DEQ-CFW_00088138

Form A: Certification Form
Facility 1D #: 0900009
Permit #(s): 03735
North Carolina Department of Environment and Natural Resources
r i Division of Air Quality
2000 Annual Air Pollutant Point Source Emissions Inventory
Notice: - Any company that receives this form is required to complete and return even if not operational or
emissions are zero.
- If pre-printed information is incorrect, you must strike -over and provide corrections
Facility Name: DuPont Company - Fayetteville Works
Facility (Physical) Address: 22828 NC Hiqhway 87 W
(Please use 911 address if not
already shown) Fayetteville. NC 28306-7332 _
County: Bladen
Facility Classification: Title V Major
Authorized Contact: Barry L. Hudson
(Legally Responsible Official)
Title: Plant Manager
Phone Number: 910-678-1512 Fax Number: [phone]
e-mail Address:
Address: 22828 NC Hiqhway 87 W, Fayetteville, NC 28306-7332
Any Confidential
Material Enclosed? _X_Yes No (Please read instructions carefully reqardinq confidentiality)
CERTIFICATION STATEMENT: (Important: Legally Responsible Official. Read and sign after completing all forms)
I hereby certify that I have personally reviewed the information contained in this air emissions report and that, to the
best of my knowledge and belief, the submitted information is true, accurate, and complete (subject to legal penalties as
outlined in G.S. 5 143-512.3(a)(2)).
Authorized Signature (use blue ink) Date Signed
Due to th ppropriate Reqional Office by March 31, 2001 if possible, but no later than June 30, 2001.
Two copies of this inventory should be submitted.
Information on Form A cannot be held confidential.
DEQ-CFW 00088138

� r
Form B: General Information
Facility ID #: 0900009
North Carolina Department of Environment and Natural Resources
► s Division of Air Quality
2000 Annual Air Pollution Point Source Emissions Inventory
If pre-printed information is incorrect, you must strike -over and provide corrections.
Technical/Permit Contact: Michael E. Johnson
(Contact for Regulatory or Technical Questions)
Title: Environmental Manager Telephone #: [phone]
Fax #: [phone] e-mail Address: [e-mail]
Facility Mailing Address: 22828 NC Highway 87 W
(Primary mailing contact) Fayetteville, NC 28306-7332
Facility Contact: Michael E. Johnson
(Person to Contact when Inspecting Facility)
Billinq/Invoice Contact: Michael E. Johnson
Title: Environmental Manaaer
Fax #: [phone]
Billinq/Invoice Company:
Billinq/Invoice Address:
Telephone #: [phone]
Telephone #: [phone]
e-mail Address: [e-mail]
DuPont Company - Fayetteville Works
22828 NC Highway 87 W
Fayetteville NC 28306-7332
Standard Industrial Classification (SIC) Code(s):
North American Industry Classification System
(NAICS - six digit) Code(s) - If known:
(see instructions)
Report Prepared by:
Michael E. Johnson
3081 3083 2821
Telephone #: [phone]
Due to Appropriate DAQ Regional Office by March 31, 2001 if possible, but no later than June 30, 2001
Two copies of this inventory should be submitted.
Information on Form B cannot be held confidential.
DEQ-CFW 00088139

Form C: Facility Total CY 2000 Emissions Summary/Stack Data (1 of 5) Facility ID # 0900009
(For Use In Situations Where It Is Not Possible to Use Pre -filled Form C-a)
North Carolina Department of Environment and Natural Resources
0 Division of Air Quality
Calendar 2000 Air Pollutant Point Source Emissions Inventory
"Per Ton" Pollutants
ED #Is of Sources
Actual Emissions
Contributing
Tons/Year *
Carbon Monoxide (CO)
PS-1, PS-2,
11.01
(Reporting required, but no fees based on CO
Oxides of Nitrogen (NOx)
PS-1, PS-2
147.53
Report as tons of NO2 equivalent
PM-10
PS-1, PS-2, BS-8
33.61
Particulate Matter with mean aerodynamic particle size less than 10 micrometers.
Include all condensables, including Sulfur Trioxide and Sulfuric Acid as PM-10
PM-2.5
PS-1, PS-2, BS-8
33.61
Particulate Matter with mean aerodynamic particle size less than 2.5 micrometers.
This is -a new reporting pollutant and includes all condensables using best information
available. Plan to improve quantification by CY 2002
PM/TSP - Particulate Matter (total -Not used for Fees)
PS-1, PS-2, BS-8
47.36
Sulfur Dioxide (S02)
PS-1, PS-2, NS-6
687.97
Do not include Sulfur Trioxide and Sulfuric Acid
VOC
All Sources
165.06
Volatile Organic Compounds -See 1999 Instructions for Federal definition excluding
some non -photo chemically reactive organics.
Other "Billable" Pollutants
CAS
ID #Is of Sources
Actual Emissions
(Regulated HAPS but not VOC or PM)
Number
Contributing
Pounds/Year
Chlorine
7782-50-5
Riverwater, Labs
192
Fluorine
7782-41-4
Hydrazine
302-01-2
Hydrogen Chloride (Reported as weight of HCl in
7647-01-0
PS-1, PS-2
50,331
solutions)
Hydrogen Fluoride (Reported as weight of HF in
7664-39-3
NS-1,2,4-7,9,15;
1,766.5
solutions)
SW-1,2; FS-A; TFE
Hydrogen Sulfide
7783-06-4
Lead (as metal or lead compounds -mass of total)
LEADCPDS
PS-1, PS-2
71.68
Methyl Chloroform (Not a VOC due to Federal definition)
71-55-6
Methylene Chloride (Not a VOC due to Federal definition)
75-09-2
McCI Fugitives
5,917
Ozone (Not expected as a facility emission)
10028-15-6
Perchloroethylene (Not a VOC due to Federal definition)
127-18-4
Phosphine
7803-51-2
Next Page- Enter, in Alphabetical Order, All Other HAPs/TAPs Required by Instructions
Sum Process Emissions From D Forms
*Attach supporting documentation and calculations. For CY 2000 Inventory use a 1000 lb (facility total)
Ohreshold, except for compounds not previously reported to DAQ in 1999 inventory.
Information on Form C cannot be held confidential.
DEQ-CFW 00088140

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L-
Form C: Facility Total Emissions Summary/Stack Data (2 of 5)
Continued from page 1 of Form C. Sum facility totals from process emissions on D Forms.
All Other HAPs/TAPs as listed in Instructions and Pollutant Tables
Sum from D Forms. Please, list in alphabetical order.
Use additional copies of this sheet if necessary.
Pollutant
(From 1999 Instructions
CAS Number
See 1999 Instructions
ID Numbers of
Contributing Sources
Actual Emissions
Pounds per ear
Acetic Acid
64197
NS-11, Sitewide Labs
108
Acetonitrile
75058
NS-2, NS-15
9,625
Ammonia
7664417
Sitewide Labs
2
Antimony
ANTIMONYCPDS
PS-1, PS-2
22.66
Arsenic
ARSENICCPDS
PS-1, PS-2
43.37
Benzene
71432
Sitewide Labs
1
Beryllium
BERYLLIUMCPDS
PS-1, PS-2
2.72
Cadmium
CADMIUMCPDS
PS-1, PS-2
73.8
Chromium
CHROMIUMCPDS
PS-1, PS-2
48.55
Chromium VI
7440473
PS-1, PS-2
0.17
Cobalt
COBALTCPDS
PS-1, PS-2
64.09
Diethylene glycol ether
GLYCOLETHERS
NS-4
6,435
Dimethyl formamide
68122
BS-6
1,311
Ethyl acetate
141786
Sitewide Labs
12
Ethylene dichloride
107062
Sitewide Labs
239
Copy and add more sheets if necessary.
Attach supporting documentation and calculations.
Stack (Emission Point) Data* and Process Cross -Reference:
Complete the following for each stack/vent (use additional sheets if necessarv)
STACK PARAMETER
ID# BEP-A
ID# BEP-BI
ID# BEP-B2
ID# BEP-C
ID# BEP-D
Height (feet)
29
50
50
60
35
Diameter (feet)
0.16
0.98
0.98
4.5
1.94
Temperature (OF)
Ambient
100
100
125
95
Velocity (Feet per Second)
0.13
0.98
0.98
42
52
Volume Flow Rate (ACFM)
0.16
45
45
40,000
9,200
Sources/Processes Exhausted
(Source ID #
BS-1
BS-2
BS-2
BS-8
BS-6
Stacks and processes may sometimes be grouped, if similar -See instructions from CY 1999 or DAQ web pages
Information on Form C cannot be held confidential.
DEQ-CFW 00088141

4
Form C: Facility Total Emissions Summary/Stack Data (3 of 5)
Continued from page 1 of Form C. Sum facility totals from process emissions on D Forms.
All Other HAPs/TAPS as listed in Instructions and Pollutant Tables
Sum from D Forms. Please, list in alphabetical order.
Use additional copies of this sheet if necessary.
Pollutant
From 1999 Instructions
CAS Number
See 1999 Instructions
ID Numbers of
Contributing Sources
Actual Emissions
Pounds per ear
Formaldehyde
50000
PS-1, PS-2
183.2
Manganese
MANGANESECPDS
PS-1, PS-2
31.7
Mercury
MERCURYCPDS
PS-1, PS-2
11.01
Methanol
67561
BS-2; PVA Unload & Tanks;
NS-8,9,10
17,688
Nickel
NICKELCPDS
PS-1, PS-2
1,025.5
Nitric Acid
7697372
Sitewide Labs
142
POM
POM
PS-1, PS-2
5.11
Selenium
SELENIUMCPDS
PS-1, PS-2
24.6
Sulfuric Acid
7664939
Sitewide Labs
75
Tetraethylene glycol ether
GLYCOLETHERS
NS-5
3,157
Toluene
108883
NS-1
2,237
Trichloro-trifluoroethane
76131
NS-7, NS-10
7,555
Copy and add more sheets if necessary.
Attach supporting documentation and calculations.
Stack (Emission Point) Data* and Process Cross -Reference:
Complete the following for each stack/vent (use additional sheets if necessarv)
*Stacks and processes may sometimes be grouped, if similar -See instructions from CY 1999 or DAQ web pages
STACK PARAMETER
ID# NEP-Hdrl
ID# NEP-Hdr2
ID# NEP-G
ID# NEP-HI
ID# NEP-H2
Height (feet)
85
81.3
70
50
50
Diameter (feet)
3.0
2.3
2.2
2.0
2.0
Temperature (OF)
75
75
75
Ambient
Ambient
Velocity (Feet per Second)
58
46
54
48
48
Volume Flow Rate (ACFM)
24,500
11,700
12,300
9,000
9,000
Sources/Processes Exhausted
(Source ID #
NS-1 thru 8;
TFE Purific'n
NS-15
NS-9 NS-10
'
NS-11
NS-11
Information on Form C cannot be held confidential.
DEQ-CFW 00088142

Form C: Facility Total Emissions Summary/Stack Data (4 of 5)
Continued from page 1 of Form C. Sum facility totals from process emissions on D Forms.
4
L_
All Other HAPs/TAPs as listed in Instructions and Pollutant Tables
Sum from D Forms. Please, list in alphabetical order.
Use additional copies of this sheet if necessary.
Pollutant
From 1999 Instructions
CAS Number
See 1999 Instructions)
ID Numbers of
Contributing Sources
Actual Emissions
(Pounds per ear
Copy and add more sheets if necessary.
Attach supporting documentation and calculations.
Stack (Emission Point) Data* and Process Cross -Reference:
Complete the following for each stack/vent (use additional sheets if necessary)
STACK PARAMETER
ID# NEP-I
ID# NEP-J1
ID# NEP-J2
ID# NEP-J3
ID# NEP-K
Height (feet)
50
28
26
26
Various
Diameter (feet)
2.0
2.3
1.9
1.9
Various
Temperature (OF)
Ambient
Ambient
Ambient
Ambient
Ambient
Velocity (Feet per Second)
0.4
24
23
23
Various
Volume Flow Rate (ACFM)
74
6,000
3,900
3,900
Various
Sources/Processes Exhausted
(Source ID #
NS-12
SW-1
SW-2
NS-J3
NS-K
0Stacks and processes may sometimes be grouped, if similar -See instructions from CY 1999 or DAQ web pages
Information on Form C cannot be held confidential.
DEQ-CFW 00088143

6
Form C: Facility Total Emissions Summary/Stack Data (5 of 5)
Continued from page 1 of Form C. Sum facility totals from process emissions on D Forms.
All Other HAPs/TAPS as listed in Instructions and Pollutant Tables
Sum from D Forms. Please, list in alphabetical order.
Use additional copies of this sheet if necessary.
Pollutant
(From 1999 Instructions)
CAS Number
(See 1999 Instructions
ID Numbers of
Contributing Sources
Actual Emissions
Pounds per ear
Copy and add more sheets if necessary.
Attach supporting documentation and calculations.
Stack (Emission Point) Data* and Process Cross -Reference:
Com lete the following for each stack/vent use additional sheets if necessary)
0 Stacks and processes may sometimes be grouped, if similar -See instructions from CY 1999 or DAQ web pages
STACK PARAMETER
ID# PEP-1
ID# FEP-Al
ID# FEP-A2
Height (feet)
100
100
8' above bldg.
Diameter (feet)
5.6
1.7
0.5
Temperature (OF)
650
Ambient
Ambient
Velocity (Feet per Second)
36
120
66
Volume Flow Rate (ACFM)
53,000
18,000
800
Sources/Processes Exhausted
Source ID #
PS-1, PS-2
FS-1
FS-1
Information on Form C cannot be held confidential.
DEQ-CFW 00088144

Form D: Process Information (Page 1 of 2) Facility ID# 0900009
• North Carolina Department of Environment and Natural Resources
Division of Air Quality
Calendar 2000 Air Pollutant Point Source Emissions Inventory
1. Source ID No. (same as in permit) PS-1 and PS-2
2. Process Description:
3. Maximum Process Rate:
(Ex: gal/hr, mmcf/hr)
N/A
No. 6 Fuel Oil Boilers
4. CY 2000 Process Throughput:
(Ex: lb, gal) N/A
include units
5. Normal Operating Schedule:
Hours per Days per
Day Week
6. Typical Start & End Times For Process:
7. Percentage Annual Throughput:
Dec -Feb 25 Mar -May
include units
Weeks Hours per
per Year Year 8784
End:
25 Sept -Nov 25
N/A
8. Capture Efficiency (% of Emissions from this Process Vented Through Control Device):
N/A
9. Control Device Descriptions Primary •
Secondary:
Start:
25 June -Aug
N/A
10. Combined (Net) Control Device Efficiency (%):
(Control efficiency is pollutant specific)
PM
PM-10
PM-2.5
S02
NOx
VOC
N/A
11. ANNUAL FUEL USAGE For This Process (Coal. oil. wood. natural Eras. etc.) -Use additional sheets as needed.
Type of Fuel Used in This Process/Source
Amount (gal, tons, mmcf/year)
% Sulfur
% Ash
No. 6 Fuel Oil
4,404,000 gal.
1.99
0.04
If you do not provide annual throughput your inventory will be deemed incomplete and returned to you
K'o review instructions or get a new copy, go to web page: httn://dag.statE.ne.us/Offices/Plannin2/Attainment/est.htmi or
Information on Form D cannot be held confidential.
DEQ-CFW 00088145

•
•
Form D: Process Information (Page 2 of 2)
CY 2000 Facility ED#
0900009 Source ED#
Actual Emissions per Pollutant Listed for Source/Process Identified Above:
r
Attach calculations and documentation of emission factors or other estimation methods used.
PS-1 and PS-2
"Per Ton" Pollutant:
PM
PM-10
PM-2.5
S02
NOX
VOC
CO
Actual Emissions: Tons/year
47.36
33.61
33.61
687.97
147.53
0.62
11.01
***All Other HAPs/TAPs Per Instructions (use additional sheets if necessary)***
Pollutant
CAS #
Emitted
lbs./ r.
Comments
Chlorine
7782-50-5
Fluorine
7782-414
Hydrazine
302-01-2
Hydrogen Chloride (As weight of HCl in solutions)
7647-01-0
50,331
Hydrogen Fluoride (As weight of HF in solutions)
7664-39-3
Hydrogen Sulfide
7783-06-4
Lead (As metal or compounds -mass of total)
LEADCPDS
71.86
Methyl Chloroform (toot a VOC, by rule)
71-55-6
Methylene Chloride (toot a VOC, by rule)
75-09-2
Ozone (Not expected as a facility emission)
10028-15-6
Perchloroethylene (Not a VOC, by rule)
127-18-4
Phosphine
7803-51-2
List all other HAP/TAPs below IN ALPHABETICAL
ORDER, Per Instructions. Use more sheets, as needed
Antimony
ANTIMONYCPDS
22.66
Arsenic
ARSENTICCPDS
43.37
Beryllium
BERYLCPDS
2.72
Cadmium
CADMIUMCPDS
73.80
Cobalt
COBALTCPDS
64.09
Chromium
CHROMCPDS
48.55
Formaldehyde
50-00-0
183.21
Maganese
MANGCPDS
31.72
Mercury
MERCCPDS
11.01
Nickel
NICKCPDS
1025.46
Selenium
SEC
24.60
Polycyclic Organic Matter
POM
5.11
Chromium VI
CHROM6CPDS
0.17
Information on Form D cannot be held confidential.
DEQ-CFW 00088146

NAME OF FACILITY: DUPONT - FAYETTEVILLE WORKS APP 018734
CITY: DUART Review Engineer M.E. JOHNSON
COUNTY:, BLADEN
ENTER FUEL TYPE #1,2,4,5,6 :
Fuel sulfur content
FUEL USAGE :
Facility heat input from non -wood fuel
ENTER BOILER SIZE:
Hours of operation
CONTROL EFFICIENCY:
ACTUAL CRITERIA EMISSIONS
6
For utility boilers
% only, firing type
gal/yr Normal = 2
mmBtu/hr
mmBtu/hr
hr/yr
%
1.99
4404000
57.5
139.4
8,760
0.00
2
Factor
Emission Rates
Pollutant
(lb poll./1000 gal)
(lb/yr)
(lb/hr)
(tpy)
PM
21.5
94,722
10.81
47.36
PM-10
15.3
67,226
7.67
33.61
S02
312.4
1,375,942
157.07
687.97
S03
5.7
25,103
2.87
12.55
NOx
67.0
295,068
33.68
147.53
VOC's
0.3
1,233
0.14
0.62
CO
5.0
22,020
2.51
11.01
CO2
25500.0
112,302,000
12819.86
56151.00
Sum emissions =1
114,183,313 Ib.
of criteria
ACTUAL TOXIC EMISSIONS
Pollutant
Factor
(lb poll./1 Ell Btu)
(lb/yr)
Emission Rates
(lb/hr)
(tpy)
ANTIMONY
35.00
22.66
2.59E-03
1.13E-02
ARSENIC
67.00
43.37
4.95E-03
2.17E-02
BERYLLIUM
4.20
2.72
3.10E-04
1.36E-03
CADMIUM
114.00
73.80
8.42E-03
3.69E-02
CHROMIUM
75.00
48.55
5.54E-03
2.43E-02
CHROMIUM VI
0.27
0.17
1.99E-05
8.70E-05
COBALT
99.00
64.09
7.32E-03
3.20E-02
FORMALDEHYDE
283.00
183.21
2.09E-02
9.16E-02
LEAD
111.00
71.86
8.20E-03
3.59E-02
MANGANESE
49.00
31.72
3.62E-03
1.59E-02
MERCURY
17.00
11.01
1.26E-03
5.50E-03
NICKEL
1584.00
1025.46
1.17E-01
5.13E-01
POMS
7.90
5.11
5.84E-04
2.56E-03
SELENIUM
38.00
24.60
2.81 E-03
1.23E-02
TOTAL TOXICS
1
1608.35
1.84E-01
8.04E-01
Total emissions =
114184 922 lb.
DEQ-CFW 00088147

2000 AIR EMISSIONS INVENTORY
POWERHOUSE BOILERS
(PS-1 and PS-2)
EMISSIONS DETERMINATION
No. 6 Fuel Oil consumed = 4,404,000 gallons
104,857 barrels
Standard emission factor for HCl from the combustion of No. 6 Fuel Oil:
0.48 lb. HCl per barrel of oil
104,857 barrels multiplied by 0.48 lb. HCl per barrel of oil equals:
50,331 lb. HCl emissions
P:\Excel\State\Air\2000em-inv\PS-1 PS-2.xls
06/08/2001
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DEQ-CFW 00088148