DEQ-CFW_00087942

Vinyl Ethers North Air Emissions Inventory PSEPVE Process Emissions
Page 1 of 17
0 2004 AIR EMISSIONS INVENTORY SUPPORTING DOCUMENTATION
Emission Source ID No: NS-B
Emission Source Description: VE-North PSEPVE Manufacturing Process
Process & Emission Description: The VE-North PSEPVE manufacturing process is a continuous chemical
reaction. All emissions from the process are vented through the Nafion Division Waste Gas Scrubber (Control
Device ID No. NCD-Hdr) which has a documented control efficiency of 99.6% for all acid fluoride compounds.
Some emitted compounds are assumed to pass completely through the scrubber, so the control efficiency for
those compounds is assumed to be 0%. The control of emissions of specific compounds will be addressed and
detailed in the following pages.
The PSEPVE process in VE-North emits compounds in the acid fluoride family. In the presence of water (such
as in atmospheric moisture), these acid fluorides can eventually hydrolyze to hydrogen fluoride. For the purpose
of this emissions inventory, a conservative approach will be taken and the acid fluorides will be reported both as
a VOC and as the equivalent quantity of hydrogen fluoride.
Basis and Assumptions:
- The PSEPVE process flowsheet is the basis for relative concentrations of before -control emissions of gaseous
wastes.
- Calculations of point source emissions are based on actual vent flow totals taken from the IP21 Historian.
- All emission determination calculations are available on the EXCEL spreadsheet found at
S:/Everyone/cecilkd/VEN 2003 Emissions.xls.
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DEQ-CFW 00087942

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Vinyl Ethers North Air Emissions Inventory PSEPVE Process Emissions
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Point Source Emission Determination
A. HFP
Hexafluoropropylene
HF Potential:
HFP is a VOC without the potential to form HF
Quantity Released
HFP is a byproduct present in the HFPO feed. It is an inert in VE-North that is
vented to the WGS.
HFP vented per the process flowsheet
CAS No. 116-15-4
0.15 kgHFP
Vented from the Condensation Reactor: 3 C d2xV 1F1
66k
0
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Vinyl Ethers North Air Emissions Inventory PSEPVE Process Emissions
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B. HFPO CAS No. 428-59-1
Hexafluoropropylene oxide
HF Potential:
HFPO is a VOC without the potential to form HF
Quantity Released
HFPO is a byproduct present in the HFPO feed. It is an inert in V E-North that is
vented to the WGS.
HFPO vented per the process flowsheet
3.28 kg HFPO
Vented from the Condensation Reactor:
3.66 kg Cond Rx Vent Flow
Vented from the Crude Receiver
0 kg HFPO
118.76
kg Crude Receiver Vent
0 kg HFPO
Vented from the Foreshots Receiver
0.33 kg ForeshotsReceiverVen
HFPO vented based on
1,060 kg in the Condensation Reactor vent stream.
HFPO vented based on
27,984 kg in the Crude Receiver vent stream.
HFPO vented based on
19 kg in the Foreshots Receiver vent stream.
HFPO vented from Condensation Reactor:
3.28 kg HFPO x
1,060 kg CndRx = 950 kg HFPO
3.66 kg CndRx
HFPO vented from Crude Receiver
0.00 kg HFPO x
27,984 kg CrRec = 0 kg HFPO
18.76 kg CrRec
HFPO vented from Foreshots Receiver
0.00 kg HFPO x
19 kg FsRec = 0 kg HFPO
0.33 kg FsRec
VOC Emissions
950 kg from Condensation Reactor
+
0 kg from Crude Receiver
+
0 kg from Foreshots Receiver
=
950 kg HFPO = 950 kg VOC
2,090 lb VOC
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C. PPF
Perfluoropropionyl fluoride
HF Potential:
Ea
CAS No. 422-61-7
ch mole of PPF (MW = 166) can generate 1 mole of HF (MW = 20).
E PPF-1 molePPF 20g HF 1 moleHF
PPF• = 0.120kg HF
166g PPF 1 moleHF 1 molePPF
Therefore, each 1 kg of PAF generates
Quantity Released
Before -control PPF vented per the process flowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
0.120 kg of HF
0.20 kg PPF
3.66 kg Cond Rx Vent Flow
0 kg PPF
18.76 kg Crude Receiver Vent
0 kg PPF
033 kg ForeshotsReceiver Vent
PPF vented based on
1,060 kg in the Condensation Reactor vent stream.
PPF vented based on
27,984 kg in the Crude Receiver vent stream.
PPF vented based on
19 kg in the Foreshots Receiver vent stream.
Before control PPF vented from Condensation Reactor:
0.20 kg PPF x
1,060 kg CndRx =
59 kg PPF
3.66 kg CndRx
PPF vented from Crude Receiver
0.00 kg PPF x
27,984 kg CrRec =
0 kg PPF
18.76 kg CrRec
PPF vented from Foreshots Receiver
0.00 kg PPF x
19 kg FsRec =
0 kg PPF
0.33 kg FsRec
Total before -control PPF vented
=
59 kg PPF
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
VOC Emissions
59 kg PPF
Waste Gas Scrubber
x (100%-99.6%) Control Efficiency
= 0.24 kg PAF =
0.24 kg VOC
=
0.52 Ib. VOC
HF Equivalent Emissions 0 kg PPF
x 0.120 kg HF/kg PPF
= 0.03 kg HF 0.06 Ib. HF
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D. TFE
Tetrafluoroethylene
CAS No. 116-14-3
HF Potential:
TFE is a VOC without the potential to form HF
Ouantity Released
TFE is a byproduct present in the TFE feed.
It is an inert in VE-North that is
vented to the WGS.
TFE vented per the process flowsheet
0 kg TFE
Vented from the Condensation Reactor:
3.66 kg Cond Rx Vent Flow
0.01 kg TFE
Vented from the Crude Receiver
18.76 kg Crude Receiver Vent
0 kg TFE
Vented from the Foreshots Receiver
0.33 kg ForeshotsReceiver Vent
TFE vented based on
1,060 kg in the Condensation Reactor vent stream.
TFE vented based on
27,984 kg in the Crude Receiver vent stream.
TFE vented based on
19 kg in the Foreshots Receiver vent stream.
TFE vented from Condensation Reactor:
0.00
x 1,060 kg CndRx = 0 kg TFE
3.66 kg TFE
kg CndRx
TFE vented from Crude Receiver
0.01
x 27,984 kg CrRec = 14 kg TFE
18.76 kg TFE
kg CrRec
TFE vented from Foreshots Receiver
0.00
x 19 kg FsRec = 0 kg TFE
0.33 kg TFE
kg FsRec
VOC Emissions
0 kg from Condensation Reactor
+ 14 kg from Crude Receiver
+ 0 kg from Foreshots Receiver
14 kg TFE = 14 kg VOC
30 Ib VOC
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Air Emissions Inventory
PSEPVE Process Emissions
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E. PSEPVE
Perfluoro-2-(2-Fluorosulfonylethoxy) Propyl Vinyl Ether
HF Potential:
PSEPVE is a VOC without the potential to form HF
Quantity Released
PSEPVE vented per the process flowsheet
CAS No. 1623-5-8
0 kg PSEPVE
Vented from the Condensation Reactor:
3.66 kg Cond Rx Vent Flow
0 kg PSEPVE
Vented from the Crude Receiver
18.76 kg Crude Receiver Vent
0.07 kg PSEP VE
Vented from the Foreshots Receiver
0.33 kg ForeshotsReceiver Vent
PSEPVE vented based on
1,060 kg in the Condensation Reactor vent stream.
PSEPVE vented based on
27,984 kg in the Crude Receiver vent stream.
PSEPVE vented based on
19 kg in the Foreshots Receiver vent stream.
PSEPVE vented from Condensation Reactor:
0.00
x 1,060 kg CndRx = 0 kg PSEPVE
3.66 kg PSEPVE
kg CndRx
PSEPVE vented from Crude Receiver
0.00
x 27,984 kg CrRec = 0 kg PSEPVE
18.76 kg PSEPVE
kg CrRec
PSEPVE vented from Foreshots Receiver
0.07
x 19 kg FsRec = 3.97 kg PSEPVE
0.33 kg PSEPVE
kg FsRec
VOC Emissions
0 kg from Condensation Reactor
+ 0 kg from Crude Receiver
+ 3.97 kg from Foreshots Receiver
= 3.97 kg PSEPVE = 3.97 kg VOC
8.74 lb VOC
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Vinyl Ethers North Air Emissions Inventory PSEPVE Process Emissions
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F. C4
Perfluoro-2-butene
HF Potential:
C4s are VOCs without the potential to form HF
Quantity Released
C4s are perfluorobutenes that are byproducts from the Agitated Bed Reactor system.
They are inerts in VE-North that is vented to the WGS.
C4s vented per the process flowsheet
CAS No. 360-89-4
0kgC4
Vented from the Condensation Reactor:
3.66 kg Cond Rx Vent Flow
0.46 kg C4
Vented from the Crude Receiver
18.76 kg Crude Receiver Vent
0.10 kg C4
Vented from the Foreshots Receiver
0.33 kg ForeshotsReceiveYVen
C4s vented based on
1,060 kg in the Condensation Reactor vent stream.
C4s vented based on
27,984 kg in the Crude Receiver vent stream.
C4s vented based on
19 kg in the Foreshots Receiver vent stream.
C4s vented from Condensation Reactor:
0.00
x 1,060 kg CndRx = 0 kg C4s
3.66 kg C4s
kg CndRx
C4s vented from Crude Receiver
0.46
x 27,984 kg CrRec = 685 kg C4s
18.76 kg C4s
kg CrRec
C4s vented from Foreshots Receiver
0.10
x 19 kg FsRec = 6 kg C4s
0.33 kg C4s
kg FsRec
VOC Emissions
0 kg from Condensation Reactor
+ 685 kg from Crude Receiver
+ 6 kg from Foreshots Receiver
690 kg C4s = 690 kg VOC
1,519 Ib VOC
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Vinyl Ethers North Air Emissions Inventory PSEPVE Process Emissions
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G. HFPO Trimer CAS No. 2641-34-1
Pertluoro-2,5-Di methyl-3,6-Dioxanonanoyl
HF Potential:
Each mole of HFPO Trimer MW = 498 can generate 1 mole of HF MW = 20).
1 moleTrimer 20g HF 1 moleHF
1 kg MA _ 0.0402kgHF
498g Trimer 1 moleHF 1 moleTrimer
Therefore, each 1 kg of MA generates 0.040 kg of HF
Quantity Released
HFPO Trimer is a byproduct formed in the Condensation Reactor system.
HFPO Trimer vented per the process flowsheet 0 kg HFPO Trimer
Vented from the Condensation Reactor: 3.66 kg Cond Rx Vent Flow
0 kg HFP0Trim er
Vented from the Crude Receiver:
M76 kg Crude Receiver Vent
0.01 kg HFPO Trimer
Vented from the Foreshots Receiver:
0.33 kg ForeshotsReceiverYen
HFPO Trimer vented based on 1,060 kg in the Condensation Reactor vent stream.
HFPO Trimer vented based on 27,984 kg in the Crude Receiver vent stream.
HFPO Trimer vented based on 19 kg in the Foreshots Receiver vent stream.
Before control HFPO Trimer vented from Condensation Reactor:
0.00 x 1,060 kg CndRx = 0 kg HFPO Trimer
3.66 kg HFPO Trimer
kg CndRx
HFPO Trimer vented from Crude Receiver
0.00 x 27,984 kg CrRec = 0 kg HFPO Trimer
18.76 kg HFPO Trimer
kg CrRec
HFPO Trimer vented from Foreshots Receiver
0.01 x 19 kg FsRec = 0.79 kg HFPO Trimer
0.33 kg HFPO Trimer
kg FsRec
Total before -control HFPO Trimer vented 0.79 kg VOC
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
VOC Emissions 0.79 kg HFPO Trimer
Waste Gas Scrubber x (100%-99.6%) Control Efficiency
0.0032 kg HFPO Trimer = 0.0032 kg VOC
0.007 lb. VOC
HF Equivalent Emissions
0.0032 kg HFPO Trimer
x 0.040 kg HF/kg HFPO Trimer
0.00013 kg HF 0.00028 lb. HF
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H. Monoadduct (MA)
Tetrafluoro-2-[Tetrafluoro-2-(Fluorosulfonyl)Ethoxyl-Propanoyl Fluoride
HF Potential:
Ea
CAS No. 4089-57-0
ch mole of MA MW = 346 can generate 1 mole of HF MW = 20).
1 mole MA 20 g HF 1 moleHF = 0.05Ekg8kgHF
MA
346g MA 1 moleHF 1 moleMA
Therefore, each 1 kg of MA generates
Quantity Released
Before -control MA vented per the process flowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
0.058 kg of HF
0 kg MA
3.66 kg Cond Rx Vent Flow
0kgMA
18.76 kg Crude Receiver Vent
0.0045 kg MA
0.33 kg FO7-eshotsReceiverVen
MA vented based on
1,060 kg in the Condensation Reactor vent stream.
MA vented based on
27,984 kg in the Crude Receiver vent stream.
MA vented based on
19 kg in the Foreshots Receiver vent stream.
Before control MA vented from Condensation Reactor:
0.00 kg MA x
1,060 kg CndRx = 0 kg MA
3.66 kg CndRx
MA vented from Crude Receiver
0.00 kg MA x
27,984 kg CrRec = 0 kg MA
18.76 kg CrRec
MA vented from Foreshots Receiver
0.0045 kg MA x
19 kg FsRec = 0.265 kg MA
0.33 kg FsRec
Total before -control MA vented
= 0.265 kg MA
After -control emissions utilizing the 99.6% control
efficient Waste Gas Scrubber (WGS):
VOC Emissions
0.265 kg MA
Waste Gas Scrubber
x (100%-99.6%) Control Efficiency
= 0.00106 kg MA = 0.00106 kg VOC
= 0.002 Ib. VOC
HF Equivalent Emissions 0.00106 kg MA
x 0.058 kg HF/kg MA
0.00 kg HF 0.00 Ib. HF
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I. Diadduct (DA) CAS No. 4089-58-1
Tetrafluoro-2[Hexafluoro-2-(Tetrafluoro-2-(Fluorosulfonyl)Ethoxy) Propoxy Propionyl Fluoride
HF Potential:
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•
1 mole DA 20 g HF 1 mole HF
lkgMA=0.039kgHF
512 g DA 1 mole HF 1 mole DA
Therefore, each 1 kg of DA generates
Quantity Released
Before -control DA vented per the process flowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
0.039 kg of HF
0kgDA
3.66 kg Cond Rx Vent Flow
0kgDA
18.76 kg Crude Receiver Vent
0.13 kg DA
0.33 kg ForeshotsReceiver Vent
DA vented based on 1,060 kg in the Condensation Reactor vent stream.
DA vented based on 27,984 kg in the Crude Receiver vent stream.
DA vented based on 19 kg in the Foreshots Receiver vent stream.
Before control DA vented from Condensation Reactor:
0.00 kg DA x
1,060 kg CndRx =
3.66 kg CndRx
DA vented from Crude Receiver
0.00 kg DA x
27,984 kg CrRec =
18.76 kg CrRec
DA vented from Foreshots Receiver
0.13 kg DA x
19 kg FsRec =
0.33 kg FsRec
Total before -control DA vented
=
After -control emissions utilizing the 99.6% control
efficient Waste Gas Scrubber (WGS):
VOC Emissions
7.68 kg DA
Waste Gas Scrubber
x (100%-99.6%) Control Efficiency
= 0.0307 kg DA
HF Equivalent Emissions
0.0307 kg DA
x 0.039 kg HF/kg DA
= 0.00120 kg HF =
0 kg DA
0 kg DA
7.68 kg DA
7.68 kg DA
0.031 kg VOC
0.068 Ib. VOC
0.00 lb. HF
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Vinyl Ethers North
Air Emissions Inventory
PSEPVE Process Emissions
Page 11 of 17
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J. Hydro PSEPVE
Tetrafluoro-2-[Trifluoro-2-(1,2,2,2-Tetra-fluoroethoxy)-1-(Trifluoromethyl) Ethoxy]-
Ethane Sulfonyl Fluoride
HF Potential:
Hydro-PSEPVE is a VOC without the potential to form HF
Quantity Released
Hydro-PSEPVE vented per the process flowsheet
0 kg Hydro —PSEPVE
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
3.66 kg Cond Rx Vent Flow
0 kg Hydro— PSEPVE
18.76 kg Crude Receiver Vent
0.0045 kg Hydro— PSEPVE
0.33 kg ForeshotsReceiveYVen
Hydro-PSEPVE vented based on 1,060 kg in the Condensation Reactor vent stream.
Hydro-PSEPVE vented based on 27,984 kg in the Crude Receiver vent stream.
Hydro-PSEPVE vented based on 19 kg in the Foreshots Receiver vent stream.
Hydro-PSEPVE vented from Condensation Reactor:
0.00 kg Hydro-PSEPVE x 1,060 kgCndRx
3.66 kg CndRx
Hydro-PSEPVE vented from Crude Receiver
0.00 kg Hydro-PSEPVE x
18.76 kg CrRec
Hydro-PSEPVE vented from Foreshots Receiver
0.0045 kg Hydro-PSEPVE x
0.33 kg FsRec
VOC Emissions
27,984 kg CrRec
19 kg FsRec
0 kg from Condensation Reactor
0 kg from Crude Receiver
0.265 kg from Foreshots Receiver
0.265 kg Hydro-PSEPV =
CAS No. 755-02-9
0 kg Hydro-PSEPVE
0 kg Hydro-PSEPVE
0.265 kg Hydro-PSEPVE
0.265 kg VOC
0.583 lb VOC
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Vinyl Ethers,North Air Emissions Inventory PSEPVE Process Emissions
Page 12 of 17
K. Iso-PSEPVE
Perfluoro-1-Methyl-2-(2 Fluorosulfonyl Ethoxy) Ethyl Vinyl Ether
HF Potential:
Iso-PSEPVE is a VOC without the potential to form HF
Quantity Released
Iso-PSEPVE vented per the process flowsheet
CAS No. 34805-58-8
0 kg Iso — PSEP VE
Vented from the Condensation Reactor: 3.66 kg Cond Rx Vent Flow
0 kg Is — PSEP VE
Vented from the Crude Receiver 18.76 kg Crude Receiver Vent
0.014 kg Iso — PSEP VE
Vented from the Foreshots Receiver 0.014 kg Foreshots Receiver Vent
Iso-PSEPVE vented based on 1,060 kg in the Condensation Reactor vent stream.
Iso-PSEPVE vented based on 27,984 kg in the Crude Receiver vent stream.
Iso-PSEPVE vented based on 19 kg in the Foreshots Receiver vent stream.
Iso-PSEPVE vented from Condensation Reactor:
0.00 kg Iso-PSEPVE x 1,060 kg CndRx = 0 kg Iso-PSEPVE
3.66 kg CndRx
Iso-PSEPVE vented from Crude Receiver
0.00 kg Iso-PSEPVE x
18.76 kg CrRec
Iso-PSEPVE vented from Foreshots Receiver
0.014 kg Iso-PSEPVE x
0.33 kg FsRec
VOC Emissions
27,984 kg CrRec =
19 kg FsRec =
0 kg from Condensation Reactor
0 kg from Crude Receiver
0.795 kg from Foreshots Receiver
0.795 kg Iso-PSEPVE _
0 kg Iso-PSEPVE
0.795 kg Iso-PSEPVE
0.795 kg VOC
1.749 lb VOC
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L. Glycol Ethers (GE) GLYET-Other
The emissions of glycol ethers is based on a mass balance of glycol ethers consumed in the process.
The only GE emissions in PSEPVE is DiGlyme
Quantity Released
= 2,600 kg GE introduced into processes
= 2,467 kg GE transferred to H/C waste tank
133 kg GE unaccounted for and assumed emitted
294 lb. Glycol Ethers
Assume that the emissions of glycol ethers is split evenly between the three
processes of Vinyl Ethers North.
Therefore:
Emissions of glycol ether from PSEPVE _
•
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294 lb. Glycol Ethers
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Vinyl Ethers'North Air Emissions Inventory PSEPVE Process Emissions
Page 14 of 17
M. Sulfonyl Fluoride (SOF2)
HF Potential:
Each mole of SOF2 (MW = 86) can generate 2 mole of HF (MW = 20).
CAS No. 7783-42-8
Ekg1 moleSOF2 20g HF 2 moleHF
MA = 0.465kgHF
86g SOF2 1 moleHF 1 moleSOF2
Therefore, each 1 kg of SOF2 generates
Quantity Released
Before -control SOF2 vented per the process flowsheet
Vented from the Condensation Reactor:
Vented from the Crude Receiver
Vented from the Foreshots Receiver
0.465 kg of HF
0 kg SOF2
3.66 kg Cond Rx Vent Flow
2.04 kg SOF2
18.76 kg Crude Receiver Vent
0 kg SOF2
0.33 kg Foresh ots ReceiverVen
SOF2 vented based on
1,060 kg in the Condensation Reactor vent stream.
SOF2 vented based on
27,984 kg in the Crude Receiver vent stream.
SOF2 vented based on
19 kg in the Foreshots Receiver vent stream.
Before control SOF2 vented from Condensation Reactor:
0.00 kg SOF2 x
1,060 kg CndRx = 0 kg SOF2
3.66 kg CndRx
SOF2 vented from Crude Receiver
2.04 kg SOF2 x
27,984 kg CrRec = 3,044 kg SOF2
18.76 kg CrRec
SOF2 vented from Foreshots Receiver
0.00 kg SOF2 x
19 kg FsRec = 0 kg SOF2
0.33 kg FsRec
Total before -control SOF2 vented
= 3,044 kg SOF2
After -control emissions utilizing the 99.6% control efficient Waste Gas Scrubber (WGS):
SOF2 Emissions
3,044 kg SOF2
Waste Gas Scrubber
x (100%-99.6%) Control Efficiency
= 12 kg SOF2 27 lb. SOF2
HF Equivalent Emissions 12 kg SOF2
x 0.465 kg HF/kg SOF2
= 5.66 kg HF 12.48 Ib. HF
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DEQ-CFW 00087955

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Vinyl Ethers'North
N. Carbon Monoxide (CO)
Air Emissions Inventory
CO is a criteria pollutant
Quantity Released
CO are perfluorobutenes that are byproducts from the Agitated Bed Reactor system.
They are inerts in VE-North that are vented to the WGS.
CO vented per the process flowsheet
PSEPVE Process Emissions
Page 15 of 17
CAS No. 630-08-0
0kgCO
Vented from the Condensation Reactor:
3.66 kg Cond Rx Vent Flow
1.30 kg CO
Vented from the Crude Receiver
18.76 kg Crude Receiver Vent
0kgCO
Vented from the Foreshots Receiver
0.33 kg ForeshotsReceiverVen
CO vented based on
1,060 kg in the Condensation Reactor vent stream.
CO vented based on
27,984 kg in the Crude Receiver vent stream.
CO vented based on
19 kg in the Foreshots Receiver vent stream.
CO vented from Condensation Reactor:
0.00
x 1,060 kg CndRx = 0 kg CO
3.66 kg CO
kg CndRx
CO vented from Crude Receiver
1.30
x 27,984 kg CrRec = 1,946 kg CO
18.76 kg CO
kg CrRec
CO vented from Foreshots Receiver
0.00
x 19 kg FsRec = 0 kg CO
0.33 kg CO
kg FsRec
CO Emissions 0 kg from Condensation Reactor
+ 1,946 kg from Crude Receiver
+ 0 kg from Foreshots Receiver
= 1,946 kg CO = 4,289 lb CO
DEQ-CFW 00087956

Vinyl Ethers North Air Emissions Inventory PSEPVE Process Emissions
Page 16 of 17
0 O. VOC Summary
Nafion Compound Name
Before Control
Generated
After Control
Stack Emissions
VOC
HF
k / r
Ib/ r
Ib/ r
Ib/ r
A.
I HFP
4,693
10,324
10,324
B-
HFPO
950
2,090
2,090
G.
PPF
59
130
0.52
0
D.
TFE
14
30
30
E.
PSEPVE
4
9
9
F•
C4
690
1,519
1,519
G.
HFPO Trimer
0.79
1.75
0
0
H.
MA
0.26
0.58
0.00
0
I.
DA
7.68
16.94
0.07
0
J.
Hydro PSEPVE
0.26
0.58
0.58
K.
Iso PSEPVE
0.79
1.75
1.75
L.
Glycol Ethers
133
294
294
Total
6,553
1 14,416
1 14,267
0
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Vinyl Ether9 North Air Emissions Inventory PSEPVE Process Emissions
Page 17 of 17
P. Point Source Summary
Nafion Compound Name
Stack
Emissions
lb/ r
Equipment
Emissions (Note')
lb/ r
Maintenance
Emissions (NO`BZ)
lb/ r
Total
Emissions
lb/yr
A.
HFP
10,324
766
196
11,286
B.
HFPO
2,090
155
40
2,284
C.
PPF
0.52
0.04
0.01
0.6
D.
TFE
30
2.2
0.6
33
E.
IPSEPVE
8.74
0.65
0.17
9.6
F.
C4
1,519
113
29
1,660
G.
HFPO Trimer
0.007
0
0.000
0
H.
MA
0.002
0
0.000
0
I.
DA
0.068
0.005
0.0013
0.074
J.
Hydro-PSEPVE
0.583
0.043
0.011
0.64
K.
Iso-PSEPVE
1.749
0.13
0.033
1.9
L.
Glycol Ethers
294
21.81
5.579
321
M.
SOF2
27
2.0
0.51
29
N.
CO
4,289
0
0
4,289
Total
1 18,584
1,061
271
19,915
Note 1 - See section titled "Equipment Emissions" for details
Note 2 - See section titled "Maintenance Emissions" for details
HF Equivalent Emissions
Nafion Compound Name
Stack
Emissions
lb/ r
Equipment
Emissions
lb/ r
Maintenance
Emissions
Ib/ r
Total
Emissions
lb/yr
C.
PPF
0.06
0.00
0.00
0.07
G.
HFPO Trimer
0.00
0.00
0.00
0.00
H.
MA
0.00
0.00
0.00
0.00
I.
DA
0.00
0.00
0.00
0.00
M.
I SOF2
12.48
0.93
0.24
13.65
Total
12.55
0.93
0.24
13.72
The estimated HF equivalent emissions from Equipment Emissions were determined by multiplying the
PPF HF Potential (0.12 lb. HF/lb. PPF) by the PPF Equipment Emissions (0.041b./yr) for the Compound
0.12 lb/yr HF x 0.04 lb/yr Equipment PPF = 0.005 lb/yr HF
lb/yr PPF
The estimated HF equivalent emissions from Maintenance Emissions were determined by multiplying the
PPF HF Potential (0.12 lb. HF/lb. PPF) by the PPF Maintenance Emissions (0.001 lb./yr) for the Compound
0.12 lb/yr HF x 0.010 lb/yr Maintenance PPF = 0.001 lb/yr HF
lb/yr PPF
DEQ-CFW 00087958