DEQ-CFW_00086561

IRPO Manufacturing Process
Emission Summary
A. VOC Compound Summary
11
2007 E missions
Emission ummary
Page 3 of 23
Nafion®
Compound
CAS Chemical Name
CAS No.
Point Source and Non -point
Source Emissions (Ibs)
Accidental
Emissions
Total
Emissions Ibs
COF2
PAF
A/F Solvent TFF
Carbonyl Fluoride
Trifluoroacet I Fluoride
Perfluoro-3,5,7,9,11-pentaoxadodecanoyl fluoride
353-50-4
354-34-7
690-43
2,372
1,680
471
p
0
0
��
A/F Solvent TAF
Trifluorometh I ester of carbonofluoridic acid
3299-24-9
471
0"�flra
ry�Cu
HFP
Hexafluoroproplyene
116-15-4
73,410
1 ammunmr
HFPO
Hexafluoropro I eneEpoxide
428-59-1
31,187
NEMMIFIIR
Benzene
1Benzene
71-43-2
2
�rk, # p,
""
Y zP
Toluene Meth (benzene 108-88-3 2,143
Total VOC Emissions (Ibs)
Total VOC Emissions (tons)'
rr11k1,`,77a"
B. VOL, Controi Efficiency
VOCs Generated
VOCs Emitted from Stack
Point Source
Generated (Ibs)
Equipment Emissions Inside
Buildings Ibs
Total VOC
Generated
Point Source
Emissions Ibs
Non -point Source
Emissions Ibs
Total VOC
Emitted Ibs
1,226,156
3,420
1;229,577'
96,544
2,183
1,229,577 lb VOC generated
98,727 lb VOC emitted
1 �4 lb VOC removed in control device
C. Toxic Air Polluntant Summary
1,130,849 lb VOC removed in control device
1,229,577 lb VOC generated
- 9f /o'VOC control efficiency
Nafion®
Compound
CAS Chemical Name
CAS No.
Point Source Emissions
Ibs
Non -point Source
Emissions Ibs
Accidental
Emissions
Total
Emissions Ibs
HF
Hydrogen Fluoride
7664-39-3
1,827.60
153.64„a,
, ,, ,
Benzene
Benzene
71-43-2
1.92
Toluene
Methylbenzene
108-88-3
2,143.00;';�t43�00�n
D. HF Control Efficiency Total Emissions (tons) 57.93

PO Manufacturin Process
9 200T Emissions
Emission Mumma ry
Page 4 of 23
1,828 lb HF emitted from Point Sources
(100%-99.6%) Stack Efficiency
�56t9Q1 lb HF sent to control device from Point Sources
456,901 lb HF sent to control device from Point Sources
1,981 lb HF emitted
0 lb HF removed in control device
456,901 lb HF sent to control device from Point Sources
+ 154 lb HF from Non -point Sources inside buildings
Ib HF generated
454,920 lb HF removed in control device
457,055 lb HF generated
!HF control efficiency

4 IFPG� Manufacturing Process 2007 Emissions Point Source Emission Determination
Page 10 of 23
E
F. Perfluoromethylcyclopropane (PMCP)
Oxygen (02)
Fluoroform (CF3H)
Carbon Dioxide (COZ)
CAS No. 379-16-8
CAS No. 7782-44-7
CAS No. 75-46-7
CAS No. 124-38-9
PMCP, 02, CF31-1, and CO2 are not VOCs nor do they have potential to make HF. Since they are not
reportable emissions, the calculations are not shown here.
G. Point Source Summary
Nafion Compound Name
Before Control After Control
After Control
VOC Generated Stack Emissions
Stack Emissions
k / r VOC
Ib/ r VOC Ib/ r VOC
Ib/ r HF
ton/ r VOC
Ton/ r HF
A.
COF2
244,367
$7.3 2,155
1306
1
1
B.
PAF
173,088
39 1,526
263
1
0
C.
Acid Fluoride Solvent TFF)
48,495
428
259.2
0
0
Acid Fluoride Solvent TAF)
48,495
=i 428
0
D.
HFP
29,600
Ala 65,256
33
E.
HFPO
12,134
26,751
13
TotalFIR
5 56rfit [
a 1-15-2 ,
DEQ-CFW 00086563

HFPO Manufacturing Process 2007 Emissions Non -Point Source Emissions
Page 11 of 23
Non -point Source Emission Determination:
Non -point source emissions include equipment emissions and maintenance emissions. Equipment emissions are due to leaks
Orom valves, flanges, and pumps. If these leaks occur outside of a building, they are considered fugitive emissions. Maintenance
emissions are due to opening up vessels for maintenance and though some of this equipment is located indoors, to be
conservative it will be assumed that all maintenance emissions are fugitive emissions.
I. Equipment Emissions
Equipment Emissions are a function of the number of emission points in the plant (valves, flanges, pump seals). For the
equipment emission calculations the inventory shown below is conservative and based on plant and process diagrams. Note that
the calculations below include equipment emissions (EE) inside buildings (which become stack emissions or SE) as well as
equipment emissions outside buildings (fugitive emissions or FE).
A. Equipment Emissions Inside Buildings (Stack Emissions)
1. Equipment Emissions from Reactor, Distillation Column, #1 Recycle Tank:
Emissions are vented from equipment located in the barricade and are vented through the barricade scrubber. Barricade
scrubber is 95% efficient for control of acid fluorides. From W1208078 HFPO Flowsheet:
0
Material
VOC
HF
Aver a e Vessel Contents k /hr
% of
contents
% VOC
% HF
HF
Potential
% overall HF Potential
Line 6
1 Line 6
Line 4
1 Total
0.606
0.172
0.11
0.081
02
1
2.4
2.4
4.8
0.1
COF2
X
Ix
33.7
33.7
67.4
1.4%
1.4%
1.4%
0.606
1.4%
PAF
x
Ix
25.5
25.5
51
1.0%
1.0%
1.0%
0.172
1.0%
HFP
x
76.4
76.4
152.8
3.1%
3.1%
HFPO
x
100.1
100.1
200.2
4.1%
4.1%
HFA
x
I
1
1
2
0.0%1
0.0%
PMFF
x
Ix
9.6
9.6
19.2
0.4%1
0.4%
0.4%
0.606
0.4%
PMAF
x
Ix
18.41
18.4
14.5 1
51.3
1.1%1
1.1%
1.1%
0.11
1
PMCP
86.61
86.6
80.51
253.7
5.2%
TIFF
x
x
50.3
50.3
50
150.6
3.1%
3.1%
3.1%
0.081
3.1%
TAF
x
X
500
500
495.9
1495.9
30.6%
30.6%
30.6%
0.606
30.6%
TAF
x
x
335
335
332
1002
20.5%
20.5%
20.5%
0.606
20.5%
TAF
x
x
479
479
476.3
1434.3
29.4%
29.4%
29.4%
0.606
29.4%
Total
1
48R.', 91
1%
87.4%
82.3%
1.0%
1-lo/ol
3.1%
Assume that: 95% of process materials are VOCs;
88% are acid fluorides with 95% controlled in the barricade scrubber;
7% are non-acid fluorides with 0% controlled in the barricade scrubber.
100% of the liquid is 0.504 weight fraction HF.
Barricade:
Valve emissions:
119 valves x 0.00039 Ib/hr/valve
- 0.046 Ib/hr EE
Flange emissions:
248 flanges x 0.00018 Ib/hr/flange
= 0.045 Ib/hr EE
Pump emissions:
1 pump x 0.00115 Ib/hr/pump
0.001 Ib/hr EE
Total equipment emission rate
= 0.092 Ib/hr EE
Barricade VOC:
From acid fluorides:
0.092 lb. EE/hr
710.751 lb VOC generated
x 8760 hr/year
x (100%-95%) scrubber efficiency
x 0.880 lb. A/F VOC/lb. EE
Ib/yr VOC emitted
..
7�I lb/yr VOC generated
From non-acid fluorides: 0.092 lb. EE/hr
x 8760 hr/year
x 0.070 lb. Non-A/F VOC/lb. EE
is 5_f 537 Ib/yr VOC
learricade HF: 0.092 lb. EE/hr
x 8760 hr/year
x 0.504 lb. HF/lb. EE
x (1000/6-95%) scrubber efficiency
Total Barricade VOC Emissions:
35.538 Ib/yr VOC
+ 56.537 Ib/yr VOC
13 %92Q Ib/yr VOC
DEQ-CFW 00086564

HFPO Manufacturing Process 2007 Emissions Non -Point Source Emissions
Page 12 of 23
_ r 20 353 Ib/yr HF
•
•
�J
DEQ-CFW 00086565

HFPQ Manufacturing Process 2007 Emissions Non -Point Source Emissions
Page 13 of 23
2. Fugitive Emissions From Distillation System #1
Emissions are vented from equipment located in tower and are vented through stack.
rom W1208078 HFPO Flowsheet:
Material
VOC
HF
Avera e Vessel Contents
% of
contents
% VOC
% HF
HF
Potential
% overall HF Potential
Line 8 k /hr
0.606
0.172
0.11
O2
COF2
PAF
x
x
x
x
2.4
33.7
25.5
0.93%
13.09%
9.91%
13.1%
9.9%
13.1%
9.9%
0.606
0.172
13.1%
9.9%
TT -FP
x
76.4
29.68%
29.7%
HFPO
x
99.9
38.81%
38.8%
HFA
PMFF
PMAF
x
x
x
x
x
1
9.6
3:8
0.39%
3.73%
1.48%
0.4%
3.7%
1.5%
3.7%
1.5%
0.606
0.110
3.7%
1.5%
PMCP
5.1
1.98%
TFF
x
x
TAF
x IX
TAF
x Ix
TAF
Total
x
Ix
257.4
94.7%1
87.4%
A­,r
14P
PntP-ntl.'dl
0.121
Assume that: 95 wt. % of the process material are VOCs;
100% of the liquid is 0.121 weight fraction HF.
Valve emissions: 60 valves x 0.00039 Ib/hr/valve = 0.023 lb/hr EE
Flange emissions: 120 flanges x 0.00018 Ib/hr/flange 0.022 Ib/hr EE
Total equipment emission rate 0 9201MIb/hr EE
VOC: 0.045 lb. EE/hr HF: 0.045 lb. EE/hr
x 8760 hr/year x 8760 hr/year
x 0.950 lb. VOC/lb. EE x 0.121 lb. HF/lb. EE
= w374490 Ib/yr VOC _ 47w69& lb/yr HF
Equipment Emissions From Scrubber, Dryers, and Stripper Column
Emissions are vented from equipment located in tower and are vented through stack.
From W1208078 HFPO Flowsheet:
Avera e Vessel Contents k /hr
% of
% VOC
% HF
HF
% overall HF Potential
Line 6
Line 11
Line 12
Total
0.606
0.172
0.11
Material
VOC
HF
contents
Potential
02
COF2
0.68%
068%
0.172
68%
PAF
6.5
HFP
x
75.8
75.8
75.8
227.4
23.90%
23.90%
HFPO
x
99.6
96.7
96.7
293
30.79%
30.79%
HFA
x
1
1
0.11%
0.11%
PMFF
x
x
9.6
9.6
1.01%
1.01%
1.01%E406
1.01%
PMAF
x
x
3.8
3.8
0.40%
0.40%
0.40%
11
0.40%
PMCP
5.1
5.1
10.2
1.07%
W ater
360
360
KOH
1
40
40
951.5
56.9%
2.1 %
0.7%
1.0%
0.4%
Total
n"­
WP Potential
A 008
Assume that: 57 wt. % of the process material are VOCs;
100% of the liquid is 0.008 weight fraction HF.
Valve emissions: 171 valves x 0.00039 Ib/hr/valve = 0.067 Ib/hr EE
Flange emissions: 312 flanges x 0.00018 Ib/hr/flange = 0.056 Ib/hr EE
Pump emissions: 2 pumps x 0.00115 Ib/hr/pump 0.002 Ib/hr EE
Total equipment emission rate Ib/hr EE
VOC: 0.125 lb. EE/hr
x 8760 hr/year
x 0,570 lb. VOC/lb. EE
6g ff99? Ib/yr VOC
HF: 0.125 lb. EE/hr
x 8760 hr/year
x 0.008 lb. HF/lb. EE
871 Ib/yr HF
DEQ-CFW 00086566

HFPO Manufacturing Process 2007 Emissions Non -Point Source Emissions
1 Page 14 of 23
B. Equipment Emissions Outside Buildings (Fugitive Emissions)
1. Fugitive Emissions From Distillation System #2
Wrorn W1208078 HFPO Flowsheet:
Material
VOC
HF
Avera e Vessel Contents k /hr
% of
contents
% VOC
% HF
Line 18
Line 23
Total
02
COF2
x
x
PAF
x
x
HFP
x
74.5
73.8
148.3
3.18%
3.18%
HFPO
x
1
95.8
7.7
103.5
2.22%
2.22%
HFA
x
PMFF
x
x
PMAF
x
x
PMCP
5.1
5.1
10.2
0.22%
Toluene
x
2200
2200
4400
94.38%
94.38%
Total I
I
1
1
4662
99.78%
0.00%
Assume that : 100 wt. % of the process material are VOCs (most of the mass is toluene CAS No. 108-88-3)
0 wt. % of the liquid is HF.
Valve emissions: 155 valves x 0.00039 Ib/hr/valve = 0.060 Ib/hr FE
Flange emissions: 300 flanges x 0.00018 Ib/hr/flange = 0.054 Ib/hr FE
Pump emissions: 1 pump x 0.00115 Ib/hr/pump 0.001 Ib/hr FE
Total fugitive emission rate lb/hr FE
VOC: 0.116 lb. FE/hr HF: 0.116 lb. FE/hr
x 8760 hr/year x 8760 hr/year
x 1.00 lb. VOC/lb. FE x 0.0 lb. HF/lb. FE
_ 1012 66� Ib/yr VOC (assume all is toluene) 0: ©Q Ib/yr HF
2 Fugitive Emissions From HFP Storage and Feed
*Assume that : This system contains only HFP, so 100 wt. % of the process material are VOCs
HFP has no potential to form HF, so 0 wt. % of the liquid is HF.
Valve emissions: 120 valves x 0.00039 Ib/hr/valve = 0.047 Ib/hr FE
Flange emissions: 135 flanges x 0,00018 lb/hr/flange = 0.024 Ib/hr FE
Total fugitive emission rate _LQQ71�Ib/hr FE
VOC: 0.071 lb. FE/hr
x 8760 hr/year
x 1.00 lb. VOC/lb. FE
=1 __ .., �_2.2 84{ Ib/yr VOC
3. Fugitive Emissions From Benzene
HF: 0.071 lb. FE/hr
x 8760 hr/year
x 0.0 lb. HF/lb. FE
Liffi22AM Ib/yr HF
Basis: Fugitive emissions are determined via mass balance, i.e. any mass of benzene unaccounted for in the mass balance
will be assumed to be air emissions.
Assume that: Benzene introduced into the process is mostly destroyed by reaction.
Ratio of emissions to benzene used = 1.9 lb emission/368 lb benzene used
(2002) (Future)
Calculations: 1.92 Ibs benezene = 4.62 Ibs Toluene
1126145 kg fresh HFP 2,707,354 kg fresh HFP
Benzene introduced to process: 372 Ibs from SARA 313
Benzene emissions:
372 Ibs from: x 1.90 lb emission
Is 368 lb benzene
E'92Ib benzene emission
DEQ-CFW 00086567

HFPO Manufacturing Process 2007 Emissions Non -Point Source Emissions
Page 15 of 23
4. Fugitive Emissions From Toluene
Basis: Fugitive emissions are determined via mass balance, i.e. any mass of toluene unaccounted for in the mass balance will
I* be assumed to be air emissions.
Assume that: 95% of raw ingredient becomes waste
Mass Balance:
Toluene inventory in process as of January 1:
Toluene added to process:
Toluene inventory in process as of December 31:
Toluene destroyed in process:
Toluene shipped off with product:
Toluene removed from process as a solid waste:
Toluene released to air via permitted stack:
Toluene released to process wastewater:
Toluene released to the ground (spill):
Unaccounted for difference in mass:
+ 3184 lb
+ lb
3715 lb
0 lb
151 lb injected into product
0 lb
0 lb
- 0 lb
lb toluene = 2143 lb VOC
In section B-1, fugitive emissions from distillation system #2, the assumption was made that all of the fugitive
emissions were toluene. As the mass balance above shows the unaccounted for toluene, the amount calculated
in section 3 is extremely conservative. Therefore, for the purpose of toluene and VOC emissions, the amount
actually vented will be reported based on the mass balance calculation.
5. Total Equipment Emissions
Emission Source
Inside Emissions
Outside Emissions
(Stack Emissions)
(Fugitive Emissions)
lb VOC
lb HF
lb VOC
lb HF
-1
Reactor, Distillation Columns, #1 Recycle Tank
92.07
20.35
-2
Distillation System #1
374.49
47.70
A-3
Scrubbing, Dryers, Stripper Column
624.90
8.771
B-1
Distillation System #2
1013
B-2
HFP Storage and Feed
622.84
B-4
Toluene System
2143.00
Total
109=1 46
-: 7E 82
3�7849
0 00
In order to be conservative, the calculated values will be multiplied by a factor of 2.
Conservative amount (total x 2)
Inside Emissions
Outside Emissions
(Stack Emissions)
(Fugitive Emissions)
Ib/yr VOC
I Ib/yr HF
Ib/yr VOC
Ib/yr HF
Total HF emissions: 154 Ibs HF from outside building
+ 0 Ibs HF from inside building
Ibs HF
Total VOCs generated inside building:_ 710.75 lb VOC from Reactor, Distillation Column, #1 Recycle Tank
+ 374.49 lb VOC from Scrubber, Dryers, Stripper Column
+ 624.90 lb VOC from Scrubber, Dryers, Stripper Column
= lb VOC generated (before control device)
Conservative amount (total x 2) lb VOC generated (before control device)
11
DEQ-CFW 00086568

HFPO Manufacturing Process 2007 Emissions Non -Point Source Emissions
Page 16 of 23
II. Maintenance Emissions
Background
During preparation of equipment for maintenance, a vessel is first de -inventoried of liquid (to another process vessel), then
de -pressurized (to a vacuum), then nitrogen is used for a series of pressurize/vent-down cycles until a vessel is fume free.
For the purpose of estimating emissions from vessel preparation, the plant can be broken down into three sections: HFP
Storage and Feed, HFPO Distillation system #2, and everything else. Below are the definitions, assumptions, and
calculations of maintenance emissions for each section.
A. HFP Storage and Feed
The HFP Storage section consists of the two HFP Storage Tanks and the associated equipment to transfer HFP into the
tanks. When maintenance clearing is required for these tanks (scheduled once per year), the liquid inventory is
transferred to the other tank, the vapors are compressed into the tank (down to 10 psig), and then the residue is
evacuated to the Nafion® Division Waste Gas Scrubber. The emissions to the atmosphere, therefore, are the HFP vapors
remaining at 10 psig.
Calculations:
PV = nRT
Tank Volume = 3000 gal =
Contents =
Tank pressure = 10 psig =
Tank temperature = ambient = 77 deg F =
R=
401 ft3
100 % HFP (MW=150 Ib/Ibmol)
24.7 psia
537 R
10.73 psia-ft3/Ibmol/R
n = PV/RT
n = 24.7 psia x 401 ft3 «_ 1 72Ibmol HFP
10.7 psia-ft3/Ibmol/R 537 R
1.72 Ibmol HFP x 150 lb HFP lb HFP = 258 lb VOC per cleaning
Ibmol HFP
Clearings/year: Each tank scheduled once per year; two tanks is two clearings/year scheduled; to be conservative,
assume one extra clearing a year, so three clearings performed per year.
VOC from HFP Storage Tank =
B. Disposal of Off -Spec Material
258 lb HFP
x 3 clearings/year
F=':774 Ib/yr HFP
258 lb VOC per cleaning
x 3 clearings/year
'77" Ib/yr VOC
In May 2007, two HFPO cylinders containing high levels of HFA were re -worked through the division WGS (see TA NF-07-
1650). HFA was removed in the HDR facility while the HFPO was vented from the process. VOC emissions resulting
from this work are recorded here.
Cylinder Number
HFPO
(lb)(lb)
HFA
Total Mass
(lb)
35459
12.447 '
448.553
461
414-2-69
888.879
914.121
1803
Total
901.326
1362.674
2264
is
DEQ-CFW 00086569

HFPO Manufacturing Process 2007 Emissions Non -Point Source Emissions
I Page 17 of 23
C. Distillation System #2
When maintenance clearing is required for the column and tanks (scheduled once per year), the liquid inventory is
Aransferred to the other tank, the vapors are compressed into the tank (down to 10 psig), and then the residue is
vacuated to the Nafion® Division Waste Gas Scrubber. For the purposes of these calculations, the average operating
pressure and total volume are used.
Calculations:
PV = nRT
Tank Volume = 3300 gal =
Contents =
(Conservative approximation based off of vessel
contents and volatility of compounds)
Average system pressure = 20 psig =
Average system temperature = 30 deg F =
R=
n = PV/RT
n = 34.7 psia x
10.7 psia-ft3/lbmol/R
2.91 Ibmol material
2.91 Ibmol material
x
441 ft3
490 R
441 ft3
50 % HFP (MW=150 Ib/lbmol)
40 % HFPO (MW=166 lb/Ibmol)
10 % Toluene (MW=92 lb/Ibmol)
34.7 psia
490 R
10.73 psia-ft3/lbmol/R
91 Ibmol material
50 % HFP x 150 lb HFP =2 _ lb HFP
Ibmol HFP
x 40 % HFPO x
166 lb HFPO = 1 lb HFPO
Ibmol HFPO
2.91 Ibmol material x 10 % Toluene x 92 lb Toluene = 27-'lb Toluene
0 Ibmol Toluene
As stated previously, toluene amounts are calculated by mass balance. The amount vented calculated by mass balance
will be used for toluene and VOC emisssions.
Total VOC per cleaning: 218 lb HFP
+ 193 lb HFPO
_412 Ib VOC
Clearings/year: Each tank scheduled once per year; to be conservative, assume one extra clearing a year, so two
clearinas Der year.
VOC from Distillation system #2 =
C
218 lb HFP
x 2 clearings/year
437 Ib/yr HFP
412 lb VOC
x 2 clearin sl ear
_ '�& ' Ib/yr VOC
193 lb HFPO
x 2 clearings/year
( k = 38 )lb/yr HFPO
DEQ-CFW 00086570

HFPO Manufacturing Process 2007 Emissions Non -Point Source Emissions
. i Page 18 of 23
D. 'Rest of the Process"
The rest of the HFPO process contains HFP, HFPO, and both low and high vapor pressure acid fluorides (acid fluorides
re organic compounds which release HF when exposed to the atmosphere). The calculations below do not include the
w-pressure acid fluorides because at temperatures at which the vessels are prepared for maintenance the concentration
of the low vapor pressure acid fluorides is very low. The high vapor pressure acid fluorides are not included because they
are assumed to go to the WGS during decontamination. Though some of the process is located inside buildings, to be
conservative it will be assumed that all emissions are fugitive emissions.
Assume that: Pressure is vapor pressure of HFP/HFPO at ambient temperature (HFP and HFPO have the same
vapor pressures)
Composition HFP to HFPO of vapor space in equipment is equivilant to ratio in line 11 of HFPO
Flowsheet W130878 :
44 wt% HFP
56 wt% HFPO
Calculations:
PV = nRT
Tank Volume = 1100 gal =
Contents =
Average system pressure
Average system temperature = 77 deg F =
R=
147 ft3
44 wt% HFP (MW=150 Ib/lbmol) = 47 mol% HFP
56 wt% HFPO (MW=166 Ib/lbmol) = 53 mol% HFPO
100 Asia
537 R
10.73 psia-ft3/ibmol/R
n = PWRT
n = 100 psia x 147 ft3, 55 Ibmol material
10.7 psia43/lbmol/R 537 R
2.55 Ibmol material x 47 % HFP x 150 lb HFP = 18.0_ Ib HFP
Ibmol HFP
2.55 Ibmol material x 53 % HFPO x 166 lb HFPO = 224.5_ lb HFPO
Ibmol HFPO
Total VOC per cleaning: 179.9 lb HFP
+ 224.5 lb HFPO
40 3 Ib VOC
Clearings/year: Each tank scheduled once per year; to be conservative, assume one extra clearing per year, so two
clearings per year.
180 lb HFP 224.5 lb HFPO
x 2 clearings/year x 2 clearings/year
Ib/yr HFP - b.9_ Ib/yr HFPO
VOC from 'Rest of the Process" _
404.3 lb VOC
x 2 clearings/year
­ " Ib/yr VOC
DEQ-CFW 00086571

HFPO Manufacturing Process 2007 Emissions
E. Total fugitive Emissions from Maintenance Work
Non -Point Source Emissions
Page 19 of 23
ID
Source
Ib/yr HFP
Ib/yr HFPO
Ib/yr VOC
II -A JHFP Storage and Feed
774
774,
II-B Off -spec HFPO Disposal
0
901
901:'
II-C
I Distillation System #2
437
387
823
11-D
"Rest of the System"
360
449
809
Total
1,4701
1,72
3;307
III. Non -Point Source VOC Emission Summary
Nafion®
Compound
COF2
Point -Source
Emissions
Ibs
2,155
Stack Emissions
Fugitive Emissions
Total
Inside Emissions
(Ibs)
49
Outside
Emissions (Ibs)
169
Maintenance
Emissions (Ibs)
Ibs
21372
PAF
1,526
35
119
1,680
TFF
428
10
33
471
TAF
428
10
33. -
471
HFP
65,256
1475
5108
1570
73,410
HFPO
26,751
605
2094
1737
Benzene
1.92
2
Toluene
2143
Total
96,544
1 21183
9,702
3,307
111,736
Note: Speciated emissions (except for benzene, toluene, and maintenance emissions) were estimated by assuming that
each compound's emission concentration was equal to the compound's stack emissions fraction of the total stack
emissions.
For example: the stack emission of PAF was 1,526 Ibs
with the total stack emission of VOCs being 96,544 Ibs
The total outside fugitive emission (minus benzene & toluene) was 7,556.98 Ibs VOC
1,526 Ibs PAF x 7,556.98 fugitive VOC = 119 lb fugitive PAF emissions
96,544 Ibs VOC
Ul
DEQ-CFW 00086572

HFPO Manufacturing Process 2007 Emissions Accidental Releases
Page 20 of 23
•
Accidental Releases to Atmosphere
A. IR-2007-57 Date: 3/13/2007
Material Released: KOH t - ' r
Quantity Released: I—
I
Quantity VOC Released:
50.0 Ibs KOH/water
0.0 lb VOC
B. IR-2007-68 Date: 6/22/2007
Material Released:0��
Quantity Released:
Quantity VOC Released:
0.1 Ibs COF2
0.1 lb VOC
F. Total Emissions from Accidental Releases
� t, CAS W 353 50;4
Source
lb DCM
lb HFP
lb HFPO
lb COF2
lb PAF
Ib HFA
Ib Toluene
Ib/ r VOC
Ib/ r HF
A.1
IR-2007-57
0.0
0
0.0
0
0
0
0.0
0.0
0
B.1
IR-2007-68
0.0
0.0
0.1
0.1
0.0
0.0
0.1
0.1
0
0.0
0
0.0
0
0.0
0.1
0.0
Total
DEQ-CFW 00086573