DEQ-CFW_00088261

DEQ-CFW 00088261

Form D: Process Information (Page 1 of 2) Facility ID# 0900009
North Carolina Department of Environment and Natural Resources
Division of Air Quality
Calendar 2000 Air Pollutant Point Source Emissions Inventory
1. Source ID No. (same as in permit) Naton® Fugitive Emissions
Fugitive emissions of methylene chloride from Nation® refrigeration
2. Process Description: system
4. Maximum Process Rate: 4. CY 2000 Process Throughput:
(Ex: gal/hr, mmcf/hr) Confidential (Ex: lb., gal) Confidential
include units include units
5. Normal Operating Schedule:
Hours per Days per Weeks Hours per
Day Week per Year Year Confidential
6. Typical Start & End Times For Process: Start: Continuous End:
7. Percentage Annual Throughput:
Dec -Feb 25 Mar -May 25 June -Aug 25 Sept -Nov 25
8. Capture Efficiency (% of Emissions from this Process Vented Through Control Device): N/A
9, Control Device Descriptions Primary
0 Secondary:
None
10. Combined (Net) Control Device Efficiency (%): PM
(Control efficiency is pollutant specific)
PM-10
PM-2.5
SO2
NOx
VOC
N/A
11. ANNUAL FUEL USAGE For This Process (Coal, oil, wood, natural as, etc.) -Use additional sheets as needed.
Type of Fuel Used in This Process/Source
Amount (gal, tons, mmcf/year)
% Sulfur
% Ash
.f you do not provide annual throu h ut your invento will be deemed incomplete and returned to you
0
g P rY
To review instructions or get a new copy, go to web page: httn://da4.state.nc.us/Offices/Plannina/Attainment/est.html or
htta://daa.state.nc.us/Offices/Plannine/Attainment/1999/99forms.htmi
Information on Form D cannot be held confidential.
DEQ-CFW 00088262

Form U: Process Information (Page 2 of 2)
CY 2000 Facility ID# 0900009 Source Narion® Fugitive
ID# Emissions
Actual Emissions per Pollutant Listed for Source/Process Identified Above:
AhAttach calculations and documentation of emission factors or other estimation methods used.
"Per Ton" Pollutant:
PM
PM-10
PM-2.5
S02
Nox
VOC
CO
Actual Emissions: Tons/year
***All Other HAPs/TAPS Per Instructions (use additional sheets if necessary)***
Pollutant
CAS #
Emitted
lbs./ r.
Comments
Chlorine
7782-50-5
Fluorine
7782-41-4
Hydrazine
302-01-2
Hydrogen Chloride (As weight of HCI in solutions)
7647-01-0
Hydrogen Fluoride (As weight of HF in solutions)
7664-39-3
Hydrogen Sulfide
7783-06-4
Lead (As metal or compounds -mass of total)
LEADCPDS
Methyl Chloroform (Not a VOC, by rule)
71-55-6
Methylene Chloride (Not a VOC, by rule)
75-09-2
5917
Ozone (Not expected as a facility emission)
10028-15-6
Perchloroethylene (Not a VOC, by rule)
127-18-4
Phosphine
7803-51-2
List all other HAP/TAPs below IN ALPHABETICAL
ORDER, Per Instructions.
Use more sheets, as needed
9W Information on Form D cannot be held confidential.
DEQ-CFW 00088263

ADDITIVES
EMISSIONS
(venting and fugitive)
ACCUMULATION
Brine Storage Tank
FRESH METHYLENE CHLORIDE
WASTE
SPILLS
data from log notes and Setcim kept by Waste Mechanical Facilitator
INPUT + GENERATION - OUTPUT - CONSUMPTION = ACCUMULATION
INPUT = ADDITIVES + FRESH METHYLENE CHLORIDE
INPUT -OUTPUT -ACCUMULATION = FUGITIVE OUTPUT = WASTE + EMISSIONS = WASTE + VENT + FUGITIVE+ SPILLS
5711 Ilb ACCUMULATION = CHANGE IN LBS IN TANK OVER THE YEAR
EMISSIONS = FUGTIVE + VENT GENERATION = 0
5917 Ib CONSUMPTION = 0
INPUT
lb
ADDITIVES
4730 lb
Convert Ibs of additives into equivilent Ibs of methylene chloride based on volume
Ibs gal
Ibs
Diallylamine
Methylene Chloride
03/11 /2000
348
53
584
04/17/2000
100
15
168
04/18/2000
250
38
419
04/27/2000
175
27
294
04/28/2000
175
27
294
11 /03/2000
350
53
587
Propylene Oxide
04/17/2000
750
108
1193
04/25/2000
750
108
1193
Page 1 of 3
physical properties
spg
Diallylamine 0.787
Methylene Chloride 0.830
Propylene Oxide 1.320

0
0
n
m
i
0
0
0
00
00
N
FRESH METHYLENE CHLORIDE
# of Drums
lb
02/08/2000 8
04/05/2000 4
04/12/2000 4
OUTPUT
WASTE
02/22/2000
04/09/2000
05/18/2000
12/19/2000
326
3983
1354
2755
TOTAL WASTE
8418
•
9694 lb
55 gallon
4847
2423
2423
-FUGITIVE lb
taken from Waste Manifest and spreadsheet kept by Catherine Bass
VENTING (see page 3 for calculation)
206 lb
SPILLS
06-Sep 10lb
ACCUMULATION
% LEVEL in Brine Storage Tank
01 /01 /2000 17.84 0
12/30/2000 17.84
% LEVEL in Tempered Brine Tank in Polymers
01 /01 /2000 54.2 150 gallon tank
12/30/2000 49.4 79lb
Page 2 of 3

Venting Calculation
R=
1 KPa =
1 m3=
lb = 453.59 g
8.314 m3 Pa/mol K
1000 Pa
264.17 gal
0.265
Pressure
Pressure
volume
temperature
n
05/05/2000
venting
K a g
Kaa
gal
C
K
initial
83.87
184.87
2426
-36
237.15
3249
final
62.7
163.7
2426
-36
237.15
2877
372
mol
MW
85
/mol
31553
70
lb
Pressure
Pressure
volume
temperature
n
11/08/2000
1 venting
K a a
Kaa
gal
C
K
initial
103
204
1908
-31
242.15
2762
final
63
164
1747
-31
242.15
2033
729
mol
61808
136
Ib
Page 3of3