DEQ-CFW_00088486

DEQ-CFW 00088486

Form D: Process Information (Page 1 of 2) Facility ID# 0900009
North Carolina Department of Environment and Natural Resources
Division of Air Quality
1998 Annual Air Pollutant Emissions Inventory
1. Source ID No(s): Waste DMSO Storage Tank
3. Process Description: "Nafion" Waste DMSO Storage Tank
4. Operational Schedule:
Hour per Day per
Day Week
5. Start Hour of Process: Continuous
6. Percentage Annual Throughput:
Dec -Feb 25
0
7. Maximum Process
Rate per Hour: (ex:
gal/hr, mmcf/hr)
Mar -May 25
7,500 Ib/hr
include units
2. Permit Item No(s): Insignificant Activity
Weeks per
Year
June -Aug 25
8. Annual Process
Throughput:
(ex: lb/yr, gal/yr)
9. Capture Efficiency (% of Process Emissions Vented Through Control Device): n/a
10. Control Device Descriptions Primary None
Secondary
11. Combined Control Device Efficiency (%): n/a
12. ANNUAL FUEL USAGE (e.g. Coal, oil, wood, natural gas, etc.) - Use additional sheets if necessary
•
Hours per 8760
Year
Sept -Nov 25
232,368 Ibs
include units
DEQ-CFW 00088487

,, Form-D: Process Information (Page 2 of 2)
Facility ID# 0900009 Source ID # Wast DMSO Tk
•
Actual Emissions per Pollutant Listed for Source Described Above:
Attach calculations and documentation of emission factors or other estimation methods used.
"Per Ton" Pollutant:
TSP
PM-10
SO2
NOx
VOC
CO
0%
Actual Emissions: Tons/year
0.08
***All Other HAPs/TAPs as listed in Appendix C or Appendix D (use additional sheets if necessary)***
P{�itLlA114 a - L k 4+
t'A5 Nnbeie its
c F ! a2
Chlorine 7782-50-5
Fluorine 7782-41-4
Hydrazine 302-01-2
Hydrogen Chloride 7647-01-0
Hydrogen Fluoride 7664-39-3
Hydrogen Sulfide 7783-06-4
Lead Compounds LEADCPDS
Methyl Chloroform 71-55-6
Methylene Chloride 75-09-2
Ozone 10028-15-6
Perchloroethylene 127-18-4
Phosphine 7803-51-2
Information on Page 2 of Form D cannot be held confidential.
DEQ-CFW 00088488

I
0 1998 WASTE DMSO STORAGE TANK EMISSIONS
BASIS: Direct vent to atmosphere
Tank volume = 6,000 gallons = 802 ft3
DMSO vapor pressure = 0.5 mmHg at 20°C
Assume one complete tank volume turnover per day
Mole fraction DMSO in vapor: 0.5 mmHg = 0.00066 mole DMSO
760 mmHg mole gas in tank
Pounds of DMSO per tank volume:
802 ft' I lb mole 1 0.00066 mole DMSO 1 78 lb DMSO = 0.11 lb DMSO
tank volume 1 359 ft3 ( mole gas in tank ( mole DMSO tank volume
Total DMSO emissions per year from tank volume turnovers:
0.11 lb DMSO i tank volume 1 365 days = 42 lb DMSO per year
tank volume I day I year
Total Emissions = Turnover Emissions + Fugitive Emissions
42 lb/yr + 114 lb/yr = 156 lb/yr = 0.08 ton/yr VOC Emissions
•
DEQ-CFW 00088489

Ftcri7W Eml,,(.
F" WSIE 7*a
PERIMEML
�1�Idr (�/yR)
1+�'P F/C S1G 41C
EMSSICNS
1g 1' F/C Z!C
VLV
"M
DOSSICNS
IUID VLV
Cm VLV2
48 163.987
6.833
24
81.994
BUD FIG
4 13.666
1
3.416
TAO07M
25 1.577
3
14
0.000
n-cw Ck1F'II.F.
3.154
2
3.154
Aft FrIT1N;
1 1.577
2
1.577
RIV
1W 1.577
1
24
0.000
FILIM
71FINXCLRE
10.074
2 0.000
1
0.000
10.074
Rl Ute DISC Ian
00
2
2
0.000
3 l�py VLV.
0
1
0.000
PRESS
1 3.416
0.000
PIPE a
1 0.000
0.000
MIT !EQUIP
0•000
'060 ATICN VWp
0.000
0.000
0.000
LI
WST F/C gffp m
04BM
EmssIft
27
92.243
1
3.416
0.000
10
0.000
1
3.154
2
1.577
10
0.000
1
10.074
0.000
0.000
2
0.000
1
3.416
0.000
1
0•000
0
'MX (1E/YR) .VW
'IWX MCN/Y�) 0.102o
1029 100.214
MAE: or 0.0501 113.880
Q{zrit ��lla>IC factors were 0.0569
Flange e1dssi � allall
t factors were used for 'eg p %lvIM a,4 .
0
m
p
C�
m
I
0
0
0
00
00
cm
0
MM rIEC & RMe
NWM 11' ICt4S
37
126.407
3
10.249
2
6.833
1
3.154
7
0.000
44
0.000
0.000
1
10.074
1
4.730
2
0.000
0.000
0.000
0.000
1
0.0m
3
0.0m
161.447
0.0807
•
H/C = 9K
1 HOSSICNS
IFS SUP IK
H!hm J:mI%I(t1
12 40.997
2 6.833
18 61.4y',
0.000
0.OLK)
7 1.577
2 6.811
1 0.000
4 0.000
0.000
1 O.UOU
1.577
0.000
0.000
O.OIw
0.000
1 10.U14
1 1.577
1•S71
0.000
1 •
0.000
O.O w
1 0.000
O.Ow
0.000
0.000
0.000
O.000
1 32.587
1 0.000
1 32.58/
85.147
0.0426
114.141
IiAhn

A H
C
OtiPONT EX:SSION FACTORS
COMPONENT
SERVICE
PUMP SEALS
LIGHT LIQ.
HEAVY LIQ.
VALVES
GAS
LIGHT LIQ
HEAVY LIQ
PRESSURE
GAS/VAPOR
RELIEF SEALS
OPEN END LINES
ALL
FLANGES
ALL
SAMPLING
ALL
CONNECTIONS
COMPRESSOR
GAS/VAPOR
SEALS
0ERALL EMISSION
FACTOR
D E
F
G
H
r
53
EMISSION.FACTORS
(L8/HR)
SUPERIOR
EXCELLE
GOOD
EPA
.xxxxx
0.00115
0.0075
0.109
55
.XXX=
0.00115
0.0075
0.047
.xxxxx
0.00039
0.00542
0.012
.xxxxx
0.00036
0.00352
0.016
.xxxxx
0.00036
0.00352
0.00051
60
.xxxxx
0.00012
0.00013
0.23
.XXX=
0.001
0.0215
0.0037
65
.xxxxx
0.00018
0.00031
0.0018
.xxxxx
0.00018
0.00031
0.033
70
N/A
N/A
N/A
0.50
1/10000
1/20
1/3
1/1
75
DEQ-CFW 00088491