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TECHNICAL MEMORANDUM
Date: January 25, 2019 File: 1026.105
To: Kim Witt (Duke Energy)
Cc: Jerry Wylie (SynTerra)
From: Peggy Altman P W A,
Subject: Additional Soil Assessment - Mayo Steam Electric Plant
Ash Basin Perimeter Soil Assessment
Duke Energy Progress, LLC (Duke Energy) owns and operates the Mayo Steam Electric
Plant (Mayo, Plant, or Site) in Roxboro, Person County, North Carolina. Additional soil
assessment activities proposed for the perimeter of the ash basin are described herein.
Regulatory Background
In 2014, The North Carolina General Assembly passed the Coal Ash Management Act
(CAMA). CAMA required owners of a coal combustion residuals (CCR) surface
impoundment to conduct detailed assessment of site groundwater and soil within and
around the CCR surface impoundments.
A primary source of CCR-related constituents was identified during the
Comprehensive Site Assessment (CSA) for CAMA to be the ash basin. In response to
the October 2017 CSA Update, the North Carolina Department of Environmental
Quality (NC DEQ) requested additional evaluation of shallow soil surrounding the ash
basin to determine the presence, absence, and/or degree of possible impact from
historical coal combustion waste management at Mayo.
Site Description
The Mayo Plant began operations in 1983 with a single 727-megawatt capacity
generating coal-fired unit. CCR have historically been managed in the Plant's on -site
ash basin (surface impoundment). CCR were initially deposited in the ash basin by
hydraulic sluicing operations until 2013 when the Plant converted to a dry ash system
in which 90 percent of CCR was dry. Final system upgrades were completed in October
2016; all CCR collection is currently handled dry. CCR from the Plant is managed in the
onsite Industrial Landfill permitted by the NC DEQ Division of Waste Management
(DWM) (PN 7305-INDUS) or beneficially reused. Discharge from the ash basin to Mayo
Reservoir is permitted by the NCDEQ Division of Water Resources (DWR) under the
National Pollutant Discharge Elimination System (NPDES) Permit NC0038377.
P: \ Duke Energy Progress.1026 \ 105. Mayo Ash Basin GW Assessment Plan \ Additional Assessment \ Ash Basin
Perimeter Soil 2019 \ Mayo Ash Basin Soil Sampling Tech Memo.docx
Ash Basin Perimeter Soil Assessment January 25, 2019
Mayo Steam Electric Plant Page 2 of 3
Ash Basin Perimeter Soil Assessment Objectives
Objectives of the ash basin perimeter soil assessment include the following:
• Characterize inorganic constituent concentrations in shallow soil along the
ash basin perimeter
• Compare inorganic constituent concentrations in these shallow soils to Site
background concentrations
Soil Assessment
Ash basin perimeter soils will be sampled and analyzed for inorganic parameters to
determine the presence, absence, and/or degree of possible impact from the CCR
materials in the ash basin. Soil samples are planned to be collected at 24 locations
around the perimeter of the ash basin (Figure 1). The sample locations will be field -
located and will be located as close to the ash basin as practical with no sample
collected closer than five feet from the edge of the ash basin. At Mayo, the extent of the
ash basin and CCR material is easily discernable. However, the "water line" of the ash
basin does vary by a few feet in some areas in response to heavy precipitation/run-off
events. Therefore, the sample locations will be placed no closer than five feet from the
edge of the basin defined as the point where CCR material is visually observed.
Similarly, unless safety considerations require, no boring will be placed further than 10
feet from the edge of the discernable ash basin limits. GPS coordinates will be recorded
for each sample location, and a pin flag with the sample identifier will be placed.
Borings will be made using either a hand -auger or manual direct -push probe to a
maximum depth of two feet. Samples will be collected between a depth interval of one
to two feet. One sample per location will be collected for laboratory analysis. Soil
samples will be "grab" samples and will not be composited. Collected soil will be place
directly into new bottleware provided by the NC certified analytical laboratory. The
hand auger, bucket, and/or direct push probe tip will be decontaminated after sample
collection at each location. Soap and water and mechanical scrubbing will be used to
clean the equipment, followed by rinsing with deionized water. Soil samples will be
analyzed for inorganic parameters listed on Table 1.
Ash Basin Perimeter Soil Assessment Report
An ash basin perimeter soil assessment report will be included as an appendix in the
forthcoming Corrective Action Plan (CAP) update document. The report will be
prepared once all soil sample analytical data is received, validated, and evaluated.
P: \ Duke Energy Progress.1026 \ 105. Mayo Ash Basin GW Assessment Plan \ Additional Assessment \ Ash Basin
Perimeter Soil 2019 \ Mayo Ash Basin Soil Sampling Tech Memo.docx
Ash Basin Perimeter Soil Assessment
January 25, 2019
Mayo Steam Electric Plant
ATTACHMENTS:
Figure 1: Proposed Ash Basin Perimeter Soil Assessment Sample Locations
Table 1: Soil Analytical Parameters
Page 3 of 3
P: \ Duke Energy Progress.1026 \ 105. Mayo Ash Basin GW Assessment Plan \ Additional Assessment \ Ash Basin
Perimeter Soil 2019 \ Mayo Ash Basin Soil Sampling Tech Memo.docx
Ash Basin Perimeter Soil Assessment
January 25, 2019
Mayo Steam Electric Plant
ATTACHMENTS
P: \ Duke Energy Progress.1026 \ 105. Mayo Ash Basin GW Assessment Plan \ Additional Assessment \ Ash Basin
Perimeter Soil 2019 \ Mayo Ash Basin Soil Sampling Tech Memo.docx
LEGEND
Q� MW-3
EXISTING MONITORING WELL
SB-3
EXISTING SOIL BORING LOCATION
Q PSB-3
PROPOSED SOIL BORING LOCATION
PARCEL LINE DUKE ENERGY (APPROXIMATE)
HIGHWAY 501 RIGHT-OF-WAY
(DUKE ENERGY PROPERTY)
— — —
500 ft COMPLIANCE BOUNDARY
APPROXIMATE ASH BASIN WASTE BOUNDARY
APPROXIMATE STREAM (NON -JD)
SURFACE WATER FLOW DIRECTION
—
APPROXIMATE POND OR RESERVOIR (NON -JD)
APPROXIMATE EFFLUENT CHANNEL
®
APPROXIMATE FREE PONDED ASH BASIN WATER
CULVERT LOCATION
100' RIGHT OF WAY
c
1951 AERIAL PHOTOGRAPH }2(a
hil
BR
.R^107BR
FORMER INTERMITTENT STREAM B
ON 1968 USGS TOPOGRAPHIC MAP
to
pp • Our 1j11 11llll��i�l
-
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0
SOURCE NOTES:
NOT ALL UTILITIES ARE IDENTIFIED ON THIS DRAWING. THE UTILITIES SHOWN ON THIS DRAWING ARE VISUAL AIDS TO LOCATE
THE STREAMS AND WETLANDS IN THE FIELD. THE HORIZONTAL LOCATION AND THE VERTICAL LOCATIONS HAVE NOT BEEN FIELD
LOCATED ON ANY UTILITIES AND THE SHOWN LOCATIONS ARE APPROXIMATE.
THE TOPOGRAPHY IS A COMPILATION OF LIDAR DATA OBTAINED FROM FRIS- NORTH CAROLINA FLOOD RISK INFORMATION
SYSTEM AT ftp.,//ftpl.ncem.org/Data_Requests/County_LIDAR_Data/Personcounty/ AND AN AERIAL TOPOGRAPHIC
SURVEY-MAYO PLANT BY WSP, DATER JULY 24, 2015, JOB NUMBER: 1570002.00, DWG NAME: MAYO OVERALL WK.DWG
FOR STREAM JURISDICTIONAL STATUS REFER TO THE STREAM CLASSIFICATION TABLE CONTAINED IN THE CURRENT
USACOE MAYO STEAM ELECTRIC PLANT JURISDICTIONAL STREAM AND WETLAND SURVEY.
FGD SETTLING
vA sti�_a 4so ABMW 4D v /' `POND g,
PROPOSED LINED ABMW 46R ABMW 4 a p %' j / 1
RETENTION BASIN AREA a ° \
5
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MW LRB-1�•o, �\ a \'OOP 5 ///'/ 'Zi yam° 5zo MW-196R
SIp "�Y (7 rn dam' S / / � � / �'' � 1 9 �'�s.. o•- f A o�' -
PRIMARY AND SECONDARY
SETTLING PONDS
200 GRAPHIC SC200 400
FIGURE 1
DUKE IN FEET PROPOSED LOCATIONS
148 RIVER STREET, SUITE 220
ENERGY PHONE 64-421-9999CAROLINA 29601 ASH BASIN PERIMETER SOIL ASSESSMENT
PHONE864-421-9999 MAYO STEAM ELECTRIC PLANT
ao TerraDRAWNWS Y: C. NEWELL COm
PROGRESS 5� ww's C. GER:J. DATE:0122/2019 ROXBORO NORTH CAROLINA
PROJECT MANAGER: J. WYLIE �
LAYOUT: FIG 1(PROP SOIL LOCI
Ol/25/201911:29AM P:\Duke Energy Pro ress.1026105. Mayo Ash Basin GW Assessment Plan 49.EHS-Ex anded CAP Sco a dw DE MAYOSOIL ASSESSMENT -2.dw
TABLE 1
SOIL SAMPLE ANALYTICAL METHODS
MAYO STEAM ELETRIC PLANT
DUKE ENERGY PROGRESS LLC, ROXBORO, NC
INORGANIC COMPOUNDS
UNITS
METHOD
Aluminum
mg/kg
EPA 6010D
Antimony
mg/kg
EPA 6020B
Arsenic
mg/kg
EPA 6020B
Barium
mg/kg
EPA 6010D
Beryllium
mg/kg
EPA 6010D
Boron
mg/kg
EPA 6010D
Cadmium
mg/kg
EPA 6020B
Calcium
mg/kg
EPA 6010D
Chloride
mg/kg
EPA 9056A
Chromium
mg/kg
EPA 6010C
Cobalt
mg/kg
EPA 6020A
Copper
mg/kg
EPA 6010C
Iron
mg/kg
EPA 6010C
Lead
mg/kg
EPA 6020B
Magnesium
mg/kg
EPA 6010D
Manganese
mg/kg
EPA 6010C
Mercury
mg/kg
EPA 7471B
Molybdenum
mg/kg
EPA 6010D
Nickel
mg/kg
EPA 6010C
Nitrate as Nitrogen
mg/kg
EPA 9056A
pH
SU
EPA 9045D
Potassium
mg/kg
EPA 6010D
Selenium
mg/kg
EPA 6020B
Sodium
mg/kg
EPA 6010D
Strontium
mg/kg
EPA 6010C
Sulfate
mg/kg
EPA 9056A
Thallium
mg/kg
EPA 6020B
Total Organic Carbon
mg/kg
EPA 9060
Vanadium
mg/kg
EPA 6020B
Zinc
mg/kgmg/kg
EPA 6010C
Prepared by: RBI Checked by: SRW/TCP/VTV
Notes:
1. Soil samples to be analyzed for Total Inorganics using USEPA Methods 6010/6020 and pH using USEPA Method 9045, as noted above.
2. Analytical methods and reporting limits as presented were developed for CSA field implementation in 2015. Analytical methods and
reporting limits are updated periodically and applied as appropriate.
meq/100g - millequivalents per 100 grams
mg/kg - Milligrams per kilogram
my - Millivolts
S.U. - Standard Unit
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