ug/1
0.50
1-0
11/26/02
18.11
STC
o-Rylene
ND
ug/1
0.50
1.0
11/26/02
18:11
STC
95-47-6
1-Chloro-3-fluorobenzene (S)
122
%
1.0
11/26/02
16:11
STC
625-98-9
Pat:*.- 12/03/02
i aherat0 "rmfion IDs
NC Wastewater 12
NC Drinking Wafer 37705
SC 99t108
D
Page. 6 of i8
��VATER SECT IOIvJ
ASHEVILLE REL.IOtNAL OFFICE
Qs
REPORT OF LABORATORY ANALYSIS KY Ddn�kiing Wafer��tion 90M
This report shalt not be reproduced. except in rub. VA Drinldnp Water 213
without the win consent of Pace Anatydcal Services. Inc. FL NELAP E879V

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MICROS`
Q
Pace Analytic.,
. 54 Rav
ace Analytical � �� acne:82
acelabs.com -� Phone:828.2
www,
P � Fax: 828.25,.
Lab Sample No: 931057012
Client Sample ID: WELL R87S5 ,
Bioassay
pH
pH
Metals
Lab Project Number: 9325207
Client Project ID: Wells/4500126184
Project Sample Number: 9325207-003 Date Collected: 11/27/01 12:25
Matrix: Water Date Received: 11/28/01'12:15
r
Results Units Report Limit Analyzed CAS No. Ftnote Reg Limit
Prep/Method: EPA 150.1 / EPA 150.1
6.03 units 11/29/01 JMS 1
ICP Meta " trace -level
Prep/Method:
EPA 3010
/ EPA 200.7
SJ,JVL-�r�
ND -
mg/l
0.0020
12/05/01 15:59
TRW 7440-22-4
0qL�a`e Digested
12/03/01
01`
Wet Chemistry
Total Dissolved Solids
Prep/Method:
EPA 160.1
/ EPA 160.1
Total Dissolved Solids
260
mg/l
10.
12/06/01
AAB
Ammonia
Prep/Method:
EPA 350.1
/ EPA 350.1
Nitrogen, Ammonia
0.700
mg/l
0.100
12/07/01
JDA 7727-37-9
Nitrogen, Nitrate plus Nitrite
Prep/Method:
EPA 353.2
/ EPA 353.3
Nitrogen, Nitrate
2.2
mg/l
0.10
11/29/01
JDA
Chemical Oxygen Demand
Prep/Method:
EPA 410.4
/ EPA 410.4
Chemical Oxygen Demand
NO
mg/l
50.
12/03/01
WWB
Phenolics, Total Recoverable
Prep/Method:
EPA 420.1
/ EPA 420.1
Phenolics, Total Recoverable
0.00700
mg/l
0.00500
12/10/01
JDA
Total Organic Carbon
Prep/Method:
SM 5310C / EPA 9060
Total Organic Carbon
60.
mg/l
4.0
12/12/01
AAB 7440.44-0
Date: 12/17/01
Page: 3
Laboratory Certification IDs REPORT OF LABORATORY ANALYSIS Laboratory Certification IN
NC Wastewater 40 TN Drinking Water 02980
This report shall not be reproduced, except in full,
NC Drinking Water 37712 SC Environmental 99030
without the written consent of Pace Analytical Services, Inc.
\N FCCpgD
� \C
h f
�: i-a

4

RESEARCh & ANALyTICAI
LAbORATOMES, INC.
AnalyticalfflmrPss Consultations
Chemical Analysis for Selected parameters and Sampling Locations
(A Face Analytical Services, InG Project fdentafiad as Agfa, collected 27 November 2001)
I. Volatile Organics
Imeetlon
EPA, Method 6230D
UmIts
R87S5
Faremeter
MID
TOLD
1,1-Dichloroethane
0.001
BDL
2,2-Dicbloropropafle
0.001
BDL
Chloroform
0.00I
BDL
1,1,1-Tricbloroethane
0.001
BDL
Dicbloroptopene
0.001
BDL
r1,1
Carbon Tetrachloride
0.001
BDL
Benzene
0.001
BDL
1,2-Dichloroetharre
0.001
BDL.
Trlchloroethene
0.001
BDL
1.2-pichloropropane
0.001
BDL
Mromomethane
0.001
BDL
Toluene `
0.001
BDL
1,1,2 Trichloroethane
0.001
BDL.
1,3-Dichloropropane
0.001
BpL
Tetmachloreetbene
0.001
BDL
1,1,1,2-Tetrachloroethanc
0.001
BDL
1,1,2,2-Tetrachtoroethane
0.001
BDL
1,2,3-Ttichloropropane'
0.001
BDL
Hoxachlorobutadiene
0.001
13DL
13romobenzene
0.001
BDL
1;thylbenzene
0.001
BDL
Styrene
0.001
BDL
HrnMofortn
0.001
BDL
p-Isopropyltoluene
0-001
BDL
N-Butylbenzene
0.001
BOL
Naphtbalenc
0.001
DT)L
1,3,5,T tnethylbenzene
0.001
B13L
1,2,4-Trimethylbenzene _
0.001
BDL
1,2,4-Trieblorobenzene
0,001
BDL
1,2,3-Trichlorobenzene
0,001
HDL
Chiorobenzene
0.001
BDL
2-Chlorotoluene
0.001
BDI.
4-Chlorotolueoe
0.001
BDL
Tent-Butylbenzene
0,001
BDL
Sec-Butylbenzeae
0.001
BDL
i,4-Dicblorobcnrene
0.001
BDL
1,2-Dicb1orobenzene
0.001
B13L
I-propylbenzene
0.001
HDL
N-Ptopylbenzene
0.001
13DL
1,3.Dichlorolicnzene
0.001
BDI.
Dibromochloromethane
0.001
BDL
Diahlorodifluaromethane
0.001
BDL
Chloromethane
0.001
BDL
Vinyl. Cblotide
0.001
SM
Bromometbane
0.001
HOL
Chlormtbane
0.001
BDL
Trichloroiluoromethane
0.001
BDL
1,1-Dichloroethene
0.001
BDL
Methylene Chloride
0,001
BDL
Trans-1,2 Dichloroetbene
0.001
BDL
Cis-1,2-Dichloroethenc
0.001
BDL
aromodiehloromethane
0.001
t3DL
13romochlorometbane
0.001
BDL
Cis-1,3-Dicbloropropena
0-001
BDL
Turns-1,3-Dichloropropene
0-001
BDL
Total Xylence
0.001
BDL
Dilution factor
1
Sample Number
437518
Sample Date
13/27/0l
1225
Sample Time (Hre)
mgl1. = milligrama Per Llter - Pans Pcr Millivh BDL Helow Detection Limits
rZO ti
fa' NC;
PN: L1..lwetom\6230tAPACP.0t CH

0

Pace Analye.,
9800 Kincey,
Hunters.
Phone: Ic
Fax. 704.,,
Lab Project Number: 9228135
Client Project ID: Agfa 9325207
-- .aor.Je— — V✓/Vim. ii VJ— OG uk— LYWIWCii J14V1✓✓—V V✓ —1. .—'
Client Sample ID: WELL R87S5 Matrix: Water Date Received: 11/28/01 12:15
Parameters Results Units Report Limit Dilution Analyzed CAS No. Ftnote Reg Limit
Wet Chemistry
Ion Chromatography Prep/Method: EPA 300.0 / EPA 300.0
Sulfate 5.7 mg/1 1.0 1.0 12/04/01 CBJ
Date: 12/04/01
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Page: 3
REPORT OF LABORATORY ANALYSIS Laboratory rankingWater
IN
KY Drinking Water 90090
This report shall not be reproduced, except in full, VA Drinking Water 213
without the written consent of Pace Analytical Services, Inc. FL NELAP E87627

0

Pace Analyi,,,
._ 9800 Kincey, .,
dX nal i{caf� Hunters,
WAV. pacelabs.com Phone: Fax: 704.E
Lab Project Number: 9228135
Client Project ID: Agfa 9325207
PARAMETER FOOTNOTES
ND Not Detected
NC Not Calculable
Date: 12/04/01
Laboratory certification IDs NC Wastewater 12 REPORT OF -LABORATORY ANALYSIS
NC Drinking Water 37706 This report shall not be reproduced, except in full,
Sc 99006 without the written consent of Pace Analytical Services, Inc.
Page: 4
Laboratory Certification IDs
KY Drinking Water 90090
VA Drinking Water 213
FL NELAP E87627

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NC DENR/DWQ Chemistry Laboratory
No signature
❑ Incomplete information
❑ Documentation
❑ Fieldsheet wet/illegible
0 Fieldsheet incomplete:
o Records not written in indelible ink
❑ Other (specify):
ount'.
Collector: I Atli
Priority:
Affected Parameters:.
The condition of these samples were not acceptable because (check all that apply):
❑ Samples (affected samples are described below)
Coolers
o Samples were not received on wet ice
❑
Samples not received, but listed on fieldsheet
u
No temperature blank submitted:
❑
Samples received, but not listed on fieldsheet
❑ Sample T° reading (IR gun): oC
C2
❑
Samples not received, but listed on COC
Samples received, but not listed on COC
❑ Cooler T° reading: °C
e
❑
Mislabeled as to tests, preservatives, etc.
❑
Temperature >6°C. T° reading: to . °C
❑
Holding time expired
❑
Samples frozen
C
improper container used
❑
Insufficient quantity for analysis
❑ Containers
❑
Leaking
❑ Chain
of Custody
❑
Broken
:INo
custody seals
❑
Without labels
❑
Custody seals not intact
❑
VOA vials with headspace
❑
Not relinquished.
❑
Sulfide samples with headspace
❑ No date/time relinquished
❑ Container Labels
❑ Not the same ID/info. as on COC
❑ Not the same ID/info. as on fieldsheet
❑ Incomplete. Missing the following:
❑ Station #/Sample ID
0 Collection date
❑ Collector
❑ Analysis
❑ Preservative
❑ Other:
❑ Markings smeared or illegible
❑ Tom
Comments:
Corrective Action:
❑ Samples were rejected by DWQ Lab. Authorized by:
❑ Accepted and_analyzed.per collector's request after notifying the collector.
❑ Accepted and analyzed:after notifying the client and determining that another sample could not be secured.
❑ Sample(s) on hold until:,:_
❑ Other (explain):
Person Contacted: t i\ t Date:/J /C
Form completed by: Date:_/�� r
Unit Leader Review (initial):
NUT VOA
WCH PEST
SVOA MET
11C
6/22/01dbs
QA\FormsZample ReceivinOCUR

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Agfa Corporation
P.O. Box 267
Staton Road
Brevard, NC 28712-0267
June 1, 2000
ANN C. RUMBOUGH
DEPARTMENT OF ENVIRONMENT, HEALTH
AND NATURAL RESOURCES
59 WOODFIN PLACE
ASHEVILLE, NC 28801
Dear Ms. Rumbough:
Attached is the analysis from our groundwater sampling on 5/9/01. Benzene was still
detected in well R87s5 but the level has come down under the 1 ppb limit.
If you have any questions, please call me at [phone].
Attachments
Si cerely,
R.ER D. GALLO�/'AY
ENVIRONMENTAL SPECIALIST
,JUN - i 2001
Gmundw*r Sedan
Asheville Reftmat Q ce -1

k

Environmental
Testing
Solutions, LLC
PO Box 790
Phone: [phone]
Pisgah Forest, NC 28768
Fax: [phone]
Certificate
of Analysis
Project name: AGFA Corporation
Project number: 010511.503
Collection date: 09-May-01
Date received: 11-May-01
Results:
Sample identification: Monitoring Well R87s3
_
Sample number: 1674
Parameters Method
Date Analyst Footnotes
Result
MDL
Units,
Analyzed
Ammonia Nitrogen EPA 350.3
100
2.0
mg/L
a-may-oi KEK 1
Results:
Sample identification: Monitoring Well R87s4
Sample number: 1675
Parameters Method
Date
Analyst Footnotes
Rest. -It
MDL
Units
Analyzed
Ammonia Nitrogen EPA 350.3
<0.1
0.1
mg/L
w-may-0i KEK
Results:
Sample identification: Monitoring Well R8s5
Sample number: 1676
Parameters Method
e
AnalDateed Analyst Footnotes
Result
MDL
Units
Ammonia Nitrogen EPA 350.3
0.72
0.1
mg/L
is-mayoi KEK
Results:
Sample identification: Monitoring Well R87s7
Sample number: 1677
Parameters Method
Result
MDL '
Units
Date Analyst Footnotes
AnalYzed
Ammonia Nitrogen EPA 350.3
0.13
0.1
mg/L
ia-gray-oi KEK
Footnotes:
1. MDL is 2.0 mg/L due to sample dilution.
NC Certification Number: 600 nn NC Drinking Water Certification Number: 37786
Y
-JUN — 7 20QL ,
Asheville

4
■@F a
�.,,�M}�ilFk` 4lMmwAlf,hsy{

TRITEST, INC.
3909 Beryl Road
Raleigh, NC 27607
Telephone: [phone]
Fax: [phone]
NC/WW Cert.#: 067
L a b o r a t o r y R e p o r t
- Prepared for - Page 1 of 1
KELLEY KEENAN / JIM Report Date: 5/21/01
ENVIRONMENTAL TESTING SOLUTION Date Received: 5/15/01
P.O. BOX 790
PISGAH FOREST, NC 28768 Work Order #: 0105-00539
Cust. Code: EN8193
Project ID: 01 Cust. P.O.# --
Project Info: AGFA CORP / MONITORING WELL
No. Sample ID Date Sampled Time Sampled Matrix Condition
001 MONITORING WELL R8755 5/09/2001 14:50 GW On Ice
Test Performed Method Results Tech Analyzed Qual
VOCs in GWSM 6230D MB 5/16/01
Benzene 6230D 0.728 ug/L MB 5/16/01
Report certified by:
for Tritest, Inc.
,
f
i
JUN - 7 2001
CrourtdWater $ecfion
Asheville Re Tonal Office
E
f
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-
Pace Analy k.
9800KiHunter
aceAnalytical
Hunterso,
www.pacelabs.com
Phone. 704.
Fax: 704.8,
AGFA Corporation
Lab Project Numt:er: 9220092
P. 0. Box 1176
Client Project ID: Agfa-931750
Brevard, NC 28712
Attn: Mr. Roger Galloway
Lab sample No: 93774438
Date Collected: /
Project sample N r: 9220092-001
Client Sample ID: WELL R87S5
Matrix: Water
Date Received: 01/23/01 13:50
Parameters Results units PRL Dilution Analyzed
Analyst CAS# Ftnote Limit
GC Volatiles
GC VCCs in Water
Method: SM 6230D Prep Method: SM 6230D
Benzene
1.4 ug/t 0.50 1.0 01/25/01
MAG 71-43-2
1-ChLoro-3-fluorobenzene (S)
95 % 1.0 01/25/01
MAG 625-98-9
Date: 01/29/01
Pam: 1
Laboratory Certification IN REPORT OF LABORATORY ANALYSIS
Laboratory Certification IN
NC Wastewater 12
KY Drinking Water 90090
NC Drinking Water 37706
This report shall not be reproduced, except in full,
TN UST List
Sc 99006 without the written consent of Pace Analytical Services, Inc.
VA Drinking Water 213

_ Pace Analytica,.
9800 Kincey Avo
aceAnalytical' Huntersv
www.pacelabs.com Phone: 704. a,
Fax: 704.875.
Lab Project Nurber: 9220092
Client Project ID: Agfa-93178!1)
PARAMETER FOOTNOTES
ND Not Detected
NC Not Calculable
PRL Pace Reporting Limit
(S) Surrogate
Date: 01/29/01 Page: 2
Laboratory Certification IDs REPORT �F LABORATORY ANALYSIS Laboratory Certification IN
NC Wastewater 12 KY Drinking Water 90090
NC Drinking Water 37706 This report shall not be reproduced, except in full, TN UST List
SC 99006 without the written consent of Pace Analytical Services, Inc. VA Drinking Water 213

0

-
Pace Analytic,
aceAnalytical
9800 KinceyA�,
Huntersvii,,
www.pacelabs.com
Phone: 704.,
Fax: 704.8i
QUALITY CONTROL DATA
Lab Project Nurber: 9220092
Client Project ID: Agfa-93178:0
OC Batch: 37303 OC Batch Method: SM 6230D
Analysis Method: SM 6230D Analysis Description: GC VOCs in Water
Associated Lab Samples: 93774438
METHOD BLANK: 921431235
Associated Lab Samples:
93774438
Method
Blank
Parameter Units Result PRL Footnotes
Benzene WT— ND --
1'•Chloro-3-fluorobenzene (S) % 96
LABCRATCRY CONTROL SAMPLE: 921431243
Spike LCS Spike
Parameter Units Conc. Result % Rec Footnotes
Benzene uT— —
1-Chloro-3-fluorobenzene (S) 97
Date: 01/29/01
Page: 3
Laboratory Certification lDs REPORT OF LABORATORY ANALYSIS
Laboratory Certification IDs
NC Wastewater 12
KY Drinking Water 9009090
NC Drinking Water 37706 This report shall not be reproduced, except in full,
TN UST List
Sc 99006 without the written consent of Pace Analytical Services, Inca
VA Drinking Water 213

EW
H
....... .....

Pace Analytica,.
j�ce /� nalytna/TM+ 9800 Kincntersv
IrGH� I {� Huntersvdle,
www.pacelabs.com Phone: 704. b,
Fax. 704.876.,
Lab Project Nurber: 9220092
Client Project ID: Agfa-931785)
QUALITY CONTROL DATA PARAMETER FOOTNOTES
Consistent with EPA guidelines unrou ded concentraticns are displayed and have been used to calculate % Rec and RPD values.
ND Not Detected
NC Not Calculable
PRL Pace Reporting Limit
RPD Relative Percent Difference
(S) Surrogate
Date: 01/29/01 Page: 4
Laboratory Certification IN REPORT �F LABORATORY Laboratory Certification IN
NC Wastewater 12 KY Drinking Water 90090
NC Drinking Water 37706 This report shall not be reproduced, except in full, TN UST List
Sc 99006 without the written consent of Pace Analytical Services, Inc. VA Drinking Water 213

0 0

Q
Agfa Corporation
P.O. Box 267
Staton Road
9b69''1'1A d 2001
ANN C. RUMBOUGH
DEPARTMENT OF ENVIRONMENT, HEALTH
AND NATURAL RESOURCES
59 WOODFIN PLACE
ASHEVILLE, NC 28801
Dear Ms. Rumbough:
Attached is the analysis from our groundwater sampling on well R87s5. We will sample
this well again in May for benzene as Kay Dechant requested.
If you have any questions, please call me at [phone].
Attachments
Sincerely,]
71
ROGER D. GALLOWAY
ENVIRONMENTAL SPECIALIST
E C E I avvV11111

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Pace Analytica.
IceAnal icaf- 5�
www.pacelabs.com Phc 828
DATE; 12/14/00
'I
PAGE: 4
Pace Project Number: 9316795
Client Project ID: Wells/4500119639
Pace Sample No: 93730356 Date Collected: 11/27/00 Matrix: Water
Client Sample ID: WELL R87S5 Date Received: 11/28/00
Parameters Results Units PRL Analyzed Analyst CAS# Footnotes
Bioassay
pH Method: EPA 150.1 Prep Method: EPA 150.1
PH 6.3units 0 11/29/00 HLL 1
Metals
ICP Metals, trace -level Method: EPA 200.7 Prep Method: EPA 3010
Silver NO mg/l 0.002 12/11/00 TRW 7440-22-4'
Date Digested 12/06/00
Wet Chemistry
Total Dissolved Solids- Method: EPA 160.1 Prep Method: EPA 160.1
Total Dissolved Solids 240 mg/l 10 12/01/00 JMS
Ammonia Method: EPA 350.3 Prep Method: EPA 350.3
Nitrogen, Ammonia 8.5 mg/l _0.1 12/08/00 JDA 7727.37-9
Nitrogen Nitrate plus Nitrite Method: EPA 353.3 Prep Method; EPA 353.3
Nitrogen, Nitrate 0.14, mg/l 0.1 12/07/00 JDA
Sulfate,Automated Colorimetric Method: EPA 375.2 Prep Method: EPA 375.2
Sulfate ND mg/l 5 12/07/00 JDA
Chemical OxygenDemandMethod: EPA 410.4 Prep Method: EPA`410.4
Chemical Oxygen Demand 66 mg/1 50 12/05/00 AAB
Phenolics, Total Recoverable Method: EPA 420.1 Prep Method: EPA 420.1
Phenolics, Total Recoverable 0.0067 mg/1 0.005 12/06/00 JMS 108.95-2
Total Organic Carbon Method: EPA 9060 Prep Method: SM 5310C
Total Organic Carbon NO mg/1 2 12/11/00 AAB 7440-44-0
Laboratory Certification IDs REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
NC Wastewater 40 TN Drinking Water 02980
NC Drinking Water 37712 This report shall not. be reproduced, except in full, - SC Environmental 99030
without the written consent of Pace Analytical Services, Inc.

0

IzeAnalj4ical"ac
Pace Anatytr,,,
l
9800 Krncey,r,
Huntersvr,
www.pacelabs.com
Phone: 704.
i
Fax. 704.8,
DATE: 12/13/00
PAGE: 5
Pace Project Number:
9218932
Client Project
ID:
Agfa-9316795
Pace Sample No: 93730356
Date
Collected:
11/27/00
Matrix: Water
Client Sample ID: WELL R87S5
Date
Received:.
11/28/00
Parameters
Results Units
PRL
App.
DF Analyzed
Analyst CAS# Footnotes
GC Votatiles
GC VOCs in Water
Method: SM 6230D
Prep Method: SM
6230D
Dichtorodiftuoromethane
ND
ug/L
0.5
1.00
12/09/00
KST
75-71-8
Chloromethane '
ND
ug/l
0.5
1.00
12/09/00
KST
74-87-3'
Vinyl Chloride
ND
ug/t
0.5
1.00
12/09/00
KST
75-0.1-4 -
Bromomethane
ND
ug/t
0.5
1.00
12/09/00
KST
74-83-9
Chloroethane
ND
ug/t
0.5
1.00
12/09/00
KST
75-00-3
Trichtoroftuoromethane
ND'
ug/L
0.5
1.00
- 12/09/00
KST
75-69-4
1,1-Dichloroethene
ND
ug/l
0.5
1.00
12/09/00
KST
75-35-4
Methylene Chloride
ND
ug/l
0.5
1.00
12/09/00
KST
75-09-2
trans-1,2-Dichloroethene
ND
ug/L
0.5
1.00
12/09/00
KST'
156-60-5
1,1-Dichloroethane
ND
ug/L
0.5
1.00
12/09/00
KST
75-34-3
cis-1,2-Dichloroethene
ND
ug/l
0.5
1.00
12/09/00
KST
156-59-2
BromochLoromethane
ND
ug/L
0.5
1.00
12/09/00
KST
74-97-5
Chloroform
ND
ug/L
0.5
1.00
12/09/00
KST
67-66-3
2,2-Dichtoropropane
ND
ug/l
0.5
1.00
12/09/00
KST
594-20-7
1,2-Dichloroethene
ND
ug/L
0.5
1.00
12/09/00
KST
107-06-2
1,1,1-Trichloroethane
ND
ug/L
0.5
1.00
12/09/00
KST
71-55-6
1,1-Dichloropropene
ND
ug/L
0.5
1.00
12/09/00
KST
563-58-6
Carbon Tetrachloride
ND
ug/l
0.5
1.00
12/09/00
KST
56-23-5
Dibromomethane
ND
ug/l
0.5
1.00
12/09/00
KST
74-95-3
1,2-Dichloropropane
ND
ug/l '
0.5
1.00
12/09/00
KST
78-87-5
Trichloroethene
ND
ug/L
0.5
1.00
12/09/00
KST
79-01-6
Bromodichtoromethane,
ND
ug/"L
0.5
1.00
12/09/00
KST
75-27-4
cis-1,3-Dichtoropropene
ND.
ug/t
0.5
1.00
12/09/00
KST
10061-01-5
trans-1,3-Dichtoropropene
ND
ug/l
0.5
1.00
12/09/00
KST
10061-02-6
1,1,2-TrichLoroethane
ND
ug/L
0.5
1.00
12/09/00
KST
79-00-5
1,3-Dichloropropane
ND
ug/t
0.5
1.00
12/09/00
KST
142-28-9
Dibromochloromethane
ND
ug/l
0.5
1.00
12/09/00
KST
124-48-1
1,2-Dibromoethane
ND
ug/L
0.5
1.00
'12/09/00
KST
106-93-4
Tetrachtoroethene
ND
ug/L
0.5:
1.00 -
12/09/00
KST
127-18-4
1,1,1,2-Tetrachloroethane
ND
ug/t
0.5
1.00
12/09/00
KST
630-20-6
Chtorobenzene -
ND
ug/L
0.5
1.00
12/09/00
KST
108-90.7
Bromoform
ND
ug/L
0.5
1.00
12/09/00-
KST
75-25-2
1,1,2,2-Tetrachtoroethane
ND
ug/t
0.5
1.00
12/09/00 'KST
79-34-5
1,2,3-Trichtoropropane
ND
ug/l
0.5
1.00
12/09/00
KST
96-18-4
Bromobenzene
ND
ug/L
0.5
1.00
12/09/00
KST
108-86-1
2-Chlorotoluene
ND
ug/t
0.5
1.00
12/09/00
KST
95-49-8
Laboratory Certification IN
Wastewater 12
REPORT OF
LABORATORY ANALYSIS
Laboratory Certification INNC
NC Drinking Water 37706
This report shall not be reproduced, except in full,
KY Drinking Water 90090
TN UST List
Sc 99006
without the written
consent
of Pace Analytical Services, Inc.
VA Drinking Water 213

0

aceAnalytical"
M
www.pacelabs.com
' Pace Analytic
9800 Kinc6y .7.
Hunlersv
Phcce 705.
Pax. 704. &,
DATE: 12/13/00
PAGE: 6
Pace Project Number: 9218932
Pace Sample No: _93730356
Date
Collected:
11/27/00
Matrix: Water
Client Sample ID: WELL R87S5
Date
Received:
11/28/00
Parameters
Results Units
PRL
App.
DF Analyzed
Analyst CAS#
Footnotes
4-Chlorotoluene
ND
ug/t
0.5
1.00
12/09/00
KST
106-43-4
1,3-Dichlorobenzene
ND
ug/L
1
1.00
12/09/00
KST
541-73-1
1,4-Dichlorobenzene
ND
ug/L
1
1.00
12/09/00
KST
106-46-7
1,2-Dichlorobenzene
ND
ug/l
1
1.00
12/09/00
KST
95-50-1
1,2-Dibromo-3-Chtoropropane
ND
ug/l
2
1.00
12/09/00
KST
96-12-8
1,2,4-Trichlorobenzene
ND
.ug/L
2
1.00
12/09/00
KST
120-82-1
Hexachloro-1,3-butadiene
ND
ug/l
2
1.00
12/09/00
KST
87-68-3
1,2,3-Trichlorobenzene
ND
ug/l
2
1.00
12/09/00
KST
87-61-6
MethyL-tert-butyl Ether
ND
ug/l
0.5
1.00
12/09/00
KST
1634-04-4
Diisopropyl ether
ND
ug/l
0.5
1.00
12/09/00
KST
108-20-3
Benzene
2.6
ug/t
0.5
1.00
12/09/00
KST
71-43-2
Toluene
ND
ug/L
0.5
1.00
12/09/00
KST
108-88-3
Ethylbenzene
ND
ug/l
0.5
1.00
12/09/00
KST
100-41-4
m&p-Xylene
ND
ug/L
0.5
1.00
12/09/00
KST
7816-60-0'
Styrene
ND
ug/L
0.5
1.00
12/09/00
KST
100-42-5
o-Xylene (1,2-DimethyLbenzene)
ND
ug/l
0.5
1.00
12/09/00
KST
95-47-6
Isopropylbenzene (Cumene)
ND
ug/l
0.5
1.00
12/09/00
KST
98-82-8
n-Propylbenzene
ND
ug/L
0.5
1.00
12/09/00
KST
103-65-1
1,3,5-TrimethyLbenzene
ND
ug/L
0.5
1.00
12/09/00
KST
108-67-8
tert-Butylbenzene_
ND
ug/t
0.5
1.00
12/09/00
KST
98-06-6
1,2,4-Trimethylbenzene
ND
ug/L
0.5
1.00
12/09/00
KST
95-63-6
sec-Butylbenzene
ND
ug/L
0.5
1.00
12/09/00
KST
135-98-8
p-Isopropyltoluene
ND
ug/l
1
1.00
12/09/00
KST
99-87-6
n-Butylbenzene
ND
ug/t
1
1.00
12/09/00
KST
104-51-8
Naphthalene
ND
ug/l
2
1.00
12/09/00
KST
91-20-3
1-Chloro-3-fLuorobenzene (S)''
109
- Y
1.00
12/09/00
KST
625-98-9
Laboratory Certification IN
REPORT of LABORATORY AHALYS�S
Laboratory Certification IN
NC Wastewater 12
s7
KY
Drinking Water 90090
NC Drinking Water 37706
This report
shall not
be reproduced, except in full,
TN
LIST List
SC 99006_
without the written consent of Pace Analytical Services, Inc;
VA
Drinking Water 213

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DDK Environmental, Inc.
LABORATORY DIVISION
506 Colwell Drive Phone: [phone]
Brevard, NC 28712 Fax: [phone]
Certificate of Analysis
Project name: AGFA Monitoring Wells Project number: 000503.516
Collection date: 2-May-00
Date received: 3-May-00
Results:
Sample identification: Well R87s3 Sample number: 2026
Parameters Method Result MDL Units Footnotes
Ammonia, Nitrogen
EPA 350.3 104 2.0 mg/l
Sample identification: Well R87s4
Parameters Method
Result
Sample number: 2027
MDL Units
Footnotes
Ammonia, Nitrogen EPA 350.3 7.7
0.10 mg/l
Sample identification: Well R87s5
Sample number: 2028
Parameters Method Result
MDL Units Footnotes
Ammonia, Nitrogen EPA 350.3 <0.1
0.10 mg/l
Sample identification: Well R87s7
Sample number: 2029
Parameters
Method
Result
MDL
Units Footnotes
Ammonia, Nitrogen
EPA 350.3
<0.1
0.10
mg/1
NC Certification Number: 588 NC Drinking Water Certification Number: 37778 SC Certification Number: 99052

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0

Pace Analytical,
ice Analytical 54 Raven.
Asheville,
Tel: 828-254
Fax: [phone]L
DATE: 11/23/99
PAGE: 4
Pace Project Number: 939118
Client Project ID: Wells/4500095496
Pace Sample No: 93403129
Date
Collected: 11/08/99
Matrix: Water
Client Sample ID: WELL R8755
Date
Received: 11/09/99
Parameters
---------------------------------
Resuits Units
---------- ---------
PRL
----------
Analyzed
--------
Analyst
-----
CAS#
----------
Footnotes
----------
Bioassay
PH
Method: EPA
150.1
Prep
Method: EPA
150.1
PH
6.1
units
0
11/09/99
RCS
1
Metals
ICP Metals, trace -level
Method: EPA
200.7
Prep
Method: EPA
3010
Silver
ND
mg/1
0.002
11/10/99
TRW
7440-22-4
Date Digested
11/10/99
Wet Chemistry
Total Dissolved Solids
Method: EPA
160.1
Prep
Method: EPA
160.1
Total Dissolved Solids
340
mg/l
1
11/15/99
JMS
Ammonia
Method: EPA
350.3
Prep
Method: EPA
350.3
Nitrogen, Ammonia
ND
mg/t
0.1
11/15/99
AAB
7727-37-9
Nitrogen, Nitrate plus Nitrite
Method: EPA
353.3
Prep
Method: EPA
353.3
Nitrogen, Nitrate
NO
mg/l
0.1
11/16/99
JDA
Sulfate, Total
Method: EPA
375.4
Prep
Method: EPA
375.4
Sulfate
5.79
mg/t
1
11/16/99
AAB
Chemical Oxygen Demand
Method: EPA
410.4
Prep
Method: EPA
410.4
Chemical Oxygen Demand
86
mg/1
50
11/17/99
AAB
Phenolics, Total Recoverable
Method: EPA
420.1
Prep
Method: EPA
420.1
Phenolics, Total Recoverable
0.007 mg/l
0.005
11/11/99
JDA
108-95-2
Totat Organic Carbon
Method: EPA
9060
Prep
Method: SM 5310C
Total Organic Carbon
17
mg/1
2
11/22/99
JDA
7440-44-0
Laboratory Certification IDs Laboratory Certification IDs
NC Wastewater 40 REPORT OF LABORATORY ANALYSIS TN Drinking Water 02980
NC Drinking Water 37712 SC Environmental 99030
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.

0 0

i
Pace Analytical b
9800 Kincey Avenue,
race Analytical Huntersville, Nu
Tel: 704-87E
DATE: 11/1P09704-87;
PAGE: 4
Pace Sample No: 93403129
Client Sample ID: WELL R8755
Pace Project Number: 929942
Client Project ID: Sterling-939118
Date Collected: 11/08/99 Matrix: Water
Date Received: 11/10/99
Parameters Results Units PRL App. OF Analyzed Analyst CAS# Footnotes
--------------------------------- ------------------- ------------------ -------- ----- ----------
GC/MS Volatiles
Volatile GC/MS by 624
Method: EPA 624
Prep Method:
EPA 624
Chloromethane
NO
ug/t
5
1.00
11/15/99
RPJ
74-87-3
Vinyl Chloride
ND
ug/l
5
1.00
11/15/99
RPJ
75-01-4
Bromomethane
NO
ug/l
5
1.00
11/15/99
RPJ
74-83-9
Chloroethane
ND
ug/t
5
1.00
11/15/99
RPJ
75-00-3
Trichlorofluoromethane
ND
ug/l
5
1.00
11/15/99
RPJ
75-69-4
1,1-Dichloroethene
NO
ug/l
5
1.00
11/15/99
RPJ
75-35-4
Methylene Chloride
ND
-ug/l
5
1.00
11/15/99
RPJ
75-09-2
trans-1,2-Dichloroethene
NO
ug/l
5
1.00
11/15/99
RPJ
156-60-5
1,1-Dichloroethane
ND
ug/l
5
1.00
11/15/99
RPJ
75-34-3
cis-1,2-Dichloroethene
NO
ug/l
5
1.00
11/15/99
RPJ
156-59-2
Chloroform
ND
ug/l
5
1.00
11/15/99
RPJ
67-66-3
1,1,1-Trichloroethane
ND
ug/l
5
1.00
11/15/99
RPJ
71-55-6
1,2-Dichloroethane
NO
ug/t
5
1.00
11/15/99
RPJ
107-06-2
Carbon Tetrachloride
ND
ug/l
5
1.00
11/15/99
RPJ
56-23-5
Benzene
NO
ug/t
5
1.00
11/15/99
RPJ
71-43-2
Trichloroethene
ND
ug/l
5
1.00
11/15/99
RPJ
79-01-6
1,2-Dichloropropane
NO
ug/l
5
1.00
11/15/99
RPJ
78-87-5
Bromodichloromethane
NO
ug/t
5
1.00
11/15/99
RPJ
75-27-4
2-Chloroethyl Vinyl Ether
NO
ug/t
10
1.00
11/15/99
RPJ
110-75-8
cis-1,3-Dichloropropene
NO
ug/t
5
1.00
11/15/99
RPJ
10061-01-5
Toluene
NO
ug/l
5
1.00
11/15/99
RPJ
108-88-3
trans-1,3-Dichloropropene
ND
ug/t
5
1.00
11/15/99
RPJ
10061-02-6
1,1,2-Trichloroethane
NO
ug/l
5
1.00
11/15/99
RPJ
79-00-5
Dibromochloromethane
ND
ug/t
5
1.00
11/15/99
RPJ
124-48-1
Tetrachloroethene
NO
ug/l
5
1.00
11/15/99
RPJ
127-18-4
Chlorobenzene
ND
ug/l
5
1.00
11/15/99
RPJ
108-90-7
Ethylbenzene
NO
ug/t
5
1.00
11/15/99
RPJ
100-41-4
Bromoform
ND
ug/t
5
1.00
11/15/99
RPJ
75-25-2
1,1,2,2=Tetrachloroethane
NO
ug/l
5
1.00
11/15/99
RPJ
79-34-5
1,3-Dichlorobenzene
NO
ug/t
5
1.00
11/15/99
RPJ
541-73-1
1,4-Dichlorobenzene
NO
ug/l
5
1.00
11/15/99
RPJ
106-46-7
1,2-Dichlorobenzene
ND
ug/l
5
1.00
11/15/99
RPJ
95-5071
Dibromofluoromethane (S)
92
%
1.00
11/15/99
RPJ
1868-53-7
Toluene-d8 (S)
103
%
1.00
11/15/99
RPJ
2037-26-5
4-Bromofluorobenzene (S)
97
%
1.00
11/15/99
RPJ
460-00-4
Laboratory Certification IDs Laboratory Certification IDNC s
NC Drinking Water 37706 REPORT OF LABORATORY ANALYSIS N Drinking iWater 90090
Sc 99006 This report shall not be reproduced, except in full, VA Drinking Water 213
without the written consent of Pace Analytical Services, Inc.

0 0
..............

Pace Sampte No: 93403137
Client Sample ID: TRAVEL BLANK
Pace Analytical St
9800 Kincey Avenue, ;
Huntersville, NC .
Tel: [phone]
Fax: [phone])
DATE: 11/19/99
PAGE: 5
Pace Project Number: 929942
Ctient Project ID: Sterling-939118
Date Collected: 11/08/99 Matrix: Water
Date Received:, 11/10/99
Parameters Results Units PRL App. DF Analyzed Analyst CAS# Footnotes
--------------------------------- ---------- --------- ---------- -------- ---- -------------------------
GC/MS Votatiles
Volatile GC/MS by 624
Method: EPA 624
Prep Method:
EPA 624
Chloromethane
ND
ug/t
5
1.00
11/15/99
RPJ
74-87-3
Vinyl Chloride
ND
ug/t
5
1.00
11/15/99
RPJ
75-01-4
Bromomethane
ND
ug/l
5
1.00
11/15/99
RPJ
74-83-9
Chloroethane
ND
ug/l
5
1.00
11/15/99
RPJ
75-00-3
Trichtorofluoromethane
ND
ug/l
5
1.00
11/15/99
RPJ
75-69-4
1,1-Dichloroethene
ND
ug/l
5
1.00
11/15/99
RPJ
75-35-4
Methylene Chloride
ND
ug/l
5
1.00
11/15/99
RPJ
75-09-2
trans-1,2-Dichloroethene
ND
ug/l
5
1.00
11/15/99
RPJ
156-60-5
1,1-Dichloroethane
ND
ug/t
5
1.00
11/15/99
RPJ
75-34-3
cis-1,2-Dichloroethene
ND
ug/t
5
1.00
11/15/99
RPJ
156-59-2
Chloroform
ND
ug/l
5
1.00
11/15/99
RPJ
67-66-3
1,1,1-Trichloroethane
ND
ug/l
5
1.00
11/15/99
RPJ
71-55-6
1,2-Dichloroethane
ND
ug/l
5
1.00
11/15/99
RPJ
107-06-2
Carbon Tetrachloride
ND
ug/l
5
1.00
11/15/99
RPJ
56-23-5
Benzene
ND
ug/l
5
1.00
11/15/99
RPJ
71-43-2
Trichloroethene
ND
ug/L
5
1.00
11/15/99
RPJ
79-01-6
1,2-Dichloropropane
ND
ug/t
5
1.00
11/15/99
RPJ
78-87-5
Bromodichloromethane
ND
ug/L
5
1.00
11/15/99
RPJ
75-27-4
2-Chloroethyl Vinyl Ether
ND
ug/l
10
1.00
11/15/99
RPJ
110-75-8
cis-1,3-DichLoropropene
ND
ug/l
5
1.00
11/15/99
RPJ
10061-01-5
Toluene
ND
ug/l
5
1.00
11/15/99
RPJ
108-88-3
trans-1,3-Dichloropropene
ND
ug/t
5
1.00
11/15/99
RPJ
10061-02-6
1,1,2-Trichloroethane
ND
ug/t
5
1.00
11/15/99
RPJ
79-00-5
Dibromochloromethane
ND
ug/t
5
1.00
11/15/99
RPJ
124-48-1
Tetrachtoroethene
ND
ug/t
5
1.00
11/15/99
RPJ
127-18-4
Chlorobenzene
ND
ug/l
5
1.00
11/15/99
RPJ
108-90-7
Ethylbenzene
ND
ug/l
5
1.00
11/15/99
RPJ
100-41-4
Bromoform
ND
ug/L
5
1.00
11/15/99
RPJ
75-25-2
1,1,2,2-Tetrachloroethane
ND
ug/t
5
1.00
11/15/99
RPJ
79-34-5
1,3-Dichlorobenzene
ND
ug/t
5
1.00
11/15/99
RPJ
541-73-1
1,4-Dichlorobenzene
ND
ug/t
5
1.00
11/15/99
RPJ
106-46-7
1,2-Dichlorobenzene
ND
ug/l
5
1.00
11/15/99
RPJ.
95-50-1
Dibromofluoromethane (S)
90
%
1.00
11/15/99
RPJ
1868-53-7
Toluene-d8 (S)
101
%
1.00
11/15/99
RPJ
2037-26-5
4-Bromofluorobenzene (S)
96
%
1.00
11/15/99
RPJ
460-00-4
Laboratory Certification IDs Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS N Drinking Water 90090
TN
NC Drinking Water 37706 UST List
Sc 99006 This report shall not be reproduced, except in full, VA Drinking Water 213
without the written consent of Pace Analytical Services, Inc.

0 0

Pace Analytical S.
9800 Kincey Avenue,
Huntersville, NG
Tel: [phone]L
Fax:[phone],
DATE: 11/19/99
PAGE: 6
Pace Project Number: 929942
Client Project ID: Sterling-939118
PARAMETER FOOTNOTES
ND Not Detected
NC Not Calculable
PRL Pace Reporting Limit
(S) Surrogate
App. DF Applied Dilution Factor
Laboratory Certification IDs Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Drinking Water 90090
TN
NC Drinking Water 37706 TN UST List
SC 99006 This report shall not be reproduced, except in full, VA Drinking Water 213
without the written consent of Pace Analytical Services, Inc.

0 0

Sterling Diagnostic Imaging
P. 0. Box 267
Brevard, NC 28712
Attn: Mr. Roger Galloway
QC Batch ID: 19568
Analysis Method: EPA 624
Associated Pace Samples:
METHOD BLANK: 92720127
Associated Pace Samples:
QUALITY CONTROL DATA
-� Pace Analytical
9800 Kincey Avenue,
Huntersville, NC.
Tel: [phone].
Fax: [phone].
DATE: 11/19/99
PAGE: 7
Pace Project Number: 929942
Client Project ID: Sterling-939118
QC Batch Method: EPA 624
Analysis Description: Volatile GC/MS by 624
93403103 93403111 93403129 93403137
93403103 93403111 93403129 93403137
Method
Blank
Parameter
Units
Result PRL Footnotes
Chloromethane
ug/l
ND 5
Vinyl Chloride
ug/t
ND 5
Bromomethane
ug/l
ND 5
Chtoroethane
ug/t
ND 5
Trichlorofluoromethane
ug/l
ND 5
1,1-Dichloroethene
ug/l
ND 5
Methylene Chloride
ug/t
ND 5
trans-1,2-Dichloroethene
ug/l
ND 5
1,1-Dichloroethane
ug/t
ND 5
cis-1,2-Dichloroethene
ug/l
ND 5
Chloroform
ug/t
ND 5
1,1,1-Trichloroethane
ug/t
ND 5
1,2-Dichloroethane
ug/t
ND 5
Carbon Tetrachloride
ug/l
ND 5
Benzene
ug/l
ND 5
Trichloroethene
ug/t
ND 5
1,2-Dichloropropane
ug/t
ND 5
Bromodichloromethane
ug/t
ND 5,
2-Chloroethyl Vinyl Ether
ug/l
ND 10
cis-1,3-Dichloropropene
ug/l
ND 5
Toluene
ug/t
ND 5
trans-1,3-Dichloropropene
ug/l
ND 5
1,1,2-Trichloroethane
ug/l
ND 5
Dibromochloromethane
ug/l
ND 5
Tetrachloroethene
ug/l
ND 5
Laboratory Certification IDs
Laboratory Certification IDs
NC ater
37706
REPORT LABORATORY
Drinking Water g°°g°
NC Drinking Water
OF ANALYSIS
N i
Sc 99006
This report shall not be reproduced, except in full,
VA Drinking Water 213
without the written consent of Pace Analytical Services, Inc

METHOD BLANK: 92720127
Associated Pace Samples:
93403103
Parameter Units
Chlorobenzene
ug/t
Ethylbenzene
ug/l
Bromoform
ug/L
1,1,2,2-Tetrachloroethane
ug/t
1,3-Dichlorobenzene
ug/t
1,4-Dichlorobenzene
ug/t
1,2-Dichlorobenzene
ug/L
Dibromoftuoromethane (S)
%
Toluene-d8 (S)
%
4-Bromofluorobenzene (S)
%
Pace Analytical
9800 Kincey Avenue
Huntersville, N
Tel: 704-875
Fax: [phone],
QUALITY CONTROL DATA DATE: 11/19/99
PAGE: 8
Pace Project Number: 929942
Client Project ID: Sterling-939118
93403111 93403129 93403137
Method
Blank
Result PRL Footnotes
---------- ---------- ----------
ND 5
ND 5
ND 5
NO 5
NO 5
ND 5
ND 5
92
103
98
MATRIX SPIKE 8 MATRIX SPIKE
DUPLICATE:
92720135
92720143
Spike
Parameter
------------------------------
Units
93403103
Conc.
Chloromethane
----------
ug/L
----------
0
-------
20
Vinyl Chloride
ug/l
0
20
Bromomethane
ug/L
0
20
Chloroethane
ug/l
0
20
Trichlorofluoromethane
ug/t
0
20
1,1-Dichloroethene
ug/l
0
20
Methylene Chloride
ug/l
0
20
trans-1,2-Dichloroethene
ug/l
0
20
1,1-Dichloroethane
ug/l
0
20
cis-1,2-Dichloroethene
ug/t
0
20
Chloroform
ug/l
0
20
1,1,1-Trichloroethane
ug/t
0
20
1,2-Dichloroethane
ug/l
0
20
Carbon Tetrachloride
ug/l
0
20
Benzene
ug/L
0
20
Trichloroethene
ug/l
0
20
1,2-Dichloropropane
ug/l
0
20
Bromodichloromethane
ug/t
0
20
2-Chloroethyl Vinyl Ether
ug/l
0
40
cis-1,3-Dichloropropene
ug/L
0
20
Toluene
ug/l
0
20
trans-1,3-Dichloropropene
ug/L
0
20
Laboratory Certification IDs
Matrix
Matrix
Spike
Spike
Spike
Sp. Dup.
Dup
Result
% Rec
Result
% Rec
RPD
13.74
68.7
12.76
63.8
7
9.990
50.0
9.421
47.1
6
13.92
69.6
12.87
64.3
8
14.95
74.8
13.69
68.4
9
13.60
68.0
12.57
62.8
8
15.43
77.2
14.42
72.1
7
13.55
67.7
13.33
66.6
2
15.85
79.2
15.06
75.3
5
14.75
73.8
14.51
72.6
2
15.04
75.2
14.63
73.2
3
15.08
75.4
14.95
74.7
1
16.24
81.2
15.79
79.0
3
12.63
63.1
12.73
63.6
1
15.19
76.0
14.27
71.3
6
15.83
79.2
15.46
77.3
2
18.43
92.2
18.02
90.1
2
15.32
76.6
15.09
75.4
2
13.71
68.5
13.49
67.4
2
0
0
0
0
0
14.49
72.5
14.11
70.6
3
17.89
89.4
17.44
87.2
2
14.68
73.4
14.37
71.8
2
NC Wastewater 12 NC Drinking Water 37706 REPORT OF LABORATORY ANALYSIS
Sc 99006 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Footnotes
a
Laboratory Certification IDs
KY Drinking Water 90090
TN UST List
VA Drinking Water 213

0 0

Pace Analytical
9800 Kincey Avenue,
eace Analvtical Huntersville N,
Tel: 704-875
Fax:[phone]a
QUALITY CONTROL DATA DATE: 11/19/99
PAGE: 9
Pace Project Number: 929942
Client Project ID: Sterling-939118
MATRIX SPIKE 8 MATRIX SPIKE
DUPLICATE:
92720135
92720143
Matrix
Matrix
Spike
Spike
Spike
Sp. Dup.
Parameter
------------------------------
Units
----------
93403103
----------
Conc.
Result
% Rec
Result
1,1,2-Trichloroethane
ug/l
0
-------
20
----------
16.75
-----
83.7
----------
16.89
Dibromochloromethane
ug/l
0
20
13.61
68.1
13.71
Tetrachloroethene
ug/l
0
20
15.27
76.4
15.16
Chlorobenzene
ug/l
0
20
17.45
87.3
17.36
Ethylbenzene
ug/l
0
20
15.10
75.5
15.08
Bromoform
ug/l
0
20
12.58
62.9
12.44
1,1,2,2-Tetrachloroethane
ug/l
0
20
13.47
67.3
13.96
1,3-Dichlorobenzene
ug/l
0
20
16.87
84.3
17.26
1,4-Dichlorobenzene
ug/t
0
20
16.55
82.7
17.21
1,2-Dichlorobenzene
ug/l
0
20
15.88
79.4
16.55
Dibromofluoromethane (S)
94
Toluene-d8 (S)
104
4-Bromofluorobenzene (S)
99
LABORATORY CONTROL SAMPLE:
92720168
Spike
LCS
Spike
Parameter
------------------------------
Units
----------
Conc.
Result
% Rec Footnotes
Chloromethane
ug/l
-------
20
----------
14.85
----- ----------
74.2
Vinyl Chloride
ug/l
20
11.02
55.1
Bromomethane
ug/l
20
14.45
72.2
Chtoroethane
ug/l
20
16.47
82.3
Trichlorofluoromethane
ug/l
20
15.24
76.2
1,1-Dichloroethene
ug/t
20
17.16
85.8
Methylene Chloride
ug/l
20
18.12
90.6
trans-1,2-Dichloroethene
ug/l
20
17.38
86.9
1,1-Dichloroethane
ug/l
20
16.31
81.6
cis-1,2-Dichloroethene
ug/l
20
16.38
81.9
Chloroform
ug/l
20
16.48
82.4
1,1,1-Trichloroethane
ug/l
20
17.92
89.6
1,2-Dichloroethane
ug/l
20
13.69
68.5
Carbon Tetrachloride
ug/t
20
16.86
84.3
Benzene
ug/t
20
17.19
85.9
Trichtoroethene
ug/t
20
20.47
102
1,2-Dichloropropane
ug/l
20
16.90
84.5
Bromodichloromethane
ug/l
20
15.50
77.5
2-Chloroethyl Vinyl Ether
ug/l
40
29.62
74.0
cis-1,3-Dichloropropene
ug/l
20
16.17
80.9
Toluene
ug/l
20
19.66
98.3
trans-1,3-Dichloropr^opene
ug/l
20
16.22
81.1
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NC Wastewater 12
REPORT OF LABORATORY ANALYSIS
NC Drinking Water 37706
Sc 99006
This report shall not
be reproduced, except in full,
without the
written consent of Pace Analytical Services, Inc.
Spike
Dup
% Rec
RPD Footnotes
84.5
1
68.5
1
75.8
1
86.8
1
75.4
0
62.2
1
69.8
4
86.3
2
86.0
4
82.7
4
93
103
98
Laboratory Certification IDs
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c 0

QUALITY CONTROL DATA
LABORATORY CONTROL SAMPLE: 92720168
Pace Analytical
9800 Kincey Avenue,
Huntersville, NL
Tel: [phone].
Fax:[phone]
DATE: 11/19/99
PAGE: 10
Pace Project Number: 929942
Client Project ID: Sterling-939118
Spike
LCS
Spike
Parameter
------------------------------
Units
----------
Conc.
Result
% Rec Footnotes
1,1,2-Trichtoroethane
ug/l
-------
20
----------
18.37
----- ----------
91.9
Dibromocluoromethane
ug/L
20
16.11
80.6
Tetrachtoroethene
ug/L
20
16.92
84.6
Chlorobenzene
ug/l
20
18.96
94.8
Ethylbenzene
ug/L
20
16.58
82.9
Bromoform
ug/L
20
15.53
77.7
1,1,2,2-Tetrachloroethane
ug/l
20
14.53
72.6
1,3-Dichlorobenzene
ug/t
20
18. u
90.7
1,4-Dichlorobenzene
ug/t
20
17.62
88.1
1,2-Dichlorobenzene
ug/l
20
16.87
84.4
Dibromofluoromethane (S)
90
Toluene-d8 (S)
101
4-Bromofluorobenzene (S)
96
SAMPLE DUPLICATE: 92720150
Parameter
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1-Dichtoroethene
Methylene Chloride
trans-1,2-Dichloroethene
1,1-Dichloroethane
cis-1,2-Dichloroethene
Chloroform
1,1,1-Trichloroethane
1,2-Dichloroethane
Carbon Tetrachloride
Benzene
Trichloroethene
1,2-Dichtoropropane
Bromodichloromethane
2-ChtoroethyL Vinyl Ether
cis-1,3-DichLoropropene
Toluene
trans- l,3-Dichtoropropene
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
Dup.
Units
93403111 Result RPD Footnotes
ug/L
ND ND NC
ug/L
ND NO NC
ug/L
ND NO NC
ug/L
ND ND NC
ug/L
ND ND NC
ug/L
ND ND NC
ug/L
ND ND NC
ug/t
ND ND NC
ug/l
ND NO NC
ug/L
NO ND NC
ug/l
NO ND NC
ug/L
ND ND NC
ug/l
ND ND NC
ug/t
ND ND NC
ug/l
ND ND NC
ug/L
NO NO NC
ug/l
ND NO NC
ug/t
NO ND NC
ug/l
ND NO NC
ug/l
ND ND NC
ug/L
ND ND NC
ug/L
ND ND NC
Laboratory Certification IDs
REPORT OF LABORATORY ANALYSIS
Drinking Water 90090
TNN UST List
This report shall not be reproduced, except in full,
VA Drinking Water 213
without the written consent of Pace Analytical Services, Inc.

0 0

-- Pace Analytical S.
9800 Kincey Avenue, .
race Analvtical Huntersville NG
Tel: [phone],
Fax:[phone],
QUALITY CONTROL DATA DATE: 11/19/99
PAGE: 11
Pace Project Number: 929942
Client Project ID: Sterling-939118
SAMPLE DUPLICATE: 92720150
Dup.
Parameter
------------------------------
Units
----------
93403111
Result
RPD Footnotes
1,1,2-Trichloroethane
ug/t
----------
ND
----------
NO
------ ----------
NC
Dibromochloromethane
ug/1
ND
NO
NC
Tetrachloroethene
ug/L
ND
ND
NC
Chlorobenzene
ug/L
NO
ND
NC
Ethytbenzene
ug/L
NO
ND
NC
Bromoform
ug/L
NO
ND
NC
1,1,2,2-Tetrachloroethane
ug/L
NO
ND
NC
1,3-Dichlorobenzene
ug/t
NO
ND
NC
1,4-Dichlorobenzene
ug/t
NO
ND
NC
1,2-Dichlorobenzene
ug/l
ND
NO
NC
Dibromofluoromethane (S)
%
93
93
0
Toluene-d8 (S)
%'
103
104
0
4-Bromofluorobenzene (S)
%
98
98
0
Laboratory Certification IN Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS KY Drinking Water 90090
NC Drinking Water 37706 TN UST List
Sc 99006 This report shall not be reproduced, except in full, VA Drinking Water 213
without the written consent of Pace Analytical Services, Inc.

cl, 0

Pace Analytical
9800 Kincey Avenue,..
Huntersville, Nu
Tel: [phone],
Fax: [phone]%
DATE: 11/19/99
PAGE: 12
Pace Project Number: 929942
Client Project ID: Sterling-939118
QUALITY CONTROL DATA PARAMETER FOOTNOTES
Consistent with EPA guidelines unrounded concentrations are displayed and have been used to calculate % Rec and RPD values.
NO Not Detected
NC Not Calculable
PRL Pace Reporting Limit
RPD Relative Percent Difference
(S) Surrogate
Ell The method required sample preservation is incompatible with the analysis of this compound, therefore acceptable
recoveries of this compound may not be achieved in matrix spikes.
Laboratory Certification IDs Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS NTN Drinking Water 9°09O
C Drinking Water 37706 TN UST List
Sc 99006 This report shall not be reproduced, except in full, VA Drinking Water 213
without the written consent of Pace Analytical Services, Inc.

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Pace Analytical
54 Ravens
Analytical Asheville, Nt-
Tel: 828-254
Fax: [phone]',..
DATE: 05/20/99
PAGE: 3
Pace Project Number: 935415
Client Project ID: Groundwater Monitoring
Pace Sample No: 93248490 Date Collected: 05/03/99 Matrix: Water
Client Sample ID: WELL R87S5 Date Received: 05/04/99
Parameters Results Units PRL Analyzed Analyst CAS# Footnotes
--------------- ---------------------------------------------- --------------- ----------
Wet Chemistry
Ammonia Method: EPA 350.3 Prep Method: EPA 350.3
Nitrogen, Ammonia ND mg/l 0.1 05/10/99 KEK 7727-37-9

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s

Pace Analytical Se,.
i-' 9800 Kincey Avenue, S,
ca Huntersville NC`�
Tel: [phone]'.
Fax:[phone]
DATE: 11/25/98
PAGE: 5
Pace Project Number: 922925
Client Project ID: Sterling - 932256
Pace Sample No: 92207323 Date CoLlected: 11/17/98 Matrix: Water
Client Sample ID: WELL R87S5 - 93105831 Date Received: 11/18/98
Parameters Results Units PRL Analyzed Analyst CAS# Footnotes
--------- ------------------- -------- ----- ---------- ----------
GC -- Volatiles
Halogen. 8 Aromatic Vol. Orgs.
Dichlorodifluoromethane
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethene
Methylene Chloride
' trans-1,2-Dichloroethene
1,1-Dichloroethane
Bromochloromethane
Chloroform
2,2-Dichloropropane
1,2-Dichloroethane
1,1,1-Trichloroethane
1,1-Dichloropropene
Carbon Tetrachloride
Dibromomethane
1,2-Dichloropropane
Trichloroethene
Bromodichloromethane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
1,3-Dichloropropane
Dibromochloromethane
1,2-Dibromoethane
Tetrachloroethene
1,1,1,2-Tetrachloroethane
Chlorobenzene
Bromoform
1,1,2,2-Tetrachloroethane
1,2,3-Trichloropropane
Bromobenzene
2-ChLorotoluene
4-Chlorotoluene
Laboratory Certifi_ cation Ili
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
Method: SM 6230D
Prep
Method: EPA 8021
ND
ug/L
1
11/23/98
CLL
75-71-8
ND
ug/L
1
11/23/98
CLL
74-87-3
ND
ug/L
1
11/23/98
CLL
75-01-4
ND
ug/L
1
11/23/98
CLL
74-83-9
ND
ug/L
1
11/23/98
CLL
75-00-3
ND
ug/L
0.5
11/23/98
CLL
75-69-4
ND
ug/L
0.5
11/23/98
CLL
75-35-4
ND
ug/L
0.5
11/23/98
CLL
75-09-2
ND
ug/L
0.5
11/23/98
CLL
156-60-5
ND
ug/L
0.5
11/23/98
CLL
75-34-3
ND
ug/L
0.5
11/23/98
CLL
74-97-5
ND
ug/L
0.5
11/23/98
CLL
67-66-3
ND
ug/L
0.5
11/23/98
CLL
594-20-7
ND
ug/L
0.5
11/23/98
CLL
107-06-2
ND
ug/L
0.5
11/23/98
CLL
71-55-6
ND
ug/L
0.5
11/23/98
CLL
563-58-6
ND
ug/L
0.5
11/23/98
CLL
56-23-5
ND
ug/L
0.5
11/23/98
CLL
74-95-3
ND
ug/L
0.5
11/23/98
CLL
78-87-5
ND
ug/L
0.5
11/23/98
CLL
79-01-6
ND
ug/L
0.5
11/23/98
CLL
75-27-4
ND
ug/L
0.5
11/23/98
CLL
10061-01-5
ND
ug/L
0.5
11/23/98
CLL
10061-02-6
ND
ug/L
0.5
11/23/98
CLL
79-00-5
ND
ug/L
0.5
11/23/98
CLL
142-28-9
ND
ug/L
0.5
11/23/98
CLL
124-48-1
ND
ug/L
0.5
11/23/98
CLL
106-93-4
ND
ug/L
0.5
11/23/98
CLL
127-18-4
ND
ug/L
0.5
11/23/98
CLL
630-20-6
ND
ug/L
0.5
11/23/98
CLL
108-90-7
ND
ug/L
0.5
11/23/98
CLL
75-25-2
ND
ug/L
1 ,
11/23/98
CLL
79-34-5
ND
ug/L
0.5
11/23/98
CLL
96-18-4
ND
ug/L
0.5
11/23/98
CLL
108-86-1
ND
ug/L
0.5
11/23/98
CLL
95-49-8
ND
ug/L
0.5
11/23/98
CLL
106-43-4
REPORT
OF
LABORATORY ANALYSIS
This report shall not be reproduced,
except in full,
without the written
consent of Pace
Analytical Services,
Inc,
Laboratory Certification IN
KY Drinking Water 90090
TN UST List
VA Drinking Water 213

A I •
Pace Analytical St.
9800 Kincey Avenue, L,
Huntersville, NC.
Tel: [phone]b,
Fax:[phone]i
DATE: 11/25/98
PAGE: 6
Pace Project Number: 922925
Client Project ID: Sterling - 932256
Pace Sample No: 92207323 Date Collected: 11/17/98 Matrix: Water
Client Sample ID: WELL R87S5 - 93105831 Date Received: 11/18/98
Parameters
---------------------------------
Results
----------
Units
---------
PRL
Analyzed
Analyst CAS# Footnotes
1,3-Dichlorobenzene
ND
ug/L
----------
0.5
--------
11/23/98
-----
CLL
---------- ----------
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.5
11/23/98
CLL
106-46-7
1,2-Dichlorobenzene
ND
ug/L
0.5
11/23/98
CLL
95-50-1
1,2-Dibromo-3-Chtoropropane
ND
ug/L
2
11/23/98
CLL
96-12-8
1,2,4-Trichtorobenzene
ND
ug/L
2
11/23/98
CLL
120-82-1
Hexachlorobutadiene
ND
ug/L
2
11/23/98
CLL
87-68-3
1,2,3-Trichtorobenzene
ND
ug/L
2
11/23/98
CLL
87-61-6
Methyt-tert-butyl Ether
ND
ug/L
0.5
11/23/98
CLL
1634-04-4
Isopropyl Ether
ND
ug/L
0.5
11/23/98
CLL
108-20-3
Benzene
1.3
ug/L
0.5
11/23/98
CLL
71-43-2
Toluene
ND
ug/L
0.5
11/23/98
CLL
108-88-3
Ethylbenzene
ND
ug/L
0.5
11/23/98
CLL
100-41-4
miip-Xytene
ND
ug/L
0.5
11/23/98
CLL
7816-60-0
Styrene
ND
ug/L
0.5
11/23/98
CLL
100-42-5
o-Xytene (1,2-Dimethytbenzene)
ND
ug/L
0.5
11/23/98
CLL
95-47-6
Isopropylbenzene (Cunene)
ND
ug/L
0.5
11/23/98
CLL
98-82-8
n-Propylbenzene
ND
ug/L
0.5
11/23/98
CLL
103-65-1
1,3,5-Trimethylbenzene
ND
ug/L
0.5
11/23/98
CLL
108-67-8
tert-Butylbenzene
ND
ug/L
0.5
11/23/98
CLL
98-06-6
1,2,4-Trimethylbenzene
ND
ug/L
0.5
11/23/98
CLL
95-63-6
sec-Butylbenzene
ND
ug/L
0.5
11/23/98
CLL
135-98-8
p-Isopropyttotuene
ND
ug/L
0.5
11/23/98
CLL
99-87-6
n-Butytbenzene
ND
ug/L
0.5
11/23/98
CLL
104-51-8
Naphthalene
ND
ug/L
2
11/23/98
CLL
91-20-3
1-Chtoro-3-ftuorobenzene (S)
77
%
11/23/98
CLL
625-98-9
Laboratory Certification Laboratory Certification IDs
Drinking Water 90090
KYNC
REPORT OF LABORATORY ANALYSIS TN
TN UST List
This report shall not be reproduced, except in full, VA Drinking Water 213
without the written consent of Pace Analytical Services, Inc.
IDs
NC Wastewater
12
Drinking Water
37706
SC
99006

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0 0

�s Pace Analytica.
/�
race Analvtical
54 Raven.
As
Asheville l�
Tel: 704-254
Fax: [phone].
Sterling Diagnostic Imaging, Inc.
June 02, 1998
P.O. Box 267
PACE Project Number: A80519513,
Staton Rd. Cedar Mtn.
Brevard, NC 28712
NC Wastewater Lab Cert. #40
NC Drinkingwater lab Cert. #3771;
SC Lab Cert. #99030
Attn: Mr. Roger Galloway
Client Reference: Routine Samples
4500017649
PACE Sample Number:
93 0567940 93 0567959 93 0567967
Date Collected:
05/18/98 05/18/98 05/18/98
Date Received:
05/19/98 05/19/98 05/19/98
Client Sample ID:
Well Well Well
Parameter
Units
PRL #R8753 #R8754 #R8755
�134 �g755
INORGANIC ANALYSIS
INDIVIDUAL PARAMETERS
Nitrogen, Ammonia
mg/L
0.10 - 5.2 ND
Nitrogen, Ammonia
mg/L
1.0 64 - -
PACE Sample Number:
93 0567975
Date Collected:
05/18/98
Date Received:
05/19/98
Client Sample ID:
Well
Parameter Units PRL
#R8757
INORGANIC ANALYSIS
Q�f757
INDIVIDUAL PARAMETERS
Nitrogen, Ammonia mg/L 0.10
NO
These data have been reviewed and are approved for release.
rl
! � ,wIlL
Walter L. Miller
Operations Manager
Laboratory Certification
IDc
NC Wastewater
40
NC Drinking Water
37712
SC Environmental
99030
IDs
REPORT OF LABORATORY ANALYSIS N Drnki g Waterr1yatr02980
This report shall not be reproduced, except in full, FL Environmental 96317
without the written consent of Pace Analytical Services, Inc.

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Pace Analytical Service.
Pa Analytira'
54 Ravenscroft D�
.[�
"
Asheville NC 2880
Tel: [phone]
Fax: [phone]
Sterling Diagnostic Imaging, Inc.
P.O. Box 267
May 15,
1996
Staton Rd. Cedar Mtn.
PACE Project
Number: A60507511
Brevard, NC 28712
Attn: Mr. Roger Galloway
Client Reference: Monitoring Wells
PACE Sample Number:
Date Collected:
93 0202950
93 0202969 93 0202977
Date Received:
05/06/96
05/06/96 05/06/96
Client Sample ID:
05/07/96
05/07/96 05/07/96
Parameter
Units
MDL
._.
Well #
R87S3
_._
Well # Well #
R87S4 R87S5
_..-
INORGANIC ANALYSIS
INDIVIDUAL PARAMETERS
Barium
Cadmium
mg/L
0.10
1.11
ND ND
Chromium
mg/L
0.01
ND
ND ND
Copper
mg/L
0.020
ND
ND ND
Iron
mg/L
0.01
ND
ND ND
Nitrogen, Ammonia
mg/L
m9/L
0.05
0.1
9.80
2.76 61.3
-
4.8 ND
Nitrogen, Ammonia
mg/L
1.0
66
Nitrogen, Nitrate in Wastewater
mg/L
0.1
0.46
ND ND
Specific Conductivity
umhos/cm
10
910
240 230
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. Inc