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19991233 Ver 1_Monitoring Report_20001031
OCT J 2A00 ... ?W?ttlnl a6 y ?u?G+?r?? Environmental Monitoring Program The Preserve at Jordan Lake Golf Club Chatham County, North Carolina October 27, 2000 Prepared By: Turf & Environmental management .Associates . Raleigh, North Carolina Environmental Monitoring Program The Preserve at Jordan Lake Golf Club Chatham County, North Carolina October 27, 2000 Prepared By: Turf & Environmental management Associates Raleigh, North Carolina Table of Contents 1.0 Introduction 1 2.0 Phase I: Background Construction and Development Phase - Surface Water, Groundwater, and Sediment Quality 2 2.1. Sample Locations 2 2.2. Sample Frequency 3 2.3. Sample Variables 3 2.4. Field Methods 5 2.5. Laboratory Methods 10 3.0 Phase H: Surface Water, Groundwater, and Sediment Quality During Operations 11 3.1. Sample Locations 11 3.2. Sample Frequency 11 3.3. Sample Variables 12 3.4. Field Methods 12 Laboratory Methods 12 4.0 Data Storage, Reporting, and Criteria for Management Response 4.1. Data Storage and Reporting 13 4.2. Data Analysis 13 4.3. Criteria for Management Response 14 5.0 Field Quality Control and General Water and Sediment Sampling Considerations 17 5.1. General Measures 17 5.2. Prevention of Sample Contamination 17 5.3. Field Quality Control 18 6.0 References 19 Appendix I 20 Turf & Environmental Management Associates, Inc. Raleigh, North Carolina I Environmental Monitoring Program Page 1.0 Introduction ' A water quality monitoring program has been established for The Preserve at Jordan Lake Golf Club. The monitoring program will include monitoring of surface water, pond sediments, and ' ground water. The monitoring plan, based on sound, scientific principles will: 1. Establish a baseline of water and sediment quality prior to construction, 2. Provide data that will establish environmental conditions, thus providing a basis for measuring compliance with environmental regulations, and 3. Ensure that Integrated Pest Management is functioning properly. ' An adaptation from a model proposed by Madhun and Freed (1990) notes that there are four basic types of monitoring which can occur: 1) Reconnaissance - periodic observation to disclose ' changes or trends. With IPM employed this is an integral part of this program; 2) Surveillance - to comply with an enforcement program. Pesticide application licensing programs require record- keeping which may be monitored at any time. This will be required by law and serves as a record ' of a part of the cultural program; 3) Subjective - spot-checking for broad or open-ended exploration of problems. A superintendent with training and experience in the golf course management industry has the background and resources to investigate problems and make ' intelligent decisions; and 4) Objective - to provide data for use in developing or confirming the results of on-going programs. Monitoring operations at The Preserve at Jordan Lake Golf Club will focus on maintaining environmental quality and obtaining information on which to make ' adjustments in cultural programs using all of these approaches. ' Results of the Environmental Water Quality monitoring program provide feedback to the golf course superintendent, and thus provide a useful management tool. For example, the results of the program are used in determining the correct application rates and timing of pesticides and fertilizers, and the optimum operation of irrigation programs. The Environmental Monitoring Program is established in two phases that coincide with golf ' course development. Phase I is during the construction and development phase and immediate post-development time-frame, and Phase II is the post-development, operational golf course. I Environmental Monitoring Program Page 2.0 PHASE I: BACKGROUND CONSTRUCTION AND DEVELOPMENT PHASE - SURFACE WATER, GROUNDWATER, SEDIMENT QUALITY AND MACROBENTHOS MONITORING. The goal of Phase I is to establish background surface water, groundwater, sediment quality and macrobenthos population data at The Preserve at Jordan Lake Golf Club. 2.1. Sample Locations. Surface Water. Surface water on the property are several unnamed tributaries which ultimately egress the property to Jordan Lake. Water will be sampled at locations on the creeks that are described below and shown on attached map (SW means surface water): Sample Station SW-1, SW-2, & SW-3. Surface water test location at discharge location Sample Station SW-4 & SW-5. Surface water test location upstream of project Obtaining water samples from the same location is important so that comparisons can be made. Sample stations will be located and permanently marked in the field, identified on maps, and photographed so that stations are easily located during subsequent sampling efforts. Data from these sample stations will allow an assessment of the quality of the water. Groundwater. Surficial groundwater will be sampled at nine locations that will be determined by the geologist based on flow directions. Four wells will be up-gradient, and five wells will be down-gradient of the golf course. Locations will be described once they are determined, and will be given below and shown on attached map (MW means monitor well). Sample Station MW-1 thru MW4 and MW-9 are downgradient Sample Station MW-5 thru MW-8 are upgradient. ' Groundwater sample stations will be field marked, identified on maps, and photographed. Data from these sample stations will allow an assessment of the quality of the groundwater on the site. ' Environmental Monitoring Program Page Sediment Pond sediment will be sampled from the sediments of three tributaries. The ' location is described below and shown on attached map (S means sediment). Sample Stations S-1 thru S-3 are downgradient • Sample Station S-4 thru S-6 are upg[adient to measure sediment that may be ' entering the property. The sediment samplina station will be impounded during construction. Thus, in ' subsequent sampling phases, the location will be changed from the tributary to the pond that will be constructed. ' Macrobenthos Sampling for benthic macroinvertebrates will be conducted at four locations. The location is described below and shown on attached map ( MB means ' macrobenthos ). Sample Stations MB-1 thru MB-3 are downgradient Sample Station M13-4 is upgradient 2.2. Sample Frequency. The goal of Phase I is to define conditions at the site. i i Surface Water. Surface water samples will be collected three times prior to beginning Phase H. Depending on the construction schedule, one sample event will be in Winter (December, January, February), Spring (March, April, May), one in Summer (June, July, August), and one in Autumn (September, October, November). Should water not be available on a given sample date, two additional attempts should be made to obtain a sample within the time period. Groundwater. Groundwater samples will be collected three times during this phase. Sediment. Sediment will be collected one time during the spring sample time. Macrobenthos. Macrobenthos samples will be collected one time prior to any construction activity in the fall or winter. This phase of the monitoring program will be converted to Phase II when grassing has been completed. 2.3. Sample Variables. Surface water, groundwater and sediments will be analyzed for the variables fisted in Table 1. Macrobenthos parameters are discussed in the following section. The inclusion of pesticides in the analytes was based on several factors that are detailed in the Integrated Pest Management plan (in preparation) for The Preserve at Jordan Lake Golf Club. The primary factors were potential quantity of a chemical that may be used at the club, and the chemical's mobility, leaching potential, persistence and toxicity based on data in the scientific I J I J I I I J Environmental Monitoring Program Page 4 literature and computer models. Restrictions have been placed on pesticides and herbicides that have a high leaching potential; those that have a low to moderate leaching potential will be used sparingly; and those that will be used most frequently have a very low to no leaching potential and a rapid degradation time. Table 1. Variables to be Analyzed (x) in Surface- and Ground- Water and Sediments at The Preserve at Jordan Lake Golf Club. Variable PHASE I and II Environmental Monitoring Program Surface Water Ground Water Sediment Field Analyses pH X X Water Temperature X X Specific Conductance X X Dissolved Oxygen X Laboratory Analyses Nitrate Nitrogen X X Ammonia Nitrogen X Total Kjeldahl Nitrogen X Orthophosphate Phosphorus X Total Phosphorus X X X Fecal coliforms X Total Dissolved Solids X X Chlorophyll a X Turbidity X Mecoprop X X Chlorpyrifos X X X Propiconozole X X X Turf & Environmental Management Associates, Inc Raleigh, North Carolina ' Environmental Monitoring Program Page 5 14. Field Methods. Variables, container type, preservation and holding times for water samples ' are given in Table 2, and for sediment samples in Table 3. ' Surface Water. A number of variables will be measured on-site, including pH, water temperature, dissolved oxygen, and specific conductance. pH will be measured with a pH probe that has been calibrated dust prior to use. Specific conductance will be measured ' with a calibrated specific conductance meter. Dissolved oxygen will be measured with a dissolved oxygen probe (or by wet chemistry methods) that has been properly calibrated. Water temperature will be measured with a temperature probe attached to the specific ' conductance meter or the dissolved oxygen meter. Surface water will be sampled by obtaining 'discrete' grab samples of water. Discrete grab ' samples are taken at a selected location, depth and time, and then analyzed for the constituents of interest. Water will be collected in sample bottles that face upstream, and water is transferred to sample containers that include proper preservatives and labels. The ' sample containers are immediately placed in a cooler with ice and are taken to a laboratory for analysis. A chain-of-custody program is followed to assure that proper transportation and storage practices are documented and that the appropriate analyses are being conducted. A field sampling log of surface water sampling and observations will be maintained. The log book documents site conditions, including stream water depth, weather conditions, and field measurements and observations. An example of a page from a field log is given in Appendix I. Groundwater. Groundwater elevation is determined for each well on each sampling date. After measuring water elevation, the standing water in the well is removed, and replaced by fresh formation water. The quantity of water removed is determined from the well volume and recharge rate. In general, high-yield wells are purged of three well casing volumes of water and low-yield wells are pumped to dryness. Each well is purged using a portable pump or with a Teflon® bailer that is cleaned between well samples. Water is suitable for sampling when three consecutive measures of water have stable pH, temperature and specific conductance readings. Wells are allowed to recharge after purging to allow the system to equilibrate. Depth to the water table is re-measured, recorded and water samples are extracted. Extraction occurs with a pump, or a dedicated Teflon® bailer. Water temperature, pH, and specific conductance are measured in water that will not be used for laboratory analyses. Water samples are taken and decanted or drained into an appropriate sample container that has Turf & Environmental Management Associates, Inc Raleigh, North Carolina Environmental Monitoring Program Page 6 the proper preservatives and is labeled. Samples are transferred from the sample device to ' the sample container in a manner that will minimize turbulence and the loss of volatile compounds. Samples are immediately placed in a cooler with ice and transported to the analytical laboratory. Whenever non-dedicated equipment is used, cleaning procedures outlined by the EPA (1986) will be instituted. Special attention will be given to thoroughly cleaning samplers, tubing, and other equipment. And, to ensure that the ' sample is not contaminated, blanks will be collected and analyzed. A chain-of-custody program is followed to assure that proper transportation and storage practices are documented and that the appropriate analyses are being conducted. A field sampling log on groundwater sampling and observations will be maintained. The log book documents site conditions, including water depth, observations, weather ' conditions, and field measurements. An example of a page from a field log is given in Appendix I. ' Sediment. Sediment will be collected with a gravity type sediment coring device or by hand. Sampling will occur at three locations around the edge of the creek and will be composited into one sample in the field. The three samples will be collected from near shore sediments. The approximate top 10-cm of the sediment will retained and analyzed for the variables listed in Table 1. A chain-of-custody program is followed to assure that proper transportation and storage ' practices are documented and that the appropriate analyses are being conducted. A field sampling log on sediment sampling and observations will be maintained. The log book documents site conditions, including water depth, sediment texture, observations, and ' weather conditions. An example of a page from a field log is given in Appendix I. ' Macrobenthos. Macro-benthos sampling. Standard qualitative collection methods for small 1' and 2nd order streams are inappropriate. Therefore, it is recommended that an abbreviated collection technique be used. This technique is a modification of the standard ' method in which only four samples are collected (rather than ten): one kick net sample, one sweep net sample, one leaf-pack and "visuals". It is recommended that all organisms are collected and processed during using this survey type. This collection method is ' referred to in this guidance as a Qual4 technique. A list of all taxa collected, taxa richness values (total and EPT), EPT abundance and biotic index values should be given for each sample collected using this method. ' This collection protocol is semi-quantitative. The result is lists of taxa and relative abundance values (DWQ assigns Rare, Common and Abundant value to 1-2, 3-9 and 10 or more specimens, respectively). One of the primary objectives of semi-qualitative Turf & Environmental Management Associates, Inc ' Raleigh, North Carolina ' Environmental Monitoring Program Page 7 surveys is to make within or between site comparisons and to determine the presence or t absence of benthic macroinvertebrate species with various tolerances to water pollution. When conducting these types of surveys, attempts are made to collect as many taxa as possible in an allotted time period and usually requires some experience to select the most ' productive habitat. A disadvantage of semi-qualitative methods is that no information on standing crop or biomass can be generated. ' DWQ protocols for processing benthic macroinvertebrate samples are discussed in the Standard Operating Procedures manual (NCEHNR 1997). Benthic macroinvertebrate ' samples collected by biologists are "picked" and preserved in the field. It is not necessary to know the total number of organisms from a specific habitat type when qualitative or semi-qualitative samples are collected. It is only necessary to know if those taxa are present and if they are rare, common or abundant. Specimens are "picked" from the sample and preserved in 6 dram vials using 95% ethanol. Larger organisms (dragonflies, crayfish, Megaloptera) are preserved in larger containers. Standard qualitative collection ' methods will take approximately 1 1/z to 2 hours for a team of three biologists to collect and Qual-4 collection methods will take approximately one hour per site. Field processing samples in this fashion minimizes laboratory processing. Turf & Environmental Management Associates, Inc ' Raleigh, North Carolina 1 I Fnxrirnnmvntal TVtAn1tAT171a p1YlATatT1 Page 8 YTable-2. Variables, Container Type, Preservation, and Holding Tunes-for Water Samples in Surface- and Ground-`Water at The Preserve at Jordan Lake Golf Club. Variable Container Preservation Holding Analytical Method Type Time pH not not applicable not EPA 150.1 applicable applicable Water Temperature not not applicable not EPA 170.1 applicable applicable Specific not not applicable not EPA 120.1 Conductance applicable applicable Dissolved Oxygen not not applicable not EPA 360.1 applicable licable Nitrate Nitrogen P,G Cool, 4-?'LC 48 h EPA 353.1 Ammonia Nitrogen P,G Cool, 4-C 48 h EPA 350.1, 350.2 Total Nitrogen P,G Cool, 4-C 7 d APHA 4500 or EPA summation for Kjeldahl, nitrate, and ammonia nitrogen Orthophosphate P,G Cool, 4-C 48 h EPA 365.4, 365.1, 365.2 Phosphorus Total Phosphorus P.G Cool, 4`® C, 28 d EPA 365.4 H2SO4 to pH <2 Fecal coliform P,G Cool, 4-C 6 h Standard methods 9222 Total Dissolved P,G Cool, 4`wC 7 d EPA 160.1 Solids Chlorophyll a P,G Cool, 4-wC; keep filter water Standard methods 10200 in the dark within 24 h, and then store filtrate in desiccant in freezer; 28 d once filtered and stored in desiccant Turbidity P,G Cool, 4-C 48 h EPA 180.1 Mecoprop G Cool, 4`®C 7 d EPA 8150, GC with ECD Target detection limit= 2.50-g/0 Chlorpyrifos G Cool, 4-C 7 d extraction: EPA 3510 liquid/liquid analysis: EPA 8080 GC ECD Target detection limit= 0.2®'glO Turf & Environmental Management Associates, Inc Raleigh, North Carolina t:nvironmentat Momtorm mgram rage Y Propiconozole G Cool, 4-C 7 d EPA 8080 Target detection limit= 2- O From: USEPA, Methods for Chemical Analysis of Water and Wastes, EIIIA-600/4-79-020, updated 1983. USEPA, Analytical Support Branch, Operations and Quality Control Manual, June 1985. USEPA, Test Methods for Evaluating Solid Waste, SW-846, 1986, updated in 1987. USGS. Laboratory Theory and Methods for Sediment Analysis. 40 CFR Part 136 Table U: Required Containers, Preservation Techniques and Holding Times (Water/Wastewater Samples), 1988. note that container yes are `G' for ass and 'P' for plastic. Table 3. Variables, Container Type, Preservation, and Holding Times for Sediment Samples at he Preserve at Jordan Lake Golf Club. Variable Container Preservation Holding Analytical` Method Type Time Chlorpyrifos Glass Jar Cool, 4 `®C 14 d extraction: EPA 3510 liquid/liquid analysis: EPA 8080 GC ECD Propiconozole Glass Jar Cool, 4 `®C 14 d extraction: EPA 3510 liquid/liquid anal sis: EPA 8080 Total Phosphorus P,G Cool, 4 °®C 14 d EPA 365.4 From: USEPA, Methods for Chemical Analysis of Water and Wastes, EPA-600/4-79-020, updated 1983. USEPA, Analytical Support Branch, Operations and Quality Control Manual, June 1985. USEPA, Test Methods for Evaluating Solid Waste, SW-846, 1986, updated in 1987. USGS. Laboratory Theory and Methods for Sediment Analysis. 40 CFR Part 136 Table H: Required Containers, Preservation Techniques and Holding Times (Water/Wastewater Samples), 1988. Turf & Environmental Management Associates, Inc Raleigh, North Carolina Environmental Monitoring Program Page 10 2.5. Laboratory Methods The Laboratory used for sample analysis must retain certification by the Environmental Protection Agency (EPA) or its designated State Agency to conduct chemical analysis on surface water and drinking water. Certification of the laboratory is maintained by successful performance of the EPA Water Pollution Study and EPA Water Supply Study. Sample analyses will follow accepted, standard methods as defined in the laboratories accreditation and detailed in their Quality Assurance and Quality Control procedures. Sample containers, properly cleaned and containing the proper preservative, should be supplied by the analytical laboratory. In cases where standard methods are not available, the Laboratory will execute method development and follow closely related standard practices, and demonstrate accuracy and precision of the method with at least a 5-point standard curve, sample spikes, and duplicate analyses. ' Macrobenthos sampling will be conducted by a certified laboratory based on a list approved by NC Division of Water Quality. Turf & Environmental Management Associates, Inc Raleigh, North Carolina Environmental Monitoring Program Page 11 3.0. PHASE II: SURFACE WATER, GROUNDWATER, AND SEDIMENT QUALITY ' DURING OPERATIONS The goal of Phase H is to assess the effect of construction and operational activities on surface water, groundwater and sediment quality. 3.1. Sample Locations. Surface Water. Surface water will be sampled at the same locations that are described in Phase I monitoring program. Groundwater. Groundwater will be sampled at the same locations that are identified in the Phase I monitoring program. Sediment. Pond sediment will be sampled at the same locations that are identified in the Phase I monitoring program. The Phase I sediment sampling station will be ponded during construction. Thus, in this phase of the sampling program the location will be changed from the tributary to the pond that will be constructed. Macrobenthos. Macrobenthos sampling will occur at the same locations that are identified in the Phase I monitoring program Sample locations will be photographed and marked on maps. Data from this sample station will allow an assessment of the quality of the sediment in the pond. 3.2. Sample Frequency. The goal of Phase H is to monitor surface water, ground water and sediment quality during operation of the golf course. Surface water samples will be collected four times per year. One surface sample will be taken in the Winter, Spring, Summer, and Autumn. Should water not be available on a given sample date, two additional attempts will be made to obtain a sample within the time period. Groundwater samples will be collected four times per year during Winter, Spring, Summer, and Autumn. A sediment sample will be collected one time per year at the time of surface water sampling in the Spring. Turf & Environmental Management Associates, Inc Raleigh, North Carolina I Environmental Monitoring Program Page 12 ' Macrobenthos sampling will occur one time per year at stations MB-2, MB-3, & MB-4 and twice a year at station MB-l. Annual sampling will occur during the I winter and biannual sampling during winter and summer. Water quality sampling will be reduced to Spring and Autumn events after three years of ' operation, provided that the no significant detections or changes in water quality have occurred. The Criteria for Management Response outlines the detections or changes that are significant. Detections of a pesticide listed in Table 1, will trigger additional analyses as described in Criteria for Management Response. r 3.3. Sample Variables . Surface water, groundwater and pond sediments will be analyzed for the variables listed in Table 1. 3.4. Field Methods. Variables, container type, preservation and holding times for water samples are given in Table 2, and for sediment samples in Table 3. ' Surface Water. Surface water sampling will follow the protocols outlined in Phase I. Groundwater. Groundwater sampling will follow the protocols outlined in Phase I. ' Sediment. Sediment will be collected with a gravity type sediment coring device or by hand. Sampling will occur at three locations around the edge of the pond (sample points will form a triangle around the center of the pond) and will be composited into one sample in the field. The three samples will be collected from near shore sediments. The approximate top 10-cm of the sediment will retained and analyzed for the variables listed ' in Table 1. Macrobenthos. Sampling will follow the protocols outlined in Phase I. 3.5. Laboratory Methods . Laboratories used for sample analysis will follow the protocols outlined in Phase I. Turf & Environmental Management Associates, Inc Raleigh, North Carolina i i i i i i Environmental Monitoring Program Page 13 4.0. DATA, REPORTING, AND RESPONSE CRITERIA 4.1 Data Storage and Reporting Data generated from this monitoring program will be maintained by the superintendent along with other course records and data on pesticide and fertilizer use, personnel, and training. The data from the monitoring report will be available to governmental officials within 20 working days from the date of sampling. Monitoring data from field sampling and from laboratory analyses will be entered into a computer spreadsheet (e.g., QuattroPro, Lotus 1,2,3). Data analyses will be performed with this data set. A summary of the results of the surface and groundwater and sediment samples, with a list of any remedial actions that were taken will be kept. The golf course superintendent will maintain records of cultural activities at the course. Items will include application schedules of all pesticides and fertilizers applied to the golf course as outlined in the Pesticide section of this Plan. Information will include the date of application, rate of application, product used, and specific location where the material was applied. Scouting records as part of the IPM program will also be kept. 4.2 Data Analysis Data generated in the monitoring program will be compared to background concentrations and State surface water and groundwater standards. Data will also be compared with State water quality criteria and the USEPA pesticide Health Advisories Limits (HAL's, given in Table 5) that have been reduced by a factor of 0.5. This is a very conservative factor given that HALs have a margin of safety of 100 to 1000 already built into the HAL number. In Phase II , concentrations of water and sediment variables will be compared with background concentrations to determine changes from background conditions. Soils data will be compared with known requirements for turfgrass and adjustments in the fertilization rates will be made. Protection of aquatic life will be evaluated by comparing measured concentrations against LCso data (Table 5) that have been reduced by a factor of 10. LCso data exist for most of the chemicals, and the lowest LCso obtained for the pesticide was divided by a correction factor of 10 to obtain a screening criteria (Suter et al., 1989; Warren-Hicks et al., 1989). This is a conservative factor in that most measured chronic values would be higher than those estimated from this factor (Suter et al. 1983). Turf & Environmental Management Associates, Inc Raleigh, North Carolina Environmental Monitoring Program Page 14 4.3 Criteria for Management Response Non pesticide analytes. If concentrations of non-pesticide variables exceed Applicable State Water Quality Criteria, or if an increasing trend is observed (a statistically significant trend), or if measured concentrations of nutrients exceed the standard deviation of background levels by more than two-times, then the media will be resampled and a review of management practices, site conditions and weather conditions will be implemented to determine reasons for increased concentrations. The immediate action will also include a reduction in fertilizer use and/or an increased proportion of slow-release fertilizers. Following the review cited above, these immediate restrictions may be lifted or modified, as appropriate. Records of all actions taken will be maintained by the superintendent. i i Pesticide analytes. If a pesticide listed in Table 1 is' detected in samples at concentrations below a toxicologically significant level as determined by the USEPA Health Advisories Limits (HAL x 0.5) or by the aquatic toxicity as measured by LC5o x 0. 1, whichever is lower, the following responses will result: 1. The sample station, from which the exceedance was obtained, will be resampled and reanalyzed for the pesticide. 2. Further testing will be required for an additional suite of pesticides ('secondary level'). A list of secondary pesticides is given is Table 4. Pesticides were included in this second tier based on the results of the Tier 1 analysis. 3. A review of the use, weather conditions after its application, and possible alternative control measures will be made and a decision made on the continued use of the s ecific roblem esticide. Table 4. ' The 'Second Level` ('Tier H) List' of Pesticides To Be Analyzed if Routine Analyses Indicate Concentrations of Pesticides in Samples. Ground Water Surface Water chloroneb chloroneb diclofop-methyl diclofop-methyl dithiopyr dithiopyr fonofos fonofos cyfluthrin cyfluthrin fenamiphos if used in the last 50 days fenamiphos if used in the last 50 days Turf & Environmental Management Associates, Inc Raleigh, North Carolina Environmental Monitoring Program Page 15 If a pesticide listed in Table 1 is detected in samples at a concentration above a toxicologically significant level as determined by the USEPA Health Advisories Limits (HAL x 0.5) or by the aquatic toxicity as measured by LC5o x 0. 1, whichever is lower, the following responses will result: 1. The pesticide will be immediately removed from the list of recommended pesticides for use on the golf course, and its use will be terminated. 2. Further testing will be required for an additional suite of pesticides ('secondary level). A list of secondary pesticides is given is Table 4. 3. The sample station, from which the exceedance was obtained, will be resampled twice and reanalyzed for the pesticide. Should subsequent resampling and analysis indicate concentrations below HAL's, the golf course may reinstate the pesticide on the list of recommended pesticides. 4. If a pesticide listed in Table 1 is detected in samples at a concentration above a toxicologically significant level as determined by the USEPA Health Advisories Limit (HAL x 0.5) or by the aquatic toxicity as measured by LC50 x 0.1, whichever is lower, water samples from the drinking water wells of the most immediate property owners downgradient will also be analyzed for the contaminant. Should the material be detected at a level above that as stated above, The Preserve at Jordan Lake Golf Club will be responsible for appropriate remediation. This could include providing bottled drinking water and re-sampling of the wells until the contaminant level drops or having new wells installed for the property owners. Criteria for management response are summarized in Table 5. Turf & Environmental Management Associates, Inc Raleigh, North Carolina Environmental Monitoring Program Page 16 i i i i Table 5. Response' hresholds for Variables at The Ereserve at Jordan Lake Golf Club. Variable Surface Water Ground, Water'. pH Outside of 6.5 to 8.5 Outside of 6.5 to 8.5 Nitrate Nitrogen North Carolina water standard or two standard deviations above the baseline mean, whichever is lower; or an increasing trend (see text). 5 ppm or two standard deviations above the baseline mean, whichever is lower; or an increasing trend (see text). Total Phosphorus North Carolina water standard or two standard deviations above the baseline mean, whichever is lower; or an increasing trend (see text). North Carolina water or two standard deviations above the baseline mean, whichever is lower; or an increasing trend (see text). Chloride two standard deviations above the baseline mean 250 ppm Total Dissolved Solids 500 ppm NA Turbidity no increase from baseline NA Chlorpyrifos LC50 x 0-1=0.71 ppb LC5o x 0.1 =0.71 ppb Mecoprop HAL x 0.5= 17.5 ppb HAL x 0.5= 17.5 ppb Fenamiphos HAL x 0.5 = 1 ppb HAL x 0.5 = 1 ppb chloroneb HAL x 0.5 = 45 ppb HAL x 0.5 = 45 ppb diclofop-methyl HAL x 0.5 = 5 ppb HAL x 0.5 = 5 ppb dithiopyr LC50 x 0.1 = 48 ppb LC50 x 0-1= 48 ppb fonofos LC5o x 0.1 = 2 ppb LC5o x 0.1 = 2 ppb oyfluthrin LC50 x 0-1= 0.014 ppb LC50 x 0.1 = 0.014 ppb f Note that for non pesticide analytes, if an increasing trend is observed (a statistically significant trend) action will also be triggered. Nate that for pesticides, the lower of HAL and LC50 is used as the trigger concentration, thus maldn this very conservative. Turf & Environmental Management Associates, Inc Raleigh, North Carolina IR i i Environmental Monitoring Program Page 17 5.0. FIELD QUALITY CONTROL AND GENERAL WATER AND SEDUAENT SAMPLING CONSIDERATIONS. The field quality assurance program is a systematic process which, together with the laboratory quality assurance programs, ensures a specified degree of confidence in the data collected for an environmental survey. The field quality assurance program involves a series of steps, procedures and practices which are described below. 5.1. General Measures. a. All equipment, apparatus and instruments should be kept clean and in good working condition. b. Records should be kept of all repairs to the instruments and apparatus and of any irregular incidents or experiences which may affect the measures taken. C. It is essential that standardized and approved methodologies be used by field personnel. d. Macrobenthos sampling by the certified laboratory should follow the criteria as outlined in the NC Division of Water Quality Standard Operating Procedures manual. 5.2. Prevention of Sample Contamination . The quality of data generated in a laboratory depends primarily on the integrity of the samples that arrive at the laboratory, Consequently, the field personnel must take appropriate measures to protect samples from deterioration and contamination. a. Field measurements should always be made on a separate sub-sample, which is then discarded once the measurements have been made. They should never be made on the same water sample which is returned to the analytical laboratory for chemical analysis. b. Sample bottles, new or used, must be cleaned according to recommended procedures. C. Only the recommended type of sample bottle for each parameter should be used. d. Water sample bottles should be employed for water samples only. e. Recommended preservation methods must be used. All preservatives must be of an analytical grade. f. Solvent-rinsed Teflon liners can be used to prevent contamination from the bottle caps of water samples which are to be analyzed for organic compounds. g. The inner portion of sample bottles and caps should not be touched with bare hands, gloves, mitts, etc. h. Sample bottles must be kept in a clean environment, away from dust, dirt, fumes, and grime. Vehicle cleanliness is important. Turf & Environmental Management Associates, Inc Raleigh, North Carolina Environmental Monitoring Program Page 18 i. All foreign and especially metal objects must be kept out of contact with acids and water samples. Petroleum products and exhaust fumes should be kept away from samples. j. Specific conductance should never be measured in sample water that was first used for pH measurements. Potassium chloride diffusing from the pH probe alters the conductivity of the sample. k. Samples must never be permitted to stand in the sun; they should be stored in an ice chest. 1. Samples must be shipped to the laboratory without delay. M. The sample collector should keep their hands clean and refrain from smoking while working with water samples. n. Samplers must wear latex gloves. ' 5.3. Field Quality Control . Quality control is an essential element of a field quality assurance program. In addition to standardized field procedures, field quality control requires the ' submission of samples to check contamination, sample containers, or any equipment that is used in sample collection or handling, and to detect other systematic and random errors occurring from the time of sampling to the time of analysis. Replicate samples must also be collected to check the ' reproducibility of the sampling. The timing and the frequency of equipment blanks, duplicate, and replicate samples are listed in Table 6. ' Equipment Blanks. An equipment blank is prepared in the field at the end of each day's sampling; and one equipment rinsate blank per water medium per day is prepared. An equipment blank is prepared by filling appropriate sample bottles with rinsate from the ' final cleaning of non-dedicated, sample equipment, and transporting them to the laboratory in the same manner as the water samples for analysis. ' Duplicates. Duplicate samples (splits) are obtained by dividing one sample into two sub- samples. One sample in every ten water samples is split. Splits are done periodically to ' obtain the magnitude of errors owing to contamination, random and systematic errors, and any other variables which are introduced from the time of sampling until the samples arrive at the laboratory. ' Replicates. Two samples are taken simultaneously in a given location. The samples are taken to measure the cross-sectional variations in the concentration of the parameters of ' interest in the system. One water sample per quarter will be replicated. Turf & Environmental Management Associates, Inc ' Raleigh, North Carolina ' Environmental Monitoring Program Page 19 Table 6. Number and Types of Samples Taken-for Field uali Control. Equipment Blank one equipment rinsate blank per water medium per day Duplicate one per 10 samples Replicate one per sample medium per quarter 6.0. REFERENCES Madhun, Y.A. and V.H. Freed. 1990. Impact of pesticides on the environment. In Pesticide in the Soil Environment. pp. 429-466. (ed. H.H. Cheng). Soil Science Society of America, Inc., Madison, WI. Suter, G.W. 1989. Ecological end points. PP 1-2 -- 2-28. In W. Warren-Hicks, B.R. Parkhurst and S.S. Baker, (eds) Ecological Assessment of Hazardous Waste Sites: A field and laboratory reference. EPA/600/3-89.013. Suter, G.W. 1990. Endpoints for regional ecological risk assessments. Environ. Manag. 14:19- 23. Suter, G.W. 1993. Ecological risk assessment. Chelsea, MI. Lewis Publishers. USEPA. 1983. Methods for Chemical Analysis of Water and Wastes, EPA-600/4-79-020. USEPA. 1985. Analytical Support Branch, Operations and Quality Control Manual. USEPA. 1987. Test Methods for Evaluating Solid Waste, SW-846, 1986. USGS. 1976. Laboratory Theory and Methods for Sediment Analysis. USEPA. 1993. Guidance Specifying Management Measures For Sources of Nonpoint Pollution in Coastal Waters. EPA 840-B-92-002. Washington, DC. Warren-Hicks, W., B.R. Parkhurst and S.S. Baker, (eds). 1989. Ecological Assessment of Hazardous Waste Sites: A field and laboratory reference. EPA/600/3-89.013 Turf & Environmental Management Associates, Inc Raleigh, North Carolina I Environmental Monitoring Program Page 20 APPENDIX I Turf & Environmental Management Associates, Inc ' Raleigh, North Carolina Sample of Pesticide Use Record Application Date: ' Ti e f Da m o y: Operator: Su i perv sor: PEST: i i i Weather Conditions Temperature degrees F Humidity % Wind Speed MPH Wind Direction Rainfall inches Soil Moisture Pesticide Active Ingredient Amount of Formulation Amount of Water Adjuvant/Surfactant Area Treated: Amount of Pesticide Used:_ Application Equipment: Acres Sprayer Amount of Formulation Square Feet Spreader Remarks: a. Surface Water Field Sampling Sheet ' Station Number: Samplers: Description:: 1 Date' of Sampling: Time of Sampling: ' Weather: Field Measurements Water Temp (°C) Air Temp (°C) pH Specific Cond(u.S) Depth of Water (m) Depth Sample Taken (m) Wetted Area (m) Water Flow (m/sec) 1 Calibration of Instruments Specific Conductance: Meter Reading in IKC1 soln: pH meter Model: Calibration Buffers used: ' Sample Apparatus: Mode of Trasport ' Shipping Date: Remarks: i Turf & Environmental Management Associates, Inc Raleigh, North Carolina b. Sediment Sampling Sheet ¦ Station Number: Samplers: ' Description: Date' of Sampling: Day Month Year ' Time of Sampling: Hour Minute i i i i i i i i i i i i i Field Measurements Water Temp ('C) Air Temp ('C) pH Specific Cond(uS) Depth of Water at which sample, taken (in)' Specific Conductance: Meter pH Meter Model: Sample Apparatus: Mode of Transport: Shipping Date: Remarks: Calibration of Instruments Meter Reding in KC 1 soln: Calibration buffers used: Turf & Environmental Management Associates, Inc Raleigh, North Carolina i i i i e. Ground Water Field Sampling Sheet Well Number: Samplers: Description: Weather: Date of Sampling: Day Month Year Time of Sampling: Hour Minute Field Measurements Water Temp (°C) Air Temp (°C) pH Specific Cond (uS) Depth of Water at which sample was taken (m); Calibration of Instruments Specific Conductance: Meter Meter Reading in KC I soln: pH Meter Model: Calibration buffers used: Sample Apparatus: Mode of Transport: Shipping Date: Remarks: Turf & Environmental Management Associates, Inc Raleigh, North Carolina I I d. Soils Field Sampling Sheet Station Number: Samplers: Description: Weather: Date' of Sampling: Day" Month Year Time of Sampling: Hour Minute Mode of Transport: Shipping Date: Remarks: Turf & Environmental Management Associates, Inc Raleigh, North Carolina 1 © W A T?R? Michael F. Easley, Governor William G. Ross Jr., Secretary O , 9 North Carolina Department of Environment and Natural Resources - i Alan Klimek, P.E., Director Q C Division of Water Quality Coleen H. Sullins, Deputy Director Division of Water Quality . May 5, 2004 DWQ # 99-1233 Chatham County CERTIFIED MAIL - RETURN RECEIPT REQUESTED Ms. Elaine Chiasso Haw River Assembly P.O. Box 187 Bynum, NC 27228 Dear Ms. Chiasso: RE: Receipt of the Revised Water Quality Monitoring Report for The Preserve development\ Attached please find a copy of a recent response to the Division's April 13, 2004 letter to The Preserve at Jordan Lake Golf Club. You have asked to be copied on all information and further correspondence for this . project - this letter satisfies request. The Division has not completed its review of this document but once that is done, we will copy you on that letter as well. Please telephone me at 919-733-9646 if you have any questions about this information.. This project will remain on hold as incomplete in accordance with 15A NCAC 2H .0505(c). The processing time for this application will begin when this information is received. If we do not hear from you by writing or by fax at (919) 733-6893 within three (3) weeks we will assume you no longer want to pursue the project and will consider it withdrawn. Sincerely, o rR. orney 40 Quality ert' ication Program JRD/bs cc: Raleigh DWQ Regional Office Central Files File Copy Derb Carter, Southern Environmental Law Center J. David Edwards; The Preserve at Jordan Lake Gold Club, 840 The Preserve Trail, Chapel Hill, NC 27517 A N. C. Division of Water Quality, 401 Wetlands Certification Unit, 1650 Mail Service Center, Raleigh, NC 27699-1650 (Mailing Address) 2321 Crabtree Blvd., Raleigh, NC 27604-2260 (Location) (919) 733-1786 (phone); 919-733-6893 (fax), (httn://h2o.enr.state.uc.us/ncwetlands) Customer Service #: 1-877-623-6748 A4- Environmental Golf Concepts, Inc. Golf Course and Environmental Specialists 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell May 4, 2004 Mr. John Dorney NC Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 RE: Letter of April 13, 2004 2003 Water Quality Monitoring Report The Preserve at Jordan Lake DWQ # 99-1233 Chatham County Dear Mr. Dorney: 4( 1 MAY 0 4 2004 I am writing on behalf of Blugreen Corp. to respond to the items as outlined in the above- referenced letter. Also, a revised monitoring report has been prepared and is attached. 1. Phase II a. The November TSS data are missing. Please address this issue. TSS data were not collected by the Aqua Tech Environmental Laboratories, Inc. (ATEL) in November 2003. As discussed below, this is one of a number of sampling and analysis omissions by ATEL. Bluegreen has not received satisfactory explanation of these omissions from ATEL. Due to ATEL's failure to fully implement the monitoring protocols, Bluegreen has terminated its relationship with ATEL and is currently negotiating with Environment 1, Inc. of Greenville, North Carolina, to assume the responsibility for the monitoring program. Additionally, Environmental Golf Concepts has been retained to collate and analyze the data and generate the required reports. This restructuring of the oversight of the monitoring program will ensure that the requirements of the 401 certification are met. b. On Table 1, the footnote states "Note: no DO-Mar, Jun, Oct and Nov ". Please elaborate and explain the missing data. Dissolved oxygen data were not collected by ATEL as required by the monitoring protocol. C. Data on dissolved oxygen, ammonia nitrogen and TKN are missing. Please address this issue. Environmental Golf Concepts, Inc. Golf Course and Environmental Specialists 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell As noted above, DO data was not collected by ATEL and ammonia-N and TKN were not determined by ATEL for the water samples collected even though specified in the monitoring protocol. d. The subsequent sheets of Table I and Table 2 do not have a first column that describes the representative sample rows. Please modify the table accordingly. New data tables have addressed this issue. e. The macrobenthos analysis refers to Stream 1, Stream 2, etc. while the monitoring plan refers to MB 1, MB 2, etc. Please clarify this issue in your written response. MB sample designations are identical to the Stream sample designations. f. The monitoring plan requires sediment samples. Please provide these data or discuss why they are not available. Please clarify this issue in your written response. No sediment samples were collected for analysis by ATEL as required by the monitoring protocol. g. Please address the elevated levels of total P, ortho P, Nitrate, chlorophyll a and turbidity for SW2 in June of 2003. Also address what remedial actions (if any) need to be taken to resolve this issue. Nitrate, chlorophyll a and turbidity levels in SW2 were somewhat higher than previously observed, but still fell within state water quality standards and acceptable statistical ranges. We do not have an explanation for these elevations, which did not recur in subsequent sampling. Total P and Ortho P were not elevated in June of 2003. h. Coliform data should also be presented as geometric means in addition to averages and standard deviations. Coliform data have been transformed and expressed as a geometric mean across all sample locations for each sampling date (see Tables and Figures in revised report). 2. Phase I a. The following data appear to be missing from this monitoring phase-Ammonia nitrogen, TKN, chlorophyll a, fecal coliform and one set of pesticide data (only two sets provided rather than the three that are required). Please provide these data or discuss why they are not available. Ammonia N, TKN, chlorophyll a, fecal coliform analyses of surface water samples were not performed by ATEL as required by the monitoring protocol. Environmental Golf Concepts, Inc. Golf Course and Environmental Specialists 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax - 919.906.1324 - cell Similarly, pesticide analyses were not performed on one set of samples by ATEL. b. The subsequent sheets of Table 1 and Table 2 do not have a first column that describes the representative sample rows. Please modify the table accordingly. This issue has been addressed on the new data tables. C. Groundwater-Only two samples appear to have been taken rather than the three that were required. Please provide these data or discuss why they are not available. Both 2001 and 2002 were significant drought years. ATEL has indicated that it was unable to perform surface water and groundwater sampling on numerous occasions during these years due to drought conditions. d. Macrobenthos data-Why was stream number 3 not sampled? Again, due to drought conditions, ATEL claims that it was unable to perform the required sampling. e. The monitoring plan requires sediment samples. Please provide these data or discuss why they are not available. ATEL failed to follow the protocol and collect sediment samples for analysis. 3. Overall issues related to the report a. Please consolidate the water chemistry data into graphs (Y axis for concentration and X axis for time) so we can more readily examine the data for trends. The data tables should continue to be provided. The data have been reorganized by sample location and new tables have been included. The data have also been charted for each sample location for each analysis over time. A statistical mean +/- 2SD line is included on the charts. b. Please discuss any data that are greater than the standards or guidelines in both Phase I and Phase II of the monitoring. Please also address any remedial actions needed to address these exceedances. Each analysis of concern will be addressed separately as follows: SWl Fecal coliform counts for Jun, 2003 and Oct, 2003 - This is the major stream below the detention pond at the south end of the property. During low flow any accumulation of organic matter or feces from birds or mammals frequenting the stream could cause his elevation. Fecal coliform counts for Nov, 2003 and Mar, 2004 were well below the acceptable limit. Additionally, the mean fecal coliform count across all sample locations for Jun, 2003 and Oct, 2003 was below the acceptable limit. Environmental Golf Concepts, Inc. Golf Course and Environmental Specialists 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell SWl Turbidity for Mar, 2001 - As noted below, at the time of this sampling event, this stream was showing increased turbidity at the point of entry onto the property. The turbidity levels at this sampling location were considerably lower than at the upstream location. However, construction activity on the property may have contributed to an increase in turbidity in this time frame. SW4 Turbidity for Mar, 2001 - SW4 is at the point where the main stream enters the property from the north. Erosion from upstream was probably a factor. SW5 Turbidity for Mar, 2004 - This site is near an area where active development is occurring. There could have been some turbidity increase associated with land disturbance prior to the sampling date. All other sampling data from this location have not shown problems. This site will be examined to determine the reason for this increase. Dissolved oxygen readings for Mar, 2004 - All readings at the site were exceptionally low and inconsistent with prior and subsequent data and expected field conditions. The most likely explanation is that ATEL had a faulty sensor on its DO meter. MW3 TDS level for Oct, 2001 - This was the initial reading after the well was installed. It was only slightly elevated above the acceptable limit of 500 mg/1(reading of 560 mg/1). All subsequent samples have been below 100 mg/l. C. Macrobenthos data-Who collected and identified the aquatic insect samples? The monitoringplan requires a DWQ-certified lab. Please address this matter in your written response. ATEL's report for the macrobenthos data did not specify who collected the samples and analyzed the data in October 2000 and March 2001. MACTEC of Charlotte, North Carolina, collected and analyzed the data for 2003. d. Macrobenthos data-There appears to have been a decline in macrobenthos numbers, taxa number, Dominants in Common and EPT taxa in streams I and 4 from Phase I to Phase II. Please address this issue in your written response and discuss what remedial actions (if any) you plan to take to address this issue. According to the macrobenthos sampling reports for 2000 and 2001 supplied by ATEL, the bioclassifications for the streams were a concern from the first sampling. According to a communication with Ms. Patricia MacPherson, NCDNER, the streams sampled were so small that NC state biologists would not apply a bioclassification to them. They indicated they are currently developing criteria to help assess small, first-order streams such as the ones sampled for this project. Based on this information, any change in stream flow Environmental Golf Concepts, Inc. Golf Course and Environmental Specialists 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell could have a dramatic impact on macrobenthos numbers, taxa numbers and/or dominant common or EPT species. The drought conditions during 2001 and 2002 certainly impacted the ability of the laboratory to sample surface and groundwater and low stream flows could have had an exceptionally detrimental effect on stream biota. If you have any questions or concerns about any aspect of the responses to your letter or the revised monitoring report please do not hesitate to contact me. Sincerely, Charles H. Peacock, PhD President Enclosure cc: J. David Edwards Steven J. Levitas, Esq. 2003 Water Quality Monitoring Report The Preserve at Jordan Lake Prepared for: B1ueGreen Golf Revised May 4, 2004 Prepared by: Dr. Charles H. Peacock Environmental Golf Concepts, Inc. Environmental Golf Concepts, Inc. Golf Course Consultants Introduction The Section 401 Water Quality Certification issued on August 9, 2000, by the North Carolina Division of Water Quality (DWQ) to Bluegreen Corporation (Bluegreen) for the development of The Preserve at Jordan Lake (the Project) required Bluegreen to implement an environmental monitoring plan for the Project and to submit an annual monitoring report to DWQ. The required environmental monitoring plan was prepared for Bluegreen by Turf & Environmental Management Associates, Inc. This report summarizes the results of the environmental monitoring program for 2003, which was the first year that Phase II (post-development) of the monitoring program was implemented. In addition, Appendix A of the report summarizes and presents data collected in previous years pursuant to Phase I of the environmental monitoring program and Appendix B presents trend analysis data through the most current monitoring. The required environmental monitoring was performed under the direction of Aqua Tech Environmental Labs, Inc., Sanford, NC. Portions of the sample analyses were outsourced to various subcontractors for specific components of the testing. Data are presented in table format for specific parameters tested. Statistical analysis included comparisons using standard water quality criteria testing which compared individual values with the mean plus or minus two standard deviations. Aquatic macroinvertebrate data were evaluated for EPT taxa and the streams categorized according to DWQ criteria for flowing streams in the Piedmont as follows: Metric Range EPT Taxa Richness >27 21-27 14-21 7-13 0-6 Interpretation Excellent Good Good-Fair Fair Poor Environmental Golf Concepts, Inc. 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com Environmental Golf Concepts, Inc. Golf Course Consultants Water Quality Data Surface water and groundwater quality monitoring data for 2003 are presented in Tables land 2, respectively. Surface water quality was sampled four times. Fecal coliform concentrations were low in the Spring, peaked in the Summer and returned to low levels in the Fall with the exception of the October sampling for the SW1 location. All values were within the mean +/- 2SD range for each sampling date. Some seasonal variability is to be expected and this was noted. The high values at SW 1 for June and October would indicate that an anaerobic condition may have existed at this location or that animal droppings may have contributed to the high count. Ortho-P levels were low ranging from 0.01 to a high of 0.07 mg/l. Turbidity values were low, as were Total Dissolved Solids (TDS) values, which ranged from 64 to 160 mg/l. Temperatures were consistent across sample locations showing only temporal variability. pH was more alkaline in the March samples but all values were within the acceptable mean +/- 2SD range and only slightly above the recommended range of 6 to 8 and only at the March sample date. Conductivity was highest for the June readings and lowest for the March sampling. This is probably linked to the amount of runoff in June compared to March. Chlorophyll values were highest in Mar, but all values fell within the mean +/- 2SD range and were less than 20 gg/1 which is often set as a eutrophication criteria level. Nitrates and Total P values were also low. No pesticides were detected in any sample. Groundwater monitoring data found low levels for TDS for all sample dates with the highest values found in October and November. pH was within an acceptable range for all dates with only the MW6 location above 8 and only for the Mar and Jun dates. Conductivity was lowest at the June sampling and highest at the October date. Conductivity values were lower in November than October for all locations except MW6 although this value was still within acceptable limits. Nitrate values were very low with no concentration above 0.25 mg/1. Total P was highly variable not only among sample locations but among sample dates at the same location. The MW2 November sampling date value was the only one outside the acceptable limit and only by 0.8%. No pesticides were detected in any sample. Environmental Golf Concepts, Inc. 2 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com Environmental Golf Concepts, Inc. Golf Course Consultants Benthic Macroin vertebrate Data Benthic macroinvertebrates were collected from four streams within the boundary of the Project on March 25, 2003. Samples were collected using the Ephemeroptera, Plecoptera, and Trichoptera (EPT) method described in the most recent Standard Operating Procedures from DWQ. It involves one kick net sample, one sweep net sample, one leaf-pack, and one visual collection at each location. The final bioclassification for this type of collection is based solely on the number of EPT taxa in the sample. The bioclassifications for the streams sampled on March 25, 2003 were "Poor" for all sample locations with EPT numbers of Creek 1 (4 EPT taxa present), Creek 2 (6 EPT), Creek 3 (2 EPT) and Creek 4 (6 EPT).However, the streams sampled were so small that state biologists would not apply a bioclassification to them. DWQ is currently developing criteria to help assess small, first- order streams such as the ones sampled for the Project (communication between Aqua Tech personnel and Patricia MacPherson, NCDENR). Moreover, the extreme drought during 2002 is likely to have had a significant impact on these small streams from a biological perspective. Data for 2004 will hopefully see a recovery, although only one stream at one sampling date ever had EPT taxa which categorized it as "Good-Fair." Macroinvertebrates collected from streams within the Project on March 25, 2003 are identified below. An "R" means a taxon was rare (1 or 2 collected), C is common (3 to 9), and A is abundant (10 or more). Taxon Creek 1 Creek 2 Creek 3 Creek 4 Annelida Oligochaeta Branchiobdellida Branchiobdellidae R R Haplotaxida Naididae Bratislavia unidentata R Nais elinguis R A C Pristinella jenkenae R Arthropoda Arachnoidea Environmental Golf Concepts, Inc. 3 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com Environmental Golf Concepts, Inc. Golf Course Consultants Acarina Hydrachnellidae Hydracarina R Crustacea Amphipoda Talitridae Hyalella azteca R C C Decapoda Cambaridae Cambarus spp. R Isopoda Asellidae Caecidotea spp. R C Insecta Coleoptera Dryopidae Helichus lithophilus R Dytiscidae Bidessus spp. R Ptilodactylidae Anchytarsus bicolor C Diptera Ceratopogonidae Alluaudomyia spp. R Chironomidae-Chironominae Glyptotendipes spp. R R Polypedilum flavum R Polypedilum tritum R R R Chironomidae-Orthocladiinae Orthocladius robacki C A R Parametriocnemus spp. R R Chironomidae-Tanypodinae Rheopelopia spp. R R R Tipulidae R Hexatoma spp. R R Tipula spp. R Environmental Golf Concepts, Inc. 4 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com Environmental Golf Concepts, Inc. Golf Course Consultants Ephemeroptera Baetidae Baetis punctiventris Ephemerellidae Eurylophella doris Heptageniidae StMacron interpunctatum Stenonema femoratum Leptophlebiidae Paraleptophlebia spp. Heteroptera Corixidae Corixidae Plecoptera Leuctridae Leutra spp. Nemouridae Amphinemura spp. Perlodidae Isoperla spp. Trichoptera Hydropsychidae Cheumatopsyche spp. Diplectrona modesta Limnephilidae Ironoquia punctatissima Phryganeeidae Agyrpnia vestita Rhyacophilidae Rhyacophilia glaberrima Mollusca Gastropoda Basommatophora Physidae R C A R R R C R R C C C A C R R Physella spp. A Total Taxa Found 15 19 13 Number of EPT Taxa 4 6 2 Environmental Golf Concepts, Inc. 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com R R A R C C R 18 6 5 O •- O O OD I- N CO Z I- ? M 0 0 LO - M N M U ? CO N co ? N r- Lo N ti O t-? M 4 6 6 I_: M f_ O It C 00 ti C.) 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O It O M 00 Lo Ln 00 N -,t W Z M O O O O O O .- M N M U N .- L1) O CO C M O O O M N r,: ',0 7 CC) N I- 00 N O 0 0 0 0 0 O c- - N O C M 0) `- CO O N - LO O It O d M LO .4 O co LL) LC) d N 00 ?- 0 0 O O O O O O O C? ?- M N a C U C D 0 C C O ? C ? LLo CD CD , 'O O O O O O O O • O H > O Un O LO O C N N <- LO O U) O 0) O r` O M - 'It 0 N N Z O O 0 0 0 0 0 0 0 0 V 00 O LL] O Lo N r-- O ? G C O O O .-- 00 O l! ) LO L1) N O) O 0 0 6 0 0 O O O O O O C ? .- rn M co 00 LO co d• O h M 7 '-'t .- 0 0 0 0 0 0 0 0 0 0 0 0 O M CT O O N O N N Z { LO O C O O O C 0 co N 0 LO 0 M 0 N C O O O O O O O O C) 0 0 J C Z fD 72 >O M M -0 m m M M O O CO Z N N C t17 I? N CO ? N w "t N (6 N Z a) cn V 0 O N co LO N t 'a C N O 0 0 4 06 06 N (O 00 "t 00 - O .C ? F O E ' CU 0 C Cp N M CO O N to N CO L) M ? M O N N cP N d N j C co co i O M CD C >. O > C ? 7 Cfl '7 LO r--: C W A M N *0 C M CO 00 O 00 N f- co O d dO ? M N C 0 IV Q o 3 c c/) O N M d LC) Co I- co C Q N N O rG N C6 C U CO J C N C6 N co II Q O Q H N Z 6 O 6 a) O N C 00 ` N "? '? 'O "O '6 'O O V ` C M O > Z a Q n w 0 o ' o ? cn O O Q Z -0 N N o a o a Z n a 0 ` U 0 C) CL 7 0 -) O Z N 2 N -p 'q -p -p -p -p -p 'O O - i i J N p D OO E E ? 2 Z cu 72 o •a -a ? -o -o -o a a) Z (n 0 0 0 d U "d '5 'O 'L7 'd -0 Q -0 -0 -0 -0 m c ? a? a) s CD F- 0 3 c ° ° ° ? ? -0 ? 0 o n n n CD :3 c y c > II II O O O O. N '0 -O 'a .6 .D a .0 'O +' M O Z E O _ .O -0 C ID Q Z N N CO - - 6 0 0 0 0 a• O Y • 3 Q O ? .0 N m t L n D ( r- co c Q N N 32 32 Q U > » > > : > >>» M UC)l X + f6 ? ? ? ? ? ? ? ? N C Co C7 cu J CV N '0 y N C7 I I O D H N M r U) Li Environmental Golf Concepts, Inc. Golf Course Consultants APPENDIX A Phase I Surface Water and Groundwater Quality Monitoring Data Environmental Golf Concepts, Inc. 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com Environmental Golf Concepts, Inc. Golf Course Consultants Phase I of the environmental monitoring plan called for pre-development sampling and analysis to establish baseline conditions at the Project. Unfortunately, drought conditions in 2001 and 2002 prevented much of the sampling envisioned by the plan. All available Phase I data is presented in this Appendix. Surface water quality data from the Fall of 2000 and the Spring of 2001 are presented in Tables A-1 and A-2, respectively. During the Fall of 2000, dissolved oxygen content exceeded what is considered a minimum threshold level of 4.5 mg/1 for all locations. Turbidity levels were low and ranged from 2.7 to 9.4 NTU. Temperatures were moderate and averaged -21 C. Water pH was slightly acidic to near neutral and ranged from 6.4 to 7.4 which is considered within an acceptable range of 6 to 8. Conductivity was also low and ranged from 100 to 188 gmhos/cm. All values fell within statistical standards of mean +/- 2 standard deviations (SD). In the Spring 2001, dissolved oxygen content was also acceptable ranging from 6.7 to 8.5. Turbidity values varied widely from 12.5 to 410 at sample location SW 1 and 825 at sample location SW4. All values were within acceptable statistical standards based on the mean +/- 2SD criteria. Winter rainfall runoff and construction activities may have contributed to the increases observed for the two sample locations compared to Fall 2000 values. TDS values were also variable, ranging from 94 to 302. However, values for all locations were within acceptable limits. Temperature was consistent across all sample locations and pH was within the acceptable range. Conductivity was still low even with increased turbidity levels at locations SW1 and SW4. Nitrates and Total Nitrogen (N) were low with nitrates less than 0.07 mg/l for all locations. Total Phosphorus (P) values ranged from 0.09 to 0.94 with the highest values at locations SW1 (0.54 mg/1) and SW4 (0.94 mg/1) which correlates to those locations showing increased turbidity levels. No pesticides were detected in any of the samples. Groundwater monitoring data for the Fall of 2001 and the Fall of 2002 are presented in Tables A-3 and A-4, respectively. TDS values ranged from 190 to 560 mg/l. This is not unusual since materials dissolved in groundwater will vary from one location to another. All values fell within the mean +/- 2SD criteria. pH was also highly variable with values ranging from 5.8 to 8.3 There was no correlation with pH and TDS. Conductivity was low with values ranging from 90 to 337 kcmhos/cm. Nitrates were low at all locations with the highest value at MW9 (1.25 mg/1). Total N was also low with the highest value at MW2 (2.8 mg/1). Similarly Total P was less than 1 mg/1 except for MW6. No pesticides were found in any samples. In the Fall of 2002, fecal coliform counts in groundwater varied widely from <2 to 600. While all values fell within the mean +/- 2SD range, the values for MW 2 of 240 and MW4 of Environmental Golf Concepts, Inc. 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com Environmental Golf Concepts, Inc. Golf Course Consultants 600 would seem to be extremely high for groundwater samples. Suspended solids were low ranging from 31 to 165 mg/1. pH was highly variable ranging from 6.0 to 9.4, however, all values fell within an acceptable range. Conductivity was low ranging from 23 to 65. Nitrate levels were acceptable ranging from 0.05 to 2.7 mg/1. Total P ranged from 0.06 to 1.41 mg/l. There was no correlation between Total P levels from the previous sample date. The location with the highest value for Total P at the Fall 2001 sample date (MW6) with a concentration of 5 mg/l had an extremely low value of 0.12 mg/l at this sampling. Only the value from MW2 had a value outside the acceptable range of mean +/- 2SD and it was only 1.4% greater. No pesticides were detected in any samples. Benthic Macroin vertebrate Data Benthic macro invertebrates were collected from three streams within the boundary of the Project on October 12, 2000. A fourth stream was scheduled to be sampled, but it had obviously been dry for some time prior to the sampling date. Samples were collected using the EPT method. The final bioclassification for this type of collection is based solely on the number of EPT taxa in the sample. The bioclassifications for the streams sampled on October 12, 2000 were "Fair" for Creeks 1 and 4 where there were 8 and 9 EPT taxa, respectively, and "Poor" for Creek 2 where only 2 EPT's were present. The streams sampled were so small that state biologists would not apply a bioclassification to them. Environmental Golf Concepts, Inc. ii 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com Environmental Golf Concepts, Inc. Golf Course Consultants Macroinvertebrates collected from streams within the Project on October 12, 2000 are identified below. An "R" means a taxon was rare (1 or 2 collected), C is common (3 to 9), and A is abundant (10 or more). Taxon Creek 1 Creek 2 Creek 4 Annelida Oligochaeta Branchiobdellida Branchiobdellidae R Haplotaxida Naididae Nais communis R Tubificidae Tubifex tubifex A Arthropoda Crustacea Amphipoda Talitridae Hyalella azteca C A C Decapoda Carnbaridae R A Isopoda Asellidae Caecidotea spp. A Insecta Coleoptera Dytiscidae Bidessus spp. C R Psephenidae Psephenus herricki A A Diptera Chironomidae-Chironominae Chironomus spp. R Microtendipes pedellus gp. R Paratanytarsus spp. R Paratendipes spp. R Phaenopsectra spp. R R Environmental Golf Concepts, Inc. 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com iii Environmental Golf Concepts, Inc. Golf Course Consultants Polypedilum fallax R Polypedilum flavum R R Polypedilum illinoense C Chironomidae-Orthocladiinae Cricotopus triannulator R Chironomidae-Tanypodinae Procladius bellus R Zavrelimyia spp. R R Culicidae Aedes spp. R Anopheles sp. R Tipulidae R Pseudolimnophila spp. R Tipula spp. R Ephemeroptera Baetidae Baetis intercalaris C Baetis spp. R Centroptilum spp. A Caenidae Caenis spp. C A Heptageniidae Heptagenia marginalis R C Stenacron interpunctatum C Stenonema femoratum C A A Leptophlebiidae Paraleptophlebia spp. C Hemiptera Saldidae R R R Heteroptera Corixidae A Megaloptera Corydalidae Nigronia serricornis R Sialidae Sialis spp. R C Environmental Golf Concepts, Inc. iv 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com Environmental Golf Concepts, Inc. Golf Course Consultants Odonata-Anisoptera Aeshnidae Aeshna umbrosa R Boyeria vinosa R Corduliidae Neurocordulia obsoleta C Gomphidae Stylogomphus albistylus R Odonata-Zygoptera Calopterygidae Calopteryx dimidiata R Calopteryx maculata R Coenagrionidae Argia spp. C Plecoptera Perlidae Eccoptura xanthenes C C Trichoptera Hydropsychidae Hydropsyche slossonae C R Philopotamidae Chimarra spp. R A Polycentropodidae Polycentropus spp. R Total Taxa Found 22 19 24 Number of EPT Taxa 8 2 9 Environmental Golf Concepts, Inc. 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com v Environmental Golf Concepts, Inc. Golf Course Consultants Benthic macroinvertebrates were collected from three streams within the boundary of the Project on March 15, 2001. A fourth stream location was scheduled, but it was dry in spite of recent rain. Samples were collected using the EPT method. The bioclassifications for the streams sampled on March 15, 2001 were "Good-Fair" for Creek 1 (19 EPT taxa present), "Poor" for Creek 2 (4 EPT) and "Fair" for Creek 4 (12 EPT). As previously noted, the streams sampled were so small. that state biologists would not apply a bioclassification to them. Macroinvertebrates collected from streams within the Project boundaries on March 15, 2001 are identified below. An "R" means a taxon was rare (1 or 2 collected), C is common (3 to 9), and A is abundant (10 or more). Taxon Creek 1 Creek 2 Creek 4 Annelida Oligochaeta Branchiobdellida Branchiobdellidae C Haplotaxida Naididae Pristina breviseta R Arthropoda Crustacea Amphipoda Gammaridae Gammarus spp. R C Talitridae Hyalella azteca C A Decapoda Carnbaridae R C C Isopoda Asellidae Caecidotea spp. A Insecta Coleoptera Curculionidae Rhinoncus longulus R Environmental Golf Concepts, Inc. vi 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com Environmental Golf Concepts, Inc. Golf Course Consultants Dryopidae Helichus lithophilus R Dytiscidae Bidessus spp. R R Hydrophilidae Tropisternus spp. R Psephenidae Psephenus herricki A Diptera Chironomidae-Chironominae Cryptochironmus spp. R Microtendipes pedellus gp. R Paralauterborniella nigrohalterale R Polypedilum spp. R Chironomidae-Orthocladiinae Cricotopus tremulus R Heterotrissocladius spp. R Parametriocnemus spp. R C Chironomidae-Tanypodinae Rheopelopia spp. R Dixidae Dixella spp. C R Simuliidae Prosimulium spp. R Simulium spp. R Tipulidae R Hexatoma spp. C Tipula spp. C C Ephemeroptera Baetidae Acentrella spp. R Acerpenna pygmaeus R Baetis intercalaris R R Centroptilum spp. A Caenidae Caenis spp. C Environmental Golf Concepts, Inc. vii 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com Environmental Golf Concepts, Inc. Golf Course Consultants Ephemerellidae Ephemerella hispida R Timpanoga simplex C Heptageniidae Stenacron interpunctatum C Stenonema femoratum R C Stenonema modestum C Leptophlebiidae Leptophlebia spp. A Paraleptophlebia spp. R A Oligoneuriidae Isonychia spp. C Siphlonuridae Ameletus lineatus R C Megaloptera Corydalidae Nigronia fasciatus R Nigronia serricornis R Odonata-Anisoptera Aeshnidae Boyeria spp. R Cordulegastridae Cordulegaster maculata R Corduliidae Neurocordulia spp. R Gomphidae Lanthus vernalis R Stylogomphus albistylus R Odonata-Zygoptera Calopterygidae Calopteryx maculata R Plecoptera Nemouridae Amphinemura spp. C C Perlidae Eccoptura xanthenes C Environmental Golf Concepts, Inc. viii 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com Environmental Golf Concepts, Inc. Golf Course Consultants Perlodidae Isoperla spp. C Trichoptera Hydropsychidae Diplectrona modesta A C Hydropsyche betteni R Lepidostomatidae Lepidostoma spp. A Limnephilidae Ironoquia spp. A Pycnopsyche spp. R C Philopotamidae Chimarra spp. R R Polycentropodidae Polycentropus spp. R R Uenoidae Neophylax ornatus R R Total Taxa Found 35 16 25 Number of EPT Taxa 19 4 12 Table A-1. Surface water quality monitoring data for The Preserve at Jordan La ke, Fall 2000 2000 data DO mg/I Turbidity NTU Temperature C pH Conductivity umhos/cm Location Oct Oct Oct Oct Oct SW 1 8.8 2.74 21.1 6.4 173 SW2 4.6 9.4 20.7 7.2 100 SW3 8.6 7.6 20.8 7.4 188 SW4 8.6 5 20.8 7.2 188 Mean 7.7 6.19 20.9 7.1 162 SD 2.0 2.9 0.17 0.44 42 2SD 4.1 5.8 0.35 0.89 84.2 Mean - 2SD 3.6 0.3 20.5 6.2 78.1 Mean + 2SD 11.7 12.0 21.2 7.9 246.4 SD = standard deviation Environmental Golf Concepts, Inc. 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com ix Environmental Golf Concepts, Inc. Golf Course Consultants Table A-2. Surface water ualit moni toring data for The Preserve at Jordan Lake, Spring 2001 2001 data DO mg/l Cl mg/1 Ortho-P mg/1 Turbidity NTU TDS mg/l Temperature C pH Conductivity umhos/cm Location Mar Mar Mar Mar Mar Mar Mar Mar SW1 8.5 13 nd 410 141 10.9 7.4 108 SW2 7.7 18 nd 27.4 94 10.5 6.9 83 SW3 nd nd nd nd nd nd nd nd SW4 6.7 9 nd 825 302 10.5 6.9 55 SW5 7.9 11 nd 12.5 110 10.6 7.4 122 Mean 7.7 12.8 318.7 161.8 10.6 7.2 92 SD 0.75 3.9 384.4 95.5 0.2 0.3 29 2SD 1.50 7.7 768.8 191.0 0.4 0.6 59 Mean - 2SD 6.20 5.03 -450.07 -29.28 10.25 6.57 33.05 Mean + 2SD 9.20 20.5 1087.5 352.8 11.0 7.7 151 SD = standard deviation Table A-2. Surface water quality monitoring d ata for The Preserve at Jordan Lake, Spring 2001 2001 data Chlorophyll a ug/I N03+NO2 mg/I Total N mg/I Total P mg/1 Chlorpyrifos ug/I Mecoprop ug/1 Propiconazole ug/I Location Mar Mar Mar Mar Mar Mar Mar SW1 nd 0.05 0.5 0.54 bdl bdl bdl SW2 nd 0.05 0.5 0.09 bdl bdl bdl SW3 nd nd nd nd nd nd nd SW4 nd 0.07 1.18 0.94 bdl bdl bdl SW5 nd 0.05 0.5 0.13 bdl bdl bdl Mean nd = no data 0.055 0.67 0.425 bdl = below detection limit SD 0.01 0.34 0.40 2SD 0.02 0.68 0.80 Note: Note: Note: Mean - 2SD 0.04 -0.01 -0.37 detection detection detection Mean + 2SD 0.08 1.35 1.22 limit = limit = limit = SD = standard deviation 0.25 0725 0.25 Environmental Golf Concepts, Inc. x 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com Environmental Golf Concepts, Inc. Golf Course Consultants Table A-3. Groundwater q uality monitoring data for The Preserve at Jordan Lake, Fall 2001 2001 data TDS mg/I Temperature C H Conductivity umhos/cm Cl mg/I N03+NO2 m /I Total N m /I Total P m /I Location Oct Oct Oct Oct Oct Oct Oct Oct MW2 190 17.7 6.3 254 33 0.09 2.8 0.26 MW3 560 18 5.8 90 17 0.19 0.89 0.65 MW4 nd nd nd nd nd nd nd nd MW5 nd nd nd nd nd nd nd nd MW6 192 18.3 6.7 165 14 0.16 0.5 5 MW7 224 16.8 7.5 251 16 0.1 0.5 0.04 MW8 424 16 8.3 337 43 0.06 0.67 0.18 MW9 190 16.5 6.8 202 11 1.25 0.5 0.53 Mean 297 17.2 6.9 239 21 0.31 0.98 1.11 SO 158 0.9 0.9 74 15 0.46 0.91 1.92 2xSD 316 1.8 1.8 149 30 0.93 1.81 3.84 Mean - 2xSD ! 19 15 5 90 -9 -0.62 -0.84 -2.73 Mean + 2x-MD xSD 612 19.0 8.7 387 51 1.24 2.79 4.95 SD = standard deviation Table A-4. Groundwater q uality monitoring data for The Preserve at Jordan Lake, Fall 2002. 2002 data Fecal coliforms CFU/100 ml Suspended Solids mg/I TDS mg/I Temperature C pH Location Sep Sep Sep Sep Sep MW2 240 165 nd 22.2 6 MW3 nd nd nd nd nd MW4 600 51 nd 20 6.1 MW5 nd nd nd nd nd MW6 8 77 nd 19.6 7.7 MW7 <2 31 nd 23.5 9.4 MW8 60 35 nd 23 7 MW9 <2 48 nd 18.4 6.5 Mean 227 68 21.1 7.1 SD 268 50 2.1 1.3 2SD 536 101 4.1 2.6 Mean - 2SD -309 -33 17.0 4.6 Mean + 2SD 763 168 25.2 9.7 SD = standard deviation Environmental Golf Concepts, Inc. xi 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com Environmental Golf Concepts, Inc. Golf Course Consultants Table A-4. Groundwater q uality monitoring data for The Preserve at Jordan Lake, Fall 2002. 2002 data Conductivity umhos/cm N03+N02 m /I Total P mg/I Chlorp rifos u /I Meco ro u /I Pro iconazole m /I Location Se Sep Se Se Se Se MW2 23 0.05 1.41 bdl bdl bdl MW3 nd nd nd nd nd nd MW4 31 0.13 0.06 bdl bdl bdl MW5 nd nd nd nd nd nd MW6 58 0.11 0.12 bdl bdl nd MW7 65 0.1 0.06 bdl bdl bdl MW8 63 0.82 0.11 bdl bdl bdl MW9 28 2.7 0.06 bdl bdl bdl Mean 49 0.65 0.30 bdl = below detection limit SD 18 1.04 0.54 2SD 36 2.09 1.09 Note: Note: Note: Mean - 2SD 13 -1.44 -0.78 detection detection detection Mean + 2SD 85 2.74 1.39 limit = 0.2 limit = 2 limit = 0.002 SD = standard deviation Environmental Golf Concepts, Inc. xii 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com Environmental Golf Concepts, Inc. Golf Course Consultants Appendix B Trend Analysis for Surface Water and Groundwater Quality Monitoring Data Environmental Golf Concepts, Inc. 2009 Longwood Drive Raleigh, NC 27612 919.846.5634 - voice or fax • 919.906.1324 - cell Email: CharlesPeacock@nc.rr.com U O ?- O) LO M M N N LO 07 M (D N O - N - Il N M r- N - I-- - N 4 O M 0- E a) O) E - 0 O m O CO CO N 0b LO d' N M d O I- 0 CO - `- `- M (0 In 0 0 Z >, 00 r- ?t Lo m CN O O O) 00 _ a N CO LO ti r-: 't Lo p N M L L? F- E N I? C) N CO N Lo N O Lo ? N CO I-- ? ' q q q q C5 O O O O O O O O O 6 6 O O O O co O E O y C J O) a O (.0 OR Cn Cfl r- Cn 00 N 00 d: CD ti ) O 0 r O O CO _O N N O E O w O U is U O) LL ? N O ? N fl. U r- M M M E O O M O p ? ? "t ? ti " C C IS LO r- cM ? M ? N 't (D O Lo N Q O aL) U > O v m a? tL ? O _ i? co U?' p 0 0 0 co 0 0 0 C) R CN > - r N C) C) C) N N N N 0 > N N N N a) ? U) 1 C: + cu j ? U co co D U > (CE N (0 CD _0 -5 O Z 2 N co U CO = I I ? 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N 2 m V5 O C 1 p 07 Surface Water Site #1 Fecal coliform CFU/100 ml 700 -------------------------- 600 500 400 - SW1 300 - -Mean +2SD 200 100 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 Surface Water Site #2 Fecal coliform CFU/100 ml 700 600 500 400 -SW2 300 --- Mean +2SD 200 100 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 1 Surface Water Site #3 Fecal coliform CFU/100 ml 700 600 500 400 -SW3 300 - -Mean +2SD -------------------------- 200 100 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 Surface Water Site #4 Fecal coliform CFU/100 ml 700 600 500 400 - SW4 300 - -Mean +2SD 200 100 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 2 Surface Water Site #5 Fecal coliform CFU/100 ml 700 600 500 400 - SW5 300 ... Mean +2SD -------------------------- 200 100 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 Surface Water Site #1 Fecal coliform CFU/100 ml geometric means 4 3.5 - 3- 2.5 2 -SW1 • 1.5 Mean +2SD I- 0.5 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 3 Surface Water Site #2 Fecal coliform CFU/100 ml geometric means 4- 3.5 3 2.5 2 - SW2 • Mean +2SD 1.5 1 0.5- 0- Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 Surface Water Site #3 Fecal coliform CFU/100 ml geometric means 4- 3.5 3 2.5 -SW3 2 • Mean +2SD 1.5 1 0.5 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 4 Surface Water Site #4 Fecal coliform CFU/100 ml geometric means 4 3.5 3 2.5 • Mean +2SD 1.5 1 0.5 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 Surface Water Site #5 Fecal coliform CFU/100 ml geometric means 4- 3.5 3 --- -- - 2.5 2 -SW5 • 1.5 Mean +2SD 1 0.5 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 5 Surface Water Fecal Coliform Counts Across Sample Locations - Geometric means 250 200 150 -- E3 Mean 100 ¦ Mean +2SD 50 0 Mar, 2003 Jun, 2003 Oct, 2003 Nov, 2003 Surface Water Site #1 Ortho-P mg/I 0.08 - 0.06-- 0.05-- 0.04-- - SW1 0.03 Mean +2SD 0.02 0.01 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 6 Surface Water Site #2 Ortho-P mg/I 0.08 - 0.06 0.05 SW2 0.04 - • • Mean +2SD 0.03 0.02 0.01 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 Surface Water Site #3 Ortho-P mg/I 0.08 0.07 0.06- 0.05- 0.04 - SW3 • Mean +2SD 0.03 -------------------------- 0.02 0.01 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 7 Surface Water Site #4 Ortho-P mg/I 0.08 0.07 0.06 0.05 0.04 - SW4 • Mean +2SD 0.03 -------------------------- 0.02 0.01 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 Surface Water Site #5 Ortho-P mg/l 0.08 - 0.06- 0.05- 0.04- -SW5 0.03 • Mean +2SD 0.02- 0.01 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 Surface Water Site #1 Turbidity NTU 450 400 ---- ---------------------- 350 300 250 - SW1 200 - • Mean +2SD 150 100 50 0 Oct, Mar, Mar, Jun, Oct, Nov, Mar, 2000 2001 2003 2003 2003 2003 2004 Surface Water Site #2 Turbidity NTU 450 400 350 300 250 -SW2 200 ... Mean +2SD 150 100 50 0 Oct, Mar, Mar, Jun, Oct, Nov, Mar, 2000 2001 2003 2003 2003 2003 2004 9 Surface Water Site #3 Turbidity NTU 450 400 350 300 250 200 150 100 50 0 Oct, 2000 Mar, 2003 Jun, 2003 Oct, 2003 Nov, 2003 Mar, 2004 SW3 -Mean +2SD Surface Water Site #4 Turbidity NTU 900 800 ---- ---------------------- 700 600 500 - SW4 400 ... Mean +2SD 300 200 100 0 Oct, Mar, Mar, Jun, Oct, Nov, Mar, 2000 2001 2003 2003 2003 2003 2004 10 Surface Water Site #5 Turbidity NTU 450 400 350 300 250 - SW5 200 ... Mean +2SD 150 100 50 0 Mar, Mar, Jun, Oct, Nov, Mar, 2001 2003 2003 2003 2003 2004 Surface Water Site #1 TDS mg/l 200 180 160 140 120 -S W1 100 80 - • Mean +2SD 60 40 20 0 Mar, Mar, Jun, Oct, Nov, Mar, 2001 2003 2003 2003 2003 2004 11 Surface Water Site #2 TDS mg/I 200 180 160 140 -----•-------------------- 120 - SW2 100 80 r--- Mean +2SD 60 40 20 0 Mar, Mar, Jun, Oct, 2003 Nov, 2001 2003 2003 2003 Surface Water Site #3 TDS mg/I 200 180 160 -------------------------- 140 120 -SW3 100 80 ... Mean +2SD 60 40 20 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 12 Surface Water Site #4 TDS mg/I 200 180 160 140 120 - SW4 100 80 ... Mean +2SD 60 40 20 0 Mar, Mar, Jun, Oct, Nov, Mar, 2001 2003 2003 2003 2003 2004 Surface Water Site #5 TDS mg/I 200 180 160 140 120 - SW5 100 80 ... Mean +2SD 60 40 20 0 Mar, Mar, Jun, Oct, Nov, Mar, 2001 2003 2003 2003 2003 2004 13 Surface Water Site #1 Temperature °C 35 30 25 20 - SW 1 15 ... Mean +2SD 10 5 0 Oct, Mar, Mar, Jun, Nov, Mar, 2000 2001 2003 2003 2003 2004 Surface Water Site #2 Temperature °C 35 30 ---------------------------- 25 20 - 15 --- Mean +2SD 10 5 0 Oct, Mar, Mar, Jun, Nov, Mar, 2000 2001 2003 2003 2003 2004 14 Surface Water Site #3 Temperature °C 35 30 25 20 - 15 ... Mean +2SD 10 5- 0 Oct, 2000 Mar, 2003 Jun, 2003 Nov, Mar, 2004 2003 Surface Water Site #4 Temperature °C 35 30 ---------------------------- 25 20 - SW4 15 ... Mean +2SD 10 5- 0 Oct, Mar, Mar, Jun, Nov, Mar, 2000 2001 2003 2003 2003 2004 15 Surface Water Site #5 Temperature °C 35 30 --------------------------- 25 20 -SW5 15 - • Mean +2SD 10 5 0 Mar, 2001 Mar, 2003 Jun, 2003 Nov, Mar, 2004 2003 Surface Water Site #1 Conductivity Nmhos/cm 300 250 --------------------------- 200 150 -SW1 - • Mean +2SD 100 50 0 Oct, Mar, Mar, Jun, Nov, Mar, 2000 2001 2003 2003 2003 2004 16 Surface Water Site #2 Conductivity pmhos/cm 300 250 200 --------------------------- 150 - SW2 . Mean +2SD 100 50 0 - >sz Oct, Mar, Mar, Jun, Nov, Mar, 2000 2001 2003 2003 2003 2004 Surface Water Site #3 Conductivity pmhos/cm 300 ------------------- ------ 250 200 150 - SW3 -Mean +2SD 100 50 0 Oct, 2000 Mar, Jun, Nov, Mar, 2003 2003 2003 2004 17 Surface Water Site #4 Conductivity pmhos/cm 300 250 200 150 - SW4 ... Mean +2SD 100 50 0 Oct, Mar, Mar, Jun, Nov, Mar, 2000 2001 2003 2003 2003 2004 Surface Water Site #5 Conductivity pmhos/cm 300 250 -------------------------- 200 150 -SW5 • Mean +2SD 100 50 0 Mar, Mar, Jun, Nov, Mar, 2001 2003 2003 2003 2004 18 Surface Water Site #1 Dissolved Oxygen mg/I 12 10 ...................... 8 6 - SW1 - Mean +2SD 4 2 0 Oct, 2000 Mar, 2001 Mar, 2004 Surface Water Site #2 Dissolved Oxygen mg/I 12 ...................... 10 8 6 - SW2 . Mean +2SD 4- 2 0 Oct, 2000 Mar, 2001 Mar, 2004 19 Surface Water Site #3 Dissolved Oxygen mg/l 12 10 8 6- 4- 0 3 2- Oct, 2000 Surface Water Site #4 Dissolved Oxygen mg/I 12 10 8 6 - SW4 • Mean +2SD 4 2- 0- Oct, 2000 Mar, 2001 Mar, 2004 20 Surface Water Site #5 Dissolved Oxygen mg/l 12 10 8 6 -SW5 4- 2 0 Mar, 2001 Mar, 2004 Surface Water Site #1 Chlorophyll pgh 40 35 30 25 20 -SW1 15 • Mean +2SD 10 5 0 Mar, 2003 Jun, 2003 Oct, 2003 Nov, Mar, 2004 2003 21 Surface Water Site #2 Chlorophyll Ng/I 40 35 30 25 20 - SW2 • Mean +2SD 15 10 5 0 Mar, 2003 Jun, 2003 Oct, 2003 Nov, Mar, 2004 2003 Surface Water Site #3 Chlorophyll Ng/I 40 35 30 25 20 15 10 5 0 -------------------------- Mar, 2003 Jun, 2003 Oct, 2003 Nov, Mar, 2004 2003 F SW3 7.--Mean +2SD 22 Surface Water Site #4 Chlorophyll pg/I 40 35 30 25 20 - SW4 • Mean +2SD 15 10 5 0 Mar, 2003 Jun, 2003 Oct, 2003 Nov, Mar, 2004 2003 Surface Water Site #5 Chlorophyll pg/I 40 35 30 25 -SW5 20 -Mean +2SD 15 10 5 0 Mar, 2003 Jun, 2003 Oct, 2003 Nov, Mar, 2004 2003 23 Surface Water Site #1 N03+NO2 mg/I 0.16 0.14- 0.12 0.1 0.08 - SW1 • 0.06 Mean +2SD 0.04 0.02 0 Mar, Mar, Jun, Oct, Nov, Mar, 2001 2003 2003 2003 2003 2004 Surface Water Site #2 N03+NO2 mg/I 0.16- 0.14- 0.12 0.1 0.08 - SW2 0.06 • Mean +2SD 0.04- 0.02 0 Mar, Mar, Jun, Oct, Nov, Mar, 2001 2003 2003 2003 2003 2004 24 Surface Water Site #3 N03+NO2 mg/I 0.16- 0.14- 0.12 0.1 0.08 - SW3 0.06 -Mean +2SD 0.04- 0.02 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 Surface Water Site #4 N03+NO2 mg/I 0.16 0.14- 0.12 0.1 0.08 - SW4 ------------------------ -.Mean +2SD 0.06- 0.04- 0.02 0 Mar, Mar, Jun, Oct, Nov, Mar, 2001 2003 2003 2003 2003 2004 25 Surface Water Site #5 N03+NO2 mg/I 0.16 0.14 0.12 0.1 0.08 ------------------------- I-SW5 0.06 ... Mean +2SD 0.04- 0.02 0 Mar, Mar, Jun, Oct, Nov, Mar, 2001 2003 2003 2003 2003 2004 Surface Water Site #1 Total P mg/I 0.35 - 0.25- 0.2 - SW1 0.15 ... Mean +2SD 0.1 0.05-- 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 26 Surface Water Site #2 Total P mg/l 0.35- 0.3 0.25 0.2 - SW2 0.15 --------------- ---------- 0.15- Mean +2SD 0.1 0.05-- 0 Mar, Mar, Jun, Oct, Nov, Mar, 2001 2003 2003 2003 2003 2004 Surface Water Site #3 Total P mg/l 0.35- 0.3 0.25- 0.2 - SW3 0.15 ... Mean +2SD 0.1 0.05 0 Mar, Jun, Oct, 2003 Nov, Mar, 2003 2003 2003 2004 27 Surface Water Site #4 Total P mg/l 1 0.9 - 0.8 0.7 0.6 - SW4 0.5- 0.4 .. Mean +2SD 0.3 0.2 0.1 0 Mar, Mar, Jun, Oct, Nov, Mar, 2001 2003 2003 2003 2003 2004 Surface Water Site #5 Total P mg/I 0.35- 0.3 0.25- 0.2 - SW 5 0.15 --------------------------- ..Mean +2SD 0.1 0.05-- 0 Mar, Mar, Jun, Oct, Nov, Mar, 2001 2003 2003 2003 2003 2004 28 Monitoring Well #2 TDS mg/I 700 600 500 400 - M W2 300 -------------------------- ..Mean+2SD - .0e 200 100 0 Oct, Mar, Jun, Oct, Nov, Mar, 2001 2003 2003 2003 2003 2004 Monitoring Well #3 TDS mg/I 700 600 ' 500 400 - M W3 300 - • Mean +2SD 200 100 0 Oct, 2001 Jun, Oct, 2003 Nov, Mar, 2003 2003 2004 29 Monitoring Well #4 TDS mg/I 700 600 500 400 - M W4 300 --- Mean +2SD 200 100 0 Mar, 2003 Jun, 2003 Oct, 2003 Monitoring Well #5 TDS mg/I 700 600 500 400 - 300 - • Mean +2SD 200 100 0 Mar, 2003 Jun, 2003 Oct, 2003 Nov, 2003 30 Monitoring Well #6 TDS mg/I 700 600 500 400 - M W6 300 .. Mean +2SD 200 100 0 Oct, Mar, Jun, Oct, Nov, Mar, 2001 2003 2003 2003 2003 2004 Monitoring Well #7 TDS mg/I 700 600 500 400 -MW7 300 ---- --- Mean +2SD ---------------------- 200 100 0 Oct, 2001 Mar, Jun, Nov, Mar, 2003 2003 2003 2004 31 Monitoring Well #8 TDS mg/I 700 600 --------------------------- 500 400 I-MW8 300 • • Mean +2SD 200 100 0 Oct, Mar, Jun, Oct, Nov, Mar, 2001 2003 2003 2003 2003 2004 Monitoring Well #9 TDS mg/I 700 600 500 400 - M W9 300 ... Mean +2SD 200 100 0 Oct, 2001 Jun, 2003 Oct, 2003 Mar, 2004 32 Monitoring Well #2 Temperature °C 30 25 ----------------------------• 20 15 - MW2 . Mean +2SD 10 5- 0- Oct, Sep, Mar, Jun, Oct, Nov, Mar, 2001 2002 2003 2003 2003 2003 2004 Monitoring Well #3 Temperature °C 30 25 --------------------------- 20 15 -MW3 -Mean +2SD 10 5 0 Oct, 2001 Jun, 2003 Oct, 2003 Nov, Mar, 2004 2003 33 Monitoring Well #4 Temperature °C 30 25 ------------------------- 20 15 -MW4 • Mean +2SD 10 5 0 Sep, 2002 Mar, 2003 Jun, 2003 Oct, 2003 Monitoring Well #5 Temperature °C 30 25 ------------------------- 20 -MW5 15 . Mean +2SD 10 5- 0 Mar, 2003 Jun, 2003 Oct, 2003 Nov, 2003 34 Monitoring Well #6 Temperature °C 30 25 20 15 - MW6 - • Mean +2SD 10 5- 0 Oct, Sep, Mar, Jun, Oct, Nov, Mar, 2001 2002 2003 2003 2003 2003 2004 Monitoring Well #7 Temperature °C 30 ---------------------------- 25 20 15 - MW7 • Mean +2SD 10 5 0 Oct, Sep, Mar, Jun, Nov, Mar, 2001 2002 2003 2003 2003 2004 35 Monitoring Well #8 Temperature °C 30 ............................. 25 20 15 -• Mean +2SD 10 5 0 Oct, Sep, Mar, Jun, Oct, Nov, Mar, 2001 2002 2003 2003 2003 2003 2004 Monitoring Well #9 Temperature °C 30 25 .....................•..... 20 15 -MW9 • Mean +2SD 10 5 0 Oct, 2001 Sep, 2002 Jun, 2003 Oct, 2003 Mar, 2004 36 Monitoring Well #2 pH 9 8 ----------------------------- 7 6 5 -MW2 4 - -Mean +2SD 3- 2- 1- 0- Oct, Sep, Mar, Jun, Oct, Nov, Mar, 2001 2002 2003 2003 2003 2003 2004 Monitoring Well #3 pH 9 8 --------------------------- 7 6 5 -MW3 4 --- Mean +2SD 3 2 1 0 Oct, 2001 Jun, 2003 Oct, 2003 Nov, 2003 Mar, 2004 37 Monitoring Well #4 pH 9 8 ----------------------- 7 6 5 -MW4 4 - • Mean +2SD 3 2 1 0 Sep, 2002 Mar, 2003 Oct, 2003 Monitoring Well #5 pH 9 8 7 6 5 -MW5 4 .. Mean +2SD 3- 2- I- 0- Mar, 2003 Jun, 2003 Oct, 2003 Nov, 2003 38 Monitoring Well #6 pH 9 ----------------------------- 87 6 5 -MW6 4 ... Mean +2SD 3 2 1 0 Oct, Sep, Mar, Jun, Oct, Nov, Mar, 2001 2002 2003 2003 2003 2003 2004 Monitoring Well #7 pH 12 10 t8 MW7 6 Mean +2SD 4 2 0 Oct, Sep, Mar, Jun, Nov, Mar, 2001 2002 2003 2003 2003 2004 39 Monitoring Well #8 pH 9 -•--------------------------- 8 7 6- 5 - MW8 4 - • Mean +2SD 3 2 1 0 Oct, Sep, Mar, Jun, Oct, Nov, Mar, 2001 2002 2003 2003 2003 2003 2004 Monitoring Well #9 pH 9 8 --------------------------- 7 6 5 -MW9 4 --- Mean +2SD 3- 2- 1- 0- Oct, 2001 Sep, 2002 Jun, 2003 Oct, 2003 Mar, 2004 40 Monitoring Well #2 Conductivity pmhos/cm 400 350 300 250 -------------------------- -MW2 200 . Mean +2SD 150 100 50 0 Oct, Sep, Mar, Jun, Oct, Nov, Mar, 2001 2002 2003 2003 2003 2003 2004 Monitoring Well #3 Conductivity pmhos/cm 400 350 300 250 200 - M W3 Mean +2SD 150 -------------------------- 100 50 0 Oct, 2001 Jun, Oct, 2003 Nov, Mar, 2003 2003 2004 41 Monitoring Well #4 Conductivity Nmhos/cm 400 350 300 250 -MW4 200 ------------------------ --Mean+2SD 150 100 50 0 Sep, 2002 Mar, 2003 Jun, 2003 Oct, 2003 Monitoring Well #5 Conductivity Nmhos/cm 400 350 300 250 200 -MW5 - Mean +2SD 150 100 50 0 Mar, 2003 Jun, 2003 Oct, 2003 Nov, 2003 42 Monitoring Well #6 Conductivity Nmhos/cm 400 350 300 250 -MW6 200 -------------------------- --Mean +2SD 150 100 50 0 Oct, Sep, Mar, Jun, Oct, Nov, Mar, 2001 2002 2003 2003 2003 2003 2004 Monitoring Well #7 Conductivity Nmhos/cm 400 350 300 250 200 - M W 7 • 150 Mean +2SD 100 50 0 Oct, Sep, Mar, Jun, Nov, Mar, 2001 2002 2003 2003 2003 2004 43 Monitoring Well #8 Conductivity pmhos/cm 400 350 --------------------------- 300 250 M W8 200 - • Mean +2SD 150 100 50 0 Oct, Sep, Mar, Jun, Oct, Nov, Mar, 2001 2002 2003 2003 2003 2003 2004 Monitoring Well #9 Conductivity Nmhos/cm 400 350 300 250 -------------------------- 200 - M W9 -Mean +2SD 150 100 50-- 0- Oct, 2001 Sep, Jun, Oct, 2003 Mar, 2002 2003 2004 44 Monitoring Well #2 N03+NO2 mg/I 3.5- 3 2.5 2 -MW2 1.5 --- Mean +2SD 1 0.5- 0 ------ Oct, Sep, Mar, Jun, Oct, Nov, Mar, 2001 2002 2003 2003 2003 2003 2004 Monitoring Well #3 N03+NO2 mg/l 3.5 3 2.5 2 -MW3 1.5 --- Mean +2SD 1 0.5 Oct, 2001 Jun, Oct, 2003 Nov, Mar, 2003 2003 2004 45 Monitoring Well #4 N03+NO2 mg/1 3.5- 3 2.5- 2 -MW4 1.5 --- Mean +2SD 1 0.5 --------------- ------ 0 Sep, 2002 Mar, 2003 Jun, 2003 Oct, 2003 Monitoring Well #5 N03+NO2 mg/I 3.5 3 2.5 2 -MW5 1.5 - -Mean +2SD 1 0.5 ------------------------- 0 Mar, 2003 Jun, 2003 Oct, 2003 Nov, 2003 46 Monitoring Well #6 N03+NO2 mg/1 3.5 3 2.5 2 -MW6 1.5 --- Mean +2SD 1 0.5- 0 Oct, Sep, Mar, Jun, Oct, Nov, Mar, 2001 2002 2003 2003 2003 2003 2004 Monitoring Well #7 N03+NO2 mg/I 3.5- 3 2.5- 2 - MW7 1.5 --- Mean +2SD 1 0.5 0 --------- - Oct, 2001 Sep, Jun, Nov, Mar, 2002 2003 2003 2004 47 Monitoring Well #8 N03+NO2 mg/I 3.5- 3 2.5 2 -MW8 1.5 - -Mean +2SD 1 ---- - 0 Oct, Sep, Mar, Jun, Oct, Nov, Mar, 2001 2002 2003 2003 2003 2003 2004 Monitoring Well #9 N03+NO2 mg/I 3.5 2.5- -------------------------- 3- 2 -MW9 1.5 - • Mean +2SD I- 0.5 0 Oct, 2001 Sep, Jun, Oct, 2003 Mar, 2002 2003 2004 48 Monitoring Well #2 Total P mg/l 6 5 4 3 -MW2 • Mean +2SD 2 1 0 Oct, Sep, Mar, Jun, Oct, Nov, Mar, 2001 2002 2003 2003 2003 2003 2004 Monitoring Well #3 Total P mg/I 6 5 4 -MW3 3 • Mean +2SD 2 1 Oct, 2001 Jun, 2003 Oct, 2003 Nov, 2003 Mar, 2004 49 Monitoring Well #4 Total P mg/I 6 5 4- 3 -MW4 • Mean +2SD 2- .......................... 1 0 Sep, 2002 Mar, 2003 Jun, 2003 Oct, 2003 Monitoring Well #5 Total P mg/I 6- 5 4 - MW5 3 • Mean +2SD 2 1 0 Mar, 2003 Jun, 2003 Oct, 2003 Nov, 2003 50 Monitoring Well #6 Total P mg/l 6 5 -------------------------- 4 3 - MM W6 - • Mean +2SD 2 1 0 Oct, Sep, Jun, Oct, Nov, Mar, 2001 2002 2003 2003 2003 2004 Monitoring Well #7 Total P mg/I 6 5 4- 3 - MW7 • Mean +2SD 2- 1 0 Oct, Sep, Mar, Jun, Nov, Mar, 2001 2002 2003 2003 2003 2004 51 Monitoring Well #8 Total P mg/I 6 5 4- 3 - MW8 • Mean +2SD 2 1 0 Oct, Sep, Jun, Oct, Nov, Mar, 2001 2002 2003 2003 2003 2004 Monitoring Well #9 Total P mg/I 6 5 4 -MW9 3 • Mean +2SD 2 1 0 Oct, 2001 Sep, 2002 Jun, 2003 Oct, 2003 Mar, 2004 52